TW201710195A - Glass manufacturing apparatus and method with flow through capability - Google Patents

Glass manufacturing apparatus and method with flow through capability Download PDF

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Publication number
TW201710195A
TW201710195A TW105117754A TW105117754A TW201710195A TW 201710195 A TW201710195 A TW 201710195A TW 105117754 A TW105117754 A TW 105117754A TW 105117754 A TW105117754 A TW 105117754A TW 201710195 A TW201710195 A TW 201710195A
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Taiwan
Prior art keywords
slot
glass
molten glass
root
length
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TW105117754A
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Chinese (zh)
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偉登威廉安東尼
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康寧公司
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Publication of TW201710195A publication Critical patent/TW201710195A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • C03B17/064Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • C03B17/067Forming glass sheets combined with thermal conditioning of the sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • C03B5/265Overflows; Lips; Tweels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • C03B7/005Controlling, regulating or measuring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Glass Compositions (AREA)

Abstract

A glass forming apparatus and method include a glass forming device having an inlet end and a compression end and a trough extending between the inlet end and the compression end. The glass forming device has first and second sides that each extend from weirs on each side of the trough to a root of the glass forming device in the vertical direction. The trough has a depth that decreases between the inlet end and the compression end and the glass forming device further includes a slot that extends along at least a length of the trough in the horizontal direction and extends from the trough to the root of the glass forming device in the vertical direction.

Description

具可流通性的玻璃製造設備及方法 Glass manufacturing equipment and method with flowability

本申請案根據專利法主張2015年6月4日申請之美國臨時申請案序列號第62/170,873號之優先權權益,該申請案之內容為本文之基礎且以全文引用方式併入本文中。 The present application claims the benefit of priority to U.S. Provisional Application Serial No. 62/170,873, filed on Jun. 4, 2015, the disclosure of which is incorporated herein in

本揭示內容總體上係關於玻璃製造設備及方法,且更明確而言係關於具可流通性的玻璃製造設備。 The present disclosure relates generally to glass manufacturing equipment and methods, and more particularly to glass manufacturing equipment having flowability.

用於製造諸如用於顯示器應用(包括LCD、電視及手持式電子裝置)的平板玻璃之玻璃材料的方法包括熔合拉製方法,其中熔融玻璃溢流出玻璃成形裝置之相對側,且隨後重新結合以在裝置之底部或根部下方形成玻璃片。此種方法可允許具有高表面品質之相對薄的、平坦玻璃片的生產,該高表面品質為意欲用於顯示器應用中之玻璃的合意特性。 A method for making a glass material such as flat glass for display applications, including LCDs, televisions, and handheld electronic devices, includes a fusion draw process in which molten glass overflows the opposite side of the glass forming apparatus and is subsequently recombined to A glass sheet is formed at the bottom or under the root of the device. This approach allows for the production of relatively thin, flat glass sheets of high surface quality that are desirable properties for glass intended for use in display applications.

在此種製造製程中,存在增加熔融玻璃流率的持續需要。然而,增加的流率可導致關於玻璃成形裝置的若干技術挑戰。此種技術挑戰可包括例如玻璃成形裝置,由於增加玻璃成形裝置之橫截面及/或增加熔融玻璃之操作溫度以便達成較高流率,該玻璃成形裝置隨時 間推移經受增加的變形。增加操作溫度亦可導致玻璃成形裝置之增加的腐蝕或化學侵蝕。因此,在緩和此等潛在不合需要之效應的同時達成較高玻璃流率將為合意的。 In such a manufacturing process, there is a continuing need to increase the flow rate of the molten glass. However, the increased flow rate can lead to several technical challenges with respect to glass forming devices. Such technical challenges may include, for example, glass forming devices that are readily available due to the increased cross-section of the glass forming device and/or increased operating temperature of the molten glass to achieve higher flow rates. The transition is subject to increased deformation. Increasing the operating temperature can also result in increased corrosion or chemical attack of the glass forming apparatus. Therefore, it would be desirable to achieve a higher glass flow rate while mitigating these potentially undesirable effects.

本文揭示一種用於產生玻璃物件之設備。該設備包括玻璃成形裝置,該玻璃成形裝置包括入口端及壓縮端以及在入口端與壓縮端之間延伸的槽。該玻璃成形裝置亦包括第一側及第二側,該等側各自在水平方向上自該入口端延伸至該壓縮端。該第一側在垂直方向上自該槽之第一側上的第一堰口延伸至該玻璃成形裝置之根部,而該第二側在垂直方向上自該槽之第二側上的第二堰口延伸至該玻璃成形裝置之該根部。該槽具有一深度,該深度在該入口端與該壓縮端之間減小。該玻璃成形裝置進一步包括一狹槽,該狹槽在該水平方向上沿該槽之至少一長度延伸,且在該垂直方向上自該槽延伸至該玻璃成形裝置之該根部。 Disclosed herein is an apparatus for producing a glass article. The apparatus includes a glass forming apparatus including an inlet end and a compression end and a groove extending between the inlet end and the compression end. The glass forming apparatus also includes a first side and a second side, each of the sides extending horizontally from the inlet end to the compression end. The first side extends in a vertical direction from a first port on the first side of the slot to a root of the glass forming device, and the second side is in a vertical direction from a second port on the second side of the slot Extending to the root of the glass forming apparatus. The slot has a depth that decreases between the inlet end and the compression end. The glass forming apparatus further includes a slot extending in the horizontal direction along at least one length of the slot and extending from the slot to the root of the glass forming device in the vertical direction.

本文亦揭示一種產生玻璃物件之方法。該方法包括將熔融玻璃引入至玻璃成形裝置。該玻璃成形裝置包括入口端及壓縮端以及在入口端與壓縮端之間延伸的槽。該玻璃成形裝置亦包括第一側及第二側,該等側各自在水平方向上自該入口端延伸至該壓縮端。該第一側在垂直方向上自該槽之第一側上的第一堰口延伸至該玻璃成形裝置之根部,而該第二側在垂直方向上自該槽 之第二側上的第二堰口延伸至該玻璃成形裝置之該根部。該槽具有一深度,該深度在該入口端與該壓縮端之間減小。該玻璃成形裝置進一步包括一狹槽,該狹槽在該水平方向上沿該槽之至少一長度延伸,且在該垂直方向上自該槽延伸至該玻璃成形裝置之該根部。熔融玻璃自該槽溢流出該第一堰口及第二堰口且流動穿過該狹槽。 Also disclosed herein is a method of producing a glass article. The method includes introducing molten glass to a glass forming apparatus. The glass forming apparatus includes an inlet end and a compression end and a groove extending between the inlet end and the compression end. The glass forming apparatus also includes a first side and a second side, each of the sides extending horizontally from the inlet end to the compression end. The first side extends in a vertical direction from a first port on the first side of the slot to a root of the glass forming device, and the second side extends in the vertical direction from the slot A second port on the second side extends to the root of the glass forming apparatus. The slot has a depth that decreases between the inlet end and the compression end. The glass forming apparatus further includes a slot extending in the horizontal direction along at least one length of the slot and extending from the slot to the root of the glass forming device in the vertical direction. The molten glass overflows from the groove into the first port and the second port and flows through the slot.

另外,本文揭示的為藉由上文方法製成的玻璃片以及包括此種玻璃片之電子裝置。 Additionally, disclosed herein are glass sheets made by the above methods and electronic devices including such glass sheets.

此等及其他實施例之另外的特徵及優勢將在以下詳細描述中闡述,且在部分程度上,熟習此項技術者將根據該描述而容易明白該等特徵及優勢,或藉由實踐如本文(包括後續實施方式、發明申請專利範圍以及隨附圖式)所述的實施例來認識該等特徵及優勢。 Additional features and advantages of the present invention will be set forth in the <RTIgt; </RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; These features and advantages are recognized by the embodiments described in the following, including the accompanying claims, the claims, and the accompanying drawings.

應理解,前述的一般描述及以下詳細描述提出本揭示內容之實施例,且意欲提供用於理解如所主張的實施例之性質及特徵的概述及框架。隨附圖式係納入來提供對此等及其他實施例之進一步理解,且併入本說明書中並構成本說明書之一部分。圖式例示此等及其他實施例之各種實施例,且與說明書一起用於解釋該等實施例之原理及操作。 It is to be understood that the foregoing general description of the embodiments of the present invention A further understanding of these and other embodiments is provided by the accompanying drawings, which are incorporated in this specification and constitute a part of this specification. The drawings illustrate various embodiments of the invention, and are in the

101‧‧‧玻璃成形設備 101‧‧‧glass forming equipment

103‧‧‧玻璃帶/熔融玻璃帶 103‧‧‧glass ribbon/fused glass ribbon

105‧‧‧熔融容器 105‧‧‧Melt container

107‧‧‧批料 107‧‧‧ batches

109‧‧‧儲倉 109‧‧‧Warehouse

111‧‧‧分批遞送裝置 111‧‧‧Batch delivery device

113‧‧‧馬達 113‧‧‧Motor

115‧‧‧控制器 115‧‧‧ Controller

117‧‧‧箭頭 117‧‧‧ arrow

119‧‧‧玻璃位準探針 119‧‧‧Glass quasi-probe

121‧‧‧玻璃熔體 121‧‧‧ glass melt

123‧‧‧豎管 123‧‧‧ standpipe

125‧‧‧通訊線路 125‧‧‧Communication lines

127‧‧‧澄清容器 127‧‧‧Clarification container

129‧‧‧第一連接管 129‧‧‧First connecting pipe

131‧‧‧混合容器 131‧‧‧Mixed container

133‧‧‧遞送容器 133‧‧‧ delivery container

135‧‧‧第二連接管 135‧‧‧Second connection tube

137‧‧‧第三連接管 137‧‧‧The third connecting tube

139‧‧‧降流管 139‧‧‧ downflow tube

141‧‧‧入口 141‧‧‧ entrance

143‧‧‧成形裝置 143‧‧‧Forming device

201‧‧‧槽 201‧‧‧ slot

203‧‧‧第一堰口/堰口 203‧‧‧ First import / import

205‧‧‧第二堰口/堰口 205‧‧‧Second Pass / Import

207‧‧‧底部壁 207‧‧‧ bottom wall

209‧‧‧軸 209‧‧‧Axis

210‧‧‧虛線 210‧‧‧ dotted line

211‧‧‧成形楔形物 211‧‧‧ Forming wedges

213‧‧‧向下傾斜成形表面部分 213‧‧‧Look down the forming surface section

215‧‧‧向下傾斜成形表面部分 215‧‧‧Look down the forming surface section

217‧‧‧下游方向 217‧‧‧ downstream direction

219‧‧‧根部 219‧‧‧ root

221‧‧‧拉製平面 221‧‧‧ drawn plane

223‧‧‧邊緣導向器 223‧‧‧Edge director

225‧‧‧第一相反末端 225‧‧‧ first opposite end

227‧‧‧第二相反末端 227‧‧‧second opposite end

300‧‧‧玻璃成形裝置 300‧‧‧glass forming device

302‧‧‧槽 302‧‧‧ slots

304‧‧‧第一堰口 304‧‧‧ first pass

306‧‧‧第二堰口 306‧‧‧Second Pass

310‧‧‧狹槽 310‧‧‧ slot

312‧‧‧入口端 312‧‧‧ entrance end

314‧‧‧壓縮端 314‧‧‧Compressed end

316‧‧‧第一側 316‧‧‧ first side

318‧‧‧第二側 318‧‧‧ second side

320‧‧‧邊緣導向器 320‧‧‧Edge director

322‧‧‧邊緣導向器 322‧‧‧Edge director

330‧‧‧根部 330‧‧‧ root

350A-D‧‧‧加熱元件 350A-D‧‧‧ heating element

D‧‧‧深度 D‧‧‧Deep

D1‧‧‧深度 D 1 ‧‧‧depth

D2‧‧‧深度 D 2 ‧‧‧depth

L1‧‧‧水平長度 L1‧‧‧ horizontal length

L2‧‧‧水平長度 L2‧‧‧ horizontal length

W1‧‧‧寬度 W1‧‧‧Width

W2‧‧‧寬度 W2‧‧‧Width

第1圖為根據本揭示內容之態樣的用於產生玻璃物件的包括成形裝置之設備的示意圖; 第2圖為第1圖之成形裝置之橫截面放大透視圖;第3圖為根據本文所揭示實施例的玻璃成形裝置之透視圖;第4A圖為第3圖之玻璃成形裝置之入口端視圖;第4B圖為第3圖之玻璃成形裝置之壓縮端視圖;第5A圖為第3圖之玻璃成形裝置之頂視圖;第5B圖為第3圖之玻璃成形裝置之底視圖;且第6圖為根據本文所揭示實施例的玻璃成形裝置之端部剖視圖,其中加熱元件係安置成鄰近於成形裝置。 1 is a schematic view of an apparatus including a forming apparatus for producing a glass article in accordance with aspects of the present disclosure; 2 is a cross-sectional enlarged perspective view of the forming apparatus of FIG. 1; FIG. 3 is a perspective view of the glass forming apparatus according to the embodiment disclosed herein; and FIG. 4A is an inlet end view of the glass forming apparatus of FIG. 4B is a compression end view of the glass forming apparatus of FIG. 3; FIG. 5A is a top view of the glass forming apparatus of FIG. 3; FIG. 5B is a bottom view of the glass forming apparatus of FIG. 3; The figure is an end cross-sectional view of a glass forming apparatus in accordance with embodiments disclosed herein, wherein the heating element is disposed adjacent to the forming apparatus.

現將參考本揭示內容之實施例,在隨附圖式中例示該等實施例之實例。在任何可能的情況下,整個圖式中將使用相同元件符號來指代相同或相似部件。 Embodiments of the embodiments will now be described with reference to the embodiments of the present disclosure. Wherever possible, the same reference numerals will be used throughout the drawings to refer to the same.

如本文所使用,術語 As used herein, the term

第1圖例示玻璃成形設備101之示範性示意圖,該玻璃成形設備用於熔合拉製玻璃帶103以供後續處理成玻璃片。所例示的玻璃成形設備包含熔合拉製設備,儘管可在其他實例中提供其他熔合成形設備。玻璃成形設備101可包括熔融容器(或熔融爐)105,其經配 置以自儲倉109接收批料107。批料107可藉由以馬達113供電的分批遞送裝置111而引入。可選控制器115可經配置以啟動馬達113,以將所欲量之批料107引入熔融容器105中,如箭頭117所指示。玻璃位準探針119可用於量測豎管123內玻璃熔體(例如熔融玻璃)121之位準,且經由通訊線路125將所量測資訊傳達至控制器115Schematic diagram of a first exemplary apparatus 101 illustrated in FIG glass forming the glass forming apparatus 103 for fusion drawing a glass ribbon into glass sheets for subsequent processing. The illustrated glass forming apparatus includes a fusion drawing apparatus, although other fusion forming apparatus may be provided in other examples. The glass forming apparatus 101 can include a melting vessel (or melting furnace) 105 configured to receive the batch 107 from the storage silo 109 . Batch 107 can be introduced by a batch delivery device 111 powered by motor 113 . The optional controller 115 can be configured to activate the motor 113 to introduce the desired amount of batch 107 into the molten vessel 105 as indicated by arrow 117 . The glass level probe 119 can be used to measure the level of the glass melt (e.g., molten glass) 121 in the riser 123 and communicate the measured information to the controller 115 via the communication line 125 .

玻璃成形設備101亦可包括諸如澄清管的澄清容器127,其位於熔融容器105下游且經由第一連接管129流體耦接至熔融容器105。諸如攪拌腔室的混合容器131亦可位於澄清容器127下游,且諸如槽池(bowl)的遞送容器133可位於混合容器131的下游。然而,應注意,混合容器131可定位於澄清容器127上游,且在某些實施例中,可使用多個混合容器,例如定位於澄清容器127上游之第一混合容器131及定位於澄清容器127下游之第二混合容器131。如圖所示,第二連接管135可將澄清容器127耦接至混合容器131,且第三連接管137可將混合容器131耦接至遞送容器133。如圖進一步所例示,降流管139可經定位以自遞送容器133遞送玻璃熔體121至成形裝置143之入口141。如圖所示,熔融容器105、澄清容器127、混合容器131、遞送容器133及成形裝置143為可沿玻璃成形設備101串聯定位的玻璃熔體站之實例。 The glass forming apparatus 101 can also include a clarification vessel 127 , such as a clarification tube, located downstream of the smelting vessel 105 and fluidly coupled to the fused vessel 105 via a first connecting tube 129 . A mixing vessel 131, such as a mixing chamber, may also be located downstream of the clarification vessel 127 , and a delivery vessel 133 , such as a bowl, may be located downstream of the mixing vessel 131 . However, it should be noted that the mixing vessel 131 can be positioned upstream of the clarification vessel 127 , and in certain embodiments, a plurality of mixing vessels can be utilized, such as the first mixing vessel 131 positioned upstream of the clarification vessel 127 and positioned in the clarification vessel 127. A second mixing vessel 131 downstream. As shown, the second connecting tube 135 can couple the clarification container 127 to the mixing container 131 , and the third connecting tube 137 can couple the mixing container 131 to the delivery container 133 . As further illustrated, the downcomer 139 can be positioned to deliver the glass melt 121 from the delivery container 133 to the inlet 141 of the forming device 143 . As shown, the molten vessel 105 , the clarification vessel 127 , the mixing vessel 131 , the delivery vessel 133, and the forming apparatus 143 are examples of glass melt stations that can be positioned in series along the glass forming apparatus 101 .

熔融容器105典型地自諸如耐火(例如陶瓷)磚之耐火材料製成。玻璃成形設備101可進一步包括典型地由鉑或含鉑金屬(諸如鉑-銠、鉑-銥及其組合)製成的組件,但該等組件亦可包含諸如鉬、鈀、錸、鉭、鈦、鎢、釕、鋨、鋯及其合金的耐火金屬及/或二氧化鋯。含鉑組件可包括以下一或多者:第一連接管129、澄清容器127(例如澄清管)、第二連接管135、豎管123、混合容器131(例如,攪拌腔室)、第三連接管137、遞送容器133(例如,槽池)、降流管139及入口141。成形裝置143由諸如耐火材料的陶瓷材料製成,且係設計來形成玻璃帶103The melting vessel 105 is typically made from a refractory material such as a refractory (e.g., ceramic) brick. The glass forming apparatus 101 may further comprise an assembly typically made of platinum or a platinum-containing metal such as platinum-ruthenium, platinum-ruthenium, and combinations thereof, but such components may also include molybdenum, palladium, rhodium, iridium, titanium, etc. , refractory metals and/or zirconia of tungsten, tantalum, niobium, zirconium and their alloys. The platinum-containing component may include one or more of the following: a first connecting tube 129 , a clarifying container 127 (eg, a clarifying tube), a second connecting tube 135 , a standpipe 123 , a mixing container 131 (eg, a stirring chamber), a third connection Tube 137 , delivery container 133 (eg, tank), downcomer 139, and inlet 141 . The forming device 143 is made of a ceramic material such as a refractory material and is designed to form a glass ribbon 103 .

第2圖為玻璃成形設備101的沿第1圖之線2-2的橫截面透視圖。如圖所示,成形裝置143可包括槽201,該槽至少部分地藉由一對堰口界定,該對堰口包含界定槽201之相對側的第一堰口203及第二堰口205。如圖進一步所示,槽亦可至少部分地藉由底部壁207界定。如圖所示,堰口203、205之內表面及底部壁207界定可具備圓形拐角之實質上U形。在其他實例中,U形可具有相對於彼此實質上90°之表面。在其他實例中,槽可具有藉由堰口203、205之內表面之相交區段(intersection)界定的底表面。例如,槽可具有V形輪廓。雖然未展示,但是槽可在另外實例中包括其他組態。 FIG 2 is a cross-sectional perspective view along line 2-2 in FIG. 1 of the glass forming apparatus 101. As shown, the forming device 143 can include a slot 201 that is at least partially defined by a pair of jaws that include a first jaw 203 and a second jaw 205 that define opposite sides of the slot 201 . As further shown, the trough can also be at least partially defined by the bottom wall 207 . As shown, the inner surface of the jaws 203, 205 and the bottom wall 207 define a substantially U-shape that can have rounded corners. In other examples, the U shape can have a surface that is substantially 90° relative to each other. In other examples, the trough can have a bottom surface defined by the intersection of the inner surfaces of the jaws 203, 205 . For example, the trough can have a V-shaped profile. Although not shown, the slot may include other configurations in another instance.

如圖所示,槽201可具有介於第一堰口203及/或第二堰口205之頂部與槽201之底部壁207之間的深度「D」,該深度沿軸209變化,但深度可沿軸209為實質上相同的。改變槽201之深度「D」可促進跨於玻璃帶103之寬度的玻璃帶厚度之一致性。在僅僅一個實例中,如第2圖所示,接近成形裝置143之入口的深度「D 1 」可大於槽201中於槽201之入口下游之位置處的深度「D 2 」。如藉由虛線210所示範,底部壁207可以相對於軸209之銳角延伸,以提供沿成形裝置143之長度自入口端至相對端在深度上的實質上連續減少。 As shown, the slot 201 can have a depth " D " between the top of the first port 203 and/or the second port 205 and the bottom wall 207 of the slot 201 , the depth varying along the axis 209 , but the depth can be along The shafts 209 are substantially identical. Changing the depth " D " of the groove 201 promotes the uniformity of the thickness of the glass ribbon across the width of the glass ribbon 103 . In just one example, as shown in FIG. 2, the depth "D 1" means forming an inlet 143 may be greater than the proximity of the tank 201 to the inlet 201 at a position downstream of the groove depth "D 2." As exemplified by dashed line 210 , bottom wall 207 can extend at an acute angle relative to shaft 209 to provide a substantially continuous reduction in depth from the inlet end to the opposite end along the length of forming device 143 .

成形裝置143進一步包括成形楔形物211,其包含在成形楔形物211之相反末端之間延伸的一對向下傾斜成形表面部分213、215。該對向下傾斜成形表面部分213、215沿下游方向217會合以形成根部219。拉製平面221延伸穿過根部219,其中玻璃帶103可在下游方向217上沿拉製平面221拉製。如圖所示,拉製平面221可平分根部219,儘管拉製平面221可相對於根部219以其他定向延伸。 The forming device 143 further includes a shaped wedge 211 that includes a pair of downwardly angled shaped surface portions 213, 215 that extend between opposite ends of the shaped wedge 211 . The pair of downwardly inclined forming surface portions 213, 215 meet in a downstream direction 217 to form a root portion 219 . The draw plane 221 extends through the root 219 where the glass ribbon 103 can be drawn along the draw plane 221 in the downstream direction 217 . As shown, the draw plane 221 can bisect the root 219 , although the draw plane 221 can extend in other orientations relative to the root 219 .

成形裝置143可視需要具備一或多個邊緣導向器223,其與該對向下傾斜成形表面部分213、215之至少一者相交。在其他實例中,一或多個邊緣導向器可與兩個向下傾斜成形表面部分213、215相交。在其他實例中,邊緣導向器可定位於成形楔形物211之相反末端中之每一者處,其中玻璃帶103之邊緣係藉由流動 離開邊緣導向器之熔融玻璃形成。例如,如第2圖所示,邊緣導向器223可定位於第一相反末端225處,且第二相同邊緣導向器(第2圖中未示出)可定位於第二相反末端處(參見第1圖227)。每一邊緣導向器223可配置來與兩個向下傾斜成形表面部分213、215相交。每一邊緣導向器223可大體上彼此相同,儘管在其他實例中邊緣導向器可具有不同特性。各種成形楔形物及邊緣導向器組態可根據本揭示內容之態樣來使用。例如,本揭示內容之態樣可與美國專利第3,451,798號、美國專利第3,537,834號、美國專利第7,409,839號及/或2009年2月26日申請之美國臨時專利申請案第61/155,669號中所揭示的成形楔形物及邊緣導向器組態一起使用,該等專利各自以全文引用方式併入本文。 The forming device 143 can optionally include one or more edge directors 223 that intersect at least one of the pair of downwardly inclined forming surface portions 213, 215 . In other examples, one or more edge directors can intersect the two downwardly inclined forming surface portions 213, 215 . In other examples, the edge directors can be positioned at each of the opposite ends of the shaped wedge 211 , wherein the edges of the glass ribbon 103 are formed by molten glass flowing away from the edge director. For example, as shown in FIG . 2 , the edge director 223 can be positioned at the first opposite end 225 , and the second identical edge director (not shown in FIG. 2 ) can be positioned at the second opposite end (see the 1 in the picture 227 ). Each edge director 223 can be configured to intersect the two downwardly inclined forming surface portions 213, 215 . Each edge director 223 can be substantially identical to one another, although in other examples the edge directors can have different characteristics. Various shaped wedges and edge director configurations can be used in accordance with aspects of the present disclosure. For example, the disclosure of the present disclosure can be found in U.S. Patent No. 3,451,798, U.S. Patent No. 3,537,834, U.S. Patent No. 7,409,839, and/or U.S. Patent Application Serial No. 61/155,669, filed on Feb. 26, 2009. The disclosed shaped wedges and edge director configurations are used together, each of which is incorporated herein by reference in its entirety.

本文所揭示實施例包括其中沿軸209之至少一部分存在狹槽(第2圖為示出)的彼等實施例。此種實施例之實例展示於第3-6圖。雖然第2圖之某些細節在第3-6圖中未展示,但是應理解此種細節及相關描述可適用於第3-6圖所示的實施例。亦應理解,第3-6圖所示的玻璃成形裝置可用於玻璃成形設備101Embodiments disclosed herein include embodiments in which slots (shown in Figure 2) are present along at least a portion of the shaft 209 . Examples of such embodiments are shown in Figures 3-6. Although certain details of Figure 2 are not shown in Figures 3-6, it should be understood that such details and related descriptions are applicable to the embodiments shown in Figures 3-6. It should also be understood that the glass forming apparatus shown in Figures 3-6 can be used in the glass forming apparatus 101 .

第3圖展示根據本文所揭示實施例的玻璃成形裝置之側面透視圖。第4A及4B圖分別展示第3圖所示的實施例之入口端視圖及壓縮端視圖,而第5A及5B圖分別展示第3圖所示的實施例之頂視圖及底視圖。在第3-4B圖之實施例中,玻璃成形裝置300包括入口端 312、壓縮端314及在入口端312與壓縮端314之間延伸的槽302。玻璃成形裝置亦包括第一側316及第二側318,其中第一側316在垂直方向上自槽302之第一側上的第一堰口304延伸至玻璃成形裝置之根部330。第二側318類似地在垂直方向上自槽302之第二側上的第二堰口306延伸至玻璃成形裝置之根部330。如第3圖中可見,槽302具有深度「D」,該深度在入口端312與壓縮端314之間減小。因此,槽302之橫截面積(例如第4A圖所示)在入口端312與壓縮端314之間減小。 Figure 3 shows a side perspective view of a glass forming apparatus in accordance with embodiments disclosed herein. 4A and 4B are respectively an entrance end view and a compression end view of the embodiment shown in Fig. 3, and Figs. 5A and 5B respectively show a top view and a bottom view of the embodiment shown in Fig. 3. In the embodiment of Figures 3-4B, the glass forming apparatus 300 includes an inlet end 312 , a compression end 314, and a groove 302 extending between the inlet end 312 and the compression end 314 . The glass forming apparatus also includes a first side 316 and a second side 318 , wherein the first side 316 extends in a vertical direction from the first port 304 on the first side of the slot 302 to the root 330 of the glass forming apparatus. The second side 318 similarly extends in a vertical direction from the second port 306 on the second side of the slot 302 to the root 330 of the glass forming apparatus. As can be seen in Figure 3, the slot 302 has a depth " D " that decreases between the inlet end 312 and the compression end 314 . Thus, the cross-sectional area of the slot 302 (e.g., as shown in FIG. 4A) decreases between the inlet end 312 and the compression end 314 .

玻璃成形裝置300另外包括狹槽310,該狹槽在水平方向上沿槽302之至少一長度延伸(如例如第3及5A圖所示)且在垂直方向上自槽302延伸至玻璃成形裝置300之根部330(如例如在第3、4A及4B圖所示)。例如,狹槽310可在水平方向上在入口端312與壓縮端314之間沿槽302延伸幾乎整體距離,或狹槽310可僅延伸彼距離之一部分,諸如彼距離之10%至90%,且另外諸如彼距離之20%至80%。 The glass forming apparatus 300 additionally includes a slot 310 that extends horizontally along at least one length of the slot 302 (as shown, for example, in FIGS. 3 and 5A) and extends from the slot 302 in the vertical direction to the glass forming apparatus 300. The root 330 is as shown, for example, in Figures 3, 4A and 4B. For example, the slot 310 can extend an almost overall distance along the slot 302 between the inlet end 312 and the compression end 314 in a horizontal direction, or the slot 310 can extend only a portion of the distance, such as 10% to 90% of the distance, And another such as 20% to 80% of the distance.

如第3及5B圖所示,邊緣導向器320322經配置成在玻璃成形裝置300之任一末端上鄰近於根部330As shown in Figures 3 and 5B, edge directors 320 and 322 are configured to be adjacent to root 330 at either end of glass forming apparatus 300 .

在某些示範性實施例中,諸如第5A圖所示的彼等實施例,在水平方向上沿槽302之至少一長度延伸的狹槽310具有寬度,該寬度在入口端312與壓縮端314之間增加。如第5B圖所示,狹槽310中最接近壓縮 端314之寬度「W2」大於狹槽310中最接近入口端312之寬度「W1」。例如,狹槽310中最接近壓縮端314之寬度「W2」可比狹槽310中最接近入口端312之寬度「W1」寬至少10%,諸如至少20%,且另外諸如至少50%,且仍另外諸如至少100%。例如,狹槽310中最接近入口端312之寬度「W1」的範圍可在狹槽310中最接近壓縮端314之寬度「W2」的50%至90%,諸如55%至85%,且另外諸如60%至80%。 In certain exemplary embodiments, such as the embodiment illustrated in FIG. 5A, the slot 310 extending along at least one length of the slot 302 in the horizontal direction has a width at the inlet end 312 and the compression end 314. Increase between. As shown in FIG. 5B, the width " W2 " of the slot 310 closest to the compression end 314 is greater than the width " W1 " of the slot 310 closest to the inlet end 312 . For example, the width " W2 " of the slot 310 closest to the compression end 314 may be at least 10% wider than the width " W1 " of the slot 310 closest to the inlet end 312 , such as at least 20%, and additionally such as at least 50%, and still Also such as at least 100%. For example, the width " W1 " of the slot 310 closest to the inlet end 312 may range from 50% to 90% of the width " W2 " of the compression end 314 in the slot 310 , such as 55% to 85%, and Such as 60% to 80%.

狹槽寬度隨入口端312與壓縮端314之間距離變化的差異可經設計來補償當玻璃成形裝置處於完全操作中時在槽302之給定橫截面積上於狹槽310上方的熔融玻璃量之差異(及因此熔融玻璃壓力之差異),進而允許熔融玻璃沿狹槽310之縱向長度的相對恆定流動。狹槽寬度與槽深度之間的關係將另外取決於諸如以下各項之因素:熔融玻璃黏性及熔融玻璃密度以及狹槽於水平方向及垂直方向兩者上之絕對寬度。 The difference in slot width as a function of the distance between the inlet end 312 and the compression end 314 can be designed to compensate for the amount of molten glass above the slot 310 over a given cross-sectional area of the slot 302 when the glass forming apparatus is in full operation. The difference (and thus the difference in molten glass pressure), in turn, allows for a relatively constant flow of molten glass along the longitudinal length of the slot 310 . The relationship between the slot width and the groove depth will additionally depend on factors such as the viscosity of the molten glass and the density of the molten glass and the absolute width of the slot in both the horizontal and vertical directions.

如第3及5B圖所示,狹槽310在水平方向上沿根部330之長度延伸。在某些示範性實施例中,狹槽310可在水平方向上沿根部330延伸幾乎整體距離,或狹槽310可僅延伸彼距離之一部分,諸如彼距離之5%至95%,且另外諸如彼距離之10%至90%。 As shown in Figures 3 and 5B, the slot 310 extends along the length of the root 330 in the horizontal direction. In certain exemplary embodiments, the slot 310 can extend an almost overall distance along the root 330 in the horizontal direction, or the slot 310 can extend only a portion of the distance, such as 5% to 95% of the distance, and additionally 10% to 90% of the distance.

在某些示範性實施例中,諸如第3圖所示的彼實施例,狹槽310沿根部330之長度延伸的水平長度「L2」長於狹槽310沿槽302之長度延伸的水平長度 「L1」。在其他實施例中(未示出),狹槽沿根部之水平長度可大致等於或短於狹槽沿槽之水平長度。當狹槽310沿根部330之長度的水平長度長於狹槽310沿槽302之長度的水平長度時,長度「L2」可比長度「L1」長至少5%,諸如至少10%,且另外諸如至少15%,諸如長5%至30%,包括長10%至25%,且另外包括長15%至20%。 Horizontal length "310 extending along the length of the slot 302 in certain exemplary embodiments, such as shown in FIG Peter embodiment to the third embodiment, the horizontal length of the slot 310 extending along the length of the root portion 330" L2 "is longer than the slot L1 "." In other embodiments (not shown), the horizontal length of the slot along the root may be substantially equal to or shorter than the horizontal length of the slot along the slot. When the horizontal length of the slot 310 along the length of the root 330 is longer than the horizontal length of the slot 310 along the length of the slot 302 , the length " L2 " may be at least 5% longer than the length " L1 ", such as at least 10%, and additionally such as at least 15 %, such as 5% to 30% in length, including 10% to 25% in length, and additionally including 15% to 20% in length.

具有沿根部之長度相對長的水平長度之狹槽可至少部分地補償熔融玻璃帶之衰減(亦即,寬度之縮短),該熔融玻璃帶藉由將熔融玻璃穿過狹槽之流動朝向熔融玻璃帶之最外邊緣轉向而溢流出堰口且沿玻璃成形裝置之第一側及第二側向下流動。此可潛在地增加熔融玻璃帶之品質區域,亦即,玻璃帶中包含實質上均勻厚度之區域,且可允許對帶材之最外邊緣之卷邊形成的控制。 A slot having a relatively long horizontal length along the length of the root portion at least partially compensates for the attenuation (i.e., the shortening of the width) of the molten glass ribbon by flowing the molten glass through the slot toward the molten glass The outermost edge of the belt is deflected to overflow the mouth and flow down the first side and the second side of the glass forming apparatus. This can potentially increase the quality area of the molten glass ribbon, i.e., the area of the glass ribbon that contains a substantially uniform thickness, and can allow control of the formation of the bead of the outermost edge of the strip.

在第5B圖所示的實施例中,沿根部330之長度延伸的狹槽310具有寬度,該寬度沿該根部之長度的大部分大致恆定且在該根部末端(接近邊緣導向器320322)處漸縮。例如,沿根部330之長度延伸的狹槽310具有寬度,該寬度沿該根部之長度的大部分,諸如沿該根部之長度的至少75%,且另外諸如沿該根部之長度的至少85%,且仍另外諸如沿該根部之長度的至少95%,且甚至另外諸如沿該根部之長度的實質上全部而大致恆定(以使得沿根部330之長度延伸的狹槽310之 末端不漸縮)。沿根部330之長度延伸的具有沿該根部之長度的至少大多數大致恆定的狹槽310可進一步允許具有大致恆定寬度之熔融玻璃帶。 In the embodiment illustrated in Figure 5B, the slot 310 extending along the length of the root 330 has a width that is substantially constant along a majority of the length of the root and at the end of the root (near the edge directors 320 and 322 ) Gradually. For example, the slot 310 extending along the length of the root 330 has a width that is along a majority of the length of the root, such as along at least 75% of the length of the root, and additionally such as along at least 85% of the length of the root, And still additionally such as at least 95% along the length of the root, and even otherwise substantially constant along substantially all of the length of the root (so that the ends of the slots 310 extending along the length of the root 330 do not taper). At least a majority of substantially constant slots 310 extending along the length of the root 330 along the length of the root may further permit a molten glass ribbon having a substantially constant width.

因此,第5A及5B圖所示的實施例展示在水平方向上沿槽302之至少一長度延伸的狹槽310,該狹槽具有寬度,該寬度在入口端312與壓縮端314之間增加(其中「W2」>「W1」),其中狹槽310以沿根部330之長度的至少大多數大致恆定寬度來延伸。此實施例(如第3圖所示)亦展示狹槽310,該狹槽具有沿根部330之長度延伸的水平長度「L2」,該水平長度長於狹槽310沿槽302之長度延伸的水平長度「L1」。 Thus, the embodiment illustrated in Figures 5A and 5B shows a slot 310 extending horizontally along at least one length of the slot 302 , the slot having a width that increases between the inlet end 312 and the compression end 314 ( Wherein " W2 ">" W1 "), wherein the slot 310 extends at least a substantially constant width along the length of the root 330 . This embodiment (shown in Figure 3) also shows a slot 310 having a horizontal length " L2 " extending along the length of the root 330 that is longer than the horizontal length of the slot 310 extending along the length of the slot 302 . " L1 ".

第6圖展示根據本文所揭示實施例的玻璃成形裝置之端部剖視圖,其中玻璃帶103在玻璃成形裝置300之根部330下方形成。如第6圖所示,熔融玻璃自槽302溢流出第一堰口304,且沿第一側316向下朝向根部330流動。熔融玻璃亦自槽302溢流出第二堰口306,且沿第二側318向下朝向根部330流動。另外,熔融玻璃自槽302流動且向下穿過狹槽310朝向根部330流動。熔融玻璃帶103係形成為溢流出第一堰口304及第二堰口306之熔融玻璃,在根部330處結合流動穿過狹槽310之熔融玻璃。 6 shows an end cross-sectional view of a glass forming apparatus in accordance with embodiments disclosed herein, wherein a glass ribbon 103 is formed below the root 330 of the glass forming apparatus 300 . As shown in FIG. 6, the molten glass overflows from the slot 302 out of the first port 304 and flows down the first side 316 toward the root 330 . The molten glass also overflows from the trough 302 out of the second port 306 and flows down the second side 318 toward the root 330 . Additionally, molten glass flows from the trough 302 and flows downwardly through the slot 310 toward the root 330 . The molten glass ribbon 103 is formed as molten glass that overflows the first port 304 and the second port 306 , and joins the molten glass flowing through the slot 310 at the root 330 .

在第6圖所示的實施例中,加熱元件350A-D係安置成鄰近於成形裝置(雖然第6圖展示四個加熱元件,但應理解,本文中之實施例包括包含更大或 更少數量之加熱元件的彼等實施例)。加熱元件350A-D可例如包含電氣電阻加熱元件,諸如美國公開專利申請案第2008/0282736號中所揭示的彼等元件,該專利申請案之整體揭示內容係以引用方式併入本文中。就此點而言,雖然加熱元件350A-D在第6圖中示意地展示為具有矩形或平行四邊形橫截面,但應理解加熱元件可具有任何幾何組態或橫截面,包括圓形及橢圓形橫截面。 In the embodiment illustrated in Figure 6, the heating elements 350A-D are disposed adjacent to the forming device (although Figure 6 shows four heating elements, it should be understood that embodiments herein include greater or less Examples of the number of heating elements). The heating elements 350A-D may, for example, comprise electrical resistance heating elements, such as those disclosed in U.S. Patent Application Serial No. 2008/0282736, the entire disclosure of which is incorporated herein by reference. In this regard, although the heating elements 350A-D are shown schematically in Figure 6 as having a rectangular or parallelogram cross section, it should be understood that the heating element can have any geometric configuration or cross section, including circular and elliptical transverse. section.

加熱元件350A-D可經配置以便提供對溢流出第一堰口304及第二堰口306之熔融玻璃之溫度的控制。例如,加熱元件350A-D可經配置及操作以允許自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度處於相對於自狹槽310到達根部330的熔融玻璃之溫度的預定溫度範圍內。例如,加熱元件350A-D可經配置及操作以使得自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度處於自狹槽310到達根部330的熔融玻璃之溫度的20℃內,諸如10℃內,且另外諸如5℃內。加熱元件350A-D可經配置及操作以使得自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度處於大致等於自狹槽310到達根部330的熔融玻璃之溫度的預定溫度範圍內。維持自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度處於相對於自狹槽310到達根部330的熔融玻璃之溫度的預定範圍內可例如允許改良的玻璃帶流動及玻璃片性質。 The heating elements 350A-D can be configured to provide control of the temperature of the molten glass that overflows the first port 304 and the second port 306 . For example, the heating elements 350A-D may be configured and operated to allow from over the first weir 304 and a second weir 306 reaches the temperature of the molten glass of the root 330 is the relative from the slot 310 reaches the temperature of the molten glass root portion 330 of a predetermined Within the temperature range. For example, the heating elements 350A-D can be configured and operated such that the temperature of the molten glass from the upper first port 304 and the second port 306 reaching the root 330 is within 20 ° C of the temperature of the molten glass from the slot 310 reaching the root 330 , such as within 10 ° C, and additionally such as within 5 ° C. The heating elements 350A-D can be configured and operated such that the temperature of the molten glass from the upper first port 304 and the second port 306 reaching the root 330 is at a predetermined temperature range substantially equal to the temperature of the molten glass from the slot 310 to the root 330 . Inside. Maintained from port 304 over the first weir and the weir 306 reaches the second temperature of the molten glass in the root portion 330 is within a predetermined range with respect to the slot 310 from the temperature of the molten glass reaches the root 330 may be modified, for example, allow the flow of glass and glass tape nature.

雖然本文所揭示實施例包括其中熔融玻璃經由單一入口(諸如第1圖所示的入口141)進料至玻璃成形裝置300的彼等實施例,但本文所揭示實施例亦包括包含對玻璃成形裝置300之第一熔融玻璃進料及對玻璃成形裝置300之第二熔融玻璃進料的彼等實施例,其中第一熔融經配置以主要將熔融玻璃流導向出第一堰口304及第二堰口306,而第二熔融玻璃進料經配置以主要將熔融玻璃流導向至狹槽310中。因此,本文所揭示實施例包括將第一熔融玻璃進料引入至玻璃成形裝置且將第二熔融玻璃進料引入至玻璃成形裝置300,其中來自第一熔融玻璃進料之大多數熔融玻璃溢流出第一堰口304及第二堰口306,而來自第二熔融玻璃進料之大多數熔融玻璃流動至狹槽310中。較佳地,第一熔融玻璃進料將垂直地高於第二熔融玻璃進料。 Although the embodiments disclosed herein include embodiments in which molten glass is fed to the glass forming apparatus 300 via a single inlet, such as inlet 141 shown in FIG. 1, the embodiments disclosed herein also include a pair of glass forming apparatus. An embodiment of the first molten glass feed of 300 and the second molten glass feed to the glass forming apparatus 300 , wherein the first melt is configured to primarily direct the flow of molten glass out of the first port 304 and the second port 306 And the second molten glass feed is configured to primarily direct the flow of molten glass into the slot 310 . Accordingly, embodiments disclosed herein include introducing a first molten glass feed to a glass forming apparatus and introducing a second molten glass feed to the glass forming apparatus 300 , wherein most of the molten glass from the first molten glass feed overflows The first port 304 and the second port 306 , while most of the molten glass from the second molten glass feed flows into the slot 310 . Preferably, the first molten glass feed will be vertically higher than the second molten glass feed.

在某些示範性實施例中,第一熔融玻璃進料之至少60%,諸如至少70%,且另外諸如至少80%,且仍另外諸如至少90%(包括第一熔融玻璃進料之60%至99%且另外包括70%至95%)溢流出第一堰口304及第二堰口306。此種實施例可包括其中第二熔融玻璃進料之至少60%,諸如至少70%,且另外諸如至少80%,且仍另外諸如至少90%(包括第二熔融玻璃進料之60%至99%且另外包括70%至95%)流動至狹槽310中之彼等實施例。 In certain exemplary embodiments, at least 60% of the first molten glass feed, such as at least 70%, and additionally such as at least 80%, and still additionally such as at least 90% (including 60% of the first molten glass feed) Up to 99% and additionally 70% to 95%) overflows the first port 304 and the second port 306 . Such embodiments may include wherein at least 60% of the second molten glass feed, such as at least 70%, and additionally such as at least 80%, and still additionally such as at least 90% (including 60% to 99% of the second molten glass feed) % and additionally include 70% to 95%) of the embodiments flowing into the slot 310 .

當使用第一熔融玻璃進料及第二熔融玻璃進料時,第一熔融玻璃進料及第二熔融玻璃進料之組成可為相同或不同的。第一熔融玻璃進料及第二熔融玻璃進料之溫度亦可為相同或不同的。例如,在一些實施例中,第一熔融玻璃進料之溫度可至少稍微高於第二熔融玻璃進料之溫度,諸如高至少5℃,且另外諸如高至少10°,包括高5℃至100℃,諸如高10℃至50℃。 When the first molten glass feed and the second molten glass feed are used, the composition of the first molten glass feed and the second molten glass feed may be the same or different. The temperatures of the first molten glass feed and the second molten glass feed may also be the same or different. For example, in some embodiments, the temperature of the first molten glass feed can be at least slightly higher than the temperature of the second molten glass feed, such as at least 5 ° C high, and additionally such as at least 10 ° high, including 5 ° C to 100 high. °C, such as 10 ° C to 50 ° C.

維持第一熔融玻璃進料處於比第二熔融玻璃進料更高的溫度下可取決於玻璃組成物、流動運輸特性及其他條件而允許更多第一熔融玻璃進料溢流出第一堰口304及第二堰口306,此係由於在較高溫度下較低的相對密度及因此槽302內增加的浮力。維持第一熔融玻璃進料處於比第二熔融玻璃進料更高的溫度下亦可進一步允許自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度處於相對於自狹槽310到達根部330的熔融玻璃之溫度的預定溫度範圍內,而無需諸如加熱元件350A-D之加熱元件。例如,維持第一熔融玻璃進料處於比第二熔融玻璃進料更高的預定溫度下可允許自上方第一堰口304及第二堰口306到達根部330的熔融玻璃之溫度大致等於自狹槽310到達根部330的熔融玻璃之溫度,而無需諸如加熱元件350A-D之加熱元件。 Maintaining the first molten glass feed at a higher temperature than the second molten glass feed may allow more of the first molten glass feed to overflow the first opening 304 and depending on the glass composition, flow transport characteristics, and other conditions. The second port 306 is due to the lower relative density at higher temperatures and thus the increased buoyancy within the slot 302 . Maintaining the first molten glass feed at a higher temperature than the second molten glass feed may further allow the temperature of the molten glass from the upper first port 304 and the second port 306 to reach the root 330 to be at a relative to the slot 310. The temperature of the molten glass reaching the root 330 is within a predetermined temperature range without the need for heating elements such as heating elements 350A-D . For example, maintaining the first molten glass feed at a higher predetermined temperature than the second molten glass feed may allow the temperature of the molten glass from the upper first port 304 and the second port 306 to reach the root 330 to be substantially equal to the slot 310. The temperature of the molten glass reaching the root 330 is eliminated without the need for heating elements such as heating elements 350A-D .

引入至玻璃成形裝置300(經由一或多種熔融玻璃進料)的流動至狹槽310中(與溢流出堰口304306相對)的熔融玻璃之總流動密度百分比(雖然不受限制但)可例如在以下範圍變化:5%至95%,諸如10%至90%,且另外諸如20%至80%,且仍另外諸如自30%至70%,且再另外諸如40%至60%。在某些實施例中,引入至玻璃成形裝置300的熔融玻璃之總流動密度之至少50%,諸如至少60%,且另外諸如至少70%流動至狹槽310中。 The total flow density percentage (although unrestricted) of the molten glass introduced into the glass forming apparatus 300 (via one or more molten glass feeds) into the slots 310 (as opposed to the overflow weirs 304 , 306 ) may for example It varies in the following ranges: 5% to 95%, such as 10% to 90%, and additionally such as 20% to 80%, and still additionally such as from 30% to 70%, and still another such as 40% to 60%. In certain embodiments, at least 50% of the total flow density of the molten glass introduced to the glass forming apparatus 300 , such as at least 60%, and additionally such as at least 70% flow into the slot 310 .

沿槽302之長度延伸的狹槽310之面積相對於槽302之底部之總面積而言(雖然不受限制但)可在槽302之底部之總面積的例如以下範圍變化:5%至50%,諸如10%至40%,且另外諸如15%至30%,且仍另外諸如20%至25%。 Area along the length of the slot 310 of the slot 302 extending relative to the total area of the bottom of the groove 302 (but is not limited although) may vary in the range, for example, the total area of the bottom of the groove 302: 5-50% , such as 10% to 40%, and additionally such as 15% to 30%, and still additionally such as 20% to 25%.

雖然不限於任何特定材料,但在某些示範性實施例中,玻璃成形裝置300可包含耐火材料,該耐火材料對使用該裝置形成的熔融玻璃具有最小反應性。用於玻璃成形裝置之示範性材料包括但不限於等壓縮的基於鋯石之陶瓷材料,諸如美國專利申請公開案第2004/0055338號及第2005/0130830號中揭示的彼等陶瓷材料,該等公開案之整體揭示內容係以引用方式併入本文中。用於玻璃成形裝置之示範性材料亦可包括等壓縮的基於磷釔礦的或磷釔礦穩定的基於鋯石之陶瓷材料,諸如美國專利申請公開案第2009/0131241號中揭示的彼等陶瓷材料,該公開案之整體揭示內容係以引用方式併入本文中。 While not limited to any particular material, in certain exemplary embodiments, glass forming apparatus 300 can comprise a refractory material that has minimal reactivity to the molten glass formed using the apparatus. Exemplary materials for the glass forming apparatus include, but are not limited to, an iso-compressed zircon-based ceramic material such as those disclosed in U.S. Patent Application Publication Nos. 2004/0055338 and 2005/0130830, which are incorporated herein by reference. The entire disclosure of the disclosure is incorporated herein by reference. Exemplary materials for use in a glass forming apparatus may also include an isobaric-based or xenotime-based stabilized zircon-based ceramic material such as those disclosed in U.S. Patent Application Publication No. 2009/0131241 The material, the entire disclosure of which is incorporated herein by reference.

包含狹槽310之玻璃成形裝置可藉由任何種類之方法之一來製成。例如,根據本文所揭示實施例之玻璃成形裝置可藉由將玻璃成形裝置之兩個實質上鏡像半部黏結在一起而製成,其中自每一半部形成、佈置(routed)或切出包含狹槽310之區域。例如在美國專利第7,988,804號中揭示用於黏結玻璃成形裝置之組件的方法,該專利之整體揭示內容係以引用方式併入本文中。例如在美國專利公開案第2014/0318523號中揭示用於自玻璃成形裝置切割或移除材料的方法,該公開案之整體揭示內容係以引用方式併入本文中。 The glass forming device comprising the slot 310 can be made by one of any of a variety of methods. For example, a glass forming apparatus in accordance with embodiments disclosed herein can be made by bonding together two substantially mirrored halves of a glass forming apparatus, wherein each half is formed, routed, or cut out. The area of the slot 310 . A method for bonding components of a glass forming apparatus is disclosed, for example, in U.S. Patent No. 7,988,804, the entire disclosure of which is incorporated herein by reference. A method for cutting or removing material from a glass forming apparatus is disclosed, for example, in U.S. Patent Publication No. 2014/0318523, the entire disclosure of which is incorporated herein by reference.

本文所揭示實施例可允許諸如玻璃片之玻璃物件之生產,同時提供優於先前已知方法之至少一個優點,諸如在本文中其他處所論述的優點。此外,本文所揭示實施例可允許諸如玻璃片之玻璃物件之生產,其中針對給定熔融玻璃流動密度而言,玻璃成形裝置300之重量相對於先前已知玻璃成形裝置之重量顯著減少。例如,對給定熔融玻璃流動密度而言,玻璃成形裝置300之重量可比先前已知玻璃成形裝置少至少10%,諸如少至少20%,且另外諸如少至少30%,且仍另外諸如少至少40%,包括少10%至少50%。本文所揭示實施例亦可允許諸如玻璃片之玻璃物件之生產,其中針對給定熔融玻璃流動密度而言,玻璃成形裝置300之溫度相對於先前已知玻璃成形裝置之重量為較低的。例如,對給定熔融玻璃流動密度而言,玻璃成形裝置300之溫度可比先 前已知玻璃成形裝置低至少20℃,諸如低至少50℃,且另外諸如低至少100℃,低諸如20℃至200℃。針對給定熔融玻璃流率降低玻璃成形裝置之重量及/或溫度可緩和許多潛在的缺點,諸如玻璃成形裝置隨時間推移經受增加的變形及/或玻璃成形裝置之增加的腐蝕或化學侵蝕。替代言之,本文中之實施例可允許諸如玻璃片之玻璃物件之生產,其中熔融玻璃流動密度較高,同時最小化本文論述的缺點中之至少一者。 Embodiments disclosed herein may allow for the production of glass articles such as glass sheets while providing at least one advantage over previously known methods, such as those discussed elsewhere herein. Moreover, the embodiments disclosed herein may allow for the production of glass articles such as glass sheets, wherein the weight of the glass forming device 300 is significantly reduced relative to the weight of previously known glass forming devices for a given molten glass flow density. For example, for a given molten glass flow density, the glass forming apparatus 300 can be at least 10% less, such as at least 20% less than the previously known glass forming apparatus, and additionally such as at least 30% less, and still additionally, such as at least 40%, including at least 10% less than 50%. Embodiments disclosed herein may also allow for the production of glass articles such as glass sheets, wherein the temperature of the glass forming apparatus 300 is lower relative to the weight of previously known glass forming apparatus for a given molten glass flow density. For example, for a given molten glass flow density, the temperature of the glass forming apparatus 300 can be at least 20 ° C lower than previously known glass forming apparatus, such as at least 50 ° C lower, and additionally such as at least 100 ° C lower, such as 20 ° C to 200 lower. °C. Reducing the weight and/or temperature of the glass forming apparatus for a given molten glass flow rate can alleviate many potential drawbacks, such as the glass forming apparatus undergoing increased deformation over time and/or increased corrosion or chemical attack of the glass forming apparatus. Alternatively, embodiments herein may allow for the production of glass articles such as glass sheets, wherein the molten glass has a higher flow density while minimizing at least one of the disadvantages discussed herein.

藉由本文所揭示方法造成的包括玻璃片之玻璃物件可用於各種應用,該等應用包括併入電子裝置中之平坦玻璃面板及螢幕,該等電子裝置諸如LCD電視及手持式電子裝置。在此種玻璃片中,玻璃片中於厚度方向上之中間部分將自流動穿過狹槽310之玻璃提供,而玻璃片之第一表面區域和第二表面區域將自溢流出堰口304、306之玻璃提供。例如,在某些實施例中,玻璃片之總厚度之至少20%,諸如至少30%,且另外諸如至少40%,且仍另外諸如至少50%,且再另外諸如至少60%(包括20%至80%且另外包括30%至70%)可自流動穿過狹槽310之玻璃提供。 Glass articles comprising glass sheets by the methods disclosed herein can be used in a variety of applications, including flat glass panels and screens incorporated into electronic devices such as LCD televisions and handheld electronic devices. In such a glass sheet, the intermediate portion of the glass sheet in the thickness direction will be provided from the glass flowing through the slot 310 , and the first surface area and the second surface area of the glass sheet will flow out of the mouth 304, 306. The glass is provided. For example, in certain embodiments, at least 20% of the total thickness of the glass sheets, such as at least 30%, and additionally such as at least 40%, and still additionally such as at least 50%, and yet another such as at least 60% (including 20%) Up to 80% and additionally 30% to 70%) may be provided from the glass flowing through the slot 310 .

以此種方式,可在相對於先前已知生產方法的潛在更低生產成本下達成具有高表面品質之相對薄的、平坦玻璃片之生產。 In this way, the production of relatively thin, flat glass sheets with high surface quality can be achieved with potentially lower production costs relative to previously known production methods.

雖然已關於溢流下拉製程來描述本文所揭示的特定實施例,但應理解,此種實施例之操作原理亦可 適用於諸如流動製程及狹槽拉製製程的其他玻璃成形製程。 Although the specific embodiments disclosed herein have been described in terms of an overflow pull-down process, it should be understood that the operating principles of such embodiments may also Suitable for other glass forming processes such as flow processes and slot drawing processes.

熟習此項技術者將明白的是,可在不脫離本揭示內容之精神及範疇的情況下對本揭示內容之實施例做出各種修改及變化。因此,本揭示案意欲涵蓋此等及其他實施例之修改及變化,前提條件是該等修改及變化屬於隨附發明申請專利範圍及其等效物之範疇內。 It will be apparent to those skilled in the art that various modifications and changes can be made to the embodiments of the present disclosure without departing from the spirit and scope of the disclosure. Therefore, the present disclosure is intended to cover such modifications and alternatives, and

302‧‧‧槽 302‧‧‧ slots

304‧‧‧第一堰口 304‧‧‧ first pass

306‧‧‧第二堰口 306‧‧‧Second Pass

310‧‧‧狹槽 310‧‧‧ slot

316‧‧‧第一側 316‧‧‧ first side

318‧‧‧第二側 318‧‧‧ second side

330‧‧‧根部 330‧‧‧ root

Claims (20)

一種用於生產一玻璃物件之設備,其包含:一玻璃成形裝置,其包含:一入口端及一壓縮端以及在該入口端與該壓縮端之間延伸的一槽;一第一側及一第二側,該等側各自在一水平方向上自該入口端延伸至該壓縮端,其中該第一側在一垂直方向上自該槽之一第一側上的一第一堰口延伸至該玻璃成形裝置之一根部,而該第二側在該垂直方向上自該槽之一第二側上的一第二堰口延伸至該玻璃成形裝置之該根部;其中該槽具有一深度,該深度在該入口端與該壓縮端之間減小;且其中該玻璃成形裝置進一步包含一狹槽,該狹槽在該水平方向上沿該槽之至少一長度延伸,且在該垂直方向上自該槽延伸至該玻璃成形裝置之該根部。 An apparatus for producing a glass article, comprising: a glass forming device comprising: an inlet end and a compression end; and a groove extending between the inlet end and the compression end; a first side and a a second side, each of the sides extending from the inlet end to the compression end in a horizontal direction, wherein the first side extends in a vertical direction from a first port on the first side of the slot to the a root of the glass forming device, the second side extending in the vertical direction from a second opening on a second side of the groove to the root of the glass forming device; wherein the groove has a depth, the depth Decreasing between the inlet end and the compression end; and wherein the glass forming device further comprises a slot extending in the horizontal direction along at least one length of the slot, and in the vertical direction The groove extends to the root of the glass forming device. 如請求項1所述之設備,其中沿該槽之至少一長度延伸的該狹槽具有一寬度,該寬度在該入口端與該壓縮端之間增加。 The apparatus of claim 1 wherein the slot extending along at least one length of the slot has a width that increases between the inlet end and the compression end. 如請求項2所述之設備,其中該狹槽中最接近該壓縮端之該寬度為該狹槽中最接近該入口端之 該寬度的至少兩倍。 The device of claim 2, wherein the width of the slot closest to the compression end is the closest to the inlet end of the slot At least twice the width. 如請求項1所述之設備,其中該狹槽在該水平方向上沿該根部之一長度延伸,其中沿該根部之該長度延伸的該狹槽之水平長度長於沿該槽之一長度延伸的該狹槽之水平長度。 The device of claim 1, wherein the slot extends along a length of the root in the horizontal direction, wherein a horizontal length of the slot extending along the length of the root is longer than a length along a length of the slot The horizontal length of the slot. 如請求項4所述之設備,其中沿該根部之該長度延伸的該狹槽之每一末端漸縮。 The device of claim 4, wherein each end of the slot extending along the length of the root tapers. 如請求項1所述之設備,其中該設備進一步包含對該玻璃成形裝置之一第一熔融玻璃進料及對該玻璃成形裝置之一第二熔融玻璃進料,其中該第一熔融玻璃進料經配置以將熔融玻璃流導向出該第一堰口及該第二堰口,且該第二熔融玻璃進料經配置以將熔融玻璃流導向至該狹槽中。 The apparatus of claim 1 wherein the apparatus further comprises a first molten glass feed to one of the glass forming devices and a second molten glass feed to the glass forming apparatus, wherein the first molten glass feed A flow of molten glass is directed out of the first port and the second port, and the second molten glass feed is configured to direct a flow of molten glass into the slot. 如請求項1所述之設備,其中該設備進一步包含安置成鄰近於該玻璃成形裝置之至少一個加熱元件。 The apparatus of claim 1 wherein the apparatus further comprises at least one heating element disposed adjacent to the glass forming apparatus. 一種生產一玻璃物件之方法,該方法包含以下步驟:將熔融玻璃引入至一玻璃成形裝置,該玻璃成形裝置包含:一入口端及一壓縮端以及在該入口端與該壓縮端之間延伸的一槽;一第一側及一第二側,該等側各自在一水平方向上 自該入口端延伸至該壓縮端,其中該第一側在一垂直方向上自該槽之一第一側上的一第一堰口延伸至該玻璃成形裝置之一根部,而該第二側在該垂直方向上自該槽之一第二側上的一第二堰口延伸至該玻璃成形裝置之該根部;其中該槽具有一深度,該深度在該入口端與該壓縮端之間減小;其中該玻璃成形裝置進一步包含一狹槽,該狹槽在該水平方向上沿該槽之至少一長度延伸,且在該垂直方向上自該槽延伸至該玻璃成形裝置之該根部;且其中熔融玻璃自該槽溢流出該第一堰口及第二堰口且流動穿過該狹槽。 A method of producing a glass article, the method comprising the steps of: introducing molten glass into a glass forming apparatus, the glass forming apparatus comprising: an inlet end and a compression end and extending between the inlet end and the compression end a slot; a first side and a second side, each of the sides being in a horizontal direction Extending from the inlet end to the compression end, wherein the first side extends in a vertical direction from a first opening on a first side of the groove to a root of the glass forming device, and the second side is Extending in the vertical direction from a second port on a second side of the slot to the root of the glass forming device; wherein the slot has a depth that decreases between the inlet end and the compression end; Wherein the glass forming device further comprises a slot extending in the horizontal direction along at least one length of the groove and extending from the groove to the root of the glass forming device in the vertical direction; and wherein the melting The glass overflows the first and second ports from the slot and flows through the slot. 如請求項8所述之方法,其中沿該槽之至少一長度延伸的該狹槽具有一寬度,該寬度在該入口端與該壓縮端之間增加。 The method of claim 8 wherein the slot extending along at least one length of the slot has a width that increases between the inlet end and the compression end. 如請求項9所述之方法,其中該狹槽中最接近該壓縮端之該寬度為該狹槽中最接近該入口端之該寬度的至少兩倍。 The method of claim 9, wherein the width of the slot closest to the compression end is at least twice the width of the slot closest to the inlet end. 如請求項8所述之方法,其中該狹槽在該水平方向上沿該根部之一長度延伸,其中沿該根部之一長度延伸的該狹槽之水平長度長於沿該槽之一長度延伸的該狹槽之水平長度。 The method of claim 8, wherein the slot extends along the length of the root in the horizontal direction, wherein the slot extending along one of the lengths of the root has a horizontal length that is longer than a length of the slot The horizontal length of the slot. 如請求項11所述之方法,其中沿該根部之該長度延伸的該狹槽之每一末端漸縮。 The method of claim 11, wherein each end of the slot extending along the length of the root tapers. 如請求項8所述之方法,其中該方法進一步包含以下步驟:將一第一熔融玻璃進料引入至該玻璃成形裝置且將一第二熔融玻璃進料引入至該玻璃成形裝置,其中來自該第一熔融玻璃進料之大多數熔融玻璃溢流出該第一堰口及該第二堰口,而來自該第二熔融玻璃進料之大多數熔融玻璃流動至該狹槽中。 The method of claim 8 wherein the method further comprises the steps of: introducing a first molten glass feed to the glass forming apparatus and introducing a second molten glass feed to the glass forming apparatus, wherein Most of the molten glass of the first molten glass feed overflows the first port and the second port, and most of the molten glass from the second molten glass feed flows into the slot. 如請求項13所述之方法,其中該第一熔融玻璃進料及該第二熔融玻璃進料之組成相同。 The method of claim 13 wherein the composition of the first molten glass feed and the second molten glass feed are the same. 如請求項13所述之方法,其中該第一熔融玻璃進料及該第二熔融玻璃進料之該組成不同。 The method of claim 13 wherein the composition of the first molten glass feed and the second molten glass feed are different. 如請求項13所述之方法,其中該第一熔融玻璃進料及該第二熔融玻璃進料之溫度不同。 The method of claim 13 wherein the first molten glass feed and the second molten glass feed are at different temperatures. 如請求項8所述之方法,其中引入至該玻璃成形裝置的熔融玻璃之一總流動密度之至少50%流動至該狹槽中。 The method of claim 8 wherein at least 50% of the total flow density of one of the molten glass introduced into the glass forming apparatus flows into the slot. 如請求項8所述之方法,其中溢流出該第一堰口及該第二堰口之熔融玻璃在該根部處結合流動穿過該狹槽之熔融玻璃,其中自上方該第一堰口及該第二堰口到達該根部的熔融玻璃之一溫度處於自 該狹槽到達該根部的熔融玻璃之一溫度的20℃內。 The method of claim 8, wherein the molten glass overflowing the first opening and the second opening joins the molten glass flowing through the slot at the root, wherein the first opening and the second from above One of the molten glass that reaches the root of the mouth is at a temperature The slot reaches 20 ° C of the temperature of one of the molten glass of the root. 一種玻璃片,其藉由如請求項8所述之方法製成。 A glass sheet produced by the method of claim 8. 一種電子裝置,其包含如請求項19所述之玻璃片。 An electronic device comprising the glass piece as claimed in claim 19.
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