TW201315394A - Filter cigarette - Google Patents

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Publication number
TW201315394A
TW201315394A TW100137120A TW100137120A TW201315394A TW 201315394 A TW201315394 A TW 201315394A TW 100137120 A TW100137120 A TW 100137120A TW 100137120 A TW100137120 A TW 100137120A TW 201315394 A TW201315394 A TW 201315394A
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Taiwan
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filter
cigarette
paper
rod
attached
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TW100137120A
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Chinese (zh)
Inventor
Wakako Kanto
Fumihiro Omori
Yoshitaka Ide
Hiroyoshi Ono
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Japan Tobacco Inc
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Abstract

The invention provides a filter cigarette having a cigarette rod containing shredded tobacco leaves wrapped with a cigarette paper in a rod shape, a filter rod provided at one end of the cigarette rod and containing a filter element wrapped with a filter paper, and a tip paper covering the outer peripheral surface of the filter rod and a part of the outer peripheral surface of the cigarette rod. The tip paper carries a feeling-stimulant and the filter paper is hardly pervious to the feeling-stimulant.

Description

附有過濾器之香煙Cigarette with filter

本發明係有關於一種附有過濾器(filter)之香煙(cigarette)。The present invention relates to a cigarette with a filter attached thereto.

香煙係為享受煙草(tobacco)葉之香味之代表性之吸煙物品。近年來,因應吸煙者多樣化之嗜好,係於香煙之各種部位添加與煙草絲所賦予之香味不同之感覺刺激劑。例如,專利文獻1係揭示,於連接香煙棒(cigarette rod)與過濾器棒(filter rod)之外層紙(tip paper)添加冷感劑之技術。添加於外層紙之冷感劑係為對於吸煙時與外層紙直接接觸之吸煙者嘴唇賦予直接冷感,藉此使吸煙者感受到持續的爽快感。Cigarettes are representative smoking articles that enjoy the aroma of tobacco leaves. In recent years, in response to the diversification of smokers, a sensory stimulant different from the scent imparted by tobacco silk is added to various parts of the cigarette. For example, Patent Document 1 discloses a technique of adding a cold sensitizer to a tip paper which is connected to a cigarette rod and a filter rod. The cold sensitizer added to the outer paper imparts a direct cold sensation to the lips of the smoker who is in direct contact with the outer paper when smoking, thereby allowing the smoker to feel a continuous refreshing feeling.

(先前技術文獻)(previous technical literature) (專利文獻)(Patent Literature)

(專利文獻1)日本國特開2009-148233號(Patent Document 1) Japanese Special Opening 2009-148233

然而,具備添加感覺刺激劑之外層紙之附有過濾器之香煙,係於保存中感覺刺激劑自外層紙轉移至香煙其他部位、尤其是過濾器中,造成外層紙上之感覺刺激劑之量減少。結果,直接賦予吸煙者之嘴唇之感覺刺激減弱。However, a cigarette with a filter attached to the outer layer of the sensory stimulant is used to transfer the sensory stimulant from the outer layer to other parts of the cigarette, especially the filter, resulting in a reduction in the amount of sensory stimulant on the outer sheet. . As a result, the sensory stimulation directly imparted to the smoker's lips is weakened.

因此本發明之目的係為提供一種必然抑制添加於外層紙之感覺刺激劑轉移至過濾器之附有過濾器之香煙。It is therefore an object of the present invention to provide a filter-attached cigarette that necessarily inhibits the transfer of the sensory stimulator added to the outer layer to the filter.

本發明係提供一種附有過濾器之香煙,係具備:以捲煙紙將煙草絲包成棒狀之香煙棒;設置於前述香煙棒一端面,且以過濾器捲紙將過濾器素材包成棒狀之過濾器棒;及包覆前述過濾器棒之外周面的同時,局部地包覆前述香煙棒之外周面之外層紙;其中,前述外層紙係附著有感覺刺激劑,前述過濾器捲紙係為感覺刺激劑難滲透性。The invention provides a cigarette with a filter, which comprises: a cigarette rod which is wrapped with tobacco paper into a stick shape; and is arranged on one end surface of the cigarette rod, and the filter material is wrapped into a rod by a filter paper roll. a filter rod having a shape; and coating the outer surface of the outer surface of the cigarette rod while covering the outer peripheral surface of the filter rod; wherein the outer paper is attached with a feeling stimulating agent, the filter paper roll It is a sensory irritant that is difficult to penetrate.

本發明之附有過濾器之香煙,係必然地抑制添加於外層紙之感覺刺激劑轉移至過濾器。The cigarette with the filter of the present invention inevitably inhibits the transfer of the sensory stimulator added to the outer layer paper to the filter.

以下係說明本發明之各種實施形態。Hereinafter, various embodiments of the present invention will be described.

本發明之一實施形態的附有過濾器之香煙係具備香煙棒、過濾器棒、及外層紙。香煙棒係具備煙草絲、及將此煙草絲包成香煙狀(通常為圓柱狀)之捲煙紙。過濾器棒係具備過濾器素材、及將此過濾器素材包成棒狀(通常為圓柱狀)之過濾器捲紙。過濾器棒係藉由外層紙被安裝於香煙棒之一端面。外層紙係包覆過濾器棒(更詳細而言係為過濾器捲紙)之外周,且局部地包覆香煙棒(更詳細而言係為捲煙紙)之外周。A cigarette with a filter according to an embodiment of the present invention includes a cigarette rod, a filter rod, and an outer layer paper. The cigarette rod is provided with a tobacco yarn and a cigarette paper in which the tobacco yarn is wrapped into a cigarette shape (usually a cylindrical shape). The filter rod has a filter material and a filter roll that wraps the filter material into a rod shape (usually a cylindrical shape). The filter rod is attached to one end of the cigarette rod by the outer paper. The outer paper is coated with a filter rod (more specifically, a filter roll paper) and peripherally coated with a cigarette rod (more specifically, a cigarette paper).

構成香煙棒之煙草絲及捲煙紙係與一般香煙所使用之煙草絲及捲煙紙相同。The tobacco yarn and cigarette paper constituting the cigarette rod are the same as the tobacco yarn and cigarette paper used in general cigarettes.

雖外層紙亦為與一般附有過濾器之香煙所使用之外層紙相同,惟於本發明中,係附著有感覺刺激劑。就感覺刺激劑而言,係以冷感劑為佳。冷感劑係可選擇自例如3-1-薄荷氧基丙烷-1,2-二醇(3-1-menthoxy propane-1,2-diol)、N-乙基-對-薄荷烷-3-甲醯胺(N-ethyl-p-menthane-3-carboxamide)、3-1-薄荷氧基-2-甲基丙烷-1,2-二醇(3-1-menthoxy-2-methyl propane-1,2-diol)、薄荷醇(menthol)、薄荷酮(menthone)、樟腦(camphor)、洋薄荷醇(pulegol)、異洋薄荷醇(isopulegol)、桉樹腦(cineole)、薄荷油(mint oil)、胡椒薄荷(peppermint)油、綠薄荷(spearmint)油、桉樹(eucalyptus)油、對-薄荷烷-3,8-二醇(p-menthane-3,8-diol)、2-1-薄荷氧基乙烷-1-醇(2-1-menthoxyethane-1-ol)、3-1-薄荷氧基丙烷-1-醇(3-1-menthoxypropane-1-ol)、4-1-薄荷氧基丁烷-1-醇(4-1-menthoxybutane-1-ol)、3-羥基丁酸薄荷酯(menthyl 3-hydroxybutanoate)、乳酸薄荷酯、薄荷酮丙三醇縮醛(menthone glycerin acetal)、2-(2-1-薄荷氧基乙基)乙醇(2-(2-1-menthyloxyethyl)ethanol)、乙醛酸薄荷酯(menthyl glyoxylate)、1-(2-羥基-4-甲基環乙基)乙酮(1-(2-hydroxy-4-methylcyclohexyl)ethanone)、N-甲基-2,2-異丙基甲基-3-甲基丁醯胺(N-methyl-2,2-isopropylmethyl-3-methylbutane amide)、2-吡咯啶酮-5-羧酸薄荷酯(menthyl 2-pyrrolidone-5-carboxylate)、2-異丙基-N-2,3-三甲基丁醯胺1,2-丙二醇(2-isopropyl-N-2,3-trimethylbutyramide 1,2-propane diol)所構成之群中。如冷感劑之感覺刺激劑係可塗佈於外層紙上。Although the outer layer paper is also the same as the outer layer paper used for the cigarette to which the filter is generally attached, in the present invention, the sensory stimulating agent is attached. In the case of a feeling stimulant, a cold sensitizer is preferred. The cold sensitizer can be selected, for example, from 3-1-1-menthoxypropane-1,2-diol, N-ethyl-p-menthane-3- N-ethyl-p-menthane-3-carboxamide, 3-1-1-menthoxy-2-methylpropane-1,2-diol (3-1-menthoxy-2-methyl propane-1) , 2-diol), menthol, menthone, camphor, pulegol, isopulegol, cineole, mint oil , peppermint oil, spearmint oil, eucalyptus oil, p-menthane-3,8-diol, 2-1-menthol 2-ephthyl-1-ol, 3-1-1-menthoxypropane-1-ol, 4-1-menthyloxy Butyr-1-butan-1-ol, menthyl 3-hydroxybutanoate, menthyl lactate, menthone glycerin acetal, 2 -(2-1-menthyloxyethyl)ethanol, menthyl glyoxylate, 1-(2-hydroxy-4-methylcycloethyl Ethyl ketone (1-(2-hydroxy-4-methylc) Yclohexyl)ethanone), N-methyl-2,2-isopropylmethyl-3-methylbutane amide, 2-pyrrolidone- Menthyl 2-pyrrolidone-5-carboxylate, 2-isopropyl-N-2,3-trimethylbutanamine 1,2-propanediol (2-isopropyl-N-2,3 -trimethylbutyramide 1,2-propane diol). A sensory stimulator such as a cold sensitizer can be applied to the outer layer of paper.

構成過濾器棒之過濾器素材,係可為與一般附有過濾器之香煙所使用之過濾器素材相同。於該過濾器素材係含有乙酸纖維素纖維(cellulose acetate)之纖維束(tow)。乙酸纖維素纖維之纖維束係可含有5至10重量%之比例之如甘油三乙酸酯(triacetin)之可塑劑。然而,過濾器素材係以不含可塑劑、亦即無(free)可塑劑者為佳。可塑劑係有吸附感覺刺激劑且減弱感覺刺激之傾向。就不含可塑劑之過濾器素材而言,可例示(不含可塑劑之)乙酸纖維素纖維之纖維束、紙(paper)等。The filter material constituting the filter rod may be the same as the filter material used for the cigarette to which the filter is generally attached. The filter material contains a tow of cellulose acetate. The fiber bundle of cellulose acetate fibers may contain a plasticizer such as triacetin in a proportion of 5 to 10% by weight. However, the filter material is preferably a plasticizer free, that is, a free plasticizer. Plasticizers have a tendency to adsorb sensory stimuli and attenuate sensory stimuli. As the filter material containing no plasticizer, a fiber bundle, paper, or the like of cellulose acetate fibers (excluding a plasticizer) can be exemplified.

與過濾器素材構成過濾器棒之過濾器捲紙,係為對於感覺刺激劑為難滲透性,亦即不易使感覺刺激劑滲透者。就不易滲透感覺刺激劑之過濾器捲紙而言,雖可考慮塑膠薄膜(plastic film)或塑膠薄膜與紙之積層(laminate)加工紙,惟此等透氣性不佳,例如,具有14至20μm之聚乙烯(polyethylene)層之一般的積層加工紙為不易滲透水分且有與以往之香煙相比味道會變化之情形。再者,雖可考慮習知之具有耐油性與水蒸氣滲透性之使用氟系化合物之加工紙來作為耐油紙,惟因不易分解故對地球環境而言不佳。如此,本發明所使用之過濾器捲紙較佳為,實質上雖不使感覺刺激劑滲透,惟具有水蒸氣滲透性並且對環境較佳之玻璃紙(glassine)及描圖紙(tracing paper)、羊皮紙(parchment)(硫酸紙)等。尤其,較佳為使用具備基重30至60g/m2之基重之基層(base)紙、及塗佈於前述基層紙至少單面之水溶性高分子物質,且顯現50,000至300,000秒之抗透氣度與2,000至4,000g/m2‧24hr之透溼度之耐油紙作為過濾器捲紙。如此之紙係記載於日本國專利第4520138號,由日本製紙PAPYLIA股份有限公司於所販售。依據日本國專利第4520138號,該耐油紙之基層紙係為:於肖柏(Schopper)濾水度85至90°SR之製紙用天然纖維含有相對於纖維為2至10質量%之對光線之折射率為1.8至3.0之填料者,並顯現50,000至200,000秒之抗透氣度。高分子物質係可選擇自氧化澱粉、有機磷酸鹽化澱粉、乙醯化(acetylation)澱粉、未變性澱粉、羧甲基纖維(carboxymethylcellulose)鹽,並以0.2至1.0 g/m2之比例塗佈於基層紙上。就塗料而言,係列舉有金紅石(rutile)型二氧化鈦(titanium)(折射率2.76)、銳錐石(anatase)型二氧化鈦(折射率2.52)、氧化鋯石(zircon)(折射率2.40)、氧化鋅(折射率2.01)等無機顏料、二氧化鈦披覆雲母(折射率2.3)、氧化鐵披覆雲母(折射率2.9)、二氧化鈦披覆二氧化矽(silica)、披覆二氧化鈦之玻璃薄板(glass flake)等複合顏料。該等填料係對於製紙用天然纖維添加2至10質量%,較佳為填加3至7質量%。The filter roll paper constituting the filter rod with the filter material is impenetrable to the sensory stimulating agent, that is, it is difficult to permeate the sensory stimulating agent. In the case of a filter roll paper which is not easily permeable to a feeling stimulating agent, although a plastic film or a plastic film and a paper laminating paper may be considered, the gas permeability is not good, for example, 14 to 20 μm. A general laminated paper of a polyethylene layer is a case in which moisture is not easily permeable and the taste is changed as compared with a conventional cigarette. Further, although a conventional processing paper using a fluorine-based compound having oil resistance and water vapor permeability can be considered as an oil-resistant paper, it is not preferable for the global environment because it is hard to be decomposed. Thus, the filter roll paper used in the present invention is preferably a glassine and a tracing paper, parchment which is substantially water vapor permeable and environmentally friendly, although it does not penetrate the sensory irritant. Parchment) (sulphuric acid paper) and the like. In particular, it is preferred to use a base paper having a basis weight of 30 to 60 g/m 2 and a water-soluble polymer substance coated on at least one side of the base paper, and exhibit an anti-wear resistance of 50,000 to 300,000 seconds. Oil-resistant paper with a gas permeability of 2,000 to 4,000 g/m 2 ‧24 hrs as a filter roll paper. Such a paper is described in Japanese Patent No. 4520138, and is sold by Nippon Paper PAPYLIA Co., Ltd. According to Japanese Patent No. 4520138, the base paper of the oil-resistant paper is: the natural fiber of papermaking having a water filtration degree of 85 to 90° SR of Schopper contains a refraction of 2 to 10% by mass relative to the fiber. A filler of 1.8 to 3.0 and exhibits a gas permeability of 50,000 to 200,000 seconds. The polymer material may be selected from the group consisting of self-oxidized starch, organic phosphated starch, acetylated starch, unmodified starch, carboxymethylcellulose salt, and coated at a ratio of 0.2 to 1.0 g/m 2 . On the base paper. In terms of coatings, the series includes rutile type titanium dioxide (refractive index of 2.76), anatase type titanium dioxide (refractive index of 2.52), zirconium (zircon) (refractive index of 2.40), Inorganic pigment such as zinc oxide (refractive index 2.01), titanium dioxide coated mica (refractive index 2.3), iron oxide coated mica (refractive index 2.9), titanium dioxide coated with silica, glass coated with titanium dioxide (glass) Fluke) and other composite pigments. These fillers are added in an amount of 2 to 10% by mass, preferably 3 to 7% by mass, to the natural fibers for papermaking.

第1圖係為本發明之一實施形態之附有過濾器之香煙100之概略剖面圖。此附有過濾器之香煙100係具備香煙棒110、過濾器棒120、及外層紙130。Fig. 1 is a schematic cross-sectional view showing a cigarette 100 with a filter according to an embodiment of the present invention. The cigarette 100 with the filter is provided with a cigarette rod 110, a filter rod 120, and an outer layer paper 130.

香煙棒110係為以捲煙紙112將煙草絲111包覆成棒狀(一般係為圓柱狀)者。過濾器棒120係為以過濾器捲紙122將乙酸纖維素纖維之纖維束等過濾器素材121包覆成棒狀(一般係為圓柱狀)者,且具有與香煙棒大致相同之直徑。香煙棒110與過濾器棒120係彼此之端面與端面相接觸,且由附著有感覺刺激劑(未圖示)之外層紙130所固定。外層紙130係包覆過濾器棒之外周面,且局部地包覆香煙棒之外周面。The cigarette rod 110 is a case in which the tobacco yarn 111 is covered with a cigarette paper 112 in a rod shape (generally, a column shape). The filter rod 120 is formed by coating the filter material 121 such as a fiber bundle of cellulose acetate fibers into a rod shape (generally a columnar shape) with a filter roll 122, and has substantially the same diameter as the cigarette rod. The cigarette rod 110 and the filter rod 120 are in contact with each other at the end surface and the end surface, and are fixed by a layer paper 130 to which a feeling stimulating agent (not shown) is attached. The outer layer paper 130 covers the outer peripheral surface of the filter rod and partially covers the outer peripheral surface of the cigarette rod.

接著,藉由實施例說明本發明,惟本發明非為由該等實施例所限定者。The invention is illustrated by the following examples, but the invention is not limited by the examples.

(實施例)(Example)

準備具有下述表1所示之規格之香煙。比較例之附有過濾器之香煙係為市售品。本發明之香煙係為,僅所使用之過濾器捲紙或過濾器素材與比較例之附有過濾器之香煙不同。作為過濾器捲紙使用之50NFB係為由日本製紙PAPYLIA股份有限公司所販售之耐油紙,基重(有稱為「磅數」之情形,表示紙張單位面積的重量)為35 g/m2,依據JIS P-8117:2009所測量出之抗透氣度為130,000秒,依據JIS Z0208-1976所記載之防濕包裝材料之透溼度試驗方法(卡普法),於溫度40±0.5℃、相對溼度90±2%之條件下測量出之透溼度為2,700g/m2‧24hr。P10000係為由日本製紙PAPYLIA股份有限公司所販售之一般過濾器捲紙。A cigarette having the specifications shown in Table 1 below was prepared. The cigarette with the filter of the comparative example is a commercially available product. The cigarette of the present invention is such that only the filter paper or filter material used is different from the cigarette with the filter of the comparative example. The 50NFB used as the filter roll paper is an oil-resistant paper sold by Nippon Paper PAPYLIA Co., Ltd., and the basis weight (in the case of "pounds", the weight per unit area of the paper) is 35 g/m 2 . According to JIS P-8117:2009, the air resistance is 130,000 seconds, according to the moisture permeability test method (Kap method) of the moisture-proof packaging material described in JIS Z0208-1976, at a temperature of 40 ± 0.5 ° C, relative humidity The moisture permeability measured under conditions of 90 ± 2% was 2,700 g/m 2 ‧24 hr. P10000 is a general filter roll paper sold by Nippon Paper PAPYLIA Co., Ltd.

於附有過濾器之香煙A至C各三支之外層紙,塗佈冷感劑(N-乙基-對-薄荷烷-3-甲醯胺)或(3-1-薄荷氧基丙烷-1,2-二醇),於55℃之恆溫室保存預定之期間。之後,係藉由以下手法抽出殘留於外層紙之冷感劑,並予以定量。算出將冷感劑初期之添加量設為100%時之冷感劑的殘留率(三支之平均值)。將結果顯示於下述表2。On the outer layer of three cigarettes A to C with filter, coated with cold sensitizer (N-ethyl-p-menthane-3-carboxamide) or (3-1-menthoxypropane- 1,2-diol), stored in a constant temperature chamber at 55 ° C for a predetermined period of time. Thereafter, the cold sensitizer remaining on the outer layer paper was taken out and quantified by the following method. The residual ratio (average value of the three branches) of the cold sensitizer when the amount of the initial addition of the cold sensitizer was 100% was calculated. The results are shown in Table 2 below.

(冷感劑之抽出、定量手法)(Extraction of cold sensitizer, quantitative method)

由保存後之附有過濾器之香煙切取外層紙,添加乙醇10ml,搖晃1小時。以GC/MS將搖晃後之抽出液所含之冷感劑予以定量。The outer layer paper was cut out from the cigarette with the filter attached thereto, and 10 ml of ethanol was added thereto, followed by shaking for 1 hour. The cold sensitizer contained in the extract after shaking was quantified by GC/MS.

由表格2所示之結果得知,本發明之附有過濾器之香煙係為,冷感劑之殘留率遠比比較例之附有過濾器之香煙之冷感劑之殘留率高。再者,於使用不含可塑劑之素材作為過濾器素材之情形時,上述之殘留率會更加提升。As is apparent from the results shown in Table 2, in the filter-attached cigarette of the present invention, the residual ratio of the cold sensitizer is much higher than that of the cold sensitizer of the cigarette with the filter of the comparative example. Furthermore, when the material containing no plasticizer is used as the filter material, the above residual ratio is further improved.

100...附有過濾器之香煙100. . . Cigarette with filter

110...香煙棒110. . . Cigarette stick

111...煙草絲111. . . Tobacco silk

112...捲煙紙112. . . Cigarette paper

120...過濾器棒120. . . Filter rod

121...過濾器素材121. . . Filter material

122...過濾器捲紙122. . . Filter roll paper

130...外層紙130. . . Outer paper

第1圖係為表示本發明之一實施形態之附有過濾器之香煙的剖面圖。Fig. 1 is a cross-sectional view showing a cigarette with a filter according to an embodiment of the present invention.

100...附有過濾器之香煙100. . . Cigarette with filter

110...香煙棒110. . . Cigarette stick

111...煙草絲111. . . Tobacco silk

112...捲煙紙112. . . Cigarette paper

120...過濾器棒120. . . Filter rod

121...過濾器素材121. . . Filter material

122...過濾器捲紙122. . . Filter roll paper

130...外層紙130. . . Outer paper

Claims (4)

一種附有過濾器之香煙,係具備:香煙棒,係以捲煙紙將煙草絲包覆成棒狀而成者;過濾器棒,係設置於前述香煙棒之一端面,且以過濾器捲紙將過濾器素材包覆成棒狀而成者;及外層紙,係包覆前述過濾器棒之外周面的同時,局部地包覆前述香煙棒之外周面;其中,前述外層紙係附著有感覺刺激劑,前述過濾器捲紙係為感覺刺激劑難滲透性。A cigarette with a filter comprising: a cigarette rod, which is formed by wrapping a tobacco wire into a rod shape with a cigarette paper; and a filter rod disposed on one end surface of the cigarette rod and being wound by a filter And coating the filter material into a rod shape; and coating the outer peripheral surface of the cigarette rod while covering the outer surface of the filter rod; wherein the outer paper has a feeling attached thereto The irritant, the filter paper roll described above is a sensory irritant that is difficult to penetrate. 如申請專利範圍第1項之附有過濾器之香煙,其中,前述過濾器捲紙係為耐油紙,該耐油紙係具備:具有30至60g/m2之基重之基層紙、及塗佈於前述基層紙之至少單面之水溶性高分子物質,並顯示有50,000至300,000秒之抗透氣度及2,000至4,000 g/m2‧24hr之透溼度。The cigarette with a filter according to the first aspect of the invention, wherein the filter paper is an oil-resistant paper comprising: a base paper having a basis weight of 30 to 60 g/m 2 , and coating The water-soluble polymer material on at least one side of the aforementioned base paper, and exhibits an air permeability of 50,000 to 300,000 seconds and a moisture permeability of 2,000 to 4,000 g/m 2 ‧24 hr. 如申請專利範圍第1項之附有過濾器之香煙,其中,前述香料係為冷感劑。A cigarette attached with a filter according to the first aspect of the invention, wherein the fragrance is a cold sensitizer. 如申請專利範圍第1項之附有過濾器之香煙,其中,前述過濾器素材係不含可塑劑。A cigarette attached with a filter according to the first aspect of the invention, wherein the filter material is free of a plasticizer.
TW100137120A 2011-10-13 2011-10-13 Filter cigarette TW201315394A (en)

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