201249757 六、發明說明: 【發明所屬之技術領域】 本發明是與廢水回收生物處理設備有關,特別是一種有關 自發性南溫好氧併·氧的廢水生物處理系統。... ..... 【先前技術】 、傳統廢水生物處理包括有:—為「好氧生物處理」,典型 方法為活)±污泥法(Actlvated灿啦卩⑽⑶,AW ),藉廢水中 污木:(即办解性與膠體有機物質)被微生物代謝分解達到去 除1木物目的’無法代謝分解的懸浮有機顆粒則由生物體的自 然膠凝作^崎聚,㈣伴隨部份微生物體職後有效分 離…為「厭氧生物處理」,典型方法為藉發酵過程轉化部份 富含能源的有機物,部份殘餘的有機物和無機二氧化碳則被使 ,為電子(氫)接受者,該過程產生的化學能即為供給厭氧 微生物生存所需的能源。厭氧系統的化學需氧量之移除乃將部 伤有機物轉化為溶解度頗低的甲燒反應中,而在此種轉化過程 中除了:烧外’易產生大量的二氧化碳及少量的氫氣及其他氣 體。厭氧反應槽的操作溫度提高,將促進槽内的生物反應速 率’右將操作溫度操作在35〜38oC或50〜55oC將可加速反應 ,率。但通常維持厭氧反應槽溫度,因進流廢水溫度較反應槽 操作溫度為低’而需料供給熱轉持反應槽溫度。 傳統高溫好氧處理的特性為系統中微生物可處於45〜 65〇C的操作條件,適合處理化學需氧量介於5,⑻〇〜3〇,〇〇〇 mg/L的咼濃度有機污染物,有機負荷約可達0.5〜2.0 201249757 g_COf/g-MLSS-day ’ 根據 LaPara 等人(1997; 1999)的研究指 出,局溫好氡處理可處理的油脂濃度可達2000 mg/L。 根據VantHGff_A]Thenius定律,在高溫系統的條件下可 提高污染物降解的反應速率。_ ’就熱力學誠,高溫環境 降低系微生物細麟能量的使肢率,較生化反應過程 中,基貝還原能中以熱能損失所佔的比例增加,相對的可用於 細胞生長的能量所佔的比例變小,因而可減少污泥產生量,顯 示高溫系統適合應用於高濃度有機廢水之處理。經前人研究技 術和經驗得知微生物生長與线放生成的隨參數有:一、 微生t高溫分解有赌祕的動力參數(k)顯示,高溫動力參數 幸又中脈好氧系統為佳;二、微生物最大比基質利用率⑷較中溫 系統的典型值高出3〜1G倍;三、衰退係數為典型值的1〇倍 以上。 工程觀點評價上,高溫好氧菌的生長係數(gr〇wthyidd) 較低,表示單位污染物(即基質)降解後產生的污泥量較傳統 生物處理法產出污泥量更少,意即高溫環境提供基質較高的降 解速率’相對可以提高系統體積負荷率(v〇lumetric 1〇ading加e, VLR)但又卻具有低污泥淨產量的優點。換言之,高溫好氧處 理中的微生物有車交低生長係數,以傳统連續進流處理的角度來 看,微生物在高溫環境中生存,首要微生物自身必須提供較高 維護能量(maintenance energy)以維持生長,對比其合成自身 新細胞的能量比例(energyforcellsymhesis)顯著降低,此為 其獲致較低生長係數的關鍵,細胞衰退係數(decayc〇nstam) 可由一般0.05 day-1提高至0.5 day -卜 201249757 綜合以上結論,高溫好氧生物處理適合處理高濃度流質態 有機污染物,並且有效降低污泥產出量及有效減少致病菌的優 點。然1¾溫好氧處理技術雖可有效的降解有機污染物,削減率 可達90%,但因進流原水屬高濃度廢水(c〇D約5,〇〇〇〜3〇,〇〇〇 mg/L) ’處理後出流水COD仍高達500〜3,000 mg/L,因此須再 進一步處理,以付合放流水水質標準。而由於高溫好氧處理程 序,已將進流高濃度流質有機污染物快速降解成較小分子的有 機物,如單醣類、胺基酸及短鏈脂肪酸等,如此,可以縮短厭 氧反應的水解及酸化反應,有利於厭氧生物處理之進行。且厭 氧反應槽溫度可達37oC以上,因此將自發性高溫好氧反應槽 置於厭氧槽巾’可縮小熱傳導侧的溫度梯度,減少槽體的熱 傳導損失。並可藉由高溫好氧反應槽出流的高溫流質態小分子 有機物,提高厭氧反應的反應速率及甲烷化產率。 本發明的設計除達到能源再利用的目的外,尚可達能源回 收之效果。槽體均採用不銹鋼材料製造,可以達到耐高溫暨耐 酸鹼目的,另於槽體外層再以耐高溫暨保熱(絕熱)材料包覆, 可以達到耐高溫、阻絕反應槽熱能逸散及有效回收循環再利用 反應槽產生的熱能;整體系統操作可以循環再利用生物系統產 熱。因此,直接效益除了可以減少系統動力(即系統額外供應 熱源)之餘,尚有高溫菌相加速污染物質消化分解的反應速 率,因而有效減少反應槽體積,相較於傳統生物處理單元或系 統所需較大反應槽體積而言’本發明可有效減少反應槽體5積、, 相對減少生物處理單元或系統的初次設置的固定成本及後續 操作的變動成本,除了提升生物處理技術亦增加實務面的可= 201249757 >傳統性污泥法、厭氧處理法或其他_組合的生物 ’此發日収加提升生物處理技術的處理效 立处理對象,_符合環境需錢為環境友善化為 其實的綠色技術。 τ 【發明内容】 . -· < ' 、i - 一因此本發明一目的在提供—種具備自發性高溫好氧併同 ϋ溫厭氧處m用歧善傳統好氧生物處理⑽低有機負 荷耐叉性及高污泥產出的問題。 π ,發明的另一目的是在提供一種自發性高溫好氧併同高 ’皿,氧處m用以有效分解高溫好氧生物處理之後所殘留 的或產出_分解有機物與代謝產物,並產生曱炫氣且將其回 收。鬲溫厭氧處理兼具有消化分解高溫好氧處理後所產出的污 泥,達到污泥減量的目的。 / 根據本發明之上述目的,提出一種自發性高溫好氧併同高 溫厭氧處理系統’主要具有—自發性高溫好氧併同高溫厭氧反 應槽,及一固液分離槽,兩槽之間以管路相連接。其中,自發 性同溫好氧併同高溫厭氧反應槽中,自發性高溫好氧槽中的菌 相為好氧性嗜高溫微生物菌相,高溫厭氧槽中為厭氧性嗜高溫 微生物菌相。 ° 自發性高溫好氧併同高溫厭氧反應槽為一自發性高溫好 氧反應槽’及一高溫厭氧反應槽,前述自發性高溫好氧反應槽 置於高溫厭氣反應槽之中。自發性高溫好氧反應槽包含有一曝 氣模組,其中包含一供氣裝置,並利用供氣裝置提供曝氣所需 201249757 之氣體,並經由曝氣管輸送至一曝氣裝置,用以產生氣泡。依 照本發明一較佳實施例’曝氣裝置之形狀為盤狀,其材質為一 多孔性物質,氣體通量大於15公升/分鐘(lpm; liters per minute)曝氣裝置設置於該自發性高溫好氧反應槽底部。 自發性高溫好氧併同高溫厭氧處理系統,經高溫馴養穩定 後獲侍可以在高溫環境下(即操作溫度可達45〇c以上)的高溫 微生物ij相,藉以處理南漠度有機廢水。系統操作參數調控 有··曝氣量藉由溶氧模組控制、酸鹼值藉由酸驗(pH)模组二 控、反應槽㈣酸驗鋪由加藥模組㈣、溶氧藉由溶氧模= =(:要時辅以曝氣量調整)、溫度值藉由感測模組監控以 及微生物活性藉由各模組監測結果另予調整。 高溫好氧併同高溫厭氧處理系統為—創新且極直 力的新穎技術’結合典型傳缺域理的活性污泥法愈 厭氧處理法而成,此法最佳優勢 ^ /、 有效分解廢料有祕㈣,料八厭*=生物處理法 與分解㈣高溫聽料有效代謝 分解高溫好氧處理後所產出的^解具有效消化 逆主】/可尼減置的目的。 【實施方式】 本發明主要為具備時㈣溫好 卜 統,主要包含:廢水混合槽、自發性言°’里厭氧處理系 應槽、沉澱槽與污泥濃縮;if。 ⑴皿好氧併同高溫厭氧反 敬凊參照第二圖’繪示依據 意圖。 本發明的最佳實施 糸統設備示 201249757 I . _ 自發性咼溫好氧併同高溫厭氧處理系統主要設施包含:一 廢水混合槽201、一自發性高溫好氧生物反應槽2〇2、一高溫 厭氧生物反應槽203、一沉澱槽2〇4與一污泥濃縮槽2〇5。 如圖所示’廢水混合槽201以管線與自發性高溫好氧生物 反地槽202連通’進流原廢水236進入廢水混合槽201且由攪 拌器235混合均勻後,以抽水幫浦221抽取,再經由流量監測 控制器227予以穩定進流至自發性高溫好氧生物反應槽2〇2。 該自發性高溫好氧生物反應槽202係設置於該高溫厭氧生 物反應槽203内,自發性高溫好氧生物反應槽2〇2内之良好的 反應速率、生物產熱及最適操作參數控制乃源自於適當的酸鹼 值(pH)’pH值必須藉由酸鹼值(pH)感應器211監控於6〜8, 並且將讀取數值經由酸驗值控制迴路傳遞至一自動控制模組 233,藥品添加模組為必要時辅以藥品添加,方能有效調整控 制酸鹼值(pH)於最適值;本發明中並設有一藥品添加模組包 含有一鹼液貯槽206與一鹼液加藥泵浦219以及一入料管路連 接至該高溫好氧生物反應槽、一酸液貯槽207與一酸液加藥泵 浦220以及一入料管路連接至該高溫好氧生物反應槽。自發性 高溫好氧生物反應槽2 〇 2内溫度必須藉由内部所設置的溫度感 應器213監控於45〜65oC,藉溫度感應器213監控溫度於最適 反應溫度;一溶氧感應器212設於該自發性高溫好氧生物反應 槽内’監測自發性高溫好氧生物反應槽202的溶氧值,當溶氧 值低於2.0 mg/L,則藉由一氣體流量控制器228予以調整外部 連接的一供氣裝置224的使用功率,以確保有效增加曝氣量。 該曝氣裝置的氣體通量大於30公升/分鐘。自發性高溫好氧 201249757 生物反應槽202的曝氣來自設置於反應槽底部所設置的曝氣管 208 ’藉供氣裝置224將空氣或氧氣經由曝氣管2〇8送入自發 性高溫好氧生物反應槽202,形成氣泡。一則提供微生物生^ 及有機物分解所需要氧氣’二則兼具反應槽攪拌之功能,可^ 有效將反應槽202内廢水充份混合為均勻態。自發性高溫好氧 生物反應槽202内反應生成的蒸氣熱能可以利用反應檜蓋232 上方設置的蒸氣導管210,將蒸氣導至設置在高溫厭氧θ生物反 應槽203内部的熱導管215,即能有效供給自發性高溫厭氧生 物反應槽203所需要熱能。自發性高溫好氧生物反應槽2〇2内 的好氧性嗜尚溫微生物以有機物生物分解及污泥水解進行反 應。槽202内產生過量污泥可以經由所連接的一排泥管237與 流量監測器230予以計量後排至該污泥濃縮槽2〇5 ;自發性高 溫好氧生物反應槽202内微生物含量的有效控制,乃藉由一泵 浦222抽取經過流量監測器229控制最適污泥迴流量;自發性 高溫好氧生物反應槽202處理後的廢水,流經連通管214排入 自發性高溫厭氧生物反應槽203。 如圖所示,自發性高溫厭氧生物反應槽2〇3包圍著自發性 高溫好氧生物反應槽202,其中蒸氣導管21〇入口設置在自發 性咼溫好氧生物反應槽蓋232,連結熱導管215設置於自發性 咼溫厭氧生物反應槽203 ;蒸氣熱能的傳輸途徑有兩種。一、 藉由熱導管215將排氣中的熱能傳導至自發性高溫厭氣生物反 應槽203 ;二、透過自發性高溫好氧生物反應槽2〇2的不銹鋼 槽壁將熱能直接傳導至自發性高溫厭氧生物反應槽2〇3 ;系統 供熱模式完全採用自發性且熱循環再利用,可以有效提升與控 201249757 制水溫於45〜65〇c。高溫厭氧圭物反應槽設有一監控模組,該 &測控制模組共有酸鹼值(p Η )感應器 216、溫度感應器218、 氧化還原電位(ORP)感應器217,予以監控操作該高溫厭氧 生物反應槽内氧化還原電位維持於小於-150 mV。 廢水進入自發性高溫厭氧生物反應槽203且利用厭氧性嗜 而溫微生物進行有機物生物分解友污泥水解後,污泥定期排棄 之排泥管239 ;處理後廢水流經流董監測控制器231的一出流 水官238後排入沉澱槽2〇4,可以予以有效監測自發性高溫厭 氧生物反應槽203出流水量。自發性高溫好氧生物反應槽2〇2 與自發性尚溫厭氧生物反應槽203之間具有連通管214連通, 且自發性高溫好氧生物反應槽2 〇 2處理後廢水利用液位壓差排 入自發性高溫厭氣生物反應槽203。 該沉殿槽204功能為固液分離。 污泥濃縮槽205功能為增加污泥的固體含量,以減少所產 出污泥的含水率與減少反應槽所需要的體積。 本發明在南溫厭氧反應槽2〇3的反應槽外層披附密閉且具 保溫效果的絶熱層209,此保溫措施主要防止系統熱能流失。 另於自發性南溫好氧反應槽2〇2併同高溫厭氧反應槽2〇3槽頂 上方設置槽蓋232,降低反應槽202與203的水蒸氣蒸散量與 防止系統熱能損失,有利於維持系統溫度穩定性(溫度控制於 45〜65oC,熱傳導係數應小於〇 〇1 kcal/ min- m_ °C ),同時避 免反應槽202與203内揮發性物質逸散。 本發明採用全系統自動化操作、監測與管理,運用綠色設 計理念及採用數位科技監測運算管理系統予以後續作業之有 201249757 放操\、准護和官理。自發性高溫好氧搬併同高溫厭氧反應 槽採用自動曝氣(224)、自動加藥(206、207、219、220、 225 226)、自動進水〈221與227)、自動排水(214與以8)、 自動監測酸驗值(ρΗ)_ (·211與216)、自動監測溶氧(212)、 自動:測酿度(213與.218)的智慧型綠色節能廢水生物處理 反^器。其中溶氧與曝氣模組為溶氧感應器212及氣體流量控 弗J»又備208組σ而成,曝氣管'2〇8於曝氣時提供反應槽内 生物刀解需要的氧氣’且溶氧感應.器212除了監控槽2〇2水中 溶氧亦可以控制魏量,減少過鱗氣和聽能職f ;酸驗 值(pH)以感應器211監控,辅以加藥模組(2〇6、2〇7、219、 220、225、226)進行反應槽(202)的酸驗值(pH) (211)調 整功能;當酸鹼值(pH)感應器211偵測酸鹼值(pH)大於8, 系統立即啟動酸液貯槽207的加酸泵浦22〇進行加藥;反之, 酸鹼值(pH)小於6,啟動鹼液貯槽2〇6的加鹼泵浦219進行 加藥;酸鹼值(pH)控制在6〜8為最適操作參數。 綜合上述酸鹼值(pH)、溫度數值、氧化還原電位值 (ORP)、流量監測數值等均會由自動控制模組233予以有效 監控’並且經由迴路將各別讀取數值予以記錄與顯示於一系統 資訊接收分析模組234。 敬請參照第一圖’繪示依據本發明的最佳實施系統處理流 程圖。 如步驟110所示’進流原廢水進入廢水混合槽且由擾拌器 混合均勻後’以抽水幫浦抽取,再經由流量監測控制器予以穩 定進流至自發性高溫好氧生物反應槽。 201249757 必須藉二二了不,自發性高溫好氧生物反應槽酸鹼值(pH〉 回:夂(ph)感應器監控於6〜8,並且將讀取數值經 傳遞至自動控制模組;藥品添加模組在必要時輔以藥品 方能有效職控鑛鹼值(pH)於最適值;藥品添加模組 =鹼液貯槽與驗液加浦、酸液貯槽與醆液加藥泵浦。自發 -45二溫好t生*反應槽内溫度必須藉由溫度感廣器監控於 5〇c ’藉溫度感應器監控溫度於最適反應盈度溶氧感應 器監測自發性高溫好氧生物反應槽的溶氧值,當溶氧值低於 mg/L ’則藉由氣體流量控制器予以調整供氣裝置使用功率 ,保有效,加曝氣量。反應槽的曝氣裝置來自設置於反應槽底 ^的+軋f藉供軋裝置將空氣或氧氣經由曝氣管送入自發性 同/皿好氧生物反應槽’所形成的氣泡一則提供微生物生長及有 機物刀解所而要的氧氣之餘,亦兼具反應槽授拌設施功能,可 以有效將反應槽内廢水充份混合為均勻態。自發性高溫好氧生 物反應槽内反應生成的蒸氣熱能可以利用反應槽蓋上方設置 的瘵氣導官迴路,將蒸氣導至設置在高溫厭氧生物反應槽内部 的”、、導y即此有效供給南溫厭氧生物反應槽所需要熱能。自 發性高溫好氧生物反應#_好氧性嗜高溫微生物可以進行 有機物生物分解及污泥水解反應。槽内產生過量污泥可以經由 排泥官與流量監測計予以計量後排至污泥濃縮槽;為維持高溫 好氧生物反應槽内微生物含量之有效控制,乃藉由泵浦抽取經 過流量監測器控制最適污泥迴流量;高溫好氧生物反應槽處理 後的廢水,則流經連通管排入高溫厭氧生物反應槽。 如步驟130所示’高溫厭氧生物反應槽,監測控制模組共忘 201249757 有@文驗值(pH)感應器、溫度感應器、氧化還原電位(〇Rp) ,應益^以監控操作;廢水進人高溫厭氧生物反應槽利用厭 氧性S π溫微生物進行有機物生物分解及污泥水解後污泥定 ,月排棄,處理後廢水流歸量監測㈣㈣連通管後排入沉殿 可X予以有效監測尚溫厭氧生物反應槽出流水量。 如步驟140所示,沉澱槽功能為固液分離。 曰 W 5〇所示,/亏泥》辰縮槽功能為增加污泥的固體含 里可減)產出污泥的含水率與減少反應槽所需要體積。 ‘合上述酸驗值(ρΗ)、溫度數值、氧化還原電位值201249757 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a wastewater treatment biological treatment facility, and more particularly to a wastewater biological treatment system for spontaneous south temperature aerobic oxygen. ..... [Previous technology], traditional wastewater biological treatment includes: - "aerobic biological treatment", the typical method is live) ± sludge method (Actlvated can be (10) (3), AW), by wastewater Medium-stained wood: (ie, solution and colloidal organic matter) is decomposed by microbial metabolism to remove 1 wood object. 'The suspended organic particles that cannot be metabolized and decomposed are naturally gelled by the organism to make agglomeration, (4) accompanying some microorganisms Effective separation after physical service... is “anaerobic biological treatment”. The typical method is to convert some energy-rich organic matter by fermentation process, and some residual organic matter and inorganic carbon dioxide are used as electron (hydrogen) acceptors. The chemical energy produced by the process is the energy source needed to supply anaerobic microorganisms. The removal of the chemical oxygen demand of the anaerobic system converts the organic matter into a very low-combustion reaction, and in addition to: burning, it is easy to produce a large amount of carbon dioxide and a small amount of hydrogen and other gas. An increase in the operating temperature of the anaerobic reaction tank will promote the rate of biological reaction within the tank. The right operating temperature at 35~38oC or 50~55oC will accelerate the reaction rate. However, the temperature of the anaerobic reaction tank is usually maintained, and the temperature of the influent wastewater is lower than the operating temperature of the reaction tank, and the temperature of the heat transfer reactor is required to be supplied. The traditional high-temperature aerobic treatment is characterized in that the microorganisms in the system can be operated at 45~65〇C, and it is suitable for treating organic pollutants with a chemical oxygen demand of 5, (8) 〇~3〇, 〇〇〇mg/L. The organic load can reach about 0.5~2.0 201249757 g_COf/g-MLSS-day' According to the study by LaPara et al. (1997; 1999), the concentration of oil that can be treated by local temperature is up to 2000 mg/L. According to VantHGff_A] Thenius' law, the reaction rate of pollutant degradation can be increased under high temperature system conditions. _ 'In terms of thermodynamics, the high temperature environment reduces the rate of microbial energy of the microbes. Compared with the biochemical reaction process, the proportion of heat loss in the reduction energy of the kibbe increases, and the relative energy used for cell growth accounts for The proportion is reduced, so that the amount of sludge generated can be reduced, indicating that the high temperature system is suitable for the treatment of high concentration organic wastewater. According to the previous research techniques and experience, the parameters of microbial growth and line emission generation are as follows: 1. The dynamic parameters (k) of microbial t-decomposition have gambling, and the high-temperature dynamic parameters are better than the mid-velocity aerobic system; Second, the maximum microbial biomass utilization ratio (4) is 3~1G times higher than the typical value of the medium temperature system; third, the decay coefficient is more than 1〇 of the typical value. In engineering evaluation, the growth coefficient of high temperature aerobic bacteria (gr〇wthyidd) is low, indicating that the amount of sludge produced by the degradation of unit pollutants (ie, matrix) is less than that produced by traditional biological treatment methods. The high temperature environment provides a higher rate of degradation of the matrix' relative to the system's volumetric loading rate (v〇lumetric 1〇ading plus e, VLR) but with the advantage of a low net sludge yield. In other words, the microorganisms in the high temperature aerobic treatment have a low growth coefficient of the vehicle. In the traditional continuous inflow treatment, the microorganisms survive in a high temperature environment, and the primary microorganism itself must provide higher maintenance energy to maintain growth. Compared with the energy ratio (energyforcellsymhesis) of synthesizing its own new cells, it is the key to the lower growth coefficient, and the cell decay coefficient (decayc〇nstam) can be increased from 0.05 day-1 to 0.5 day - 201249757 Conclusion: High-temperature aerobic biological treatment is suitable for the treatment of high-concentration fluid organic pollutants, and effectively reduces the sludge output and effectively reduces the advantages of pathogenic bacteria. Although the 13⁄4 temperature aerobic treatment technology can effectively degrade organic pollutants, the reduction rate can reach 90%, but the influent raw water is a high concentration wastewater (c〇D about 5, 〇〇〇~3〇, 〇〇〇mg /L) 'The COD of the effluent water after treatment is still as high as 500~3,000 mg/L, so it needs to be further processed to meet the water quality standards. Due to the high-temperature aerobic treatment procedure, the influent high-concentration fluid organic pollutants have been rapidly degraded into smaller molecular organic substances, such as monosaccharides, amino acids and short-chain fatty acids, thus shortening the hydrolysis of anaerobic reactions. And the acidification reaction is beneficial to the anaerobic biological treatment. Moreover, the temperature of the anaerobic reaction tank can reach above 37oC, so placing the spontaneous high-temperature aerobic reaction tank on the anaerobic tank can reduce the temperature gradient on the heat conduction side and reduce the heat conduction loss of the tank. The high-temperature flow state small molecule organic matter which is discharged from the high-temperature aerobic reaction tank can increase the reaction rate of the anaerobic reaction and the methanation yield. In addition to the purpose of energy reuse, the design of the present invention can achieve the effect of energy recovery. The tank body is made of stainless steel material, which can achieve the purpose of high temperature resistance and acid and alkali resistance. It is coated with high temperature resistant and heat retaining (adiabatic) material in the outer layer of the tank, which can reach high temperature resistance, prevent heat dissipation of the reaction tank and effectively The recycling cycle reuses the heat generated by the reaction tank; the overall system operation can recycle the heat generated by the biological system. Therefore, in addition to reducing the system power (that is, the system additionally supplies heat source), the direct benefit has the reaction rate of the high temperature bacteria phase to accelerate the digestion and decomposition of pollutants, thus effectively reducing the reaction tank volume, compared with the traditional biological treatment unit or system. In view of the large reaction tank volume, the present invention can effectively reduce the reaction tank body 5, and relatively reduce the fixed cost of the initial setting of the biological treatment unit or system and the variable cost of subsequent operations, in addition to improving the biological treatment technology and increasing the practical surface. = 201249757 >Traditional sludge method, anaerobic treatment method or other _ combination of organisms' this day to increase the treatment of biological treatment technology, _ compliant with environmental needs for environmental friendliness Green technology. τ [Summary of the Invention] -· < ', i - one Therefore, the object of the present invention is to provide a kind of spontaneous high-temperature aerobic and the same temperature and anaerobic place, m with a poor traditional aerobic biological treatment (10) low organic load Resistance to fork and high sludge production. π, another object of the invention is to provide a spontaneous high-temperature aerobic and high-efficiency dish, the oxygen is used to effectively decompose the high temperature aerobic biological treatment after the residual or output _ decomposition of organic matter and metabolites, and曱 曱 且 and recycle it. The anaerobic treatment and the sludge produced after digestion and decomposition of high temperature aerobic treatment achieve the purpose of sludge reduction. / According to the above object of the present invention, a spontaneous high-temperature aerobic and high-temperature anaerobic treatment system is proposed, which mainly has a spontaneous high-temperature aerobic and high-temperature anaerobic reaction tank, and a solid-liquid separation tank, between the two tanks. Connected by pipes. Among them, in the spontaneous isothermal aerobic and high-temperature anaerobic reaction tank, the bacterial phase in the spontaneous high-temperature aerobic tank is an aerobic thermophilic microbial phase, and the anaerobic thermophilic microbial bacteria in the high-temperature anaerobic tank phase. ° Spontaneous high temperature aerobic and high temperature anaerobic reaction tank is a spontaneous high temperature aerobic reaction tank' and a high temperature anaerobic reaction tank. The spontaneous high temperature aerobic reaction tank is placed in a high temperature anaerobic reaction tank. The spontaneous high-temperature aerobic reaction tank comprises an aeration module, which comprises a gas supply device, and uses the gas supply device to supply the gas of 201249757 required for aeration, and is sent to an aeration device through the aeration pipe to generate bubble. According to a preferred embodiment of the present invention, the aeration device has a disk shape and is made of a porous material. The gas flux is greater than 15 liters per minute (lpm; liters per minute). The aeration device is disposed in the spontaneous state. The bottom of the high temperature aerobic reaction tank. Spontaneous high-temperature aerobic and high-temperature anaerobic treatment system, after being sterilized by high temperature, can be used to treat high-temperature microbial ij phase in high temperature environment (that is, operating temperature up to 45〇c), so as to treat organic wastewater of South Desert. Control of system operating parameters: · Aeration volume controlled by dissolved oxygen module, pH value by acid test (pH) module two control, reaction tank (four) acid test shop by dosing module (four), dissolved oxygen by Dissolved oxygen mode = = (: When necessary, supplemented by aeration volume adjustment), temperature value is monitored by sensing module and microbial activity is adjusted by monitoring results of each module. High-temperature aerobic and high-temperature anaerobic treatment system is a new technology that is innovative and extremely straightforward. Combined with the typical anaerobic treatment method of activated sludge method, the best advantage of this method is ^ /, effective decomposition The waste has the secret (4), the material is eight-rejected*=the biological treatment method and the decomposition (4) the high-temperature hearing material is effectively metabolized and the high-temperature aerobic treatment produces the solution that has the effect of digesting the inverse main]/canni reduction. [Embodiment] The present invention mainly provides a temperature (four) temperature system, and mainly includes: a wastewater mixing tank, a spontaneous anaerobic treatment tank, a sedimentation tank, and sludge concentration; (1) The aerobics of the dish and the high temperature anaerobic anti-respecting are shown in accordance with the second figure'. The best implementation system of the present invention shows 201249757 I. _ Spontaneous temperature aerobic and high temperature anaerobic treatment system main facilities include: a wastewater mixing tank 201, a spontaneous high temperature aerobic biological reaction tank 2 〇 2 A high temperature anaerobic biological reaction tank 203, a sedimentation tank 2〇4 and a sludge concentration tank 2〇5. As shown in the figure, the wastewater mixing tank 201 is connected to the spontaneous high-temperature aerobic biological reverse tank 202 by the pipeline. The inflow raw wastewater 236 enters the wastewater mixing tank 201 and is uniformly mixed by the agitator 235, and then pumped by the pumping pump 221. Then, the flow monitoring controller 227 is stably introduced into the spontaneous high-temperature aerobic biological reaction tank 2〇2. The spontaneous high-temperature aerobic biological reaction tank 202 is disposed in the high-temperature anaerobic biological reaction tank 203, and the good reaction rate, bio-heat generation and optimum operating parameter control in the spontaneous high-temperature aerobic biological reaction tank 2〇2 are The pH value derived from the appropriate pH value must be monitored by the pH sensor 211 at 6-8, and the read value is passed to the automatic control module via the acid test control loop. 233, the medicine adding module is supplemented with a medicine when necessary, so as to effectively adjust and control the pH value to the optimum value; in the present invention, a medicine adding module includes an alkali liquid storage tank 206 and an alkali liquid plus The drug pump 219 and a feed line are connected to the high temperature aerobic biological reaction tank, an acid liquid storage tank 207 and an acid liquid dosing pump 220, and a feed line connected to the high temperature aerobic biological reaction tank. The temperature in the spontaneous high-temperature aerobic biological reaction tank 2 〇2 must be monitored by the internal temperature sensor 213 at 45~65oC, and the temperature sensor 213 monitors the temperature at the optimum reaction temperature; a dissolved oxygen sensor 212 is provided at The spontaneous high temperature aerobic biological reaction tank monitors the dissolved oxygen value of the spontaneous high temperature aerobic biological reaction tank 202. When the dissolved oxygen value is lower than 2.0 mg/L, the external connection is adjusted by a gas flow controller 228. The power of a gas supply unit 224 is used to ensure an effective increase in the amount of aeration. The aeration device has a gas flux greater than 30 liters per minute. Spontaneous high temperature aerobic 201249757 The aeration of the biological reaction tank 202 comes from the aeration tube 208 provided at the bottom of the reaction tank. The air supply unit 224 sends air or oxygen through the aeration tube 2〇8 to the spontaneous high temperature aerobic The biological reaction tank 202 forms bubbles. One provides the oxygen required for the decomposition of microorganisms and organic matter, and the function of mixing the reaction tank is to effectively mix the wastewater in the reaction tank 202 into a uniform state. The steam heat generated by the reaction in the spontaneous high-temperature aerobic biological reaction tank 202 can be guided to the heat pipe 215 disposed inside the high-temperature anaerobic θ biological reaction tank 203 by using the vapor conduit 210 disposed above the reaction lid 232. The heat energy required for the spontaneous high temperature anaerobic biological reaction tank 203 is effectively supplied. The aerobic temperature-sensitive microorganisms in the spontaneous high-temperature aerobic biological reaction tank 2〇2 react with organic matter decomposition and sludge hydrolysis. Excess sludge generated in the tank 202 can be metered through the connected drain pipe 237 and the flow monitor 230 and discharged to the sludge concentration tank 2〇5; the microbial content in the spontaneous high-temperature aerobic biological reaction tank 202 is effective. The control is controlled by a pump 222 to control the optimum sludge return flow through the flow monitor 229; the waste water treated by the spontaneous high-temperature aerobic biological reaction tank 202 is discharged through the communication pipe 214 into the spontaneous high-temperature anaerobic biological reaction. Slot 203. As shown in the figure, the spontaneous high-temperature anaerobic biological reaction tank 2〇3 surrounds the spontaneous high-temperature aerobic biological reaction tank 202, wherein the steam conduit 21 inlet is disposed in the spontaneous 咼temperature aerobic biological reaction tank cover 232, and the heat is connected. The conduit 215 is disposed in the spontaneous anaerobic biological reaction tank 203; there are two ways of transporting the vapor heat energy. 1. The heat energy in the exhaust gas is transmitted to the spontaneous high-temperature anaerobic biological reaction tank 203 by the heat pipe 215; 2. The heat energy is directly transmitted to the spontaneous energy through the stainless steel tank wall of the spontaneous high-temperature aerobic biological reaction tank 2〇2 The high temperature anaerobic biological reaction tank 2〇3; the system heating mode is completely spontaneous and recyclable, which can effectively raise and control the water temperature of 201249757 at 45~65〇c. The high temperature anaerobic solution reaction tank is provided with a monitoring module, and the & control module has a pH value (p Η ) sensor 216, a temperature sensor 218, an oxidation reduction potential (ORP) sensor 217, and is monitored and operated. The oxidation-reduction potential in the high-temperature anaerobic biological reaction tank is maintained at less than -150 mV. After the wastewater enters the spontaneous high-temperature anaerobic biological reaction tank 203 and the anaerobic thermophilic microorganism is used to carry out the organic matter biodegradation, the sludge is periodically drained by the sludge 239; the treated wastewater is monitored and controlled by the flow Dong The effluent 238 of the 231 is discharged into the sedimentation tank 2〇4, and the amount of water discharged from the spontaneous high-temperature anaerobic biological reaction tank 203 can be effectively monitored. The spontaneous high temperature aerobic biological reaction tank 2〇2 is connected with the spontaneous temperature anaerobic biological reaction tank 203 through the communication pipe 214, and the spontaneous high temperature aerobic biological reaction tank 2 〇2 treatment wastewater wastewater level pressure difference The spontaneous high temperature anaerobic biological reaction tank 203 is discharged. The sink channel 204 functions as a solid-liquid separation. The sludge concentration tank 205 functions to increase the solids content of the sludge to reduce the moisture content of the produced sludge and to reduce the volume required for the reaction tank. The invention is provided with a sealed and heat insulating layer 209 on the outer layer of the reaction tank of the south temperature anaerobic reaction tank 2〇3, and the heat preservation measure mainly prevents the heat energy loss of the system. In addition, the spontaneous south temperature aerobic reaction tank 2〇2 and the high temperature anaerobic reaction tank 2〇3 tank top are provided with a tank cover 232, which reduces the steam evapotranspiration of the reaction tanks 202 and 203 and prevents the system heat energy loss, which is beneficial to Maintain system temperature stability (temperature controlled at 45~65oC, heat transfer coefficient should be less than 〇〇1 kcal/min-m_ °C), while avoiding the escape of volatile substances in reaction tanks 202 and 203. The invention adopts the whole system automatic operation, monitoring and management, adopts the green design concept and adopts the digital technology monitoring and calculation management system to carry out the follow-up operations 201249757, and the maintenance and administration. Spontaneous high temperature aerobic reaction with high temperature anaerobic reaction tank using automatic aeration (224), automatic dosing (206, 207, 219, 220, 225 226), automatic water intake <221 and 227), automatic drainage (214 With 8), automatic monitoring of acid value (ρΗ)_ (·211 and 216), automatic monitoring of dissolved oxygen (212), automatic: measuring the degree of brewing (213 and .218) of intelligent green energy-saving wastewater biological treatment Device. The dissolved oxygen and aeration module is formed by a dissolved oxygen sensor 212 and a gas flow control device, and a 208 group of σ is formed. The aeration tube '2〇8 provides oxygen required for bio-knife in the reaction tank during aeration. 'And dissolved oxygen sensor. In addition to monitoring tank 2 〇 2 dissolved oxygen in water can also control the amount of Wei, reduce over-scaling gas and listening to energy f; acid test value (pH) monitored by sensor 211, supplemented with dosing mode The group (2〇6, 2〇7, 219, 220, 225, 226) performs the acid value (pH) (211) adjustment function of the reaction tank (202); when the pH value sensor 211 detects the acid When the base value (pH) is greater than 8, the system immediately starts the acid pump 22 of the acid storage tank 207 to carry out the dosing; on the contrary, the pH value is less than 6, and the alkaline pump 219 of the alkali storage tank is started. Dosing is carried out; the pH value is controlled at 6 to 8 as the optimum operating parameter. The above-mentioned pH value, temperature value, oxidation-reduction potential value (ORP), flow monitoring value, etc. are all effectively monitored by the automatic control module 233 and the respective read values are recorded and displayed via the loop. A system information receiving analysis module 234. Referring to the first figure, a process flow diagram in accordance with a preferred embodiment of the present invention is illustrated. As shown in step 110, the influent raw wastewater enters the wastewater mixing tank and is uniformly mixed by the scrambler, and is pumped by the pumping pump, and then stably flowed into the spontaneous high-temperature aerobic biological reaction tank via the flow monitoring controller. 201249757 must borrow two or two, spontaneous high-temperature aerobic biological reaction tank pH value (pH> back: 夂 (ph) sensor is monitored at 6~8, and the read value is transmitted to the automatic control module; Adding a module, if necessary, supplemented with a drug to effectively control the ore value (pH) at an optimum value; the drug addition module = lye storage tank and liquid test plus pump, acid storage tank and sputum dosing pump. -45 two temperature is good t raw * reaction tank temperature must be monitored by temperature sensor in 5〇c 'by temperature sensor to monitor temperature in the optimal reaction of the dissolved oxygen sensor to monitor the spontaneous high temperature aerobic biological reaction tank The dissolved oxygen value, when the dissolved oxygen value is lower than mg/L ', the gas flow controller is used to adjust the power consumption of the gas supply device to ensure effective and aeration. The aeration device of the reaction tank is disposed at the bottom of the reaction tank. The air bubble formed by the feeding device that sends air or oxygen through the aeration tube into the spontaneous aerobic biological reaction tank, which provides the oxygen required for microbial growth and organic matter solution. It also has the function of the reaction tank mixing facility, which can effectively counter The wastewater in the tank is fully mixed into a uniform state. The steam heat generated by the reaction in the spontaneous high-temperature aerobic biological reaction tank can be guided to the high-temperature anaerobic biological reaction tank by using the helium gas guiding loop disposed above the reaction tank cover. The internal "," y is the heat energy required for the effective supply of the south temperature anaerobic biological reaction tank. Spontaneous high temperature aerobic biological reaction #_ aerobic thermophilic microorganisms can carry out organic decomposition and sludge hydrolysis reaction. The excess sludge can be metered by the sludge discharger and the flow monitor to the sludge concentration tank; the effective control of maintaining the microbial content in the high-temperature aerobic biological reaction tank is optimally controlled by the pump through the flow monitor. The sludge return flow; the wastewater treated by the high-temperature aerobic biological reaction tank is discharged into the high-temperature anaerobic biological reaction tank through the connecting pipe. As shown in step 130, the high-temperature anaerobic biological reaction tank, the monitoring control module is forgotten 201249757 There are @文值值(pH) sensors, temperature sensors, oxidation-reduction potentials (〇Rp), should be used to monitor operations; wastewater into human high-temperature anaerobic organisms The reaction tank uses the anaerobic S π warm microorganism to carry out the biological decomposition of the organic matter and the sludge after the sludge hydrolysis, and the monthly discharge, the monitoring of the wastewater flow after the treatment (4) (4) After the connected pipe is discharged into the Shen Dian, the X can be effectively monitored. The amount of water flowing out of the oxygen biological reaction tank. As shown in step 140, the function of the sedimentation tank is solid-liquid separation. As shown by 曰W 5〇, the function of the shrinkage tank is to increase the solid content of the sludge. The water content of the sludge and the volume required to reduce the reaction tank. 'The above acid value (ρΗ), temperature value, oxidation-reduction potential value
Rp)仙·里監測數值等均會由自動控制模組予以有效監 ^且㈣稱將各卿取數值料記雜顯示於系統資訊 接收分析槿細。 -述錢操作效益^反㈣可持續在較高污染物有機 xl I、件下操作、減少傳統上所必須輔以設置的三級處理 一二少空間需求、有效削減污泥量及避免污泥泡沫化、提 再利^11Μ ΐ效減少巧染物負荷變化的衝擊及系統熱能回1 I之’前述系統難分解有機物的處理效率可以: 二、尸分旦產熱可以回收再利用,而達到節能的目的,同時兼-讀改善㈣H等效果,讀解生 或傳統尚溫好氧系統所面臨的瓶頸。 卞理溫好氧㈣高溫厭氧處㈣統採用自發性好i 留於反應釋出的熱能’以最適化設計將該熱能有效4 、…1 ^时再利用能源,且其溫度穩定維持^ 201249757 二。-々化明優勢為不需要依賴外界予系統額外添加 成的熱能有效傳導回系統,再:欠二:=== 好氧=厭)處理系统’藉以達到維持高二^ 本U顯者效益為―、自發性提供反 =效循環制用該熱能,此法不但㈣且耗 =二環境操作高溫好氧併同高溫厭氧處理系統可加 減少污泥淨產量轉持較佳的出流水品質,此為 二、向溫反應槽可以持續在較高污染負荷的條件下 二解::適二處:高濃度有機廢水及有更佳的難分解有機物 處料元高濃度有機廢水或廢水生物 旦叮、… 戈其此合物、可以有效降低污淨泥產生 =應槽的有效體積,同時具有能源回收再利用熱 月匕為她友善化且綠色的新穎廢水處理技術。 特此說明,圖示自發性高溫好氧併同高溫厭氧處理系 ==ΑΤ)的個财賴施包含設料造型、及尺寸僅 #_施包含設_外型均可為各種適當 邊予以呈現。同時,本發明案實施例雖然採用—座 厭氧處理系統(a·)為主轴,然而併同r ㈣顺合'純為他類串 L1此本發明祀圍理當不因此故產生發 限糊咖細如塊,並= 201249757 【圖式簡單說明】 第-圖展現本發明實施例一種自發性高溫好 厭氧處理系統的流程圖。 乳併冋1%溫 第二圖,繪雜齡發明的最佳實施系統設備示音罔 【主要元件符號說明】 201 廢水混合槽 202:自發性尚溫好氧生物反應槽 203 :自發性高溫厭氧生物反應槽 204 :沉澱槽 205 :污泥濃縮槽 206 :鹼液貯槽 207 :酸液貯槽 208 :曝氣裝置 209 :絶熱層 210 :蒸氣導管 211 :酸鹼值(PH)感應器 212 :溶氧感應器 213 :溫度感應器 214 :自發性高溫好氧生物反應槽與自發性高溫厭氧生物 反應槽連通管 215 :熱導管 216 :酸鹼值(pH)感應器 217 ··氧化還原電位(〇RP)感應器 201249757 218:溫度感應器: 219〜223 :泵浦 224:供氣裝置1 225〜231 :流量監測控制器 232 :自發性高溫4子氧生物反應槽與高溫厭氧生物反應槽 的反應槽蓋 I: ’二 233 :自動控制模組 二· / · 234:系統資訊接收分析模組 235 :攪拌器 236:進流原廢水 237:自發性高溫好氧生物反應槽的排泥管 238:自發性高溫厭氧生物反應的出流水管 239:自發性高溫厭氧生物反應槽的排泥管 240:沉澱槽的排泥管Rp) The monitoring values of Xian·Li will be effectively supervised by the automatic control module. (4) It is said that each member takes the numerical data and displays it in the system information. - Explain the benefits of operation and control. (4) Sustainably operate under high-contaminant organic xl I, and reduce the traditional three-stage treatment required by the three-stage treatment, effectively reduce the amount of sludge and avoid sludge. Foaming, refinancing, and reducing the impact of the load change of the dye and the heat of the system. The treatment efficiency of the above-mentioned system is difficult to decompose organic matter: 2. The heat of the body can be recycled and reused. The purpose, at the same time, is to read and improve (4) H and other effects, to read the bottleneck of the raw or traditional temperature aerobic system.卞 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温 温- The advantage of 々化明 is that it does not need to rely on the outside world to add additional heat energy to the system to effectively transmit back to the system, and then: owe two: === aerobic = anatomical treatment system 'to maintain high 2 ^ The benefit of U is ― Spontaneously provide anti-effect cycle for the use of this thermal energy. This method not only (4) but also consumes two environmentally-operated high-temperature aerobic and high-temperature anaerobic treatment systems can reduce the net output of the sludge to better maintain the quality of the outflow water. For the second, the temperature reaction tank can continue to be under the condition of higher pollution load: two: high concentration of organic wastewater and better difficult to decompose organic matter, high concentration of organic wastewater or wastewater bio-denier, ... Geqi this compound can effectively reduce the production of dirty mud = the effective volume of the tank, and at the same time, it has the energy recovery and reuse heat moon as her friendly and green novel wastewater treatment technology. It is hereby stated that the description of the spontaneous high-temperature aerobic and high-temperature anaerobic treatment system ==ΑΤ) includes the design of the material, and the size can only be presented for various appropriate sides. . At the same time, although the embodiment of the present invention adopts the anaerobic treatment system (a·) as the main axis, and the same as the r (four) compliant 'purely the other type of string L1, the present invention does not cause the occurrence of the limit. As a block, and = 201249757 [Schematic description of the drawings] The first figure shows a flow chart of a spontaneous high temperature anaerobic treatment system according to an embodiment of the present invention. Milk and 冋1% temperature second picture, the best implementation system of the invention of the invention shows the sound of the device 主要 [main symbol description] 201 wastewater mixing tank 202: spontaneous temperature aerobic biological reaction tank 203: spontaneous hyperthermia Oxygen biological reaction tank 204: precipitation tank 205: sludge concentration tank 206: alkali storage tank 207: acid storage tank 208: aeration device 209: heat insulation layer 210: vapor conduit 211: pH sensor 212: Dissolved oxygen sensor 213: temperature sensor 214: spontaneous high temperature aerobic biological reaction tank and spontaneous high temperature anaerobic biological reaction tank communication tube 215: heat pipe 216: pH sensor 217 · redox potential (〇RP) sensor 201249757 218: Temperature sensor: 219~223: Pump 224: Air supply unit 1 225~231: Flow monitoring controller 232: Spontaneous high temperature 4 Oxygen biological reaction tank and high temperature anaerobic biological reaction Tank reaction tank cover I: 'II233: Automatic control module II · / · 234: System information receiving analysis module 235: Stirrer 236: Influent raw wastewater 237: Spontaneous high temperature aerobic biological reaction tank draining mud Tube 238: Outflow tube for spontaneous high temperature anaerobic biological reaction 2 39: Discharge pipe of spontaneous high temperature anaerobic biological reaction tank 240: Drain pipe of sedimentation tank