TW201817694A - System and method for making and applying a non-portland cement-based material - Google Patents

System and method for making and applying a non-portland cement-based material Download PDF

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TW201817694A
TW201817694A TW105136165A TW105136165A TW201817694A TW 201817694 A TW201817694 A TW 201817694A TW 105136165 A TW105136165 A TW 105136165A TW 105136165 A TW105136165 A TW 105136165A TW 201817694 A TW201817694 A TW 201817694A
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binder mixture
portland cement
based material
cement based
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TWI758262B (en
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尤金 詹姆士 卡馬里
安卓亞斯 史墜爾
羅伯特 喬治 班斯
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英科技股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

A system and method for applying a construction material is provided. The method may include mixing blast furnace slag material, geopolymer material, alkali-based powder, and sand at a batching and mixing device to generate a non-Portland cement-based material. The method may also include transporting the non-Portland cement-based material from the mixing device, through a conduit to a nozzle and combining the transported non-Portland cement-based material with liquid at the nozzle to generate a partially liquefied non-Portland cement-based material. The method may further include pneumatically applying the partially liquefied non-Portland cement-based material to a surface.

Description

用於製作並施用非波特蘭水泥基材料之系統與方法System and method for making and applying non-Portland cement based materials

本發明係關於建構材料,且更具體言之,本發明係關於一種用於製作且施用建構材料之方法。This invention relates to construction materials and, more particularly, to a method for making and applying a construction material.

下水道翻新及混凝土復原及建構之領域中之現存做法可涉及可氣動式地突出朝需要修復或建構之表面之噴漿混凝土之施用。此噴漿混凝土包含在鹼性混凝土中發現之材料,諸如砂、波特蘭水泥及液體。在一特定施工現場中,此噴漿混凝土可為一乾拌或一濕拌應用之形式。術語「乾拌」通常涉及將處於一乾式狀態之部分或全部材料氣動式地傳送通過一軟管至一噴嘴,其中在物質突出之前一操作者可控制在該噴嘴處將液體施加至乾拌。相比而言,術語「濕拌」通常涉及將包含液體之一先前混合之混凝土在突出之前傳送通過一軟管。 一些公司已嘗試改變噴漿混凝土之材料組成以獲得某些優勢。據此,一些做法可涉及無機聚合物之使用。然而,此等材料由於此等產物中固有之有機材料而通常遭受腐蝕。例如,Milliken®在其等產品之GeoSpray™及GeoSpray™ AMS線下製造各種產品。AMS產品可經施用作為GeoSpray™產品之一預先及/或後處理。GeoSpray係波特蘭水泥基且僅含有一小部分無機聚合物。此混合物不耐酸。AMS含有抵抗酸在波特蘭水泥基混凝土上之效應及與波特蘭水泥基材料發生之微生物引起之腐蝕之效應之有機物。Existing practices in the field of sewer refurbishment and concrete restoration and construction may involve the application of a shotcrete that can be pneumatically protruded toward a surface that needs to be repaired or constructed. This shotcrete contains materials found in alkaline concrete such as sand, Portland cement and liquids. In a particular construction site, the shotcrete can be in the form of a dry mix or a wet mix application. The term "dry mix" generally involves pneumatically transferring some or all of the material in a dry state through a hose to a nozzle where an operator can control the application of liquid to the dry mix prior to protrusion of the material. In contrast, the term "wet mix" generally involves transferring a previously mixed concrete containing one of the liquids through a hose prior to protrusion. Some companies have tried to change the material composition of the shotcrete to achieve certain advantages. Accordingly, some practices may involve the use of inorganic polymers. However, such materials typically suffer from corrosion due to the organic materials inherent in such products. For example, Milliken® manufactures a wide range of products under its GeoSprayTM and GeoSprayTM AMS lines. The AMS product can be applied as one of the GeoSprayTM products in advance and/or after treatment. GeoSpray is Portland cement based and contains only a small portion of inorganic polymer. This mixture is not acid resistant. AMS contains organics that resist the effects of acid on Portland cement-based concrete and the effects of micro-organisms associated with Portland cement-based materials.

在一第一實施方案中,提供一種用於施用一建構材料之方法。該方法可包含在一分批處理及混合裝置中混合高爐熔渣材料、無機聚合物材料、鹼基粉末及砂以產生一非波特蘭水泥基材料。該方法亦可包含:將該非波特蘭水泥基材料自該分批處理及混合裝置通過一導管輸送至一噴嘴;且將輸送之非波特蘭水泥基材料與液體在噴嘴處組合以產生一部分液化之非波特蘭水泥基材料。該方法可進一步包含將該部分液化之非波特蘭水泥基材料氣動式地施用至一表面。 可包含以下特徵之一或多者。在一些實施例中,無機聚合物材料係火山岩粉或浮石之至少一者。鹼基粉末可包含矽酸鹽。可將混合執行為一乾拌。非波特蘭水泥基材料可為無機的。可在一行動分批處理及混合車輛中執行混合。非波特蘭水泥基材料可包含黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石或沸石之至少一者。混合可包含在一可攜帶槍中混合,該可攜帶槍經構形以自分批處理及混合裝置接收非波特蘭水泥基材料。非波特蘭水泥基材料之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值(Blaine fineness value)。 在另一實施方案中,提供一種用於施用一建構材料之系統。該系統可包含經構形以分批處理且混合高爐熔渣材料、無機聚合物材料、鹼基粉末及砂以產生一非波特蘭水泥基材料之一分批處理及混合裝置。該系統亦可包含經構形以自分批處理及混合裝置輸送非波特蘭水泥基材料之一導管。該系統可進一步包含經構形以接收該非波特蘭水泥基材料且將輸送之非波特蘭水泥基材料與液體組合以產生一部分液化之非波特蘭水泥基材料之一噴嘴,其中該噴嘴進一步經構形以將部分液化之非波特蘭水泥基材料氣動式地施用至一表面。 可包含以下特徵之一或多者。在一些實施例中,無機聚合物材料可為火山岩粉或浮石之至少一者。鹼基粉末可包含矽酸鹽。可將混合執行為一乾拌。非波特蘭水泥基材料可為無機的。可在一行動分批處理及混合車輛中執行混合。非波特蘭水泥基材料可包含黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石或沸石之至少一者。混合可包含在一可攜帶槍中混合,該可攜帶槍經構形以自分批處理及混合裝置接收非波特蘭水泥基材料。非波特蘭水泥基材料之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值。 在另一實施方案中,提供一種非波特蘭水泥基建構材料。該非波特蘭水泥基建構材料包含高爐熔渣材料、火山岩粉、鹼基粉末及砂。在一些實施例中,該鹼基粉末可為矽酸鹽。 在隨附圖式及以下描述中闡述一或多個實施方案之細節。將自描述、圖式及申請專利範圍明白其他特徵及優勢。In a first embodiment, a method for applying a construction material is provided. The method can include mixing a blast furnace slag material, an inorganic polymer material, a base powder, and sand in a batch processing and mixing apparatus to produce a non-Portland cement based material. The method may also include: transporting the non-Portland cement based material from the batch processing and mixing device to a nozzle through a conduit; and combining the transported non-Portland cement based material with the liquid at the nozzle to produce a portion Liquefied non-Portland cement based materials. The method can further comprise pneumatically applying the partially liquefied non-Portland cement based material to a surface. One or more of the following features may be included. In some embodiments, the inorganic polymeric material is at least one of volcanic rock powder or pumice. The base powder can comprise a decanoate. The mixing can be performed as a dry mix. Non-Portland cement based materials can be inorganic. Mixing can be performed in a mobile batch and hybrid vehicle. The non-Portland cement based material may comprise at least one of clay, gneiss, granite, rhyolite, andesite, peridotite, potash feldspar, albite, pumice or zeolite. Mixing can include mixing in a portable gun that is configured to receive non-Portland cement based materials from a batch processing and mixing device. The composition of the non-Portland cement based material may comprise a Blaine fineness value of from about 2500 cm 2 /g to 5000 cm 2 /g. In another embodiment, a system for applying a construction material is provided. The system can include a batch processing and mixing device configured to batch process and mix blast furnace slag material, inorganic polymer material, base powder, and sand to produce a non-Portland cement based material. The system can also include a conduit configured to deliver a non-Portland cement based material from a batch processing and mixing device. The system can further include a nozzle configured to receive the non-Portland cement based material and combine the transported non-Portland cement based material with a liquid to produce a portion of the liquefied non-Portland cement based material, wherein the nozzle Further configured to pneumatically apply a partially liquefied non-Portland cement based material to a surface. One or more of the following features may be included. In some embodiments, the inorganic polymeric material can be at least one of volcanic rock powder or pumice. The base powder can comprise a decanoate. The mixing can be performed as a dry mix. Non-Portland cement based materials can be inorganic. Mixing can be performed in a mobile batch and hybrid vehicle. The non-Portland cement based material may comprise at least one of clay, gneiss, granite, rhyolite, andesite, peridotite, potash feldspar, albite, pumice or zeolite. Mixing can include mixing in a portable gun that is configured to receive non-Portland cement based materials from a batch processing and mixing device. The composition of the non-Portland cement based material may comprise a Brian fineness value of from about 2500 cm 2 /g to 5000 cm 2 /g. In another embodiment, a non-Portland cement based construction material is provided. The non-Portland cement based construction material comprises blast furnace slag material, volcanic rock powder, base powder and sand. In some embodiments, the base powder can be a citrate. The details of one or more embodiments are set forth in the accompanying drawings and description. Other features and advantages will be apparent from the description, drawings and patent claims.

相關申請案之交叉參考 本申請案係2015年5月6日在美國專利及商標局申請之美國專利申請案第14/705,534號之一部份接續申請案。該案之全文以引用之方式併入本文中。 本發明之實施例係關於具有一鹼激發黏結劑(即,非波特蘭水泥基)之一建構材料及用於製作且施用該建構材料之一系統及方法。儘管在混凝土改造之背景內容中討論本文包含之諸多實例,但應注意本文描述之建構材料可在任何適合之應用中使用。部分此等應用可包含(但不限制於)下水道改造工程、經歷一酸侵蝕之任何混凝土結構等等。 參考圖1,其展示一行動分批處理及混合車輛100,行動分批處理及混合車輛100具有與其相關聯之數個容器、隔間及裝置。在一些實施例中,車輛100可包含可經構形以儲存砂或其他材料之第一容器102。儲存單元104可經構形以儲存水或其他液體。車輛100可進一步包含一分批處理及混合裝置106,裝置106可包含數個組件,部分組件可包含(但不限制於)第二容器108、可調整傳遞機構110及可攜帶槍212。如圖2中所展示,可攜帶槍212可經由導管或軟管216連接至噴嘴214。 在一些實施例中,行動分批處理及混合車輛100可經構形以分批處理、混合及施用一非波特蘭水泥基建構材料。此材料可在放置於第二容器108之前在車輛處(例如,在分批處理及混合裝置106內)進行分批處理及混合。可將此材料輸送至噴嘴214,在噴嘴214中此材料可在當需要建構或修復時施用至表面之前與儲存單元104中之液體混合。在下文中進一步詳細討論非波特蘭水泥基建構材料之特性。 在一些實施例中,相較於現存材料,本文描述之非波特蘭水泥基建構材料可具有更佳強度值、一高抵抗力且與無機及有機酸無反應且另外具有早期高強度值。非波特蘭水泥基建構材料可顯示對高溫之一改良之抵抗力以及顯著較高之強度及持久性性質。在一項實例中,非波特蘭水泥基建構材料可對強無機酸具有一絕佳抵抗力。此外,自非波特蘭水泥基建構材料產生之產品可具有絕佳壓縮強度及一十分低之熱導率。該材料可包含在一分批處理及混合裝置中之高爐熔渣材料、無機聚合物材料、鹼基粉末及砂之一乾拌(例如,一結合劑混合物)以產生非波特蘭水泥基材料。在一些實施例中,該結合劑混合物可用於產生該非波特蘭水泥基材料。 在一些實施例中,一結合劑混合物可包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、選自群組:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物之10重量%至45重量%之鹼性成分及20重量%至90重量%之粒料之一或多者。在一些實施例中,結合劑混合物可包含污染物形式之小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 在一些實施例中,非波特蘭水泥基建構材料可包含各種類型之無機聚合物材料。無機聚合物材料可包含(但不限制於)火山岩。因而,術語「無機聚合物材料」及「火山岩」可在本發明之範疇內交替使用。此等無機聚合物材料之一部分可包含(但不限制於)可與強鹼反應且使得該摻合物與砂及/或粗砂混合之火山灰材料。火山灰或火山灰材料可為由二氧化矽、黏土、石灰岩、氧化鐵及鹼性物質組成之可通過熱效應獲得之合成或自然岩石。當與氫氧化鈣及水組合時,其等可形成結合劑。天然火山灰(pozzolana)可為岩漿岩,諸如凝灰岩或德國萊茵浮石凝灰岩,但亦可為含有一高比例之可溶性矽酸之沉積岩,且有時亦可為反應性氧化鋁(黏土)。在一些實施例中,火山灰可為一易於得到之原材料且可用作為非波特蘭水泥基建構材料中之火山岩或無機聚合物材料。然而,亦可使用如火山岩或一些其他物質之天然材料,若較少部分用作為十分精細之粉末(例如,此一火山岩粉)則可更期望使用此等天然材料。 在一些實施例中,非波特蘭水泥基建構材料可包含任何數目之火山灰材料,其一部分可包含(但不限制於)細磨黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石、沸石等等以及其等混合物。此等材料可以煅燒及/或非煅燒之一岩土形式使用。另外及/或替代地,含有充足反應性(例如,亞穩態玻璃) SiO2 及Al2 O3 量之所有原材料(包含(但不限制於)灰燼、火山灰、熔渣)亦可適合用於本發明之實施例。 在一些實施例中,非波特蘭水泥基建構材料可包含一潛在水硬材料。本文使用之一潛在水硬材料可包含(但不限制於)飛灰、高嶺土、浮石凝灰岩、粒狀熔渣(例如,高爐熔渣材料)及/或其等之一混合物。在一項實例中,可使用褐煤飛灰及無煙煤飛灰之形式之飛灰。在一些實施例中,火山灰材料可包含活性矽酸鹽,如熔渣砂或飛灰。在一些實施例中,磚灰(耐火黏土)或來自燃燒無煙煤或褐煤之植物之飛灰可被稱為合成火山灰。因而,本文使用之術語「飛灰」可係指一非天然或合成火山灰。在一些實施例中,可由二氧化矽與氧化鋁及氧化鈣之一有利比例引起飛灰之特定有利性質,此可區分此等物質。然而,且如將在下文更詳細地討論,飛灰可含有部分硫酸鹽及/或氧化鈣。因此,若將飛灰用於結合劑混合物中,則可使用含有具有一有利比例之指定物質之一種類型之飛灰。 在一些實施例中,非波特蘭水泥基建構材料可包含一鹼基粉末材料及/或各種混合液體。一些可能之混合液體可包含(但不限制於)鉀及鈉水玻璃、鹼金屬類氫氧化物等等。在一些實施例中,鹼或鹼性成分可為一水溶液矽酸鈉形式或一粉末矽酸鈉形式之矽酸鈉。在一些實施例中,可使用一噴霧乾燥矽酸鹽。當使用鹼金屬類氫氧化物或鹼金屬碳酸鹽時,此等材料可以其等液體形式或以一粉末或粒狀使用。 在一些實施例中,含有SiO2 /Al2 O3 之成分與鹼性混合液體之間之反應可導致具有一三維結構之矽鋁酸鹽。此等框架結構允許產生在其化合物中不含波特蘭水泥之一建構材料。 如以上所討論,結合劑混合物及/或結合劑混合物之成分可包含鈣。在一些實施例中,結合劑混合物可含有部分氧化鈣(CaO)形式之鈣。結合劑混合物及/或非波特蘭水泥基建構材料中之此等CaO部分可在與鹼水溶液及/或成分反應之後導致水化矽酸鈣,此可具有已知不利化學性質。此外,作為水泥基結晶結構之一成分之鈣離子通常顯示一非所要可溶性,此可隨著時間之推移導致水泥結構之一弱化。為此理由可使用一最少可能比例之鈣。利用可溶性矽酸形式之SiO2 、氧化鐵、鋁酸鹽形式之Al2 O3 及氧化鈣之本發明之實施例可經與水溶性矽酸鹽或強鹼一起實施,因此導致具有較少鈣或幾乎無鈣之一無機結合系統。 在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式且具有至多5重量%之一比例之鈣。在一些實施例中,結合劑混合物中可含有氧化鈣形式且具有至多2重量%之一比例之鈣。另外及/或替代地,可含有氧化鈣形式且具有至多1重量%之一比例之鈣。 在一些實施例中,結合劑混合物中可含有污染物形式及/或具有小於1重量%之一比例之硫酸鹽(SO4 -2 )。以其鹽之形式出現之硫酸鹽係一與環境相關之物質。由農業施肥及廢料管理引起具有硫酸鹽之環境之增加之污染物。已證實硫酸鹽導致土地及地下水之酸化。由於硫酸鹽在水中之一通常較高之可溶性,所以其易於在地下水、滲漏及表面水流中輸送,最終增加廢料儲存設備中之含有硫酸鹽之材料之環境中之酸化效應。通過微生物程序將硫酸鹽分解為亞硫酸鹽,繼而可對動植物具有一負面效應。在一些實施例中,結合劑混合物中之硫酸鹽比例可盡可能地降低以至少避免此等負面效應。在一些實施例中,結合劑混合物中可含有污染物形式及/或具有小於0.5重量%之一比例之硫酸鹽(SO4 -2 )。在一項實施例中,可含有具有小於0.25重量%之一比例之硫酸鹽(SO4 -2 )。 在一些實施例中,非波特蘭水泥基建構材料可包含砂。然而,亦可使用其他粒料。例如,在一結合劑混合物中用作為一非水泥基混凝土之其他粒料可包含(但不限制於)砂礫、砂、玄武岩等等。亦可使用本發明之範疇內之用於非水泥基混凝土之其他材料。替代地且在各種應用中,亦可使用珍珠岩、膨脹葉岩、浮石或其等之一混合物。在一些實施例中,結合劑混合物可包含20重量%至70重量%之粒料。另外及/或替代地,20重量%至50重量%之粒料可包含於結合劑混合物中。在一項實施例中,20重量%至40重量%之粒料可包含於結合劑混合物中。 在一些實施例中,結合劑混合物亦可含有水。因此,在一項實施例中,可藉由由4重量%至45重量%之火山岩(例如,無機聚合物材料)、0重量%至40重量%之潛在水硬材料(例如,高爐熔渣材料)、10重量%至45重量%之鹼性成分(例如鹼)、20重量%至90重量%之粒料(例如砂)及/或水構成之一結合劑混合物展現對各種化學物質且尤其係對酸之一極高抵抗力。在一些實施例中,鹼性成分可包含矽酸鈉、鹼金屬類氫氧化物及/或鹼金屬碳酸鹽。另外及/或替代地,結合劑混合物可包含污染物形式及/或小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物可包含氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 在操作中,原料可粗略經分批處理及混合物(例如,全部或部分在車輛100中)且接著傳遞至可攜帶槍212。可經由壓縮空氣將非波特蘭水泥基建構材料攜帶通過導管216至噴嘴214。在一特定實施例中,矽酸鉀、固體含量48%、密度1,52 g/cm3、Wt SiO2:K2O 1,14及一些液體可經加入且將部分液化混合物氣動式地施用至受關注表面之前在噴嘴214內短時間(例如,小於1秒)粗略混合。 本文包含之實施例可包含含有以下之部分或全部之一混合物:熔渣(例如,非天然火山灰、基礎或潛在水硬材料)、飛灰(例如,非天然火山灰及配方中之選項)、無機聚合物(例如,天然火山灰及選項、地面火山材料/火山岩)、鹼/鹼性成分(例如,粉末或液體)、包含水(選項)及砂/粗砂或其他粒料之其他液體。以下提供特定混合物之實例,然而應注意,僅以實例方式包含本文提供之特定混合物。數個額外及替代實施例亦落於本發明之範疇內。 在一特定實例中,非波特蘭水泥基建構材料可包括以下混合物: 表1 在一些實施例中,混合物之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值。該布萊恩值係用於水泥粉化程度之一標準量測。該布萊恩值經給出作為利用一布萊恩裝置在一實驗室中判定之一特定表面值(cm2 /g)。例如,標準波特蘭水泥(CEM I 32.5)具有3000至4500之一布萊恩值。在一些實施例中,結合劑混合物、火山岩及/或潛在水硬材料之成分可以具有大於3000之一布萊恩值之一細磨狀態使用。在一項實施例中,火山岩及/或潛在水硬材料可具有大於3500之一布萊恩值。細磨成分可導致一顯著改良之反應速度。細磨火山岩可更易處理且可進一步導致對成品中之各種不同化學物質(尤其係對酸)之一增加之抵抗力。 在另一實例中,非波特蘭水泥基建構材料可包括以下混合物: 表2 在另一實例中,非波特蘭水泥基建構材料可包括以下混合物: 表3 在一些實施例中,相較於一液壓硬化結合劑,可使用自4重量%至45重量%之火山岩、0重量% (或大於0重量%)至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分及20重量%至90重量%之粒料之反應產生之一非波特蘭水泥基建構材料或結合劑混合物。在一些實施例中,鹼性成分可包含矽酸鈉、鹼金屬類氫氧化物及/或鹼金屬碳酸鹽。另外,結合劑混合物可包含污染物形式及/或小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 非波特蘭水泥基建構材料之實施例產生一預料之外之結果,因為鹼性原料與岩石粉之反應時間足夠產生一黏性化合物。通過數個測試,發現此化合物極其牢固地黏著於一垂直表面上,建立一緊密結合且在3天內經硬化具有大約50 N/mm2 (8000 psi)之壓縮強度值。 在一些實施例中,結合劑混合物或非波特蘭水泥基建構材料可用於應用之不同技術領域中:乾砂漿、石膏及噴射混凝土 可藉由混合乾性成分產生乾砂漿及石膏混合物。為此目的,可使用噴霧乾燥反應性矽酸鹽或鹼金屬類氫氧化物。基於此情況,可針對其等用途將成品混合物生產作為噴射混凝土。發泡混凝土 商用發泡混凝土係具有300 kg/m3 至800 kg/m3 之一原密度之一基於礦質之蒸壓發泡大塊建構材料。發泡混凝土通常產自諸如石灰、無水石膏、水泥、水及矽砂之原材料且可組合支撐結構之性質與隔熱性。高度隔熱砌體建構可經產生具有整體單壁建構中之發泡混凝土。 在一些實施例中,一生產程序可包含磨碎一矽砂直至其在(例如)礫磨機中經磨細具有大於3000之布萊恩值。原料可經組合以形成(例如) 1:1:4之一比率之一砂漿混合物且同時加入水。在一些實施例中,一小部分鋁粉或糊漿可加入至完成之漿料中。可將砂漿混合物倒入其中金屬微粒鋁在鹼性砂漿漿料中形成氫氣之水槽內。可獲得使得逐漸硬化之砂漿發泡之氣泡。15至50分鐘後可獲得最終容積。此時,可獲得三米至八米長、一米至一點五米寬及50釐米至80釐米高之塊體。可使用金屬線將此等固體塊狀物或塊體切割至任何所要尺寸。在一些實施例中,此等塊體可在特殊蒸汽壓力鍋爐(例如,蒸壓釜)中以180° C至200° C之蒸汽溫度在其中該材料在6至12小時之後可含有其最終特性之10巴至12巴之一大氣下經固化。從化學角度來說,發泡混凝土可大部分對應於天然礦質雪矽鈣石,但其可為一合成材料。 除了低熱導率外,該建構材料可由其缺乏易燃性來區分,使得其可(例如)在歐洲消防分類A1中進行分類。現代發泡混凝土成分可含有生石灰、水泥、砂及水之一混合物。取決於烘乾密度及生石灰與水泥之比率,該成分可區分富含石灰及富含水泥之混合物。另外,可使用無水石膏或石膏形式之硫酸鹽載體改良壓縮強度及收縮性質,此係由於雪矽鈣石中之結晶「紙牌屋」結構之改良之生長。由於此等發現,在前數十年已證實加入無水石膏/石膏形式之硫酸鹽載體在生產中係有利的且因此係當前所有發泡混凝土組成物之一成分。 建構材料可通過在混合過程期間加入少量鋁粉而獲得一孔結構。在混合物中細分之鋁可在一鹼性媒介中反應,從而形成可使得原料混合物緩慢起泡之氫氣。此孔結構可留在產品中,即使係在實際熱液固化程序之後,且實質上可對最終產品之特性負責。 在一些實施例中,生產程序可分解為以下動作之一或多者: 1.磨碎矽砂且製備再循環泥漿 2.混合且倒入發泡混凝土泥漿 3.使得粗糙塊狀物或塊體膨脹、凝固且切割該等粗糙塊狀物或塊體 4.在熱液狀況下固化未切割塊體 5.打包且儲存成品 在混合發泡混凝土化合物且將其倒入鋼模具內之後,數個複雜化學反應可在凝固與熱液固化相之間發生。當加入水時,可在混合相期間開始生石灰之氫化。由於此係一放熱反應,所以可加熱發泡混凝土化合物且加速水泥物相之水化反應。因此,可在由氫的生長產生之膨脹期間發生發泡混凝土化合物之一連續硬化。為了獲得一同質孔結構,氣體生長可調整至膨脹發泡混凝土化合物之黏度曲線。若未能達成此步驟,則可在膨脹期間發生所謂之膨脹破裂之結構損壞,此在隨後之生產程序期間可係無法校正的。在數小時之一凝固時間段之後,未切割之塊體可藉由拉緊之金屬線切割成合適岩石構造。在切割程序期間產生之所有廢料可在組成中循環,使得在生產過程期間不存在廢料。 再循環能力之問題在未來至關重要。一方面,歐洲需求要求減少廢料,此伴隨垃圾場之關閉及對更多再循環之一增加之要求。另一方面,對於環境保護具有一增加之需求,諸如最低臨限值及關於地下水/替代建築材料/土壤保護之一覆面法規之框架中之替代建築材料法規之草案指南,此至少在一些情況中使得再循環市場上可用之建築材料變得更困難。可由900 mg/l與1650 mg/l之間之洗出液中之硫酸鹽濃度產生關於硫酸鹽之浸出規律。根據替代建築材料法規,用於洗出液中之基於礦質之替代建築材料之臨限值係250 mg/l硫酸鹽。在生產發泡混凝土中省略硫酸鹽載體及水泥可徹底減少洗出液中之上述硫酸鹽濃度且可能夠將發泡混凝土建構廢料用作為一基於礦質之替代建築材料。 在一些實施例中,使用根據本發明之非水泥基黏結劑可消除此缺點,且此外可具有一十分低之鈣含量。典型技術性質在其他方面可不受影響。預鑄混凝土 一預鑄混凝土部件或混凝土元件係由混凝土、鋼筋混凝土或預應力混凝土組成之一成分,其在一工廠中預先工業化製作且隨後(通常)使用一吊車將其置於最終位置中。廣泛使用且在各種建築技術中實施預鑄混凝土元件及鋼筋混凝土元件。用於開放渠道系統之預鑄元件之生產可用於本發明之一些實施例中。防火 在DIN 4102中列出用於混凝土元件及鋼筋混凝土元件之石膏成品(建築材料及建築元件與火之反應)。技術上適合用於防火之石膏係蛭石及珍珠岩絕緣石膏及根據DIN 18550, Part 2之石膏。 在一些實施例中,一噴射混合物可經供應作為具有一液壓硬化結合劑且在施用前不久與水混合之一乾砂漿——礦質纖維之一混合物,諸如玻璃絲、岩棉或礦物棉。關於防火之技術特性可與噴射石棉之技術特性相同。 在石膏成品中使用非水泥基結合劑可進一步改良防火性,因為一非水泥基結合劑可具有一更有利之膨脹行為且可展現高溫下之較低收縮性。 在本發明之一些實施例中,習知混合器不可用於生產結合劑混合物。在一些實施例中,將一所謂之黏土攪拌器或連續混合器用於生產一預先混合物且隨後將一加強混合器或行星式混合器用於在粒料中混合可導致可在模具中壓縮或圍封且可在一機械壓縮後生產所要產品之一無機材料。 以下提供之表4展示根據本發明之實施例之哪些混合及施用技術可導致用於結合劑混合物之應用之哪些領域。 表4 在本發明之一些實施例中,提供一種用於生產一可模製混凝土化合物之方法。該方法可包含以下動作之一或多者: 該方法可包含供應含有4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一項實例中,該鹼性成分或鹼可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一些實施例中,結合劑混合物中可含有以結合劑混合物中之污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一黏土攪拌器或連續混合器生產結合劑混合物之一預先混合物。在一些實施例中,該方法可進一步包含使用一強力混合器或行星式混合器將預先混合物與20重量%至90重量%之粒料混合以產生一可模製混凝土化合物。在一些實施例中,此可在1分鐘至5分鐘之一時間段內實施。在一項實施例中,此可在大約2分鐘之一時間段內實施。 該方法亦可包含通過壓縮或震動來壓縮可模製混凝土化合物以形成管道、預鑄混凝土元件、鐵枕、混凝土塊體、形成鋪地石、人行道板等等。 在本發明之一些實施例中,提供一種用於生產一可模製混凝土化合物之方法。該方法可包含以下展示之實施例之一或多者。 在一些實施例中,該方法可包含供應包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一些實施例中,該鹼性成分可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一項實例中,結合劑混合物可包含20重量%至90重量%之粒料。在一些實施例中,結合劑混合物中可含有污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一乾式混合器產生一乾式混合物。該方法可進一步包含使用一強力混合器或行星式混合器混合與水產生之乾式混合物以產生一可模製混凝土化合物。 在本發明之一些實施例中,提供一種用於產生一可噴射混凝土化合物之方法。該方法可包含以下展示之實施例之一或多者。 在一些實施例中,該方法可包含供應包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一些實施例中,該鹼性成分可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一些實施例中,結合劑混合物可包含20重量%至90重量%之粒料。在一些實施例中,結合劑混合物中可含有污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一乾式混合器產生一乾式混合物。在一些實施例中,該方法可進一步包含在一噴射槍中混合乾式混合物與水以用於產生且立即施用一可噴射混凝土化合物。 在一些實施例中,可針對不同應用領域製備結合劑混合物,包含(例如)以上表4中所列出。以下提供之實例1至5可繪示本發明之一或多個實施例。 實例1 在具有一擠出螺桿之一混合及捏合機器中,可組合且大力混合1份細磨火山岩(例如,布萊恩值3500)、0.15份飛灰及0.8份矽酸鈉直至獲得一同質可傾倒石膏。 此石膏可在一強力混合器(或行星式混合器)中與4份玄武岩及砂混合約2分鐘。藉此可獲得適合用於在生產混凝土塊體時施用為面混凝土之一土地潮濕無水泥混凝土。 混合物之硫酸鹽含量可達到0.16重量%且氧化鈣含量可為0.8重量%。 可通過(例如)在砌塊成型機器中實踐之壓縮及震動達成此一混合物之壓縮。 所得產品可由顯著較高抗酸性、更有利之機械強度性質及一顯著更強之彩色印刷區分。 當使用其他粒料混合物(諸如砂礫及砂)時,亦可產生混凝土管或特殊預鑄混凝土元件,此取決於一特定粒子尺寸分佈曲線。藉由控制水分含量及調適施用技術(例如,傾倒、離心分離等等),其他產品變動亦可行。 實例2 在一強力混合器中,可混合0.2份粒狀熔渣、1份細磨火山岩及3份砂。可將此乾式混合物置於一袋中。 在一施工現場中,可將依此方式產生之1份混合物在一路面混合物中與0.7份矽酸鈉混合且使其變為所要稠度。 混合物之硫酸鹽含量可高達0.19重量%且氧化鈣含量可為0.57重量%。 以此方式獲得之非水泥基砌塊及抹灰砂漿可以不同方式施用至待塗佈之一表面(例如,藉由習知抹灰、噴射等等)。 實例3 在一乾式混合器中可產生由1份火山灰(例如,大於3500之布萊恩值)、0.4份飛灰、1份珍珠岩及0.7份粉末矽酸鈉構成之一乾式混合物。 可通過與高剪力之強力混合而使得乾式混合物與水濕潤且倒入模具內而經壓縮。 濕潤混合物之硫酸鹽含量可高達0.32重量%且氧化鈣含量可為1.8重量%。 在基於以上實例之一實踐中,在一硬化相之後(在受到一延長時間段之焚燒後)獲得樣本且不顯示破裂或可見裂痕且在測試之後未展現減弱之機械強度性質。在遭受凍結溫度之後也不存在任何明顯損傷。 實例4 在一乾式混合器中,可產生由1份火山灰(例如,大於3500之布萊恩值)、0.4份粒狀熔渣、1份珍珠岩及0.7份粉末矽酸鈉構成之一乾式混合物。 可將乾式混合物連續施加至一噴射槍且可與水組合而產生一可噴射混凝土。可利用噴射技術使得管道及電纜穿墻、熱敏建築材料及表面無困難地經密封或塗佈具有抗熱性及防火非水泥基化合物。 可噴射混凝土之硫酸鹽含量可高達0.31重量%且氧化鈣含量可為1.29重量%。 實例5 為了生產一發泡混凝土,可在一商用混合器中集中地預先混合16.2份火山岩、3.35份飛灰、23份矽砂。此乾式混合物可在38° C之強剪力下增加至33份矽酸鈉,且可進一步在相同混合器中與0.43份鋁漿混合。 可將結合劑混合物倒入一特氟龍模具內且在該模具中加熱120分鐘至80° C。該混合物可變堅硬且同時急劇增加容積但仍然可切割。針對固化,可將該模具置於一固化腔室中且可在180° C之情況下在其內停留30分鐘。替代地,可在120° C之情況下使用一蒸壓釜。 可獲得具有可與根據典型方法獲得之一發泡混凝土比較之光學性質之一模製本體。與典型發泡混凝土不同,該材料可為抗酸的且具有0.21重量%之一硫酸鹽含量及0.6重量%之一氧化鈣含量。在一項實施例中,所得建構材料可具有一十分低之硫酸鹽及鈣含量。 本文使用之術語僅係為了描述特定實施例之目的且不意欲限制本發明。如本文所使用,除非本文另外明確指示,否則單數形式「一」(a、an)及「該」亦意欲包含複數形式。將進一步瞭解,術語「包括」(comprises及/或comprising)當在本說明書中使用時指定存在陳述之特徵、整數、步驟、操作、元件及/或組件,但不排除出現或增加一或多個其他特徵、整數、步驟、操作、元件、組件及/或其群組。 以下申請專利範圍中之所有裝置或步驟附加功能元件之對應結構、材料、動作及等效物意欲包含用於執行與特定提及之其他元件組合之功能之任何結構、材料或動作。本發明之描述係為了繪示及描述之目的呈現但不意欲具有窮舉性或將本發明限制於所揭示之形式。熟習技術者將明白在不違背本發明之範疇及精神之情況下之諸多修改及變動。實施例經選擇及描述以最佳地解釋本發明及實踐應用之原理,且使得一般技術者能夠了解本發明,因為具有各種修改之各種實施例適合設想之特定用途。 因為已詳細描述且參考本申請案之實施例來描述本申請案之發明內容,所以將明白在不違背隨附申請專利範圍中界定之本發明之範疇之情況下,修改及變動係可行的。 CROSS REFERENCE TO RELATED APPLICATIONS This application is a continuation-in-part of U.S. Patent Application Serial No. 14/705,534, filed on Jan. 6, 2015. The full text of the case is incorporated herein by reference. Embodiments of the present invention are directed to systems and methods for constructing materials having an alkali-activated binder (i.e., non-Portland cement based) and for making and applying the building materials. Although many examples contained herein are discussed in the context of concrete retrofitting, it should be noted that the construction materials described herein can be used in any suitable application. Some of these applications may include, but are not limited to, sewer renovation projects, any concrete structures that experience an acid attack, and the like. Referring to Figure 1, there is shown a mobile batch processing and hybrid vehicle 100, the mobile batch processing and hybrid vehicle 100 having a plurality of containers, compartments and devices associated therewith. In some embodiments, vehicle 100 can include a first container 102 that can be configured to store sand or other materials. The storage unit 104 can be configured to store water or other liquid. The vehicle 100 can further include a batch processing and mixing device 106, which can include a number of components, some of which can include, but are not limited to, a second container 108, an adjustable delivery mechanism 110, and a portable gun 212. As shown in FIG. 2, the portable gun 212 can be coupled to the nozzle 214 via a conduit or hose 216. In some embodiments, the mobile batch processing and hybrid vehicle 100 can be configured to batch process, mix, and apply a non-Portland cement based construction material. This material can be batch processed and mixed at the vehicle (e.g., within the batch processing and mixing device 106) prior to placement in the second container 108. This material can be delivered to a nozzle 214 where it can be mixed with the liquid in the storage unit 104 prior to application to the surface when construction or repair is required. The properties of non-Portland cement based construction materials are discussed in further detail below. In some embodiments, the non-Portland cement based building materials described herein may have better strength values, a higher resistance, and are unreactive with inorganic and organic acids and additionally have early high strength values compared to existing materials. Non-Portland cement based construction materials exhibit resistance to one of the high temperatures and significantly higher strength and durability properties. In one example, non-Portland cement based construction materials provide excellent resistance to strong mineral acids. In addition, products derived from non-Portland cement based construction materials can have excellent compressive strength and a very low thermal conductivity. The material may comprise a blast furnace slag material, an inorganic polymer material, a base powder, and a sand dry mix (e.g., a binder mixture) in a batch processing and mixing apparatus to produce a non-Portland cement based material. In some embodiments, the binder mixture can be used to produce the non-Portland cement based material. In some embodiments, a binder mixture may comprise from 4% to 45% by weight of volcanic rock, from 0% to 40% by weight of latent hydraulic material, selected from the group consisting of sodium citrate, alkali metal hydroxides One or more of 10% by weight to 45% by weight of the alkali component of the alkali metal carbonate and the like, and 20% by weight to 90% by weight of the pellet. In some embodiments, the binder mixture can comprise a sulfate (SO 4 2- ) in a proportion of less than 1% by weight of the contaminant. In some embodiments, the binder mixture may contain calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. In some embodiments, the non-Portland cement based building material can comprise various types of inorganic polymeric materials. The inorganic polymeric material can include, but is not limited to, volcanic rock. Thus, the terms "inorganic polymeric material" and "volcanic rock" may be used interchangeably within the scope of the present invention. One portion of such inorganic polymeric materials may include, but is not limited to, pozzolanic materials that can react with a strong base and cause the blend to be mixed with sand and/or grit. The volcanic ash or pozzolanic material may be a synthetic or natural rock composed of cerium oxide, clay, limestone, iron oxide, and an alkaline material that can be obtained by thermal effects. When combined with calcium hydroxide and water, they can form a binding agent. Natural pozzolana may be magmatic rocks, such as tuff or German rheology pumice, but may also be sedimentary rocks containing a high proportion of soluble tannic acid, and sometimes reactive alumina (clay). In some embodiments, the pozzolan may be a readily available raw material and may be used as a volcanic rock or inorganic polymeric material in a non-Portland cement based building material. However, natural materials such as volcanic rock or some other substance may also be used, and if a small portion is used as a very fine powder (for example, such a volcanic rock powder), it is more desirable to use such natural materials. In some embodiments, the non-Portland cement based construction material may comprise any number of pozzolanic materials, some of which may include, but are not limited to, finely ground clay, gneiss, granite, rhyolite, andesite, peridotite , potassium feldspar, albite, pumice, zeolite, etc. and mixtures thereof. These materials can be used in the form of one of calcined and/or non-calcined geotechnical. Additionally and/or alternatively, all raw materials (including, but not limited to, ash, pozzolan, slag) containing sufficient reactivity (eg, metastable glass) of SiO 2 and Al 2 O 3 may also be suitable for use. Embodiments of the invention. In some embodiments, the non-Portland cement based construction material can comprise a latent hydraulic material. One of the potentially hydraulic materials used herein may include, but is not limited to, fly ash, kaolin, pumice tuff, particulate slag (eg, blast furnace slag material), and/or mixtures thereof. In one example, fly ash in the form of lignite fly ash and anthracite fly ash can be used. In some embodiments, the pozzolanic material may comprise an active citrate, such as slag sand or fly ash. In some embodiments, brick ash (refractory clay) or fly ash from plants burning anthracite or lignite may be referred to as synthetic ash. Thus, the term "flying ash" as used herein may refer to a non-natural or synthetic volcanic ash. In some embodiments, certain advantageous properties of fly ash may be caused by a favorable ratio of cerium oxide to one of alumina and calcium oxide, which may distinguish such materials. However, and as will be discussed in more detail below, the fly ash may contain a portion of the sulfate and/or calcium oxide. Therefore, if fly ash is used in the binder mixture, one type of fly ash containing a specified substance having a favorable ratio can be used. In some embodiments, the non-Portland cement based building material can comprise a one base powder material and/or various mixed liquids. Some possible mixed liquids may include, but are not limited to, potassium and soda water glasses, alkali metal hydroxides, and the like. In some embodiments, the base or alkaline component can be in the form of an aqueous solution of sodium citrate or a sodium citrate in the form of a powdered sodium citrate. In some embodiments, a spray dried citrate can be used. When an alkali metal hydroxide or an alkali metal carbonate is used, these materials may be used in their liquid form or in a powder or granule form. In some embodiments, the reaction between the SiO 2 /Al 2 O 3 containing component and the alkaline mixed liquid can result in a yttrium aluminate having a three dimensional structure. These frameworks allow the creation of one of the Portland cement-free construction materials in their compounds. As discussed above, the components of the binder mixture and/or binder mixture can comprise calcium. In some embodiments, the binder mixture can contain calcium in the form of partial calcium oxide (CaO). Such CaO moieties in the binder mixture and/or non-Portland cement based building material may result in hydration of calcium citrate after reaction with an aqueous base and/or component, which may have known adverse chemical properties. In addition, calcium ions, which are a component of the cement-based crystalline structure, generally exhibit an undesirable solubility which can result in weakening of one of the cement structures over time. For this reason a minimum possible proportion of calcium can be used. Embodiments of the invention utilizing soluble citric acid in the form of SiO 2 , iron oxide, aluminate in the form of Al 2 O 3 and calcium oxide can be carried out with a water-soluble decanoate or a strong base, thus resulting in less calcium Or almost no calcium one of the inorganic binding systems. In some embodiments, the binder mixture may contain calcium oxide (CaO) form and have a ratio of up to 5% by weight calcium. In some embodiments, the binder mixture may contain calcium in the form of calcium and have a ratio of up to 2% by weight of calcium. Additionally and/or alternatively, calcium may be included in the form of calcium oxide and having a ratio of up to 1% by weight. In some embodiments, the binder mixture may contain a form of contaminants and/or a sulfate (SO 4 -2 ) in a proportion of less than 1% by weight. Sulfate in the form of its salt is an environmentally relevant substance. Contaminants with an increased environment of sulphate are caused by agricultural fertilization and waste management. Sulfate has been shown to cause acidification of land and groundwater. Since sulfate is generally more soluble in water, it is easily transported in groundwater, seepage and surface water streams, ultimately increasing the acidification effect in the environment of the sulfate-containing material in the waste storage facility. The decomposition of sulphate into sulfite by a microbial procedure can have a negative effect on plants and animals. In some embodiments, the proportion of sulfate in the binder mixture can be reduced as much as possible to at least avoid such negative effects. In some embodiments, the binder mixture may contain contaminants and/or sulfates (SO 4 -2 ) in a proportion of less than 0.5% by weight. In one embodiment, a sulfate (SO 4 -2 ) having a ratio of less than 0.25 wt% may be included. In some embodiments, the non-Portland cement based building material can comprise sand. However, other pellets can also be used. For example, other pellets used as a non-cement based concrete in a binder mixture may include, but are not limited to, gravel, sand, basalt, and the like. Other materials for non-cement based concrete within the scope of the present invention may also be used. Alternatively and in various applications, a mixture of perlite, expanded rock, pumice or the like may also be used. In some embodiments, the binder mixture can comprise from 20% to 70% by weight of the pellets. Additionally and/or alternatively, from 20% to 50% by weight of the pellets may be included in the binder mixture. In one embodiment, from 20% to 40% by weight of the pellets may be included in the binder mixture. In some embodiments, the binder mixture can also contain water. Thus, in one embodiment, from 4% to 45% by weight of volcanic rock (eg, inorganic polymeric material), 0% to 40% by weight of potentially hydraulic material (eg, blast furnace slag material) a 10% to 45% by weight of an alkaline component (for example a base), 20% to 90% by weight of a pellet (for example sand) and/or water, one of which forms a binder mixture for various chemicals and especially Extremely high resistance to one of the acids. In some embodiments, the alkaline component can comprise sodium citrate, an alkali metal hydroxide, and/or an alkali metal carbonate. Additionally and/or alternatively, the binder mixture may comprise a sulfate form (SO 4 2- ) in the form of a contaminant and/or in a proportion of less than 1% by weight. In some embodiments, the binder mixture can comprise calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. In operation, the feedstock can be roughly processed batchwise and mixed (eg, wholly or partially in the vehicle 100) and then transferred to the portable gun 212. The non-Portland cement based building material can be carried through conduit 216 to nozzle 214 via compressed air. In a particular embodiment, potassium citrate, solids content 48%, density 1,52 g/cm3, Wt SiO2:K2O 1,14 and some liquids may be added and a portion of the liquefied mixture is pneumatically applied to the surface of interest. Rough mixing is previously performed within nozzle 214 for a short period of time (eg, less than 1 second). Embodiments included herein may comprise a mixture comprising some or all of the following: slag (eg, non-natural pozzolan, base or latent hydraulic material), fly ash (eg, non-natural pozzolans and options in formulations), inorganic Polymers (eg, natural pozzolans and options, ground volcanic materials/volcanic rocks), alkali/alkaline ingredients (eg, powder or liquid), other liquids containing water (optional) and sand/grit or other pellets. Examples of specific mixtures are provided below, however, it should be noted that the specific mixtures provided herein are included by way of example only. Several additional and alternative embodiments are also within the scope of the invention. In a particular example, the non-Portland cement based construction material can include the following mixtures: Table 1 In some embodiments, the ingredients of the mixture may comprise a Brian fineness value of from about 2500 cm 2 /g to 5000 cm 2 /g. The Brian value is used for one of the standard measurements of cement chalking. The Brian value is given as a specific surface value (cm 2 /g) determined in a laboratory using a Bryan device. For example, standard Portland cement (CEM I 32.5) has a Brian value of 3,000 to 4,500. In some embodiments, the composition of the binder mixture, volcanic rock, and/or latent hydraulic material can be used in a finely ground state of one of the Brian values of greater than 3,000. In one embodiment, the volcanic rock and/or the latent hydraulic material may have a Brian value of greater than 3,500. Fine grinding of the ingredients can result in a significantly improved reaction rate. Finely ground volcanic rock can be more manageable and can further contribute to increased resistance to one of a variety of different chemicals in the finished product, especially to acids. In another example, the non-Portland cement based construction material can include the following mixtures: Table 2 In another example, the non-Portland cement based building material can include the following mixtures: Table 3 In some embodiments, from 4% to 45% by weight of volcanic rock, 0% by weight (or more than 0% by weight) to 40% by weight of latent hydraulic material may be used, compared to a hydraulic hardening binder, The reaction of 10% to 45% by weight of one of the alkaline components and 20% to 90% by weight of the pellets produces one of the non-Portland cement based building materials or the binder mixture. In some embodiments, the alkaline component can comprise sodium citrate, an alkali metal hydroxide, and/or an alkali metal carbonate. Additionally, the binder mixture may comprise a sulfate form (SO 4 2- ) in the form of contaminants and/or in a proportion of less than 1% by weight. In some embodiments, the binder mixture may contain calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. An example of a non-Portland cement based construction material produces an unexpected result because the reaction time of the alkaline material with the rock powder is sufficient to produce a viscous compound. Through several tests, it was found that the compound adhered extremely strongly to a vertical surface, establishing a tight bond and hardening within 3 days with a compressive strength value of about 50 N/mm 2 (8000 psi). In some embodiments, a binder mixture or a non-Portland cement based construction material can be used in various technical fields of application: dry mortar, gypsum, and shotcrete can produce dry mortar and gypsum mixtures by mixing dry ingredients. For this purpose, spray-dried reactive phthalates or alkali metal hydroxides can be used. Based on this, the finished mixture can be produced as shotcrete for its use. Foamed concrete Commercial foamed concrete is one of the original density of 300 kg/m 3 to 800 kg/m 3 based on mineral-based autoclaved foamed bulk construction materials. Foamed concrete is usually produced from raw materials such as lime, anhydrite, cement, water and strontium and can combine the properties and thermal insulation of the support structure. The highly insulated masonry construction can result in a foamed concrete having an integral single wall construction. In some embodiments, a production procedure can include grinding a slaked sand until it is ground in, for example, a gravel mill having a Brian value greater than 3,000. The feedstocks can be combined to form a mortar mixture of, for example, one of a ratio of 1:1:4 while adding water. In some embodiments, a small portion of aluminum powder or paste can be added to the finished slurry. The mortar mixture can be poured into a water tank in which metal particulate aluminum forms hydrogen in the alkaline mortar slurry. Bubbles which foam the gradually hardened mortar can be obtained. The final volume is obtained after 15 to 50 minutes. At this time, a block of three meters to eight meters long, one meter to 1.5 meters wide, and 50 cm to 80 cm high can be obtained. These solid blocks or blocks can be cut to any desired size using metal wires. In some embodiments, the blocks may be in a special steam pressure boiler (eg, autoclave) at a steam temperature of 180 ° C to 200 ° C in which the material may contain its final characteristics after 6 to 12 hours. It is cured in the atmosphere of 10 to 12 bar. From a chemical point of view, foamed concrete can mostly correspond to natural mineral slaked calcite, but it can be a synthetic material. In addition to low thermal conductivity, the construction material can be distinguished by its lack of flammability such that it can be classified, for example, in the European Fire Protection Classification A1. Modern foamed concrete components can contain a mixture of quicklime, cement, sand, and water. Depending on the drying density and the ratio of quicklime to cement, this component distinguishes between lime-rich and cement-rich mixtures. Alternatively, a sulfate carrier in the form of anhydrite or gypsum can be used to improve the compressive strength and shrinkage properties due to the improved growth of the crystalline "card house" structure in the ferrets. As a result of these findings, it has been demonstrated in the past few decades that the addition of a sulfate carrier in the form of anhydrite/gypsum is advantageous in production and is therefore a component of all currently foamed concrete compositions. The build material can be obtained by adding a small amount of aluminum powder during the mixing process to obtain a pore structure. The aluminum subdivided in the mixture can be reacted in an alkaline medium to form hydrogen which allows the raw material mixture to slowly foam. This pore structure can be left in the product, even after the actual hydrothermal curing process, and is essentially responsible for the properties of the final product. In some embodiments, the production process can be broken down into one or more of the following actions: 1. Milling the ceramsite and preparing the recycled mud 2. Mixing and pouring into the foamed concrete slurry 3. Making the coarse mass or block Expanding, solidifying and cutting the rough mass or block 4. Curing the uncut block under hydrothermal conditions 5. Packing and storing the finished product After mixing the foamed concrete compound and pouring it into the steel mold, several Complex chemical reactions can occur between solidification and hydrothermal solidification. When water is added, the hydrogenation of the quicklime can be initiated during the mixing phase. Since this is an exothermic reaction, the foamed concrete compound can be heated and the hydration reaction of the cement phase can be accelerated. Therefore, one of the foamed concrete compounds can be continuously hardened during the expansion caused by the growth of hydrogen. In order to obtain a homogenous pore structure, the gas growth can be adjusted to the viscosity curve of the expanded foamed concrete compound. If this step is not achieved, structural damage such as expansion cracking can occur during expansion, which can be uncorrected during subsequent production procedures. After one of several hours of solidification, the uncut block can be cut into a suitable rock configuration by tensioning the wire. All waste generated during the cutting process can be cycled through the composition such that no waste is present during the production process. The issue of recycling capacity is critical in the future. On the one hand, European demand calls for reduced waste, which is accompanied by the closure of the landfill and the requirement for an increase in one of the more recycling. On the other hand, there is an increasing demand for environmental protection, such as minimum thresholds and draft guidelines for alternative building materials regulations in the framework of groundwater/alternative building materials/soil protection, which is at least in some cases. Making building materials available on the recycling market more difficult. The leaching rule for sulfate can be generated from the sulfate concentration in the eluate between 900 mg/l and 1650 mg/l. According to alternative building material regulations, the threshold for mineral-based alternative building materials used in eluates is 250 mg/l sulphate. Omission of the sulfate carrier and cement in the production of foamed concrete can completely reduce the above-mentioned sulfate concentration in the eluate and can be used as a substitute building material based on minerals. In some embodiments, the use of a non-cement based binder according to the present invention eliminates this disadvantage and, in addition, can have a very low calcium content. Typical technical properties may not be affected in other respects. Concrete A concrete component or concrete component consists of concrete, reinforced concrete or prestressed concrete, which is pre-industrialized in a factory and then (usually) placed in a final position using a crane. It is widely used and implements concrete components and reinforced concrete elements in various building technologies. The production of tantalum elements for open channel systems can be used in some embodiments of the invention. Fire protection Gypsum finished products (reactions of building materials and building elements with fire) for concrete elements and reinforced concrete elements are listed in DIN 4102. Gypsum-based vermiculite and perlite-insulated gypsum technically suitable for fire protection and gypsum according to DIN 18550, Part 2. In some embodiments, a spray mixture can be supplied as a dry mortar, one of mineral fibers, such as glass wool, rock wool or mineral wool, having a hydraulic hardening binder and mixed with water shortly before application. The technical characteristics of fire protection can be the same as those of jetted asbestos. The use of a non-cement based binder in the finished gypsum further improves the fire resistance because a non-cement based binder can have a more favorable expansion behavior and can exhibit lower shrinkage at elevated temperatures. In some embodiments of the invention, conventional mixers are not useful for producing a binder mixture. In some embodiments, a so-called clay mixer or continuous mixer is used to produce a premix and then a reinforcing mixer or planetary mixer for mixing in the pellets can result in compression or encapsulation in the mold. And an inorganic material of one of the desired products can be produced after mechanical compression. Table 4, provided below, shows which mixing and application techniques according to embodiments of the present invention can result in which fields of application for the binder mixture. Table 4 In some embodiments of the invention, a method for producing a moldable concrete compound is provided. The method may comprise one or more of the following: The method may comprise supplying from 4% to 45% by weight of volcanic rock, from 0% to 40% by weight of the latent hydraulic material, from 10% to 45% by weight A binder mixture of one or more of the alkaline components. In one example, the basic component or base can be selected from the group and/or can comprise: sodium citrate, an alkali metal hydroxide, an alkali metal carbonate, and the like. In some embodiments, the binder mixture may contain a sulfate (SO 4 2- ) in the form of a contaminant in the binder mixture and having a ratio of less than 1% by weight. Additionally, the binder mixture may contain calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. The method may also comprise producing a premix of one of the binder mixtures using a clay mixer or a continuous mixer. In some embodiments, the method can further comprise mixing the pre-mix with 20% to 90% by weight of the pellets using a strong mixer or planetary mixer to produce a moldable concrete compound. In some embodiments, this can be performed in one of 1 minute to 5 minutes. In one embodiment, this can be performed in one of about 2 minutes. The method may also include compressing the moldable concrete compound by compression or vibration to form a pipe, concrete element, iron pillow, concrete block, paving stone, sidewalk board, and the like. In some embodiments of the invention, a method for producing a moldable concrete compound is provided. The method can include one or more of the embodiments shown below. In some embodiments, the method can include supplying a volcanic rock comprising from 4% to 45% by weight, from 0% to 40% by weight of the latent hydraulic material, from 10% to 45% by weight of one of the alkaline ingredients or One of the many binder mixtures. In some embodiments, the alkaline component can be selected from the group and/or can comprise: sodium citrate, an alkali metal hydroxide, an alkali metal carbonate, and the like. In one example, the binder mixture can comprise from 20% to 90% by weight of the pellets. In some embodiments, the binder mixture may contain a sulfate (SO 4 2- ) in the form of a contaminant and having a ratio of less than 1% by weight. Additionally, the binder mixture may contain calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. The method can also include producing a dry mixture using a dry mixer. The method can further comprise mixing a dry mixture with water using a strong mixer or a planetary mixer to produce a moldable concrete compound. In some embodiments of the invention, a method for producing a sprayable concrete compound is provided. The method can include one or more of the embodiments shown below. In some embodiments, the method can include supplying a volcanic rock comprising from 4% to 45% by weight, from 0% to 40% by weight of the latent hydraulic material, from 10% to 45% by weight of one of the alkaline ingredients or One of the many binder mixtures. In some embodiments, the alkaline component can be selected from the group and/or can comprise: sodium citrate, an alkali metal hydroxide, an alkali metal carbonate, and the like. In some embodiments, the binder mixture can comprise from 20% to 90% by weight of the pellets. In some embodiments, the binder mixture may contain a sulfate (SO 4 2- ) in the form of a contaminant and having a ratio of less than 1% by weight. Additionally, the binder mixture may contain calcium in a proportion of up to 5% by weight of the calcium oxide (CaO) form. The method can also include producing a dry mixture using a dry mixer. In some embodiments, the method can further comprise mixing the dry mixture with water in a spray gun for producing and immediately applying a sprayable concrete compound. In some embodiments, the binder mixture can be prepared for different fields of application, including, for example, those listed in Table 4 above. Examples 1 through 5 provided below may illustrate one or more embodiments of the invention. Example 1 In a mixing and kneading machine having one of the extrusion screws, 1 part of finely ground volcanic rock (for example, Brian value 3500), 0.15 parts of fly ash, and 0.8 part of sodium citrate can be combined and vigorously mixed until a homogenous mass is obtained. Pour the plaster. This gypsum can be mixed with 4 parts of basalt and sand in an intensive mixer (or planetary mixer) for about 2 minutes. In this way, it is possible to obtain a moist, cement-free concrete suitable for use in the application of concrete as a concrete when producing concrete blocks. The mixture may have a sulfate content of 0.16% by weight and a calcium oxide content of 0.8% by weight. Compression of this mixture can be achieved, for example, by compression and vibration practiced in a block forming machine. The resulting product can be distinguished by significantly higher acid resistance, more favorable mechanical strength properties, and a significantly stronger color print. When other pellet mixtures (such as gravel and sand) are used, concrete pipes or special concrete elements can also be produced, depending on a particular particle size distribution curve. Other product changes can also be made by controlling the moisture content and adapting the application technique (eg, pouring, centrifuging, etc.). Example 2 In an intensive mixer, 0.2 parts of granular slag, 1 part of finely ground volcanic rock and 3 parts of sand were mixed. This dry mixture can be placed in a bag. In a construction site, one part of the mixture produced in this manner can be mixed with 0.7 parts of sodium citrate in a pavement mixture and brought to the desired consistency. The mixture may have a sulfate content of up to 0.19% by weight and a calcium oxide content of 0.57% by weight. The non-cement-based blocks and plasters obtained in this manner can be applied to one surface to be coated in different ways (e.g., by conventional plastering, spraying, etc.). Example 3 A dry blend of one volcanic ash (e.g., a Brian value greater than 3,500), 0.4 parts fly ash, 1 part perlite, and 0.7 part powdered sodium citrate can be produced in a dry mixer. The dry mixture can be compressed by wetting it with water and wetting it with water and pouring it into the mold. The wet mixture may have a sulfate content of up to 0.32% by weight and a calcium oxide content of 1.8% by weight. In one practice based on the above examples, the sample was obtained after a hardened phase (after being incinerated for an extended period of time) and showed no cracks or visible cracks and did not exhibit attenuated mechanical strength properties after testing. There is also no significant damage after being subjected to freezing temperatures. Example 4 In a dry mixer, a dry mixture of one part of pozzolan (e.g., a Brian value greater than 3,500), 0.4 parts of granulated slag, one part of perlite, and 0.7 part of sodium citrate was produced. The dry mixture can be continuously applied to a spray gun and combined with water to produce a sprayable concrete. Jet technology can be used to seal pipes or cables through walls, heat-sensitive building materials and surfaces without difficulty to seal or coat non-cement-based compounds with heat resistance and fire resistance. The sprayable concrete may have a sulfate content of up to 0.31% by weight and a calcium oxide content of 1.29% by weight. Example 5 To produce a foamed concrete, 16.2 parts of volcanic rock, 3.35 parts of fly ash, and 23 parts of strontium sand were pre-mixed in a commercial mixer. This dry mixture can be increased to 33 parts of sodium citrate at a strong shear force of 38 ° C and can be further mixed with 0.43 parts of aluminum paste in the same mixer. The binder mixture can be poured into a Teflon mold and heated in the mold for 120 minutes to 80 ° C. The mixture can be hard and at the same time dramatically increase the volume but still cut. For curing, the mold can be placed in a curing chamber and can be held therein for 30 minutes at 180 ° C. Alternatively, an autoclave can be used at 120 ° C. A molded body having one of optical properties comparable to one of the foamed concrete obtained according to a typical method can be obtained. Unlike typical foamed concrete, the material may be acid resistant and have a sulfate content of 0.21% by weight and a calcium oxide content of 0.6% by weight. In one embodiment, the resulting construction material can have a very low sulfate and calcium content. The terminology used herein is for the purpose of describing particular embodiments and is not intended to limit the invention. The singular forms "a", "an" and "the" are intended to include the plural. It will be further understood that the term "comprises" and / or "comprising", when used in this specification, is intended to mean the presence of the recited features, integers, steps, operations, components and/or components, but does not exclude the occurrence or addition of one or more Other features, integers, steps, operations, components, components, and/or groups thereof. The structure, materials, acts, and equivalents of all of the means or steps of the present invention are intended to include any structure, material or action for performing the function in combination with other elements specifically mentioned. The description of the present invention has been presented for purposes of illustration and description. A person skilled in the art will recognize many modifications and variations without departing from the scope and spirit of the invention. The embodiments were chosen and described in order to best explain the invention and the embodiments of the invention Since the invention of the present application has been described in detail with reference to the embodiments of the present invention, it will be understood that modifications and variations are possible without departing from the scope of the invention as defined in the appended claims.

100‧‧‧行動分批處理及混合車輛100‧‧‧Action batch processing and hybrid vehicles

102‧‧‧第一容器102‧‧‧First container

104‧‧‧儲存單元104‧‧‧ storage unit

106‧‧‧分批處理及混合裝置106‧‧‧ batch processing and mixing device

108‧‧‧第二容器108‧‧‧Second container

110‧‧‧可調整傳遞機構110‧‧‧Adjustable transmission mechanism

212‧‧‧可攜帶槍212‧‧‧Can carry a gun

214‧‧‧噴嘴214‧‧‧ nozzle

216‧‧‧導管或軟管216‧‧‧catheter or hose

圖1係根據本發明之一實施例之經構形以分批處理、混合及施用一非水泥基材料之一行動系統之一側視圖; 圖2係根據本發明之一實施例之經構形以分批處理、混合及施用一非水泥基材料之一行動系統之一側視後視圖;且 圖3係描繪根據本發明之一實施例之符合一非水泥基施用程序之操作之一流程圖。 各種圖式中之相同參考符號可指示相同元件。1 is a side elevational view of one of the mobile systems configured to batch process, mix and apply a non-cement based material in accordance with an embodiment of the present invention; FIG. 2 is a configuration of an embodiment of the present invention. A side view rear view of one of the non-cement based materials operating systems in batch processing, mixing and application; and FIG. 3 depicts a flow chart of operation in accordance with a non-cement based application procedure in accordance with an embodiment of the present invention. . The same reference symbols in the various drawings may indicate the same elements.

Claims (32)

一種用於施用一建構材料之方法,其包括: 在一分批處理及混合裝置中混合高爐熔渣材料、無機聚合物材料、鹼及砂以產生一非波特蘭水泥基材料; 將該非波特蘭水泥基材料自該分批處理及混合裝置通過一導管輸送至一噴嘴; 將該輸送之非波特蘭水泥基材料與液體在該噴嘴處組合以產生一部分液化之非波特蘭水泥基材料;且 將該部分液化之非波特蘭水泥基材料氣動式地施用至一表面。A method for applying a construction material, comprising: mixing a blast furnace slag material, an inorganic polymer material, an alkali and sand in a batch processing and mixing device to produce a non-Portland cement based material; The Portland cement-based material is conveyed from the batch processing and mixing device through a conduit to a nozzle; the transported non-Portland cement-based material is combined with the liquid at the nozzle to produce a portion of the liquefied non-Portland cement base Material; and the partially liquefied non-Portland cement based material is pneumatically applied to a surface. 如請求項1之方法,其中該非波特蘭水泥基材料包含4重量%至45重量%之無機聚合物材料。The method of claim 1, wherein the non-Portland cement based material comprises from 4% to 45% by weight of the inorganic polymeric material. 如請求項2之方法,其中該非波特蘭水泥基材料包含大於0重量%至40重量%之高爐熔渣材料。The method of claim 2, wherein the non-Portland cement based material comprises greater than 0% to 40% by weight of the blast furnace slag material. 如請求項3之方法,其中該非波特蘭水泥基材料包含10重量%至45重量%之鹼。The method of claim 3, wherein the non-Portland cement based material comprises from 10% to 45% by weight of a base. 如請求項4之方法,其中該非波特蘭水泥基材料包含20重量%至90重量%之砂。The method of claim 4, wherein the non-Portland cement based material comprises from 20% to 90% by weight sand. 如請求項5之方法,其中該非波特蘭水泥基材料包含小於1重量%之硫酸鹽。The method of claim 5, wherein the non-Portland cement based material comprises less than 1% by weight of sulfate. 如請求項6之方法,其中該非波特蘭水泥基材料包含至多5重量%之氧化鈣。The method of claim 6, wherein the non-Portland cement based material comprises up to 5% by weight of calcium oxide. 如請求項1之方法,其中該高爐熔渣包含飛灰、高嶺土、浮石凝灰岩及粒狀熔渣之一或多者。The method of claim 1, wherein the blast furnace slag comprises one or more of fly ash, kaolin, pumice tuff, and granular slag. 如請求項1之方法,其中該鹼包含矽酸鈉、鹼金屬類氫氧化物及鹼金屬碳酸鹽之一或多者。The method of claim 1, wherein the base comprises one or more of sodium citrate, an alkali metal hydroxide, and an alkali metal carbonate. 一種用於施用一建構材料之系統,該系統包括: 一分批處理及混合裝置,其經構形以混合高爐熔渣材料、無機聚合物材料、鹼基粉末及砂以產生一非波特蘭水泥基材料,該非波特蘭水泥基材料包含以下一或多者: 4重量%至45重量%之無機聚合物材料; 大於0重量%至40重量%之高爐熔渣材料; 10重量%至45重量%之鹼; 20重量%至90重量%之砂; 小於1重量%之硫酸鹽;及 至多5重量%之氧化鈣; 一導管,其經構形以自該分批處理及混合裝置輸送該非波特蘭水泥基材料;及 一噴嘴,其經構形以接收該非波特蘭水泥基材料且將該輸送之非波特蘭水泥基材料與液體組合以產生一部分液化之非波特蘭水泥基材料,其中該噴嘴進一步經構形以將該部分液化之非波特蘭水泥基材料氣動式地施用至一表面。A system for applying a construction material, the system comprising: a batch processing and mixing device configured to mix a blast furnace slag material, an inorganic polymer material, a base powder, and sand to produce a non-Portland a cement-based material comprising one or more of the following: 4% to 45% by weight of an inorganic polymer material; more than 0% to 40% by weight of a blast furnace slag material; 10% to 45% 8% by weight to 90% by weight of sand; less than 1% by weight of sulphate; and up to 5% by weight of calcium oxide; a conduit configured to deliver the non-particulation from the batch processing and mixing device a Portland cement based material; and a nozzle configured to receive the non-Portland cement based material and combine the transported non-Portland cement based material with a liquid to produce a portion of the liquefied non-Portland cement based A material, wherein the nozzle is further configured to pneumatically apply the partially liquefied non-Portland cement based material to a surface. 如請求項10之系統,其中該高爐熔渣包含飛灰、高嶺土、浮石凝灰岩及粒狀熔渣之一或多者。The system of claim 10, wherein the blast furnace slag comprises one or more of fly ash, kaolin, pumice tuff, and granular slag. 如請求項10之系統,其中該鹼包含矽酸鈉、鹼金屬類氫氧化物及鹼金屬碳酸鹽之一或多者。The system of claim 10, wherein the base comprises one or more of sodium citrate, an alkali metal hydroxide, and an alkali metal carbonate. 一種結合劑混合物,其包括: 4重量%至45重量%之火山岩; 大於0重量%至40重量%之潛在水硬材料; 10重量%至45重量%之一鹼性成分; 20重量%至90重量%之粒料; 小於1重量%之硫酸鹽;及 至多5重量%之鈣。A binder mixture comprising: 4% to 45% by weight of volcanic rock; greater than 0% to 40% by weight of latent hydraulic material; 10% to 45% by weight of one alkaline component; 20% to 90% % by weight of granules; less than 1% by weight of sulphate; and up to 5% by weight of calcium. 如請求項13之結合劑混合物,其中該鹼性成分包含矽酸鈉、鹼金屬類氫氧化物及鹼金屬碳酸鹽之一或多者。The binder mixture of claim 13, wherein the alkaline component comprises one or more of sodium citrate, an alkali metal hydroxide, and an alkali metal carbonate. 如請求項14之結合劑混合物,其中該鹼性成分係矽酸鈉。The binder mixture of claim 14, wherein the alkaline component is sodium citrate. 如請求項15之結合劑混合物,其中該矽酸鈉係一水溶液矽酸鈉、一粉末矽酸鈉及一噴霧乾燥矽酸鹽之一者。The combination of claim 5, wherein the sodium citrate is one of aqueous sodium citrate, one powder of sodium citrate, and one spray dried citrate. 如請求項13之結合劑混合物,其中該結合劑混合物中之該硫酸鹽係污染物之形式。The binder mixture of claim 13, wherein the sulfate mixture is in the form of a sulfate-based contaminant. 如請求項13之結合劑混合物,其中該結合劑混合物中之該硫酸鹽小於0.5重量%。The binder mixture of claim 13, wherein the sulfate in the binder mixture is less than 0.5% by weight. 如請求項13之結合劑混合物,其中該結合劑混合物中之該鈣係氧化鈣之形式。The binder mixture of claim 13, wherein the calcium-based calcium oxide is in the binder mixture. 如請求項13之結合劑混合物,其中該結合劑混合物中之該鈣為至多2重量%。The binder mixture of claim 13, wherein the calcium in the binder mixture is at most 2% by weight. 如請求項13之結合劑混合物,其中該火山岩係火山灰。The binder mixture of claim 13, wherein the volcanic rock is volcanic ash. 如請求項13之結合劑混合物,其中該潛在水硬材料包含褐煤飛灰、無煙煤飛灰、高嶺土及浮石凝灰岩之一或多者。The binder mixture of claim 13, wherein the latent hydraulic material comprises one or more of lignite fly ash, anthracite fly ash, kaolin, and pumice tuff. 如請求項13之結合劑混合物,其中該粒料包含砂礫、砂、玄武岩、珍珠岩及膨脹葉岩之一或多者。The binder mixture of claim 13, wherein the pellet comprises one or more of gravel, sand, basalt, perlite, and expanded rock. 如請求項13之結合劑混合物,其中該火山岩及/或該潛在水硬材料具有大於3000之一布萊恩值。The combination of claimants of claim 13, wherein the volcanic rock and/or the latent hydraulic material has a Brian value greater than 3,000. 如請求項13之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至70重量%。The binder mixture of claim 13, wherein the pellets in the binder mixture are from 20% to 70% by weight. 如請求項13之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至50重量%。The binder mixture of claim 13, wherein the pellets in the binder mixture are from 20% to 50% by weight. 如請求項13之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至40重量%。The binder mixture of claim 13, wherein the pellets in the binder mixture are from 20% to 40% by weight. 如請求項13之結合劑混合物,其進一步包括水。The binder mixture of claim 13, which further comprises water. 一種用於產生一可噴射混凝土化合物之方法,其包括: 使用一乾式混合器混合4重量%至45重量%之火山岩、大於0重量%至40重量%之潛在水硬材料、10重量%至45重量%之鹼性成分及20重量%至90重量%之粒料之一或多者以產生一乾式結合劑混合物; 在一噴嘴處將該乾式結合劑混合物與水組合以產生一可噴射混凝土化合物。A method for producing a sprayable concrete compound, comprising: mixing 4% to 45% by weight of volcanic rock, more than 0% to 40% by weight of latent hydraulic material, 10% to 45% using a dry mixer One or more of a weight percent alkaline component and from 20% to 90 weight percent of the pellets to produce a dry binder mixture; the dry binder mixture is combined with water at a nozzle to produce a sprayable concrete compound . 如請求項29之方法,其中該乾式結合劑混合物包含小於1重量%之硫酸鹽。The method of claim 29, wherein the dry binder mixture comprises less than 1% by weight of sulfate. 如請求項29之方法,其中該乾式結合劑混合物包含小於5重量%之鈣。The method of claim 29, wherein the dry binder mixture comprises less than 5% by weight calcium. 一種用於產生一可模製混凝土化合物之方法,其包括: 使用一乾式混合器混合4重量%至45重量%之火山岩、大於0重量%至40重量%之潛在水硬材料、10重量%至45重量%之鹼性成分及20重量%至90重量%之粒料之一或多者以產生一乾式結合劑混合物; 使用一行星式混合器將該乾式結合劑混合物與水組合以產生一可模製混凝土化合物。A method for producing a moldable concrete compound, comprising: mixing 4% to 45% by weight of volcanic rock, more than 0% to 40% by weight of latent hydraulic material, and 10% by weight to a dry mixer 45% by weight of the alkaline component and 20% to 90% by weight of the pellets to produce a dry binder mixture; the dry binder mixture is combined with water using a planetary mixer to produce a Molded concrete compound.
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