TW201330952A - Gas purging plug for metal casting vessel comprising anti-clogging system and method for the production thereof - Google Patents
Gas purging plug for metal casting vessel comprising anti-clogging system and method for the production thereof Download PDFInfo
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Description
本發明係有關於例如耐火淨化塞體、風管嘴、擴散器、起泡擋塊或墊、或其他類似者等普遍地被用於將氣體吹入冶金容器內之裝置。此尤其有關於這類可防止該塞體被熔融金屬或熔渣之逆流滲入所阻塞。為了簡化之緣故,在本文中將針對淨化塞體進行說明,但應清楚理解的是本發明並不只受限於此。 The present invention relates to apparatus commonly used to blow a gas into a metallurgical vessel, such as a refractory plug body, a duct nozzle, a diffuser, a foaming stop or pad, or the like. This is particularly relevant in this regard to prevent the plug from being blocked by countercurrent infiltration of molten metal or slag. For the sake of simplicity, the description will be made with respect to the purification plug body, but it should be clearly understood that the invention is not limited thereto.
在金屬成形方法中,金屬熔融物被從一冶金容器轉移至另一冶金容器或鑄模處。例如,一澆斗被填滿來自熔爐之金屬熔融物並被轉移至一喂槽處。此金屬熔融物可接著從喂槽被澆鑄至一用於形成大板坯、小鋼坯或大鋼坯之鑄模內。或者,鑄錠亦可直接從澆斗處被傾倒入。在大部分情形中,最好將氣體吹入被包含在此類冶金容器中之熔融金屬內。此可有助於加速溫度與浴槽成分的均一化,以便將存在大浴槽中之非金屬內含物向上帶至熔渣頂層,以便在此熔融金屬內創造有利之條件,以及諸如此類者。氣體通常藉由若干被安置在一諸如澆斗或喂槽等之冶金容器的底部或側邊處之淨化塞體而被吹入熔融金屬內。 In the metal forming process, the molten metal is transferred from a metallurgical vessel to another metallurgical vessel or mold. For example, a bucket is filled with molten metal from the furnace and transferred to a feed tank. This metal melt can then be cast from the feed tank into a mold for forming a large slab, a billet or a billet. Alternatively, the ingot can be poured directly from the bucket. In most cases, it is preferred to blow a gas into the molten metal contained in such a metallurgical vessel. This may help to accelerate the homogenization of the temperature and bath components to bring the non-metallic inclusions present in the large bath up to the slag top layer to create favorable conditions within the molten metal, and the like. The gas is typically blown into the molten metal by a plurality of purge plugs disposed at the bottom or sides of a metallurgical vessel such as a bucket or feed tank.
淨化塞體係成耐火材料塊之形狀,其通常沿著一縱向軸線延伸。在此塊體之一端處,一被連接至一加壓氣體源處之氣體入口被流體地連接至一位於此塊體之相對端處之氣體出口。此氣體入口及此氣體出口可經由一開 孔網狀物、藉由一或多個通道(例如成狹縫形狀或具有圓形截面者)、或兩者之組合而被相互連接。一開孔網狀物有時據稱可產生「間接滲透性」,而一通道則據稱可產生「直接滲透性」。一般被認定的是,間接滲透性塞體係比直接滲透性塞體更具效率,不論在開孔比率及攪動效果(由於氣泡大小及有效面積所致)方面均是。多孔塞體(間接)之一不利處在於:材料通常較差(較小之熱及冷碎強度及在較高流速下較快之腐蝕)。 The plug system is shaped into a refractory block that generally extends along a longitudinal axis. At one end of the block, a gas inlet connected to a source of pressurized gas is fluidly coupled to a gas outlet at the opposite end of the block. The gas inlet and the gas outlet can be opened The mesh of the holes is interconnected by one or more channels (e.g., in the shape of a slit or having a circular cross section), or a combination of the two. An open mesh is sometimes said to produce "indirect permeability", while a channel is said to produce "direct permeability." It is generally accepted that indirect osmotic plug systems are more efficient than direct osmosis plugs, both in terms of open cell ratio and agitation (due to bubble size and effective area). One disadvantage of the porous plug body (indirect) is that the material is generally poor (smaller heat and cold crush strength and faster corrosion at higher flow rates).
如第5圖中所示,一淨化塞體(1)通常被埋置在一冶金容器之壁及內襯中,使得氣體入口面朝此冶金容器之外側,且使得氣體出口面朝此容器之與熔融金屬相接觸之內側。「氣體入口」及「氣體出口」係相對於被注入冶金容器內之氣體的流動方向(11)而被界定。一與氣體淨化塞體有關之主要問題在於:如果壓力在當流動被擋止時下降,熔融金屬可能經由氣體出口藉由重力而滲入塞體之諸通道及/或諸細孔內。此不只增加安全之顧慮且還產生操作上之問題。更確切而言,當諸通道或諸細孔中之熔融金屬凍結時,此塞體至少會被部分地阻塞。僅可藉將高壓氣體吹入此諸通道或諸細孔內或藉由在此冶金容器成空時以氧氣通過塞體之上表面而暢通此已被阻塞之塞體,但這些技術係耗時的,非總是合適的,因而導致耐火材料之嚴重腐蝕,且非總是成功地暢通該塞體。為了降低滲入之風險,一通道之直徑或寬度通常被限制不大於1 mm,以便可藉由毛細管而提供對滲入之有效防制。然而,此措施並不利於此淨化塞體之功效,因為其 強烈地限制氣體通過此塞體之流速。 As shown in Figure 5, a purge plug (1) is typically embedded in the wall and liner of a metallurgical vessel such that the gas inlet faces the outside of the metallurgical vessel and the gas outlet faces the vessel The inner side in contact with the molten metal. The "gas inlet" and "gas outlet" are defined relative to the flow direction (11) of the gas injected into the metallurgical vessel. A major problem associated with gas purge plugs is that if the pressure drops when the flow is stopped, the molten metal may seep into the passages and/or pores of the plug body by gravity through the gas outlet. This not only increases security concerns but also creates operational problems. More specifically, when the molten metal in the channels or the pores freezes, the plug body is at least partially blocked. The blocked plug can only be unblocked by blowing high pressure gas into the channels or pores or by passing oxygen through the upper surface of the plug when the metallurgical vessel is empty, but these techniques are time consuming. Not always suitable, thus causing severe corrosion of the refractory material and not always successfully opening the plug body. In order to reduce the risk of infiltration, the diameter or width of a channel is usually limited to no more than 1 mm so that the capillary can be used to provide effective control of penetration. However, this measure is not conducive to the efficacy of purifying the plug body because it The flow rate of gas through this plug is strongly limited.
本發明提出一種可延長一淨化塞體之使用壽命的方法,甚至是在諸通道已部分地被熔融金屬所深入後。本發明亦可與具有接近或甚至大於1 mm直徑之通道配合運作,因為部分之滲入並無害於此淨化塞體之使用。 The present invention provides a method for extending the service life of a purge plug, even after the passages have been partially penetrated by the molten metal. The invention can also be operated in conjunction with a channel having a diameter that is close to or even greater than 1 mm, since partial penetration does not compromise the use of the purge plug.
本發明係由所附之申請專利範圍所界定。諸獨立項界定多個較佳之實施例。具體而言,本發明係有關於一種用於將氣體吹入冶金容器內之氣體淨化塞體,如申請專利範圍第1項所界定者。 The invention is defined by the scope of the appended claims. The individual items define a number of preferred embodiments. In particular, the invention relates to a gas purification plug for blowing a gas into a metallurgical vessel, as defined in claim 1 of the scope of the patent application.
一「從通道之氣體出口起伸展至氣體入口處之最短線條」概括而言係與熔融金屬會沿著流動之理論方向成對應,假使此熔融金屬尤其因重力而滲入一狹縫形狀通道內。在一較佳實施例中,任一從被該第一最短線條所攔截之該第一橋體的任一側起伸展至該通道之氣體入口處之第二最短線條將必然會攔截到至少一第二橋體之凹側。較佳地,相同情況是用於一攔截到至少一第三橋體之凹側的第三最短線條,且依此類推,其中任何從一被一第(i-1)最短線條所攔截之第(i-1)橋體的任一側起伸展至該通道之氣體入口處之第i最短線條必然攔截到至少一第i橋體之凹側,直到第N橋體及氣體入口之間已無任何橋體為止。N之值較佳地係至少等於3,更佳地係至少等於5,最佳地係至少等於10。 A "shortest line extending from the gas outlet of the passage to the gas inlet" generally corresponds to the molten metal in the theoretical direction of the flow, provided that the molten metal penetrates into a slit-shaped passage, especially by gravity. In a preferred embodiment, any second shortest line extending from either side of the first bridge that is intercepted by the first shortest line to the gas inlet of the passage will necessarily intercept at least one The concave side of the second bridge body. Preferably, the same case is for a third shortest line that intercepts the concave side of at least one third bridge body, and so on, any of which is intercepted by a shortest line of (i-1) (i-1) The i-th shortest line extending from either side of the bridge body to the gas inlet of the passage must be intercepted to the concave side of at least one i-th bridge body until there is no between the Nth bridge body and the gas inlet Any bridge body. The value of N is preferably at least equal to 3, more preferably at least equal to 5, and most preferably at least equal to 10.
一或多個狹縫狀通道之多種不同構形係可能的。在一第一實施例中,至少一通道環繞縱向軸線(X1),因此 界定一藉由形成該通道之狹縫而與一環繞層相隔開之心部。在一第二實施例中,至少一狹縫係大致沿著一平面而延伸。此平面較佳地成徑向地延伸自該淨化塞體之縱向軸線(X1)處。在又一較佳實施例中,多個狹縫(相連接或相分離)沿著多個平面延伸,而此諸平面則包括並被徑向分布在該淨化塞體之縱向軸線(X1)附近。「大致沿著一平面延伸」一辭乃意指包括該在其中狹縫通道係相對於一平面成波狀之實施例。 Many different configurations of one or more slit-like channels are possible. In a first embodiment, at least one channel surrounds the longitudinal axis (X1), thus A core portion is defined that is separated from a surrounding layer by a slit forming the channel. In a second embodiment, at least one of the slits extends substantially along a plane. This plane preferably extends radially from the longitudinal axis (X1) of the purification plug body. In still another preferred embodiment, a plurality of slits (connected or phase separated) extend along a plurality of planes, and the planes are included and radially distributed adjacent the longitudinal axis (X1) of the purification plug body . The phrase "extending substantially along a plane" is intended to include embodiments in which the slit channel is undulated relative to a plane.
諸凹形橋體形成作為許多容器,此諸容器適於收納並保留金屬,而此金屬之流動前端則攔截到此諸容器。諸橋體可具有許多不同之幾何形狀。尤其較佳地,此諸凹形橋體具有下列幾何形狀中之一者:U形、V形、較佳為圓或橢圓之弧形、敞開之矩形或方形盒體、一拋物線、及類似者之形狀。該狹縫之形狀及因此該等凹形橋體之厚度較佳地不超過2.0 mm,更佳地不超過1.5 mm,更佳地不超過1.0 mm,及最佳地不超過0.5 mm,此取決於所用之熔融金屬的黏滯性及流體張力。概括而言,使用具有在0.25mm至0.5mm間之厚度的狹縫狀通道可獲得絕佳之結果。 The concave bridges are formed as a plurality of containers adapted to receive and retain metal, and the flow front of the metal intercepts the containers. The bridges can have many different geometries. Particularly preferably, the concave bridge bodies have one of the following geometric shapes: U-shaped, V-shaped, preferably circular or elliptical curved, open rectangular or square box, a parabola, and the like. The shape. The shape of the slit and thus the thickness of the concave bridge body preferably does not exceed 2.0 mm, more preferably does not exceed 1.5 mm, more preferably does not exceed 1.0 mm, and optimally does not exceed 0.5 mm, depending on The viscosity of the molten metal used and the fluid tension. In summary, excellent results can be obtained using slit-shaped channels having a thickness between 0.25 mm and 0.5 mm.
本發明之淨化塞體之本體可整個由密度大之耐火材料所製成,因此連同至少一狹縫狀通道共同界定一直接可滲透系統。在一可替代之實施例中,至少部分該淨化塞體(例如該環繞層)係由一多孔性耐火材料所製成,因此連同(諸)狹縫狀通道共同界定一混合式直接及間接可滲透系統。例如,此塞體可包括一由密度大之難火材量 所製之心部,其與一環繞多孔耐火層間相隔一環狀狹縫形通道。 The body of the purge plug of the present invention can be made entirely of dense refractory material, thereby collectively defining a direct permeable system in conjunction with at least one slit-like passage. In an alternative embodiment, at least a portion of the purge plug (eg, the wrap layer) is formed from a porous refractory material, thereby collectively defining a hybrid direct and indirect together with the slit-like passage(s) Permeable system. For example, the plug body may include a large amount of difficult fire material The core portion is formed by an annular slit-shaped passage from a surrounding porous refractory layer.
本發明亦有關於一種冶金容器,其包括一如上所述之淨化塞體,其中氣體出口係與該容器之內部成流體連通;以及有關於一種用於製造此類淨化塞體之方法。此用於製造一如上所述之淨化塞體的方法包括下列步驟:(a)提供一工具,其腔室界定淨化塞體沿著一中心縱向軸線(X1)而延伸之長形本體的體積;(b)在此工具中之一與通道狹縫之所要位置對應之位置處安置至少一箔片,其在本方法之加熱步驟(d)進行期間可被移除;此箔片在其表面上具有多個孔,並在此諸孔之間界定一從其與通道氣體入口相對應的第一端部至其與氣體出口相對應的第二對立端部之連續路徑;(c)在此具有該箔片之工具中澆鑄一可鑄造性成分;(d)以一足以硬化耐火材料並消除箔片之溫度加熱一淨化塞體。根據本發明所實施之方法的特徵在於:該等孔具有一凹形幾何形狀以使其凹側被定位朝向一與該通道氣體出口相對應之第一箔片部分,並被配置成交錯型態以致使任一從第一箔片部分起伸展至一與該通道之通道氣體入口相對應之對立第二箔片部分處之最短線條必然會攔截到至少一孔之凹側。 The invention also relates to a metallurgical vessel comprising a purge plug body as described above, wherein the gas outlet is in fluid communication with the interior of the vessel; and a method for making such a purge plug body. The method for manufacturing a purge plug as described above comprises the steps of: (a) providing a tool having a chamber defining a volume of the elongated body extending the cleaning plug body along a central longitudinal axis (X1); (b) at least one foil is placed at a position corresponding to the desired position of the channel slit in one of the tools, which may be removed during the heating step (d) of the method; the foil is on its surface Having a plurality of apertures and defining a continuous path between the apertures from a first end thereof corresponding to the passage gas inlet to a second opposite end thereof corresponding to the gas outlet; (c) having The foil tool casts a castable component; (d) heats a purge plug at a temperature sufficient to harden the refractory material and eliminate the foil. The method according to the invention is characterized in that the holes have a concave geometry such that their concave sides are positioned towards a first foil portion corresponding to the gas outlet of the passage and are configured in a staggered configuration. The shortest line at any of the opposing second foil portions extending from the first foil portion to a channel gas inlet of the passage necessarily intercepts the concave side of at least one of the holes.
在一較佳實施例中,該工具的一部分變成此淨化塞體的一部分以作為一包覆耐火材料之周圍表面的金屬鑄件。製造一淨化塞體需要一個以上的這類箔片,此取決 於諸狹縫之所要幾何形狀。此(諸)箔片在加熱步驟(d)進行期間可藉由熔化、焚化、或昇華而被移除。加熱步驟(d)可包括一用於乾燥淨化塞體的步驟。例如,此乾燥步驟可包括:一漸次增溫次步驟;一停駐次步驟(例如在一介於300℃至650℃間歷經3至10小時的溫度下)以便可從耐火材料中實質地去除游離水,並燒掉一塑膠箔片;及一漸次冷卻次步驟。或者,加熱步驟(d)可包括一起火步驟。例如,此起火步驟可包括:一漸次增溫次步驟;一停駐次步驟(例如在一介於1200℃至1700℃間歷經3至10小時的溫度下)以便可在耐火材料中形成一陶瓷黏結,並燒掉一塑膠箔片;及一漸次冷卻次步驟。 In a preferred embodiment, a portion of the tool becomes part of the purge plug body as a metal casting covering the surrounding surface of the refractory material. More than one such foil is required to make a clean plug, depending on The desired geometry of the slits. The foil(s) may be removed by melting, incineration, or sublimation during the heating step (d). The heating step (d) may comprise a step of drying the plug body. For example, the drying step can include: a step of gradually increasing the temperature; a step of stopping the station (for example, at a temperature between 300 ° C and 650 ° C for 3 to 10 hours) so that the free removal can be substantially removed from the refractory material. Water, and burn off a plastic foil; and a step of cooling down. Alternatively, the heating step (d) may comprise a simultaneous fire step. For example, the igniting step may include: a step of gradually increasing the temperature; and a step of stopping the station (for example, at a temperature between 1200 ° C and 1700 ° C for 3 to 10 hours) so that a ceramic bond can be formed in the refractory material. And burn off a plastic foil; and a step of cooling down.
在本方法之另一實施例中,一界定一內部空間的外部層可先被形成。一箔片接著在步驟(b)中被插入該外部層之內部空間,且一心部然後在步驟(c)中被鑄造於由該箔片所界定之內部空間的其餘部分中。一箔片可在步驟(b)中被包裹在該心部周圍,且一外部層接著在步驟(c)中被鑄造於被界定在該腔室與被包裹在心部周圍的該箔片間之體積中。憑藉此技術,將可產出一種淨化塞體,其包括一具有與鞘部不同之多孔性的心部,而此心部與此鞘部間相隔一環狀狹縫。 In another embodiment of the method, an outer layer defining an interior space may be formed first. A foil is then inserted into the interior space of the outer layer in step (b), and a core is then cast in step (c) into the remainder of the interior space defined by the foil. A foil may be wrapped around the core in step (b), and an outer layer is then cast in step (c) between the chamber and the foil wrapped around the core. In the volume. By virtue of this technique, a purified plug body can be produced which includes a core having a porosity different from that of the sheath, and the core is separated from the sheath by an annular slit.
如第1圖中可見的,一根據本發明所實施之淨化塞體(1)包括一本體,其沿著一縱向軸線(X1)延伸於一位於此本體之一第一端部處的氣體入口(3a)與一位於此本體之一相對端部處的氣體出口(3b)之間;沿著此縱向軸 線,氣體入口(3a)經由至少一呈通道(3)形狀之狹縫而與此氣體出口(3b)形成流體連通。此狹縫形狀之通道係由第一通道表面及相對之第二通道表面所界定,而此兩表面相隔之距離則界定此通道狹縫(3)之開口寬度W。此通道之開口長度L係一段距離,其與開口寬度W整合時產生一與縱向軸線(X1)成垂直之切口區域(參第4c圖)。在一如第1圖中所示之環狀狹縫的情形中,此狹縫之開口長度L係此環狀狹縫之周長。在一如第4c圖中所示之平面狀狹縫的情形中,狹縫之開口長度L就是其長度。一狹縫形狀之通道被界定成一具有一開口寬度W之通道,而此寬度則遠小於此通道之開口長度L。具體而言,一通道被視為是狹縫形狀,如果長度對寬度比係L/W≧3,較佳地L/W≧5,更佳地L/W≧10及甚至L/W≧50。(諸)通道狹縫在此淨化塞體之本體內的幾何形狀與配置對本發明而言並非重要的,只要是通道便可被視為狹縫形狀者。 As can be seen in Figure 1, a purification plug body (1) according to the invention comprises a body extending along a longitudinal axis (X1) to a gas inlet at a first end of one of the bodies (3a) between a gas outlet (3b) at one end opposite one of the bodies; along the longitudinal axis The line, gas inlet (3a) is in fluid communication with the gas outlet (3b) via at least one slit in the shape of a channel (3). The slit-shaped passage is defined by the first passage surface and the opposite second passage surface, and the distance between the two surfaces defines the opening width W of the passage slit (3). The opening length L of this passage is a distance which, when integrated with the opening width W, produces a slit region perpendicular to the longitudinal axis (X1) (see Figure 4c). In the case of the annular slit as shown in Fig. 1, the opening length L of the slit is the circumference of the annular slit. In the case of a planar slit as shown in Fig. 4c, the opening length L of the slit is its length. A slit-shaped passage is defined as a passage having an opening width W which is much smaller than the opening length L of the passage. Specifically, one channel is regarded as a slit shape, and if the length to width ratio is L/W ≧ 3, preferably L/W ≧ 5, more preferably L/W ≧ 10 and even L/W ≧ 50 . The geometry and configuration of the channel slits in the body of the purge plug is not critical to the invention, as long as it is a channel shape.
本發明必不會完全防止熔融金屬意外地滲入諸通道內,但其可強力地限制此類滲入之深度;具體而言,儘管有局部之深入,仍允許此塞體可運作。此係藉由使用一系列連續之凹形橋體(4),其連接界定通道之第一表面及第二相對表面,使得其等之凹側(4a)可朝向氣體出口(3b)。各凹形橋體因此可作為一小型保持槽,其可補獲並保留某一量之已滲入通道內的溶融金屬。諸凹形橋體(4)被相互隔開並配置成交錯之型態,以致使得此通道之任一從氣體出口(3b)延展至氣體入口(3a)之第一最短線 條將必然會攔截至少一第一橋體(41)之凹側(4a)。此通道之一「從氣體出口延展至氣體入口之最短線條」將遵循熔融金屬之流動方向,假使此由重力所驅動之熔融金屬滲入一不具凹形橋體之狹縫狀通道。因為此最短線條將必然會攔截至少一第一橋體(41),故熔融金屬(10)之流動將被此至少一橋體擋止,直到由此至少一橋體之凹側所形成之容器被填滿金屬為止。諸凹形橋體被相互分開以便提供一連續之氣體路徑,藉此使得經加壓氣體可從氣體入口(3a)流至氣體出口(3b)。介於任兩個相鄰橋體間之間隙可被填充以一位於前述兩橋體下游處之橋體,其中在本文中「下游」一詞係相對於熔融金屬流動之方向(其相反於氣體流動之方向)而被定義。 The present invention must not completely prevent the molten metal from inadvertently penetrating into the channels, but it can strongly limit the depth of such penetration; in particular, it allows the plug to operate despite partial depth. This is accomplished by the use of a series of continuous concave bridges (4) that define a first surface and a second opposing surface defining the passage such that its concave side (4a) can face the gas outlet (3b). Each concave bridge can thus act as a small retaining groove that can replenish and retain a certain amount of molten metal that has penetrated into the passage. The concave bridges (4) are spaced apart from each other and arranged in a staggered configuration such that either of the passages extends from the gas outlet (3b) to the first shortest line of the gas inlet (3a) The strip will necessarily intercept the concave side (4a) of at least one of the first bridge bodies (41). One of the channels "the shortest line extending from the gas outlet to the gas inlet" will follow the direction of flow of the molten metal, provided that the molten metal driven by gravity penetrates into a slit-like passage that does not have a concave bridge. Since the shortest line will inevitably intercept at least one first bridge body (41), the flow of molten metal (10) will be blocked by the at least one bridge body until the container formed by the concave side of at least one of the bridge bodies is filled Full of metal. The concave bridges are separated from each other to provide a continuous gas path whereby pressurized gas can flow from the gas inlet (3a) to the gas outlet (3b). The gap between any two adjacent bridges may be filled with a bridge located downstream of the two bridges, wherein the term "downstream" is used herein to refer to the direction of flow of the molten metal (which is opposite to the gas) The direction of flow) is defined.
被如此交錯以致使任一從氣體出口(3b)延展至氣體入口(3a)之最短線條可確實攔截一凹形橋體的一整組凹形橋體將界定一「補集等級」,N=1。就理論而言以及端視各個凹形橋體可包含之液態金屬量而定地,一包括補集等級N=1之淨化塞體將足以至少部分地保留住金屬流。實際上,較佳地係將補集等級之數目增加至較高值以便減少洩漏之風險。從氣體出口(3b)延展至氣體入口(3a)之補集等級的總數界定「補集度N」。一旦攔截熔融金屬流之至少一橋體(41)被填滿金屬,此熔融金屬將在此橋體之任一側上溢流,,並進一步遵循該最短路線流動至氣體入口(3a)。如上所討論的,一具有補集度為1(N=1)之淨化塞體在小熔融金屬流的情形下可能足以完全擋止此熔融金屬流以便節制滲入之程度,但在發生會導 致橋體(41)溢流之較大滲入情形時,將沒有另外之保留裝置可從該橋體下游處減緩及擋止此流動。為此緣故,本發明之淨化塞體較佳地包括一大於1之補集度(N≧1),較佳地至少2(N≧2),較佳地至少3(N≧3),更佳地至少5(N≧5),最佳地至少10(N≧10)。 The entire set of concave bridges that are so staggered such that any shortest line extending from the gas outlet (3b) to the gas inlet (3a) can indeed intercept a concave bridge will define a "complement level", N = 1. Theoretically, and depending on the amount of liquid metal that each concave bridge can contain, a purge plug comprising a complement level N = 1 will be sufficient to at least partially retain the metal flow. In practice, it is preferred to increase the number of complement levels to a higher value in order to reduce the risk of leakage. The total number of complement levels extended from the gas outlet (3b) to the gas inlet (3a) defines "replenishment N". Once at least one of the bridges (41) intercepting the flow of molten metal is filled with metal, the molten metal will overflow over either side of the bridge and further follow the shortest route to the gas inlet (3a). As discussed above, a purge plug having a degree of complementation of 1 (N = 1) may be sufficient to completely block the flow of molten metal in order to control the extent of penetration in the case of a small flow of molten metal, but in the event of a conduction In the event of a large infiltration of the bridge body (41) overflow, there will be no additional retaining means to slow and stop this flow from downstream of the bridge. For this reason, the purification plug body of the present invention preferably includes a degree of complementation (N≧1) greater than 1, preferably at least 2 (N≧2), preferably at least 3 (N≧3), more Preferably at least 5 (N≧5), optimally at least 10 (N≧10).
如第3圖所示,一大於1之補集度N可用一交錯配置而被獲得,其中任何從被第一最短線條所攔截之第一橋體(41)的任一側伸展至通道之氣體入口(3a)之第二最短線條必然攔截至少一第二橋體(42)之凹側(4a)且依此類推,其中任何從一被一第(i-1)最短線條所攔截之第(i-1)橋體(4(i-1))的任一側起伸展至該通道之氣體入口(3a)處之第i最短線條必然攔截到至少一第i橋體(4i)之凹側(4a),直到第N橋體及氣體入口(3a)之間已無任何橋體為止。 As shown in Fig. 3, a degree of complementation N greater than one may be obtained in a staggered configuration in which any gas extending from either side of the first bridge (41) intercepted by the first shortest line to the channel The second shortest line of the entrance (3a) necessarily intercepts the concave side (4a) of at least one second bridge (42) and so on, any of which is intercepted by a shortest line of (i-1) I-1) The i-th shortest line extending from either side of the bridge body (4(i-1)) to the gas inlet (3a) of the channel necessarily intercepts the concave side of at least one i-th bridge body (4i) (4a) until there is no bridge between the Nth bridge and the gas inlet (3a).
凹形橋體可具有多種形狀、大小及分布,只要:(a)此橋體適於在其凹部保留一給定量之熔融金屬,並因此形成一橫跨過狹縫之全寬及橫跨過介於其兩端部間之全長的不滲透壁,(b)此橋體之交錯配置不會讓一最短自由流動線條從氣體出口(3b)延展至氣體入口(3a),及(c)此橋體之分布可界定一從氣體入口(3a)至氣體出口(3b)並產生一可接受壓力降之氣體流動路徑。 The concave bridge body can have a variety of shapes, sizes, and distributions as long as: (a) the bridge body is adapted to retain a given amount of molten metal in its recess and thereby form a full width across the slit and across a full-length impermeable wall between the ends thereof, (b) the staggered arrangement of the bridges does not allow a shortest free-flowing line to extend from the gas outlet (3b) to the gas inlet (3a), and (c) The distribution of the bridge body defines a gas flow path from the gas inlet (3a) to the gas outlet (3b) and produces an acceptable pressure drop.
第2圖顯示多個適用於本發明之凹形橋體之幾何形狀的可行實施例。例如,此橋體可為一U形、一V形、一較佳為圓或橢圓之弧形、一敞開之矩形或方形盒體、 一拋物線等之形狀。此幾何形狀並不必然要「規則」,只要其包括一可界定一保持槽之凹側(4a)。一相同之淨化塞體可包括多個具有不同幾何形狀及/或大小並被分布在其(諸)狹縫通道上之橋體,且其等之分布亦可在一相同塞體之狹縫內或兩狹縫之間變化。 Figure 2 shows a possible embodiment of a plurality of geometric shapes suitable for use with the concave bridge of the present invention. For example, the bridge body can be a U-shape, a V-shape, a curved shape, preferably a circle or an ellipse, an open rectangular or square box, A shape such as a parabola. This geometry is not necessarily "rule" as long as it includes a concave side (4a) that defines a retaining groove. An identical purification plug body may include a plurality of bridge bodies having different geometries and/or sizes and distributed over the slit passages thereof, and the distribution thereof may also be in the slit of the same plug body. Or change between the two slits.
諸狹縫通道(3)可具有複數種幾何形狀。例如,第4圖顯示多種淨化塞體之實施例,其包括多個被不同地配置在一與縱向軸線(X1)成垂直之平面上的狹孔。第4(a)及(b)圖顯示兩個實施例,其中一及兩通道各別地環繞縱向軸線(X1),因此界定一以形成通道(3)之狹縫而與一環繞層(2b)相隔開之心部(2a)。兩個以上之環繞通道可被使用,且顯然其等並不需是如第4(a)及(b)圖所示之圓形,而是可具有任何之形狀、曲線或多邊形狀,其形成一閉迴路或不是像第4(e)圖所示之星形設計者。第4(c)及(d)圖顯示兩個實施例,其中狹縫並不形成一閉迴路。在此諸經顯示之實施例中,諸狹縫係呈直線的且被配置成從橫斷面之中心起徑向地延伸(參第4(c)圖)或彼此相互平行地延伸(參第4(d)圖)。再者,當諸直線狹縫被顯示於第4(c)及(d)圖中時,顯然其等可如第4(e)圖所示般為彎曲及/或鋸齒形狀。 The slit channels (3) can have a plurality of geometric shapes. For example, Figure 4 shows an embodiment of a plurality of purge plugs comprising a plurality of slits that are differently disposed in a plane perpendicular to the longitudinal axis (X1). Figures 4(a) and (b) show two embodiments in which one and two channels individually surround the longitudinal axis (X1), thus defining a slit to form the channel (3) with a surrounding layer (2b) ) separated by the heart (2a). More than two surround channels can be used, and obviously they need not be circular as shown in Figures 4(a) and (b), but can have any shape, curve or polygon shape, which forms A closed loop is not a star designer as shown in Figure 4(e). Figures 4(c) and (d) show two embodiments in which the slit does not form a closed loop. In the illustrated embodiments, the slits are linear and are configured to extend radially from the center of the cross-section (see Figure 4(c)) or extend parallel to each other (see paragraph 4(d) Figure). Further, when the linear slits are displayed in the fourth (c) and (d) drawings, it is apparent that they may be curved and/or sawtooth shapes as shown in Fig. 4(e).
(諸)狹縫通道從氣體入口(3a)沿縱向軸線(X1)延伸至位於相對端部處之氣體出口(3b)。諸通道可大致平行或不平行於縱向軸線(X1)而延伸。在第1圖中所示之實施例中,通道(3)並不平行於縱向軸線,且遵循一錐體之母線的方向,而此錐體與該淨化塞體之外側本體共有相 同之頂點。在通道配置係如第4(c)及(d)圖中所示之情形中,雖非強制但較適合使通道成平行於縱向軸線(X1)而延伸。通道可成直線地延伸於氣體入口及出口之間或可為彎曲的。後一個實施例可被期盼或可為一在不佳控制下作業之結果,其中被用以形成通道(3)之箔片(23)在作業期間將會變形或起皺。 The slit channels extend from the gas inlet (3a) along the longitudinal axis (X1) to the gas outlet (3b) at the opposite ends. The channels may extend substantially parallel or non-parallel to the longitudinal axis (X1). In the embodiment shown in Figure 1, the channel (3) is not parallel to the longitudinal axis and follows the direction of the busbar of a cone which shares a phase with the outer body of the purification plug body The same vertex. In the case where the channel configuration is as shown in Figures 4(c) and (d), it is not mandatory but it is more suitable to extend the channel parallel to the longitudinal axis (X1). The passage may extend linearly between the gas inlet and outlet or may be curved. The latter embodiment can be expected or can be the result of a job under poor control wherein the foil (23) used to form the channel (3) will deform or wrinkle during operation.
一狹縫通道(3)之開口寬度W可在縱向方向上以及沿著開口長度L而變化,但較簡單製造的是一種具有一恆定寬度W之狹縫通道(3),此將在下文中可察知。憑藉在本發明中所提議之幾何形狀,此狹縫通道可具有一比在本藝中一般認為可做為用來消除淨化塞體因熔融金屬滲入而遭嚴重損壞風險之安全防護者更大之寬度W。具體而言,寬度達2mm之狹縫通道可與本發明共同運作。然而,此通道之寬度較佳地係不大於1.5mm,更佳地係不大於1.0mm,及最佳地係不大於0.5mm。 The opening width W of a slit channel (3) can vary in the longitudinal direction and along the length L of the opening, but a simpler fabrication is a slit channel (3) having a constant width W, which will be hereinafter Know. By virtue of the geometry proposed in the present invention, the slit channel can have a greater degree of safety than would normally be considered as a safety shield for eliminating the risk of severe damage to the plug body due to molten metal infiltration. Width W. In particular, slit channels having a width of up to 2 mm can operate in conjunction with the present invention. However, the width of the passage is preferably no greater than 1.5 mm, more preferably no greater than 1.0 mm, and most preferably no greater than 0.5 mm.
被用於製造此淨化塞體之本體的耐火材料較佳地係至少部分地由一種對氣體具有相當低滲透性之材料所製成。一種耐火材料被認為是對氣體具有相當低滲透性,如果其滲透性係小於4 μm2(相當於40 nPm)。如果淨化塞體的本體係整個由一種對氣體具有相當低滲透性之耐火材料所製成,則此淨化塞體界定一如前所界定之「直接滲透性」系統。一混合之「直接/間接滲透性」系統可藉由使用一種對氣體具有比本體部分之4 μm2還高之滲透性的耐火材料而被獲得。例如,在第1與4(a)及(b)圖中所示之心部/鞘部幾何形狀中,此心部可由一種具有第一 滲透性之耐火材料所製成,而環繞之鞘部則由一種具有第二滲透性(其係高於或低於心部之滲透性)之耐火材料所製成。例如,諸如氧化鋁、鋁碳或尖晶石、及其他類似者之耐火材料可被使用(如有,可供具滲透性及無滲透性(或具有一相當低氣體滲透性)材料用)。 The refractory material used to make the body of the purge plug is preferably at least partially made of a material that has a relatively low permeability to the gas. A refractory material is considered to have a relatively low permeability to gases if its permeability is less than 4 μm 2 (equivalent to 40 nPm). If the system for purifying the plug body is made entirely of a refractory material having a relatively low permeability to the gas, the purge plug body defines a "direct permeability" system as previously defined. A mixed "direct/indirect permeability" system can be obtained by using a refractory material having a gas permeability higher than that of the bulk portion of 4 μm 2 . For example, in the core/sheath geometry shown in Figures 1 and 4(a) and (b), the core may be made of a refractory material having a first permeability and surrounding the sheath. It is made of a refractory material having a second permeability which is higher or lower than the permeability of the core. For example, refractory materials such as alumina, aluminum carbon or spinel, and the like can be used (if available, for materials that are permeable and non-permeable (or have a relatively low gas permeability)).
諸圖式中所示之淨化塞體雖為截頭圓錐狀,但本發明當然並不限於如此之幾何形狀,其可取決於冶金線之設計而變化。一如前所述由耐火材料所製之心部的周圍表面經常被覆蓋一金屬殼體以便藉機械方式強化結構。在一些實施例中,此金屬殼體在製造淨化塞體之過程中可被使用作為由耐火材料所鑄成之模子的一部分。在一可替代實施例中,金屬殼體係經由黏著劑或水泥而被連結至一已完全製成之耐火本體上。 Although the purge plug shown in the figures is frustoconical, the invention is of course not limited to such a geometry, which may vary depending on the design of the metallurgical line. The peripheral surface of the core portion made of refractory material as described above is often covered with a metal casing to mechanically strengthen the structure. In some embodiments, the metal housing can be used as part of a mold cast from a refractory material during the manufacture of the purge plug. In an alternative embodiment, the metal casing is joined to a fully fabricated refractory body via an adhesive or cement.
一根據本發明所實施之淨化塞體可非常簡單地只用一包括下列步驟之方法而被製成:(a)提供一工具(21),其腔室(22)界定淨化塞體沿著一中心縱向軸線(X1)而延伸之長形本體(2)的體積。在一較佳實施例中,此工具的一部分係由一可供以機械方式強化結構用之金屬殼體所製成,其將是最終淨化塞體成品之一部分;(b)如第6(a)圖所示,在此工具中之一與通道狹縫(3)之所要位置對應之位置處安置至少一箔片(23),其在本方法之加熱步驟(d)進行期間係可移除的;此箔片在其表面上具有多個孔(24),並在此諸孔之間界定一從其與通道氣體入口(3a)相對應的第一端部(23a) 至其與氣體出口(3b)相對應的第二對立端部(23b)之連續路徑;此箔片可由紙、卡紙、蠟或諸如PVC、PE或PP之聚合物材料所製成,並應足夠剛硬以免在作業期間本身彎摺、起皺或成波狀;(c)在此具有該箔片之工具中澆鑄一可鑄造性成分(25)(參照第6(b)圖);(d)以一足以硬化耐火材料並消除箔片之溫度加熱一淨化塞體(參照第6(c)圖);通常需要一大於300℃之溫度來硬化耐火材料;例如,一介於400℃與650℃之間的溫度,較佳介於450℃與550℃之間,通常足以硬化大部分耐火材料,並足以燃燒或至少熔化箔片,而此箔片之消除將產生一包含上述之諸交錯凹形橋體的狹縫狀通道。 A cleaning plug body according to the invention can be produced very simply by a method comprising the steps of: (a) providing a tool (21), the chamber (22) defining a cleaning plug body along a The volume of the elongate body (2) extending along the central longitudinal axis (X1). In a preferred embodiment, a portion of the tool is formed from a metal housing that can be used to mechanically reinforce the structure, which will be part of the final purified plug body; (b) as in item 6 (a) As shown in the figure, at least one foil (23) is placed at a position corresponding to the desired position of the channel slit (3), which is removable during the heating step (d) of the method. The foil has a plurality of holes (24) on its surface and defines a first end (23a) from the holes corresponding to the channel gas inlet (3a) a continuous path to the second opposite end portion (23b) corresponding to the gas outlet (3b); the foil may be made of paper, cardboard, wax or a polymer material such as PVC, PE or PP, and Sufficiently rigid to avoid bending, wrinkling or wavy itself during operation; (c) casting a castable component (25) in the tool having the foil (see Figure 6(b)); d) heating a clean plug body at a temperature sufficient to harden the refractory material and eliminate the foil (see Figure 6(c)); typically a temperature greater than 300 ° C is required to harden the refractory material; for example, one between 400 ° C and 650 The temperature between ° C, preferably between 450 ° C and 550 ° C, is generally sufficient to harden most of the refractory material and is sufficient to burn or at least melt the foil, and the elimination of the foil will produce a staggered concave shape comprising the above A slit-like passage of the bridge body.
本發明之方法的特徵在於:諸孔(24)具有一凹形之幾何形狀以使得其凹側(24a)被定位成朝向一與通道氣體出口(3b)相對應之第二箔片部分(23b),並被配置成交錯型態以便使得任何從第二箔片部分(23b)起伸展至一與通道氣體入口(3a)相對應之對立第一箔片部分(23a)處之最短線條必然會攔截到至少一孔(24)之凹側(24a)。 The method of the invention is characterized in that the holes (24) have a concave geometry such that their concave sides (24a) are positioned towards a second foil portion (23b) corresponding to the passage gas outlet (3b) And configured to be staggered so that any shortest line extending from the second foil portion (23b) to a opposing first foil portion (23a) corresponding to the channel gas inlet (3a) is bound to The concave side (24a) of at least one hole (24) is intercepted.
箔片(24)之厚度界定一在此箔片消除時所形成之狹縫通道的寬度W。當可鑄性耐火材料(25)填滿諸孔並因此連接位於箔片(23)任一側上之耐火材料時,在此箔片(23)中之諸孔(24)可供形成跨越此狹縫通道之寬度W的諸凹形橋體(4)。在此箔片消除後,多個由耐火材料所製之橋體(4)立即被形成,其具有與此箔片之諸孔相同之外 廓,且具有與此箔片相同之寬度W。 The thickness of the foil (24) defines a width W of the slit channel formed when the foil is removed. When the castable refractory (25) fills the holes and thus joins the refractory material on either side of the foil (23), the holes (24) in the foil (23) are available to form across Concave bridges (4) of the width W of the slit channels. After the foil is removed, a plurality of bridges (4) made of refractory material are immediately formed, which have the same holes as the foils. Profile, and has the same width W as this foil.
如第7圖所示,在另一實施例中,一心部(2a)在步驟(b)之前先被形成(參照第7(b)圖),其週圍包裹以該箔片(23)(參照第7(c)及(d)圖)。在步驟(c)中,一外部層接著被鑄造於一被界定於腔室(21)與被包裹在心部(2a)周圍之箔片(23)間的體積中(參照第7(e)圖)。在加熱之後,該淨化塞體可被從工具處移除。此實施例適於用來製造混合式「直接/間接滲透性」塞體,其中形成心部並環繞在本體鞘部周圍之耐火材料具有一不同之成分及/或孔隙率。 As shown in Fig. 7, in another embodiment, a core portion (2a) is formed before step (b) (refer to Fig. 7(b)), and the foil (23) is wrapped around it (refer to Figures 7(c) and (d)). In step (c), an outer layer is then cast into a volume defined between the chamber (21) and the foil (23) wrapped around the core (2a) (see Figure 7(e) ). After heating, the purge plug can be removed from the tool. This embodiment is suitable for use in the manufacture of a hybrid "direct/indirect permeability" plug body in which the refractory material forming the core and surrounding the body sheath has a different composition and/or porosity.
本淨化塞體(1)尤其適於將氣體注射入一澆斗、一喂槽以及其他類似之冶金容器內。此塞體可被安置在如第5圖中所示該類冶金容器之底部地板處,此處正是對熔融金屬之滲入最敏感。幸虧由對滲入氣體通道(3)內之深度形成一屏障的多個保持凹形橋體(4)所構成之陣列,使得此淨化塞體之使用壽命與現存之淨化塞體相比較已被實質地增加了。此外,較寬通道將可比傳統者被更安全地使用,因為相對照於傳統淨化塞體,熔融金屬的較少滲入將不會造成塞體性能的實質下降。確實,在硬化時除了將滲入之區域與深度控制在有限數量之填滿金屬的橋體外,雖然金屬仍填充一些橋體的凹側,但連接一橋體與下一位於下游處之橋體的金屬突舌經常會斷掉,因此使得氣體甚至可流動在兩個填滿金屬的橋體之間。 The purge plug (1) is particularly suitable for injecting gas into a bucket, a feed tank, and other similar metallurgical vessels. This plug body can be placed at the bottom floor of the metallurgical vessel as shown in Figure 5, where it is most sensitive to the infiltration of molten metal. Fortunately, an array of a plurality of retaining concave bridges (4) forming a barrier to the depth of the gas passage (3) allows the service life of the purge plug to be substantially compared with the existing purge plug body. The land has increased. In addition, wider channels will be safer to use than conventional ones, as less penetration of molten metal will not result in a substantial drop in plug performance compared to conventional purge plugs. Indeed, in hardening, in addition to controlling the infiltrated area and depth to a limited number of metal-filled bridges, although the metal still fills the concave side of some of the bridges, the metal that connects the bridge to the next downstream bridge The tabs are often broken, so that the gas can even flow between the two metal-filled bridges.
1‧‧‧淨化塞體 1‧‧‧ Purified plug body
2‧‧‧本體 2‧‧‧ Ontology
2a‧‧‧心部 2a‧‧‧heart
2b‧‧‧環繞層 2b‧‧‧ wrapping layer
3‧‧‧通道 3‧‧‧ channel
3a‧‧‧氣體入口 3a‧‧‧ gas inlet
3b‧‧‧氣體出口 3b‧‧‧ gas export
4‧‧‧橋體 4‧‧‧ Bridge body
4a‧‧‧凹側 4a‧‧‧ concave side
10‧‧‧熔融金屬 10‧‧‧ molten metal
11‧‧‧氣體動方向 11‧‧‧ Gas direction
21‧‧‧工具 21‧‧‧ Tools
22‧‧‧腔室 22‧‧‧ chamber
23‧‧‧箔片 23‧‧‧Foil
23a‧‧‧第一端部 23a‧‧‧First end
23a‧‧‧第一箔片部分 23a‧‧‧First foil section
23b‧‧‧第二端部 23b‧‧‧second end
23b‧‧‧第二箔片部分 23b‧‧‧Second foil section
24‧‧‧孔 24‧‧‧ hole
24a‧‧‧凹側 24a‧‧‧ concave side
41‧‧‧第一橋體 41‧‧‧First Bridge
L‧‧‧長度 L‧‧‧ length
W‧‧‧寬度 W‧‧‧Width
X1‧‧‧縱向軸線 X1‧‧‧ longitudinal axis
本發明之各種不同實施例被顯示說明於下列之諸附 圖中:第1圖顯示一根據本發明所實施之淨化塞體的立體圖,其具有一用於顯示諸凹形橋體之部分切除區域;第2圖顯示多個根據本發明所實施之凹形橋體之幾何形狀的各種實施例;第3圖顯示一根據本發明所實施之橋體陣列,其顯示一熔融金屬之流動路徑,以及多條將氣體入口連接至氣體出口或至一第n橋體處之最短線條;第4圖顯示與縱向軸線(X1)成垂直之多種橫截面,其顯示不同之狹縫通道形狀;第5圖顯示一被安裝在一冶金容器之底部地板上的淨化塞體。 Various embodiments of the invention are shown in the following In the drawings: Figure 1 shows a perspective view of a cleaning plug body according to the invention having a partially cut-away area for displaying concave bridges; Figure 2 shows a plurality of concave shapes according to the invention. Various embodiments of the geometry of the bridge; Figure 3 shows a bridge array implemented in accordance with the present invention showing a flow path of molten metal and a plurality of gas inlets connected to the gas outlet or to an nth bridge The shortest line in the body; Figure 4 shows a variety of cross sections perpendicular to the longitudinal axis (X1) showing different slit channel shapes; Figure 5 shows a cleaning plug mounted on the bottom floor of a metallurgical vessel body.
第6圖示意地顯示用於製造一根據本發明所實施之淨化塞體之第一實施例的多個不同步驟;及第7圖示意地顯示用於製造一根據本發明所實施之淨化塞體之第二實施例的多個不同步驟。 Figure 6 is a schematic illustration of a plurality of different steps for fabricating a first embodiment of a purge plug body implemented in accordance with the present invention; and Figure 7 is a schematic representation of a purge plug body for use in the manufacture of a purification plug body according to the present invention. A number of different steps of the second embodiment.
本發明並不限於諸圖中所示之諸實施例。因此,應理解的是,在被提及於後附之申請專利範圍中之諸特徵被隨後標記以參考符號處,此類符號將僅被包含用以加強申請專利範圍之可理解性,而並非用以限制申請專利範圍。 The invention is not limited to the embodiments shown in the figures. Therefore, it is to be understood that the features of the appended claims are to be Used to limit the scope of patent applications.
1‧‧‧淨化塞體 1‧‧‧ Purified plug body
2‧‧‧本體 2‧‧‧ Ontology
2a‧‧‧心部 2a‧‧‧heart
2b‧‧‧環繞層 2b‧‧‧ wrapping layer
3‧‧‧通道 3‧‧‧ channel
3a‧‧‧氣體入口 3a‧‧‧ gas inlet
3b‧‧‧氣體出口 3b‧‧‧ gas export
4‧‧‧橋體 4‧‧‧ Bridge body
11‧‧‧氣體動方向 11‧‧‧ Gas direction
W‧‧‧寬度 W‧‧‧Width
X1‧‧‧縱向軸線 X1‧‧‧ longitudinal axis
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Cited By (2)
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CN105087869A (en) * | 2015-08-31 | 2015-11-25 | 濮阳濮耐高温材料(集团)股份有限公司 | Gas supply element, composite gas supply brick and manufacturing method of composite gas supply brick |
CN105087870A (en) * | 2015-08-31 | 2015-11-25 | 濮阳濮耐高温材料(集团)股份有限公司 | Blowing element, combined blowing brick and manufacturing method of combined blowing brick |
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Cited By (2)
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CN105087869A (en) * | 2015-08-31 | 2015-11-25 | 濮阳濮耐高温材料(集团)股份有限公司 | Gas supply element, composite gas supply brick and manufacturing method of composite gas supply brick |
CN105087870A (en) * | 2015-08-31 | 2015-11-25 | 濮阳濮耐高温材料(集团)股份有限公司 | Blowing element, combined blowing brick and manufacturing method of combined blowing brick |
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