TW201536507A - Injector for the charging of material to a mold and process for the production of moldings from foamed polymer particles - Google Patents

Injector for the charging of material to a mold and process for the production of moldings from foamed polymer particles Download PDF

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Publication number
TW201536507A
TW201536507A TW103135168A TW103135168A TW201536507A TW 201536507 A TW201536507 A TW 201536507A TW 103135168 A TW103135168 A TW 103135168A TW 103135168 A TW103135168 A TW 103135168A TW 201536507 A TW201536507 A TW 201536507A
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Taiwan
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polymer particles
mold
foamed polymer
introducing
gas
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TW103135168A
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Chinese (zh)
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Markus Buscher
Gerhard Weis
Juergen Bartl
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Basf Se
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C31/00Handling, e.g. feeding of the material to be shaped, storage of plastics material before moulding; Automation, i.e. automated handling lines in plastics processing plants, e.g. using manipulators or robots
    • B29C31/04Feeding of the material to be moulded, e.g. into a mould cavity
    • B29C31/041Feeding of the material to be moulded, e.g. into a mould cavity using filling or dispensing heads placed in closed moulds or in contact with mould walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/38Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
    • B29C44/44Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
    • B29C44/445Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3415Heating or cooling
    • B29C44/3426Heating by introducing steam in the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2025/00Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
    • B29K2025/04Polymers of styrene
    • B29K2025/06PS, i.e. polystyrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00Use of unspecified macromolecular compounds as moulding material
    • B29K2101/12Thermoplastic materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Robotics (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The invention relates to an injector for the charging of material to a mold (11) for the production of moldings from foamed polymer particles (1), comprising a duct (5) for the introduction of foamed polymer particles (1), a feed neck (9), and an injector piston (29), where the feed neck (9) adjoins the duct (5) for the introduction of foamed polymer particles (1), and where the injector piston (29) has, at its end facing toward the mold (11), a cross-sectional area (31) which corresponds to the cross-sectional area at the outlet (21) of the feed neck (9) into the mold (11), and the movement of the injector piston (29) is such that foamed polymer particles (1) can be forced from the feed neck (9) with the aid of the injector piston (29) into the mold (11), wherein the feed neck (9) has at least one aperture (19) through which compressed gas can be introduced into the feed neck (9). The invention further relates to a process for the production of a molding from foamed polymer particles.

Description

用於充添材料至模具之注射器及從發泡聚合物顆粒生產模製品之方法 Syringe for filling material to mold and method for producing molded article from foamed polymer particles

本發明係關於一種充添材料至模具以用於從發泡聚合物顆粒生產模製品之注射器,其包含用於引入發泡聚合物顆粒之管道、至少一個用於引入氣體之管道、饋料頸及注射器活塞,其中該饋料頸毗連用於引入發泡聚合物顆粒之管道,且用於引入氣體之管道在該饋料頸之上游通向用於引入發泡聚合物顆粒之管道,且其中該注射器活塞在其朝向該模具之末端處具有對應於該饋料頸之截面積的截面積,且移動該注射器活塞以使得可憑藉該注射器活塞迫使聚合物顆粒從該饋料頸進入該模具中。本發明進一步係關於一種從發泡聚合物顆粒生產模製品之方法。 The present invention relates to a syringe for filling a mold to a mold for producing a molded article from expanded polymer particles, comprising a pipe for introducing foamed polymer particles, at least one pipe for introducing a gas, and a feed neck And a syringe piston, wherein the feed neck abuts a conduit for introducing foamed polymer particles, and a conduit for introducing a gas leads upstream of the feed neck to a conduit for introducing foamed polymer particles, and wherein The syringe piston has a cross-sectional area corresponding to the cross-sectional area of the feed neck at its end toward the mold, and moves the syringe piston such that polymer particles can be forced into the mold from the feed neck by the syringe piston . The invention further relates to a method of producing a molded article from expanded polymer particles.

由發泡熱塑性聚合物顆粒製成的模製品具有許多可能的應用:此等模製品以實例說明之可用作支撐物、座墊、床墊或其他一一鞋之外底。藉由將發泡聚合物顆粒引入模具中,基於當前所用的模製機之現存技術,在模具中蒸汽處理或蒸汽加熱該等模製品以此方式使得其外側彼此熔融來生產各別模製品。 Molded articles made from expanded thermoplastic polymer particles have many possible applications: such molded articles can be used as support, seat cushions, mattresses or other outsole by way of example. By introducing the foamed polymer particles into the mold, the respective molded articles are steam-treated or steam-heated in the mold in accordance with the existing techniques of the currently used molding machine in such a manner that the outer sides thereof are melted with each other to produce the respective molded articles.

為充添材料至模具以用於從發泡熱塑性聚合物顆粒生產模製品,當前使用注射器,憑藉氣流經由注射器將發泡聚合物顆粒推至模具中。為此目的,注射器毗連模具上之饋料頸。一旦模具已經填充,將注射器活塞移至饋料頸中,以此方式迫使包含於該饋料頸中之顆粒進入該模具 中。先前技術之注射器具有以下缺點:無法接著藉由注射器活塞迫使累積於饋料頸中之一些發泡聚合物顆粒進入模具中。因此在模製品上產生非所要的突起。 To add material to the mold for producing the molded article from the foamed thermoplastic polymer particles, a syringe is currently used to push the foamed polymer particles into the mold via a syringe by means of a gas stream. For this purpose, the syringe abuts the feed neck on the mould. Once the mold has been filled, the syringe plunger is moved into the feed neck, in such a way that particles contained in the feed neck are forced into the mold in. Prior art syringes have the disadvantage that some of the expanded polymer particles accumulated in the feed neck cannot be forced into the mold by the syringe piston. Undesirable protrusions are thus produced on the molded article.

可用於充添材料至模具用以從發泡熱塑性聚合物顆粒生產 模製品之注射器以實例說明之描述於EP-A 1 813 409中。此具有用於引入發泡聚合物顆粒之中心管道且亦具有允許將空氣吹至系統中之環形間隙。一旦已將材料充添至模具,使用第二環形間隙引入蒸汽。此外,描述於彼文件中之注射器不准許將饋料頸中之發泡聚合物顆粒數量降至最低,以此方式使得當藉由注射器活塞迫使發泡聚合物顆粒進入系統中時不在模製品上產生突起。 Can be used to fill materials to molds for production from foamed thermoplastic polymer pellets The syringe of the molded article is described by way of example in EP-A 1 813 409. This has a central conduit for introducing foamed polymer particles and also has an annular gap that allows air to be blown into the system. Once the material has been filled into the mold, steam is introduced using a second annular gap. Furthermore, the syringes described in the document do not permit the minimization of the amount of foamed polymer particles in the feed neck, in such a way that when the foamed polymer particles are forced into the system by the syringe piston, they are not on the molded article. A protrusion is generated.

因此,本發明之目標為提供一種注射器及一種從發泡熱塑性 聚合物顆粒生產模製品之方法,該方法准許製造在毗連注射器之位置處不具有突起之模製品。 Accordingly, it is an object of the present invention to provide a syringe and a thermoplastic from foaming The method of producing a molded article from polymer particles, which permits the manufacture of a molded article having no protrusion at a position adjacent to the syringe.

經由充添材料至模具用於從發泡聚合物顆粒生產模製品之 注射器實現此目標,該注射器包含用於引入發泡聚合物顆粒之管道、饋料頸及注射器活塞,其中該饋料頸毗連用於引入發泡聚合物顆粒之管道,且其中該注射器活塞在其朝向該模具之末端處具有對應於該饋料頸之截面積的截面積,且移動該注射器活塞以使得可憑藉該注射器活塞迫使聚合物顆粒從該饋料頸進入該模具中,其中該饋料頸具有至少一個孔口,可經由孔口將壓縮氣體引入該饋料頸。 Producing a molded article from foamed polymer particles via a filling material to a mold This object is achieved by a syringe comprising a conduit for introducing foamed polymer particles, a feed neck and a syringe piston, wherein the feed neck abuts a conduit for introducing foamed polymer particles, and wherein the syringe piston is in A cross-sectional area corresponding to a cross-sectional area of the feed neck toward the end of the mold, and moving the syringe piston such that polymer particles can be forced into the mold from the feed neck by the syringe piston, wherein the feed The neck has at least one orifice through which compressed gas can be introduced into the feed neck.

進一步經由從發泡聚合物顆粒生產模製品之方法實現該目標,該方法包含以下步驟:(a)藉助於用於充添材料至模具之注射器充添發泡聚合物顆粒至模具,其中經由用於引入發泡聚合物顆粒之管道引入該等發泡聚合物顆粒, 且在已將材料充添至該模具之後,經由用於引入壓縮氣體之孔口將壓縮氣體引入饋料頸中,(b)將仍包含在該饋料頸內的發泡聚合物顆粒推至該模具中且一旦該模具已經完全填充,經由在該模具之方向上移動注射器活塞來封閉該模具,及(c)加熱該等發泡聚合物顆粒以致此等顆粒變得彼此黏結從而產生模製品。 This object is further achieved by a method of producing a molded article from expanded polymer particles, the method comprising the steps of: (a) filling a foamed polymer particle to a mold by means of a syringe for filling a material to a mold, wherein Introducing the foamed polymer particles into a pipe into which the foamed polymer particles are introduced, And after the material has been charged to the mold, the compressed gas is introduced into the feed neck via the orifice for introducing the compressed gas, and (b) the foamed polymer particles still contained in the feed neck are pushed to And in the mold, once the mold has been completely filled, the mold is closed by moving the syringe piston in the direction of the mold, and (c) heating the foamed polymer particles such that the particles become bonded to each other to produce a molded article .

將壓縮氣體引入饋料頸避免以下之任何情況:其中在已填充模具之後饋料頸同樣變得完全填充。所得氣流使饋料頸中之發泡聚合物顆粒液化且一旦已完全填充模具,使發泡聚合物顆粒逆向流動至注射器中。此避免以下之任何情況:其中累積在饋料頸內的發泡聚合物顆粒之數量為如此大,以致在已藉由注射器活塞迫使發泡聚合物顆粒從饋料頸進入模具中之後,在所得模製組件上形成突起。注射器活塞因此可能形成與模具之內壁齊平的密封件,以此方式可在所需模製品上實現平滑表面。 Introducing the compressed gas into the feed neck avoids any of the following situations: where the feed neck also becomes completely filled after the mold has been filled. The resulting gas stream liquefies the foamed polymer particles in the feed neck and, once the mold has been completely filled, causes the expanded polymer particles to flow countercurrently into the syringe. This avoids any situation in which the amount of foamed polymer particles accumulated in the feed neck is so large that after the foamed polymer particles have been forced into the mold from the feed neck by the syringe piston, A protrusion is formed on the molding assembly. The syringe piston thus may form a seal that is flush with the inner wall of the mold, in such a way that a smooth surface can be achieved on the desired molding.

在一個具體實例中,注射器具有至少一個管道,其欲用於引入氣體且其在饋料頸之上游通向用於引入發泡聚合物顆粒之管道。若包含用於引入至少一種氣體之管道,則可能藉由經由用於引入至少一種氣體之管道引入壓縮氣體來輔助填充程序。此外有利的是,在材料已充添至模具之後經由至少一個用於引入氣體之管道引入壓縮氣體。然而,替代地,亦可能的是,僅經由用於引入壓縮氣體之孔口將壓縮氣體傳送至饋料頸中。 In one embodiment, the syringe has at least one conduit intended to be used to introduce a gas and which leads upstream of the feed neck to a conduit for introducing foamed polymer particles. If a conduit for introducing at least one gas is included, it is possible to assist the filling procedure by introducing a compressed gas via a conduit for introducing at least one gas. It is furthermore advantageous if the compressed gas is introduced via at least one conduit for introducing a gas after the material has been charged to the mold. Alternatively, however, it is also possible to transfer the compressed gas into the feed neck only via the orifice for introducing the compressed gas.

經由用於將壓縮氣體引入饋料頸中之孔口及視情況經由至少一個用於引入氣體之管道引入壓縮氣體,用以在用於引入發泡聚合物顆粒之管道中產生逆流,本文之目標為無另外發泡聚合物顆粒在模具之方向上傳輸且在饋料頸區域中累積。當藉由注射器活塞迫使聚合物顆粒進入系統中時,此等情況將促使模具上之非所要突起進一步擴大。 The purpose of this document is to introduce a countercurrent in a conduit for introducing foamed polymer particles via an orifice for introducing compressed gas into the feed neck and optionally introducing a compressed gas via at least one conduit for introducing gas. No additional foamed polymer particles are transported in the direction of the mould and accumulate in the feed neck region. When the polymer particles are forced into the system by the syringe piston, this condition will cause the undesired protrusions on the mold to expand further.

同樣較佳憑藉氣體實現經由用於引入發泡聚合物顆粒之管 道傳輸發泡聚合物顆粒。因此經由用於引入發泡聚合物顆粒之管道藉由氣體將發泡聚合物顆粒吹至模具中。 It is also preferred to carry out via a tube for introducing foamed polymer particles by means of a gas The channel transports the foamed polymer particles. The foamed polymer particles are thus blown into the mold by a gas via a pipe for introducing the foamed polymer particles.

對所用聚合物呈惰性之任何所要氣體可用於經由注射器將 發泡聚合物顆粒傳輸至模具中。適合氣體之實例為稀有氣體、氮氣、二氧化碳、蒸汽及空氣。優先考慮氮氣、蒸汽或空氣且空氣為尤其較佳氣體。 壓縮氣體較佳與用於傳輸發泡聚合物顆粒之氣體相同,在充添程序結束時經由用於引入氣體之孔口將壓縮氣體注射至饋料頸中,且視情況將其注射至用於引入氣體之管道中。本文中壓縮空氣為尤其較佳的。用於傳輸發泡聚合物顆粒之氣體及經由饋料頸中的用於引入壓縮氣體之孔口引入與視情況經由用於引入氣體之管道引入的氣體之壓力較佳在高於大氣壓力0巴至8巴的範圍內。 Any desired gas that is inert to the polymer used can be used via a syringe The foamed polymer particles are transferred to a mold. Examples of suitable gases are rare gases, nitrogen, carbon dioxide, steam and air. Nitrogen, steam or air is preferred and air is a particularly preferred gas. The compressed gas is preferably the same as the gas used to transport the foamed polymer particles, and the compressed gas is injected into the feed neck via the orifice for introducing the gas at the end of the filling process, and is optionally injected for use Introduced into the gas pipeline. Compressed air is particularly preferred herein. The gas for transporting the foamed polymer particles and the pressure introduced through the orifice for introducing the compressed gas in the feed neck and optionally introduced by the gas for introducing the gas are preferably at a pressure higher than atmospheric pressure of 0 bar. To the extent of 8 bar.

任何所要之適合方法可用於加熱充添至模具之發泡聚合物 顆粒,以便此等顆粒變得黏結從而產生模製品。尤其較佳的是,為此目的,使熱氣流穿過模具。適合氣體為任何對所用聚合物呈惰性之所要氣體。特定言之,蒸汽用作氣體。 Any suitable method can be used to heat the foamed polymer that is added to the mold The granules are such that the granules become viscous to produce a molded article. It is especially preferred that for this purpose a hot gas stream is passed through the mould. Suitable gases are any desired gas which is inert to the polymer used. In particular, steam is used as a gas.

若使用注射器,亦經由注射器引入用於黏結發泡聚合物顆粒 之氣體(特定言之蒸汽),則如同以實例說明之EP-A 1 813 409中所描述的使用注射器之情況,藉助於實例可能使注射器活塞穿孔,孔直徑小於發泡聚合物顆粒直徑,以此方式使得蒸汽可經由注射器活塞中的孔流至模具中。當然,替代地,亦可能為蒸汽提供獨立輸入設備。為此目的,可使用熟習此項技術者已知的任何所要之輸入設備,特定言之,包括當前已經用於將蒸汽引入模具中之類型的設備。 If a syringe is used, it is also introduced via a syringe for bonding foamed polymer particles. The gas (specifically, the steam), as in the case of the use of a syringe as described in the example of EP-A 1 813 409, by means of which it is possible to perforate the syringe piston with a pore diameter smaller than the diameter of the foamed polymer particles, This way the steam can flow into the mold via the holes in the syringe piston. Of course, it is also possible to provide a separate input device for the steam. For this purpose, any desired input device known to those skilled in the art can be used, in particular, including devices of the type currently used to introduce steam into the mold.

為了得到饋料頸中之發泡聚合物顆粒之足夠液化,用於將壓 縮氣體引入饋料頸中之孔口之有利定向使得引入之壓縮氣體具有垂直於饋 料頸之軸線之速度分量。垂直於饋料頸之軸線之速度分量產生交叉流,其使得發泡聚合物顆粒液化。為了得到垂直於饋料頸之軸線之速度分量,用於引入壓縮氣體之孔口之定向可垂直於饋料頸之軸線或在相對於饋料頸之軸線之大於0°的任何所要角度處。較佳地,用於引入壓縮氣體之孔口之定向在30°至90°範圍內、特定言之在75°至90°範圍內之角度處,且極特定言之在90°之角度處,亦即垂直於饋料頸之軸線。 In order to obtain sufficient liquefaction of the foamed polymer particles in the feed neck, for pressing The favorable orientation of the condensing gas introduced into the orifice in the feed neck is such that the introduced compressed gas has a perpendicular to the feed The velocity component of the axis of the neck. The velocity component perpendicular to the axis of the feed neck creates a cross-flow that causes the foamed polymer particles to liquefy. In order to obtain a velocity component perpendicular to the axis of the feed neck, the orientation of the orifice for introducing the compressed gas may be perpendicular to the axis of the feed neck or at any desired angle greater than 0° with respect to the axis of the feed neck. Preferably, the orientation of the orifice for introducing the compressed gas is in the range of 30° to 90°, in particular in the range of 75° to 90°, and in particular at an angle of 90°, That is, perpendicular to the axis of the feed neck.

若用於引入壓縮氣體之孔口之定向在相對於饋料頸之軸線 之小於90°的角度處,則該孔口可在任何所要方向上傾斜。然而,優先考慮平行於饋料孔口之軸線之傾斜,且極其優先考慮使得壓縮氣體在模具方向上注射之傾斜。 If the orifice for introducing the compressed gas is oriented relative to the axis of the feed neck At an angle less than 90°, the orifice can be tilted in any desired direction. However, the inclination parallel to the axis of the feed orifice is prioritized, and the inclination of the injection of the compressed gas in the direction of the mold is highly preferred.

藉助於在模具方向上之定向,藉由藉助於用於引入壓縮氣體 之孔口引入的壓縮氣體輔助填充程序。在該種狀況下,亦宜在整個填充程序期間藉助於饋料頸中的用於引入壓縮氣體之孔口來引入壓縮氣體。當用於引入壓縮氣體之孔口之定向為再注射器方向上時,有利的是,藉助於用於引入壓縮氣體之孔口將壓縮氣體延遲引入饋料頸中直至模具已經填充,以致在已完全填充模具之前不會又將發泡聚合物顆粒吹離模具。若同時藉助於所有孔口引入壓縮氣體,則替代地,亦可能改變壓縮氣體之速度或尤其改變壓力。注射器中之氣體的壓力接著在填充程序期間更高,然而在填充程序之後,藉助於用於引入壓縮氣體之孔口引入饋料頸中的氣體之壓力增加至如此程度,以致模具中不再有足夠的可用空間將顆粒在與輸送過程之方向相反的方向上吹回至注射器中。 By means of orientation in the direction of the mould, by means of introducing compressed gas The compressed gas introduced by the orifice assists the filling procedure. In this case, it is also preferred to introduce the compressed gas during the entire filling procedure by means of an orifice in the feed neck for introducing compressed gas. When the orientation of the orifice for introducing the compressed gas is in the direction of the reinjector, it is advantageous to introduce a compressed gas into the feed neck by means of an orifice for introducing a compressed gas until the mold has been filled so that it is completely The foamed polymer particles are not blown away from the mold until the mold is filled. If the compressed gas is introduced at the same time by means of all the orifices, it is alternatively possible to change the speed of the compressed gas or in particular to change the pressure. The pressure of the gas in the injector is then higher during the filling procedure, however after the filling procedure, the pressure of the gas introduced into the feed neck by means of the orifice for introducing the compressed gas is increased to such an extent that there is no longer any Sufficient free space blows the particles back into the syringe in a direction opposite to the direction of the delivery process.

即使用於將壓縮氣體引入饋料頸中之孔口垂直於饋料孔口 之軸線,有利的是,延遲注射壓縮氣體直至模具已經填充,或替代地,一旦已完全填充模具,則增加注射至饋料頸中的壓縮氣體之壓力或體積流動速率,此外本文之目的在於避免不完全填充模具或過度冗長的填充程序。 然而,當用於將壓縮氣體引入饋料頸中之孔口之定向垂直於饋料孔口之軸線時,另一可能性為亦在填充程序期間注射壓縮氣體。 Even the orifice for introducing compressed gas into the feed neck is perpendicular to the feed orifice The axis, advantageously, delays the injection of compressed gas until the mold has been filled, or alternatively, once the mold has been completely filled, the pressure or volumetric flow rate of the compressed gas injected into the feed neck is increased, and the purpose of this document is to avoid Do not completely fill the mold or excessively lengthy filling procedures. However, when the orientation of the orifice for introducing compressed gas into the feed neck is perpendicular to the axis of the feed orifice, another possibility is to also inject compressed gas during the filling procedure.

出於在饋料頸內產生均勻流動且因此均勻充添材料至模具 以便實現一致產物品質之目的,此外較佳的是,設置至少兩個用於將壓縮氣體引入饋料頸中之孔口,其中該配置具有均勻地分佈於饋料頸之周邊上的孔口。 For producing a uniform flow in the feed neck and thus uniformly filling the material to the mold In order to achieve consistent product quality, it is further preferred to provide at least two orifices for introducing compressed gas into the feed neck, wherein the configuration has orifices evenly distributed over the periphery of the feed neck.

對各孔可能設置獨立壓縮氣體供應線,其目的在於當存在複 數個用於引入壓縮氣體之孔口時為所有孔口供應壓縮氣體。然而,較佳地使用共用供應線對所有孔口饋料。為此目的,以實例說明之可能將至少兩個用於將壓縮氣體引入饋料頸中之孔口連接至包圍饋料頸之氣體分佈環。 接著藉助於氣體分佈環使用於引入壓縮氣體之個別孔口供應壓縮氣體。氣體分佈環具有至少一個連接,可藉助於該連接引入壓縮氣體以便向氣體分佈環供應壓縮氣體。 An independent compressed gas supply line may be provided for each hole, and the purpose is to have a complex Several orifices are supplied with compressed gas for the introduction of compressed gas orifices. However, it is preferred to feed all of the orifices using a common supply line. For this purpose, it is possible by way of example to connect at least two orifices for introducing compressed gas into the feed neck to a gas distribution ring surrounding the feed neck. The compressed gas is then supplied by means of a gas distribution ring for the individual orifices into which the compressed gas is introduced. The gas distribution ring has at least one connection by means of which a compressed gas can be introduced to supply a compressed gas to the gas distribution ring.

出於防止注射器活塞在充添材料至模具期間妨礙發泡聚合 物顆粒之流動之目的,有利的是設計的注射器使得當注射器活塞處於靜止時,亦即在充添發泡聚合物顆粒至模具期間,注射器活塞在位於引入發泡聚合物顆粒之點處的後方之位置處。本文之引入發泡聚合物顆粒之點以實例說明之可側向地位於注射器上。若用於引入發泡聚合物顆粒之管道之直徑大於饋料頸之直徑,則替代地,亦可能的是,發泡聚合物顆粒在充添材料至模具期間圍繞注射器活塞流動。然而,較佳地選擇注射器活塞之位置,以此方式使得在注射器活塞前面引入發泡聚合物顆粒,以此方式使得其不必圍繞注射器活塞流動。 To prevent the syringe piston from interfering with foaming polymerization during the filling of the material to the mold For the purpose of the flow of particles, it is advantageous to design the syringe such that when the syringe piston is at rest, i.e., during the filling of the foamed polymer particles to the mold, the syringe piston is located at the point where the foamed polymer particles are introduced. The location. The point of introduction of the foamed polymer particles herein can be laterally located on the syringe by way of example. If the diameter of the conduit for introducing the expanded polymer particles is larger than the diameter of the feed neck, it is alternatively possible that the expanded polymer particles flow around the syringe piston during the filling of the material to the mold. However, the position of the syringe piston is preferably selected in such a way that the foamed polymer particles are introduced in front of the syringe piston in such a way that it does not have to flow around the syringe piston.

在一個具體實例中,設計用於引入在充添程序結束時注射的 氣體以便在與傳輸發泡聚合物顆粒之方向相反的方向上產生流動以致無另外發泡聚合物顆粒在模具方向上傳輸之管道,以使得用於引入氣體之管道 同軸地包圍用於引入發泡聚合物顆粒之管道。在該種狀況下,尤其較佳的是,藉助於環形間隙在管道的末端處將氣體注射至用於引入發泡聚合物顆粒之管道中。因此以防止任何發泡聚合物顆粒可累積之死體積形成之方式實現均勻流動。 In a specific example, it is designed to introduce an injection at the end of the filling process. The gas is such that a flow is generated in a direction opposite to the direction in which the expanded polymer particles are transported so that no additional foamed polymer particles are transported in the direction of the mold, so that the conduit for introducing the gas A conduit for introducing foamed polymer particles is coaxially surrounded. In this case, it is especially preferred to inject gas at the end of the pipe by means of an annular gap into the pipe for introducing the foamed polymer particles. Uniform flow is thus achieved in a manner that prevents the formation of dead volume that can be accumulated by any of the foamed polymer particles.

替代地,亦可能的是,至少兩個用於引入氣體之管道與用於 引入發泡聚合物顆粒之管道平行運行,其中該配置具有圍繞用於引入發泡聚合物顆粒之管道均勻分佈的用於引入氣體之管道。藉助於用於引入氣體之管道圍繞用於引入發泡聚合物顆粒之管道均勻分佈的配置,本文此外產生均勻流動以便防止發泡聚合物顆粒可累積之死體積的形成。 Alternatively, it is also possible for at least two conduits for introducing gas and for The pipe into which the foamed polymer particles are introduced is operated in parallel, wherein the configuration has a pipe for introducing a gas uniformly distributed around a pipe for introducing the foamed polymer particles. A configuration in which the conduit for introducing the gas is evenly distributed around the conduit for introducing the foamed polymer particles, in addition, produces a uniform flow in order to prevent the formation of a dead volume which the foamed polymer particles can accumulate.

為了准許發泡聚合物顆粒在模具中黏結以經由加熱、例如經 由蒸汽之注射產生模製品,較佳地,發泡聚合物顆粒包含熱塑性聚合物。 用於發泡熱塑性聚合物顆粒之熱塑性聚合物可為任何所要之熱塑性塑膠。 In order to permit the foamed polymer particles to bond in the mold for heating, for example via The molded article is produced by injection of steam, and preferably, the expanded polymer particles comprise a thermoplastic polymer. The thermoplastic polymer used to foam the thermoplastic polymer particles can be any desired thermoplastic.

尤其較佳的是,發泡熱塑性聚合物係選自膨脹聚丙烯 (expanded polypropylene;EPP)、膨脹聚乙烯(expanded polyethylene;EPE)、膨脹聚苯乙烯(expanded polystyrene;EPS)及膨脹熱塑性聚胺甲酸酯(expanded thermoplastic polyurethane;ETPU)及此等聚合物之混合物及包含此等聚合物之單體單元之共聚物。極其較佳的是,發泡熱塑性聚合物為膨脹熱塑性聚胺甲酸酯。 It is especially preferred that the foamed thermoplastic polymer is selected from expanded polypropylene (expanded polypropylene; EPP), expanded polyethylene (EPE), expanded polystyrene (EPS) and expanded thermoplastic polyurethane (ETPU) and mixtures of such polymers and A copolymer comprising monomer units of such polymers. Most preferably, the expanded thermoplastic polymer is an expanded thermoplastic polyurethane.

發泡熱塑性聚合物可包含任何用於加工熱塑性聚合物之所 要填充劑及添加劑。熟習此項技術者知曉適當的填充劑及添加劑。 The foamed thermoplastic polymer can comprise any of the materials used to process thermoplastic polymers. Fillers and additives. Those skilled in the art will be aware of suitable fillers and additives.

發泡熱塑性聚合物可因此包含(以實例說明之)潤滑劑、塑 化劑、UV穩定劑、著色劑、顏料及任何通常添加至聚合物之所要的其他添加劑。亦可包含填充劑或增強材料,實例為纖維,特定言之短纖維。 The foamed thermoplastic polymer can thus comprise (illustrated by way of example) a lubricant, plastic Chemicals, UV stabilizers, colorants, pigments, and any other additives typically added to the polymer. Fillers or reinforcing materials may also be included, examples being fibers, in particular short fibers.

在一個具體實例中,發泡熱塑性聚合物包含內部或外部潤滑 劑。在生產發泡熱塑性聚合物顆粒期間此通常以添加劑之形式添加。內部 或外部潤滑劑黏附至個別發泡熱塑性聚合物顆粒之表面且因此輔助潤滑,因此准許防止結塊。 In one embodiment, the foamed thermoplastic polymer comprises internal or external lubrication Agent. This is usually added in the form of an additive during the production of the foamed thermoplastic polymer particles. internal Or an external lubricant adheres to the surface of the individual foamed thermoplastic polymer particles and thus assists in lubrication, thus permitting prevention of agglomeration.

個別發泡熱塑性聚合物顆粒之平均直徑通常在1mm至10 mm之範圍內,特定言之在1.5mm至6mm之範圍內。發泡熱塑性聚合物顆粒之容積密度較佳在5g/l至600g/l之範圍內,更佳在10g/l至500g/l之範圍內,且特定言之在15g/l至200g/l之範圍內。 The average diameter of individual foamed thermoplastic polymer particles is usually from 1 mm to 10 Within the range of mm, specifically in the range of 1.5 mm to 6 mm. The bulk density of the expanded thermoplastic polymer particles is preferably in the range of from 5 g/l to 600 g/l, more preferably in the range of from 10 g/l to 500 g/l, and specifically from 15 g/l to 200 g/l. Within the scope.

發泡熱塑性聚合物顆粒之形狀視需要可為例如圓柱形或球形或橢球形。尤其較佳的是,發泡熱塑性聚合物顆粒之形狀為球形。 The shape of the foamed thermoplastic polymer particles may be, for example, a cylindrical shape or a spherical shape or an ellipsoidal shape as needed. It is especially preferred that the foamed thermoplastic polymer particles have a spherical shape.

圖式描繪了本發明之一個具體實例,在以下描述中更詳細地解釋該具體實例。 The drawings depict one specific example of the invention, which is explained in more detail in the following description.

1‧‧‧發泡聚合物顆粒 1‧‧‧Foamed polymer particles

3‧‧‧氣流 3‧‧‧ airflow

5‧‧‧管道 5‧‧‧ Pipes

7‧‧‧注射器 7‧‧‧Syringe

9‧‧‧饋料頸 9‧‧‧Feed neck

11‧‧‧模具 11‧‧‧Mold

13‧‧‧管道 13‧‧‧ Pipes

15‧‧‧環形間隙 15‧‧‧ annular gap

17‧‧‧錐形直徑縮減部分 17‧‧‧Cone diameter reduction

19‧‧‧孔口 19‧‧‧孔口

21‧‧‧出口 21‧‧‧Export

23‧‧‧氣體分佈環 23‧‧‧ gas distribution ring

25‧‧‧連接 25‧‧‧Connect

29‧‧‧注射器活塞 29‧‧‧Syringe piston

31‧‧‧截面積 31‧‧‧ cross-sectional area

圖1展示了從發泡聚合物顆粒生產模製品之方法之第一步驟,圖2展示了從發泡聚合物顆粒生產模製品之方法之第二步驟,圖3展示了從發泡聚合物顆粒生產模製品之方法之第三步驟,及圖4展示了從發泡聚合物顆粒生產模製品之方法之第四步驟。 Figure 1 illustrates the first step of a method of producing a molded article from expanded polymer particles, Figure 2 illustrates a second step of a method of producing a molded article from expanded polymer particles, and Figure 3 illustrates the particles from a foamed polymer. The third step of the method of producing a molded article, and Figure 4, shows the fourth step of the method of producing a molded article from the expanded polymer particles.

圖1描繪了從發泡聚合物顆粒生產模製品之方法之第一步驟。 Figure 1 depicts the first step of a method of producing a molded article from expanded polymer particles.

為了從發泡聚合物顆粒1生產模製品,憑藉氣流3將發泡聚合物顆粒1引入注射器7之中心管道5。任何對聚合物呈惰性之適合氣體可用作本文之氣體。適合氣體之實例為空氣、氮氣或蒸汽,特定言之為空氣。 In order to produce a molded article from the foamed polymer particles 1, the foamed polymer particles 1 are introduced into the center pipe 5 of the syringe 7 by means of the gas stream 3. Any suitable gas inert to the polymer can be used as the gas herein. Examples of suitable gases are air, nitrogen or steam, in particular air.

注射器7包含饋料頸9,其將注射器7連接至模具11。憑藉氣流3經由體料頸9將發泡聚合物顆粒1推至模具11中。 The syringe 7 contains a feed neck 9 which connects the syringe 7 to the mold 11. The foamed polymer particles 1 are pushed into the mold 11 via the body neck 9 by means of the gas stream 3.

在本文所描繪的具體實例中,存在環形管道13,其包圍中 心管道5且經由環形管道另外引入氣體。為此目的,環形管道13通向中心管道5之末端處的環形間隙15。在本文所描繪的具體實例中,環形管道13在環形間隙15之區域中在其末端處具有錐形直徑縮減部分17,其中直徑減小至饋料頸9之直徑。與本文所描繪的錐形直徑縮減部分17並存,當然另一可能性為該直徑縮減部分被設計成具有任何其他所要之幾何形狀。藉助於實例,在一或多個步驟中之不連續直徑縮減因此為可能的。替代地,直徑縮減部分之形狀根據其半徑亦可為凹形或凸形;其亦可為橢圓、拋物線或雙曲線形。亦可能為混合形狀。 In the specific example depicted herein, there is an annular duct 13 that is surrounded by The heart duct 5 is additionally introduced with gas via an annular duct. For this purpose, the annular duct 13 leads to an annular gap 15 at the end of the central duct 5. In the particular example depicted herein, the annular duct 13 has a tapered diameter reduction portion 17 at its end in the region of the annular gap 15, wherein the diameter is reduced to the diameter of the feed neck 9. Coexisting with the tapered diameter reduction portion 17 depicted herein, of course, another possibility is that the diameter reduction portion is designed to have any other desired geometry. By way of example, discontinuous diameter reduction in one or more steps is therefore possible. Alternatively, the shape of the reduced diameter portion may be concave or convex depending on its radius; it may also be elliptical, parabolic or hyperbolic. It may also be a mixed shape.

經由環形管道13引入的氣流輔助填充程序直至已完全填充 模具11。穿過環形管道13之氣體較佳與用於經由中心管道5傳輸發泡聚合物顆粒1之氣體相同。 The airflow introduced via the annular duct 13 assists the filling procedure until it is completely filled Mold 11. The gas passing through the annular duct 13 is preferably the same as the gas for transporting the foamed polymer particles 1 via the central duct 5.

在本發明中之饋料頸9內,存在至少一個用於引入壓縮氣體 之孔口19。較佳地存在複數個經設置用於引入壓縮氣體之孔口19,其中該配置可在孔口之間具有任何所要距離或可具有彼此等距之孔口。優先考慮孔口19之等距配置,且在該種狀況下,較佳的是,孔口中之每一者在距離饋料頸9之出口21之相同軸向距離處,且該配置在孔口19之間具有相等距離。亦可能藉由相對於彼此之偏移將孔口19定位在距離饋料頸9之出口21之不同軸向距離處。所有孔口19是具有距離饋料頸9之出口21之相同軸向距離或具有距離饋料頸9之出口21之不同距離尤其視饋料頸之長度而定。 In the feed neck 9 of the present invention, there is at least one for introducing a compressed gas The orifice 19 is. Preferably there are a plurality of orifices 19 arranged to introduce a compressed gas, wherein the configuration may have any desired distance between the orifices or may have orifices equidistant from each other. Priority is given to the equidistant arrangement of the orifices 19, and in this case it is preferred that each of the orifices is at the same axial distance from the outlet 21 of the feed neck 9 and that the configuration is at the orifice There is an equal distance between 19. It is also possible to position the orifice 19 at a different axial distance from the outlet 21 of the feed neck 9 by offset relative to each other. All orifices 19 are of the same axial distance from the outlet 21 of the feed neck 9 or have a different distance from the outlet 21 of the feed neck 9, in particular depending on the length of the feed neck.

較佳的是,藉助於氣體分佈環23將壓縮氣體引入孔口19 中。本文之氣體分佈環23包圍饋料頸9之內壁15,且孔口19中之每一者之一個末端通向氣體分佈環23。因此將壓縮氣體均勻地供應至所有孔口19。替代地,當然亦可能將僅個別孔口19連接至氣體分佈環23且藉助於第二氣體分佈環使其他孔口19供應壓縮氣體或將壓縮氣體分別供應至其他孔口19中之每一者。本文之藉助於孔口19引入的壓縮氣體同樣較佳地與用於 傳輸發泡聚合物顆粒之氣體相同。 Preferably, the compressed gas is introduced into the orifice 19 by means of the gas distribution ring 23. in. The gas distribution ring 23 herein surrounds the inner wall 15 of the feed neck 9, and one end of each of the orifices 19 leads to the gas distribution ring 23. The compressed gas is thus uniformly supplied to all of the orifices 19. Alternatively, it is of course also possible to connect only the individual orifices 19 to the gas distribution ring 23 and to supply the other orifices 19 with compressed gas or to supply compressed gas to each of the other orifices 19 by means of the second gas distribution ring. . The compressed gas introduced here by means of the orifice 19 is likewise preferably used with The gas transporting the foamed polymer particles is the same.

較佳藉助於氣體連接25將壓縮氣體供應至氣體分佈環23。 與如本文所描繪的單一氣體連接25並存,另一可能性為在氣體分佈環23處設置複數個氣體連接。然而,優先考慮僅一個氣體連接25。 The compressed gas is preferably supplied to the gas distribution ring 23 by means of a gas connection 25. In conjunction with a single gas connection 25 as depicted herein, another possibility is to provide a plurality of gas connections at the gas distribution ring 23. However, only one gas connection 25 is preferred.

若無氣體分佈環23使用以將壓縮氣體供應至孔口19,則有 必要對各個別孔口19設置氣體連接。然而,此增加裝置成本,且因此較佳為將所有孔口19連接至氣體分佈環23,且以此方式實現壓縮氣體之供應。 If no gas distribution ring 23 is used to supply compressed gas to the orifice 19, then It is necessary to provide a gas connection to each of the orifices 19. However, this increases the cost of the device, and therefore it is preferred to connect all of the orifices 19 to the gas distribution ring 23 and in this way achieve a supply of compressed gas.

在充添材料至模具11期間,可藉助於環形管道13及孔口 19引入氣體。替代地,亦可能的是,僅藉由使用用於傳輸發泡聚合物顆粒之氣流充添材料。在該種狀況下,環形間隙15及孔口19之尺寸標註尤為有利,使得無發泡聚合物顆粒可被吹至環形管道13或孔口19中。為此目的,以實例說明之可能使用具有小於發泡聚合物顆粒之最小直徑的網目寬度之柵格以阻塞環形間隙15及孔口19。替代地,亦可能製造具有小於發泡聚合物顆粒之最小直徑的間隙寬度之環形間隙,及製造具有相應較小孔口直徑之孔口19。然而,較佳的是,在整個填充程序期間藉助於環形間隙15及孔口19將氣體注射至管道中以防止發泡聚合物顆粒傳送至環形間隙15或孔口19中。 During the filling of the material to the mould 11, the annular duct 13 and the orifice can be used 19 introduces a gas. Alternatively, it is also possible to fill the material only by using a gas stream for transporting the foamed polymer particles. In this case, the annular gap 15 and the size of the orifice 19 are particularly advantageous so that the non-foamed polymer particles can be blown into the annular duct 13 or the orifice 19. For this purpose, it is possible to use a grid having a mesh width smaller than the smallest diameter of the foamed polymer particles to block the annular gap 15 and the orifice 19 by way of example. Alternatively, it is also possible to produce an annular gap having a gap width smaller than the smallest diameter of the foamed polymer particles, and to manufacture the orifice 19 having a correspondingly smaller orifice diameter. Preferably, however, gas is injected into the conduit by means of the annular gap 15 and the orifice 19 throughout the filling procedure to prevent the expanded polymer particles from being transferred into the annular gap 15 or orifice 19.

此外可能設置直接通向饋料頸9之前的中心管道5之個別管 道來代替環形管道13。在該種狀況下,有利的是設置複數個管道,較佳等距離地圍繞中心管道配置。在另一變型中,亦可能設置各個供應有壓縮氣體或藉助於共用氣體分配器供應有壓縮氣體之孔口來代替環形間隙15。 It is also possible to provide individual tubes of the central duct 5 directly before the feed neck 9 The road replaces the annular duct 13. In such a situation, it is advantageous to provide a plurality of conduits, preferably equidistantly disposed around the central conduit. In a further variant, it is also possible to provide an orifice which is supplied with compressed gas or which is supplied with compressed gas by means of a common gas distributor instead of the annular gap 15.

圖2描繪了本發明之方法之第二步驟。 Figure 2 depicts the second step of the method of the present invention.

在圖2中所描繪的步驟中,模具11已完全填充有發泡聚合 物顆粒1。藉助於經由環形管道13及環形間隙15之氣體流動,在中心管道5中產生逆流,以此方式使得無另外發泡聚合物顆粒1在饋料頸9方向上傳 輸。另外,由於在模具11中不存在另外空間,憑藉經由孔口19注射之壓縮氣體將發泡聚合物顆粒從饋料頸9吹回至中心管道5中。此防止發泡聚合物顆粒1在饋料頸中累積,在經由個別聚合物顆粒之熔融製造模製品期間該累積將在模製品上形成突起。 In the step depicted in Figure 2, the mold 11 has been completely filled with foamed polymerization. Particle 1. By means of the gas flow via the annular duct 13 and the annular gap 15, a countercurrent is generated in the central duct 5 in such a way that no additional foamed polymer particles 1 are uploaded in the direction of the feed neck 9 lose. In addition, the foamed polymer particles are blown back from the feed neck 9 into the center duct 5 by the compressed gas injected through the orifice 19 due to the absence of additional space in the mold 11. This prevents the foamed polymer particles 1 from accumulating in the feed neck, which will form protrusions on the molded article during the manufacture of the molded article via the melting of the individual polymer particles.

為了將發泡聚合物顆粒從饋料頸吹回至中心管道中,必要的 是,設計的孔口19如此使得經由孔口19注射之壓縮空氣具有垂直於饋料頸9之軸線27的速度分量。為此目的,必要的是,通常呈孔之形式的孔口19相對於饋料頸9之中心軸線27呈現大於0°之角度。尤其較佳的是,如本文所描繪,孔口19垂直於饋料頸9之軸線27運行,以此方式使得在來自孔口19之出口處,唯一速度分量垂直於饋料頸9之軸線27。以實例說明之藉由用於傳輸發泡聚合物顆粒1之氣流或另外藉由流經複數個孔口19之氣流的彼此碰撞或與相對於孔口19之饋料頸9的壁碰撞,引起經由孔口19引入的氣流之偏轉。 In order to blow the foamed polymer particles back from the feed neck to the central pipe, necessary Yes, the orifice 19 is designed such that the compressed air injected via the orifice 19 has a velocity component perpendicular to the axis 27 of the feed neck 9. For this purpose, it is necessary that the orifice 19, usually in the form of a hole, exhibits an angle greater than 0° with respect to the central axis 27 of the feed neck 9. It is especially preferred that, as depicted herein, the orifice 19 runs perpendicular to the axis 27 of the feed neck 9 in such a way that at the exit from the orifice 19, the only velocity component is perpendicular to the axis 27 of the feed neck 9. . By way of example, the gas flow for transporting the foamed polymer particles 1 or otherwise by the gas flow through the plurality of orifices 19 collides with each other or with the wall of the feed neck 9 with respect to the orifice 19, causing The deflection of the air flow introduced via the aperture 19.

圖3描繪了本發明之方法之第三步驟。 Figure 3 depicts the third step of the method of the present invention.

一旦已完成充添材料至模具11,經由中心管道5在模具11 方向上移動注射器活塞29。在充添發泡聚合物顆粒1至模具11期間,如圖1及圖2中所描繪,注射器活塞29之位置位於本文未描繪的靜止位置。本文之靜止位置之位置較佳在將發泡聚合物顆粒1引入注射器7中的點處之後方,以便注射器活塞29不破壞發泡聚合物顆粒1流至模具11中。 Once the filling material has been completed to the mold 11, via the center pipe 5 in the mold 11 The syringe plunger 29 is moved in the direction. During the filling of the foamed polymer particles 1 to the mold 11, as depicted in Figures 1 and 2, the position of the syringe piston 29 is in a rest position not depicted herein. The position of the rest position herein is preferably after the point at which the foamed polymer particles 1 are introduced into the syringe 7, so that the syringe piston 29 does not destroy the flow of the expanded polymer particles 1 into the mold 11.

壓縮氣體經由孔口19流動保持饋料頸9不含發泡聚合物顆 粒1。此外,壓縮氣體經由孔口19流動確保無發泡聚合物顆粒1從模具11傳送回至饋料頸9中且因此回至注射器7中。因此維持模具11之最佳化填充。藉由經由饋料頸中的孔口19及經由環形間隙15之氣體流動將仍位於中心管道5內的發泡聚合物顆粒1吹回。因此可能以准許注射器活塞29移動至饋料頸9中而不破壞發泡聚合物顆粒1之方式保持中心管道5實質上極 其不含發泡聚合物顆粒1。 The compressed gas flows through the orifice 19 to keep the feed neck 9 free of foamed polymer particles. Granule 1. Furthermore, the flow of compressed gas through the orifice 19 ensures that the non-foamed polymer particles 1 are transported back from the mould 11 into the feed neck 9 and thus back into the syringe 7. Therefore, the optimum filling of the mold 11 is maintained. The foamed polymer particles 1 still located in the central duct 5 are blown back by the flow of the gas through the orifice 19 in the feed neck and via the annular gap 15. It is therefore possible to maintain the central duct 5 substantially in a manner that permits the syringe piston 29 to move into the feed neck 9 without damaging the foamed polymer particles 1. It does not contain foamed polymer particles 1.

本文之注射器活塞29之設計較佳使得末端31之截面積對應 於饋料頸9之進入模具11的出口21之截面積。因此可能使用注射器活塞29封閉饋料頸9之進入模具11的出口21以形成模製品。此外,注射器活塞29之末端31之設計為有利的,使得此末端提供模具11之連續的內部表面,因此避免在充添點處之模製品形狀的任何不連續性。 The syringe piston 29 herein is preferably designed such that the cross-sectional area of the tip 31 corresponds to The cross-sectional area of the feed neck 9 into the outlet 21 of the mold 11. It is therefore possible to use the syringe piston 29 to close the inlet 21 of the feed neck 9 into the mold 11 to form a molded article. Furthermore, the design of the end 31 of the syringe piston 29 is advantageous such that this end provides a continuous inner surface of the mold 11, thus avoiding any discontinuities in the shape of the molded article at the point of filling.

將注射器活塞29移至注射器7中直至其封閉饋料頸9之進 入模具11的出口21。將此描繪為圖4中之第四步驟。 The syringe plunger 29 is moved into the syringe 7 until it closes the feed neck 9 Enter the outlet 21 of the mold 11. This is depicted as the fourth step in Figure 4.

為了防止聚合物顆粒1隨後進一步流至中心管道5中,此外 藉助於環形管道13及環形間隙15引入氣體。在注射器活塞29處於其前向終端位置且封閉饋料頸9之進入模具11的出口21時,氣體因此經由中心管道5流動離開模具且因此保持中心管道5本質上不含發泡聚合物顆粒1,以此方式使得一旦已完成模製品之生產且可使模製品脫模,當移回注射器活塞29時,無發泡聚合物顆粒1可阻塞注射器活塞29之路徑。 In order to prevent the polymer particles 1 from subsequently flowing further into the central pipe 5, The gas is introduced by means of the annular duct 13 and the annular gap 15. When the syringe piston 29 is in its forward end position and encloses the inlet 21 of the feed neck 9 into the mold 11, the gas thus flows away from the mold via the central conduit 5 and thus the central conduit 5 is essentially free of foamed polymer particles 1 In this way, once the production of the molded article has been completed and the molded article can be demolded, the non-foamed polymer particles 1 can block the path of the syringe piston 29 when moving back to the syringe plunger 29.

為了完成模製品之生產,一旦注射器活塞29已到達其前向 終端位置,加熱發泡聚合物顆粒1之表面直至顆粒變軟且可彼此熔融。為此目的,以實例說明之可能經由模具11傳送熱氣體,尤其較佳蒸汽。一旦已黏結發泡聚合物顆粒1從而產生模製品,打開模具11且可移出模製品。 同時,將注射器活塞29移回至其靜止位置,以此方式使得,一旦已移出模製品且接著已封閉設備,可重複該過程。 In order to complete the production of the molded article, once the syringe piston 29 has reached its forward direction The terminal position heats the surface of the foamed polymer particles 1 until the particles become soft and can melt with each other. For this purpose, it is possible to transfer hot gases, in particular steam, via a mould 11 by way of example. Once the foamed polymer particles 1 have been bonded to produce a molded article, the mold 11 is opened and the molded article can be removed. At the same time, the syringe piston 29 is moved back to its rest position in such a way that the process can be repeated once the molded article has been removed and then the device has been closed.

1‧‧‧發泡聚合物顆粒 1‧‧‧Foamed polymer particles

5‧‧‧管道 5‧‧‧ Pipes

7‧‧‧注射器 7‧‧‧Syringe

9‧‧‧饋料頸 9‧‧‧Feed neck

11‧‧‧模具 11‧‧‧Mold

13‧‧‧管道 13‧‧‧ Pipes

15‧‧‧環形間隙 15‧‧‧ annular gap

19‧‧‧孔口 19‧‧‧孔口

21‧‧‧出口 21‧‧‧Export

23‧‧‧氣體分佈環 23‧‧‧ gas distribution ring

25‧‧‧連接 25‧‧‧Connect

29‧‧‧注射器活塞 29‧‧‧Syringe piston

31‧‧‧截面積 31‧‧‧ cross-sectional area

Claims (14)

一種用於充添材料至模具(11)以從發泡聚合物顆粒(1)生產模製品之注射器,其包含用於引入發泡聚合物顆粒(1)之管道(5)、饋料頸(9)及注射器活塞(29),其中該饋料頸(9)毗連用於引入發泡聚合物顆粒(1)之該管道(5),且其中該注射器活塞(29)在其朝向該模具(11)之末端處具有對應於該饋料頸(9)之進入該模具(11)的出口(21)處的截面積之截面積(31),且移動該注射器活塞(29)以使得可憑藉該注射器活塞(29)迫使發泡聚合物顆粒(1)從該饋料頸(9)進入該模具(11)中,其中該饋料頸(9)具有至少一個孔口(19),可經由該孔口將壓縮氣體引入該饋料頸(9)中。 A syringe for filling a material to a mold (11) to produce a molded article from the foamed polymer particles (1), comprising a pipe (5) for feeding the foamed polymer particles (1), a feed neck ( 9) and a syringe piston (29), wherein the feed neck (9) adjoins the conduit (5) for introducing foamed polymer particles (1), and wherein the syringe piston (29) faces the mold ( 11) has a cross-sectional area (31) corresponding to the cross-sectional area of the feed neck (9) at the outlet (21) of the mold (11), and moves the syringe piston (29) so that The syringe piston (29) forces the foamed polymer particles (1) from the feed neck (9) into the mold (11), wherein the feed neck (9) has at least one orifice (19) via The orifice introduces compressed gas into the feed neck (9). 如申請專利範圍第1項之注射器,其中用於將壓縮氣體引入該饋料頸(9)中之該孔口(19)之定向使得引入的該壓縮氣體具有垂直於該饋料頸(9)之軸線的速度分量。 A syringe according to claim 1, wherein the orifice (19) for introducing compressed gas into the feed neck (9) is oriented such that the introduced compressed gas has a perpendicular to the feed neck (9) The velocity component of the axis. 如申請專利範圍第1項之注射器,其中存在至少兩個經設置用於將壓縮氣體引入該饋料頸(9)中之孔口(19),其中該配置具有均勻地分佈於該饋料頸(9)之周邊上的該等孔口(19)。 A syringe according to claim 1 wherein there are at least two orifices (19) arranged to introduce compressed gas into the feed neck (9), wherein the configuration has a uniform distribution over the feed neck The apertures (19) on the perimeter of (9). 如申請專利範圍第3項之注射器,其中存在該等至少兩個用於將壓縮氣體引入該饋料頸(9)中之孔口(19)至包圍該饋料頸(9)之氣體分佈環(23)的連接。 A syringe according to claim 3, wherein there are at least two orifices (19) for introducing compressed gas into the feed neck (9) to a gas distribution ring surrounding the feed neck (9) (23) connection. 如申請專利範圍第4項之注射器,其中該氣體分佈環(23)具有至少一個連接(25),可藉助於該連接引入壓縮氣體。 A syringe according to claim 4, wherein the gas distribution ring (23) has at least one connection (25) by means of which a compressed gas can be introduced. 如申請專利範圍第1項之注射器,其中另外包含至少一個用於引入氣體之管道(13)且在該饋料頸(9)之上游通向用於引入發泡聚合物顆粒之該管道(5)。 A syringe according to claim 1 which additionally comprises at least one conduit (13) for introducing a gas and leading to the conduit for introducing foamed polymer particles upstream of the feed neck (9) (5) ). 如申請專利範圍第6項之注射器,其中用於引入氣體之該管道(13) 同軸地包圍用於引入發泡聚合物顆粒(1)之該管道(5)。 A syringe according to claim 6 wherein the conduit for introducing a gas (13) The pipe (5) for introducing the foamed polymer particles (1) is coaxially surrounded. 如申請專利範圍第6項之注射器,其中至少兩個用於引入氣體之管道與用於引入發泡聚合物顆粒(1)之該管道(5)平行運行,其中該配置具有圍繞用於引入發泡聚合物顆粒(1)之該管道(5)均勻分佈的用於引入氣體之該等管道。 A syringe according to claim 6 wherein at least two of the conduits for introducing a gas run in parallel with the conduit (5) for introducing the foamed polymer particles (1), wherein the configuration has a circumference for introducing the hair The tubes (5) of the blister polymer particles (1) are uniformly distributed for the introduction of the gas. 一種從發泡聚合物顆粒(1)生產模製品之方法,其包含以下步驟:(a)藉助於如申請專利範圍第1項至第8項中任一項之用於充添材料至該模具(11)之注射器(7)充添發泡聚合物顆粒(1)至模具(11),其中經由用於引入該等發泡聚合物顆粒(1)之該管道(5)引入該等發泡聚合物顆粒(1),且在已將材料充添至該模具(11)之後,經由用於引入壓縮氣體之該孔口(19)將壓縮氣體引入該饋料頸(9)中,(b)將仍在該饋料頸(9)內包含的該等發泡聚合物顆粒(1)推至該模具(11)中且一旦該模具(11)已經完全填充,經由在該模具(11)之方向上移動該注射器活塞(29)來封閉該模具(11),及(c)加熱該等發泡聚合物顆粒(1)以致此等顆粒變得彼此黏結以產生該模製品。 A method for producing a molded article from a foamed polymer particle (1), comprising the steps of: (a) supplying a material to the mold by means of any one of items 1 to 8 of the patent application; The syringe (7) of (11) is filled with the foamed polymer particles (1) to the mold (11), wherein the foaming is introduced via the pipe (5) for introducing the foamed polymer particles (1) Polymer particles (1), and after the material has been charged to the mold (11), compressed gas is introduced into the feed neck (9) via the orifice (19) for introducing compressed gas, (b) Pushing the foamed polymer particles (1) still contained in the feed neck (9) into the mold (11) and once the mold (11) has been completely filled, via the mold (11) The syringe piston (29) is moved in the direction to close the mold (11), and (c) the foamed polymer particles (1) are heated so that the particles become bonded to each other to produce the molded article. 如申請專利範圍第9項之方法,其中為了在步驟(c)中加熱該等發泡聚合物顆粒(1),使蒸汽穿過該模具(11)。 The method of claim 9, wherein the steam is passed through the mold (11) in order to heat the foamed polymer particles (1) in the step (c). 如申請專利範圍第9項之方法,其中該等發泡聚合物顆粒(1)包含熱塑性聚合物。 The method of claim 9, wherein the foamed polymer particles (1) comprise a thermoplastic polymer. 如申請專利範圍第11項之方法,其中該熱塑性聚合物係選自膨脹熱塑性聚胺甲酸酯、膨脹聚丙烯及此等聚合物之混合物及包含此等聚合物之單體單元之共聚物。 The method of claim 11, wherein the thermoplastic polymer is selected from the group consisting of expanded thermoplastic polyurethanes, expanded polypropylene, and mixtures of such polymers and copolymers comprising monomeric units of such polymers. 如申請專利範圍第9項之方法,其中在步驟(a)中之整個充添程序期間,藉助於用於引入氣體之該管道(13)及藉助於用於引入壓縮氣體 之該等孔口(19)引入氣體。 The method of claim 9, wherein during the entire filling procedure in step (a), by means of the conduit (13) for introducing a gas and by means of introducing a compressed gas The orifices (19) introduce a gas. 如申請專利範圍第9項之方法,其中該氣體係選自空氣、氮氣及蒸汽。 The method of claim 9, wherein the gas system is selected from the group consisting of air, nitrogen, and steam.
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