201233541 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種生產效益高，用於金屬產品包裝，更具有抗 候、抗撕裂、抗氧化、防水、防潮及防銹效能增進的高強度抗氧 防銹膜。 【先前技術】 傳統上’為了避免金屬製品產生錄蚀’會在金屬製品上所有201233541 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a high production efficiency, which is used for packaging metal products, and has higher resistance to weathering, tearing, oxidation, water, moisture and rust. Strength anti-oxidation anti-rust film. [Prior Art] Traditionally, in order to avoid the occurrence of organic corrosion in metal products, all will be on metal products.
可能與空氣接觸的地方塗上一層油脂，以阻斷氧氣與水跟金屬製 品產生接觸。另外’也有人將油脂吸附在紙張上，利用該吸滿油 脂的紙張包裝金屬製品。然，傳統的金屬製品包裝方式具有以下 缺點：1、包裝費時且成本高。2、油脂久放後會變質。3、拆封耗 a寸’人力需求高。4、大量使用油脂嚴重造成環境污染，不符合環 保。因此❹難真㈣包裝方式，其可完纽隔空氣中的氧氣 與水跟金屬製品的接觸；但其縣過高，且金屬製品經過長時間 =置放後，其包裝材料變質，空氣中的氧氣與水亦會渗透入驾 I内’使該金屬製品賴。之後，出現另—防錄技術，其係於 統包裝材料上加人氣化性細爾物C。⑽_碰· να)材料’此赌料於包裝金屬製品時，會揮發域體分子， 乳體分子會_覆該金屬製品形成—保護膜，該保護膜可阴 錢製品產生化學反應，具有防止馳的效果。如美 h:告弟4321297 f虎，該氣化性細抑制材料係附著於一紙 H氏張包裝金屬製品時，該氣化性祕抑制材料會自 201233541 揮發出氣體分子覆蓋該金屬製品形護膜，達到防錄的效果。 然，於長時職放後’空氣中的魏與柄有可能滲透過紙張包 裝材，使防錄效果降低，尤其是用於大型物品的運送過程’抗拉 強度不佳的紙張材，容“過財賴動或外力的撞及產生裂痕 或破損，使防銹效能被破壞。習用如中華民國公告號第3 8㈣ y 8「_包魏」發财’是將揮發性馳抑制劑K / 混合在PE料中押出或吹出成型—vc {防顧，再將K工防 籲錄膜藉由結合劑結合一編織膜，並由編織膜的另側還藉結合劑結. 合有其他材料，如紹落、真空電鑛特多龍、特多龍及 其雖能得到抗拉強度的提昇，唯，過於複雜的加卫程序，顯=會 對防銹膜的整體生產效率造成影響，且編_的彻，這使結合 劑所結合的三層防銹膜厚度達到約〇.32麵，造成有些金屬物的I 出現不服貼的問題’尤其是在乾雜難交麵酷冷或酷熱的 %境下，時因結合劑無法全部適應而破壞三層結合緊密度，造成. 防銹能力的降低或喪失。制如中華民國公告第〗2 8 U 〇 9 號「防銹真空袋」發明專利案，其袋體包括有—位於袋體外層的 _層及位於袋體内層的_層，該隔絕層為透氣性差的材料， 而防銹層則由塑膠聚合物與氣化性銹姓抑制（v π 並以淋膜加工方式附著於隔絕層上，其雖不需使用結合雙 層結合的手段，但仍須淋膜的二次加工，而捨棄編織膜的使用， 勢必減弱抗㈣度’且_層是㈣紐歸聚合物，如聚乙稀 P E載體容置v c !防錄劑材，採淋膜加I方式附著於隔絕層， 4 201233541 /日轉與隔絕層架橋不完善，造成附著不安定的問題出現，另外， 攸各種實施例中獲知，防賴袋所包覆的金屬物，是以對内阻水、 阻氣’對外透氣（排出殘留氣）vc !防銹劑不流失最能得到長 效防銹效果（這也是前述·防銹包裝_編_作為夾層，牛 找作為外層的相），上述習贿空袋不騎透氣收納防錄 ㈣層（防防_流失層），靠低透氣性隔絕層阻隔防_外茂， 部也影響了殘氣排出性能，只好進—步透過抽真空方式，將袋内 殘留的氧氣與錢抽出，唯不採抽真空方式包_物，是各種 防銹膜使用最主要的目的，若_抽真空才能真正發揮或得到良 好的防銹效果’這已違背防錄膜運用在金屬產品上防銹的原意。 【發明内容】 u 本發明之主要目的係在提供一種高強度抗氧防錄膜，係在各別 的配料程序中完成内層、中層及外層料的配製，再由押出機，將 内層、中層及外層料以—次多層共播方式成型_三層複合膜；該 曰料疋包3將約總比例5 %的揮發性銹姓抑制劑v c丨均勻 混合在聚乙稀p E母料中，成型構成為三層複合朗—K】防 銹内層；該中層料，是包含將約總比例3%的4,4，—二笨盼基丙院 劑⑵-、⑶醇石_均勻混合在聚乙稀PE母料中，成型構成為 "亥-層複。膜的—架橋中層；該外層料，是包含將約總比例1 3 =的聚丙稀PP及約總比例3〇%的金屬化聚丙稀心卩均勾混 -κ乙：I#P E料’成型構成為該三層複合膜的—卩竭外層；藉由 上述-次多層共擠壓成型三層複合膜，除具有高生產鱗符:低 201233541 製造成本之經濟效益外，驗金屬物產品包裝上，還能發揮更佳 的抗候、抗撕裂、抗氧化、防水、防潮及防錄的效益。 本發明之次一目的係在提供一種高強度抗氧防錄膜，其中，該 内層料，疋將約總比例5 %的揮發性銹钱仰制劑v c I和聚乙烯 P E母料均勻混合’這裡的聚乙稀p E母料，係包含約總比例6 0% 的低密度聚乙;JfLDPE ( Low-density poly ethylene)與約總 比例3 5 %的線型低密度聚乙稀L L D p E (Linear ―如咖 • polyethyiene);俾押出機將内層、中層及外層料以一次共擠方式所 成型的三層複合膜，是由低密度聚乙烯LDPE和線型低密度聚 乙烯L L D P E共同形成透氣多孔性載體來容置揮發性銹蝕制劑 VC I，並構成為一v C I防銹内層，這使三層複合膜對金屬物 的包裝，能夠透過揮發性銹蝕抑制劑VC I從載體的多孔洞中揮 發出陰離子氣體分子至被包裝金屬物上，形成防銹膜產生防銹效 果。 鲁 本發明之再一目的係在提供一種高強度抗氧防銹膜，其中，該 中層料，是將約總比例3 %的4,4’一二苯酚基丙烷劑C12-C15醇 填酸 g旨（P〇ly4,4-isopropylidenediphenol C12-C15 Alcohol Phosphite)和聚乙烯P E母料均勻混合，這裡的聚乙烯p £母料， 係包含約總比例5 0 %的線型低密度聚乙烯L L D P E (Linear low-density polyethylene)約總比例3 0 %的茂金屬線性低密度聚 乙烯ML L D P E(Metallocene LLDPE)，約總比例 1 7%的高密 度聚乙稀HDPE( High-density polyethylene );俾押出機將内層、 201233541 帽及外層料以—次共擦方式所成_三層複合膜，是由線型低 密=乙稀L L D P E、茂金屬雜低密度聚乙烯社L d p e 寺同讀*乙烯HD PE共同形成透氣多孔彈性載體來容置具广 氧化性的4,4，-二笨紛基丙烧劑α2_α5 __，並構為= 橋中層，這使三騎合騎金屬物的包裝，㈣透過架橋中層達 到VC I防錄⑽與阻隔外相穩定不裂解的架橋性連結， 乳多孔彈性載體的抗拉防撞，緩歧抗氧化性能，則外力拉扯、 •撕裂、㈣、擠壓及縣時，有效加強VC ί防_層及阻隔外 ^的防蔓月b力並且在V c J防銹内層揮發出陰離子氣體分子 時’還能長__可能外_循糖離子分子收納祕放回V . C 1防錄㈣’令使揮發性騎抑㈣VC !不流失的使循環陰 離子不斷被利用，達到長時間的金屬物防銹效果。 本么月之另-目的係在提供一種高強度抗氧防銹膜，其中，該 外層料，是將約總比例丄3%的聚丙稀”（ρ〇ι雨叩細）及約 • 2比例3 0 %的金屬化聚丙烯M p p陶础- ♦乙稀PE料均勻混合，這裡的聚乙雄，係包含約總比例 3CU的_度聚乙烯HDPE( p〇1yethy ^)與約 總比例2 7%的線型低密度聚乙稀L L D p E (Lineari〇w_den卿 polyethylene);俾押出機將⑽、中層及外層料以—次共擠方式所 f型的三層複合膜’是由高密度聚乙稀HD P E混合線型低密度 久乙稀L L D P E來合成較高熱變形溫度、低溫抗沖擊的金屬化 ♦丙稀MP P純祕點的聚丙烯？ p，共同形成減（耐高低 201233541 為阻(強初)、防水、防潮且兼具透氣的P且隔膜，並構成 ^阻^卜層’這使三層複麵對金屬物的包裝，能夠在惡劣（極 娜㈣嶋無㈣與氧氣（濕 目的係在提供—種高強度抗氧防鱗膜，其中，該 円層、中層及外層料，是由—三層共擠吹膜押出機，—次：層址 套袋形三層複合膜，並由捲收裝置以捲筒方式捲收三 利於市場流通及能直接套置金屬物㈣後進行 士、，，讀二層複合_能透職切方錢f成平膜後， 由捲收裝置以捲筒方式捲收，在、 封合包覆金屬物進行防錄。 掀用上，可配合膠帶的 —本毛明之-人再-目的係在提供一種高強度抗氧防鱗膜，其中， 層、中層及外層料，是由三層共播平膜押出機，—次三層共. 押出平_三賴合臈，動捲絲方式捲=A layer of grease may be applied to the area where it may come into contact with air to block contact between oxygen and water and metal products. In addition, some people have adsorbed grease on paper and used the grease-filled paper to wrap metal products. However, the traditional metal product packaging has the following disadvantages: 1. The packaging is time consuming and costly. 2, the oil will deteriorate after a long time. 3, unpacking consumption a inch 'manpower demand is high. 4. A large amount of oil is used to cause serious environmental pollution and does not comply with environmental protection. Therefore, it is difficult to really (4) the packaging method, which can complete the contact between oxygen and water in the air and the metal products; but the county is too high, and the metal products after a long time = placed, the packaging material deteriorates, in the air Oxygen and water will also penetrate into the car I'm making the metal products. After that, another anti-recording technology appeared, which added a gasifying fine substance C to the packaging material. (10)_碰·να) Material 'This gambling material will volatilize the domain molecules when the metal products are packaged, and the milk molecules will form a protective film covering the metal products. The protective film can produce chemical reactions in the money products, and has the prevention. Chi effect.如美h:告弟4321297f虎, the gasification fine suppression material is attached to a paper H-sheet packaging metal product, the gasification secret suppression material will volatilize gas molecules from 201233541 to cover the metal product shape protection Membrane to achieve anti-recording effect. However, after the long-term release, the Wei and the handle in the air may penetrate the paper packaging material, which reduces the anti-recording effect, especially for the transportation process of large items, the paper material with poor tensile strength. If the financial interference or external force collides and cracks or breaks, the anti-rust performance is destroyed. The use of the Republic of China Bulletin No. 3 8 (four) y 8 "_ Bao Wei" Fortune' is the volatile relaxation inhibitor K / mixed Extrusion or blowing out of the PE material - vc {anti-care, and then the K-work anti-recording film is combined with a woven film by a bonding agent, and the other side of the woven film is also bonded by a bonding agent. Shaoluo, vacuum electric mine Teduolong, Teduolong and although it can get the tensile strength improvement, only, too complicated to strengthen the program, obviously = will affect the overall production efficiency of the anti-rust film, and edit _ The thoroughness of the three-layer anti-rust film combined with the bonding agent reaches about 〇.32 surface, causing the problem of the disapproval of some metal I's, especially in the case of dry or hot. Under the time, due to the inability of the binder to fully adapt to the destruction of the three layers of tightness, resulting. Reduction or loss of ability to rust. For example, the Republic of China Announcement No. 2 8 U 〇 9 "Anti-rust Vacuum Bag" invention patent case, the bag body includes - a layer located outside the outer layer of the bag and a layer _ located inside the bag body, the insulation layer is breathable Poor material, and the anti-rust layer is inhibited by plastic polymer and vaporized rust (v π and attached to the insulation layer by lamination process, although it does not need to use the combination of two layers, but still The secondary processing of the coating, while discarding the use of the woven film, is bound to weaken the resistance (four) degree 'and _ layer is (four) New Zealand polymer, such as polyethylene, PE carrier, vc! anti-recording agent, mining film plus I The method is attached to the insulation layer, 4 201233541 / day rotation and the isolation bridge are not perfect, causing the problem of unstable attachment. In addition, it is known in various embodiments that the metal object covered by the tamper bag is internal resistance. Water, gas barrier 'external ventilation (exhaust residual gas) vc! Anti-rust agent can not get long-lasting anti-rust effect (this is also the aforementioned · anti-rust packaging _ _ as a sandwich, cattle looking for the outer phase), the above The bribery empty bag does not ride the breathable storage anti-recording (four) layer (anti-defense_loss ), relying on the low permeability barrier layer to prevent the anti-external ray, the part also affects the residual gas discharge performance, and has to step through the vacuum method to extract the residual oxygen and money in the bag, but not to take the vacuum method package _ The object is the most important purpose of using various anti-rust films. If it is vacuumed, it can really exert or get good anti-rust effect. This has violated the original intention of anti-rust film used in metal products. [Invention] u This The main object of the invention is to provide a high-strength anti-oxidation anti-recording film, which is prepared by completing the inner layer, the middle layer and the outer layer in separate batching procedures, and then the inner layer, the middle layer and the outer layer are multi-layered by an extruder. Co-broadcasting molding_three-layer composite film; the crucible bag 3 uniformly mixes about 5% of the total volatile rust surname inhibitor vc丨 in the polyethylene p-masterbatch, and is formed into a three-layer composite - K] rust-proof inner layer; the intermediate layer material comprises a mixture of 4, 4, - 2 dioxin-based propylene (2)-, (3) phenolite in a total proportion of 3%, uniformly mixed in a polyethylene-containing PE masterbatch, Forming is composed of "Hai-Layer complex. Membrane-bridged middle layer; The material comprises a polypropylene PP having a total ratio of about 13 = 3 and a metalized polypropylene crucible having a total proportion of 3 % by weight - Kappa B: I#PE material is formed into a three-layer composite film. - exhausted outer layer; by the above-mentioned multi-layer co-extrusion three-layer composite film, in addition to the high production scale: low 201233541 manufacturing cost economic benefits, the metal product packaging can also play a better resistance The utility of the present invention is to provide a high-strength anti-oxidation anti-recording film, wherein the inner layer material will have a total proportion of about 5%. Volatile rust money vc I and polyethylene PE masterbatch are uniformly mixed 'here the polyethylene ep p masterbatch, containing about 60% of the total low-density polyethylene; JfLDPE (Low-density poly ethylene) and A total of 35% of the linear low-density polyethylene LLD p E (Linear - such as coffee • polyethyiene); the three-layer composite film formed by the extrusion process of the inner, middle and outer layers in a co-extrusion manner is Low-density polyethylene LDPE and linear low-density polyethylene LLDPE together form a breathable The carrier is used to house the volatile rusting agent VC I and is formed into a v CI rust-proof inner layer, which enables the packaging of the metal layer of the three-layer composite film to be volatilized from the porous hole of the carrier through the volatile rust inhibitor VC I The anion gas molecules are discharged onto the metal to be packaged to form an anti-rust film to produce an anti-rust effect. A further object of the invention is to provide a high-strength anti-oxidation anti-rust film, wherein the middle layer material is a C4-C15 alcohol filled with about 4% of a total proportion of 4,4'-diphenol propane agent. (P〇ly4,4-isopropylidenediphenol C12-C15 Alcohol Phosphite) and polyethylene PE masterbatch are uniformly mixed. The polyethylene p £ masterbatch here contains about 50% of the total linear low density polyethylene LLDPE (Linear). Low-density polyethylene) A total of 30% metallocene linear low density polyethylene ML LDPE (Metallocene LLDPE), about 1% of total high density polyethylene HD (High-density polyethylene); The inner layer, 201233541 cap and outer layer material are formed into a three-layer composite film by the method of secondary rubbing, which is formed by linear low density = ethylene LLDPE, metallocene miscellaneous low density polyethylene, L dpe temple, and *ethylene HD PE. The ventilated porous elastic carrier accommodates the widely oxidized 4,4,-di- succinyl-based propene agent α2_α5 __, and is configured as = middle layer of the bridge, which enables the packaging of the metal riding of the three riding, (4) through the middle layer of the bridge VC I anti-recording (10) and the frame that blocks the external phase and is not cracked Sexual connection, the anti-collision and anti-oxidation performance of the milk porous elastic carrier, the external force pull, • tear, (4), extrusion and county, effectively strengthen the VC ί layer and the barrier b force and in the V c J rust inner layer volatilization of anion gas molecules 'can still be long __ may be outside _ sugar ion molecule storage secret back to V. C 1 anti-recording (four) 'make volatile riding (four) VC! The lost circulating anion is continuously utilized to achieve a long-term anti-rust effect of metal objects. Another month of this month is to provide a high-strength anti-oxidation anti-rust film, wherein the outer layer material is a polypropylene which has a total proportion of about 3% ("ρ〇ι雨叩") and a ratio of about 2 30% metallized polypropylene M pp Tao base - ♦ Ethylene PE material is evenly mixed, here the polyethylene male, containing about 3CU total PCT polyethylene HD (p〇1yethy ^) and about the total ratio of 2 7 % linear low-density polyethylene LLD p E (Lineari〇w_denqing polyethylene); 俾 extruder will (10), middle layer and outer layer material in a co-extrusion mode f-type three-layer composite film 'is made of high-density polyethylene Dilute HD PE mixed linear low-density long-thick LLDPE to synthesize high heat distortion temperature, low temperature impact resistant metallization ♦ propylene MP P pure secret point of polypropylene? p, together form a reduction (resistant high and low 201233541 for resistance (strong early ), waterproof, moisture-proof and breathable P and diaphragm, and constitute a ^ block ^ layer 'This makes the three-layer complex facing the metal packaging, can be in the harsh (polar Na (four) 嶋 no (four) and oxygen (wet destination) Providing a high-strength anti-oxidation anti-scalar film, wherein the enamel layer, the middle layer and the outer layer material are made of -3 Co-extrusion blown film extrusion machine, - times: layered bag-shaped three-layer composite film, and retracted by the retracting device in a reel manner to facilitate the market circulation and can directly place metal objects (4) after the squad, and read After the two-layer composite _ can pass through the cutting square money f into a flat film, the retracting device is wound up in a roll manner, and the metal material is sealed and sealed for prevention. 掀Used, can be matched with the tape - Ben Maoming -People--the purpose is to provide a high-strength anti-oxidation anti-scalar film, in which the layer, the middle layer and the outer layer material are made up of three layers of co-broadcasting film extrusion machine, and the third layer is common. , moving coil method volume =
層複&膜，利於市場流通及能配合膠帶_合包覆域物進行防 銹。 J 【實施方式】 一種高強度抗氧防銹膜，如圖i、2，係在各別的配料程序 中完成内層、中層及外層料的配製，再由押出機1()，將内層、 中層及料料以—次多層共播方式成型—三層複合膜2 〇 ;該内 層料’是包含將約總_5獅揮發性_抑_” 合在聚乙稀PE母料中，成型構成為三層複相2 0的-VC ^ 201233541 防銹内層2 1 ;該中層料，是包含將約總比例3 %的4,4,一二笨酚 基丙烷劑C12-C15醇磷酸酯均勻混合在聚乙烯p E母料中，成型 構成為該三層複合膜2 〇的一架橋中層22 ;該外層料，是包含 將約總比例1 3%的聚丙烯p p及約總比例3 〇%的金屬化聚丙 烯MP P均勻混合聚乙烯p E料，成型構成為該三層複合膜2 〇 的一阻隔外層2 3 ·’藉由上述一次多層共擠壓成型三層複合膜2 0，除具有高生產效率符合低製造成本之經濟效益外，如圖3， • 用於金屬物3 〇產品包裝上，還能發揮更佳的抗候、抗撕裂、抗 氧化、防水、防潮及防錢的效益。 根據上述貫施例，其中，如圖1、2，該内層料，是將約總比 例5%的揮發性銹蝕仰制劑v C I和聚乙烯P E母料均勻混合， 這裡的聚乙烯PE母料，係包含約總比例6 〇%的低密度聚乙烯 L D P E (Low-density polyethylene)與約總比例 3 5 %的線型低 岔度聚乙烯 LLDP E (Linear low-density polyethylene);俾押出機 • 1 ◦將内層、中層及外層料以一次共擠方式所成型的三層複合膜. 2 0，是由低密度聚乙烯L D P E和線型低密度聚乙烯乙l D P E共同形成透氣多孔性載體來容置揮發性銹蝕制劑vc丨，並構 成為一VC I防銹内層，如圖3 ’這使三層複合膜2 〇對金屬物 3 0的包裝，能夠透過揮發性銹蝕抑制劑v c丨從載體的多孔洞 中揮發出陰離子210氣體分子至被包裝金屬物3 〇上，形成防 銹膜產生防銹效果。 根據上述實施例’其中，如圖1、2，該中層料，是將約總比 201233541 例3 %的4,4’ 一二苯酚基丙烷劑C12-C15醇磷酸酯 (Po丨y4,4-isopropylidenediphenol C12-C15 Alcohol Phosphite )和聚 乙烯P E母料均勻混合’這裡的聚乙烯P E母料，係包含約總比 例5 0 %的線型低德、度聚乙細L L D P E ( Linear low-density polyethylene)’約總比例3 0%的茂金屬線性低密度聚乙烯ML L D P E(Metallocene LLDPE)，約總比例17%的高密度聚乙烯η D P E (High-density polyethylene);俾押出機 1 〇 將内層、中層 # 及外層料以一次共擠方式所成型的三層複合膜2 0，是由線型低 密度聚乙烯L L D P E、茂金屬線性低密度聚乙烯ml L D P E： 和高密度聚乙烯HD P E共同形成透氣多孔彈性載體來容置具抗 氧化性的4,4’一二苯酚基丙烷劑C12_c15醇磷酸酯，並構為一架 橋中層2 2，這使三層複合膜20對金屬物3〇的包裝，能夠透 過架橋中層2 2達到V C I闕内層與阻隔外層2 3間穩定不裂 解的架橋性連結’而透好孔彈性載體的抗拉防撞，緩壓及抗氧 •化性能，則外力拉扯、撕裂、穿刺、擠厪及撞擊時，有效加強v c I防銹内層及阻隔外層的防護能力，如圖3，並且在^防 錄内層21揮發出陰離子2 i Q氣體分子時，還能長期維持將可 能外_循環陰離子2 i i分子收納後釋放回vc !防鱗内層， 令使揮發性_抑侧vc丨不流失的使循猶離子2丄^斷 被利用，達到長時間的金屬物3 0防銹效果。 根據上述實施例，其中，如圖1、2，該外層料，是將約她比 例1 3%的聚丙烯p p⑽yp_ene)及約總比例3 的金屬 10 201233541 化聚丙稀Μ P P (Metailized Polypropylene)和聚乙稀p E料均勻混 合，這裡的聚乙烯P E料，係包含約總比例3 〇%的高密度聚乙 烯 H D P E ( High-density polyethylene)與約總比例 2 7 % 的線型 低岔度聚乙浠 L L D P E ( Linear low-density polyethy丨ene);俾押 出機1 0將内層、中層及外層料以一次共擠方式所成型的三層複 合膜2 0，是由高密度聚乙烯HDPE混合線型低密度聚乙烯l L D P E來合成較高熱變形溫度、低溫抗沖擊的金屬化聚丙烯M • pp與較高熔點的聚丙烯PP，共同形成抗候（耐高低溫）、耐沖 擊（強韌）、防水、防潮且兼具透氣的阻隔膜，並構成為一阻隔外 層2 3，如圖3，這使三層複合膜2 0對金屬物3〇的包裝，能 夠在惡劣（極大溫差）環境條件下仍能維持良好的強度與阻止水 液與氧氣4 0 (濕氣）滲透的能力。 根據上述實施例，其中，如圖丄、2，該内層、中層及外層料， 是由-三層共撥吹膜押出機i 〇，一次三層共播方式吹出套袋形 籲三層複合膜20，並由捲收裝置5〇以捲筒方式捲收三層複合膜 2〇為成品，利於市場流通及能直接套置金屬物密封後進行防 銹；上述套袋形三層複合膜2 〇還能透過裁切方式裁剪成平膜（圖 未示）後’由敝裝置轉筒方式捲收，在料流通制上，可 配合膠帶的封合包覆金屬物進行防銹。 根據上述實施例，其中，如圖！、2，該内層、中層及外層料， 是由三層共梅平膜押出機丄〇，一次三層共擦方式押出平膜形三 層複合膜2 0，並由捲收裝置5 〇以捲筒方式捲收三層複合膜; 201233541 〇，利於市場流通及能配合膠帶的封合包覆金屬物進行防錄。 由上述實關所成型的三層複合膜2 Q (如圖2 ),雖三層相 加^料—經由防錄試驗（如附件…二、三） 錄犯力7L全不輸給夾層為編織獏的習用—般三層式防銹紙（严户 約為0.32〜0.38mm)的防鱗效果，其中，阻隔外層2 3的* =Layered & film, which facilitates market circulation and can be combined with tape _ coated domain for rust prevention. J [Embodiment] A high-strength anti-oxidation anti-rust film, as shown in Figures i and 2, is used to complete the preparation of inner, middle and outer layers in separate batching procedures, and then by the extruder 1 (), the inner and middle layers And the material is formed by a multi-layer co-broadcasting method - a three-layer composite film 2 〇; the inner layer material is composed of a total of _5 lion volatility_ _ _" combined in the polyethylene raw material of the polyethylene, formed into Three-layer complex phase 20-VC ^ 201233541 rust-proof inner layer 2 1 ; the middle layer material comprises a mixture of 4,4,2-diphenylphenol propane agent C12-C15 alcohol phosphate ester in a total proportion of about 3% In the polyethylene p E masterbatch, a bridge intermediate layer 22 is formed into the three-layer composite film 2 ;; the outer layer material is a metal containing about 3% of the total polypropylene pp and about 3% by weight of the total proportion. The polypropylene MP P is uniformly mixed with the polyethylene p E material, and is formed into a three-layer composite film 2 〇 a barrier outer layer 2 3 ·' by the above-mentioned primary multilayer co-extrusion three-layer composite film 20, in addition to having high Production efficiency is in line with the economic benefits of low manufacturing costs, as shown in Figure 3, • For metal products, 3 〇 product packaging, can also play a better Benefits of waiting, tearing, anti-oxidation, waterproof, moisture-proof and anti-money. According to the above-mentioned embodiments, wherein, as shown in Figures 1 and 2, the inner layer material is about 5% of the total volatile rusting agent preparation v CI and polyethylene PE masterbatch are uniformly mixed. The polyethylene PE masterbatch here contains about 6% by weight of low density polyethylene LDPE (Low-density polyethylene) and about 0.35% of the total linear low temperature. Polyethylene LLDP E (Linear low-density polyethylene); 俾Extracting machine • 1 三 Three-layer composite film formed by inner co-extrusion of inner, middle and outer layers. 20 0 is made of low density polyethylene LDPE and linear type The low-density polyethylene ethylene D DPE together form a gas permeable porous carrier to accommodate the volatile rusting agent vc 丨 and constitute a VC I rustproof inner layer, as shown in FIG. 3 'This makes the three-layer composite film 2 〇 to the metal object 3 0 The package can volatilize the anion 210 gas molecules from the porous hole of the carrier through the volatile rust inhibitor vc丨 to the packaged metal object 3 to form a rust preventive film to produce a rust preventive effect. According to the above embodiment, Figure 1, 2, the middle layer , is a total of more than 201233541 3% of 4,4' bisphenol propane C12-C15 Alcohol Phosphite (Polyhy 4,4-isopropylidenediphenol C12-C15 Alcohol Phosphite) and polyethylene PE masterbatch evenly mixed ' The polyethylene PE masterbatch herein comprises a metallocene linear low density polyethylene ML LDPE having a total proportion of about 50% of a linear low-density polyethylene. (Metallocene LLDPE), about 17% of high-density polyethylene η DPE (High-density polyethylene); 俾 extruder 1 〇 The inner layer, the middle layer # and the outer layer material are formed by a co-extrusion method. 0, is a linear low-density polyethylene LLDPE, metallocene linear low-density polyethylene ml LDPE: and high-density polyethylene HD PE together form a gas permeable porous elastic carrier to accommodate the 4,4'-diphenolic group with oxidation resistance The propane agent C12_c15 alcohol phosphate is constructed as a bridge middle layer 2 2, which enables the packaging of the three-layer composite film 20 to the metal material 3〇, and can achieve stable and non-cleavage between the VCI inner layer and the barrier outer layer 23 through the middle layer 2 of the bridge. Bridging 'With the anti-collision, anti-collision, anti-oxidation and anti-oxidation properties of the porous elastic carrier, the external force pulling, tearing, puncture, squeezing and impacting can effectively strengthen the protective ability of the vc I rust inner layer and the barrier outer layer. As shown in Fig. 3, when the anion 2 i Q gas molecules are volatilized in the anti-recording inner layer 21, it is also possible to maintain the outer-cycle anion 2 ii molecules for a long time and then release them back to the vc! anti-scale inner layer, so that the volatile _ The side vc 丨 does not lose the use of the uranium ion 2 丄 ^ break is used to achieve a long-term metal object 30 rust effect. According to the above embodiment, wherein, as shown in FIGS. 1 and 2, the outer layer material is about 0.1% of the polypropylene p p(10) yp_ene) and about 3 of the total proportion 3 of the metal 10 201233541 propylene (Metailized Polypropylene) and The polyethylene PE material is uniformly mixed. The polyethylene PE material here contains about 0.3% of the total high-density polyethylene HDPE (High-density polyethylene) and about a total proportion of 27% of the linear low-degree polyethylene.浠LLDPE (Linear low-density polyethy丨ene); 俾 出 10 10 The inner layer, the middle layer and the outer layer material are formed by a co-extrusion method. The three-layer composite film 20 is made of high-density polyethylene HDPE mixed linear low density. Polyethylene l LDPE to synthesize high thermal deformation temperature, low temperature impact resistant metallized polypropylene M • pp and higher melting polypropylene PP to form weather resistance (high and low temperature resistance), impact resistance (toughness), waterproof, Moisture-proof and breathable barrier film, and formed as a barrier outer layer 23, as shown in Figure 3, which allows the three-layer composite film 20 to metal 3〇 packaging, can still be in the harsh (very large temperature difference) environment conditions Maintain good strength Preventing liquid water and oxygen capacity 4 0 (moisture) penetration. According to the above embodiment, wherein, as shown in FIG. 2, the inner layer, the middle layer and the outer layer material, the three-layer co-blowing film extrusion machine i 〇, the three-layer co-broadcasting method blows out the bag-shaped three-layer composite film. 20, and the three-layer composite film 2 is wound up by the retracting device 5 卷 as a finished product, which is favorable for market circulation and can be directly sealed with metal materials for rust prevention; the above-mentioned bag-shaped three-layer composite film 2 〇 It can also be cut into a flat film (not shown) by cutting. 'It is retracted by the twisting device. In the material circulation system, the metal can be sealed with the tape to prevent rust. According to the above embodiment, wherein, as shown in the figure! 2, the inner layer, the middle layer and the outer layer material are extruded by a three-layered common flat film, and a three-layer three-layer composite film is extruded by a three-layer rubbing method, and the reeling device 5 is used for reeling. The method is to take up three layers of composite film; 201233541 〇, which is beneficial to the market circulation and can be combined with the sealing material of the tape to prevent the recording. The three-layer composite film 2 Q (as shown in Figure 2) formed by the above-mentioned actual customs, although the three layers are added together - through the anti-recording test (such as accessories... 2, 3), the recording force is 7L, and the interlayer is not woven. The anti-scaling effect of the three-layer anti-rust paper (the strict household is about 0.32~0.38mm), in which the outer layer 2 3 is blocked*
率是一般制（單層或雙層）以防顧的八倍以上（轉= 超過1 2 0個小時），耐高溫（液態溫度）達2 5代不變形 低溫可達零下3 (TC不破裂；且整體三層複合膜所擁有的超強章 性’通過縱向拉力試驗（如附件四），橫向拉力試驗（如附件五)初 内外牙刺趣（如附件六）及靜動態磨擦係數試驗（如附件七） 證實具有良好的抗拉強度，抗穿觀力及抗磨紐能；· 物的包裝防錄使用上，確具有抗候、抗撕裂、抗氧化、防水、 潮及防銹效果的提昇及能使防銹時效延長。 方 以上說明’謹屬本發明較佳具體實施例，舉凡就上述實 作之簡易等效改變，仍應屬本發明技術範_。 所 【圖式簡單說明】 圖1係本發明製程示意圖 圖2係本發明構造示意圖 圖3係本發明驗金屬物包裝所產生的效果示意 【主要元件符號說明】 三層複合膜2 0 陰離子210 押出機1 〇 VC I防鱗内層2 1 201233541 循環陰離子21 阻隔.外層2 3 水液與氧氣4〇 【附件說明】 架橋中層2 2 金屬物3 0 捲收裝置5 0 附件-為本伽三層複合膜「 報告 中國鋼鐵股份有限公 」的試驗·The rate is more than eight times that of the general system (single or double layer) (rotation = more than 120 hours), high temperature (liquid temperature) up to 25 generations, no deformation, low temperature up to minus 3 (TC does not break And the overall three-layer composite film possesses the super-strength 'through the longitudinal tensile test (such as Annex IV), the transverse tensile test (such as Annex V), the initial and external teeth (such as Annex VI) and the static and dynamic friction coefficient test ( As shown in Annex VII) It has been proved to have good tensile strength, anti-wearing power and anti-wearing energy; · The packaging of the object has anti-weathering, tear resistance, anti-oxidation, waterproof, moisture and anti-rust effects. The improvement and the rust-proof aging can be extended. The above description is intended to be a preferred embodiment of the present invention, and the simple equivalent change of the above-mentioned implementation should still belong to the technical scope of the present invention. 1 is a schematic view of the process of the present invention. FIG. 2 is a schematic view showing the structure of the present invention. FIG. 3 is a schematic diagram showing the effect of the metal object packaging of the present invention. [Main component symbol description] Three-layer composite film 2 0 anion 210 extruder 1 〇 VC I Scale inner layer 2 1 201233541 Ring anion 21 barrier. Outer layer 2 3 water and oxygen 4〇 [Attachment description] Bridge middle layer 2 2 Metal object 3 0 Retracting device 5 0 Annex - This gamma three-layer composite film "Report China Iron and Steel Co., Ltd." test ·
寸件-為附件-武驗報告的試驗方法 附件三為附件—試驗樣品的來源證明書 附件四為本發明三層複麵的縱向拉力試驗報生 附件五為本發明三層複麵的橫向拉力試驗報二 附件六為本發明三層複合膜的穿刺試驗報告° 附件七為本發明三層複麵的雜倾咏報生The dimensions of the test method are attached. Annex III - Annex 4 of the source certificate of the test sample is the longitudinal tensile test of the three-layer complex of the invention. Annex 5 is the transverse tension of the three-layer complex of the invention. Test Report 2, Annex 6 is the puncture test report of the three-layer composite film of the present invention. Annex VII is the three-layer complex surface of the invention.