TW201519785A - Composition for controlling plant diseases and method for controlling plant diseases - Google Patents

Composition for controlling plant diseases and method for controlling plant diseases Download PDF

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TW201519785A
TW201519785A TW103113826A TW103113826A TW201519785A TW 201519785 A TW201519785 A TW 201519785A TW 103113826 A TW103113826 A TW 103113826A TW 103113826 A TW103113826 A TW 103113826A TW 201519785 A TW201519785 A TW 201519785A
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plant
ethaboxam
seed
parts
diseases
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TW103113826A
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Chinese (zh)
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Takuya Inoue
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Sumitomo Chemical Co
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Abstract

Provided is a composition for controlling plant diseases containing ethaboxam and fluopicolide, a seed treating agent containing ethaboxam and fluopicolide, a plant seed attached an effective amount of ethaboxam and fluopicolide, and a method for controlling plant diseases by applying an effective amount of ethaboxam and fluopicolide to a plant or soil for cultivating a plant. Thus this invention can provide a composition for controlling plant diseases having excellent plant disease controlling activity and a method for controlling plant diseases.

Description

植物病害防除用組成物及植物病害的防除方法 Plant disease control composition and plant disease prevention method

本發明,係關於植物病害防除用組成物及植物病害的防除方法。 The present invention relates to a method for controlling a plant disease control composition and a plant disease.

先前已知,噻唑菌胺(ethaboxam)(參考如專利文獻1。)及氟比來(fluopicolide)(參考如專利文獻2。),係植物病害防除劑之有效成分。 Etoboxam (refer to, for example, Patent Document 1) and fluopicolide (refer to Patent Document 2) are known as active ingredients of plant disease control agents.

[先前技術文獻] [Previous Technical Literature] 專利文獻 Patent literature

[專利文獻1]美國專利第5514643號說明書 [Patent Document 1] US Patent No. 5154643

[專利文獻2]專利特表2002-503723號公報 [Patent Document 2] Patent Special Table 2002-503723

本發明之課題,係在提供具優良植物病害防除效力之植物病害防除用組成物、及植物病害的防除方法。 An object of the present invention is to provide a plant disease control composition having excellent plant disease control effect and a method for controlling plant diseases.

本案之發明人等,為尋求具優良植物病害防 除效力之植物病害防除用組成物而加以檢討,結果發現含噻唑菌胺及氟比來之植物病害防除用組成物,對植物病害可發揮優良之效力。 The inventor of the case, etc., in order to seek for prevention of excellent plant diseases In addition to the efficacy of the plant disease control composition, it was found that the composition of the plant disease control agent containing the ethaboxam and the fluorine ratio exerted excellent effects on plant diseases.

亦即,本發明係如下之項目。 That is, the present invention is as follows.

[1]一種植物病害防除用組成物,其係含噻唑菌胺及氟比來。 [1] A plant disease control composition comprising thiastrobin and a fluorine ratio.

[2]如[1]項記載之植物病害防除用組成物,其中噻唑菌胺與氟比來之重量比為1:0.01至1:50。 [2] The plant disease control composition according to [1], wherein the weight ratio of ethaboxam to fluorine is from 1:0.01 to 1:50.

[3]一種種子處理劑,其係含噻唑菌胺及氟比來。 [3] A seed treatment agent comprising ethaboxam and a fluorine ratio.

[4]一種植物種子,其係附著有效量之噻唑菌胺及氟比來。 [4] A plant seed which is attached to an effective amount of ethaboxam and a fluorine ratio.

[5]一種植物病害的防除方法,其係以有效量之噻唑菌胺及氟比來,施用於植物或栽培植物之土壤。 [5] A method for controlling a plant disease, which is applied to a soil of a plant or a cultivated plant in an effective amount of ethaboxam and a fluorine ratio.

[6]一種噻唑菌胺與氟比來之組合之用途,係用以防除植物病害。 [6] A use of a combination of ethaboxam and fluorine to control plant diseases.

本發明之植物病害防除用組成物中所使用之噻唑菌胺,係美國專利第5514643號說明書中所記載之化合物,可由商品化之製劑得到、或以一般已知之方法製造。 The ethaboxam used in the plant disease control composition of the present invention is a compound described in the specification of U.S. Patent No. 5,514,643, which can be obtained from a commercially available preparation or by a generally known method.

本發明植物病害防除用組成物中所使用之氟比來,係專利特表2002-503723號公報中記載之化合物,可由商品化之製劑得到、或以一般已知之方法製造。 The fluorine ratio used in the composition for controlling plant diseases of the present invention is a compound described in JP-A-2002-503723, which can be obtained from a commercially available preparation or by a generally known method.

本發明之植物病害防除用組成物中,噻唑菌胺與氟比來之重量比,一般以1:0.01至1:50為佳,1:0.05至1:20更佳。同時,在使用作為種子處理劑時,一般以1:0.01至1:50為佳,1:0.04至1:25更佳。 In the composition for controlling plant diseases of the present invention, the weight ratio of ethaboxam to fluorine is generally preferably from 1:0.01 to 1:50, more preferably from 1:0.05 to 1:20. Meanwhile, when used as a seed treatment agent, it is generally preferably from 1:0.01 to 1:50, more preferably from 1:0.04 to 1:25.

本發明之植物病害防除用組成物,可單獨以噻唑菌胺與氟比來混合,但是一般亦可以噻唑菌胺、氟比來、及固體載體、液體載體等非活性載體混合,並視須要再添加界面活性劑及其他製劑用助劑,然後經過製劑化成為油劑、乳劑、可濕性粉劑、水和劑、顆粒水和劑、粉劑、粒劑等。 The plant disease control composition of the present invention may be mixed with ethiazoline and fluorine ratio alone, but generally, it may be mixed with an inactive carrier such as ethaboxam, a fluorine ratio, a solid carrier or a liquid carrier, and if necessary, Adding surfactants and other auxiliary agents for formulation, and then formulating them into oils, emulsions, wettable powders, water and agents, granular water and agents, powders, granules and the like.

本發明之植物病害防除用組成物中,噻唑菌胺及氟比來之合計含量一般以0.1至99重量%為佳,0.2至90重量%更佳。 In the plant disease controlling composition of the present invention, the total content of the ethaboxam and the fluorine ratio is preferably from 0.1 to 99% by weight, more preferably from 0.2 to 90% by weight.

製劑化時所使用之固體載體,可舉如由:高嶺土、鎂鋁海泡石黏土、膨潤土、蒙脫石、酸性白土、葉蠟石、滑石、矽藻土、方解石等礦物,玉米穗軸粉、核桃殼粉等天然有機物,尿素等合成有機物,碳酸鈣、硫酸銨等鹽類,合成含水氧化矽等合成無機物等所成之微粉末或粒狀物等;液體載體,可舉如:二甲苯、甲苯、甲基萘等芳族烴類,2-丙醇、乙二醇、丙二醇、乙二醇單乙醚等醇類,丙酮、環己酮、異佛酮等酮類,大豆油、棉子油等植物油,石油系脂族烴類,酯類,二甲基亞碸、乙腈及水。 The solid carrier used in the formulation may be, for example, kaolin, magnesium aluminum sepiolite clay, bentonite, montmorillonite, acid white clay, pyrophyllite, talc, diatomaceous earth, calcite, etc., corn cob powder Natural organic matter such as walnut shell powder, synthetic organic matter such as urea, salt such as calcium carbonate and ammonium sulfate, fine powder or granule formed by synthesizing inorganic minerals such as aqueous cerium oxide; liquid carrier, for example, xylene , aromatic hydrocarbons such as toluene and methylnaphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol, and ethylene glycol monoethyl ether; ketones such as acetone, cyclohexanone, and isophorone, soybean oil, and cottonseed Vegetable oils such as oils, petroleum aliphatic hydrocarbons, esters, dimethyl hydrazine, acetonitrile and water.

界面活性劑,可舉如:烷基硫酸酯鹽、烷基芳基磺酸鹽、二烷基磺基琥珀酸鹽、聚氧伸乙基烷基芳基 醚磷酸酯鹽、木質素磺酸鹽、萘磺酸酯甲醛聚縮物等陰離子界面活性劑及聚氧伸乙基烷基芳基醚、聚氧伸乙基烷基聚氧伸丙基嵌段共聚物、山梨醇酐脂肪酸酯等非離子界面活性劑,及烷基三甲基銨鹽等陽離子界面活性劑。 The surfactant may, for example, be an alkyl sulfate salt, an alkyl aryl sulfonate, a dialkyl sulfosuccinate or a polyoxyethylidene aryl group. Anionic surfactants such as ether phosphate ester, lignosulfonate, naphthalenesulfonate formaldehyde polycondensate, and polyoxyalkylene aryl ether, polyoxyalkylene polyoxyalkylene propyl block A nonionic surfactant such as a copolymer or a sorbitan fatty acid ester, or a cationic surfactant such as an alkyltrimethylammonium salt.

其他之製劑用助劑,可舉如:聚乙烯醇、聚乙烯吡咯烷酮等水溶性高分子,阿拉伯膠、褐藻酸及其鹽、CMC(羧甲基纖維素)、三仙膠等多醣類,矽酸鋁鎂、氧化鋁溶膠等無機物,防腐劑、著色劑及PAP(酸性磷酸異丙酯)、BHT等安定劑。 Other auxiliary agents for preparation include water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, polysaccharides such as gum arabic, alginic acid and salts thereof, CMC (carboxymethyl cellulose), and Sanxian gum. An inorganic substance such as aluminum magnesium citrate or alumina sol, a preservative, a coloring agent, and a stabilizer such as PAP (acid isopropyl phosphate) or BHT.

本發明之植物病害防除用組成物,在各以噻唑菌胺及氟比來依照前述方法製劑化以外,亦可視其須要各以經水稀釋之製劑或各稀釋液混合調配。 The plant disease controlling composition of the present invention may be formulated according to the above-mentioned method in the form of each of the ethaboxam and the fluorine ratio, and may be prepared by mixing each diluted with water or each diluted solution.

本發明之植物病害防除用組成物,亦可再含其他1種以上之殺菌劑及/或殺蟲劑。 The plant disease controlling composition of the present invention may further contain one or more other fungicides and/or insecticides.

可以本發明防除之植物病害,可例舉如下者。水稻病害:稻熱病(Magnaporthe grisea)、胡麻葉枯病(Cochliobolus miyabeanus)、紋枯病(Rhizoctonia solani)、苗徒長病(Gibberella fujikuroi)。 The plant diseases which can be prevented by the present invention can be exemplified as follows. Rice diseases: rice fever ( Magnaporthe grisea ), flax leaf blight ( Cochliobolus miyabeanus ), sheath blight (Rizoctonia solani ), and Gibberella fujikuroi .

小麥病害:白粉病(Erysiphe graminis)、赤黴病(Fusarium graminearumF.avenacerumF.culmorumMicrodochium nivale)、層銹病(Puccinia striiformisP.graminisP.recondita)、紅色雪腐病(Micronectriella nivale)、雪腐小球菌核病(Typhula spp.)、裸黑穗病(Ustilago tritici)、腥黑穗病(Tilletia caries)、眼點病(Pseudocercosporella herpotrichoides)、葉枯病(Mycosphaerella graminicola)、冠腐病(Stagonospora nodorum)、黃斑病(Pyrenophora tritici-repentis)。 Wheat diseases: Erysiphe graminis , Fusarium graminearum , F. avenacerum , F. culmorum , Microdochium nivale , layer rust ( Puccinia striiformis , P. graminis , P. recondita ), red snow rot ( Micronectriella) nivale), snow ball Sclerotinia rot (Typhula spp.), loose smut (Ustilago tritici), bunt (Tilletia caries), eyespot (Pseudocercosporella herpotrichoides), leaf blight (Mycosphaerella graminicola), crown Stungospora nodorum , Pyrenophora tritici-repentis .

大麥病害:白粉病(Erysiphe graminis)、赤黴病(Fusarium graminearumF.avenacerumF.culmorumMicrodochium nivale)、葉銹病(Puccinia striiformisP.graminisP.hordei)、裸黑穗病(Ustilago nuda)、雲紋葉枯病(Rhynchosporium secalis)、網紋病(Pyrenophora teres)、斑點病(Cochliobolus sativus)、斑葉病(Pyrenophora graminea)、立枯病絲核菌屬(Rhizoctonia)菌引起之苗立枯病(Rhizoctonia solani)。 Barley diseases: Erysiphe graminis , Fusarium graminearum , F. avenacerum , F. culmorum , Microdochium nivale , leaf rust ( Puccinia striiformis , P. graminis , P. hordei ), bare smut ( Ustilago Nuda ), Rhynchosporium secalis , Pyrenophora teres , Cochliobolus sativus , Pyrenophora graminea , Rhizoctonia Rhizoctonia solani .

玉米病害:黑穗病(Ustilago maydis)、胡麻葉枯病(Cochliobolus heterostrophus)、環斑病(Gloeocercospora sorghi)、南方型銹病(Puccinia polysora)、灰斑病(Cercospora zeae-maydis)、立枯病絲核菌屬菌引起之曲立枯病(Rhizoctonia solani)。 Corn diseases: Ustilago maydis , Cochliobolus heterostrophus , Gloeocercospora sorghi , Puccinia polysora , Cercospora zeae-maydis , Litchi Rhizoctonia solani caused by the genus Rhizoctonia .

柑橘病害:黑點病(Diaporthe citri)、瘡痂病(Elsinoe fawcetti)、鞘腐敗病(Penicillium digitatumP.italicum)、裾腐病(Phytophthora parasiticaPhytophthora citrophthora)。 Citrus diseases: Diaporthe citri , Elsinoe fawcetti , Penicillium digitatum , P.italicum , Phytophthora parasitica , Phytophthora citrophthora .

蘋果病害:花腐病(Monilinia mali)、果腐病(Valsa ceratosperma)、白粉病(Podosphaera leucotricha)、葉斑病(Alternaria alternata apple pathotype)、黑星病(Venturia inaequalis)、炭疽病(Colletotrichum acutatum)、疫病 (Phytophtora cactorum)、褐斑病(Diplocarpon mali)、輪紋病(Botryosphaeria berengeriana)、紫紋羽病(Helicobasidium mompa)。 Apple diseases: Monilinia mali , Valsa ceratosperma , Podosphaera leucotricha , Alternaria alternata apple pathotype, Venturia inaequalis , Colletotrichum acutatum , Phytophtora cactorum , Diplocarpon mali , Botryosphaeria berengeriana , Helicobasidium mompa .

梨樹病害:黑星病(Venturia nashicolaV.pirina)、黑斑病(Alternaria alternate Japanese pear pathotype)、赤星病(Gymnosporangium haraeanum)、疫病(Phytophtora cactorum)。 Pear disease: black spot disease ( Venuria nashicola , V. pirina ), Alternaria alternate Japanese pear pathotype, Gymnosporangium haraeanum , Phytophtora cactorum .

桃樹病害:灰星病(Monilinia fructicola)、黑星病(Cladosporium carpophilum)、果腐病(Phomopsis spp.)。 Peach disease: Monilinia fructicola , Cladosporium carpophilum , Phomopsis spp.

葡萄病害:黑痘病(Elsinoe ampelina)、晚腐病(Glomerella cingulata)、白粉病(Uncinula necator)、層銹病(Phakopsora ampelopsidis)、黑腐病(Guignardia bidwellii)、露菌病(Plasmopara viticola)。 Grape diseases: Elsinoe ampelina , Glomerella cingulata , Uncinula necator , Phakopsora ampelopsidis , Guignardia bidwellii , Plasmopara viticola .

柿樹病害:炭疽病(Gloeosporium kaki)、角斑落葉病(Cercospora kakiMycosphaerella nawae)。 Persimmon disease: anthrax ( Gloeosporium kaki ), keratosis ( Cercospora kaki , Mycosphaerella nawae ).

瓜類病害:炭疽病(Colletotrichum lagenarium)、白粉病(Sphaerotheca fuliginea)、蔓枯病(Mycosphaerella melonis)、莖裂病(Fusarium oxysporum)、白粉病(Pseudoperonospora cubensis)、疫病(Phytophthora spp.)、曲立枯病(Pythium spp.)。 Melon diseases: Colletotrichum lagenarium , Sphaerotheca fuliginea , Mycosphaerella melonis , Fusarium oxysporum , Pseudoperonospora cubensis , Phytophthora spp., Qu Li Blight ( Pythium spp.).

蕃茄病害:輪紋病(Alternaria solani)、葉黴病(Cladosporium fulvum)、疫病(Phytophthora infestans)。 Tomato diseases: Alternaria solani , Cladosporium fulvum , Phytophthora infestans .

茄子病害:褐紋病(Phomopsis vexans)、白粉病(Erysiphe cichoracearum)。 Eggplant disease: Phomopsis vexans , Erysiphe cichoracearum .

十字花科蔬菜病害:黑斑病(Alternaria japonica)、白斑 病(Cercosporella brassicae)、根瘤病(Plasmodiophora brassicae)、露菌病(Peronospora parasitica)。 Cruciferous vegetable diseases: Alternaria japonica , Cercosporella brassicae , Plasmodiophora brassicae , Peronospora parasitica .

葱病害:層銹病(Puccinia allii)、露菌病(Peronospora destructor)。 Onion disease: Puccinia allii , Peronospora destructor .

大豆病害:紫斑病(Cercospora kikuchii)、黑痘病(Elsinoe glycines)、黑點病(Diaporthe phaseolorum var.sojae)、褐紋病(Septoria glycines)、斑點病(Cercospora sojina)、層銹病(Phakopsora pachyrhizi)、疫黴根腐病(Phytophthora sojae)、立枯病絲核菌屬菌引起之曲立枯病(Rhizoctonia solani)。 Soybean diseases: Cercospora kikuchii , Elsinoe glycines , Diaporthe phaseolorum var. sojae , Septoria glycines , Cercospora sojina , Phakopsora pachyrhizi , Phytophthora sojae , Rhizoctonia solani caused by Rhizoctonia solani .

菜豆病害:炭疽病(Colletotrichum lindemthianum)。 Bean diseases: anthracnose (Colletotrichum lindemthianum).

落花生病害:黑澀病(Cercospora personata)、褐斑病(Cercospora arachidicola)、白絹病(Sclerotium rolfsii)。 Groundnut disease: Cercospora personata , Cercospora arachidicola , Sclerotium rolfsii .

碗豆病害:白粉病(Erysiphe pisi)、根腐病(Fusarium solaniF.sp.pisi)。 Bowl bean disease: powdery mildew ( Erysiphe pisi ), root rot ( Fusarium solani , F. sp. pisi ).

馬鈴薯病害:早疫病(Alternaria solani)、疫病(Phytophthora infestans)、紅腐病(Phytophthora erythroseptica)、粉痂病(Spongospora subterranean F.sp.subterranea)、黑痣病(Rhizoctonia solani)。 Potato diseases: Alternaria solani , Phytophthora infestans , Phytophthora erythroseptica , Spongospora subterranean F. sp. subterranea , Rhizoctonia solani .

草莓病害:白粉病(Sphaerotheca humuli)、炭疽病(Glomerella cingulata)。 Strawberry disease: Sphaerotheca humuli , Glomerella cingulata .

茶樹病害:網餅病(Exobasidium reticulatum)、白星病(Elsinoe leucospila)、輪斑病(Pestalotiopsis spp.)、炭疽病(Colletotrichum theae-sinensis)。 Tea tree diseases: Exobasidium reticulatum , Elsinoe leucospila , Pestalotiopsis spp., and Colletotrichum theae-sinensis .

菸草病害:赤星病(Altermaria longipes)、白粉病(Erysiphe cichoracearum)、炭疽病(Colletotrichum tabacum)、露菌病(Peronospora tabacina)、疫病(Phytophthora nicotianae)。 Tobacco diseases: Altermaria longipes , Erysiphe cichoracearum , Colletotrichum tabacum , Peronospora tabacina , and Phytophthora nicotianae .

油菜病害:菌核病(Sclerotinia sclerotiorum)、立枯病絲核菌屬菌引起之曲立枯病(Rhizoctonia solani)。 Rape disease: Rhizoctonia solani caused by Sclerotinia sclerotiorum and Rhizoctonia solani .

棉花病害:立枯病絲核菌屬菌引起之苗立枯病(Rhizoctonia solani)。 Cotton disease: Rhizoctonia solani caused by Rhizoctonia solani .

甜菜病害:褐斑病(Cercospora beticola)、葉腐病(Rhizoctonia solani)、根腐病(Rhizoctonia solani)、黑根病(Aphanomyces cochlioides)。 Beet diseases: Cercospora beticola , Rhizoctonia solani , Rhizoctonia solani , Aphanomyces cochlioides .

薔薇病害:黑星病(Diplocarpon rosae)、白粉病(Sphaerotheca pannosa)、露菌病(Peronospora sparsa)。 Rose disease: Diplocarpon rosae , Sphaerotheca pannosa , and Peronospora sparsa .

菊及菊科蔬菜病害:露菌病(Bremia lactucae)、褐斑病(Septoria chrysanthemi-indici)、白銹病(Puccinia horiana)。 Chrysanthemum and Composita vegetable diseases: Bremia lactucae , Septoria chrysanthemi-indici , and white rust ( Puccinia horiana ).

各種植物病害:草苗立枯病菌屬(Pythium)菌所引起之病害(Pythium debarianumPythium graminicolaPythium irregularePythium ultimum)、灰黴病(Botrytis cinerea)、菌核病(Sclerotinia sclerotiorum)、白絹病(Sclerotium rolfsii)。 Various plant diseases: grass species seedling blight (Pythium) of diseases caused by fungi (Pythium debarianum, Pythium graminicola, Pythium irregulare, Pythium ultimum), gray mold (Botrytis cinerea), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum), southern blight Disease ( Sclerotium rolfsii ).

蘿蔔病害:黑斑病(Alternaria brassicicola)。 Radish disease: Alternaria brassicicola .

草坪病害:錢幣斑病(Sclerotinia homeocarpa)、褐斑病葉腐病及巨斑病(Rhizoctonia solani)。 Lawn diseases: Sclerotinia homeocarpa , brown spot leaf rot and Rhizoctonia solani .

香蕉病害:葉斑病(Mycosphaerella fijiensisMycosphaerella musicola)。 Banana disease: leaf spot disease ( Mycosphaerella fijiensis , Mycosphaerella musicola ).

向日葵病害:露菌病(Plasmopara halstedii)。 Sunflower diseases: Lou Junbing (Plasmopara halstedii).

Aspergillus(麴菌)屬、Penicillium(青黴菌)屬、Fusarium(鐮菌)屬、Gibberella(赤黴菌)屬、Trichoderma(木黴菌)屬、Thielaviopsis(根串珠黴)屬、Rhizopus(根黴菌)屬、Mucor(毛黴)屬、Corticium(皮殼菌)屬、Phoma(桑胴枯病菌)屬、Rhizoctonia(立枯絲核菌)屬、及Diplodia属菌等所引起,各種植物之種子病害及成長初期之病害。 Aspergillus , Penicillium , Fusarium , Gibberella , Trichoderma , Thielaviopsis , Rhizopus , Rhizopus Mucor (Muscular), Corticium , Phoma , Rhizoctonia , and Diplodia , causing seed diseases and early growth of various plants The disease.

Polymixa(多黏梭菌)屬或Olpidium(油壺菌)屬等所媒介之各種植物病毒病。 Polymixa (Clostridium polymyxa) genus or Olpidium (oiler bacteria) belongs to the media and other viral diseases of various plants.

在處理種子或球根等之情形時,可期待能有高效力之病害,可具體例舉如:小麥、大麥、玉米、水稻、高梁、大豆、棉花、油菜、甜菜及草坪之草苗立枯病屬菌所引起之苗立枯病及甘腐病(Pythium debarianumPythium graminicolaPythium irregularePythium ultimum)、甜菜黑根病(Aphanomyces cochlioides)、大豆疫黴根腐病(Phytophthora sojae)、菸草疫病(Phytophthora nicotianae)、向日葵露菌病(Plasmopara halstedii)、馬鈴薯疫病(Phytophthora infestans)等。 In the case of treating seeds or bulbs, etc., diseases capable of high efficiency can be expected, and specific examples thereof include: wheat, barley, corn, rice, sorghum, soybean, cotton, rape, beet, and turf grass blight. caused by bacteria of the genus Gan rot and seedling blight (Pythium debarianum, Pythium graminicola, Pythium irregulare, Pythium ultimum), black root rot of sugar beet (Aphanomyces cochlioides), Phytophthora root rot (Phytophthora sojae), tobacco disease ( Phytophthora nicotianae ), sunflower bacillus (P lasmopara halstedii ), potato blight (Phytophthora infestans ), and the like.

以有效量之噻唑菌胺及氟比來,施用於植物或栽培植物之土壤,即可防除植物病害。施用對象之植物,可舉如植物之莖葉、植物之種子、植物之球根等。再者,其中所謂球根,意指鱗莖、球莖、根莖、塊莖、塊根及根托。 By applying an effective amount of ethaboxam and a fluorine ratio to the soil of plants or cultivated plants, plant diseases can be prevented. The plant to which the object is applied may, for example, be a stem or leaf of a plant, a seed of a plant, a bulb of a plant, or the like. Furthermore, the so-called bulb, which means bulbs, bulbs, rhizomes, tubers, roots and roots.

在施用於植物、栽培植物之土壤等之情形時,可在同時期分別施用噻唑菌胺及氟比來,惟由一般施用時的簡便性之觀點而言,以施用本發明之植物病害防除用組成物較 佳。 In the case of application to plants, soil of cultivated plants, etc., it is possible to separately apply the ethaboxam and the fluorine ratio at the same time, but from the viewpoint of the simplicity of ordinary application, the plant disease control for applying the present invention is used. Composition good.

本發明之防除方法,具體上可舉如散布在莖葉等之植物莖葉處理、處理土壤等之植物栽培地處理、以種子消毒/種子塗布等之植物種子處理、對塊莖、塊根等球根之處理等。 Specific examples of the control method of the present invention include plant stem treatment such as treatment of plant stems and leaves, treatment of soil, etc., plant seed treatment such as seed disinfection/seed coating, and bulbs such as tubers and roots. Processing and so on.

本發明之防除方法中之植物莖葉處理,具體上,可舉如移植前由植物直接吸收的處理方法、莖葉散布、樹幹散布等在植物表面施用之處理方法。移植前由植物直接吸收的處理方法,可舉將植物整體或根部浸漬的方法,根部浸漬的方法,亦可使經過礦物粉末等固體載體製劑化者附著於根部。 The treatment of the plant stems and leaves in the method for controlling the present invention may be, for example, a treatment method for directly absorbing plants by transplantation, a stem and leaf dispersion, a trunk spread, or the like applied to the surface of the plant. The treatment method for directly absorbing the plant before transplantation may be a method of immersing the whole plant or the root portion, a method of immersing the root portion, or adhering to a root portion by a solid carrier formulation such as mineral powder.

本發明之防除方法中對植物栽培地之處理方法,可舉如散布在土壤、混合土壤、灌注(藥液灌溉、灌注土壤、藥液滴灌)藥液在土壤;處理之場所可舉如:植穴、植行、植穴附近、植行附近、栽培地全面、植物近地面部分、植株間、樹幹下、主幹畦土、覆土、育苗箱、育苗盤、苗床等;處理之時期可舉如:播種前、播種時、播種後即刻、育苗期、定植前、定植時、及定植後之成長期等。同時,對植物栽培地之處理,可同時以有效成分處理植物,亦可以含有效成分之糊劑肥料等固狀肥料施用於土壤。此外,亦可與灌溉液混合,如:灌注在灌溉設備(灌溉滴管、灌溉導管、噴水器等)內、灌注在植行間浸水液內、混入在水耕液內等。同時,亦可預先以灌溉液與有效成分混合,再以如上述灌溉方法及其他之澆水、浸水等適當的灌溉方法處理。 The method for treating plant cultivation sites in the method for controlling the present invention may be carried out in soil, mixed soil, perfusion (medical solution irrigation, perfusion soil, drug droplet irrigation) in the soil; the treatment site may be as follows: Acupoints, planting, near planting points, near planting, comprehensive cultivation, near-ground parts of plants, between plants, under trunks, main soil, covering soil, seedling boxes, seedling trays, seedbeds, etc.; Before sowing, sowing, immediately after sowing, seedling period, before planting, at the time of planting, and the growth period after planting. At the same time, the plant cultivation site can be treated with the active ingredient at the same time, or the solid fertilizer such as the paste fertilizer containing the active ingredient can be applied to the soil. In addition, it can also be mixed with irrigation liquid, such as: infusion equipment (irrigation pipettes, irrigation pipes, water sprayers, etc.), infusion in the interplanting water, and in the water. At the same time, the irrigation liquid may be mixed with the active ingredient in advance, and then treated by an appropriate irrigation method such as the above irrigation method and other watering and water immersion.

本發明之防除方法中所謂對種子之處理,可舉如:以本發明之植物病害防除用組成物處理欲保護使免受植物病害的植物之種子、球根等,具體而言例如:將本發明之植物病害防除用組成物的懸浮液以霧狀噴撒在種子表面或球根表面之噴撒處理、以本發明之植物病害防除用組成物的水和劑、乳劑或可濕性粉劑等加入少量水或直接塗布在種子或球根之塗布處理、以本發明之植物病害防除用組成物的溶液浸漬種子一定時間之浸漬處理、塗膜處理、粒膜處理。 In the method for controlling the seed of the present invention, the seed treatment, the bulb, and the like of the plant to be protected from plant diseases are treated with the plant disease control composition of the present invention, specifically, for example, the present invention The suspension of the plant disease control composition is sprayed on the surface of the seed or the surface of the bulb in a mist, and the water and the agent, the emulsion or the wettable powder of the plant disease control composition of the present invention are added in a small amount. The water is applied directly to the coating treatment of the seed or the bulb, and the seed is impregnated with the solution of the plant disease controlling composition of the present invention for a certain period of time, immersion treatment, coating treatment, and granule treatment.

以噻唑菌胺及氟比來,處理植物或栽培植物之土壤之情形時,其處理量,可視處理植物之種類、防除對象之植物病害的種類及發生程度、製劑形態、處理時期、氣象條件等而變化,但對每10000m2之噻唑菌胺及氟比來之合計含量(以下,稱為「本有效成分量」。),一般,以1至5000g為佳,2至500g更佳。 When the soil of a plant or a cultivated plant is treated with ethaboxam and a fluorine ratio, the amount of the treatment, the type of the plant to be treated, the type and degree of occurrence of the plant disease, the form of the preparation, the treatment period, the weather condition, etc. In addition, the total content (hereinafter referred to as "the amount of the active ingredient") per 10,000 m 2 of the ethaboxam and the fluorine ratio is preferably 1 to 5000 g, more preferably 2 to 500 g.

乳劑、水和劑、可濕性粉劑等一般以水稀釋後再撒布處理。該情形下,本有效成分量之濃度一般以0.0001至3重量%為佳,0.0005至1重量%更佳。粉劑、粒劑等一般不經過稀釋而直接處理。 Emulsions, water and agents, wettable powders, etc. are generally diluted with water and then sprinkled. In this case, the concentration of the active ingredient is generally preferably 0.0001 to 3% by weight, more preferably 0.0005 to 1% by weight. Powders, granules, etc. are generally processed directly without dilution.

對種子之處理,對於種子1kg本有效成分量一般以施用0.001至10g為佳,0.01至3g更佳。 For the treatment of the seed, the amount of the active ingredient of 1 kg of the seed is generally preferably 0.001 to 10 g, more preferably 0.01 to 3 g.

本發明之防除方法,可使用於旱田、水田、草皮、果園等農耕地或非農耕地。 The method for controlling the present invention can be used for agricultural fields or non-agricultural fields such as dry fields, paddy fields, turf and orchards.

此外,本發明,在栽培以下所舉之「植物」等之農耕 地中,可在對該植物等不造成藥害之下,使用以防除該農耕地之植物病害。 Further, the present invention cultivates the following "plants" and the like In the ground, it can be used to prevent plant diseases of the agricultural land without causing phytotoxicity to the plant or the like.

農作物:玉米、水稻、小麥、大麥、黑麥、燕麥、高梁、棉花、大豆、花生、蕎麥、甜菜、油菜、向日葵、甘蔗、菸草等,蔬菜:茄科蔬菜(茄子、蕃茄、甜椒、辣椒、馬鈴薯等)、瓜科蔬菜(胡瓜、南瓜、美國南瓜、西瓜、洋香瓜、金線瓜等)、十字花科蔬菜(蘿蔔、蕪菁、辣根、球莖甘藍、白菜、甘藍菜、芥菜、花椰菜、甘藍等)、菊科蔬菜(牛蒡、茼蒿、洋薊、萵苣等)、百合科蔬菜(葱、洋葱、大蒜、蘆筍)、香芹科蔬菜(胡蘿蔔、香芹、芹菜、美國食用芹菜等)、藜科蔬菜(菠菜、菾菜等)、唇形花科蔬菜(紫蘇、薄荷、羅勒等)、草莓、山芋、山藥、甘薯等,花卉,觀葉植物,草坪,果樹:仁果類(蘋果、西洋梨、橫山梨、榠、榅桲等)、核果類(桃、李、油桃、梅、甜櫻桃、杏、乾果李等)、柑橘類(溫州蜜柑、橘、檸檬、萊姆、葡萄柚等)、堅果類(栗、胡桃、板栗、扁桃、阿月渾子、腰果、澳洲胡桃等)、漿果類(藍莓、越橘、黑莓、覆盆子等)、葡萄、柿、橄欖、枇杷、香蕉、咖啡、海棗、可可椰子等、果樹以外之樹:茶樹、桑樹、觀花木、油桐、行道樹(梣樹、樺樹、山茱萸、桉樹、銀杏、紫丁香、槭樹、櫟樹、 楊樹、紫荊、楓香樹、梧桐樹、櫸樹、金鐘柏、樅樹、鐵杉、杜松、松樹、雲杉、紫杉)等。 Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, peanuts, buckwheat, beets, canola, sunflower, sugar cane, tobacco, etc. Vegetables: Solanaceae vegetables (eggplant, tomato, sweet pepper, chili) , potato, etc.), melon vegetables (courgette, pumpkin, American pumpkin, watermelon, cantaloupe, golden gourd, etc.), cruciferous vegetables (radish, turnip, horseradish, stalk, cabbage, kale, mustard, broccoli , cabbage, etc.), Compositae vegetables (burdock, artemisia, artichoke, lettuce, etc.), lily vegetables (onions, onions, garlic, asparagus), parsley vegetables (carrots, parsley, celery, American edible celery, etc.) , vegetables (spinach, leeks, etc.), lip-shaped vegetables (perilla, mint, basil, etc.), strawberries, hawthorn, yam, sweet potato, etc., flowers, foliage plants, lawns, fruit trees: pome fruits (apples) , Western pear, Yokohama, Poria, Poria , etc.), stone fruit (peach, plum, nectarine, plum, sweet cherry, apricot, dried fruit, etc.), citrus (Wenzhou mandarin, orange, lemon, lime, grape) Pomelo, etc., nuts (chestnut, walnut Chestnut, almond, pistachio, cashew, Australian walnut, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, olives, alfalfa, bananas, coffee, dates, coconut palms, etc. Trees other than tea: mulberry, mulberry, flower, tung tree, street tree (eucalyptus, birch, hawthorn, eucalyptus, ginkgo, lilac, maple, eucalyptus, poplar, bauhinia, sweet gum tree, sycamore tree, dragonfly Trees, thuja, eucalyptus, hemlock, juniper, pine, spruce, yew).

上述中,特別以使用於防除栽培玉米、水稻、小麥、大麥、高梁、棉花、大豆、甜菜、油菜、草坪、馬鈴薯之農耕地的病害較佳。 Among the above, it is particularly preferable to use a disease for controlling cultivation of corn, rice, wheat, barley, sorghum, cotton, soybean, sugar beet, rape, lawn, and potato.

上述「植物」亦包含基因重組植物。 The above "plants" also contain genetically modified plants.

實施例 Example

以下,再以製劑例、種子處理例、及試驗例更詳細說明本發明,惟本發明並不只限定於以下之例。再者,在以下之例中,若無特別限定則份係表示重量份。 Hereinafter, the present invention will be described in more detail by way of formulation examples, seed treatment examples, and test examples, but the present invention is not limited to the following examples. In the following examples, the parts represent parts by weight unless otherwise specified.

製劑例1 Formulation Example 1

將噻唑菌胺10份、氟比來2份、聚環氧乙烷苯乙烯基苯基醚14份、十二碳烷基苯并磺酸鈣6份、及二甲苯76.5份混合均勻而製得製劑。 10 parts of ethaboxam, 2 parts of fluorine, 14 parts of polyethylene oxide styrylphenyl ether, 6 parts of calcium dodecyl benzosulfonate, and 76.5 parts of xylene were uniformly mixed. preparation.

製劑例2 Formulation Example 2

將噻唑菌胺8份、氟比來2份、碳白與聚環氧乙烷烷基醚硫酸酯銨鹽之混合物(重量比例1:1)35份、及水55份混合,並以濕式粉碎法微粉碎而製得製劑。 8 parts of ethaboxam, 2 parts of fluorine ratio, 35 parts of a mixture of carbon white and polyethylene oxide alkyl ether sulfate ammonium salt (weight ratio 1:1), and 55 parts of water are mixed, and wet type The pulverization method is finely pulverized to prepare a preparation.

製劑例3 Formulation Example 3

將含噻唑菌胺2份、氟比來10份、山梨醇酐三油酸酯1.5份、及聚乙烯醇2份之水溶液31.5份混合,經過濕式粉碎法微粉碎之後,再於其中加入含三仙膠0.05份及矽酸鋁鎂0.1份之水溶液45份,再加入丙二醇10份並攪拌混合而製得製劑。 Mixing 2 parts of ethaboxam, 10 parts of fluorine, 1.5 parts of sorbitan trioleate, and 31.5 parts of an aqueous solution of 2 parts of polyvinyl alcohol, after being finely pulverized by wet pulverization, and then added thereto A solution of 0.05 parts of Sanxian gum and 0.1 part of aluminum magnesium citrate was added, and 10 parts of propylene glycol was further added and stirred to prepare a preparation.

製劑例4 Formulation Example 4

以噻唑菌胺40份、氟比來5份、丙二醇5份(NACALAI TESQUE公司製造)、Soprophor FLK 5份(Rhodia Nicca公司製造)、消泡劑C乳劑0.2份(Dow Corning Toray公司製造)、PROXEL GXL0.3份(Arch Chemical公司製造)、及離子交換水49.5份之比例加以混合,調配成原體漿料。在100份該漿料中投入150份玻璃細珠(Φ=1mm),並在同時以冷卻水冷卻下,粉碎2小時。粉碎後,過濾去除玻璃細珠,而得到製劑。 40 parts of ethaboxam, 5 parts of fluorine ratio, 5 parts of propylene glycol (manufactured by NACALAI TESQUE), 5 parts of Soprophor FLK (manufactured by Rhodia Nicca Co., Ltd.), 0.2 parts of antifoam C emulsion (manufactured by Dow Corning Toray Co., Ltd.), PROXEL GXL 0.3 parts (manufactured by Arch Chemical Co., Ltd.) and ion-exchanged water were mixed at a ratio of 49.5 parts to prepare a raw material slurry. 150 parts of glass fine beads (Φ = 1 mm) were placed in 100 parts of the slurry, and pulverized for 2 hours while being cooled with cooling water. After pulverization, the glass beads were removed by filtration to obtain a preparation.

製劑例5 Formulation Example 5

以噻唑菌胺10份、氟比來40份、NN高嶺土38.5份(竹原化學工業公司製造)、10份之Morwet D425、1.5份之Morwet EFW(AkzoNobel公司製造)之比例加以混合,並將製得之混合物以噴射磨機粉碎,而得到製劑。 10 parts of ethaboxam, 40 parts of fluorine ratio, 38.5 parts of NN kaolin (manufactured by Takehara Chemical Industry Co., Ltd.), 10 parts of Morwet D425, and 1.5 parts of Morwet EFW (manufactured by AkzoNobel Co., Ltd.) were mixed and prepared. The mixture was pulverized by a jet mill to obtain a formulation.

製劑例6 Formulation Example 6

將噻唑菌胺3份、氟比來2份、合成含水氧化矽1份、木質素磺酸鈣2份、膨潤土30份、及高嶺土62份完全粉碎混合,在加入水並拌混之後,經過造粒乾燥而得到製劑。 3 parts of ethaboxam, 2 parts of fluorine, 1 part of synthetic hydrous cerium oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite, and 62 parts of kaolin are completely pulverized and mixed, and after adding water and mixing, after making The granules were dried to give a preparation.

製劑例7 Formulation Example 7

將噻唑菌胺20份、氟比來15份、木質素磺酸鈣3份、月桂基硫酸鈉2份、及合成含水氧化矽60份完全粉碎混合而得到製劑。 20 parts of ethaboxam, 15 parts of fluorine ratio, 3 parts of calcium lignosulfonate, 2 parts of sodium lauryl sulfate, and 60 parts of synthetic aqueous cerium oxide were completely pulverized and mixed to obtain a preparation.

製劑例8 Formulation Example 8

將噻唑菌胺5份、氟比來1份、高嶺土84份、及滑石 10份完全粉碎混合而得到製劑。 5 parts of ethaboxam, 1 part of fluorine, 84 parts of kaolin, and talc Ten parts were completely pulverized and mixed to obtain a preparation.

種子處理例1 Seed treatment example 1

將依照製劑例1所製作之製劑,以相對於高梁乾燥種子100kg為500mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 The preparation prepared in accordance with Formulation Example 1 was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed at a rate of 500 mL per 100 kg of sorghum dried seeds.

種子處理例2 Seed treatment example 2

將依照製劑例2所製作之製劑,以相對於油菜乾燥種子10kg為50mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 The preparation prepared in accordance with Formulation Example 2 was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed, with 50 mL of 10 kg of dried rapeseed seeds.

種子處理例3 Seed treatment example 3

將依照製劑例3所製作之製劑,以相對於玉米乾燥種子10kg為40mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 The preparation prepared in accordance with Formulation Example 3 was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed in an amount of 40 mL with respect to 10 kg of dried corn seeds.

種子處理例4 Seed treatment example 4

將依照製劑例4所製作之製劑5份、色料BPD6135(Sun Chemical公司製造)5份、及水35份混合,調配成混合物。將該混合物,以相對於水稻乾燥種子10kg為60mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 5 parts of the preparation prepared in Formulation Example 4, 5 parts of the coloring material BPD6135 (manufactured by Sun Chemical Co., Ltd.), and 35 parts of water were mixed to prepare a mixture. The mixture was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed in an amount of 60 mL with respect to 10 kg of dried rice seeds.

種子處理例5 Seed treatment example 5

將依照製劑例5所製作之製劑,以相對於玉米乾燥種 子10kg為50g,進行粉衣處理,而得到處理之種子。 The preparation prepared according to Formulation Example 5 is dried relative to corn. The seed of 10 kg was 50 g, and the powder coating treatment was carried out to obtain a treated seed.

種子處理例6 Seed treatment example 6

將依照製劑例1所製作之製劑,以相對於甜菜乾燥種子100kg為500mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 The preparation prepared in accordance with Formulation Example 1 was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed, 500 kg of 100 kg of dried beet seeds.

種子處理例7 Seed treatment example 7

將依照製劑例2所製作之製劑,以相對於大豆乾燥種子10kg為50mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 The preparation prepared in accordance with Formulation Example 2 was subjected to a coating treatment with a rotary seed processor (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain a treated seed, 50 kg of 10 kg of soybean dried seeds.

種子處理例8 Seed treatment example 8

係將依照製劑例3所製作之製劑,以相對於小麥乾燥種子10kg為50mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 According to the preparation prepared in Formulation Example 3, 50 mL of 10 kg of wheat dry seeds was applied and coated by a rotary seed treatment machine (Seed Dresser, manufactured by Hans-Ulrich Hege GmbH) to obtain treated seeds.

種子處理例9 Seed treatment example 9

將依照製劑例4所製作之製劑5份、色料BPD6135(Sun Chemical公司製造)5份、水35份混合,以相對於向日葵種子10kg為70mL,經過旋轉式種子處理機(Seed Dresser,Hans-Ulrich Hege GmbH公司製造)塗布處理,而得到處理之種子。 5 parts of the preparation prepared in accordance with Formulation Example 4, 5 parts of coloring material BPD6135 (manufactured by Sun Chemical Co., Ltd.), and 35 parts of water were mixed, and 70 mL of 10 kg with respect to sunflower seeds was passed through a rotary seed treatment machine (Seed Dresser, Hans- The coating treatment was carried out by Ulrich Hege GmbH, and the treated seeds were obtained.

種子處理例10 Seed treatment example 10

係將依照製劑例5所製作之製劑,以相對於棉花乾燥 種子10kg為40g,進行粉衣處理,而得到處理之種子。 It will be dried in accordance with the preparation prepared in Preparation Example 5 in relation to cotton. The seed 10 kg was 40 g, and the powder coating treatment was carried out to obtain the treated seed.

試驗例1 Test example 1

將噻唑菌胺之二甲基亞碸(以下,以DMSO表示。)溶液及氟比來之DMSO溶液以成為預定濃度之方式混合而成的試驗用藥液30mL在栽培於直徑5.5cm缽中之蕃茄苗上進行噴霧處理。次日,再於苗上接種Phytophthora infestans(蕃茄疫病病菌)之孢子懸浮液,於20℃下、濕度100%下栽培蕃茄24小時,其次再於20℃下栽培5日,然後,測定發病面積,求出發病面積率。 30 mL of a test drug solution obtained by mixing a solution of thiazolamide dimethylammonium (hereinafter referred to as DMSO) and a DMSO solution having a fluorine ratio at a predetermined concentration in a tomato cultivated in a diameter of 5.5 cm Spray treatment on the seedlings. On the next day, the seedlings were inoculated with a spore suspension of Phytophthora infestans ( tobacco plague ), and the tomatoes were cultivated at 20 ° C and humidity of 100% for 24 hours, and then at 20 ° C for 5 days, and then the area was determined. The incidence area ratio was determined.

為進行比較,再調配含預定濃度的噻唑菌胺之DMSO溶液、及含預定濃度的氟比來之DMSO溶液,各別進行同樣之試驗。 For comparison, a DMSO solution containing a predetermined concentration of ethaboxam and a DMSO solution containing a predetermined concentration of a fluorine ratio were further prepared, and the same test was carried out.

(以下,稱為處理區發病面積率。) (Hereinafter, it is called the treatment area incidence area rate.)

發病面積率=100×(發病蕃茄葉面積值/蕃茄葉面積值) Incidence area ratio = 100 × (incidence tomato leaf area value / tomato leaf area value)

然後以水30mL取代試驗用藥30mL進行與上述相同之操作,求出發病面積率(以下,稱為無處理區發病面積率。)。 Then, 30 mL of water was used instead of 30 mL of the test drug, and the same operation as described above was carried out to obtain an area ratio of incidence (hereinafter referred to as a disease-free area ratio of no treatment area).

由處理區發病面積率及無處理區發病面積率,以下式計算防除力價。 From the incidence area of the treatment area and the area ratio of the treatment area, the control price is calculated by the following formula.

防除力價(%)=100×(A-B)/A Control price (%) = 100 × (A-B) / A

A:無處理區發病面積率 A: area of disease-free area

B:處理區發病面積率 B: incidence area of treatment area

其結果如表1所示。 The results are shown in Table 1.

試驗例2 Test example 2

以噻唑菌胺之丙酮溶液與氟比來之丙酮溶液混合,調配成含預定濃度之噻唑菌胺及氟比來的丙酮溶液。將該丙酮溶液附著在黃瓜(相模半白種)之種子表面後,靜置一夜。然後於塑膠缽中裝入砂壤土,播種該種子,並以混合已培養立枯病菌(Pythium ultimum)之麥糠培養基的砂壤土加以覆土。經過灌溉之後於25℃下成長7日,再調查其防除效果。 The acetone solution of ethaboxam is mixed with the acetone solution of the fluorine ratio to prepare an acetone solution containing a predetermined concentration of ethaboxam and a fluorine ratio. The acetone solution was attached to the surface of the seed of cucumber (phase mold semi-white) and allowed to stand overnight. Then, the loam was placed in the plastic crucible, the seed was sown, and the soil was covered with the sandy loam soil mixed with the wheat mash culture medium of Pythium ultimum . After irrigation, it was grown at 25 ° C for 7 days, and the control effect was investigated.

為進行比較,另調配含預定濃度噻唑菌胺之丙酮溶液、及含預定濃度氟比來之丙酮溶液,各別進行同樣之試驗。 For comparison, an acetone solution containing a predetermined concentration of ethaboxam and an acetone solution containing a predetermined concentration of fluorine were additionally prepared, and the same test was carried out.

(以下,稱為處理區植物發病率。) (Hereinafter, it is called the plant area incidence rate in the treatment area.)

同時,為計算防除力價,再合併調查無藥劑處理下之發病率(以下,稱為無處理區植物發病率。)。 At the same time, in order to calculate the control price, the incidence rate under the no-agent treatment (hereinafter referred to as the untreated area plant incidence rate) was investigated.

由式1計算處理區、及無處理區之發病率,再根據該發病率,以式2計算防除力價。其結果如表2所示。 The incidence rate of the treatment zone and the non-treatment zone is calculated by the formula 1, and the control price is calculated by the formula 2 according to the incidence rate. The results are shown in Table 2.

「式1」發病率=(未發芽種子數及發病苗數)×100/(總播種數) Incidence rate of "Formula 1" = (number of ungerminated seeds and number of seedlings) × 100 / (total number of seeds)

「式2」防除力價=100×(C-D)/C "Formula 2" control price = 100 × (C-D) / C

C:無處理區植物發病率 C: Untreated area plant incidence

D:處理區植物發病率 D: Plant incidence rate in the treatment area

產業上利用之可能性 Industrial use possibility

以本發明之組成物,可以防除植物病害。 With the composition of the present invention, plant diseases can be prevented.

Claims (6)

一種植物病害防除用組成物,其係含噻唑菌胺及氟比來。 A plant disease control composition comprising thiastrobin and a fluorine ratio. 如申請專利範圍第1項中記載之植物病害防除用組成物,其中噻唑菌胺與氟比來之重量比為1:0.01至1:50。 The plant disease controlling composition according to the first aspect of the invention, wherein the weight ratio of the ethaboxam to the fluorine is 1:0.01 to 1:50. 一種種子處理劑,其係含噻唑菌胺及氟比來。 A seed treatment agent comprising ethaboxam and a fluorine ratio. 一種植物種子,其係附著有效量之噻唑菌胺及氟比來。 A plant seed that is attached to an effective amount of ethaboxam and a fluorine ratio. 一種植物病害的防除方法,其特徵係以有效量之噻唑菌胺及氟比來,施用於植物或栽培植物之土壤。 A method for controlling plant diseases, characterized by applying an effective amount of ethaboxam and a fluorine ratio to a soil of a plant or a cultivated plant. 一種噻唑菌胺與氟比來之組合之用途,係用以防除植物病害。 The use of a combination of ethaboxam and fluorine is used to control plant diseases.
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