201231969 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種水垢酸洗判斷劑，尤指一種用以檢測熱導管、 熱交換器、熱交換裝置及空壓機、空調、冷凍機、塑膠射出機、 油冷卻器、模溫機、高周波、雷射切割、熱處理、怪溫值濕機、 化工製程、鍋爐、加熱器、冷卻水塔、冷凝器、蒸發器、蒸發 式冷凝器、密閉式冷卻水塔、密閉型冷卻水塔…等設備之除垢劑 的酸洗液濃度，進而判斷水垢清除程度階段，以避免管件因侵蝕過度 而受損之酸洗判斷劑。 【先前技術】 按；一般之熱導管、熱交換器、熱交換裝置等設備，於使用酸洗 液清除水垢時，通常係以傳統PH試紙測試酸液之濃度，惟由於傳統 PH試紙於測試酸液時所產生的顏色色澤太過接近，因此，使用者往往 難以判定，難易判斷PH精準度範圍及酸液濃度，故而常造成清除水 垢之化學藥劑的浪費’且難以精準的清除水垢，更可能使設備之管路 造成金屬不必要之侵蝕，增加設備之維修成本及降低機台之使用年 限。申請人有鑑於此，乃秉持從事該項業務多年之經驗，經不斷研究、 實驗’遂萌生發明，祈使清除水垢之化學藥劑的使用得以更精準。 【發明内容】 本發明之主要目的，即在提供一種水垢酸洗判斷劑，藉由液體變 201231969 化指示劑色澤，使精準度範圍遠高於PH試紙，從而減少清除水垢之 化學藥劑驗費’且可更鮮的清除水垢，以及可避免管路造成金屬 不必要之知钱，減少设備的維修及確保機台使用之年限。 别述之水垢酸洗判斷劑，係包含96%之去離子水、1·2%之月桂 醇聚氧化乙稀醚硫酸鈉、1-2%之十二烷基二甲基苄基氣化銨以及〇 5 -1%之孔雀石綠等成份。 前述之水垢酸洗判斷劑，其製程係先將去離子水倒入容器中，加 入月桂醇聚氧化乙稀醚硫酸鈉攪拌後，再加入十二烧基二甲基节基氣 化敍繼續攪拌，最後再加入孔雀石綠攪拌溶解後即可完成。 【實施方式】 請參閱第一圖，係為本發明之製造流程圖。如圖所示，本發明之 製程，主要係包含以下之步驟： 1 ·將96%比例之去離子水倒入容器中。 2 ·加入.1-2%比例之月桂醇聚氧化乙稀醚硫酸鈉 3 ·將前述之去離子水及月桂醇聚氧化乙稀醚硫酸鈉適當攪拌。 4 ·加入1-2%比例之十二烷基二甲基苄基氣化銨，並繼續攪拌。 5 ·加入0.5-1%比例之孔雀石綠攪拌溶解，構成水垢酸洗判斷劑。 所製成之水垢酸洗判斷劑，係供用以檢測熱導管、熱交換器、熱 交換裝置及空壓機、空調、冷凍機、塑膠射出機、油冷卻器、 模溫機、高周波、雷射切割、熱處理、恆溫恆濕機、化工製程、 鍋爐、加熱器、冷卻水塔、冷凝器、蒸發器、蒸發式冷凝器、 201231969 密閉式冷卻水塔、㈣型冷卻水塔...等設備之除垢_酸洗液濃 度’其判別之標準係叫同之顏色顯示（本實施例係為三種顏色）酸 液之濃度，判斷水垢清除程度階段，以避免管件因侵蝕過度而受損。 本發明之檢測方式’係與水垢量厚薄程度與酸洗液濃度有關應 每30分鐘或（一段時間）檢測酸洗液濃度即可判斷水垢清除程度階 段，為避免管件觉知敍過度，其依據水垢量可區分為： a·正常保養少量水垢：（請參附件一） 1 ·酸劑投入水中後取透明塑膠容器採取以混和酸液再用吸液 管吸取0.5-lcc水垢酸洗判斷劑（指示劑)檢測濃度，此時 若呈金黃色’表示酸洗液濃度足夠。 2 ·清洗過程中應每隔3〇分鐘後取透明塑膠容器採取以混和酸 液再用吸液管吸取〇.5-lcc水垢酸洗判斷劑（指示劑）檢測 濃度，此時若呈黃綠色代表水垢已有溶解中，但酸液濃度 減弱。 3·若再經30分鐘後取透明塑膠容器採取以混和酸液再檢測 同樣呈現黃綠色不變時，代表管路清水垢洗已完全溶解去 除。表示酸洗工作已完成。 b·非正常保養中量水垢：（請參附件二） 1 ·酸劑投入水中後取透明塑膠容器採取以混和酸液再用吸液 管吸0. 5-lcc水垢酸洗判斷劑(指示劑)檢測濃度，此時若 呈金黃色，表示酸洗液濃度足夠量。 201231969 2·清洗過程中應每隔30分鐘後取透明塑膠容器採取以混和酸 液再用吸液管吸取0.5-lcc水垢酸洗判斷劑（指示劑）檢測 濃度’此時若呈黃綠色代表水垢已有溶解中，但酸液濃度 減弱。 3·若再經30分鐘後取透明塑膠容器採取以混和酸液再檢測， 此時呈現草綠色代表酸液薄弱表示藥液濃度不足，需再補 充酸劑至呈回黃綠色。 4·若再經30分鐘後取透明塑膠容器採取以混和酸液再檢測 同樣呈現黃綠色不變時’代表管路清水垢洗已完全溶解去 除。表示酸洗工作已完成。 c·長期保養高量妈垢：（請參附件三） 1 ·酸劑投入水中後取透明塑膠容器採取以混和酸液再用吸液 管吸0.5-lcc水垢酸洗判斷劑（指示劑）檢測濃度，此時若 呈金黃色，表示酸洗液濃度足夠量。 2·清洗過程中應每隔30分鐘後取透明塑膠容器採取以混和 酸液再用吸液管吸取〇. 5-lcc水垢酸洗判斷劑（指示劑）檢 測濃度，此時若呈草綠色代表水垢已有溶解中，但酸液濃 度呈現薄弱表示藥液濃度不足’需再補充酸劑至成金黃色。 6 201231969 3 ·再經30分鐘後取透明塑膠容器採取以混和酸液再用吸液管 吸取0.5-lcc水垢酸洗判斷劑（指示劑)檢測濃度，此時若 呈黃綠色代表水垢已有溶解中，但酸液濃度減弱。 4·若再經30分鐘後取透明塑膠容器採取以混和酸液再檢測 同樣呈現黃綠色不變時，代表管路清水垢洗已完全溶解去 除。表示酸洗工作已完成。 按，一般鹽酸型濃度32%作酸度值判斷劑色澤區分標準為： 以5%溶液濃度所測試PH值範圍刻度PH0.3>判斷劑呈現金黃色。 以3.5%溶液濃度所測試PH值範圍刻度PH0.6>判斷劑呈現黃綠色。 以1.5%溶液濃度所測試PH值範圍刻度ΡΗ1·〇>判斷劑呈現草綠色。 另，使用本發明水垢酸洗判斷劑有下列優點： 1. 降低藥量，減少污染，完全符合以最少量的藥劑，達到最大的效果，經濟 又省時。 2. 依顏色判斷加藥時間點。 3. 冷卻水塔以及閉迴路冷卻設備，經過一段長時間使用後有時彳艮難去 估算水垢及污泥的堆積層厚度.所以指示劑可代替管路長短之水量換 算藥劑。 4. 清洗中很容易判別藥劑量是否與足夠。 5. 清洗完畢可降低使用中和劑之劑量以利快速使水質呈中性減少廢水排 201231969 6. 降低熱交換器因清洗過程中造成腐蝕而破管。 7. 操作簡單容易辨識。 8. 顏色變化判定水垢之性質避免用錯藥而不經中和隨液排放造成環境之 汙染。 9. 減輕人力負擔。 !〇·作業循環清洗水垢過程詳知酸液濃度水垢s洗情形，以便正確觸是否 洗淨。 11·新進人員或-般人員操作上手容㈣可降低清洗技術門檻，不需很專業 就能操作此產品。 則述實施例，僅為綱本㈣之較佳實财式，畴關本發明 之範圍，凡經由些微修飾、變更，仍生 叉尺1乃不失本發明之要義所在，亦不脫 本發明之精神範疇。 細上所述，本發明以包含去雜 *科水、賴醇聚氧化6稀醚硫酸201231969 VI. Description of the Invention: [Technical Field] The present invention relates to a scale pickling judging agent, and more particularly to a heat pipe, a heat exchanger, a heat exchange device, an air compressor, an air conditioner, a refrigerator, Plastic injection machine, oil cooler, mold temperature machine, high frequency, laser cutting, heat treatment, strange temperature value wet machine, chemical process, boiler, heater, cooling tower, condenser, evaporator, evaporative condenser, closed type The concentration of the pickling solution of the descaling agent of the cooling tower, the sealed cooling tower, etc., and then the level of scale removal is judged to avoid the pickling agent which is damaged by excessive corrosion of the pipe. [Prior Art] According to the general heat pipe, heat exchanger, heat exchange device, etc., when using acid washing liquid to remove scale, the concentration of acid solution is usually tested by traditional PH test paper, but the acid is tested by traditional pH test paper. The color of the color produced by the liquid is too close. Therefore, it is often difficult for the user to judge, and it is difficult to judge the pH accuracy range and the acid concentration, so the waste of the chemical agent for removing scale is often caused and it is difficult to accurately remove the scale, more likely Make the pipeline of the equipment cause unnecessary erosion of the metal, increase the maintenance cost of the equipment and reduce the service life of the machine. In view of this, the applicant has been practicing the business for many years and has been researching and experimenting with the invention, so that the use of chemical agents for removing scale can be more precise. SUMMARY OF THE INVENTION The main object of the present invention is to provide a scale pickling judging agent, which can change the color of the indicator by the liquid change 201231969, so that the precision range is much higher than the pH test paper, thereby reducing the chemical fee for removing scale. It can also remove scale more freshly, and can avoid unnecessary metal knowledge of the pipeline, reduce the maintenance of the equipment and ensure the age of the machine. The scale pickling judging agent includes 96% deionized water, 1.2% lauryl sulfate polyoxyethylene ether sulfate, and 1-2% dodecyldimethylbenzyl ammonium sulfate. And 〇5 -1% of malachite green and other ingredients. The above-mentioned scale pickling judging agent is prepared by pouring deionized water into a container, adding lauryl alcohol polyoxyethylene ether sulfate, stirring, and then adding a 12-alkyl dimethyl sulfhydryl group to continue stirring. Finally, add malachite green and stir to dissolve. [Embodiment] Please refer to the first drawing, which is a manufacturing flow chart of the present invention. As shown, the process of the present invention mainly comprises the following steps: 1 - Pour 96% of deionized water into a container. 2 · Add a 1-2% ratio of lauryl alcohol polyoxyethylene ether sulfate 3 · Stir the above deionized water and sodium lauryl polyoxyethylene ether sulfate. 4 - Add 1-2% proportion of dodecyldimethylbenzylammonium hydride and continue to stir. 5 · Add 0.5-1% of malachite green to stir and dissolve to form a scale pickling agent. The scale pickling judging agent is used for detecting heat pipes, heat exchangers, heat exchange devices and air compressors, air conditioners, refrigerators, plastic injection machines, oil coolers, mold temperature machines, high frequency waves, and lasers. Descaling of equipment such as cutting, heat treatment, constant temperature and humidity machine, chemical process, boiler, heater, cooling tower, condenser, evaporator, evaporative condenser, 201231969 closed cooling tower, (four) cooling tower... The standard of the acid pickling concentration is called the same color display (in this embodiment, three colors), and the concentration of the acid solution is judged to prevent the pipe from being damaged due to excessive erosion. The detection method of the present invention is related to the degree of the thickness of the scale and the concentration of the pickling solution. The concentration of the pickling solution should be detected every 30 minutes or (for a period of time) to determine the degree of scale removal, in order to avoid excessive awareness of the tube, the basis thereof The amount of scale can be divided into: a. Normal maintenance of a small amount of scale: (Please refer to Appendix 1) 1 · After the acid is put into the water, take a transparent plastic container and take the acid solution and then pipette 0.5-lcc scale pickling agent ( The indicator is used to detect the concentration, and if it is golden yellow, it means that the concentration of the pickling liquid is sufficient. 2 · During the cleaning process, take a transparent plastic container every 3 minutes, take the acid solution and then pipette the 〇.5-lcc scale pickling agent (indicator) to detect the concentration. It means that the scale has dissolved, but the acid concentration is weak. 3. If the transparent plastic container is taken after 30 minutes, and the mixed acid is used for re-testing, the yellow-green color is also unchanged, and the water-cleaning washing of the pipeline is completely dissolved. Indicates that the pickling work has been completed. b. Abnormal maintenance of medium scale: (Please refer to Annex II) 1 · After the acid is put into the water, take a transparent plastic container to take the acid and then use the pipette to absorb 0. 5-lcc scale pickling agent (indicator) The concentration is detected, and if it is golden yellow, it means that the concentration of the pickling liquid is sufficient. 201231969 2·In the cleaning process, take a transparent plastic container every 30 minutes to take the acid solution and then use a pipette to absorb 0.5-lcc scale pickling agent (indicator) to detect the concentration. Already dissolved, but the acid concentration is weakened. 3. If the transparent plastic container is taken after 30 minutes, the mixed acid is used for re-detection. At this time, the green color indicates that the acid is weak, indicating that the concentration of the liquid is insufficient, and the acid is required to be replenished to a yellow-green color. 4. If after 30 minutes, take a transparent plastic container and take it with mixed acid solution and test again. When the yellow-green color is unchanged, the representative pipeline cleansing water is completely dissolved and removed. Indicates that the pickling work has been completed. c·Long-term maintenance of high-volume mother scale: (please refer to Annex III) 1 · After the acid agent is put into the water, take the transparent plastic container and take the acid solution and then use the pipette to absorb 0.5-lcc scale pickling agent (indicator). The concentration, if golden yellow at this time, indicates that the acid wash concentration is sufficient. 2. During the cleaning process, the transparent plastic container should be taken every 30 minutes to mix the acid solution and then suck the sputum with a pipette. The concentration of 5-lcc scale pickling agent (indicator) is detected at the time. The scale has been dissolved, but the acid concentration is weak, indicating that the concentration of the liquid is insufficient. 'The acid needs to be replenished until golden brown. 6 201231969 3 · After 30 minutes, take the transparent plastic container and take the acid solution and then use the pipette to absorb the concentration of 0.5-lcc scale pickling agent (indicator). If it is yellowish green, the scale has dissolved. Medium, but the acid concentration is weakened. 4. If the transparent plastic container is taken after 30 minutes, and the mixed acid is used for re-testing, the yellow-green color is also unchanged, and the cleansing of the pipeline is completely dissolved. Indicates that the pickling work has been completed. According to the general hydrochloric acid type concentration of 32% as the acidity value judgment agent, the color discrimination standard is: The pH value range of the test is 5% solution concentration PH0.3> The judgment agent is golden yellow. The pH range of the test was measured at a concentration of 3.5% solution, pH 0.6 > the judger appeared yellow-green. The pH range of the test was measured at a concentration of 1.5% solution ΡΗ1·〇> The judgment agent exhibited grass green. In addition, the use of the scale pickling judging agent of the present invention has the following advantages: 1. Lowering the dose, reducing the pollution, fully complying with the minimum amount of the medicament, achieving the maximum effect, economical and time-saving. 2. Determine the dosing time by color. 3. The cooling tower and closed-circuit cooling equipment may be difficult to estimate the thickness of the scale and sludge after a long period of use. Therefore, the indicator can replace the amount of water in the pipeline. 4. It is easy to determine whether the dose is sufficient during cleaning. 5. Cleaning can reduce the dosage of neutralizer to quickly reduce the water discharge in a neutral manner. 201231969 6. Reduce the heat exchanger to break the tube due to corrosion during the cleaning process. 7. Easy to operate and easy to identify. 8. Color change determines the nature of the scale to avoid environmental pollution caused by the use of the wrong medicine without neutralizing the liquid discharge. 9. Reduce the burden of manpower. !〇·Working cycle cleaning scale process knows the acid concentration scale s wash situation, so that it can be cleaned properly. 11. New recruits or general personnel (4) can lower the threshold of cleaning technology and can operate this product without any professionalism. The embodiments described herein are only the preferred embodiments of the present invention. The scope of the present invention is not limited to the scope of the present invention, and the present invention is not deviated from the present invention. The spiritual category. As described above, the present invention contains dehydrogenated ketone, lysine polyoxygenated 6-dish ether sulfuric acid
鈉、十二絲二樹基氯倾、孔雀石綠等成份，構成水垢酸洗判 斷劑，藉罐⑽概澤，使精準度細遠高於PH試紙，從 而減少清除搞德賴劑驗費，且可更精準的清除水垢’以及可 避免管路造齡财必要之伽，·設__麟賴台使用之 年限。為一實用之設計，誠屬—相 、新穎性之發明，爰依法提出發明專 利之申請’祈躺予以審查，早日賜准專利，至感德便。 201231969 【圖式簡單說明】 第一圖係本發明之製造流程圖。 【主要元件符號說明】Sodium, 12-leaf dibasic chloride, malachite green and other ingredients constitute a scale pickling agent. The tank (10) is used to make the precision much higher than the pH test paper, thus reducing the cost of cleaning the German drug. And it can remove the scale more accurately', and can avoid the necessary gems of pipeline ageing, and set the age of __麟赖台. For a practical design, it is an invention of the same-phase, novelty, and the application for patents for inventions is legally prayed for review, and patents are granted as soon as possible. 201231969 [Simplified description of the drawings] The first figure is a manufacturing flow chart of the present invention. [Main component symbol description]