TW201825404A - Auto-activated ion-exchange resin column system for precious metal - Google Patents
Auto-activated ion-exchange resin column system for precious metal Download PDFInfo
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- TW201825404A TW201825404A TW105127177A TW105127177A TW201825404A TW 201825404 A TW201825404 A TW 201825404A TW 105127177 A TW105127177 A TW 105127177A TW 105127177 A TW105127177 A TW 105127177A TW 201825404 A TW201825404 A TW 201825404A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Treatment Of Water By Ion Exchange (AREA)
Abstract
Description
本發明涉及貴金屬回收設備領域,具體是一種貴金屬自動活化離子交換樹脂塔組系統。The invention relates to the field of precious metal recovery equipment, in particular to a precious metal automatic activation ion exchange resin tower system.
現有貴金廢液中吸附貴金屬離子交換樹脂塔組主要為一台水泵,一個儲存槽,含貴金廢液經過一個或多個樹脂塔正洗時達到吸附貴金屬,產生廢水排放。正洗時人工切換圖1中的閥門13a,閥門15a,閥門22a,閥門26a開啟,其他閥門關閉,正洗經一段時間後樹脂塔內產生懸浮物污染造成樹脂層堵塞需靠人工反洗,反洗時人工切換如圖2所示的閥門11a,閥門14a,閥門21a,閥門24a開啟,其他閥門關閉,反洗時產生廢水排放,如情況嚴重需將樹脂取出清洗後再裝填入塔內。The existing precious metal ion exchange resin tower group for adsorbing precious metal is mainly a water pump and a storage tank, and the precious metal waste liquid reaches the adsorption of precious metal when it is being washed by one or more resin towers, thereby generating waste water discharge. Manually switch valve 13a, valve 15a, valve 22a, valve 26a in Figure 1 while other valves are closed, and other valves are closed. After a period of positive washing, suspended matter contamination in the resin tower will cause the resin layer to become clogged. During washing, the valve 11a, valve 14a, valve 21a, and valve 24a shown in Figure 2 are manually switched, and other valves are closed. Waste water is discharged during backwashing. If the situation is serious, the resin must be removed and cleaned before being loaded into the tower.
因只有一台水泵及一個前端含貴金水槽,當樹脂需預處理及受污染時(如矽化物,有機物,懸浮物等)單靠習知技術及人工正反洗是無法達到樹脂再生及處理樹脂污染問題,因新樹脂需預處理,新樹脂常含有少量有機低聚物及無機雜質,在使用初期會逐漸溶解釋放,單靠習知技術及人工正反洗,是無法保證樹脂獲得充分再生與恢復樹脂吸附能力,導致後續處理貴金屬流失。當樹脂受污染,懸浮物堵塞樹脂層的空隙中,從而增大其水流阻力,也會覆蓋在樹脂顆粒的表面,因而降低其工作交換容量,單靠習知技術及人工正反洗是無法在適當時間科學有效達到固定流量,甚至造成水泵損毀及貴金屬流失。因習知技術為人工正反洗只有一個水泵及一個前端含貴金水槽,當正洗剛啟動時水流不穩定,有部分含貴金廢水會經過樹脂層排出到廢水排放,當反洗時因樹脂為非密實狀態,有大部分含貴金廢水會經過樹脂層排出到廢水排放,導致處理貴金屬流失。習知技術為人工正反洗,在各個不同貴金廢水及外在環境下,造成樹脂污染程度均不同,當人工正反洗時,很難有效即時處理因樹脂污染而造成水流速不穩定造成貴金屬流失,而且耗費人工且效率不佳。Because there is only one water pump and one front end tank containing precious gold, when the resin needs to be pretreated and contaminated (such as silicide, organic matter, suspended matter, etc.), the regeneration and treatment of the resin cannot be achieved by conventional techniques and manual forward and reverse washing. Resin pollution. Because new resins require pretreatment, new resins often contain a small amount of organic oligomers and inorganic impurities, and they will gradually dissolve and release during the initial use. Relying on conventional techniques and manual backwashing alone cannot ensure that the resin is fully regenerated. And restore the resin adsorption capacity, leading to the loss of precious metals in subsequent processing. When the resin is contaminated, suspended matter blocks the gaps in the resin layer, which increases its resistance to water flow, and also covers the surface of the resin particles, thus reducing its work exchange capacity. It is impossible to rely on conventional techniques and manual backwashing alone. Scientifically and effectively achieve a fixed flow rate at the appropriate time, and even cause damage to the pump and loss of precious metals. Because of the conventional technology, there is only one water pump and one front-end gold-containing water tank for manual forward and reverse washing. When the forward washing is just started, the water flow is unstable, and some precious gold-containing wastewater will be discharged to the wastewater discharge through the resin layer. In a non-compact state, most of the precious metal-containing wastewater will be discharged to the wastewater discharge through the resin layer, leading to the loss of treated precious metals. The conventional technique is manual forward and reverse washing, which causes different degrees of resin pollution in different precious gold wastewater and external environments. When manual forward and reverse washing, it is difficult to effectively deal with the instability of water flow caused by resin pollution. The loss of precious metals is labor-intensive and inefficient.
總結以上習知技術問題:(1)新樹脂預處理無法保證樹脂獲得充分再生,導致後續處理貴金屬流失;(2)當樹脂受污染無法在適當時間科學有效達到固定流量,甚至造成水泵損毀及貴金屬流失;(3)正反洗交替時樹脂為非密實狀態,導致貴金屬流失;(4)耗費人工且效率不佳,甚至造成人工誤操作。Summarize the above-mentioned conventional technical problems: (1) Pre-treatment of new resins cannot guarantee sufficient regeneration of resins, leading to the loss of precious metals in subsequent processing; (2) When the resins are contaminated, it cannot scientifically and effectively reach a fixed flow rate at an appropriate time, and even cause pump damage and precious metals Loss; (3) Resin is in a non-compact state when the front and back washing are alternated, leading to the loss of precious metals; (4) It is labor-intensive and inefficient, and even causes manual misoperation.
因此,為了克服習知技術中存在的不足,本發明的目的即在提供一種貴金屬自動活化離子交換樹脂塔系統。Therefore, in order to overcome the shortcomings in the conventional technology, the object of the present invention is to provide a system for automatically activating an ion exchange resin column of precious metals.
為解決上述技術問題,本發明的一種貴金屬自動活化離子交換樹脂塔系統,包括含貴金廢液儲存槽、正洗泵、排放迴路及多個樹脂塔,正洗泵通過正洗管連接樹脂塔沖洗迴路,樹脂塔沖洗迴路與各個樹脂塔的頂部連通;各個樹脂塔底部分別通過管路連接循環迴路,循環迴路與樹脂塔沖洗迴路連通,還包括樹脂活化劑儲存桶,其通過管路與反洗泵連通,反洗泵通過反洗管與循環迴路連通,而反洗管和正洗管分別與正反洗電動三通閥的其中兩個介面連接,正反洗電動三通閥的另一個介面與排放迴路連通,而循環迴路也與反洗管連通。設置反洗泵及反洗管,從各個樹脂塔底部向上沖洗,能夠使得樹脂被充分沖洗活化。In order to solve the above technical problems, a precious metal automatic activated ion exchange resin tower system of the present invention includes a precious liquid waste storage tank, a forward washing pump, a discharge circuit, and a plurality of resin towers. The forward washing pump is connected to the resin tower through a forward washing pipe. The flushing circuit, the resin tower flushing circuit communicates with the top of each resin tower; the bottom of each resin tower is connected to the circulation circuit through a pipeline, and the circulation circuit communicates with the resin tower flushing circuit, and also includes a resin activator storage barrel, which is connected with The wash pump is connected. The backwash pump communicates with the circulation circuit through the backwash tube. The backwash tube and the forward wash tube are connected to two interfaces of the three-way valve of the forward and backwash, and the other interface of the three-way valve of the forward and reverse wash. It is connected to the drain circuit, and the circulation circuit is also connected to the backwash pipe. A backwash pump and a backwash tube are set, and the resin is flushed upward from the bottom of each resin tower, so that the resin can be fully washed and activated.
進一步,還包括壓縮空氣迴路,壓縮空氣迴路與各個樹脂塔底部連通,在壓縮空氣迴路上還設置有壓縮空氣調節閥以及電磁閥。氣體由下而上地將樹脂衝擊擾動,使樹脂處於懸浮松狀態,樹脂表面截留物即能得到反洗水泡的充分洗脫。Further, it further comprises a compressed air circuit, the compressed air circuit is in communication with the bottom of each resin tower, and the compressed air circuit is further provided with a compressed air regulating valve and a solenoid valve. The gas shocks the resin from the bottom to the top, so that the resin is in a suspended loose state, and the retentate on the surface of the resin can fully elute the backwash blisters.
進一步,正反洗電動三通閥與正洗管和反洗管之間分別設有電動閥,而在這兩個電動閥的週邊還設有備用迴路,備用迴路與正洗管、反洗管以及排放迴路連通,在備用迴路與正洗管、反洗管連接的管路上分別設有電動閥。當正反洗電動三通閥出現故障不能工作時,調整備用迴路上的電動閥的啟閉,以及正反洗電動三通閥和正洗管、反洗管之間的電動閥,即可啟動備用迴路,繞過正反洗電動三通閥,此時可對正反洗電動三通閥進行維修或者更換。Further, an electric valve is respectively provided between the forward and reverse washing electric three-way valve and the forward washing pipe and the reverse washing pipe, and a backup circuit is provided around the two electric valves. And the drain circuit is communicated, and electric valves are respectively provided on the pipelines connecting the backup circuit to the forward washing pipe and the reverse washing pipe. When the forward and reverse washing electric three-way valve fails to work, adjust the opening and closing of the electric valve on the standby circuit, and the electric valve between the forward and reverse washing electric three-way valve and the forward and reverse washing pipe and backwashing pipe to start the backup. The circuit bypasses the positive and negative washing electric three-way valve. At this time, the positive and negative washing electric three-way valve can be repaired or replaced.
進一步,排放迴路末端並聯設置有排水循環電動三通閥,該排水循環電動三通閥的其中兩個介面連接排放迴路,另外一個介面通過回水管路連接含貴金廢液儲存槽。通過切換排水循環電動三通閥,可選擇排放迴路是與含貴金廢液貯存槽接通,還是直接排放廢液。Further, a drain circulation electric three-way valve is provided in parallel at the end of the drain circuit. Two interfaces of the drain circulation electric three-way valve are connected to the drain circuit, and the other interface is connected to the precious liquid waste storage tank through a return water pipe. By switching the drain circulation electric three-way valve, you can choose whether the discharge circuit is connected to the storage tank containing precious gold waste liquid or directly discharge the waste liquid.
進一步,排放迴路與回水管路之間通過設置有電動閥的管路連通,可直接繞過排水循環電動三通閥,可作為備用,排水循環電動三通閥與排放迴路以及回水管路連接的介面處設置電動閥,在排放迴路末端設置電動閥,通過設置各個電動閥的通斷,控制廢液的流向。Further, the discharge circuit and the return water pipeline are communicated through a pipeline provided with an electric valve, which can directly bypass the drainage circulation electric three-way valve, and can be used as a backup. An electric valve is set at the interface, and an electric valve is set at the end of the discharge circuit. The on-off of each electric valve is set to control the flow of waste liquid.
進一步,樹脂塔沖洗迴路包括多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,多條管路在各個樹脂塔上方入口匯成一路,循環迴路與樹脂塔沖洗迴路的其中一條管路連通,循環迴路與其中一條管路連通的部位在該管路上相鄰兩個電動閥之間的位置。Further, the resin tower flushing circuit includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin towers. The multiple pipelines are merged into an inlet above each resin tower. A pipeline is connected, and the position where the circulation circuit communicates with one of the pipelines is between two adjacent electric valves on the pipeline.
進一步,循環迴路包括多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,其中一條管路與樹脂塔沖洗迴路連通,多條管路在各個樹脂塔底部匯成一路並與各個樹脂塔底部分別連通。Further, the circulation loop includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin tower, and one of the pipelines communicates with the resin tower flushing circuit, and the plurality of pipelines merge into one at the bottom of each resin tower and communicate with The bottoms of the respective resin towers are respectively communicated.
進一步,在正洗管與反洗管上均依次設有調節閥、上下限流量計開關、止回閥。Further, a regulating valve, an upper and lower limit flow meter switch, and a check valve are sequentially arranged on the forward washing pipe and the reverse washing pipe.
進一步,在正洗泵與反洗泵之間設有連通管,在連通管上設有切換閥。當其中一個泵出現故障時,通過切換閥切換,即可實現用另一個泵替換出現故障的泵,在不影響生產的同時即可對出現故障的泵進行更換。Further, a communication pipe is provided between the forward washing pump and the backwash pump, and a switching valve is provided on the communication pipe. When one of the pumps fails, the switching of the switching valve can be used to replace the failed pump with the other pump, and the failed pump can be replaced without affecting production.
進一步,在排放迴路上設有止回閥,防止廢液倒流至樹脂塔內。Further, a check valve is provided on the discharge circuit to prevent waste liquid from flowing back into the resin tower.
有益效果:本發明的一種貴金屬自動活化離子交換樹脂塔系統,可解決習知技術存在問題:(1)新樹脂預處理,使其充分再生,後續處理貴金屬提高樹脂交換量;(2)樹脂使用後降低受污染程度及提高貴金屬樹脂交換量;(3)正反洗交替時貴金屬不流失;(4)利用自動控制處理工作流程及原理,有效科學管理替代人工作業,進而提高效率。Beneficial effects: A noble metal automatic activation ion exchange resin tower system according to the present invention can solve the problems of the conventional technology: (1) pretreatment of new resin to make it fully regenerate, and subsequent treatment of noble metal to increase the resin exchange amount; (2) use of resin It will reduce the pollution level and increase the amount of precious metal resin exchange; (3) the precious metal will not be lost during the forward and reverse washing; (4) the use of automatic control processing workflow and principles, and effective scientific management to replace manual operations, thereby improving efficiency.
本發明與習知技術相比具有的優點:因本發明前期新樹脂預處理及使用中流量穩定,且自動去除樹脂受污染程度,提高吸附貴金的效能及提高樹脂交換量,保證了出水不超標。因本發明不需人員操作,大大節省人工維護費及因人員誤操作或維護不周造成設備損壞及貴金流失。因本發明不會因樹脂污染後造成出水超標,所以可節省新樹脂更換頻率而達到節省樹脂用量。因本發明採用自動控制 ,採用科學指令引數可有效調整如正反洗時間,壓縮空氣壓力及流量,反洗活化水槽內活化劑及預估樹脂含貴金百分比及收料時間等,對不同的含貴金廢液有不同參數設定及控制。Compared with the conventional technology, the invention has the advantages: because the new resin in the early stage of the invention has a stable flow during pretreatment and use, and automatically removes the degree of resin contamination, improves the efficiency of adsorbing precious gold, and increases the resin exchange amount, ensuring that the effluent is not Exceeding standards. Because the present invention does not require human operation, it greatly saves labor maintenance costs and equipment damage and loss of precious gold due to personnel's misoperation or poor maintenance. Because the present invention does not cause the effluent to exceed the standard due to resin pollution, it can save the frequency of new resin replacement and achieve savings in resin consumption. Because the present invention adopts automatic control and adopts scientific instruction parameters, it can effectively adjust such as forward and reverse washing time, compressed air pressure and flow rate, backwash activated activator in the water tank and estimated resin containing precious gold percentage and receiving time, etc. The precious gold-containing waste liquid has different parameter settings and controls.
下面結合附圖對本發明作更進一步的說明。The present invention will be further described below with reference to the drawings.
如圖3、圖4所示的一種貴金屬自動活化離子交換樹脂塔系統,包括含貴金廢液儲存槽1、正洗泵5、排放迴路61及多個樹脂塔,正洗泵5通過正洗管9連接樹脂塔沖洗迴路7,樹脂塔沖洗迴路7與各個樹脂塔的頂部連通;各個樹脂塔底部分別通過管路連接循環迴路8,循環迴路8與樹脂塔沖洗迴路7連通,還包括樹脂活化劑儲存桶2,其通過管路與反洗泵6連通,反洗泵6通過反洗管10與循環迴路8連通,而反洗管10和正洗管9分別與正反洗電動三通閥3的其中兩個介面連接,正反洗電動三通閥3的另一個介面與排放迴路61連通,而循環迴路8也與反洗管10連通。在正洗管9上順液體流向依次設置有調節閥91、上下限流量計開關93、取樣口92以及止回閥94,反洗管10上順液體流向依次設置調節閥101、上下限流量計開關102、取樣口103以及止回閥104。在正洗泵5與反洗泵6之間設置連通管64、52,在連通管64、52上安裝有切換閥。當其中一個泵出現故障時,通過切換閥切換,即可實現用另一個泵替換出現故障的泵,在不影響生產的同時即可對出現故障的泵進行更換。在排放迴路61上設置有止回閥62,防止廢液倒流至樹脂塔內。設置反洗泵6及反洗管10,從各個樹脂塔底部向上沖洗,能夠使得樹脂被充分沖洗活化。本發明的系統還包括壓縮空氣迴路51,壓縮空氣迴路51與各個樹脂塔底部連通,在壓縮空氣迴路51上還設置有壓縮空氣調節閥以及電磁閥,用於調節壓縮空氣的通斷以及氣體流量。氣體由下而上地將樹脂衝擊擾動,使樹脂處於懸浮松狀態,樹脂表面截留物即能得到反洗水的充分洗脫。正反洗電動三通閥3與正洗管9和反洗管10之間分別設置電動閥31和電動閥32,而在這兩個電動閥的週邊還設置備用迴路4,備用迴路4與正洗管9、反洗管10以及排放迴路61連通,在備用迴路4與正洗管9、反洗管10連接的管路上分別設置有電動閥41和電動閥32。當正反洗電動三通閥3出現故障不能工作時,調整備用迴路4上的各個電動閥的啟閉,以及正反洗電動三通閥3和正洗管9、反洗管10之間的電動閥31、電動閥32,即可啟動備用迴路4,繞過正反洗電動三通閥3,此時可對正反洗電動三通閥3進行維修或者更換。排放迴路61末端並聯設置有排水循環電動三通閥71,該排水循環電動三通閥71的其中兩個介面連接排放迴路61,另外一個介面通過回水管路72連接含貴金廢液儲存槽1。通過切換排水循環電動三通閥71,可選擇排放迴路61是與含金廢液貯存槽1接通,還是直接排放廢液。排放迴路61與回水管路72之間通過設置有電動閥73的管路連通,可直接繞過排水循環電動三通閥71,可作為備用,排水循環電動三通閥71與排放迴路61連接的介面處設置有電動閥76,排水循環電動三通閥71與回水管路72連接的介面處設置電動閥75,在排放迴路61末端設置電動閥74,通過設置各個電動閥的通斷,控制廢液的流向。樹脂塔沖洗迴路7包括多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,多條管路在各個樹脂塔上方入口匯成一路,循環迴路8與樹脂塔沖洗迴路7的其中一條管路連通,循環迴路8與其中一條管路連通的部位在該管路上相鄰兩個電動閥之間的位置。循環迴路8包括多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,其中一條管路與樹脂塔沖洗迴路7連通,多條管路在各個樹脂塔底部匯成一路並與各個樹脂塔底部分別連通。A noble metal automatic activation ion exchange resin tower system as shown in FIG. 3 and FIG. 4 includes a precious liquid waste storage tank 1, a forward washing pump 5, a discharge circuit 61, and a plurality of resin towers. The forward washing pump 5 passes forward washing The pipe 9 is connected to the resin tower flushing circuit 7, the resin tower flushing circuit 7 communicates with the top of each resin tower; the bottom of each resin tower is connected to the circulation circuit 8 through a pipeline, and the circulation circuit 8 communicates with the resin tower flushing circuit 7, and also includes resin activation The agent storage barrel 2 communicates with the backwash pump 6 through a pipeline, the backwash pump 6 communicates with the circulation circuit 8 through the backwash tube 10, and the backwash tube 10 and the forward wash tube 9 are respectively connected to the forward and backwash electric three-way valve 3 Two of the interfaces are connected, the other interface of the forward and reverse washing electric three-way valve 3 is in communication with the drain circuit 61, and the circulation circuit 8 is also in communication with the backwash pipe 10. A regulating valve 91, an upper and lower limit flow meter switch 93, a sampling port 92, and a check valve 94 are sequentially provided on the forward washing pipe 9 in the order of the liquid flow direction, and an adjusting valve 101 and the upper and lower limit flow meters are sequentially provided on the back washing pipe 10 in the liquid direction. Switch 102, sampling port 103, and check valve 104. Communication pipes 64 and 52 are provided between the forward washing pump 5 and the backwash pump 6, and switching valves are installed on the communication pipes 64 and 52. When one of the pumps fails, the switching of the switching valve can be used to replace the failed pump with the other pump, and the failed pump can be replaced without affecting production. The discharge circuit 61 is provided with a check valve 62 to prevent waste liquid from flowing back into the resin tower. A backwash pump 6 and a backwash pipe 10 are provided to flush upward from the bottom of each resin tower, so that the resin can be fully flushed and activated. The system of the present invention further includes a compressed air circuit 51, which is in communication with the bottom of each resin tower. The compressed air circuit 51 is also provided with a compressed air regulating valve and a solenoid valve for regulating the on-off and gas flow of the compressed air. . The gas shocks the resin from bottom to top, so that the resin is in a suspended loose state, and the retentate on the resin surface can be fully eluted by the backwash water. An electric valve 31 and an electric valve 32 are respectively provided between the forward and reverse washing electric three-way valve 3 and the forward washing pipe 9 and the reverse washing pipe 10, and a backup circuit 4 is provided around the two electric valves. The washing pipe 9, the back washing pipe 10, and the discharge circuit 61 communicate with each other, and the electric valve 41 and the electric valve 32 are provided on the pipelines connecting the standby circuit 4 to the forward washing pipe 9 and the back washing pipe 10, respectively. When the forward and reverse washing electric three-way valve 3 fails to work, adjust the opening and closing of each electric valve on the standby circuit 4 and the electric power between the forward and reverse washing electric three-way valve 3 and the forward washing pipe 9 and the reverse washing pipe 10. The valve 31 and the electric valve 32 can start the backup circuit 4 and bypass the forward and reverse washing electric three-way valve 3. At this time, the forward and reverse washing electric three-way valve 3 can be repaired or replaced. A drain circulation electric three-way valve 71 is arranged in parallel at the end of the drain circuit 61. Two interfaces of the drain circulation electric three-way valve 71 are connected to the drain circuit 61, and the other interface is connected to the precious liquid waste storage tank 1 through a return water pipe 72. . By switching the drainage circulation electric three-way valve 71, it is possible to select whether the discharge circuit 61 is connected to the gold-containing waste liquid storage tank 1 or directly discharges the waste liquid. The drain circuit 61 and the return water line 72 communicate with each other through a pipeline provided with an electric valve 73, which can directly bypass the drainage circulation electric three-way valve 71 and can be used as a backup. The drainage circulation electric three-way valve 71 is connected to the drainage circuit 61. The interface is provided with an electric valve 76, the electric circuit of the drainage circulation electric three-way valve 71 and the return water line 72 are provided with an electric valve 75, an electric valve 74 is provided at the end of the discharge circuit 61, and the waste is controlled by setting the on and off of each electric valve. The flow of liquid. The resin tower flushing circuit 7 includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin tower. The multiple pipelines are merged into the inlet above each resin tower. The circulation circuit 8 and the resin tower flushing circuit 7 One of the pipelines is in communication, and the position where the circulation circuit 8 communicates with one of the pipelines is between the two adjacent electric valves on the pipeline. The circulation loop 8 includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin tower. One of the pipelines communicates with the resin tower flushing circuit 7, and a plurality of pipelines merge into one at the bottom of each resin tower and communicate with The bottoms of the respective resin towers are respectively communicated.
下面通過具體實施例對上述發明內容進行進一步的解釋說明。The above-mentioned summary of the invention is further explained below through specific embodiments.
本發明在工作中,主要包括以下工作流程:The work of the present invention mainly includes the following work processes:
如圖4及圖中箭頭所指流向所示,樹脂塔內前期新樹脂預處理流程:使用樹脂活化劑儲存桶2裝純水,正反洗電動三通閥3和其周邊的電動閥切換為電動閥31,電動閥32開、電動閥41、電動閥42關,啟動與壓縮空氣迴路51連接的空氣源,向樹脂塔A和樹脂塔B內通入壓縮空氣數秒後,再啟動反洗泵6抽樹脂活化劑儲存桶2內純水反洗對樹脂塔A和樹脂塔B內的樹脂層,利用水泡原理將樹脂展開率達90%以上,停止輸入壓縮空氣後數秒再將反洗泵6停止,此時可將內部空氣利用水排出,再使用含貴金廢液儲存槽1裝純水,如圖3及圖中的箭頭所指流向所示,正洗泵5抽含貴金廢液儲存槽1內的純水正洗樹脂塔A和樹脂塔B內的樹脂層,期間利用PLC控制正反洗電動三通閥3及排水循環電動三通閥71切換正洗排水時為排入含貴金廢液儲存槽1後循環,反洗排水入樹脂活化劑儲存桶2後循環,期間正反洗流量如超出上下限時,上下限流量計開關93或上下限流量計開關102報警,反覆2-3次正反洗,直到出水清晰,無氣味,無細碎樹脂為止,樹脂層密實後進入生產吸附貴金離子。As shown in the flow direction indicated by the arrow in the figure 4 and the figure, the pre-stage new resin pretreatment process in the resin tower: using a resin activator storage bucket 2 for pure water, and washing the electric three-way valve 3 and its surrounding electric valves to Electric valve 31, electric valve 32 is open, electric valve 41, electric valve 42 are closed, the air source connected to the compressed air circuit 51 is activated, and compressed air is introduced into resin tower A and resin tower B for a few seconds, and then the backwash pump is started 6 pump resin activator storage tank 2 backwash pure water in resin tower A and resin tower B, using the principle of blister to expand the resin expansion rate of more than 90%, stop the input of compressed air and then backwash the pump 6 seconds Stop, at this time, the internal air can be discharged with water, and then use the precious gold-containing waste liquid storage tank 1 for pure water. As shown by the flow direction indicated by the arrow in Figure 3 and the figure, the positive washing pump 5 pumps the precious gold-containing waste liquid. The pure water in the storage tank 1 is used to wash the resin layers in the resin tower A and resin tower B. During the control of the forward and reverse washing electric three-way valve 3 and the drainage cycle electric three-way valve 71 by PLC, the discharge is included in the discharge. Precious gold waste liquid storage tank 1 circulates, backwash and drain into resin activator storage bucket 2 During the period when the positive and reverse washing flow exceeds the upper and lower limits, the upper and lower limit flowmeter switch 93 or the upper and lower limit flowmeter switch 102 alarms and repeats the forward and reverse washing 2-3 times until the water is clear, odorless, and no fine resin, and the resin layer is dense. After entering the production to adsorb precious gold ions.
如圖3所示,正常生產流程:含貴金廢液儲存槽1內水位到啟動上限時,正反洗電動三通閥3切換正洗位置,即電動閥32開,電動閥31開、電動閥41、電動閥42關,排水循環電動三通閥71切換循環位置,即,電動閥75、電動閥76開、電動閥74、電動閥73關閉。上述設置完成後,正洗泵5啟動,抽取含貴金廢液儲存槽1內的水數秒後,排水循環電動三通閥71切換到廢水排放位置,即電動閥75關閉,電動閥76打開,正洗時間可調整進行吸附貴金屬離子時間,當時間到設定正洗時間後正洗泵5停止,如圖4所示,正反洗電動三通閥3切換反洗位置,即電動閥31,電動閥32開、電動閥41、電動閥42關,排水循環電動三通閥71切換循環至含貴金廢液儲存槽1,即電動閥74、電動閥73關閉,電動閥76,電動閥75開啟,此時啟動與壓縮空氣迴路51連接的空氣源,壓縮空氣進入各個樹脂塔內數秒後啟動反洗泵6抽樹脂活化劑儲存桶2內的純水反洗各個樹脂塔內的樹脂層,數秒後排水循環電動三通閥71切換到廢水排放位置,即切換到電動閥75、電動閥76開,電動閥73、電動閥74關閉,反洗時間可調整,壓縮空氣迴路51的電磁閥提前數秒停止壓縮空氣入各個樹脂塔,此時可將各樹脂塔內部的空氣利用水排出,當時間到達設定反洗時間後反洗泵6停止,當含貴金廢液儲存槽1內水位未到停止下限時,重複正洗正常生產, 當含金廢液儲存槽1內水位到達停止下限時,系統停止工作並待機,下次水位到達啟動上限延續前期時間控制動作及參數,期間正反洗流量如超出上下限流量時,上下限流量計開關93或上下限流量計開關102報警。As shown in Figure 3, the normal production process: when the water level in the precious liquid-containing waste storage tank 1 reaches the starting limit, the forward and reverse washing electric three-way valve 3 switches the forward washing position, that is, the electric valve 32 opens, the electric valve 31 opens, and the electric The valve 41 and the electric valve 42 are closed, and the drainage cycle electric three-way valve 71 switches the cycle position, that is, the electric valve 75, the electric valve 76 is opened, the electric valve 74, and the electric valve 73 are closed. After the above setting is completed, the forward washing pump 5 is started, and the water in the precious liquid containing waste liquid storage tank 1 is pumped for a few seconds. The drain circulation electric three-way valve 71 is switched to the waste water discharge position, that is, the electric valve 75 is closed and the electric valve 76 is opened. The forward washing time can be adjusted to adsorb precious metal ions. When the time reaches the set positive washing time, the forward washing pump 5 stops. As shown in FIG. 4, the forward and reverse washing electric three-way valve 3 switches the reverse washing position, that is, the electric valve 31, which is electrically operated. Valve 32 is open, electric valve 41, electric valve 42 are closed, and the drainage circulation electric three-way valve 71 is switched to the precious liquid waste storage tank 1, that is, electric valve 74, electric valve 73 are closed, electric valve 76, and electric valve 75 are opened At this time, the air source connected to the compressed air circuit 51 is started. After the compressed air enters each resin tower for several seconds, the backwash pump 6 is started to pump pure water in the resin activator storage bucket 2 to backwash the resin layers in each resin tower for several seconds. The rear drainage cycle electric three-way valve 71 is switched to the waste water discharge position, that is, the electric valve 75, the electric valve 76 is opened, the electric valve 73, the electric valve 74 are closed, the backwash time can be adjusted, and the solenoid valve of the compressed air circuit 51 is advanced by a few seconds. Stop compacting The air enters each resin tower. At this time, the air inside each resin tower can be exhausted by water. When the time reaches the set backwash time, the backwash pump 6 stops. When the water level in the precious liquid waste storage tank 1 does not reach the lower limit of stopping. , Repeat the normal washing and normal production. When the water level in the gold-containing waste liquid storage tank 1 reaches the lower limit of stopping, the system stops working and waits. The next time the water level reaches the upper limit of activation, continue the previous time control actions and parameters. When the lower limit flow rate is reached, the upper or lower limit flow meter switch 93 or the upper or lower limit flow meter switch 102 alarms.
本發明採用兩個水槽:含貴金廢液儲存槽1以及樹脂活化劑儲存桶2,可作為新樹脂預處理所用水槽,在正常生產時自動活化樹脂及防止貴金流失,與習知技術相比,習知技術技術採用一個含貴金廢液儲存槽,無法自動進行新樹脂預處理及正常生產時無法活化樹脂,因此造成貴金流失。The invention adopts two water tanks: a storage tank 1 containing waste liquid containing precious gold and a storage tank 2 for resin activator, which can be used as a water tank for pretreatment of new resin, which automatically activates the resin during normal production and prevents the loss of precious gold, which is in accordance with the conventional technology In contrast, the conventional technology uses a storage tank for waste liquid containing precious gold, which cannot automatically perform new resin pretreatment and cannot activate the resin during normal production, thus causing the loss of precious gold.
本發明採用正洗泵5與反洗泵6的組合,正常生產時,正洗泵用於正洗流程,反洗泵用於反洗流程,採用自動化方式,兩個水泵可替代備用,而習知技術只採用一個正洗水泵,能夠正常生產正洗,但需要人工切換閥門反洗,且無備用泵,在正洗水泵損壞或者故障時,無替代,影響工作進度。The present invention adopts a combination of a forward washing pump 5 and a reverse washing pump 6. In normal production, the forward washing pump is used for the forward washing process, and the reverse washing pump is used for the reverse washing process. In an automated manner, two water pumps can be used instead of standby. Known technology uses only one forward washing pump, which can produce normal washing normally, but requires manual switching of the valve for back washing, and there is no backup pump. When the forward washing pump is damaged or malfunctions, there is no replacement, which affects the work progress.
本發明採用壓縮空氣結構,使用壓縮空氣迴路51連接壓縮空氣源以及兩個樹脂塔,可自動設定配合反洗泵6運行,形成水泡原理降低樹脂受污染程度,保證在正洗時流量穩定提高吸附貴金的效能及提高樹脂交換量,保證了出水不超標,而原有技術無此功能。The invention adopts a compressed air structure, and uses a compressed air circuit 51 to connect a compressed air source and two resin towers, which can be automatically set to operate in conjunction with the backwash pump 6 to form a water bubble principle to reduce the degree of resin contamination and ensure that the flow rate is stable and the adsorption is increased during forward washing The efficiency of precious gold and the increase of resin exchange volume ensure that the effluent does not exceed the standard, but the original technology does not have this function.
樹脂塔沖洗迴路7中包含的多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,管路的數量可根據樹脂塔的數量進行調整,而通過調整各個管路上的電動閥啟閉,可選擇正洗或反洗時液體的流動方向,如限定液體是依次經過各個樹脂塔,還是同時經過多個樹脂塔。正常情況下,只啟動其中一條管路,關閉其他管路上的電動閥,而這些管路作為備用管路使用,在常用的管路出現問題時,通過電動閥的切換,即可啟動備用管路,對損壞管路的維修也不影響正常生產。The resin tower flushing circuit 7 includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin towers. The number of the pipelines can be adjusted according to the number of the resin towers, and by adjusting the electric valves on each pipeline Opening and closing, you can choose the direction of liquid flow during forward or reverse washing, such as limiting whether the liquid passes through each resin tower in sequence or through multiple resin towers at the same time. Under normal circumstances, only one of the pipelines is activated, and the electric valves on the other pipelines are closed, and these pipelines are used as backup pipelines. When common pipelines have problems, the electrical pipelines can be switched by switching the electrical valves. The maintenance of damaged pipelines does not affect normal production.
循環迴路8包括多條並聯的並分別設置有與樹脂塔數量相同的電動閥的管路,其中一條管路與樹脂塔沖洗迴路7連通,多條管路在各個樹脂塔底部匯成一路並與各個樹脂塔底部分別連通。多條管路的作用也在於備用,通過切換各個管路上電動閥的啟閉,選擇不同路徑,實現對樹脂塔不同的沖洗方式。The circulation loop 8 includes a plurality of pipelines connected in parallel and each provided with the same number of electric valves as the resin tower. One of the pipelines communicates with the resin tower flushing circuit 7, and a plurality of pipelines merge into one at the bottom of each resin tower and communicate with The bottoms of the respective resin towers are respectively communicated. The function of multiple pipelines is also for backup. By switching the opening and closing of the electric valve on each pipeline and choosing different paths, different washing methods for the resin tower can be realized.
如在本發明實施方式中,採用樹脂塔A和樹脂塔B兩個樹脂塔,那麼從樹脂塔A到樹脂塔B依次正洗,從樹脂塔B到樹脂塔A依次反洗的過程中,樹脂塔沖洗迴路7與循環迴路8上的電動閥13,15,22,26開啟,電動閥11,12,14,16,21,23,24,25均為關閉狀態,正洗時正洗泵5啟動,反洗時,正洗泵5停止,反洗泵6啟動工作,液體依次流經上述開啟的電動閥,並依次通過樹脂塔A、樹脂塔B。For example, in the embodiment of the present invention, two resin towers, resin tower A and resin tower B, are used. Then, from resin tower A to resin tower B, the resin is being washed in sequence, and from resin tower B to resin tower A. The electric valves 13, 15, 22, and 26 on the tower flushing circuit 7 and the circulation circuit 8 are opened, and the electric valves 11, 12, 14, 16, 21, 23, 24, and 25 are all closed, and the pump 5 is being washed during forward washing When starting and backwashing, the forward washing pump 5 stops and the backwashing pump 6 starts to work, and the liquid flows through the above-mentioned open electric valve in turn, and then passes through resin tower A and resin tower B in sequence.
而需要單獨沖洗某個樹脂塔時,如單獨沖洗樹脂塔A,則打開電動閥11,14,關閉其他電動閥,啟動反洗泵6即可,如單獨沖洗樹脂塔B,則打開電動閥21,24,關閉其他電動閥,啟動反洗泵6,即可。而上述電動閥的啟閉排列方式並非唯一,可通過不同電動閥之間的啟閉組合而實現不同的沖洗模式。When a resin tower needs to be flushed separately, if the resin tower A is flushed separately, the electric valves 11, 14 are opened, other electric valves are closed, and the backwash pump 6 is started; if the resin tower B is flushed separately, the electric valve 21 is opened , 24, close other electric valves, start the backwash pump 6, and you can. The above-mentioned arrangement of the opening and closing of the electric valve is not unique, and different flushing modes can be realized through the combination of opening and closing between different electric valves.
實際案例比較說明:習知技術樹脂塔系統每天用總水量65T,進水含金濃度0.9ppm,出水大於0.3ppm需收料,人員維護週期工時:習知技術每週3次,2人/次,8小時/次,本發明每週1次,1人/次,4小時/次,原有技術每週48小時,本發明每週4小時,節省人力91.6%,每週節省人力及交通,餐費開銷每週節省人工費合計RMB1300元。Comparison of actual cases: the conventional technology resin tower system uses a total of 65T of water per day, the concentration of gold in the incoming water is 0.9ppm, and the effluent is greater than 0.3ppm, and the material needs to be collected. Working hours of the maintenance cycle: 3 times a week in the conventional technology, 2 people / Times, 8 hours / time, the present invention is once a week, 1 person / time, 4 hours / time, the original technology is 48 hours a week, the invention is 4 hours a week, saving 91.6% of manpower, saving manpower and traffic each week , Meal expenses saved weekly labor costs totaled RMB 1300 yuan.
收料週期及金:出水大於0.3ppm需收料,原有技術總樹脂90KG,每20天收料1次得金0.4%,每月得金540克,本發明投入樹脂240KG已2.5個月未收料含金0.5625%以上,2.5個月樹脂節省97.5KG以上(節省RMB1950元),含金%提高40%以上,每週節省樹脂物料費RMB195元以上。收入樹脂金吸附提高40%以上。Receiving cycle and gold: the water needs to be reclaimed if the effluent is greater than 0.3ppm. The original technology has a total resin weight of 90KG. It receives 0.4% gold every 20 days, and receives 540 grams of gold per month. The received material contains more than 0.5625% of gold, the resin can save more than 97.5KG (saving RMB1950 yuan) in 2.5 months, the gold content can be increased by more than 40%, and the resin material cost can be saved more than RMB195 per week. Revenue of resin gold adsorption increased by more than 40%.
設備異常:原有技術每1.5個月水泵損壞1個(RMB1800元),1個月漫水罰金RMB750元,本發明投入2.5個月未發生異常,每週節省設備異常費RMB1050元以上。Equipment abnormality: The original technology damages one pump every 1.5 months (RMB 1800), and the fine for one month is RMB 750. The invention has not been abnormal for 2.5 months, and the equipment abnormality fee has been saved over RMB 1,050 per week.
綜合以上每月節省RMB10180元以上,收入提高40%以上。Based on the above, it can save more than RMB10,180 per month and increase the income by more than 40%.
以上之敘述以及說明僅為本發明之較佳實施例之說明,對於此項技術具有通常知識者當可依據以下所界定申請專利範圍以及上述之說明而作其他之修改,惟此些修改仍應是為本發明之創作精神而在本發明之權利範圍中。The above descriptions and descriptions are merely illustrations of the preferred embodiments of the present invention. Those with ordinary knowledge of this technology may make other modifications based on the scope of the patent application defined below and the above description, but these modifications should still be made. It is within the scope of rights of the present invention for the creative spirit of the present invention.
1‧‧‧貴金廢液儲存槽 1‧‧‧Precious gold waste liquid storage tank
10‧‧‧反洗管10‧‧‧Backwash tube
101‧‧‧調節閥101‧‧‧ regulating valve
102、93‧‧‧流量計開關102、93‧‧‧Flowmeter switch
103‧‧‧取樣口103‧‧‧Sampling port
104、62、63、94‧‧‧止回閥104, 62, 63, 94‧‧‧ check valve
11、12、13、14、15、16、21、22、23、24、25、26、31、32、41、42、73、74、75、76‧‧‧電動閥11, 12, 13, 14, 15, 16, 21, 22, 23, 24, 25, 26, 31, 32, 41, 42, 73, 74, 75, 76‧‧‧ electric valve
11a、13a、15a、21a、22a、24a、26a‧‧‧閥門11a, 13a, 15a, 21a, 22a, 24a, 26a
2‧‧‧樹脂活化劑儲存桶2‧‧‧Resin activator storage bucket
3‧‧‧正反洗電動三通閥3‧‧‧ Forward and reverse washing electric three-way valve
4‧‧‧備用迴路4‧‧‧ backup circuit
5‧‧‧正洗泵5‧‧‧Flushing pump
51‧‧‧壓縮空氣迴路51‧‧‧Compressed air circuit
52、64‧‧‧連通管52, 64‧‧‧ connecting pipe
53‧‧‧氣體流量計53‧‧‧Gas flow meter
6‧‧‧反洗泵6‧‧‧Backwash pump
61‧‧‧排放迴路61‧‧‧Drain circuit
7‧‧‧樹脂塔沖洗迴路7‧‧‧Resin tower flushing circuit
71‧‧‧排水循環電動三通閥71‧‧‧Drain circulation electric three-way valve
72‧‧‧回水管路72‧‧‧Backwater pipeline
8‧‧‧循環迴路8‧‧‧Circle
9‧‧‧正洗管9‧‧‧ washing tube
91‧‧‧調節閥91‧‧‧ regulating valve
92‧‧‧取樣口92‧‧‧Sampling port
A‧‧‧向樹脂塔A‧‧‧direction resin tower
B‧‧‧樹脂塔B‧‧‧resin tower
圖1為習知技術樹脂塔正洗流程示意圖,圖中箭頭所示為正洗時液體流向; 圖2為習知技術樹脂塔反洗流程示意圖,圖中箭頭所示為反洗時液體流向; 圖3為本發明正洗流程示意圖,圖中箭頭所示為正洗時液體流向; 圖4為本發明反洗流程示意圖,圖中箭頭所示為反洗時液體流向及壓縮空氣管路的空氣流向FIG. 1 is a schematic diagram of a conventional technology resin tower forward washing process, the arrows in the figure show the flow direction of the liquid during forward washing; FIG. 2 is a conventional technique resin tower back washing flow diagram, the arrows show the direction of the liquid flow during back washing; Figure 3 is a schematic diagram of the forward washing process of the present invention, and the arrows in the figure show the liquid flow direction during the forward washing; Figure 4 is a schematic diagram of the reverse washing process of the present invention, and the arrows in the figure are the liquid flow direction and the air in the compressed air pipeline during the reverse washing. Flow direction
Claims (10)
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CN201610247317.4A CN105905981A (en) | 2016-04-20 | 2016-04-20 | Noble metal automatic activation ion exchange resin column set system |
??201610247317.4 | 2016-04-20 |
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TW201825404A true TW201825404A (en) | 2018-07-16 |
TWI639560B TWI639560B (en) | 2018-11-01 |
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CN107510957A (en) * | 2017-10-16 | 2017-12-26 | 昆山鸿福泰环保科技有限公司 | A kind of cleaning device of recovery tower |
CN110801870A (en) * | 2018-08-06 | 2020-02-18 | 兰州蓝星纤维有限公司 | Strong-alkaline anion resin activation system and activation method |
CN112191281B (en) * | 2020-11-07 | 2024-09-10 | 浙江华康药业股份有限公司 | Ion exchange system and method for improving xylitol ion exchange efficiency |
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JPS56141844A (en) * | 1980-04-04 | 1981-11-05 | Japan Organo Co Ltd | Regeneration method for ion exchange resin of sugar solution desalting apparatus |
JP3797029B2 (en) * | 1999-07-30 | 2006-07-12 | 栗田工業株式会社 | Condensate desalination method |
CN201343479Y (en) * | 2009-01-13 | 2009-11-11 | 厦门市威士邦膜科技有限公司 | Electroplating wastewater treatment device |
CN201411496Y (en) * | 2009-06-20 | 2010-02-24 | 永兴县元泰应用材料有限公司 | Device for recovering noble metals from silver electrolysis residual liquid in ionic way |
CN201999974U (en) * | 2010-12-10 | 2011-10-05 | 游京初 | Processing device for recycling waste liquid containing noble metal |
CN202196341U (en) * | 2011-07-13 | 2012-04-18 | 东莞市圣田实业投资有限公司 | Temperature and humidity controller |
CN202193641U (en) * | 2011-08-10 | 2012-04-18 | 郭春美 | Recovery treating equipment capable of realizing recycling of precious metal |
CN202290065U (en) * | 2011-10-14 | 2012-07-04 | 山东电力工程咨询院有限公司 | Mixed bed full-automatic reclamation system |
CN103691493B (en) * | 2013-12-20 | 2016-01-20 | 潍坊英轩实业有限公司 | A kind of anion exchange resin technique water-saving method and water saving fixtures |
CN103991926B (en) * | 2014-06-06 | 2015-06-10 | 四川恒达环境技术有限公司 | Electrolytic manganese waste water ion exchange treatment system under automatic control in whole process and adopting aeration type ion exchange device |
CN205575718U (en) * | 2016-04-20 | 2016-09-14 | 夏夷虎 | Noble metal auto -activation duolite tower system system |
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