TW201818468A - Structure of critical dimension bar and semiconductor thereof - Google Patents

Structure of critical dimension bar and semiconductor thereof Download PDF

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TW201818468A
TW201818468A TW105135679A TW105135679A TW201818468A TW 201818468 A TW201818468 A TW 201818468A TW 105135679 A TW105135679 A TW 105135679A TW 105135679 A TW105135679 A TW 105135679A TW 201818468 A TW201818468 A TW 201818468A
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polysilicon layer
patterned
layer
isolation
stack
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TW105135679A
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TWI717411B (en
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龔文文
孫張虎
曉飛 韓
李召兵
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聯華電子股份有限公司
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Abstract

The present invention provides a structure of critical dimension bar, formed on a substrate, comprising: a isolation structure, comprising a first isolation island and a second isolation island; a patterned polysilicon layer, formed on the isolation structure, comprising a first polysilicon pattern and a second polysilicon pattern on the first isolation island and a second isolation island respectively; and a patterned protective layer, formed on the patterned polysilicon layer, comprising a first protective pattern and a second protective pattern, wherein the first isolation island, a first polysilicon pattern, and the first protective pattern together form a first stack, the second isolation island, the second polysilicon pattern, and the second protective pattern together form a second stack, the first and second stacks are separated from and parallel to each other. The present invention also provides a semiconductor structure comprises the above critical dimension bar.

Description

關鍵尺寸欄結構與半導體結構Key size column structure and semiconductor structure

本發明是關於一種關鍵尺寸欄結構,形成於切割道之部分基材上,具有與元件區中記憶體結構對應之高度。SUMMARY OF THE INVENTION The present invention is directed to a critical dimension bar structure formed on a portion of a substrate of a dicing street having a height corresponding to a memory structure in the component region.

隨著科技的進步,半導體產業成為科技業中一個非常重要的發展領域,而在半導體製程也日趨複雜。在半導體的製程步驟中,黃光蝕刻與研磨製程可以說是極為重要的製程步驟,光刻製程的結果可以決定產品的品質表現。而圖案化後的材料層具有關鍵尺寸(critical dimension,簡稱CD),可以說是評斷元件品質的一個重要指標,而具有關鍵尺寸的材料層或是材料層堆疊結構被稱為關鍵尺寸欄(CD bar),用以方便量測集成電路或是晶片中元件的關鍵尺寸。With the advancement of technology, the semiconductor industry has become a very important development area in the technology industry, and the semiconductor manufacturing process has become increasingly complex. In the semiconductor manufacturing process, the yellow etching and polishing process can be said to be an extremely important process step, and the result of the lithography process can determine the quality performance of the product. The patterned material layer has a critical dimension (CD), which can be said to be an important indicator for judging the quality of components. A material layer with a critical dimension or a stack of material layers is called a key dimension bar (CD). Bar) is used to conveniently measure the critical dimensions of components in an integrated circuit or wafer.

一般來說,元件區中具有集成電路之元件,結構相對複雜,不易進行測量,因此關鍵尺寸欄設置於元件區之外,其結構應要能對應元件區中元件的關鍵尺寸,以確保測量之結果能正確反應元件區中的關鍵尺寸。 但目前習知技術來說,由於不同區域間所包含的元件不完全相同,加上製程中對於晶圓的邊緣區域控制不易,例如化學機械研磨製程中,越遠離圓心的部分晶的研磨厚度偏差值越大,導致關鍵尺寸欄的量測結果無法準確對應元件區域或是接近圓心區域的量測結果。In general, components with integrated circuits in the component area are relatively complicated in structure and difficult to measure. Therefore, the critical dimension bar is disposed outside the component area, and its structure should correspond to the critical dimensions of the components in the component area to ensure measurement. The result is a correct response to the critical dimensions in the component area. However, in the prior art, since the components included in different regions are not completely the same, it is not easy to control the edge region of the wafer in the process. For example, in the chemical mechanical polishing process, the grinding thickness deviation of the partial crystal away from the center of the circle is difficult. The larger the value, the measurement result of the key size bar cannot accurately correspond to the measurement result of the component area or the center of the circle.

因此,本發明在提供一種關鍵尺寸欄結構,用以解決習知技術中的上述問題。Accordingly, the present invention is directed to a key size column structure for solving the above problems in the prior art.

本發明提供一種關鍵尺寸欄結構,形成於基材上,包含:隔離結構,至少包含第一隔離島與第二隔離島;圖案化多晶矽層,形成於隔離結構上,包含第一多晶矽層圖案與第二多晶矽層圖案,分別於第一隔離島與第二隔離島上;以及圖案化保護層,形成於圖案化多晶矽層上,包含第一保護層圖案與第二保護層圖案,其中第一隔離島、第一多晶矽層圖案與第一保護層圖案共同形成第一堆疊,第二隔離島、第二多晶矽層圖案與第二保護層圖案共同形成第二堆疊,第一堆疊與第二堆疊彼此分離且相互平行。The invention provides a key size column structure formed on a substrate, comprising: an isolation structure comprising at least a first isolation island and a second isolation island; and a patterned polysilicon layer formed on the isolation structure, comprising a first polysilicon layer a pattern and a second polysilicon layer pattern respectively on the first isolation island and the second isolation island; and a patterned protection layer formed on the patterned polysilicon layer, including the first protection layer pattern and the second protection layer pattern, wherein The first isolation island, the first polysilicon layer pattern and the first protection layer pattern together form a first stack, and the second isolation island, the second polysilicon layer pattern and the second protection layer pattern together form a second stack, first The stack and the second stack are separated from each other and are parallel to each other.

在本發明的較佳實施例中,其中部分該隔離結構嵌於該基材中,且具有一上表面高於該基材之一上表面。In a preferred embodiment of the invention, a portion of the isolation structure is embedded in the substrate and has an upper surface that is higher than an upper surface of the substrate.

在本發明的較佳實施例中,其中該隔離結構之該上表面高於該基材之該上表面450~650埃之間。In a preferred embodiment of the invention, the upper surface of the isolation structure is between 450 and 650 angstroms above the upper surface of the substrate.

在本發明的較佳實施例中,其中該第一隔離島與該第二隔離島之間具有一間距介於210~310埃之間。In a preferred embodiment of the invention, the first isolation island and the second isolation island have a spacing between 210 and 310 angstroms.

在本發明的較佳實施例中,還包含:一圖案化ONO結構層,形成於該隔離結構與該圖案化多晶矽層之間,包含一第一ONO結構層圖案與一第二ONO結構層圖案,其中該第一ONO結構層圖案包含於該第一堆疊中,位於該第一隔離島與該第一多晶矽層圖案之間,該第二ONO結構層圖案包含於該第二堆疊中,位於該第二隔離島與該第二多晶矽層圖案之間。In a preferred embodiment of the present invention, the method further includes: a patterned ONO structure layer formed between the isolation structure and the patterned polysilicon layer, comprising a first ONO structure layer pattern and a second ONO structure layer pattern The first ONO structure layer pattern is included in the first stack, between the first isolation island and the first polysilicon layer pattern, and the second ONO structure layer pattern is included in the second stack. Located between the second isolation island and the second polysilicon layer pattern.

在本發明的較佳實施例中,還包含:一多晶矽層,形成於基材上、該第一堆疊與該第二堆疊之間,並且該多晶矽層具有一晶圓內高度差值小於60埃。In a preferred embodiment of the present invention, the method further includes: a polysilicon layer formed on the substrate, between the first stack and the second stack, and the polysilicon layer having an in-wafer height difference of less than 60 angstroms .

在本發明的較佳實施例中,其中該第一多晶矽層圖案與該第一保護層圖案共同形成一部分第一堆疊,該第二多晶矽層圖案與該第二保護層圖案共同形成一部分第二堆疊,並且該第一隔離島與該第二隔離島之間具有一間距小於該部分第一堆疊與該部份第二堆疊之間具有的一間距。In a preferred embodiment of the present invention, the first polysilicon layer pattern and the first protective layer pattern together form a portion of the first stack, and the second polysilicon layer pattern and the second protective layer pattern are formed together A portion of the second stack has a spacing between the first isolation island and the second isolation island that is less than a spacing between the portion of the first stack and the portion of the second stack.

在本發明的較佳實施例中,其中第一多晶矽層圖案與第一保護層圖案共同形成部分第三堆疊,第二多晶矽層圖案與第二保護層圖案共同形成部分第四堆疊,並且第一隔離島與第二隔離島之間具有的間距大於部分第三堆疊與部份第四堆疊之間具有的間距。In a preferred embodiment of the present invention, the first polysilicon layer pattern and the first protective layer pattern together form a partial third stack, and the second polysilicon layer pattern and the second protective layer pattern together form a partial fourth stack And a spacing between the first isolation island and the second isolation island is greater than a spacing between the portion of the third stack and the portion of the fourth stack.

在本發明的較佳實施例中,還包含:一部分多晶矽層,形成於該基材上,包含彼此分離的一第一部分多晶矽層與一第二部分多晶矽層,該第一部分多晶矽層與該第一隔離島相鄰,該第二部分多晶矽層與該第二隔離島相鄰,並且該第一部分多晶矽層被該第一多晶矽層圖案覆蓋,該第二部分多晶矽層被該第二多晶矽層圖案覆蓋。In a preferred embodiment of the present invention, the method further includes: forming a portion of the polysilicon layer on the substrate, comprising a first portion of the polysilicon layer and a second portion of the polysilicon layer separated from each other, the first portion of the polysilicon layer and the first layer Adjacent to the isolation island, the second partial polysilicon layer is adjacent to the second isolation island, and the first partial polysilicon layer is covered by the first polysilicon layer pattern, and the second partial polysilicon layer is covered by the second polysilicon layer Layer pattern overlay.

本發明還同時提供一種半導體結構,包含:基材,具有元件區與檢測區;隔離結構,包含複數個元件區隔離島於元件區中彼此分離且相互平行,複數個檢測區隔離島於檢測區中彼此分離且相互平行,其中元件區隔離島與檢測區隔離島具有相互垂直的延伸方向;第一圖案化多晶矽層,形成於元件區隔離島之間;圖案化ONO結構層,形成於元件區中的第一圖案化多晶矽層上,以及檢測區中的複數個檢測區隔離島上;第二圖案化多晶矽層,形成於圖案化ONO結構層上;以及圖案化保護層,形成於第二圖案化多晶矽層上。The invention also provides a semiconductor structure, comprising: a substrate having an element region and a detection region; and an isolation structure comprising a plurality of component regions, the islands are separated from each other in the component region and are parallel to each other, and the plurality of detection regions are isolated from the detection region. Separating from each other and parallel to each other, wherein the element isolation island and the detection region isolation island have mutually perpendicular extending directions; the first patterned polysilicon layer is formed between the isolation regions of the element region; and the patterned ONO structural layer is formed in the component region a first patterned polysilicon layer, and a plurality of detection regions on the island in the detection region; a second patterned polysilicon layer formed on the patterned ONO structure layer; and a patterned protective layer formed in the second pattern On the polycrystalline layer.

在本發明的較佳實施例中,其中該第一圖案化多晶矽層與該元件區隔離島分別具有高於基材1之二高度,且該二高度範圍介於450-650埃之間。In a preferred embodiment of the present invention, the first patterned polysilicon layer and the element isolation island have a height higher than the substrate 1 and the two heights are between 450 and 650 angstroms.

在本發明的較佳實施例中,其中該第一圖案化多晶矽層與該檢測區隔離島具有相同之延伸方向。In a preferred embodiment of the invention, the first patterned polysilicon layer has the same extension direction as the detection region isolation island.

在本發明的較佳實施例中,其中該檢測區中的該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層三者所形成的一堆疊結構的一側壁,與該檢測區隔離島之一側壁共平面。In a preferred embodiment of the present invention, a sidewall of a stacked structure formed by the patterned ONO structure layer, the second patterned polysilicon layer and the patterned protective layer in the detection region One side wall of the isolation zone of the detection zone is coplanar.

在本發明的較佳實施例中,其中該檢測區中的該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層三者形成複數個堆疊結構,二相鄰之該堆疊結構具有一間距大於該二相鄰之該堆疊結構下方的二該檢測區隔離島之一間距。In a preferred embodiment of the present invention, the patterned ONO structure layer, the second patterned polysilicon layer and the patterned protection layer in the detection region form a plurality of stacked structures, and the adjacent ones of the stacked The structure has a pitch greater than one of the two isolation regions of the detection zone below the two adjacent stack structures.

在本發明的較佳實施例中,其中該第一圖案化多晶矽層之一上表面與該檢測區隔離島之一上表面共平面。In a preferred embodiment of the invention, an upper surface of the first patterned polysilicon layer is coplanar with an upper surface of the isolation island isolation island.

在本發明的較佳實施例中,還包含:一第三圖案化多晶矽層,形成於該元件區中的該第一圖案化多晶矽層、該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層四者共同組成的複數個記憶體堆疊結構之間,以及該檢測區中的該檢測區隔離島、該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層四者所共同組成的複數個關鍵尺寸欄結構之間,其中該第三圖案化多晶矽層具有一晶圓內高度差值小於60埃。In a preferred embodiment of the present invention, the method further includes: a third patterned polysilicon layer, the first patterned polysilicon layer formed in the element region, the patterned ONO structure layer, and the second patterned polysilicon layer And a plurality of memory stack structures formed together with the patterned protective layer, and the detection region isolation island, the patterned ONO structure layer, the second patterned polysilicon layer and the patterning in the detection region The protective layer has a plurality of key dimension column structures, wherein the third patterned polysilicon layer has an in-wafer height difference of less than 60 angstroms.

因此,本發明利用蝕刻與研磨製程中對小塊區域小於大塊區域移除速率、小塊區域製程後具有相對小的區域內差異值等之上述特性,藉由形成與元件區相同分佈方式的隔離結構3於檢測區之方法,來改善邊緣區域的關鍵尺寸欄結構各層的移除速率控制不易的問題。Therefore, the present invention utilizes the above-mentioned characteristics that the small block area is smaller than the bulk area removal rate, the small area process has a relatively small intra-area difference value, and the like in the etching and polishing process, by forming the same distribution pattern as the element area. The method of isolating the structure 3 from the detection zone is to improve the problem that the removal rate control of each layer of the critical dimension column structure of the edge region is not easy.

本發明提供一種關鍵尺寸欄結構,為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文以實施例配合所附圖式,同時以揭示本發明實施例相關製程步驟的方式來做詳細說明,以使本發明之結構與功效能更容易理解。並且,為方便說明與容易理解,不同實施例中具有相同功能的元件延用相同元件標號,但並非用以限制本發明。The above-described and other objects, features and advantages of the present invention will become more apparent and understood. Detailed description will be made to make the structure and efficacy of the present invention easier to understand. Also, for convenience of explanation and ease of understanding, elements having the same functions in different embodiments are given the same reference numerals, but are not intended to limit the present invention.

圖1所示為依據本發明所繪製之半導體結構俯視示意圖,包含元件區R1與檢測區R2,圖1a所示為圖1中A-A’切線上元件區R1與檢測區R2的結構剖面示意圖,而圖1b所示為圖1中B-B’切線與b-b’切線之結構剖面示意圖,分別對應並示意元件區R1與檢測區R2中Y方向的剖面結構。於元件區R1與檢測區R2中分別形成有複數個隔離結構3於基材1中,隔離結構3相互平行且彼此分離,隔離結構3分別在元件區R1與檢測區R2中將基材1定義出主動區R11,主動區R11位於隔離結構3之間,用以做為其後所形成元件工作的主動區域,例如圖1所示之配置為依據本發明之一實施例所繪製的主動區R11,但在此不做限制。另外,元件區R1中形成有複數個相互平行的記憶體堆疊結構20 (包含圖案化後的多晶矽層4、ONO結構層5、多晶矽層6以及保護層7)於基材1上,垂直地形成於元件區R1中延X方向延伸的部分主動區R11上,且垂直於隔離結構3上;而檢測區R2中形成有複數個相互平行的關鍵尺寸欄結構21 (包含隔離結構3以及圖案化後的ONO結構層5、多晶矽層6、保護層7)於基材1上,記憶體堆疊結構20、關鍵尺寸欄結構21與主動區R11皆延Y方向延伸,關鍵尺寸欄結構21與主動區R1相間配置,而元件區R1中與檢測區R2中的隔離結構3分別延不同方向延伸,且兩區中的隔離結構3延伸方向相互垂直。並且元件區R1中與檢測區R2中的隔離結構3皆高於基材1上表面,其中,元件區R1中的隔離結構3之間具有多晶矽層4,用以做為製程完成時記憶元件的浮游閘極。元件區R1可以為記憶體單元形成的晶片區,而檢測區R2可以是環繞於晶片區的切割道區域。而多晶矽層9後續會做為字線使用,填充於記憶體堆疊結構20、關鍵尺寸欄結構21之間的基材1上。1 is a top plan view of a semiconductor structure according to the present invention, including an element region R1 and a detection region R2, and FIG. 1a is a schematic cross-sectional view showing the structure of the device region R1 and the detection region R2 on the A-A' tangent line in FIG. FIG. 1b is a schematic cross-sectional view showing the structure of the B-B' tangent line and the b-b' tangent line in FIG. 1, respectively corresponding to and showing the cross-sectional structure in the Y direction of the element region R1 and the detection region R2. A plurality of isolation structures 3 are formed in the substrate 1 in the element region R1 and the detection region R2, and the isolation structures 3 are parallel to each other and separated from each other. The isolation structure 3 defines the substrate 1 in the element region R1 and the detection region R2, respectively. The active area R11 is located between the isolation structures 3, and is used as an active area for the components formed later. For example, the configuration shown in FIG. 1 is an active area R11 according to an embodiment of the present invention. But there is no limit here. In addition, a plurality of mutually parallel memory stack structures 20 (including the patterned polysilicon layer 4, the ONO structure layer 5, the polysilicon layer 6 and the protective layer 7) are formed on the substrate 1 in the element region R1, and are formed vertically. a portion of the active region R11 extending in the X direction in the element region R1 is perpendicular to the isolation structure 3; and a plurality of mutually parallel key dimension column structures 21 are formed in the detection region R2 (including the isolation structure 3 and the patterned structure) The ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7) are on the substrate 1. The memory stack structure 20, the critical dimension column structure 21 and the active region R11 are all extended in the Y direction, and the critical dimension column structure 21 is interposed with the active region R1. The arrangement, and the isolation structure 3 in the element region R1 and the detection region R2 extend in different directions, and the isolation structures 3 in the two regions extend in a direction perpendicular to each other. And the isolation structure 3 in the element region R1 and the detection region R2 are higher than the upper surface of the substrate 1, wherein the isolation structure 3 in the device region R1 has a polysilicon layer 4 between them for use as a memory element during process completion. Floating gate. The element area R1 may be a wafer area formed by the memory unit, and the detection area R2 may be a scribe line area surrounding the wafer area. The polysilicon layer 9 is subsequently used as a word line, and is filled on the substrate 1 between the memory stack structure 20 and the key size column structure 21.

為能更清楚說明本發明之結構與功效,圖2a-2g所示為依據本發明之另一實施例所繪製之關鍵尺寸欄結構於不同製程步驟中,延對應圖1中切線A-A’之剖面示意圖 (相同元件使用相同標號,尺寸比例可以依不同實施例而有不同)。如圖2a所示,基材1包含基板11與覆蓋整個基板11的介電層12,之後形成隔離結構3於基材1上,方法例如是於介電層12(於一實施例中為氧化層)上形成氮化層後,對氮化層與介電層12進行圖案化,接著以氮化層與介電層12為罩幕對基板11進行蝕刻,移除暴露之部分基板11以形成複數個凹槽,形成隔離材料層於凹槽中並且覆蓋氮化層,之後進行平坦化研磨製程並且移除氮化層,即可得到如圖2a所示的隔離結構3。上述說明隔離結構3的形成方法並非用以限制本發明,舉例說明中使用的氮化層、介電層12、隔離材料層使用的材料選擇也可做調整,由於此部分可套用既有知識,因此不做贅述。隔離結構3彼此分離且相互平行,並且形成於檢測區R2中的隔離結構3延Y方向延伸,形成於元件區R1中的隔離結構3延X方向延伸,如圖1所示。隔離結構3具有嵌於基材1(基板11與介電層12)中的嵌入部31與凸出於基材1(基板11與介電層12)的凸出部32,凸出部32具有高於介電層12表面的高度D1,介於850~1050埃之間,並且任兩相鄰的隔離結構3之間距介於210~310埃之間。並且,由於隔離結構3具有類似島狀構型,因此單一個隔離結構3又可以被稱隔離島(本篇說明中「隔離島」即代表單一個隔離結構3)。接著沉積多晶矽層於基材1上,覆蓋整個基材1以及隔離結構3,之後進行化學機械研磨(CMP)製程,以隔離結構3為終止層,產生如圖2b所示之結構,多晶矽層4具有高度D2同樣介於850~1050埃之間,並且具有晶圓內高度差值(within wafer variation)小於60埃。另外,由於圖2a-2g是延圖1中切線A-A’所繪製之結構剖面示意圖,因此元件區R1的隔離結構3不會出現於圖2a-2g中,但元件區R1中的製程步驟與檢測區R2一致,所產生的結構也與檢測區R2類似。依據本發明之一實施例,隔離結構3的間距為261埃,D1與D2為950埃,並且至少部分多晶矽層4的上表面與隔離結構3的上表面共平面。In order to more clearly illustrate the structure and efficacy of the present invention, FIGS. 2a-2g show the key dimension column structure drawn in accordance with another embodiment of the present invention in different process steps, corresponding to the tangent A-A' in FIG. Schematic cross-section (the same components are given the same reference numerals, and the dimensional ratios may vary according to different embodiments). As shown in FIG. 2a, the substrate 1 comprises a substrate 11 and a dielectric layer 12 covering the entire substrate 11, and then an isolation structure 3 is formed on the substrate 1, for example, in the dielectric layer 12 (in one embodiment, oxidized). After the nitride layer is formed on the layer, the nitride layer and the dielectric layer 12 are patterned, and then the substrate 11 is etched by using the nitride layer and the dielectric layer 12 as a mask to remove the exposed portion of the substrate 11 to form A plurality of recesses are formed in the recess and cover the nitride layer, followed by a planarization polishing process and removal of the nitride layer to obtain the isolation structure 3 as shown in FIG. 2a. The above description of the method for forming the isolation structure 3 is not intended to limit the present invention. The material selection used for the nitride layer, the dielectric layer 12, and the isolation material layer used in the illustration may also be adjusted, since this part can apply existing knowledge. Therefore, do not repeat them. The isolation structures 3 are separated from each other and are parallel to each other, and the isolation structure 3 formed in the detection region R2 extends in the Y direction, and the isolation structure 3 formed in the element region R1 extends in the X direction as shown in FIG. The isolation structure 3 has an embedded portion 31 embedded in the substrate 1 (the substrate 11 and the dielectric layer 12) and a protruding portion 32 protruding from the substrate 1 (the substrate 11 and the dielectric layer 12), and the protruding portion 32 has The height D1 of the surface of the dielectric layer 12 is between 850 and 1050 angstroms, and the distance between any two adjacent isolation structures 3 is between 210 and 310 angstroms. Moreover, since the isolation structure 3 has an island-like configuration, the single isolation structure 3 can be referred to as an isolation island (the "isolation island" in this description represents a single isolation structure 3). Then depositing a polycrystalline germanium layer on the substrate 1, covering the entire substrate 1 and the isolation structure 3, followed by a chemical mechanical polishing (CMP) process to isolate the structure 3 as a termination layer, resulting in a structure as shown in FIG. 2b, the polysilicon layer 4 The height D2 is also between 850 and 1050 angstroms and has a wafer variation of less than 60 angstroms. In addition, since FIGS. 2a-2g are schematic cross-sectional views of the structure drawn by the tangential line A-A' in FIG. 1, the isolation structure 3 of the element region R1 does not appear in FIGS. 2a-2g, but the process steps in the element region R1 Consistent with the detection zone R2, the resulting structure is also similar to the detection zone R2. In accordance with an embodiment of the present invention, the isolation structure 3 has a pitch of 261 angstroms, D1 and D2 are 950 angstroms, and at least a portion of the upper surface of the polysilicon layer 4 is coplanar with the upper surface of the isolation structure 3.

接著對多晶矽層4與隔離結構3之凸出部32進行回蝕製程,使元件區R1與檢測區R2中的多晶矽層4以及隔離結構3的凸出部32,兩者皆具有介於450~650埃之間的高度(凸出於基材1),形成如圖2c所示之結構,多晶矽層4填充於隔離結構3的凸出部32之間,並且多晶矽層4的晶圓內高度差值(within wafer variation)小於60埃。之後依序形成ONO結構層5、多晶矽層6、保護層7,ONO結構層5厚度介於120~180埃之間,多晶矽層6厚度介於700~900埃之間,並且保護層7厚度介於1200~1700埃之間,如圖2d所示,元件區R1中堆疊後的總高度與檢測區R2中堆疊後的總高度一致,兩區中堆疊後凸出於基材1的總高度介於2470~3400埃。依據本發明之一實施例,多晶矽層4以及隔離結構3的凸出部32之高度皆為450埃,ONO結構層5厚度為150埃,多晶矽層6厚度為800埃,保護層7厚度為1500埃)。Then, the polycrystalline germanium layer 4 and the protruding portion 32 of the isolation structure 3 are etched back, so that the polycrystalline germanium layer 4 in the element region R1 and the detecting region R2 and the protruding portion 32 of the isolation structure 3 are both 450~. A height between 650 angstroms (projected from the substrate 1) forms a structure as shown in FIG. 2c, the polysilicon layer 4 is filled between the projections 32 of the isolation structure 3, and the wafer height difference of the polysilicon layer 4 is The within wafer variation is less than 60 angstroms. Then, the ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7 are sequentially formed. The thickness of the ONO structural layer 5 is between 120 and 180 angstroms, and the thickness of the polycrystalline germanium layer 6 is between 700 and 900 angstroms, and the thickness of the protective layer 7 is Between 1200 and 1700 angstroms, as shown in FIG. 2d, the total height after stacking in the component region R1 is consistent with the total height after stacking in the detection region R2, and the total height of the substrate 1 after stacking is projected. At 2470~3400 angstroms. According to an embodiment of the present invention, the height of the polycrystalline germanium layer 4 and the protruding portion 32 of the isolation structure 3 are 450 angstroms, the thickness of the ONO structural layer 5 is 150 angstroms, the thickness of the polycrystalline germanium layer 6 is 800 angstroms, and the thickness of the protective layer 7 is 1500 Å. A).

之後如圖2e所示,於元件區R1中形成記憶體堆疊結構20,於檢測區形成關鍵尺寸欄結構21,其中位於關鍵尺寸欄結構21之間的部分多晶矽層4被完全移除。形成方式例如是先對ONO結構層5、多晶矽層6、保護層7三者進行圖案化後,使圖案化的ONO結構層5、多晶矽層6、保護層7具有相同的寬度,並且三者所形成的推疊結構僅覆蓋部分凸出部32,使圖案化後的三者形成的堆疊結構的寬度D6小於隔離結構3的凸出部32寬度D5。之後於圖案化後的ONO結構層5、多晶矽層6以及保護層7三者延堆疊方向延伸的側壁上先形成第一間隙壁81,再以圖案化後的ONO結構層5、多晶矽層6以及保護層7三者的堆疊結構,以及第一間隙壁81為罩幕對多晶矽層4進行圖案化,以移除檢測區R2中之全部多晶矽層4以及元件區R1中未被覆蓋之部分多晶矽層4,之後再形成第二間隙壁82於元件區R1中圖案化後的多晶矽層4、ONO結構層5、多晶矽層6以及保護層7四者延堆疊方向延伸的側壁上、第一間隙壁81遠離四者上述側壁的一側壁上,以及檢測區R2中的隔離結構3中凸出部32以及圖案化後的ONO結構層5、多晶矽層6、保護層7四者延堆疊方向延伸的側壁上、第一間隙壁81遠離四者上述側壁的一側壁上,形成如圖2e所示之結構,第一間隙壁81與第二間隙壁82共同組成間隙壁8,而圖案化後的ONO結構層5、多晶矽層6、保護層7三者延堆疊方向延伸的側壁共平面,並且圖案化後的ONO結構層5、多晶矽層6、保護層7三者僅覆蓋部分的隔離結構3,使相鄰之隔離結構3的凸出部32的間距,小於其上ONO結構層5、多晶矽層6、保護層7三者形成的堆疊結構之間的間距,而三者形成的上述堆疊結構之間的間距則介於250~350埃之間(上述堆疊結構的相對兩側壁與其下方隔離結構3的相對兩側壁具有約略各為20埃的最短水平間距)。Thereafter, as shown in Fig. 2e, a memory stack structure 20 is formed in the element region R1, and a critical dimension column structure 21 is formed in the detection region, wherein a portion of the polysilicon layer 4 located between the key size column structures 21 is completely removed. For example, after the ONO structure layer 5, the polysilicon layer 6, and the protective layer 7 are patterned, the patterned ONO structure layer 5, the polysilicon layer 6, and the protective layer 7 have the same width, and the three layers are The formed push-up structure covers only a portion of the protrusions 32 such that the width D6 of the stacked structure formed by the three patterned ones is smaller than the width D5 of the protrusions 32 of the isolation structure 3. Then, a first spacer 81 is formed on the sidewalls of the patterned ONO structure layer 5, the polysilicon layer 6 and the protective layer 7 extending in the stacking direction, and then the patterned ONO structure layer 5 and the polysilicon layer 6 are patterned. The stacked structure of the protective layer 7 and the first spacer 81 are patterned by the mask to remove all of the polysilicon layer 4 in the detection region R2 and the uncovered polysilicon layer in the element region R1. 4, after the second spacer 82 is formed in the element region R1, the polysilicon layer 4, the ONO structure layer 5, the polysilicon layer 6 and the protective layer 7 are extended on the sidewall extending in the stacking direction, and the first spacer 81 is formed. On a side wall of the above-mentioned side wall away from the four, and the protrusion 32 in the isolation structure 3 in the detection area R2 and the patterned ONO structure layer 5, the polysilicon layer 6, and the protective layer 7 are extended on the side wall extending in the stacking direction. The first spacer 81 is separated from a sidewall of the four sidewalls to form a structure as shown in FIG. 2e. The first spacer 81 and the second spacer 82 together form a spacer 8 and the patterned ONO structural layer. 5, polycrystalline germanium layer 6, protective layer 7 three extension The sidewalls extending in the stack direction are coplanar, and the patterned ONO structure layer 5, the polysilicon layer 6, and the protective layer 7 cover only a portion of the isolation structure 3, so that the pitch of the protrusions 32 of the adjacent isolation structures 3 is Less than the spacing between the stacked structures formed by the upper ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7, and the spacing between the stacked structures formed by the three is between 250 and 350 angstroms (the above stacking) The opposite side walls of the structure and the opposite side walls of the underlying isolation structure 3 have a minimum horizontal spacing of approximately 20 angstroms each).

形成方法又或是先圖案化多晶矽層4、ONO結構層5、多晶矽層6、保護層7四者之堆疊,之後形成間隙壁8於元件區R1中的圖案化後的多晶矽層4、ONO結構層5、多晶矽層6以及保護層7四者延堆疊方向延伸的側壁上,以及檢測區R2中的隔離結構3中凸出部32以及圖案化後的ONO結構層5、多晶矽層6、保護層7四者延堆疊方向延伸的側壁上,形成如圖3所示的結構,其中元件區R1中圖案化後的多晶矽層4、ONO結構層5、多晶矽層6以及保護層7四者延堆疊方向延伸的側壁共平面,檢測區R2中隔離結構3的凸出部32以及圖案化後的ONO結構層5、多晶矽層6以及保護層7四者延堆疊方向延伸的側壁共平面,此方式所形成的間隙壁8可以為單層或多層結構。而依據上述方法形成的圖3所示的本發明實施例,於元件區R1中,圖案化後多晶矽層4、ONO結構層5、多晶矽層6以及保護層7具有相同的寬度,而檢測區R2中,圖案化後的ONO結構層5、多晶矽層6以及保護層7,四者堆疊的寬度D6’與隔離結構3的凸出部32寬度D5相同。圖3所示為本發明之實施例,其與圖2a-2g所示實施例具有另一不同之處,即隔離結構3與圖2a-2g所示實施例具有不同構型,本發明隔離結構3的構型不限,可依照不同製程做調整,本發明所繪製的構型僅為示意之用,並非用以限制本發明。The forming method is either first patterning the stack of the polysilicon layer 4, the ONO structure layer 5, the polysilicon layer 6, and the protective layer 7, and then forming the patterned polycrystalline layer 4 and the ONO structure of the spacer 8 in the element region R1. The layer 5, the polysilicon layer 6 and the protective layer 7 are extended on the sidewall extending in the stacking direction, and the protrusion 32 in the isolation structure 3 in the detection region R2 and the patterned ONO structure layer 5, the polysilicon layer 6, and the protective layer 7 is formed on the side wall extending in the stacking direction to form a structure as shown in FIG. 3, wherein the patterned polycrystalline germanium layer 4, the ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7 in the element region R1 are stacked in the stacking direction. The extended sidewalls are coplanar, and the protrusions 32 of the isolation structure 3 in the detection region R2 and the patterned ONO structure layer 5, the polysilicon layer 6 and the protective layer 7 are coplanar in the stacking direction. The spacers 8 may be of a single layer or a multilayer structure. According to the embodiment of the present invention shown in FIG. 3 formed according to the above method, in the element region R1, the patterned polysilicon layer 4, the ONO structure layer 5, the polysilicon layer 6 and the protective layer 7 have the same width, and the detection region R2 In the patterned ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7, the width D6' of the four stacks is the same as the width D5 of the convex portion 32 of the isolation structure 3. 3 is an embodiment of the present invention, which has another difference from the embodiment shown in FIGS. 2a-2g, that is, the isolation structure 3 has different configurations from the embodiment shown in FIGS. 2a-2g, and the isolation structure of the present invention The configuration of 3 is not limited and can be adjusted according to different processes. The configurations drawn by the present invention are for illustrative purposes only and are not intended to limit the present invention.

形成方法還可以是先對ONO結構層5、多晶矽層6、保護層7三者進行圖案化,形成如圖4a所示的結構,可以藉由檢測區R2中看到,圖案化後的ONO結構層5、多晶矽層6、保護層7三者不僅完全覆蓋隔離結構3,並且三者堆疊具有的寬度D6’’大於隔離結構3的凸出部32寬度D5,即兩相鄰之隔離結構3的間距大於兩相鄰的三者堆疊的間距。接著如圖4b所示,於圖案化後的ONO結構層5、多晶矽層6以及保護層7三者延堆疊方向延伸的側壁上先形成第一間隙壁81,再以圖案化後的ONO結構層5、多晶矽層6以及保護層7三者的堆疊結構,以及第一間隙壁81為罩幕對多晶矽層4進行圖案化,以移除元件區R1與檢測區中未被覆蓋的部分多晶矽層4。因此檢測區R2部分多晶矽層4’被保留,多晶矽層4’與凸出部32相鄰、位於隔離結構3之間,並且被圖案化後的ONO結構層5、多晶矽層6以及保護層7三者的堆疊結構以及第一間隙壁81覆蓋。並且該部分多晶矽層4遠離隔離結構3的側壁與第一間隙壁81的一側壁共平面。之後再形成第二間隙壁82,如圖4c所示,於元件區R1中第一間隙壁81與多晶矽層4’共平面的該側壁上,覆蓋第一間隙壁81與多晶矽層4’,同時間接覆蓋圖案化後的ONO結構層5、多晶矽層6以及保護層7三者延堆疊方向延伸的側壁上,以及於檢測區R2中圖案化後的多晶矽層4’與第一間隙壁81的上述側壁上,因此第二間隙壁82同時覆蓋ONO結構層5、多晶矽層6以及保護層7三者延堆疊方向延伸的側壁上。上述不同實施例中的間隙壁8,材料可以為SiO、SiN、SiON、SiCN,或上述任一組合,第一間隙壁81與第二間隙壁82可以為相同會不同材質。間隙壁的使用與相關形成方法由於可套用習知知識,因此其他製程細節不在此多做說明。The forming method may further be that the ONO structural layer 5, the polycrystalline germanium layer 6, and the protective layer 7 are first patterned to form a structure as shown in FIG. 4a, which can be seen by the detection region R2, and the patterned ONO structure. The layer 5, the polysilicon layer 6, and the protective layer 7 not only completely cover the isolation structure 3, but also the width D6'' of the three stacks is larger than the width D5 of the protrusion 32 of the isolation structure 3, that is, the structure of the two adjacent isolation structures 3. The spacing is greater than the spacing of the two adjacent stacks of three. Next, as shown in FIG. 4b, a first spacer 81 is formed on the sidewalls of the patterned ONO structural layer 5, the polysilicon layer 6 and the protective layer 7 extending in the stacking direction, and then the patterned ONO structural layer is formed. 5. A stacked structure of the polysilicon layer 6 and the protective layer 7, and the first spacer 81 is patterned by the mask to pattern the polysilicon layer 4 to remove the uncovered portion of the polysilicon layer 4 in the element region R1 and the detection region. . Therefore, the polycrystalline germanium layer 4' of the detecting region R2 is retained, the polycrystalline germanium layer 4' is adjacent to the protruding portion 32, located between the isolating structures 3, and the patterned ONO structural layer 5, polycrystalline germanium layer 6, and protective layer 7 The stacked structure of the person and the first spacer 81 are covered. And the sidewall of the portion of the polysilicon layer 4 away from the isolation structure 3 is coplanar with a sidewall of the first spacer 81. Then, a second spacer 82 is formed. As shown in FIG. 4c, on the sidewall of the element region R1 where the first spacer 81 and the polysilicon layer 4' are coplanar, the first spacer 81 and the polysilicon layer 4' are covered. Indirectly covering the patterned ONO structural layer 5, the polycrystalline germanium layer 6 and the protective layer 7 on the side walls extending in the stacking direction, and the above-described patterned polycrystalline germanium layer 4' and the first spacer 81 in the detecting region R2 On the side wall, therefore, the second spacer 82 simultaneously covers the ONO structure layer 5, the polysilicon layer 6 and the protective layer 7 on the side walls extending in the stacking direction. The spacers 8 in the different embodiments may be made of SiO, SiN, SiON, SiCN, or any combination thereof, and the first spacers 81 and the second spacers 82 may be the same material. The use of spacers and associated formation methods can be applied to other process details as they can apply conventional knowledge.

之後步驟以圖2e所示實施例做說明,但並非用以限制本發明,下述說明步驟同樣可以套用於圖3與圖4b所示實施例或是其他實施例中。接著沉積多晶矽層於基材1上,至少填滿於記憶體堆疊結構20之間、關鍵尺寸欄結構21之間,選擇性完整覆蓋記憶體堆疊結構20與關鍵尺寸欄結構21,之後進行平坦化製程(如化學機械研磨),形成多晶矽層9。其中多晶矽層9可以是僅位於記憶體堆疊結構20之間、關鍵尺寸欄結構21之間,使保護層7暴露,因此多晶矽層9的上表面與保護層7的上表面共平面;也可以依據平坦化製程中的移除多晶矽層厚度的不同,形成如圖2f所示的多晶矽層9,除了位於記憶體堆疊結構20之間、關鍵尺寸欄結構21之間外,同時還覆蓋保護層7的上表面,其中多晶矽層9於基材1上的高度D3介於2500~3500埃之間。於本發明之一實施例中,多晶矽層9之高度約為3000埃。之後進行回蝕製程,如圖2g所示,移除部分多晶矽層9以形成多晶矽層9’於記憶體堆疊結構20之間、關鍵尺寸欄結構21之間,用以做為字線(word line),並且回蝕後的多晶矽層9’具有約1200埃之高度D4,並且多晶矽層9’的晶圓內高度差值(within wafer variation)同樣小於60埃。另外,形成如井區、深井區、源/汲極等的摻雜製程,可適當的插入於上述步驟之間,在此不做限定。The subsequent steps are illustrated by the embodiment shown in FIG. 2e, but are not intended to limit the present invention. The following description steps can also be applied to the embodiment shown in FIG. 3 and FIG. 4b or other embodiments. Then depositing a polycrystalline germanium layer on the substrate 1 to fill at least between the memory stack structures 20 and between the critical dimension column structures 21, selectively covering the memory stack structure 20 and the critical dimension column structure 21, and then planarizing A process (such as chemical mechanical polishing) forms a polycrystalline germanium layer 9. The polycrystalline germanium layer 9 may be located only between the memory stacked structures 20 and between the critical size column structures 21, so that the protective layer 7 is exposed, so that the upper surface of the polycrystalline germanium layer 9 is coplanar with the upper surface of the protective layer 7; The difference in thickness of the removed polysilicon layer in the planarization process forms a polysilicon layer 9 as shown in FIG. 2f, except that it is located between the memory stack structure 20 and between the critical dimension column structures 21, and also covers the protective layer 7. The upper surface, wherein the height D3 of the polysilicon layer 9 on the substrate 1 is between 2500 and 3500 angstroms. In one embodiment of the invention, the polysilicon layer 9 has a height of about 3000 angstroms. Then, an etch back process is performed. As shown in FIG. 2g, a portion of the polysilicon layer 9 is removed to form a polysilicon layer 9' between the memory stack structure 20 and between the key size column structures 21 for use as a word line. And the etched polycrystalline germanium layer 9' has a height D4 of about 1200 angstroms, and the polysilicon layer 9' has an within wafer variation of less than 60 angstroms. In addition, a doping process such as a well region, a deep well region, a source/drain electrode, and the like may be appropriately inserted between the above steps, which is not limited herein.

因此,本發明所提供的關鍵尺寸欄結構,形成於基材(1)上,包含:隔離結構(3),至少包含第一隔離島與第二隔離島;圖案化多晶矽層(6),形成於隔離結構(3)上,包含第一多晶矽層圖案與第二多晶矽層圖案,分別於第一隔離島與第二隔離島上(對應於圖式中位於不同隔離島上的圖案化後的多晶矽層6);以及圖案化保護層(7),形成於圖案化多晶矽層上,包含第一保護層圖案與第二保護層圖案(對應於圖式中位於不同隔離島上的圖案化後的保護層7),其中第一隔離島、第一多晶矽層圖案與第一保護層圖案共同形成第一堆疊,第二隔離島、第二多晶矽層圖案與第二保護層圖案共同形成第二堆疊,第一堆疊與第二堆疊彼此分離且相互平行 (對應於圖式中不同的關鍵尺寸欄結構21,彼此分離且相互平行)。本發明還提供一種半導體結構,包含:基材(1),具有元件區(R1)與檢測區(R2);隔離結構(3),包含複數個元件區隔離島(對應於圖式中元件區R1中的部分隔離結構3)於元件區(R1)中彼此分離且相互平行,複數個檢測區隔離島(對應於圖式中檢測區R2中的部分隔離結構3)於檢測區(R2)中彼此分離且相互平行,其中元件區隔離島與檢測區隔離島具有相互垂直的延伸方向;第一圖案化多晶矽層(對應於圖2e-2g中,位於元件區R1中圖案化後的多晶矽層4),形成於元件區隔離島之間;圖案化ONO結構層(5),形成於元件區(R1)中的第一圖案化多晶矽層(4)上,以及檢測區(R2)中的複數個檢測區隔離島上;第二圖案化多晶矽層(對應於圖2e-2g中,圖案化後的多晶矽層6),形成於圖案化ONO結構層上;以及圖案化保護層(對應於圖2e-2g中,圖案化後的保護層7),形成於第二圖案化多晶矽層上。Therefore, the key dimension column structure provided by the present invention is formed on the substrate (1), comprising: an isolation structure (3) comprising at least a first isolation island and a second isolation island; and a patterned polycrystalline germanium layer (6) formed On the isolation structure (3), the first polysilicon layer pattern and the second polysilicon layer pattern are respectively disposed on the first isolation island and the second isolation island (corresponding to the patterning on the different isolation islands in the drawing) a polysilicon layer 6); and a patterned protective layer (7) formed on the patterned polysilicon layer, comprising a first protective layer pattern and a second protective layer pattern (corresponding to the patterned ones on different islands in the drawing) a protective layer 7), wherein the first isolation island, the first polysilicon layer pattern and the first poly layer pattern together form a first stack, and the second isolation island, the second polysilicon layer pattern and the second protection layer pattern are formed together The second stack, the first stack and the second stack are separated from each other and are parallel to each other (corresponding to different key size bar structures 21 in the drawing, separated from each other and parallel to each other). The invention also provides a semiconductor structure comprising: a substrate (1) having an element region (R1) and a detection region (R2); an isolation structure (3) comprising a plurality of component region isolation islands (corresponding to the component regions in the drawing) The partial isolation structures 3) in R1 are separated from each other in the element region (R1) and are parallel to each other, and a plurality of detection region isolation islands (corresponding to a partial isolation structure 3 in the detection region R2 in the drawing) are in the detection region (R2). Separating from each other and parallel to each other, wherein the element isolation island and the detection region isolation island have mutually perpendicular extending directions; the first patterned polysilicon layer (corresponding to the patterned polycrystalline germanium layer 4 in the element region R1 in FIGS. 2e-2g) Formed between the isolation regions of the element region; patterned ONO structure layer (5), formed on the first patterned polysilicon layer (4) in the element region (R1), and plural in the detection region (R2) a detection zone isolation island; a second patterned polysilicon layer (corresponding to the patterned polysilicon layer 6 in Figures 2e-2g) formed on the patterned ONO structure layer; and a patterned protective layer (corresponding to Figures 2e-2g) The patterned protective layer 7) is formed on the second patterned polysilicon layer.

研磨與蝕刻製程中,由於製程與機台本身的限制,對晶圓的邊緣區域控制不易。以半徑為300毫米(mm)的晶圓為例,在離圓心超過130毫米的邊緣區域內的關鍵尺寸欄結構,其製程後的邊緣區域內高度差值可以高達500埃,遠大於離圓心小於等於130毫米的中心區域內的高度差值,因此導致習知技術中,關鍵尺寸欄結構根本無法反應元件的測量結果之問題。雖然習知技術中使用各種方式,例如調整製程參數,來改善晶圓邊緣區域針對此問題,增加了製程成本但卻還是無法根本性的改善晶圓邊緣區域控制不易的問題。針對上述問題,本案發明人研究後發現,雖然邊緣區域內的關鍵尺寸欄結構其製程後的區域內高度差值可以高達500埃,但邊緣區域內的記憶體元件結構,其製程後的區域內高度差值卻可以維持在60埃以下的範圍,而記憶體堆疊結構與關鍵尺寸欄結構最大的差異就在於,關鍵尺寸欄結構僅為監測元件區的記憶體堆疊結構而存在,因此在結構上不需要與元件區完全相同,只要堆疊結果上能達到一致即可,因此習知技術中,設計位於切割道上的關鍵尺寸欄結構其堆疊、密度、形狀、分佈等與元件區並不會相同,但這也間接導致了研磨與蝕刻製程時,切割道與元件區移除速率的落差。雖然位於較接近圓心的區域,由於製程控制效果佳,因此移除速率的落差不會明顯反應出來,但邊緣區域本身就有製程控制效果不易的問題,因此促成了區域內高度差值過大的問題。In the grinding and etching process, the edge area of the wafer is not easily controlled due to the limitations of the process and the machine itself. Taking a wafer with a radius of 300 mm (mm) as an example, in a critical dimension column structure in an edge region of more than 130 mm from the center of the circle, the height difference in the edge region after the process can be as high as 500 angstroms, which is much larger than the center of the circle. A difference in height in the central region equal to 130 mm, thus leading to the problem in the prior art that the critical dimension bar structure simply does not reflect the measurement results of the component. Although various methods are used in the prior art, such as adjusting process parameters to improve the edge area of the wafer, the process cost is increased, but the problem of difficulty in controlling the edge area of the wafer cannot be fundamentally improved. In view of the above problems, the inventor of the present invention found that although the height dimension column structure in the edge region can have a height difference of up to 500 angstroms after the process, the memory component structure in the edge region is within the process area. The height difference can be maintained below 60 angstroms, and the biggest difference between the memory stack structure and the critical dimension column structure is that the critical dimension column structure exists only for the memory stack structure of the monitoring component area, and thus the structure It does not need to be identical to the component area, as long as the stacking result can be consistent. Therefore, in the prior art, the stacking, density, shape, distribution, etc. of the key size column structure located on the cutting path are not the same as the component area. However, this also indirectly leads to a drop in the rate of removal of the scribe line from the component area during the grinding and etching process. Although it is located in the area closer to the center of the circle, the process control effect is good, so the drop of the removal rate will not be clearly reflected, but the edge area itself has a problem that the process control effect is not easy, thus contributing to the problem of excessive height difference in the area. .

本發明提供的關鍵尺寸欄結構位於切割道上的檢測區R2中,並且在元件區R1形成隔離結構3的步驟中,同時形成具有同樣分佈方式的隔離結構3於檢測區R2中,使檢測區R2中的隔離結構3具有與後續製程中元件區R1中記憶體堆疊結構20中的多晶矽層4相同的高度。由於需要於後續製程中,在檢測區R2中的隔離結構3上形成對應於記憶體堆疊結構20中的ONO結構層5、第二多晶矽層6以及保護層7的各層,因此方向上檢測區R2中的隔離結構3與元件區R1中的隔離結構3相互垂直,其餘分佈條件,如形狀、間距、寬度等,皆與元件區R1中的隔離結構3類似或相同。因此,本發明利用蝕刻與研磨製程中對小塊區域小於大塊區域移除速率、小塊區域製程後具有相對小的區域內差異值等之上述特性,藉由形成與元件區R1相同分佈方式的隔離結構3於檢測區R2之方法,來改善邊緣區域的關鍵尺寸欄結構各層的移除速率控制不易的問題。The key dimension column structure provided by the present invention is located in the detection region R2 on the scribe line, and in the step of forming the isolation structure 3 in the element region R1, simultaneously forming the isolation structure 3 having the same distribution pattern in the detection region R2, so that the detection region R2 The isolation structure 3 in the middle has the same height as the polysilicon layer 4 in the memory stack structure 20 in the element region R1 in the subsequent process. In the subsequent process, the layers corresponding to the ONO structure layer 5, the second polysilicon layer 6 and the protective layer 7 in the memory stack structure 20 are formed on the isolation structure 3 in the detection region R2, so the direction detection The isolation structure 3 in the region R2 is perpendicular to the isolation structure 3 in the element region R1, and the remaining distribution conditions, such as shape, pitch, width, etc., are similar or identical to the isolation structure 3 in the element region R1. Therefore, the present invention utilizes the above-described characteristics such that the small block region is smaller than the bulk region removal rate and the small region region process has a relatively small intra-region difference value in the etching and polishing process, and the same distribution pattern as the device region R1 is formed. The isolation structure 3 is in the detection zone R2 method to improve the problem that the removal rate control of each layer of the critical dimension column structure of the edge region is not easy.

綜上所述,本發明提供之關鍵尺寸欄結構,具有與元件區中記憶體堆疊結構中的浮閘多晶矽層(對應圖式中元件區R1中,圖案化後的多晶矽層4)一致高度隔離結構(應圖式中檢測區R2中的隔離結構3),進而使後續形成的堆疊層皆能與元件區中記憶體堆疊結構中的各層對應,改善關鍵尺寸欄結構與元件結構落差的問題,並且本發明提供之關鍵尺寸欄結構,還具有能直接套用於習知製程步驟中之優點。雖然本發明已以實施例揭露如上,然其並非用以限定本發明。任何該領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾。因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。In summary, the present invention provides a key dimension column structure having a high degree of isolation from the floating gate polysilicon layer in the memory stack structure of the device region (corresponding to the patterned polysilicon layer 4 in the element region R1 in the figure). The structure (the isolation structure 3 in the detection area R2 in the drawing), so that the subsequently formed stacked layers can correspond to the layers in the memory stack structure in the component region, thereby improving the problem of the difference between the key dimension column structure and the component structure. Moreover, the key dimension column structure provided by the present invention also has the advantage that it can be directly applied to the conventional process steps. Although the present invention has been disclosed above by way of example, it is not intended to limit the invention. Anyone having ordinary knowledge in the field can make some changes and refinements without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.

1‧‧‧基材1‧‧‧Substrate

3‧‧‧隔離結構3‧‧‧Isolation structure

4、4’、6、9、9’‧‧‧多晶矽層4, 4', 6, 9, 9'‧‧‧ polycrystalline layer

5‧‧‧ONO結構層5‧‧‧ONO structural layer

7‧‧‧保護層7‧‧‧Protective layer

8、81、82‧‧‧間隙壁8, 81, 82‧ ‧ spacers

11‧‧‧基板11‧‧‧Substrate

12‧‧‧介電層12‧‧‧Dielectric layer

20‧‧‧記憶體堆疊結構20‧‧‧Memory stack structure

21‧‧‧關鍵尺寸欄結構21‧‧‧Key size bar structure

31‧‧‧嵌入部31‧‧‧ embedded department

32‧‧‧凸出部32‧‧‧Protruding

D1、D2、D3、D4‧‧‧高度D1, D2, D3, D4‧‧‧ height

D5、D6、D6’、D6’’‧‧‧寬度D5, D6, D6’, D6’’‧‧‧ width

R1‧‧‧元件區R1‧‧‧ component area

R2‧‧‧檢測區R2‧‧‧ inspection area

R11‧‧‧主動區R11‧‧‧ active area

A-A’、B-B’、b-b’‧‧‧切線A-A’, B-B’, b-b’‧‧‧ tangent

為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉數個較佳實施例,並配合所附圖式,作詳細說明如下: 圖1所示為依據本發明所繪製之半導體結構俯視示意圖; 圖1a所示為圖1中A-A’ 切線的結構剖面示意圖; 圖1b所示為圖1中B-B’切線與b-b’切線之結構剖面示意圖,分別對應並示意元件區R1與檢測區R2中Y方向的剖面結構; 圖2a-2g所示為依據本發明之另一實施例所繪製之關鍵尺寸欄結構於不同製程步驟中的剖面結構示意圖; 圖3所示為依據本發明之另一實施例所繪製之剖面結構示意圖;以及 圖4a-4c所示為依據本發明之另一實施例所繪製之關鍵尺寸欄結構於不同製程步驟中的剖面結構示意圖。The above and other objects, features, and advantages of the present invention will become more apparent from the aspects of the invention. A schematic plan view of the semiconductor structure is drawn; FIG. 1a is a schematic cross-sectional view of the structure of the line A-A' in FIG. 1; FIG. 1b is a cross-sectional view of the structure of the B-B' tangent line and the b-b' tangent line in FIG. Corresponding to and illustrating the cross-sectional structure of the element region R1 and the detection region R2 in the Y direction; FIGS. 2a-2g are schematic diagrams showing the cross-sectional structure of the key dimension column structure drawn in different process steps according to another embodiment of the present invention; 3 is a schematic cross-sectional view taken in accordance with another embodiment of the present invention; and FIGS. 4a-4c are cross-sectional structures showing key dimension columns in different process steps in accordance with another embodiment of the present invention. schematic diagram.

Claims (16)

一種關鍵尺寸欄結構,形成於一基材上,包含: 一隔離結構,形成於該基材上,包含一第一隔離島與一第二隔離島; 一圖案化多晶矽層,形成於該隔離結構上,包含一第一多晶矽層圖案與一第二多晶矽層圖案;以及 一圖案化保護層,形成於該圖案化多晶矽層上,包含一第一保護層圖案與一第二保護層圖案, 其中該第一隔離島、該第一多晶矽層圖案與該第一保護層圖案共同形成一第一堆疊,該第二隔離島、該第二多晶矽層圖案與該第二保護層圖案共同形成一第二堆疊,該第一堆疊與該第二堆疊彼此分離且相互平行。A key dimension bar structure is formed on a substrate, comprising: an isolation structure formed on the substrate, comprising a first isolation island and a second isolation island; a patterned polysilicon layer formed on the isolation structure a first polysilicon layer pattern and a second polysilicon layer pattern; and a patterned protective layer formed on the patterned polysilicon layer, comprising a first protective layer pattern and a second protective layer a pattern, wherein the first isolation island, the first polysilicon layer pattern and the first protection layer pattern together form a first stack, the second isolation island, the second polysilicon layer pattern and the second protection The layer patterns collectively form a second stack that is separate from each other and parallel to each other. 如請求項1所述之關鍵尺寸欄結構,其中部分該隔離結構嵌於該基材中,且具有一上表面高於該基材之一上表面。The key dimension column structure of claim 1, wherein a portion of the isolation structure is embedded in the substrate and has an upper surface higher than an upper surface of the substrate. 如請求項2所述之關鍵尺寸欄結構,其中該隔離結構之該上表面高於該基材之該上表面450~650埃之間。The key dimension column structure of claim 2, wherein the upper surface of the isolation structure is between 450 and 650 angstroms above the upper surface of the substrate. 如請求項1所述之關鍵尺寸欄結構,其中該第一隔離島與該第二隔離島之間具有一間距介於210~310埃之間。The key size bar structure of claim 1, wherein the first isolation island and the second isolation island have a spacing between 210 and 310 angstroms. 如請求項1所述之關鍵尺寸欄結構,還包含: 一圖案化ONO結構層,形成於該隔離結構與該圖案化多晶矽層之間,包含一第一ONO結構層圖案與一第二ONO結構層圖案,其中該第一ONO結構層圖案包含於該第一堆疊中,位於該第一隔離島與該第一多晶矽層圖案之間,該第二ONO結構層圖案包含於該第二堆疊中,位於該第二隔離島與該第二多晶矽層圖案之間。The key dimension column structure of claim 1, further comprising: a patterned ONO structure layer formed between the isolation structure and the patterned polysilicon layer, comprising a first ONO structure layer pattern and a second ONO structure a layer pattern, wherein the first ONO structure layer pattern is included in the first stack between the first isolation island and the first polysilicon layer pattern, and the second ONO structure layer pattern is included in the second stack Medium between the second isolation island and the second polysilicon layer pattern. 如請求項1所述之關鍵尺寸欄結構,還包含: 一多晶矽層,形成於基材上、該第一堆疊與該第二堆疊之間,並且該多晶矽層具有一晶圓內高度差值小於60埃。The key dimension column structure of claim 1, further comprising: a polysilicon layer formed on the substrate, between the first stack and the second stack, and the polysilicon layer having an in-wafer height difference is less than 60 angstroms. 如請求項1所述之關鍵尺寸欄結構,其中該第一多晶矽層圖案與該第一保護層圖案共同形成一部分第一堆疊,該第二多晶矽層圖案與該第二保護層圖案共同形成一部分第二堆疊,並且該第一隔離島與該第二隔離島之間具有一間距小於該部分第一堆疊與該部份第二堆疊之間具有的一間距。The key size bar structure of claim 1, wherein the first polysilicon layer pattern and the first protective layer pattern together form a portion of the first stack, the second polysilicon layer pattern and the second protective layer pattern A portion of the second stack is formed together, and a spacing between the first isolation island and the second isolation island is less than a spacing between the portion of the first stack and the portion of the second stack. 如請求項1所述之關鍵尺寸欄結構,其中該第一多晶矽層圖案與該第一保護層圖案共同形成一部分第三堆疊,該第二多晶矽層圖案與該第二保護層圖案共同形成一部分第四堆疊,並且該第一隔離島與該第二隔離島之間具有一間距大於該部分第三堆疊與該部份第四堆疊之間具有的一間距。The key size column structure of claim 1, wherein the first polysilicon layer pattern and the first protective layer pattern together form a portion of a third stack, the second polysilicon layer pattern and the second protective layer pattern A portion of the fourth stack is formed together, and a spacing between the first isolation island and the second isolation island is greater than a spacing between the portion of the third stack and the portion of the fourth stack. 如請求項1所述之關鍵尺寸欄結構,還包含: 一部分多晶矽層,形成於該基材上,包含彼此分離的一第一部分多晶矽層與一第二部分多晶矽層,該第一部分多晶矽層與該第一隔離島相鄰,該第二部分多晶矽層與該第二隔離島相鄰,並且該第一部分多晶矽層被該第一多晶矽層圖案覆蓋,該第二部分多晶矽層被該第二多晶矽層圖案覆蓋。The key dimension column structure of claim 1, further comprising: a portion of a polysilicon layer formed on the substrate, comprising a first partial polysilicon layer and a second partial polysilicon layer separated from each other, the first partial polysilicon layer and the Adjacent to the first isolation island, the second partial polysilicon layer is adjacent to the second isolation island, and the first partial polysilicon layer is covered by the first polysilicon layer pattern, and the second partial polysilicon layer is covered by the second The wafer layer pattern is covered. 一種半導體結構,包含: 一基材,具有一元件區與一檢測區; 一隔離結構,包含彼此分離且相互平行的複數個元件區隔離島於該元件區中,以及彼此分離且相互平行的複數個檢測區隔離島於該檢測區中,其中該元件區隔離島與該檢測區隔離島具有相互垂直的延伸方向; 一第一圖案化多晶矽層,形成於該元件區中、該複數個元件區隔離島之間; 一圖案化ONO結構層,形成於該元件區中的該第一圖案化多晶矽層上、該檢測區中的該複數個檢測區隔離島上; 一第二圖案化多晶矽層,形成於該圖案化ONO結構層上;以及 一圖案化保護層,形成於該第二圖案化多晶矽層上。A semiconductor structure comprising: a substrate having an element region and a detection region; an isolation structure comprising a plurality of element regions separated from each other and parallel to each other in the element region, and separated from each other and parallel to each other a detection zone isolation island in the detection zone, wherein the component zone isolation island and the detection zone isolation island have mutually perpendicular extending directions; a first patterned polysilicon layer formed in the component region, the plurality of component regions Separating islands between the islands; a patterned ONO structure layer formed on the first patterned polysilicon layer in the element region, the plurality of detection regions on the isolation island in the detection region; a second patterned polysilicon layer forming On the patterned ONO structure layer; and a patterned protective layer formed on the second patterned polysilicon layer. 如請求項10所述之半導體結構,其中該第一圖案化多晶矽層與該元件區隔離島分別具有高於基材1之二高度,且該二高度範圍介於450-650埃之間。The semiconductor structure of claim 10, wherein the first patterned polysilicon layer and the element isolation island have a height higher than the substrate 1 and the two heights are between 450 and 650 angstroms. 如請求項10所述之半導體結構,其中該第一圖案化多晶矽層與該檢測區隔離島具有相同之延伸方向。The semiconductor structure of claim 10, wherein the first patterned polysilicon layer has the same extension direction as the detection region isolation island. 如請求項10所述之半導體結構,其中該檢測區中的該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層三者所形成的一堆疊結構的一側壁,與該檢測區隔離島之一側壁共平面。The semiconductor structure of claim 10, wherein a side wall of the stacked structure formed by the patterned ONO structure layer, the second patterned polysilicon layer and the patterned protection layer in the detection region One side wall of the isolation zone of the detection zone is coplanar. 如請求項10所述之半導體結構,其中該檢測區中的該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層三者形成複數個堆疊結構,二相鄰之該堆疊結構具有一間距大於該二相鄰之該堆疊結構下方的二該檢測區隔離島之一間距。The semiconductor structure of claim 10, wherein the patterned ONO structure layer, the second patterned polysilicon layer and the patterned protection layer in the detection region form a plurality of stacked structures, and the adjacent ones of the stacked The structure has a pitch greater than one of the two isolation regions of the detection zone below the two adjacent stack structures. 如請求項10所述之半導體結構,其中該第一圖案化多晶矽層之一上表面與該檢測區隔離島之一上表面共平面。The semiconductor structure of claim 10, wherein an upper surface of the first patterned polysilicon layer is coplanar with an upper surface of the isolation island isolation island. 如請求項10所述之半導體結構,還包含: 一第三圖案化多晶矽層,形成於該元件區中的該第一圖案化多晶矽層、該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層四者共同組成的複數個記憶體堆疊結構之間,以及該檢測區中的該檢測區隔離島、該圖案化ONO結構層、該第二圖案化多晶矽層與該圖案化保護層四者所共同組成的複數個關鍵尺寸欄結構之間,其中該第三圖案化多晶矽層具有一晶圓內高度差值小於60埃。The semiconductor structure of claim 10, further comprising: a third patterned polysilicon layer, the first patterned polysilicon layer formed in the element region, the patterned ONO structure layer, and the second patterned polysilicon layer And a plurality of memory stack structures formed together with the patterned protective layer, and the detection region isolation island, the patterned ONO structure layer, the second patterned polysilicon layer and the patterning in the detection region The protective layer has a plurality of key dimension column structures, wherein the third patterned polysilicon layer has an in-wafer height difference of less than 60 angstroms.
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