201243425 t、發明說明： 【發明所屬之技術領域】 隱形眼鏡可將之著色或染色以對眼鏡提供不同外 觀效果。藉此矯正眼睛外觀問題或美容。 【先前技術】 美國專利第4,652,099號提出一種具有周圍部位 著以白色之隱形眼鏡。然而，僅將該部位著以白色通 常無法獲得能使眼睛外觀自然或期望效果的鏡片。本 發明之鏡片可解決此問題。 【發明内容】 本發明係一隱形眼鏡，其具有中心部位及配置圍 繞中心部位之周圍部位。該周圍部位係著以亮色且具 有向鏡片外徑漸層至透明的圖案。 該亮彩周圍部位在接近周圍部位内徑可為不透 明、半不透明或半透明，且可包括著以顏色之（角膜） 緣（limbus )或緣環。該明亮部位自緣的邊緣延伸至 周圍部位，產生較明亮或較白鞏膜的效果。加上緣環， 提供對比添加及有助於較明亮或較白鞏膜的整體效 果。在本發明另一態樣中，該隱形眼鏡周圍部位係依 幾何圖案著以顏色。 本發明之鏡片具有自然的外觀呈現。 201243425 【實施方式】 本發明之鏡片具有強化鏡片配戴者鞏膜外觀呈現 的圖案。彼等鏡片亦可包括能形成虹膜顯現較原來更 大或更深或更輪廓分明的緣環圖案。此外，本發明之 鏡片可具有完全或部分覆蓋配戴者虹膜上的附加圖案 元件。 ' 「緣環」係一環狀色帶，當鏡片在眼上且位於中 心時，會部分或完全上覆鏡片配戴者的輪部或鞏膜與 角膜交界。緣環最内部邊緣或最接近鏡片幾何中心^ 邊緣可形成一具有直徑約8 mm至約12 mm的圓形， 較佳的是約11 mm至約13 mm，該圓係對準鏡片的幾 何中心。該環可具有任何適當之寬度，且較佳的是約 0.5至約2.5 mm的寬度，更佳的是約〇 75至約2 〇〇 mm 的寬度。 該中心部分含用以配戴時覆蓋虹膜的區域。該中 心部分因此亦可著以顏色且含—緣環。較佳的是虹膜 和緣環兩者均依美國專利第7,246,9〇3號圖案化，其在 本文中引用列為參考。此種著色視情況實質上包括三 角形狀結構，類似輪輻，自緣環最内部邊緣向鏡片幾 何中心往内延伸。上述一端漸細輪輻形可以，但最好 是不要延伸超過整個鏡片的虹膜部分，即當鏡片在眼 上且位於中心時鏡片上覆虹膜的部分。應該說，較佳 的是該輪輻自緣環最内部邊緣往内延伸，使得輪輻圖 案最内部邊緣位於距_片幾何中心約6 5 mm 4 201243425 相同= _或更多。該輪輻可形狀及大小 且較麵是長度約丨至約2_。 用於隱形眼常:為圓形’但可為任何適 具有-中心ln /狀’例如橢圓形或截圓形。該鏡片 η且延伸至於^及中㈣分u。配置圍繞該中心區 部分且有內周圍邊緣者係-周圍部分2〇。該周園 1刀具有—内# 21及一外僻？？，甘叮 須與签個鏡片之外邊 其可以但不-定必 色、2〇係著以亮色。「亮色」係定義為白 淺綠色$ ΗΛ白&、淺黃色、淡藍色、淺粉紅色、 鞏膜逐_^均組合。該亮色伽置⑽與配戴者 判視情況亦可具有—緣環或圖案13(圖2)。 …。Ρ刀20係依本發明著以顏色之部分，以強化鞏 膜外觀呈現。本鏡片周圍部分的上色可為不透明、半 透明或介於兩者間（半不透明）。其不一定為一致的顏 色，但依本發明之實施例，較佳的是藉由提供鞏膜具 有朝氣、較自然的外觀，以強化其外觀。針對這些目 的的「不透明」意指能使波長380至780 nm光的平均 透光度（％ T)範圍在0至約50% T的色彩，較佳的 疋7至約50% T。針對這些目的的「半透明」意指能 使波長380至780 nm光的平均透光度（％τ)範圍在 約50至約85% Τ的色彩’較佳的是約65至約85% Τ。 201243425 圖2顯示本發明之一實施例， ，自周圍内徑21至周圍外徑22為== 透明或透明的漸層變化，以及緣環13。中 + =著=二果其眼上效果係為覆蓋:強化 明亮著 實一及深色緣環對 =、虹膜圖案及塗於周圍的白色著=: 的適合寬度或圖案。該緣環可為半透明或不透明。中 ^分11通常係直徑10·13 mm，且較佳的是直徑大 於 11 mm。 圖3顯示本發明具有以幾何圖案形式塗於周圍2〇 之明壳色彩的鏡片。在此例中，該圖案隨自鏡片表面 移除的圓形形態呈現（否則就為著以白色），使各圓沿 切線方向接觸其相鄰圓。其亦可視為由彼等圓形形成 的多個橫列之十字形亮色結構。包含幾何形狀之圖案 可形成自規則形狀結構或如圖4所見之複數個隨機小 點或形狀。可使用任何其他展現逼真或強化色調感的 合適形狀，特別是可達成所需之色調或色度的幾何形 狀。用於本發明之圖案的小點可為任何大小，而較佳 的是直徑約0.060至約0.180 mm者，更佳的是直徑約 〇·〇〇75至約〇·〇π5 mm。小點有助於鏡片不同元件邊 緣的融合。 6 201243425 在本發明之任何圖案中，該中心較佳的是澄清 的。然而，中心部分可為半透明或不透明顏色或不透 明和半透明顏色的任何組合的區域。 在使用於鏡片中作為強化或改變配戴者眼睛顏色 時，較佳的是該緣環元件係遮蓋鏡片配戴者緣區顏色 之實心色帶，更佳的是該遮蓋色彩係不透明顏色。剩 餘的元件，即輪輻、小點及其他圖案元件，視所需的 眼上美容結果，可為半透明或不透明。 選作為各緣環及虹膜圖案元件的顏色，係由鏡片 配戴者的虹膜自然顏色及所需的強化或顏色改變決 定。因此，元件可為任何顏色，包括但不限於藍色、 綠色、灰色、褐色、深黄、紅色或其組合的多種色調 及色度中的任何一種。緣環的較佳顏色包括但不限於 黑色、褐色、灰色、藍色及深綠色的多種色調及色度 中的任何一種。 包含周圍部分之亮色元件可為純白色、近白色、 灰白色、淺黃色、淡藍色、淺粉紅色、淺綠色或上述 之任何組合。較佳的是，其為相稱而不會與未被鏡片 覆蓋的鞏膜可見部分有突兀的對比。這些顏色較佳的 是藉由使用具有較高量Ti02獲得，以產生較大的不透 明度及對比。加入之顏料包括但不限於小量的氧化鐵 黑、氧化鐵棕、氧化鐵黃、氧化鐵紅、二氧化鈦及其 類似物和其組合，以調整較白的已著色元件。除了這 些顏料，還可使用可溶及不可溶性染料，其包括但不 201243425 限於二氣三嗪和乙烯砜系染料。較佳實施例為具有 10%至20%的Ti02以及80%至90%澄清黏結聚合物的 著色劑，以提供適當之半透明色。 一般而言，著色元件可由任何適用於隱形眼鏡之 有機或無機顏料或此種顏料組合製成。不透明度可藉 由改變所使用的顏料和二氧化鈦之濃度控制，較高的 量獲得較大的不透明度。示例性的有機顏料包括但不 限於酞花青藍、酞花青綠、咔唑紫、還原橙ι號&扣 ⑽啡#丨）及其_物和其組合。可用的無機顏料例 子包括但不限於氧化鐵黑、氧化鐵棕、氧化鐵黃、氧 化鐵紅、二氧化鈦及其類似物，和其組合。除了這些 顏料外’還可使用可溶及不可溶性染料，其包括但不 限於-乳三。秦和乙細系染料。可用的染料 市售可得。〆 处耳Ϊ擇之染料或顏料可結合一或多種預聚合物或黏 4 =物’以及—溶L成歸生產本發明之鏡 2半透明及不透明層著色劑。亦可使用隱形眼鏡著 的ΐ他添加劑。可用於本發明的顏色層的黏 二，口，、溶劑及其他添加劑係為 已知，且為市售可 得或其製造方法已知者。 該，件可施加或印刷至鏡片的—或多個表面上， :才具的一個多個表面上，其中鏡片形成 f 模具中。在形成包括本發明的設 見x方法中，使用由任何合適的材料製成的 8 201243425 ^光學模具，這些材料包括但不限於環狀聚 例如聚㈣或聚苯乙烯樹脂。該元件被 模具的成型表面的所需部分上。所謂「成型表、I 指用於形成鏡片表面賴具麵具半_表面= 的疋，該沈積係藉由如下之移印來進行。 又 —金屬板被覆以在固化時可變為水不溶性之光 材料’該金屬板較佳岐由鋼製成，更佳的是由不= 鋼製成。該元件係經選擇或設計，接著使 = 之任=種（例如感光技術）縮至所需大小、置於金: 板上並將光阻材料固化。隨後用水溶液洗滌該板，並 將所得之圖像蝕刻在該板上至合適深度，例如約加微 米。接著將含黏結聚合物、溶劑和顏料或染料的著色 劑沈積在該元件上，以使著色劑填充凹陷部。 該金屬板亦可使用適當軟體及雷射作雷射蝕刻， 以抽出含較佳圖像區域之金屬，因此產生深度”； 至30 um的複製圖像凹處。此外，較佳圖案的雷射蝕 刻可發生於其他基質上，例如陶免。 將一幾何形狀適合用於在表面上印刷且有可變硬 度（一般是約1度至約10度）的矽質墊壓抵於板上影 像以去除染色劑，然後藉由讓溶劑蒸發的方式緩慢乾 燥該染色劑。然後將該墊壓抵於一光學模具的造模表 面。讓模具進行脫氣作業高達12小時以去除過量溶劑 和氧’隨後用鏡片材料填滿模具。然後用一互補半模 元成模具組件且使該模具組件暴露於適合讓所用鏡片 201243425 材料固化的條件下。此等條件;^^^ ，所選用之鏡片材料。-旦完成固使 鏡片釋離模具，在一緩衝鹽水溶液内平衡。乍業使 ^-較佳實施例中，使用—透明預聚合物層，此 ，聚s物層至少蓋住緣環及點圖案且較佳形成鏡片之 及外表_整體。該預聚合物可為能夠分散所用顏料 壬何失透劑（opacifying agent)的任何聚合物。在 一替代實施例中’各翻案或緣環可藉由噴墨印刷置 於鏡片上或鏡片模具。 本發明可被用來提供以任何已知鏡片形成材料製 成的著色硬式或軟式隱形眼鏡，或是以適於製造此^ 鏡片之材料製成的著色硬式或軟式隱形眼鏡。較佳的 是，本發明之眼鏡是軟式隱形眼鏡，被選來形成鏡片 的材料是適於製造軟式隱形眼鏡的任何材料。用於形 成使用本發明之方法的軟式隱形眼鏡的合用較佳材料 包含但不限於矽酮彈性體類、含矽酮的巨分子（其中 非侷限性包括揭示於美國專利第5,371，147號、 5,314,960號及5,057,578號者，該等專利以引用的方 式併入本文中）、水凝膠類、含矽酮水凝膠類和其類似 物以及其組合。更佳的是，該鏡片係由一含有;5夕氧燒 官能性的材料製成，此等材料包含但不限於聚二甲基 矽氧烷巨分子、曱基丙烯醯氧伸丙基聚烷矽氧烷類及 其混合物、矽酮水凝膠或一由含有羥基圑、綾基團或 二者兼具之單體製成的水凝膠。用以製造軟式隱形眼 10 201243425 鏡的材料為熟知且市售可得。較佳的是，該鏡片材料 為爾夸富康（acquafilcon )、珍富康（genfilcon )、連尼 富康（lenefilcon)、巴拉富康（balafilcon)、羅特富康 (lotrafilcon )或加利富康（gaiyfilcon )。在另一實施 例中，該鏡片可以習知之水凝膠材料製成，例如伊它 富康（etafilcon )。 本發明進一步以下列非限制實例說明。 實例 實例1 :澄清基底墨水組合物製備 使用96 g的1-十二烷硫醇（「d〇DT」）、56.54 g 的曱基丙烯酸月桂酯（「LMA」）、7.40 g的曱基丙烯酸 (「MAA」）、1367 g的曱基丙烯酸經基乙酉旨 (「HEMA」）、68.5 g的甘油、378 g的1-乙氧基-.2-丙 醇（「EP」）、1511 g的乳酸異丙醋（「IPL」）及8.89 g 的2,2’_偶氮雙(2_曱基丁腈）（「AMBN」）製成黏結聚合 物。除了約50至1〇〇 cc的IPl外，首先加入DODT、 單體及溶劑，於一 5公升藍色蓋子的瓶中混合，並且 授拌10分鐘。此混合物隨後被倒入一 5公升具有攪拌 盗及氮氣的不鏽鋼反應器中。將混合物攪拌及加熱大 約25分鐘直至溫度為68°c。當溫度穩定於68〇c後， 將AMBN溶解於剩餘的IpL中，並於開啟氮氣排出時 添加。使此聚合反應進行16至24小時，而後提升溫 度至80°C ’即完成反應。接著將混合物平衡至室溫。 201243425 藉混合4份之IPL與1份之EP，依需要調整混合物之 黏度。 實例2 :黑色墨水製備 黑色移印油墨的製備，係稱重243.47 g的1D明 黑（ID Black Define)(由11.76重量％黑色氧化鐵顏 料（FeO.Fe2〇3，CAS # 12227-89-3)組成，溶於實例 1中所述之澄清基底）’置入一 400 niL玻璃瓶。亦將6 重量％的1-丙醇加至瓶中。將瓶子置於授拌器上，以 1800 rpm條件下混合，直至墨水外觀為均質態。 實例3 :白色墨水製備 白色移印油墨的製備，係稱重49.98 g的原白 (primary white)(由30.00重量％二氧化鈦顏料 (Ti〇2，CAS # 13463-67-7)組成’溶於實例1中所述 之澄清基底）’置入一250 raL玻璃瓶。將1〇〇 〇〇 g的 澄清基底（於實例1中說明）及6重量％的i•丙醇加 入瓶中。將瓶子置，拌器上，以1__條件下混 合，直至墨水外觀為均質態。 本文所述之墨水係用以藉由本領域已知之方法及 裝置生產染色鏡片。舉例來說，其包括於美國專利公 =】__79號中所述之方法，其於本文引用作 马參考。 201243425 實例4 :較白鞏膜鏡片製造—於周圍條件下（2ι% 氧，25 C )’自聚苯乙稀射出成形—凹面模件及凸面模 件。該凹面模件置入移印機内之乾燥氮通道（約1⑽ 秒）。該凹面曲線於0.5%氧下移印，首先為一 15 深的全圓澄清基底組合物（15 μπι深的澄清層，具有 來自實例1之澄清基底組合物），並接著為一 2〇卩咖深 的黑色墨水組合物（20μιη深的緣凸印版（dich6)圖 案層，具有來自實例2之黑色墨水組合物），再接著為 一 20 μιη深的白色圓形組合物（2〇 μιη深的白色圓形 凸印版（clich0)圖案層，具有來自實例3之白色墨水 組合物）。該模具接著返至周圍條件（21%氧，25°c ) 約20秒。該凹面及凸面曲線於2.8%氧條件下重建約 70秒。該印刷之凹面模件隨後注以73 mg的伊它富康 A (etafilconA)反應單體混合物。該凸面模件置於給 定用量的反應單體混合頂部，並給予預固化重量（〜2〇〇 克）’以確保模具適當閉合。該帶有預固化重量的組件 置於預固化通道，在無光條件於25°c下共75秒，使 單體鑽入印刷層。將預固化重量移走，並將該曲面置 入具控溫（70°C)及光強度（370至440 nm)之固化 通道共約4分鐘。將該閉合之組件拆模，並將鏡片自 模具移走，且於70°C(+/- 5)浸入去離子水及土溫乳化 劑（Tween)組合液中最少60分鐘，以自鏡片溶濾任 何未固化卓體或稀釋物。該鏡片隨後於緩衝生理食鹽 水中平衡、包裝及消毒。 201243425 【圖式簡單說明】 圖1係隱形眼鏡的前視圖。 圖2係一周圍部位具有從内徑至周圍的外徑方向 為不透明、半不透明或半透明白色至半透明或透明漸 層的隱形眼鏡之前視圖。緣環亦運用至鏡片之圖案。 圖3係一周圍部位具有從内徑至周圍的外徑方向 為不透明、半不透明或半透明白色至半透明或透明漸 層的隱形眼鏡之前視圖。其顏色係施加以幾何圖案， 例如圓形透明部位由行列形成之網格或輻狀網格。 圖4顯不一具有圖3中顯示之隱形眼鏡幾何圖案之替 代隨機幾何圖案的隱形眼鏡。 【主要元件符號說明】 10.. .中心 11…中心部位 13.. .緣環或圖案 20.. .周圍部位 21.. .周圍内徑 22.. .周圍外徑201243425 t, invention description: [Technical field to which the invention pertains] Contact lenses can be colored or dyed to provide different appearance effects to the glasses. This corrects eye appearance problems or beauty. [Prior Art] U.S. Patent No. 4,652,099 proposes a contact lens having a white portion around it. However, it is often impossible to obtain a lens that can make the appearance of the eye natural or desired only by whitening the portion. The lens of the present invention solves this problem. SUMMARY OF THE INVENTION The present invention is a contact lens having a central portion and a surrounding portion disposed around the central portion. The surrounding portion is patterned in a bright color and has a gradual to transparent outer diameter of the lens. The surrounding portion of the bright color may be opaque, semi-opaque or translucent near the surrounding portion and may include a color (limus) margin or margin ring. This bright portion extends from the edge of the edge to the surrounding area, producing a brighter or whiter sclera effect. Together with the edge ring, it provides a contrasting effect and contributes to the overall effect of a brighter or whiter sclera. In another aspect of the invention, the area surrounding the contact lens is colored in a geometric pattern. The lenses of the present invention have a natural appearance. 201243425 [Embodiment] The lens of the present invention has a pattern which enhances the appearance of the sclera of the lens wearer. The lenses may also include edge ring patterns that form an iris that appears larger or deeper or more distinct. In addition, the lenses of the present invention may have additional pattern elements that completely or partially cover the wearer's iris. The 'edge ring' is an endless ribbon that partially or completely overlies the lens wearer's wheel or sclera to the cornea when the lens is on the eye and in the center. The innermost edge of the edge ring or closest to the geometric center of the lens can form a circle having a diameter of from about 8 mm to about 12 mm, preferably from about 11 mm to about 13 mm, which is aligned with the geometric center of the lens. . The ring may have any suitable width, and is preferably a width of from about 0.5 to about 2.5 mm, more preferably a width of from about 〇75 to about 2 〇〇 mm. The center portion contains the area that covers the iris when worn. The center portion can therefore also be colored and contain a ring. Preferably, both the iris and the edge ring are patterned in accordance with U.S. Patent No. 7,246,9,3, which is incorporated herein by reference. Such coloring essentially includes a triangular shaped structure, similar to spokes, extending from the innermost edge of the edge ring toward the center of the lens geometry. The one end tapered spar may, but preferably does not extend beyond the iris portion of the entire lens, i.e., the portion of the lens overlying the iris when the lens is on the eye and at the center. It should be noted that it is preferred that the spoke extends inwardly from the innermost edge of the edge ring such that the innermost edge of the spoke pattern is located at about 6 5 mm 4 201243425 = _ or more from the geometric center of the slice. The spokes can be shaped and sized and have a length of about 2 to about 2 mm. For invisible eye: it is circular 'but can be any suitable - center ln / shape' such as elliptical or truncated. The lens η extends to and from (four) minutes u. A portion around the central portion and having an inner peripheral edge - a surrounding portion 2 配置 is disposed. The Zhouyuan 1 knife has - inside # 21 and a secluded? ? , Ganzi must be with the outside of the lens. It can be, but not, must be colored, 2 〇 is bright. "Bright color" is defined as white light green $ ΗΛ white & light yellow, light blue, light pink, and sclera. The bright gamma (10) and the wearer may also have a rim ring or pattern 13 (Fig. 2). .... The file 20 is based on the color of the present invention to enhance the appearance of the sclera. The coloring of the portion around the lens can be opaque, translucent, or somewhere in between (semi-opaque). It is not necessarily a uniform color, but in accordance with embodiments of the present invention, it is preferred to provide an attractive, natural appearance by providing a sclera to enhance its appearance. "Opacity" for these purposes means a color having an average transmittance (% T) of light having a wavelength of from 380 to 780 nm ranging from 0 to about 50% T, preferably from 疋7 to about 50% T. "Translucent" for these purposes means that the average transmittance (% τ) of light having a wavelength of 380 to 780 nm ranges from about 50 to about 85% ', preferably from about 65 to about 85%. . 201243425 Figure 2 shows an embodiment of the invention in which a gradient from the surrounding inner diameter 21 to the peripheral outer diameter 22 is == transparent or transparent, and the edge ring 13. Medium + = = = two fruit on the eye effect is covered: enhanced bright and solid and dark edge ring pair =, iris pattern and painted white around = = suitable width or pattern. The edge ring can be translucent or opaque. The middle portion 11 is usually 10·13 mm in diameter, and preferably has a diameter greater than 11 mm. Figure 3 shows the lens of the present invention having a geometric pattern applied to the surrounding shell color. In this case, the pattern appears in a circular configuration that is removed from the surface of the lens (otherwise, in white), causing the circles to contact their adjacent circles in a tangential direction. It can also be regarded as a cross-shaped bright color structure of a plurality of courses formed by their circles. The pattern containing the geometric shapes can be formed from a regular shape structure or a plurality of random dots or shapes as seen in FIG. Any other suitable shape that exhibits a realistic or enhanced tone feel can be used, particularly a geometric shape that achieves the desired hue or chromaticity. The dots used in the pattern of the present invention may be of any size, and preferably have a diameter of from about 0.060 to about 0.180 mm, more preferably from about 〇·〇〇75 to about 〇·〇π5 mm. Small dots contribute to the fusion of the edges of the different components of the lens. 6 201243425 In any of the patterns of the invention, the center is preferably clarified. However, the central portion can be a translucent or opaque color or an area of any combination of opaque and translucent colors. When used in a lens to reinforce or alter the wearer's eye color, it is preferred that the edge ring member is a solid ribbon that covers the color of the lens wearer's edge region, and more preferably the cover color is an opaque color. The remaining components, ie spokes, dots and other graphic elements, may be translucent or opaque depending on the desired cosmetic results on the eye. The color selected as the edge of the ring and the iris pattern element is determined by the natural color of the lens wearer's iris and the desired enhancement or color change. Thus, the elements can be of any color, including but not limited to any of a variety of shades and shades of blue, green, gray, brown, dark yellow, red, or combinations thereof. Preferred colors of the edge ring include, but are not limited to, any of a variety of shades and shades of black, brown, gray, blue, and dark green. The bright color elements comprising the surrounding portion can be pure white, nearly white, off-white, light yellow, light blue, light pink, light green, or any combination of the above. Preferably, it is commensurate with no abrupt contrast with the visible portion of the sclera that is not covered by the lens. These colors are preferably obtained by using a higher amount of Ti02 to produce greater opacity and contrast. Pigments added include, but are not limited to, small amounts of iron oxide black, iron oxide brown, iron oxide yellow, iron oxide red, titanium dioxide, and the like, and combinations thereof to adjust the whitener colored elements. In addition to these pigments, soluble and insoluble dyes can be used, including but not limited to 201243425, which are limited to dioxetazine and vinylsulfone dyes. A preferred embodiment is a colorant having 10% to 20% TiO 2 and 80% to 90% clear binder polymer to provide a suitable translucent color. In general, the coloring elements can be made from any organic or inorganic pigment suitable for use in contact lenses or a combination of such pigments. Opacity can be controlled by varying the concentration of pigment and titanium dioxide used, with higher amounts achieving greater opacity. Exemplary organic pigments include, but are not limited to, phthalocyanine blue, phthalocyanine, carbazole violet, reduced orange ι & buckle (10) brown #丨), and combinations thereof. Examples of useful inorganic pigments include, but are not limited to, iron oxide black, iron oxide brown, iron oxide yellow, iron oxide red, titanium dioxide, and the like, and combinations thereof. In addition to these pigments, soluble and insoluble dyes may be used including, but not limited to, -milk. Qin and B fine dyes. Useful dyes are commercially available. The dye or pigment selected from the ear can be combined with one or more of the prepolymer or the viscous material to form the translucent and opaque layer colorant of the present invention. You can also use the sputum additive in contact lenses. Viscosity, mouth, solvent and other additives which can be used in the color layer of the present invention are known and are commercially available or known in the art. The piece can be applied or printed onto - or a plurality of surfaces of the lens: on a plurality of surfaces, wherein the lens forms in the mold. In forming the design x method including the present invention, an 8 201243425 ^ optical mold made of any suitable material, including but not limited to a cyclic poly such as poly(tetra) or polystyrene resin, is used. The component is placed on the desired portion of the molding surface of the mold. The so-called "molding table, I refers to the enamel used to form the mask surface half mask _ surface =, the deposition is carried out by the following pad printing. Also - the metal plate is coated to become water-insoluble when cured The light material 'the metal plate is preferably made of steel, more preferably made of steel. The element is selected or designed, and then the = (for example, photosensitive) is reduced to the desired size, Place on a gold: plate and cure the photoresist material. The plate is then washed with an aqueous solution and the resulting image is etched onto the plate to a suitable depth, for example, approximately micron. The adhesive polymer, solvent and pigment will then be applied. Or a coloring agent of the dye is deposited on the element to fill the recess with the colorant. The metal plate can also be laser etched using a suitable soft body and laser to extract the metal containing the preferred image area, thus creating a depth" ; Copy image recesses up to 30 um. In addition, the preferred pattern of laser etching can occur on other substrates, such as ceramics. A geometry suitable for printing on a surface and having a variable hardness (typically from about 1 degree to about 10 degrees) is applied to the image on the board to remove the stain and then by evaporation of the solvent. The stain was slowly dried. The mat is then pressed against the molding surface of an optical mold. Allow the mold to degas for up to 12 hours to remove excess solvent and oxygen. Then fill the mold with the lens material. A complementary mold half is then used to form the mold assembly and expose the mold assembly to conditions suitable for curing the lens 201243425 material used. These conditions; ^^^, the lens material selected. Once the lens is released from the mold, it is equilibrated in a buffered saline solution. In the preferred embodiment, a transparent prepolymer layer is used, wherein the polys layer covers at least the edge ring and the dot pattern and preferably forms the lens and the outer surface. The prepolymer may be any polymer capable of dispersing the pigment used and any opacifying agent. In an alternate embodiment, each flip or edge ring can be placed on the lens or lens mold by ink jet printing. The present invention can be used to provide colored hard or soft contact lenses made of any known lens forming material, or colored hard or soft contact lenses made of materials suitable for making such lenses. Preferably, the spectacles of the present invention are soft contact lenses, and the material selected to form the lens is any material suitable for making soft contact lenses. Preferred materials for use in forming soft contact lenses using the methods of the present invention include, but are not limited to, anthrone elastomers, anthrone-containing macromolecules (wherein non-limiting properties include those disclosed in U.S. Patent Nos. 5,371,147, 5,314,960 Nos. 5,057,578, the disclosures of each of which are incorporated herein by reference. More preferably, the lens is made of a material containing; oxime oxygen-burning functional materials, including but not limited to polydimethyl methoxy olefin macromolecules, mercapto propylene oxypropylene propylene polyalkylene A siloxane or a mixture thereof, an fluorenone hydrogel or a hydrogel made of a monomer containing a hydroxy hydrazine, a hydrazine group or both. Materials used to make soft contact lenses 10 201243425 Mirrors are well known and commercially available. Preferably, the lens material is acquafilcon, genfilcon, lenefilcon, balafilcon, lotrafilcon or gaiyfilcon. In another embodiment, the lens can be made from conventional hydrogel materials such as etafilcon. The invention is further illustrated by the following non-limiting examples. EXAMPLES Example 1: Clarification of a base ink composition Preparation using 96 g of 1-dodecanethiol ("d〇DT"), 56.54 g of lauryl methacrylate ("LMA"), 7.40 g of methacrylic acid ( "MAA"), 1367 g of mercaptoacrylic acid via thioacetate ("HEMA"), 68.5 g of glycerol, 378 g of 1-ethoxy-.2-propanol ("EP"), 1511 g of lactic acid Isopropyl vinegar ("IPL") and 8.89 g of 2,2'-azobis(2-mercaptobutyronitrile) ("AMBN") were made into a cemented polymer. In addition to IPl of about 50 to 1 cc, DODT, monomer and solvent were first added, mixed in a 5 liter blue lid bottle, and mixed for 10 minutes. This mixture was then poured into a 5 liter stainless steel reactor with agitation and nitrogen. The mixture was stirred and heated for about 25 minutes until the temperature was 68 °C. When the temperature stabilized at 68 ° C, AMBN was dissolved in the remaining IpL and added when nitrogen gas was turned on. The polymerization was allowed to proceed for 16 to 24 hours, and then the temperature was raised to 80 ° C to complete the reaction. The mixture was then equilibrated to room temperature. 201243425 By mixing 4 parts of IPL with 1 part of EP, adjust the viscosity of the mixture as needed. Example 2: Preparation of Black Ink Preparation Black Pad Printing Ink, weighing 243.47 g of 1D Black (ID Black Define) (from 11.76 wt% black iron oxide pigment (FeO.Fe2〇3, CAS # 12227-89-3) The composition, dissolved in the clear substrate described in Example 1) was placed in a 400 niL glass vial. 6 wt% 1-propanol was also added to the bottle. Place the bottle on the stirrer and mix at 1800 rpm until the ink looks homogeneous. Example 3: Preparation of a white ink for white ink preparation, weighing 49.98 g of primary white (composed of 30.00% by weight of titanium dioxide pigment (Ti〇2, CAS #13463-67-7)' dissolved in the example The clarified substrate described in 1) was placed in a 250 raL glass vial. A 1 〇〇 g clear substrate (described in Example 1) and 6% by weight of i•propanol were added to the bottle. Place the bottle on the mixer and mix at 1__ until the appearance of the ink is homogeneous. The inks described herein are used to produce dyed lenses by methods and apparatus known in the art. For example, it is included in the method described in U.S. Patent No. __79, which is incorporated herein by reference. 201243425 Example 4: Whiter scleral lens manufacturing - under ambient conditions (2% oxygen, 25 C), from polystyrene injection molding - concave and convex modules. The concave module is placed into the dry nitrogen channel in the pad printer (about 1 (10) seconds). The concave curve was pad printed at 0.5% oxygen, first a 15 round deep round clear substrate composition (15 μm deep clear layer with clear substrate composition from Example 1), followed by a 2 〇卩 coffee Deep black ink composition (20 μm deep edge embossed (dich6) pattern layer with black ink composition from Example 2) followed by a 20 μm deep white circular composition (2 〇 μιη deep A white circular relief (clich0) pattern layer having the white ink composition from Example 3. The mold was then returned to ambient conditions (21% oxygen, 25 ° C) for about 20 seconds. The concave and convex curves were reconstructed under 2.8% oxygen for about 70 seconds. The printed concave module was then filled with 73 mg of etafilcon A reactive monomer mixture. The convex module is placed on top of a given amount of reactive monomer mixture and a pre-cured weight (~2 gram) is applied to ensure proper closure of the mold. The pre-cured weight assembly was placed in a pre-cure channel for 75 seconds in the absence of light at 25 ° C to allow the monomer to penetrate the print layer. The pre-cured weight was removed and the surface was placed in a curing channel with temperature control (70 ° C) and light intensity (370 to 440 nm) for about 4 minutes. The closed component is demolded, and the lens is removed from the mold and immersed in a deionized water and soil temperature emulsifier (Tween) combination solution at 70 ° C (+/- 5) for at least 60 minutes to dissolve from the lens. Filter any uncured matrix or dilution. The lens is then equilibrated, packaged and sterilized in buffered saline. 201243425 [Simple description of the diagram] Figure 1 is a front view of the contact lens. Figure 2 is a front view of a contact lens having a peripheral portion having an outer diameter from the inner diameter to the periphery, opaque, semi-opaque or translucent white to translucent or transparent gradation. The edge ring is also applied to the pattern of the lens. Figure 3 is a front elevational view of a contact lens having a peripheral portion having an outer diameter from the inner diameter to the periphery, opaque, semi-opaque or translucent white to translucent or transparent gradation. The color is applied in a geometric pattern, such as a grid or radial grid of circularly transparent portions formed by rows and columns. Figure 4 shows a contact lens having an alternate random geometric pattern of the contact lens geometry shown in Figure 3. [Description of main component symbols] 10.. Center 11...center part 13.. .edge ring or pattern 20..around area 21...around inner diameter 22...around outer diameter