TW201632669A - Fabric for making airbags and method of making same - Google Patents

Fabric for making airbags and method of making same Download PDF

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TW201632669A
TW201632669A TW104106596A TW104106596A TW201632669A TW 201632669 A TW201632669 A TW 201632669A TW 104106596 A TW104106596 A TW 104106596A TW 104106596 A TW104106596 A TW 104106596A TW 201632669 A TW201632669 A TW 201632669A
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yarn
fabric
fibers
melted
ground
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TW104106596A
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Chinese (zh)
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珍妮H 梅爾斯
維如聶許 夏瑪
馬丁 湯森
羅伯特V 華許
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英威達技術有限公司
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Abstract

A woven fabric comprising a base yarn and a secondary yarn, wherein the secondary yarn is interwoven into the base yarn, and wherein the secondary yarn has a melting point that is lower than the melting point of base yarn. Also disclosed is a method of making a base yarn and a secondary yarn, wherein the secondary yarn is interwoven into the base yarn, and wherein the secondary yarn has a melting point that is lower than the melting point of base yarn.

Description

用於製造安全氣囊的織物及其製造方法 Fabric for manufacturing airbag and manufacturing method thereof 相關申請案Related application

本申請案主張2014年2月26日申請之美國臨時申請案第61/944,899號的優先權。 The present application claims priority to US Provisional Application No. 61/944,899, filed on Feb. 26, 2014.

本發明係關於可用於生產安全氣囊的由基於多聚合物之紗形成之編織物。 This invention relates to woven fabrics formed from multi-polymer based yarns that can be used to produce airbags.

可充氣安全氣囊為車輛安全系統之關鍵組件。如本文所用,「安全氣囊」意謂用於汽車及許多其他運輸形式,包括軍事及航空應用之可充氣被動安全約束。安全氣囊為一種形式之可充氣被動安全約束裝置,其現為汽車使用中之標準物。近年來,安全氣囊數目及此等安全氣囊之覆蓋區已增加。在使用中的多種安全氣囊配置包括用於前座區、用於側撞保護、用於後座使用、用於頂篷區氣簾中及用於可充氣安全帶中之安全氣囊。 Inflatable airbags are a key component of vehicle safety systems. As used herein, "airbag" means an inflatable passive safety constraint for use in automobiles and many other forms of transportation, including military and aerospace applications. Airbags are a form of inflatable passive safety restraint that is now a standard in automotive use. In recent years, the number of airbags and the coverage of such airbags have increased. A variety of airbag configurations in use include airbags for front seat areas, for side impact protection, for rear seat use, for use in ceiling area air curtains, and for use in inflatable seat belts.

為滿足有效充氣之要求,安全氣囊織物必須具有受控的低透氣性。儘管諸如紗之線性密度、撚係數、織紋結構及厚度及重量之織物特性全部影響透氣性,通常需要添加塗層或額外層至安全氣囊織物以滿足工業標準。 To meet the requirements for effective inflation, airbag fabrics must have controlled low gas permeability. While fabric properties such as linear density of yarn, twist coefficient, textured structure, and thickness and weight all affect breathability, it is often desirable to add a coating or additional layer to the airbag fabric to meet industry standards.

為滿足有效充氣之要求,安全氣囊織物必須具有抵抗空氣通過 之能力,其藉由透氣性及孔隙率測試。因此,需要編織耐綸或聚酯安全氣囊具有極低孔隙率及相應較低的透氣性。儘管諸如紗之線性密度、撚係數、織紋結構及厚度及重量之織物特性全部影響透氣性,通常需要添加塗層或額外層至安全氣囊織物以滿足工業標準。 In order to meet the requirements of effective inflation, airbag fabrics must have resistance to air passage. The ability to test by gas permeability and porosity. Therefore, it is required to weave a nylon or polyester airbag having a very low porosity and a correspondingly low gas permeability. While fabric properties such as linear density of yarn, twist coefficient, textured structure, and thickness and weight all affect breathability, it is often desirable to add a coating or additional layer to the airbag fabric to meet industry standards.

已知具有各種塗層以減小滲透性之聚酯及聚醯胺織物。美國專利第5,897,929號描述一種塗佈有聚醯胺材料之氣孔之聚酯或聚醯胺織物。美國專利第5,110,666號描述一種通常塗佈有提供一定滲透性、可撓性、韌性、耐熱性及其他特性之聚碳酸酯-聚醚聚胺基甲酸酯之織物基底。美國專利第5,076,975號描述一種形成具有定義形狀之彈性體塗佈織物之成型操作。美國專利第5,763,330號描述一種將聚乙烯樹脂擠壓塗佈至耐綸織物上之方法。 Polyester and polyamide fabrics are known which have various coatings to reduce permeability. U.S. Patent No. 5,897,929 describes a polyester or polyamide fabric coated with pores of a polyamide material. U.S. Patent No. 5,110,666 describes a fabric substrate that is typically coated with a polycarbonate-polyether polyurethane that provides some permeability, flexibility, toughness, heat resistance and other characteristics. U.S. Patent No. 5,076,975 describes a forming operation for forming an elastomer coated fabric having a defined shape. U.S. Patent No. 5,763,330 describes a method of extrusion coating a polyethylene resin onto a nylon fabric.

傳統地加工空氣袋之編織物亦可塗佈有彈性材料(尤其為聚矽氧橡膠)以管理織物之透氣性。此外,塗佈方法為緩慢且費力的方法,其增加安全氣囊墊織物之成本且用於塗佈中之典型聚矽氧彈性體亦為昂貴的。因此,過去數年已尋求塗佈之替代方案。然而,此等替代方案涉及其他方法步驟及更多複雜性。另外,無替代技術已在商業上成功且未達成安全氣囊墊應用中所需的所有關鍵效能參數之最佳效能。 The braid of the conventionally processed air bag may also be coated with an elastic material (especially a polyoxymethylene rubber) to manage the breathability of the fabric. In addition, the coating method is a slow and laborious method that increases the cost of the airbag cushion fabric and is also expensive for typical polyoxyxene elastomers used in coating. Therefore, alternatives to coating have been sought in the past few years. However, such alternatives involve other method steps and more complexity. In addition, no replacement technology has been commercially successful and does not achieve the best performance of all the key performance parameters required in airbag pad applications.

因此,在此項技術中需要一種不需要塗層且仍可滿足諸如低透氣性及孔隙率之關鍵效能標準之安全氣囊織物。 Accordingly, there is a need in the art for an airbag fabric that does not require a coating and that still meets key performance criteria such as low gas permeability and porosity.

本發明係關於一種包含多根聚合物紗之編織物及生產及使用此類織物之方法。 This invention relates to a woven fabric comprising a plurality of polymeric yarns and a method of producing and using such woven fabrics.

因此,在本發明之一個態樣中,係關於一種包含底紗及第二紗之編織物,其中第二紗交織至底紗中,且其中第二紗之熔點低於底紗之熔點。 Accordingly, in one aspect of the invention, a braid comprising a ground yarn and a second yarn, wherein the second yarn is interwoven into the ground yarn, and wherein the melting point of the second yarn is lower than the melting point of the ground yarn.

在一個非限制性實施例中,編織物含有間隙且第二紗的至少一 部分已熔融,使得底紗之間的間隙藉由第二紗之熔融部分橋接。 In one non-limiting embodiment, the braid contains a gap and at least one of the second yarns The portion has been melted such that the gap between the ground yarns is bridged by the molten portion of the second yarn.

在另一非限制性實施例中,織物具有介於80至450公克/平方公尺範圍內之基重。 In another non-limiting embodiment, the fabric has a basis weight in the range of from 80 to 450 grams per square meter.

在另一非限制性實施例中,第二紗以10至40重量%之範圍存在於織物中。 In another non-limiting embodiment, the second yarn is present in the fabric in the range of 10 to 40% by weight.

在另一非限制性實施例中,底紗由聚醯胺纖維形成。在另一非限制性實施例中,底紗由聚酯纖維形成。 In another non-limiting embodiment, the ground yarn is formed from polyamide fibers. In another non-limiting embodiment, the ground yarn is formed from polyester fibers.

在另一非限制性實施例中,第二紗具有介於20至800分特(decitex)範圍內之線性質量密度。 In another non-limiting embodiment, the second yarn has a linear mass density in the range of 20 to 800 decitex.

在另一非限制性實施例中,第二紗由聚烯烴纖維形成。在另一非限制性實施例中,第二紗由高密度聚乙烯纖維形成。 In another non-limiting embodiment, the second yarn is formed from a polyolefin fiber. In another non-limiting embodiment, the second yarn is formed from high density polyethylene fibers.

在另一非限制性實施例中,編織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低50%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。 In another non-limiting embodiment, the braid has a gas permeability that is at least 50% lower than the air permeability of at least a portion of the second yarn prior to melting, such that the gap between the bottom yarns is melted by the second yarn. Partially bridged.

在另一非限制性實施例中,編織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低75%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。 In another non-limiting embodiment, the braid has a gas permeability that is at least 75% lower than the permeability of at least a portion of the second yarn prior to melting, such that the gap between the loops is melted by the second yarn. Partially bridged.

在另一非限制性實施例中,揭示一種包含來自本發明之各種實施例之編織物的安全氣囊。 In another non-limiting embodiment, an airbag incorporating a braid from various embodiments of the present invention is disclosed.

在本發明之另一態樣中,揭示一種熔化織物,其包含有含底紗之編織物,其中底紗含有間隙,及至少部分填充底紗中之間隙之填充材料。 In another aspect of the invention, a melted fabric comprising a woven fabric comprising a ground yarn, wherein the ground yarn comprises a gap, and a filler material at least partially filling a gap in the ground yarn, is disclosed.

本發明之另一態樣係關於製造經處理織物之方法。該方法包含以下步驟:交織底紗與第二紗以形成編織物,其中第二紗之熔點比底紗之熔點低,及將編織物加熱至第二紗之熔點以上及底紗之熔點以下之溫度,其中第二紗的至少一部分熔融以形成經處理織物。在另一非 限制性實施例中,揭示一種由此方法形成之經處理織物。在另一非限制性實施例中,揭示一種由此方法之經處理織物形成之安全氣囊。 Another aspect of the invention pertains to a method of making a treated fabric. The method comprises the steps of interlacing a base yarn and a second yarn to form a braid, wherein the second yarn has a lower melting point than the base yarn and heating the braid to a temperature above the melting point of the second yarn and below the melting point of the ground yarn Temperature wherein at least a portion of the second yarn is melted to form a treated fabric. In another non In a limiting embodiment, a treated fabric formed by this method is disclosed. In another non-limiting embodiment, an airbag formed from a treated fabric of this method is disclosed.

10‧‧‧黑紗 10‧‧‧Black yarn

20‧‧‧白紗 20‧‧‧White yarn

30‧‧‧PE紗 30‧‧‧PE yarn

40‧‧‧耐綸6,6紗 40‧‧‧Nylon 6,6 yarn

50‧‧‧PE組分 50‧‧‧PE components

60‧‧‧耐綸6,6紗 60‧‧‧Nylon 6,6 yarn

隨附圖式說明本發明之例示性實施例,且連同上文給出之一般描述及下文給出之詳細描述用以解釋(例如)本發明之原理。 The exemplary embodiments of the present invention are described by way of example, and the description

圖1為描繪織物中之HDPE之量及其耐熱性之間的關係之圖。 Figure 1 is a graph depicting the relationship between the amount of HDPE in a fabric and its heat resistance.

圖2為根據本發明之織物設計。 Figure 2 is a fabric design in accordance with the present invention.

圖3為經由根據本發明之織物設計之掃描電子顯微術獲得之影像。 Figure 3 is an image obtained by scanning electron microscopy of a fabric design in accordance with the present invention.

圖4A為根據本發明之織物設計之另一影像,其中第二紗顯示為熔融的且存在於織物之一側上。 4A is another image of a fabric design in accordance with the present invention in which the second yarn is shown to be molten and present on one side of the fabric.

圖4B為根據本發明之織物設計之另一影像,其中底紗顯示為織造的且存在於織物之一側上。 Figure 4B is another image of a fabric design in accordance with the present invention in which the ground yarn is shown to be woven and present on one side of the fabric.

在某些實施例中,本發明係關於一種經處理編織物及其製造方法,其中織物由底紗及至少一根第二紗形成。當相比於僅由基底織物製成之編織物或由基底織物及至少一根第二紗形成之編織物時,所得織物展現減小之透氣性及孔隙率。 In certain embodiments, the present invention is directed to a treated knit fabric and method of making the same, wherein the fabric is formed from a bottom yarn and at least one second yarn. The resulting fabric exhibits reduced gas permeability and porosity when compared to a woven fabric made only of a base fabric or a woven fabric formed from a base fabric and at least one second yarn.

以引用的方式併入在本文中所引用之所有專利、專利申請案、測試程序、優先權文件、文章、公開案、手冊及其他文件,引用之程度為該等揭示內容符合本發明及在所有權限中准許該併入。 All of the patents, patent applications, test procedures, priority documents, articles, publications, manuals, and other documents cited herein are incorporated by reference to the extent that the disclosures This incorporation is permitted in the permissions.

本發明之編織物包含底紗。底紗可以產生60至99.9重量%之編織物之範圍存在。在某些實施例中,底紗可例如以介於60至99.5%、60至99%、60至95%、60至90%、60至85%、60至80%、60至75%、65至99.9%、65至99.5%、65至99%、65至95%、65至90%、65至85%、65至80%、70至99.9%、70至99.5%、70至99%、70至95%、70至90%、 70至85%、70至80%、75至99.9%、75至99.5%、75至99%、75至95%、75至90%、80至99.9%、80至99.5%、80至99%及80至95%範圍內的量(全部以編織物之重量計)存在。底紗可選自任何適合之合成紗。可用於底紗之適合之合成紗之實例包括由聚醯胺或聚酯纖維形成之紗。 The woven fabric of the present invention comprises a ground yarn. The ground yarn can be present in a range of from 60 to 99.9% by weight of the woven fabric. In certain embodiments, the ground yarn can be, for example, between 60 and 99.5%, 60 to 99%, 60 to 95%, 60 to 90%, 60 to 85%, 60 to 80%, 60 to 75%, 65 Up to 99.9%, 65 to 99.5%, 65 to 99%, 65 to 95%, 65 to 90%, 65 to 85%, 65 to 80%, 70 to 99.9%, 70 to 99.5%, 70 to 99%, 70 To 95%, 70 to 90%, 70 to 85%, 70 to 80%, 75 to 99.9%, 75 to 99.5%, 75 to 99%, 75 to 95%, 75 to 90%, 80 to 99.9%, 80 to 99.5%, 80 to 99% and The amount in the range of 80 to 95% (all based on the weight of the woven fabric) is present. The ground yarn can be selected from any suitable synthetic yarn. Examples of suitable synthetic yarns that can be used for the ground yarn include yarns formed from polyamide or polyester fibers.

適合之聚醯胺纖維具有介於100至950分特,諸如200至900分特、250至850分特、300至850分特、350至850分特、400至850分特、400至800分特及450至800分特範圍內之線性質量密度。適合之聚醯胺纖維包括由耐綸6,6、耐綸6、耐綸6,12、耐綸12、耐綸4,6或其共聚物或摻合物形成之彼等纖維。在本發明之一個非限制性實施例中,底紗由耐綸6,6纖維形成。 Suitable polyamide fibers have a basis weight of from 100 to 950 dtex, such as from 200 to 900 dtex, from 250 to 850 dtex, from 300 to 850 dtex, from 350 to 850 dtex, from 400 to 850 dtex, from 400 to 800 Linear mass density in the range of 450 to 800 dtex. Suitable polyamide fibers include those formed from nylon 6,6, nylon 6, nylon 6,12, nylon 12, nylon 4,6 or copolymers or blends thereof. In one non-limiting embodiment of the invention, the ground yarn is formed from nylon 6,6 fibers.

適合之聚酯纖維具有在200至950分特,諸如300至900分特、300至850分特、350至850分特、400至850分特、400至800分特、450至800分特及500至800分特範圍內之線性質量密度。適合之聚酯纖維包括由以下形成之彼等聚酯纖維:聚對苯二甲酸乙二酯(PET)、聚對苯二甲酸伸丁酯、聚萘二甲酸乙二酯、聚萘二甲酸伸丁酯、聚伸乙基-1,2-雙(苯氧基)乙烷-4,4'-二甲酸酯、聚(對苯二甲酸1,4-伸環己基-二亞甲酯)及包含上文所提及之聚合物之至少一種類型之重複單元的共聚物,例如聚對苯二甲酸乙二酯/聚間苯二甲酸乙二酯共聚酯、聚對苯二甲酸伸丁酯/聚萘二甲酸伸丁酯共聚酯、聚對苯二甲酸伸丁酯/聚癸烷二甲酸伸丁酯共聚酯或其共聚物或摻合物。在本發明之一個非限制性實施例中,底紗由PET纖維形成。 Suitable polyester fibers have a basis weight of from 200 to 950 dtex, such as from 300 to 900 dtex, from 300 to 850 dtex, from 350 to 850 dtex, from 400 to 850 dtex, from 400 to 800 dtex, and from 450 to 800 dtex. Linear mass density in the range of 500 to 800 dtex. Suitable polyester fibers include the polyester fibers formed from the following: polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate, polyethylene naphthalate Butyl ester, polyethylidene-1,2-bis(phenoxy)ethane-4,4'-dicarboxylate, poly(1,4-cyclohexyl-dimethylene terephthalate) And a copolymer comprising at least one type of repeating unit of the above-mentioned polymers, such as polyethylene terephthalate/polyethylene isophthalate copolyester, polybutylene terephthalate Ester/polybutylene naphthalate butyl acrylate copolyester, polybutylene terephthalate/polydecane dicarboxylic acid butyl acrylate copolyester or copolymer or blend thereof. In one non-limiting embodiment of the invention, the ground yarn is formed from PET fibers.

本發明之編織物進一步包含可以產生0.1至40重量%之編織物之範圍存在的第二紗。在某些實施例中,第二紗可例如以介於0.1至35%、0.1至30%、0.1至25%、0.1至20%、0.5至40%、0.5至35%、0.5至30%、0.5至25%、0.5至20%、1至40%、1至35%、1至30%、1至 25%、1至20%、5至40%、5至35%、5至30%、5至25%、5至20%、10至40%、10至35%、10至30%、10至25%、10至20%、15至40%、15至35%、15至30%、20至40%及20至35%範圍內的量(全部以編織物之重量計)存在。第二紗可選自熔點低於底紗之熔點的任何適合之合成紗。適合之第二紗包括具有在20至800分特範圍內之線性質量密度及在攝氏60度至攝氏160度範圍內之熔點的合成紗。在某些實施例中,第二紗可例如具有介於100至700分特、150至500分特、200至600分特、250至550分特、300至550分特及300至500分特範圍內的線性質量密度。在其他實施例中,第二紗可例如具有介於攝氏80度至攝氏160度、攝氏90度至攝氏160度、攝氏100度至攝氏160度、攝氏110度至攝氏160度、攝氏120度至攝氏160度、攝氏60度至攝氏155度、攝氏80度至攝氏155度、攝氏90度至攝氏155度、攝氏100度至攝氏155度、攝氏110度至攝氏155度、攝氏120度至攝氏155度、攝氏80度至攝氏150度、攝氏90度至攝氏150度、攝氏100度至攝氏150度、攝氏110度至攝氏150度及攝氏120度至攝氏150度範圍內的熔點。適合之合成紗之實例係由聚烯烴及共聚醯胺單絲縫合紗形成。適合之聚烯烴紗包括(但不限於)由聚乙烯或高密度聚乙烯(HDPE)纖維形成之彼等聚烯烴紗。在本發明之一個非限制性實施例中,底紗係由HDPE纖維形成。 The woven fabric of the present invention further comprises a second yarn which is present in a range which produces from 0.1 to 40% by weight of the woven fabric. In certain embodiments, the second yarn can be, for example, between 0.1 and 35%, 0.1 to 30%, 0.1 to 25%, 0.1 to 20%, 0.5 to 40%, 0.5 to 35%, 0.5 to 30%, 0.5 to 25%, 0.5 to 20%, 1 to 40%, 1 to 35%, 1 to 30%, 1 to 25%, 1 to 20%, 5 to 40%, 5 to 35%, 5 to 30%, 5 to 25%, 5 to 20%, 10 to 40%, 10 to 35%, 10 to 30%, 10 to The amounts in the range of 25%, 10 to 20%, 15 to 40%, 15 to 35%, 15 to 30%, 20 to 40%, and 20 to 35% (all based on the weight of the woven fabric) are present. The second yarn may be selected from any suitable synthetic yarn having a melting point below the melting point of the base yarn. Suitable second yarns include synthetic yarns having a linear mass density in the range of 20 to 800 dtex and a melting point in the range of 60 degrees Celsius to 160 degrees Celsius. In certain embodiments, the second yarn can have, for example, between 100 and 700 dtex, 150 to 500 dtex, 200 to 600 dtex, 250 to 550 dtex, 300 to 550 dtex, and 300 to 500 dtex. Linear mass density within the range. In other embodiments, the second yarn may have, for example, between 80 degrees Celsius and 160 degrees Celsius, 90 degrees Celsius to 160 degrees Celsius, 100 degrees Celsius to 160 degrees Celsius, 110 degrees Celsius to 160 degrees Celsius, 120 degrees Celsius to 160 ° C, 60 ° C to 155 ° C, 80 ° C to 155 ° C, 90 ° C to 155 ° C, 100 ° C to 155 ° C, 110 ° C to 155 ° C, 120 ° C to 155 Celsius Melting point, in the range of 80 ° C to 150 ° C, 90 ° C to 150 ° C, 100 ° C to 150 ° C, 110 ° C to 150 ° C and 120 ° C to 150 ° C. Examples of suitable synthetic yarns are formed from polyolefin and copolyamide monofilament stitching yarns. Suitable polyolefin yarns include, but are not limited to, polyolefin yarns formed from polyethylene or high density polyethylene (HDPE) fibers. In one non-limiting embodiment of the invention, the ground yarn is formed from HDPE fibers.

第二紗亦可包含不同材料之纖維及長絲。若使用含有一種以上纖維或長絲類型之第二紗,則僅彼等纖維或長絲類型中之一者將需要具有低於底紗之熔點的熔點。在一個非限制性實施例中,第二紗可含有聚醯胺及聚烯烴纖維及長絲之混合物。 The second yarn may also comprise fibers and filaments of different materials. If a second yarn of more than one type of fiber or filament is used, only one of its fiber or filament types would need to have a melting point below the melting point of the ground yarn. In one non-limiting embodiment, the second yarn may comprise a mixture of polyamidamine and polyolefin fibers and filaments.

用於形成底紗及第二紗之纖維亦可包含用於生產及加工纖維之各種添加劑。適合之添加劑包括(但不限於)熱穩定劑、抗氧化劑、光穩定劑、平滑劑、抗靜電劑、塑化劑、增稠劑、顏料、阻燃劑或其組合。 The fibers used to form the bottom and second yarns may also contain various additives for the production and processing of the fibers. Suitable additives include, but are not limited to, heat stabilizers, antioxidants, light stabilizers, smoothing agents, antistatic agents, plasticizers, thickeners, pigments, flame retardants, or combinations thereof.

本發明之編織物可使用此項技術中已知之編織技術由經紗及緯紗形成。適合之編織技術包括(但不限於)平紋編織、斜紋編織、緞紋編織、此等類型之經修改編織或多軸編織。可用於編織之適合之織機包括噴水織機、噴氣織機或劍桅式織機。適合之本發明之編織物具有在80至450公克/平方公尺範圍內之總基重。在某些實施例中,編織物之總基重可在100至450公克每平方公尺、100至400公克/平方公尺、100至350公克/平方公尺、150至450公克/平方公尺、150至400公克/平方公尺、150至350公克/平方公尺、200至450公克/平方公尺、200至400公克/平方公尺、200至350公克/平方公尺、250至450公克/平方公尺、250至400公克/平方公尺及250至350公克/平方公尺範圍內變化。 The woven fabric of the present invention can be formed from warp and weft yarns using weaving techniques known in the art. Suitable weaving techniques include, but are not limited to, plain weave, twill weave, satin weave, modified weave or multi-axial weave of these types. Suitable weaving machines for weaving include water jet loom, air jet loom or sword looms. Suitable braids of the present invention have a total basis weight in the range of from 80 to 450 grams per square meter. In certain embodiments, the braid may have a total basis weight of from 100 to 450 grams per square meter, from 100 to 400 grams per square meter, from 100 to 350 grams per square meter, from 150 to 450 grams per square meter. 150 to 400 g/m2, 150 to 350 g/m2, 200 to 450 g/m2, 200 to 400 g/m2, 200 to 350 g/m2, 250 to 450 g / m ^ 2 , 250 to 400 g / m ^ 2 and 250 to 350 g / m ^ 2 range.

表1概述適合之本發明之實施例。 Table 1 summarizes suitable embodiments of the invention.

在本發明之一個實施例中,第二紗交織至底紗中,其中且第二紗的至少一部分已熔融,使得底紗之間的間隙藉由第二紗之熔融部分橋接。不受任何特定理論束縛,咸信第二紗之熔融部分填充編織物中之間隙以減小編織物之透氣性及孔隙率。 In one embodiment of the invention, the second yarn is interwoven into the bottom yarn, wherein at least a portion of the second yarn has been melted such that the gap between the bottom yarns is bridged by the molten portion of the second yarn. Without being bound by any particular theory, it is believed that the molten portion of the second yarn fills the gap in the braid to reduce the gas permeability and porosity of the braid.

在本發明之一個實施例中,編織物之透氣性比僅由底紗以相同織物結構形成之編織物之透氣性低至少50%。在本發明之另一實施例中,編織物之透氣性比僅由底紗以相同織物結構形成之編織物之透氣性低至少75%。在其他實施例中,編織物之透氣性比僅由底紗以相同織物結構形成之編織物之透氣性低以下量:至少80%、至少85%、至少90%及至少95%。 In one embodiment of the invention, the woven fabric has a gas permeability that is at least 50% lower than the woven fabric formed from the same woven fabric of the same woven fabric. In another embodiment of the invention, the woven fabric has a gas permeability that is at least 75% lower than the woven fabric formed from the same woven fabric of the same woven fabric. In other embodiments, the woven fabric has a gas permeability that is less than the permeability of the woven fabric formed from the same yarn structure only by the bottom yarn: at least 80%, at least 85%, at least 90%, and at least 95%.

在本發明之一個實施例中,編織物之孔隙率比僅由底紗以相同織物結構形成之編織物之孔隙率低至少50%。在本發明之另一實施例中,編織物之孔隙率比僅由底紗以相同織物結構形成之編織物之孔隙率低至少75%。在其他實施例中,編織物之孔隙率比僅由底紗以相同織物結構形成之編織物之孔隙率低以下量:至少80%、至少85%、至少90%及至少95%。 In one embodiment of the invention, the porosity of the woven fabric is at least 50% lower than the porosity of the woven fabric formed from the same yarn structure only by the ground yarn. In another embodiment of the invention, the porosity of the woven fabric is at least 75% lower than the porosity of the woven fabric formed from the same yarn structure only by the ground yarn. In other embodiments, the porosity of the woven fabric is less than the porosity of the woven fabric formed from only the bottom woven fabric in the same fabric structure: at least 80%, at least 85%, at least 90%, and at least 95%.

在本發明之一個實施例中,編織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低50%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。 In one embodiment of the invention, the braid has a gas permeability that is at least 50% lower than the air permeability of at least a portion of the second yarn prior to melting, such that the gap between the bottom yarns is melted by the second yarn. bridging.

在本發明之一個實施例中,編織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低75%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。在其他實施例中,編織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低以下量,使得底紗之間的間隙藉由第二紗之熔融部分橋接:至少80%、至少85%、至少90%及至少95%。 In one embodiment of the invention, the woven fabric has a gas permeability at least 75% lower than the woven fabric of at least a portion of the second yam prior to melting, such that the gap between the yams is melted by the second yarn. bridging. In other embodiments, the braid is at least less gas permeable than the at least a portion of the second yarn prior to melting, such that the gap between the loops is bridged by the molten portion of the second yarn: at least 80%, at least 85%, at least 90% and at least 95%.

在本發明之一個實施例中,編織物之孔隙率至少比第二紗的至少一部分經熔融之前的編織物之孔隙率低50%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。在本發明之另一實施例中,編織物之孔隙率至少比第二紗的至少一部分經熔融之前的編織物之孔隙率低75%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。在其他實施例中,編織物之孔隙率至少比第二紗的至少一部分經熔融之前的編織物之孔隙率低以下量,使得底紗之間的間隙藉由第二紗之熔融部分橋接:至少80%、至少85%、至少90%及至少95%。 In one embodiment of the invention, the porosity of the woven fabric is at least 50% lower than the porosity of the woven fabric prior to melting of at least a portion of the second yarn such that the gap between the yams is melted by the fused portion of the second yarn bridging. In another embodiment of the invention, the porosity of the woven fabric is at least 75% lower than the porosity of the woven fabric prior to melting of at least a portion of the second yarn, such that the gap between the yams is melted by the second yarn. Partially bridged. In other embodiments, the porosity of the braid is at least less than the porosity of the knitted fabric prior to melting of at least a portion of the second yarn such that the gap between the bottom yarns is bridged by the molten portion of the second yarn: at least 80%, at least 85%, at least 90% and at least 95%.

在本發明之另一態樣中,揭示一種熔化織物,其包含有含底紗之編織物,其中底紗含有間隙;及至少部分填充底紗中之間隙之填充材料。 In another aspect of the invention, a melted fabric comprising a woven fabric comprising a ground yarn, wherein the ground yarn comprises a gap; and a filler material at least partially filling a gap in the bottom yarn is disclosed.

在此等實施例中,且如上文所述,底紗可以產生60至99.9重量%之熔化織物之範圍存在。如上文所述,底紗可選自任何適合之合成紗。可用於底紗之適合之合成紗之實例包括由聚醯胺或聚酯纖維形成之紗。 In such embodiments, and as described above, the ground yarn may be present in a range of from 60 to 99.9% by weight of the melted fabric. As mentioned above, the ground yarn can be selected from any suitable synthetic yarn. Examples of suitable synthetic yarns that can be used for the ground yarn include yarns formed from polyamide or polyester fibers.

適合之聚醯胺纖維具有介於100至950分特範圍內之線性質量密度。適合之聚醯胺纖維包括由耐綸6,6、耐綸6、耐綸6,12、耐綸12、 耐綸4,6或其共聚物或摻合物形成之彼等纖維。在本發明之一個非限制性實施例中,底紗由耐綸6,6纖維形成。 Suitable polyamide fibers have a linear mass density in the range of from 100 to 950 dtex. Suitable polyamide fibers include nylon 6,6, nylon 6, nylon 6,12, nylon 12, Nylon 4, 6 or a copolymer or blend thereof forms the same fibers. In one non-limiting embodiment of the invention, the ground yarn is formed from nylon 6,6 fibers.

適合之聚酯纖維具有在200至950分特範圍內之線性質量密度。適合之聚酯纖維包括由聚對苯二甲酸乙二酯(PET)、聚對苯二甲酸伸丁酯、聚萘二甲酸乙二酯、聚萘二甲酸伸丁酯、聚伸乙基-1,2-雙(苯氧基)乙烷-4,4'-二甲酸酯、聚(對苯二甲酸1,4-伸環己基-二亞甲酯)及包含上文所提及之聚合物之至少一種類型之重複單元的共聚物,例如聚對苯二甲酸乙二酯/間苯二甲酸酯共聚酯、聚對苯二甲酸伸丁酯/萘二甲酸酯共聚酯、聚對苯二甲酸伸丁酯/癸烷二羧酸酯共聚酯或其共聚物或摻合物形成之彼等聚酯纖維。在本發明之一個非限制性實施例中,底紗由PET纖維形成。 Suitable polyester fibers have a linear mass density in the range of from 200 to 950 dtex. Suitable polyester fibers include polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene-1 , 2-bis(phenoxy)ethane-4,4'-dicarboxylate, poly(1,4-cyclohexyl-dimethylene terephthalate) and comprising the polymerization mentioned above a copolymer of at least one type of repeating unit, such as polyethylene terephthalate/isophthalate copolyester, polybutylene terephthalate/naphthalate copolyester, Polyester fibers formed from polybutylene terephthalate/decane dicarboxylate copolyester or copolymers or blends thereof. In one non-limiting embodiment of the invention, the ground yarn is formed from PET fibers.

本發明之熔化織物進一步包含可以產生0.1至40重量%之經處理織物之範圍存在的填充材料。在某些實施例中,填充材料可例如以介於0.1至35%、0.1至30%、0.1至25%、0.1至20%、0.5至40%、0.5至35%、0.5至30%、0.5至25%、0.5至20%、1至40%、1至35%、1至30%、1至25%、1至20%、5至40%、5至35%、5至30%、5至25%、5至20%、10至40%、10至35%、10至30%、10至25%、10至20%、15至40%、15至35%、15至30%、20至40%及20至35%範圍內的量(全部以熔化織物之重量計)存在。填充材料可選自熔點低於底紗之熔點的任何適合之合成聚合物。適合之合成聚合物之實例為聚烯烴,諸如上文所述之彼等者。適合之聚烯烴包括(但不限於)由聚乙烯或高密度聚乙烯(HDPE)纖維形成之彼等聚烯烴。在本發明之一個非限制性實施例中,填充材料為HDPE。 The molten fabric of the present invention further comprises a filler material which can be present in the range of from 0.1 to 40% by weight of the treated fabric. In certain embodiments, the filler material can be, for example, between 0.1 and 35%, 0.1 to 30%, 0.1 to 25%, 0.1 to 20%, 0.5 to 40%, 0.5 to 35%, 0.5 to 30%, 0.5. Up to 25%, 0.5 to 20%, 1 to 40%, 1 to 35%, 1 to 30%, 1 to 25%, 1 to 20%, 5 to 40%, 5 to 35%, 5 to 30%, 5 Up to 25%, 5 to 20%, 10 to 40%, 10 to 35%, 10 to 30%, 10 to 25%, 10 to 20%, 15 to 40%, 15 to 35%, 15 to 30%, 20 The amount in the range of 40% and 20 to 35% (all based on the weight of the melted fabric) is present. The filler material can be selected from any suitable synthetic polymer having a melting point below the melting point of the base yarn. Examples of suitable synthetic polymers are polyolefins, such as those described above. Suitable polyolefins include, but are not limited to, those polyolefins formed from polyethylene or high density polyethylene (HDPE) fibers. In one non-limiting embodiment of the invention, the filler material is HDPE.

本發明亦提供由本文揭示之編織物及熔化織物形成之安全氣囊。如本文所用之術語安全氣囊包括安全氣囊墊。安全氣囊墊通常由多組織物形成且可快速充氣。 The present invention also provides an airbag formed from the woven fabric and the melted fabric disclosed herein. The term airbag as used herein includes an airbag cushion. Airbag pads are typically formed from multiple tissues and can be inflated quickly.

本發明亦提供製造經處理織物之方法。可將來自此等方法之經處理織物用於生產安全氣囊。可用於許多工業應用(諸如安全氣囊)中之編織物需要滿足機械及效能標準,同時限制總織物重量及成本之織物。 The invention also provides a method of making a treated fabric. Treated fabrics from such methods can be used to produce airbags. Knits that can be used in many industrial applications, such as airbags, require fabrics that meet mechanical and performance criteria while limiting overall fabric weight and cost.

在此等方法中,底紗與第二紗交織形成編織物,其中第二紗之熔點低於底紗之熔點。已知曉用於編織紗之各種方法及裝置且其可用於生產本發明之織物。適合之編織技術包括(但不限於)平紋編織、斜紋編織、緞紋編織、此等類型之經修改編織或多軸編織。適合之織機包括(但不限於)噴水織機、噴氣織機或劍桅式織機。如上文所述,適合之本發明之編織物具有在80至450公克/平方公尺範圍內之基重。 In such methods, the ground yarn is interwoven with the second yarn to form a braid, wherein the second yarn has a melting point lower than the melting point of the base yarn. Various methods and devices for weaving yarns are known and can be used to produce the fabrics of the present invention. Suitable weaving techniques include, but are not limited to, plain weave, twill weave, satin weave, modified weave or multi-axial weave of these types. Suitable weaving machines include, but are not limited to, water jet loom, air jet loom or sword looms. As noted above, suitable braids of the present invention have a basis weight in the range of from 80 to 450 grams per square meter.

在一個實施例中,將編織物加熱至第二紗之熔點以上及底紗之熔點以下之溫度,其中第二紗的至少一部分熔融以形成經處理織物。可使用各種用於熔融一部分第二紗之方法。在一個非限制性實施例中,編織物經壓延以熔融或軟化第二紗,使得編織物之間隙經熔融或軟化之第二紗填充。 In one embodiment, the braid is heated to a temperature above the melting point of the second yarn and below the melting point of the ground yarn, wherein at least a portion of the second yarn is melted to form a treated fabric. Various methods for melting a portion of the second yarn can be used. In one non-limiting embodiment, the braid is calendered to melt or soften the second yarn such that the gap of the braid is filled with the second yarn that is melted or softened.

如熟習此項技術者在閱讀本發明後將理解,有導致熔融第二紗的至少一部分之本文中例示之方法及裝置之替代方法及裝置可資利用且本發明包含其用途。 As will be appreciated by those skilled in the art after reading the present invention, alternative methods and apparatus for the methods and apparatus exemplified herein that result in melting at least a portion of the second yarn are available and the invention encompasses its use.

如上文所述,底紗可以產生60至99.9重量%之編織物之範圍存在。底紗可選自任何適合之合成紗。可用於底紗之適合之合成紗之實例包括由聚醯胺或聚酯纖維形成之紗。 As mentioned above, the ground yarn can be present in the range of from 60 to 99.9% by weight of the woven fabric. The ground yarn can be selected from any suitable synthetic yarn. Examples of suitable synthetic yarns that can be used for the ground yarn include yarns formed from polyamide or polyester fibers.

如上文所述,適合之聚醯胺纖維具有介於100至950分特範圍內之線性質量密度。適合之聚醯胺纖維包括由耐綸6,6、耐綸6、耐綸6,12、耐綸12、耐綸4,6或其共聚物或摻合物形成之彼等纖維。在本發明之一個實施例中,底紗係由耐綸6,6纖維形成。 As noted above, suitable polyamide fibers have a linear mass density in the range of from 100 to 950 dtex. Suitable polyamide fibers include those formed from nylon 6,6, nylon 6, nylon 6,12, nylon 12, nylon 4,6 or copolymers or blends thereof. In one embodiment of the invention, the bottom yarn is formed from nylon 6,6 fibers.

適合之聚酯纖維具有在200至950分特範圍內之線性質量密度。 適合之聚酯纖維包括由聚對苯二甲酸乙二酯(PET)、聚對苯二甲酸伸丁酯、聚萘二甲酸乙二酯、聚萘二甲酸伸丁酯、聚伸乙基-1,2-雙(苯氧基)乙烷-4,4'-二甲酸酯、聚(對苯二甲酸1,4-伸環己基-二亞甲酯)及包含上文所提及之聚合物之至少一種類型之重複單元的共聚物,例如聚對苯二甲酸乙二酯/間苯二甲酸酯共聚酯、聚對苯二甲酸伸丁酯/萘二甲酸酯共聚酯、聚對苯二甲酸伸丁酯/癸烷二羧酸酯共聚酯或其共聚物或摻合物形成之彼等聚酯纖維。在本發明之一個實施例中,底紗由PET纖維形成。 Suitable polyester fibers have a linear mass density in the range of from 200 to 950 dtex. Suitable polyester fibers include polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene-1 , 2-bis(phenoxy)ethane-4,4'-dicarboxylate, poly(1,4-cyclohexyl-dimethylene terephthalate) and comprising the polymerization mentioned above a copolymer of at least one type of repeating unit, such as polyethylene terephthalate/isophthalate copolyester, polybutylene terephthalate/naphthalate copolyester, Polyester fibers formed from polybutylene terephthalate/decane dicarboxylate copolyester or copolymers or blends thereof. In one embodiment of the invention, the ground yarn is formed from PET fibers.

此方法之編織物進一步包含第二紗,如上文所述,其可以產生0.1至40重量%之編織物之範圍存在。第二紗可選自熔點低於底紗之熔點的任何適合之合成紗。適合之第二紗包括具有在20至800分特範圍內之線性質量密度及在攝氏60度至攝氏160度範圍內之熔點的合成紗。適合之合成紗之實例由聚烯烴及共聚醯胺單絲縫合紗形成。適合之聚烯烴紗包括(但不限於)由聚乙烯或高密度聚乙烯(HDPE)纖維形成之彼等聚烯烴紗。在生產本發明之安全氣囊之一個實施例中,底紗由HDPE纖維形成。 The knit of this method further comprises a second yarn which, as described above, can be present in the range of from 0.1 to 40% by weight of the knit. The second yarn may be selected from any suitable synthetic yarn having a melting point below the melting point of the base yarn. Suitable second yarns include synthetic yarns having a linear mass density in the range of 20 to 800 dtex and a melting point in the range of 60 degrees Celsius to 160 degrees Celsius. Examples of suitable synthetic yarns are formed from polyolefin and copolyamide monofilament stitching yarns. Suitable polyolefin yarns include, but are not limited to, polyolefin yarns formed from polyethylene or high density polyethylene (HDPE) fibers. In one embodiment of producing the airbag of the present invention, the ground yarn is formed from HDPE fibers.

第二紗亦可由不同材料之纖維及長絲組成。若使用含有一種以上纖維或長絲類型之第二紗,則僅彼等纖維或長絲類型中之一者將需要具有低於底紗之熔點的熔點。在一個非限制性實施例中,第二紗可含有聚醯胺及聚烯烴纖維及長絲之混合物。 The second yarn may also be composed of fibers and filaments of different materials. If a second yarn of more than one type of fiber or filament is used, only one of its fiber or filament types would need to have a melting point below the melting point of the ground yarn. In one non-limiting embodiment, the second yarn may comprise a mixture of polyamidamine and polyolefin fibers and filaments.

用於形成底紗及第二紗之纖維亦可包含用於生產及加工纖維之各種添加劑。適合之添加劑包括(但不限於)熱穩定劑、抗氧化劑、光穩定劑、平滑劑、抗靜電劑、塑化劑、增稠劑、顏料、阻燃劑或其組合。 The fibers used to form the bottom and second yarns may also contain various additives for the production and processing of the fibers. Suitable additives include, but are not limited to, heat stabilizers, antioxidants, light stabilizers, smoothing agents, antistatic agents, plasticizers, thickeners, pigments, flame retardants, or combinations thereof.

需要本發明之方法之經處理織物具有比僅由底紗形成之編織物顯著較低的透氣性及/或孔隙率。此將允許本文揭示之經處理織物在 不需要塗覆塗層、膜或非編織品的情況下用於諸如安全氣囊的工業應用中。在該方法之一個實施例中,經處理織物之透氣性比僅由底紗以相同織物結構形成之編織物之透氣性低至少50%。如上文所述,其他實施例涵蓋透氣性比僅由底紗以相同織物結構形成之編織物之透氣性低以下量之經處理織物:至少75%、至少80%、至少85%、至少90%及至少95%。在本發明之另一實施例中,經處理織物之孔隙率比僅由底紗以相同織物結構形成之編織物之孔隙率低至少50%。如上文所述,其他實施例涵蓋孔隙率比僅由底紗以相同織物結構形成之編織物之孔隙率低以下量之編織物或經處理織物:至少75%、至少80%、至少85%、至少90%及至少95%。 Treated fabrics that require the method of the present invention have significantly lower gas permeability and/or porosity than braids formed only from the ground yarn. This will allow the treated fabric disclosed herein to be It is not used in industrial applications such as airbags where coating, film or nonwovens are not required. In one embodiment of the method, the treated fabric has a gas permeability that is at least 50% lower than the air permeability of the woven fabric formed from the same yarn structure only by the ground yarn. As described above, other embodiments encompass a treated fabric having a gas permeability that is less than the breathability of a woven fabric formed from only the bottom yarn in the same fabric structure: at least 75%, at least 80%, at least 85%, at least 90%. And at least 95%. In another embodiment of the invention, the treated fabric has a porosity that is at least 50% lower than the porosity of the woven fabric formed from the same yarn structure only by the bottom yarn. As noted above, other embodiments encompass a woven or treated fabric having a porosity that is less than the porosity of the woven fabric formed from only the bottom woven fabric of the same fabric structure: at least 75%, at least 80%, at least 85%, At least 90% and at least 95%.

在本發明之方法之一個實施例中,經處理織物之透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低50%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。同樣,如上文所述,其他實施例涵蓋透氣性至少比第二紗的至少一部分經熔融之前的編織物之透氣性低以下量,使得底紗之間的間隙藉由第二紗之熔融部分橋接之經處理織物:至少75%、至少80%、至少85%、至少90%及至少95%。 In one embodiment of the method of the present invention, the treated fabric has a gas permeability at least 50% lower than the air permeability of at least a portion of the second yarn prior to melting, such that the gap between the ground yarns is by the second yarn The molten portion is bridged. Also, as described above, other embodiments encompass that the gas permeability is at least less than the gas permeability of at least a portion of the second yarn before being melted, such that the gap between the bottom yarns is bridged by the molten portion of the second yarn. Treated fabric: at least 75%, at least 80%, at least 85%, at least 90%, and at least 95%.

在本發明之方法之另一實施例中,經處理織物之孔隙率至少比第二紗的至少一部分經熔融之前的編織物之孔隙率低50%,使得底紗之間的間隙藉由第二紗之熔融部分橋接。同樣,如上文所述,其他實施例涵蓋孔隙率至少比第二紗的至少一部分經熔融之前的編織物之孔隙率低以下量,使得底紗之間的間隙藉由第二紗之熔融部分橋接之經處理織物:至少75%、至少80%、至少85%、至少90%及至少95%。 In another embodiment of the method of the present invention, the treated fabric has a porosity that is at least 50% lower than the porosity of the knitted fabric prior to melting of at least a portion of the second yarn, such that the gap between the ground yarns is second The molten portion of the yarn is bridged. Also, as described above, other embodiments contemplate that the porosity is at least less than the porosity of the knitted fabric prior to melting of at least a portion of the second yarn such that the gap between the ground yarns is bridged by the molten portion of the second yarn Treated fabric: at least 75%, at least 80%, at least 85%, at least 90%, and at least 95%.

織紋設計及結構規定第二紗於何處而將在壓延之後產生織物結構。舉例而言,平紋編織將在整個織物結構中產生第二紗之均勻分佈。吾人可根據織物之最終用途應用按需要選擇織紋設計。圖4顯示織物形成織紋設計,其中第二紗主要發現於織物之一側上。如在圖 4A中可見,在壓延之後,第二紗在織物之一側上形成層50。如在圖4B中可見,原紗在織物之另一側上保持於編織形式60。織物之機械特性主要藉由底紗指示,底紗在非限制性實施例中可為耐綸6,6。第二紗(其在非限制性實施例中可為聚乙烯)主要經由閉合紗間間隙以及經由有助於織物之耐熱性作出貢獻。添加劑亦可與熔融組分一起使用以進一步增強織物結構之耐熱性。 The weave design and structure specifies where the second yarn will produce a fabric structure after calendering. For example, plain weave will produce a uniform distribution of the second yarn throughout the fabric structure. We can choose the weave design according to the needs of the final use of the fabric. Figure 4 shows a fabric forming textured design in which a second yarn is primarily found on one side of the fabric. As shown in the figure It can be seen in 4A that after calendering, the second yarn forms a layer 50 on one side of the fabric. As can be seen in Figure 4B, the original yarn is held in a woven form 60 on the other side of the fabric. The mechanical properties of the fabric are primarily indicated by the ground yarn, which in the non-limiting embodiment may be nylon 6,6. The second yarn, which may be polyethylene in a non-limiting embodiment, contributes primarily by closing the inter-yarn gap and by contributing to the heat resistance of the fabric. Additives can also be used with the molten component to further enhance the heat resistance of the fabric structure.

實例Instance

以下實例展示本發明及其供使用之能力。本發明能具有其他及不同實施例,且在不偏離本發明之範疇及精神的情況下能夠在不同顯而易見的態樣中對其若干細節加以改動。因此,該等實例被視為本質上說明性且非限制性的。 The following examples demonstrate the invention and its ability to be used. The invention is capable of other and various embodiments and modifications may Accordingly, the examples are considered to be illustrative in nature and not limiting.

測試方法testing method

織物耐熱性測定:織物折衷熱微粒穿透之耐受性根據Barnes及Rawson[Barnes,J.A.,及Rawson,N.J.Proc.8th World Textile Congress,Industrial,Technical and High Performance Textiles,University of Huddersfield,1998年7月15-16日,第329-338頁]描述之測試方法測定。簡言之,具有0.9至44g之質量之一系列鋼穿透器用於施加熱負荷至織物樣品。記錄各加熱穿透器熔穿織物所需的靜時間,且根據方程式1計算轉化為入射能之轉化率:E=mρ△T (方程式1) Fabric Heat Resistance Measurement: Fabric Tolerance Thermal Particle Penetration Tolerance According to Barnes and Rawson [Barnes, JA, and Rawson, NJ Proc. 8th World Textile Congress, Industrial, Technical and High Performance Textiles, University of Huddersfield, July 1998 Test methods described in 15-16, pages 329-338]. Briefly, a series of steel penetrator having a mass of 0.9 to 44 g is used to apply a thermal load to the fabric sample. Record the static time required for each heated penetrator to penetrate the fabric, and calculate the conversion rate converted to incident energy according to Equation 1: E = mρ ΔT (Equation 1)

其中E=能量(J),m=質量(kg),ρ=比熱容[J/(kg*K)],且△T(K)為穿透器之初始溫度與環境溫度之間的差值。隨後構建熔融時間相對於入射能之曲線圖以給出織物樣品之比較效能之可靠測定。 Where E = energy (J), m = mass (kg), ρ = specific heat capacity [J / (kg * K)], and ΔT (K) is the difference between the initial temperature of the penetrator and the ambient temperature. A plot of melting time versus incident energy is then constructed to give a reliable measure of the comparative performance of the fabric sample.

織物之透氣性:根據ASTM D737測定織物之透氣性。 Breathability of fabric: The breathability of the fabric was determined according to ASTM D737.

實例1:Example 1:

將由耐綸6,6底紗製得之平紋編織物與高密度聚乙烯(HDPE)第二 紗一起縫合以形成編織物。將編織物加熱至攝氏135度之溫度。觀測到一部分HDPE第二紗熔融且填充編織物之間隙。 Plain weave fabric made of nylon 6,6 base yarn and high density polyethylene (HDPE) second The yarns are stitched together to form a braid. The braid is heated to a temperature of 135 degrees Celsius. A portion of the HDPE second yarn was observed to melt and fill the gap of the braid.

實例2Example 2

亦對於來自第一試驗之織物測試織物耐熱性。典型的安全氣囊織物塗佈有基於聚矽氧之彈性體以增加基底織物之耐熱性。如圖1中描繪之表中所示,增加織物中之HDPE之量使織物之耐熱性較高。 The fabric was also tested for heat resistance to the fabric from the first test. A typical airbag fabric is coated with a polyoxymethylene-based elastomer to increase the heat resistance of the base fabric. As shown in the table depicted in Figure 1, increasing the amount of HDPE in the fabric results in a higher heat resistance of the fabric.

在第二試驗中,將多絲PE紗用於織物建構物,其隨後經由壓延熔融以減小織物之透氣性。 In a second test, a multifilament PE yarn was used for the fabric construction, which was then melted by calendering to reduce the breathability of the fabric.

織物設計說明於圖2中,其中黑紗10表示上表中之所有結構中所述之PE,且白紗20表示耐綸6,6。當此結構在剛好位於PE紗之熔點以上之溫度下壓延時,其產生經由圖3中描繪之SEM橫截面顯示之封閉 氣孔結構,其中耐綸6,6紗40以其初始形式可見且PE紗30顯示為熔融的且填充耐綸6,6紗中之間隙。 The fabric design is illustrated in Figure 2, in which the black yarn 10 represents the PE described in all of the structures in the above table, and the white yarn 20 represents the nylon 6,6. When the structure is delayed at a temperature just above the melting point of the PE yarn, it produces a closure via the SEM cross-section shown in Figure 3. A vent structure in which the nylon 6,6 yarn 40 is visible in its original form and the PE yarn 30 is shown to be molten and filled with a gap in the nylon 6,6 yarn.

使用的此織物結構使得PE組分50能夠主要保持於織物之一側上,如圖4A中描繪之光顯微照片中所見。圖4B顯示耐綸6,6紗60在織物之另一側上仍呈編織形式。在另一非限制性實施例中,可使用織物建構物,其中第二紗經織造以使其嵌入底紗內。 This fabric structure is used to enable the PE component 50 to be primarily retained on one side of the fabric as seen in the light micrographs depicted in Figure 4A. Figure 4B shows that the nylon 6,6 yarn 60 is still woven on the other side of the fabric. In another non-limiting embodiment, a fabric construct can be used in which the second yarn is woven to be embedded within the bottom yarn.

應注意,本文中比率、濃度、量及其他數字資料可呈範圍格式表示。應瞭解此類範圍格式係出於便利及簡便而使用,因此應以靈活方式解釋為不僅包括明確敍述作為該範圍界限之數值,而且亦包括所有涵蓋於該範圍內之單個數值或子範圍,如同各數值及子範圍明確敍述一般。舉例說明,「約0.1%至約5%」之濃度範圍應解釋為不僅包括明確敍述之約0.1重量%至約5重量%之濃度,而且亦包括所指示範圍內之個別濃度(例如1%、2%、3%及4%)及子範圍(例如0.5%、1.1%、2.2%、3.3%及4.4%)。術語「約」可包括所修飾數值之±1%、±2%、±3%、±4%、±5%、±8%或±10%。另外,片語「約『x』至『y』」包括「約『x』至約『y』」。儘管已具體描述本發明之說明性實施例,但應瞭解本發明能夠具有其他及不同實施例且各種其他修改將為熟習此項技術者顯而易知且可易於由熟習此項技術者在不脫離本發明之精神及範疇下作出。因此,本發明申請專利範圍之範疇不欲限於本文中闡述之實例及描述,而是希望申請專利範圍解釋為涵蓋存在於本發明中的具有可專利新穎性之所有特徵,包括將由熟習本發明所屬技術者當做其等效物的所有特徵。 It should be noted that the ratios, concentrations, amounts, and other digital data herein may be expressed in a range format. It is to be understood that such range format is used for convenience and convenience, and therefore should be construed in a flexible manner to include not only the stated value as a limitation of the scope, but also all individual values or sub-ranges Each value and sub-range is clearly stated in general. For example, a concentration range of "about 0.1% to about 5%" should be interpreted to include not only the concentration of about 0.1% by weight to about 5% by weight, which is explicitly stated, but also individual concentrations within the indicated range (eg, 1%, 2%, 3%, and 4%) and sub-ranges (eg, 0.5%, 1.1%, 2.2%, 3.3%, and 4.4%). The term "about" can include ±1%, ±2%, ±3%, ±4%, ±5%, ±8%, or ±10% of the modified value. In addition, the phrase "about "x" to "y"" includes "about "x" to about "y"". Although the illustrative embodiments of the present invention have been specifically described, it is understood that the present invention is capable of other and various embodiments and various modifications may be apparent to those skilled in the art It is made without departing from the spirit and scope of the invention. Therefore, the scope of the claims of the present invention is not intended to be limited to the examples and descriptions set forth herein, but the scope of the claims is intended to cover all features of the patentable novelity present in the present invention, including The technician is considered to be all the features of its equivalent.

Claims (39)

一種編織物,其包含:a)底紗;及b)第二紗,其中該第二紗交織至該底紗中,且其中該第二紗之熔點低於該底紗之熔點。 A woven fabric comprising: a) a ground yarn; and b) a second yarn, wherein the second yarn is interwoven into the ground yarn, and wherein the second yarn has a melting point lower than a melting point of the ground yarn. 如請求項1之編織物,其中該編織物含有間隙且該第二紗的至少一部分已熔融,使得該底紗之間的間隙藉由該第二紗之該熔融部分橋接。 The braid of claim 1, wherein the braid contains a gap and at least a portion of the second yarn has been melted such that a gap between the bottom yarns is bridged by the molten portion of the second yarn. 如請求項1之編織物,其中該織物具有介於80至450公克/平方公尺範圍內之基重。 A braid of claim 1 wherein the fabric has a basis weight in the range of from 80 to 450 grams per square meter. 如請求項1之編織物,其中該第二紗係以10至40重量%之範圍存在於該織物中。 The braid of claim 1, wherein the second yarn is present in the fabric in a range from 10 to 40% by weight. 如請求項1之編織物,其中該底紗係由聚醯胺纖維形成。 The braid of claim 1, wherein the ground yarn is formed of polyamide fibers. 如請求項1之編織物,其中該底紗係由耐綸6,6纖維形成。 The woven fabric of claim 1, wherein the undertext is formed of nylon 6,6 fibers. 如請求項1之編織物,其中該底紗係由聚酯纖維形成。 The braid of claim 1, wherein the ground yarn is formed of polyester fibers. 如請求項1之編織物,其中該底紗係由聚對苯二甲酸乙二酯纖維形成。 The woven fabric of claim 1, wherein the undertext is formed of polyethylene terephthalate fibers. 如請求項1之編織物,其中該第二紗具有介於20至800分特(decitex)範圍內之線性質量密度。 The braid of claim 1, wherein the second yarn has a linear mass density in the range of from 20 to 800 decitex. 如請求項1之編織物,其中該第二紗係由聚烯烴纖維形成。 The woven fabric of claim 1, wherein the second yarn is formed of polyolefin fibers. 如請求項1之編織物,其中該第二紗係由高密度聚乙烯纖維形成。 The woven fabric of claim 1, wherein the second yarn is formed of high density polyethylene fibers. 如請求項2之編織物,其中該編織物之透氣性至少比該第二紗的至少一部分經熔融之前的該編織物之透氣性低50%,使得該底紗之間的間隙藉由該第二紗之該熔融部分橋接。 The woven fabric of claim 2, wherein the woven fabric has a gas permeability at least 50% lower than a gas permeability of the woven fabric before at least a portion of the second yarn is melted, such that a gap between the yarns is obtained by the first The molten portion of the second yarn is bridged. 如請求項2之編織物,其中該編織物之透氣性至少比該第二紗的至少一部分經熔融之前的該編織物之透氣性低75%,使得該底紗之間的間隙藉由該第二紗之該熔融部分橋接。 The woven fabric of claim 2, wherein the woven fabric has a gas permeability at least 75% lower than a gas permeability of the woven fabric before at least a portion of the second yarn is melted, such that a gap between the yarns is obtained by the first The molten portion of the second yarn is bridged. 一種安全氣囊,其包含如請求項1至13中任一項之編織物。 An airbag comprising the braid of any one of claims 1 to 13. 一種熔化織物,其包含:a)包含底紗之編織物,其中該底紗含有間隙;及b)至少部分填充該底紗中之該等間隙之填充材料。 A melted fabric comprising: a) a knit comprising a ground yarn, wherein the ground yarn comprises a gap; and b) a filler material at least partially filling the gaps in the ground yarn. 如請求項15之熔化織物,其中該填充材料係以該熔化織物之10至40重量%之範圍存在。 The melted fabric of claim 15, wherein the filler material is present in a range from 10 to 40% by weight of the melted fabric. 如請求項15之熔化織物,其中該底紗係由聚醯胺纖維形成。 The melted fabric of claim 15, wherein the ground yarn is formed of polyamide fibers. 如請求項15之熔化織物,其中該底紗係由耐綸6,6纖維形成。 The melted fabric of claim 15, wherein the ground yarn is formed of nylon 6,6 fibers. 如請求項15之熔化織物,其中該底紗係由聚酯纖維形成。 The melted fabric of claim 15, wherein the ground yarn is formed of polyester fibers. 如請求項15之熔化織物,其中該底紗係由聚對苯二甲酸乙二酯纖維形成。 The melted fabric of claim 15, wherein the ground yarn is formed of polyethylene terephthalate fibers. 如請求項15之熔化織物,其中該填充材料係由聚烯烴形成。 The melted fabric of claim 15 wherein the filler material is formed from a polyolefin. 如請求項15之熔化織物,其中該填充材料係由高密度聚乙烯形成。 The melted fabric of claim 15 wherein the filler material is formed from high density polyethylene. 一種安全氣囊,其包含如請求項15至22中任一項之熔化織物。 An airbag comprising the melted fabric of any one of claims 15 to 22. 一種製造經處理織物之方法,其包含以下步驟:a)交織底紗與第二紗以形成編織物,其中該第二紗之熔點低於該底紗之熔點;及b)加熱該編織物至該第二紗之熔點以上及該底紗之熔點以下之溫度,其中該第二紗的至少一部分熔融形成經處理織物。 A method of making a treated fabric comprising the steps of: a) interlacing a base yarn and a second yarn to form a braid, wherein a melting point of the second yarn is lower than a melting point of the ground yarn; and b) heating the braid to a temperature above the melting point of the second yarn and below the melting point of the ground yarn, wherein at least a portion of the second yarn is melted to form a treated fabric. 如請求項24之方法,其中該第二紗的至少一部分熔融,使得該底紗之間的間隙藉由第二紗之該熔融部分橋接。 The method of claim 24, wherein at least a portion of the second yarn is melted such that a gap between the ground yarns is bridged by the molten portion of the second yarn. 如請求項24之方法,其中該經處理織物之透氣性至少比於步驟 (a)中形成之該編織物之透氣性低50%。 The method of claim 24, wherein the treated fabric is at least more breathable than the step The woven fabric formed in (a) has a gas permeability of 50% lower. 如請求項24之方法,其中該經處理織物之透氣性至少比於步驟(a)中形成之該編織物之透氣性低75%。 The method of claim 24, wherein the treated fabric has a gas permeability that is at least 75% lower than the gas permeability of the knitted fabric formed in step (a). 如請求項24之方法,其中該編織物具有介於80至450公克/平方公尺範圍內之基重。 The method of claim 24, wherein the braid has a basis weight in the range of from 80 to 450 grams per square meter. 如請求項24之方法,其中該第二紗係以1至40重量%之範圍存在於該編織物中。 The method of claim 24, wherein the second yarn is present in the braid in a range from 1 to 40% by weight. 如請求項24之方法,其中該底紗係由聚醯胺纖維形成。 The method of claim 24, wherein the ground yarn is formed from polyamide fibers. 如請求項24之方法,其中該底紗係由耐綸6,6纖維形成。 The method of claim 24, wherein the undertext is formed from nylon 6,6 fibers. 如請求項24之方法,其中該底紗係由聚酯纖維形成。 The method of claim 24, wherein the ground yarn is formed of polyester fibers. 如請求項24之方法,其中該底紗係由聚對苯二甲酸乙二酯纖維形成。 The method of claim 24, wherein the ground yarn is formed from polyethylene terephthalate fibers. 如請求項24之方法,其中該第二紗具有介於20至800分特範圍內之線性質量密度。 The method of claim 24, wherein the second yarn has a linear mass density in the range of 20 to 800 dtex. 如請求項24之方法,其中該第二紗係由聚烯烴纖維形成。 The method of claim 24, wherein the second yarn is formed from polyolefin fibers. 如請求項24之方法,其中該第二紗係由聚乙烯纖維形成。 The method of claim 24, wherein the second yarn is formed from polyethylene fibers. 如請求項24之方法,其中該第二紗係由高密度聚乙烯纖維形成。 The method of claim 24, wherein the second yarn is formed from high density polyethylene fibers. 一種經處理織物,其係由如請求項24至37中任一項之方法形成。 A treated fabric formed by the method of any one of claims 24 to 37. 一種安全氣囊,其係由如請求項38之經處理織物形成。 An airbag formed from the treated fabric of claim 38.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115369547A (en) * 2022-06-09 2022-11-22 常州艾克特纺织科技有限公司 Reinforcing fabric, injection molded part and manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115369547A (en) * 2022-06-09 2022-11-22 常州艾克特纺织科技有限公司 Reinforcing fabric, injection molded part and manufacturing method

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