TW201319242A - Device and process to feed renewable fuels into the area of the radiant boiler casing in gasification reactors - Google Patents

Device and process to feed renewable fuels into the area of the radiant boiler casing in gasification reactors Download PDF

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TW201319242A
TW201319242A TW101123139A TW101123139A TW201319242A TW 201319242 A TW201319242 A TW 201319242A TW 101123139 A TW101123139 A TW 101123139A TW 101123139 A TW101123139 A TW 101123139A TW 201319242 A TW201319242 A TW 201319242A
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gasification reactor
space
boiler casing
cooling
radiant boiler
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TW101123139A
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Chinese (zh)
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Norbert Ullrich
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Thyssenkrupp Uhde Gmbh
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • C10J3/487Swirling or cyclonic gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • C10J3/76Water jackets; Steam boiler-jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/86Other features combined with waste-heat boilers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1612CO2-separation and sequestration, i.e. long time storage
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1659Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1662Conversion of synthesis gas to chemicals to methane (SNG)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Abstract

The invention relates to a device to feed renewable fuels into the area of the radiant boiler casing of coal gasification reactors, which consist of a reaction space with burners arranged in the reaction space and a cool-down space, and the cool-down space is equipped with a radiant boiler casing for the cooling down and solidifying of the liquid slag, wherein, according to the invention the ring-shaped part of the cool-down space, in which the radiant boiler casing is arranged, is equipped with burners, which lead through the radiant boiler casing into the cool-down space, through which a renewable fuel can be introduced into the cool-down space. Through this device renewable fuel can be introduced through a radiant boiler casing into the cool-down space, which is located beneath the reaction space, so that the thermal enthalpy of the hot synthesis gas can also be used in the cool-down space for the post-gasification of renewable fuel. The invention also relates to a process for feeding renewable fuels through the radiant boiler casing of the cool-down space of a coal gasification reactor and the use of the synthesis gas produced by the process.

Description

將再生性燃料饋料至氣化反應器中的輻射鍋爐套管區域內的裝置和方法 Apparatus and method for feeding regenerative fuel into a radiant boiler casing region in a gasification reactor

本發明係關於一種將再生性燃料饋料至氣化反應器中之輻射鍋爐套管區域內之裝置,該等氣化反應器由反應空間(其中燃燒器位於反應空間中)及冷卻空間(其中冷卻空間裝備有用於冷卻及固化液態爐渣之輻射鍋爐套管)組成,其中根據本發明,定位輻射鍋爐套管之冷卻空間部分將裝備有經由輻射鍋爐套管引入冷卻空間內之燃燒器,允許再生性燃料沿冷卻空間封閉容器之切向引入冷卻空間內。以此方式,即使在用於使再生性燃料後氣化之冷卻空間中,亦可更有效地利用熱合成氣之熱焓。本發明亦係關於一種將再生性燃料經由輻射鍋爐套管沿反應器壁之切向引入煤氣化反應器之冷卻空間內之方法,及由該方法產生之合成氣之用途。 The present invention relates to a device for feeding a regenerative fuel into a zone of a radiant boiler casing in a gasification reactor, the gasification reactor consisting of a reaction space in which the burner is located in the reaction space and a cooling space (wherein The cooling space is provided with a radiant boiler casing for cooling and solidifying the liquid slag, wherein according to the invention, the cooling space portion of the positioning radiant boiler casing will be equipped with a burner introduced into the cooling space via the radiant boiler casing, allowing regeneration The fuel is introduced into the cooling space tangentially along the cooling space closed container. In this way, even in the cooling space for vaporizing the regenerative fuel, the heat of the hot syngas can be utilized more effectively. The invention also relates to a method of introducing regenerative fuel into a cooling space of a coal gasification reactor via a radiant boiler casing along the tangential direction of the reactor wall, and the use of syngas produced by the process.

在大多數具體實例中,煤氣化反應器由反應空間(其中合成氣藉由使其與冷卻器外部介質混合來冷卻)及爐渣收集槽(其裝滿水且經冷卻之爐渣隨後引入該爐渣收集槽內)組成。反應空間含有燃燒器,該等燃燒器用於將含碳燃料與含氧氣體的混合物引入,以在挾帶流氣化反應中產生合成氣。 In most embodiments, the coal gasification reactor is collected from the reaction space (where the synthesis gas is cooled by mixing it with the external medium of the cooler) and a slag collection tank (which is filled with water and then cooled to the slag for subsequent collection into the slag collection) In the tank) composition. The reaction space contains burners for introducing a mixture of a carbonaceous fuel and an oxygen-containing gas to produce a syngas in the gas stream gasification reaction.

在大多數具體實例中,冷卻空間直接垂直伸展於反應空間下方,以使含有液化爐渣及灰分之合成氣最初與灰分及爐渣一起到達冷卻空間。在冷卻空間中,熱合成氣與冷 卻器外部介質摻合以使此熱合成氣冷卻,且排出大部分灰分及爐渣。整個裝置懸掛於耐壓封閉容器中以有助於執行反應之高壓及高溫。 In most embodiments, the cooling space extends directly vertically below the reaction space such that the syngas containing liquefied slag and ash initially reaches the cooling space along with the ash and slag. In the cooling space, hot syngas and cold The external medium is blended to cool the hot syngas and to discharge most of the ash and slag. The entire unit is suspended in a pressure-resistant closed container to help perform the high pressure and high temperature of the reaction.

所排出之爐渣及灰分由冷卻空間轉移至位於冷卻空間下方之爐渣收集槽內。在大多數具體實例中,該爐渣收集槽亦用於收集渣水。在爐渣收集槽中,該渣水經由壓力閘自反應容器中處置出去。合成氣經由側向出料連接器供應以用於進一步處理及使用。實際煤氣化反應典型地發生在超過1400℃至1500℃之溫度及0.5 MPa至8 MPa之壓力下。在離開冷卻空間之後,該合成氣具有約900℃之溫度,且在其與冷卻器外部介質混合之後,其仍具有在200℃與300℃之間的溫度。此合成氣在此溫度下藉助於反應器自封閉容器中引出。 The discharged slag and ash are transferred from the cooling space to a slag collecting tank located below the cooling space. In most embodiments, the slag collection tank is also used to collect slag water. In the slag collection tank, the slag water is disposed of from the reaction vessel via a pressure gate. Syngas is supplied via a lateral discharge connector for further processing and use. The actual coal gasification reaction typically occurs at temperatures in excess of 1400 ° C to 1500 ° C and pressures from 0.5 MPa to 8 MPa. After leaving the cooling space, the syngas has a temperature of about 900 ° C and after it is mixed with the cooler external medium, it still has a temperature between 200 ° C and 300 ° C. This syngas is withdrawn from the closed vessel by means of a reactor at this temperature.

DE 102008012734 A1描述一種根據先前技術回收由煤氣化反應產生之合成氣之方法及裝置,其中所生成之合成氣在位於反應器內頂部處之第一反應器空間中產生,輸入材料在該第一反應器空間之頂部區域中饋入,且液態爐渣在該第一反應器空間之側壁上沈積(該液態爐渣可自由流動,且此爐渣表面無硬化),且該第一反應器空間之底部上定位有具有滴落棱邊(drip down edge)之開口,由該開口將所回收之合成氣向下移動且向下流動之液態爐渣可滴落,且設計為冷卻空間之第二空間連接於開口之底部,且第二空間藉由水膜限制,在該第二空間中第三空間連接於第二空間之底部,在該第三空間中藉由向合成氣內饋水來 發生冷卻,且設計為爐渣連接槽之水浴連接於第三空間之底部,且在第三空間之底部或側面(但在水浴上方),所生成之且經冷卻之合成氣自壓力容器中引出。反應空間下方之第二空間設計為冷卻空間且含有側向限制性水膜以防止沈積。 DE 10 2008 012 734 A1 describes a method and a device for recovering synthesis gas produced by a coal gasification reaction according to the prior art, wherein the synthesis gas produced is produced in a first reactor space at the top of the reactor, the input material being at the first Feeding in the top region of the reactor space, and liquid slag is deposited on the sidewall of the first reactor space (the liquid slag is free flowing, and the slag surface is not hardened), and the bottom of the first reactor space Positioning an opening having a drip down edge from which the recovered syngas is moved downward and the liquid slag flowing downward can be dripped, and the second space designed as a cooling space is connected to the opening a bottom portion, and the second space is limited by a water film in which the third space is connected to the bottom of the second space, in which water is fed into the syngas Cooling occurs and a water bath designed as a slag connection tank is connected to the bottom of the third space, and at the bottom or side of the third space (but above the water bath), the cooled and produced syngas is drawn from the pressure vessel. The second space below the reaction space is designed as a cooling space and contains a laterally restrictive water film to prevent deposition.

由於吾人力圖獲得儘可能不含爐渣及灰分之合成氣,故存在冷卻空間裝備有所謂輻射鍋爐套管之煤氣化反應器具體實例。此等輻射鍋爐套管充當冷卻板且定位於氣化反應器之側壁上。同時,反應容器受此方法保護。自反應空間中流出之合成氣具有角動量,使得其與冷卻器輻射鍋爐套管接觸。在該製程期間,爐渣固化且由於重力作用或由於氣體流動而落入爐渣收集槽內。 Since my manpower map obtains syngas which is as free of slag and ash as possible, there is a specific example of a coal gasification reactor equipped with a so-called radiant boiler casing for the cooling space. These radiant boiler casings act as cooling plates and are positioned on the side walls of the gasification reactor. At the same time, the reaction vessel is protected by this method. The syngas flowing out of the reaction space has an angular momentum such that it contacts the cooler radiating boiler casing. During this process, the slag solidifies and falls into the slag collection tank due to gravity or due to gas flow.

DE 102005041930 A1描述一種用含游離氧之氧化劑藉助於部分氧化使固體燃料在具有固體燃料之挾帶流內氣化之方法,其中將粉煤饋料至氣動計量系統內且粉煤經由貯槽到達至少一個壓力閘,且在加載無冷凝物之氣體之後饋料至計量容器內,在該計量容器底部引入惰性氣體,以便形成流化床,該流化床經由輸送管道到達反應器之燃燒器,使經由輸送管道饋料至反應器內之粉煤與含游離氧之氧化劑一起在具有冷卻幕之反應空間中進行部分氧化,燃料灰分在此熔融,且與熱氣化氣體一起經由排出裝置轉移至驟冷器之驟冷室內,且使經驟冷之蒸汽飽和的原料氣體進行原料氣體洗滌或機械除塵以清除所挾帶之微粒。驟冷器中定位有一個或數個噴嘴環,藉助於該等噴嘴環注入所 需驟冷水,其中噴嘴末端與內部磨損殼層(inner wear shell)齊平,該內部磨損殼層由金屬環形件製成,配置在反應器壓力殼層上以保護反應器壓力殼層。 DE 10 2005 041 930 A1 describes a method for gasifying a solid fuel in a sputum stream with a solid fuel by means of partial oxidation with a free oxygen-containing oxidant, wherein the pulverized coal is fed into a pneumatic metering system and the pulverized coal reaches at least via the sump a pressure gate, fed to the metering vessel after loading the condensate-free gas, introducing an inert gas at the bottom of the metering vessel to form a fluidized bed, the fluidized bed reaching the burner of the reactor via the transfer conduit, The pulverized coal fed into the reactor via the transfer line is partially oxidized together with the oxidant containing free oxygen in a reaction space having a cooling curtain, where the fuel ash is melted and transferred to the quenching via the discharge device together with the hot gasification gas The quenching chamber is cooled, and the quenched steam saturated raw material gas is subjected to raw material gas washing or mechanical dust removal to remove the entrained particles. One or several nozzle rings are positioned in the quench, by means of which nozzles are injected The quench water is required, wherein the nozzle tip is flush with the inner wear shell, which is made of a metal ring and is disposed on the reactor pressure shell to protect the reactor pressure shell.

DE 102005041931 A1描述一種用含游離氧之氧化劑藉助於部分氧化使挾帶流中之固體燃料氣化之方法,該方法由以下製程步驟組成:對粉煤進行氣動計量、在具有冷卻之反應器空間輪廓之反應器中進行氣化反應、部分驟冷、冷卻、原料氣體洗滌及部分冷凝,其中粉煤經由貯槽到達至少一個壓力閘,且在加載無冷凝物之氣體之後饋料至計量容器內,在該計量容器底部引入惰性氣體,以便形成流化床,該流化床經由輸送管道到達反應器之燃燒器,且其中經由輸送管道饋料至反應器內之粉煤與含游離氧之氧化劑一起在具有冷卻幕之反應空間中進行部分氧化,其中粉煤灰分在此熔融,且與熱燃燒氣體一起經由排出裝置轉移至驟冷器之驟冷室內且進行部分驟冷,且使經部分驟冷之原料氣體在廢熱鍋爐中冷卻,且隨後進行清潔及進一步處理。 DE 10 2005 041 931 A1 describes a process for the gasification of a solid fuel in a stream of hydrazine by partial oxidation with an oxidant containing free oxygen, which process consists of the following process steps: pneumatically metering pulverized coal in a reactor space with cooling a gasification reaction, partial quenching, cooling, raw material gas washing and partial condensation in the reactor of the profile, wherein the pulverized coal reaches the at least one pressure gate via the storage tank, and is fed into the measuring container after loading the gas without condensate, An inert gas is introduced at the bottom of the metering vessel to form a fluidized bed that reaches the burner of the reactor via a transfer conduit, and wherein the pulverized coal fed into the reactor via the transfer conduit is combined with an oxidant containing free oxygen Partial oxidation is carried out in a reaction space having a cooling curtain where the fly ash is melted and transferred together with the hot combustion gases via a discharge device to the quenching chamber of the quencher for partial quenching and partial quenching The feed gas is cooled in a waste heat boiler and subsequently cleaned and further processed.

在該發明之一具體實例中,驟冷器空間直接通向廢熱鍋爐,該廢熱鍋爐中定位有用於產生蒸汽之管道,且其下部定位有使用水浴移除原料氣體及爐渣之開口。以此方式,廢熱鍋爐之熱量可用於產生蒸汽。 In one embodiment of the invention, the quench space is directed to a waste heat boiler in which a conduit for generating steam is positioned and a lower portion of which is positioned to remove the feed gas and slag using a water bath. In this way, the heat of the waste heat boiler can be used to generate steam.

許多具體實例將合成氣引入裝備有輻射鍋爐套管之冷卻空間內,其中輻射鍋爐套管由內部磨損殼層(其自金屬製得用於保護反應器壓力殼層)組成或由管道(水經由該 等管道引導用於產生蒸汽)組成。兩種具體實例均具有以下目的:不直接將熱合成氣引入冷卻空間內,或不直接朝向封閉容器之輻射鍋爐套管引導熱合成氣,而是冷卻,以使爐渣可固化且自合成氣排出。 Many specific examples introduce syngas into a cooling space equipped with a radiant boiler casing, wherein the radiant boiler casing is composed of an internal wear shell (which is made of metal to protect the reactor pressure shell) or is piped (water The The pipeline is guided to produce steam). Both specific examples have the following objectives: no direct introduction of hot syngas into the cooling space, or directing of the hot syngas directly towards the radiant boiler casing of the closed vessel, but cooling, so that the slag is curable and discharged from the syngas .

有時亦可能朝向為此目的而設置之冷卻板(亦稱為「擋板(bulkhead)」)引導含有爐渣之熱合成氣,其中此等冷卻板沿冷卻空間及整個反應器之垂直伸展的幾何中心軸方向錐形同心伸展。此等冷卻板亦可由管道組成。後者則宜與氣流方向平行以改良冷卻。 It is sometimes possible to direct the hot syngas containing slag to the cooling slag (also known as the "bulkhead") provided for this purpose, wherein the geometry of the cooling plates along the cooling space and the vertical extension of the entire reactor The central axis is tapered concentrically. These cooling plates can also be composed of pipes. The latter should be parallel to the direction of the gas flow to improve cooling.

在本發明之一典型具體實例中,已在反應器中使合成氣適當地具備有角動量,以使後者不直接垂直引入冷卻空間內,而是已以微小角動量朝向冷卻空間中之冷卻板。反應器自身具有漏斗形出口,其使氣體速度增加,且因此加強熱合成氣朝向冷卻板之方向。定位在冷卻板周圍之實際壁常裝備有管道,該等管道保護壁免受合成氣之高溫。用於外部介質之入口噴嘴沿氣流方向定位在冷卻板或擋板之後方。 In a typical embodiment of the invention, the syngas has been suitably provided with angular momentum in the reactor so that the latter is not introduced directly into the cooling space, but rather has been directed towards the cooling plate in the cooling space with a small angular momentum. . The reactor itself has a funnel shaped outlet which increases the gas velocity and thus enhances the direction of the hot syngas towards the cooling plate. The actual walls positioned around the cooling plates are often equipped with pipes that protect the walls from the high temperatures of the syngas. The inlet nozzle for the external medium is positioned behind the cooling plate or baffle in the direction of the air flow.

此方法具有離開反應器之合成氣之顯熱仍未使用之缺點。合成氣離開反應器時之溫度超過1500℃,且在藉由供應冷卻性氣態、汽態或液態外部介質進行冷卻之後為200℃至300℃。以此方式,合成氣之熱量在未使用之情況下損失。 This method has the disadvantage that the sensible heat of the syngas leaving the reactor is still unused. The syngas leaves the reactor at a temperature in excess of 1500 ° C and is between 200 ° C and 300 ° C after being cooled by supply of a cooling gaseous, vapor or liquid external medium. In this way, the heat of the syngas is lost without being used.

因此,將定位於反應器出口與輻射鍋爐套管之間的合成氣之熱量用於化學製程將較有利,其中應考慮冷卻空間 中用於此化學製程進程所需之特定停留時間。因此,存在使以下方法可用之問題:其在反應器出口之後將合成氣之焓或顯熱直接用於後續製程,確保冷卻空間中之停留時間增加,且仍然有助於藉由冷卻空間中之輻射鍋爐套管及在輻射鍋爐套管後方沿氣流方向供應外部介質來冷卻合成氣。 Therefore, it would be advantageous to use the heat of the syngas positioned between the reactor outlet and the radiant boiler casing for the chemical process, where cooling space should be considered. The specific residence time required for this chemical process. Therefore, there is a problem that the following method can be used: it directly uses the syngas or sensible heat of the syngas after the reactor outlet to ensure subsequent residence time in the cooling space, and still contributes to the cooling space. The radiant boiler casing and an external medium are supplied in the direction of the gas flow behind the radiant boiler casing to cool the syngas.

本發明利用以下裝置解決此問題:其中燃燒器沿反應器壁之切向以一定角度定位於冷卻空間中,藉此所注入之燃料受到圍繞冷卻空間之中心軸引導之角動量,以使所注入之材料在冷卻空間中之停留時間增加,且因此以合成氣之剩餘熱焓促進化學反應。 The present invention solves this problem by using a device in which the burner is positioned at a certain angle in the cooling space along the tangential direction of the reactor wall, whereby the injected fuel is subjected to angular momentum guided around the central axis of the cooling space for injection. The residence time of the material in the cooling space increases, and thus the chemical reaction is promoted with the remaining heat of the syngas.

燃燒器可以隨氣流方向或逆氣流方向以一定角度注入再生性燃料。然而,根據本發明,必須遵循切線方向,其中切線方向係指切角,其在冷卻空間之水平橫截面上在冷卻空間壁之對面形成。 The burner can inject regenerative fuel at an angle in the direction of the gas flow or in the direction of the reverse gas flow. However, according to the invention, the tangential direction must be followed, wherein the tangential direction refers to the chamfer, which is formed on the opposite side of the cooling space wall in the horizontal cross section of the cooling space.

同時,燃燒器必須經由封閉容器壁及輻射鍋爐套管引導。通常,此舉需要較高設計費用,因為輻射鍋爐套管常含有管道或厚壁金屬幕。實施此燃燒器配置之常用設計為「管道-網-管道(tube-web-tube)」設計。 At the same time, the burner must be guided through the closed vessel wall and the radiant boiler casing. Often, this requires a high design cost because the radiant boiler casing often contains pipes or thick-walled metal curtains. A common design for implementing this burner configuration is a "tube-web-tube" design.

再生性原料較佳以附加燃料之形式注入冷卻空間內。再生性原料具有與合成氣反應且在反應期間不使溫度實質上升高之性質。經由再生性燃料之切向注入,冷卻空間中之停留時間增加,以便有助於再生性燃料與仍然較熱的合成氣反應。合成氣溫度常隨著添加再生性原料而進一步降 低。再生性燃料與合成氣組分反應,消耗熱量。在反應期間產生附加的合成氣。 The regenerative feedstock is preferably injected into the cooling space in the form of an additional fuel. The regenerable feedstock has the property of reacting with the syngas and not increasing the temperature substantially during the reaction. Through the tangential injection of regenerative fuel, the residence time in the cooling space is increased to facilitate the reaction of the regenerative fuel with the still hoter syngas. Syngas temperature is often further reduced with the addition of regenerative materials low. The regenerative fuel reacts with the syngas component and consumes heat. Additional syngas is produced during the reaction.

經由根據本發明之裝置,可實質上改良煤氣化製程之經濟效率。由於再生性原料在氣化製程中僅傳遞少量灰分,故藉由根據本發明之方法,輻射鍋爐套管負載有實質上較少的灰分及爐渣。最後,輻射鍋爐套管藉由後續引入再生性燃料而暴露於顯著較低的熱負載。 The economic efficiency of the coal gasification process can be substantially improved via the apparatus according to the invention. Since the regenerative feedstock only transfers a small amount of ash in the gasification process, the radiant boiler casing is loaded with substantially less ash and slag by the method according to the invention. Finally, the radiant boiler casing is exposed to a significantly lower heat load by subsequent introduction of regenerative fuel.

特定言之,主張一種將再生性燃料饋料至煤氣化反應器之輻射鍋爐套管區域內之裝置,其包含:●反應空間,其適用於藉由與含氧氣體或含水蒸汽及氧之氣體發生反應來氣化固體含碳燃料,且其裝備有燃燒器,●第二空間,其設計為冷卻空間,且其沿氣流方向配置於反應空間下方,其中此冷卻空間裝備有用於氣態、汽態及液態冷卻介質之饋料設備,其中●冷卻空間沿氣流方向之至少一個延伸部分裝備有配置在冷卻空間內壁上之環形輻射鍋爐套管,且其特徵在於:●配置輻射鍋爐套管之冷卻空間之環形部分裝備有燃燒器,該等燃燒器經由輻射鍋爐套管引入冷卻空間內,再生性燃料可經由該等燃燒器引入冷卻空間內,●燃燒器沿反應器壁之切向以一定角度配置在冷卻空間中。 In particular, a device for feeding a regenerative fuel into a zone of a radiant boiler casing of a coal gasification reactor is proposed, comprising: a reaction space suitable for use with an oxygen-containing gas or a vapor containing water and oxygen A reaction occurs to vaporize the solid carbonaceous fuel, and is equipped with a burner, a second space, which is designed as a cooling space, and which is disposed below the reaction space along the gas flow direction, wherein the cooling space is equipped with a gas state and a vapor state. And a feeding device of the liquid cooling medium, wherein: the cooling space is equipped with at least one extension of the airflow direction with an annular radiation boiler casing disposed on the inner wall of the cooling space, and is characterized by: ● Configuring cooling of the radiation boiler casing The annular portion of the space is equipped with burners that are introduced into the cooling space via a radiant boiler casing through which regenerative fuel can be introduced into the cooling space. The burner is angled at a tangential direction along the reactor wall. Configured in the cooling space.

從而由輻射鍋爐套管之類型確定用於饋料之增加之設計費用。為了執行本發明,僅需要經由氣密輻射鍋爐套管介質緊密地引導至少一個燃燒器。在本發明之一具體實例中,管道配置於冷卻空間內部,其中冷卻介質可沿氣流方向流經管道。燃燒器因而必須經由封閉容器在管道之間或經由管道引入冷卻空間內。在氣化反應器製造中,輻射鍋爐套管之設計有時會大大不同,使得燃燒器配置之設計費用由輻射鍋爐套管之設計來確定。 The design cost for the increase in the feed is thus determined by the type of radiant boiler casing. In order to carry out the invention, it is only necessary to closely guide at least one burner via a hermetic radiation boiler casing medium. In one embodiment of the invention, the conduit is disposed within the cooling space, wherein the cooling medium can flow through the conduit in the direction of the gas flow. The burner must therefore be introduced into the cooling space between the pipes or via pipes via closed containers. In the manufacture of gasification reactors, the design of the radiant boiler casing is sometimes quite different, so that the design cost of the burner configuration is determined by the design of the radiant boiler casing.

在本發明之另一具體實例中,越過冷卻空間之特定長度之管道覆蓋冷卻空間之整個內部周邊,其中冷卻介質可沿氣流方向流經管道。在此情形中,燃燒器必須在各種情況下經由管道引導至特定位置。此可利用管道套環實現,然而,其在一有利具體實例中利用所謂「管道-網-管道」設計實現。EP 0840053 B1教示「管道-網-管道」設計之一典型具體實例,其用於在燃燒器裝配情況下防止水流經管道之不合需要的中斷。 In another embodiment of the invention, a conduit of a particular length across the cooling space covers the entire interior perimeter of the cooling space, wherein the cooling medium can flow through the conduit in the direction of the gas flow. In this case, the burner must be guided to a specific location via a pipe in each case. This can be achieved with a pipe collar, however, it is implemented in an advantageous embodiment using a so-called "pipe-net-pipe" design. EP 0840053 B1 teaches a typical example of a "pipe-net-pipe" design for preventing undesired interruption of water flow through the pipe in the case of burner assembly.

在本發明之另一具體實例中,環形壁定位於冷卻空間壁與管道之間作為輻射鍋爐套管。因此,在冷卻含有爐渣之合成氣期間使封閉容器之機械負載維持較低。在本發明之另一具體實例中,其他管道配置於冷卻空間內部,冷卻介質可沿氣流方向流經該等管道,且該等管道藉由其沿冷卻空間之幾何中心軸之同心方向的平行配置來進行配置。此等管道較佳地與越過冷卻空間之特定長度圍繞冷卻空間 之整個內部周邊之管道組合配置,其中冷卻介質可沿氣流方向流經所有管道。與冷卻空間之幾何中心軸齊平伸展之管道配置使合成氣之冷卻改良且又延長冷卻空間中之停留時間。此等管道之同心配置亦稱為「擋板」。在一簡單具體實例中,此等「擋板」亦可作為板執行。此配置典型地不延伸至冷卻空間之縱軸中心,而是僅延伸至冷卻空間中之橫截面區域之三分之一。 In another embodiment of the invention, the annular wall is positioned between the cooling space wall and the conduit as a radiant boiler casing. Therefore, the mechanical load of the closed vessel is kept low during the cooling of the syngas containing the slag. In another embodiment of the present invention, other ducts are disposed inside the cooling space through which the cooling medium can flow in the direction of the airflow, and the ducts are arranged in parallel by concentric directions along the geometric central axis of the cooling space. To configure. These pipes preferably surround the cooling space with a specific length across the cooling space The entire inner perimeter of the pipe combination configuration wherein the cooling medium can flow through all of the pipes in the direction of the gas flow. The arrangement of the tubes that are flush with the geometric center axis of the cooling space improves the cooling of the syngas and extends the residence time in the cooling space. The concentric configuration of these pipes is also known as the "baffle." In a simple embodiment, such "baffles" can also be implemented as a plate. This configuration typically does not extend to the center of the longitudinal axis of the cooling space, but only extends to one-third of the cross-sectional area in the cooling space.

在本發明之一個具體實例中,輻射鍋爐套管由耐熱板組成。輻射鍋爐套管亦可含有管道,該等管道以任何配置包含於輻射鍋爐套管中。輻射鍋爐套管亦可完全由管道組成。管道用於引導任何間接冷卻的介質。在此情形中,為了執行本發明,燃燒器必須緊靠著冷卻介質引入管道內且穿過氣密輻射鍋爐套管(「管道-網-管道」設計)。為了執行本發明,亦可沿冷卻空間方向設置具有耐火襯裡之管道。DE 3809313 A1提供輻射鍋爐套管之來自先前技術之一具體實例,其含有管道。為了執行本發明,將經由環形伸展之管道壁及耐火襯裡來介質緊密地引導至少一個燃燒器。 In one embodiment of the invention, the radiant boiler casing is comprised of a heat resistant plate. The radiant boiler casing can also contain pipes that are included in the radiant boiler casing in any configuration. The radiant boiler casing can also consist entirely of pipes. The pipe is used to guide any indirectly cooled media. In this case, in order to carry out the invention, the burner must be placed in close proximity to the cooling medium introduction conduit and through the hermetic radiation boiler casing ("pipe-net-pipe" design). In order to carry out the invention, it is also possible to provide a refractory lined pipe along the direction of the cooling space. DE 3809313 A1 provides a radiant boiler casing from a specific example of the prior art which contains a pipe. In order to carry out the invention, the medium is tightly guided through the annularly extending duct wall and the refractory lining to at least one burner.

在本發明之另一具體實例中,另一環形壁作為輻射鍋爐套管圍繞同心配置的管道定位。此亦可具有用於在面向反應空間之側上冷卻之其他管道,冷卻介質可流經該等管道。因而,此等管道較佳圍繞反應空間之幾何中心軸伸展以達成冷卻之改良。 In another embodiment of the invention, the other annular wall is positioned as a radiant boiler casing around a concentrically configured conduit. This may also have other conduits for cooling on the side facing the reaction space through which the cooling medium may flow. Thus, such conduits preferably extend around the geometric central axis of the reaction space to achieve an improvement in cooling.

亦可在輻射鍋爐套管與冷卻空間內壁之間配置中間空 間,氣體可經由該中間空間循環。DE 102008012734 A1提供該輻射鍋爐套管之一實例。為了執行本發明,用於再生性燃料之燃燒器隨後經由此中間空間及內壁引導。輻射鍋爐套管可例如亦由以空心圓柱形式設計之同心圍繞冷卻空間之對流式鍋爐組成。EP 616022 B1提供具有冷卻空間之一具體實例之一實例,其由以空心圓柱形式設計之用於冷卻之對流式鍋爐組成。對流式鍋爐亦可多重劃分,或在其一部分上裝備冷卻板。亦可預想為了實施本發明,瀑布樣冷卻機構沿氣流方向定位在燃燒器後方以用於再生性原料,如例如DE 102008012734 A1中所主張。 It is also possible to arrange intermediate space between the radiant boiler casing and the inner wall of the cooling space. Between the gases, the gas can circulate through the intermediate space. An example of such a radiant boiler casing is provided in DE 10 2008 012 734 A1. In order to carry out the invention, the burner for the regenerative fuel is then guided via this intermediate space and the inner wall. The radiant boiler casing can, for example, also consist of a convection boiler which is concentrically surrounded by a cooling space in a hollow cylindrical design. EP 616 022 B1 provides an example of a specific example with a cooling space consisting of a convection boiler designed for cooling in a hollow cylindrical design. Convection boilers can also be divided into multiple sections or equipped with cooling plates on a part thereof. It is also envisaged that in order to carry out the invention, the waterfall-like cooling device is positioned behind the burner in the direction of the gas flow for the regenerative material, as is claimed, for example, in DE 10 2008 012 734 A1.

經由輻射鍋爐套管饋料再生性原料之燃燒器可以任何方式設計。此等燃燒器可例如設計為燃燒槍。但此等燃燒器亦可設計為噴嘴。燃燒器亦可以切向及同心方式配置。燃燒器亦可經配置以使其沿氣流方向處於反應空間之出料連接器之前方,以使其在操作期間處於合成氣流之「流影(flow shadow)」中。以此方式,燃燒器較佳地防止成渣。為了執行本發明,僅要求至少一個燃燒器經由氣密輻射鍋爐套管介質緊密地引導,且在至少一部分冷卻空間中在引入冷卻性氣態、汽態或液態外部介質之前沿氣流方向引導或可引導再生性燃料。 The burner feeding the regenerative feedstock via the radiant boiler casing can be designed in any manner. These burners can for example be designed as burner guns. However, such burners can also be designed as nozzles. The burner can also be configured in a tangential and concentric manner. The burner can also be configured such that it is in front of the discharge connector of the reaction space in the direction of the gas flow so that it is in the "flow shadow" of the syngas stream during operation. In this way, the burner preferably prevents slag formation. In order to carry out the invention, it is only required that at least one burner is guided tightly via the hermetic radiation boiler casing medium and guided or guided in the direction of the gas flow before introduction of the cooling gaseous, vaporous or liquid external medium in at least a portion of the cooling space Renewable fuel.

反應空間及冷卻空間之壓力容器可以作為具有相同直徑之單一組件設置用於構建裝置。但反應空間及冷卻空間亦可為置於彼此之上之具有不同直徑之兩個壓力容器,其中冷卻空間-壓力容器之直徑在此情形中比反應空間-壓力 容器之直徑大。 The pressure vessel of the reaction space and the cooling space can be provided as a single component having the same diameter for constructing the device. However, the reaction space and the cooling space may also be two pressure vessels having different diameters placed on each other, wherein the cooling space-pressure vessel diameter is in this case more than the reaction space-pressure The diameter of the container is large.

亦主張一種將燃料切向注入氣化反應器之冷卻空間內之方法。燃料可在冷卻空間中沿著氣流方向或逆著氣流方向、然而在冷卻空間水平割面中沿反應器壁之切角注入。由此,實質上增加在反應空間中之停留時間。 A method of tangentially injecting fuel into the cooling space of a gasification reactor is also claimed. The fuel can be injected in the cooling space along the direction of the gas flow or against the direction of the gas flow, but in the horizontal cutting plane of the cooling space along the corners of the reactor wall. Thereby, the residence time in the reaction space is substantially increased.

再生性燃料典型地用於注入。再生性燃料經由輻射鍋爐套管經由至少一個燃燒器同心切向地饋料至冷卻空間內,以便產生另一挾帶流氣化反應,經由該另一挾帶流氣化反應,流出氣體之溫度下降且焓差用於再生性原料之附加氣化(「化學驟冷(chemical quench)」)。切向注入燃料伴以停留時間延長有助於此程序或至少促進了此程序。 Regenerative fuels are typically used for injection. The regenerative fuel is fed concentrically tangentially into the cooling space via the at least one burner via the radiant boiler casing to generate another gas stream gasification reaction, through which the temperature of the effluent gas decreases and The enthalpy difference is used for additional gasification of the regenerative raw material ("chemical quench"). Tangential injection of fuel with extended residence time contributes to this procedure or at least facilitates this procedure.

亦主張一種將再生性燃料饋料至煤氣化反應器之輻射鍋爐套管區域內之方法,其中:●將自外部沿水平方向同心或向下引導之細粉狀含碳燃料與氧氣或含氧氣體之混合物自上方注入耐火反應空間內,以便使燃料在反應空間中在挾帶流氣化反應中反應形成合成氣,及●所獲得之合成氣在0.5 MPa至8 MPa之壓力下且沿向上及向下方向自反應空間引出,及●在完成引出之後,將由此獲得之合成氣引入設計為冷卻空間之第二反應空間內,且在該第二反應空間中將出於冷卻目的所供應之氣體與冷卻器氣態、汽態或液態外部介質混合,且其特徵在於 ●在反應空間與用於外部介質之饋料點之間,再生性燃料經由輻射鍋爐套管經由至少一個燃燒器同心饋料至冷卻空間內,以便產生另一挾帶流氣化反應,經由該另一挾帶流氣化反應,流出氣體之溫度下降且焓差用於再生性原料之附加氣化,及●再生性燃料沿冷卻空間壁之切線方向以一定角度注入冷卻空間內,以使再生性燃料在注入來自反應空間之原料氣流內期間接受角動量。 A method of feeding regenerative fuel into the area of a radiant boiler casing of a coal gasification reactor is also claimed, wherein: - a finely powdered carbonaceous fuel and oxygen or oxygen which are concentrically or downwardly directed from the outside in a horizontal direction. a mixture of gases is injected into the refractory reaction space from above to cause the fuel to react in the reaction space to form a synthesis gas in the gas stream reaction, and the obtained synthesis gas is at a pressure of 0.5 MPa to 8 MPa and is upwardly directed Deriving from the reaction space in a downward direction, and ● after completion of the extraction, introducing the synthesis gas thus obtained into a second reaction space designed as a cooling space, and supplying the gas supplied for cooling purposes in the second reaction space Mixed with a gaseous, vapor or liquid external medium of the cooler, and characterized by - between the reaction space and the feed point for the external medium, the regenerative fuel is fed concentrically via the at least one burner into the cooling space via the radiant boiler casing to generate another gas stream gasification reaction via which With a gasification reaction, the temperature of the effluent gas decreases and the enthalpy difference is used for additional gasification of the regenerative raw material, and the regenerative fuel is injected into the cooling space at an angle along the tangential direction of the cooling space wall to make the regenerative fuel Angular momentum is received during injection into the feed gas stream from the reaction space.

所有生物材料均可用作再生性燃料,其適於以作為反應氣體之含氧氣體來產生合成氣。此再生性燃料可為精細切碎、壓碎、精細研磨之能源作物、任何形式之木材、稻草、牧草、穀類、生物殘餘物、海洋植物或家畜糞肥。再生性原料可在氣化之前進行預處理,其中預處理步驟包括例如乾燥、碳化、研磨或此等步驟之組合。為了氣化,隨後將再生性燃料與含蒸汽或含氧之氣體、水蒸汽、或含氧氣體及水蒸汽之混合物引入冷卻空間內。再生性燃料與含碳燃料或化石燃料之混合物亦可用作冷卻空間中之燃燒器之燃料。 All biological materials can be used as regenerative fuels, which are suitable for producing syngas with an oxygen-containing gas as a reactive gas. This regenerative fuel can be a finely chopped, crushed, finely ground energy crop, any form of wood, straw, pasture, cereals, biological residues, marine plants or livestock manure. The regenerative feedstock can be pretreated prior to gasification, wherein the pretreatment step includes, for example, drying, carbonization, milling, or a combination of such steps. For gasification, a regenerative fuel is then introduced into the cooling space with a mixture of steam or oxygen containing gas, water vapor, or oxygen containing gas and water vapor. A mixture of regenerative fuel and a carbonaceous fuel or fossil fuel can also be used as a fuel for a burner in a cooling space.

基本上已知向挾帶流氣化反應內添加再生性原料。EP 1027407 B1描述一種藉由在燃燒器中使燃料與氣態氧或含氧氣體一起燃燒而由再生性燃料及化石燃料產生可燃氣體、合成氣及還原氣體之方法。DE 102009011174 A1(在本申請案時尚未揭示)描述一種在延伸越過反應空間總高度之部分區域之第二燃燒器位準內,經由再生性燃料之附 加氣化反應來使用合成氣之焓的方法。 It is basically known to add a regenerative raw material to the gas stream reaction of the anthraquinone stream. EP 1027407 B1 describes a process for producing combustible gases, syngas and reducing gases from regenerative fuels and fossil fuels by burning the fuel together with gaseous oxygen or an oxygen-containing gas in a burner. DE 102009011174 A1 (not yet disclosed at the time of this application) describes a second burner level in a region extending over the total height of the reaction space, via regenerative fuel A method of adding a gasification reaction to use a synthesis gas.

DE 102010008384.4(在本申請案時尚未揭示)描述一種方法,其中經由配置在冷卻空間內部之冷卻空間中之其他開口將生物燃料同心引入冷卻空間內,以便與合成氣發生另一反應,藉此進一步降低合成氣之溫度。此申請案將燃料直接引入冷卻空間中且完全未提供經由輻射鍋爐套管切向引入再生性燃料之複雜設計的指示。 DE 102010008384.4 (not yet disclosed at the time of this application) describes a method in which biofuels are concentrically introduced into a cooling space via other openings arranged in a cooling space inside the cooling space for another reaction with the syngas, thereby further Reduce the temperature of the syngas. This application introduces fuel directly into the cooling space and does not provide an indication of the complex design of tangential introduction of regenerative fuel via the radiant boiler casing.

合成氣之溫度在自反應空間排出期間典型地為1400℃至1500℃,在引入再生性燃料之後約為1,200℃至1,300℃且在離開冷卻空間之後約為900℃。離開冷卻空間時約900℃之溫度利用量測值加以記錄,其餘值為估算值。 The temperature of the syngas is typically from 1400 ° C to 1500 ° C during discharge from the reaction space, from about 1,200 ° C to 1,300 ° C after introduction of the regenerative fuel and about 900 ° C after leaving the cooling space. The temperature of about 900 ° C when leaving the cooling space is recorded using the measured value, and the remaining values are estimated values.

燃燒器可以任何方式配置在冷卻空間中。再生性燃料必須僅經由切向配置之燃燒器切向地引入圓柱形冷卻空間內,以使冷卻空間中之挾帶流接受角動量,藉此增加燃料在冷卻空間中之停留時間。由於燃燒器經由輻射鍋爐套管介質緊密地引導,故此等燃燒器在輻射鍋爐套管區域中典型地裝備有密封套環。然而,密封可以任何方式實現且密封類型可以任何方式進行。 The burner can be configured in the cooling space in any manner. The regenerative fuel must be introduced tangentially into the cylindrical cooling space only via the tangentially disposed burners to allow the enthalpy flow in the cooling space to accept angular momentum, thereby increasing the residence time of the fuel in the cooling space. Since the burners are tightly guided via the radiant boiler casing medium, such burners are typically equipped with a sealing collar in the radiant boiler casing region. However, the sealing can be achieved in any manner and the type of sealing can be performed in any manner.

合成氣之顯熱可用於產生蒸汽。外部介質用於此目的,其經由輻射鍋爐套管中之冷卻板或管道中之間接冷卻來吸收來自冷卻空間之熱量。此熱量可用於下游廢熱鍋爐以產生蒸汽或高壓蒸汽。為了執行本發明,亦可利用拍打器或吹灰器或兩者清潔輻射鍋爐套管及擋板。 The sensible heat of the syngas can be used to generate steam. An external medium is used for this purpose, which absorbs heat from the cooling space via intercooling in a cooling plate or pipe in the radiant boiler casing. This heat can be used in downstream waste heat boilers to produce steam or high pressure steam. In order to perform the present invention, the radiant boiler casing and baffle may also be cleaned using a beater or soot blower or both.

亦主張由所提及方法產生之合成氣之用途,此合成氣 可用於例如在發電廠中發電。此外,此合成氣可在二氧化碳與燃燒氣體分離之情況下用於在發電廠中發電。此用途之一實例為IGCC技術(IGCC:「整合氣化複合循環(Integrated Gasification Combined Cycle)」)。最後,亦可能使用根據本發明產生之合成氣來產生合成馬達燃料或合成天然氣。此外,根據本發明產生之合成氣之任何用途均可能用於產生化學品(「多聯產(polygeneration)」)。 Also advocates the use of syngas produced by the mentioned method, this syngas It can be used, for example, to generate electricity in a power plant. In addition, the syngas can be used to generate electricity in a power plant where carbon dioxide is separated from the combustion gases. An example of this use is IGCC technology (IGCC: "Integrated Gasification Combined Cycle"). Finally, it is also possible to use the syngas produced according to the invention to produce synthetic motor fuel or synthetic natural gas. Furthermore, any use of syngas produced in accordance with the present invention may be used to produce chemicals ("polygeneration").

本發明具有亦在裝備有輻射鍋爐套管之冷卻空間中使用來自煤氣化反應之熱合成氣之焓的優點。因此,可實質上改良煤氣化製程之經濟效率。由於再生性燃料在氣化製程中僅傳遞少量灰分,故藉由根據本發明之方法,輻射鍋爐套管負載有實質上較少的灰分及爐渣。最後,輻射鍋爐套管經由後續引入再生性燃料而暴露於實質上較低的熱負載。 The present invention has the advantage of using a hot syngas from a coal gasification reaction in a cooling space equipped with a radiant boiler casing. Therefore, the economic efficiency of the coal gasification process can be substantially improved. Since the regenerative fuel transfers only a small amount of ash in the gasification process, the radiant boiler casing is loaded with substantially less ash and slag by the method according to the invention. Finally, the radiant boiler casing is exposed to a substantially lower thermal load via subsequent introduction of regenerative fuel.

借助於兩個圖式更詳細地闡明本發明,其中本發明不限於此等具體實例。圖1展示根據本發明之具有後氣化反應之煤氣化反應器,其中輻射鍋爐套管自裝備有重疊冷卻板之水引導管道或冷卻介質引導管道設計。圖2展示根據本發明之具有後氣化反應之煤氣化反應器,其中輻射鍋爐套管由冷卻板組成,該冷卻板裝備有引導冷卻介質之圍繞其上方冷卻空間環形配置之管道。 The invention is illustrated in more detail by means of two figures, wherein the invention is not limited to such specific examples. 1 shows a coal gasification reactor having a post gasification reaction according to the present invention, wherein the radiant boiler casing is designed from a water guiding pipe or a cooling medium guiding pipe equipped with an overlapping cooling plate. 2 shows a coal gasification reactor having a post gasification reaction according to the present invention, wherein the radiant boiler casing is composed of a cooling plate equipped with a pipe that guides the cooling medium around the cooling space above it.

圖1展示根據本發明之煤氣化反應器(1),其裝備有用於對含碳化石燃料進行氣化之反應空間(2)、具有輻射鍋爐套管(4)之冷卻空間(3)、及設計為水浴(5a)之 爐渣收集槽(5)。反應空間(2)裝備有燃燒器(6),含碳化石燃料(6a)與含氧燃料之混合物經由該等燃燒器(6)引入反應空間(2)內,且該反應空間(2)經由懸掛裝置(2a)懸掛於耐壓封閉容器(7)中。在氣化反應期間產生合成氣(8),在使用切向燃燒器時該合成氣(8)接受角動量(8a)。反應空間(2)之底面上定位用於流出合成氣(8b)之出料連接器(2b),該合成氣(8b)經由此出料連接器(2b)進入冷卻空間(3)內。出料連接器(2b)裝備有套環形開口。封閉容器(7)在冷卻空間(3)之高度上裝備有輻射鍋爐套管(4),該輻射鍋爐套管(4)由圍繞冷卻空間內壁(7)配置之環形耐熱板組成。管道(9)定位在封閉容器(7)壁與輻射鍋爐套管之間,該等管道(9)引導間接冷卻的冷卻介質且沿氣流方向平行於封閉容器(7)壁伸展。管道(10)亦定位在輻射鍋爐套管(4)之內側上,該等管道(10)引導間接冷卻的冷卻介質,其中該等管道(10)以環形方式圍繞冷卻空間(3)軸引導。在輻射鍋爐套管(4)之內側上引導冷卻介質之管道(10)裝備有給料連接器(10a)及出料連接器(10b)。根據本發明之燃燒器(11)沿氣流方向配置在輻射鍋爐套管(4)之前方用於再生性燃料(11a),該等燃燒器(11)經由輻射鍋爐套管(4)饋料,且再生性燃料(11a)經由該等燃燒器(11)饋料至冷卻空間(3)內且得以氣化。因此,後氣化反應開始且合成氣之溫度下降。固化爐渣沈澱在輻射鍋爐套管(4)上。此固化爐渣由於重力作用而進入配置在其 下方之裝滿水(5a)之爐渣收集槽(5)中或被氣流帶走。隨後,流出合成氣(8b)沿輻射鍋爐套管(4)後方之氣流方向進入冷卻區域,其中給料噴嘴(12)經配置用於冷卻性氣態、汽態或液態外部介質(12a)。所供應之外部介質(12a)持續使冷卻空間中之合成氣(8c)冷卻,隨後此(13)經由出料連接器(14)沿側向離開冷卻空間(3)。爐渣(15)經由閘(16)及出料連接器(17)定期引導出反應器(1)。圖1中亦展示截面A-A,其橫截面展示於圖2中。 Figure 1 shows a coal gasification reactor ( 1 ) according to the invention equipped with a reaction space ( 2 ) for gasification of a carbonaceous fossil fuel, a cooling space ( 3 ) with a radiant boiler casing ( 4 ), and Designed as a slag collection tank ( 5 ) for the water bath ( 5a ). The reaction space ( 2 ) is equipped with a burner ( 6 ) through which a mixture of a carbonaceous fossil fuel ( 6a ) and an oxy-fuel is introduced into the reaction space ( 2 ) via the burners ( 6 ), and the reaction space ( 2 ) is passed through The suspension device ( 2a ) is suspended in a pressure-resistant closed container ( 7 ). Syngas ( 8 ) is produced during the gasification reaction, and the syngas ( 8 ) receives angular momentum ( 8a ) when a tangential burner is used. A discharge connector ( 2b ) for flowing out of the synthesis gas ( 8b ) is positioned on the bottom surface of the reaction space ( 2 ), and the synthesis gas ( 8b ) enters the cooling space ( 3 ) via the discharge connector ( 2b ). The discharge connector ( 2b ) is equipped with a set of annular openings. Closed container (7) in the cooling space (3) of the radiation boiler equipped with a height of the sleeve (4), the radiation boiler sleeve (4) by the inner wall of the cooling space surrounding the composition (7) Disposing the annular heat-resistant sheet. The conduit ( 9 ) is positioned between the wall of the closed vessel ( 7 ) and the radiant boiler casing, the conduits ( 9 ) directing the indirectly cooled cooling medium and extending parallel to the wall of the closed vessel ( 7 ) in the direction of the gas flow. Pipe (10) also positioned on the (4) of the radiation boiler inner sleeve, such duct (10) guiding the cooling medium in the indirect cooling, wherein such conduit (10) in an annular manner (3) guided around the axis of the cooling space. A conduit ( 10 ) for guiding the cooling medium on the inside of the radiant boiler casing ( 4 ) is equipped with a feed connector ( 10a ) and a discharge connector ( 10b ). (11) arranged in the direction of airflow radiation boiler tube (4) prior to the regeneration side of the fuel (11a), such a burner (11) via a radiation tube boiler (4) feed was burner according to the invention, And the regenerative fuel ( 11a ) is fed into the cooling space ( 3 ) via the burners ( 11 ) and is vaporized. Therefore, the post gasification reaction starts and the temperature of the synthesis gas decreases. The solidified slag is deposited on the radiant boiler casing ( 4 ). The solidified slag enters or is carried away by the gas stream due to gravity into the slag collecting tank ( 5 ) of the filled water ( 5a ) disposed therebelow. Subsequently, the outflow syngas ( 8b ) enters the cooling zone in the direction of the gas flow behind the radiant boiler casing ( 4 ), wherein the feed nozzle ( 12 ) is configured for a cooling gaseous, vaporous or liquid external medium ( 12a ). The supply of the external medium (12a) continuous cooling of the synthesis gas in the space (8c) was cooled, then this (13) via a discharge connector (14) away from the cooling space (3) laterally. The slag ( 15 ) is periodically directed out of the reactor ( 1 ) via a gate ( 16 ) and a discharge connector ( 17 ). Section AA is also shown in Figure 1, and its cross section is shown in Figure 2.

圖2展示氣化反應器之橫截面,該橫截面之平面以A-A指示於圖1中。可見冷卻空間之封閉容器、反應空間(2)之內部、用於合成氣之出料連接器(2b)、輻射鍋爐套管(4)、用於冷卻之封閉容器內壁上之管道(9)以及管道(10),該等管道以環形方式配置在冷卻空間(3)側面上。封閉容器(7)之內壁上之管道(9)裝備有沿冷卻空間(3)之幾何中心軸方向同心伸展之冷卻管(9a,「擋板」),以便改良冷卻。根據本發明,燃燒器(11)沿封閉容器之切線方向配置,以便使合成氣接受角動量(8c)。 Figure 2 shows a cross section of a gasification reactor, the plane of which is indicated in Figure 1 by AA. The closed container of the cooling space, the interior of the reaction space ( 2 ), the discharge connector for the synthesis gas ( 2b ), the radiant boiler casing ( 4 ), the pipe on the inner wall of the closed container for cooling ( 9 ) And pipes ( 10 ) arranged in an annular manner on the side of the cooling space ( 3 ). The pipe ( 9 ) on the inner wall of the closed vessel ( 7 ) is equipped with cooling pipes ( 9a , "baffles") concentrically extending in the direction of the geometric central axis of the cooling space ( 3 ) for improved cooling. According to the invention, the burner ( 11 ) is arranged along the tangential direction of the closed container to allow the syngas to receive angular momentum ( 8c ).

1‧‧‧煤氣化反應器 1‧‧‧ coal gasification reactor

2‧‧‧反應空間 2‧‧‧Reaction space

2a‧‧‧反應空間之懸掛裝置 2a‧‧‧suspension device for reaction space

2b‧‧‧合成氣之出料連接器 2b‧‧‧Synchronous gas discharge connector

3‧‧‧冷卻空間 3‧‧‧Cooling space

4‧‧‧輻射鍋爐套管 4‧‧‧radiation boiler casing

4a‧‧‧冷卻板 4a‧‧‧Cooling plate

5‧‧‧爐渣收集槽 5‧‧‧ slag collection tank

5a‧‧‧水浴 5a‧‧‧ water bath

6‧‧‧含碳化石燃料之燃燒器 6‧‧‧ Burners containing carbon fossil fuels

6a‧‧‧含碳化石燃料 6a‧‧‧Carbonized fossil fuel

7‧‧‧耐壓封閉容器 7‧‧‧ Pressure sealed container

8‧‧‧合成氣 8‧‧‧Syngas

8a‧‧‧具有角動量之合成氣 8a‧‧‧ Syngas with angular momentum

8b‧‧‧流出合成氣 8b‧‧‧ out of syngas

8c‧‧‧冷卻空間中具有角動量之合成氣 8c‧‧‧ Syngas with angular momentum in the cooling space

9‧‧‧封閉容器內壁上用於冷卻介質之管道 9‧‧‧The pipe for the cooling medium on the inner wall of the closed container

9a‧‧‧冷卻介質之給料連接器 9a‧‧‧Feeding material feeder connector

9b‧‧‧冷卻介質之出料連接器 9b‧‧‧Draining medium discharge connector

10‧‧‧攜帶冷卻介質之管道 10‧‧‧ Pipes carrying cooling medium

10a‧‧‧冷卻介質之給料連接器 10a‧‧‧Supply connector for cooling medium

10b‧‧‧冷卻介質之出料連接器 10b‧‧‧Draining medium discharge connector

11‧‧‧燃燒器 11‧‧‧ Burner

11a‧‧‧再生性燃料 11a‧‧‧Renewable fuel

12‧‧‧出料之合成氣 12‧‧‧Synthesizing syngas

12a‧‧‧冷卻性氣態、汽態或液態外部介質 12a‧‧‧Cooling gaseous, vaporous or liquid external media

13‧‧‧出料連接器 13‧‧‧Drop connector

14‧‧‧爐渣 14‧‧‧ slag

15‧‧‧閘 15‧‧‧ brake

16‧‧‧出料連接器 16‧‧‧Drop connector

17‧‧‧輻射鍋爐套管之管道 17‧‧‧Pipeline for radiant boiler casing

17a‧‧‧輻射鍋爐套管之管道之給料連接器 17a‧‧‧Feeder connector for pipe of radiant boiler casing

1‧‧‧煤氣化反應器 1‧‧‧ coal gasification reactor

2‧‧‧反應空間 2‧‧‧Reaction space

2a‧‧‧反應空間之懸掛裝置 2a‧‧‧suspension device for reaction space

2b‧‧‧合成氣之出料連接器 2b‧‧‧Synchronous gas discharge connector

3‧‧‧冷卻空間 3‧‧‧Cooling space

4‧‧‧輻射鍋爐套管 4‧‧‧radiation boiler casing

4a‧‧‧冷卻板 4a‧‧‧Cooling plate

5‧‧‧爐渣收集槽 5‧‧‧ slag collection tank

5a‧‧‧水浴 5a‧‧‧ water bath

6‧‧‧含碳化石燃料之燃燒器 6‧‧‧ Burners containing carbon fossil fuels

6a‧‧‧含碳化石燃料 6a‧‧‧Carbonized fossil fuel

7‧‧‧耐壓封閉容器 7‧‧‧ Pressure sealed container

8‧‧‧合成氣 8‧‧‧Syngas

8a‧‧‧具有角動量之合成氣 8a‧‧‧ Syngas with angular momentum

8b‧‧‧流出合成氣 8b‧‧‧ out of syngas

8c‧‧‧冷卻空間中具有角動量之合成氣 8c‧‧‧ Syngas with angular momentum in the cooling space

9‧‧‧封閉容器內壁上用於冷卻介質之管道 9‧‧‧The pipe for the cooling medium on the inner wall of the closed container

9a‧‧‧冷卻介質之給料連接器 9a‧‧‧Feeding material feeder connector

9b‧‧‧冷卻介質之出料連接器 9b‧‧‧Draining medium discharge connector

10‧‧‧攜帶冷卻介質之管道 10‧‧‧ Pipes carrying cooling medium

10a‧‧‧冷卻介質之給料連接器 10a‧‧‧Supply connector for cooling medium

10b‧‧‧冷卻介質之出料連接器 10b‧‧‧Draining medium discharge connector

11‧‧‧燃燒器 11‧‧‧ Burner

11a‧‧‧再生性燃料 11a‧‧‧Renewable fuel

12‧‧‧出料之合成氣 12‧‧‧Synthesizing syngas

12a‧‧‧冷卻性氣態、汽態或液態外部介質 12a‧‧‧Cooling gaseous, vaporous or liquid external media

13‧‧‧出料連接器 13‧‧‧Drop connector

14‧‧‧爐渣 14‧‧‧ slag

15‧‧‧閘 15‧‧‧ brake

16‧‧‧出料連接器 16‧‧‧Drop connector

17‧‧‧輻射鍋爐套管之管道 17‧‧‧Pipeline for radiant boiler casing

Claims (23)

一種具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其包含:●反應空間(2),其適用於藉由與含氧氣體或含水蒸汽及含氧氣體發生反應來氣化固體含碳燃料(6a),且其裝備有燃燒器(6),●第二空間(3),其設計為冷卻空間(3),且其沿氣流(8b)方向配置於該反應空間(2)下方,其中此冷卻空間(3)裝備有用於氣態、汽態及液態冷卻介質(12a)之饋料設備(12),其中●該冷卻空間(3)沿該氣流(8b)方向之至少一個延伸部分裝備有在該冷卻空間(3)內壁上配置之環形輻射鍋爐套管(9),其特徵在於:●配置該輻射鍋爐套管(9)之該冷卻空間(3)之環形部分裝備有燃燒器(11),該等燃燒器(11)經由該輻射鍋爐套管(9)引入該冷卻空間(3)內,再生性燃料(11a)可經由該等燃燒器(11)引入該冷卻空間(3)內,及●該等燃燒器(11)沿該反應器壁(7)之切向以一定角度配置在該冷卻空間(3)中。 A gasification reactor (1) having a device (11) for feeding a regenerative fuel (11a) to a zone of a radiant boiler casing (9) of a gasification reactor (1), comprising: a reaction space ( 2), which is suitable for gasifying a solid carbonaceous fuel (6a) by reacting with an oxygen-containing gas or a water vapor and an oxygen-containing gas, and is equipped with a burner (6), a second space (3), It is designed as a cooling space (3) and is arranged below the reaction space (2) in the direction of the gas flow (8b), wherein the cooling space (3) is equipped with a feed for the gaseous, vaporous and liquid cooling medium (12a) discharge device (12), ● wherein the cooling space (3) equipped with at least a portion extending along the gas stream (8b) has a direction of (3) radiation boilers annular sleeve (9) arranged on the inner wall of the cooling space, which The feature is: • the annular portion of the cooling space (3) configuring the radiant boiler casing (9) is equipped with a burner (11), the burner (11) introducing the cooling via the radiant boiler casing (9) Within the space (3), the regenerative fuel (11a) can be introduced into the cooling space (3) via the burners (11), and the tangential direction of the burners (11) along the reactor wall (7) Take A certain angle is arranged in the cooling space (3). 如申請專利範圍第1項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝 置(11)之氣化反應器(1),其特徵在於管道(9)配置在該冷卻空間(3)內部在該冷卻空間(3)之該內壁(7)上,其中冷卻介質(9a,9b)可沿該氣流(8b)方向流經該等管道(9)。 a gasification reactor (1) having a device (11) for feeding a regenerative fuel (11a) to a zone of a radiant boiler casing (9) of a gasification reactor (1), as claimed in claim 1 The utility model is characterized in that a pipe (9) is arranged inside the cooling space (3) on the inner wall (7) of the cooling space (3), wherein the cooling medium (9a, 9b) can flow in the direction of the air flow (8b) These pipes (9). 如申請專利範圍第1項或第2項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該冷卻空間(3)之該內壁(7)上之該等管道(9)越過特定長度覆蓋該冷卻空間(3)之整個內部周邊,其中冷卻介質(9a,9b)可沿該氣流(8b)方向流經該等管道(9)。 A device (11) having a regenerative fuel (11a) fed to a zone of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 or 2 a gasification reactor (1), characterized in that the pipes (9) on the inner wall (7) of the cooling space (3) cover the entire inner periphery of the cooling space (3) over a specific length, wherein the cooling medium (9a, 9b) can flow through the tubes (9) in the direction of the gas stream (8b). 如申請專利範圍第2項或第3項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於環形壁(4)作為輻射鍋爐套管(4)定位在該冷卻空間(3)之該壁(7)與該等管道(9)之間。 A device (11) having a regenerative fuel (11a) fed to a zone of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 2 or 3. A gasification reactor (1) characterized in that an annular wall (4) is positioned as a radiant boiler casing (4) between the wall (7) of the cooling space (3) and the pipes (9). 如申請專利範圍第1項至第4項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於其他管道(10)定位在該冷卻空間(3)內部,冷卻介質(10a,10b)可沿該氣流(8b)方向流經該等管道(10),且該等管道(10)藉由其沿該冷卻空間(3)之幾何中心軸之同心方向平行配置來進行配置。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 4 a gasification reactor (1), characterized in that other pipes (10) are positioned inside the cooling space (3), and the cooling medium (10a, 10b) can flow through the pipes (10) in the direction of the gas flow (8b), And the pipes (10) are arranged by their parallel arrangement along the concentric direction of the geometric central axis of the cooling space (3). 如申請專利範圍第5項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝 置(11)之氣化反應器(1),其特徵在於另一環形壁(4)作為輻射鍋爐套管圍繞同心配置之該等管道(10)定位。 a gasification reactor (1) having a device (11) for feeding a regenerative fuel (11a) to a zone of a radiant boiler casing (9) of a gasification reactor (1), as in claim 5, It is characterized in that the other annular wall (4) is positioned as a radiant boiler casing around the conduits (10) arranged concentrically. 如申請專利範圍第1項至第6項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該另一環形壁(4)由耐熱板(4)組成。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 6. A gasification reactor (1), characterized in that the other annular wall (4) consists of a heat-resistant plate (4). 如申請專利範圍第1項至第6項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該另一環形壁(4)含有內部引導間接冷卻的介質(10a,10b)之管道(10)。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 6. A gasification reactor (1), characterized in that the further annular wall (4) contains a conduit (10) which internally directs the indirectly cooled medium (10a, 10b). 如申請專利範圍第8項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於管道(10)在該另一環形壁(4)之該反應空間側(3)上圍繞該反應空間(3)之幾何中心軸環形伸展,且冷卻介質(10a,10b)可流經該等管道(10)。 a gasification reactor (1) having a device (11) for feeding a regenerative fuel (11a) to a zone of a radiant boiler casing (9) of a gasification reactor (1), as in claim 8 It is characterized in that the pipe (10) extends annularly around the geometric central axis of the reaction space (3) on the reaction space side (3) of the other annular wall (4), and the cooling medium (10a, 10b) can flow through These pipes (10). 如申請專利範圍第1項至第6項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該另一環形壁(4)由同心圍繞該冷卻空間(3)之以空心圓柱方式設計之容器組成。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 6. A gasification reactor (1), characterized in that the further annular wall (4) consists of a container designed concentrically around the cooling space (3) in a hollow cylindrical manner. 如申請專利範圍第1項至第10項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管 (9)區域內之裝置(11)之氣化反應器(1),其特徵在於該等燃燒器(11)設計為燃燒槍。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 10 A gasification reactor (1), characterized in that the burners (11) are designed as combustion burners. 如申請專利範圍第1項至第10項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該等燃燒器(11)設計為噴嘴。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 10 A gasification reactor (1), characterized in that the burners (11) are designed as nozzles. 如申請專利範圍第1項至第12項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該等燃燒器(11)或燃燒槍經配置以使其沿該氣流(8b)方向處於該反應空間(2)之出料連接器(2b)之前方,以使其在操作期間處於該合成氣之流影(flow shadow)中。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 12 a gasification reactor (1) characterized in that the burner (11) or the burner is configured such that it is in the direction of the gas stream (8b) before the discharge connector (2b) of the reaction space (2) So that it is in the flow shadow of the syngas during operation. 如申請專利範圍第1項至第13項中任一項之具有將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之裝置(11)之氣化反應器(1),其特徵在於該反應空間(2)及該冷卻空間(3)由置於彼此之上之具有不同直徑之兩個壓力容器組成,其中該冷卻空間壓力容器(3)之直徑比該反應空間壓力容器(2)之直徑大。 A device (11) having a regenerative fuel (11a) fed to a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in any one of claims 1 to 13 a gasification reactor (1), characterized in that the reaction space (2) and the cooling space (3) are composed of two pressure vessels having different diameters placed on each other, wherein the cooling space pressure vessel (3) The diameter is larger than the diameter of the reaction space pressure vessel (2). 一種將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法,其中將自外部沿水平方向同心或向下引導之細粉狀含碳燃料(6a)與氧氣或含氧氣體之混合物自上方注入耐火反應空間(2)內,以便使該燃料(6a)在該反應空間(2)中在挾帶流氣化反應(8a)中反應形成合成氣(8b),及 所獲得之該合成氣(8b)在0.5 MPa至8 MPa之壓力下且沿向上或向下方向自該反應空間(2)引出,及在完成引出之後,將由此獲得之該合成氣(8b)引入設計為冷卻空間(3)之第二反應空間(3)內,且在該第二反應空間(3)中將出於冷卻目的所供應之該氣體(8b)與冷卻器氣態、汽態或液態外部介質(12a)混合,其特徵在於在該反應空間(2)與用於外部介質(12a)之饋料點(12)之間,再生性燃料(11a)經由該輻射鍋爐套管(9)經由至少一個燃燒器(11)同心饋料至該冷卻空間(3)內,以便產生另一挾帶流氣化反應(8c),經由該另一挾帶流氣化反應(8c),該流出氣體(8b)之溫度下降且焓差用於再生性原料(11a)之附加氣化,及該再生性燃料(11a)沿該冷卻空間(3)之該壁(7)之切線方向以一定角度注入該冷卻空間(3),以使該再生性燃料(11a)在注入來自該反應空間(2)之該原料氣流(8b)內期間接受角動量(8c)。 A method of feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1), wherein finely powdered carbonaceous fuel is guided concentrically or downwardly from the outside in a horizontal direction (6a) a mixture with oxygen or an oxygen-containing gas is injected into the fire-resistant reaction space (2) from above to cause the fuel (6a) to react in the gas stream reaction (8a) in the reaction space (2) to form a synthesis The gas (8b), and the obtained synthesis gas (8b) are taken out from the reaction space (2) at a pressure of 0.5 MPa to 8 MPa and upward or downward, and after the completion of the extraction, the thus obtained The synthesis gas (8b) is introduced into a second reaction space (3) designed as a cooling space (3), and the gas (8b) supplied for cooling purposes is cooled in the second reaction space (3) Mixing a gaseous, vaporous or liquid external medium (12a) characterized by a regenerative fuel (11a) passing between the reaction space (2) and a feed point (12) for the external medium (12a) a radiant boiler casing (9) is fed concentrically into the cooling space (3) via at least one burner (11) to produce another enthalpy flow gasification reaction (8c), From the other gas stream reaction (8c), the temperature of the effluent gas (8b) is lowered and the enthalpy difference is used for additional gasification of the regenerative raw material (11a), and the regenerative fuel (11a) is along the cooling space. (3) the tangential direction of the wall (7) is injected into the cooling space (3) at an angle such that the regenerative fuel (11a) is injected into the raw material gas stream (8b) from the reaction space (2) Accept angular momentum (8c). 如申請專利範圍第15項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法,其特徵在於將精細切碎、壓碎、精細研磨之能源作物、任何形式之木材、稻草、牧草、穀類、生物殘餘物、海洋植物或家畜糞肥用作再生性燃料(11a)。 A method for feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1) as claimed in claim 15 is characterized in that it is finely chopped, crushed, and finely Grinded energy crops, any form of wood, straw, pasture, cereals, biological residues, marine plants or livestock manure are used as regenerative fuels (11a). 如申請專利範圍第15項或第16項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9) 區域內之方法,其特徵在於該等再生性燃料(11a)在氣化之前進行預處理,其中該等預處理步驟包括乾燥、碳化、研磨或此等步驟之組合。 A method of feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1) according to any one of claims 15 or 16, wherein The regenerative fuel (11a) is pretreated prior to gasification, wherein the pretreatment steps include drying, carbonization, milling, or a combination of such steps. 如申請專利範圍第15項至第17項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法,其特徵在於將該再生性燃料(11a)與含氧氣體、水蒸汽、或含氧氣體及水蒸汽之混合物引入該冷卻空間內。 A method of feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1) according to any one of claims 15 to 17, characterized in that The regenerative fuel (11a) is introduced into the cooling space with an oxygen-containing gas, water vapor, or a mixture of an oxygen-containing gas and water vapor. 如申請專利範圍第15項至第18項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法,其特徵在於將再生性燃料與含碳燃料之混合物用作該冷卻空間(3)中之該等燃燒器(11)之燃料(11a)。 A method of feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1) according to any one of claims 15 to 18, characterized in that A mixture of regenerative fuel and carbonaceous fuel is used as the fuel (11a) for the burners (11) in the cooling space (3). 如申請專利範圍第15項至第19項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法,其特徵在於由該輻射鍋爐套管(9,10)中之外部介質(9a,10a)吸收之該合成氣(8b)之熱量用於產生蒸汽(9b,10b)或高壓蒸汽(9b,10b)。 A method of feeding a regenerative fuel (11a) into a region of a radiant boiler casing (9) of a gasification reactor (1) according to any one of claims 15 to 19, characterized in that The heat of the syngas (8b) absorbed by the external medium (9a, 10a) in the radiant boiler casing (9, 10) is used to generate steam (9b, 10b) or high pressure steam (9b, 10b). 一種如申請專利範圍第15項至第20項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法的用途,其特徵在於所產生之該合成氣(13)用於在發電廠中發電。 A patent application range of items 20 to 15, any one of a fuel nature Jiangzai (11a) fed to the gasification reactor feed (1) of the radiation boiler casing (9) Use of the method within the region, which It is characterized in that the syngas (13) produced is used to generate electricity in a power plant. 一種如申請專利範圍第15項至第21項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套 管(9)區域內之方法的用途,其特徵在於所產生之該合成氣(13)在自燃燒氣體分離二氧化碳之情況下用於在發電廠中發電。 A patent application scope items 15 to 21 in any one Jiangzai nature of the fuel (11a) fed to the gasification reactor feed (1) of the radiation boiler Use of the method within the sleeve region (9), which It is characterized in that the syngas (13) produced is used to generate electricity in a power plant in the case of separating carbon dioxide from combustion gases. 一種如申請專利範圍第15項至第22項中任一項之將再生性燃料(11a)饋料至氣化反應器(1)之輻射鍋爐套管(9)區域內之方法的用途,其特徵在於所產生之該合成氣(13)用於產生合成馬達燃料或合成天然氣。 A patent application scope items 15 to 22 in any one Jiangzai nature of the fuel (11a) fed to the gasification reactor feed (1) of the radiation boiler Use of the method within the sleeve region (9), which It is characterized in that the syngas (13) produced is used to produce synthetic motor fuel or synthetic natural gas.
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