TW201231529A - An ionic gelator, a gel, a process for preparation of the gel and a cross-linker - Google Patents

Abstract

The present invention is to provide a gel for resolving a point at issue of traditional technique, which has high electro-conductibility and is able to inhibit corrosion of metal contacted with the gel in an electro-chemistry device. Further, provided is a gelator used in the formation of said gel, a process for preparation of the gel for easily preparing the said gel and a cross-linker for formation of said gel. The aforesaid object of the present invention is resolved by discovering a gel formed by means of a gelator containing a specific cross-linker, and a high molecular compound having an atom capable of forming an onium salt.

Description

201231529 VI. Description of the Invention: [Technical Field] The present invention relates to an ionic gelling agent, a gel, a method for producing a gel, and a crosslinking agent. [Prior Art] In recent years, gels have attracted attention from a wide range of fields such as basic research on structure and physical properties, and applications such as foods, pharmaceuticals, cosmetics, and batteries. In addition, the electrolyte enrichment technique has attracted attention in the field of various electrochemical discharges as a technique for preventing harmful electrolyte vapor leakage which may cause drug damage or explosion. However, when the electrolyte is gelled, there is a problem that the conductivity of the electrolyte is lowered. The countermeasures are to improve the conductivity of the gelation by ionicity of the gelling agent. The gelation of ionic cations has been developed in the use of a gelatin-based polymer battery (Patent Documents 1 to 3, Non-Patent Document 1). = In the case of the readings described herein, there is a problem that the metal portion in contact with the gel in the electrochemical device is rotted due to the high concentration of the organic compound ions. According to this problem, the lifetime of the electrochemical I is shortened, and since the material can be limited, it can be applied only to a specific jaw region, and is not sufficient for use in various fields of electrochemical materials. [Prior Art Document] [Patent Document] Patent Document 1: JP-A-2003-203520, JP-A-2003-203520, JP-A-2003-203520, JP-A-2003-203520, JP-A-2003-203520 [Non-Patent Document i] T. Kato, A. 0kazaki - s Hayase, chem

Commun·, 2005, 363-365. SUMMARY OF THE INVENTION [Problems to be Solved by the Invention] In order to solve the above problems, the inventors of the present invention have studied in the above-mentioned special documents 1 to 3, and the clogging by containing a high concentration of an organic acid or a toothed product. Ions, and the gold chemical that is in contact with the gel in the electrochemical element is less prolonged, and the focus is on the ability to solve the problems by solving the problems. Create insights into durable and more versatile gels. In other words, the object of the present invention is to solve the problems of the prior art and to provide a kind of 'conserving conductivity' in an electrochemical device or the like without interfering with the gel. iMi. Further, a method for producing a gel for forming the above gel, a method for producing a gel of the above gel, and a method for forming the above-mentioned gel are also provided. [Means for Solving the Problem] # According to the above-mentioned work, the inventors have continuously explored and found that the straw is composed of a specific cross-linking agent and a polymerized substance having a nitrogen, sulfur-like or sulfur atom. The gel breaker can form a gel which can solve the above problems, and the present invention has been completed as a result of further research. That is, the present invention relates to the following: (a) a type of agent-containing a cross-linked polymer compound, and as a result, a gelling agent which forms a mesh structure by forming a phosphonium salt, and the crosslinking agent comprises: Ke _ _ _ containing a plurality of substituents which may be the same or different, containing a saturated hydrocarbon, an unsaturated fe or an aromatic saturated 5/4! 201231529 Hydrocarbon A: •N (S〇2Ri) (A ώ v/\; where R is an independent group of fluorine-based and trifluoromethylfluoropropyl groups, and the gas ethyl and seven polymer compounds contain one or two. The ethnic group selected by the N, P and s A alone 7 ° prime monomer unit. In the case of the above-mentioned formula, the (4) agent is one or two selected from the group consisting of the following ten compounds, and is represented by the following formula: AT^i^CH2^A H3 .x^CH2t and (7) . (3)

Rc

〇-(cH2)y A

In the formula Z (4), the ruler 3 and the lanthanide are independent of each other, H or % is an integer of 1 to 3G, ', ', and the substituent base, = are independent of each other. The integer to Μ is an integer from 15 to RC, and the RC system may have an integer of 1 to 15 for the carbon number of the substituent, and an integer of 2 to "0" of μ. (C) In (a) or (b), it is composed of a compound of the following formula: the co-polymerization cross-linking agent is contained. One or two selected from the six groups are 6/41

201231529

It is an integer with a ms system of 1 to 3 。. ί== </ RTI> </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Kind or more than two kinds of monomer two intermediate knife CH-

D (10) in the form of two == r broadly shown in the formula E, in the species or more than two kinds of early elements (11) R and R3 are independent of hydrogen or methyl, D is composed of N, P One or two types of 7/41 201231529 or more elements selected from the group t composed of S, an E-based organic group, a main chain to which the carbon atom of the main chain bonded to the group D is bonded to the base E In the case where the carbon atoms are adjacent to each other, D and E may be bonded to each other with the carbon atoms of the main chain to form a ring, and in the case where the monomer unit represented by the formula (H) is contained, The equivalent ratio of the monomer unit represented by the formula (n) is from 1:9 to 9:1 with respect to the equivalent ratio of the monomer unit represented by the formula (?). (a) The gelling agent according to any one of (a) to (e), wherein the polymer compound is one or more selected from the group consisting of monomer units represented by the following formula: :

And (2〇) where η丨, 叱, ru, and ns are independent integers of 1 to 1〇, n3 is an integer of 0 to 10, A is N (S02CF3) 2, and R4 is from carbon number 1 to 20 linear or branched alkyl, allyl, B 8/4!

S 201231529 an alkenyl group, a benzyl group which may have a substituent, a phenyl group which may also have a substituent, and a group consisting of a linear or branched fluoroalkyl group having 1 to 20 carbon atoms; The case where any one of the formulae (18) to (20) is selected as the monomer unit contains at least one monomer of the formulae (12) to (?7). (g) The gelling agent according to any one of (a) to (f), wherein the polymer compound has a number average molecular weight of 1, 〇〇〇 to 1,00 〇, 〇〇〇. (h) The gelling agent according to any one of (a) to (g) which gels a liquid medium containing an organic solvent, an ionic liquid and/or an electrolyte solution. (1) The gelling agent described in (h), wherein the organic solvent is dimercaptopurine, amine (DMF), dimethylacetamide (DMA), diterpene sapphire (DMS®), Propylene carbonate (PC), ethylene carbonate (EC), dinonyl carbonate (DMC), γ-butane (GBL), acetonitrile (AN), methoxypropionitrile (mpn), tetrahydroanthracene ( THF), toluene, dioxane, decyloxyacetonitrile (^n), and team methyl group 0 to 17. Ketone (NMP), 2-mercaptotetrahydrofuran, l,3-dioxane, iota, dioxan, methyl ether, dimethyl ether glycol (m〇n〇g丨yme), propionitrile , 4_decyl·2_pentanone, butyronitrile, valeronitrile, benzonitrile, 1,2-dioxaethane, dimethoxyethane, methyl decanoate, ethyl acetate, methyl propionate , ethyl propionate, ethylene carbonate, acid-blocking-1,2-butenyl ester, ethyl hydrazine carbonate, dimethylthiocarbamamine sulfolane, 3, mercapto sulfolane, trimethyl citrate, triethyl carbonate, One or two or more selected from the group consisting of nitrodecane, acetone, gas, and dioxane and carbon tetrachloride. (j) The gelling agent described in (h) or (i), wherein the organic solvent is diamyl acetamide (DMA), dimethyl decyl amide (DMF), dimercapto sulfoxide (DMSO) ), propylene carbonate (pc), ethylene carbonate (EC), γ-butyrolactone (GBL), acetonitrile (ΑΝ), methoxypropionitrile (ΜρΝ), methoxy acetonitrile (MAN), Ν-甲One or two or more selected from the group consisting of pyrrolidone (anthracene), acetone, chloroform, di-methane, and tetra-carbonized carbon. 9/41 201231529 00 The gelling agent described in (8), wherein the ionic liquid contains a cationic species and an anionic species, the scale ions may also have a substituent and the (4) pin ion 'bite 镔 ion, tetragreen, touch I or two or more selected from the group consisting of ionic, lindane, sulphur-based squamous ions, ♦ spicy sputum ions, tri-silk yttrium, yoghurt ions, and gypta ions (g_idinium ion); It is composed of a sulphate ion (fluorine, gas, desert), a tetra-acid ion (BFr), a hexafluorophosphate ion (PK-), a bis (three-form methanesulfonyl) quinone imine ion (TFSA-), Thiocyanate ion (SCN-), nitrate ion (n〇3), sulfate ion (SO/), thiosulfate ion (S2〇32-), carbonate ion (co32-), bicarbonate ? (Ηαν), dish acid ion, arsenate, sub-disk acid ion, ugly acid ion (war, X〇2 and X0 'in this 'X-ray fluorine, gas, desert or sputum), toothed acetate Ions ((CXnI-I3—n) C00, here, X is fluorine, gas, desert or hydrazine, n is 1 to 3), tetraphenylborate ion (ΒΡιν) and its derivative (B (Ary丨) The plant, or two or more species selected from the group consisting of 'phenyl having Ary 1 = substituents'. (丨) The gelling agent described in (h), wherein the electrolyte solution is selected from the group t consisting of a solution containing a stone and a telluride, a mixture containing a whisker and a wire. Kind or more than two. (a) The gelling agent according to any one of (a) to (1) wherein the content of the polymer compound is from 15 to 9% by weight based on the gelling agent. The gel agent according to any one of (a) to (m), wherein the content of the crosslinking agent is from 25 to 85% by weight based on the gelling agent. (a) The gelling agent according to any one of (h) to (n), wherein, when the gel is formed, the total content of the liquid medium is from α1 to 5〇% by weight. (P) The gelling agent according to any one of (a) to (〇), which is used in a gel used for a portion connected to an electrode at 10/41 or more 201231529 liters. (q) A gel described in any one of (a) to a gelling agent. Any one of (0) a crosslinking agent used in (a) to a gelling agent, and a method of producing a gel by (4)-type, which is used in (1) to 壬, a gelling agent And including a mixed gel and liquid [effect of the invention] 7 is the author of the invention, to solve the problem of the technology, can provide a kind of condensation, which does not greatly reduce the conduction of electricity The shirt will be glued to the metal. It is also possible to provide a cross-linking agent for the gel of the gel which is easy to manufacture the gel. In the following, the ionic gelling agent, the gel, the method for producing the gel, and the crosslinking agent of the present invention will be described. <Gelting Agent> ~ The present invention contains __ Molecular compound. Moreover, this specializes in forming a gel by forming a cerium salt. Here, the term "sodium salt" refers to a compound having an electron pair unrelated to chemical bonding', and other cationic red compounds by the electron pair The compound formed by the coordination bond is b. For example, 'by acridine and alkylation T The FSA is reacted, and the cation of the alkylpyridinium is bonded to the anion of the TFSA to form a gel. 11/41 201231529 (crosslinking agent) First, the description will be directed to the crosslinking agent. The joint ship contains: a type A with a τ extract, which can also contain a _ sub-containing hydrocarbon, a hepta and a hydrocarbon or an aromatic saturated N (S02Rl) 2 ΚΛ) where R1 is independent of fluorine The base, or the succinyl group or the aryl group, or the aryl group may have a substituent, and the cross-linking of the soil may form a polymer compound. In addition, such cross-linking is carried out by using the substituent A as a base point; ^,, when the gel is formed, the metal ion is not contained or the metal which is electrically connected to the ray is not used. It is difficult to carry out the crosslinking reaction at normal temperature. Another aspect 2 glue, for example, enables the formation of a gel 2 . ..., can be condensed = is a saturated hydrocarbon', for example, a thief ring and a hydrocarbon may have a substituent VIII which is saturated or branched. (Substituent) Alternatively, it may be linear

As the unsaturated smoke, I can also, for example, the above-mentioned m, such as thin, series, block and ring block. Further, the substituent may be a substituent of the group A, and the aromatic tobacco may, for example, be a substituent other than the substituent of benzene or biphenyl. Not limited. Or a silk or aryl group, the alkyl group having no hetero group has a carbon number of the base group] &gt;2/41 201231529 = right = base ' is preferably a carbon number having a g group To the filament of 1G, it is more preferable to have a carbon number of i to 3, and the step is preferably a trimethyl group, a pentafluoroethyl group and a heptafluoropropyl group. As a substituent A, _such as: -N (Qing) 2, _N (off you) Μ ^ (S〇2C2F5) 2' ~~N (S02C3F7) 2 &gt; -N (S02CHF2) 2 ^ -n (so2ch2f) 2 and so on. 2 Among these, 'from the viewpoint of easy availability, the substituent A is preferably -n 2〇Ρ^ 2 ' ~N ^S〇2C2F5) 2λ-ν (so2c3f7) 2 〇=the above substitution other than the a group a α The base is not affected by such gorges, and may be exemplified by a base of 1 to 30, an ester group having a carbon number of i to 3, and the like. The main generation of the fire, the silk, the silk and the county can also be replaced by silk and cyano, or it can be linear or branched. Examples of the hetero atom include a nitrogen atom, a sub, a sulfur atom and the like. From the viewpoint of a sub-step, a hetero atom is a woven atom and a sulphur, and a compound represented by the following formulas (1) to (4).

Ai-rO3r%bi . / \ ~\ y r (2) (CH2t; and '" ’ (3)

Z rC-o-{ch2)--a 13/41 (4) 201231529 Gelatinization. 1 to 10, if it is the above-mentioned range, it is possible to make the various liquid mediums condensed to each other by an integer of 30, preferably 2 to 5. The lanthanide 2 or 3 is preferably 3. An integer of from 15 to 15, preferably from 1 to 10, more preferably from 2 to 5. The i group may have an alkyl group having a carbon number of 取代 to 2 取代 of the substituent, and these are preferably from 1 to 10, more preferably from 5 to 5. y is an integer from 15 to 15, preferably from 3 to 15. The integer of 知2 to 〇 is preferably 4 to 10 〇β from the viewpoint of gelation ability, and the substituent is not particularly limited, and examples thereof include: carbon number: S1 炫 炫, alkoxy, gambling, a mercaptan group, a sulfur group, a silk, a light amine group, etc., the alkyl group, a thiol group, a thiol group, a guanamine group, and a quinone group can also have a hospital base. The substituents of the alkoxy group, the acetoxy group, the thiol group, the thioether group, the decylamine group and the aryl group can also be directly recorded or branched. The above-mentioned glare base may, for example, be a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, a secondary butyl group or a tertiary butyl group. The above-mentioned alkoxy group may, for example, be a methoxy group, an ethoxy group, a n-propoxy group, an isopropoxy group, a n-t-oxy group, a secondary oxy group or a tertiary butoxy group. The above-mentioned saturated hydrocarbon, unsaturated hydrocarbon or aromatic hydrocarbon is preferably a compound of the following formula (5) 1 (9).

(6)

14/41 (7) 201231529

The ms is an integer from 1 to 30, preferably from 3 to 2, more preferably from 6 to ι. The number of the substituents A and the smoke, the unsaturated hydrocarbon, or the aromatic tobacco contained in the parent-linked agent is 2 to 3G, and is not particularly limited, but from the viewpoint of ease of synthesis, it is preferable. It is 2 to 5. The gel-like cross-linking content is defined as 25 to 30% by weight, and the viewpoint of the thermal conductivity of the bonfire is preferably 25 to 5% by weight, and is 25 to 30% by weight. (13⁄4 molecular compound) Next, the polymer compound will be described. The polymer compound is a monomer unit having one or more elements of a group consisting of N, P and s. The above-mentioned polymer compounding n is not particularly limited as long as it contains an upper monomer unit, and for example, it can be prepared to contain a single element or more as shown in the following formula. (4) 2 species

(10) Appropriately, the lij molecular compound is crosslinked by the above-mentioned crosslinking agent. In the formula, the 'R2 hydrogen or fluorenyl' D system has a group of one or more elements selected from the group consisting of N, p and s. 15/41 201231529 The second easy-to-take point of view is called the foundation of the nitrogen atom. The monomer unit of the formula (10) may, for example, be an ethylene ring unit, an ethylene ring unit, an ethyl unit, a dimethyl dimethylamine unit, an ethylene sulph unit, a dimethyl amide group, or a unit. The dimethylamino oleyl acrylate unit, the dimethylamine thiopropyl propylamine unit, the vinyl phosphine private, and the ethylene. The phenotype unit and the ethylene sulfide unit are 0 谞, 丄dd w The above monomer s may also have /V. The stilbene group is not limited by these, and for example, the smoldering base of the sinter range of 1 to 30, the thiol group, the sulfur (tetra) group, the amide group and the quinone imine group may also enter V /, There are appearances, alkoxy groups, g-based groups, thiol groups, sulfur scales, _anji and acid imine fresh silk, sputum, can also be planar or branched. As the above-mentioned record, for example, a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, a secondary butyl group, a tertiary butyl group or the like can be given. The above-mentioned oxo group may, for example, be a methoxy group, an ethoxy group, a n-propoxy group, a propyl group, a n-oxy group, a secondary oxy group or a tertiary oxy group. In the monomer unit represented by the above formula (10), from the viewpoint of easy gelation, the monomer units shown in (1)) and (15) are more exemplified by the following weighting unit.

In the formula (14), the integer of 1 to 10 is preferably from 1 to 5', more preferably from 2 to 3. In view of the formula (5), the '112 is an integer from 1 to 1 G'. From the viewpoint of easy availability, 16/41 201231529 is preferably from 1 to 5, more preferably from 2 to 3. The preferred integer is from the viewpoint of easy availability, and the monomer compound may contain a monomer unit other than the above monomer unit, for example, a 'polymer compound, and may further contain the following handle or two or more monomer units. . Species

Ε (11) wherein 'R3 is a hydrogen or a fluorenyl group, which is an organic group. As the £ =,, dilute, alkynyl, alkoxy, phenyl, phenyl, oxime = syllabary, scales are also substituted, and W is a straight heterogeneous St, from the viewpoint of solvent solubility. Preferably, the alkyl group is dissolved in 4: i::; among the monomer units, from the oblique organic solvent

Π5 or (20) The formula (18) towel ' _ 〇 to 1G integer, from the acquisition of the car father 0 to 2, more preferably 〇. In the formula (19), ns is an integer from 1 to 10, preferably from 丨 to 卜. 17/41 201231529 is from 1 to 3. A is N (s〇2Cf3) 2. The system may also have a substituent group and/or a hospital base having a hetero atom, a base of a woman, a square base, and the like. Among these, from the viewpoint of easy availability, R4 is preferably a linear, branched or cyclic green, allyl, ethyl, or a substituent having a carbon number of 2 to 2 Å. And a filament having a substituent, and a linear, branched or cyclic fluoroalkyl group having a carbon number of 1 JL 30. Regardless of the number of calls, the cross-linking reaction proceeds well. The polymer compound contains a monomer unit represented by the formula (10), and further contains a monomer of the formula (1〇) and the formula (11) in the case where the single unit represented by the formula (11) is further contained. A single it can also be any of the following four types of fibers. -ch2~ch*—CHCH?; ΌΗ2-〇Η~ΌΗ2-〇Η-^~00-11,)

CH—CH2-CH—CH2-D E (10-11)

(pH - CH2~CH2-?H~j~

D

Further, 'haves at least one monomer unit represented by the formula (II), and more preferably one or two selected from the group consisting of the formulas (丨8), (19) and (20). the above. However, any one of the formulae (18) to (2) is selected as a monomer unit to contain at least one monomer of the formulae (12) to (17). In the case where the carbon atom of the primary bond to which the group D is bonded is adjacent to the carbon atom of the main chain to which the group e is bonded, D and E may also bond the carbon atoms of the main chain to each other.

S 201231529 The result is that the single element is not limited, for example, V ', as shown in the following formula. (17) —= For the monomer unit represented by the formula (1〇), the formula (not the unit cell equivalent ratio is 丨: 9 to 9: from the viewpoint of the nature of the crosslinking reaction)佳为丨: 9 to 5: 5, more preferably 3: 7 to 5: The number average molecular weight of the polymer compound is not particularly limited, i, 〇〇〇 to 1, 〇〇〇, 000, from the polymer The viewpoint of solubility is preferably 1 〇, _ to 200,000 ', more preferably 1 〇, _ to 1 〇〇, _ 〇 polymer compound silk _, silk _ mosquito, for example, may also be a block copolymer, Newcomb (4), random co-hetero, alternating copolymer-term copolymer or a combination thereof. The weight ratio of the parent-linking agent to the south-molecular compound is not limited, and from the viewpoint of condensing waist, it is preferably 丨: 2 To: 30, more preferably 丨: 2 to 丨: 1 〇 / or more, since the gelling agent of the present invention has an ionic property after gel formation, and has a guide. When formed, it will not be sub-generated, or the metal part of the ship will be attached to the gel. Therefore, if the gel formed by the gel is used, it is superior. The manufacture of inert components is possible. In addition, the gel of the present invention is capable of gelling a very wide range of secret media. Moreover, the gel of the present invention has high heat resistance and transparency. In addition, since the gel ship of the present invention is capable of suppressing the reaction at normal temperature, it is possible to prevent unintentional gelation. In addition, since gelation can be easily performed by heating or the like, it is also excellent in gelation. Moldability: 19/41 201231529 Ingredients. = Ming. In the present invention, the second gelling agent can be used in combination with two or more kinds of the above-mentioned gelatin. In the liquid medium (liquid solute), β is particularly limited to, for example, % of various liquid inorganic substances, and an organic solvent is used, and an ionic liquid or the like is used. Among them, one type or two or more types can be used in combination, and it is suitable for use. The liquid medium can be gelated. Examples of the liquid inorganic substance include water. Examples of the organic solvent include dimercapto, amine (dmf) and dimethyl b (DMA). , Dimethoate (DMS), propylene carbonate (PC), ethylene carbonate ( EC), dimethyl carbonate (DMC), 丫_丁内酉 (GBL), acetonitrile (ΑΝ), methoxypropionitrile (ΜΡΝ), tetrahydrofuran (THF), benzene, dioxin , methoxyacetonitrile (ΜΑΝ), Ν-methyl-transfer (ΝΜΡ) ' 2_methyltetrahydro (tetra), 】, 3_two-noise, 1,4-one. Odor, stupid ether, one 曱Detecting glycol (m〇n〇giyme), propionitrile, mercapto-2-pentanone, Ding guess, valeronitrile, benzomethazine, Erqiyiyuan, dimethoxyethane, formic acid, Acetate B3, propionic acid, propyl g, vinyl carbonate, anabolic-1,2-butyric acid ester, ethyl acetate, diterpenoid thiocyanamide, sulfolane, 3-methyl Sulfone, trimethyl phosphate, triethyl phosphate, nitromethane, acetone, chloroform, dichlorodecane and carbon tetrachloride. From the viewpoint of conductivity, it is preferably monomethylacetamide (DMA), decyloxyacetonitrile (MAN), N-methylpyrrolidone (NMP), dimercaptosulfoxide (DMS®), propylene carbonate. (PC), ethylene carbonate (EC), γ-butyrolactone (GBL), acetonitrile (AN), 20/41 201231529 f oxypropyl (MPN), propyl hydrazine, chloroform, dichloro W and tetrachlorination carbon. As an ion, for example, containing a fabric species and a linden seed, the cation may also have a substituent and is a (four) ion, a lion, a tetrazolium ion, a scale (tetra) ion, a four-wire lion One or more selected from the group consisting of ions, tri-green, and fragrant ion-emitting greens; the anion is composed of auto-ion ions (fluorine, chlorine, smectite), tetrafluoropenic acid Ion (10) plant), hexahydrate acid ion (pf6-), bis(trifluoromethyl) amide ion (tfsa_), thiocyanate, ion (SCN-), two ions (N〇3—) , sulfate ion (s〇4), thiosulfate ion (s#-), carbonate ion (α^2): hydrogencarbonate Xuan (HOV), __子, Agugen ion, secondary coffee _ Ions, remnant acid ions (χαΓ, ―, take - and ΧΟ 'in this 'X-ray fluorine, chlorine, desert or hard), _ _ acetate acetate ((a war n) C 〇〇 ' here' X Fluorine 'chlorine, derivation or hydrazine, η series 1 to 3), tetraphenyl hydride ion (BPV) and its charm (Β (cut), here, phenyl with Aryl=substituent) As electricity The qualitative solution may, for example, be a solution containing strontium and a stone compound: a night, a solution containing _ sub, a solution containing four thieves, and a liquid containing a liquid, etc. a solution of a compound, a solution of 3 ions, a solution containing a tetrasodiumammonium salt, a raw material, and a solution of the above, preferably containing a H-rich agent such as B-method and methoxypropionitrile. γ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ For the factory &quot;00 weight, use 2 〇〇 to 1 〇〇, _ parts by weight, preferably _ to 5, _ parts by weight. The total content of the liquid medium is within the range 21 / 41 Further, in the embodiment of the present invention, the gel contains a conductive material, and the conductive material contributes to an improvement in conductivity of the gel, and for example, : electrolyte, conductive fine particles, etc. The electrolyte is made by dissolving it in a liquid medium to improve conductivity. The electrolyte is not particularly limited, and examples thereof include hydrazine, a hydrazine compound, a lithium salt, and a tetraalkylammonium salt, and may be contained in one type or two or more types. Further, the conductive particles are dispersed and present in a liquid medium. In the case where the conductivity is imparted to the liquid medium, it is not particularly limited. Since the gel of the present invention is formed after the gel is formed, the gel agent has ionicity and is electrically conductive even without a conductive substance. Since the gel of the lyre towel is not miscellaneous, the gel described above suppresses metal parts in the electrochemical device and the like. Therefore, it can be used for a part such as an electrode. For example, solar power generation, lithium ion, electric double layer capacitors, etc. '&lt;Method of manufacturing gel>

The method of producing a gel using the gel of the present invention is carried out by mixing an additive compound and a liquid medium into a gel medium, and a liquid medium is mixed into the polymer compound. The condensed manufacturing method of the present invention comprises the step of mixing the stimulating agent and the liquid medium. In the present embodiment, the step of heating is further included. The mixing method in the method is not particularly limited. For example, it is also possible to use a high-crosslinking agent or a cross-linking agent and economical considerations and I 80 c. The heating temperature is not limited to the method, and the heating temperature is not particularly limited. When the reactivity is broad, it is preferably 40 to 12 (TC, more preferably 4 to 8 〇g 22/41 201231529 degrees is the case of the _ The gel formation will proceed well. The gel of the method described above can be produced according to the content of the crosslinking agent, the polymer compound and the liquid medium. In the method for producing the gel of the present invention, It is difficult to carry out the "other-side S" at room temperature, and it can be suitably gelled by heating, etc. Therefore, it is possible to control the formation of the gel and facilitate the molding of the gel. The problem of the occurrence of the non-patent document t is that the reaction is vigorously carried out at room temperature due to the high reactivity of the functional group, and further, it is difficult to fill the obtained gel in accordance with each use by the intense reaction. Therefore, the manufacturing method described above can be used as a method for producing a gel such as an electrochemical device having a wide range. However, in the above-mentioned form, a cross-linking reaction mechanism with a polymer compound is formed. Details _ although not yet determined It is generally considered that the gel is constructed by forming a surface in accordance with the following reaction. An example of this polymerization reaction is shown below. TFSA yarn N (Sq2CF3) 2, ph silk shows a stupid base.

/ η (The above reaction formula (1) shows poly(4-vinylpyridine) having 2 or more compounds containing 23/41 201231529 atomic groups having a nitrogen atom per molecule, and bis(trifluorofluorene) per molecule The number of sulfonamide groups is an addition reaction of two organic compounds of N,N,N',N'-tetrakis(trifluorosulfonylsulfonyl)dodecane-1,12-diamine, and the synthesis consists of The reaction of a polymer composed of a crosslinked product of N rust salt.

The above reaction formula (II) is a poly(vinylphenyldiphenylphosphine) having a compound having two or more atomic groups containing a phosphorus atom per molecule, and a bis(difluoromethane) of each molecule. The number of bases is an addition reaction of two organic compounds of N, N, N', N'-tetrakis(trifluoromethanesulfonyl)dodecane-oxime, 12-diamine, and the synthesis is from a rust salt containing P The reaction of the polymer formed by the crosslinked product. 24/41

S 201231529

+ TFSA-tCHoj-TFSA

-H2C—CH

H2C-CH The above reaction formula (III) is a poly(4-vinylphenyl stupyl sulfide) having a compound having two or more atomic groups containing a sulfur atom per molecule, and a double (three) per molecule. The number of fluorosulfonamides is 2, N, N', N'-tetrakis(trifluoromethanesulfonyl)dodecane·anthracene, addition reaction of 12-diamine A reaction of a polymer composed of a crosslinked product containing a rust salt of S. The present invention has been described above based on suitable embodiments of the present invention, but the present invention is not limited to the embodiments. a The present invention can be used in combination with any of the above structures. For example, the parent agent of the present invention comprises: a saturated hydrocarbon, a dehydrogenated hydrocarbon, or a hetero atom, which may or may not contain a plurality of compounds. Or the Fang and the Yi people, and the shirt is limited by the shame. —N (s〇W) 2 (4) where is formed by trimethyl, pentafluoroethyl and domain propyl

Further, for example, the polymer compound of the present invention (4) is preferably a monomer unit containing t or two or more elements selected from the group consisting of N, 25/41 201231529 and s, and the above-mentioned polymer The compound is defined. In the method for producing a gel of the present invention, it is also possible to use a light force such as uv to specifically crosslink it instead of heating. [Examples] Next, the present invention will be specifically described based on the following examples, and the present invention is not limited thereto. [Examples 1 to 18] Gelation test A silicone resin was prepared by using a combination of the crosslinking agent shown below and a polymer compound shown in Table 1. Crosslinking agent: N, N, N', N'-tetrakis (trifluoromethane fluorenyl) propyl succinyl ^ 3-diamine (TFSA-(C:H2) 3-TFSA) N, N, N', N' -tetrakis(trifluoromethane-xanthine) hexamethylenediamine (TFSA-(CH2) 6-TFSA) N,N,N',N'·tetrakis(trifluorosulfonylsulfonyl) _, _, 12 Diamine (TFSA_(CH2) 12-TFSA) N,N,N',N'-tetrakis(trifluorosulfonyl)p-diphenylene diamine (TFSA-CH2-Ph-CH2-TFSA ) ]^ ,&gt;«[,]^',&gt;1',&gt;'1",]^''-six (trifluoromethane yellow wine)-]^,',,'^,,,,1 ^',,-Tris(amineethyl)amine (N (C2H4-TFSA) 3) High molecular compound: Poly(4-ethylene D ratio bite) (P4VP, molecular weight: 6〇, 〇〇〇) Poly (4 - ethylene ° ratio - co--4-ethyl-N-allyl d ratio π rust bis(trifluorosulfonyl sulfhydryl) decylamine) (P4VP-Ally molecular weight: 6 〇, 〇〇〇) Poly(N-vinylimidazole) (PVlm) 26/41 201231529 χκ (monopropylmethylamine) (pdΑΜΑ) poly(diammonium methacrylate) (pdmaema) by mixing and heating the above coagulation The gel is prepared with a liquid medium as shown below. Liquid medium: Dimethyl sulfoxide (DMSO) Dimercaptocaramine (DMF) Propylene carbonate (PC) Ethylene carbonate (EC) γ-butyrolactone (GBL) Acetonitrile (AN) Toluene Gas-like (CHC13) acetone (Acetone) dimethyl carbonate (DMC) iodine / lithium iodide / tertiary butyl pyridine (I2 / Li [/ t - BuPy ) borofluorinated tetraethyl ammonium (NJEt4BF4) lithium bis ( Trifluoromethanesulfonyl) decylamine (LiTFSA) iodide propylmethylimidazolium (PMIml) allyl butylimidazolium bis(trifluoromethanesulfonyl decylamine) (ABImTFSA) as the above-mentioned combination The preparation examples of the gel obtained by the gelling agent and the liquid medium (Table 1), and the preparation methods of Examples 1, 9, 17, and 18 are shown below. [Example 1] Poly(4-vinylpyridine) ( P4VP, molecular weight: 60,000) 50 mg (0-47 mmol) dissolved in DMF 0.5 mL, mixed with Ν, Ν, Ν', Ν'·tetra (trifluoromethane 27/41 201231529 sulfonyl) propane-3-diamine ( TFSA-(CH2) rTFSA) 50 mg (0.50 mmol), heated to 8 ° C, and a gel sample was obtained after 30 minutes. [Example 9] Poly(dimethylaminoethyl methacrylate) ( PDMAEMA) 50mg (0.26 mmol) dissolved Toluene 0.5 mL, mixed with N,N,N,,N,-tetrakis(trifluoromethanesulfonyl)decane-1,12-diamine (TFSA-(CH2) l2-TFSA) 12.5 mg ( 0.02 mmol ). Heating to 8 ° C, and obtaining a sample of the gel after 30 minutes [Example 17] Dissolving poly(4-vinylindole ratio) (P4VP) 20 mg (0.19 mmol) in allyl butyl imidazole Mixed with N, N, N', N'-iz9 (trifluoromethanesulfonyl) oxime-1 &gt; 12 · diamine (TFSA_ (CH2) 12 in 0.5 mL of bis(trifluoromethanesulfonyl decylamine) -TFSA) 12.5 mg (0.02 mmol). Heat to 1 〇〇. (;, a white opaque gel was obtained after 30 minutes. [Example 18] Poly(diamidoethyl methacrylate) (PDMAEMA) 20 mg (0.11 mmol) was dissolved in allyl butylimidazolium ( Trifluoromethanesulfonyl decylamine) 0·5 mL of 'mixed N, N, N', N'-tetrakis(trifluoromethanesulfonyl) smoldering January female (TFSA-(CH2) 12-TFSA) 12.5 mg (0.02 mmol), heated to 100 ° C, and a clear gel was obtained after 30 minutes. [Results of Examples 1 to 18] 28/41

S 201231529 [Table 1]

EXAMPLES Gels-----Combination^(Morby Ratio) Heating Temperature (°C) Gelatinizable Liquid Medium Crosslinking Polymer Compound 1 tfsa-(ch2)3-tfsa P4VP 0.17 80 DMF, PC, EC and GBL 2 TFSA-(CH2)6-TFSA P4VP 0.17 DMF, PC, EC and GBL 3 tfsa-(ch2)I2-tfsa P4VP 0.17 DMF, DMSO, PC, EC and GBL 4 TFSA-CH2- Ph-CH2-TFSA P4VP 0.17 DMF, DMSO, PC, EC and GBL 5 N(C2H4-TFSA)3 P4VP 0.17 DMF, DMSO, PC, EC and GBL 6 TFSA-(CH2)i2-TFSA P4VP-allyl 0.19 DMF ' DMSO 'PC, EC, GBL and AN 7 n(c2h4-tfsa)3 P4VP-allyl 0.19 DMF, DMSO, PC, EC, GBL and AN 8 tfsa-(ch2)丨2-tfsa PVIm 0.15 DMF, G BL 9 TFSA -(CH2),2-TFSA PDMAEMA 0.17 Toluene, CHC13, Acetone and DMC 10 TFSA-(CH2), 2-TFSA PDAMA 〇.Γδ~ GBL and AN 11 n(c2h4-tfsa)3 PDAMA 0.18~ GBL and AN 12 TFSA-(CH2), 2-TFSA P4VP-allyl 0.19 I2/LiI/t-BuPy AN solution 13 TFSA-(CH2), 2-TFSA P4VP 0.17 Net4BF4 PC solution 14 TFSA-(CH2), 2-TFSA P4VP PC of 0.17 LiTFSA: EC (1:1) solution 15 TFSA-(CH2)I2-TFSA P4VP 0.17 LiTFSA PC solution 16 TFSA-(CH2 I2-TFSA P4VP ο.π 100 PMIml 17 TFSA-(CH2), 2-TFSA P4VP 0.11 ABImTFSA 18 TFSA-(CH2), 2-tfsa PDMAEMA 0.18 ABImTFSA 29/41 201231529 with blend ratio = (crosslinking agent) The number of moles / (the number of moles of the monomer unit contained in the polymer compound) was calculated. The gelling agent of the present invention, as described later, is as shown in the Table, and is suitable for gelling various types of liquid media. [Examples 19 to 23] Conductivity test [Example 19] Poly(diisopropylmethylamine) (PDAMA) 50 mg (〇.45 mmol) was dissolved in L/Lil 0.01 mol/L/0.1 mol/L. AN solution 〇5 mL, mixed with N, N, N', N'·© (trifluoromethanesulfonyl) oxime _1 &gt; 12_diamine (tfsa_ (CH2) irTFSA) 25 mg (〇·〇 4 mmol). Heat to 8 ° C and obtain a sample of the gel after 30 minutes. [Example 20]

Dissolve poly(4-vinylpyridine) (P4VP, molecular weight: 60,000) 50 mg (0.47 mmol) in 0.5 mL of I2/LiT 0.01 mol/L/0.1 mol/L GBL solution, and mix N, N, N', N,-iz9 (trifluorosulfonyl) decane-], 12·j$(TFSA-(CH2) 12-TFSA) 25 mg (0.04 mmol). Heat to 8 ° C and obtain a sample of the gel after 30 minutes. [Example 21] Poly(4-ethylene ratio: di-co-vinylallyl) ratio t bis (trifluorosite yellow-branched) amine (P4VP-Allyl, molecular weight: 60,000) 50 Mg( 0.47 mmol) dissolved in 0.5 mL of I2/Lil 0.01 mol/L/0.1 mol/L AN solution, mixed with N, N, N', N'-tetrakis (trifluorosulfonyl) , 12-Diamine (TFSA-(CH2) 12-TFSA) 25 mg (0.03 mmol). Heat to 80 ° C and obtain a clear gel after 30 minutes. [Example 22] Dissolve poly(dipropylpropylguanamine) (PDAMA) 50 mg (0.45 mmol) 30/41 201231529 in 0.5 mL of I2 0.01 mol/L AN solution, and mix N, N, N, , N,-tetrakis(trifluorosulfonylsulfonyl)oxime-1,12-diamine (TFSA_(CH2)丨rTFSA) 25 mg (0.03 mmol). Heat to 80 ° C and a clear gel was obtained after 30 minutes. [Example 23] Poly(4-vinylpyridine) (P4VP, molecular weight: 60, _) 25 mg (〇.24 mmol) was dissolved in 0.5 rnL of LiTFSA 1.0 mol/L pc solution, and N, N, N' was mixed. , N'-tetrakis (trifluoromaleite), diamine (tfSA-(CH2) n-TFSA) 12.55 mg (0_02 mmol). Heat to 80 ° C and obtain a clear gel after 3 minutes. [Reference Examples 1 to 4] Reference examples were prepared by modulating the electrolyte shown in Table 2 below, and the conductivity was measured. [Table 2] Reference example Electrolyte conductivity Electrolyte concentration Organic solvent (mS/cm) 1 I2/Lil 0.01 mol/L/0.1 mol/L AN 9.3 2 I2/UI 0.01 mol/L/0.1 mol/L GBL 2.3 3 I2 0.01 mol/L AN 0.1 4 LiTFSA 1.0 mol/L PC 6.2 [Comparative Example 1]

Poly(4-ethylene) bite (P4VP, molecular weight: 6〇, 〇〇〇) 5〇mg (〇47 mmol) dissolved in I/Lil 〇.〇1 m〇l/L/0. lm〇丨/L of GBL solution 〇 5 mL 'mix 1,12-dibromofluorene (Br-(CH2)丨rBr) i3.i mg (〇.〇3 mmol). Heat to 80 ° C and a clear gel was obtained after 30 minutes. 31 /41 201231529 [Comparative Example 2] Poly(4-ethylene ° ratio - co-ethylene-N-dilyl group. Tough rust bis(trifluorite xanthine) decylamine) (P4VP-Allyl, molecular weight :6〇,〇〇〇)5〇mg(0.47 mmol) dissolved in 0.5 mL of I2 0.01 mol/L AN solution, mixed with 1,12-two deserts (Br-(CH2)丨2 〇13.1 mg (〇.〇3mmol). After heating to 80 ° C, a transparent gel was obtained after 30 minutes. The impedance of each sample was measured at a temperature of 27 ° C and a frequency of 1 〇 6 -1 〇 _1 (Dongyang Technica Co., Ltd. The results of comparison with the corresponding reference examples are shown in Tables 2 and 3. Further, the conductivity retention ratio (%) = (impedance of each embodiment / impedance of each reference example) xlOO (% [Table 3] Conductivity of solid gel electrolyte (mS/cm) Conductivity retention (%) Example Crosslinker Polymer Compound 19 TFSA-(CH2)12-TFSA (50 g/L PDAMA (100 g/L) Reference Example 1 9.3 100 20 TFSA-(CH2)丨2-TFSA (50 g/L) P4VP (100 g/L) Reference Example 2 2.0 89 21 TFSA-(CH2)i2-TFSA (50 g/L) P4VP-aIlyl (100 g/L) Reference Example 3 6.2 6200 22 TFSA-(CH2), 2-t Fsa (50 g/L) PDAMA (100 g/L) Reference Example 3 10.0 10000 23 TFSA-(CH2)12-TFSA (25 g/L) P4VP (50 g/L) Reference Example 4 4.6 74 32/41

S 201231529 [Table 4]

As shown in Table 3, the results. Material, 4. When the gelation is reduced, the conductivity of the gel is reduced. The gel formed is shown in Table 2 and Table 4, and the gel coefficient of the gel in the case of the county invention. ~, the member can not maintain the higher conductivity of the gels of Comparative Examples 1 and 2. Example 24] Corrosion test The test samples are shown in Table 5. L Table 5]

Br-(CH2) ι^-Β7(3^£/ΓΛ~~ TVQAirjJ \T^C ΓΤ^τ^ TFSA-(CH2)12-TFSA (72 _s^y electrolyte to molecular compound-P4VP LiTFSA (1.0M /PC P4VP LiTFSA(1.0M)/PC P4VP LiTFSA(1.0M)/PC Crosslinker Gel 33/41 201231529 Test. Condition f test solution ~ Τϊ .0 M LiTFSA-PC~] Temperature ~rrc gas Environment pf2 size lOmL If# ~ - blood measurement range anode res-&gt;+3V cathode M sweep speed 10 mV/sec action electrode WE A1 0.5 cm2 reference electrode RE Ag/Ag ten opposite electrode CE Ft - experimental method using Potentiostat ( The lsv measurement (acting electrode, electrode: platinum, reference electrode: Ag/Ag+AN) was carried out by Hokuto Electric Co., Ltd. HSV_】〇〇. The results measured by the anodes in samples J, 2 and 3 are shown in Fig. 1. In the case of the sample 2 containing the desertification, due to the large oxidation in the + 2 ¥, the Ming Ming electrode is mixed with the lion. On the other hand, the sample 1 and the sample have the TFSA material; The financial system is not oxidized, and the worse: on the electrode miscellaneous surface, the gel formed by using the gelling agent of the application of the present invention shows more than the gel containing halogen. [The possibility of industrial use] Due to the high conductivity of the towel of the invention, it does not promote the contact with the gel during the electrochemical treatment. Solidification use. Electrolyte used in drying equipment [Simple description] 34/41

S 201231529 Figure 1 is a corrosion test, and the LiTFSA-PC solution, the gel crosslinked with 1,12-dibromododecane, and Ν,Ν,Ν',Ν'- were determined by LSV measurement. The result of the determination of the anode of the gel crosslinked by tetrakis(trifluoromethanesulfonyl)-dodecane-1,12-diamine. [Main component symbol description] None 35/41

Claims (1)

201231529 VII 1. 2. Scope of application: - a kind of gelling agent, which contains a cross-linked acid polymer compound, and because of this, it forms a condensate axis of the 轴 柯 轴 网 网 网 , , , , , A plurality of saturated hydrocarbons, hetero and atomic saturated aromatic hydrocarbons, A: -N (SOjy) 2 (A) ^ wherein R is independent of each other by tri-anthracene, pentafluoroethane Selected from the group, the polymer compound contains; the species selected from the group consisting of = i:=:r - the gel of the scope of the patent, wherein the crosslinking agent is contained below, (1) and (2) selected from the group consisting of compounds such as W + 勒七., 乂(3) *· cH2 A (4) where the Xiangshen sinensis family base is 1 An integer of 30, 吒 m m m m m m m m 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 , , , , , , 201231529 y is an integer from 1 to 15, and z is an integer from 2 to 10. 3. The gelling agent according to the first aspect of the invention, wherein the selected one of the groups of the compounds represented by the crosslinking agent is: -, 3, or 2 or more: (\ Γ Τ A (6) -CH (δ) A A, ljT~A A A Ό O 0- O- (9) and (8) A where the formula is an integer from 1 to 30. 4. The gelling agent according to claim 1 of the patent scope, a substituent A.肀 肀 肀 肀 具有 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀 肀The molecular compound is a monomer unit having one or more types of formulas selected from the group consisting of: 37/41 (11) 201231529 wherein R2 and r3 are independent hydrogen or hydrazine. The group D has a group of one or more elements selected from the group caps composed of 8 and E, and the E-based organic group, =5=:=3=the main carbon atom bonded to the group E The ring is formed, and the carbon chains of the main chain are bonded to each other. In the case of the element, the equivalent ratio of the phase __ 6. is 丨: 9 to 9: 丨. . The monomer unit represented by formula (〖)) ====:, the polymer compound contains more than one species: one or two selected from the group of 冓成 (12), (15) (13) , (14) (17) &gt;1:» (18) (19) (16) n5 (20) In the formula, η, η2, 〜2 and ns are independent of each other from i to 10, 38/41 S 201231529 n; 3 is an integer from 0 to l〇, Α is N (S02CF3) 2, R is a linear or branched alkyl group having 1 to 20 carbon atoms, an allyl group, an ethyl group, a base group which may have a substituent, a stupid group which may have a substituent, and a carbon number of 1 to 20 It is selected from the group consisting of a linear or branched fluoroalkyl group, but any one of the formulae (18) to (2〇) is selected as a monomer unit. 12) to at least one monomer of (17). 7. For the towel, please specify _ i condensed _, the average molecular weight of the polymer compound of the towel is 1,000 to 1, _, 〇〇〇. 8. The gelling agent of the ninth aspect of the invention, which gels a liquid medium containing an organic solvent, an ionic liquid and/or an electrolyte solution. 9. The gelling agent according to item 4 of the (4) patent scope, wherein the organic solvent is dimethyl decanoate (DMF), dimethyldiethylamine (DMA), dimethyl sulphur (DMSO) 'carbonic acid Propylene Cool (PC), Ethylene Carbonate (ec), Dimethyl Carbonate (DMC), γ·Bing (GBL), Acetonitrile (AN), Methoxypropionitrile (MPN), Tetrahydrofuran (THF) , toluene, methylene chloride, methoxyacetonitrile (MAN), N-fluorenyl trans) (NMp), 2-mercaptotetrahydrocarbamate, 1,3-dioxane, iota, monooxane , anisole, dimethyl ether monoglyme, propionitrile, 4-methyl-2-pentanone, butyronitrile, valeronitrile, benzonitrile, 1,2-one gas, trimethoxyethane 6 , formic acid brewing, ethyl acetate, methyl propionate, ethyl propionate, ethylene carbonate, decyl butyrate, ethyl methyl carbonate, dimethyl carbamide, cyclobutyl hydrazine, 3-methyl The species selected from the group consisting of sulfolane, trimethyl phosphate, triethyl phosphate, decyl, C, chloroform, methylene chloride and tetra-carbonized carbon, or two or more. 10. The gelling agent according to claim 8 wherein the organic solvent is dimethyl 39/41 201231529 acetamide (DMA), dimethylformamide, dimethyl argon (DMSO), Propylene carbonate (PC), ethylene carbonate (EC) butane vinegar (GBL), acetonitrile (AN), methoxypropionitrile (MPN), methoxyacetonitrile (MAN), N-methylpyrrolidone (NMp), acetone, gas, two gas-fired and four gasified carbons, selected from the group or two or more. 11. The gelling agent according to item 8 of the patent scope, wherein the ionic liquid is a cationic species and an anionic species, the contact ion may also have a substituent and is a (four) erbium ion, a 疋镔° 疋镔 ion, a four-burning base One selected from the group consisting of ions, strontium rust ions, brigade erbium ions, four-burning squamous ions, sputum sulphur ions, 'smoke-based ions, and morpholin quinone ions' 2 or more; The anion system consists of _ cation ions (I, gas 'moth and desert), tetrafluorocyanate ion (BF4), hexafluorophosphate ion (pFr), bis(trifluoromethanesulfonyl) quinone imine ion ( TFSA-), thiocyanate ion (SCN_), nitrate ion 2-(ΝΟΓ), sulfate ion (slave), thiosulfate ion (S203), carbonate ion (co^-), bicarbonate Ions), phosphorus to ions, phosphite ions, secondary root ions, and functional acid oxide ions (X04-, X〇3-, 乂〇2- and χ〇-, here, lanthanide gas, gas, bromine , 石典), is acetic acid ion ((CXnH3 n) C00_, here, lanthanide chlorofluoro / odor or 峨 'n system i to 3), tetraphenyl phosphite ion (muscle plant) and eight derivatives One or two or more selected from the group consisting of (B (Aryl) 4 and phenyl having Afyl=substituent). 12. A gelling agent according to item 8 of the litter material, wherein the electrolyte solution is composed of a solution containing 1, human, a compound, a solution containing a clock ion, and a solution containing a tetrakisole salt. One or more selected from the group. 2Specialize her 1] Dimethine agent, the content of the 咼7 knife compound is 15 to 75% by weight relative to the gel. 40/41 S 201231529 14. 15. 16. 17. 18. 19. The gelling agent of claim 1, wherein the crosslinking agent is present in an amount of from 25 to 85% by weight. In the case of a gelling agent, as in the gelling agent of claim 8, the total content of the sexual medium is (U to 5 G weight%. When the solution is 4%, the liquid is as in the scope of the patent application) Gel = the part of the rotation. ,, read for the shaft to the electro-gluon gel's use as the patent application fine; the species exchange system 'the _ Na Chengru _ _ ^ ^ ^ glue = manufacturing gel The method of using the method of mixing the gelling agent with the liquid medium is used as the item i of the patent application scope.