TW201431696A - Rubber fabric for floating on water and manufacturing method thereof - Google Patents

Rubber fabric for floating on water and manufacturing method thereof Download PDF

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TW201431696A
TW201431696A TW102104426A TW102104426A TW201431696A TW 201431696 A TW201431696 A TW 201431696A TW 102104426 A TW102104426 A TW 102104426A TW 102104426 A TW102104426 A TW 102104426A TW 201431696 A TW201431696 A TW 201431696A
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rubber
weight
floating
cloth
parts
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TW102104426A
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TWI510371B (en
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Jun-Wen Peng
zheng-ji Xu
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Formosan Rubber Group Inc
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Abstract

This invention discloses a rubber fabric for floating on water and manufacturing method thereof. Firstly, rubber paste is coated to a top surface and bottom surface of a base fabric with specific weight less than 1. Then, two rubber fabrics, which contains foaming agent, main rubber, diphenylamine, naphthenic oil, tackifying agent, carbon black, and sulfur and has a specific weigh less than 1, are respectively adhered to the top surface and the bottom surface through the rubber paste. Since the specific weights of the base fabric and rubber fabric of this invention are all less than 1 collaborated with the tiny holes generated in the rubber by the foaming agent, the overall rubber fabric can be floated on the water surface to be isolated from water and external contamination, which has excellent floating effect.

Description

水上漂浮膠布及其製作方法 Floating cloth on water and manufacturing method thereof

本發明係有關一種製作技術,特別是關於一種水上漂浮膠布及其製作方法。 The invention relates to a manufacturing technique, in particular to a floating plastic tape and a manufacturing method thereof.

遊艇係用於除了供水上休閒活動外,更是一個水上緊急救援或運輸的重要工具,例如船難、水災等。特別是在緊急救援時,例如船難時,漂流過程中遊艇將需承受相當劇烈的氣候日夜溫度變化與堅硬物體如礁岩的磨、刮,因此遊艇所使用之膠布必須具備相當程度的高度耐候、抗磨損與材料間的高接著力才能符合各種實際應用上的需求。 The yacht is used for recreational activities in addition to water supply. It is also an important tool for emergency rescue or transportation on the water, such as shipwrecks and floods. Especially in emergency rescue, such as when the ship is difficult, the yacht will have to withstand the violent weather and temperature changes during the rafting process and the hard objects such as reef grinding and scraping. Therefore, the tape used by the yacht must have a high degree of weather resistance. The anti-wear and high adhesion between materials can meet the needs of various practical applications.

但就目前市面上膠布的製作過程所製得的膠布,如聚氯乙烯(PVC)、聚胺脂(TPU)比重大部分大於一,且不耐久,或聚胺脂有水解的現象發生,使用橡膠材質的使用期限較其他材料耐用,故選用橡膠材質。然,橡膠種類眾多,搭配不同的補強填充劑、加工助劑,老防劑,促進劑等,會賦予橡膠有各種不同的特性。由於大部分的原料配方比重都大於一,所以選用的原材料,添加量及布的選擇變成一個重要關鍵。要能將橡膠皮漂在水上,橡膠本身及布的比重都要小於一,唯獨一種比重小於一,有可能還是會沉於水裡,除非其中一個比重與另一個差異大,才有可能浮在水面上。 However, the tapes produced in the current production process of the tape, such as polyvinyl chloride (PVC) and polyurethane (TPU), are mostly larger than one, and are not durable, or the hydrolysis of polyurethane occurs. Rubber is used in a longer life than other materials, so rubber is used. However, there are many types of rubber, with different reinforcing fillers, processing aids, anti-aging agents, accelerators, etc., which will give rubber a variety of different properties. Since most of the raw material formulations have a specific gravity greater than one, the choice of raw materials, added amount and cloth selection becomes an important key. To be able to float the rubber skin on the water, the specific gravity of the rubber itself and the cloth should be less than one. Only one specific gravity is less than one, and it may still sink in the water. Unless one of the specific gravity is different from the other, it is possible to float. On the water.

因此,本發明係在針對上述之困擾,提出一種水上漂浮膠布及其製作方法,以解決習知所產生的問題。 Accordingly, the present invention has been made in view of the above problems, and proposes a floating cloth on water and a method of manufacturing the same to solve the problems caused by the prior art.

本發明之主要目的,在於提供一種水上漂浮膠布及其製作方法,其係設計一種含有發泡劑之橡膠膠料,以與比重小於一之基布結合,成為漂浮於水上之皮料,用來隔絕水與外界的污染,亦可用於船艇,降低沈船的機率。 The main object of the present invention is to provide a floating plastic tape and a manufacturing method thereof, which are designed to be a rubber compound containing a foaming agent, which is combined with a base fabric having a specific gravity of less than one to become a leather material floating on the water for use. Isolation of water and outside pollution can also be used in boats to reduce the chance of shipwrecks.

為達上述目的,本發明提供一種水上漂浮膠布,其包含一 基布,其比重小於一,基布之頂面與底面皆形成有一橡膠糊。另有二橡膠布,其比重小於一,並至少包含發泡劑,此二橡膠布透過橡膠糊分別貼於基布之頂面與底面。 In order to achieve the above object, the present invention provides a floating plastic tape comprising one The base fabric has a specific gravity of less than one, and a rubber paste is formed on the top surface and the bottom surface of the base fabric. The other two rubber sheets have a specific gravity of less than one and include at least a foaming agent, and the two rubber sheets are respectively adhered to the top surface and the bottom surface of the base fabric through the rubber paste.

本發明亦提供一種水上漂浮膠布之製作方法,首先,塗布一橡膠糊於一基布之頂面與底面,此基布之比重小於一。接著,將至少含有發泡劑與比重小於一之二橡膠布透過橡膠糊分別貼於基布之頂面與底面,即完成製作。 The invention also provides a method for manufacturing a floating cloth on water. Firstly, a rubber paste is applied on the top surface and the bottom surface of a base cloth, and the specific gravity of the base cloth is less than one. Next, the rubber sheet containing at least a foaming agent and a specific gravity of less than one is applied to the top surface and the bottom surface of the base fabric through the rubber paste, respectively, to complete the production.

茲為使 貴審查委員對本發明之結構特徵及所達成之功效更有進一步之瞭解與認識,謹佐以較佳之實施例圖及配合詳細之說明,說明如後: For a better understanding and understanding of the structural features and the achievable effects of the present invention, please refer to the preferred embodiment and the detailed description.

10‧‧‧基布 10‧‧‧Kib

12‧‧‧橡膠布 12‧‧‧Rubber cloth

14‧‧‧尼龍套布 14‧‧‧Nylon cloth

第1圖為本發明之漂浮膠布結構立體圖。 Figure 1 is a perspective view showing the structure of a floating tape of the present invention.

第2圖為本發明之製作流程圖。 Figure 2 is a flow chart of the production of the present invention.

第3圖為本發明之橡膠布之形成流程圖。 Fig. 3 is a flow chart showing the formation of the rubber sheet of the present invention.

請參閱第1圖。本發明包含一基布10,其比重小於一,例如聚丙烯布,比重為0.9~0.91。基布10之頂面與底面皆形成有一橡膠糊,其組成成分含8重量份(PHR)之甲苯、3重量份之橡膠、1重量份之促進劑與1重量份之硬化劑,其中促進劑包含2-硫醇基咪唑啉與橡膠彈性體的預分散體和一硫化四甲基秋蘭姆與橡膠彈性體的預分散體,硬化劑包含聚異氰酸酯(polyisccyanate)、二氯甲烷(Methylene chloride)。另有二橡膠布12,其比重亦小於一,並至少包含發泡劑,二橡膠布12透過橡膠糊分別貼於基布10之頂面與底面,其中此發泡劑為二亞硝基五甲基四胺。發泡劑可以在橡膠內部間產生氣體,但肉眼看不見小孔洞,這樣可以讓橡膠內部充滿微小孔洞,更容易浮於水面。此二橡膠布12係由含有發泡劑之一橡膠膠料送入一壓延機中,經壓延而形成。橡膠膠料之組成成分包含100重 量份之主膠、1~3重量份之發泡劑、1~3重量份之二苯胺(diphenylamine)、2~5重量份之環烷油、5~10重量份之增黏劑、20~30重量份之碳黑與1~4重量份之硫磺,其中主膠更包含比重為0.91-0.93之天然橡膠與比重為0.86-0.87之乙烯丙烯二烯單體(EPDM),增黏劑更包含聚異丁烯與二氧化矽。由於本發明具有膠布膠之結構,故可用在覆蓋於水面上,又不會沉入水底之皮料,可用來隔絕水與外界的污染;亦或可用在船艇上,一般船艇的皮料都會沉入於水,當受到外物產生漏氣時,就會有沉船的發生,如用漂浮橡膠之皮料製成船艇,漏氣時還可以浮在水上,降低沉船機率的發生。 Please refer to Figure 1. The present invention comprises a base fabric 10 having a specific gravity of less than one, such as polypropylene cloth, having a specific gravity of from 0.9 to 0.91. A rubber paste is formed on the top surface and the bottom surface of the base fabric 10, and the composition thereof comprises 8 parts by weight (PHR) of toluene, 3 parts by weight of rubber, 1 part by weight of a promoter and 1 part by weight of a hardener, wherein the accelerator a predispersion comprising a 2-thiol imidazoline and a rubber elastomer and a predispersion of tetramethylthiuram and a rubber elastomer, the hardener comprising polyisccyanate, Methylene chloride . The second rubber cloth 12 has a specific gravity of less than one, and at least comprises a foaming agent. The second rubber cloth 12 is respectively adhered to the top surface and the bottom surface of the base fabric 10 through a rubber paste, wherein the foaming agent is dinitroso-5. Methyltetramine. The foaming agent can generate gas between the rubbers, but small holes are not visible to the naked eye, so that the inside of the rubber is filled with tiny holes, and it is easier to float on the water surface. The two rubber sheets 12 are formed by feeding a rubber compound containing one of the foaming agents into a calender and rolling. The composition of the rubber compound contains 100 weights Amount of main glue, 1 to 3 parts by weight of foaming agent, 1 to 3 parts by weight of diphenylamine, 2 to 5 parts by weight of naphthenic oil, 5 to 10 parts by weight of tackifier, 20~ 30 parts by weight of carbon black and 1 to 4 parts by weight of sulfur, wherein the main rubber further comprises a natural rubber having a specific gravity of 0.91 to 0.93 and an ethylene propylene diene monomer (EPDM) having a specific gravity of 0.86 to 0.87, and the tackifier further comprises Polyisobutylene and cerium oxide. Since the invention has the structure of the rubber tape, it can be used for covering the water surface without sinking into the bottom of the water, which can be used to insulate the pollution of the water and the outside; or can be used on the boat, the leather of the general boat They will sink into the water. When a foreign object leaks, there will be a shipwreck. For example, a floating rubber can be used to make a boat. When it leaks, it can float on the water to reduce the probability of shipwreck.

以下介紹製作過程,請同時參閱第1圖與第2圖。首先,如步驟S10所示,塗布橡膠糊於基布10之頂面與底面。接著,如步驟S12所示,將基布10送入烘箱以攝氏100~120度烘烤,以烘乾橡膠糊之溶劑。再來,如步驟S14所示,將二橡膠布12透過橡膠糊分別貼於基布10之頂面與底面。最後,如步驟S16所示,進行一加硫步驟,其係將基布10與二橡膠布12送入鼓式加硫機(ROTO CURE)加硫8~10分鐘,使基布10與二橡膠布12具有彈性,溫度設定為攝氏140~160度,壓力設定為40~50公斤/平方公分,速度為0.3~0.35碼/分鐘。 The production process is described below. Please refer to both Figure 1 and Figure 2. First, as shown in step S10, a rubber paste is applied to the top and bottom surfaces of the base fabric 10. Next, as shown in step S12, the base fabric 10 is sent to an oven to be baked at 100 to 120 degrees Celsius to dry the solvent of the rubber paste. Then, as shown in step S14, the two rubber sheets 12 are attached to the top surface and the bottom surface of the base fabric 10 through the rubber paste. Finally, as shown in step S16, a vulcanization step is performed, in which the base fabric 10 and the second rubber cloth 12 are sent to a drum vulcanizer (ROTO CURE) for sulfur for 8 to 10 minutes to make the base fabric 10 and the second rubber. The cloth 12 has elasticity, the temperature is set to 140 to 160 degrees Celsius, the pressure is set to 40 to 50 kg/cm 2 , and the speed is 0.3 to 0.35 yards per minute.

上述流程,亦可省略步驟S12或步驟S16,抑或同時省略,同樣可以製作出漂浮膠布。當省略步驟S12時,在步驟S10進行完後,直接進行步驟S14。此外,在步驟S14中,可先將其中一橡膠布12透過橡膠糊貼於基布10之頂面,再將此頂面上的橡膠布12套上尼龍套布14。然後再將另一橡膠布12透過橡膠糊貼於基布10之底面後,於底面上的橡膠布12亦套上尼龍套布14,如第3圖所示。最後,才進行步驟S16。 In the above process, step S12 or step S16 may be omitted, or omitted at the same time, and a floating tape can also be produced. When step S12 is omitted, after step S10 is completed, step S14 is directly performed. In addition, in step S14, one of the rubber sheets 12 may be first applied to the top surface of the base fabric 10 through a rubber paste, and the rubber cloth 12 on the top surface is placed on the nylon cloth cover 14. Then, another rubber cloth 12 is applied to the bottom surface of the base fabric 10 through a rubber paste, and the rubber cloth 12 on the bottom surface is also covered with a nylon cloth cloth 14, as shown in Fig. 3. Finally, step S16 is performed.

請繼續參閱第4圖,以下介紹橡膠布之製作流程。首先,如步驟S18所示,橡膠膠料先經過萬馬力混煉機混合。接著,如步驟S20所示,在攝氏80~100度的環境下以二滾輪混合橡膠膠料,此滾輪包含一粗輪與一細輪。最後,如步驟S22所示,將橡膠膠料送入壓延機中,以形成二橡膠布12。 Please continue to refer to Figure 4, the following describes the production process of rubber cloth. First, as shown in step S18, the rubber compound is first mixed by a 10,000 horsepower mixer. Next, as shown in step S20, the rubber compound is mixed by two rollers in an environment of 80 to 100 degrees Celsius, and the roller includes a coarse wheel and a thin wheel. Finally, as shown in step S22, the rubber compound is fed into the calender to form a second rubber cloth 12.

綜上所述,本發明製作的漂浮膠布,不但可以隔絕水與外界的污染,應用在船上,還可以降低沈船機率。 In summary, the floating tape made by the invention not only can isolate the pollution of water and the outside, but also can be applied to the ship, and can also reduce the probability of shipwreck.

以上所述者,僅為本發明一較佳實施例而已,並非用來限 定本發明實施之範圍,故舉凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 The above is only a preferred embodiment of the present invention and is not intended to be limiting. The scope of the present invention is intended to be included within the scope of the invention as defined by the appended claims.

Claims (19)

一種水上漂浮膠布,包含:一基布,其比重小於一,該基布之頂面與底面皆形成有一橡膠糊;以及二橡膠布,其比重小於一,並至少包含發泡劑,該二橡膠布透過該橡膠糊分別貼於該頂面與該底面。 A floating cloth for water, comprising: a base cloth having a specific gravity of less than one, a rubber paste formed on a top surface and a bottom surface of the base fabric; and a second rubber cloth having a specific gravity of less than one and containing at least a foaming agent, the second rubber The cloth is attached to the top surface and the bottom surface through the rubber paste. 如請求項1所述之水上漂浮膠布,其中該基布為聚丙烯布。 The floating cloth of water according to claim 1, wherein the base fabric is a polypropylene cloth. 如請求項1所述之水上漂浮膠布,其中該橡膠糊之組成成分含8重量份(PHR)之甲苯、3重量份之橡膠、1重量份之促進劑與1重量份之硬化劑。 The water floating tape according to claim 1, wherein the rubber paste component comprises 8 parts by weight of (PHR) toluene, 3 parts by weight of rubber, 1 part by weight of a promoter, and 1 part by weight of a hardener. 如請求項3所述之水上漂浮膠布,其中該促進劑包含2-硫醇基咪唑啉與橡膠彈性體的預分散體和一硫化四甲基秋蘭姆與橡膠彈性體的預分散體,該硬化劑包含聚異氰酸酯(polyisccyanate)、二氯甲烷(Methylene chloride)。 The floating cloth of water according to claim 3, wherein the accelerator comprises a predispersion of 2-thiol imidazoline and a rubber elastomer, and a predispersion of tetramethylthiuram and a rubber elastomer. The hardener comprises polyisccyanate, Methylene chloride. 如請求項1所述之水上漂浮膠布,其中該二橡膠布係由含有該發泡劑之一橡膠膠料送入一壓延機中,經壓延而形成。 The floating cloth of water according to claim 1, wherein the two rubber sheets are formed by feeding a rubber compound containing one of the foaming agents into a calender and calendering. 如請求項5所述之水上漂浮膠布,其中該橡膠膠料之組成成分包含100重量份之主膠、1~3重量份之該發泡劑、1~3重量份之二苯胺(diphenylamine)、2~5重量份之環烷油、5~10重量份之增黏劑、20~30重量份之碳黑與1~4重量份之硫磺。 The floating cloth of water according to claim 5, wherein the rubber composition comprises 100 parts by weight of the main glue, 1 to 3 parts by weight of the blowing agent, and 1 to 3 parts by weight of diphenylamine. 2 to 5 parts by weight of naphthenic oil, 5 to 10 parts by weight of a tackifier, 20 to 30 parts by weight of carbon black and 1 to 4 parts by weight of sulfur. 如請求項6所述之水上漂浮膠布,其中該主膠更包含天然橡膠與乙烯丙烯二烯單體(EPDM);以及該增黏劑更包含聚異丁烯與二氧化矽。 The floating cloth of water according to claim 6, wherein the main glue further comprises natural rubber and ethylene propylene diene monomer (EPDM); and the tackifier further comprises polyisobutylene and cerium oxide. 7.如請求項1所述之水上漂浮膠布,其中該發泡劑為二亞硝基五甲基四胺。 7. The floating cloth of water according to claim 1, wherein the blowing agent is dinitrosopentamethyltetramine. 一種水上漂浮膠布之製作方法,其係包含下列步驟:塗布一橡膠糊於一基布之頂面與底面,該基布之比重小於一;以及將至少含有發泡劑與比重小於一之二橡膠布透過該橡膠糊分別貼於該頂 面與該底面。 The invention relates to a method for manufacturing a floating adhesive tape, comprising the steps of: coating a rubber paste on a top surface and a bottom surface of a base fabric, wherein the base cloth has a specific gravity smaller than one; and comprising at least a foaming agent and a specific gravity less than one rubber The cloth is attached to the top through the rubber paste Face and the bottom surface. 如請求項8所述之水上漂浮膠布之製作方法,其中在形成該橡膠糊於該基布之該頂面與該底面之步驟後,將該基布送入烘箱以攝氏100~120度烘烤,再進行將該二橡膠布透過該橡膠糊分別貼於該頂面與該底面之步驟。 The method for producing a water floating tape according to claim 8, wherein after the step of forming the rubber paste on the top surface and the bottom surface of the base cloth, the base cloth is sent to an oven to be baked at 100 to 120 degrees Celsius. And the step of attaching the two rubber sheets to the top surface and the bottom surface through the rubber paste. 如請求項8所述之水上漂浮膠布之製作方法,更包含一加硫步驟,其係將該基布與該二橡膠布送入加硫機加硫8~10分鐘,溫度設定為攝氏140~160度,壓力設定為40~50公斤/平方公分,速度為0.3~0.35碼/分鐘。 The method for preparing a floating plastic tape according to claim 8, further comprising a vulcanization step of feeding the base fabric and the second rubber cloth to a vulcanizer for 8 to 10 minutes, and setting the temperature to 140 ° C. 160 degrees, the pressure is set to 40 ~ 50 kg / cm ^ 2, the speed is 0.3 ~ 0.35 yards / minute. 如請求項8所述之水上漂浮膠布之製作方法,其中該基布為聚丙烯布。 The method for producing a water floating tape according to claim 8, wherein the base fabric is a polypropylene cloth. 如請求項8所述之水上漂浮膠布之製作方法,其中該橡膠糊之組成成分含8重量份(PHR)之甲苯、3重量份之橡膠、1重量份之促進劑與1重量份之硬化劑。 The method for producing a water floating tape according to claim 8, wherein the rubber paste component comprises 8 parts by weight (PHR) of toluene, 3 parts by weight of rubber, 1 part by weight of a promoter and 1 part by weight of a hardener. . 如請求項12所述之水上漂浮膠布之製作方法,其中該促進劑包含2-硫醇基咪唑啉,與橡膠彈性體的預分散體和一硫化四甲基秋蘭姆與橡膠彈性體的預分散體,該硬化劑包含聚異氰酸酯(polyisccyanate)、二氯甲烷(Methylene chloride)。 The method for producing a water floating tape according to claim 12, wherein the accelerator comprises a 2-thiol imidazoline, a predispersion with a rubber elastomer, and a pre-dispersion of tetramethylthiuram and a rubber elastomer. A dispersion comprising polyisccyanate or Methylene chloride. 如請求項8所述之水上漂浮膠布之製作方法,其中該二橡膠布係由含有該發泡劑之一橡膠膠料送入一壓延機中,經壓延而形成。 The method for producing a water floating tape according to claim 8, wherein the two rubber cloths are formed by feeding a rubber compound containing one of the foaming agents into a calender and rolling. 如請求項14所述之水上漂浮膠布之製作方法,其中該橡膠膠料之組成成分包含100重量份之主膠、1~3重量份之該發泡劑、1~3重量份之二苯胺(diphenylamine)、2~5重量份之環烷油、5~10重量份之增黏劑、20~30重量份之碳黑與1~4重量份之硫磺。 The method for producing a water floating tape according to claim 14, wherein the rubber compound comprises 100 parts by weight of the main gum, 1 to 3 parts by weight of the foaming agent, and 1 to 3 parts by weight of diphenylamine ( Diphenylamine), 2 to 5 parts by weight of naphthenic oil, 5 to 10 parts by weight of a tackifier, 20 to 30 parts by weight of carbon black and 1 to 4 parts by weight of sulfur. 如請求項15所述之水上漂浮膠布之製作方法,其中該主膠更包含天然橡膠與乙烯丙烯二烯單體(EPDM);以及該增黏劑更包含聚異丁烯與二氧化矽。 The method for producing a water floating tape according to claim 15, wherein the main glue further comprises natural rubber and ethylene propylene diene monomer (EPDM); and the tackifier further comprises polyisobutylene and cerium oxide. 如請求項14所述之水上漂浮膠布之製作方法,其中該橡膠膠料有先後分別經過萬馬力混煉機與在攝氏80~100度的環境下以二滾輪所混合過,再送入該壓延機中,以形成該二橡膠布。 The method for manufacturing a floating plastic tape according to claim 14, wherein the rubber compound is mixed with two rollers in an environment of 80 to 100 degrees Celsius and then fed into the calender. Medium to form the two rubber sheets. 如請求項17所述之水上漂浮膠布之製作方法,其中該二滾輪包含一粗輪與一細輪。 The method for manufacturing a floating cloth of water according to claim 17, wherein the two rollers comprise a coarse wheel and a thin wheel. 如請求項8所述之水上漂浮膠布之製作方法,其中該發泡劑為二亞硝基五甲基四胺。 The method for producing a water floating tape according to claim 8, wherein the foaming agent is dinitrosopentamethyltetramine.
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