TW201313317A - Process for speeding up photo catalysis reaction by ethylene diamine tetraacetic acid-iron complex - Google Patents

Abstract

The present invention relates to a process for speeding up photo catalysis reaction by ethylene diamine tetraacetic acid-iron complex (EDTA-Fe). Primarily, the EDTA-Fe has formations of ethylene diamine tetraacetic acid and ferrous ions to serve as an electron transfer mudium, and after being illuminated, it can be used to speed up the catalysis and degradation of polluted organism in various environments. During the photo catalyst reaction with addition of titanium into a EDTA-FE solution, it is found that the efficiency for degradation of crystal violet can be substantially promoted. As a result, EDTA-Fe complex is appropriately used as an electron transfer medium to efficiently speed up the degradation of polluted organism.

Description

Method for accelerating photocatalytic reaction by ethylenediaminetetraacetic acid-iron complex

The invention relates to a method for accelerating photocatalytic reaction with ethylenediaminetetraacetic acid-iron complex, in particular to an ethylene diamine tetraacetic acid (EDTA) and an iron ion complex. The medium, which is used to accelerate the photocatalytic reaction to degrade organic pollutants, is the inventor of the invention.

According to titanium dioxide (TiO2), a compound with semiconducting properties, it appears as white particles at normal temperature and pressure, and is often used as a catalytic particle for photocatalytic reaction. After being irradiated by a light source (generally an ultraviolet light source), electrons and electricity are generated. Hole, but has the ability to sterilize and decontaminate. In the third-generation Dayang energy-sensitive sensitized battery, TiO2 is also used as the material for the electron hole and the electrons are exported by a specific dye to form an electric current. The photocatalytic reaction of titanium dioxide (TiO2) for pollutant degradation has the following advantages and considerable development potential:
(1) The reaction can be carried out under normal temperature and normal pressure.
(2) A cyclic intermediate product such as a photolysis reaction can be avoided.
(3) Mineralization of organic pollutants is feasible.
(4) Economically viable.
(5) High operability, such as easy to cover on different media.
(6) The reactivity after the nanocrystallization can be further increased.

In addition, EDTA is often used for metal chelation, which is medically removing excess metal antidote in the body; it is a heavy metal ion remover in the ring, and EDTA is easy to grasp positive metal ions due to multiple negatively charged ligands. . When EDTA is misaligned with iron, an EDTA-Fe complex can be formed and the ability to catalyze the degradation of environmental organic matter has been demonstrated.

Therefore, the inventor has in view of this, and has been rich in design development and practical production experience in the related industries for many years, and is a good electron transfer medium for EDTA-Fe, and it is further confirmed in the present invention that it can be improved in photocatalytic reaction. The degradation efficiency of organic pollutants has invented a method for using EDTA-Fe complex as a medium to accelerate the photocatalytic reaction to degrade organic pollutants, in order to achieve better practical value.

The main object of the present invention is to provide a method for accelerating photocatalytic reaction with ethylenediaminetetraacetic acid-iron complex and use thereof, in particular to use ethylene diamine tetraacetic acid and iron ion complex as a medium for A method for accelerating the photocatalytic reaction to degrade organic pollutants is aimed at.

The purpose and efficacy of the method for accelerating photocatalytic reaction of ethylenediaminetetraacetic acid-iron complex according to the present invention is achieved by the following techniques:

It mainly combines ethylene diamine tetraacetic acid with iron ions to form ethylene diamine tetraacetic acid-iron complex (EDTA-Fe) as an electron transport medium, and simultaneously EDTA- After exposure to light (which can be used for solar sunlight or ultraviolet light), Fe is applied to accelerate the catalytic degradation of various environmentally-contaminated organic matter, which is found in the process of photocatalytic degradation of crystal violet by titanium dioxide, which can improve the degradation of crystal violet. Efficiency, by virtue, allows EDTA-Fe to act as an electron transport medium in photocatalytic reactions and effectively accelerate the degradation of organic pollutants.

For a more complete and clear disclosure of the technical content, the purpose of the invention and the effects thereof achieved by the present invention, it is explained in detail below, and please refer to the drawings and drawings:

First, referring to the sixth figure, the schematic diagram of the process for accelerating the photocatalytic reaction of ethylenediaminetetraacetic acid-iron complex according to the present invention is as follows:

I.EDTA-Fe solution

a. Prepare phosphate buffer solution: take 60±12g of disodium hydrogen phosphate (Na2HPO4) and 114±23g of sodium dihydrogen phosphate (NaH2PO4) in 1 liter of deionized water with appropriate amount of sodium hydroxide (NaOH) Adjust the pH to 7 for use.

b. Preparation of EDTA solution: Take 63 ± 13 grams of EDTA dissolved in 1 liter of phosphate buffer solution and mix for use.

c. Prepare the iron ion solution: Take 60 ± 12 g of iron sulfate heptahydrate (FeSO4.7H2O) dissolved in 1 liter of deionized water and mix for use.

d. Mixing equal volumes of EDTA and iron solution: mixing an equal volume of EDTA solution and iron ion solution to obtain an EDTA-Fe solution.

II. TiO2 powder

A titanium oxide powder having a particle diameter of 21 nm was prepared.

III. Starting photocatalytic reaction

In 29.85 ml of 10 mg/L crystal violet solution (exemplified here), add 0.05 ml of the EDTA-Fe solution prepared in item I and 0.05 g of titanium dioxide (TiO2) powder, and add water to the total volume of 30 ml. After that, light is applied to initiate the reaction.

VII. Measuring the residual value of pollutants

It measures and tracks the concentration of organic pollutants by measuring equipment. In this example, crystal violet (CV) is used to measure and track the crystal violet concentration in the system by UV spectrophotometry. If necessary, EDTA-Fe or titanium dioxide may be added again to increase the degradation rate of crystal violet. The above treatment target is exemplified by crystal violet. If other contaminants are treated, the dosage of EDTA-Fe and titanium dioxide added will be different.

Referring to Figures 1 to 6, the ethylenediaminetetraacetic acid can release hydrogen ions and the negatively charged dentine is an acidic compound. The structural formula is as shown in the first figure, and the negatively charged EDTA is easy to The positively charged iron ions are combined into an EDTA-Fe complex [as shown in the second figure], and the EDTA-Fe complex is used as an electron transport medium for photocatalytic reaction to accelerate the degradation of organic pollutants. When the EDTA-Fe complex is added to the titanium dioxide (TiO2) photocatalytic system for at least 2 hours, the relevant reaction is shown in the third figure.

Please refer to the fourth figure, which is the percentage of crystal violet (CV) degradation of different groups in the photocatalytic reaction system. As shown in the figure, there are groups of EDTA or EDTA-Fe added, which can increase the crystal violet 32 and 35% degradation efficiency; in addition, please refer to the fifth figure, the percentage of degradation of chlorophenol (CPs) in different groups in the photocatalytic reaction system, as shown in the figure, the addition of EDTA-Fe can be increased by 3- 30, 18, and 24% degradation efficiencies of chlorophenol, 3,4-dichlorophenol, and 3,5-dichlorophenol; and the degradation efficiency of chlorophenol (CPs) with only Fe2+ and EDTA alone is low. . It can be seen that both EDAT and EDTA-Fe can be used as electron transport media in photocatalytic reactions and accelerate the degradation of pollutants, but the effect of EDTA-Fe is better.

However, the above-described embodiments or drawings are not intended to limit the structure or the use of the present invention, and any suitable variations or modifications of the invention will be apparent to those skilled in the art.

In summary, the embodiments of the present invention can achieve the expected use efficiency, and the specific structure disclosed therein has not been seen in similar products, nor has it been disclosed before the application, and has completely complied with the provisions of the Patent Law. And the request, the application for the invention of a patent in accordance with the law, please forgive the review, and grant the patent, it is really sensible.

First figure: molecular structure diagram of EDTA of the present invention

Second: the EDTA-Fe mismatched molecular structure of the present invention

Third: Schematic diagram of the reaction of adding EDTA-Fe complex in the TiO2 photocatalytic system of the present invention

Figure 4: Percentage of crystal violet degradation of different groups in the photocatalytic reaction system of the present invention

Figure 5: Percentage of chlorophenol degradation in different groups in the photocatalytic reaction system of the present invention

Figure 6 is a schematic view showing the process of the photocatalytic reaction of the present invention

Claims (6)

A method for accelerating photocatalytic reaction with ethylenediaminetetraacetic acid-iron complex by adding titanium dioxide (TiO2) to ethylenediaminetetraacetic acid-iron complex for degrading organic pollutants, and applying a light program It is formed to accelerate the photocatalytic reaction, so that the ethylenediaminetetraacetic acid-iron complex improves the efficiency of degrading organic pollutants. A method for accelerating a photocatalytic reaction of ethylenediaminetetraacetic acid-iron complex according to the first aspect of the patent application, wherein a titanium dioxide (TiO2) powder having a particle diameter of 21 nm is used. A method for accelerating a photocatalytic reaction of an ethylenediaminetetraacetic acid-iron complex according to the first or second aspect of the patent application, wherein the light is irradiated with sunlight or ultraviolet light. A method for accelerating a photocatalytic reaction of ethylenediaminetetraacetic acid-iron complex according to item 3 of the patent application, wherein the irradiation time is at least two hours. A method for accelerating a photocatalytic reaction of an ethylenediaminetetraacetic acid-iron complex according to the first aspect of the patent application, wherein the EDTA-Fe complex solution is obtained by the following procedure:
a. Prepare phosphate buffer solution: take disodium hydrogen phosphate (Na2HPO4) and sodium dihydrogen phosphate (NaH2PO4) in deionized water, adjust the pH to 7 with sodium hydroxide (NaOH);
b. Prepare EDTA solution: take EDTA dissolved in phosphate buffer solution and mix for use;
c. Prepare the iron ion solution: take iron sulfate heptahydrate (FeSO4.7H2O) dissolved in deionized water and mix for use;
d. Mixing equal volumes of EDTA and iron solution: mixing an equal volume of EDTA solution and iron ion solution to obtain an EDTA-Fe complex solution. For example, in the method of claim 1, the method for accelerating the photocatalytic reaction of ethylenediaminetetraacetic acid-iron complex is to measure the photocatalytic reaction by measuring the residual value of the pollutant, which is measured by timing. Equipment that measures and tracks the concentration of organic pollutants.