201226044 六、發明說明： 【發明所屬之技術領域】 本案發明係屬於工業有機性氣體廢氣處理裝置領域，特別是涉及 一種結合奈米光觸媒及磁化微波兩種最新處理技術，能有效·且快速分 解有機性工業廢氣之高效能有機物氣體磁化熱處理方法及其設備者。 【先前技術】 在空氣中為數眾多的有機性污染物中，揮發性有機物（volatile organiccompounds; VOCs)因產生源廣泛，從煉油廠到生活週遭的乾洗業、 電子業、表面處理業、皮革業、油漆業及最大宗的化學製造業…等等，都 可發現其普遍存在於環境中，而這些有機性氣體大多具有易揮發性及化學 ^性而對人體健康有相當程度的影響與潛在威脅；美國更於199〇年通過」 空氣清淨法修正案(Clean Air ActAmendment; CAAA)」，將多種揮發性有機 物列為有毒空氣污染物（toxic air pollutants; TAPs)可見一般。 而控制有機性氣體常見的方法包括：燃燒(combustion)、觸媒焚化、 吸附(adS〇rpti〇n)、濕式洗條、凝結(condensati〇n)、光氧化程式、 念物，理及一些高級氧化程式（Advanced 〇xidati〇n Pr〇cesses; A〇ps)〜 e 土私然f處理及n級氧化程式麟這些有機性氣體產生有效的破壞 Ϊ大多初期投資成本或處理成本過高；而吸附及吸收法又往往只 非達到的減量及減毒的環境處理目標，因此尋找各種高效 率、柄處理技術即·研究環賴題當前的主要課題之一。 的會ί據發明人之研究發現’近二十年來，光觸雜序制許多學者 究’是近年來相當具有潛力的—項處理技術， 另外，已知的有機染物’以達到分解、礦化之目的。 主要是藉磁波’其能量的鮮範圍從_到3GGGHZ， 污料和偶極轉㈣使得目的分子•進而造成標的 達成，預期將能 【發明内容】 廢氣處i裝較課於依現行-般工業有機性 染。 處理成本，影響廠商裝設意願，造成環境之汙 本案解決_之技解段餘於m氧化鈦、氧化料奈米化光觸 201226044 氧Ϊ性碳等高介電常數物f作為擔體，並填充於微波反 堂上之管體，成；令含卫業有機性之廢氣經由輸 通過送^管反應主體，藉由結合奈米光觸媒及 ΪΪΪ2 ttt f反駐㈣，氧化鈦/四氧化三鐵等複合觸媒受 、*▲. 產生微獻、射，分別產生减量的自由基、電子、電洞對及快 ί【:ίί:將通過介質的工業有機性之廢氣完全給破壞、分解而產生無 容易:Si前ί;性==研發逹到提供低耗能、高效率、組裝 【實施方式】 請參閱第ϋ本發明反應主敝成示賴，包括： 一反應主槽（1 )，於其空間中包括： 空間了磁控管（1 1 )，係為微波產生源’並以其導波管（1 2 )構成反應 一反應主體（2 ) ’係置於該反應主槽（i )導波管（ ΐ 以上 21)所組成，該 為佳；s夬^玻璃管或相關耐向溫材料所製成，且以圓柱管 ϊ 反ίίϊϋ)^一進氣口（22)及-排氣口（23); 氣口 ^ ί) ^串遠组2i ^為胡各/體（2 1)間以進氣口（ 2 2 )與排 科沒膜㈣(參閱第—圖），或是並聯組成（參閱第三圖）； 且該高數(體填充有高介電常數複合擔體⑶， 叙其中之! 擔)係選自二氧化欽、氧化鋅所組成光觸媒群 數^料所域群二鐵等峨化物或雜氧錄等其他高介電常 (一^^^^^微波擔體之贿與表面分析： 三鐵π# 二氧化鈦、氧化鋅等光觸媒溶液加入適量的四氧化 _〜90(TC，燒結時f ^複合觸媒結合強度即可，燒結溫度為 、-。，β為3〜24小時，所得固體顆粒即為光觸媒/微波擔體。 (二及微波熱處理反應： 〇.5谓w 微波輸出功率設定在 度高（200〜2000。〇=^3主^介電常數高、加熱時間短、處理溫 马選擇依據，本身除可降低氣體通過速度外，且具有"^ 4 201226044 催化效果。 本發明廢氣處理流程說明如下： 將工廠產生之有機性廢氣經由輸送管路輸送至反應主槽（1 )，另一方 面控制進流之混合空氣、氧氣比率，以及調整進氣之溫、溼度，如第四圖 所示，於該輸送管路十先後經過氣體混合槽（4)及過濾器（5 )，並經由 一冷卻系統（6)降溫，最後輸送進入至反應主槽（1)中； - 於已啟動磁控管（11)產生微波之反應主槽Q )中，進行二 欽光反應，以及觸媒微波之熱反應，藉由反應主槽（1 )中之自由基、電 子、電洞對，及觸媒微波熱處理效應將有機性排放廢氣完全給 , 無害性的二氧化碳與水蒸氣。 而反應之進行係由相關電子元件及電腦精控。 本發明Sx備採用奈来化一氧化欽、氧化辞、混合四氧化三鐵等鐵氧化 物、鈷鎳氧化物、活性碳、沸石等形成光觸媒^/微波擔體，g將其填充於 高^能有機物氣體磁化熱處理設備中，一則提高原填充擔體的介^常數，、 提高微波效應；二則利用磁控管所產生的微波能量激發氧化鋅、二氧化鈦 等觸媒產生高能量的自由基及電子、電洞來處理工業廢氣中有機性氣體， 三則利用活性碳、沸石等多孔性擔體來增加比表面積、反應速率，成 效能有機物氣體磁化熱處理設備》 … 本發明設備所述以磁控管產生非游離照射的微波能量，藉由離子的傳 導和偶極的轉動而使得目的分子運動，進而造成標的污染物破壞與分解。 卞發明高效能有機物氣體磁化熱處理設備除了具有省能源、^能量損 失省時、無需添加任何化學氧化物，更不會造成二次污染等環保的優點 • 外，更主要是磁化熱處理技術是自物體的内部而外，故不會有表面效應的 ，題與_ ’符合安全性及適用性’因此，可以預期以奈米化氧化辞’、' 二 ^化鈦、四氧化三鐵等鐵氧化物、鈷鎳氧化物觸媒結合磁化熱處理技術應 ，於工業廢氣中有機性氣體的處理程式，應具有充分之產業上可利用性及 價值。 本發明可達成的具體功效包括： 1、結合奈米光觸媒及磁化微波兩種最新處理技術，能有效且快速分 解有機性工業廢氣。 、本發明處理有機性工業廢氣，使其受高溫之破壞而產生無害之二 軋化碳與水蒸氣，因此具有反應時間短，低耗能、無二次公害等諸多優點。 3、本發明由於反應時間短，可使反應器之體積較一般處理設備小， 、且組裝簡單、建造成本與處理成本較低廉，連小型的工廠都有能力裝設 201226044 使用，有效降低廉商經濟負擔。 4、 本發明可視處理標的對象調整控制廢氣由反應主體（2)之進氣 口（2 2)以並聯或串連方式送入多管反應主體（£)中，以增加廢氣之 處理量或處理效率的彈性操作。 5、 本發明可提高廠商處理有機性空氣污染物之意願，減少工業有機 性廢氣對於環境與人體的汙染與危害。 以上所述，僅是本發明可能之實施例，當不能以此限定本發明之範圍， 凡依本案發明說明、圖式或申請專利範圍所作之等效變化、修飾或置換， 皆應屬於本案之專利權涵蓋之範圍。 【圖式簡單說明】 第一圖係本發明反應主槽组成示意圖 圖係本發明反應主體各管體以串連組成示意圖 f三圖係本發明反應主體各管體以並聯組成示意圖 第四圖係本發明設備之示意圖 【主要元件符號說明】 1反應主槽 土1磁控管 12導波管 2反應主體 2 1管體 2 2進氣口 2 3排氣口 $高介電常數複合擔體 4氣體混合槽 5過濾器 6冷卻系統201226044 VI. Description of the invention: [Technical field of invention] The invention belongs to the field of industrial organic gas exhaust gas treatment devices, and particularly relates to a new combination of nano photocatalyst and magnetized microwave, which can effectively and quickly decompose organic High-performance organic matter gas magnetization heat treatment method and equipment for industrial industrial waste gas. [Prior Art] Among the many organic pollutants in the air, volatile organic compounds (VOCs) are produced from a wide range of sources, from refineries to dry cleaning, electronics, surface treatment, and leather. The paint industry and the largest chemical manufacturing industry, etc., can be found to be ubiquitous in the environment, and most of these organic gases are volatile and chemically resistant and have a considerable degree of impact and potential threat to human health; The United States passed the Clean Air Act Amendment (CAAA) in 199, and classified various volatile organic compounds as toxic air pollutants (TAPs). Common methods for controlling organic gases include: combustion, catalyst incineration, adsorption (adS〇rpti〇n), wet scrubbing, condensation (condensati〇n), photooxidation, reading, and some Advanced oxidation program (Advanced 〇xidati〇n Pr〇cesses; A〇ps) ~ e soil private f treatment and n-level oxidation program, these organic gases produce effective damage, most of the initial investment costs or processing costs are too high; Adsorption and absorption methods often only achieve non-achievable environmental treatment targets for reduction and attenuation. Therefore, it is one of the main topics of high efficiency and handle processing technology. According to the research of the inventor, 'in the past two decades, many scholars in the photo-touch system have been quite potential in recent years--the treatment technology, in addition, the known organic dyes' to achieve decomposition and mineralization. The purpose. Mainly by the magnetic wave 'the range of its energy from _ to 3GGGHZ, the dirt and the dipole turn (four) make the target molecule and then the target is achieved, it is expected to be able to [explanation] the exhaust gas is installed in the current industry Organic dyeing. The treatment cost, affecting the manufacturer's willingness to install, causing the environmental pollution to be solved in this case. The technical solution is to use the high dielectric constant f such as m-titanium oxide and oxidized material nano-photometric contact 201226044 oxonium carbon as the support. Filling the tube on the microwave counter, so that the exhaust gas containing the organic matter of the industry is transported through the tube to the reaction main body, by combining the nano photocatalyst and the antimony (4), titanium oxide/ferric oxide, etc. Composite catalysts are received, *▲. Produce micro-distribution and radiation, respectively, to produce deductive free radicals, electrons, holes and fast ί [: ίί: The industrial organic exhaust gas through the medium is completely destroyed and decomposed. No easy: Si pre- ί; Sex == R & D to provide low energy consumption, high efficiency, assembly [Implementation] Please refer to the third aspect of the present invention, including: a reaction main tank (1), The space includes: a space magnetron (1 1 ), which is a microwave generating source 'and a reaction tube (1 2 ) constituting a reaction-reaction body (2) ' is placed in the main tank of the reaction (i) The waveguide tube (ΐ 21 above) is composed, which is better; s夬^ glass tube or related resistance Made of warm material, with cylindrical tube ϊ ί ϊϋ ^ ^ 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气 进气Between the inlet (2 2 ) and the row of membranes (4) (see the figure - figure), or in parallel (see the third figure); and the high number (the body is filled with a high dielectric constant composite carrier (3), In the middle of it, it is selected from the group consisting of dioxins and zinc oxide, the number of photocatalyst groups, the group of materials, the group of ferric compounds such as diiron, or other high dielectric constants (a ^^^^^ microwave carrier). Bribe and surface analysis: Three iron π# photocatalyst solution such as titanium dioxide or zinc oxide is added with an appropriate amount of oxidized _~90 (TC, f ^ composite catalyst bonding strength when sintering, sintering temperature is -, -, β is 3 ~24 hours, the obtained solid particles are photocatalyst / microwave carrier. (2) Microwave heat treatment reaction: 〇.5 said w microwave output power is set at a high degree (200~2000. 〇=^3 main ^ dielectric constant is high, The heating time is short, the processing temperature is selected according to the basis, and the gas passing speed can be reduced, and the catalytic effect is "^ 4 201226044. The exhaust gas treatment of the invention The process is as follows: The organic waste gas generated by the factory is sent to the reaction main tank (1) via the transfer line, and the mixed air and oxygen ratio of the intake flow are controlled on the other hand, and the temperature and humidity of the intake air are adjusted, as shown in the fourth figure. As shown, the conveying line 10 passes through the gas mixing tank (4) and the filter (5) successively, and is cooled by a cooling system (6), and finally conveyed into the reaction main tank (1); The magnetron (11) generates a microwave reaction in the main tank Q), performs a dichroic reaction, and a thermal reaction of the catalyst microwave, by reacting the radical, electron, and hole pairs in the main tank (1), and The catalyst microwave heat treatment effect completely gives the organic exhaust gas, harmless carbon dioxide and water vapor. The reaction is carried out by the relevant electronic components and computers. In the Sx preparation of the present invention, a photocatalyst/microwave carrier is formed by using iron oxide, cobalt nickel oxide, activated carbon, zeolite or the like of Neflon, Oxidation, and mixed ferroferric oxide, and g is filled in the high ^ In the organic gas magnetization heat treatment equipment, one increases the dielectric constant of the original filling carrier and increases the microwave effect; and the other uses the microwave energy generated by the magnetron to excite the catalyst such as zinc oxide and titanium dioxide to generate high energy free radicals and Electron and electric holes are used to treat organic gases in industrial waste gas, and thirdly, porous supports such as activated carbon and zeolite are used to increase the specific surface area and reaction rate, and the organic gas magnetization heat treatment equipment can be effectively produced. The tube generates non-free-irradiated microwave energy, which causes the target molecule to move by the conduction of ions and the rotation of the dipole, thereby causing destruction and decomposition of the target pollutant.卞Invented high-efficiency organic matter gas magnetization heat treatment equipment, in addition to energy-saving, energy loss, time-saving, no need to add any chemical oxides, and will not cause secondary pollution and other environmental advantages. In addition, the magnetization heat treatment technology is self-object The inside and outside, so there will be no surface effect, the problem and _ 'in line with safety and applicability', therefore, it can be expected to use iron oxides such as nano-oxidation, titanium dioxide, iron trioxide, etc. Cobalt-nickel oxide catalyst combined with magnetization heat treatment technology should have sufficient industrial availability and value in the treatment of organic gases in industrial waste gas. The specific effects that can be achieved by the present invention include: 1. Combining the latest processing technologies of nano photocatalyst and magnetized microwave, the organic industrial waste gas can be effectively and quickly decomposed. The present invention treats organic industrial waste gas to be harmed by high temperature and produces harmless secondary carbon and water vapor, and thus has many advantages such as short reaction time, low energy consumption, and no secondary pollution. 3. The invention has short reaction time, can make the reactor volume smaller than general processing equipment, and has simple assembly, low construction cost and low processing cost, and even small factories have the ability to install 201226044 to effectively reduce the low-cost business. economic burden. 4. The object of the invention can adjust the control exhaust gas to be sent into the multi-tube reaction main body (£) by the air inlet (2 2) of the reaction main body (2) in parallel or in series to increase the treatment amount or treatment of the exhaust gas. Flexible operation of efficiency. 5. The invention can improve the willingness of manufacturers to deal with organic air pollutants, and reduce the pollution and harm of industrial organic waste gas to the environment and the human body. The above is only a possible embodiment of the present invention. When the scope of the present invention is not limited thereto, the equivalent changes, modifications or replacements made by the invention, the drawings or the scope of the patent application should belong to the present case. The scope covered by the patent. BRIEF DESCRIPTION OF THE DRAWINGS The first diagram is a schematic diagram of the composition of the main tank of the reaction of the present invention. The main body of the reaction body of the present invention is a series of schematic diagrams. The three diagrams are the schematic diagrams of the tubes of the reaction body of the present invention. Schematic diagram of the apparatus of the present invention [Key element symbol description] 1 reaction main tank soil 1 magnetron 12 waveguide tube 2 reaction body 2 1 tube body 2 2 air inlet 2 3 exhaust port $ high dielectric constant composite carrier 4 Gas mixing tank 5 filter 6 cooling system