TW201779B - - Google Patents

Description

5. Description of the invention (1) A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs. Non-staining, modernization, extension, adaptation, and special agents make the low room need to be anticipated. Hard can be hard to choose the agent, fat conversion-located in the storage and demand lead and the agent section is also alcohol selection and preparation of resin is often hard, this need is due to the order of sulfur. Hard Oxygen Tree and Tongzhong are sticky because they don't need to be limited. It is worth the potential. Law, and wait for-the difference between the number of fats and amines will be different after the use is different. May want to make special solution. The piece needs to be produced with an anti-cobalt ring, and it is connected to a fat strip in the local body of the adhesive. Phased rubber grades in point-stage stains, He Heshu and anaerobic control agents have hardware and B. Defective C. Pre-ordered pre-mixed oxygen to use ring-level caution and staining system as described by B With the addition of Hun, the hard-faced table should be the same as the pre-scratch case. It is not only true that there is a vulgarity in addition to the modulation, but it can be confirmed by the external indication. Frequently, the predication is predictable, and the physical characteristics of the spermatozoa are also obviously more suitable for the blending of the product and the sticky body. Incompatible area. -A few days ago, the reaction system of the high-stain-like reaction segment of the body-building system was mixed with the moisturizing compound and the pseudo-hard layer and the pre-sequence of the pre-stained stains showed that the fat was added and the alcohol was added. The acrosomal stem is the body fluid of the sulphur-bearing gas which has been preliminarily confirmed in step B. This kind of agent will be soaked in this kind of agent until the test sample is stored. Dhd. The storage of the classics such as cyclic anti-heparin amine} sulfur pre-stick should be less hard and the performance is mixed by the need (a ..................... ........................... ^ ................ ............. ^ ........................ Please read the back first Please fill in this page again) A4 (210X 297 public) A6 B6 V. Description of the invention (2) (b) Latent ring gas resin hardener that starts the reaction only at a temperature of at least 8〇υ (by DSC to ίου Calculation of heating rate per minute), (C) an amine having at least one amine hydrogen and (d) a sulfatase having at least one SH group, wherein the amine (c) has at least a dip hydrogen atom connected to more than one nitrogen atom or at least two The mercaptan with a dip S Η group reacts with a heating rate of 10 t: / min in the DSC chart, and the difference between the peaks is at least 3010. When this mixture is heated in a DSC device (DSC = Differential Scanning Calorimeter), DSC (the reaction's enthalpy temperature function) represents the significant peak and net baseline of Erhu. In the initial reaction, the composition selected by Nong, for example, in the range of about 80 to about 130 * 0, the maximum value is attributed to the anti-plaque of the resin and the amine / thiol mixture (stage B) and measured. In addition, in the range of about 100 to 200, preferably about 130 to 18〇υ measured by the latent hardener complex (please read the precautions of the plan first and then fill out this page) Big difference. The peak value of the inter-temperature value of the fruit temperature should be the highest and the second should be the second. The peak height should be the middle of the difference between the difference. The best combination is the mixed one at ρ ο 0 5 40 is the body less immersed under the base 0Η in the presence of the body fat synthesis tree re-enriched amine ring / one two 漲 彳 6 0 15 three o'ding no br 3 special 1, in the book, said the good things The national base of the chemical specialty «1 Ying SH or as an example, as an agent, the level of chemical stearin is known to the level of the tree with high fat into a tree to connect the gas ring agent with a hard C medium should be reversed or similar step anhydride I, classified as amine, the Central Standards Bureau of the Ministry of Economic Affairs, it can be used as a homogenous compound. It is used for any combination of chemical sealing technology, grease or tree gas, and the ring is stuck to the fat tree. 4 (210X 297 public) or 'A6 B6 V. Description of the invention (3) Fat tree "Qi is an example of Chen Zi, a mixed fat mixed tree, Ming Qi hair ring is used to make the oil glycidyl base at a certain place. Or when the yeast is suitable, the ester is present under the atmosphere-there is a difference in age and the combination of the material and the anti-Lu Lu.-(基 得 聚 carboxy 得Ethylene diester oil should have anti-glycol water and less condensed to epipolymerization. -7 Purpose yyA- HH into the second body of glutaric acid, or acidified allium succinate. Or acid acid oxalate as a seed, for example, the second type of acid octanoic acid, carboxylic acid polyheptane, C acid with two hex · Synthetic acid phthalocyanine four examples are acid carboxypolyaliphatic alicyclics. Use acid to make the oil can also be anesthetized, sub-reduced methyl or acid phthalide iso. Acid acid phthalide phthalate such as hydrogen Example six, based formic acid 4- complete Or polyacrylic acid phthalocyanine hydrogen aromatic six, make acid can be phthalic

0 Use immediately with the following media stored in the next or next. Strips of acidic diamines in benzene} have less than K to or make alcohols and gaseous bases and base hydroxy alcohols from 0 kinds of two bases with a ΠΊΤ group derived oil glycan water ether condensed type A-this β · Polymerization can obtain anti-0 alcohol ether nitrogen epimethyl methyl and poly or hydroxy ether oleyl phenol glycerol or water, shrinkage diethylene glycol diethyl alcohol-like ring-shaped non- (please read the notes on the back of the matter first Fill in this page). Xiang., Set ·. Line · poly-grade high-ene and propanol diethane propanol diethylene ethane gas / V-poly or alcohol dialkyl propane 0 dioxane poly f Unitary Ministry of Economy Central Printed by the Bureau of Standards, Alkanol pentanyl alcohol ditriethyl 6-, 撺, 4 A-2 tetrakane gas hexane hexanol dialkyl propanol trimethyl tri, tetra alcohol pentane quaternary 4 (210> ,: 297 public ): 0177 ^ A6 B6 V. Description of the invention (4) f Please read the precautions on the back before filling this page) Yeast, sorbitol and polyepichlorohydrin. Furthermore, this compound is also derived from aliphatic fatty enzymes such as 1,4-hexamethylene dimethanol, bis- (4-hydrohexyl) -methane, or 2,2-bis- (4-hydrohexyl) )-Propane, or having an aromatic nucleus, such as Ν, Η- 燹-(2-hydroethyl) aniline or?, I'-bis- (2-hydroethylamino) -diphenylmethane. The ring gas compounds can also be derived from mononuclear phenols, such as resorcinol or diethylphenol; or based on polynuclear phenols, such as bis- (4-hydrophenyl) -methane, 4,4'- Dihydrobiphenyl, bis- (4-hydrophenyl) -Asia ", 1,1,2,2-four. Order. Pour- (4-hydrophenyl) -Beiyuan, 2, 2-bis- ( 4-氲 phenyl) -propanol, 2,2-bis- (3,5-dibromo-4-hydrophenyl) -propane or based on novolac from aldehydes, such as formaldehyde, acetaldehyde, gas aldehyde Or furfural and phenols such as phenol, or in the core by the chlorine atom or Ci-Cs alkyl, such as 4-nitrophenol, 2-methylphenol or 4-tert-butylphenol condensation, or as above Shows the availability of the condensation of bisphenols. I) A poly- (N-glycidyl) compound can be obtained by the dehydrogenation of the reaction product of epigas alcohol and an amine containing at least a bis enamine hydrogen atom. Examples of such amines are aniline, n-butylamine, bis- (4-aminophenyl) -methane, m-xylenediamine or bis- (4-methylaminophenyl) -methane. • Line. Poly- (H-glycidyl) compounds also include N, N'-diglycidyl derivatives of triglycidyl, oleyl isocyanate, naphthenic urea, such as ethylene urea or 1,3-propene urea , And diglycidyl derivatives of hydantoin, such as 5,5-dimethylhydantoin. IV) Poly (S-glycidyl) compounds, for example, derived from dithiols, -6-A 4 (210X of 7 male; A6 _ B6 V. Description of the invention (5; such as ethane-1,2- Dithiol or bis- (4-tolyl) ether bis-S-glycidyl derivatives. V) Cycloaliphatic ring gas resins, such as bis- (2,3-pyrrole gas phenyl 2, 3-Chen Qi Chen phenyl glycidyl alcohol, 1,2-bis- (2,3-Heng gas pentanyl)-ethane or 3,4- Jing gas cyclohexyl 3'4'- Hun gas Cyclohexane carboxylic acid. In addition, available Hun gas resins in which 1,2-benzyl groups are bonded to different heteroatoms or functional groups, these compounds include, for example, N of 4-aminophenol , Ν, Ο-triglycidyl derivative, glycidyl ether / glycidyl ester of salicylic acid, Ν-glycidyl-Ν '-(2-glycidoxypropyl) -3,5-dimethylethyl Internal urea or 2-glycidyl oil-based-1,3-bis- (5,5-dimethyl-glycidyl hydantoin-3-yl) -propane. Suitable resins have 2 to 10 gram equivalent / thousand grams of gas content is glycidyl ether, glycidol or aromatic, heteroaromatic, aliphatic or aliphatic compound N-glycidyl derivatives. Particularly suitable ring gas resins are polyhydric phenols, such as 2,2-bis- (4-hydroxyphenyl) -propane (bisphenol A) or bis- (4-hydroxybenzene Base) -methane (bisphenol F), or novolac. The epoxy resin used should be liquid, but also pseudo-liquid or a liquid mixture of solid and liquid resin. (Please read the notes on the back before reading (Fill in this page) k. • Order. Phenol bis or A phenol bis 4 'is 4, phenolic or lacquer gas-clear cyclic aldehyde phenol is suitable for phenol, methyl oxycyclylamine, diglycerin, glycerin, and glycerin. Tetramethylmethylbenzine · Line · Agent i ^ 0 0 The bio-derived derivative of the base type of submersibles is considered to be acceptable, but it was originally printed in the Central Standards Bureau of the Ministry of Economic Affairs. The qi and the ring, but the r is 80, the temperature is limited by the definition of the temperature, and the bounds of the world are as the same. The combination of low material and chemical knowledge is any wayward lazy armor 4 (210X 297 public) 0177 ^ 1 A6 B6 V. Description of invention (6) Degree ο Temperature 10 is the limit and it is unique. Super P and 85 should be the speed limit and the temperature limit of fat temperature. The thermal latent application makes the known quasi-pseudo-chemicals combined into an example, such as the guanidinocyanamide 0 dicyandiamide. The application of the agent in the case of the application can be hardened by the commerce of the dive industry. 9. 5 strokes 8 cases 4, Li 0 special amines of the national family Meixiang or or guanidine, or the compound, the combination of the subunits of oxybenzene shows benzyl diisothiol 51 amine, 4 di (such as 2 cases 1-, such as amine) The production of class 0 polypyrazole can be changed from serotonin to acetyl or N-, such as guanidine, good example, shuangan, base 5 (agent benzene 14, methyl 20, hard o-β latent-e 1 1 C, such as a, ca Appropriate An Ku phenyl benzene three Sanli special country participate in £! 1 shows the combination of the compound or oxazolyl benzene this book 0 azole or squint 01 propane 3 'iso 87-5 2, 1 4 醯 和 豪 2 ^ 9 A special country such as a compound salt such as gold and azole is a compound 20 hard 21 to 3, when 74 is suitable and special 6 fight 3 '0 Li Er or acid' two kinds of self-like things, such as derived W azine Aldehydic acid 'Carboxy I # of _ shows acid 78 or 9, 8 # 77 cool 6, two Ί5 acid phthalate 00 different (please read the precautions on the back before filling this page). Smoke. • Order. For example, amine_Kr- 不 三1 掲 • 基 “si #-« Material-based moon amine {△ r 一 I 三 之 -6S- 提 -4 基 〶 £ ¾ Benzene it most 2-V such as base 7 Guiwu 24 Monthly birth 0, _ row 3 2 ^ 0 or its 3,-and Liamine special secret country and the United States amine guanidine benzoic acid vinegar cyanide special-national salt medicinal acid such as vinegar, cyanide-complex group 0 ethyl cyanide as agent BC hard Latent S of 52 when 3 suitable 28 bis-alcohol diethylpentyl cyanide · line · Central Ministry of Economic Affairs of the Ministry of Economic Affairs or cracked vinegar or cyanogen chloride-diazepam-0 6- salt 1 acid, vinegar according to 8 cyanohydrin T-based bis-butanol isomethane hexamethylene 4 (210X 297 异 发) A6 B6 Fifth, the description of the invention (7) H-atmoyl amide compound. For example, Ν, Ν'-dicyanoadipate dialdehyde amine It is a suitable latent hardener. This compound is contained in U.S. Patent Nos. 4,529,821, 4,550,203 and 4,618,712. Other suitable latent hardeners are shown in US Pat. No. 4,694,096, sulfopropyl phenols, and US Pat. No. 3,386,955, showing urea derivatives such as toluene-2,4-bis- (N, H-dimethylurea> A suitable latent hardener is 4,4'-diaminodiphenyl sulfide. Especially dicyandialdehyde. The mixture of the present invention may also contain an accelerator for complexing reaction with the latent hardener. Agent (e). Examples of suitable accelerators (e) are hemp derivatives such as ^ -dimethyl-^ '-(3-gas-4-tolyl) screen (gas toluene), 1 ^'-dimethyl -N '-(4-Phenylphenyl) -P (monosaccharide aldehyde) or Ν, Ν'-dimethyl-H'-(3,4-dicyanophenyl) diurea (bis aldehyde), 2 , 4-Bis- (Ν, Ν'-dimethylsulfonyl) -toluene or 1,4-bis-U ', Ν'-dimethylureido) -benzene. These compounds used are shown in the above-mentioned U.S. Patent 4,283,520. In addition, the urea derivative contained in US Patent 1,192,790 is also a suitable accelerator (please read the precautions on the back before filling out this page) • Order. Printed by the Ministry of Economic Affairs Central Standards Bureau $ !. 1- 1, cyanocyanine, -4-based or oxazolyl ammonium ammonium 4-ethyl 2-ammonium, bromobenzene or quaternary phenol-up-t 2¾ or}, cyanotriazole-based Ethylbenzyl methyl- or 4-aminoamines. Amine methylation 2-w_ three 1 one M, -z into the first-(the base of the oxazol-2 to promote the trimethyl squint group 6-four as ethyl when into 4, 4, for example, cyanogen promote 2, salt, 1- for , Phenols, ammonium, oxazolazole, toluene, succinimide and bistriyl benzene, .Line · A 4 (210X 297 public release) 5. Description of the invention (8 A6 B6 ammonium; alkali metal alkoxide, such as 2,4 -dihydro-3-hydroxymethyl compound sodium alkoxide. Krypton solid solution and phenol / aldehyde resin contained in EP-A200,678, and polymerized phenol shown in EP-A351,365 Class Mannich (Mannich) is also a suitable accelerator. The best accelerator (e) is azoles or hemp derivatives. As mentioned, the amine component (c) of the mixture of the present invention is at least Any amine with an amine hydrogen. To obtain good results, the amine (c) or thiol (d) must contain at least three slap hydrogen atoms that are active on the ring gas resin. For amine strips, only 0 Ziyuan 0 two less than the need to combine the situation, the first situation is to use PC containing amines. The use of all amines and any use of the original results in a amine ring heterocyclic and aromatic aromatic alicyclic. Lipogen is Example three suitable or} bis (C category, amine diamine N, such as octane,, n-pentylamino, 3 benzene T aminoethane 4-propane methylamine diamine dimethyl hexamethylene {please read first Note on the back and then fill out this page). Therefore. I 2 RM »tree-1 0 methyl methyl / aminobenzene diamine triene ethylamine benzyl new yfv amine dipropyl propylamine pentene ethylene tetramine tetraene ethylene Triamine methyl! \ 1 / propylpropylamine, and amine 2-hexyl 1, ene, ethylamine glutaryl, ylaminobenzene-alkanehexylcycloethyltriamine 4-one-amine. Order. Diamine methylhexyl Bicyclo-yl. Line. Dialkylmethane-\ — / Alkylamine and alkylpropyl-ylhexylcycloamino: Hexane? Cyclomethine 3 Limbrane diisopropyl / IV Amine Cyclomethine Central Standard of the Ministry of Economy Local printing of oxazolidine amine polydihexylamine), family amine lipid two by ketol Kolverfo compound and this is for example amine 0 amine amine polyamine suitable 0 to obtain fatty acid lipid body A 4 ( 210〆297 Public Issue) A6 B6 V. Description of the invention (9) (c) Polyalkylene amines, known by Jeffa ^ ines® produced by Texaco, such as Jeffanines® E0R148. D230, D400 or T403o and suitable amines are 1,14-diamino-4,11-dioxadecane, dipropylene triamine, 2-methyl-1,5-pentanediamine, Ν, Ν '-Diethylhexyl-1,6-hexanediamine, Ν, Ν'-dimethyl-1,3-diaminopropane, Ν'-diethyl-1,3-diaminopropane, Ν, Ν-dimethyl-1,3-diaminopropane, second polypropene diamines and triamines, such as EPS7315 and EPS7325 produced by Texaco, 2,5-diamino-2,5-di Methylhexane, bis- (aminomethyl) -tricyclopentadiene, m-aminobenzylamine, 1,8-diamino-p-methane, bis_ (4-amino-3,5-di Methylcyclohexyl) -methane, 1,3-bis- (aminomethyl) -cyclohexane, dipentylamine, bis- (4-amino-3,5-diethylphenyl) -methane, 3, 5-Diethyltoluene-2,4-diamine and 3,5-diethyltoluene-2,6-diamine (Please read the precautions on the t side before filling out this page) -Subscribe. Make W 0 items The oil diglycerin is less water and shrinks to be the best one with special envoys. There are amine minorities to Zhiyi and} ethnic groups. (c Lipid-based cyclic amine groups are made of pseudo-lipids, such as the group of tree-based components, which is suitable for the most suitable mixed amine aliphatic lipids or family § β-ring is. The line is suitable for those with the most Among them, the ® class Γ amine du group ΓΟ fat E ring 0 is sold in the market, which is printed by the example of the alkylhexyl amine di AG methyl group in the Central Ministry of Economics and Trade of the Ministry of Economic Affairs. Hexacyclomethyl trisylidene compound), the amine VI di or ketone I Erfuroline isoxazole νίν succinylamine poly and alkylmethylamine methyl 4 (210X 297 Koji) V. Description of the invention (10) A6 B6 H2N-R-NH2 (I), H2N ~ (-CH2CH20) aCH2CH2NH2 (Π), CH3 CH,

H2N (CH2CH2CH2NH) fCH2CH2CH2NH2 (V), H2N (CH2CH2NH) gCH2CH2NH2 (VI) printed by the Central Bureau of Standards of the Ministry of Economic Affairs, where 1 ^ is a straight or branched C2-CW alkylene base painting, a is an integer from 1 to 10 , Preferably 2, b is an integer from 1 to 10, preferably 2 to 6, c, d and e are each described as an integer from 1 to 20, preferably from 2 to 5, f is an integer from 1 to 5 , Should be 1, and g is 1 to 10, preferably 1 to CH 2 ~ I 5, and! ? ! It is a trivalent group of formula CH- or may be CH3CH2C I CH 2 ~, preferably in the middle of the aliphatic amine (c). Formula] Jeffanine® EDR148 of I. That is 2,2,2-trimethylhexane-1,6-diamine where a = 2, Jeffaminee® D230 or D400 of formula Ϊ where b = 2-3 or b = 5 -6, J effaminee β T 4 0 3 of formula IV, namely bis- (3-aminopropyl) -amine, diethylenetriamine, triethylenetetramine, 2,2-dimethyl-1,3-propane Diamine and pentamethylene hexylamine are to be applied separately. The most suitable amines are n-octylamine, 4,4'-diaminodioxanyl methane, Teffanine® EDR 1 48, Laromin ® C-260, (BASF, 3,3'- 12 (please read the back (Notes and then fill out this page) A4 (210X 297 Public Broadcasting) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs (ονϋΊά α6 * Β6 V. Description of the invention (11) Dimethyl-4,4'-diaminodichen hexanemethane ), 1,2-dimeryl hexane and isophorone diamine. In the first stage of complexing, amine (c) and thiol (d) are used together as a hardener. Generally, at least one Any suitable compound that is preferably a distillate or tri-SH group can be used as the thiol (d). A suitable example of the thiol is triethylene glycol dithiol or 1,2-bis- (2'- Ethane gas) -ethane, such as the formula HS (CHZ CH2 OCHz OCHz CHz SS) n CHz CHz 〇CHz OCHz CHZ S polymerized polysulfide under the name Thiokols®, trimethanol propane trithioglycol salt and Other thioglycol salts, such as the compounds contained in U.S. Patent 3,352,810, are shown in U.S. Patent Nos. 3,716,588,3,734,968, 3,718,700, and 3,278,496 for aliphatic and cycloaliphatic dithiols. Poly- (Alkanoyl) aromatic compounds contained in 3,310,527, alkane dithiols or hydroxyalkane dithiols described in US Patent 3,363,026, pentaerythritol hexa- (3-amylpropionate), Monomercaptans such as cetyl mercaptan, benzyl mercaptan, pentyl mercaptan, hexyl mercaptan, octyl mercaptan or decyl mercaptan or trithiols such as 2,4,6-S-triazine tris Mercaptan. Suitable thiols are polyoxyalkylene derivatives, especially polyoxyalkylene dithiols or trithiols. For example, these thiols can be polyethylene glycol derivatives, polypropylene glycol The derivative may be a copolymer containing oxyethylene units or propylene units. This copolymer is a segmented polymer or a random polymer. The related segmented polymers are sometimes referred to as polypropylene glycol hydroxyethyl or polymer Ethylene glycol hydroxypropyl ester, its 傜 以 所 -1 3-(Please read the precautions on the back before filling in this page) • Insect · · Order · • Line armor 4 (210X 297 father hair) A6 ^ _ V. Invention The description (12) depends on the terminal polyethylene glycol segment or polypropylene glycol segment. Commercially available polypropylene glycol mainly has a second terminal hydroxyl group; of course, it is known that it has the first. Polythiol-based polypropylene glycol can also be used. Other suitable dithiols are derived from polytetrahydrofurandiols. Polytetrahydrofurandiols are also known as commercial grade products. The products of these products Examples are poly-THF 650®, P〇ly-THF1000e P〇ly-THF2000® produced by BASF. These commercially available diols, for example, can be converted into dihydric derivatives by reacting with thionaldehyde nitrogen, which reacts with thiourea to produce a different gaseous isopeptide, and then The product is hydrolyzed to dithiol. The conversion of alcohols to sulfur enzymes is explained in detail in Organic Synthesis, Collective Volume 3, pp698-700 and Collective Volueie 4 pp 401-433, Wiley, New Yook, 1955 and 1963. Appropriate thiols (d) injure polyalkylene derivatives sold by CapCuree (Henkel Hapco AG), such as CapCure® V / R-6 or VR-36, especially CapCure® of formula R-KHOHjHCHirCHIHCI ^ SHh,

CH3 OH where n = l-2 and R is a trivalent base of aliphatic hydrocarbons. Particularly suitable dithiols are compounds of the formula HS (CHz CH2 〇4m Η 2 C Η 2 S Η and HS (CH2 CHz CHz CH2 0 4τττ ~ ε Η 2 CHz CH2 CHz SH π compound = 7- 8, 12- 13 or 26-27. The Central Bureau of Standards of the Ministry of Economic Affairs has cracked (please read the notes on the back and then fill out this page). Order .. Line. The most suitable is triethylene glycol dithiol, CapCure® 3-800 And trimethyl enzyme propane trithioglycolate. -14-A 4 (210X 297 public) A6 B6 — V. Description of the invention (13) Suitable for the mixture of the present invention may also contain amine / mercaptan hardening accelerator For example, phenols, such as nonylphenol or resorcinol, or organic acids, such as p-toluenesulfonic acid. The ratio of the components of the mixture of the present invention is determined by the specific components to be widely pseudo. The latent hardener is suitable Use, for example, in the range of about 3 to 60, preferably based on 100 parts by weight of the ring gas resin, the amount is about 6 to 30 parts by weight. As in the manufacturing stage of B, usually these mixtures contain about 5 to 50SS, especially about 10-35X resin ring gas base is connected by amine / mercaptan mixture, and the remaining ring gas base is made by latent hardener Hardening. The equivalent ratio of NH group / SH group is also very wide, depending on the thiol or amine used and the required characteristics of stage B. For example, the NH / SH equivalent ratio is about 15: 1 to 1: 6, which is the most suitable It is about 10: 1 to about 1: 3. The usage of components (c) and (d) is determined according to the application design, that is, depending on the flexibility required for the B stage and the required service life of the mixture Do a moderate increase or decrease. Generally, if you increase flexibility and use the game, the amount of thiol in the thiol / amine mixture is also increased. The amount of accelerator (e > can be added to promote the latent hardener ( b) Produce hardening or add an accelerator to harden the amine (e) and thiol (d), and those skilled in the art can use any type of accelerator at will. The proper amount of the mixture fraction of the invention For examples, please refer to the specific facts (please read the precautions on the t side before filling out this page). Xiang · • ΛΤΤ ·.

The Economic Discharge Central Standards Bureau prints $ L. B is changed to A. It is absent and hardened as usual, and a stage C is used to dissolve it at an increased liquid temperature. By dissolving the hardening stage, the addition stage is more mixed, and the energy can be clearly distributed. The cost line group is routinely administered with ketone methyl 4 (210X 297 g; A6 B6 V. Invention description (14). In case of pain, reactive diluents such as butanediol diglycidyl ether, isomerized high-enzyme monoglycidyl ether, such as Grilonit RV 1814 * (Ens-Chedce company product), or butyl glycerol Glycerol ether, 2,2,4-tritolyl glycidyl alcohol, phenyl glycidyl ether, tolyl glycidyl ether or glycidyl ester can be added to the hardenable mixture to reduce the viscosity. The mixture of the present invention also contains adhesion promotion_ , In principle, any known adhesion promoter can be used. Silanes, such as 7-glycidyl gas propyl trimethyl gas silane (U ni ο n C arbidee company produced S i 1 ane A-1 8 7) or γ -Acetyltrimethylsilane (Silane A-189 manufactured by Union Carbidee) or titanium compounds such as tetraisopropylbis- (dioctanoic acid)-Qin acid cooler (KR 41B manufactured by Kenrich Petrochenicals, USA) ) Has proved to be particularly suitable for an adhesion promotion _. Printed by the Central Bureau of Standards (please read the precautions on the back before filling in this page) • Order · _LINE_ in other conventional additives, the mixture of the present invention may also contain extenders, fillers and reinforcements such as Bituminous coal tar, leach, skeletal iron, glass fiber, asbestos mineral, boron fiber, fiber, mineral silicate, mica, quartz powder, hydrated aluminum oxide, bentonite, wollastonite, kaolin, silicon Aerogel or gold powder, such as aluminum powder or iron powder, as well as pigments and dyes, such as nitric black, vaporized pigments and titanium dioxide, fire retardants, altering agents, flow control agents such as silicon and paraffin And stearate, some of which can be used as a mold release agent, anti-gasification agent and light stabilizer., -16-A 4 (210X 297 public) ,, *) f ^ 01 r-- A6 _B6 V. Description of the invention (15) The mixture of the present invention is prepared by mixing the components by conventional methods using the existing mixing equipment (mixer, drum machine). The mixture of the present invention can be used as an adhesive (adhesive film, hot melt, glue, single-component adhesive, gold foil, for example), matrix resins, surface coatings, sealing compounds or injection compounds, or generally manufactured Use of hardened products. The formula used in each case is used in different fields without filling or filling, for example, as a sealing compound, paint, coating composition, finishing material, impregnating resin, thin casting resin, especially prepreg resin, Layered resin, frame resin and adhesives are used. Therefore, the present invention also relates to a conjugated product which is obtained by hardening the mixture of the present invention. The hardening of the mixture is preferably carried out in a temperature range of about 80-18010. After completing the hardening reaction with the amine / mercaptan hardener, for example, hardening at 90-12 ° C for about 2-10 minutes, a stable storage, non-critical B-stage bar is obtained and the product exhibits excellent flexibility and adhesiveness. The complete complexing function with shaping is preferably carried out at about 100-1801 for about 20-60 minutes. Even if the hardenable mixture is stored for a long time (a few weeks to several months) or is completely hardened in the B stage, it has excellent mechanical strength (please read the precautions on the back and fill in this page). Ministry of Central Bureau of Standards 'Printing and Burning' dimensional preparation of synthetic fiber blendable fat in a tree to make a stain for the dip ring as a maintenance dimension, as well as straightening the hair to make the heat suitable for hair, plus the original material Vit is mixed with synthetic fiber Fit together. The collapse of the mixed use of the Ming Baptist made the hair fat appear on the tree. This stain, sex, prepreg is described in particular. Body stains are based on the material stains pre-preserved by the upper body and are obtained as a multidimensional fiber, thread · A 4 (210Χ 297 Gonglu)-ΟΐΙΊά Α6 ^ _ Β6_ V. Description of the invention (16) (a) When the reaction between the amine (c) and the thiol (d) is completed, the epoxy resin (a) and the latent hardener (b) are not reacted at the same time due to the pre-collapse Complete hardening to obtain laminates. Furthermore, the mixture of the present invention can be used as an adhesive, except for the thermal melting of reactive cobalt thin I and adhesive films. After forming the B stage at a temperature of 25 ~ 501C, the storage stability of the adhesive mash can be obtained. The filler can be added or not added during the process. The viscosity of adhesion varies with the degree of B stage. The following examples illustrate the invention. Examples 1-11 The following components were pseudo-used in the composition defined in Table 1: Ambient Resin 1: Bisphenol A diglycidyl ether with 186.2 grams of cyclic gaseous substance in place. m mm m 2: oxycresol novolac with 235 g epoxide equivalent. Atmosphere resin 3: Solid bisphenol a resin with 380 grams of epoxy resin. Latent hardening cut 1: 2 5. 2 parts of dicyandiamide, 12.5 parts of methyl toluene (^), 1 dimethyl-{< '-(3-gas-4-tolyl) -Hemp], a mixture of 46.5 parts by weight of bisphenol A diglycidyl ether having a ring gas equivalent of 192.3 grams and 15.5 parts by weight of bisphenol A diglycidyl ether having a ring gas equivalent of 222.2 grams. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs "-(please read the precautions on the back before filling in this page) * Take a line • Latent hardening remuneration 2: 28 parts by weight of radon dialdehyde amine and 72 parts by weight with 192.3 grams Epoxy equivalent of a mixture of bisphenol A diglycidol. Potentially confirmed remuneration 3: 4,4'-diaminodiphenylyafeng. -18-A4 (210 > '297 Public Issue) Fifth, invention description printed by Shan 1 of the Central Standards Bureau of the Ministry of Economic Affairs (17) Mix all the components and heat them slightly if necessary to prepare the composition. PP) and high-quality products: prepare glass fiber (92146-1-550) (43X 25c ») manufactured by Interglas at 50TC on a sheet with a binder mixture. Remove the air and distribute the adhesive evenly. Roll the glass rod onto the pre-stain. To the B-stage, each pre-stained body is heated on a hot plate of 90 to 120 for 2 to 10 minutes (see Table 2). Manufacture the layered product, and cut the pre-stained body into equal-sized sheets (6.5X9.9cm). After removing the sheet, the 12 layers are laminated and pressed under a pressure of up to 5 MPa through the mold and hardened at an appropriate temperature. The thickness of the laminate is 3-3.3 mm. Cut the layered product as a sample to calculate the shear strength of the inner layer. Use the Techne Gelation Time "GT 3" manufactured by Tec Hne of Cambridge, England at a gel time of 50 (refer to Table 3). In 1 2 The gel time of 0 is measured by the automatic gel time hot plate. The wire strip (diameter 0.4ιπβ) pseudo-pulls the object until the latter reaches the solidification defined by Y. Manufactured by Swiss Dottikon Epprecht Tool Company ICI cone and plate viscometer to measure its viscosity. Use Mettler TA3000 thermal analysis to calculate DSC and Tg. A6 B6 (please read the notes on the back before filling this page) • Xiang. 4 (210X '297 public) L01773 A6 B6 V. Description of the invention (17a) Mi 1: Sweet product: > suspected "It is executed as UH2 N- (CH2 CH2 0) 2 CH2 CH2 HH2 produced by Texco 2 ) Manufactured by Enkel Hapco, H Town 3) Measured by DSC (using Metller TA 3000: heating rate 1〇υ / min). Example number Jing gasified resin 1 (g) ... ............................................. It ... .......................... ^ ... .......................... ^ (Please read the precautions on the back before filling in the purchase) Ministry of Economic Affairs Central Standards Bureau Printed Armor 4 (210X297 official compliance) A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economy V. Description of Invention (18) Throw 1: Cyan Cheng; > Xuan Cheng "is executed as example number 1 2 3 4 5 Resin 1 (g) 70 70 80 80 80 Ring gas resin 2 (g) 30 30 Ring gas resin 3 (g) 20 20 20 Latent hardener 1 (g) 37.3 31.5 34.8 33.8 33.3 η-octylamine (g) 2.5 Isophorone diamine (g > 2.63 4, 4'-diamino-dicyclohexyl 2.9 methane (g) Jeffamine® EDR- 2.4 1 48 1 (g) 1,2-dimeryl cyclohexylamine (G) 2.1 Triethylene glycol dithiol (g) CapCure ® 3 -800 2 (g) 4.3 5.6 2.82 2.8 2.8 B Stage max (" C) 3 94 102 85 93 91 c Stage mQx (X)) 3 146 147 147 146 146 — 20-(please read the precautions on the back before filling in this page) A4 (210X 297 public). Xiang ... Order ... Line

Oim A6 B6 5. Description of the invention (19) ”H2N ~ eCH2CH20) 2CH2CH2NH2 produced by Texco 2) R-

-〇tCH2CHO) i3-CH2CHCH2SH CH3 OH manufactured by Henke 丨 Napco 3) Determined by DSC (using Mettler ΤΑ 3000; heating rate IOC points) ο (please read the precautions on the back before filling in this page) • Installed • Order. • LINE_ The Central Standards Bureau of the Ministry of Economic Affairs Printed Split Armor 4 (21〇X 297W issued) 3 νί 4ax ο

AB 5. Description of the invention (20) Example number 6 7 8 9 10 11 Epoxy resin 1 (g) 100 100 100 100 70 100 Cyclo-vaporide resin 2 (g) 30 Latent hardener 1 (g) 35.1 Latent Hardener 2 (g) 38 Latent hardener 3 (g) 32.9 27.4 6 2,4-pyridine- (Ν, Ν'-dimethylurea) -toluene (g) 6 1,4-bis- (Ν, Ν '-Dimethylurea) -benzene (g) 6 1-benzaldehyde-2-isopropylimidazole (g) 2.3 1- (2 ·, 4', 6, -trimethylphenyl) -2-benzene Gemazole (g) 3 1-ethyl-2-ethyl-4-methylimidazole (g) 1.7 isoflurane_diamine (g) 2.1 2.3 2 2.75 2 2.33 CapCure ® 3-800 5.4 Triethyl Glycol dithiol 5.8 7 4 7 Triol propyl propane trithioglycolate 7.3 b stage maximum (υ) 68 86 102 128 127 97 c stage maximum (υ) 133 143 151 162 171 159 (please read the notes on the back first Please fill in this page again.). Installed. • Ordered.. _ The Central Bureau of Economic Affairs of the Ministry of Economic Affairs printed the cracked armor 4 (210X 297 issued) 5. Description of the invention (21) A6 B6 Table 2: Pre-clearing body (PP): > The composition of Yung No. 1 point for PP preparation / it is up to X high days = medium ^ sleep viscosity is low and X days dad is very good & good catchability 1 10/100 11 15 16 11 15 2 10/100-30 45 48 58 5/110-30 45 45 50 3/120-30 45 40 45 3 5/110 17 24 30 20 30 4 5/110 14 19 22 14 22 5 5/110 10 20 22 14 22 6 5/110 7 10 14 7 12 7 5/90 3 6 7 3 7 8 5/100 1 7 18 7 18 9 5/110 5 20 26 20 26 4/120 5 12 18 12 18 10 5/100 — 10 16 10 16 3/120 11 5/110 24 50 56 30 50 1 Pre-stained mash prepared by heating and impregnating the fiber at the specified time and temperature ........................... ........................ ^ ......................... ...........- ίτ (please read the precautions on the back and then fill out this page) The Armored Printed Armor 4 (210Χ · 297:;: issued) by the Central Bureau of Economic Development of the Ministry of Line Economy -23 olt ^ V. Description of the invention (22) A6 B6

N Printed Armor of the Central Bureau of Standards of the Ministry of Economic Affairs Armor 4 (210X297 M'Ai) m 130CJ enamel 35Φ 皤 0NCT Chen Liantan stoneware. mlsoci stuffed 35ΦΚ 淘 < ΓΓ 萍! f 樾 as: iM-T (Hettleer TA 3000). m130rf 联 35 冰 "Yeling Ping If-Yi Zuo S porch W Revelation 22 | _ _ 豳« δπΝ · a-ssl: «Jin Wei! Alpha bismuth chrysanthemum 3 | lotus ||-; 8 chrysanthemum chrysanthemum | 0 | Qunxi Xing 1, > iflfaTechne Gelation TBer GT3MIt ○ lotus wsf ^ Nl · Wu Jinyun a 漤. -^ 3 C »CJl CO ts5 1— * Composition of example number 3473 3424 3191 2947 3364 3212 Flexural test elastic modulus (N / mn 2) 143 131 116 110 110 81 = one s arsenic 〇Private knowledge ^ Ol CJ1 t ^ O 05 CO 3 452) External fiber degree change ⑴ 115 114 114 104 119 110 108 Tg 2 (V) CTl〇5〇3 0303- ^ 3- ^ 30¾-^ 305-0 * ^ < DOtOO〇- 〇5Cococooro ILS (AST A (N / mm 2) 66.0 69.7 67.3 68.0 60.8 65.6 65.3 53.1 MD-2344): B (N / mm 2) ►-ai tO t— * i— * CJItOCO »—» 4 ^ .Ca3C0C0 Ϊ: PP change 丨 (days) i- 54 13,5 > 72 70 80 1 21.9 9.3 at 50Ό gel time 4 (hours) 5000 5600 1040 1120 1000 8300 (RT) 1600 at 55T: Viscosity 5 (mPa.s) 鎺 3: Mai Ban Mai atlMb Xu Mahan N-fi.g ................................. ..................... ¾ ............................... ........ tr ............................. End (please read the back first Note, please fill out this page) 24, ον 'A6 B6 V. Description of the invention (23) Fresh 5 days 15 days II 12,46 " 11,11 ”11,53 ,, 1 Mash setting time [minutes / second] Fresh 3 days 15 II 12'00 ”14,40: 15 Ό6 " 2 gel time [min / sec] fresh 5 days 16 days II 10Ί5 " 14'19 " 13'44 " 3 gel time [min / sec] fresh 4 days 12 Day II 10'20 " 13,31 ”12’41 " 4 Gel time [minutes / second] Zhejiang 4: Ke 1203 Quan Lianlian: > Luo Sleeping» Hoarding and Cultivation Fei Xionghan

0 ^ 谢 锒 m 17> H (please read the precautions on the back and fill in this page) • Installed. • Ordered.. Green. The Central Bureau of Standards of the Ministry of Economic Affairs printed the cracked armor 4 (210X 297 public) ji® a 【 Bing / 2 1105 " 14-37- 1409 " 25 A6 B6 V. Description of the invention (24) Table 5: Adhesion of aluminum H strip to the pre-preservation body as a function of the pre-preservation body stored at room temperature for the adhesive shear resistance Strength Shear strength storage period (DIH 53 283) [N / Hi m 2] [N / bm 2] 1 day 15.1 14.2 5 days 11.9 11.6 9 days 13.9 14.9 15 days 12.1 13.2 {Please read the notes on the back before filling in This page) _XIANG · .BOOK · GUAN Guan Example 12: The availability of Setju resin flow as a functional time-pre-destructor of Fu Cunwu Qingjing. The flow is generally measured for reference. If the flow volume is too small, for example less than 10%, the pre-stain cannot be pressurized and a good laminate is obtained. Weighing (= W1) 2 flat pre-collapsed body with side length of 5 cm (prepared using Example 2), correctly stacked and placed between 2 separate papers and preheated to 1001C under pressure. Immediately open and close the press machine and pressurize to 2MPa. After 5 minutes, self-heating — 26 — A 4 (210Χ 297 g). Line. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs

5. Description of the invention (25) The press takes out the formed layered product, and cuts out the resin flowing out along the edge of the layered product. Re-scale the weight of the layered product (= w2), the weight difference between wl and w2 is expressed in χ as a percentage of " flowable " weight. The weight of the pre-crushed body during storage at room temperature of the resin U weight) 1 day 19.3 4 days 21.0 11 days 20.8 Endeavour Example HI: Use sweet as the adhesive for the melting anti-seating component to form the B stage after storage stability to determine the composition contained in Table 6. The viscosity of the hot melt (in (Measured by Rheonat Viscometer manufactured by Contraves AG, Zurich) After various storage times, the heat and mechanical strength are shown in Table 7, and the shear strength of the adhesive (hardened at 160 * 0 for 30 minutes) combined with aluminum H is as false It is shown in Table 8. Accelerator 1: Chorotoluron Accelerator 2: Mizoline of the following formula

A4 (210X 297 public issue) (please read the precautions on the back before filling in this page). Packing. Ordering. • Line · 〇V '-3 A6 B6 5. Description of the invention (26) (derived from EP- Example 1 of A 288359) Accelerator 3: 2,4,6-tris- (dimethylaminomethyl) -phenol and phenol / phenol β varnish resin M Grade s-2 (Maruzen Petrschenica KK, Tokyo) solid The solution was prepared according to EP-A 200,678 (accelerator VI). Accelerator 4: Polyvinylphenol resin M Grade s-2 (Maruzen Petrochenical KK, Tokyo), produced by the Mannich reaction of formaldehyde and dimethylamine It is prepared according to the method of EP-A 351,365 (promoting XI) Table 6: Composition of hot melt (please read the notes on the back before filling in this page) 14 15 16 cyclic gasification resin 1 (g) 10 10 10 10 dicyandialdehyde (g) 1 0.3 0.96 0.96 accelerator 1 (g) 0.05 accelerator 2 (g) 1 accelerator 3 (g) 0.04 accelerator 4 (g) 0.04 Isophorone diamine (g) 0.11 0.11 0.11 0.11 Triethylene glycol disulfatase (g) 0.25 0.49 0.49 0.49 -28. Order. * Line. A 4 (210X 297y eaves) 5. Description of the invention (27)

Table 7: Properties of hot melt Example 13 14 15 16 Viscosity after storage at 40C (Pas) 1 day 9.3 15.5 15.3 12 days 13.2 14 days 19.1 15.7 28 days 22.6 19.5 Phase B maximum (¾) 111.4 144.5 111.0 111.5 (Maximum ΓΌ in C stage) 159.9 160.5 171.5 182.5 Gel time at 140Ό 10'43 " 13.26 " 13'50 " 27,02 " Glass transition temperature Tg after stage C 116¾ 136¾ 116 ^ 103 * C Table 8: After hardening ( Shear strength of 30 minutes / 1600 adhesive (DIN 53 283) Example 13 14 15 16 Storage 40 days / RT 1 day / 40TC 1 day / 40Ό 1 day MOC Shear strength (Ν / πμβ 2) 21.1 20.9 25.8 25.7 (Please read the precautions on the back before filling in this page). Packing. Ordering. Endeavor Example 17: The cyan product is used as a sticky pound. Use the resin component: Heat 75g of the ring gasified resin 1 and stir until 80-100Ό, and then add 25 g of finely ground ring vaporized resin 2. Continue winding and stirring at 80-100Ό until it is completely dissolved. -29- A4 (210X 297 public) • Line. Printed by Central Bureau of Standards, Ministry of Economic Affairs Preparation ^ A6 B6 V. Description of the invention (28) Hardener component: 23,3 grams ^ 丨 〇``〇1; 〇114 '' 〇11, 15.2 grams of triethylene glycol disulfatase and 13.9 grams of isophorone diamine are thoroughly mixed. Add 47.6 grams of dicyandiethylene glycol to the resulting suspension and Disperse the mixture in a dissolver to obtain a white glue. Mix 100 parts of resin component with 15 parts of hardener at the same time and use it for non-twisting cloth (Firdt 3255 EL> manufactured by Lantor of the Netherlands. Formed as B After the stage (5 minutes at U0C), an adhesive film with a resin content of about 80% is obtained. The shear strength (DI Ν 5 3 2 8 2) of the adhesive bonded to the aluminum strip (hardened at 129C for 30 minutes) is 2 0 N / m β 2. (Please read the precautions on the back before filling in this page). Insects.. Orders • Lines. Armored 4 printed by the Central Standards Bureau of the Ministry of Economic Affairs (21〇Χ 297 public)

Claims (1)

IL 、 呻: 〇v '• f. In each W year: _ ............ $; t.; H D7 Printed by R Industrial and Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Scope No. 79 1 09 6 86 Patent Case for "Hardenable Amine Resin Mixture Containing Latent Hardening Amine and Sulfur Fermentation" (Amended in December 81) 1. A hardenable mixture containing (a) a ring gas resin, which is a double Phenol A diglycidyl ether or cresol cresol novolac, (b) dicyandiamide or 4-4'-diaminodiphenylsac, which accounts for 3% to 40% by weight of component (a), (( c> 1 to 10% by weight of the amine of component (a), pseudo-selected from n-octylamine, isophorone diamine, 1,8-diamino-3,6-dioxoctane, 4 , 4, -Diaminocyclohexylmethane and 1,2-diaminohexyl and (d) account for component (a) 1 ~ 10% by weight selected from triethylene glycol-containing dithiol and trimethanol propane trioxide The thioglycol ester base and the formula R + 〇 ~ ^ CH: CHO ^^ H: CpCH: SH] 3 Cri3 〇H where η = 1-2 and R is an aliphatic hydrocarbon triglyceryl group. 2 . If the mixture of the first item of the patent application scope, the ring gas resin (a) is the liquid pith. 3. If the mixture of the first item of the patent application scope. In addition to the components (a) to (b), it also contains the accelerator U) in the reaction of the gas resin (a) and the latent hardener (b), which is a azole or urea derivative. 1 This paper size is used in the B National Standard (CNS) A4 specification (210 X 297 g *) (please read the precautions on the back before writing this page) -installed- .11. Thread · A7 B7 C7 D7 VI. Application for patent Fan Garden 4 For example, the mixture of item 1 of the patent application scope is used to diffuse the obtained composite materials. 5. If the mixture of item 1 of the patent scope is applied, the product will be produced through hardening. 6. For example, if you apply for the compound in item 4 of the patent scope, the secondary-dimensional composite material used in it is completely hardened to produce products. Printed by the Employee Consumer Cooperative of the Central Ministry of Economic Affairs