TW201713974A - Glass plate - Google Patents

Glass plate Download PDF

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Publication number
TW201713974A
TW201713974A TW105123784A TW105123784A TW201713974A TW 201713974 A TW201713974 A TW 201713974A TW 105123784 A TW105123784 A TW 105123784A TW 105123784 A TW105123784 A TW 105123784A TW 201713974 A TW201713974 A TW 201713974A
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TW
Taiwan
Prior art keywords
light
glass plate
glass
end surface
less
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TW105123784A
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Chinese (zh)
Inventor
Naoya Wada
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Asahi Glass Co Ltd
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Priority claimed from JP2015219370A external-priority patent/JP2018145016A/en
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Publication of TW201713974A publication Critical patent/TW201713974A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C19/00Surface treatment of glass, not in the form of fibres or filaments, by mechanical means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21SNON-PORTABLE LIGHTING DEVICES; SYSTEMS THEREOF; VEHICLE LIGHTING DEVICES SPECIALLY ADAPTED FOR VEHICLE EXTERIORS
    • F21S2/00Systems of lighting devices, not provided for in main groups F21S4/00 - F21S10/00 or F21S19/00, e.g. of modular construction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B27/00Other grinding machines or devices
    • B24B27/06Grinders for cutting-off
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B9/00Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Planar Illumination Modules (AREA)

Abstract

A glass plate 12 having a light-emitting surface 26, a light-reflecting surface 32, and a light-incident end surface 28 that is perpendicular to the light-emitting surface 26 and the light-reflecting surface 32. A light-incident-side beveled surface 40 is provided so as to be adjacent to the light-emitting surface 26 and the light-incident end surface 28, and a light-incident-side beveled surface 40 is also provided so as to be adjacent to the light-reflecting surface 32 and the light-incident end surface 28. Given that the point at which the light-incident-side beveled surface 40 and the light-emitting surface 26 intersect is a first intersecting point P1 and the point at which the light-incident-side beveled surface 40 and the light-incident end surface 28 intersect is a second intersecting point P2, then the slope angle [Theta] of a line segment L connecting P1 and P2 relative to the light-incident end surface 28 satisfies the equation 0.01<=tan[Theta]<=0.75.

Description

玻璃板 glass plate

本發明係關於一種玻璃板。 The present invention relates to a glass sheet.

液晶電視、數位標牌等所代表之液晶顯示裝置具備構成背光之面狀發光裝置、及與面狀發光裝置之光出射面對向配置之液晶面板。面狀發光裝置具有正下方型與邊緣照明型,但大多使用可實現光源之小型化之邊緣照明型。邊緣照明型之面狀發光裝置具有光源、導光板、反射片、及各種光學片(擴散片、亮度提高片等)等。於專利文獻1、2中揭示有將內部透過率較高、剛性亦較高且耐熱性亦優異之玻璃板用作面狀發光裝置之導光板。 A liquid crystal display device represented by a liquid crystal television or a digital signage includes a planar light-emitting device that constitutes a backlight, and a liquid crystal panel that is disposed to face the light emission of the planar light-emitting device. The planar light-emitting device has a direct-type type and an edge-illuminated type, but an edge-illuminated type that can realize miniaturization of a light source is often used. The edge-illuminated planar light-emitting device includes a light source, a light guide plate, a reflection sheet, and various optical sheets (a diffusion sheet, a brightness enhancement sheet, and the like). Patent Literatures 1 and 2 disclose a light guide plate in which a glass plate having a high internal transmittance, high rigidity, and excellent heat resistance is used as a planar light-emitting device.

玻璃板之剛性較用作導光板之壓克力板高,耐熱性亦優異,但若製成將玻璃板切斷之狀態,則有邊緣鋒利而危險,並且會導致玻璃板之強度降低之虞。因此,進行對邊緣進行倒角之倒角加工。藉此,玻璃板之邊緣具備相對於玻璃板之主平面及端面傾斜之倒角面。倒角面之形狀如專利文獻3所揭示,通常為於相對於玻璃板之主平面及端面垂直之剖面,相對於主平面及端面之傾斜角度為45°之形狀。 The rigidity of the glass plate is higher than that of the acrylic plate used as the light guide plate, and the heat resistance is also excellent. However, if the glass plate is cut, the edge is sharp and dangerous, and the strength of the glass plate is lowered. . Therefore, the chamfering process of chamfering the edge is performed. Thereby, the edge of the glass plate has a chamfered surface that is inclined with respect to the main plane and the end surface of the glass sheet. As shown in Patent Document 3, the shape of the chamfered surface is generally a cross section perpendicular to the principal plane and the end surface of the glass sheet, and has an inclination angle of 45° with respect to the principal plane and the end surface.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2013-093195號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2013-093195

[專利文獻2]日本專利特開2013-030279號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2013-030279

[專利文獻3]日本專利再表2013/31548號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2013/31548

本發明之目的在於提供一種可作為導光板用於例如可有效利用光源之光量之面狀發光裝置之玻璃板。 SUMMARY OF THE INVENTION An object of the present invention is to provide a glass sheet which can be used as a light guide plate for, for example, a planar light-emitting device which can effectively utilize the amount of light of a light source.

根據本發明之某一態樣,提供一種玻璃板,其係具有主平面及相對於主平面垂直之端面,且於主平面與端面之間,與主平面及端面相鄰地具備倒角面者,於相對於主平面及端面垂直之剖面,連結倒角面與主平面交叉之第1交叉點、和倒角面與端面交叉之第2交叉點之線段的相對於端面之傾斜角度θ滿足0.01≦tanθ≦0.75。 According to an aspect of the present invention, a glass plate having a main plane and an end surface perpendicular to the main plane and having a chamfered surface adjacent to the main plane and the end surface is provided between the main plane and the end surface. The angle of inclination θ with respect to the end face of the line segment perpendicular to the main plane and the end surface, the first intersection point connecting the chamfered surface and the main plane, and the second intersection point where the chamfered surface intersects the end surface satisfies 0.01 ≦tanθ≦0.75.

根據本發明之另一態樣,提供一種玻璃板,其係具有主平面及相對於主平面垂直之端面,且於主平面與端面之間具備與主平面相鄰之倒角面及配置於倒角面與端面之間之傾斜面者,於相對於主平面及端面垂直之剖面,以連結倒角面與主平面交叉之第1交叉點、和倒角面與傾斜面交叉之第2交叉點之線段相對於端面以傾斜角度θ1傾斜之方式,具備上述倒角面,傾斜角度θ1滿足0.01≦tanθ1≦0.75,連結第2交叉點和傾斜面與端面交叉之第3交叉點之線段之相對於端面之傾斜角度θ2小於傾斜角度θ1,且滿足0<tanθ2≦0.4。 According to another aspect of the present invention, a glass plate having a main plane and an end surface perpendicular to the main plane and having a chamfered surface adjacent to the main plane between the main plane and the end surface is provided The inclined surface between the corner surface and the end surface is a cross section perpendicular to the main plane and the end surface, and a first intersection where the chamfered surface intersects the main plane and a second intersection where the chamfered surface and the inclined surface intersect The line segment includes the chamfered surface so as to be inclined with respect to the end surface at an inclination angle θ 1 , and the inclination angle θ 1 satisfies 0.01 ≦ tan θ 1 ≦ 0.75, and the line connecting the second intersection point and the third intersection point where the inclined surface intersects the end surface The inclination angle θ 2 with respect to the end surface is smaller than the inclination angle θ 1 and satisfies 0 < tan θ 2 ≦ 0.4.

根據本發明之玻璃板,於用作例如面狀發光裝置之導光板之情形時可有效利用光源之光量。 The glass plate according to the present invention can effectively utilize the amount of light of the light source when used as a light guide plate such as a planar light-emitting device.

10‧‧‧液晶顯示裝置 10‧‧‧Liquid crystal display device

12、112‧‧‧玻璃板 12, 112‧‧‧ glass plate

14‧‧‧面狀發光裝置 14‧‧‧Face light emitting device

16‧‧‧液晶面板 16‧‧‧LCD panel

18‧‧‧光源 18‧‧‧Light source

20‧‧‧反射片 20‧‧‧reflector

22‧‧‧各種光學片 22‧‧‧Various optical sheets

24A、24B、24C‧‧‧反射點 24A, 24B, 24C‧‧‧ reflection points

26、126‧‧‧光出射面 26, 126‧‧‧ light exit surface

28、128‧‧‧入光端面 28, 128‧‧‧ light end face

30‧‧‧反射器 30‧‧‧ reflector

32、132‧‧‧光反射面 32, 132‧‧‧ light reflecting surface

34、36、38‧‧‧非入光端面 34, 36, 38‧‧‧ non-lighting end faces

40、140‧‧‧入光側倒角面 40, 140‧‧‧ into the light side chamfered surface

42‧‧‧非入光側倒角面 42‧‧‧ Non-lighting side chamfering surface

44‧‧‧玻璃原材料 44‧‧‧Glass raw materials

46‧‧‧玻璃基材 46‧‧‧ glass substrate

148‧‧‧傾斜面 148‧‧‧ sloped surface

a‧‧‧長度 A‧‧‧ length

b‧‧‧長度 B‧‧‧ Length

D‧‧‧長度 D‧‧‧ Length

L‧‧‧線段 L‧‧‧ line segment

L11‧‧‧線段 L11‧‧‧ line segment

L12‧‧‧線段 L12‧‧‧ line segment

La‧‧‧第1延長線 La‧‧‧1st extension cord

LA‧‧‧直徑 L A ‧‧‧diameter

Lb‧‧‧第2延長線 Lb‧‧‧2nd extension cord

LB‧‧‧直徑 L B ‧‧‧diameter

LC‧‧‧直徑 L C ‧‧‧diameter

P1‧‧‧第1交叉點 P1‧‧‧1st intersection

P2‧‧‧第2交叉點 P2‧‧‧2nd intersection

P3‧‧‧第3交叉點 P3‧‧‧3rd intersection

P4‧‧‧第4交叉點 P4‧‧‧4th intersection

P11‧‧‧第1交叉點 P11‧‧‧1st intersection

P12‧‧‧第2交叉點 P12‧‧‧2nd intersection

P13‧‧‧第3交叉點 P13‧‧‧3rd intersection

S10‧‧‧步驟 S10‧‧‧ steps

S12‧‧‧步驟 Step S12‧‧‧

S14‧‧‧步驟 S14‧‧‧ steps

S16‧‧‧步驟 S16‧‧ steps

t‧‧‧厚度 T‧‧‧thickness

T‧‧‧切線 T‧‧‧ tangent

W‧‧‧長度 W‧‧‧ length

θ‧‧‧傾斜角度 Θ‧‧‧ tilt angle

θ1‧‧‧傾斜角度 θ 1 ‧‧‧ tilt angle

θ2‧‧‧傾斜角度 θ 2 ‧‧‧ tilt angle

圖1係表示液晶顯示裝置之概略構成之液晶顯示裝置之側視圖。 Fig. 1 is a side view showing a liquid crystal display device having a schematic configuration of a liquid crystal display device.

圖2係玻璃板之俯視圖。 Figure 2 is a plan view of a glass plate.

圖3係玻璃板之整體立體圖。 Figure 3 is an overall perspective view of a glass sheet.

圖4係玻璃板之剖面放大圖(省略了一部分)。 Fig. 4 is an enlarged cross-sectional view of a glass plate (a part of which is omitted).

圖5係實施形態之玻璃板之製造方法之步驟圖。 Fig. 5 is a process chart showing a method of manufacturing a glass sheet according to an embodiment.

圖6係玻璃板之玻璃原材料之俯視圖。 Figure 6 is a plan view of a glass raw material of a glass plate.

圖7係將玻璃原材料切出之玻璃基材之俯視圖。 Fig. 7 is a plan view of a glass substrate from which a glass raw material is cut out.

圖8係入光側倒角面之剖面形狀為圓弧狀之玻璃板之主要部分放大剖視圖。 Fig. 8 is an enlarged cross-sectional view showing the main part of a glass plate having a circular arc shape in a cross-sectional shape on a light side chamfered surface.

圖9係表示了於厚度為1.7mm之玻璃板中非波導光相對於tanθ之比率之繪製而成之圖。 Fig. 9 is a graph showing the ratio of non-waveguide light to tan θ in a glass plate having a thickness of 1.7 mm.

圖10係表示用以藉由模擬算出圖9之非波導光之比率所必需之資料之表。 Fig. 10 is a table showing the data necessary for calculating the ratio of the non-waveguide light of Fig. 9 by simulation.

圖11係表示了於厚度為2.5mm之玻璃板中非波導光相對於tanθ之比率之繪製而成之圖。 Figure 11 is a graph showing the ratio of non-waveguide light to tan θ in a glass plate having a thickness of 2.5 mm.

圖12係表示用以藉由模擬算出圖11之非波導光之比率所必需之資料之表。 Fig. 12 is a table showing the data necessary for calculating the ratio of the non-waveguide light of Fig. 11 by simulation.

圖13係另一實施形態中之玻璃板之放大局部剖視圖。 Figure 13 is an enlarged partial cross-sectional view showing a glass plate in another embodiment.

繼而,一面參照隨附圖式,一面對本發明之較佳之實施形態進行說明。 A preferred embodiment of the present invention will now be described with reference to the accompanying drawings.

再者,於圖式中之記載中,對相同或對應之構件或零件標註相同或對應之符號,藉此省略重複之說明。又,只要未特別指定,則圖式之目的並不在於表示構件或零件間之相對比。因此,具體之尺寸可由業者參照以下並非限定性之實施形態而確定。 In the description of the drawings, the same or corresponding components or components are denoted by the same or corresponding reference numerals, and the description thereof will not be repeated. Further, the drawings are not intended to indicate the relative ratio between members or parts unless otherwise specified. Therefore, the specific dimensions can be determined by the operator with reference to the following non-limiting embodiments.

[液晶顯示裝置10] [Liquid Crystal Display Device 10]

圖1係表示液晶顯示裝置10之概略構成之液晶顯示裝置10之側視圖。圖2係組入至液晶顯示裝置10之實施形態之玻璃板12之俯視圖。 FIG. 1 is a side view showing a liquid crystal display device 10 having a schematic configuration of a liquid crystal display device 10. 2 is a plan view of the glass sheet 12 incorporated in the embodiment of the liquid crystal display device 10.

如圖1般,液晶顯示裝置10具備具有玻璃板12之面狀發光裝置14、及液晶面板16而構成。液晶顯示裝置10例如搭載於液晶電視、數 位標牌等實現了薄型化之電子機器。 As shown in FIG. 1, the liquid crystal display device 10 includes a planar light-emitting device 14 having a glass plate 12 and a liquid crystal panel 16. The liquid crystal display device 10 is mounted on, for example, a liquid crystal television. A signage card or the like realizes a thinned electronic machine.

<液晶面板16> <LCD panel 16>

液晶面板16係以夾住配設於厚度方向之中央之液晶層之方式將配向層、透明電極、玻璃基板及偏光濾光器積層而構成。又,於液晶層之單面配設有彩色濾光片。液晶層之分子係藉由對透明電極施加驅動電壓而繞配光軸旋轉,藉此進行特定之顯示。 The liquid crystal panel 16 is formed by laminating an alignment layer, a transparent electrode, a glass substrate, and a polarizing filter so as to sandwich a liquid crystal layer disposed at the center in the thickness direction. Further, a color filter is disposed on one side of the liquid crystal layer. The molecular layer of the liquid crystal layer is rotated around the optical axis by applying a driving voltage to the transparent electrode, thereby performing a specific display.

<面狀發光裝置14> <Face-shaped light-emitting device 14>

作為面狀發光裝置14,採用用以實現薄型化之邊緣照明型。面狀發光裝置14具有光源18、玻璃板12、反射片20、各種光學片22(擴散片、亮度提高片等)、及反射點24A~24C。 As the planar light-emitting device 14, an edge illumination type for achieving a reduction in thickness is employed. The planar light-emitting device 14 includes a light source 18, a glass plate 12, a reflection sheet 20, various optical sheets 22 (a diffusion sheet, a brightness enhancement sheet, and the like), and reflection points 24A to 24C.

自光源18入射至玻璃板12之內部之光如圖1之箭頭所示,一面於玻璃板12之光出射面26之內表面、及光反射面32之內表面反覆經全反射一面前進。又,藉由反射點24A~24C及反射片20而改變了前進方向之光自玻璃板12之與液晶面板16對向之光出射面26出射至外部。出射至外部之光藉由各種光學片(由擴散片、亮度提高片等構成,可為單一,亦可為複數個)22擴散後,入射至液晶面板16。 The light incident from the light source 18 to the inside of the glass plate 12 is advanced as shown by the arrow of Fig. 1 on the inner surface of the light exit surface 26 of the glass plate 12 and the inner surface of the light reflecting surface 32 over the total reflection surface. Further, the light whose direction of advancement is changed by the reflection points 24A to 24C and the reflection sheet 20 is emitted from the light exit surface 26 of the glass sheet 12 opposed to the liquid crystal panel 16 to the outside. The light that has been emitted to the outside is diffused by various optical sheets (which may be composed of a diffusion sheet, a brightness enhancement sheet, or the like, and may be plural or plural) 22, and then incident on the liquid crystal panel 16.

光源18並無特別限定,可使用LED(Light Emitting Diode,發光二極體)、熱陰極管、或冷陰極管。光源18配置在與玻璃板12之入光端面28對向之位置。 The light source 18 is not particularly limited, and an LED (Light Emitting Diode), a hot cathode tube, or a cold cathode tube can be used. The light source 18 is disposed at a position opposed to the light incident end surface 28 of the glass sheet 12.

又,藉由於光源18之背面側設置反射器30而提高自光源18以放射狀發射之光對玻璃板12之入射效率。 Further, by providing the reflector 30 on the back side of the light source 18, the incident efficiency of the light emitted from the light source 18 to the glass plate 12 is increased.

反射片20係藉由於丙烯酸系樹脂等樹脂片之表面對光反射構件進行被膜而構成。反射片20係以與玻璃板12之光反射面32對向之方式配設。此外,反射片20亦可配設於非入光端面34、36、38(參照圖2)。反射片20均可與玻璃板12隔開空間而配設,亦可藉由黏著劑貼合於玻璃板12。光反射面32係玻璃板12之與光出射面26對向之主平面。 又,入光端面28係與光源18對向之玻璃板12之端面。非入光端面34、36、38係除入光端面28以外之玻璃板12之端面。 The reflection sheet 20 is configured by coating a light reflection member on the surface of a resin sheet such as an acrylic resin. The reflection sheet 20 is disposed to face the light reflection surface 32 of the glass sheet 12. Further, the reflection sheet 20 may be disposed on the non-light-incident end faces 34, 36, 38 (see FIG. 2). The reflection sheet 20 may be disposed in a space apart from the glass sheet 12, or may be attached to the glass sheet 12 by an adhesive. The light reflecting surface 32 is a principal plane of the glass plate 12 opposite to the light exit surface 26. Further, the light incident end surface 28 is an end surface of the glass plate 12 opposed to the light source 18. The non-light-incident end faces 34, 36, 38 are end faces of the glass plate 12 except for the light end face 28.

再者,於將反射片20配設於非入光端面之情形時,只要至少配設於非入光端面34、36、38中之與入光端面28對向之非入光端面38即可。藉此,自入光端面28入射之光一面於玻璃板12之內部反覆經全反射,一面向遠離光源之方向(朝向圖1及圖2中之右方向)前進,於到達至非入光端面38時,藉由反射片20而再次反射至玻璃板12之內部。又,於將反射片20亦配設於非入光端面34、36之情形時,可藉由反射片20使於玻璃板12之內部散射之光於到達至非入光端面34、36時再次反射至玻璃板12之內部。藉此,可有效利用光源18之光量。 In addition, when the reflection sheet 20 is disposed on the non-light-incident end surface, it is only required to be disposed at least in the non-light-incident end surface 28 opposite to the light-incident end surface 28 of the non-light-incident end faces 34, 36, 38. . Thereby, the light incident from the light incident end surface 28 is totally totally reflected inside the glass plate 12, and a direction away from the light source (toward the right direction in FIGS. 1 and 2), reaching to the non-light-incident end face. At 380, it is reflected again to the inside of the glass sheet 12 by the reflection sheet 20. Moreover, when the reflection sheet 20 is also disposed on the non-light-incident end faces 34, 36, the light scattered inside the glass plate 12 by the reflection sheet 20 can be again reached when reaching the non-light-incident end faces 34, 36. Reflected to the inside of the glass sheet 12. Thereby, the amount of light of the light source 18 can be effectively utilized.

作為構成反射片20之樹脂片之材質,例示丙烯酸系樹脂,但並不限定於此,例如可使用PET(Polyethylene Terephthalate,聚對苯二甲酸乙二酯)樹脂等聚酯樹脂、胺基甲酸酯樹脂、及將其等組合而成之材料等。 The acrylic resin is exemplified as the material of the resin sheet constituting the reflection sheet 20, but the acrylic resin is not limited thereto. For example, a polyester resin such as PET (polyethylene terephthalate) resin or a urethane can be used. An ester resin, a material obtained by combining the same, and the like.

作為構成反射片20之光反射構件,例如可使用樹脂中內包有氣泡或粒子之膜或金屬蒸鍍膜等。 As the light reflecting member constituting the reflection sheet 20, for example, a film in which bubbles or particles are contained in a resin, a metal deposition film, or the like can be used.

亦可於反射片20設置黏著層,並貼合於玻璃板12。作為設置於反射片20之黏著層,例如可使用丙烯酸系樹脂、聚矽氧樹脂、胺基甲酸酯樹脂、合成橡膠等。 An adhesive layer may be provided on the reflection sheet 20 and attached to the glass plate 12. As the adhesive layer provided on the reflection sheet 20, for example, an acrylic resin, a polyoxymethylene resin, a urethane resin, a synthetic rubber or the like can be used.

反射片20之厚度並無特別限定,例如可使用0.01~0.50mm者。 The thickness of the reflection sheet 20 is not particularly limited, and for example, 0.01 to 0.50 mm can be used.

各種光學片22可使用乳白色之丙烯酸系樹脂製膜等。各種光學片22使自玻璃板12之光出射面26出射之光擴散,故而無亮度不均之均勻之光照射至液晶面板16之背面側。再者,各種光學片22係以不與玻璃板12抵接之方式對向地配設於特定位置。 As the various optical sheets 22, a milky white acrylic resin film or the like can be used. Since the various optical sheets 22 diffuse the light emitted from the light exit surface 26 of the glass sheet 12, uniform light having no unevenness in brightness is irradiated onto the back surface side of the liquid crystal panel 16. Further, the various optical sheets 22 are disposed opposite to each other so as not to be in contact with the glass sheet 12.

<玻璃板12之物性> <Physical properties of the glass plate 12>

玻璃板12係由透明度較高之玻璃構成。於實施形態中,作為用 作玻璃板12之玻璃之材料,使用多成分系之氧化物玻璃。 The glass plate 12 is composed of a glass having a high transparency. In the embodiment, as a use As the material of the glass of the glass plate 12, a multi-component oxide glass is used.

具體而言,作為玻璃板12,較佳為使用50mm長度下之波長400~700nm下之平均內部透過率為90%以上之玻璃。藉此,可極力抑制入射至玻璃板12之光之衰減。50mm長度下之透過率係藉由將玻璃板12沿與主平面垂直之方向割斷,自該玻璃板之中心部分以縱50mm×橫50mm之尺寸取樣,於以相互對向之第1及第2割斷面成為算術平均粗糙度Ra≦0.03μm之方式製成之樣本A中,以距上述第1割斷面沿法線方向為50mm之長度,利用狹縫等使入射光之束寬窄於板厚,並利用可進行50mm長度下之測定之分光測定裝置(例如UH4150:日立高新技術公司製造)進行測定。自以如上方式而獲得之50mm長度下之透過率去除表面之反射而導致之損耗,藉此獲得50mm長度下之內部透過率。50mm長度下之波長400~700nm下之平均內部透過率較佳為92%以上,更佳為95%以上,進而較佳為98%以上,尤佳為99%以上。 Specifically, as the glass plate 12, it is preferable to use a glass having an average internal transmittance of 90% or more at a wavelength of 400 to 700 nm at a length of 50 mm. Thereby, the attenuation of light incident on the glass plate 12 can be suppressed as much as possible. The transmittance at a length of 50 mm is obtained by cutting the glass sheet 12 in a direction perpendicular to the main plane, and sampling from the central portion of the glass sheet at a length of 50 mm × a width of 50 mm to the first and second sides facing each other. In the sample A prepared in such a manner that the cut surface has an arithmetic mean roughness Ra ≦ 0.03 μm, the beam width of the incident light is narrower than the plate thickness by a slit or the like with a length of 50 mm from the normal direction of the first cut surface. The measurement was carried out by a spectroscopic measuring device (for example, UH4150: manufactured by Hitachi High-Technologies Corporation) which can measure the length of 50 mm. The transmittance at a length of 50 mm obtained in the above manner removes the loss caused by the reflection of the surface, thereby obtaining the internal transmittance at a length of 50 mm. The average internal transmittance at a wavelength of 400 to 700 nm at a length of 50 mm is preferably 92% or more, more preferably 95% or more, further preferably 98% or more, and particularly preferably 99% or more.

就滿足上述50mm長度下之波長400~700nm下之平均內部透過率之方面而言,用作玻璃板12之玻璃之鐵之含量之總量A較佳為100質量ppm以下,更佳為40質量ppm以下,進而較佳為20質量ppm以下。另一方面,就於製造多成分系之氧化物玻璃時提高玻璃之熔解性之方面而言,用作玻璃板12之玻璃之鐵之含量之總量A較佳為5質量ppm以上,更佳為8質量ppm以上,進而較佳為10質量ppm以上。再者,用作玻璃板12之玻璃之鐵之含量之總量A可藉由製造玻璃時所添加之鐵之量進行調節。 The total amount A of the content of iron used as the glass of the glass plate 12 is preferably 100 ppm by mass or less, more preferably 40%, in terms of satisfying the average internal transmittance at a wavelength of 400 to 700 nm in the above 50 mm length. It is preferably ppm or less, more preferably 20 ppm by mass or less. On the other hand, the total amount A of the content of iron used as the glass of the glass plate 12 is preferably 5 ppm by mass or more, more preferably in terms of improving the meltability of the glass in the production of the multi-component oxide glass. It is 8 ppm by mass or more, and more preferably 10 ppm by mass or more. Further, the total amount A of the content of iron used as the glass of the glass plate 12 can be adjusted by the amount of iron added when the glass is produced.

於本說明書中,將玻璃之鐵之含量之總量A表示為Fe2O3之含量,但玻璃中所存在之鐵並非全部以Fe3+(3價鐵)之形式存在。通常,玻璃中同時存在Fe3+與Fe2+(2價鐵)。Fe2+及Fe3+於波長400~700nm之範圍內存在吸收,但Fe2+之吸收係數(11cm-1 Mol-1)較Fe3+之吸收係數 (0.96cm-1 Mol-1)大十倍,故而會使波長400~700nm下之內部透過率進一步降低。因此,就提高波長400~700nm下之內部透過率之方面而言,較佳為Fe2+之含量較少。 In the present specification, the total amount A of the content of iron in the glass is expressed as the content of Fe 2 O 3 , but not all of the iron present in the glass exists in the form of Fe 3+ (trivalent iron). Usually, Fe 3+ and Fe 2+ (bivalent iron) are present in the glass. Fe 2+ and Fe 3+ absorb in the range of wavelength 400~700nm, but the absorption coefficient of Fe 2+ (11cm -1 Mol -1 ) is larger than that of Fe 3+ (0.96cm -1 Mol -1 ) Ten times, the internal transmittance at a wavelength of 400 to 700 nm is further lowered. Therefore, in terms of increasing the internal transmittance at a wavelength of 400 to 700 nm, it is preferred that the content of Fe 2+ is small.

就於有效光程長度下滿足上述可見光區域之平均內部透過率之方面而言,用作玻璃板12之玻璃之Fe2+之含量B較佳為20質量ppm以下,更佳為10質量ppm以下,進而較佳為5質量ppm以下。另一方面,就於製造多成分系之氧化物玻璃時提高玻璃之熔解性之方面而言,用作玻璃板12之玻璃之Fe2+之含量B較佳為0.01質量ppm以上,更佳為0.05質量ppm以上,進而較佳為0.1質量ppm以上。 The content B of Fe 2+ used as the glass of the glass sheet 12 is preferably 20 ppm by mass or less, more preferably 10 ppm by mass or less, in terms of satisfying the average internal transmittance of the visible light region under the effective optical path length. Further, it is preferably 5 ppm by mass or less. On the other hand, in terms of improving the meltability of the glass in the production of the multi-component oxide glass, the content B of Fe 2+ used as the glass of the glass plate 12 is preferably 0.01 ppm by mass or more, more preferably 0.05 mass ppm or more, further preferably 0.1 mass ppm or more.

再者,用作玻璃板12之玻璃之Fe2+之含量可根據製造玻璃時所添加之氧化劑之量、或熔解溫度等進行調節。關於製造玻璃時所添加之氧化劑之具體之種類與其等之添加量,於下文中進行敍述。Fe2O3之含量A係藉由螢光X射線測定而求出之換算成Fe2O3之總鐵之含量(質量ppm)。Fe2+之含量B係依據ASTM C169-92進行測定。再者,所測得之Fe2+之含量係換算成Fe2O3後記載。 Further, the content of Fe 2+ used as the glass of the glass plate 12 can be adjusted depending on the amount of the oxidizing agent added at the time of glass production, the melting temperature, and the like. The specific type of the oxidizing agent added when the glass is produced and the amount of the oxidizing agent added thereto will be described later. Fe 2 O 3 content of the A-type fluorescent X-ray measurement is determined by the content of the total iron in terms of Fe 2 O 3 of (mass ppm). The content B of Fe 2+ was measured in accordance with ASTM C169-92. Further, the content of Fe 2+ measured is measured in terms of Fe 2 O 3 .

將用作玻璃板12之玻璃之組成之具體例示於以下。但是,用作玻璃板12之玻璃之組成並不限定於該等。 Specific examples of the composition of the glass used as the glass plate 12 are shown below. However, the composition of the glass used as the glass plate 12 is not limited to these.

用作玻璃板12之玻璃之一構成例(構成例A)以氧化物基準之質量百分率表示,包含SiO2 60~80%、Al2O3 0~7%、MgO 0~10%、CaO 0~20%、SrO 0~15%、BaO 0~15%、Na2O 3~20%、K2O 0~10%、Fe2O3 5~100質量ppm。 A configuration example (constitution example A) of the glass used as the glass plate 12 is expressed by mass percentage based on oxide, and includes SiO 2 60 to 80%, Al 2 O 3 0 to 7%, MgO 0 to 10%, and CaO 0 . ~20%, SrO 0~15%, BaO 0~15%, Na 2 O 3~20%, K 2 O 0~10%, Fe 2 O 3 5~100 mass ppm.

用作玻璃板12之玻璃之另一構成例(構成例B)以氧化物基準之質量百分率表示,包含SiO2 45~80%、Al2O3超過7%且30%以下、B2O3 0~15%、MgO 0~15%、CaO 0~6%、SrO 0~5%、BaO 0~5%、Na2O 7~20%、K2O 0~10%、ZrO2 0~10%、Fe2O3 5~100質量ppm。 Another configuration example (constitution example B) of the glass used as the glass plate 12 is expressed by mass percentage based on oxide, and includes SiO 2 45 to 80%, Al 2 O 3 of more than 7% and 30% or less, and B 2 O 3 . 0~15%, MgO 0~15%, CaO 0~6%, SrO 0~5%, BaO 0~5%, Na 2 O 7~20%, K 2 O 0~10%, ZrO 2 0~10 %, Fe 2 O 3 5 to 100 ppm by mass.

用作玻璃板12之玻璃之又一構成例(構成例C)以氧化物基準之質 量百分率表示,包含SiO2 45~70%、Al2O3 10~30%、B2O3 0~15%、MgO、CaO、SrO及BaO合計5~30%、Li2O、Na2O及K2O合計0%以上且未達3%、Fe2O3 5~100質量ppm。 Another configuration example (constitution example C) of the glass used as the glass plate 12 is represented by mass percentage of the oxide standard, and includes SiO 2 45 to 70%, Al 2 O 3 10 to 30%, and B 2 O 3 0 to 15 The total amount of %, MgO, CaO, SrO, and BaO is 5 to 30%, and Li 2 O, Na 2 O, and K 2 O are 0% or more in total and less than 3%, and Fe 2 O 3 is 5 to 100 ppm by mass.

然而,用作玻璃板12之玻璃並不限定於該等。 However, the glass used as the glass plate 12 is not limited to these.

以下對具有上述成分之本實施形態之玻璃板12之玻璃之組成之各成分之組成範圍進行說明。再者,各組成之含量之單位均為氧化物基準之質量百分率表示或質量ppm表示,分別簡單表示為「%」、「ppm」。 Hereinafter, the composition range of each component of the composition of the glass of the glass plate 12 of the present embodiment having the above-described composition will be described. Further, the unit of the content of each component is expressed by the mass percentage of the oxide standard or the mass ppm, and is simply expressed as "%" or "ppm".

SiO2係玻璃之主要成分。 The main component of SiO 2 -based glass.

為了確保玻璃之耐候性、失透特性,SiO2之含量於構成例A中,較佳為60%以上,更佳為63%以上,於構成例B中,較佳為45%以上,更佳為50%以上,於構成例C中,較佳為45%以上,更佳為50%以上。 In order to ensure the weather resistance and devitrification resistance of the glass, the content of SiO 2 is preferably 60% or more, more preferably 63% or more in the configuration example A, and more preferably 45% or more in the configuration example B, more preferably It is 50% or more, and in Structural Example C, it is preferably 45% or more, and more preferably 50% or more.

另一方面,為了容易熔解而使氣泡品質良好,且為了將玻璃中之二價鐵(Fe2+)之含量抑制為較低而使光學特性良好,SiO2之含量於構成例A中,較佳為80%以下,更佳為75%以下,於構成例B中,較佳為80%以下,更佳為70%以下,於構成例C中,較佳為70%以下,更佳為65%以下。 On the other hand, in order to facilitate the melting, the quality of the bubbles is good, and in order to suppress the content of ferrous iron (Fe 2+ ) in the glass to be low, the optical characteristics are good, and the content of SiO 2 is in the configuration example A. Preferably, it is 80% or less, more preferably 75% or less, and in Structural Example B, it is preferably 80% or less, more preferably 70% or less, and in Structural Example C, it is preferably 70% or less, more preferably 65. %the following.

Al2O3於構成例B及C中係提高玻璃之耐候性之必需成分。於本實施形態之玻璃中,為了維持實際使用所必需之耐候性,Al2O3之含量於構成例A中,較佳為1%以上,更佳為2%以上,於構成例B中,較佳為超過7%,更佳為10%以上,於構成例C中,較佳為10%以上,更佳為13%以上。 Al 2 O 3 is an essential component for improving the weather resistance of the glass in the constituent examples B and C. In the glass of the present embodiment, in order to maintain the weather resistance necessary for practical use, the content of Al 2 O 3 is preferably 1% or more, more preferably 2% or more in the configuration example A, and in the configuration example B, It is preferably more than 7%, more preferably 10% or more, and in Composition Example C, it is preferably 10% or more, and more preferably 13% or more.

但是,為了將二價鐵(Fe+)之含量抑制為較低而使光學特性良好,並使氣泡品質良好,Al2O3之含量於構成例A中,較佳為7%以下,更佳為5%以下,於構成例B中,較佳為30%以下,更佳為23%以下,於構成例C中,較佳為30%以下,更佳為20%以下。 However, in order to suppress the content of the ferrous iron (Fe + ) to a low level, the optical characteristics are good, and the bubble quality is good, and the content of Al 2 O 3 is preferably 7% or less, more preferably 7% or less, in the configuration example A. It is 5% or less, and is preferably 30% or less, more preferably 23% or less in the configuration example B, and is preferably 30% or less, more preferably 20% or less in the configuration example C.

B2O3係促進玻璃原料之熔融並提高機械特性或耐候性之成分,為了不產生揮發所導致之脈理(ream)、爐壁之侵蝕等不良情況,B2O3之含量於玻璃A中,較佳為5%以下,更佳為3%以下,於構成例B及C中,較佳為15%以下,更佳為12%以下。 B 2 O 3 is a component that promotes melting of a glass raw material and improves mechanical properties or weather resistance, and the content of B 2 O 3 is in glass A in order to prevent problems such as ream and erosion of the furnace wall due to volatilization. The amount is preferably 5% or less, more preferably 3% or less, and in the configuration examples B and C, it is preferably 15% or less, more preferably 12% or less.

Li2O、Na2O、及K2O等鹼金屬氧化物係對促進玻璃原料之熔融並調整熱膨脹、黏性等有用之成分。 An alkali metal oxide such as Li 2 O, Na 2 O, or K 2 O is a useful component for promoting melting of a glass raw material and adjusting thermal expansion and viscosity.

因此,Na2O之含量於構成例A中,較佳為3%以上,更佳為8%以上。Na2O之含量於構成例B中,較佳為7%以上,更佳為10%以上。但是,為了保持熔解時之澄清性而確保所製造之玻璃之氣泡品質,Na2O之含量於構成例A及B中,較佳為設為20%以下,進而較佳為設為15%以下,於構成例C中,較佳為設為3%以下,更佳為設為1%以下。 Therefore, the content of Na 2 O is preferably 3% or more, and more preferably 8% or more in the configuration example A. The content of Na 2 O is preferably 7% or more, and more preferably 10% or more in the configuration example B. However, in order to maintain the clarity at the time of melting, the bubble quality of the glass to be produced is ensured, and the content of Na 2 O is preferably 20% or less, and more preferably 15% or less in the configuration examples A and B. In Structural Example C, it is preferably 3% or less, and more preferably 1% or less.

又,K2O之含量於構成例A及B中,較佳為10%以下,更佳為7%以下,於構成例C中,較佳為2%以下,更佳為1%以下。 In addition, the content of K 2 O is preferably 10% or less, more preferably 7% or less, and is preferably 2% or less, and more preferably 1% or less in Structural Example C.

又,Li2O為任意成分,為了容易進行玻璃化並將源自原料之以雜質之形式而包含之鐵含量抑制為較低而將批量成本抑制為較低,於構成例A、B及C中,可含有2%以下之Li2O。 Further, Li 2 O is an optional component, and in order to facilitate the vitrification, the iron content contained in the form of impurities derived from the raw material is suppressed to be low, and the batch cost is suppressed to be low, in the configuration examples A, B, and C. In the middle, it may contain 2% or less of Li 2 O.

又,為了保持熔解時之澄清性而確保所製造之玻璃之氣泡品質,該等鹼金屬氧化物之合計含量(Li2O+Na2O+K2O)於構成例A及B中,較佳為5%~20%,更佳為8%~15%,於構成例C中,較佳為0%~2%,更佳為0%~1%。 Further, in order to maintain the time of melting and fining the bubble to ensure the quality of the manufactured glass, the total content of such alkali metal oxides (Li 2 O + Na 2 O + K 2 O) in Examples A and B configuration, more Preferably, it is 5% to 20%, more preferably 8% to 15%, and in the composition example C, it is preferably 0% to 2%, more preferably 0% to 1%.

MgO、CaO、SrO、及BaO等鹼土金屬氧化物係對促進玻璃原料之熔融並調整熱膨脹、黏性等有用之成分。 An alkaline earth metal oxide such as MgO, CaO, SrO, or BaO is a useful component for promoting melting of a glass raw material and adjusting thermal expansion and viscosity.

MgO具有降低玻璃熔解時之黏性而促進熔解之作用。又,具有降低比重而不易對玻璃板造成瑕疵之作用,故而可於構成例A、B及C中含有。又,為了降低玻璃之熱膨脹係數而使失透特性良好,MgO之 含量於構成例A中,較佳為10%以下,更佳為8%以下,於構成例B中,較佳為15%以下,更佳為12%以下,於構成例C中,較佳為10%以下,更佳為5%以下。 MgO has the effect of lowering the viscosity at the time of glass melting and promoting melting. Further, since it has a function of lowering the specific gravity and is less likely to cause enthalpy to the glass sheet, it can be contained in the configuration examples A, B, and C. Moreover, in order to lower the thermal expansion coefficient of the glass, the devitrification property is good, and MgO is The content of the composition example A is preferably 10% or less, more preferably 8% or less, and in the configuration example B, it is preferably 15% or less, more preferably 12% or less, and in the configuration example C, it is preferably 10% or less, more preferably 5% or less.

CaO係促進玻璃原料之熔融且調整黏性、熱膨脹等之成分,因此可於構成例A、B及C中含有。為了獲得上述作用,於構成例A中,CaO之含量較佳為3%以上,更佳為5%以上。又,為了使失透良好,於構成例A中,較佳為20%以下,更佳為10%以下,於構成例B中,較佳為6%以下,更佳為4%以下。 Since CaO promotes melting of a glass raw material and adjusts components such as viscosity and thermal expansion, it can be contained in Structural Examples A, B, and C. In order to obtain the above effects, in the configuration example A, the content of CaO is preferably 3% or more, more preferably 5% or more. In addition, in the configuration example A, it is preferably 20% or less, more preferably 10% or less, and in the configuration example B, it is preferably 6% or less, and more preferably 4% or less.

SrO具有增大熱膨脹係數及降低玻璃之高溫黏度之效果。為了獲得該效果,於構成例A、B及C中,可含有SrO。但是,為了將玻璃之熱膨脹係數抑制為較低,SrO之含量於構成例A及C中,較佳為設為15%以下,更佳為設為10%以下,於構成例B中,較佳為設為5%以下,更佳為設為3%以下。 SrO has the effect of increasing the coefficient of thermal expansion and lowering the high temperature viscosity of the glass. In order to obtain this effect, in the configuration examples A, B, and C, SrO may be contained. However, in order to suppress the thermal expansion coefficient of the glass to be low, the content of SrO is preferably 15% or less, more preferably 10% or less in the configuration examples A and C. It is set to 5% or less, and more preferably set to 3% or less.

BaO與SrO同樣地具有增大熱膨脹係數及降低玻璃之高溫黏度之效果。為了獲得上述效果,可含有BaO。但是,為了將玻璃之熱膨脹係數抑制為較低,於構成例A及C中,較佳為設為15%以下,更佳為設為10%以下,於構成例B中,較佳為設為5%以下,更佳為設為3%以下。 BaO has the same effect of increasing the coefficient of thermal expansion and lowering the high temperature viscosity of the glass, similarly to SrO. In order to obtain the above effects, BaO may be contained. However, in order to suppress the thermal expansion coefficient of the glass to be low, in the configuration examples A and C, it is preferably 15% or less, more preferably 10% or less, and in the configuration example B, it is preferably set to 5% or less, more preferably 3% or less.

又,為了將熱膨脹係數抑制為較低、使失透特性良好、並維持強度,該等鹼土金屬氧化物之合計含量(MgO+CaO+SrO+BaO)於構成例A中,較佳為10%~30%,更佳為13%~27%,於構成例B中,較佳為1%~15%,更佳為3%~10%,於構成例C中,較佳為5%~30%,更佳為10%~20%。 Further, in order to suppress the thermal expansion coefficient to a low level, to improve the devitrification property, and to maintain the strength, the total content of the alkaline earth metal oxides (MgO + CaO + SrO + BaO) is preferably 10% in the configuration example A. ~30%, more preferably 13% to 27%, in Composition B, preferably 1% to 15%, more preferably 3% to 10%, and in Composition C, preferably 5% to 30% %, more preferably 10% to 20%.

於本實施形態之玻璃板12之玻璃之玻璃組成中,為了提高玻璃之耐熱性及表面硬度,於構成例A、B及C中,可含有10%以下、較佳為5%以下之ZrO2作為任意成分。藉由設為10%以下,玻璃變得不易失 透。 In the glass composition of the glass of the glass plate 12 of the present embodiment, in order to improve the heat resistance and surface hardness of the glass, the composition examples A, B, and C may contain 10% or less, preferably 5% or less of ZrO 2 . As an optional ingredient. By setting it to 10% or less, glass becomes hard to devitrify.

於本實施形態之玻璃板12之玻璃之玻璃組成中,為了提高玻璃之熔解性,於構成例A、B及C中,可含有5~100ppm之Fe2O3。再者,Fe2O3量之較佳之範圍如上所述。 In the glass composition of the glass of the glass plate 12 of the present embodiment, in order to improve the meltability of the glass, the composition examples A, B, and C may contain 5 to 100 ppm of Fe 2 O 3 . Further, the preferred range of the amount of Fe 2 O 3 is as described above.

又,本實施形態之玻璃板12之玻璃亦可含有SO3作為澄清劑。於此情形時,SO3含量以質量百分率表示,較佳為超過0%且0.5%以下。更佳為0.4%以下,進而較佳為0.3%以下,進而較佳為0.25%以下。 Further, the glass of the glass plate 12 of the present embodiment may contain SO 3 as a clarifying agent. In this case, the SO 3 content is expressed by mass percentage, preferably more than 0% and 0.5% or less. It is more preferably 0.4% or less, further preferably 0.3% or less, further preferably 0.25% or less.

又,本實施形態之玻璃板12之玻璃亦可含有Sb2O3、SnO2及As2O3中之一種以上作為氧化劑及澄清劑。於此情形時,Sb2O3、SnO2或As2O3之含量以質量百分率表示,較佳為0~0.5%。更佳為0.2%以下,進而較佳為0.1%以下,進而較佳為實質上不含有。 Further, the glass of the glass plate 12 of the present embodiment may contain one or more of Sb 2 O 3 , SnO 2 and As 2 O 3 as an oxidizing agent and a clarifying agent. In this case, the content of Sb 2 O 3 , SnO 2 or As 2 O 3 is expressed by mass percentage, preferably 0 to 0.5%. It is more preferably 0.2% or less, further preferably 0.1% or less, and further preferably substantially not contained.

但是,由於Sb2O3、SnO2及As2O3係作為玻璃之氧化劑發揮作用,故而亦可以調節玻璃之Fe2+之量為目的於上述範圍內進行添加。但是,就環境方面而言,較佳為實質上不含有As2O3However, since Sb 2 O 3 , SnO 2 and As 2 O 3 act as oxidizing agents for glass, it is also possible to adjust the amount of Fe 2+ in the glass for the purpose of adding in the above range. However, in terms of the environment, it is preferred that substantially no As 2 O 3 is contained.

又,本實施形態之玻璃板12之玻璃亦可含有NiO。於含有NiO之情形時,NiO亦作為著色成分發揮功能,因此NiO之含量相對於上述玻璃組成之總量,較佳為設為10ppm以下。尤其就不降低波長400~700nm下之玻璃板之內部透過率之觀點而言,NiO較佳為設為1.0ppm以下,更佳為設為0.5ppm以下。 Further, the glass of the glass plate 12 of the present embodiment may contain NiO. When NiO is contained, NiO also functions as a coloring component. Therefore, the content of NiO is preferably 10 ppm or less based on the total amount of the glass composition. In particular, NiO is preferably 1.0 ppm or less, and more preferably 0.5 ppm or less from the viewpoint of not lowering the internal transmittance of the glass plate at a wavelength of 400 to 700 nm.

本實施形態之玻璃板12之玻璃亦可含有Cr2O3。於含有Cr2O3之情形時,Cr2O3亦作為著色成分發揮功能,因此Cr2O3之含量相對於上述玻璃組成之總量,較佳為設為10ppm以下。尤其就降低波長400~700nm下之玻璃板之內部透過率之觀點而言,Cr2O3較佳為設為1.0ppm以下,更佳為設為0.5ppm以下。 Aspect of this embodiment of the glass sheet glass 12 may also contain Cr 2 O 3. When Cr 2 O 3 is contained, Cr 2 O 3 also functions as a coloring component. Therefore, the content of Cr 2 O 3 is preferably 10 ppm or less based on the total amount of the glass composition. In particular, from the viewpoint of lowering the internal transmittance of the glass plate at a wavelength of 400 to 700 nm, Cr 2 O 3 is preferably 1.0 ppm or less, more preferably 0.5 ppm or less.

本實施形態之玻璃板12之玻璃亦可含有MnO2。於含有MnO2之情形時,MnO2亦作為吸收可見光之成分發揮功能,因此MnO2之含量相 對於上述玻璃組成之總量,較佳為設為50ppm以下。尤其就降低波長400~700nm下之玻璃板之內部透過率之觀點而言,MnO2較佳為設為10ppm以下。 Aspect of this embodiment of the glass sheet glass 12 may also contain MnO 2. When MnO 2 is contained, MnO 2 also functions as a component that absorbs visible light. Therefore, the content of MnO 2 is preferably 50 ppm or less based on the total amount of the glass composition. In particular, from the viewpoint of lowering the internal transmittance of the glass plate at a wavelength of 400 to 700 nm, MnO 2 is preferably 10 ppm or less.

本實施形態之玻璃板12之玻璃亦可包含TiO2。於含有TiO2之情形時,TiO2亦作為吸收可見光之成分發揮功能,因此TiO2之含量相對於上述玻璃組成之總量,較佳為設為1000ppm以下。就降低波長400~700nm下之玻璃板之內部透過率之觀點而言,TiO2更佳為將含量設為500ppm以下,尤佳為設為100ppm以下。 The glass of the glass plate 12 of this embodiment may also contain TiO 2 . When TiO 2 is contained, TiO 2 also functions as a component that absorbs visible light. Therefore, the content of TiO 2 is preferably 1000 ppm or less based on the total amount of the glass composition. From the viewpoint of lowering the internal transmittance of the glass plate at a wavelength of 400 to 700 nm, the content of TiO 2 is preferably 500 ppm or less, and more preferably 100 ppm or less.

本實施形態之玻璃板12之玻璃亦可包含CeO2。CeO2具有降低鐵之氧化還原之效果,且可減小Fe2+量相對於總鐵量之比率。另一方面,為了抑制將鐵之氧化還原降低至未達3%,CeO2之含量相對於上述玻璃組成之總量,亦較佳為設為1000ppm以下。又,CeO2之含量更佳為設為500ppm以下,進而較佳為設為400ppm以下,尤佳為設為300ppm以下,最佳為設為250ppm以下。 The glass of the glass plate 12 of this embodiment may also contain CeO 2 . CeO 2 has the effect of reducing the redox of iron and can reduce the ratio of the amount of Fe 2+ to the total amount of iron. On the other hand, in order to suppress the reduction of the redox of iron to less than 3%, the content of CeO 2 is preferably set to 1000 ppm or less based on the total amount of the glass composition. Further, the content of CeO 2 is more preferably 500 ppm or less, further preferably 400 ppm or less, more preferably 300 ppm or less, and most preferably 250 ppm or less.

本實施形態之玻璃板12之玻璃亦可包含選自由CoO、V2O5及CuO所組成之群中之至少1種成分。於含有該等成分之情形時,由於亦作為吸收可見光之成分發揮功能,因此上述成分之含量相對於上述玻璃組成之總量,較佳為設為10ppm以下。尤佳為實質上不含有該等成分使得波長400~700nm下之玻璃板之內部透過率不會降低。 The glass of the glass plate 12 of the present embodiment may further contain at least one component selected from the group consisting of CoO, V 2 O 5 and CuO. When the components are contained, since they function as a component that absorbs visible light, the content of the above components is preferably 10 ppm or less based on the total amount of the glass composition. It is particularly preferable that the components are not substantially contained so that the internal transmittance of the glass plate having a wavelength of 400 to 700 nm is not lowered.

<玻璃板12之形狀> <Shape of glass plate 12>

圖3係玻璃板12之整體立體圖,圖4係玻璃板12之剖面放大圖。再者,於圖4中,將相對於主平面與入光端面28垂直之剖面之一部分放大後表示。 3 is an overall perspective view of the glass sheet 12, and FIG. 4 is an enlarged cross-sectional view of the glass sheet 12. Further, in Fig. 4, a portion of the cross section perpendicular to the principal plane and the light incident end surface 28 is enlarged and shown.

俯視矩形狀之玻璃板12具有光出射面26、光反射面32、入光端面28、非入光端面34、36、38、入光側倒角面40、及非入光側倒角面42。 The glass plate 12 having a rectangular shape in plan view has a light exit surface 26, a light reflecting surface 32, a light incident end surface 28, non-light incident end faces 34, 36, 38, a light incident side chamfer surface 40, and a non-light incident side chamfer surface 42. .

此處,光出射面26及光反射面32相當於本實施形態之主平面,入光端面28相當於本實施形態之端面。又,入光側倒角面40相當於本實施形態之倒角面。 Here, the light exit surface 26 and the light reflecting surface 32 correspond to the principal plane of the embodiment, and the light incident end surface 28 corresponds to the end surface of the embodiment. Further, the light incident side chamfered surface 40 corresponds to the chamfered surface of the present embodiment.

光出射面26係與液晶面板16對向之面。於實施形態中,將光出射面26設為俯視下為矩形狀,但光出射面26之形狀並不限定於此。又,由於光出射面26之大小係對應於液晶面板16而確定,故而並無特別限定,於使用玻璃板12作為導光板之情形時,例如較佳為500mm×500mm以上之尺寸。由於玻璃板12具有較高之剛性,故而尺寸越大,越發揮出其效果。 The light exit surface 26 is opposed to the liquid crystal panel 16. In the embodiment, the light exit surface 26 is formed in a rectangular shape in plan view, but the shape of the light exit surface 26 is not limited thereto. Further, since the size of the light exit surface 26 is determined in accordance with the liquid crystal panel 16, it is not particularly limited. When the glass plate 12 is used as the light guide plate, for example, it is preferably 500 mm × 500 mm or more. Since the glass plate 12 has a high rigidity, the larger the size, the more the effect is exerted.

光反射面32係與光出射面26對向之面。光反射面32係以相對於光出射面26成為平行之方式構成。又,光反射面32之形狀及尺寸係以與光出射面26成為相同之方式構成。 The light reflecting surface 32 is opposed to the light emitting surface 26 . The light reflecting surface 32 is configured to be parallel to the light emitting surface 26 . Further, the shape and size of the light reflecting surface 32 are configured to be the same as the light emitting surface 26.

再者,光反射面32相對於光出射面26未必需要設為平行,亦可設為設置有階差或傾斜之構成。又,光反射面32之尺寸亦可設為與光出射面26不同之尺寸。 Further, the light reflecting surface 32 is not necessarily required to be parallel to the light emitting surface 26, and may be configured to have a step or a tilt. Further, the size of the light reflecting surface 32 may be set to be different from the light emitting surface 26.

如圖1及圖2所示,於光反射面32具備複數個圓形狀之反射點24A、24B、24C。反射點之配置可如圖2般設為柵格狀,亦可設為其他任意之圖案,亦可設為無規狀,以自光出射面26出射之光之亮度之分佈變得均勻之方式適當調整。反射點24A~24C係利用將樹脂印刷成點狀等方法形成,亦可含有散射粒子或氣泡。自入光端面28入射之光之亮度較強,但其亮度會隨著一面於玻璃板12之內部反覆反射一面前進而逐漸降低。 As shown in FIGS. 1 and 2, the light reflecting surface 32 is provided with a plurality of circular reflecting points 24A, 24B, and 24C. The arrangement of the reflection points may be a grid shape as shown in FIG. 2, or may be any other pattern, or may be a random shape, and the distribution of the brightness of the light emitted from the light exit surface 26 may be uniform. Appropriate adjustments. The reflection points 24A to 24C are formed by printing a resin into a dot shape or the like, and may also contain scattering particles or bubbles. The light incident from the light incident end face 28 has a strong brightness, but its brightness gradually decreases as one side is reflected back inside the glass plate 12.

因此,於實施形態中,使反射點24A、24B、24C之大小自入光端面28朝向非入光端面38不同。具體而言,以將靠近入光端面28之區域中之反射點24A之直徑(LA)設定為較小,隨著較其更朝向光之前進方向而反射點24B之直徑(LB)、及反射點24C之直徑(LC)增大之方式設定 (LA<LB<LC)。反射點之直徑係以自光出射面26出射之光之亮度之分佈變得均勻之方式適當調整。 Therefore, in the embodiment, the sizes of the reflection points 24A, 24B, and 24C are different from the light incident end surface 28 toward the non-light incident end surface 38. Specifically, the diameter (L A ) of the reflection point 24A in the region close to the light incident end face 28 is set to be small, and the diameter (L B ) of the reflection point 24B is changed as it goes further toward the light forward direction. And the diameter (L C ) of the reflection point 24C is increased (L A <L B <L C ). The diameter of the reflection point is appropriately adjusted so that the distribution of the brightness of the light emitted from the light exit surface 26 becomes uniform.

如此,藉由使反射點24A、24B、24C之大小朝向玻璃板12之內部之光之前進方向變化,可使自光出射面26出射之出射光之亮度均勻化,從而可抑制產生亮度不均。再者,藉由使反射點24A、24B、24C之數密度代替反射點24A、24B、24C之大小而朝向玻璃板12之內部之光之前進方向變化,亦可獲得同等之效果。又,藉由於光反射面32形成使入射之光反射般之槽代替反射點24A、24B、24C,亦可獲得同等之效果。 By changing the size of the reflection points 24A, 24B, and 24C toward the inside of the glass plate 12, the brightness of the emitted light emitted from the light exit surface 26 can be made uniform, thereby suppressing uneven brightness. . Further, by changing the number of the reflection points 24A, 24B, and 24C in place of the reflection points 24A, 24B, and 24C, the light toward the inside of the glass sheet 12 is changed in the forward direction, and the same effect can be obtained. Further, the same effect can be obtained by forming a groove in which the incident light is reflected by the light reflecting surface 32 instead of the reflection points 24A, 24B, and 24C.

玻璃板12之非入光端面34、36、38由於不會使來自光源18之光入射,故而無需對其表面高精度地進行加工直至達到入光端面28之程度,其表面粗糙度Ra只要為0.8μm以下即可。但是,為了抑制光於端面散射而產生亮度不均,非入光端面34、36、38之表面粗糙度Ra較佳為0.4μm以下,進而較佳為0.1μm以下。再者,於本說明書中,於記載為表面粗糙度Ra之情形時,係指依據JIS B 0601~JIS B 0031所得之算術平均粗糙度(中心線平均粗糙度)。 Since the non-light-incident end faces 34, 36, and 38 of the glass plate 12 do not cause light from the light source 18 to enter, it is not necessary to process the surface with high precision until the light-incident end face 28 is reached, and the surface roughness Ra is only It can be 0.8 μm or less. However, in order to suppress unevenness in luminance due to scattering of light at the end faces, the surface roughness Ra of the non-light-incident end faces 34, 36, and 38 is preferably 0.4 μm or less, and more preferably 0.1 μm or less. In the present specification, when it is described as the surface roughness Ra, it means the arithmetic mean roughness (center line average roughness) obtained in accordance with JIS B 0601 to JIS B 0031.

入光端面28於製造作為玻璃板12之玻璃時進行鏡面加工。為了使來自光源18之光有效率地入射至玻璃板12之內部,入光端面28之表面粗糙度Ra為0.1μm以下,較佳為未達0.03μm,進而較佳為0.001μm以下,尤佳為0.0005μm以下。因此,提高自光源18入射至玻璃板12之內部之光之入射效率。就提高生產效率之觀點而言,非入光端面34、36、38之表面粗糙度Ra既可與入光端面28之表面粗糙度Ra同等,亦可大於入光端面28之表面粗糙度Ra。 The light incident end face 28 is mirror finished when the glass as the glass plate 12 is manufactured. In order to efficiently inject light from the light source 18 into the inside of the glass sheet 12, the surface roughness Ra of the light incident end surface 28 is 0.1 μm or less, preferably less than 0.03 μm, more preferably 0.001 μm or less, and particularly preferably It is 0.0005 μm or less. Therefore, the incidence efficiency of light incident from the light source 18 into the inside of the glass plate 12 is increased. The surface roughness Ra of the non-light-incident end faces 34, 36, 38 may be equal to the surface roughness Ra of the light-incident end face 28 or may be larger than the surface roughness Ra of the light-incident end face 28 from the viewpoint of improving production efficiency.

<入光側倒角面40(倒角面)> <light side chamfering surface 40 (chamfered surface)>

於光出射面26與入光端面28之間、及光反射面32與入光端面28之間具備入光側倒角面40。即,於光出射面26與入光端面28之間,與 光出射面26及入光端面28相鄰地具備入光側倒角面40。同樣地,於光反射面32與入光端面28之間,與光反射面32及入光端面28相鄰地具備入光側倒角面40。 A light incident side chamfering surface 40 is provided between the light exit surface 26 and the light incident end surface 28 and between the light reflecting surface 32 and the light incident end surface 28. That is, between the light exit surface 26 and the light incident end surface 28, The light exit surface 26 and the light incident end surface 28 are provided adjacent to the light incident side chamfer surface 40. Similarly, between the light reflecting surface 32 and the light incident end surface 28, the light incident side chamfering surface 40 is provided adjacent to the light reflecting surface 32 and the light incident end surface 28.

於實施形態中,例示了於光出射面26與入光端面28之間、光反射面32與入光端面28之間之兩者具備入光側倒角面40者,但亦可設為僅於其中一者具備入光側倒角面40之構成。又,入光側倒角面40之表面粗糙度Ra較佳為0.8μm以下,更佳為0.4μm以下,進而較佳為0.1μm以下。藉由將入光側倒角面40之表面粗糙度Ra設為0.8μm以下,亦可抑制自玻璃板12出射之光產生亮度不均。就其他觀點而言,藉由將入光側倒角面40之表面粗糙度Ra設為0.8μm以下,可將所入射之光有效率地提取至玻璃板12。又,藉由將入光側倒角面40之表面粗糙度Ra設為0.4μm以下,可抑制玻璃屑產生量。另一方面,入光側倒角面40之表面粗糙度Ra之下限並無限定,Ra越小,越可抑制玻璃板12之亮度不均之產生,但相應地於下述倒角步驟(S12)中需要時間。就提高生產效率之觀點而言,入光側倒角面40之表面粗糙度Ra較佳為大於入光端面28之表面粗糙度Ra。此處,非入光端面34、36、38之各非入光側倒角面42之表面粗糙度Ra較佳為0.8μm以下。藉由如上所述般設定,於在非入光端面及/或非入光側倒角面設置有反射帶時,可使自非入光端面及/或非入光側倒角面暫時洩漏之光經反射帶反射而自非入光側倒角面再次有效率地入射。 In the embodiment, the light-emitting side chamfering surface 40 is provided between the light-emitting surface 26 and the light-incident end surface 28, and the light-reflecting surface 32 and the light-incident end surface 28 are both provided. One of them has a configuration in which the light-incident side chamfered surface 40 is provided. Moreover, the surface roughness Ra of the light-incident side chamfering surface 40 is preferably 0.8 μm or less, more preferably 0.4 μm or less, and still more preferably 0.1 μm or less. By setting the surface roughness Ra of the light-incident side chamfering surface 40 to 0.8 μm or less, unevenness in brightness due to light emitted from the glass plate 12 can be suppressed. In other respects, by setting the surface roughness Ra of the light incident side chamfer surface 40 to 0.8 μm or less, the incident light can be efficiently extracted to the glass plate 12. In addition, by setting the surface roughness Ra of the light-incident side chamfering surface 40 to 0.4 μm or less, the amount of glass swarf generated can be suppressed. On the other hand, the lower limit of the surface roughness Ra of the light-incident side chamfering surface 40 is not limited, and the smaller the Ra, the more the unevenness of the brightness of the glass sheet 12 can be suppressed, but the chamfering step (S12) is correspondingly performed. It takes time. The surface roughness Ra of the light-incident side chamfered surface 40 is preferably larger than the surface roughness Ra of the light-incident end surface 28 from the viewpoint of improving production efficiency. Here, the surface roughness Ra of each of the non-light-incident side chamfered surfaces 42 of the non-light-incident end faces 34, 36, and 38 is preferably 0.8 μm or less. By setting as described above, when a reflection band is provided on the non-light-incident end surface and/or the non-light-incident side chamfering surface, the non-light-incident end surface and/or the non-light-incident side chamfer surface can be temporarily leaked. The light is reflected by the reflection band and is incident efficiently again from the non-light-incident side chamfered surface.

再者,關於入光側倒角面40之形狀及作用、效果,於下述玻璃板12之特徵之欄中進行說明。 In addition, the shape, action, and effect of the light-incident side chamfer surface 40 will be described in the column of the characteristics of the glass plate 12 described below.

於如實施形態般要求薄型化之面狀發光裝置14中,亦需要使玻璃板12之厚度較薄。因此,實施形態之玻璃板12之厚度為0.7~3.0mm。藉由使玻璃板12之厚度為3.0mm以下,可使面狀發光裝置14較薄,藉由使其為0.7mm以上,可獲得充分之剛性。再者,玻璃板12之 厚度並不限定於該值,但即便為該厚度,亦可提供與具有厚度4mm以上之丙烯酸製之導光板之面狀發光裝置相比較具備充分之強度之面狀發光裝置14。 In the planar light-emitting device 14 which is required to be thinned as in the embodiment, it is also necessary to make the thickness of the glass plate 12 thin. Therefore, the thickness of the glass plate 12 of the embodiment is 0.7 to 3.0 mm. By making the thickness of the glass plate 12 3.0 mm or less, the planar light-emitting device 14 can be made thin, and by making it 0.7 mm or more, sufficient rigidity can be obtained. Furthermore, the glass plate 12 The thickness is not limited to this value, but even if it is this thickness, the planar light-emitting device 14 having sufficient strength as compared with the planar light-emitting device having a light guide plate made of acrylic having a thickness of 4 mm or more can be provided.

[玻璃板12之製造方法] [Manufacturing Method of Glass Plate 12]

圖5、圖6、圖7係用以說明玻璃板12之製造方法之圖。圖5係表示玻璃板12之製造方法之步驟圖。圖6係玻璃原材料44之俯視圖,圖7係玻璃基材46之俯視圖。 5, 6, and 7 are views for explaining a method of manufacturing the glass sheet 12. Fig. 5 is a view showing the steps of a method of manufacturing the glass sheet 12. 6 is a plan view of the glass material 44, and FIG. 7 is a plan view of the glass substrate 46.

於製造玻璃板12時,首先準備圖6之玻璃原材料44。玻璃原材料44之厚度為0.7~3.0mm,50mm長度下之波長400~700nm下之平均內部透過率為90%以上。玻璃原材料44設為大於玻璃板12之既定形狀之形狀。 When manufacturing the glass sheet 12, the glass raw material 44 of Fig. 6 is first prepared. The thickness of the glass material 44 is 0.7 to 3.0 mm, and the average internal transmittance at a wavelength of 400 to 700 nm at a length of 50 mm is 90% or more. The glass raw material 44 is set to have a shape larger than the predetermined shape of the glass plate 12.

<切斷步驟> <cutting step>

首先對玻璃原材料44實施圖5之步驟(S)10所示之切斷步驟。於切斷步驟(S10)中,使用切削裝置於圖6之虛線所示之各位置(1處入光端面側之位置與3處非入光端面側之位置)實施切斷加工。再者,亦可未必對3處非入光端面側之位置實施切斷加工,亦可僅對與1處入光端面側之位置對向之1處非入光端面側之位置進行切斷加工。 First, the glass raw material 44 is subjected to the cutting step shown in the step (S) 10 of Fig. 5 . In the cutting step (S10), the cutting device is used to perform the cutting process at each position (the position on the light-incident end side and the position on the non-light-incident end face side) shown by the broken line in Fig. 6 . In addition, it is not necessary to perform cutting processing at the position of the three non-light-incident end faces, and it is also possible to cut only the position on the non-light-incident end face side opposite to the position on the light-incident end face side. .

藉由實施切斷加工,自圖6之玻璃原材料44切出圖7之玻璃基材46。再者,於實施形態中,由於將玻璃板12製成俯視下為矩形狀,故而對1處入光端面側之位置與3處非入光端面側之位置實施切斷加工,切斷位置係根據玻璃板12之形狀而適當選定。 The glass substrate 46 of Fig. 7 is cut out from the glass material 44 of Fig. 6 by performing a cutting process. In addition, in the embodiment, the glass plate 12 has a rectangular shape in plan view. Therefore, the position of the light incident end surface side and the position of the three non-light incident end faces are cut, and the cutting position is performed. It is suitably selected according to the shape of the glass plate 12.

再者,作為玻璃原材料44之切斷方法,例如可實施劃線割斷法或雷射切斷法等。就生產性之觀點而言,較佳為劃線割斷法。又,於將入光側倒角面40製成圓弧形狀之情形時,較佳為可將切剖面設為圓弧形狀之雷射切斷法。 Further, as the cutting method of the glass material 44, for example, a scribing method or a laser cutting method can be applied. From the viewpoint of productivity, the scribing method is preferred. Further, in the case where the light incident side chamfered surface 40 is formed into an arc shape, it is preferable to use a laser cutting method in which the cut cross section is an arc shape.

<第1倒角步驟> <1st chamfering step>

如圖5般,當切斷步驟(S10)結束時,實施第1倒角步驟(S12)。於第1倒角步驟(S12)中,使用研削裝置於光出射面26與非入光端面38之間、及光反射面32與非入光端面38之間之兩者分別形成非入光側倒角面42。 As shown in Fig. 5, when the cutting step (S10) is completed, the first chamfering step (S12) is performed. In the first chamfering step (S12), a non-light-in side is formed between the light-emitting surface 26 and the non-light-incident end surface 38, and between the light-reflecting surface 32 and the non-light-incident end surface 38, respectively, using a grinding device. Chamfered surface 42.

再者,於欲在光出射面26與非入光端面34之間、光反射面32與非入光端面34之間、光出射面26與非入光端面36之間、及光反射面32與非入光端面36之間之全部或任一處形成非入光側倒角面42之情形時,於該第1倒角步驟(S12)實施倒角加工。 Furthermore, between the light exit surface 26 and the non-light incident end surface 34, between the light reflecting surface 32 and the non-light incident end surface 34, between the light exit surface 26 and the non-light incident end surface 36, and the light reflecting surface 32 When the non-light-incident side chamfered surface 42 is formed at all or any of the non-light-incident end faces 36, the chamfering process is performed in the first chamfering step (S12).

又,就生產性之觀點而言,較佳為於第1倒角步驟(S12)中,對光出射面26與入光端面28之間、或光反射面32與入光端面28之間進行倒角加工。於此情形時,就生產性之觀點而言,所獲得之入光側倒角面40'(未圖示)之表面粗糙度Ra較佳為大於在下述第2倒角步驟中獲得之入光側倒角面40之表面粗糙度Ra。藉此,形成入光側倒角面40',於該階段連結下述P1與P2之線段L之相對於入光端面28之傾斜角度θ並無特別限定。 Further, from the viewpoint of productivity, it is preferable to perform between the light exit surface 26 and the light incident end surface 28 or between the light reflecting surface 32 and the light incident end surface 28 in the first chamfering step (S12). Chamfer processing. In this case, from the viewpoint of productivity, the surface roughness Ra of the obtained light-incident side chamfered surface 40' (not shown) is preferably larger than that obtained in the second chamfering step described below. The surface roughness Ra of the side chamfered surface 40. Thereby, the light incident side chamfered surface 40' is formed, and the inclination angle θ of the line segment L of the following P1 and P2 to the light incident end surface 28 is not particularly limited.

於第1倒角步驟(S12)中,對非入光端面34、36、38亦實施研削處理或研磨處理。對非入光端面34、36、38實施研削處理或研磨處理之時期既可為形成非入光側倒角面42之前段亦可為後段,亦可同時地進行。再者,關於非入光端面34、36,亦可將實施了切斷加工之面直接作為非入光端面34、36。 In the first chamfering step (S12), the non-light-incident end faces 34, 36, 38 are also subjected to a grinding process or a grinding process. The period in which the non-light-incident end faces 34, 36, and 38 are subjected to the grinding treatment or the polishing treatment may be performed in the front stage or the rear stage in which the non-light-incident side chamfered surface 42 is formed, or may be simultaneously performed. Further, regarding the non-light-incident end faces 34 and 36, the surface subjected to the cutting process may be directly used as the non-light-incident end faces 34 and 36.

就生產性之觀點而言,較佳為於第1倒角步驟(S12)中,對入光端面28亦實施研削處理或研磨處理。對入光端面28實施研削處理或研磨處理之時期既可為形成入光側倒角面42之前段亦可為後段,亦可同時地進行。 From the viewpoint of productivity, it is preferable that the light incident end surface 28 is also subjected to a grinding treatment or a polishing treatment in the first chamfering step (S12). The period in which the light-incident end surface 28 is subjected to the grinding treatment or the polishing treatment may be performed in the front stage or the rear stage in which the light-incident side chamfered surface 42 is formed, or may be simultaneously performed.

第1倒角步驟(S12)亦可與下述鏡面加工步驟(S14)及第2倒角步驟(S16)同時、或者於其等之後段進行,較佳為於早於其等之前段進 行。藉此,可於第1倒角步驟(S12)中以相對較快之速率實施對應於玻璃板12之形狀之加工,故而生產性提高。 The first chamfering step (S12) may be performed simultaneously with the mirror processing step (S14) and the second chamfering step (S16), or at a later stage thereof, preferably before the preceding stage. Row. Thereby, the processing corresponding to the shape of the glass sheet 12 can be performed at a relatively fast rate in the first chamfering step (S12), so that productivity is improved.

<鏡面加工步驟> <Mirror surface processing step>

當第1倒角步驟(S12)結束時,繼而實施鏡面加工步驟(S14)。於鏡面加工步驟(S14)中,對圖7所示之玻璃基材46之入光端面28實施鏡面加工,藉此形成表面粗糙度Ra為0.1μm以下之入光端面28。 When the first chamfering step (S12) is completed, the mirror finishing step (S14) is performed. In the mirror processing step (S14), the light incident end surface 28 of the glass substrate 46 shown in Fig. 7 is mirror-finished to form the light incident end surface 28 having a surface roughness Ra of 0.1 μm or less.

<第2倒角步驟> <2nd chamfering step>

若於鏡面加工步驟(S14)中於玻璃基材46形成入光端面28,則繼而實施第2倒角步驟(S16),對光出射面26與入光端面28之間、及光反射面32與入光端面28之間進行研削處理或研磨處理。藉此,形成入光側倒角面40。藉此於所形成之入光側倒角面40,連結下述P1與P2之線段L相對於入光端面28之傾斜角度θ滿足0.01≦tanθ≦0.75。藉此,可抑制光源18之光量損耗。再者,第2倒角步驟(S16)亦可於早於鏡面加工步驟(S14)之前段實施,又,亦可與鏡面加工步驟(S14)同時地實施。 When the light incident end surface 28 is formed in the glass substrate 46 in the mirror surface processing step (S14), the second chamfering step (S16) is performed, and between the light exit surface 26 and the light incident end surface 28, and the light reflecting surface 32. A grinding process or a grinding process is performed between the light incident end face 28 and the light incident end face 28. Thereby, the light incident side chamfer surface 40 is formed. Thereby, the inclination angle θ of the line segment L connecting the following P1 and P2 with respect to the light incident end surface 28 satisfies 0.01 ≦ tan θ ≦ 0.75 on the light incident side chamfering surface 40 formed. Thereby, the amount of light loss of the light source 18 can be suppressed. Further, the second chamfering step (S16) may be performed before the mirror processing step (S14), or may be performed simultaneously with the mirror processing step (S14).

於形成入光側倒角面40時,既可使用磨石作為實施研削處理或研磨處理之工具,又,除磨石以外,亦可使用包含布、皮、橡膠等之拋光輪或刷子等,此時,亦可使用氧化鈰、氧化鋁、碳化矽、膠體二氧化矽等研磨劑。其中,就尺寸穩定性之觀點而言,較佳為使用磨石作為研磨工具。 When the light-incident side chamfering surface 40 is formed, a grindstone may be used as a tool for performing a grinding process or a grinding process, and a polishing wheel or a brush including a cloth, a skin, a rubber, or the like may be used in addition to the grindstone. In this case, an abrasive such as cerium oxide, aluminum oxide, cerium carbide or colloidal cerium oxide can also be used. Among them, from the viewpoint of dimensional stability, it is preferred to use a grindstone as an abrasive tool.

藉由經過以上S10~S16所示之各步驟,製造玻璃板12。再者,反射點24A、24B、24C係藉由於製造玻璃板12後對光反射面32進行印刷等方法形成。 The glass sheet 12 is produced by the respective steps shown in the above S10 to S16. Further, the reflection points 24A, 24B, and 24C are formed by printing the glass plate 12 and then printing the light reflection surface 32.

[玻璃板12及面狀發光裝置14之特徵] [Features of the glass plate 12 and the planar light-emitting device 14]

如圖1般,作為面狀發光裝置14之玻璃板12,為了有效利用光源18之光量,要求使自入光端面28入射至玻璃板12之內部之光於並未賦 予反射點24A~C之狀態下不漏光至外部而一面於玻璃板12之內表面反覆全反射一面前進。 As shown in Fig. 1, in order to effectively utilize the amount of light of the light source 18 as the glass plate 12 of the planar light-emitting device 14, it is required that the light incident from the light-incident end surface 28 to the inside of the glass plate 12 is not In the state of the reflection point 24A to CC, the light is prevented from leaking to the outside, and the inner surface of the glass plate 12 is reflected and totally reflected.

然而,於專利文獻3所揭示之具有通常形狀之倒角面之玻璃板中,自倒角面入射至玻璃板之內部之光會因折射而使前進方向大幅彎曲,故而存在不會於玻璃板內進行波導而漏光至外部之問題。亦確認到於入光端面之附近位置頻繁產生此種漏光現象。即,於先前之玻璃板中,並不存在可不使光源之光量損耗而有效利用者。 However, in the glass plate having the chamfered surface of the usual shape disclosed in Patent Document 3, the light incident from the chamfered surface to the inside of the glass plate is greatly curved in the advancing direction due to the refraction, so that it does not exist in the glass plate. The problem of leaking light to the outside while conducting the waveguide. It is also confirmed that such light leakage occurs frequently in the vicinity of the entrance end face. That is, in the prior glass plate, there is no effective use without depleting the amount of light of the light source.

因此,於本實施形態中,可提供一種可有效利用光源18之光量之面狀發光裝置14、及可作為導光板用於面狀發光裝置14之玻璃板12。 Therefore, in the present embodiment, it is possible to provide a planar light-emitting device 14 that can effectively utilize the amount of light of the light source 18, and a glass plate 12 that can be used as a light guide plate for the planar light-emitting device 14.

繼而,基於圖4進行說明。圖4係將玻璃板12之特徵放大後表示之說明圖,且係相對於作為主平面之光出射面26及光反射面32與作為端面之入光端面28垂直之剖視圖。 Next, it demonstrates based on FIG. 4 is an enlarged plan view showing the features of the glass sheet 12, and is a cross-sectional view perpendicular to the light-emitting surface 26 and the light-reflecting surface 32 as main planes and the light-incident end surface 28 as an end surface.

重複進行說明,玻璃板12具有光出射面26及光反射面32,且具有相對於光出射面26及光反射面32垂直之入光端面28。又,與光出射面26及入光端面28相鄰地具備入光側倒角面40,與光反射面32及入光端面28相鄰地具備入光側倒角面40。 Repeatedly, the glass plate 12 has a light exit surface 26 and a light reflecting surface 32, and has a light incident end surface 28 that is perpendicular to the light exit surface 26 and the light reflecting surface 32. Further, the light-emitting side chamfered surface 40 is provided adjacent to the light-emitting surface 26 and the light-incident end surface 28, and the light-incident-side chamfering surface 40 is provided adjacent to the light-reflecting surface 32 and the light-incident end surface 28.

並且,於相對於光出射面26及入光端面28垂直之剖面,於將入光側倒角面40與光出射面26交叉之點設為第1交叉點P1,將入光側倒角面40與入光端面28交叉之點設為第2交叉點P2時,連結P1與P2之線段L之相對於入光端面28之傾斜角度θ滿足0.01≦tanθ≦0.75。再者,光反射面32側之入光側倒角面40亦為相同之構成,因此省略光反射面32側之入光側倒角面40之說明。 Further, at a cross section perpendicular to the light exit surface 26 and the light incident end surface 28, a point at which the light incident side chamfered surface 40 and the light exit surface 26 intersect is referred to as a first intersection P1, and a light incident side chamfered surface is formed. When the point at which the light incident end surface 28 intersects with the light incident end surface 28 is the second intersection point P2, the inclination angle θ of the line segment L connecting the P1 and the P2 with respect to the light incident end surface 28 satisfies 0.01 ≦ tan θ ≦ 0.75. Further, since the light incident side chamfering surface 40 on the light reflecting surface 32 side has the same configuration, the description of the light incident side chamfering surface 40 on the light reflecting surface 32 side is omitted.

本案發明者對作為玻璃板12而可有效利用光源18之光量之入光側倒角面40之形狀進行了努力研究,發現即便為具備入光側倒角面40之玻璃板,亦可將光源18之光量損耗抑制為最小限度之玻璃板12。 The inventors of the present invention have made an effort to study the shape of the light-incident side chamfering surface 40 which can effectively utilize the light amount of the light source 18 as the glass plate 12, and have found that the light source can be used even for the glass plate having the light-incident side chamfering surface 40. The light loss of 18 is suppressed to the minimum of the glass plate 12.

即,提供一種玻璃板,其係如圖4般於相對於光出射面26及入光端面28垂直之剖面,連結入光側倒角面40與光出射面26交叉之第1交叉點P1和入光側倒角面40與入光端面28交叉之第2交叉點P2之線段L的相對於入光端面28之傾斜角度θ滿足0.01≦tanθ≦0.75。 That is, a glass plate is provided which is perpendicular to the light exit surface 26 and the light incident end surface 28 as shown in FIG. 4, and is connected to the first intersection P1 where the light side chamfered surface 40 and the light exit surface 26 intersect. The inclination angle θ of the line segment L of the second intersection P2 where the light incident side chamfered surface 40 intersects the light incident end surface 28 with respect to the light incident end surface 28 satisfies 0.01 ≦ tan θ ≦ 0.75.

又,本案發明者發現可進一步抑制光源18之光量損耗之另一實施形態之玻璃板。 Moreover, the inventors of the present invention have found a glass plate of another embodiment which can further suppress the loss of the amount of light of the light source 18.

圖13係另一實施形態中之玻璃板112之放大局部剖視圖。如圖13般,玻璃板112於相對於光出射面126及入光端面128垂直之剖面,具備入光側倒角面140,該入光側倒角面140係連結入光側倒角面140與光出射面126交叉之第1交叉點P11和入光側倒角面140與傾斜面148交叉之第2交叉點P12之線段L11相對於入光端面128具有傾斜角度θ1。傾斜角度θ1滿足0.01≦tanθ1≦0.75。 Figure 13 is an enlarged partial cross-sectional view showing a glass plate 112 in another embodiment. As shown in FIG. 13, the glass plate 112 has a light incident side chamfered surface 140 which is connected to the light side chamfered surface 140 in a cross section perpendicular to the light exit surface 126 and the light incident end surface 128. The line segment L11 of the first intersection P11 intersecting the light exit surface 126 and the second intersection P12 where the light incident side chamfered surface 140 intersects the inclined surface 148 has an inclination angle θ 1 with respect to the light incident end surface 128. The inclination angle θ 1 satisfies 0.01 ≦ tan θ 1 ≦ 0.75.

進而,玻璃板112於相對於光出射面126及入光端面128垂直之剖面,具備傾斜面148,該傾斜面148係連結第2交叉點P12和傾斜面148與入光端面128交叉之第3交叉點P13之線段L12的相對於入光端面128之傾斜角度θ2小於傾斜角度θ1且滿足0<tanθ2≦0.4。即,傾斜角度θ1滿足tanθ1>tanθ2Further, the glass plate 112 has an inclined surface 148 which is perpendicular to the light exit surface 126 and the light incident end surface 128, and the inclined surface 148 is connected to the third intersection P12 and the third surface where the inclined surface 148 intersects the light incident end surface 128. The inclination angle θ 2 of the line segment L12 of the intersection P13 with respect to the light incident end surface 128 is smaller than the inclination angle θ 1 and satisfies 0 < tan θ 2 ≦ 0.4. That is, the inclination angle θ 1 satisfies tan θ 1 > tan θ 2 .

於圖4所示之玻璃板12及圖13所示之玻璃板112中,自此種形狀之入光側倒角面(40、140)入射之光源18之光一面於玻璃板12或玻璃板112之光出射面(26、126)之內表面及光反射面(32、132)之內表面反覆全反射,一面沿玻璃板12或玻璃板112之內部前進。藉此,根據該等實施形態,可提供一種可有效利用光源18之光量之玻璃板12或玻璃板112、及面狀發光裝置14。 In the glass plate 12 shown in FIG. 4 and the glass plate 112 shown in FIG. 13, the light source 18 from the light-incident side chamfered surface (40, 140) of this shape is incident on the glass plate 12 or the glass plate. The inner surface of the light exit surface (26, 126) of 112 and the inner surface of the light reflecting surface (32, 132) are totally totally reflected, and are advanced along the inside of the glass plate 12 or the glass plate 112. Accordingly, according to the embodiments, the glass plate 12 or the glass plate 112 and the planar light-emitting device 14 which can effectively utilize the amount of light of the light source 18 can be provided.

再者,於圖4中表示了剖面形狀為直線狀之入光側倒角面40,但亦包含入光側倒角面40之剖面形狀為圓弧狀者。於此情形時,如圖8之玻璃板12之主要部分放大剖視圖般,於相對於光出射面26及入光端 面28垂直之剖面,將對形成入光側倒角面40之圓弧進行2等分之圓弧上之點設為點P3,且點P3上之上述圓弧之切線T相對於入光端面28之傾斜角度θ滿足0.01≦tanθ≦0.75。即便於圖13所示之玻璃板112中,亦包含入光側倒角面140及傾斜面148之剖面形狀為圓弧狀者。 In addition, in FIG. 4, the light-incident side chamfering surface 40 which has a linear cross-sectional shape is shown, but the cross-sectional shape of the light-injecting side chamfering surface 40 is also circular arc shape. In this case, as shown in the enlarged cross-sectional view of the main part of the glass plate 12 of FIG. 8, with respect to the light exit surface 26 and the light incident end The vertical cross section of the surface 28 is defined as a point P3 on a circular arc which is equally divided into two arcs forming the arc-inclination surface 40, and the tangent T of the arc on the point P3 is opposite to the light incident end surface. The inclination angle θ of 28 satisfies 0.01 ≦ tan θ ≦ 0.75. That is, in the glass plate 112 shown in FIG. 13, the cross-sectional shape of the light-incident side chamfered surface 140 and the inclined surface 148 is also circular.

於圖4所示之玻璃板12中,若上述tanθ為0.01以上,則倒角部不會變得極度過小而可實現去除玻璃板12之邊緣以提高強度之最初之目標。若上述tanθ為0.75以下,則來自玻璃板12之漏光減少,於將玻璃板12用作導光板之情形時,亮度增高。為了進一步減少漏光,上述θ較佳為滿足0.01≦tanθ≦0.5,更佳為滿足0.01≦tanθ≦0.4,進而較佳為滿足0.01≦tanθ≦0.3,尤佳為滿足0.01≦tanθ≦0.2。尤其是於上述θ滿足0.01≦tanθ≦0.2之情形時,可完全消除漏光。 In the glass plate 12 shown in FIG. 4, when the tan θ is 0.01 or more, the chamfered portion is not excessively too small, and the initial goal of removing the edge of the glass sheet 12 to improve the strength can be achieved. When the tan θ is 0.75 or less, the light leakage from the glass plate 12 is reduced, and when the glass plate 12 is used as a light guide plate, the brightness is increased. In order to further reduce light leakage, the above θ preferably satisfies 0.01 ≦ tan θ ≦ 0.5, more preferably satisfies 0.01 ≦ tan θ ≦ 0.4, further preferably satisfies 0.01 ≦ tan θ ≦ 0.3, and particularly preferably satisfies 0.01 ≦ tan θ ≦ 0.2. In particular, when the above θ satisfies 0.01 ≦ tan θ ≦ 0.2, light leakage can be completely eliminated.

於圖13所示之玻璃板112中,若上述tanθ1為0.01以上,則倒角部不會變的極度過小而可實現去除玻璃板112之邊緣以提高強度之最初之目標。若上述tanθ1為0.75以下,則來自玻璃板112之漏光減少,於將玻璃板112用作導光板之情形時,亮度增高。為了進一步減少漏光,上述θ1較佳為滿足0.01≦tanθ1≦0.5,更佳為滿足0.01≦tanθ1≦0.4,進而較佳為滿足0.01≦tanθ1≦0.3,尤佳為滿足0.01≦tanθ1≦0.2。尤其是於上述θ1滿足0.01≦tanθ1≦0.2之情形時,可完全消除漏光。 In the glass plate 112 shown in FIG. 13, when the tan θ 1 is 0.01 or more, the chamfered portion does not become extremely small, and the first objective of removing the edge of the glass plate 112 to improve the strength can be achieved. When the above tan θ 1 is 0.75 or less, the light leakage from the glass plate 112 is reduced, and when the glass plate 112 is used as a light guide plate, the brightness is increased. In order to further reduce light leakage, the above θ 1 preferably satisfies 0.01 ≦ tan θ 1 ≦ 0.5, more preferably satisfies 0.01 ≦ tan θ 1 ≦ 0.4, and further preferably satisfies 0.01 ≦ tan θ 1 ≦ 0.3, and particularly preferably satisfies 0.01 ≦ tan θ 1 ≦0.2. In particular, when the above θ 1 satisfies 0.01 ≦ tan θ 1 ≦ 0.2, light leakage can be completely eliminated.

於一般之倒角形狀中,上述θ成為45°,tanθ或tanθ1成為1,於此情形時,於自入光側倒角面(40、140)入射至玻璃板12或玻璃板112時,光之前進方向會因折射而大幅彎曲。使前進方向大幅彎曲後之光不會沿玻璃板12或玻璃板112內導波而容易自玻璃板12或玻璃板112洩漏。本案發明者發現藉由將tanθ或tanθ1設為0.75以下,可抑制折射之影響,結果可減少漏光。 The chamfered shape in general, the above-described θ becomes 45 °, tanθ tan [theta] 1 becomes 1, or, when in this case, since the light incident on the side chamfered surface (40, 140) is incident to the glass sheet 12 or a glass plate 112, The direction of the light before entering will be greatly bent by refraction. The light which is largely bent in the advancing direction does not leak along the glass plate 12 or the glass plate 112, and is easily leaked from the glass plate 12 or the glass plate 112. The inventors of the present invention have found that by setting tan θ or tan θ 1 to 0.75 or less, the influence of refraction can be suppressed, and as a result, light leakage can be reduced.

又,實施形態之玻璃板12或玻璃板112較佳為入光側倒角面(40、 140)之表面粗糙度Ra為0.1μm以下。藉此,來自光源18之光不會於入光側倒角面(40、140)散射或者漫反射而入射至玻璃板12或玻璃板112之內部。藉此,可更有效利用光源18之光。 Moreover, the glass plate 12 or the glass plate 112 of the embodiment is preferably a light-incident side chamfered surface (40, 140) The surface roughness Ra is 0.1 μm or less. Thereby, the light from the light source 18 is not scattered or diffusely reflected on the light incident side chamfering surface (40, 140) and is incident on the inside of the glass plate 12 or the glass plate 112. Thereby, the light of the light source 18 can be utilized more effectively.

進而,實施形態之玻璃板12或玻璃板112較佳為50mm長度下之波長400~700nm下之平均內部透過率為90%以上,因此成為內部透過率較高之玻璃板12或玻璃板112。藉此,可進一步有效利用光源18之光。 Further, the glass plate 12 or the glass plate 112 of the embodiment preferably has an average internal transmittance of 90% or more at a wavelength of 400 to 700 nm at a length of 50 mm, and thus has a glass plate 12 or a glass plate 112 having a high internal transmittance. Thereby, the light of the light source 18 can be further effectively utilized.

[實施例] [Examples]

本案發明者為了找出上述tanθ之範圍,使用光線追蹤軟體(Light Tools:Cybernet System公司製造)並利用光線根數100萬根進行了模擬。於該模擬所使用之樣本中,以與700mm×700mm之尺寸之矩形之玻璃板12對向之方式與入光端面28隔開0.5mm之距離配置光源18,並以包圍光源18之方式配置反射器30。又,玻璃板12具有倒角面40,並使其傾斜角及尺寸如下所述般進行各種變化而進行模擬。光源18設為包含並聯之複數個點光源,於波長400nm~700nm之範圍內發光,且具有朗伯分佈之配光特性者。反射器30具有σ=15°之高斯反射特性,且擴散反射率為98%。玻璃板12設為具有光出射面26、及光反射面32且於光反射面32並未形成反射點者。又,以與玻璃板12對向之方式與光反射面32隔開0.1mm之距離配設反射片20。反射片具有σ=15°之高斯反射特性,且擴散反射率為98%。 In order to find out the range of the above tan θ, the inventors of the present invention simulated using a ray tracing software (Light Tools: manufactured by Cybernet Systems) and using a number of rays of 1 million. In the sample used in the simulation, the light source 18 is disposed at a distance of 0.5 mm from the light-incident end surface 28 in a manner opposed to a rectangular glass plate 12 having a size of 700 mm × 700 mm, and the reflection is arranged so as to surround the light source 18. 30. Further, the glass plate 12 has a chamfered surface 40, and the inclination angle and the size thereof are variously changed as described below. The light source 18 is configured to include a plurality of point light sources connected in parallel, emit light in a wavelength range of 400 nm to 700 nm, and have a light distribution characteristic of a Lambertian distribution. The reflector 30 has a Gaussian reflection characteristic of σ = 15° and a diffuse reflectance of 98%. The glass plate 12 is provided with the light exit surface 26 and the light reflecting surface 32, and the light reflecting surface 32 does not form a reflection point. Further, the reflection sheet 20 is disposed at a distance of 0.1 mm from the light reflection surface 32 so as to face the glass plate 12. The reflection sheet has a Gaussian reflection characteristic of σ=15° and a diffuse reflectance of 98%.

為了更正確地估算非波導光之量及波導光之量,假定於該樣本中不存在玻璃之吸收。玻璃之折射率於波長435.8nm下設為1.532,於波長486.1nm下設為1.527,於波長546.1nm下設為1.523,於波長587.6nm下設為1.521,於波長656.3nm下設為1.519,並使用利用適當之賽爾邁耶爾(sellmeyer)係數對該等值進行插值而成者。 In order to more accurately estimate the amount of non-waveguide light and the amount of waveguide light, it is assumed that there is no absorption of glass in the sample. The refractive index of the glass is 1.532 at a wavelength of 435.8 nm, 1.527 at a wavelength of 486.1 nm, 1.523 at a wavelength of 546.1 nm, 1.521 at a wavelength of 587.6 nm, and 1.519 at a wavelength of 656.3 nm. Use the appropriate value of the Sellmeyer coefficient to interpolate the values.

圖9係於厚度t為1.7mm之玻璃板12中,以實心之菱形(Solid rhombus:◆)、實心之正方形(Solid Square:■)、實心之三角形(Solid Triangle:▲)之記號對複數個非波導光相對於tanθ之比率(%)進行繪製而成之圖。圖10係表示用以藉由模擬算出圖9之非波導光之比率(%)之條件及模擬之結果之表。 Figure 9 is a solid diamond in a glass plate 12 having a thickness t of 1.7 mm (Solid Rhombus: ◆), solid square (Solid Square: ■), solid triangle (Solid Triangle: ▲) symbol is a plot of the ratio of multiple non-waveguide light to tan θ (%). Fig. 10 is a table showing the conditions and simulation results for calculating the ratio (%) of the non-waveguide light of Fig. 9 by simulation.

又,圖11係於厚度t為2.5mm之玻璃板12中,以實心之菱形(Solid rhombus:◆)、實心之正方形(Solid Square:■)、實心之三角形(Solid Triangle:▲)之記號對複數個非波導光相對於tanθ值之比率(%)進行繪製而成之圖。圖12係表示用以藉由模擬算出圖11之非波導光之比率(%)之條件及模擬之結果之表。 Further, Fig. 11 is a glass plate 12 having a thickness t of 2.5 mm, and is marked with a solid rhombus (Solid rhombus: ◆), a solid square (Solid Square: ■), and a solid triangle (Solid Triangle: ▲). A plot of a ratio (%) of a plurality of non-waveguide lights to a tan θ value. Fig. 12 is a table showing the conditions and simulation results for calculating the ratio (%) of the non-waveguide light of Fig. 11 by simulation.

所謂a,係指將如圖4般沿著光出射面26延長之第1延長線La與沿著入光端面28延長之第2延長線Lb交叉之點設為第3交叉點P3之情形時之第1交叉點P1至第3交叉點P3之長度。又,所謂b,係第2交叉點P2至第3交叉點P3之長度。即,本實施形態之特徵在於a/b=tanθ,a/b值為0.75以下。 The term “a” refers to a case where the point at which the first extension line La extended along the light exit surface 26 as shown in FIG. 4 intersects with the second extension line Lb extending along the light incident end surface 28 is the third intersection point P3. The length from the first intersection P1 to the third intersection P3. Further, b is the length from the second intersection P2 to the third intersection P3. That is, the present embodiment is characterized in that a/b = tan θ and a/b value is 0.75 or less.

進而,所謂圖10、圖12中記載之非波導光,意指於玻璃板12中自光出射面26漏出之光之合計量,所謂非波導光(%),表示將光源18之光量設為100%時之上述檢測點上之漏光量之比率。 Further, the non-waveguide light described in FIGS. 10 and 12 means the total amount of light leaking from the light exit surface 26 in the glass sheet 12, and the non-waveguide light (%) indicates that the amount of light of the light source 18 is set to The ratio of the amount of light leakage at the above detection points at 100%.

又,所謂波導光,意指一面於玻璃板12之內部全反射一面前進之光,所謂波導光(%),表示將光源18之光量設為100%時之於自入光端面28朝向非入光端面38遠離690mm之位置所檢測到之光量之比率。再者,波導光(%)與非波導光(%)之累加值不會變成100%之原因在於光會被反射器30或反射片20吸收。 In addition, the waveguide light means light that is reflected by the entire surface of the glass plate 12, and the waveguide light (%) indicates that the light source 18 has a light amount of 100%. The ratio of the amount of light detected by the light end face 38 away from the position of 690 mm. Furthermore, the cumulative value of the waveguide light (%) and the non-guided light (%) does not become 100% because the light is absorbed by the reflector 30 or the reflection sheet 20.

<模擬結果> <simulation result>

根據圖9、圖11,以實心之菱形(Solid rhombus:◆)記號分別繪製將b設定為0.1mm、將a設為0.01mm、0.02mm、0.03mm、0.05mm、0.07mm、0.1mm之情形時之非波導光(%)。同樣地,以實心之 正方形(Solid Square:■)記號分別繪製將b設定為0.2mm、將a設為0.01mm、0.03mm、0.05mm、0.1mm、0.15mm、0.2mm之情形時之非波導光(%)。同樣地,以實心之三角形(Solid Triangle:▲)記號分別繪製將b設定為0.3mm、將a設為0.01mm、0.03mm、0.05mm、0.1mm、0.2mm、0.3mm之情形時之非波導光(%)。 According to Fig. 9 and Fig. 11, the solid rhombus (◆) symbol is used to draw b to 0.1 mm and a to 0.01 mm, 0.02 mm, 0.03 mm, 0.05 mm, 0.07 mm, and 0.1 mm. Non-waveguide light (%). Similarly, with solid The square (Solid Square: ■) symbol draws non-waveguide light (%) when b is set to 0.2 mm and a is set to 0.01 mm, 0.03 mm, 0.05 mm, 0.1 mm, 0.15 mm, and 0.2 mm, respectively. Similarly, a non-waveguide is used to set b to 0.3 mm and a to 0.01 mm, 0.03 mm, 0.05 mm, 0.1 mm, 0.2 mm, and 0.3 mm with solid triangles (▲). Light(%).

此處,若將與tanθ為1時相比非波導光(%)得以降低作為評價基準,則如圖9、圖10般,於厚度t為1.7mm之玻璃板12之情形時,若a/b值為0.75以下(tanθ≦0.75),則可滿足評價基準。又,得知若a/b值為0.2以下(tanθ≦0.2),則非波導光(%)變成零。再者,亦判明為了滿足該評價基準,較佳為a為0.01~0.05mm,b為0.1~0.3mm。 Here, when the non-waveguide light (%) is lowered as compared with when tan θ is 1, the evaluation is based on the case where the glass plate 12 having a thickness t of 1.7 mm is as shown in FIGS. 9 and 10 . When the b value is 0.75 or less (tan θ ≦ 0.75), the evaluation criteria can be satisfied. Further, when the a/b value is 0.2 or less (tan θ ≦ 0.2), the non-waveguide light (%) becomes zero. Further, it has been found that in order to satisfy the evaluation criteria, a is preferably 0.01 to 0.05 mm, and b is 0.1 to 0.3 mm.

又,如圖11、圖12般,於厚度t為2.5mm之玻璃板12之情形時,若a/b值為0.75以下(tanθ≦0.75),則亦可滿足評價基準。又,得知若a/b值為0.2以下(tanθ≦0.2),則非波導光(%)變成零。如此,得知tanθ之較佳之範圍並不取決於玻璃板12之厚度。再者,亦判明為了滿足該評價基準,較佳為a為0.01~0.05mm,b為0.1~0.3mm。 Further, as in the case of the glass plate 12 having a thickness t of 2.5 mm as shown in Figs. 11 and 12, if the a/b value is 0.75 or less (tan θ ≦ 0.75), the evaluation criteria can be satisfied. Further, when the a/b value is 0.2 or less (tan θ ≦ 0.2), the non-waveguide light (%) becomes zero. Thus, it is known that the preferred range of tan θ does not depend on the thickness of the glass sheet 12. Further, it has been found that in order to satisfy the evaluation criteria, a is preferably 0.01 to 0.05 mm, and b is 0.1 to 0.3 mm.

因此,根據a/b值為0.75以下(tanθ≦0.75)之玻璃板12,無關玻璃板12之厚度而可有效利用光源18之光量。因此,根據具備實施例之玻璃板12之面狀發光裝置14,可達成電子機器之薄型化並且削減消耗功率。 Therefore, according to the glass plate 12 having an a/b value of 0.75 or less (tan θ ≦ 0.75), the amount of light of the light source 18 can be effectively utilized irrespective of the thickness of the glass plate 12. Therefore, according to the planar light-emitting device 14 including the glass plate 12 of the embodiment, the thickness of the electronic device can be reduced and the power consumption can be reduced.

以上,對本發明之較佳之實施形態進行了詳細敍述,但本發明並不限定於上述特定之實施形態,可於申請專利範圍所記載之本發明之主旨之範圍內進行各種變化、變更。 The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific embodiments described above, and various changes and modifications may be made within the scope of the invention as described in the appended claims.

本國際申請主張基於在2015年7月28日提出申請之日本專利申請2015-148561號及於2015年11月9日提出申請之日本專利申請2015-219370號之優先權,並將其全部內容援用至本文中。 Priority is claimed on Japanese Patent Application No. 2015-148561, filed on Jan. To this article.

12‧‧‧玻璃板 12‧‧‧ glass plate

26‧‧‧光出射面 26‧‧‧Light exit surface

28‧‧‧入光端面 28‧‧‧Incoming light end face

32‧‧‧光反射面 32‧‧‧Light reflecting surface

40‧‧‧入光側倒角面 40‧‧‧Enhanced side chamfered surface

a‧‧‧長度 A‧‧‧ length

b‧‧‧長度 B‧‧‧ Length

L‧‧‧線段 L‧‧‧ line segment

La‧‧‧第1延長線 La‧‧‧1st extension cord

Lb‧‧‧第2延長線 Lb‧‧‧2nd extension cord

P1‧‧‧第1交叉點 P1‧‧‧1st intersection

P2‧‧‧第2交叉點 P2‧‧‧2nd intersection

P3‧‧‧第3交叉點 P3‧‧‧3rd intersection

t‧‧‧厚度 T‧‧‧thickness

θ‧‧‧傾斜角度 Θ‧‧‧ tilt angle

Claims (8)

一種玻璃板,其係具有主平面及相對於上述主平面垂直之端面,且於上述主平面與上述端面之間,與上述主平面及上述端面相鄰地具備倒角面者,於相對於上述主平面及上述端面垂直之剖面,連結上述倒角面與上述主平面交叉之第1交叉點和上述倒角面與上述端面交叉之第2交叉點的線段相對於上述端面之傾斜角度θ滿足0.01≦tanθ≦0.75。 A glass plate having a principal plane and an end surface perpendicular to the main plane, and having a chamfered surface adjacent to the main plane and the end surface between the main plane and the end surface, a cross section perpendicular to the main plane and the end surface, a first embodiment where the chamfered surface intersects the main plane, and a line segment of the second intersection where the chamfered surface intersects the end surface has an inclination angle θ of 0.01 with respect to the end surface. ≦tanθ≦0.75. 一種玻璃板,其係具有主平面、及相對於上述主平面垂直之端面且於上述主平面與上述端面之間具備與上述主平面相鄰之倒角面、及配置於上述倒角面與上述端面之間之傾斜面者,於相對於上述主平面及上述端面垂直之剖面,以連結上述倒角面與上述主平面交叉之第1交叉點、和上述倒角面與上述傾斜面交叉之第2交叉點的線段相對於上述端面以傾斜角度θ1傾斜之方式,具備上述倒角面,上述傾斜角度θ1滿足0.01≦tanθ1≦0.75,連結上述第2交叉點和上述傾斜面與上述端面交叉之第3交叉點的線段相對於上述端面之傾斜角度θ2小於上述傾斜角度θ1,且滿足0<tanθ2≦0.4。 A glass plate having a principal plane and an end surface perpendicular to the main plane, and a chamfered surface adjacent to the main plane between the main plane and the end surface, and a chamfered surface and the a slanted surface between the end faces, a cross section perpendicular to the main plane and the end surface, a first intersection connecting the chamfered surface and the main plane, and a cross between the chamfered surface and the inclined surface The line segment of the two intersections includes the chamfered surface so as to be inclined at an inclination angle θ 1 with respect to the end surface, and the inclination angle θ 1 satisfies 0.01 ≦ tan θ 1 ≦ 0.75, and the second intersection, the inclined surface, and the end surface are connected The inclination angle θ 2 of the line segment crossing the third intersection point with respect to the end surface is smaller than the inclination angle θ 1 and satisfies 0 < tan θ 2 ≦ 0.4. 如請求項1或2之玻璃板,其中上述傾斜角度θ滿足0.01≦tanθ≦0.2。 A glass sheet according to claim 1 or 2, wherein said inclination angle θ satisfies 0.01 ≦ tan θ ≦ 0.2. 如請求項1至3中任一項之玻璃板,其中上述端面之表面粗糙度Ra為0.1μm以下。 The glass plate according to any one of claims 1 to 3, wherein the end surface has a surface roughness Ra of 0.1 μm or less. 如請求項1至4中任一項之玻璃板,其中上述玻璃板於50mm長度下之波長400~700nm下之平均內部透過率為90%以上。 The glass sheet according to any one of claims 1 to 4, wherein the glass sheet has an average internal transmittance of 90% or more at a wavelength of from 400 to 700 nm at a length of 50 mm. 如請求項1至5中任一項之玻璃板,其中上述玻璃板之厚度為0.7~3.0mm,將沿著上述主平面延長之第1延長線與沿著上述端面延長之第2延長線交叉之點設為第3交叉點,上述第1交叉點至上述第3交叉點之長度為0.01~0.05mm,上述第2交叉點至上述第3交叉點之長度為0.1~0.3mm。 The glass plate according to any one of claims 1 to 5, wherein the glass plate has a thickness of 0.7 to 3.0 mm, and the first extension line extending along the main plane intersects the second extension line extending along the end surface The point is the third intersection, the length from the first intersection to the third intersection is 0.01 to 0.05 mm, and the length from the second intersection to the third intersection is 0.1 to 0.3 mm. 如請求項1至6中任一項之玻璃板,其中上述端面之表面粗糙度Ra之值小於上述倒角面之表面粗糙度Ra之值。 The glass sheet according to any one of claims 1 to 6, wherein the value of the surface roughness Ra of the end surface is smaller than the value of the surface roughness Ra of the chamfered surface. 如請求項1至7中任一項之玻璃板,其中上述倒角面之表面粗糙度Ra為0.8μm以下。 The glass plate according to any one of claims 1 to 7, wherein the chamfered surface has a surface roughness Ra of 0.8 μm or less.
TW105123784A 2015-07-28 2016-07-27 Glass plate TW201713974A (en)

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US20210253470A1 (en) * 2018-06-26 2021-08-19 Nippon Electric Glass Co., Ltd. Plate glass

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JP3934115B2 (en) * 2003-03-26 2007-06-20 Hoya株式会社 Photomask substrate, photomask blank, and photomask
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