TW201330919A - Chemical filter device for processing low-concentration carbon disulphide - Google Patents

Chemical filter device for processing low-concentration carbon disulphide Download PDF

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TW201330919A
TW201330919A TW101142110A TW101142110A TW201330919A TW 201330919 A TW201330919 A TW 201330919A TW 101142110 A TW101142110 A TW 101142110A TW 101142110 A TW101142110 A TW 101142110A TW 201330919 A TW201330919 A TW 201330919A
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Taiwan
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activated carbon
filter
low concentration
contaminant
carbon
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TW101142110A
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Chinese (zh)
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feng-tang Zhang
hong-min Jian
Kai-Jun Nian
kun-lin Cai
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Jg Environmental Tech Co Ltd
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Publication of TW201330919A publication Critical patent/TW201330919A/en

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Abstract

The invention relates to a chemical filter device for processing low-concentration carbon disulphide. The chemical filter device includes a side frame and at least one filter nets disposed in the side frame in the form of a V-shaped crease pattern. The filter net has a V-shaped crease angle which is preferably in the range from 30 DEG to 40 DEG, better of 33 DEG. A coal-based activated carbon is utilized as a filter material for the filter net, in particular a smokeless coal-based activated carbon is utilized. Accordingly, the low-concentration of carbon disulfide at which an adverse effect can be solved, and the treatment effects for low-concentration carbon disulphide can be enhanced.

Description

處理含有低濃度二硫化碳污染物的化學過濾裝置Treatment of chemical filtration devices containing low concentrations of carbon disulfide contaminants

本發明係有關一種處理含有低濃度二硫化碳污染物的化學過濾裝置,尤指一種將濾網設計為V形皺摺狀之態樣,且採用煤基活性碳作為濾材之設計者。The present invention relates to a chemical filtration device for treating pollutants containing low concentrations of carbon disulfide, and more particularly to a designer who designs a sieve into a V-shaped wrinkle and uses coal-based activated carbon as a filter material.

按,半導體廠為了提昇製程良率通常會於外氣空調箱及氣流循環區加裝一化學過濾裝置,用以處理無塵室內所含有的微污染物質(AMC:AirborneMolecular Contamination),進而降低含硫物質、酸性物質、鹼性物質及含低沸點之揮發性有機化合物(VOCs:Volatile OrganicCompounds)等微污染物質對於製程良率的影響性。In order to improve the process yield, the semiconductor factory usually installs a chemical filtering device in the external air-conditioning box and the air circulation area to treat the micro-pollution substances (AMC: Airborne Molecular Contamination) contained in the clean room, thereby reducing sulfur content. The influence of micro-pollutants such as substances, acidic substances, alkaline substances and volatile organic compounds (VOCs: Volatile Organic Compounds) on the process yield.

次按,沸點為46℃,水溶性不佳的純二硫化碳有類似氯仿的芳香甜味,但是二硫化碳一旦稍有不純就會混有其他硫化物(如羰基硫等)而變為微黃色,並且有令人不愉快的爛蘿蔔味;惟,對於含有低濃度(約數十ppb)二硫化碳的污染物,目前的化學過濾裝置所採用的濾材,對於低濃度二硫化碳的處理效果並不佳。Sub-press, the boiling point is 46 ° C, the poor water-soluble pure carbon disulfide has a chloroform-like aromatic sweetness, but once the carbon disulfide is slightly impure, it will be mixed with other sulfides (such as carbonyl sulfide) and become yellowish, and there are Unpleasant rotten radish flavor; however, for contaminants containing low concentrations (about tens of ppb) of carbon disulfide, the filter media used in current chemical filtration devices are not effective in treating low concentrations of carbon disulfide.

本發明之主要目的,係欲解決先前技術對於低濃度二硫化碳處理效果不佳之問題,而具有強化低濃度二硫化碳處理效果之功效。The main object of the present invention is to solve the problem that the prior art has a poor effect on the treatment of low-concentration carbon disulfide, and has the effect of enhancing the treatment effect of low-concentration carbon disulfide.

為達上述功效,本發明之結構特徵,係包括有:一邊框;以及至少一濾網,設置於該邊框內部,而該濾網採用煤基活性碳作為濾材者。In order to achieve the above effects, the structural features of the present invention include: a frame; and at least one screen disposed inside the frame, and the screen uses coal-based activated carbon as the filter material.

此外,該濾網為V形皺摺狀之態樣,而該濾網之V形皺摺夾角較佳為30°~40°,且該濾網之V形皺摺夾角更佳為33°。Further, the filter screen has a V-shaped pleated shape, and the V-shaped crease angle of the filter screen is preferably 30 to 40, and the V-shaped crease angle of the filter is preferably 33°.

再者,該濾網採用無煙煤基活性碳作為濾材;又,進一步令該濾網之濾材合成改質劑,而該改質劑為Cu-EDTA;另,進一步令該濾網之濾材含浸雙重改質劑,而該第一重改質劑為醋酸鋅或醋酸錳,該第二重改質劑為碳酸鉀或氫氧化鉀。Furthermore, the filter screen adopts anthracite-based activated carbon as a filter material; further, the filter material of the filter mesh is further synthesized into a modifier, and the modifier is Cu-EDTA; further, the filter medium of the filter mesh is further impregnated. And the first heavy reforming agent is zinc acetate or manganese acetate, and the second heavy modifying agent is potassium carbonate or potassium hydroxide.

首先,請參閱「圖1」、「圖2」所示,本發明係包括有:一邊框10;以及至少一濾網20,以V形皺摺狀之態樣設置於該邊框10內部,且該濾網20之V形皺摺夾角θ較佳為30°~40°,更佳為33°,而該濾網20採用煤基活性碳作為濾材,特別是採用無煙煤基活性碳作為濾材者。First, referring to FIG. 1 and FIG. 2, the present invention includes: a frame 10; and at least one screen 20 disposed inside the frame 10 in a V-shaped wrinkle shape, and The V-shaped wrinkle angle θ of the screen 20 is preferably 30° to 40°, more preferably 33°, and the screen 20 uses coal-based activated carbon as a filter material, particularly anthracite-based activated carbon as a filter material.

再者,進一步令該濾網20之濾材合成改質劑,該改質劑可為Cu-EDTA,而合成改質之程序為:(1)取乾燥過之活性碳測試吸水量(假設其吸水量為50克水/100克乾碳);(2)取硝酸銅(結晶水)360克溶於1公升去離子水中;(3)將2公斤之活性碳分批倒入硝酸銅溶液中,使其完全將硝酸銅溶液吸乾(此舉是要讓硝酸銅/活性碳=18 wt%),將含有硝酸銅之活性碳晾乾4小時;(4)取EDTA(乙二胺四乙酸)18克溶於1公升去離子水中;(5)將含有硝酸銅之活性碳倒入含EDTA之溶液中攪拌,然後靜置30分鐘後過濾;(6)將製備好之活性碳置於100度之烘箱中烘乾,烘乾時間4小時。【00010】 另者,進一步令該濾網20之濾材含浸雙重改質劑,該第一重改質劑可為醋酸鋅或醋酸錳,該第二重改質劑可為碳酸鉀或氫氧化鉀,而雙重含浸改質之程序為:第一重用868.5克的水溶解131.5克的醋酸鋅/醋酸錳(11%的醋酸鋅/醋酸錳溶液),加入活性碳浸泡40分鐘後過濾,得到第一次浸漬活性碳;第二重用1155克的水溶解345克的碳酸鉀/氫氧化鉀(23%碳酸鉀/氫氧化鉀溶液),加入第一次浸漬活性碳浸泡40分鐘後過濾,浸泡後活性碳置於100℃加熱爐烘乾至活性碳水份在2%以下,在最初半小時的乾燥過程中,活性碳需要不時的攪拌。【00011】 基於如是之構成,本發明將濾網20設計為V形皺摺狀之態樣,且採用煤基活性碳作為濾材,甚至是進一步將濾材合成改質或是雙重含浸改質,而可對污染物中所含有之低濃度二硫化碳更有效地處理,具有強化低濃度二硫化碳處理效果之功效。【00012】 綜上所述,本發明所揭示之技術手段,確具「新穎性」、「進步性」及「可供產業利用」等發明專利要件,祈請 鈞局惠賜專利,以勵發明,無任德感。【00013】 惟,上述所揭露之圖式、說明,僅為本發明之較佳實施例,大凡熟悉此項技藝人士,依本案精神範疇所作之修飾或等效變化,仍應包括在本案申請專利範圍內。Furthermore, the filter material of the filter screen 20 is further synthesized into a modifier, and the modifier can be Cu-EDTA, and the procedure for synthesizing the reform is: (1) taking the dried activated carbon to test the water absorption amount (assuming that it absorbs water The amount is 50 grams of water / 100 grams of dry carbon); (2) taking copper nitrate (crystal water) 360 grams dissolved in 1 liter of deionized water; (3) 2 kg of activated carbon is poured into the copper nitrate solution in batches, Make it completely dry the copper nitrate solution (this is to make copper nitrate / activated carbon = 18 wt%), dry the activated carbon containing copper nitrate for 4 hours; (4) take EDTA (ethylenediaminetetraacetic acid) 18 g is dissolved in 1 liter of deionized water; (5) the activated carbon containing copper nitrate is poured into a solution containing EDTA, stirred, and then allowed to stand for 30 minutes and then filtered; (6) the prepared activated carbon is placed at 100 degrees. Dry in the oven and dry for 4 hours. [00010] In addition, the filter medium of the filter screen 20 is further impregnated with a double modifier, the first reforming agent may be zinc acetate or manganese acetate, and the second heavy modifier may be potassium carbonate or potassium hydroxide. The procedure of double impregnation modification is as follows: firstly, 868.5 g of water is used to dissolve 131.5 g of zinc acetate/manganese acetate (11% zinc acetate/manganese acetate solution), and after soaking in activated carbon for 40 minutes, it is filtered to obtain the first Secondary impregnation of activated carbon; second reuse 1155 grams of water to dissolve 345 grams of potassium carbonate / potassium hydroxide (23% potassium carbonate / potassium hydroxide solution), added to the first impregnation of activated carbon for 40 minutes, filtered, soaked after activity The carbon is dried in a heating oven at 100 ° C until the activated carbon moisture is below 2%. During the first half hour of drying, the activated carbon needs to be stirred from time to time. [00011] Based on the configuration, the present invention designs the screen 20 into a V-shaped wrinkle, and uses coal-based activated carbon as a filter material, and even further synthesizes the filter material or doubles the impregnation, and It can treat the low concentration of carbon disulfide contained in the pollutants more effectively, and has the effect of strengthening the treatment effect of low concentration carbon disulfide. [00012] In summary, the technical means disclosed in the present invention have the invention patents such as "novelty", "progressiveness" and "available for industrial use", and pray for the patent to encourage the invention. There is no sense of morality. The above drawings and descriptions are merely preferred embodiments of the present invention, and those skilled in the art who are familiar with the art, the modifications or equivalent changes made according to the spirit of the present invention should still include the patent application in this case. Within the scope.

10...邊框10. . . frame

20...濾網20. . . Filter

【00014】 圖1係本發明之結構立體圖。圖2係本發明之濾網態樣示意圖。1 is a perspective view showing the structure of the present invention. Figure 2 is a schematic view of a mesh screen of the present invention.

10...邊框10. . . frame

20...濾網20. . . Filter

Claims (9)

一種處理含有低濃度二硫化碳污染物的化學過濾裝置,係包括有:一邊框;以及至少一濾網,設置於該邊框內部,而該濾網採用煤基活性碳作為濾材者。A chemical filtration device for treating a pollutant having a low concentration of carbon disulfide comprises: a frame; and at least one filter disposed inside the frame, and the filter uses coal-based activated carbon as a filter material. 如請求項1之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該濾網為V形皺摺狀之態樣。A chemical filtration device comprising a low concentration of carbon disulfide contaminant as claimed in claim 1, wherein the sieve is in the form of a V-shaped wrinkle. 如請求項2之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該濾網之V形皺摺夾角為30°~40°。A chemical filtration device comprising a low concentration of carbon disulfide contaminant as claimed in claim 2, wherein the filter has a V-shaped wrinkle angle of 30 to 40. 如請求項3之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該濾網之V形皺摺夾角為33°。A chemical filtration device comprising a low concentration of carbon disulfide contaminant as claimed in claim 3, wherein the filter has a V-shaped wrinkle angle of 33°. 如請求項1至4項任一項之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該濾網採用無煙煤基活性碳作為濾材。The chemical filtration device containing a low concentration of carbon disulfide contaminant is treated according to any one of claims 1 to 4, wherein the sieve uses anthracite-based activated carbon as a filter medium. 如請求項5之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,進一步令該濾網之濾材合成改質劑。A chemical filtration device comprising a low concentration of carbon disulfide contaminant as claimed in claim 5, wherein the filter material of the filter is further synthesized into a modifier. 如請求項5之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,進一步令該濾網之濾材含浸雙重改質劑。A chemical filtration device comprising a low concentration of carbon disulfide contaminant as claimed in claim 5, wherein the filter material of the filter is further impregnated with a double modifier. 如請求項6之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該改質劑為Cu-EDTA,而合成改質之程序為:(1)取乾燥過之活性碳;(2)取硝酸銅溶於去離子水中;(3)將活性碳分批倒入硝酸銅溶液中,使其將硝酸銅溶液吸乾,將含有硝酸銅之活性碳晾乾;(4)取EDTA(乙二胺四乙酸)溶於去離子水中;(5)將含有硝酸銅之活性碳倒入含EDTA之溶液中攪拌,然後靜置後過濾;(6)將製備好之活性碳置於烘箱中烘乾。The chemical filtering device containing the low concentration of carbon disulfide contaminant according to claim 6, wherein the modifying agent is Cu-EDTA, and the process of synthesizing the upgrading is: (1) taking the dried activated carbon; (2) taking The copper nitrate is dissolved in deionized water; (3) the activated carbon is poured into the copper nitrate solution in batches to dry the copper nitrate solution, and the activated carbon containing copper nitrate is dried; (4) taking EDTA (Ethylene) (Aminotetraacetic acid) is dissolved in deionized water; (5) The activated carbon containing copper nitrate is poured into a solution containing EDTA, stirred, and then left to be filtered; (6) The prepared activated carbon is dried in an oven. . 如請求項7之處理含有低濃度二硫化碳污染物的化學過濾裝置,其中,該第一重改質劑為醋酸鋅或醋酸錳,該第二重改質劑為碳酸鉀或氫氧化鉀,而雙重含浸改質之程序為:第一重用水溶解醋酸鋅/醋酸錳(11%的醋酸鋅/醋酸錳溶液),加入活性碳浸泡後過濾,得到第一次浸漬活性碳;第二重用水溶解碳酸鉀/氫氧化鉀(23%碳酸鉀/氫氧化鉀溶液),加入第一次浸漬活性碳浸泡後過濾,浸泡後活性碳置於加熱爐烘乾至活性碳水份在2%以下。The chemical filtering device for treating a low concentration of carbon disulfide contaminant according to claim 7, wherein the first heavy modifying agent is zinc acetate or manganese acetate, and the second heavy modifying agent is potassium carbonate or potassium hydroxide, and the double The procedure of impregnation modification is as follows: the first heavy water dissolves zinc acetate/manganese acetate (11% zinc acetate/manganese acetate solution), is immersed in activated carbon and filtered to obtain the first impregnation of activated carbon; the second heavy water dissolves carbonic acid Potassium/potassium hydroxide (23% potassium carbonate/potassium hydroxide solution), added to the first impregnated activated carbon soaked, filtered, and after soaking, the activated carbon is dried in a heating furnace until the activated carbon moisture is below 2%.
TW101142110A 2012-11-12 2012-11-12 Chemical filter device for processing low-concentration carbon disulphide TW201330919A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWD195394S (en) 2018-08-17 2019-01-11 明光電機有限公司 Part of a double-conducting special filter

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWD195394S (en) 2018-08-17 2019-01-11 明光電機有限公司 Part of a double-conducting special filter

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