TW201708857A - Polarizer plate and on-cell touch panel - Google Patents

Polarizer plate and on-cell touch panel Download PDF

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TW201708857A
TW201708857A TW104128304A TW104128304A TW201708857A TW 201708857 A TW201708857 A TW 201708857A TW 104128304 A TW104128304 A TW 104128304A TW 104128304 A TW104128304 A TW 104128304A TW 201708857 A TW201708857 A TW 201708857A
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protective layer
layer
protective
polarizing plate
thickness
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TW104128304A
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Chinese (zh)
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TWI571660B (en
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陳仁龍
張慶宇
葉春成
吳秋蕙
徐維廷
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住華科技股份有限公司
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Abstract

A polarizer plate is provided, including: a polarizer film; and a plurality of protective layers disposed on at least one side of the polarizer film, wherein a total thickness of the polarizer film and the protective layer is from 135 [mu]m to 250 [mu]m.

Description

偏光板 Polarizer

本發明是關於一種偏光板,且特別是關於具有多層保護層之偏光板。 The present invention relates to a polarizing plate, and more particularly to a polarizing plate having a plurality of protective layers.

近年來,由於觸控功能普遍搭載於智慧手持裝置,因此電子產品輕薄短小的要求也同樣加諸於觸控面板上,目前已有單片式觸控面板(One Glass Solution,OGS)、表嵌式觸控面板(On-Cell Touch)與內嵌式觸控面板(In-Cell Touch)等解決方案問世,有效降低電子產品之整體厚度。 In recent years, since touch functions are commonly used in smart handheld devices, the requirements for thin and light electronic products are also applied to touch panels. Currently, one-piece touch panels (One Glass Solution, OGS) and surface mounts are available. Solutions such as On-Cell Touch and In-Cell Touch have been introduced to reduce the overall thickness of electronic products.

本發明一實施例提供一種偏光板,包括:偏光膜;以及複數層保護層,設置於偏光膜之至少一側,其中偏光膜及上述保護層之總厚度為135μm至250μm。 An embodiment of the present invention provides a polarizing plate comprising: a polarizing film; and a plurality of protective layers disposed on at least one side of the polarizing film, wherein a total thickness of the polarizing film and the protective layer is 135 μm to 250 μm.

根據本發明一實施例,上述偏光板之整體介電常數為2至4。 According to an embodiment of the invention, the polarizing plate has an overall dielectric constant of 2 to 4.

根據本發明一實施例,上述偏光板中,保護層之總厚度為110μm至200μm。 According to an embodiment of the invention, in the polarizing plate, the total thickness of the protective layer is from 110 μm to 200 μm.

根據本發明一實施例,上述偏光板更包括:硬 塗層,設置於該些保護層之一表面上,該硬塗層之厚度為10μm至55μm。 According to an embodiment of the invention, the polarizing plate further comprises: a hard The coating layer is disposed on a surface of one of the protective layers, and the hard coating layer has a thickness of 10 μm to 55 μm.

10‧‧‧表嵌式觸控面板 10‧‧‧In-cell touch panel

10’‧‧‧表嵌式觸控面板 10'‧‧‧In-cell touch panel

12‧‧‧觸控基板 12‧‧‧Touch substrate

14‧‧‧線路層 14‧‧‧Line layer

16‧‧‧偏光板 16‧‧‧Polar plate

18‧‧‧保護蓋板 18‧‧‧Protection cover

30‧‧‧偏光板 30‧‧‧Polar plate

161‧‧‧偏光膜 161‧‧‧ polarizing film

163‧‧‧保護膜 163‧‧‧Protective film

301‧‧‧偏光膜 301‧‧‧ polarizing film

303a‧‧‧保護層 303a‧‧‧Protective layer

303‧‧‧第一保護層 303‧‧‧ first protective layer

305‧‧‧第二保護層 305‧‧‧Second protective layer

307‧‧‧第三保護層 307‧‧‧ third protective layer

309‧‧‧硬塗層 309‧‧‧hard coating

311‧‧‧第一感壓膠層 311‧‧‧First pressure sensitive adhesive layer

313‧‧‧第二感壓膠層 313‧‧‧Second pressure layer

D‧‧‧偏光板之整體厚度 D‧‧‧The overall thickness of the polarizing plate

第1A至1B圖顯示一表嵌式觸控面板之剖面示意圖;第1C圖顯示一表嵌式觸控面板的偏光板之剖面示意圖;第2圖顯示根據本發明一些實施例中,偏光板之剖面示意圖;第3圖顯示根據本發明之第一實施例中,偏光板之剖面示意圖;第4圖顯示根據本發明之第二實施例中,偏光板之剖面示意圖;第5圖顯示根據本發明之第三實施例中,偏光板之剖面示意圖;第6圖顯示根據本發明之第四實施例中,偏光板之剖面示意圖。 1A to 1B are schematic cross-sectional views showing a surface-mounted touch panel; FIG. 1C is a cross-sectional view showing a polarizing plate of a surface-mounted touch panel; and FIG. 2 is a view showing a polarizing plate according to some embodiments of the present invention. 3 is a schematic cross-sectional view of a polarizing plate according to a first embodiment of the present invention; FIG. 4 is a cross-sectional view showing a polarizing plate according to a second embodiment of the present invention; In the third embodiment, a schematic cross-sectional view of the polarizing plate is shown; and FIG. 6 is a cross-sectional view showing the polarizing plate in the fourth embodiment of the present invention.

以下將配合所附圖式詳述本發明之實施例,應注意的是,以下圖示並未按照比例繪製,事實上,可能任意的放大或縮小元件的尺寸以便清楚表現出本發明的特 徵,而在說明書及圖式中,同樣或類似的元件將以類似的符號表示。 The embodiments of the present invention are described in detail below with reference to the accompanying drawings, in which the drawings are not drawn to scale. In fact, the size of the elements may be arbitrarily enlarged or reduced so as to clearly express the features of the present invention. In the description and the drawings, the same or similar elements will be denoted by like symbols.

以下公開許多不同的實施方法或是例子來實行本發明之不同特徵,以下描述具體的元件及其排列的例子以闡述本發明。當然這些僅是例子且不該以此限定本發明的範圍。例如,在描述中提及第一個元件形成一第二個元件上時,其可以包括第一個元件與第二個元件直接接觸的實施例,也可以包括有其他元件形成於第一個與第二個元件之間的實施例,其中第一個元件與第二個元件並未直接接觸。此外,在不同實施例中可能使用重複的標號或標示,這些重複僅為了簡單清楚地敘述本揭露,不代表所討論的不同實施例及/或結構之間有特定的關係。 The various features of the invention are set forth in the description of the various embodiments of the invention. Of course, these are only examples and should not limit the scope of the invention. For example, when the first element is referred to in the description to form a second element, it may include an embodiment in which the first element is in direct contact with the second element, and may include other elements formed in the first An embodiment between the second elements, wherein the first element is not in direct contact with the second element. In addition, repeated reference numerals or signs may be used in the various embodiments, which are merely for the purpose of simplicity and clarity of the disclosure, and do not represent a particular relationship between the various embodiments and/or structures discussed.

此外,其中可能用到與空間相關的用詞,像是“在...之下”、“下方”、“在...之上”、“在...之間”及類似的用詞,這些關係詞係為了便於描述圖示中一個(些)元件或特徵與另一個(些)元件或特徵之間的關係,這些空間關係詞包括使用中或操作中的裝置之不同方位,以及圖示中所描述的方位。裝置可能被轉向不同方位(旋轉90度或其他方位),則其中使用的空間相關形容詞也可相同地照著解釋。應理解的是,在方法進行之前、當中或之後可能具有額外的操作步驟,且所述的一些操作步驟可能在另一些實施例之方法中被取代或刪除。 In addition, space-related terms such as "under", "below", "above", "between", and similar terms may be used. These relational terms are used to facilitate the description of the relationship between one element or feature(s) in the drawing and another element or feature(s), which are intended to include different orientations of the device in operation or operation, and The orientation described in the illustration. The device may be turned to a different orientation (rotated 90 degrees or other orientation), and the spatially related adjectives used therein may also be interpreted identically. It should be understood that additional operational steps may be performed before, during, or after the method is performed, and that some of the operational steps may be replaced or deleted in the methods of other embodiments.

第1A及1B圖分別顯示表嵌式觸控面板10之剖面示意圖。如第1A圖所示,表嵌式觸控面板10一般包含觸 控基板12、線路層14、偏光板16以及保護蓋板(cover lens)18。保護蓋板18設置於偏光板16之上,作為觸控面板10的操作介面並提供表面之保護,用以避免觸控面板受到外力破壞。在一實施例中,上述線路層14可為一透明氧化導電層,如氧化銦錫(indium tin oxide,ITO)層。在一實施例中,上述保護蓋板18可為一玻璃層。 1A and 1B are schematic cross-sectional views showing the in-cell touch panel 10, respectively. As shown in FIG. 1A, the in-cell touch panel 10 generally includes touch The substrate 12, the wiring layer 14, the polarizing plate 16, and a cover lens 18 are controlled. The protective cover 18 is disposed on the polarizing plate 16 as an operation interface of the touch panel 10 and provides surface protection to prevent the touch panel from being damaged by external force. In an embodiment, the circuit layer 14 may be a transparent oxidized conductive layer, such as an indium tin oxide (ITO) layer. In an embodiment, the protective cover 18 may be a glass layer.

近年來為了降低成本取消保護蓋板,使得觸控面板之偏光板外露於環境。然而,現有之偏光板並無法擁有與保護蓋板同等的機械特性,例如:抗刮性、硬度等。另外,取消保護蓋板會使得觸控面板之整體厚度降低,進而影響到觸控模組的作動靈敏度。此外,厚度不足之偏光板亦導致觸控電路的線路層14容易受水氣或外力影響進而腐蝕。 In recent years, in order to reduce the cost, the protective cover is removed, and the polarizing plate of the touch panel is exposed to the environment. However, the existing polarizing plates do not have the same mechanical properties as the protective cover, such as scratch resistance, hardness, and the like. In addition, the removal of the protective cover may reduce the overall thickness of the touch panel, thereby affecting the sensitivity of the touch module. In addition, the polarizing plate having insufficient thickness also causes the wiring layer 14 of the touch circuit to be easily affected by moisture or external force to corrode.

本發明乃為了解決上述問題,而提出以下設計。如第1B圖所示,部份表嵌式觸控面板10’可省略保護蓋板18,因而將偏光板16暴露於環境下。第1C圖進一步顯示偏光板16之詳細結構。在一實施例中,如第1C圖所示,表嵌式觸控面板10’使用之偏光板16可不具有補償膜,偏光板16包含:偏光膜161以及形成於偏光膜161兩側之保護膜163,例如,三醋酸纖維素(triacetyl cellulose,TAC)。而偏光板16之整體厚度約為130至140um。 The present invention has been made in order to solve the above problems. As shown in Fig. 1B, a portion of the in-cell touch panel 10' can omit the protective cover 18, thereby exposing the polarizing plate 16 to the environment. FIG. 1C further shows the detailed structure of the polarizing plate 16. In one embodiment, as shown in FIG. 1C, the polarizing plate 16 used in the in-cell touch panel 10' may not have a compensation film, and the polarizing plate 16 includes a polarizing film 161 and a protective film formed on both sides of the polarizing film 161. 163, for example, triacetyl cellulose (TAC). The overall thickness of the polarizing plate 16 is about 130 to 140 um.

然而,偏光板16並無法擁有與保護蓋板同等的機械特性,如抗刮性、硬度等。另外,取消外層保護蓋板會使得表嵌式觸控面板10’整體厚度降低,進而影響到觸控 模組的作動靈敏度。 However, the polarizing plate 16 does not have the same mechanical properties as the protective cover, such as scratch resistance, hardness, and the like. In addition, the removal of the outer protective cover may reduce the overall thickness of the in-cell touch panel 10', thereby affecting the touch. The sensitivity of the module's actuation.

為解決上述問題,本發明提供一種偏光板,其具有多層保護層,使得偏光板之整體厚度增加,例如,介於135至250μm,因而改善表嵌式觸控面板之觸控功能。再者,本發明之偏光板亦可藉由對偏光板之表面進行處理,提升其表面的硬度及抗刮性。在一實施例中,本發明偏光板之硬度可達6H。在一實施例中,本發明之偏光板之表面處理粗糙度可小於50nm,因此可達成不影響觸控模組的作動靈敏度,並且可降低觸控筆於操作時對光學元件表面所造成之摩擦損傷。 In order to solve the above problems, the present invention provides a polarizing plate having a plurality of protective layers such that the overall thickness of the polarizing plate is increased, for example, between 135 and 250 μm, thereby improving the touch function of the in-cell touch panel. Furthermore, the polarizing plate of the present invention can also improve the hardness and scratch resistance of the surface of the polarizing plate by treating the surface of the polarizing plate. In one embodiment, the polarizing plate of the present invention has a hardness of up to 6H. In an embodiment, the surface treatment roughness of the polarizing plate of the present invention can be less than 50 nm, so that the actuation sensitivity of the touch module can be achieved, and the friction caused by the stylus on the surface of the optical component during operation can be reduced. damage.

以下將詳細說明本案之偏光板。第2圖顯示根據本發明一些實施例中,偏光板30之剖面示意圖。如第2圖所示,偏光板30包含:偏光膜301以及複數層保護層303a,例如,兩層以上之保護層303a。上述保護層303a可設置於偏光膜301之至少一側。在一實施例中,保護層303a設置於偏光膜301之兩側。 The polarizing plate of this case will be described in detail below. Figure 2 shows a schematic cross-sectional view of a polarizing plate 30 in accordance with some embodiments of the present invention. As shown in FIG. 2, the polarizing plate 30 includes a polarizing film 301 and a plurality of protective layers 303a, for example, two or more protective layers 303a. The protective layer 303a may be disposed on at least one side of the polarizing film 301. In an embodiment, the protective layer 303a is disposed on both sides of the polarizing film 301.

在一實施例中,偏光板30之整體厚度D,即,偏光膜301以及複數層保護層303a之總厚度可為135μm至250μm,例如,150μm至200μm或150μm至230μm。特別地,若偏光板之整體厚度D過薄,可能使得線路層14易受水氣或外力影響而腐蝕,進而影響觸控模組的作動靈敏度。反之,若偏光板之整體厚度D過厚,亦會導致觸控功能失效。 In one embodiment, the overall thickness D of the polarizing plate 30, that is, the polarizing film 301 and the plurality of protective layers 303a may have a total thickness of 135 μm to 250 μm, for example, 150 μm to 200 μm or 150 μm to 230 μm. In particular, if the overall thickness D of the polarizing plate is too thin, the circuit layer 14 may be easily corroded by moisture or external force, thereby affecting the sensitivity of the touch module. Conversely, if the overall thickness D of the polarizing plate is too thick, the touch function may be disabled.

在一實施例中,偏光膜301之厚度可為5μm至40μm,例如,20μm至35μm。在一實施例中,保護層303a 之總厚度可為110μm至200μm,例如,130μm至180μm。再者,在一實施例中,保護層303a之各別厚度可為30μm至100μm,例如,40μm至90μm。應注意的是,複數層保護層303a彼此之間的厚度及材料皆可為相同或不同,只要總厚度達110μm至200μm即可。 In an embodiment, the polarizing film 301 may have a thickness of 5 μm to 40 μm, for example, 20 μm to 35 μm. In an embodiment, the protective layer 303a The total thickness may be from 110 μm to 200 μm, for example, from 130 μm to 180 μm. Furthermore, in an embodiment, the respective thicknesses of the protective layer 303a may be from 30 μm to 100 μm, for example, from 40 μm to 90 μm. It should be noted that the thickness and material of the plurality of protective layers 303a may be the same or different from each other as long as the total thickness is from 110 μm to 200 μm.

再者,上述偏光板30之整體介電常數(dielectric constant),即,偏光膜301以及複數層保護層303a之整體介電常數可為2至4。偏光板30之整體電容值介於9*10^-8至8*10^-10法拉。 Furthermore, the overall dielectric constant of the polarizing plate 30, that is, the polarizing film 301 and the plurality of protective layers 303a may have an overall dielectric constant of 2 to 4. The overall capacitance of the polarizing plate 30 is between 9*10^-8 and 8*10^-10 Farads.

承前述,偏光膜301為偏光板的主要偏光基體,可將光線由非偏極光轉換為偏極光。偏光膜301可為吸附配向之二色性色素之聚乙烯醇(polyvinyl alcohol,PVA)薄膜或由液晶材料摻附具吸收染料分子所形成。聚乙烯醇可藉由皂化聚乙酸乙烯酯而形成。在一些實施例中,聚乙酸乙烯酯可為乙酸乙烯酯之單聚物或乙酸乙烯酯及其它單體之共聚物等。上述其它單體可為不飽和羧酸類、烯烴類、不飽和磺酸類或乙烯基醚類等。在另一些實施例中,聚乙烯醇可為經改質的聚乙烯醇,例如,經醛類改質的聚乙烯甲醛、聚乙烯乙醛或聚乙烯丁醛等。 As described above, the polarizing film 301 is a main polarizing substrate of the polarizing plate, and converts light from non-polarizing light to polarized light. The polarizing film 301 may be formed by adsorbing a polyvinyl alcohol (PVA) film of an aligning dichroic dye or by absorbing an absorbing dye molecule from the liquid crystal material. Polyvinyl alcohol can be formed by saponifying polyvinyl acetate. In some embodiments, the polyvinyl acetate may be a monomer of vinyl acetate or a copolymer of vinyl acetate and other monomers, and the like. The above other monomers may be unsaturated carboxylic acids, olefins, unsaturated sulfonic acids or vinyl ethers. In other embodiments, the polyvinyl alcohol may be a modified polyvinyl alcohol, for example, an aldehyde-modified polyethylene formaldehyde, polyvinyl acetal or polyvinyl butyral or the like.

上述偏光膜301的形成方法並無特別限制,可選用任意合適的習知方法製作。一般而言,偏光膜301的形成方法可包括:膨潤處理、染色處理、交聯處理及洗淨處理等,並於交聯處理中或交聯處理之前進行薄膜之拉伸處理,而最後將薄膜進行乾燥處理。 The method of forming the above polarizing film 301 is not particularly limited, and it can be produced by any suitable conventional method. In general, the method for forming the polarizing film 301 may include: swelling treatment, dyeing treatment, cross-linking treatment, washing treatment, etc., and performing stretching treatment of the film in the crosslinking treatment or the crosslinking treatment, and finally the film. Drying is carried out.

再者,複數層保護層303a可保護偏光膜301之光學性質以及防止偏光膜301回縮且亦提供偏光板30最外層之保護。保護層303a的材料可為聚酯樹脂、烯烴樹脂、乙酸纖維素樹脂、聚碳酸酯樹脂、丙烯酸樹脂、環烯烴樹脂或上述之組合,但不限於此。 Furthermore, the plurality of protective layers 303a can protect the optical properties of the polarizing film 301 and prevent the polarizing film 301 from being retracted and also provide protection for the outermost layer of the polarizing plate 30. The material of the protective layer 303a may be a polyester resin, an olefin resin, a cellulose acetate resin, a polycarbonate resin, an acrylic resin, a cycloolefin resin, or a combination thereof, but is not limited thereto.

在一些實施例中,保護層303a的材料可為三醋酸纖維素(triacetyl cellulose,TAC)、二醋酸纖維素(diacetyl cellulose,DAC)、聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、環烯烴聚合物(cyclic olefin polymer,COP)、聚甲基丙烯酸甲酯(Poly(methyl methacrylate)、環烯烴共聚合物(cyclic olefin copolymer,COC)、聚碳酸酯樹脂、聚醚碸、聚亞醯胺、聚碸、聚乙烯樹脂、聚氯乙烯樹脂、二醋酸纖維素、或上述之組合,但不限於此。 In some embodiments, the material of the protective layer 303a may be triacetyl cellulose (TAC), diacetyl cellulose (DAC), polyethylene terephthalate (PET), Cycloolefin polymer (COP), poly(methyl methacrylate), cyclic olefin copolymer (COC), polycarbonate resin, polyether oxime, polyarylene Amine, polyfluorene, polyethylene resin, polyvinyl chloride resin, cellulose diacetate, or a combination thereof, but is not limited thereto.

再者,保護層303a亦可含有紫外線吸收劑(例如,二苯基酮化合物或苯并三唑化合物等)或含有塑化劑(例如,苯基磷酸酯化合物或鄰苯二甲酸酯化合物等)。 Further, the protective layer 303a may contain an ultraviolet absorber (for example, a diphenylketone compound or a benzotriazole compound) or a plasticizer (for example, a phenyl phosphate compound or a phthalate compound, etc.) ).

此外,亦可進一步對上述保護層實行表面處理,例如,抗眩光處理、抗反射處理、硬塗處理、帶電防止處理或抗污處理等。上述表面處理之厚度可大於10μm,硬度可達6H,且具有高耐刮傷性、高防汙性、低透濕度之特性,因此可取代保護蓋板。 Further, the protective layer may be further subjected to surface treatment such as anti-glare treatment, anti-reflection treatment, hard coating treatment, electrification prevention treatment or anti-fouling treatment. The above surface treatment can have a thickness of more than 10 μm, a hardness of up to 6H, and high scratch resistance, high antifouling property, and low moisture permeability, so that the protective cover can be replaced.

在一些實施例中,偏光板30可包含設置於保護層303a表面上之硬塗層(未繪示)。硬塗層可大幅提升偏光板30表面的硬度及抗刮性。在一實施例中,硬塗層之厚度 可為10μm至55μm,例如,15μm至50μm。上述硬塗層之材料可為丙烯酸樹脂、胺基甲酸酯樹脂、三聚氰胺樹脂、有機矽酸鹽化合物、聚矽氧樹脂、金屬氧化物或上述之組合,但不限於此。 In some embodiments, the polarizing plate 30 may include a hard coat layer (not shown) disposed on the surface of the protective layer 303a. The hard coat layer can greatly improve the hardness and scratch resistance of the surface of the polarizing plate 30. In one embodiment, the thickness of the hard coat layer It may be from 10 μm to 55 μm, for example, from 15 μm to 50 μm. The material of the hard coat layer may be an acrylic resin, a urethane resin, a melamine resin, an organic phthalate compound, a polyoxyxylene resin, a metal oxide or a combination thereof, but is not limited thereto.

上述保護層303a及硬塗層的形成方法並無特別限制,可選用任意合適的習知方法製作。例如,蒸鍍、濺鍍、塗佈或是藉由合適的接合劑直接貼合於偏光膜之上。 The protective layer 303a and the method of forming the hard coat layer are not particularly limited, and may be produced by any suitable conventional method. For example, evaporation, sputtering, coating or directly bonding to the polarizing film by a suitable bonding agent.

此外,偏光板30亦可視需要包含設置於保護層303a表面上之一或多層感壓膠(pressure sensitive adhesive,PSA)層(未繪示)。感壓膠層可用來提供保護層303a及偏光膜301之間的貼合、複數保護層303a間之貼合,且亦可用來提供偏光板30及觸控基板之間的貼合。感壓膠層係指輕壓即可黏著於物體表面之黏著劑,是由彈性體、增黏樹脂、增塑劑和填充料調配而成。感壓膠層之性能係隨著所使用單體、聚合的方式、所控制膠體之分子量或玻璃轉化溫度而有不同。感壓膠層可為天然橡膠、苯乙烯丁二烯橡膠(Styrene Butadiene Rubber,SBR)、壓克力樹脂(例如,丙烯酸酯共聚物)或上述之組合,但不限於此。 In addition, the polarizing plate 30 may also include one or more layers of a pressure sensitive adhesive (PSA) layer (not shown) disposed on the surface of the protective layer 303a. The pressure sensitive adhesive layer can be used to provide a bonding between the protective layer 303a and the polarizing film 301 and a bonding between the plurality of protective layers 303a, and can also be used to provide a bonding between the polarizing plate 30 and the touch substrate. The pressure sensitive adhesive layer refers to an adhesive which adheres to the surface of the object under light pressure and is prepared by mixing an elastomer, a tackifying resin, a plasticizer and a filler. The properties of the pressure sensitive adhesive layer vary with the monomer used, the manner in which it is polymerized, the molecular weight of the controlled colloid, or the glass transition temperature. The pressure sensitive adhesive layer may be natural rubber, Styrene Butadiene Rubber (SBR), acrylic resin (for example, acrylate copolymer) or a combination thereof, but is not limited thereto.

值得注意的是,由於表嵌式觸控面板的結構會使線路層14直接接觸到感壓膠層,為避免感壓膠層中單體及聚寡物所含之酸根腐蝕線路層14,以及感壓膠層中所含之抗靜電劑對線路層14之電性干涉。本案使用之感壓膠層最好不含酸價以及抗靜電劑,以避免腐蝕線路層14及產生電性干擾。在一實施例中,感壓膠層之阻值為1013歐姆。 It is worth noting that, due to the structure of the in-cell touch panel, the circuit layer 14 is directly in contact with the pressure sensitive adhesive layer, in order to avoid the acid corrosion of the circuit layer 14 contained in the monomer and the oligomer in the pressure sensitive adhesive layer, and The antistatic agent contained in the pressure sensitive adhesive layer electrically interferes with the circuit layer 14. The pressure sensitive adhesive layer used in this case is preferably free of acid value and antistatic agent to avoid corrosion of the circuit layer 14 and electrical interference. In one embodiment, the pressure sensitive adhesive layer has a resistance of 10 13 ohms.

在另一實施例中,感壓膠層內亦可摻雜導電粒子,例如,透明金屬氧化物、奈米粒子、導電高分子或導電金屬如鎳(Ni)、金(Au)或上述之組合,以達到抗靜電之功能。在一實施例中,感壓膠層之阻值為107~109歐姆。 In another embodiment, the pressure sensitive adhesive layer may also be doped with conductive particles, such as transparent metal oxide, nano particles, conductive polymer or conductive metal such as nickel (Ni), gold (Au) or a combination thereof. To achieve anti-static function. In one embodiment, the pressure sensitive adhesive layer has a resistance of 10 7 to 10 9 ohms.

以下更具體描述本發明之一些實施例,以更詳細說明本案之偏光板。 Some embodiments of the present invention are described in more detail below to explain the polarizing plate of the present invention in more detail.

第3圖顯示根據本發明之第一實施例中,偏光板30之剖面示意圖。在此實施例中,偏光板30包含偏光膜301以及三層保護層,其分別為第一保護層303、第二保護層305以及第三保護層307。如第3圖所示,第一保護層303形成於偏光膜301之下,而第二保護層305及第三保護層307形成於偏光膜301之上。 Fig. 3 is a cross-sectional view showing the polarizing plate 30 in the first embodiment according to the present invention. In this embodiment, the polarizing plate 30 includes a polarizing film 301 and three protective layers, which are a first protective layer 303, a second protective layer 305, and a third protective layer 307, respectively. As shown in FIG. 3, the first protective layer 303 is formed under the polarizing film 301, and the second protective layer 305 and the third protective layer 307 are formed on the polarizing film 301.

在此實施例中,偏光膜301例如由聚乙烯醇所形成,第一保護層303及第二保護層305例如由三醋酸纖維素所形成,而第三保護層307則例如由環烯烴聚合物所形成。再者,偏光膜301之厚度為15至35μm,例如,25μm;第一保護層303之厚度為50至70μm,例如,60μm;第二保護層305之厚度為30至50μm,例如,40μm;第三保護層307之厚度為40至60μm,例如,52μm。在一實施例中,上述第二保護層305及第三保護層307之間可選擇性的包括一感壓膠層(未繪示)。 In this embodiment, the polarizing film 301 is formed, for example, of polyvinyl alcohol, the first protective layer 303 and the second protective layer 305 are formed, for example, of cellulose triacetate, and the third protective layer 307 is, for example, a cycloolefin polymer. Formed. Further, the polarizing film 301 has a thickness of 15 to 35 μm, for example, 25 μm; the first protective layer 303 has a thickness of 50 to 70 μm, for example, 60 μm; and the second protective layer 305 has a thickness of 30 to 50 μm, for example, 40 μm; The thickness of the triple protective layer 307 is 40 to 60 μm, for example, 52 μm. In an embodiment, the second protective layer 305 and the third protective layer 307 may optionally include a pressure sensitive adhesive layer (not shown).

第4圖顯示根據本發明之第二實施例中,偏光板30之剖面示意圖。在此實施例中,偏光板30亦包含偏光膜301以及三層保護層,其分別為第一保護層303、第二保 護層305以及第三保護層307。如第4圖所示,此實施例之第一保護層303以及第三保護層307形成於偏光膜301之下,而第二保護層305形成於偏光膜301之上。 Fig. 4 is a cross-sectional view showing the polarizing plate 30 in the second embodiment of the present invention. In this embodiment, the polarizing plate 30 also includes a polarizing film 301 and three protective layers, which are respectively a first protective layer 303 and a second protective layer. The cover layer 305 and the third protective layer 307. As shown in FIG. 4, the first protective layer 303 and the third protective layer 307 of this embodiment are formed under the polarizing film 301, and the second protective layer 305 is formed over the polarizing film 301.

在此實施例中,偏光膜301例如由聚乙烯醇所形成,第一保護層303及第二保護層305例如由三醋酸纖維素所形成,而第三保護層307則例如由聚甲基丙烯酸甲酯(Poly(methyl methacrylate)所形成。再者,偏光膜301之厚度為15至35μm,例如,25μm;第一保護層303之厚度為30至50μm,例如,40μm;第二保護層305之厚度為30至50μm,例如,40μm;第三保護層307之厚度為70至90μm,例如,82μm。在一實施例中,上述第一保護層303以及第三保護層307之間可選擇性的包括一感壓膠層(未繪示)。 In this embodiment, the polarizing film 301 is formed, for example, of polyvinyl alcohol, the first protective layer 303 and the second protective layer 305 are formed, for example, of cellulose triacetate, and the third protective layer 307 is, for example, polymethacrylic acid. A methyl ester (poly (methyl methacrylate) is formed. Further, the polarizing film 301 has a thickness of 15 to 35 μm, for example, 25 μm; the first protective layer 303 has a thickness of 30 to 50 μm, for example, 40 μm; and the second protective layer 305 The thickness is 30 to 50 μm, for example, 40 μm; the thickness of the third protective layer 307 is 70 to 90 μm, for example, 82 μm. In an embodiment, the first protective layer 303 and the third protective layer 307 are selectively selectable. A pressure sensitive adhesive layer (not shown) is included.

第5圖顯示根據本發明之第三實施例中,偏光板30之剖面示意圖。在此實施例中,偏光板30包含偏光膜301以及兩層保護層(第一保護層303及第二保護層305)以及硬塗層309。如第5圖所示,在此實施例中,第一保護層303以及第二保護層305分別形成於偏光膜301之兩側,而硬塗層309形成於第二保護層305之上。 Fig. 5 is a cross-sectional view showing the polarizing plate 30 in the third embodiment of the present invention. In this embodiment, the polarizing plate 30 includes a polarizing film 301 and two protective layers (a first protective layer 303 and a second protective layer 305) and a hard coat layer 309. As shown in FIG. 5, in this embodiment, the first protective layer 303 and the second protective layer 305 are respectively formed on both sides of the polarizing film 301, and the hard coat layer 309 is formed on the second protective layer 305.

在此實施例中,偏光膜301例如由聚乙烯醇所形成,第一保護層303及第二保護層305例如由三醋酸纖維素所形成,硬塗層309則例如由壓克力樹脂所形成。再者,偏光膜301之厚度為20至40μm,例如,30μm;第一保護層303之厚度為50至70μm,例如,60μm;第二保護層305之厚度為20至40μm,例如,30μm;硬塗層309之厚度為50至 60μm,例如,55μm。 In this embodiment, the polarizing film 301 is formed, for example, of polyvinyl alcohol, the first protective layer 303 and the second protective layer 305 are formed, for example, of cellulose triacetate, and the hard coat layer 309 is formed, for example, of acrylic resin. . Further, the polarizing film 301 has a thickness of 20 to 40 μm, for example, 30 μm; the first protective layer 303 has a thickness of 50 to 70 μm, for example, 60 μm; and the second protective layer 305 has a thickness of 20 to 40 μm, for example, 30 μm; Coating 309 has a thickness of 50 to 60 μm, for example, 55 μm.

第6圖顯示根據本發明之第四實施例中,偏光板30之剖面示意圖。在此實施例中,偏光板30包含偏光膜301三層保護層(第一保護層303、第二保護層305及第三保護層307)、第一感壓膠層311及第二感壓膠層313。如第6圖所示,在此實施例中,第一保護層303、第二保護層305以及第三保護層307分別形成於偏光膜301之兩側,而第一感壓層311形成於第二保護層305之下,第二感壓層313形成於第一保護層303及第二保護層305之間。 Fig. 6 is a cross-sectional view showing the polarizing plate 30 in the fourth embodiment of the present invention. In this embodiment, the polarizing plate 30 includes three protective layers (a first protective layer 303, a second protective layer 305, and a third protective layer 307), a first pressure sensitive adhesive layer 311, and a second pressure sensitive adhesive. Layer 313. As shown in FIG. 6, in this embodiment, the first protective layer 303, the second protective layer 305, and the third protective layer 307 are respectively formed on both sides of the polarizing film 301, and the first pressure sensitive layer 311 is formed on the first The second pressure sensitive layer 313 is formed between the first protective layer 303 and the second protective layer 305 under the second protective layer 305.

在此實施例中,偏光膜301例如由聚乙烯醇所形成,第一保護層303、第二保護層305及第三保護層307例如由三醋酸纖維素所形成,第一感壓膠層311及第二感壓膠層313係指輕壓即可黏著於物體表面之黏著劑,是由彈性體、增黏樹脂、增塑劑和填充料調配而成。第一感壓膠層311及第二感壓膠層313之性能係隨著所使用單體、聚合的方式、所控制膠體之分子量或玻璃轉化溫度而有不同。第一感壓膠層311及第二感壓膠層313可為天然橡膠、苯乙烯丁二烯橡膠(Styrene Butadiene Rubber,SBR)、壓克力樹脂(例如,丙烯酸酯共聚物)或上述之組合,但不限於此。 In this embodiment, the polarizing film 301 is formed of, for example, polyvinyl alcohol, and the first protective layer 303, the second protective layer 305, and the third protective layer 307 are formed, for example, of cellulose triacetate, and the first pressure sensitive adhesive layer 311 And the second pressure sensitive adhesive layer 313 is an adhesive which can be adhered to the surface of the object by light pressing, and is prepared by mixing an elastomer, a tackifying resin, a plasticizer and a filler. The properties of the first pressure-sensitive adhesive layer 311 and the second pressure-sensitive adhesive layer 313 vary depending on the monomer used, the manner of polymerization, the molecular weight of the controlled colloid, or the glass transition temperature. The first pressure sensitive adhesive layer 311 and the second pressure sensitive adhesive layer 313 may be natural rubber, Styrene Butadiene Rubber (SBR), acrylic resin (for example, acrylate copolymer) or a combination thereof. , but not limited to this.

在一實施例中,上述第一感壓膠層311及第二感壓膠層313中可摻雜了導電粒子,使得第一感壓膠層311及第二感壓膠層313之阻值為107至109歐姆。在一實施例中,上述導電粒子可包括:透明金屬氧化物、奈米粒子、導電高分子或導電金屬如可為鎳(Ni)、金(Au)或上述之組 合。 In one embodiment, the first pressure sensitive adhesive layer 311 and the second pressure sensitive adhesive layer 313 may be doped with conductive particles, so that the resistance values of the first pressure sensitive adhesive layer 311 and the second pressure sensitive adhesive layer 313 are 10 7 to 10 9 ohms. In one embodiment, the conductive particles may include: a transparent metal oxide, a nanoparticle, a conductive polymer, or a conductive metal such as nickel (Ni), gold (Au), or a combination thereof.

再者,偏光膜301之厚度為5至40μm,例如,25μm;第一保護層303之厚度為50至70μm,例如,60μm;第二保護層305之厚度為50至100μm,例如,82μm;第三保護層之厚度307之厚度為40至100μm,例如,45μm;第一感壓膠層311及第二感壓膠層313之厚度5至20μm,例如,5μm。 Further, the polarizing film 301 has a thickness of 5 to 40 μm, for example, 25 μm; the first protective layer 303 has a thickness of 50 to 70 μm, for example, 60 μm; and the second protective layer 305 has a thickness of 50 to 100 μm, for example, 82 μm; The thickness 307 of the triple protective layer is 40 to 100 μm, for example, 45 μm; the thickness of the first pressure sensitive adhesive layer 311 and the second pressure sensitive adhesive layer 313 is 5 to 20 μm, for example, 5 μm.

綜上所述,本發明提供之偏光板,其具有多層保護層,使得偏光板之整體厚度介於135至250μm,較傳統使用於表嵌式觸控面板之偏光板厚,可改善表嵌式觸控面板之觸控模組的作動靈敏度。再者,本發明之偏光板亦藉由對偏光板進行表面處理,提升偏光板表面的硬度及抗刮性,藉此可有效地替代現有表嵌式觸控面板外層之保護蓋板。 In summary, the polarizing plate provided by the present invention has a plurality of protective layers, so that the overall thickness of the polarizing plate is between 135 and 250 μm, which is thicker than the polarizing plate conventionally used for the surface-mounted touch panel, and can improve the surface-embedded type. The sensitivity of the touch panel of the touch panel. Furthermore, the polarizing plate of the present invention can also improve the hardness and scratch resistance of the surface of the polarizing plate by surface treatment of the polarizing plate, thereby effectively replacing the protective cover of the outer layer of the existing surface-mounted touch panel.

前述內文概述了許多實施例的特徵,使本技術領域中具有通常知識者可以更清楚地了解本發明的各個面向。本技術領域中具有通常知識者可以輕易地以本發明為基礎來設計或修飾其它製程及結構,並以此達到相同的目的及/或達到與本發明實施例相同的優點。本技術領域中具有通常知識者也應該了解這些均等的結構並不會背離本發明的發明精神與範圍,而可以作各種改變、置換與修改。 The foregoing description of the various embodiments of the invention may be Those skilled in the art can readily design or modify other processes and structures based on the present invention to achieve the same objectives and/or achieve the same advantages as the embodiments of the present invention. It should be understood by those of ordinary skill in the art that the present invention is not limited to the scope of the invention.

雖然本發明已以數個較佳實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作任意之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範 圍所界定者為準。 While the invention has been described above in terms of several preferred embodiments, it is not intended to limit the scope of the present invention, and any one of ordinary skill in the art can make any changes without departing from the spirit and scope of the invention. And the retouching, so the scope of protection of the present invention is attached to the patent application The definition of the enclosure shall prevail.

30‧‧‧偏光板 30‧‧‧Polar plate

301‧‧‧偏光膜 301‧‧‧ polarizing film

303a‧‧‧保護層 303a‧‧‧Protective layer

D‧‧‧偏光板之整體厚度 D‧‧‧The overall thickness of the polarizing plate

Claims (10)

一種偏光板,包括:一偏光膜;以及複數層保護層,設置於該偏光膜之至少一側,其中該偏光膜及該些保護層之總厚度為135μm至250μm。 A polarizing plate comprising: a polarizing film; and a plurality of protective layers disposed on at least one side of the polarizing film, wherein the polarizing film and the protective layers have a total thickness of 135 μm to 250 μm. 如申請專利範圍第1項所述之偏光板,其中該偏光膜之厚度為10μm至40μm,及/或該些保護層之總厚度為110μm至200μm,及/或該些保護層之各別厚度為30μm至100μm。 The polarizing plate of claim 1, wherein the polarizing film has a thickness of 10 μm to 40 μm, and/or the total thickness of the protective layers is 110 μm to 200 μm, and/or respective thicknesses of the protective layers. It is from 30 μm to 100 μm. 如申請專利範圍第1項所述之偏光板,其中該些保護層包括:三醋酸纖維素(triacetyl cellulose,TAC)、二醋酸纖維素(diacetyl cellulose,DAC)、聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、環烯烴聚合物(cyclic olefin polymer,COP)、環烯烴共聚合物(cyclic olefin copolymer,COC)或上述之組合。 The polarizing plate of claim 1, wherein the protective layer comprises: triacetyl cellulose (TAC), diacetyl cellulose (DAC), polyethylene terephthalate. (polyethylene terephthalate, PET), cyclic olefin polymer (COP), cyclic olefin copolymer (COC) or a combination thereof. 如申請專利範圍第1項所述之偏光板,更包括:一硬塗層,設置於該些保護層之一表面上,其中該硬塗層之厚度為10μm至55μm,及/或該硬塗層之材料包括:丙烯酸樹脂、胺基甲酸酯樹脂、三聚氰胺樹脂、有機矽酸鹽化合物、聚矽氧樹脂、金屬氧化物或上述之組合。 The polarizing plate of claim 1, further comprising: a hard coat layer disposed on a surface of the protective layer, wherein the hard coat layer has a thickness of 10 μm to 55 μm, and/or the hard coat layer The material of the layer includes: an acrylic resin, a urethane resin, a melamine resin, an organic phthalate compound, a polyoxyxylene resin, a metal oxide or a combination thereof. 如申請專利範圍第1項所述之偏光板,更包括:至少一感壓膠層,設置於該些保護層之一表面上,該感壓膠層之厚度為10μm至30μm。 The polarizing plate of claim 1, further comprising: at least one pressure sensitive adhesive layer disposed on a surface of the protective layer, the pressure sensitive adhesive layer having a thickness of 10 μm to 30 μm. 如申請專利範圍第5項所述之偏光板,其中該感壓膠層中可包含一導電粒子,及/或該感壓膠層之阻值為107至109歐姆。 The polarizing plate of claim 5, wherein the pressure sensitive adhesive layer may comprise a conductive particle, and/or the pressure sensitive adhesive layer has a resistance of 10 7 to 10 9 ohms. 如申請專利範圍第1項所述之偏光板,其中該些保護層係由三層保護層所組成,分別為第一保護層、第二保護層及第三保護層,其中該第一保護層設置於該偏光膜之一側,該第二保護層及該第三保護層設置於該偏光膜之另一側。 The polarizing plate of claim 1, wherein the protective layers are composed of three protective layers, respectively a first protective layer, a second protective layer and a third protective layer, wherein the first protective layer The second protective layer and the third protective layer are disposed on the other side of the polarizing film. 如申請專利範圍第7項所述之偏光板,其中該第一保護層及該第二保護層係由三醋酸纖維素所形成,該第三保護層係由環烯烴聚合物或聚甲基丙烯酸甲酯所形成。 The polarizing plate of claim 7, wherein the first protective layer and the second protective layer are formed of cellulose triacetate, and the third protective layer is composed of a cyclic olefin polymer or polymethacrylic acid. Formed by methyl ester. 如申請專利範圍第7項所述之偏光板,其中該第二保護層係緊鄰該偏光膜,且該第一保護膜及該第三保護膜係由三醋酸纖維素所形成,第二保護層係由環烯烴共聚合物所形成。 The polarizing plate of claim 7, wherein the second protective layer is adjacent to the polarizing film, and the first protective film and the third protective film are formed of cellulose triacetate, and the second protective layer It is formed from a cyclic olefin copolymer. 如申請專利範圍第1項所述之偏光板,其中該些保護層係由兩層保護層所組成,分別為第一保護層及第二保護層,其中該第一保護層及該第二保護層分別設置於該偏光膜之兩側,且該偏光板更包括一硬塗層,設置於該第二保護層之上,其中該硬塗層之厚度為10μm至55μm。 The polarizing plate of claim 1, wherein the protective layers are composed of two protective layers, respectively a first protective layer and a second protective layer, wherein the first protective layer and the second protection layer The layers are respectively disposed on the two sides of the polarizing film, and the polarizing plate further comprises a hard coating layer disposed on the second protective layer, wherein the hard coating layer has a thickness of 10 μm to 55 μm.
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TWI702425B (en) * 2018-11-20 2020-08-21 住華科技股份有限公司 Polarizer, and display device comprising the same, manufacturing method of polarizer, and manufacturing method of display device
TWI702426B (en) * 2018-11-20 2020-08-21 住華科技股份有限公司 Manufacturing methods of polarizer and display device comprising the same

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US7468199B2 (en) * 2004-12-23 2008-12-23 3M Innovative Properties Company Adhesive membrane for force switches and sensors
KR101533883B1 (en) * 2013-06-18 2015-07-03 주식회사 엘지화학 Polarizer plate and display device having the same
JP6526972B2 (en) * 2014-01-14 2019-06-05 日東電工株式会社 Adhesive, polarizing film, liquid crystal panel, optical film, and image display device

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* Cited by examiner, † Cited by third party
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TWI702425B (en) * 2018-11-20 2020-08-21 住華科技股份有限公司 Polarizer, and display device comprising the same, manufacturing method of polarizer, and manufacturing method of display device
TWI702426B (en) * 2018-11-20 2020-08-21 住華科技股份有限公司 Manufacturing methods of polarizer and display device comprising the same

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