TW201446665A - Method of separating a glass sheet from a continuous glass ribbon - Google Patents

Method of separating a glass sheet from a continuous glass ribbon Download PDF

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Publication number
TW201446665A
TW201446665A TW103117172A TW103117172A TW201446665A TW 201446665 A TW201446665 A TW 201446665A TW 103117172 A TW103117172 A TW 103117172A TW 103117172 A TW103117172 A TW 103117172A TW 201446665 A TW201446665 A TW 201446665A
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TW
Taiwan
Prior art keywords
glass ribbon
glass
edge portion
rollers
ribbon
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TW103117172A
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Chinese (zh)
Inventor
Liming Wang
Zhe-Ming Zheng
Naiyue Zhou
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Corning Inc
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Publication of TW201446665A publication Critical patent/TW201446665A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/02Re-forming glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • C03B17/065Forming profiled, patterned or corrugated sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00Severing cooled glass
    • C03B33/02Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
    • C03B33/0215Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor the ribbon being in a substantially vertical plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)

Abstract

A method of separating a glass sheet from a continuous glass ribbon wherein counter rotating wheels comprise teeth such that a tooth on one wheel aligns with the tooth on the other wheel as the wheels rotate. The aligned teeth contact bead portions of the glass ribbon and pinch the ribbon between the aligned teeth to form indents. The pinching reduces a thickness of the bead, thereby weakening the bead and facilitating crack propagation across the bead after the bead cools to an elastic solid.

Description

由連續玻璃帶分離玻璃片的方法 Method for separating glass sheets from continuous glass ribbon 【交互參照之相關申請案】[Reciprocal Reference Related Applications]

本申請案根據專利法主張於2013年5月16日提出申請之美國專利臨時申請案第61/824,169號的權益,本文依賴該臨時申請案之內容且該臨時申請案全文以引用之方式併入本文中。 The present application is based on the benefit of the U.S. Patent Provisional Application Serial No. 61/824,169, filed on May 16, 2013, which is hereby incorporated herein in In this article.

本發明大體上關於由連續玻璃帶分離玻璃片的方法,且特別關於藉由弱化玻璃帶的珠體區(bead region),來降低使裂痕擴展橫過玻璃帶的全寬度所需之能量的方法。 The present invention generally relates to a method of separating a glass sheet from a continuous glass ribbon, and more particularly to a method for reducing the energy required to extend a crack across a full width of a glass ribbon by weakening the bead region of the glass ribbon. .

通常,由熔融製程形成的玻璃片在熔融抽拉機(fusion draw machine,FDM)中藉由機械刻劃及隨後的折彎分離而自玻璃帶分離。玻璃帶通常具有外形,或換句話說,因為玻璃內部的殘留應力及熱應力之故,玻璃帶通常在水平及垂直方向上皆呈現超出平面的弓形。玻璃帶的外形也與沿著玻璃帶的側向邊緣設置之增厚部分(珠體)的存在有關,增厚部分遠較玻璃帶的中央部分更厚,並產生顯著的熱梯度及應力梯度橫過玻璃。 Typically, the glass sheets formed by the melt process are separated from the glass ribbon by mechanical scoring and subsequent bend separation in a fusion draw machine (FDM). The glass ribbon usually has a shape, or in other words, because of the residual stress and thermal stress inside the glass, the glass ribbon generally exhibits an arcuate shape beyond the plane in both the horizontal and vertical directions. The shape of the glass ribbon is also related to the presence of thickened portions (beads) placed along the lateral edges of the glass ribbon. The thickened portions are much thicker than the central portion of the glass ribbon and produce significant thermal gradients and stress gradients. Through the glass.

當玻璃帶被做得更薄,珠體的厚度對玻璃帶的中央區域的厚度之比例會變得更大。此外,隨著增加玻璃片尺寸及/或減少玻璃厚度,玻璃帶剛性會降低,這通常會造成自玻璃帶切下之玻璃片具有更大的弓形。較大的珠體-對-中央厚度比例及較小的玻璃帶剛性的結合效應可對控制玻璃帶移動及維持刻劃及分離製程期間的玻璃帶穩定性帶來顯著的挑戰。因抽拉穩定性降低之故,成形製程視窗(forming process window)及抽拉區域底部處的製程視窗二者皆變得狹窄,且產生較高的製程干擾(process upset)頻率。由於刻劃及分離製程在抽拉中造成的玻璃帶移動不僅會影響玻璃片切除製程本身,還會擴展到玻璃成形製程且終究會影響最終玻璃品質,因此狹窄的製程視窗成為嚴重的問題。 When the glass ribbon is made thinner, the ratio of the thickness of the beads to the thickness of the central portion of the glass ribbon becomes larger. In addition, as the size of the glass sheet is increased and/or the thickness of the glass is reduced, the rigidity of the glass ribbon is reduced, which typically results in a larger arcuate shape of the glass sheet cut from the glass ribbon. The combined effect of the larger bead-to-center thickness ratio and the smaller glass ribbon stiffness can present significant challenges in controlling glass ribbon movement and maintaining glass ribbon stability during the scoring and separation process. Due to the reduced pull stability, both the forming process window and the process window at the bottom of the drawing area become narrow and produce high process upset frequencies. The movement of the glass ribbon caused by the scoring and separating process not only affects the glass sheet cutting process itself, but also extends to the glass forming process and ultimately affects the final glass quality, so the narrow process window becomes a serious problem.

熔融成形製程的另一個挑戰在於,因成形本體的某些部分的老化及珠體成形區中之流體及熱控制困難之故,而形成的中空珠體(珠體內之熔融線中的空氣間隙)。一旦形成中空珠體,刻劃及分離製程視窗將變得甚至更狹窄,且可能在玻璃片分離期間發生無法控制的裂痕。 Another challenge in the melt forming process is the formation of hollow beads (air gaps in the molten wire in the bead) due to aging of certain parts of the shaped body and difficulty in fluid and thermal control in the bead forming zone. . Once the hollow bead is formed, the scoring and separation process window will become even narrower and uncontrollable cracks may occur during the separation of the glass sheets.

傳統的機械切割法包含:刻劃珠體之間的玻璃帶,接著藉由如機械性彎折來分離。因為珠體處的厚度突然增加,所以橫過珠體的刻劃非常困難且不穩定。現今切割製程的主要缺點在於增厚且無法刻劃的珠體透過結構剛性及最小的缺陷表面而對折彎分離製程具有顯著阻力。結果,因分離裂痕擴展穿過珠體失敗之故,珠體處的裂痕擴展可導致狗耳或垂直裂痕。標的玻璃厚度變得更薄,使得這樣的情況變得 更糟。 Conventional mechanical cutting involves: scribing the glass ribbon between the beads and then separating them by, for example, mechanical bending. Because the thickness at the bead suddenly increases, the scoring across the bead is very difficult and unstable. The main disadvantage of today's cutting processes is that the thickened and unmarkable beads have significant resistance to the bending separation process through structural rigidity and minimal defect surfaces. As a result, crack propagation at the beads can result in dog ears or vertical cracks due to failure of the separation crack to propagate through the beads. The target glass thickness becomes thinner, making this situation become Worse.

因此,期望導入小的彎折角度或較低的能量來分離玻璃片,因為這樣可導入較小的玻璃片移動,並對抽拉穩定性造成較少影響。 Therefore, it is desirable to introduce a small bend angle or lower energy to separate the glass sheets, as this allows for the introduction of smaller glass sheet movements with less impact on the pull stability.

因珠體厚度對玻璃帶厚度的比例及玻璃片外形之故,在抽拉底部處的玻璃分離需要明顯較多的能量以穿過珠體將玻璃分離。在某些實施例中,玻璃帶分離刻劃僅發生於玻璃帶的優質區(quality region)中,玻璃帶的優質區在側向上介於珠體之間。這在較薄的玻璃帶上變得更常見。因為機械式刻劃滾輪會跳過粗糙的珠體表面,要在珠體中達到「良好的(good)」開口裂痕(vent crack)是不可能的。由於無法在珠體表面上導入裂紋,需要額外的能量來彎折玻璃以進行分離,導致對上述的熔融成形製程造成更多干擾。若有中空珠體存在,則在分離期間將更可能發生破裂(crack out)。 Due to the ratio of the thickness of the beads to the thickness of the glass ribbon and the shape of the glass sheet, the separation of the glass at the bottom of the drawing requires significantly more energy to separate the glass through the beads. In some embodiments, the glass ribbon separation scoring occurs only in the quality region of the glass ribbon, with the high quality regions of the glass ribbon being laterally interposed between the beads. This becomes more common on thinner glass ribbons. Since the mechanical scoring wheel skips the rough bead surface, it is impossible to achieve a "good" vent crack in the bead. Since cracks cannot be introduced on the surface of the beads, additional energy is required to bend the glass for separation, resulting in more interference with the melt forming process described above. If a hollow bead is present, crack out will be more likely to occur during the separation.

本揭露內容描述藉由以下步驟以在增厚之玻璃帶的珠體存在的情況下,降低能量並進行可靠的分離製程之方法:在熔融抽拉機內部,且在珠體仍具有黏滯性(如,具有黏彈性)的高度處,以機械方式在兩側珠體導入對稱的內縮處。內縮化珠體可減少局部彎折剛性並降低在抽拉底部處(玻璃帶在此處於彈性固態)進行片分離所需的能量,進而透過應力集中促進裂痕擴展、減少玻璃片移動,並增加成形穩定性。 The present disclosure describes a method for reducing energy and performing a reliable separation process in the presence of a bead of a thickened glass ribbon by the following steps: inside the melt drawing machine, and still having viscosity in the bead At a height (e.g., viscoelastic), a symmetrical indentation is introduced mechanically on both sides of the bead. The shrinking beads reduce the local bending rigidity and reduce the energy required for sheet separation at the bottom of the drawing (where the glass ribbon is in the elastic solid state), thereby promoting crack propagation through stress concentration, reducing glass sheet movement, and increasing Forming stability.

此外,內縮化珠體可作為刻劃滾輪在沿著抽拉相交方向(cross-draw direction)上的導引,及/或因需要低得多的彎 折能量而作為刻劃線裂痕擴展進入珠體區域的導引。因此,可因為能進行低彎折(低能量)分離來減少玻璃帶移動並增加抽拉穩定性,並顯著地減少或消除珠體分離缺陷,如狗耳(dog ear)(角度轉變的擴展)或在分離期間產生之裂痕的向上垂直擴展。 In addition, the indented beads can be used as a scoring wheel for guidance along the cross-draw direction and/or because a much lower bend is required Folding energy as a guide to the scribe line crack extension into the bead area. Therefore, it is possible to reduce the movement of the glass ribbon and increase the stability of the drawing because of the low bending (low energy) separation, and to significantly reduce or eliminate the defects of the separation of the beads, such as the dog ear (expansion of the angle transition) Or upward vertical expansion of cracks generated during separation.

在玻璃片的珠體區域中之一連串的內縮處可弱化珠體,且因此減少彎折角度並降低後續玻璃片分離所需的能量。可於成形區域中機械式地以預定頻率引發內縮處,致使內縮處對準用於各玻璃片分璃循環之後續刻劃線。內縮處沿著玻璃帶的側向邊緣對稱。理想上,內縮的玻璃厚度將與優質區(quality region)玻璃厚度具有相同的玻璃厚度。 A series of indentations in the bead region of the glass sheet can weaken the beads and thus reduce the bending angle and reduce the energy required for subsequent glass sheet separation. The indentation can be initiated mechanically at a predetermined frequency in the forming region such that the indentation is aligned with the subsequent score line for each glass sheet glass cycle. The indentation is symmetrical along the lateral edges of the glass ribbon. Ideally, the indented glass thickness will have the same glass thickness as the quality region glass thickness.

因此,在一個實施例中,茲揭露一種由連續玻璃帶分離玻璃片的方法,該方法包含下列步驟:於向下抽拉製程中形成連續玻璃帶;在玻璃帶處於黏滯態(viscous state)的同時使玻璃帶接合一對相對滾輪,該對相對滾輪中的各滾輪包含從該滾輪凸出之齒部,其中相對滾輪為同步,致使在相對滾輪轉動期間,該對滾輪中的一個滾輪的齒部對準相對滾輪的齒部,以在玻璃帶的邊緣的兩側中產生相對內縮處;在玻璃帶冷卻至彈性態之後,刻劃玻璃帶,以形成刻劃線,使得刻劃線對準相對內縮處;以及施加拉應力橫過刻劃線,以透過彎折自玻璃帶分離玻璃片。可藉由使玻璃帶沿著玻璃帶的寬度接合刻劃刀片來形成刻劃線。該對滾輪中的各滾輪可包含單一齒部,或複數個齒部。在某些實施例中,介於相對內縮處之間的玻璃帶厚度實質上相同於玻璃帶的中央部分內之 玻璃帶厚度。 Thus, in one embodiment, a method of separating a glass sheet from a continuous glass ribbon is disclosed, the method comprising the steps of: forming a continuous glass ribbon in a downward draw process; in a viscous state of the glass ribbon Simultaneously engaging the glass ribbon with a pair of opposing rollers, each of the pair of opposing rollers including a tooth portion projecting from the roller, wherein the opposing rollers are synchronized such that one of the pair of rollers is rotated during rotation of the opposite roller The teeth are aligned with respect to the teeth of the roller to create a relative indentation in both sides of the edge of the glass ribbon; after the glass ribbon is cooled to the elastic state, the glass ribbon is scored to form a score line, so that the score line Aligning the relative indentations; and applying a tensile stress across the score line to separate the glass sheets from the glass ribbon by bending. The score line can be formed by engaging the glass ribbon along the width of the glass ribbon to score the blade. Each of the pair of rollers may include a single tooth, or a plurality of teeth. In certain embodiments, the thickness of the glass ribbon between the opposing indentations is substantially the same as in the central portion of the glass ribbon. Glass strip thickness.

本發明之額外特徵與優點將於下文的詳細描述中提出,並且在某種程度上熟悉本領域之技術人員從該敘述中將很容易理解該些特徵與優點,或藉由實施在此描述的本發明(包括隨後的詳細描述、申請專利範圍與附圖),而能夠認識該些特徵與優點。 The additional features and advantages of the present invention are set forth in the Detailed Description of the Drawings. The present invention (including the following detailed description, claims, and claims)

應瞭解,前文的一般說明與下文的詳細描述呈現本案揭露內容之實施例,且申請人希望前文的一般說明與下文的詳細描述提供概述或框架以使世人理解所述實施例之本質與特質。在此納入附圖以提供對本案揭露內容的進一步之理解,且該等附圖被納入本說明書並且構成本說明書之一部分。該等圖式繪示了本案揭露內容的各種實施例,並連同說明書以解釋該等實施例之原理與操作。 It is to be understood that the foregoing general description of the embodiments of the invention, The drawings are included to provide a further understanding of the present disclosure, and are incorporated in the specification and constitute a part of the specification. The drawings illustrate various embodiments of the disclosed subject matter, and together with the description of the embodiments.

10‧‧‧熔融玻璃抽拉機 10‧‧‧Melt glass drawing machine

12‧‧‧熔化的玻璃 12‧‧‧fused glass

14‧‧‧成形本體 14‧‧‧Formed body

16‧‧‧入口 16‧‧‧ Entrance

18‧‧‧槽體 18‧‧‧

20‧‧‧成形表面 20‧‧‧Formed surface

22‧‧‧根部 22‧‧‧ Root

24‧‧‧玻璃帶 24‧‧‧glass ribbon

26‧‧‧拉引輥 26‧‧‧ Pulling roller

28‧‧‧珠體 28‧‧‧ beads

30‧‧‧中央部分 30‧‧‧Central Part

32‧‧‧刻痕 32‧‧‧ Scotch

33‧‧‧抽拉方向 33‧‧‧ Pulling direction

34‧‧‧滾輪 34‧‧‧Roller

36‧‧‧齒部 36‧‧‧ teeth

38‧‧‧虛線 38‧‧‧ dotted line

40‧‧‧內縮處 40‧‧‧ contraction

42‧‧‧徑向軸 42‧‧‧ radial axis

44‧‧‧轉動軸 44‧‧‧Rotary axis

46‧‧‧刻劃裝置 46‧‧‧ scoring device

48‧‧‧機器人 48‧‧‧ Robot

49‧‧‧縱向中心線 49‧‧‧ longitudinal centerline

第1圖為根據本揭露內容用以抽拉連續玻璃帶之範例設備的正視圖;第2圖為第1圖之用以抽拉連續玻璃帶之範例設備的剖面視圖(從該範例設備的一端觀之);第3圖為玻璃帶的剖面視圖,繪示出珠體(bead);第4圖為被反向轉動滾輪夾捏之玻璃帶的珠體部分之剖面視圖,其中各反向轉動滾輪包括齒部,齒部在玻璃帶珠體中形成內縮處;第5A至5C圖繪示第4圖之反向轉動滾輪位置的時序,而反向轉動滾輪的齒部移動成對準,以夾捏玻璃帶珠體; 第6圖為玻璃帶之部分的正視圖,其中該玻璃帶正從成形本體下降,且其中內縮處形成的時間經過安排,使得內縮處的佈置與刻劃線的佈置重合;第7圖繪示具有超過一個齒部的滾輪;第8圖描繪在數種指定的彎折條件下,以玻璃帶中的垂直應力作為距離玻璃帶的縱向中心線之位置處的函數所建構之模型。 1 is a front elevational view of an exemplary apparatus for drawing a continuous glass ribbon in accordance with the present disclosure; and FIG. 2 is a cross-sectional view of the exemplary apparatus for drawing a continuous glass ribbon of FIG. 1 (from one end of the example device) Figure 3 is a cross-sectional view of the glass ribbon showing the bead; Figure 4 is a cross-sectional view of the bead portion of the glass ribbon pinched by the counter-rotating roller, with each reverse rotation The roller includes a tooth portion, and the tooth portion forms a retraction portion in the glass bead body; FIGS. 5A to 5C illustrate the timing of the reverse rotation roller position of FIG. 4, and the tooth portion of the reverse rotation roller moves to be aligned, To pinch the glass with beads; Figure 6 is a front elevational view of a portion of the glass ribbon, wherein the glass ribbon is being lowered from the shaped body, and wherein the time during which the indentation is formed is arranged such that the arrangement of the indentations coincides with the arrangement of the score lines; Figure 7 A roller having more than one tooth is illustrated; Figure 8 depicts a model constructed by a function of the vertical stress in the ribbon as a function of the distance from the longitudinal centerline of the ribbon under a number of specified bending conditions.

現在,請詳閱本案揭露內容之各實施例,該等實施例之一些實例繪示於附圖中。如可能,在所有圖式中使用相同的元件符號以指稱相同或類似部件。 Now, please refer to the various embodiments of the disclosure, and some examples of the embodiments are illustrated in the accompanying drawings. Wherever possible, the same reference numerals are used throughout the drawings to refer to the

第1及2圖繪示範例玻璃抽拉機,且特別是用於形成玻璃片的熔融玻璃抽拉機(fusion glass drawing machine,FDM)10。根據第1及2圖,熔化的玻璃12透過入口16提供至成形本體14。成形本體14包含槽體18,槽體18沿著成形本體14的上表面縱向地延伸。熔化的玻璃12溢流出槽體18,並以個別的熔化玻璃流的方式流過漸縮的成形表面20。接著,個別的熔化玻璃流沿著漸縮的成形表面會合之線,根部22,結合(熔融),以形成連續玻璃帶24。拉引輥26可自根部22抽拉玻璃帶24。 Figs. 1 and 2 depict an exemplary glass drawing machine, and in particular, a fusion glass drawing machine (FDM) 10 for forming a glass sheet. According to Figures 1 and 2, the molten glass 12 is supplied to the shaped body 14 through the inlet 16. The shaped body 14 includes a trough body 18 that extends longitudinally along the upper surface of the shaped body 14. The molten glass 12 overflows the trough 18 and flows through the tapered forming surface 20 in a separate flow of molten glass. Next, individual molten glass streams are joined along the line where the tapered forming surfaces meet, and the roots 22 are joined (melted) to form a continuous glass ribbon 24. The pull roller 26 can pull the glass ribbon 24 from the root portion 22.

第3圖繪示範例玻璃帶24的剖面視圖。抽拉力量及表面張力傾向於沿著玻璃帶的外側邊緣產生增厚部分,通常稱為珠體(bead)28。玻璃帶24的中央部分30在珠體之間延伸,且通常稱作優質區(quality region),因為中央部分是在移 除珠體之後在商業上可販售的玻璃帶部分。然而,在某些玻璃片製造操作中,玻璃片在移除珠體之前先由玻璃帶分離。因此,珠體對分離製程造成獨特的挑戰。 Figure 3 depicts a cross-sectional view of an exemplary glass ribbon 24. The pulling force and surface tension tend to create a thickened portion along the outer edge of the glass ribbon, commonly referred to as a bead 28. The central portion 30 of the glass ribbon 24 extends between the beads and is commonly referred to as the quality region because the central portion is moving A commercially available glass ribbon portion after the bead body. However, in some glass sheet manufacturing operations, the glass sheets are separated by a glass ribbon prior to removal of the beads. Therefore, the beads pose unique challenges to the separation process.

通常,在與寬度同向的方向上,於玻璃帶中形成刻痕32(參見第1圖)。可以機械手段形成刻痕,其中刻劃滾輪或其它刻劃元件與玻璃帶接觸並橫貫穿過玻璃帶的寬度。在其它實施例中,可用雷射形成刻痕。如本文所用,刻痕代表對玻璃帶造成機械性傷害的線,例如,刻痕代表對玻璃帶的機械性傷害線,例如至少部分延伸進入玻璃帶的厚度之開口裂痕。因此,刻痕也可稱作刻劃線。在許多例子中,增厚的珠體可防止所形成的刻痕橫過玻璃帶的整個寬度。因此,刻痕通常不延伸進入珠體。一旦刻痕形成,如橫過中央部分30,則通常可藉由彎折玻璃帶來產生橫過刻痕(即,正交於刻劃線)的拉應力。然而,較厚、未經刻劃的珠體需要較大的能量輸入玻璃帶來使裂痕擴展穿過玻璃帶的珠體。一旦裂痕擴展穿過珠體,過量的能量被釋放,並可形成形成擾動行進穿過玻璃帶,並干擾定型區域(setting zone)中的玻璃帶。定型區域是玻璃帶從黏滯性液體轉變成彈性固體的地方。這樣的擾動可產生凍結進入玻璃帶的應力,且可,舉例而言,影響自玻璃帶分離之玻璃片的外形。因此,增加裂痕可擴展穿過珠體的容易程度可減少後續自玻璃帶分離之玻璃片中的殘留應力。 Typically, a score 32 is formed in the glass ribbon in the same direction as the width (see Figure 1). The score can be formed mechanically, wherein the score roller or other scoring element contacts the glass ribbon and traverses across the width of the glass ribbon. In other embodiments, the laser can be used to form a score. As used herein, a score represents a line that causes mechanical damage to the glass ribbon, for example, the score represents a line of mechanical damage to the glass ribbon, such as an open crack that extends at least partially into the thickness of the glass ribbon. Therefore, the score can also be called a score line. In many instances, the thickened beads prevent the formed score from traversing the entire width of the glass ribbon. Therefore, the score usually does not extend into the bead. Once the score is formed, such as across the central portion 30, tensile stress across the score (i.e., orthogonal to the score line) can generally be created by bending the glass ribbon. However, thicker, ungrained beads require a larger energy input glass to cause the crack to extend through the beads of the glass ribbon. Once the crack propagates through the bead, excess energy is released and can form a disturbance that travels through the glass ribbon and interferes with the glass ribbon in the setting zone. The shaped area is where the glass ribbon transforms from a viscous liquid to an elastic solid. Such perturbations can create stresses that freeze into the glass ribbon and can, for example, affect the shape of the glass sheet separated from the glass ribbon. Therefore, increasing the ease with which cracks can expand through the beads reduces the residual stress in the subsequent glass sheets separated from the glass ribbon.

根據本文所揭露的實施例,在熔融抽拉機內以機械方式將對稱的內縮處導入玻璃帶的邊緣部分(如,珠體區域),以降低在抽拉底部處進行片分離所需的能量,進而透過應力 集中促進裂痕擴展、減少玻璃片移動,並增加成形穩定性。因此,一連串的內縮處被形成於玻璃帶的邊緣部分中,以弱化珠體,從而減少折彎角度並降低自玻璃帶分離玻璃片所需的能量。 According to embodiments disclosed herein, a symmetrical retraction is mechanically introduced into the edge portion of the glass ribbon (eg, the bead region) within the melt puller to reduce the need for sheet separation at the bottom of the draw. Energy, and then through stress Concentrate on promoting crack propagation, reducing glass sheet movement, and increasing form stability. Therefore, a series of indentations are formed in the edge portion of the glass ribbon to weaken the beads, thereby reducing the bending angle and reducing the energy required to separate the glass sheets from the glass ribbon.

第4圖描繪在抽拉方向33中下降之玻璃帶24的一個縱向邊緣的一部分。反向轉動的滾輪34之位置經安排而在玻璃帶的縱向邊緣處於相對的關係,使得一個滾輪經定位而鄰近邊緣的各側,其中各滾輪34包含凸出部,即,齒部36。滾輪可透過適當的連結(未繪示)耦接驅動驅動力(如,電動馬達或其它機械性驅動裝置)並同步,使得當滾輪34轉動時,各滾輪上的齒部36可對準並靠近相對滾輪上的相對齒部,如第4圖中的虛線38所表示。因此,當滾輪轉動使得各滾輪上的齒部接觸移動中的玻璃帶時,可在移動中的玻璃帶的表面上之珠體處形成相對內縮處40。換言之,對準的齒部在珠體處夾捏玻璃帶,從而減少齒部接觸玻璃處之珠體的厚度。 Figure 4 depicts a portion of one longitudinal edge of the glass ribbon 24 that is lowered in the pull direction 33. The positions of the counter-rotating rollers 34 are arranged in an opposing relationship at the longitudinal edges of the glass ribbon such that one roller is positioned adjacent each side of the edge, wherein each roller 34 includes a projection, i.e., a tooth portion 36. The roller can be coupled to a driving driving force (such as an electric motor or other mechanical driving device) through a suitable connection (not shown) and synchronized so that when the roller 34 rotates, the teeth 36 on each roller can be aligned and close. The opposing teeth on the roller are indicated by the dashed line 38 in Figure 4. Thus, as the rollers rotate such that the teeth on each roller contact the moving glass ribbon, a relative indentation 40 can be formed at the bead on the surface of the moving glass ribbon. In other words, the aligned teeth pinch the glass ribbon at the beads, thereby reducing the thickness of the beads at which the teeth contact the glass.

在移動的玻璃帶之相對邊緣處對稱地形成內縮處,意味著沿著移動的玻璃帶的一個邊緣形成之內縮處在水平方向上對準在該移動的玻璃帶的相對邊緣上形成之內縮處。 The indentation is symmetrically formed at the opposite edges of the moving glass ribbon, meaning that the indentations formed along one edge of the moving glass ribbon are aligned in the horizontal direction on the opposite edges of the moving glass ribbon. Retraction.

第5A至5C圖繪示當滾輪34在相反方向中轉動時一連串的滾輪34位置。就各滾輪而言,繪示出各滾輪上之相應齒部的徑向軸42,使得透過圖式的行進可顯示當對應的滾輪轉動時,各滾輪的徑向軸42如何轉動,使齒部更接近對準。各徑向軸42對分或實質上對分滾輪上的齒部,並通過滾輪的轉動軸44。 Figures 5A through 5C illustrate the position of a series of rollers 34 as the roller 34 rotates in the opposite direction. For each roller, the radial axis 42 of the respective tooth on each roller is depicted such that travel through the pattern can show how the radial axis 42 of each roller rotates as the corresponding roller rotates, causing the tooth to rotate Closer to alignment. Each radial shaft 42 bisects or substantially bisects the teeth on the roller and passes through the axis of rotation 44 of the roller.

此外,可選擇滾輪的直徑,使得在各次片分離循環期間,由相關刻劃裝備在移動的玻璃帶中所形成之刻劃線與在移動的玻璃帶中所形成之相對內縮處重合。應注意的是,內縮處的空間頻率(spatial frequency)不需要與刻劃裝備形成之刻劃線的空間頻率重合。如本文所使用,在內縮處的觀點中之空間頻率指的是(在玻璃帶的邊緣部分之一側上)每單位長度之內縮處數量,例如每公尺2個內縮處。刻劃線之空間頻率指的是以刻劃線的存在作為刻劃線之間的距離之函數,例如,沿著玻璃帶的長度每4公尺所產生的刻劃線。應理解到,由於可在產生第二刻劃線之前在第一刻劃線處進行分離,因此兩條刻劃線可能不會在相同時間形成(存在)於玻璃帶中。相對內縮處的空間頻率可大於刻劃線的空間頻率,但相對內縮處的空間頻率致使相對內縮處形成在各刻劃線處。或者,這可被視為當玻璃片在各刻劃線處自玻璃帶分離的同時,不需要在各內縮處形成刻劃線。就自玻璃帶切下而長度為L的玻璃片(即,沿著玻璃帶每增量L在移動的玻璃帶上產生刻劃線)而言,假設各滾輪具有單一齒部,應選擇滾輪34的直徑D使得L為pi的m倍(m為正整數)乘上直徑D。換言之,應選擇滾輪34的直徑D,使得L/mπ=D。若m大於1,則將會形成比刻劃線更多的內縮處。此假設只有在玻璃片待分離處才會刻劃玻璃帶。 In addition, the diameter of the rollers can be selected such that during each of the sheet separation cycles, the score lines formed by the associated scoring equipment in the moving glass ribbon coincide with the relative indentations formed in the moving glass ribbon. It should be noted that the spatial frequency at the indentation does not need to coincide with the spatial frequency of the scribe line formed by the scoring equipment. As used herein, the spatial frequency in the view of the indentation refers to the number of indentations per unit length (on one side of the edge portion of the glass ribbon), for example, 2 indentations per meter. The spatial frequency of the score line refers to the presence of the score line as a function of the distance between the score lines, for example, a score line produced every 4 meters along the length of the glass ribbon. It should be understood that since the separation may be performed at the first scribe line before the second scribe line is created, the two scribe lines may not be formed (present) in the glass ribbon at the same time. The spatial frequency at the relative indentation may be greater than the spatial frequency of the score line, but the spatial frequency relative to the indentation causes the relative indentation to be formed at each score line. Alternatively, this can be considered as the scribe line does not need to be formed at each indentation while the glass sheet is separated from the glass ribbon at each score line. In the case of a glass sheet having a length L cut from the glass ribbon (i.e., a score line is created on the moving glass ribbon along the glass ribbon increments L), assuming that each roller has a single tooth portion, the roller 34 should be selected. The diameter D is such that L is m times pi (m is a positive integer) multiplied by the diameter D. In other words, the diameter D of the roller 34 should be selected such that L/mπ = D. If m is greater than 1, then more indentations will be formed than the score line. This assumption only marks the glass ribbon where the glass piece is to be separated.

第6圖繪示自成形本體14(未繪示於圖中)下降之玻璃帶的一部分。當玻璃帶下降,可沿著玻璃帶的長度往下周期性地在珠體處形成內縮處40。刻劃裝置46行進於玻璃帶的 至少部分寬度,在介於珠體28之間的玻璃帶中形成刻痕(刻劃線32)。刻劃的時間經過機械式或電子式安排,使得各刻劃線對應內縮處40的一位置。在刻劃裝置46下方,機器人48接合玻璃帶的自由端,並施加彎折至玻璃帶。彎折可形成拉應力橫過機器人上方的刻劃線,從而自玻璃帶分離玻璃片。如先前所註記,由滾輪34所進行之夾捏與由刻劃裝置46所進行之刻劃之間的時間點可使得在與夾捏重合的位置處進行刻劃,致使刻劃線32對準內縮處40。 Figure 6 illustrates a portion of the glass ribbon that has been lowered from the shaped body 14 (not shown). As the ribbon is lowered, the indentation 40 can be periodically formed at the bead along the length of the ribbon. The scoring device 46 travels on the glass ribbon At least a portion of the width, a score (scribe line 32) is formed in the glass ribbon between the beads 28. The scoring time is mechanically or electronically arranged such that each score line corresponds to a position of the indentation 40. Below the scoring device 46, the robot 48 engages the free end of the glass ribbon and applies a bend to the glass ribbon. The bending can form a tensile stress across the scribe line above the robot to separate the glass sheets from the glass ribbon. As noted earlier, the point in time between the pinch by the roller 34 and the scribe by the scoring device 46 allows the scribe to be scored at a position coincident with the pinch, causing the score line 32 to be aligned The indentation is 40.

從前面描述應可清楚瞭解到,各滾輪23可具有超過一個齒部。舉例而言,第7圖繪示滾輪34,滾輪34具有以180度分隔定位的兩個齒部。在這個例子中,需藉由計入各滾輪34上之齒部的數量來修改前述公式。 As will be apparent from the foregoing description, each of the rollers 23 can have more than one tooth. For example, Figure 7 illustrates a roller 34 having two teeth positioned in a 180 degree separation. In this example, the foregoing formula is modified by counting the number of teeth on each of the rollers 34.

可發展有限元素分析(Finite Element Analysis,FEA)模型來研究上文所述之珠體凹口概念(bead notch concept)。第8圖顯示,就由Corning Eagle XGTM玻璃製作並具有內縮化珠體的範例玻璃帶(其中玻璃帶在內縮處以約6度(曲線50)及12度(曲線52)彎折),及在6度彎折(曲線54)及12度彎折(曲線56)處具有非-內縮化珠體的相同玻璃帶而言,以垂直方向應力(以每平方英吋的磅數計)作為橫過玻璃帶寬度的位置(以毫米(mm)計,從縱向中心線49測量)之函數的模型建構結果。假設範例玻璃帶在中央部分的厚度為0.3mm,且最大珠體厚度為約0.65mm。就內縮化珠體而言,可在珠體區域產生較高的應力,象徵珠體較易破裂或能以較低能量分離珠體。 A Finite Element Analysis (FEA) model can be developed to study the bead notch concept described above. Figure 8 shows on a Corning Eagle XG TM made of glass and having a retracted examples of glass beads with (where the ribbon is bent in the retracted impose about 6 degrees (curve 50) and 12 degrees (curve 52)), And in the same glass ribbon with non-retracted bead at 6 degree bend (curve 54) and 12 degree bend (curve 56), stress in the vertical direction (in pounds per square inch) The result of the model construction as a function of the position across the width of the glass ribbon (measured in millimeters (mm), measured from the longitudinal centerline 49). It is assumed that the example glass ribbon has a thickness of 0.3 mm in the central portion and a maximum bead thickness of about 0.65 mm. In the case of intrinsicized beads, higher stresses can be created in the bead region, indicating that the beads are more susceptible to breakage or can separate the beads at lower energies.

對於發明所屬技術領域中具有通常知識者而言,將 明瞭可在不悖離本揭露內容的精神與範疇下,對本文所揭露之實施例製作各種修飾形式與變化形式。因此,在這樣的修飾形式與變化形式在隨附申請專利範圍及其等效例的範疇內的情形下,本揭露內容欲涵蓋這樣的修飾形式與變化形式。 For those of ordinary skill in the art to which the invention pertains, It is apparent that various modifications and variations can be made to the embodiments disclosed herein without departing from the spirit and scope of the disclosure. Therefore, the present disclosure is intended to cover such modifications and variations as the scope of the modifications and the scope of the invention.

24‧‧‧玻璃帶 24‧‧‧glass ribbon

33‧‧‧抽拉方向 33‧‧‧ Pulling direction

34‧‧‧滾輪 34‧‧‧Roller

36‧‧‧齒部 36‧‧‧ teeth

38‧‧‧虛線 38‧‧‧ dotted line

40‧‧‧內縮處 40‧‧‧ contraction

44‧‧‧轉動軸 44‧‧‧Rotary axis

Claims (9)

一種由一連續玻璃帶分離一玻璃片的方法,包含下列步驟:於一向下抽拉製程中形成一連續玻璃帶,該玻璃帶包含一黏滯部分;使該黏滯部分的一第一邊緣部分接合第一對相對滾輪,該第一對相對滾輪中的各滾輪包含從該滾輪延伸之一凸出部,其中該第一對相對滾輪為同步,致使在該等滾輪轉動期間,該第一對滾輪中的一個滾輪的該凸出部對準該相對滾輪的該凸出部,以在該玻璃帶的該第一邊緣部分中產生相對內縮處;在該玻璃帶冷卻至一彈性態之後,刻劃該玻璃帶,以橫過該玻璃帶之一寬度形成一刻劃線,該刻劃線對準該第一邊緣部分中之該等相對內縮處;以及施加一拉應力橫過該刻劃線,以自該玻璃帶分離一玻璃片。 A method for separating a glass sheet from a continuous glass ribbon, comprising the steps of: forming a continuous glass ribbon in a downward drawing process, the glass ribbon comprising a viscous portion; and a first edge portion of the viscous portion Engaging a first pair of opposing rollers, each of the first pair of opposing rollers including a projection extending from the roller, wherein the first pair of opposing rollers are synchronized such that during the rotation of the rollers, the first pair The projection of one of the rollers is aligned with the projection of the opposing roller to create a relative indentation in the first edge portion of the glass ribbon; after the ribbon is cooled to an elastic state, Marking the glass ribbon to form a score line across a width of one of the glass ribbons, the score line being aligned with the relative indentations in the first edge portion; and applying a tensile stress across the score a wire to separate a piece of glass from the glass ribbon. 如請求項1所述之方法,其中藉由使該玻璃帶接合一刻劃元件來形成該刻劃線。 The method of claim 1, wherein the score line is formed by joining the glass ribbon to a scoring element. 如請求項1所述之方法,其中該對相對滾輪中的各滾輪僅包含一單一凸出部。 The method of claim 1, wherein each of the pair of opposing rollers comprises only a single projection. 如請求項1所述之方法,其中該對相對滾輪中的各滾輪包含複數個凸出部。 The method of claim 1, wherein each of the pair of opposing rollers comprises a plurality of projections. 如請求項1所述之方法,其中介於相對內縮處之間之該玻璃帶的厚度實質上相同於該玻璃帶的一中央部分內之該玻璃帶的厚度。 The method of claim 1 wherein the thickness of the glass ribbon between the relative indentations is substantially the same as the thickness of the glass ribbon in a central portion of the glass ribbon. 如請求項1所述之方法,其中該玻璃帶包含一第二邊緣部分位於該黏滯部分內並相對於該第一邊緣部分,該方法進一步包含下列步驟:使該第二邊緣部分接合第二對相對滾輪,該第二對相對滾輪中的各滾輪包含從該滾輪延伸之一凸出部,其中該第二對相對滾輪為同步,致使在該等滾輪轉動期間,該第二對滾輪中的一個滾輪的該凸出部對準該第二對滾輪之該相對滾輪的該凸出部,以在該玻璃帶的該第二邊緣部分中產生相對內縮處。 The method of claim 1, wherein the glass ribbon comprises a second edge portion located within the viscous portion and relative to the first edge portion, the method further comprising the step of: engaging the second edge portion with the second For each of the opposing rollers, each of the second pair of opposing rollers includes a projection extending from the roller, wherein the second pair of opposing rollers are synchronized such that during rotation of the rollers, the second pair of rollers The projection of a roller is aligned with the projection of the opposing roller of the second pair of rollers to create a relative indentation in the second edge portion of the glass ribbon. 如請求項6所述之方法,其中該刻劃線對準該第一邊緣部分之該等相對內縮處及該第二邊緣部分之該等相對內縮處。 The method of claim 6, wherein the scribe line is aligned with the relative indentations of the first edge portion and the relative indentations of the second edge portion. 如請求項7所述之方法,其中該刻劃線不延伸至該第一邊緣部分之該等相對內縮處及該第二邊緣部分之該等相對內縮處。 The method of claim 7, wherein the score line does not extend to the relative indentations of the first edge portion and the relative indentations of the second edge portion. 如請求項6所述之方法,其中介於該第二邊緣部分之該等相對內縮處之間之該玻璃帶的厚度實質上相同於該玻璃帶的一中央部分內之該玻璃帶的厚度。 The method of claim 6 wherein the thickness of the glass ribbon between the opposing indentations of the second edge portion is substantially the same as the thickness of the glass ribbon in a central portion of the glass ribbon. .
TW103117172A 2013-05-16 2014-05-15 Method of separating a glass sheet from a continuous glass ribbon TW201446665A (en)

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