TW201418405A - Method of preparing ultra-thin elastic adhesive tape - Google Patents

Method of preparing ultra-thin elastic adhesive tape Download PDF

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TW201418405A
TW201418405A TW101141771A TW101141771A TW201418405A TW 201418405 A TW201418405 A TW 201418405A TW 101141771 A TW101141771 A TW 101141771A TW 101141771 A TW101141771 A TW 101141771A TW 201418405 A TW201418405 A TW 201418405A
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adhesive
woven fabric
elastic film
thermoplastic polyurethane
ultra
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TW101141771A
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Chinese (zh)
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hong-en Zhu
zheng-ji Xu
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Formosan Rubber Group Inc
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Abstract

The present invention discloses a preparation method of an ultra-thin elastic adhesive tape, in which an adhesive is firstly formed onto the surface of a woven fabric. Subsequently, the adhesive is dried under the Celsius degree of 100~150. Finally, a thermoplastic polyurethane (TPU) elastic film with a thickness of 0.03~0.07 millimeter (mm) is formed onto the surface of the woven fabric through the adhesive to be joined with the woven fabric for completing the preparation. The present invention adopts the ultra-thin thermoplastic polyurethane elastic film, not only having the property of the environmentally-friendly material, but also being different from the prior-art processing way of the thermal calendaring and containing the light-weight advantage.

Description

超薄彈性膠布之製作方法 Ultra-thin elastic tape manufacturing method

本發明係有關一種膠布之製作方法,特別是關於一種超薄彈性膠布之製作方法。 The invention relates to a method for manufacturing a tape, in particular to a method for manufacturing an ultra-thin elastic tape.

近年來環保意識高漲,故各民生用品材料選擇環保材,熱可塑聚氨基甲酸酯系彈性(TPU)薄膜是一種成熟的無毒性之環保材料,也是一種高分子彈性體,具有耐磨、抗拉、耐高溫、耐低溫不龜裂等特性,其製成產品涵蓋了工業應用和民用必需品的範圍,可運用於救生、鞋類、運動用品、成衣類、醫療類產品等,因應世界環保意識取代聚氯乙烯(PVC),其用途廣泛,因其優越的性能和環保概念日益受到人們的歡迎目前已被大量採用。 In recent years, environmental awareness has risen. Therefore, materials for environmental protection materials are selected from environmentally friendly materials. The thermoplastic polyurethane-based elastic (TPU) film is a mature non-toxic environmentally friendly material and a kind of polymer elastomer with wear resistance and resistance. Pulling, high temperature resistance, low temperature resistance, no cracking, etc., its products cover a range of industrial applications and civilian necessities, can be used in lifesaving, footwear, sporting goods, clothing, medical products, etc., in response to world environmental awareness It replaces polyvinyl chloride (PVC), which is widely used and has been widely used due to its superior performance and environmental protection concept.

熱可塑聚氨基甲酸酯系彈性之物性屬於橡膠與塑膠之間,經過多年的研究及開發,已可製造出各種型態之產品,包括有射出級、押出級、吹膜級,熱可塑聚氨基甲酸酯系彈性之性質經各產業產品不同需求不斷改善與提昇也開發出不同之熱可塑聚氨基甲酸酯系彈性。在傳統技術中,若欲製作一彈性膠布,係以熱壓延的加工方式來製作,即是指由熱可塑聚氨基甲酸酯系彈性粒子加熱熔融壓延成薄膜,但此薄膜僅可至0.1釐米(mm)厚度,亦無法減輕整體重量。 Thermoplastic polyurethane is a property of rubber and plastic. After years of research and development, it has been able to manufacture various types of products, including injection grade, extrusion grade, blown film grade, and thermoplastic polymerization. The properties of the urethane-based elasticity have been developed through the continuous improvement and improvement of various industrial products, and different thermal plastic polyurethane elasticity has been developed. In the conventional art, if an elastic tape is to be produced, it is produced by hot calendering, that is, it is heated and melt-rolled into a film by thermoplastic polyurethane elastic particles, but the film can only be 0.1. The thickness of centimeters (mm) does not reduce the overall weight.

因此,本發明係在針對上述之困擾,提出一種超薄彈性膠布之製作方法,以解決習知所產生的問題。 Accordingly, the present invention has been made in view of the above problems, and a method for producing an ultra-thin elastic tape is proposed to solve the problems caused by the prior art.

本發明之主要目的,在於提供一種超薄彈性膠布及其製作方法,其係採用超薄之熱可塑聚氨基甲酸酯系彈性(TPU)薄膜,不但有無毒性之環保性質,更兼顧了輕量化之需求,可應用於製作救生、運動、民生等產品。 The main object of the present invention is to provide an ultra-thin elastic tape and a preparation method thereof, which are characterized by using an ultra-thin thermoplastic polyurethane elastic (TPU) film, which has environmental properties of non-toxicity and light weight. The demand can be applied to the production of lifesaving, sports, people's livelihood and other products.

為達上述目的,本發明提供一種超薄彈性膠布之製作方法,首先,形成一黏劑於一織布之表面上。接著,將厚度為0.03~0.07釐米(mm) 之一熱可塑聚氨基甲酸酯系彈性薄膜,透過黏劑形成於織布之表面上,以與織布接合,便完成製作。 In order to achieve the above object, the present invention provides a method for producing an ultra-thin elastic tape. First, an adhesive is formed on the surface of a woven fabric. Next, the thickness will be 0.03~0.07 cm (mm) A thermoplastic polyurethane-based elastic film is formed on the surface of the woven fabric through an adhesive to be bonded to the woven fabric to complete the production.

茲為使貴審查委員對本發明之結構特徵及所達成之功效更有進一步之瞭解與認識,謹佐以較佳之實施例圖及配合詳細之說明,說明如後: In order to give the review board members a better understanding and understanding of the structural features and the efficacies of the present invention, please refer to the preferred embodiment diagrams and the detailed descriptions as follows:

熱可塑聚氨基甲酸酯系彈性(TPU)之性質經各產業產品不同需求不斷改善與提昇也開發出不同之TPU,如機械強度、耐磨耗、耐寒性、耐紫外線(UV)、耐曲折、延伸率佳、生物相容性及聚醚、聚脂等各種特殊產品等。本發明乃針對輕量化熱可塑聚氨基甲酸酯系彈性之薄膜應用。 The properties of thermoplastic polyurethane elastomer (TPU) have been developed and improved by different needs of various industrial products, such as mechanical strength, wear resistance, cold resistance, UV resistance, and tortuosity. , good elongation, biocompatibility and various special products such as polyether and polyester. The present invention is directed to a lightweight thermal plastic polyurethane elastic film application.

以下請參閱第1圖與第2圖,並介紹本發明之第一實施例。首先,如步驟S10所示,均勻形成一黏劑於一織布10之表面上,並使織布10保持穩定的平整度。此黏劑之黏度為80000~90000厘泊(cps),並包含100重量份之聚氨基甲酸酯(PU)樹脂、5~10重量份之異氰酸鹽架橋劑與作為溶劑之甲苯。其中異氰酸鹽架橋劑更包含12.5~13.5重量%之異氰酸酯、73±2重量%之固成分,與0.5重量%以下之游離甲苯二異氰酸酯(TDI)。接著,如步驟S12所示,對黏劑在攝氏100~150度下乾燥之。再來,如步驟S14所示,將厚度為0.03~0.07釐米(mm)之一熱可塑聚氨基甲酸酯系彈性薄膜12,放在攝氏70~155度之環境下,預熱10~30秒,並施以5~25公斤的張力,以進行平整化。然後,如步驟S16所示,將熱可塑聚氨基甲酸酯系彈性薄膜12透過黏劑貼合於織布10之表面,並對熱可塑聚氨基甲酸酯系彈性薄膜12與織布10施以5~10公斤/平方公分(kg/cm2)之壓力,以完成貼合。完成後,如步驟S18所示,以電熱管以攝氏100~140度加熱熱可塑聚氨基甲酸酯系彈性薄膜12與黏劑,以軟化熱可塑聚氨基甲酸酯系彈性薄膜12,並揮發黏劑中之溶劑。最後,如步驟S20所示,以熱壓紋機對熱可塑聚氨基甲酸酯系彈性薄膜12與織布10施以5~10公斤/ 平方公分之壓力,以利用黏劑架橋熱可塑聚氨基甲酸酯系彈性薄膜12與織布10,並將其接合之,如第2圖所示。本發明將超薄之熱可塑聚氨基甲酸酯系彈性薄膜貼合於織布上,此方法與市面上射出及淋膜方式有所區隔,同時也改善了傳統熱壓延方式加工上,熱可塑聚氨基甲酸酯系彈性薄膜厚度限制僅到0.1釐米之問題。此外,由於本發明之熱可塑聚氨基甲酸酯系彈性薄膜之厚度為超薄之0.03~0.07釐米,故不但為無毒性之環保材料,更兼顧了輕量化之優點,可應用於救生、運動、民生等產品。 Referring to Figures 1 and 2 below, a first embodiment of the present invention will be described. First, as shown in step S10, an adhesive is uniformly formed on the surface of a woven fabric 10, and the woven fabric 10 is maintained in a stable flatness. The adhesive has a viscosity of 80,000 to 90000 centipoise (cps) and contains 100 parts by weight of a polyurethane (PU) resin, 5 to 10 parts by weight of an isocyanate bridging agent and toluene as a solvent. The isocyanate bridging agent further comprises 12.5 to 13.5% by weight of isocyanate, 73 ± 2% by weight of a solid component, and 0.5% by weight or less of free toluene diisocyanate (TDI). Next, as shown in step S12, the adhesive is dried at 100 to 150 degrees Celsius. Further, as shown in step S14, a thermoplastic polyurethane elastic film 12 having a thickness of 0.03 to 0.07 cm (mm) is placed in an environment of 70 to 155 degrees Celsius, and preheated for 10 to 30 seconds. And apply a tension of 5 to 25 kg for flattening. Then, as shown in step S16, the thermoplastic polyurethane-based elastic film 12 is adhered to the surface of the woven fabric 10 through an adhesive, and the thermoplastic resin-based elastic film 12 and the woven fabric 10 are applied. The bonding is carried out at a pressure of 5 to 10 kg/cm 2 (kg/cm 2 ). After completion, as shown in step S18, the hot plastic polyurethane elastic film 12 and the adhesive are heated by an electric heating tube at 100 to 140 degrees Celsius to soften the thermoplastic polyurethane elastic film 12 and volatilize. The solvent in the adhesive. Finally, as shown in step S20, the thermoplastic polyurethane-based elastic film 12 and the woven fabric 10 are subjected to a pressure of 5 to 10 kg/cm 2 by a heat embossing machine to thermally mold the polyamino group by using an adhesive. The formate elastic film 12 and the woven fabric 10 are joined together as shown in Fig. 2. The invention attaches an ultra-thin thermoplastic polyurethane elastic film to the woven fabric, and the method is separated from the injection and lamination methods on the market, and also improves the traditional hot rolling method. The thermoplastic polyurethane-based elastic film has a thickness limit of only 0.1 cm. In addition, since the thickness of the thermoplastic polyurethane elastic film of the present invention is ultra-thin 0.03 to 0.07 cm, it is not only a non-toxic environmentally friendly material, but also has the advantages of light weight, and can be applied to lifesaving and sports. , people's livelihood and other products.

上述步驟S14至步驟S20,亦可以一步驟取代,即在步驟S12結束後,直接將厚度為0.03~0.07釐米之熱可塑聚氨基甲酸酯系彈性薄膜12透過黏劑貼合於織布10之表面上,以完成接合。 The step S14 to the step S20 may be replaced by a step, that is, after the end of the step S12, the thermoplastic polyurethane elastic film 12 having a thickness of 0.03 to 0.07 cm is directly adhered to the woven fabric 10 through an adhesive. On the surface, to complete the joint.

以下請參閱第2圖與第3圖,並介紹本發明之第二實施例。第二實施例與第一實施例的差別在於第二實施例省略了步驟S12,即在上述步驟S10結束後,直接進行步驟S14至步驟S20。換言之,當均勻形成黏劑於織布10之表面上後,便如步驟S14所示,將厚度為0.03~0.07釐米(mm)之一熱可塑聚氨基甲酸酯系彈性薄膜12,放在攝氏70~155度之環境下,預熱10~30秒,並施以5~25公斤的張力,以進行平整化。之後的步驟S16至步驟S20,與第一實施例相同,於此不再贅述。完成圖如第2圖所示。 Referring to Figures 2 and 3 below, a second embodiment of the present invention will be described. The difference between the second embodiment and the first embodiment is that the second embodiment omits step S12, that is, after the end of step S10 described above, step S14 to step S20 are directly performed. In other words, when the adhesive is uniformly formed on the surface of the woven fabric 10, a thermoformable polyurethane elastic film 12 having a thickness of 0.03 to 0.07 cm (mm) is placed in Celsius as shown in step S14. In an environment of 70 to 155 degrees, preheat for 10 to 30 seconds and apply a tension of 5 to 25 kg for flattening. Subsequent steps S16 to S20 are the same as the first embodiment, and are not described herein again. The completion diagram is shown in Figure 2.

同樣地,上述步驟S14至步驟S20,亦可以一步驟取代,即在步驟S12結束後,直接將厚度為0.03~0.07釐米之熱可塑聚氨基甲酸酯系彈性薄膜12透過黏劑貼合於織布10之表面上,以完成接合。 Similarly, the above steps S14 to S20 may be replaced by one step, that is, after the end of step S12, the thermoplastic polyurethane elastic film 12 having a thickness of 0.03 to 0.07 cm is directly adhered to the woven fabric through an adhesive. The surface of the cloth 10 is used to complete the joint.

綜上所述,本發明直接將厚度為0.03~0.07釐米之熱可塑聚氨基甲酸酯系彈性薄膜進行貼合,以達到環保且輕量化產品之目的。 In summary, the present invention directly bonds a thermoplastic polyurethane elastic film having a thickness of 0.03 to 0.07 cm to achieve an environmentally friendly and lightweight product.

以上所述者,僅為本發明一較佳實施例而已,並非用來限定本發明實施之範圍,故舉凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, so that the shapes, structures, features, and spirits described in the claims of the present invention are equally varied and modified. All should be included in the scope of the patent application of the present invention.

10‧‧‧織布 10‧‧‧Weaving

12‧‧‧熱可塑聚氨基甲酸酯系彈性薄膜 12‧‧‧Hot plastic polyurethane elastic film

第1圖為本發明之第一實施例流程圖。 Figure 1 is a flow chart of a first embodiment of the present invention.

第2圖為本發明之超薄彈性膠布之結構立體圖。 Fig. 2 is a perspective view showing the structure of the ultra-thin elastic tape of the present invention.

第3圖為本發明之第二實施例流程圖。 Figure 3 is a flow chart of a second embodiment of the present invention.

Claims (8)

一種超薄彈性膠布之製作方法,包括下列步驟:(a)形成一黏劑於一織布之表面上;以及(b)將厚度為0.03~0.07釐米(mm)之一熱可塑聚氨基甲酸酯系彈性(TPU)薄膜,透過該黏劑形成於該表面上,以與該織布接合。 The invention relates to a method for manufacturing an ultra-thin elastic tape, comprising the steps of: (a) forming an adhesive on a surface of a woven fabric; and (b) forming a thermoplastic polyurethane having a thickness of 0.03 to 0.07 cm (mm). An ester-based elastic (TPU) film is formed on the surface through the adhesive to bond with the woven fabric. 如請求項1所述之超薄彈性膠布之製作方法,其中在形成該黏劑於該表面上之步驟後,更可對該黏劑在攝氏100~150度下乾燥之,再進行將該熱可塑聚氨基甲酸酯系彈性薄膜,透過該黏劑形成於該表面上,以與該織布接合之步驟。 The method for producing an ultra-thin elastic tape according to claim 1, wherein after the step of forming the adhesive on the surface, the adhesive is further dried at 100 to 150 degrees Celsius, and then the heat is further applied. A flexible polyurethane-based elastic film formed on the surface by the adhesive to join the woven fabric. 如請求項1所述之超薄彈性膠布之製作方法,其中該步驟(b)更包含下列步驟:(b1)將該熱可塑聚氨基甲酸酯系彈性薄膜在攝氏70~155度下,預熱10~30秒,並施以5~25公斤的張力;(b2)將該熱可塑聚氨基甲酸酯系彈性薄膜透過該黏劑貼合於該織布之該表面,並對該熱可塑聚氨基甲酸酯系彈性薄膜與該織布施以5~10公斤/平方公分(kg/cm2)之壓力;(b3)以攝氏100~140度加熱該熱可塑聚氨基甲酸酯系彈性薄膜與該黏劑,以軟化該熱可塑聚氨基甲酸酯系彈性薄膜,並揮發該黏劑中之溶劑;以及(b4)對該熱可塑聚氨基甲酸酯系彈性薄膜與該織布施以5~10公斤/平方公分之壓力,以利用該黏劑架橋該熱可塑聚氨基甲酸酯系彈性薄膜與該織布,並將其接合之。 The method for producing an ultra-thin elastic tape according to claim 1, wherein the step (b) further comprises the step of: (b1) pre-treating the thermoplastic polyurethane elastic film at 70 to 155 degrees Celsius. Heating for 10 to 30 seconds and applying a tension of 5 to 25 kg; (b2) adhering the thermoplastic polyurethane elastic film to the surface of the woven fabric through the adhesive, and thermoforming the thermoplastic The polyurethane elastic film and the woven fabric are subjected to a pressure of 5 to 10 kg/cm 2 (b3) to heat the thermoplastic polyurethane elastic film at 100 to 140 ° C. And the adhesive to soften the heat-mouldable polyurethane-based elastic film and volatilize the solvent in the adhesive; and (b4) apply the heat-mouldable polyurethane-based elastic film to the woven fabric A pressure of ~10 kg/cm 2 is used to bridge the thermoplastic polyurethane elastic film and the woven fabric by the adhesive. 如請求項3所述之超薄彈性膠布之製作方法,其中在該步驟(b3)中,係以電熱管以攝氏100~140度加熱該熱可塑聚氨基甲酸酯系彈性薄膜與該黏劑,以軟化該熱可塑聚氨基甲酸酯系彈性薄膜,並揮發該黏劑中之該溶劑。 The method for producing an ultrathin elastic tape according to claim 3, wherein in the step (b3), the thermoplastic polyurethane elastic film and the adhesive are heated by an electric heating tube at 100 to 140 degrees Celsius. To soften the thermoplastic polyurethane elastic film and volatilize the solvent in the adhesive. 如請求項3所述之超薄彈性膠布之製作方法,其中在該步驟(b4)中,係以熱壓紋機對該熱可塑聚氨基甲酸酯系彈性薄膜與該織布施以5 ~10公斤/平方公分之該壓力,以利用該黏劑架橋該熱可塑聚氨基甲酸酯系彈性薄膜與該織布,並將其接合之。 The method for producing an ultrathin elastic tape according to claim 3, wherein in the step (b4), the thermoplastic polyurethane elastic film and the woven fabric are applied by a heat embossing machine. The pressure of ~10 kg/cm 2 is used to bridge the thermoplastic polyurethane elastic film and the woven fabric by the adhesive. 如請求項1所述之超薄彈性膠布之製作方法,其中該黏劑包含100重量份之聚氨基甲酸酯(PU)樹脂、5~10重量份之異氰酸鹽架橋劑與作為溶劑之甲苯。 The method for producing an ultrathin elastic tape according to claim 1, wherein the adhesive comprises 100 parts by weight of a polyurethane (PU) resin, 5 to 10 parts by weight of an isocyanate bridging agent, and a solvent. Toluene. 如請求項6所述之超薄彈性膠布之製作方法,其中該異氰酸鹽架橋劑更包含12.5~13.5重量%之異氰酸酯、73±2重量%之固成分,與0.5重量%以下之游離甲苯二異氰酸酯(TDI)。 The method for producing an ultrathin elastic tape according to claim 6, wherein the isocyanate bridging agent further comprises 12.5 to 13.5% by weight of isocyanate, 73 ± 2% by weight of a solid component, and 0.5% by weight or less of free toluene. Diisocyanate (TDI). 如請求項1所述之超薄彈性膠布之製作方法,其中該黏劑之黏度為80000~90000厘泊(cps)。 The method for producing an ultra-thin elastic tape according to claim 1, wherein the viscosity of the adhesive is 80,000 to 90000 centipoise (cps).
TW101141771A 2012-11-09 2012-11-09 Method of preparing ultra-thin elastic adhesive tape TW201418405A (en)

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