TW201710059A - Production method for light guide plate - Google Patents

Production method for light guide plate Download PDF

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TW201710059A
TW201710059A TW105122636A TW105122636A TW201710059A TW 201710059 A TW201710059 A TW 201710059A TW 105122636 A TW105122636 A TW 105122636A TW 105122636 A TW105122636 A TW 105122636A TW 201710059 A TW201710059 A TW 201710059A
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polycarbonate
roll
sheet
roller
light guide
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TW105122636A
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Chinese (zh)
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TWI707770B (en
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Hiroshi Okada
Koji Okada
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Nitto Jushi Kogyo Co Ltd
Sumika Styron Polycarbonate
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  • Light Guides In General And Applications Therefor (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The objective of the invention is to produce a light guide plate on which shapes such as dot patterns can be accurately applied, and, despite being thin, has high strength, is readily handled, and can be put into practical use. The production method for a polycarbonate light guide plate comprises steps of: rotating a first roll and a second roll while sandwiching a sheet-form polycarbonate between a flexible support and the second roll so as to apply pressure while co-transporting the flexible support, thereby pressing the sheet-form polycarbonate against the second roll; and causing the sheet-form polycarbonate pressed against the second roll and supported on the surface of the second roll by the flexible support to be transported in the rotation direction of the second roll, and separating the sheet-form polycarbonate from the flexible support, at a position where the rotation angle of the second roll is 45 to 150 DEG, as referenced from the position where the surfaces of the first roll and the second roll are closest to one another.

Description

導光板之製造方法 Light guide plate manufacturing method

本發明係關於一種例如於智慧型手機、行動電話、移動終端、攜帶型資訊終端(PDA)、平板型個人電腦(PC)、筆記型PC(Pesonal Computer,個人電腦)、車載用儀錶板、PC用顯示監控器等之液晶顯示面板之背光裝置;及例如於智慧型手機、行動電話、移動終端、攜帶型資訊終端(PDA)、平板型個人電腦(PC)、筆記型PC等之鍵盤之背光裝置等之照明裝置內部所使用之導光板之製造方法。 The present invention relates to, for example, a smart phone, a mobile phone, a mobile terminal, a portable information terminal (PDA), a tablet type personal computer (PC), a notebook PC (Pesonal Computer), a vehicle instrument panel, and a PC. a backlight device using a liquid crystal display panel such as a monitor; and a backlight of a keyboard such as a smart phone, a mobile phone, a mobile terminal, a portable information terminal (PDA), a tablet type personal computer (PC), a notebook PC, or the like A method of manufacturing a light guide plate used inside a lighting device such as a device.

使自側面進入之光擴散,並自表面出射光之導光板作為液晶顯示面板等之背光裝置而使用。由於導光板使自其側面入射且於內部傳播之光自導光板之表面出射,故而一般於導光板之表面形成點圖案等形狀之情況居多。 A light guide plate that diffuses light entering from the side and emits light from the surface is used as a backlight device such as a liquid crystal display panel. Since the light guide plate emits light that is incident from the side surface and propagates inside from the surface of the light guide plate, generally, a shape such as a dot pattern is formed on the surface of the light guide plate.

使用導光板之照明裝置需要更輕、更薄、更低價格化。因此,需要導光板使厚度進一步變薄,且更正確地形成點圖案等形狀(提高形狀賦予性),並且提高此種導光板之生產性。導光板以往係藉由射出成形及擠出加工等製造,要進行各種處理。 Lighting devices that use light guides need to be lighter, thinner, and less expensive. Therefore, the light guide plate is required to further thin the thickness, and the shape of the dot pattern or the like is more accurately formed (improving the shape imparting property), and the productivity of the light guide plate is improved. In the past, the light guide plate was manufactured by injection molding, extrusion processing, or the like, and various processes were performed.

專利文獻1記載於兩面具有凸起部之導光板及其製造方法。專利文獻1記載以下導光板,即具備具有透光性之片狀之基部,於基部之正面及背面各者形成成為凸起之部位,一面之成為凸起之部位包含與基部相同之材料之具有脂環式結構之聚合物樹脂等熔融擠出樹脂,形成於另一面之成為凸起之部位包含丙烯酸系紫外線硬化型樹脂等游離 輻射硬化樹脂(參照專利文獻1[技術方案1]、[0009]、[0026])。專利文獻1記載導光板之厚度可設為500μm以下(參照專利文獻1[0036]、[圖5])。專利文獻1記載利用套筒法(sleeve method)之熔融擠出加工作為此種導光板之製造方法(參照專利文獻1[0037]~[0038]、[圖7]~[圖8])。 Patent Document 1 describes a light guide plate having a convex portion on both sides and a method of manufacturing the same. Patent Document 1 discloses a light guide plate having a base portion having a light-transmissive sheet shape, and a portion which is a projection on each of a front surface and a back surface of the base portion, and a portion which is a projection on one surface includes a material similar to the base portion. A melt-extruded resin such as a polymer resin having an alicyclic structure is formed on the other surface and is a convex portion including an acrylic ultraviolet curable resin or the like. Radiation-hardening resin (refer to Patent Document 1 [Technical Solution 1], [0009], [0026]). In Patent Document 1, the thickness of the light guide plate can be set to 500 μm or less (see Patent Document 1 [0036] and [FIG. 5]). Patent Document 1 describes a method of producing such a light guide plate by melt extrusion processing using a sleeve method (see Patent Documents 1 [0037] to [0038], [Fig. 7] to [Fig. 8].

專利文獻2記載具有薄型兩面導光板之光學片材及其製造方法。專利文獻2記載以下光學片材,即其係具有複數個導光板者,且於第1加壓輥與第1圖案形成輥之間之輥隙擠出第1樹脂,形成具有圖案未形成之面與圖案形成之面之第1層;將第1層搬運至第2圖案形成輥與第2加壓輥之間之輥隙;於第2加壓輥與第2圖案形成輥之間之輥隙於第1層之圖案未形成之面上擠出第2層,形成具有圖案形成之面之第2層,成為一體之第1層與第2層包含複數個導光板圖案(參照專利文獻2[技術方案1])。專利文獻2記載光學片材之厚度為0.05mm~約2mm(參照專利文獻2[技術方案4])。專利文獻2記載此種光學片材係藉由擠出鑄造方法而製造(參照專利文獻2[0034]~[0039]、[圖8A])。專利文獻2例示聚碳酸酯、PMMA(Polymethylmethacrylate,聚甲基丙烯酸甲酯)及聚烯烴系聚合物作為熔融之樹脂(參照專利文獻2[0041])。 Patent Document 2 describes an optical sheet having a thin double-sided light guide plate and a method of manufacturing the same. Patent Document 2 describes an optical sheet in which a plurality of light guide plates are provided, and a first resin is extruded in a nip between a first pressure roller and a first pattern forming roller to form a surface having a pattern not formed. a first layer on the surface formed by the pattern; a nip between the second layer forming roller and the second pressure roller; and a nip between the second pressure roller and the second pattern forming roller The second layer is extruded on the surface on which the pattern of the first layer is not formed, and the second layer having the patterned surface is formed, and the first layer and the second layer which are integrated include a plurality of light guide plate patterns (refer to Patent Document 2 [ Technical solution 1]). Patent Document 2 describes that the thickness of the optical sheet is from 0.05 mm to about 2 mm (see Patent Document 2 [Technical Solution 4]). Patent Document 2 discloses that such an optical sheet is produced by an extrusion casting method (see Patent Documents 2 [0034] to [0039] and [Fig. 8A]. Patent Document 2 discloses polycarbonate, PMMA (Polymethylmethacrylate), and a polyolefin-based polymer as a molten resin (see Patent Document 2 [0041]).

先前技術文獻 Prior technical literature 專利文獻 Patent literature

專利文獻1:日本專利特開2015-69849號公報 Patent Document 1: Japanese Patent Laid-Open No. 2015-69849

專利文獻2:日本專利特開2012-68633號公報 Patent Document 2: Japanese Patent Laid-Open Publication No. 2012-68633

專利文獻1及2均記載藉由擠出成形製造更薄之導光板之方法,但關於所形成之圖案之形狀之正確性等圖案的形狀賦予性(轉印性)未進行任何揭示。 In Patent Documents 1 and 2, a method of producing a thinner light guide plate by extrusion molding is described. However, the shape impartability (transferability) of a pattern such as the shape of the formed pattern is not disclosed.

進而,專利文獻1及2例示使用樹脂,但若將厚度變薄為本案之聚碳酸酯導光板程度之厚度,則例如丙烯酸系樹脂柔軟易破損,故而實質上無法於現實中使用。若使用丙烯酸系樹脂製造厚度較薄之導光板,則為了實際上使用,因強度之問題必須與其他基材組合。因此,實際上於實施例中,具體之使用樹脂之製造方法未揭示,專利文獻1及2並非揭示使用該等例示之材料而實際上能夠使用之厚度較薄之導光板之製造方法的發明。 Further, Patent Documents 1 and 2 exemplify the use of a resin. However, if the thickness is reduced to the thickness of the polycarbonate light guide plate of the present invention, for example, the acrylic resin is soft and easily broken, and thus it is practically impossible to use it. When a light-guide plate having a small thickness is produced using an acrylic resin, it is necessary to combine with other substrates for the purpose of strength in order to be practically used. Therefore, in actuality, in the examples, the specific method of producing the resin is not disclosed, and Patent Documents 1 and 2 do not disclose the invention of the method for producing a light guide plate which can be practically used by using the materials exemplified.

若考慮厚度較薄之導光板之實際之使用,則使用更高強度之樹脂而製造,就導光板之強度更高及更易操作之方面而言,認為較佳,但實際上使用此種樹脂正確地賦予點圖案等形狀之形狀賦予率(轉印率)較高之導光板之製造方法尚未報告。 Considering the practical use of a thinner light guide plate, it is made of a resin of higher strength, which is considered to be better in terms of higher strength and easier operation of the light guide plate, but actually uses such a resin correctly. A method of manufacturing a light guide plate having a shape imparting rate (transfer rate) having a shape such as a dot pattern has not been reported.

於形狀賦予性不充分,無法於導光板之表面正確充分地形成所需之形狀之情形時,亦產生導光板之亮度不足之問題。 When the shape imparting property is insufficient and the desired shape cannot be formed properly on the surface of the light guide plate, the problem of insufficient brightness of the light guide plate is also caused.

而且,近年來要求使具體600μm以下之厚度較薄之導光板穩定且以更低價格進行製造。若如上所述使用丙烯酸系樹脂等,則亦存在若厚度變薄(更具體而言成為600μm以下)則強度不足之問題。 Further, in recent years, it has been required to stabilize a light guide plate having a thickness of 600 μm or less and to manufacture it at a lower price. When an acrylic resin or the like is used as described above, there is a problem that the strength is insufficient if the thickness is reduced (more specifically, 600 μm or less).

本發明者等人反覆銳意研究,結果發現:以下聚碳酸酯導光板之製造方法能夠以更低價格製造可正確地賦予點圖案等形狀,厚度雖薄但強度較高,易操作,能夠於現實中使用之導光板,該聚碳酸酯導光板之製造方法包括:使用具有自立性之聚碳酸酯這一特定之熱塑性樹脂,獲得熔融狀態之片狀聚碳酸酯,片狀聚碳酸酯與可撓性支持體這一特定之支持體一同壓抵於在表面形成有圖案之輥;片狀聚碳酸酯支持於可撓性支持體,且於形成有圖案之輥上移行並固化,其後固化後之片狀聚碳酸酯與可撓性支持體分離;從而完成本發明。 As a result of intensive research, the inventors of the present invention found that the following method for producing a polycarbonate light guide plate can be manufactured at a lower price and can accurately impart a shape such as a dot pattern. The thickness is thin but the strength is high, and it is easy to handle and can be realistic. The light guide plate used in the method of manufacturing the polycarbonate light guide plate comprises: using a specific thermoplastic resin having a self-standing polycarbonate to obtain a sheet-like polycarbonate in a molten state, a sheet-like polycarbonate and a flexible The specific support of the sexual support is pressed together with a roller having a pattern formed on the surface; the sheet polycarbonate is supported on the flexible support, and is moved and cured on the patterned roll, and then cured The sheet-like polycarbonate is separated from the flexible support; thus completing the present invention.

即,本發明提供一種聚碳酸酯導光板之製造方法,其包括以下 步驟:對聚碳酸酯進行加熱熔融,自模頭擠出而獲得片狀聚碳酸酯;支持可撓性支持體之第1輥與於表面具有預先形成之圖案之第2輥平行配置,可撓性支持體係以通過第1輥與第2輥之間,且捲繞於第2輥之圓周方向之至少一部分之方式配置,第1輥及第2輥係以於可撓性支持體與第2輥之間夾著片狀聚碳酸酯一面使可撓性支持體伴行於片狀聚碳酸酯,一面進行加壓之方式旋轉,將片狀聚碳酸酯壓抵於第2輥;壓抵於第2輥之片狀聚碳酸酯藉由可撓性支持體支持(保壓)於第2輥之表面,並向第2輥之旋轉方向移行,以第1輥與第2輥之表面最接近之位置為基準,片狀聚碳酸酯與可撓性支持體於第2輥之旋轉角度為45~150°之位置分離;及第3輥與第2輥平行,且配置於第1輥之相反側,片狀聚碳酸酯通過第2輥與第3輥之間,且於第3輥之圓周方向之至少一部分被支持,第3輥係以受取片狀聚碳酸酯之方式旋轉。 That is, the present invention provides a method of manufacturing a polycarbonate light guide plate, which includes the following Step: heating and melting the polycarbonate, extruding from the die to obtain a sheet-like polycarbonate; the first roll supporting the flexible support is disposed in parallel with the second roll having a pattern formed on the surface, and is flexible The sexual support system is disposed between the first roller and the second roller and wound around at least a part of the circumferential direction of the second roller, and the first roller and the second roller are used for the flexible support and the second roller. The sheet-like polycarbonate is interposed between the rolls, and the flexible support is accompanied by the sheet-like polycarbonate, and is rotated while being pressed, and the sheet-like polycarbonate is pressed against the second roll; The sheet-like polycarbonate of the second roll is supported (holds) on the surface of the second roll by the flexible support, and travels in the direction of rotation of the second roll, and is closest to the surface of the first roll and the second roll. Based on the position, the sheet-like polycarbonate and the flexible support are separated at a position where the rotation angle of the second roller is 45 to 150°; and the third roller is parallel to the second roller and disposed opposite to the first roller. On the side, the sheet-like polycarbonate passes between the second roll and the third roll, and is supported at least in part in the circumferential direction of the third roll, and the third roll system Rotating manner by taking a sheet of polycarbonate.

本發明於一態樣中,提供一種導光板之製造方法,其中第1輥之表面具有彈性。 In one aspect of the invention, a method of manufacturing a light guide plate is provided, wherein a surface of the first roller has elasticity.

本發明於另一態樣中,提供一種導光板之製造方法,其中(i)與片狀聚碳酸酯相接之可撓性片材之表面為鏡面(經鏡面處理),且於片狀聚碳酸酯之單面形成有圖案,或(ii)於與片狀聚碳酸酯相接之可撓性片材之表面預先形成有圖案形狀,而於片狀聚碳酸酯之兩面形成有圖案。 In another aspect, the present invention provides a method of manufacturing a light guide plate, wherein (i) the surface of the flexible sheet that is in contact with the sheet-like polycarbonate is mirror-finished (mirror-treated), and is in the form of a sheet. The surface of the carbonate is formed with a pattern, or (ii) the surface of the flexible sheet which is in contact with the sheet-like polycarbonate is formed in a pattern shape in advance, and a pattern is formed on both surfaces of the sheet-like polycarbonate.

本發明於另一主旨中,提供一種聚碳酸酯導光板,其係藉由上述製造方法而製造,且於單面或兩面形成有圖案。 In another aspect, the present invention provides a polycarbonate light guide plate which is produced by the above-described manufacturing method and which has a pattern formed on one side or both sides.

本發明於較佳之主旨中,提供一種顯示裝置,其具有藉由上述 製造方法製造之聚碳酸酯導光板。 In a preferred aspect, the present invention provides a display device having the above A polycarbonate light guide plate manufactured by a manufacturing method.

本發明於又一主旨中,提供一種聚碳酸酯導光板,其係由MVR(Melt Volume Rate,熔體體積流率:300℃,1.2kg)為10~90,重量平均分子量(Mw)為16000~27000之聚碳酸酯製成,且具有100~600μm之厚度。 In another aspect, the present invention provides a polycarbonate light guide plate having a MVR (Melt Volume Rate, melt volume flow rate: 300 ° C, 1.2 kg) of 10 to 90, and a weight average molecular weight (Mw) of 16,000. ~27000 polycarbonate, and has a thickness of 100 ~ 600μm.

本發明於更佳之主旨中,提供一種顯示裝置,其具有上述聚碳酸酯導光板。 In a further preferred aspect of the invention, there is provided a display device having the above-described polycarbonate light guide plate.

本發明之製造方法由於具有如上所述之特徵,因此能夠提高形狀形成性(提高自形成有形狀之輥向聚碳酸酯之形狀之轉印性),製造於導光板之表面形成所需之精密之形狀的聚碳酸酯導光板。藉此,能夠以更低價格製造強度更高,更易操作,更高亮度之導光板,能夠製造更高亮度之背光裝置。又,由於能夠製造厚度為600μm以下之導光板,故而能夠以更低價格製造更薄型、更輕量之背光裝置。 Since the production method of the present invention has the above-described characteristics, it is possible to improve the shape formability (increasing the transfer property from the shape of the formed roll to the shape of the polycarbonate), and to manufacture the precision required for the surface of the light guide plate. The shape of the polycarbonate light guide plate. Thereby, it is possible to manufacture a light guide plate having higher strength, easier operation, and higher brightness at a lower price, and it is possible to manufacture a backlight device with higher brightness. Moreover, since the light guide plate having a thickness of 600 μm or less can be manufactured, a thinner and lighter backlight device can be manufactured at a lower price.

於第1輥之表面具有彈性之情形時,能夠進一步提高形狀形成性(轉印率),製造更高亮度之轉印板。 When the surface of the first roll is elastic, the shape formability (transfer rate) can be further improved, and a transfer plate having higher brightness can be produced.

於可撓性片材之表面為鏡面之情形時,能夠製造於單面形成有圖案之導光板,於可撓性片材之表面進行圖案形成之情形時,能夠製造於兩面形成有圖案之導光板。 When the surface of the flexible sheet is a mirror surface, it is possible to manufacture a light guide plate having a pattern formed on one side, and when patterning is formed on the surface of the flexible sheet, it is possible to manufacture a pattern guide formed on both sides. Light board.

由MVR(熔體體積流率:300℃,1.2kg)為10~90,重量平均分子量(Mw)為16000~27000之聚碳酸酯製成之聚碳酸酯導光板可為強度較高,更易操作,更高亮度之導光板,進而由於厚度為100~600μm,故而可為更薄型、更輕量之背光裝置。 Polycarbonate light guide plate made of polycarbonate with MVR (melt volume flow rate: 300 ° C, 1.2 kg) of 10 to 90 and weight average molecular weight (Mw) of 16000 to 27000 can be higher in strength and easier to handle. The light guide plate with higher brightness, and furthermore, has a thickness of 100 to 600 μm, so that it can be a thinner and lighter backlight device.

10‧‧‧第1輥 10‧‧‧1st roll

20‧‧‧第2輥 20‧‧‧2nd roller

30‧‧‧第3輥 30‧‧‧3rd roller

40‧‧‧可撓性支持體 40‧‧‧Flexible support

50‧‧‧可撓性支持體捲出輥 50‧‧‧Flexible support roll-up roll

52‧‧‧輥 52‧‧‧roll

54‧‧‧輥 54‧‧‧roll

56‧‧‧可撓性支持體捲入輥 56‧‧‧Flexible support roll-in roller

60‧‧‧T型模頭 60‧‧‧T-die

70‧‧‧熔融狀態片狀聚碳酸酯 70‧‧‧Metal state sheet polycarbonate

72‧‧‧固化狀態片狀聚碳酸酯 72‧‧‧Cured state sheet polycarbonate

w‧‧‧寬度 w‧‧‧Width

h‧‧‧高度 H‧‧‧height

θ‧‧‧旋轉角度 θ‧‧‧Rotation angle

圖1模式性地表示本發明之形態之聚碳酸酯導光板之製造方法。 Fig. 1 schematically shows a method of producing a polycarbonate light guide plate according to a mode of the present invention.

圖2模式性地表示形成於導光板之點圖案。 Fig. 2 schematically shows a dot pattern formed on a light guide plate.

圖3模式性地表示三角柱以使側面與導光板之平面相接之方式配置之形成於導光板之槽狀或線狀圖案。 Fig. 3 schematically shows a triangular or linear pattern formed on the light guide plate by arranging the triangular prisms so that the side faces are in contact with the plane of the light guide plate.

以下,一面參照隨附圖式,一面對本發明之實施形態進行詳細說明。但是,沒有必要時有省略詳細說明之情況。例如,有將已經清楚知道之事項之詳細說明或對實質上相同之構成之重複說明省略之情況。其原因在於:避免以下之說明不必要地變得冗餘,使業者更容易理解。 Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, it is not necessary to omit the detailed description. For example, a detailed description of a matter that has been clearly known or a description of a repetitive description of substantially the same components will be omitted. The reason for this is that the following description is avoided to unnecessarily become redundant, making it easier for the operator to understand.

再者,以下之說明係為了業者充分地理解本發明而提供,因此,不應解釋為藉由該等說明意欲限定申請專利範圍中記載之主題。 In addition, the following description is provided for the purpose of fully understanding the invention, and therefore is not to be construed as limiting the scope of the claims.

本發明之形態之發明提供一種聚碳酸酯導光板之製造方法。 The invention of the aspect of the invention provides a method of producing a polycarbonate light guide plate.

於本說明書中,所謂「導光板」係指使自側面進入之光擴散,並自表面出射光之一般作為導光板而瞭解者。 In the present specification, the term "light guide plate" refers to a light guide plate that diffuses light entering from the side and generally emits light from the surface.

導光板通常例如於智慧型手機、行動電話、移動終端、攜帶型資訊終端(PDA)、平板型個人電腦(PC)、筆記型PC、車載用儀錶板、PC用顯示監控器等之液晶顯示面板之背光裝置;及例如於智慧型手機、行動電話、移動終端、攜帶型資訊終端(PDA)、平板型個人電腦(PC)、筆記型PC等之鍵盤之背光裝置等之照明裝置內部使用。 The light guide plate is usually, for example, a liquid crystal display panel such as a smart phone, a mobile phone, a mobile terminal, a portable information terminal (PDA), a tablet type personal computer (PC), a notebook PC, a vehicle instrument panel, a PC display monitor, or the like. The backlight device is used internally, for example, in a lighting device such as a smart phone, a mobile phone, a mobile terminal, a portable information terminal (PDA), a tablet type personal computer (PC), a notebook PC, or the like.

所謂本發明之形態之「聚碳酸酯導光板」係使用聚碳酸酯而製造之導光板。 The "polycarbonate light guide plate" of the embodiment of the present invention is a light guide plate manufactured using polycarbonate.

本發明之形態之「聚碳酸酯導光板」係使用透明且具有自立性之聚碳酸酯(碳酸酯系樹脂)作為熱塑性樹脂而製造。聚碳酸酯通常只要能夠作為聚碳酸酯使用而獲得本發明作為目的之聚碳酸酯導光板,則並無特別限制,可適當含有添加劑等。 The "polycarbonate light guide plate" according to the embodiment of the present invention is produced by using a transparent and self-standing polycarbonate (carbonate resin) as a thermoplastic resin. The polycarbonate is not particularly limited as long as it can be used as a polycarbonate to obtain the polycarbonate light guide plate of the present invention, and an additive or the like can be appropriately contained.

聚碳酸酯之MVR(熔體體積流率:300℃,1.2kg)較佳為10~90,更佳為15~60。聚碳酸酯之MVR係藉由JIS K7210而測定。 The MVR (melt volume flow rate: 300 ° C, 1.2 kg) of the polycarbonate is preferably from 10 to 90, more preferably from 15 to 60. The MVR of polycarbonate was measured by JIS K7210.

聚碳酸酯之重量平均分子量(Mw)較佳為16000~28000,更佳為18000~25200。 The weight average molecular weight (Mw) of the polycarbonate is preferably from 16,000 to 28,000, more preferably from 18,000 to 25,200.

聚碳酸酯之重量平均分子量(Mw)係以單分散分子量聚苯乙烯換算藉由凝膠滲透層析(GPC)裝置測得之值而獲得。更具體而言,使用日本Waters公司製造之Alliance HPLC System作為GPC(Gel Permeation Chromatography,凝膠滲透層析)裝置,利用UV(ultraviolet,紫外線)檢測器測定層析圖。使用安捷倫科技公司製造之PLgel 5μm Mixed-C作為層析管。使試樣溶解於四氫呋喃,以1ml/min之流速,於40℃之管柱溫度下流動。以單分散分子量聚苯乙烯之校準曲線換算測定值而獲得Mw。 The weight average molecular weight (Mw) of the polycarbonate is obtained by a value measured by a gel permeation chromatography (GPC) apparatus in terms of monodisperse molecular weight polystyrene. More specifically, an Allied HPLC system manufactured by Waters Corporation of Japan was used as a GPC (Gel Permeation Chromatography) apparatus, and a chromatogram was measured using a UV (ultraviolet) detector. PLgel 5 μm Mixed-C manufactured by Agilent Technologies was used as a chromatography tube. The sample was dissolved in tetrahydrofuran and flowed at a column temperature of 40 ° C at a flow rate of 1 ml/min. Mw was obtained by converting the measured value into a calibration curve of monodisperse molecular weight polystyrene.

關於本發明之形態之聚碳酸酯導光板之製造方法,首先,對聚碳酸酯進行加熱熔融,自模頭擠出而獲得熔融狀態之片狀聚碳酸酯。 In the method for producing a polycarbonate light guide plate according to the aspect of the invention, first, the polycarbonate is heated and melted, and extruded from a die to obtain a sheet-like polycarbonate in a molten state.

自模頭擠出之聚碳酸酯之溫度較佳為230~290℃,更佳為240~280℃,尤佳為250~270℃。於自模頭擠出之聚碳酸酯之溫度為230~290℃之情形時,流動性較高,進一步提高轉印率,故而較佳。 The temperature of the polycarbonate extruded from the die is preferably from 230 to 290 ° C, more preferably from 240 to 280 ° C, and particularly preferably from 250 to 270 ° C. When the temperature of the polycarbonate extruded from the die is 230 to 290 ° C, the fluidity is high and the transfer rate is further improved, so that it is preferable.

模頭只要能夠製造本發明作為目的之導光板,則並無特別限制,可例示T型模頭。 The die is not particularly limited as long as it can produce the light guide plate of the present invention, and a T-die can be exemplified.

其次,準備支持可撓性支持體之第1輥及於表面具有預先形成之圖案之第2輥,且以第1輥與第2輥之中心軸彼此成為平行之方式配置。以通過第1輥與第2輥之間,捲繞於第2輥之圓周方向之至少一部分之方式配置可撓性支持體。 Next, the first roll supporting the flexible support and the second roll having a pattern formed in advance on the surface are prepared, and the center axes of the first roll and the second roll are arranged in parallel with each other. The flexible support is placed so as to be wound between at least a part of the circumferential direction of the second roll between the first roll and the second roll.

第1輥及第2輥進行旋轉,並且於可撓性支持體與第2輥之間夾著熔融狀態之片狀聚碳酸酯且使可撓性支持體伴行於片狀聚碳酸酯,而將熔融狀態之片狀聚碳酸酯壓抵於第2輥。 The first roll and the second roll are rotated, and a sheet-like polycarbonate in a molten state is interposed between the flexible support and the second roll, and the flexible support is accompanied by the sheet-like polycarbonate. The sheet-like polycarbonate in a molten state was pressed against the second roll.

藉由壓抵於第2輥,將形成於第2輥之表面之形狀轉印,於熔融 狀態之片狀聚碳酸酯之單面形成圖案。 By pressing against the second roller, the shape formed on the surface of the second roller is transferred and melted The single side of the sheet-like polycarbonate in the state is patterned.

若使用於與片狀聚碳酸酯相接之面形成有圖案之可撓性支持體,則進而將形成於可撓性支持體之表面之形狀轉印,於熔融狀態之片狀聚碳酸酯之兩面形成圖案。圖案之形狀可兩面相同,亦可不同。 When a flexible support having a pattern formed on the surface in contact with the sheet-like polycarbonate is used, the shape formed on the surface of the flexible support is further transferred to the sheet-like polycarbonate in a molten state. The two sides form a pattern. The shape of the pattern can be the same on both sides or different.

因此,亦提供一種圖案導光板之製造方法,其中(i)與片狀聚碳酸酯相接之可撓性片材之表面為鏡面(或經鏡面處理),且於片狀聚碳酸酯之單面形成有圖案,或(ii)於與片狀聚碳酸酯相接之可撓性片材之表面預先形成有圖案形狀,而於片狀聚碳酸酯之兩面形成有圖案。 Therefore, a method of manufacturing a patterned light guide plate is also provided, wherein (i) the surface of the flexible sheet which is in contact with the sheet-like polycarbonate is mirror-finished (or mirror-finished), and is in the form of a sheet-like polycarbonate. The surface is formed with a pattern, or (ii) the surface of the flexible sheet which is in contact with the sheet-like polycarbonate is formed in a pattern shape in advance, and a pattern is formed on both surfaces of the sheet-like polycarbonate.

進而,壓抵於第2輥之片狀聚碳酸酯藉由可撓性支持體支持並保壓(或為了不使壓力下降,而保持壓力)於第2輥之表面,並向第2輥之旋轉方向移行,使熔融狀態之片狀聚碳酸酯冷卻較佳為固化,片狀聚碳酸酯與可撓性支持體以第1輥與第2輥之表面最接近之位置為基準,於第2輥之旋轉方向為45~150°之旋轉角度之位置分離。 Further, the sheet-like polycarbonate pressed against the second roll is supported by the flexible support and held (or kept in pressure so as not to lower the pressure) on the surface of the second roll, and is applied to the second roll. In the direction of rotation, the sheet-like polycarbonate in a molten state is preferably cooled, and the sheet-like polycarbonate and the flexible support are based on the position closest to the surfaces of the first roll and the second roll. The rotation direction of the roller is separated by a rotation angle of 45 to 150°.

以第1輥與第2輥之表面最接近之位置為基準,固化後之片狀聚碳酸酯與可撓性支持體分離之位置之第2輥的旋轉角度較佳為45~150°,更佳為50~135°,尤佳為60~120°。 The rotation angle of the second roller at a position where the cured sheet-like polycarbonate and the flexible support are separated is preferably 45 to 150°, based on the position closest to the surface of the first roller and the second roller. Good for 50~135°, especially for 60~120°.

以第1輥與第2輥之表面最接近之位置為基準,固化後之片狀聚碳酸酯與可撓性支持體分離之位置之第2輥的旋轉角度為45~150°,由於帶來形狀之更正確之轉印而使轉印性進一步提高,更容易地進行可撓性片材與片狀聚碳酸酯之剝離,故而較佳。 Based on the position closest to the surface of the first roller and the second roller, the rotation angle of the second roller at the position where the cured sheet-like polycarbonate and the flexible support are separated is 45 to 150°, The transfer of the shape is further improved, the transfer property is further improved, and the peeling of the flexible sheet and the sheet-like polycarbonate is more easily performed, which is preferable.

第1輥之溫度較佳為5~40℃,更佳為5~35℃,尤佳為10~30℃。 The temperature of the first roll is preferably 5 to 40 ° C, more preferably 5 to 35 ° C, and particularly preferably 10 to 30 ° C.

第2輥之溫度較佳為110~180℃,更佳為120~170℃,尤佳為130~160℃。 The temperature of the second roll is preferably from 110 to 180 ° C, more preferably from 120 to 170 ° C, and particularly preferably from 130 to 160 ° C.

於第1輥之溫度為5~40℃,第2輥之溫度為110~180℃之情形 時,由於帶來形狀之更正確之轉印而使轉印性進一步提高,更容易地進行可撓性片材與片狀聚碳酸酯之剝離,故而較佳。 The temperature of the first roller is 5 to 40 ° C, and the temperature of the second roller is 110 to 180 ° C. In this case, the transfer property is further improved by the transfer of the shape which is more accurate, and the peeling of the flexible sheet and the sheet-like polycarbonate is more easily performed, which is preferable.

第1輥及第2輥之周圍之溫度較佳為所謂之室溫(5~35℃)。 The temperature around the first roll and the second roll is preferably a so-called room temperature (5 to 35 ° C).

針對自片狀聚碳酸酯分離之可撓性支持體僅適當地操作,關於該操作,並無特別限定。例如有藉由捲取機捲取之方法、以再次返回第1輥並導入至第1輥與第2輥之間之方式返回之方法等。於使用樹脂膜作為可撓性支持體之情形時,較佳為使用藉由捲取機捲取可撓性支持體之方法。 The flexible support separated from the sheet-like polycarbonate is only appropriately operated, and the operation is not particularly limited. For example, there is a method of winding back by a coiler, returning to the first roll, and introducing it to the first roll and the second roll, and the like. In the case where a resin film is used as the flexible support, a method of winding up the flexible support by a winder is preferably used.

進而,較佳為使第3輥與第2輥平行(第3輥與第2輥之中心軸彼此平行)且配置於第1輥之相反側。 Further, it is preferable that the third roller is parallel to the second roller (the center axes of the third roller and the second roller are parallel to each other) and disposed on the opposite side of the first roller.

並且,形成有形狀之片狀聚碳酸酯通過第2輥與第3輥之間,於第3輥之圓周方向之至少一部分被支持,第3輥係以受取片狀聚碳酸酯之方式旋轉。 Further, the formed sheet-like polycarbonate is supported between the second roll and the third roll in at least a part of the circumferential direction of the third roll, and the third roll is rotated by receiving the sheet-like polycarbonate.

較佳為無須於第3輥與第2輥之間對片狀聚碳酸酯進行加壓(進行挾持),第3輥與第2輥之間隔拉開。該間隔只要能夠使第3輥於其至少一部分支持片狀聚碳酸酯,並能夠受取,則並無特別限制。 It is preferable that the sheet-like polycarbonate is not pressed (clamped) between the third roll and the second roll, and the interval between the third roll and the second roll is pulled apart. The interval is not particularly limited as long as the third roller can support at least a part of the sheet-like polycarbonate and can be taken.

本發明之形態之「可撓性支持體」只要具有可撓性,具有片狀之形態,能夠將片狀聚碳酸酯支持於第2輥,能夠製造本發明作為目的之聚碳酸酯導光板,則並無特別限定。 The "flexible support" according to the embodiment of the present invention has a sheet form, and can support the sheet-like polycarbonate on the second roll, and the polycarbonate light guide plate of the present invention can be produced. There is no particular limitation.

作為可撓性支持體,例如可使用,聚酯系樹脂膜、丙烯酸系樹脂膜、聚碳酸酯系樹脂膜等樹脂膜;不鏽鋼系金屬薄板、鎳系金屬薄板、表面鎳系鍍金處理銅系金屬薄板、表面鉻系鍍金處理銅系金屬薄板等金屬薄板。 For the flexible support, for example, a resin film such as a polyester resin film, an acrylic resin film, or a polycarbonate resin film; a stainless steel metal plate, a nickel metal plate, or a surface nickel-based gold-plated copper-based metal can be used. Metal sheets such as thin plates and surface chromium-plated gold-plated metal sheets.

可撓性支持體較佳使用樹脂膜,更佳使用聚酯系樹脂膜。 A resin film is preferably used for the flexible support, and a polyester resin film is more preferably used.

可撓性支持體能夠於其一面預先形成形狀。若使用此種可撓性支持體,則能夠製造於兩面形成有形狀之導光板。只要能夠製造本發 明之形態之於兩面形成有形狀之導光板,則於一面預先形成有形狀之可撓性支持體並無特別限制。 The flexible support can be pre-formed on one side thereof. When such a flexible support is used, it is possible to manufacture a light guide plate having a shape formed on both sides. As long as it can make this hair In the case of a light guide plate having a shape formed on both sides, a flexible support body having a shape formed on one side is not particularly limited.

作為於一面預先形成有形狀之可撓性支持體,例如可例示於上述可撓性支持體之一面形成有形狀之支持體。作為此種形成有形狀之可撓性支持體,例如可列示:使用丙烯酸系光硬化樹脂等光硬化性樹脂於聚酯系樹脂膜、丙烯酸系樹脂膜、聚碳酸酯系樹脂膜等樹脂膜之表面形成形狀之樹脂膜;利用雷射加工法、鍍金法、切削加工法、蝕刻法等方法於不鏽鋼系金屬薄板、鎳系金屬薄板、銅系金屬薄板等金屬薄板之表面形成形狀之金屬薄板。 The flexible support body having a shape formed in advance may be, for example, a support having a shape formed on one surface of the flexible support. For example, a photocurable resin such as an acrylic photocurable resin can be used as the resin film such as a polyester resin film, an acrylic resin film or a polycarbonate resin film. a resin film having a shape formed on the surface thereof; a metal sheet having a shape formed on a surface of a metal thin plate such as a stainless steel-based metal sheet, a nickel-based metal sheet, or a copper-based metal sheet by a laser processing method, a gold plating method, a cutting method, or an etching method .

作為於一面預先形成有形狀之可撓性支持體,較佳為使用光硬化性樹脂形成形狀之樹脂膜,更佳為於聚酯系樹脂膜之表面使用丙烯酸系光硬化樹脂形成形狀之樹脂膜。 The flexible support having a shape formed in advance is preferably a resin film formed into a shape using a photocurable resin, and more preferably a resin film having a shape formed by using an acrylic photocurable resin on the surface of the polyester resin film. .

本發明之形態之第1輥、第2輥及第3輥通常為樹脂之擠出成形中所使用之輥,只要能夠製造本發明之導光板,則並無特別限制。 The first roll, the second roll, and the third roll in the form of the present invention are generally used for the extrusion molding of a resin, and are not particularly limited as long as the light guide plate of the present invention can be produced.

進而,第1輥~第3輥係由任一金屬製成,表面亦可為金屬,亦可為其他材料。第1輥之表面一般較佳為鏡面(或經鏡面處理)。第2輥之表面形成有形狀。第3輥之表面一般較佳為鏡面。 Further, the first to third rolls are made of any metal, and the surface may be metal or other materials. The surface of the first roll is generally preferably mirrored (or mirror finished). The surface of the second roller is formed into a shape. The surface of the third roller is generally preferably a mirror surface.

第1輥~第3輥之配置並無特別限定,有水平配置、垂直配置等,較佳為水平配置。 The arrangement of the first to third rolls is not particularly limited, and may be horizontal or vertical, and is preferably horizontal.

本發明之形態之第1輥較佳為其表面具有彈性。 The first roll of the embodiment of the present invention preferably has elasticity on its surface.

關於第1輥之彈性,JIS K6253中規定之硬度計硬度按照A型硬度計之測定值較佳為40~85,更佳為50~85,尤佳為60~80。 Regarding the elasticity of the first roll, the hardness of the durometer specified in JIS K6253 is preferably 40 to 85, more preferably 50 to 85, and particularly preferably 60 to 80, in accordance with the hardness of the type A durometer.

於第1輥之表面具有彈性之情形時,由於帶來形狀之更正確之轉印而使轉印性提高,進而不易受到製造條件之變動,能夠吸收製造條件之變動,而更穩定地進行製造,故而較佳。 When the surface of the first roll is elastic, the transfer property is improved by the transfer of the shape of the first roll, and the change in the manufacturing conditions is less likely to occur, and the change in the manufacturing conditions can be absorbed, and the manufacturing can be performed more stably. Therefore, it is better.

為了對第1輥之表面提供彈性,可由彈性體覆蓋其表面。只要為 於支持於第1輥之可撓性片材與第2輥之間夾著自T型模頭擠出之熔融之聚碳酸酯,並進行加壓時,發生彈性變形之彈性體,則並無特別限定。第1輥之表面較佳為由選自矽系彈性樹脂、丁腈橡膠系彈性樹脂等中之至少1種彈性體而覆蓋,更佳為選自矽系彈性樹脂中之至少1種而覆蓋。 In order to provide elasticity to the surface of the first roller, the surface thereof may be covered by an elastomer. Just for When the flexible sheet extruded from the T-die is sandwiched between the flexible sheet supported by the first roll and the second roll, and the elastic body is elastically deformed when pressurized, there is no Specially limited. The surface of the first roll is preferably covered with at least one type of elastomer selected from the group consisting of a lanthanum-based elastic resin and a nitrile rubber-based elastic resin, and more preferably at least one selected from the group consisting of lanthanum-based elastic resins.

本發明之形態之第2輥如上所述,於其表面形成有轉印至導光板之形狀。第2輥中所形成之形狀只要為用於導光板之圖案,則並無特別限制,例如較佳為點圖案、微透鏡圖案等。 As described above, the second roller of the embodiment of the present invention has a shape transferred to the surface of the light guide plate. The shape formed in the second roller is not particularly limited as long as it is a pattern for the light guide plate. For example, a dot pattern, a microlens pattern, or the like is preferable.

本發明之形態之聚碳酸酯導光板之厚度較佳為100~600μm,更佳為125~400μm,尤佳為150~300μm。 The thickness of the polycarbonate light guide plate of the embodiment of the present invention is preferably from 100 to 600 μm, more preferably from 125 to 400 μm, still more preferably from 150 to 300 μm.

於聚碳酸酯導光板之厚度為100~600μm之情形時,更薄,更輕量,並且能夠維持其強度,能夠實際使用而較佳。 When the thickness of the polycarbonate light guide plate is 100 to 600 μm, it is thinner, lighter, and capable of maintaining its strength, and can be practically used.

再者,聚碳酸酯導光板之厚度係指不含圖案形成部分之厚度之部分。 Further, the thickness of the polycarbonate light guide plate means a portion which does not have the thickness of the pattern forming portion.

圖案可具有以未形成圖案之導光板之部分為基準呈凸狀與凹狀之2種,較佳為凸起之形狀。 The pattern may have two types of convex and concave shapes based on a portion of the unpatterned light guide plate, and preferably has a convex shape.

例如,於圖2中,模式性地示出於導光板形成之點圖案。 For example, in FIG. 2, a dot pattern formed on a light guide plate is schematically illustrated.

進而,於圖3中,模式性地示出三角柱以使其側面與導光板之平面相接之方式配置之形成於導光板之線狀或槽狀的圖案。 Further, in FIG. 3, a pattern in which a triangular prism is formed so as to be in contact with the plane of the light guide plate so as to be formed in a linear or groove shape of the light guide plate is schematically illustrated.

關於與未形成圖案之導光板之部分相接之圖案的面,將該面之最寬之部分之尺寸稱為該圖案之「寬度(w)」。 Regarding the surface of the pattern that is in contact with the portion of the unpatterned light guide plate, the dimension of the widest portion of the surface is referred to as the "width (w)" of the pattern.

關於與未形成圖案之導光板之部分相接之圖案的面,將自該面垂直方向之最高之部分之尺寸稱為該圖案之「高度(h)」。 Regarding the surface of the pattern that is in contact with the portion of the unpatterned light guide plate, the dimension of the highest portion from the vertical direction of the surface is referred to as the "height (h)" of the pattern.

關於圖案之形狀,最大之尺寸一般為100μm以下,較佳為50μm以下,其他尺寸為其10%以上。 Regarding the shape of the pattern, the largest dimension is generally 100 μm or less, preferably 50 μm or less, and the other dimensions are 10% or more.

但是,於圖案為槽狀或線狀等之一個方向之部分與其他方向之 部分相比具有極長之尺寸之形狀的情形時(下述三角柱以使其側面與導光板之平面相接之方式配置之圖案的情形),不考慮該槽方向或線方向之部分之尺寸。將與該槽方向或線方向垂直之方向且與片狀聚碳酸酯之平面平行之方向之部分的尺寸稱為「寬度(w)」。將與該槽方向或線方向垂直之方向且與片狀聚碳酸酯之平面垂直之方向之部分的尺寸稱為「高度(h)」。於該「寬度」與「高度」之中,最大之尺寸一般為100μm以下,較佳為50μm以下。 However, in a direction in which the pattern is grooved or linear, and other directions In the case of a portion having a shape having an extremely long dimension (in the case where the triangular prism is arranged such that its side faces are in contact with the plane of the light guide plate), the size of the portion in the groove direction or the line direction is not considered. The size of a portion in a direction perpendicular to the groove direction or the line direction and parallel to the plane of the sheet-like polycarbonate is referred to as "width (w)". The size of a portion perpendicular to the groove direction or the line direction and perpendicular to the plane of the sheet-like polycarbonate is referred to as "height (h)". Among the "width" and "height", the largest dimension is generally 100 μm or less, preferably 50 μm or less.

關於本發明之形態之製造方法,所形成之圖案之轉印率係考慮所形成之圖案之底面之寬度之轉印率與高度之轉印率的兩者而進行研究。此處,所形成之圖案之寬度與高度如上所述。 In the manufacturing method of the aspect of the present invention, the transfer rate of the formed pattern is examined in consideration of both the transfer rate of the width of the bottom surface of the formed pattern and the transfer rate of the height. Here, the width and height of the formed pattern are as described above.

例如,若為點形狀,則大體上為半球狀,故而底面之寬度係指於圓形狀之底面之中最大的直徑,高度係指實質上最高之部分之高度。 For example, if it is a dot shape, it is substantially hemispherical, and therefore the width of the bottom surface refers to the largest diameter among the bottom surfaces of the circular shape, and the height refers to the height of the substantially highest portion.

例如,若為於與輥之表面平行方向上,三角柱以使其側面相接之方式配置之線狀或槽狀之圖案,則三角柱之側面為極細長之長方形,故而其寬度係指三角柱之側面之較短之邊的長度,高度係指三角柱之底面之自三角形之一邊至對向之頂點的高度。 For example, if the triangular prism is arranged in a line or groove pattern in such a manner as to be in contact with the surface of the roller so that the side faces are in contact with each other, the side of the triangular prism is a very elongated rectangle, and the width thereof refers to the side of the triangular prism. The length of the shorter side, the height refers to the height of the bottom surface of the triangular prism from one side of the triangle to the apex of the opposite.

若為點圖案,則點形狀之圓形之底面之直徑的轉印率較佳為90~100%,更佳為92~100%,尤佳為95~100%。點形狀之高度之轉印率較佳為80~100%,更佳為85~100%,尤佳為90~100%。以下,亦將其稱為轉印率1。 In the case of a dot pattern, the transfer rate of the diameter of the bottom surface of the dot shape is preferably from 90 to 100%, more preferably from 92 to 100%, and particularly preferably from 95 to 100%. The transfer rate of the height of the dot shape is preferably from 80 to 100%, more preferably from 85 to 100%, and particularly preferably from 90 to 100%. Hereinafter, this is also referred to as transfer rate 1.

於點形狀之圓形之底面之直徑的轉印率為90~100%,點形狀之高度之轉印率為80~100%之情形時,能夠製造更高亮度之導光板而較佳。 When the transfer rate of the diameter of the bottom surface of the circular shape of the dot shape is 90 to 100%, and the transfer rate of the height of the dot shape is 80 to 100%, it is preferable to manufacture a light guide plate having a higher brightness.

若為於與輥之表面平行方向上,以三角柱利用其側面相接之方式配置之線狀或槽狀之圖案,則三角柱之側面之較短之邊之長度的轉 印率較佳為90~100%,更佳為92~100%,尤佳為95~100%。三角柱之底面之自三角形之一邊至對向之頂點之高度的轉印率較佳為70~100%,更佳為80~100%,尤佳為90~100%。以下,亦將其稱為轉印率2。 If the pattern is linear or groove-shaped in a direction parallel to the surface of the roller and the triangular column is connected by the side surface thereof, the length of the shorter side of the side surface of the triangular prism is turned. The printing ratio is preferably from 90 to 100%, more preferably from 92 to 100%, and particularly preferably from 95 to 100%. The transfer rate of the bottom surface of the triangular prism from one side of the triangle to the height of the opposite vertex is preferably 70 to 100%, more preferably 80 to 100%, and particularly preferably 90 to 100%. Hereinafter, this is also referred to as transfer rate 2.

於三角柱之側面之較短之邊之長度的轉印率為90~100%,三角柱之底面之自三角形之一邊至對向之頂點之高度的轉印率為70~100%之情形時,能夠製造更高亮度之導光板而較佳。 The transfer rate of the length of the shorter side of the side of the triangular prism is 90 to 100%, and when the transfer rate of the bottom of the triangular column from the one side of the triangle to the height of the opposite vertex is 70 to 100%, It is preferred to manufacture a light guide plate of higher brightness.

參照隨附之圖1,對本發明之態樣之製造方法更具體且詳細地進行說明。 The manufacturing method of the aspect of the present invention will be described more specifically and in detail with reference to the accompanying Fig. 1.

圖1係模式性地表示本發明之形態之導光板之製造方法。 Fig. 1 is a view schematically showing a method of manufacturing a light guide plate according to a mode of the present invention.

第1輥10、第2輥20及第3輥30之3根輥係依該順序使該等之中心軸平行地進行配置。 The three rolls of the first roll 10, the second roll 20, and the third roll 30 are arranged in parallel with each other in this order.

可撓性支持體40自捲出輥50捲出,支持於第1輥10,通過第1輥10與第2輥20之間,支持於第2輥,之後離開第2輥,導入至輥52及輥54,由捲入輥56捲繞。第1輥10之表面為鏡面(或經鏡面處理)。第1輥之表面亦可具有彈性。 The flexible support 40 is wound up from the take-up roll 50, supported by the first roll 10, supported between the first roll 10 and the second roll 20, supported by the second roll, and then separated from the second roll and introduced to the roll 52. The roller 54 is wound by the winding roller 56. The surface of the first roller 10 is mirror-finished (or mirror-finished). The surface of the first roller may also have elasticity.

第2輥20於其表面形成有形狀。 The second roller 20 has a shape formed on the surface thereof.

第3輥30之表面為鏡面(或經鏡面處理)。 The surface of the third roller 30 is mirror-finished (or mirror-finished).

熔融之聚碳酸酯自T型模頭60以熔融之片狀聚碳酸酯70之形態擠出。第1輥10與第2輥20進行旋轉,將片狀聚碳酸酯70夾於可撓性支持體40與第2輥20之間並與伴隨之可撓性支持體一起被加壓。片狀聚碳酸酯70壓抵於第2輥,第2輥20之形狀轉印至片狀聚碳酸酯70。 The molten polycarbonate is extruded from the T-die 60 in the form of a molten sheet of polycarbonate 70. The first roller 10 and the second roller 20 rotate, and the sheet-like polycarbonate 70 is sandwiched between the flexible support 40 and the second roller 20 and pressurized together with the accompanying flexible support. The sheet-like polycarbonate 70 is pressed against the second roll, and the shape of the second roll 20 is transferred to the sheet-like polycarbonate 70.

壓抵於第2輥20之片狀聚碳酸酯70藉由可撓性支持體40支持於第2輥20之表面,並向第2輥20之旋轉方向移行。較佳為其間片狀聚碳酸酯70固化。片狀聚碳酸酯72與可撓性支持體40以第1輥10與第2輥20之表面最接近之位置為基準,於第2輥20之旋轉方向上45~150°之旋轉 角度(θ)之位置分離。 The sheet-like polycarbonate 70 pressed against the second roller 20 is supported by the flexible support 40 on the surface of the second roller 20 and travels in the direction of rotation of the second roller 20. It is preferred that the inter-sheet polycarbonate 70 be cured. The sheet-like polycarbonate 72 and the flexible support 40 are rotated by 45 to 150° in the rotation direction of the second roller 20 with respect to the position closest to the surface of the first roller 10 and the second roller 20. The position of the angle (θ) is separated.

可撓性支持體40通過輥52及54,由捲入輥56捲繞。可撓性支持體40亦可不由捲入輥56捲繞,例如返回至捲出輥50。 The flexible support 40 is wound by the take-up rolls 56 by the rolls 52 and 54. The flexible support 40 may also not be wound by the take-up roll 56, for example, returned to the take-up roll 50.

可撓性支持體40離開之片狀聚碳酸酯72進一步於第2輥20之表面上移行,通過第2輥20與第3輥30之間,於第3輥30之圓周方向之至少一部分被支持。第3輥30係以受取片狀聚碳酸酯72之方式旋轉。片狀聚碳酸酯72能夠由另一輥(未圖示)捲取。 The sheet-like polycarbonate 72 from which the flexible support 40 is separated further moves on the surface of the second roller 20, and is passed between the second roller 20 and the third roller 30, and at least a part of the circumferential direction of the third roller 30 is stand by. The third roller 30 is rotated in such a manner as to receive the sheet-like polycarbonate 72. The sheet polycarbonate 72 can be taken up by another roller (not shown).

本發明提供一種聚碳酸酯導光板,其係藉由上述製造方法製造,且於單面或兩面形成有圖案。 The present invention provides a polycarbonate light guide plate which is produced by the above-described manufacturing method and which is formed with a pattern on one side or both sides.

進而,本發明提供一種顯示裝置,其具有藉由上述製造方法製造之聚碳酸酯導光板。 Further, the present invention provides a display device having a polycarbonate light guide plate manufactured by the above manufacturing method.

本發明提供一種聚碳酸酯導光板,其係由MVR(熔體體積流率:300℃,1.2kg)為10~90,重量平均分子量(Mw)為16000~28000之聚碳酸酯製成,且具有100~600μm之厚度。 The present invention provides a polycarbonate light guide plate made of polycarbonate having an MVR (melt volume flow rate: 300 ° C, 1.2 kg) of 10 to 90 and a weight average molecular weight (Mw) of 16,000 to 28,000, and It has a thickness of 100 to 600 μm.

本發明提供一種具有上述聚碳酸酯導光板之顯示裝置。 The present invention provides a display device having the above polycarbonate light guide plate.

本發明之形態之聚碳酸酯導光板例如於液晶顯示面板之背光裝置、及鍵盤之背光裝置等之照明裝置內部使用,本發明提供此種照明裝置。 The polycarbonate light guide plate of the embodiment of the present invention is used, for example, in a backlight device of a liquid crystal display panel and a backlight device such as a keyboard backlight device, and the present invention provides such a lighting device.

進而,此種照明裝置例如用作智慧型手機、行動電話、移動終端、攜帶型資訊終端(PDA)、平板型個人電腦(PC)、筆記型PC、車載用儀錶板、PC用顯示監控器等之顯示裝置,本發明提供此種顯示裝置。 Further, such a lighting device is used, for example, as a smart phone, a mobile phone, a mobile terminal, a portable information terminal (PDA), a tablet type personal computer (PC), a notebook PC, an in-vehicle instrument panel, a PC display monitor, and the like. The display device of the present invention provides such a display device.

[實施例] [Examples]

以下,藉由實施例及比較例對本發明更具體且詳細地進行說明,但該等實施例僅為本發明之一態樣,本發明不受該等例任何限定。 Hereinafter, the present invention will be described more specifically and in detail by way of examples and comparative examples, but these examples are only one aspect of the invention, and the invention is not limited by the examples.

再者,於實施例之記載中,只要未特別記載,則將不考慮溶劑之部分作為重量份及重量%之基準。 In addition, in the description of the examples, unless otherwise specified, the portion excluding the solvent is used as a basis for the parts by weight and % by weight.

實施例1 Example 1

使用螺桿之外徑為40mm之無縫(no vent)單軸擠出機。使用模唇之有效寬度為450mm之T型模頭作為模頭。將以下3根輥於水平以各個中心軸之方向成為平行之方式配置而用作冷卻輥單元,即彈性輥(第1輥),其寬度為500mm,外徑為300mm,且表面由矽橡膠覆蓋;金屬輥(第2輥),其係於輥之表面無規地形成外徑為50μm,深度為5μm之點形狀而配置,且寬度為500mm,外徑為300mm;金屬輥(第3輥),其表面為鏡面,且寬度為500mm,外徑為300mmThe outer diameter of the screw is 40mm Seamless (no vent) single-axis extruder. A T-die having an effective width of 450 mm of the lip was used as the die. The following three rolls are arranged horizontally in such a manner that the directions of the respective central axes are parallel and used as a cooling roll unit, that is, an elastic roll (first roll) having a width of 500 mm and an outer diameter of 300 mm. And the surface is covered with ruthenium rubber; the metal roll (second roll) is randomly formed on the surface of the roll to have an outer diameter of 50 μm and a depth of 5 μm, and has a width of 500 mm and an outer diameter of 300 mm. Metal roll (3rd roll) with a mirror surface and a width of 500mm and an outer diameter of 300mm .

使用聚碳酸酯樹脂(住化斯泰隆聚碳酸酯公司製造,重量平均分子量(Mw):21400,MVR:29)作為熱塑性透明樹脂。 As the thermoplastic transparent resin, a polycarbonate resin (manufactured by Sutheron Polycarbonate Co., Ltd., weight average molecular weight (Mw): 21,400, MVR: 29) was used.

使用如下片材作為可撓性支持體,即其係對厚度為0.125mm之聚酯膜使用丙烯酸系光硬化樹脂於表面平行地形成間距為25μm、深度為7μm之三角柱形狀而成。 The following sheet was used as a flexible support, that is, a polyester film having a thickness of 0.125 mm was formed by using an acrylic photocurable resin in the form of a triangular prism having a pitch of 25 μm and a depth of 7 μm in parallel on the surface.

將於250~270℃下熔融之聚碳酸酯自T型模頭以熔融之片狀聚碳酸酯之形態擠出。第1輥與第2輥進行旋轉,使片狀聚碳酸酯夾於可撓性支持體與第2輥之間並且與伴隨之可撓性支持體一起被夾壓,第2輥之形狀轉印至片狀聚碳酸酯。 The polycarbonate which is molten at 250 to 270 ° C is extruded from the T-die in the form of molten sheet polycarbonate. The first roller and the second roller are rotated to sandwich the sheet-like polycarbonate between the flexible support and the second roller and are pinched together with the accompanying flexible support, and the shape of the second roller is transferred. To sheet polycarbonate.

片狀聚碳酸酯藉由可撓性支持體支持於第2輥之表面,並向第2輥之旋轉方向移行,片狀聚碳酸酯固化,以第1輥與第2輥之表面最接近之位置為基準,於第2輥之旋轉角度為90°之位置,固化後之片狀聚碳酸酯與可撓性支持體分離。可撓性支持體通過輥,由捲入輥捲取。 The sheet-like polycarbonate is supported on the surface of the second roll by the flexible support and travels in the direction of rotation of the second roll, and the sheet-like polycarbonate is solidified so as to be closest to the surface of the first roll and the second roll. The position is based on the position where the rotation angle of the second roll is 90°, and the cured sheet-like polycarbonate is separated from the flexible support. The flexible support is taken up by a take-up roll through a roller.

第1輥之溫度為10~30℃,第2輥之溫度為140~160℃。第1輥及第2輥之周圍之溫度為室溫。 The temperature of the first roll is 10 to 30 ° C, and the temperature of the second roll is 140 to 160 ° C. The temperature around the first roll and the second roll is room temperature.

製造之聚碳酸酯導光板之厚度為0.250mm。利用基恩士公司製 造之數位顯微鏡VHX-2000型(商品名)觀察導光板之表面,測定轉印率(轉印率1),其結果為,點形狀之底面之直徑之轉印率為97%~100%,點形狀之高度之轉印率為92%~98%。 The manufactured polycarbonate light guide plate has a thickness of 0.250 mm. Using the Keyence company The surface of the light guide plate was observed by a digital microscope VHX-2000 (trade name), and the transfer rate (transfer rate 1) was measured. As a result, the transfer rate of the diameter of the bottom surface of the dot shape was 97% to 100%. The transfer rate of the height of the dot shape is 92% to 98%.

針對於與表面平行方向上,三角柱以使其側面相接之方式配置之槽狀或線狀圖案測定轉印率(轉印率2),其結果為,三角柱之側面之較短之邊之長度的轉印率為98~100%,三角柱之底面之自三角形之一邊至對向之頂點之高度的轉印率為95~97%。 The transfer rate (transfer rate 2) is measured in a groove-like or linear pattern in which the triangular prisms are arranged in such a manner as to be in contact with the surface in the direction parallel to the surface, and as a result, the length of the shorter side of the side of the triangular prism is determined. The transfer rate is 98~100%, and the transfer rate of the bottom of the triangular column from the edge of the triangle to the height of the opposite vertex is 95~97%.

比較例1 Comparative example 1

使用與實施例1相同之方法製造聚碳酸酯導光板。 A polycarbonate light guide plate was produced in the same manner as in Example 1.

但是,熔融狀態之片狀聚碳酸酯不藉由可撓性支持體支持於第2輥之表面,可撓性支持體遠離片狀聚碳酸酯。即,片狀聚碳酸酯支持於可撓性支持體而移行之旋轉角度θ實質上為0°。 However, the sheet-like polycarbonate in a molten state is not supported by the surface of the second roll by the flexible support, and the flexible support is away from the sheet-like polycarbonate. That is, the rotation angle θ at which the sheet-like polycarbonate is supported by the flexible support is substantially 0°.

表面沿矽橡膠彈性輥返回,由捲取機捲取,製造厚度為0.250mm之聚碳酸酯導光板。 The surface was returned along a 矽 rubber elastic roller and taken up by a winder to produce a polycarbonate light guide plate having a thickness of 0.250 mm.

與實施例1同樣地觀察導光板之表面,測定轉印率,其結果為,點形狀之底面之直徑之轉印率為94%~97%,點形狀之高度之轉印率為57%~69%。 The surface of the light guide plate was observed in the same manner as in Example 1, and the transfer rate was measured. As a result, the transfer rate of the diameter of the bottom surface of the dot shape was 94% to 97%, and the transfer rate of the height of the dot shape was 57%. 69%.

關於在與表面平行方向上,三角柱以使其側面相接之方式配置之線狀或槽狀之圖案,三角柱之側面之較短之邊之長度的轉印率為98~100%,三角柱之底面之自三角形之一邊至對向之頂點之高度的轉印率為63~68%。 Regarding the linear or groove-like pattern in which the triangular prisms are arranged in such a manner as to be in contact with the side surface in the direction parallel to the surface, the transfer rate of the shorter side of the side surface of the triangular prism is 98 to 100%, and the bottom surface of the triangular prism The transfer rate from one side of the triangle to the height of the opposite vertex is 63 to 68%.

使用與實施例1相同之方法,製造實施例2~6及比較例2~3之導光板。 The light guide plates of Examples 2 to 6 and Comparative Examples 2 to 3 were produced in the same manner as in Example 1.

但是,有與實施例1分別不同之部分,將其詳細與結果歸總示於表1~2。 However, there are differences from the first embodiment, and the details and results are collectively shown in Tables 1 and 2.

再者,於比較例3中,使用丙烯酸系樹脂(三菱麗陽股份有限公司 製造,VH6(商品名),MFR=1.7(JISK7210))代替聚碳酸酯。 Further, in Comparative Example 3, an acrylic resin (Mitsubishi Laiyang Co., Ltd.) was used. Manufactured, VH6 (trade name), MFR = 1.7 (JISK7210)) instead of polycarbonate.

若研究實施例與比較例,則可瞭解:旋轉角度為45~150之間時,即便為0.250mm之薄度,亦能夠於圖案之高度方向上,以80%以上之較高之轉印率製造聚碳酸酯導光板。本發明之形態之製造方法利用擠出成形方法,因此容易進行製造。進而,由於能夠一次於兩面形成形狀,故而能夠更容易地製造於兩面具有形狀之聚碳酸酯導光板。 If the research examples and the comparative examples are studied, it can be understood that even when the rotation angle is between 45 and 150, even at a thinness of 0.250 mm, a higher transfer rate of 80% or more can be obtained in the height direction of the pattern. A polycarbonate light guide plate is manufactured. Since the production method of the aspect of the present invention utilizes an extrusion molding method, it is easy to manufacture. Further, since the shape can be formed on both surfaces at once, it is possible to more easily manufacture a polycarbonate light guide plate having a shape on both sides.

如以上,作為本發明中之技術之例示,說明了實施形態。因此,記載了詳細之說明。 As described above, the embodiment has been described as an example of the technique of the present invention. Therefore, a detailed description is described.

因此,於詳細之說明中所記載之構成要素之中,不僅包含為了解決課題所必需之構成要素,亦可為了例示上述技術而包含並非為了解決課題所必需之構成要素。因此,不應因於詳細說明中記載該等不必需之構成要素,而直接認定該等不必需之構成要素為必需。 Therefore, among the constituent elements described in the detailed description, not only the constituent elements necessary for solving the problem but also the constituent elements not necessary for solving the problem are included in order to exemplify the above-described techniques. Therefore, it is not necessary to directly identify such unnecessary constituent elements as necessary in the detailed description.

又,上述實施形態為用以例示本發明中之技術者,因此可於申請專利範圍或其均等之範圍中進行各種變更、替換、附加、省略等。 In addition, the above-described embodiments are intended to exemplify the technical scope of the present invention, and various changes, substitutions, additions, omissions, and the like may be made in the scope of the claims.

[產業上之可利用性] [Industrial availability]

本發明中之導光板之製造方法能夠於以先前之利用射出成形、擠出加工之導光板之製造法將形狀轉印至樹脂表面的方法中,大幅提高不充分之轉印率,進而能夠穩定製造於導光板之表面形成精密形狀之厚度為100~600μm的導光板。因此,能夠提供一種於導光板表面精密地形成有形狀之導光板,能夠達成背光裝置之高亮度,因此工業利用價值極高。 The method for producing a light guide plate according to the present invention can greatly reduce an insufficient transfer rate and further stabilize the method of transferring a shape to a resin surface by a conventional method of producing a light guide plate by injection molding or extrusion processing. A light guide plate having a precise shape and having a thickness of 100 to 600 μm is formed on the surface of the light guide plate. Therefore, it is possible to provide a light guide plate having a shape precisely formed on the surface of the light guide plate, and it is possible to achieve high brightness of the backlight device, and thus the industrial use value is extremely high.

10‧‧‧第1輥 10‧‧‧1st roll

20‧‧‧第2輥 20‧‧‧2nd roller

30‧‧‧第3輥 30‧‧‧3rd roller

40‧‧‧可撓性支持體 40‧‧‧Flexible support

50‧‧‧可撓性支持體捲出輥 50‧‧‧Flexible support roll-up roll

52‧‧‧輥 52‧‧‧roll

54‧‧‧輥 54‧‧‧roll

56‧‧‧可撓性支持體捲入輥 56‧‧‧Flexible support roll-in roller

60‧‧‧T型模頭 60‧‧‧T-die

70‧‧‧熔融狀態片狀聚碳酸酯 70‧‧‧Metal state sheet polycarbonate

72‧‧‧固化狀態片狀聚碳酸酯 72‧‧‧Cured state sheet polycarbonate

θ‧‧‧旋轉角度 θ‧‧‧Rotation angle

Claims (5)

一種聚碳酸酯導光板之製造方法,其包括以下步驟:對聚碳酸酯進行加熱熔融,自模頭擠出而獲得片狀聚碳酸酯;將支持可撓性支持體之第1輥與於表面具有預先形成之圖案之第2輥平行配置,可撓性支持體係以通過第1輥與第2輥之間,且捲繞於第2輥之圓周方向之至少一部分之方式配置,第1輥及第2輥係以於可撓性支持體與第2輥之間夾著片狀聚碳酸酯且一面使可撓性支持體伴行於片狀聚碳酸酯,一面進行加壓之方式旋轉,將片狀聚碳酸酯壓抵於第2輥;壓抵於第2輥之片狀聚碳酸酯藉由可撓性支持體支持於第2輥之表面,並向第2輥之旋轉方向移行,以第1輥與第2輥之表面最接近之位置為基準,片狀聚碳酸酯與可撓性支持體於第2輥之旋轉角度為45~150°之位置分離;及第3輥與第2輥平行,且配置於第1輥之相反側,片狀聚碳酸酯通過第2輥與第3輥之間,且於第3輥之圓周方向之至少一部分被支持,第3輥係以受取片狀聚碳酸酯之方式旋轉。 A method for producing a polycarbonate light guide plate, comprising the steps of: heating and melting a polycarbonate, extruding from a die to obtain a sheet-like polycarbonate; and supporting the first roll of the flexible support with the surface The second roller having the pattern formed in advance is disposed in parallel, and the flexible support system is disposed between the first roller and the second roller and wound around at least a part of the circumferential direction of the second roller, and the first roller and the first roller In the second roll, the sheet-like polycarbonate is interposed between the flexible support and the second roll, and the flexible support is accompanied by the sheet-like polycarbonate, and is rotated while being pressurized. The sheet-like polycarbonate is pressed against the second roll; the sheet-like polycarbonate pressed against the second roll is supported by the flexible support on the surface of the second roll, and travels in the direction of rotation of the second roll to The position where the first roller and the second roller are closest to each other is the reference, and the sheet-like polycarbonate and the flexible support are separated at a position where the rotation angle of the second roller is 45 to 150°; and the third roller and the second roller The rolls are parallel and disposed on the opposite side of the first roll, and the sheet-like polycarbonate passes between the second roll and the third roll, and is in the third At least a portion of the circumferential direction is supported by the third roll set to take a sheet of polycarbonate rotate. 如請求項1之導光板之製造方法,其中第1輥之表面具有彈性。 A method of producing a light guide plate according to claim 1, wherein the surface of the first roller has elasticity. 如請求項1或2之導光板之製造方法,其中(i)與片狀聚碳酸酯相接之可撓性片材之表面為鏡面,且於片狀聚碳酸酯之單面形成有圖案,或(ii)於與片狀聚碳酸酯相接之可撓性片材之表面預先形成有圖案形狀,而於片狀聚碳酸酯之兩面形成有圖案。 The method of manufacturing a light guide plate according to claim 1 or 2, wherein (i) the surface of the flexible sheet which is in contact with the sheet-like polycarbonate is mirror-finished, and a pattern is formed on one side of the sheet-like polycarbonate. Or (ii) forming a pattern shape on the surface of the flexible sheet which is in contact with the sheet-like polycarbonate, and forming a pattern on both sides of the sheet-like polycarbonate. 一種聚碳酸酯導光板,其係藉由如請求項1至3中任一項之製造方法而製造,且於單面或兩面形成有圖案。 A polycarbonate light guide plate manufactured by the manufacturing method according to any one of claims 1 to 3, and having a pattern formed on one side or both sides. 一種顯示裝置,其具有藉由如請求項1至3中任一項之製造方法製造之聚碳酸酯導光板。 A display device having a polycarbonate light guide plate manufactured by the manufacturing method according to any one of claims 1 to 3.
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