TW201244906A - Method for heating plastic film, and method for producing color filter - Google Patents
Method for heating plastic film, and method for producing color filter Download PDFInfo
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- TW201244906A TW201244906A TW100133772A TW100133772A TW201244906A TW 201244906 A TW201244906 A TW 201244906A TW 100133772 A TW100133772 A TW 100133772A TW 100133772 A TW100133772 A TW 100133772A TW 201244906 A TW201244906 A TW 201244906A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
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- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Abstract
Description
201244906 六、發明說明: 【發明所屬之技術領域】 本發明係關於加熱帶狀塑膠薄膜之塑膠薄膜的加熱方 法,以及包含該方法之彩色濾光片的製造方法,尤其關於 可均一且迅速地加熱塑膠薄膜之塑膠薄膜的加熱方法,及 彩色濾光片的製造方法。 【先前技術】 近年來,在構成彩色濾光片或TFT陣列之顯示器構件 中,作爲藉由金屬或樹脂來形成具有預定功能性之圖型之 基材,係針對採用具有可撓性之滾筒狀塑膠薄膜進行硏究 。如此,藉由將基材構成爲塑膠製,可使彩色濾光片或 TFT陣列達到薄型化及低成本化,並且可防止基材的斷裂 〇 此般基材上,係形成有具有預定功能性之圖型,但此 時以圖型的硬化促進、反應促進、密著性提升、熱安定性 提升、雜質去除等爲目的,一般而言會進行烘烤(燒結) 處理。當基材由玻璃所構成時,由於玻璃具有耐熱性,所 以可將形成有圖型之基材投入於所謂的烘烤爐,並以相對 較高的溫度進行烘烤處理。然而,當基材由具有可撓性之 樹脂材料所構成時,由於樹脂的耐熱性低,故難以在不會 使基材產生變形下進行烘烤處理。 爲了對應於此情形,爲人所知者有專利文獻1所示之 薄片狀基材的烘烤方法。其中,係將從捲出輥所拉出之薄 201244906 片狀基材,在烘烤爐內一邊藉由皮帶來運送一邊進行烘烤 處理。 〔先前技術文獻〕 〔專利文獻〕 〔專利文獻1〕日本特開2005_148352號公報 【發明內容】 (發明所欲解決之問題) 當藉由專利文獻1所示之方法對薄片狀基材進行烘烤 處理時,爲了確實地加熱薄片狀基材,必須增長烘烤爐內 的加熱區或是降低薄片狀基材的運送速度。然而,爲前者 的情形時,由於增長加熱區,使烘烤爐大型化而難以均一 地維持烘烤爐內的溫度分布,爲後者的情形時,烘烤處理 的時間增長,不論何種情形,均存在有能量效率降低之問 題。此外,如此在烘烤爐內的加熱區中連續地運送薄片狀 基材時,必需在烘烤爐設置薄片狀基材的出入口,使烘烤 爐內部的密閉性降低。從該情形中,亦產生烘烤爐內的溫 度分布偏離,且難以均一地加熱薄片狀基材之問題》 本發明係考量到上述情形而創作出之發明,目的在於 提供一種可均一且迅速地加熱塑膠薄膜之塑膠薄膜的加熱 方法,以及包含該方法之彩色濾光片的製造方法。 (用以解決問題之技術手段)201244906 VI. Description of the Invention: [Technical Field] The present invention relates to a method for heating a plastic film for heating a strip-shaped plastic film, and a method for manufacturing a color filter comprising the method, and more particularly to uniform and rapid heating A method of heating a plastic film of a plastic film, and a method of manufacturing a color filter. [Prior Art] In recent years, in a display member constituting a color filter or a TFT array, a substrate having a pattern having a predetermined function as a metal or a resin is used for a flexible roll shape. Plastic film is studied. By forming the substrate into a plastic material, the color filter or the TFT array can be made thinner and lower in cost, and the breakage of the substrate can be prevented. Thus, the substrate is formed with a predetermined functionality. In the case of the pattern, the baking (sintering) treatment is generally performed for the purpose of hardening promotion, reaction promotion, adhesion improvement, thermal stability improvement, impurity removal, and the like. When the substrate is composed of glass, since the glass has heat resistance, the substrate on which the pattern is formed can be put into a so-called baking furnace and baked at a relatively high temperature. However, when the substrate is composed of a flexible resin material, since the heat resistance of the resin is low, it is difficult to carry out the baking treatment without causing deformation of the substrate. In order to cope with this situation, a method of baking a sheet-like substrate shown in Patent Document 1 is known. Among them, the thin 201244906 sheet-like substrate which is pulled out from the take-up roll is baked while being conveyed by the leather belt in the baking oven. [PRIOR ART DOCUMENT] [Patent Document 1] [Patent Document 1] JP-A-2005-148352 SUMMARY OF THE INVENTION (Problems to be Solved by the Invention) When a sheet-like substrate is baked by the method disclosed in Patent Document 1, At the time of the treatment, in order to reliably heat the sheet-like substrate, it is necessary to increase the heating zone in the baking furnace or to lower the conveying speed of the sheet-like substrate. However, in the case of the former, it is difficult to uniformly maintain the temperature distribution in the baking furnace due to the increase in the heating zone, and it is difficult to uniformly maintain the temperature distribution in the baking furnace. In the latter case, the baking treatment time increases, regardless of the situation. There is a problem of reduced energy efficiency. Further, when the sheet-like substrate is continuously conveyed in the heating zone in the baking furnace as described above, it is necessary to provide the inlet and outlet of the sheet-like substrate in the baking furnace, and the sealing property inside the baking furnace is lowered. In this case, the temperature distribution in the baking furnace is also deviated, and it is difficult to uniformly heat the sheet-like substrate. The present invention has been made in view of the above circumstances, and aims to provide a uniform and rapid A heating method for heating a plastic film of a plastic film, and a method for producing a color filter comprising the method. (technical means to solve the problem)
-6- S 201244906 本發明係提供一種塑膠薄膜的加熱方法,其特徵爲具 備有:於塑膠薄膜之間夾介支撐構件而將帶狀塑膠薄膜捲 取於芯材,以利用該支撐構件使空隙層中介存在於塑膠薄 膜之間的方式來形成塑膠薄膜的捲取體之製程,將塑膠薄 膜的捲取體投入於加熱爐之製程,以及於加熱爐內,以所 期望的溫度加熱塑膠薄膜的捲取體之製程。 上述塑膠薄膜的加熱方法中,可構成爲在形成塑膠薄 膜的捲取體之製程中,塑膠薄膜以IN/mm2以下之每單位 剖面積的張力所捲取。 此外,上述塑膠薄膜的加熱方法中,可構成爲芯材由 樹脂所構成,在加熱塑膠薄膜的捲取體之製程中,塑膠薄 膜以芯材之玻璃轉移點以下的溫度被加熱。 此外,上述塑膠薄膜的加熱方法中,可構成爲支撐構 件由樹脂所構成,在加熱塑膠薄膜的捲取體之製程中,塑 膠薄膜以支撐構件之玻璃轉移點以下的溫度被加熱。 此外,上述塑膠薄膜的加熱方法中,可構成爲支撐構 件由具有塑膠薄膜之玻璃轉移點以上的玻璃轉移點之樹脂 所構成。 此外,上述塑膠薄膜的加熱方法中,可構成爲支撐構 件由與塑膠薄膜同一材料所構成。-6- S 201244906 The present invention provides a method for heating a plastic film, which is characterized in that the support member is interposed between the plastic films, and the strip-shaped plastic film is taken up to the core material to make the gap by the support member. The layer interposing between the plastic film to form a winding body of the plastic film, the winding body of the plastic film is put into the heating furnace process, and the plastic film is heated at a desired temperature in the heating furnace. The process of taking up the body. In the heating method of the plastic film, the plastic film may be wound up by a tension per unit area of IN/mm 2 or less in the process of forming the wound body of the plastic film. Further, in the heating method of the plastic film, the core material may be composed of a resin, and in the process of heating the wound body of the plastic film, the plastic film is heated at a temperature lower than a glass transition point of the core material. Further, in the heating method of the plastic film, the supporting member may be constituted by a resin, and in the process of heating the winding body of the plastic film, the plastic film is heated at a temperature lower than a glass transition point of the supporting member. Further, in the heating method of the plastic film, the support member may be composed of a resin having a glass transition point or more of a glass transition point of the plastic film. Further, in the heating method of the above plastic film, the supporting member may be constituted by the same material as the plastic film.
此外,上述塑膠薄膜的加熱方法中,可構成爲在形成 塑膠薄膜的捲取體之製程中,藉由樹脂將圖型形成於被捲 取於芯材之塑膠薄膜。 Y 此外,上述塑膠薄膜的加熱方法中,可構成爲在形成 201244906 塑膠薄膜的捲取體之製程中,支撐構件被配置在塑膠薄膜 中之圖型以外的區域。 本發明係提供一種彩色濾光片的製造方法,其特徵爲 具備有:製備帶狀塑膠薄膜之製程,將含有彩色濾光片形 成用樹脂之感光性材料塗佈於塑膠薄膜並進行乾燥,使該 感光性材料以預定形狀進行曝光並顯影’而在塑膠薄膜上 形成由該感光性材料所構成之圖型之製程’以及藉由執行 上述之塑膠薄膜的加熱方法,來加熱塑膠薄膜及圖型之製 程,而取得彩色濾光片。 發明之效果: 根據本發明,由於捲取帶狀塑膠薄膜並形成捲取體來 加熱,故可一次加熱帶狀塑膠薄膜全體。此外,由於藉由 支撐構件使空隙層中介存在於塑膠薄膜之間,所以可將加 熱爐所產生的熱,經由空隙層傳遞至塑膠薄膜全體。因此 可均一且迅速地加熱塑膠薄膜。 此外,根據本發明,由於將形成有由含有彩色濾光片 形成用樹脂之感光性材料所構成的圖型之帶狀塑膠薄膜予 以捲取並形成捲取體來加熱,故可一次加熱塑膠薄膜及圖 型全體。此外,由於藉由支撐構件使空隙層中介存在於塑 膠薄膜之間,所以可將加熱爐所產生的熱,經由空隙層傳 遞至塑膠薄膜及圖型全體。因此可均一且迅速地加熱塑膠 薄膜及圖型,並且提升塑膠薄膜與圖型之密著性。Further, in the heating method of the plastic film, the pattern may be formed by a resin on a plastic film which is taken up in a core material in a process of forming a wound body of a plastic film. Further, in the heating method of the plastic film described above, the support member may be disposed in a region other than the pattern in the plastic film in the process of forming the winding body of the 201244906 plastic film. The present invention provides a method of producing a color filter, comprising: preparing a process for preparing a strip-shaped plastic film, applying a photosensitive material containing a resin for forming a color filter to a plastic film, and drying the film The photosensitive material is exposed and developed in a predetermined shape to form a pattern of the pattern formed of the photosensitive material on the plastic film, and the plastic film and pattern are heated by performing the heating method of the plastic film described above. The process is to obtain a color filter. Advantageous Effects of Invention According to the present invention, since the strip-shaped plastic film is taken up and heated by the winding body, the entire strip-shaped plastic film can be heated at one time. Further, since the void layer is interposed between the plastic films by the supporting member, the heat generated by the heating furnace can be transmitted to the entire plastic film via the void layer. Therefore, the plastic film can be uniformly and rapidly heated. Further, according to the present invention, since the strip-shaped plastic film formed of the photosensitive material containing the color filter forming resin is taken up and heated to form a wound body, the plastic film can be heated at one time. And the whole picture. Further, since the void layer is interposed between the plastic film by the supporting member, the heat generated by the heating furnace can be transmitted to the entire plastic film and the pattern through the void layer. Therefore, the plastic film and pattern can be uniformly and rapidly heated, and the adhesion between the plastic film and the pattern can be improved.
-8- S 201244906 【實施方式】 以下參照圖面來說明本發明的實施形態。 首先藉由第1圖來說明本實施形態之塑膠薄膜1的捲 取體4。本實施形態之塑膠薄膜丨的捲取體4,是將藉由 樹脂形成有彩色濾光片7用的預定形狀的圖型6之塑膠薄 膜1捲取爲滾筒狀者。 亦即’形成於塑膠薄膜1之圖型6,是由含有彩色濾 光片7形成用之樹脂的感光性材料所構成,乃具有彩色濾 光片7用的期'望功能性。本實施形態中,係形成有彩色濾 光片7用的黑色矩陣、紅色像素、綠色像素、或藍色像素 作爲此般圖型6。 如第1圖所示,塑膠薄膜1的捲取體4,係於塑膠薄 膜1之間夾介支撐構件2而將形成有圖型6之帶狀塑膠薄 膜1捲取於圓筒狀芯材5,並藉由該支撐構件2使空隙層 3中介存在於塑膠薄膜1之間而形成。當中,支撐構件2 較佳是配置在塑膠薄膜1之圖型6以外的區域上。藉此可 防止圖型6的損傷。本實施形態中,如第1圖及第2圖( a) 、( b )所示,支撐構件2較佳是配置在塑膠薄膜1之 長邊方向的兩邊緣部,塑膠薄膜1的捲取體4是以滾紋形 態來捲取塑膠薄膜1。 具體而言,支撐構件2在塑膠薄膜1的寬度方向上, 較佳是配置在距離長邊方向的兩邊緣部爲塑膠薄膜1之寬 度的1/3以內之區域。支撐構件2,只要可維持不使塑膠 薄膜1彼此接觸之狀態’則亦可從塑膠薄膜1之長邊方向 201244906 的兩邊緣部往外邊部分地突出。 塑膠薄膜1較佳是以1 N/mm2以下之每單位剖面積的 張力所捲取’此外’尤佳爲實質上不施加張力下而捲取。 藉此可防止拉伸張力殘留於所捲取之塑膠薄膜1,並可防 止因加熱處理使塑膠薄膜1產生變形之情形。此外,捲取 塑膠薄膜1之捲取機(圖中未顯示),可使用一般所使用 者。再者,塑膠薄膜1的捲繞數,較佳是因應用途等來適 當地選擇。 接著說明塑膠薄膜1的材料。本實施形態之塑膠薄膜 1 ’只要具有可捲取爲滾筒狀之程度的可撓性即可,此外 ’並要求具有可用作爲彩色濾光片7之透明性、輕量性等 。塑膠薄膜1的材料,例如可列舉出聚對苯二甲酸乙二酯 (PET)、聚萘二甲酸乙二酯(PEN)、聚醚颯(PES;)、 聚醯亞胺(PI )、聚碳酸酯(PC )、環狀聚烯烴(COP ) '聚甲基丙烯酸甲酯(PMMA )、聚氯乙烯(PVC)、聚 乙烯醇(PVA)、尼龍66(6 6N)、丙烯腈-丁二烯-苯乙 燦(ABS)、聚乙烯(PE) '聚丙烯(PP)、聚四氟乙烯 (PTFE)、聚醚醚酮(peek)、聚苯硫酸(PPS)等之合 成樹脂等。 此外’塑膠薄膜1的厚度較佳是位在l;/m〜lOOOym 的範圍內,尤佳爲l〇V m~500 /z m的範圍內,更佳爲50μ m 〜2 5〇vm的範圍內。此係由於當塑膠薄膜!的厚度較上述 範圍更厚時’會損及可撓性而容易折斷,難以形成塑膠薄 膜1的捲取體4之故。另一方面,較上述範圍更薄時,會-8- S 201244906 [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the drawings. First, the winding body 4 of the plastic film 1 of the present embodiment will be described with reference to Fig. 1. The take-up body 4 of the plastic film cartridge of the present embodiment is obtained by winding a plastic film 1 of a pattern 6 of a predetermined shape in which a color filter 7 is formed of a resin into a roll shape. That is, the pattern 6 formed on the plastic film 1 is composed of a photosensitive material containing a resin for forming the color filter 7, and has a desired function for the color filter 7. In the present embodiment, a black matrix, a red pixel, a green pixel, or a blue pixel for the color filter 7 is formed as the pattern 6 as described above. As shown in FIG. 1, the take-up body 4 of the plastic film 1 is obtained by sandwiching the support member 2 between the plastic film 1 and winding the tape-shaped plastic film 1 having the pattern 6 on the cylindrical core material 5. And formed by interposing the void layer 3 between the plastic film 1 by the support member 2. Among them, the support member 2 is preferably disposed on a region other than the pattern 6 of the plastic film 1. Thereby, the damage of the pattern 6 can be prevented. In the present embodiment, as shown in Fig. 1 and Fig. 2(a) and Fig. 2(b), the support member 2 is preferably disposed at both edge portions in the longitudinal direction of the plastic film 1, and the take-up body of the plastic film 1. 4 The plastic film 1 is taken up in a roll form. Specifically, in the width direction of the plastic film 1, the support member 2 is preferably disposed in a region in which both edge portions in the longitudinal direction are within 1/3 of the width of the plastic film 1. The support member 2 can partially protrude from the both edge portions of the long side direction 201244906 of the plastic film 1 as long as it can maintain the state in which the plastic film 1 is not in contact with each other. The plastic film 1 is preferably taken up by a tension per unit sectional area of 1 N/mm 2 or less. Further, it is preferable to take up substantially without applying tension. Thereby, the stretching tension can be prevented from remaining on the wound plastic film 1, and the plastic film 1 can be prevented from being deformed by the heat treatment. Further, a coiler (not shown) for taking up the plastic film 1 can be used generally. Further, the number of windings of the plastic film 1 is preferably appropriately selected depending on the use and the like. Next, the material of the plastic film 1 will be described. The plastic film 1' of the present embodiment may have flexibility such that it can be wound into a roll shape, and it is required to have transparency, lightness, and the like which can be used as the color filter 7. Examples of the material of the plastic film 1 include polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyether oxime (PES;), polyimine (PI), and poly Carbonate (PC), cyclic polyolefin (COP) 'Polymethyl methacrylate (PMMA), polyvinyl chloride (PVC), polyvinyl alcohol (PVA), nylon 66 (6 6N), acrylonitrile-butyl Synthetic resins such as olefin-phenylene (ABS), polyethylene (PE) 'polypropylene (PP), polytetrafluoroethylene (PTFE), polyetheretherketone (peek), polyphenylsulfuric acid (PPS), and the like. Further, the thickness of the plastic film 1 is preferably in the range of l; / m to lOOOym, particularly preferably in the range of l 〇 V m to 500 / zm, more preferably in the range of 50 μ m to 2 5 〇 vm. . This is due to the plastic film! When the thickness is thicker than the above range, it is likely to be broken due to the loss of flexibility, and it is difficult to form the wound body 4 of the plastic film 1. On the other hand, when it is thinner than the above range,
-10- S 201244906 失去支撐性,難以在各製程中進行處理之故。 塑膠薄膜1的寬度並無特別限定,較佳例如爲100mm 〜1 000mm的範圍內,尤佳爲150mm〜600mm的範圍內。 塑膠薄膜1可爲由單一層所形成之構成,或是具有層 合有複數層之構成。 接著說明支撐構件2。本實施形態之支撐構件2,爲 用以在捲取於芯材5之塑膠薄膜1之間形成空隙層3之帶 狀構件》此般支撐構件2只要是具有可撓性且脫模性高者 即可,並無特別限定。尤其是,支撐構件2是在捲取塑膠 薄膜1時所使用,並非彩色濾光片7的構成零件,故可使 用不透明材料,例如可使用膠帶狀的金屬等。 支撐構件2可由具有較塑膠薄膜1的玻璃轉移點更高 之玻璃轉移點的樹脂所構成。藉此,於加熱處理時,可防 止支撐構件2固著於塑膠薄膜1。此時,例如可使用上述 PTFE、PI或金屬等作爲支撐構件2來賦予耐熱性。或者 是’支撐構件2可由與塑膠薄膜1相同之材料所構成。此 時,由於塑膠薄膜1與支撐構件2的熱膨脹率相同,所以 於加熱處理時,可防止塑膠薄膜1產生變形。 此外,支撐構件2的厚度較佳是位在20 v m〜20 0 m 的範圍內,尤佳爲50/zm〜150/zm的範圍內。此係由於當 支撐構件2的厚度較上述範圍更薄時,捲取塑膠薄膜i時 空隙層3會損壞,而使塑膠薄膜1彼此容易接觸,較上述 範圍更厚時,難以捲取塑膠薄膜1之故。 支撐構件2的寬度,相對於塑膠薄膜1的寬度,較佳 -11 - 201244906 爲3%以上30%以內,具體而言,較佳爲5~80mm’尤佳爲 10~5 0mm。此係由於當支撐構件2的寬度較上述範圍更小 時,在塑膠薄膜1之寬度方向的中央部分’塑膠薄膜1彼 此容易接觸,較上述範圍更大時,支撐構件2會與形成於 塑膠薄膜1之圖型6接觸之故。 此外,支撐構件2可由多孔質材質所構成。此時,較 佳例如可使用聚乙烯多孔質薄片(日東電工公司製的 Sunmap )、微孔隙雙軸拉伸聚丙燦(Yupo Corporation製 的 Yupo)、不織布等。此時,多孔質薄片的表面粗糙度 (Ra)較佳爲l/zm以上,尤佳爲2ym以上,更佳爲5/zm 以上。此係由於當Ra較上述範圍更小時,支撐構件2所 具有的空隙變少,使透氣性及透濕性降低之故。多孔質薄 片的Ra通常爲10//m以下。此外,在此所謂的「表面粗 糙度(Ra )」,爲「算術平均粗糙度」,係依據】13-B 0 6 0 1來測定。 此外,如第2圖(〇 、(d)所示,支撐構件2的表 面上可形成凹凸。藉此’由於可夾介支撐構件2的凹部2a 將透氣性賦予至空隙層.3與外部環境間,所以可將因加熱 處理而從塑膠薄膜1或由感光性材料所構成之圖型6所昇 華之昇華物質’從空隙層3中釋出,並且可防止該昇華物 質附著於塑膠薄膜1或圖型6。此時,可使用形成有凹凸 之壓花薄膜作爲支撐構件2。此般壓花薄膜,可具有例如 與塑膠薄膜1的接觸面積約爲0.〇lmm2〜100mm2之相對較 大的凹凸’凹凸的間隔例如約爲〇· 1 mm〜1 〇mm之相對較-10- S 201244906 Loss of support, it is difficult to deal with in various processes. The width of the plastic film 1 is not particularly limited, but is preferably in the range of, for example, 100 mm to 1 000 mm, and particularly preferably in the range of 150 mm to 600 mm. The plastic film 1 may be formed of a single layer or may have a laminate of a plurality of layers. Next, the support member 2 will be described. The support member 2 of the present embodiment is a belt-shaped member for forming the void layer 3 between the plastic films 1 wound around the core material 5. Thus, the support member 2 is preferably flexible and has a high mold release property. It is not particularly limited. In particular, the support member 2 is used when the plastic film 1 is taken up, and is not a component of the color filter 7, so that an opaque material can be used, and for example, a tape-like metal or the like can be used. The support member 2 may be composed of a resin having a higher glass transition point than the glass transition point of the plastic film 1. Thereby, the support member 2 can be prevented from being fixed to the plastic film 1 at the time of heat treatment. At this time, for example, the above-mentioned PTFE, PI, metal, or the like can be used as the support member 2 to impart heat resistance. Alternatively, the support member 2 may be composed of the same material as the plastic film 1. At this time, since the plastic film 1 and the supporting member 2 have the same thermal expansion coefficient, the plastic film 1 can be prevented from being deformed during the heat treatment. Further, the thickness of the support member 2 is preferably in the range of 20 v m to 20 0 m, and more preferably in the range of 50 / zm to 150 / zm. When the thickness of the support member 2 is thinner than the above range, the void layer 3 may be damaged when the plastic film i is wound, and the plastic film 1 is easily contacted with each other. When the thickness is thicker than the above range, it is difficult to take up the plastic film 1 The reason. The width of the support member 2 is preferably 3% or more and 30% or less with respect to the width of the plastic film 1, and specifically, preferably 5 to 80 mm' is preferably 10 to 50 mm. Since the plastic film 1 is easily in contact with each other in the central portion of the width direction of the plastic film 1 when the width of the support member 2 is smaller than the above range, the support member 2 is formed on the plastic film 1 The pattern 6 is in contact. Further, the support member 2 may be composed of a porous material. In this case, for example, a polyethylene porous sheet (Sunmap manufactured by Nitto Denko Corporation), a microporous biaxially stretched polypropylene (Yupo manufactured by Yupo Corporation), a nonwoven fabric, or the like can be preferably used. In this case, the surface roughness (Ra) of the porous sheet is preferably 1/zm or more, more preferably 2 μm or more, and still more preferably 5/zm or more. When the Ra is smaller than the above range, the gap of the support member 2 is reduced, and the gas permeability and the moisture permeability are lowered. The Ra of the porous sheet is usually 10 / / m or less. In addition, the "surface roughness (Ra)" referred to herein is "arithmetic mean roughness" and is measured in accordance with 13-B 0 6 0 1 . Further, as shown in Fig. 2 (〇, (d), irregularities may be formed on the surface of the support member 2. Thereby, the air permeability is imparted to the void layer by the recess 2a of the support member 2; Therefore, the sublimation substance 'sublimated from the plastic film 1 or the pattern 6 composed of the photosensitive material by heat treatment can be released from the void layer 3, and the sublimation substance can be prevented from adhering to the plastic film 1 or Fig. 6. At this time, an embossed film formed with irregularities can be used as the support member 2. The embossed film can have, for example, a relatively large contact area with the plastic film 1 of about 0.1 mm 2 to 100 mm 2 . The interval of the unevenness is, for example, approximately 〇·1 mm~1 〇mm.
-12- S 201244906 大的間隔’如此可將透氣性賦予至空隙層3,故較佳。此 外,壓花薄膜例如可使用泛用的載體膠帶等,或是藉由模 壓加工等而形成有任意凹凸形狀之構件。 接著說明芯材5。芯材5只要是在加熱處理的溫度下 不會熔解及起火之材料即可,並無特別限定,可使用塑膠 、紙、金屬等’尤佳爲使用金屬。一般而言,金屬由於其 熱膨脹率較塑膠更小’所以在加熱處理時,芯材5可防止 塑膠薄膜1進一步的膨脹,而防止塑膠薄膜1產生變形。 或者是可使用具有與塑膠薄膜1同等的熱膨脹率之樹脂, 尤其是與塑膠薄膜1爲同一材料。此時,由於塑膠薄膜1 與芯材5的熱膨脹動作相同,所以在加熱處理時可防止塑 膠薄膜1產生變形。 芯材5的長度可與塑膠薄膜1的寬度同等或以上。如 此可防止塑膠薄膜1之長邊方向的兩邊緣部產生變形。此 外’芯材5的直徑,較佳爲一般的直徑之3吋或6吋,但 爲了形成塑膠薄膜1的捲取體4,可考量捲取作業性而設 爲6吋。再者,芯材5的厚度,只要是具有用以捲取塑膠 薄膜1之強度者即可,並無特別限定,可爲1〜l〇mm,較 佳爲3〜5 mm。爲了提升塑膠薄膜1的捲取體4之加熱處理 效率,較佳係縮小芯材5的體積以降低該熱容量。 接著說明本實施形態之加熱爐。加熱爐,較佳係使用 如第3圖及第4圖所示般之所謂供烤爐1 0。於烘烤爐1 〇 內部,由於使氣體(通常爲空氣,因情況的不同可使用氮 氣等之非活性氣體)對流以均一地控制內部溫度,所以可 -13- 201244906 均一且效率佳地加熱(烘烤)塑膠薄膜1全體。烘烤爐10 可適當地使用無塵規格的烘烤爐(例如有ESPEC股份有 限公司製的無塵烘烤爐PVHC系列)。 在此般烘烤爐1 〇中加熱塑膠薄膜1的捲取體4時, 如第3圖所示’可將塑膠薄膜1的捲取體4設置(縱向設 置)在烘烤爐10內的網架11以使軸向方向呈垂直。或是 如第4圖所示,使圓柱狀的保持構件12通過圓筒狀之芯 材5的中空部,將軸承構件13安裝在烘烤爐1〇內的網架 11,並將保持構件12的兩端部安裝在軸承構件13,來設 置(橫向設置)塑膠薄膜1的捲取體4。如此,塑膠薄膜 1可在不接觸於烘烤爐10內的網架11或內壁等而設置捲 取體4,藉此可均一地加熱塑膠薄膜1全體。 烘烤爐1 0中,當芯材5由樹脂所構成時,較佳是以 該芯材5之玻璃轉移點以下的溫度,並且當支撐構件2由 樹脂所構成時,較佳是以該支撐構件2之玻璃轉移點以下 的溫度,加熱塑膠薄膜1。藉此可防止芯材5及支撐構件 2產生變形,並防止塑膠薄膜1由於加熱而產生變形。烘 烤爐1 〇的加熱溫度,只要較塑膠薄膜1的熔點更低,則 可爲玻璃轉移點以上的溫度。 接著使用第5圖,說明由此般構成所形成之本實施形 態的作用,亦即本實施形態之塑膠薄膜1的加熱方法,以 及包含該方法之彩色濾光片的製造方法。 首先準備捲取爲滾筒狀之帶狀塑膠薄膜1(製程S1) -14--12- S 201244906 A large interval' is preferable because the gas permeability can be imparted to the void layer 3. Further, the embossed film may be, for example, a general-purpose carrier tape or the like, or a member having any irregular shape formed by press molding or the like. Next, the core material 5 will be described. The core material 5 is not particularly limited as long as it does not melt and ignite at the temperature of the heat treatment, and plastic, paper, metal, etc. can be used. In general, since the metal has a smaller coefficient of thermal expansion than the plastic, the core material 5 prevents the plastic film 1 from being further expanded during the heat treatment, and prevents the plastic film 1 from being deformed. Alternatively, a resin having a thermal expansion coefficient equivalent to that of the plastic film 1 can be used, in particular, the same material as the plastic film 1. At this time, since the plastic film 1 and the core material 5 have the same thermal expansion operation, the plastic film 1 can be prevented from being deformed during the heat treatment. The length of the core material 5 may be equal to or greater than the width of the plastic film 1. Thus, deformation of both edge portions in the longitudinal direction of the plastic film 1 can be prevented. Further, the diameter of the core material 5 is preferably 3 吋 or 6 一般 of the normal diameter. However, in order to form the winding body 4 of the plastic film 1, the winding workability can be considered to be 6 。. Further, the thickness of the core material 5 is not particularly limited as long as it has the strength for winding up the plastic film 1, and may be 1 to 10 mm, preferably 3 to 5 mm. In order to improve the heat treatment efficiency of the take-up body 4 of the plastic film 1, it is preferable to reduce the volume of the core material 5 to lower the heat capacity. Next, the heating furnace of this embodiment will be described. The heating furnace is preferably a so-called oven 10 as shown in Figs. 3 and 4. In the inside of the baking oven, since the gas (usually air, depending on the situation, an inert gas such as nitrogen can be used) convection to uniformly control the internal temperature, it can be uniformly and efficiently heated (-13-201244906) Bake) All of the plastic film 1 In the baking oven 10, a dust-free baking oven (for example, a dust-free baking oven PVHC series manufactured by ESPEC Co., Ltd.) can be suitably used. When the winding body 4 of the plastic film 1 is heated in the baking oven 1 as shown in Fig. 3, the winding body 4 of the plastic film 1 can be disposed (longitudinally disposed) in the net in the baking oven 10. The frame 11 is oriented such that the axial direction is vertical. Alternatively, as shown in Fig. 4, the cylindrical holding member 12 is passed through the hollow portion of the cylindrical core member 5, the bearing member 13 is attached to the grid 11 in the baking oven 1b, and the holding member 12 is held. Both ends are attached to the bearing member 13 to set (laterally) the take-up body 4 of the plastic film 1. Thus, the plastic film 1 can be provided with the take-up body 4 without contacting the grid 11 or the inner wall of the baking oven 10, whereby the entire plastic film 1 can be uniformly heated. In the baking oven 10, when the core material 5 is composed of a resin, it is preferably a temperature lower than the glass transition point of the core material 5, and when the support member 2 is composed of a resin, it is preferably the support. The plastic film 1 is heated at a temperature below the glass transition point of the member 2. Thereby, deformation of the core material 5 and the support member 2 can be prevented, and deformation of the plastic film 1 due to heating can be prevented. The heating temperature of the oven 1 可 can be a temperature above the glass transition point as long as it is lower than the melting point of the plastic film 1. Next, the action of the present embodiment formed by the above-described configuration, that is, the heating method of the plastic film 1 of the present embodiment, and the method of manufacturing the color filter including the method will be described with reference to Fig. 5. First, prepare to take up the strip-shaped plastic film 1 (process S1) -14-
S 201244906 接著拉出捲取爲滾筒狀之塑膠薄膜1,將含有彩色濾 光片7形成用的樹脂之感光性材料塗佈於被拉出之塑膠薄 膜1(製程S2)。亦即,將彩色濾光片7用的黑色矩陣、 紅色像素、綠色像素、或藍色像素用的感光性材料塗佈於 塑膠薄膜1。 接著使塗佈後的感光性材料乾燥(製程S3)。 然後使用具有預定形狀之光罩(圖中未顯示),使塑 膠薄膜1上的感光性材料曝光(製程S4)。 接著使曝光後的感光性材顯影(製程S5)。藉此在 塑膠薄膜1上形成有由感光性材料所構成之圖型6。 然後加熱塑膠薄膜1。 此時,首先於塑膠薄膜1之間夾介支撐構件2而將帶 狀塑膠薄膜1捲取於芯材5,並藉由該支撐構件2使空隙 層3中介存在於塑膠薄膜1之間來形成塑膠薄膜1的捲取 體4(製程S6)。在此,支撐構件2係配置在塑膠薄膜1 之圖型6以外的區域,尤其配置在塑膠薄膜1之長邊方向 的兩邊緣部。此外,塑膠薄膜1,如上述般,較佳是以 lN/mm2以下之每單位剖面積的張力所捲取》 接著,將塑膠薄膜1的捲取體4投入於預先加熱至所 期望的溫度之烘烤爐1〇中(製程S7)。被投入之捲取體 4,係以第3圖或第4圖所示之形態設置在烘烤爐1 〇內。 接著於烘烤爐1 〇內,以所期望的溫度加熱(烘烤) 塑膠薄膜1的捲取體4(製程S8)。 結束加熱處理後,從烘烤爐1 〇取出塑膠薄膜1的捲 -15- 201244906 取體4 (製程S 9 )。 藉由重覆進行上述製程S2〜9,可於塑膠薄膜1上依 序形成黑色矩陣、紅色像素、綠色像素、及藍色像素。如 此,塑膠薄膜1上形成有具有彩色濾光片7用的功能性之 圖型6,而得彩色濾光片7(參照第2圖)。 如此,根據本實施形態,由於將使感光性材料曝光及 顯影而形成有圖型6之帶狀塑膠薄膜1予以捲取並形成捲 取體4來加熱,故可一次加熱塑膠薄膜1及圖型6全體。 此外,由於藉由支撐構件2使空隙層3中介存在於塑膠薄 膜1之間,所以可將烘烤爐1 〇所產生的熱,經由空隙層3 傳遞至塑膠薄膜1及圖型6全體。因此可均一且迅速地加 熱塑膠薄膜1及圖型6,並且提升塑膠薄膜1與圖型6之 密著性。 此外,根據本實施形態,由於在塑膠薄膜1之間夾介 支撐構件2而捲取形成有圖型6之帶狀塑膠薄膜1,所以 可防止塑膠薄膜1彼此接觸並因加熱而固著,並可防止塑 膠薄膜1及圖型6產生變形。尤其是藉由夾介支撐構件2 來捲取塑膠薄膜1,只要烘烤爐10的加熱溫度較塑膠薄膜 1的熔點更低,即使在玻璃轉移點以上的溫度,亦可防止 塑膠薄膜1及圖型6產生變形。 本實施形態中’係說明以滾紋形態所捲取並在烘烤爐 10內被加熱之塑膠薄膜1上,形成有彩色濾光片7用的黑 色矩陣、紅色像素、綠色像素 '及藍色像素之例子。然而 並不限定於此’亦可在塑膠薄膜1上,藉由構成作爲光學S 201244906 Next, the plastic film 1 wound into a roll shape is pulled out, and the photosensitive material containing the resin for forming the color filter 7 is applied to the drawn plastic film 1 (process S2). That is, a photosensitive material made of a black matrix, a red pixel, a green pixel, or a blue pixel for the color filter 7 is applied to the plastic film 1. The coated photosensitive material is then dried (process S3). Then, a photosensitive material having a predetermined shape (not shown) is used to expose the photosensitive material on the plastic film 1 (process S4). Next, the exposed photosensitive material is developed (process S5). Thereby, a pattern 6 composed of a photosensitive material is formed on the plastic film 1. The plastic film 1 is then heated. At this time, first, the support member 2 is interposed between the plastic film 1 to wind the tape-shaped plastic film 1 on the core material 5, and the void layer 3 is interposed between the plastic film 1 by the support member 2 to form. The winding body 4 of the plastic film 1 (process S6). Here, the support member 2 is disposed in a region other than the pattern 6 of the plastic film 1, in particular, at both edge portions in the longitudinal direction of the plastic film 1. Further, as described above, the plastic film 1 is preferably wound up by a tension per unit sectional area of 1 N/mm 2 or less. Next, the winding body 4 of the plastic film 1 is put into a preheating to a desired temperature. Baking oven 1 (Process S7). The wound body 4 to be placed is placed in the baking oven 1 in the form shown in Fig. 3 or Fig. 4. Next, the winding body 4 of the plastic film 1 is heated (baked) at a desired temperature in the baking oven 1 (process S8). After the end of the heat treatment, the roll -15-201244906 of the plastic film 1 is taken out from the baking oven 1 (Process S 9). By repeating the above-described processes S2 to S9, a black matrix, a red pixel, a green pixel, and a blue pixel can be sequentially formed on the plastic film 1. Thus, the plastic film 1 is formed with a pattern 6 having a functional color for the color filter 7, and a color filter 7 is obtained (see Fig. 2). As described above, according to the present embodiment, the strip-shaped plastic film 1 in which the pattern 6 is formed by exposing and developing the photosensitive material is taken up and heated by the winding body 4, so that the plastic film 1 and the pattern can be heated at one time. 6 overall. Further, since the void layer 3 is interposed between the plastic films 1 by the support member 2, heat generated in the baking oven 1 can be transmitted to the entire plastic film 1 and the pattern 6 via the void layer 3. Therefore, the plastic film 1 and the pattern 6 can be uniformly and rapidly heated, and the adhesion of the plastic film 1 to the pattern 6 can be improved. Further, according to the present embodiment, since the strip-shaped plastic film 1 in which the pattern 6 is formed is taken up by sandwiching the support member 2 between the plastic films 1, the plastic film 1 can be prevented from coming into contact with each other and fixed by heating, and It can prevent deformation of the plastic film 1 and the pattern 6. In particular, the plastic film 1 is taken up by interposing the support member 2, as long as the heating temperature of the baking oven 10 is lower than the melting point of the plastic film 1, even at a temperature above the glass transition point, the plastic film 1 and the figure can be prevented. Type 6 is deformed. In the present embodiment, a black matrix, a red pixel, a green pixel', and a blue color for the color filter 7 are formed on the plastic film 1 which is taken up in a embossed form and heated in the baking oven 10. An example of a pixel. However, it is not limited to this. It can also be formed on the plastic film 1 by optical
S -16- 201244906 構件之配向膜、透鏡陣列、相位差層、偏光層、或導光板 等之樹脂來形成圖型。此時亦可防止塑膠薄膜1及上述圖 型產生變形,並可均一且迅速地加熱,此外,亦可提升塑 膠薄膜1與上述圖型之密著性。 或是在塑膠薄膜1上,爲了形成作爲驅動電路之導電 性配線、T F T陣列 '或構成透明電極之預定形狀的金屬層 (圖中未顯示),亦可藉由蝕刻用樹脂來形成抗蝕層。亦 即,在塑膠薄膜1上設置上述金屬層,於該金屬層上塗佈 含有蝕刻用樹脂之抗蝕材料,進行乾燥、曝光、顯影,而 形成由抗蝕層所構成之圖型,然後爲了對該圖型進行加熱 (烘烤)處理,係將塑膠薄膜1捲取爲滾紋形態並在烘烤 爐10中加熱。此時亦可防止塑膠薄膜1及上述圖型產生 變形,並可均一且迅速地加熱,此外,亦可提升金屬層與 上述圖型之密著性。 本發明之變形例 接著說明本發明之塑膠薄膜的加熱方法,以及包含該 方法之彩色濾光片的製造方法之變形例。本變形例中,爲 未形成圖型之塑膠薄膜被捲取爲滾紋形態並在烘烤爐內被 加熱之例子,其他構成與第1圖至第5圖所示之實施形態 大致相同。 本變形例中,未形成圖型6之帶狀塑膠薄膜1被捲取 爲滾紋形態並在烘烤爐1 〇內被加熱。 亦即,在將用以形成圖型6之感光性材料塗佈於塑膠 -17- 201244906 薄膜1前(第5圖所示之製程S2前),將帶狀塑膠薄膜 1捲取爲滾紋形態來進行加熱處理。 根據本變形例,由於在將圖型6形成於塑膠薄膜1前 ’將塑膠薄膜1加熱使其產生熱收縮,所以之後在對形成 有圖型6之塑膠薄膜1進行加熱(烘烤)處理時,可防止 塑膠薄膜1產生收縮,而提升形成於塑膠薄膜1之圖型6 的尺寸精度。 此外,根據本變形例,由於將帶狀塑膠薄膜1予以捲 取並形成捲取體4來加熱,故可一次加熱帶狀塑膠薄膜1 全體。此外’由於藉由支撐構件2使空隙層3中介存在於 塑膠薄膜之間,所以可將烘烤爐1 0所產生的熱,經由空 隙層3傳遞至塑膠薄膜].全體。因此可均一且迅速地加熱 塑膠薄膜1。 再者’根據本變形例,由於在塑膠薄膜1之間夾介支 撐構件2而捲取帶狀塑膠薄膜1,所以可防止塑膠薄膜! 彼此接觸並因加熱而固著,並可防止塑膠薄膜1產生變形 。尤其是藉由夾介支撐構件2來捲取塑膠薄膜1,只要烘 烤爐1 0的加熱溫度較塑膠薄膜1的熔點更低,即使在玻 璃轉移點以上的溫度下,亦可防止塑膠薄膜1產生變形。 〔實施例〕 實施例1 首先針對藉由本發明之塑膠薄膜的加熱方法進行加熱S -16- 201244906 A resin such as an alignment film, a lens array, a retardation layer, a polarizing layer, or a light guide plate of a member to form a pattern. At this time, the plastic film 1 and the above-mentioned pattern can be prevented from being deformed, and the film can be uniformly and rapidly heated, and the adhesion of the plastic film 1 to the above pattern can be improved. Alternatively, on the plastic film 1, in order to form a conductive wiring as a driving circuit, a TFT array 'or a metal layer of a predetermined shape constituting a transparent electrode (not shown), a resist layer may be formed by etching a resin. . That is, the metal layer is provided on the plastic film 1, and a resist material containing an etching resin is applied onto the metal layer, dried, exposed, and developed to form a pattern composed of a resist layer, and then The pattern is subjected to a heating (baking) treatment in which the plastic film 1 is wound into a rolled form and heated in a baking oven 10. At this time, the plastic film 1 and the above-mentioned pattern can be prevented from being deformed, and the heating can be uniformly and rapidly heated, and the adhesion of the metal layer to the above pattern can be improved. Modification of the Invention Next, a modification of the method for heating the plastic film of the present invention and a method for producing the color filter including the method will be described. In the present modification, the plastic film in which the pattern is not formed is wound into a embossed form and heated in a baking oven, and the other configuration is substantially the same as that of the embodiment shown in Figs. 1 to 5 . In the present modification, the strip-shaped plastic film 1 in which the pattern 6 is not formed is wound into a embossed form and heated in the baking oven 1 crucible. That is, before the photosensitive material for forming the pattern 6 is applied to the plastic -17-201244906 film 1 (before the process S2 shown in FIG. 5), the tape-shaped plastic film 1 is taken up into a roll form. To heat treatment. According to the present modification, since the plastic film 1 is heated to cause heat shrinkage before the pattern 6 is formed on the plastic film 1, the heating (baking) treatment of the plastic film 1 on which the pattern 6 is formed is performed. The plastic film 1 can be prevented from shrinking, and the dimensional accuracy of the pattern 6 formed on the plastic film 1 can be improved. Further, according to the present modification, since the strip-shaped plastic film 1 is taken up and the winding body 4 is formed and heated, the entire strip-shaped plastic film 1 can be heated at a time. Further, since the void layer 3 is interposed between the plastic films by the support member 2, the heat generated by the baking oven 10 can be transmitted to the plastic film through the gap layer 3. Therefore, the plastic film 1 can be uniformly and rapidly heated. Further, according to the present modification, since the strip-shaped plastic film 1 is taken up by sandwiching the support member 2 between the plastic films 1, the plastic film can be prevented! They are in contact with each other and fixed by heating, and can prevent deformation of the plastic film 1. In particular, the plastic film 1 is taken up by interposing the support member 2, as long as the heating temperature of the baking oven 10 is lower than the melting point of the plastic film 1, even at a temperature above the glass transfer point, the plastic film 1 can be prevented. Deformation occurs. [Examples] Example 1 First, heating was performed by the heating method of the plastic film of the present invention.
S -18- 201244906 後之塑膠薄膜1是否產生變形進行調查。 首先準備寬度300mm、長度10m的PET薄膜(東洋 紡績股份有限公司製的Cosmo Shine A4100、厚度125ym 、玻璃轉移點:70〜110 °C、熔點:258 °C )作爲塑膠薄膜1 ’並準備寬度30 mm、長度10m的聚醯亞胺薄膜(Teijin DuPont Film股份有限公司製的Kapton Film、厚度75 v m 、玻璃轉移點:400t以上)作爲支撐構件2。將該聚醯亞 胺薄膜配置在PET薄膜之長邊方向的兩邊緣部(具體而言 爲距離兩邊緣部30mm的位置),並以lN/mm2之每單位 剖面積的張力捲取於圓筒狀芯材(內徑爲3吋)5,而形 成中介存在有厚度75ym的空隙層3之PET薄膜的捲取 體4。此時,可確認到PET薄膜之兩邊緣部以外的區域, 乃藉由空隙層3而使PET薄膜彼此不接觸。 接著將PET薄膜的捲取體4投入於預先加熱至23 (TC 之無塵烘烤爐(ESPEC股份有限公司製的PVHC3 3 0 )。 此時將PET薄膜的捲取體4如第3圖所示般地縱向放置, 並設置在網架1 1上。對所設置之PET薄膜進行30分鐘的 加熱處理,然後從烘烤爐1 〇中取出並進行空氣冷卻。 將此般經加熱處理後之PET薄膜拉出,來確認PET 薄膜是否產生變形,可得知即使將PET薄膜加熱至該玻璃 轉移點以上的溫度,在PET薄膜之未接觸於支撐構件2的 部分上,並未產生PET薄膜彼此的固著,且亦未觀察到扭 曲等變形。 此外,作爲比較例1,係不使用支撐構件2 (未中介 -19- 201244906 存在空隙層3 )而將與上述相同之PET薄膜捲取於芯材5 ,除此之外,其他與上述相同,於烘烤爐1〇中在2 3 0°C下 加熱3 0分鐘。 在此般經加熱處理後之PET薄膜中,可確認到皺折和 扭曲較爲劇烈,而無法保持原先形狀。 實施例2 準備PEN薄膜(Teijin DuPont Film股份有限公司製 的 Teonex Q65FA、厚度 10〇em、玻璃轉移點:155°C、 熔點:269 °C )作爲塑膠薄膜1,並將烘烤爐10的加熱溫 度設爲15(TC,除此之外,其他藉由與上述實施例1相同 之方法,來調查PEN薄膜是否產生變形。 將此般經加熱處理後之PEN薄膜拉出,來確認PEN 薄膜是否產生變形,可確認到涵蓋PEN薄膜全體,PEN薄 膜彼此均未固著,且亦未觀察到扭曲等變形。 作爲比較例2,係不使用支撐構件2 (未中介存在空 隙層3)而將與上述相同之PEN薄膜捲取於芯材5,除此 之外,其他與上述相同,於烘烤爐10中在150 °C下加熱 3 0分鐘。 在此般經加熱處理後之PEN薄膜中,可確認到皴折和 扭曲較爲劇烈,且PEN薄膜處於彼此固著而無法剝離之狀 態。 作爲比較例3,係將捲取PEN薄膜時之每單位剖面積 的張力設爲1 .7N/mm2,除此之外,其他與上述相同,於S -18- 201244906 After the plastic film 1 is deformed, investigate. First, a PET film having a width of 300 mm and a length of 10 m (Cosmo Shine A4100, thickness: 125 μm, glass transfer point: 70 to 110 ° C, melting point: 258 ° C) was prepared as a plastic film 1 'and a width of 30 was prepared. A polyimide film of mm and a length of 10 m (Kapton Film manufactured by Teijin DuPont Film Co., Ltd., thickness: 75 vm, glass transition point: 400 t or more) was used as the support member 2. The polyimide film is disposed on both edge portions of the PET film in the longitudinal direction (specifically, a position 30 mm away from both edge portions), and is taken up in a cylinder at a tension per unit area of 1 N/mm 2 The core material (inner diameter: 3 Å) 5 was formed to form a wound body 4 in which a PET film having a void layer 3 having a thickness of 75 μm was interposed. At this time, it was confirmed that the regions other than the both edge portions of the PET film were such that the PET films were not in contact with each other by the void layer 3. Next, the wound body 4 of the PET film was placed in a dust-free baking oven (PVHC3 3 0 manufactured by ESPEC Co., Ltd.) which was previously heated to 23 (TC). At this time, the wound body 4 of the PET film was as shown in Fig. 3. It is placed longitudinally and placed on the grid 11. The PET film is heat treated for 30 minutes, then taken out from the oven 1 and air cooled. The PET film was pulled out to confirm whether the PET film was deformed. It was found that even if the PET film was heated to a temperature above the transfer point of the glass, the PET film was not produced on the portion of the PET film that was not in contact with the support member 2. The fixation was not observed, and deformation such as distortion was not observed. Further, as Comparative Example 1, the same PET film as described above was taken up in the core without using the support member 2 (the void layer 3 was not present in -19-201244906). In addition to the above, the other materials were heated at 230 ° C for 30 minutes in the same manner as above. In the thus treated PET film, wrinkles and wrinkles were confirmed. The distortion is more severe and the original shape cannot be maintained. 2 A PEN film (Teonex Q65FA manufactured by Teijin DuPont Film Co., Ltd., thickness 10 〇em, glass transition point: 155 ° C, melting point: 269 ° C) was prepared as the plastic film 1, and the heating temperature of the baking furnace 10 was set. Otherwise, the PEN film was deformed by the same method as that of the above-mentioned Example 1, except that the PEN film was pulled out to confirm whether the PEN film was deformed or not. It was confirmed that the entire PEN film was covered, and the PEN film was not fixed to each other, and no deformation such as distortion was observed. As Comparative Example 2, the support member 2 was not used (the void layer 3 was not interposed) and would be the same as described above. The PEN film was taken up in the core material 5, and the other was heated in the baking oven 10 at 150 ° C for 30 minutes. The PEN film after the heat treatment was confirmed. The folding and twisting were severe, and the PEN film was in a state of being fixed to each other and could not be peeled off. As Comparative Example 3, the tension per unit sectional area when the PEN film was wound up was set to 1.7 N/mm 2 , except Other than the above ,to
-20- S 201244906 烘烤爐10中在l5〇°C下加熱30分鐘。 在此般經加熱處理後之PEN薄膜中,可確認到在PEN 薄膜之寬度方向的中央部分,產生在寬度方向上延伸之線 狀皺折。 實施例3 預先將圖型6形成於PET薄膜,除此之外,其他與上 述實施例1同樣地進行加熱,並確認PET薄膜與圖型6是 否產生變形。 PET薄膜上的圖型6係以下列方式製得。亦即藉由凹 版印刷方式’以1/ζιη的厚度塗佈抗蝕材料(感光性材料 )’然後在50 °C下使該抗蝕材料乾燥2分鐘。接著夾介具 有所期望的形狀之光罩,對塗佈於PET薄膜之抗蝕材料進 行紫外線曝光。然後進行顯影而形成由所構成之圖型6。 藉由與實施例1相同之方法對如此形成有圖型6之 PET薄膜進行加熱處理,然後確認pet薄膜與圖型6是否 產生變形’可得知即使將PET薄膜加熱至該玻璃轉移點以 上的溫度’在PET薄膜之形成有圖型6的部分上,並未觀 察到皺折和扭曲等變形。此外,圖型6與PET薄膜之密著 性’與加熱處理前相比,可確認到顯著的改善。 【圖式簡單說明】 , 第1圖係顯示本發明的實施形態之塑膠薄膜的捲取體 之立體圖。 -21 - 201244906 第2圖(a )係顯示本發明的實施形態中’支撐構件 之配置的一例之俯視圖,第2圖(b)爲第2圖(a)之側 視圖,第2圖(c )係顯示支撐構件之配置的其他例子之 俯視圖,第2圖(d )爲第2圖(c )之側視圖。 第3圖係顯示本發明的實施形態中’將塑膠薄膜的捲 取體設置在烘烤爐之狀態的一例之圖° 第4圖係顯示本發明的實施形態中’將塑膠薄膜的捲 取體設置在烘烤爐之狀態的其他例子之圖。 第5圖係顯示本發明的實施形態之塑膠薄膜的加熱方 法及彩色濾光片的製造方法之流程圖。 【主要元件符號說明】 1 :塑膠薄膜 2 :支撐構件 2a :凹部 3 :空隙層 4 :捲取體 5 :芯材 6 :圖型 7 :彩色濾光片 1 〇 :加熱爐 1 1 :網架 1 2 :保持構件 1 3 :軸承構件-20- S 201244906 The oven 10 was heated at 15 ° C for 30 minutes. In the PEN film which was subjected to the heat treatment, it was confirmed that a linear wrinkle extending in the width direction occurred in the central portion in the width direction of the PEN film. (Example 3) Heating was carried out in the same manner as in Example 1 except that the pattern 6 was formed on the PET film in advance, and it was confirmed whether or not the PET film and the pattern 6 were deformed. The pattern 6 on the PET film was produced in the following manner. That is, the resist material (photosensitive material) was applied by a gravure printing method at a thickness of 1/ζη, and then the resist material was dried at 50 ° C for 2 minutes. Next, a mask having a desired shape is interposed to expose the resist material applied to the PET film to ultraviolet light exposure. Then, development is carried out to form a pattern 6 composed of the pattern. The PET film thus formed with the pattern 6 was subjected to heat treatment in the same manner as in Example 1, and then it was confirmed whether or not the PET film and the pattern 6 were deformed. It was found that even if the PET film was heated above the glass transition point, The temperature 'on the portion of the PET film on which the pattern 6 was formed, no deformation such as wrinkles and distortion was observed. Further, the adhesion between the pattern 6 and the PET film was confirmed to be remarkably improved as compared with that before the heat treatment. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view showing a wound body of a plastic film according to an embodiment of the present invention. -21 - 201244906 Fig. 2(a) is a plan view showing an example of the arrangement of the support members in the embodiment of the present invention, and Fig. 2(b) is a side view of Fig. 2(a), and Fig. 2(c) A plan view showing another example of the arrangement of the support members, and Fig. 2(d) is a side view of Fig. 2(c). Fig. 3 is a view showing an example of a state in which a wound body of a plastic film is placed in a baking oven in the embodiment of the present invention. Fig. 4 is a view showing a winding body of a plastic film in an embodiment of the present invention. A diagram of another example of the state of the oven. Fig. 5 is a flow chart showing a method of heating a plastic film and a method of producing a color filter according to an embodiment of the present invention. [Main component symbol description] 1 : Plastic film 2 : Support member 2a : Recessed portion 3 : Void layer 4 : Winding body 5 : Core material 6 : Pattern 7 : Color filter 1 〇 : Heating furnace 1 1 : Grid 1 2 : holding member 1 3 : bearing member
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2010
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2011
- 2011-09-07 WO PCT/JP2011/070351 patent/WO2012043174A1/en active Application Filing
- 2011-09-20 TW TW100133772A patent/TW201244906A/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2012071540A (en) | 2012-04-12 |
JP5609496B2 (en) | 2014-10-22 |
WO2012043174A1 (en) | 2012-04-05 |
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