TW201225840A - Compositions containing identical polyamine salts of mixed anionic pesticides - Google Patents

Abstract

The present invention relates to a composition comprising a first salt, which contains a first ani-onic pesticide (A1) and a cationic polyamine (B), and a second salt, which contains a second anionic pesticide (A2) and a cationic polyamine (B), wherein both salts contain the same cati-onic polyamine (B), and wherein the cationic polyamine comprises at least two amino groups. It further relates to a method for preparing said comprising the step of contacting the first salt and the second salt. In addition, the invention relates to a method of combating harmful insects and/or phytopathogenic fungi, which comprises contacting plants, seed, soil or habitat of plants in or on which the harmful insects and/or phytopathogenic fungi are growing or may grow, plants, seed or soil to be protected from attack or infestation by said harmful insects and/or phy-topathogenic fungi with an effective amount of said composition. It also relates to a method of controlling undesired vegetation, which comprises allowing a herbicidal effective amount of said composition to act on plants, their habitat or on seed of said plants. Finally, the invention relates to seed comprising said composition.

Description

201225840 VI. Description of the Invention: [Technical Field] The present invention relates to a composition comprising a first salt comprising a first anionic pesticide (A1) and a cationic polyamine (B); and a second salt comprising a second anionic pesticide (A2) and a cationic polyamine (B), wherein both salts contain the same cationic polyamine (B), and wherein the cationic polyamine comprises at least two amine groups. It is further directed to a method of making the composition comprising the step of contacting the first salt with the second salt. Further, the present invention relates to a method for controlling harmful insects and/or phytopathogenic fungi, which comprises a plant, a seed, a soil or a plant habitat in which a harmful insect and/or a phytopathogenic fungus is growing or growable, Protecting plants, seeds or soil from attack or infestation by such harmful insects and/or phytopathogenic fungi with an effective amount of the composition. The invention is also directed to a method of controlling undesired vegetation comprising applying a herbicidally effective amount of the agrochemical formulation to the plant, its habitat, or the seeds of the plants. Finally, the invention relates to seeds comprising the composition. The preferred embodiments of the invention referred to below are to be understood as preferably being independent of each other or in combination with one another. [Prior Art] There are pesticides having a relatively high volatility, such as dicamba or 2,4_d, which contain a fun acid in the form of a free acid. This pesticide will drift to a higher degree, which will damage the dry crops (eg, soybeans) in nearby fields. Since most of the pesticides evaporate, 1 Γ Γ is effective. To avoid these problems, low volatility pesticides are considered. This phase is not only found in single-pesticide formulations, see also, 159869.doc 201225840 involves the formulation of at least two pesticides. Various salts of anionic pesticides are known to comprise cationic amine fluorinated compounds: US 4,405,531 and WO 97/24931 disclose various organic salts of glyphosate, for example, from ethylenediamine, diethylenediamine, and exo A salt prepared from propyl diamine, phenyldiamine or hexahydropyridine. EP 0 183 384 discloses a low volatile salt of dicamba, i.e. 2-(2-aminoethoxy)ethanolate. US 5,221,791 discloses amine alkyl pyrrolidone salts, such as dicamba, which comprise a pesticide of acidic hydrogen. EP 0 375 624 discloses low volatility amine salts of pesticides, wherein the amines are, for example, aminopropylmorpholine, jeffamine 8D-23, or 2,4,6-fluorene (didecylamino). Pending Patent Publication No. 9173368.3 discloses salts comprising anionic pesticides and various cationic polyamines. These amine salts of an anionic pesticide have several disadvantages: the starting material has a low boiling point of phase, which makes it difficult to handle (e.g., ethylenediamine Fp 117C). Although the volatility is lower than that of the free acid form of the pesticide, the residual volatility is still too high. The other problem is that the material is less active, and/or it has a degree of recombination in the water. This problem occurs especially with mixtures of pesticides (for example, deltas of different anionic pesticides). SUMMARY OF THE INVENTION The object of the present invention is to find a composition exhibiting at least two anions of low volatility 159869.doc 201225840. Such compositions should be readily available from inexpensive, easy-to-handle compounds, and the level of known compositions that are equivalent to the two-in-one system. Still another is to find a composition that allows for a high concentration of pesticide in the composition. ', the object is solved by a composition comprising a) a first salt comprising a first anionic pesticide (ai) and a cationic polyamine (8), and b) a second salt comprising a second anionic pesticide (A2) and a cationic polyamine (8), wherein both salts contain the same cationic polyamine (B), and wherein the cationic polyamine comprises at least two amine groups. [Embodiment] A compound of the term "salt". Yin will produce neutral salt ions. It is meant that the ratio of at least one anion and at least one cationic ion to cation is generally dependent on the ionic charge. In general, the salt dissociates into an anion when dissolved in water and the term "pesticide" is used within the meaning of the invention to describe one or more compounds which may be selected from the group consisting of free fungicides, insecticides, nematicides, herbicides and/or safeners or The population of growth regulators is preferably selected from the group consisting of fungicides, insecticides or herbicides, and is preferably selected from the group consisting of herbicides. Mixtures of two or more of the above categories may also be used. Those skilled in the art are familiar with such pesticides, which can be found, for example, in the pesticideicide manual, 15th Ed. (2009), The British Crop Protection Council, London. The first anionic pesticide and the second anionic pesticide may be selected from an anionic pesticide. The first anionic pesticide and the second anionic pesticide refer to different anionic pesticides. 159869.doc 201225840 Additional anionic pesticides may be present in the composition. Preferably, the first anion pesticide and the second anionic pesticide (A1) and (A2) are the only anionic pesticides present in the complex. The term "anionic pesticide" refers to a pesticide that exists in the form of an anion. Preferably, the anionic pesticide is a pesticide comprising protonatable hydrogen. More preferably, an anionic pesticide refers to a pesticide comprising a carboxylic acid, a thiocarbonic acid, a sulfonic acid, a sulfinic acid, a thiosulfonic acid or a phosphorous acid group, especially a carboxylic acid group. The above groups may be present in part in a neutral form, including protonatable hydrogen. Generally, an anion such as an anionic pesticide contains at least one anionic group. Preferably, the anionic pesticide comprises one or two anionic groups. Specifically, the anionic pesticide contains exactly one anionic group. An example of an anionic group is a carboxylate group (-C(0)0-)e. The above anionic group may be partially present in the formula (IV), including protonatable hydrogen. By way of example, t, the acid-lowering group may be partially present in the neutral form of the carboxylic acid (_C(0)0H). This is preferably the case τ in an aqueous composition in which the balance of the acid and the acid is preserved. Generally, an anion such as an anionic pesticide may contain a cationic group (e.g., an ammonium group) in addition to an anionic group. The amount of anionic groups should be higher than the number of cationic groups to ensure that the anionic pesticide can form a salt with the cationic polyamine (oxime). , ° appropriate and anionic pesticides. In the case where the name refers to an anionic pesticide or more, it means an anionic form of an anionic pesticide. For example, the anionic form of dicamba can be expressed by the following formula: 159869.doc 201225840

OMe as a further example 'An anionic form of glyphosate can be represented by one of the following formulas: at least one skilled in the art is known 'When an anionic pesticide is present in dissolved form, the functional group dissociates and thus the position of the anion can depend on, for example, PH . The acid dissociation constant PKa is usually 0.8 for the phosphonic acid (fim phGsph() nie acid), 2.3 for the slow acid, and 6 〇 for the s_d phosphonic acid, and In the case of an amine, it is u 〇. A suitable anionic pesticide herbicide comprising m acid, thiocarbonic acid, acid acid, thiophene or sulphite base, especially a slow acid group. An example is an aromatic acid herbicide comprising a carboxylic acid group, a phenoxycarboxylic acid herbicide or an organophosphorus herbicide. Suitable aromatic acid herbicides are benzoic acid herbicides, such as diflufenzopyr, naptalam, gram (chl〇rambe..., dicamba, 2,3,6-tris benzoic acid) (2,3,6-TBA), tricamba; pyrimidinyloxybenzoic acid herbicides, such as bispyribac, pyrimin bac; n-thio benzene A citric acid herbicide, such as pyrithi〇bac; a phthalic acid herbicide such as chlorthal; a pyridinium herbicide such as an aminopyralid, Clopyra丨id, 毕克烂159869.doc

S 201225840 (picl〇ram); quinoline carboxylic acid weeding! For example, quinci〇rac, quinmerac; or other aromatic acid herbicides such as amin〇CyCl〇Pyrachlor. Preferred are benzoic acid herbicides, especially dicamba. Suitable phenoxycarboxylic acid herbicides are phenoxyacetic acid herbicides, such as 4-chlorophenoxyacetic acid (4-CPA), (2,4-diphenoxy)acetic acid (2,4_D), (3) , 4_dichlorophenoxy)acetic acid (3,4-DA), MCPA (4-(4-a-o-tolyloxy)butyric acid), MCPA-thioethyl, (2,4,5 · Trichlorophenyloxy)acetic acid (2,4,5-T), the present oxybutyric acid herbicide, such as 4_cpb, 4-(2,4-dichlorophenoxy)butyric acid (2,4-DB) ), 4-(3,4-dichlorophenoxy)butyric acid (3,4_DB), 4-(4-chloro-o-phenoxy)butyric acid (MCPB), 4_(2,4,5_ Trisphenoxy)butyric acid (2,4,5-TB); phenoxypropionic acid herbicides such as cloprop, 2-(4-phenoxy)propionic acid (4_CPP) , 2,4-Dippropionic acid (dichlorprop), 2,4-dipropionic acid (dichlorprop-P), 4-(3,4-dioxagenoxy)butyric acid (3,4-DP), 2 , 4,5-propionic acid (fen〇pr0p), 2-methyl 4_propionic acid, refined 2-mercapto 4-propionic acid; aryloxyphenoxypropionic acid herbicide 'chlorhexidine' Chlorazifop), acetylidene acetyl ester (ei〇dinafop), 2-(4-(4-carbeneoxy) oxy)propionic acid (clofop), butyl safflower (eyhal〇f p), diclofop, fenoxaprop, fenoxaprop-p, fenthiaprop, fluazifop, fine Fipazifop_P, haloxyfop, fluorinated n, hal〇xyf〇pP, isoxapyrifop, metamefop, general Propaquizafop, quizalofop, serotonin 159869.doc 201225840 (quizalof〇pp), triflucymide (trif0p). Preferred are phenoxyacetic acid herbicides, especially MCPA. Suitable organophosphorus herbicides comprising a decanoic acid group are bialafos, glufosinate, glufosinate-P, glyphosate. Preferred is glyphosate. Other suitable herbicides comprising a carboxylic acid are pyridine herbicides comprising a carboxylic acid, such as a fluorine gas ratio (fluroxypyr), a triclopyr, and a di-salt comprising a carboxylic acid. dense. Herbicides, such as glysamine (cl〇ransulam); containing tickling mouth β 定 基 醯 urea herbicides, such as bensulfuron (bensulfuron), chlorimuron, chloramine Foramsulfuron, halosulfuron, mesosulfuron, primisulfuron, sulfometuron; beta-salinone herbicide, such as beta-ricinic acid ( Imazamethabenz), Imazamox, Imazamox, Imazaric, Imazapyr, Imazaquin and Imazethapyr; Triazolinone weeding Agents such as flucarbazone, propoxycarbazone and. Thiencarbazone; aromatic herbicides such as acifluorfen, bifenox, carfentrazone, flufenpyr, flumiclorac, B Fluorine 1 &| (fluoroglycofen), phoracetate, lactofen, pyraflufen. In addition, other herbicides containing carboxylic acids may be mentioned as chlorflurenol, dalapon, endothal, flamprop, flamprop-M, fluorine. Propionic acid 159869.doc -10-

S 201225840 (flupropanate), propylene (fiuren〇l), oleic acid, citric acid, TCA. Suitable are anionic pesticide fungicides comprising a carboxylic acid, a thiocarbonic acid, a sulfonic acid, a sulfinic acid, a thiosulfonic acid or a phosphorous acid group, especially a carboxylic acid group. An example is a fungicide (p〇ly0xin) fungicide, such as polyoxorim. Suitable anionic pesticide insecticide comprising carboxylic acid, thiocarbonic acid, sulfinic acid, sulfinic acid, thio a sulfonic acid or phosphorous acid group, especially a carboxylic acid group. The example is thuringiensin. Suitable are anionic pesticide plant growth regulators comprising a carboxylic acid, a thiocarbonic acid 'sulfonic acid, a sulfinic acid, a thiosulfonic acid or a phosphorous acid group, especially a carboxylic acid group. Examples are 1 - naphthylacetic acid, (2-naphthyloxy)acetic acid, ruthenium-3-ylacetic acid 4_吲°wood-3_butyric acid, glyphosine, jasmonic acid, and 2,3,5_triiodobenzoic acid, pr〇hexadi〇ne, trinexapac, preferably cyclized acid and trinexapac. The preferred anionic pesticide-based anionic herbicide is more preferably dicamba, glyphosate, 2,4-D, chloramine-based acid, ciprofloxacin and McpA. It is better to use dicamba and glyphosate H, and dicamba is better. In the preferred embodiment, '2, 4' is preferred. In another preferred embodiment, glyphosate is preferred. In another preferred embodiment, McpA is preferred. In a preferred embodiment, the first anionic pesticide (4) is an anionic pesticide (pesticide hydrazine) in which all anionic groups are selected from - or polycaprylate quinone. More preferably, the first anionic pesticide comprises - an "ionic group (which is a carboxylate group), or it comprises two anionic groups, a B-burst group (one of which is a carboxylate group). Specifically, anionic pesticides contain exactly one anionic base map, 159869.doc • 11 · 201225840, which is a carboxylate group. When all of the anionic groups of the first anionic pesticide are selected from - or a plurality of acid groups (tetra), the - anionic pesticide contains no anionic groups other than the (tetra) group. For example, it does not contain sulphuric acid, acid, rhodium, thioate or phosphonate groups. The following description of the suitable pesticide Al〇 means the anionic form of the pesticide in the case where the name refers to the neutral form or salt of the pesticide. Preferred pesticide (10) herbicides such as aromatic acid herbicides or phenoxy acid herbicides. The preferred herbicides are the gram grass, gram gram, keke grass, gas methyl phthalic acid, dicamba, 2,4 dichlorophenoxy) acetic acid (2, 4d), 4 gas o-tolyloxy ) Butyric acid (MCPA), 4_(4_gas_o-tolyloxy)butyric acid (MCPB), 2,4-d-propionic acid, refined 2,4-d-propionic acid '2-methyl·4-propionic acid , fine 2-mercapto-4 gas propionic acid, fluorine gas ratio, trichlorobenzene ratio. Suitable aromatic acid herbicides are stupid formic acid herbicides, such as gram rest, wheat straw, '2,3,6-triseobenzoic acid (2,3,6_τβα), herbicide; shouting oxybenzoic acid Herbicides 'eg bispyribyl ether, pyrimethanil; pyrimidinyl thiobenzoic acid herbicides, such as pyrimethanil; phthalic acid herbicides, such as gram grass 'picolinic acid herbicides, such as amidinopyridine Acid, bek grass, gram gram; quinoline carboxylic acid herbicides such as keke grass, gas quinolinic acid; or other aromatic acid herbicides, such as cyprodinil. Preferred are benzoic acid herbicides, especially dicamba. - Suitable phenoxy-rebel herbicides are phenoxyacetic acid herbicides, such as heart phenoxyacetic acid (4_CPA) '(2,4-dichlorophenoxy)acetic acid (2,4-D), (3 4_ Dioxophenoxy)acetic acid (3,4, octane (4_(4_气_o-tolyloxy)') 159869.doc

S •12- 201225840 acid), herbicide, (2,4,5-trisphenoxy)acetic acid (2,4,5-T); phenoxybutyric acid herbicides such as 4-CPB, 4 -(2,4-dichlorophenoxy)butyric acid (2,4_ DB), 4-(3,4-diphenoxy)butyric acid (3,4_DB), 4_(4_gas_o-toluene Oxy)butyric acid (MCPB), 4-(2,4,5-trisphenoxy)butyric acid (2,4,5-TB); phenoxypropionic acid herbicides, such as fruit acid, 2_(4_gasphenoxy)propionic acid CPP), 2,4-D-propionic acid, 2,4-dpropionic acid, 4_(3,4_diphenoxy)butyric acid (3,4- DP), 2,4,5-iperic acid, 2·mercapto_4 alkanoic acid, refined 2_methyl_4 chloropropionic acid; aryloxyphenoxypropionic acid herbicides, such as qiheling , clodinafop, 2-(4-(4-phenoxy)phenoxy)propionic acid, butyl safflower, grass stalk, sedge grass, fine chewing grass, sage Spiritual acid " is better than saying grass grass spirit, fine money grass grass spirit, chaos and spirit, fine fluorine, and spirit. The grass screams, the scorpion sulphate, the pupa, the scorpion, the scent, the scent, and the three qi. Preferred are phenoxyacetic acid herbicides, especially McpA. Containing "other suitable herbicides" (4) herbicides, such as gas-to-gas ratio 'trichloro-chloride ratio; containing (iv) three saliva and (iv) herbicides, oxalic acid; (10) continuation of urea herbicides containing tannic acid, for example Free of ice., Qi «Long, A brewing amine, Long, He Xiaolong, methylsulfuron-methyl, sulfuron-methyl. The κ degree is suitable for other pesticide A1 fungicides, for example (for example, polyoxomycin). For example, granulomycin fungicides, other suitable pesticides, A1 insecticides, such as sulindac, suitable anionic pesticides, plant growth regulators,: (2-^ ϋ a \ ^ j such as I-naphthylacetic acid, 2Qinyloxy)acetic acid, ·3_yl acetic acid phosphonium, 芏-can 5 丨木-3-ylbutyric acid, manned guanidine, 2,3,5-triiodobenzoic acid, Zhouhua brewing, anti- Pour the ester, its i59869.doc -13- 201225840 is better to adjust the cyclic acid and the anti-pour ester. The best agricultural music A1 is dicamba, 2,4_d, chloraminopyridinic acid, cyclopropyl:: fixed acid and MCPA The preferred one is dicamba. In another preferred embodiment, '4 D is preferred. In another preferred embodiment, Ni is preferred. * The preferred embodiment is 'the third anionic pesticide (A2) An anionic drug wherein at least one anionic group of the anionic pesticide is selected from one or more phosphonate groups (pesticide A2). Preferably, the herbicide herbicide comprises at least one anionic group of the herbicide selected from - or A plurality of phosphonate groups. Examples are institutional herbicides comprising a tickic acid group. Suitable organophosphorus herbicides comprising an acid group are bianafos, glufosinate, glufosinate- p, glyphosate. Preferred pesticide A2 is glyphosate. Preferably, the first anionic pesticide (A1) contains a carboxylic acid group, and the second anionic pesticide (A2) contains a phosphonate group. More preferably 'The first-anionic pesticide-based aromatic acid herbicide or phenoxy acid herbicide' and the: anionic pesticide system comprising a „group of the herbicidal second anion agrochemical pyridine acid in another preferred embodiment The first anionic pesticide and the drug are selected from the group consisting of dicamba, kuk grass, glyphosate, 2,4_d ' and MCPP. For example, the anionic pesticide and the second anionic pesticide are dicamba and glyphosate, 2, 4_ 〇 and dicamba, dicamba and ^ ' 2'4-D and MCPP or 2, 4_0 and glyphosate. In a preferred form, the first anionic pesticide and the second anionic pesticide are selected from the group consisting of dicamba and grass scales The sum of the first anionic pesticide and the second anionic pesticide (for example selected from dicamba and glyphosate) and the sum of the cationic polyamine (B) (for example, B1 or Bi 2) 159869.doc

The Mobi ratio of S 201225840 is usually 1:10 to 1〇:1, preferably i 3:1 to 1〇:1, better! η Specifically... to the 3:1 range. The molar ratio may depend on "how many. For example, it is common to include a negative charge per mole - a molar anionic pesticide combined with a positively charged cationic polyamine per mole. Preferably When the salt is at 2 〇t>c with 2 of _ in water, the anion pesticide and the eucalyptus with a molar ratio of 6.5 to 9.0 are preferably 7.0 to 8. "Polyamine" is within the meaning of the invention with respect to organic compounds comprising at least two amine groups (e.g., primary, secondary or tertiary amine groups). The term "cationic polyamine" refers to a polyamine that exists in the form of a cation. Preferably, at least one of the cationic cations is present in the cationic polyamine, such as R-N+H3, R2_n+H2 or R"N+H. When such as (Bj), (4), (4) or (B4) When the formula shows a neutral formula, its Μ is its cation form (ie, the cation form of the amine system (4): in, for example, R-N+H3, R2-N+H2 or R3-N+H) For example, the cationic form of Bi i can be represented by at least one of the following formulas: · Η3Ν+~Ν~^νη2 H〆VV, νη2 For example, the cation form of Β1.2 can be represented by the following formula. For example, the cation form of Β1.6 can be represented by the following formula: Η ΗΗ 2 h2N*x^/N:^\KILJ £ :: at least one of the tables 159869 .doc • 15-201225840

The expert knows which of the preferred protonated cationic polyamines is based on, for example, PH or physical form. In aqueous solution, the basicity of the amine group of the cationic polyamine is generally gradually increased from the tertiary amine to the primary amine to the secondary amine. Preferably 'cationic polyamine (B) is a compound of formula (B1)

(B1) wherein R, R, R4, R6 and R7 are independently H or, as the case may be, CVCV alkyl substituted by 〇H, R3 and R5 are independently C2-C丨〇-alkylene X-ray OH or NR6R7, And η is 1 to 20; or ((2)

(Β2) wherein R10 and R11 are independently alkyl, R12 is Ci-C丨2-extension, and R13 is an aliphatic Cs-C8 ring system comprising nitrogen in the ring or at least one unit thereof NR1qr&quot ; replaced. In one embodiment, the cationic polyamine has the formula

159869.doc 201225840 wherein R, R2, R4, 尺6 and R7 are independently H or, as the case may be, a CrC6-alkyl group substituted by 〇h, R3 and R5 are independently C2_Ciq-alkylene, anthracene 〇h or NR6R7 And n is 1 to 20. R1, R2, r4, ultra 6 and r7 are preferably independently fluorene or fluorenyl. Preferably, Ri, R2, R6 & Rq^, H. The ruler 6 and the ruler 7 are preferably the same as R1 and r2, respectively. R3&r5 are preferably independently CVC4-alkylene, and are independently C2-C3-alkyl, such as ethyl (-CH2CH2-) or n-propyl (-CH2CH2CH2-). Usually, it is the same as R5. R3 and r5 may be straight or branched, unsubstituted or substituted by halogen. Preferably, the rulers 3 and R5 are straight keys. Preferably, R3 and R5 are unsubstituted. X is preferably NR6R7. Preferably, the η series 1 to 10 ′ is more preferably 1 to 6, especially 1 to 4 ^ in another preferred embodiment, η is 2 to 10. Preferably, ri, R2, r4, R6 and R7 are independently H or methyl, and R3 and R5 are independently ((alkyl), hydrazine H or NR6R7, and η is 1 to 10. The group X is bonded to R5 ', which is a C2-C1()-alkylene group. This means that X can be bonded to any carbon atom of the CrC丨〇-extension group. The example of the unit _r5_x is _^^2_ CH2-CH2-OH or -ch2-ch(oh)-ch3. R1, R2, R4, R6, R7 are independently Η or C1-C6·house groups substituted by 〇H, as appropriate. (β 1.9), wherein R 4 is hydrazine or a Ci-CV alkyl group substituted by hydrazine (more specifically, ' R 4 is a C3-alkyl group substituted by hydrazine). Preferably, R 1 , R 2 , R 4 , R 6 R7 is independently H or CVC6-alkyl. In another preferred embodiment, the cationic polymer of formula (B1) does not contain an ether group (-〇-). It is known that ether groups enhance photochemical degradation. Thus, an explosive radical or a peroxy group is produced. I59869.doc -17- 201225840 An example of a cationic polyamine of the formula (B1) (wherein X-based NR6R7) is di-ethyltriamine (DETA, (B4)' k=l, corresponding to (Β1·1)), tri-ethyltetramine (ΤΕΤΑ, (Β4) 'where k=2), four Ethyl pentamine (ΤΕρΑ, (Β4), where k=3). The technical quality of ΤΕΤΑ is usually in addition to the linear TETA as the main component, which also contains 叁-aminoethylamine TAE A, N-hexaazaguanine. Mixture of Phenyl Ethyl Ethyldiamine PEED A and Diaminoethyl Hexahydrogen to D Qin DAEP. The technical quality of hydrazine is usually in addition to the direct bond of the main component and also contains aminoethyl hydrazine - Aminoethylamine oxime-oxime, aminoethyldiaminoethylhexahydrola1*Qin AE-DAEP and aminoethylhexahydro. Mixture of acetamidoethylamine AE-PEEDA Ethylamine can be purchased from d〇w Chemical Co. Other examples are pentadecyldiethylidene PMDETA (B1.3), N,N,N,,N",N"-quinone-di Propyltriamine (B1.4) (available as jeffcat® ZR_4〇), cycline (3-didecylaminopropyl)-N-isopropanolamine (available as jeffcat 9ZR-50), N,-〇(dimethylamino)propyl)-N,N-dimethyl-i,3-propanediamine (B1.5) (available as Jeffcat® Z-130) and N,N- Bis(3-aminopropyl) amidoxime (B1.2). Especially preferred (Β4) (where k 1 to 1〇), (B1.2), (B1 4) and (B1 5). Most preferred system (B4) (where k lines 2, 3 or 4) and (B1.2). Specifically, preferred are (B 1.1) and (Βΐ·2). In yet another preferred embodiment, the cationic polyamine system (Β 1.1) » in yet another preferred embodiment, a cationic polyamine system (Β丨·2).

(Β4) 159869.doc 201225840 Η I I η2ν^^ν^^ΝΗζ (Β1·1) (B1.2) I (B1.3) 1

An example of a polyamine of the formula (Bl) wherein x is 0H is ν·(3-dimethylaminopropyl)-indole, Ν·diisopropanolamine dpa (Β1.9), hydrazine, hydrazine, Ν,-trimethylaminoethyl·ethanolamine (Β1·7) (available as jeffcat® ζ-110), aminopropyl monomethylethanolamine oxime (B1.8) and aminoethylethanolamine aeea ( B1.6). Especially good (B 1.6).

(B1.6) 丄

(B1.8) OH

In another embodiment, the cationic polyamine has the formula (B2) R1

, R 12 13

R 11 (B2) wherein Ri and Ri are independently H or C丨·c6•alkyl, the caliper is C2_Ci2_alkyl, and R13 is an aliphatic Cs-C8 ring system which contains nitrogen in the ring or It is replaced by at least one unit NR10Rn. R10 and R11 are preferably independently a hydrazine or a methyl group, more preferably H. The unit q-c of RlG and R11: 6-alkyl group is usually straight-chain or branched, unsubstituted or substituted by halogen. Preferably, the units Ci_C6_alkyl of R1G and R11 are unsubstituted and linear. More preferably, R1G is the same as R11. R12 is preferably a CVC4-alkylene group such as an extended ethyl group (/ηκΗ2·) or a forward stretching propyl group (-ChCH/H2·). R12 may be linear or branched, preferably 159869.doc • 19· 201225840 straight chain. R 彳 not, 35 substituted or (tetra) substituted, preferably it is immortal. , R13 is an aliphatic Cs-C8 ring system which contains nitrogen or a complex of at least one unit NR1〇R" in the ring. Preferably, R13 is an aliphatic C"c8 ring system which contains nitrogen in the ring. The q-C8 ring system may be unsubstituted or substituted with at least one qc:6 alkyl or at least one halogen. Preferably, c5_C8 The ring system is unsubstituted or substituted with at least one Ci_C4 alkyl group. An example of an aliphatic Cs-C8 ring system containing nitrogen in the ring is hexahydropyrazinyl. An example of an RU as an aliphatic C8 ring system and containing nitrogen in the ring. A compound of the formula (B2丨丨^ and (B2.12). A compound which is substituted with at least one mono-tgNRWr11 as an aliphatic CrQ ring system is a compound of the following formula (B2 1〇). More preferably, R10 and R11 is independently: _5 or methyl, Rn is C2_C3 alkyl, and R13 is an aliphatic Cs-C8 ring system which contains nitrogen in the ring. In another preferred embodiment, formula (B2) The cationic polymer does not contain an ether group (_〇_).

The cationic polyamine of the formula (B2) is isophoronediamine IspA (B2.10), the aminoethylhexahydrogen alpha 嘻AEp(7) (1) and the thiol-4-(2^methylamino) Base) hexahydropyrazine TAP (Β 2.12). These compounds are self-contained

Purchased by Huntsman or Dow, USA. Preferred are (Β2·ι〇) and (B2.il), and more preferred (B2.ll). In another embodiment, (B211) and (B2 12) are preferred.

(B2.10) (B2.11) (B2.12) In another preferred embodiment, the 'cationic polyamine system (B 1 ·2), (B 1.5)

159869.doc • 20- S 201225840 or a compound of formula (B2). The cationic polyamines of the formulae (B1), (Β2) and (Β4) can be obtained or purchased by known methods. The invention also relates to a process for the preparation of a composition of the invention which comprises the step of contacting a first salt with a second salt. The first salt and the second salt may be combined individually or in combination with a salt in the form of its available formulations (e.g., 'dry or solid formulations and liquid formulations such as aqueous formulations). Preferably, the first salt is contacted with the second salt in water. Water can be removed after combining to separate the salts. The combination can be carried out at a usual temperature (for example, from 2 〇〇c to 1 〇 (rc, preferably 3 to 90 ° C.) The agrochemical composition can comprise at least one other pesticide. Other pesticides can be selected from free fungicides. a group consisting of an insecticide, a nematicide, a herbicide and/or a safener or a growth regulator, preferably selected from the group consisting of a fungicide, an insecticide or a herbicide, more preferably a herbicide. Other pesticides are oxazoline herbicides and triazine herbicides. Other pesticides are preferably free of anionic pesticides. The following list gives examples of pesticides that can be used for other pesticides. Other preferred pesticides from this list are not Anionic pesticides. • Examples of fungicides are: A) AZ 〇XyStr〇bin, 〇 胺 xystrobin, en_〇burin ), gas (4) xi〇 (flu〇xastr〇bin), kexinxin (kreS〇Xim_methyl), phenoxystrobin (met〇minostrobin), acesulfame (four) SaStr〇bin), n aerobic bacteria 〇xystr〇bin), Bai Kemin 159869.doc •21 · 201225840 (pyraclostrobin), 0 sit Pyramitostrobin, pyraoxystrobin, pyribencarb, trifloxystrobin and 2-(2-(3-(2,6-dichlorophenyl)-1- Methyl-allylaminooxymethyl)-phenyl)-2-decyloxyimido-N-indenyl-acetamide; B) Carboxylamamines - aniline: Ben Benalaxyl, benalaxyl-M, benodanil, bixafen 'boscalid', carboxin, fenfuram ), fenhexamid, fluolanil, furametpyr, iSOpyrazam, isotianU, kiralaxyl, annihilation Mepronil, metalaxyl, metalaxyl-M (mefenoxam), furanamide (ofurace), oxadixyl, oxycarboxin 'penflufen, penthiopyrad, sedaxane, tecloftalam, thifluzamide, tiadinil, 2-amino-4-indenyl Oxazol-5-carboxanilide, N-(3,4,5,-tris-biphenyl-2-yl)-3-difluoroindol-1-yl-1 Η-sitting-4-曱Indoleamine, N-(4'-trifluorodecylthiobiphenyl-2-yl)-3-difluoroindol-1-yl-1H-pyrazole-4-nonylamine and N-(2) -(l,3,3-trimethyl-butyl)-phenyl)-i,3-dimethyl-5-fluoro-1H-pyrazole-4-decylamine; : dimethomorph, flumorph, pyrimorph;

159869.doc -22. S 201225840 - Benzoic acid enriched amines: flumetover, fluopicolide, fluopyram, zoxamide; other rebellious Amines: carpropamid, dicyclomet, mandipropamid, oxytetracyclin, silthiofam and N-(6-decyloxy-pyridine-3 -yl)cyclopropanecarboxylic acid decylamine; C) azole-triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, to be Klee (difenoconazole), diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, care Flutriafol, hexaconazole, imibenconazole, ipcon azole, mete onazole, myelobutanil, oxpoconazole, Paclobutrazole, penc〇nazole, and propi Conazole), pr〇thioconazole, simeconazole, tebuconazole 'tetraconazole, triadimefon, triadimenol, sterile squat (triticonazole), uniconazole; - σ米β sitting class: cyazofamid, imazalil, pheasant -23- 159869.doc 201225840 seat (pefurazoate), poker pull (prochloraz ), 赛福座 (triflumizol); - stupid and 0 meters. Sitting class: benomyl, carbendazim, fuberidazole, thiabendazole; - others: ethaboxam, etridiazole, killing Ning (1^1116\32〇16) and 2-(4-gas-phenyl)-]^-[4-(3,4-dimethoxy-benyl)-iso- oxa 0--5- ]]-2-prop-2--fast-oxy-ethylamine; D) heterocyclic compound '0 ratio. Classification: fluazinam, pyrifenox, 3-[5-(4-a-phenyl)-2,3-dimethyl-isoxazol-3-yl]-pyridine , 3-[5-(4-indolyl-phenyl)-2,3-dimercaptoisoxazole-3-yl]pyridinium; ~ , ° categorization: bupirimate, match Cyprodinil, diflumetorim, fenarimol, ferimzone, mepanipyrim, nitrapyrin, nuarimol, 派美(pyrimethanil); - hexahydropyrazines: triforine; ° ratio p: dressing ° (fenpiclonil), defensive ning (fludioxonil); morphine: twelve lin (aldimorph ), dodemorph, carbendazim acetate, fenpropimorph, tridemorph; hexahydrogen ratio. Classification: phen prion (fenpr〇pidin); - dimethyl quinone imine: fluoroimid, prodone, proCymid〇ne, vinclozolin - Non-aromatic 5-membered heterocyclic ring: famoxadone, fenamidone, flutianil, octhiminone, 159869.doc -24- 201225840 (probenazole), 5-amino-2-isopropyl-3-oxo-4-o-indolephenyl-2,3-dihydro-pyrazole-1-thiocarboxylic acid S-allyl ester - Others: acibenzolar-S-methyl, ametoctradin, amisulbrom, anilazin, blasticidin- S), captafol, captan, chinomethionat, dazomet, debacarb, diclomezine, difenzoquat ), difenzoquat methylsulfate, fenoxanil, Folpet, oxolinic acid, piperalin, proquinazid ,hundred Pyroquilon, quinoxyfen, 11 m "triazoxide, tricyclazole, 2-butoxy-6-indol-3-propyl ketene-4-one, 5-gas-l-(4,6-dioxaoxy-pyrimidin-2-yl)-2-mercapto-1H-benzimidazole and 5-chloro-7-(4-methylhexahydro) ratio Pyridin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[l,5-a]pyrimidine; E) Amino phthalate- Thio and dithioamino phthalates: ferbam, mancozeb, maneb, metam, methasulphocarb, exempt Meiram, propineb, thiram, zineb, ziram; - amino phthalate · benthiavalicarb , etethofencarb, iprovalicarb, propamocarb, propamocarb hydrochlorid, 159869.doc -25- 201225840 fenlifenalate and Ν·(1-( 1-(4-Cyano-phenyl)ethylsulfonyl)-butan-2-yl)carbamic acid-(4-fluorophenyl) ester; F) Other active substances 胍 胍.胍 (guanid Ine), dodine, donin, guazatine, bis-octylamine acetate, imin〇ctadine, gram heat triacetate, gram-net hydrazine Continuation salt); -Antibiotics: kasugamycin, gibberellin hydrochloride hydrate, streptomycin, granulin, validamycin A; Phenyl derivatives: binapacryl, dinobuton, dinocap, Nitrothal-isopropyl, tecnazen, organometallic compound: triphenyltin Fentin salt 'such as fentin-acetate, fentin chloride or fentin hydroxide; _ sulfur-containing heterocyclic compound: nithia sulfur, dithianon, Isoprothiolane; _ organic dish compound: edifenphos, fosetyl, fosetyl-aluminum, iprobenfos, sub-acid and Its salt, pyrazophos, tolclofos-methyl; organic gas compounds: four different Chlorothalonil, dichlofluanid, dichlorophen, flusulfamide, hexachlorobenzene, pencycuron, pentachlorphenole and its salts, heat must

I59869.doc •26- S 201225840 phthalide, qUint〇zene, thiophanate-methyl, tolylfluanid, N-(4-gas- 2-Nitro-phenyl)_N-ethyl-4-indenyl-benzene-based amine; _Inorganic active material: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic sulfuric acid Copper, sulfur; - Others: biphenyl, bronopol, cyflufenamid, cymoxanil, diphenylamine, metrafenone, mildiomycin, fast Ning (xin-copper), prohexadione-calcium, spiroxamine, tebufloquin, methyl valproate, N-(cyclopropyl decyloxy Imino-(6--fluoro-methoxy-2,3-di-phenyl)methyl)_2-phenylacetamide, N'-(4-(4-gas-3-III) Fluorinyl-phenoxy)_2,5-didecyl-phenyl)-N-ethyl-N-methylformamidine, oxime, (4-(4-fluoro-3-trifluoromethyl) Phenoxy)-2,5-·monodecyl-benyl)-fluorenyl-ethyl-hydrazine-methylindole, ν'-(2 - indole 5-trifluoromethyl-4 -(3-tridecylfluorenyl-propoxy)-phenyl)_Ν_ethyl_Ν-methylformamidine, Ν'-(5-difluoromethyl-2-methyl-4-(3 - trimethyl sulphate-propoxy)-benzyl)-N-ethyl-N-indenyl oxime, i-[2_(5-methyl-3-trifluoromethyl-pyrazole-1- Base)-ethenyl]_hexahydropyridine_4_ylpyrrole. -4-carboxylic acid methyl-(1,2,3,4-tetraindole-naphthalen-1-yl)-decylamine, 2_{ι_[2_(5-fluorenyl-3-trifluoromethyl-pyrazole -1-yl)-ethinyl]-hexahydropyridine_4_ kibidine-4-carboxylic acid methyl-(R)-1,2,3,4-tetrahydro-naphthalene]-yl-decylamine, Methoxy-acetic acid 6-second-butyl-8-fluoro-2,3-didecyl-quinoline_4• base and A/·mercapto-2-{1-[(5·曱 base) -3-trifluoroindolyl 嗤_ι_yl)_ethinyl]-hexahydrogen ratio ° _4_yl}-#-[( 1 R)-l,2,3,4-tetrahydrogen蔡基]_4 159869.doc •27- 201225840 sighs squatting amines Examples of growth regulators are: abscisic acid, amidochlor, mouth < ancymidol, 6-benzylaminopurine, brassinoin (Hde), butralin, chl〇rmequat (kimezide hydrochloride), chlorination test, cyproterone Amine (CyClanjlide), daminozide, dikegulac, dimethipin, 2,6-dimercapto. Bipyridine, etheph〇n, flumetralin. husband. Milocol (fiurprimid〇i), oxalic acid, forchlorfenuron, gibberellic acid 'inabenfide', indole-3-acetic acid, malayan, mefluidide ), 1,1-dimercaptopurine (mepiqUat) (i, i-dimethyl 0-decane rust chloride), naphthaleneacetic acid, Ν_6·benzyl adenine, buckyrin-cyclin (adjusted) Ring acid feeding), propyl jasmonate (pr〇hydrojasmon), ° thidiazuron, bud suppression. Triapenthenol, tributyltrithiophosphonate, 2,3,5-di-benzoic acid, trinexapac_ethyl and mono- gram. Examples of herbicides are: - Ethylamine: acet〇chlor 'alachlor, butachlor, dimethachlor, dimethenamid &gt Flufenacete mefenacet, metolachlor, metazachlor, napropamide, naproanilide, pethoxamid 'Pretilachlor, propachlor'

159869.doc •28· S 201225840 thenylchlor; amino acid derivatives: biloba, glyphosate (eg glyphosate free acid glyphosate money salt, glyphosate isopropyl salt, Glyphosate trimethyl sulfonium salt glyphosate unloading salt, glyphosate dimethyl ship: gg, early tile foot 7 amine salt), glufosinate, sulfosate; aryloxy phenyloxy Acid esters: clodinafop, ethhai 〇f〇p-butyl, oxazolyl, flurazepam, flurizine, oxazolidin, pupa, quin Halin, quizol ester (quizal〇f〇p_p_ tefuryl); - guanidine: diquat, paraquat; - (thio) urethane: sub-stable (asulam), butylate, carbetamide, desmedipham, dimepiperate, eptam (EPTC), esprocarb, rice Molten, orbencarb, phenmedipham, prosulfocarb, pyributicarb, thiobencarb, triallate; Ketones: butylbenzene Butroxydim, clethodim, cycloxydim, pro foxy dim, s ethoxy dim, tepraloxydim, trimethoate (tralkoxydim); -dinitroaniline: benfluralin, ethalfluralin, oryzalin, pendimethalin, prodiamine, triptrine (trifluralin); -diphenyl ethers: acesulfame, aclonifen, bifenfen, 2-159869.doc -29- 201225840 [4(-2,4-chloroperoxy)ben Oxy]propionic acid, eth〇Xyfen, fomesafen, flufenacil, oxyfluorfen; -hydroxybenzonitrile: bromoxynil, two Dichibenbenil, ioxynil; -imidazolinone: imazamoic acid, imazamox, mezizide nicotinic acid, chlorpyrifos, beta rice salivary acid, glutinous rice Smoke; - phenoxyacetic acid: clomeprop (clomeprop), 2,4-diphenoxyacetic acid (2,4-D), 2,4-DB, 2,4-D-propionic acid, MCPA, off Grass, MCPB, 2·mercapto-4 chloropropionic acid; -0 azines: chloridazone, fiufenpyr-ethyl, oxalic acid, norflurazone, pyridate; -pyridine: amidinopyridine , chlorfenapyr, diflufenican, dithiopyr, fluridone, fluorine gas ratio, gram gram, picolinafen, tilapidine Thiazopyr); -Bearing veins: brewing ° amy sulfur (amidosulfuron), four ° sitting ° azimutur (azimsulfuron), speed-free, ethyl gas sullen, chlorsulfuron, sulphur (cinosulfuron), cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, H ° flupyrsulfuron, methotrex , Hessian sulphide, imazosulfuron, iodosulfuron, methyl disulfide, diether chloride, ratio of rhetazosulfur〇nj, methyl hydrazine 159869.doc -30-

S 201225840 (metsulfuron-methyl), nicosulfuron, oxasulfuron, fluorosulfonon, prosulfuron, pyrazosulfuron, rimsulfuron ), Jilong, Jiyu sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, fluorinated amine (triflusulfuron), tritosulfuron, 1-((2-chloro-6-propyl-flavored "sitting and [l,2-b]哒D--3-yl) continuation base) -3-(4,6·dimethoxy-cheet-2-yl) gland, - triterpenoids: ametryn, atrazine, cyanazine, isoprene Dimethametryn, ethiozin, hexazinone, metamitron, metribuzin, prometryn, simazine , terbuthylazine, terbutryn, triaziflam; -urea: chlorotoluron, daimuron, diyou (diuro) n), fluometuron, isoproturon, linuron, methabenzthiazuron, tebuthiuron; - other acetamidine lactase synthase inhibitors : Bispyribac-sodium, Chlorine S, cloransulam·methyl, diclosulam, florasulam, fluoroketone, and 0-point performance Flumetsulam, metasulam, ortho-sulfamuron, penoxsulam, propyl phenanthrene, pyribambenz-propyl, shouting Grass 159869.doc -31 - 201225840 (pyribenzoxim), pyrifalid, pyrimiminobac-methyl, pyrimisulfan, pyrimethanil, pyrocene Pyroxasulfone), methoxysulfachlor (pyr〇xsuiam); - others: amicarbazone, aminotriazole, anilofos, beflubutamid, benzallin ), bencarbazone, benfuresate, benzofenap, bedalong Ntazone), benzobicyclon's double ring. Bicyclopyrone, bromacil, bromobutide, butafenacil, butamifos, <» cafenstrole, gram grass, ketoxime (cinidon-ethlyl), clematis, cinmethylin, clomazone, cumyluron, cyprosulfamide, dicamba, wild swallow, two gas 0 bili, breech (Drechslera monoceras), bacterium, killing (ethofumesate) acetophene (etobenzanid), different. Benzosulfone, four. Sitting on fentrazamide, flumiclorac-pentyl, flumioxazin, fluoride < Sit (flupoxam), fluoxetine, flurtamone, indanofan, isoxaben, isoxaflutole, lenacil ), propanil, propyzamide, kekegrass, methotrexate, mesotrione, decyl decanoic acid, naproxene, propane oxacillin ( Oxadiargyl), oxadiazon, oxaziclomefone, pentoxazone, squat

159869.doc •32- S 201225840 pinoxaden, oxazolidine (pyraci〇n(1), pyraflufen-ethyl, pyrosuifot〇ie, puffin ( Pyrazoxyfen), pyrazolynate, quinoclamine, safiufenacil, sulcotrione, sulfentrazone, terbacil, terfusan _ (tefuryltrione), cycline _ (tembotrione), thixopine, benzopyrazone (t〇pramezone), [2-gas-4-ran-5-(3 -mercapto-2,6-two-side Oxy-4-tris-methyl-3,6-dihydro-2H-pyrimidin-1-yl)-phenoxy]-n ratio ate-2-yloxy)-ethyl acetate, 6- Amino-5-chloro-2-cyclopropyl-pyrimidine-4-decanoic acid methyl ester, 6-gas-3-(2-cyclopropyl-6-methyl-phenoxy)-purine-4- Alcohol, 4-amino-3- gas-6-(4-a-phenyl)_5-fluoro-. Bis-pyridine-2-decanoic acid, 4-amino-3-gas-6-(4-carb-2-fluoro-3-indolyloxy-phenyl)-pyridine-2-carboxylic acid decyl ester, and 4-amine Methyl-3-gas-6-(4-carb-3-didecylamino-2-fluoro-phenyl)-pyridine-2-carboxylate. Examples of insecticides are: • Organic (thio) acid vinegars such as acephate, azamethiphos, azinphos-methyl, chlorpyrifos, thiodoniasone (chlorpyrifos-methyl), chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, acesulfame (ethion), fenitrothion, fenthion, isoxathion, marathion, methamidophos, methidathion, methyl-parathion , Mei Wensong 159869.doc 33- 201225840 (mevinphos), monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, yu Phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, sulphur Pine (prothiofos), killing Sulprophos, tetrachlorvinphos, terbufos, triazophos, trichlorfon; - amino phthalates: alanycarb, dexamethasone Aldicarb), bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, 吱钱威Furathiocarb), metiocarb, methomyl, oxamyl 'pirimicarb, propoxur, thiodicarb, triazamate - pyrethroids: allethrin, bifenthrin, cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, Alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, efenine Etofenprox) 'Fenpropathin, fenvalerate, eptune (im Iprothrin), lambda-cyhalothrin, permethrin, prallethrin, pyrethrin 159869.doc -34- 201225840 (pyrethrin) I and II, resmethrin , silafluofen, tau_nuvaiinate,; tfluthrin, tetramethrin, trolomethrin, transfluthrin, fenfluthrin (profluthrin), diinefluthrin; - insect growth regulator: a) chitin synthesis inhibitor: benzoic acid urea: chlorfluazuron, cyramazin, two Diflubenzuron, fiUCyCi〇xuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, Tripulfezin; buprofezin, diofenolan, hexythiazox, etoxaz〇ie, clofentazine; b) ecdysone antagonism Agent: hafenofozide, methoxyfenozide, defenofol (tebufenozide), azadirachtin; c) juveniles: pyriproxyfen, metoprene, fenoxycarb; d) lipid biosynthesis inhibitors: Spirodiclofen, Spiromesifen, spirotetramat; - Nicotinic receptor agonist/antagonist compounds: clothianidin, dinotefuran, eddaramine Imidacloprid), thiamethoxam, nitenpyram, acetamiprid, thiacloprid, 1-(2-chloro-β plug-5-yl 159869.doc -35- 201225840 曱-)-2-nitroimino-3,5-dimethyl-[1,3,5]hydrotriazine; -GABA antagonist compound: endosulfan, espo (ethiprole), Hpronil, vaniliprole 'pyrfluprole'. Pyriprole, 5-amino-l-(2,6-dichloro-4-indolyl-phenyl)-4-amine sulfinyl-1H-pyrazole-3-indole sulfur Indoleamine; - macrolide insecticide: abba (inden), emmectin, milbemectin, lepimectin, spinosad, Spinetoram; - Mitochondrial Electron Transfer Inhibitor (METI) I Acaricide: Fenazaquin, Pyridaben, Tebufenpyrad, Tolfenpyrad ' 〇 Flufenerim; -METI II and III compounds: acequinocyl, fluacyprim and hydramethylnon; - uncoupling agent: chlorfenapyr; - oxidative filling Acidification inhibitors: cyhexatin, diafenthiuron, fenbutatin oxide, propargite; - acute interfering compound: cyromazine; - mixing function Oxidase inhibitor: piperonyl butoxide; - sodium channel blocker: indoxacarb, metaflumizone; other: iso-parasite. Sitting (benclothiaz), bifenazate, cartap, flonicamid, pyridalyl, pie

159869.doc -36- S 201225840 pymetrozine, thiazole, thi〇CyClain, flubendiamide, chlorantraniliprole, cyazypyr (HGW86), Cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet, imicyafos, bistrifluron and fluoride Pyriquinquina (pyrifluquinazon). The compositions of the invention are suitable for use as herbicides. It is suitably employed in such a state or as a suitable formulated composition. The compositions of the present invention are extremely effective in controlling vegetation on non-crop areas, particularly at high application rates. It is used to combat broadleaf weeds and grass weeds in crops such as wheat, glutinous rice, corn, soybeans and cotton without causing any significant damage to crop plants. This effect is mainly observed at low application rates. Depending on the method of application, the compositions of the invention may additionally be used in many other crop plants to remove undesirable plants. Examples of suitable crops are as follows: Onium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Avena sativa, Beta vulgaris spec, altissima , "Beta vulgaris spec, rapa" 'Brassica napus (former variant KBrassica napus var napus), Brassica napus var. napobrassica, Brassica rapa var. silvestris, Brassica oleracea, Brassica nigra, Brassica juncea, Brassica campestris, Camellia sinensis, Carthamus tinctorius, American bonito 6carya illinoinensis, lemon 159869.doc -37- 201225840 (Citrus limon), Citrus sinensis, Coffea arabica (c〇ffea canephora, Coffea liberica), Cucumis sativus, Bermudagrass ( Cynodon dactylon), wild carrot (Daucus carota), oil palm (Elaeis guineensis), white flower per (Fragaria vesca) 'large Glycine max, Gossypium hirsutum (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus 'Hevea brasiliensis , Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, genus (Malus spec.), cassava (Manihot esculenta), Medicago sativa, Musa spec, Nicotiana tabacum (N.rustica), Olea (Olea) Europaea), Uplanda s'ativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spec, Pistacia vera, Kidney Bean (Pisum sativum), European sweet cherry (Prunus avium), peach (Prunus persica), Pyrus communis, Prunus armeniaca, Prunus cerasus, Prunus dulcis and prunus domestica, Ribes sylvestre, Ricinus communis, Saccharum officinarum, Secale cereale, Sinapis alba, common Potato (Solanum 159869.doc -38- s 201225840 tuberosum), Sorghum bic〇l〇r (svulgare), Theobroma cacao, Trifium pratense, Wheat (Tdticum aestivum), Triticale, Triticum dUrum, Vicia faba, Grape (7) 仏vinifera, Zea mays. Preferred crops are: groundnut, sugar crop beet, Brassica napus (original variety), cabbage, fennel, lemon, sweet orange, small fruit coffee (medium coffee, big fruit coffee), Bermuda root, soybean, land Cotton (tree cotton, cotton wool, kapok), sunflower, barley, walnut, lentils, common flax, Fanyou, Freundea, Alfalfa, Artemisia scoparia (Huanghua Tobacco), oil withdrawal, dry rice, white bean, kidney bean , pistachio, peas, almonds, ginseng, rye, common potatoes, sorghum (蜀黍), black wheat, wheat, durum wheat, stupid beans, grapes and corn. The compositions of the invention may also be used in genetically engineered plants, e.g., to alter traits or characteristics. The term "genetically engineered plant" is understood to mean that its genetic material has been recombined in a reconstituted technique plus (iv) it is not readily accessible by cross-breeding or genetic engineering. Tongtang lost _ 十' has integrated one or more genes into the genetically modified plant's remains #% stomach towel > a ή et al (4) ... ΓΓ good properties of the plant. The * ^ ^ (but not limited to) by, for example, glycosylation or polymer

: Targeted post-translational transformation of proteins, such as isoprene-ethylation, acetylation or farnesylation, which have been carried out by breeding, mutation, and specific types of weeding Plants which have been rendered tolerant to the agent) are particularly suitable for use with the compositions of the invention 159869.doc-39-201225840. Since conventional breeding methods or genetic engineering have developed tolerance to a wide variety of herbicides, such as auxin herbicides, such as dicamba or 2,4-D; pigment-inhibiting herbicides, such as transphenylene Pyruvate dioxygenase (HPPD) inhibitor or phytoene desaturase (PDS) inhibitor; acetaminolate lactase (ALS) inhibitor, such as sulfonylurea or imidazolinone; enol acetone oxime Shikimic acid 3-phosphate synthase (EPSP) inhibitors, such as glyphosate; glutamate synthase (GS) inhibitors, such as glufosinate; protoporphyrinogen-IX oxidase (PPO) inhibitors; lipids Biosynthesis inhibitors, such as acetylated CoA carboxylase (ACCase) inhibitors; or oxynil (i.e., bromoxynil or iodobenzonitrile) herbicides. In addition, plants have been resistant to multiple types of herbicides by multiple genetic modifications, such as resistance to glyphosate and glufosinate or glyphosate and herbicides from another species (eg, ALS inhibitors, HPPD inhibition) Agents, auxin inhibitors or ACCase inhibitors). Such herbicide resistant techniques are described, for example, in the following: Pest Management Science 61, 2005, 246, 61, 2005, 258, 61, 2005, 277, 61, 2005, 269, 61, 2005, 286, 64, 2008 , 326 '64, 2008, 332, Weed Science 5, 2009, 108, Australian Journal of Agricultural Research 58, 2007, 708 ' Science 316, 2007, 1185, and references cited therein. Examples of such herbicide resistant techniques are also described in the following: US 2008/0028482, US 2009/0029891 'WO 2007/143690 'WO 2010/080829, US 6307129, US 7022896, US 2008/0015110, US 7,632,985, US 7105724 and US 7381861, each of which is incorporated herein by reference. 159869.doc -40· 201225840 The herbicide has been given a variety of cultivated plants for the benefit of herbicides by conventional breeding (mutagenization) methods, such as Clearfield® summer rape (Can〇la, BASf SE, Germany) versus imidazolinone ( For example, imazamox) is tolerant, or

ExpressSun® Sunflower (DuPont, USA) is resistant to sulfonylureas (eg, fensulfuron). Genetic engineering methods have been used to impart herbicides (eg, soybean, cotton, corn, sugar beet, and canola) to herbicides (eg, Tolerance of glyphosate, dicamba, imidazolinone and glufosinate, some of which are in the development stage or may be trademark or trade name R〇undupReady® (resistant glyphosate, Monsanto, USA), Cultivance® (tolerance. Miprene, BASF SE, Germany) and LibertyLink® (Bayer CropScience, Germany) purchased p. Also included are plants that can synthesize the following products by using recombinant DNA technology. : one or more insecticidal proteins, especially known from Bacillus licheniformis, in particular from Bacillus thuringiensis (5 such as 7/like caffeine (4), eg a endotoxin, eg

CryIA (b), CrylA (4), CryIF, CryIF (a2), ^ state stick), CrylllA, CrylllB (bl) or Cry9c; plant insecticidal protein (νιρ), such as VIP i, VIP2, VIP3 or VIP3 A; fine 帛Insecticidal proteins of the genus Nematodes such as Phosphorus (Ph0t0rhabdus spp) or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxin, arachnid toxin, wasptoxin' or other insect-specific nerves Toxins; toxins produced by fungi, such as Strept〇myeete toxins, plant lectins (such as peas or barley lectins); lectins; protease inhibitors such as trypsin inhibitors, serine egg-white enzymes Inhibitor 'Patatin 159869.doc •41 · 201225840

(patatin), cysteine protease inhibitor or papain inhibitor; ribosome inactivating protein (RIP), such as dry toxin, corn _RIp, acacia toxin, loofah, 4 oxalin or different strains of thirst Protein (bry〇din); steroid metabolism enzymes, such as 3-hydroxy-steroidal oxidase, ecdysin_IDp_glycosyl-transferase, cholesterol oxidase, ecdysone inhibitor or HMG_c〇A·reductase; ion channel Blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptor (helic〇kinin receptor); stilbene synthase, bibenzyl synthase, chitinase Or glucanase. In the context of the present invention, such insecticidal proteins or toxins are to be expressly understood to be protoxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a new combination of protein domains (see, for example, W〇 02/015701). Other examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example, in ΕΡ·α 374 753, WO 93/007278, WO 95/34656, ΕΡ-Α 427 529, ΕΡ-Α 451 878 'WO Methods for producing such genetically engineered plants are generally known to those skilled in the art and are set forth, for example, in the publications mentioned above, in 〇 3/1881 〇 & W 〇 03/52073. These insecticidal proteins contained in genetically engineered plants can confer tolerance to pests from all taxa of arthropods, especially for beetles (c〇le〇ptera). Tolerance of two-winged insects (Diptera), and moths (Lepid〇ptera) and nematodes (Nematoda). Plants capable of synthesizing one or more insecticidal proteins are described, for example, in the above publication, and some of them are commercially available, such as YieldGard® (a corn cultivar producing CrylAb toxin) and YieldGard® Plus (creating CrylAb). And, 59869d〇C -42 s 201225840

Cry3Bbl toxin corn cultivar), Starlink® (Cry9c toxin-producing corn cultivar), Herculex® RW (producing Cry34Abl, Cry35Abl and enzymes Phosphinothricin·N-Acetyltransferase) [PAT Corn cultivar); NuCOTN® 33B (cotton cultivar producing CrylAc toxin), Bollgard® 1 (cotton cultivar producing CrylAc toxin), Bollgard® 11 (cotton cultivar producing CrylAc and Cry2Ab2 toxin); VIPCOT® (Viponic cultivars producing VIP-toxin); NewLeaf® (potato cultivar producing Cry3A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Btll from Syngenta Seeds SAS, France (eg , Agrisure® CB) and Btl76 (corn cultivar producing CrylAb toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (a modified form of corn cultivar producing Cry3A toxin, see WO 03/018810), from Monsanto Europe SA, Belgium's MON 863 (Cry3Bbl toxin-producing corn cultivar), from Monsanto Europe SA, Belg IPC 531 of ium (a cotton cultivar of improved form that produces CrylAc toxin) and 1507 (a corn cultivar producing Cry IF toxin and PAT enzyme) from Pioneer Overseas, Belgium. In addition, plants are also contemplated which can synthesize one or more proteins by recombinant DNA techniques to increase their resistance or tolerance to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenicity-related proteins" (PR proteins, see, for example, EP-A 392 225), plant resistance genes (for example, potato cultivars, which are used for 159869.doc-43 - 201225840 Resistance to wild potato from Mexico (solanum secret (5) Phytophthora infestans resistance gene) or τ4_ lysozyme (eg 'can synthesize such pairs such as A. sinensis amyl_ra A method for producing a genetically engineered plant such as "Hai" is generally known to those skilled in the art and is described, for example, in the above publication. It also includes plants that can be used to form a variety of proteins to increase the productivity of their plants (eg biomass production, grain yield, starch content, oil content or protein content) by using recombinant DNA technology, Salinity or other growth limiting environmental factors, or tolerance to pests and fungal, bacterial or viral pathogens. In addition, it also includes plants which utilize a recombinant DNA technique to contain a quantity of t-containing inclusions or new inclusions to enhance human or animal nutrition, for example, to produce healthy long-chain γ·3 fatty acids or unsaturated (9) Oil crops for fatty acids (eg Nexer, rapeseed 'D〇w Agr〇

Sciences, Canada) In addition, it also includes plants that specifically produce improved raw material production by using a recombinant DNA technique containing a number of S-modified inclusions or new inclusions, such as potatoes that produce an increase in the amount of amylopectin ( For example, Amfl〇ra® potato 'BASF SE, Germany). Furthermore, it has been found that the compositions of the invention are also suitable for shedding and/or drying of plant parts and are suitable for use in crop plants such as cotton, potato, canola, sunflower, soybean or cowpea (especially cotton). In this regard, it has been discovered that there are compositions for drying and/or exfoliating plants, methods for preparing such combinations 159869.doc 201225840, and methods for drying and/or shedding plants using the compositions of the present invention. As a desiccant, the compositions of the present invention are particularly useful for detaching the aerial parts of crop plants such as potatoes, canola, sunflower and soybeans, and loquat. This makes it possible to fully mechanize the harvesting of these important crop plants. Also of economic value are other species and varieties that are beneficial for harvesting citrus fruits, olives and pome fruits, stone fruits and nuts, which can be achieved by focusing the cracking on a certain period of time or reducing the adhesion to the tree. The same mechanism, i.e., promoting the formation of detached tissue between the plant fruit portion or the leaf portion and the stem portion, is also necessary for controlled shedding of useful plants, particularly cotton. In addition, shortening the time interval between individual cotton plant maturation can increase the quality of the fiber after harvest. The compositions of the invention are applied to plants primarily by spraying the leaves. Here, the amount of spray liquid of about 丨〇〇 1 / ha to 1000 l / ha (for example, 300 1/11 & to 4 〇〇 1 /ha) can be used, for example, water as a carrier by a conventional spraying technique. Apply. The herbicidal compositions can also be applied by low volume or ultra low volume methods or in the form of microparticulates. The herbicidal composition of the present invention can be applied before or after germination or applied with crop seeds. The compounds and compositions can also be applied by applying seeds of a crop plant pretreated with the composition of the invention. If certain crop plants are less tolerant to the active compound A&C and if appropriate, the application techniques of spraying the herbicidal composition by means of a spray device can be used, such that the herbicidal compositions are as unsuitable as possible Sensitive crop plants are in contact with the leaves, and the active compounds can reach the leaves or bare soil surfaces of the plants that are grown under the plants of the crops (after directional sprinkler irrigation, loose soil). In yet another embodiment, the compositions of the invention can be applied by treating the seed. The treatment essentially comprises all procedures well known to those skilled in the art based on the compositions of the invention (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multi-layer coating, seed coating, seed dripping and Seed pelletization)_. Here, the herbicidal composition can be applied with or without dilution. The term "seed" encompasses all types of seeds, for example, grains, seeds 'fruits, rhizomes, seedlings and the like. Here, preferably, the term "seed" describes sputum and seeds. The seed used may be a seed of a useful plant as described above, and a seed of a transgenic plant or a plant obtained by a conventional breeding method. The application rate of the active compound is from 0.0001 kg/ha to 3.0 kg/ha, preferably from 1 kg/ha to 1.〇kg/has substance (as), depending on the control target, season, target plant and Growth stage. For the treatment of seeds, the amount of pesticide used is usually 0.001 to 1 〇 kg / 1 〇〇 kg of seeds. Further preferably, the invention or composition can be applied alone or in combination with other crop safety agents, e.g., in combination with an agent for controlling pests or phytopathogenic fungi or bacteria or with a population of active compounds that modulate growth. Of particular interest is its miscibility with minerals and salt solutions used to treat nutritional deficiencies and trace element deficiencies. Non-phytotoxic oils and oil concentrates can also be added. The compositions of the present invention may also be converted into conventional types of agrochemical compositions such as baths, emulsions, suspensions, powders, powders, pastes and granules. The type of composition depends on the specific intended purpose; in each case, it should be ensured that the ration of the primaries is fine and evenly distributed. Examples of composition types are suspended 159869.doc

S •46· 201225840 Floating liquid (SC, OD, FS), emulsifiable concentrate (EC), emulsion (EW, EO ES), paste, soft lozenge, wettable powder or powder, SP SS 'WS 'DP, DS) or water soluble or wettable granules (GR, FG, GG, MG), and gel formulations (GF) for treating plant propagation materials such as seeds. Typically, the type of composition (eg, %, EC WG, SG, qing, SP, ss, ws, GF) is used after dilution. The type of composition (e.g., DP, DS, GR, FG, (10), and MG) is typically used without dilution. The compositions are prepared in a known manner. When the agrochemical group is a "raw composition, the salt of the present invention can be dissociated into anions and cations. The agrochemical composition may also contain adjuvants commonly used in agrochemical compositions. The auxiliaries used depend on the particular application form and the active substance. Examples of suitable auxiliaries, solvents, solid carriers, dispersants or emulsifiers (eg, 'additional agents, protective colloids, surfactants and adhesives), organic and inorganic enhancers, bactericides, An anti-stick agent, an antifoaming agent, (if appropriate) a coloring agent and a tackifier or binder (for example, for seed treatment formulations). Suitable solvents are water, organic solvents such as: medium to high boiling mineral oil strippers (such as kerosene or diesel), and coal tar and vegetable oils or animal oils 'monthly aliphatic hydrocarbons, cyclic hydrocarbons and aromatic hydrocarbons such as toluene. , xylene, paraffin tetrahydrocelene, alkylated naphthalene or derivatives thereof; alcohols such as methanol, ethanol, propanol, butanol and cyclohexanol; glycols (for example, ethylene glycol or 12-didiol) , 嗣, such as cyclohexanone and γ-butane vinegar; fatty acid dimethyl tyranamine, fatty acid and fatty acid jobs; and strong polar solvents such as amines, such as Ν _ _ _ _ _ _ _ The preferred solvent is water. I59869.doc •47· 201225840 Solid carrier is a mineral soil (such as tannin, citrate, talc, kaolin, limestone, lime, chalk, red basalt, loess, clay, dolomite, diatomaceous earth) calcium sulfate, Magnesium sulfate, ferric sulfate, magnesium oxide, ground synthetic materials, fertilizers (such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea) and plant-derived products (such as alfalfa meal, bark meal, wood flour and nut shell powder, Cellulose powder) and other solid carriers. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants or emulsifiers) are aromatic sulfonic acids (eg lignin sulfonic acid (Borresperse® type,

Borregard, Norway), phenolsulfonic acid, naphthalenesulfonic acid (Morwet® type, Akzo Nobel, U.S.A.), dibutylnaphthalenesulfonic acid (Nekai® type, BASF,

Germany)) and alkali metal salts of fatty acids 'alkaline earth metal salts and ammonium salts, alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, sulphate sulphates, and sulphuric acid Hexadecalate, heptadecanoate and octadecanoate, sulfated fatty alcohol glycol ether, and naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenyl hydrazine, ethoxy Isooctyl hydrazine, octyl phenol, nonyl phenol, alkyl phenyl polyglycol ether 'tributyl phenyl polyglycol ether, tristearyl phenyl polyglycol ether, alkane Alkyl polyether alcohol 'alcohol and fatty alcohol / ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl polyethylene glycol ether acetal , sorbitol esters, lignin-sulfite waste liquors and proteins, denatured proteins, polysaccharides (eg methylcellulose), hydrophobically modified starches, polyvinyl alcohol (M〇w1〇l® type, Clariant, Swhzerland) , polycarboxylates (10) (five) type 1 'BASF, Germany), polyalkoxylates, polyvinylamines (Lupasol® type 'BASF, Ge_ny), polyvinylpyrrolidone Its total 159869.doc • 48 · 201225840 polymers. Other suitable surfactants (especially for agrochemical compositions comprising glyphosate) are alkoxylated c: 4·22-alkylamines (for example ethoxylated tallow amines (POEA)) and are disclosed in EP1389040 Surfactants (for example, the ones of Examples i to 14). Examples of thickeners (i.e., compounds which impart improved flowability to the composition, i.e., higher viscosity at rest and lower viscosity during agitation) are polysaccharides and organic and inorganic clays such as xanthan gum (Kelzan®, Cp Keie〇, USA), Rhodopol® 23 (Rhodia, France), Veegum® (RT

Vanderbilt, U.S.A.) or Attaclay® (Engelhard, NJ, USA). A bactericide can be added to preserve and stabilize the composition. Examples of suitable bactericides are based on the following: bisphenol and benzyl alcohol hemimethyl condensate (purchased from ICI's Proxel® or from Th〇r ChemiaActicid, rs and

Kathon® MK from Rohm & Haas and isothiazolinone derivatives (e.g., alkylisothiazolinone and benzisothiazolinone (available from Th〇r Chemie 2 Acticide® MBS)). Examples of suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin. Examples of antifoaming agents are polyoxynoxy emulsions (e.g., siiik〇n < B SRE, Wacker, Germany or Rhodorsil 9, Rh〇dia, to 6), long chain alcohols, fatty acids, fatty acid salts, fluoroorganic compounds, and mixtures thereof. Examples of tackifiers or binders are polyvinylpyrrolidone, polyvinyl acetate, =acetol and cellulose (Tylose' Shin_Etsu, examples of colorants are both micro water-soluble pigments and water-soluble dyes. Examples which may be mentioned are dyes known by the following names: Rhodamine B (R-β), CL Pigment Red 112 and CU Filler Red Bu and Pigment Blue 15:4, Pigment Blue Pigment Blue 80, Pigments Yellow 1, Yan 15 : 3, Pigment Blue 1 5: 2, Pigment Blue 1 5:1 159869.doc -49- 201225840 Pigment Red 112, Pigment Red 48:2, Pigment Red 48:1 'Pigment Red 57:1 Pigment Red 53:1, Pigment Dial 43, Pigment (4), Yan (4) 5, (4) Green 36, Pigment Green 7, Pigment White 6, Yanite Material Brown 25, Test Purple 10, Alkaline Purple S Wenling Red 5 1 Acid Red 52, acid red 14, acid blue 9, acid yellow 23, alkaline red 1 碱性, alkaline red 1 〇 8. Powder, spreading material and powder can be mixed or simultaneously ground I and (right) Preparing other active materials together with at least one solid carrier. The particles can be prepared by combining the active materials with a solid carrier, such as coated particles, impregnated particles and f particles. Examples of solid carriers are, for example, mineral soils such as tannins, silicates, talc, kaolin, activated clay 'limestone, lime, white, red basalt, loess, clay, dolomite' Algae, calcium sulfate 'magnesium sulfate, magnesium oxide; ground synthetic materials; fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea; and plant-derived products, such as cereal meal, bark meal, wood flour and Nutshell powder, cellulose powder; and other solid carriers. Examples of composition types are: 1. Types of compositions diluted with water i) Water-soluble concentrates (SL, LS) 50 parts of fractions of salt (No. The sum of the mono-salt and the second salt is dissolved in 5 parts by weight of water or a water-soluble solvent. As an alternative, a wetting agent or other adjuvant is added. After dilution with water, the active substance dissolves. In this way, a composition having a content of 10% by weight of active material is obtained. Ii) Dispersible Concentrate (DC) 20 parts by weight of salt (the sum of the first salt and the second salt) is dissolved in 7 parts by weight 159869.doc.cn

S 201225840 In a looped net, add ι 〇 parts by weight of dispersant (for example, polyvinylpyrrole _) ° diluted with water to form a dispersion. The active substance content was 20% by weight. 1 U) emulsifiable concentrate (EC) 15 parts by weight of salt (the sum of the first salt and the second salt) is dissolved in 75 parts by weight of toluene' while adding calcium dodecylbenzenesulfonate and B Oxylated cannabis oil (5 parts by weight in each case). Dilute with water to form an emulsion. The composition had an active substance content of 15% by weight. Iv) Emulsion (EW, EO, ES) 25 parts by weight of salt (sum of first salt and second salt) is dissolved in 35 parts by weight of xylene with addition of calcium dodecyl sulfonate and ethoxylate Basecast castor oil (5 parts by weight in each case). This mixture was introduced into 30 parts by weight of water by means of an emulsifier (Ultraturrax) and made into a homogeneous emulsion. Dilute with water to form an emulsion. The composition had an active substance content of 25% by weight. v) Suspension (SC, 〇D, FS) 2 parts by weight of salt (the sum of the first salt and the second salt) is pulverized in a stirred ball mill while adding 10 parts by weight of dispersant and wetting agent and 7 The water or organic solvent is part by weight to form a fine active substance suspension. It is diluted with water to form a stable suspension of the active substance. The active substance content in the composition was 20% by weight. Vi) water-dispersible granules and water-soluble granules (wg, finely ground 50 parts by weight of salt (sum of first salt and second salt), while adding parts by weight of dispersant and wetting agent, and by means of technical equipment ( For example, an extruder, a spray tower, a fluidized bed) is made into water-dispersible granules or water-soluble 159869.doc • 51 - 201225840 granules are diluted with water to form a stable dispersion or solution of the active substance. The active substance content is 50% by weight. vii) Water dispersible powder and water-soluble powder (WP, SP, SS, WS) 75 parts by weight of salt (the sum of the first salt and the second salt in the rotor-stator mill) Grinding while adding 25 parts by weight of dispersant, wetting agent and silicone. Dilute with water to form a stable dispersion or solution of the active. The active substance content in the composition was 75 parts by weight. /〇. Viii) Gel (GF) 20 parts by weight of salt (the first salt and the second salt 糸 "and" in a stirred ball mill" while adding 1 〇 parts by weight of dispersant, 丨 parts by weight gelation and humidification The agent and 70 parts by weight of water or an organic solvent form a fine suspension of the active substance. It is diluted with water to form a stable suspension of the active substance, whereby it is obtained with 20 ° /. (w/w) a composition of the active substance. 2. Type of composition to be applied without dilution ix) Sprayable powder (DP, DS) Finely grind 5 parts by weight of salt (sum of first salt and second salt) and make it fine with % by weight The crushed kaolin is thoroughly mixed. Thereby, a spreadable composition having an active substance content of 5% by weight was obtained. X) Granules (GR, FG, GG, MG) Finely grind 0.5 parts by weight of the salt (the sum of the first salt and the second salt) together with 995 parts by weight of the carrier. Current methods are, extrusion, spray drying or fluidized beds. By this, an active substance content of 5% by weight can be applied without dilution. 0 xi) ULV solution (UL) 159869.doc ^

S 201225840 Dissolve 1 part by weight of the salt (the sum of the first salt and the second salt) in 90 parts by weight of the organic agent (for example, dioxane). Thereby, a composition which can be applied without dilution after the active material content is the working weight% is formed. , and the delta type 丨), ίν), ¥丨丨) and X) are preferred. The composition type 丨) is especially good. The agrochemical composition typically comprises between 0.01% and 95% by weight, preferably between (% and 9% by weight, optimally between 〇5 and 〇 and 90% by weight) a salt between them (the sum of the first salt and the second salt). The purity of the living biomass used is up to 1 〇〇 /, preferably 95 ° / 〇 to 1 〇〇 % (according to NMR spectrum) Usually used for the treatment of plant propagation materials, especially seeds. 'Use water-soluble concentrate (LS), flowable concentrate (FS), powder for drying treatment (DS), water for slurry treatment can be dispersed Powder (ws), water soluble. Powder (SS), emulsion (ES) emulsifiable concentrate (EC) and gel (GF). These compositions can be applied to plant propagation material with or without dilution. 'In particular, the composition will form an active substance concentration of from 0.01% to 60% by weight, preferably from 〇% to 8% by weight, in the ready-to-use preparation after dilution of 2 to 1 。. A very suitable agrochemical composition for salt: a) water soluble concentrate 10-70 wt% salt (sum of first salt and second salt) And, as the case may be, at least one pesticide, 30-90 wt% water, and optionally up to 10 wt% auxiliaries (such as surfactants, thickeners or colorants), wherein all components are added in violation of 100 Wt%. b) Wetting powder 10-90 wt% salt (sum of first salt and second salt) and optionally at least 159869.doc -53- 201225840 Another pesticide, 9-80 wt% solid carrier, κο The wt% surfactant 'and optional additives' add up to 1 〇〇wt〇/〇 of all components. C) water-dispersible granules 10-90 wt% salt (sum of first salt and second salt) and optionally at least one other pesticide, 9-80 wt% solid carrier, diterpene wt% surfactant, And depending on the situation, the amount of all components added to i 〇〇wt〇 / 〇. d) particles 0·5-20 wt% salt (sum of the first salt and the second salt) and optionally at least one other pesticide, 0.5-20 wt0/〇 solvent, 40-99 wt0/〇 solid carrier, and The amount of all components in the additive is increased by 1% by weight. In another form, the highly suitable agrochemical composition of the salt of the present invention is a water-soluble concentrate comprising 1 〇 70% by weight of a salt comprising dicamba, glyphosate and (B 1.1) (first salt and The sum of the two salts and, optionally, at least one other pesticide, 30-90 wt% water, and optionally up to 1% by weight of an auxiliary agent (such as a surfactant, thickener or colorant), wherein the amount of all components Adding up to 100 wt%. In another form, the highly suitable agrochemical composition of the salt of the invention is a water-soluble concentrate comprising 1 〇 7 〇 wt% comprising dicamba grass scales and (B 1.2) a salt (sum of the first salt and the second salt), and optionally at least one other pesticide, 30-90% by weight of water, and optionally up to 1% by weight of an auxiliary agent (such as a surfactant, thickener or coloring) The amount of all components is added up to 100 wt%. The salt of the invention is particularly suitable for agrochemical compositions: a) water soluble concentrate 159869.doc

S -54- 201225840 20-60 Salt and, as the case may be, at least one other pesticide, 4〇8〇 water, and optionally 10% by weight of auxiliaries (such as surfactants, thickeners or colorants), The iso-salt contains dicamba (as A1), glyphosate (as A2) and (B1), dicamba, glyphosate and (B2), or dicamba, glyphosate and (B4) [preferably dicamba, Glyphosate and (B1丨), dicamba, glyphosate and (B1.2), dicamba, glyphosate and (B1 3), wheat straw ^, glyphosate and (Β1·4), dicamba, Glyphosate and (B15), wheat straw ^, glyphosate and dicamba, glyphosate and (Bl 7), dicamba, glyphosate and (B1.8), dicamba, glyphosate and (Β1· 9), dicamba, grass scales and (Β1·1ϋ) ' dicamba, glyphosate and (8).U), or dicamba, glyphosate and (8).12)], in which the amount of all components is added Up to _ wt%. b) Wetting powder 1〇-90 Wt% salt and, as the case may be, at least one additional pesticide, 9-80 wt% of solid carrier 1_1G wt% surfactant and optionally additives, such salt (as A1), glyphosate (as A2) and (B1), dicamba, tianwei glyphosate and (B4) [preferably wheat straw, glyphosate and (B1.1), come to be used畏田T<i Maijunwei, glyphosate and (B1 2), wheatgrass glyphosate and (B1.3), come to „ „ 麦草畏, glyphosate and (B1 4), wheatgrass glyphosate and (B1.5), come to be different ^ Mai Junwei, glyphosate and (B16), wheatgrass glyphosate and (B1.7), stem stems „ 军 畏, glyphosate and (Β1·8), Wheatgrass Glyphosate and (Β1.9), Maiji Zai, Zeng 4 * Tian Zai Glyphosate and (Β 1.10), wheat straw, glyphosate and (B1.U), or Mai 1 Middle Prostitute &; the amount of all components in the ginseng grass, glyphosate and (Β1.12)], add itH) 〇wt%. I59869.doc -55- 201225840 c) water dispersible granules 10-90 wt% salt and optionally at least one other pesticide, 9·8 〇% solid carrier, MO surfactant and optionally auxiliaries, Salt packet 3 dicamba (as A1), glyphosate (as A2) and (B1), dicamba, glyphosate and (B2), or dicamba, glyphosate and (B4) [preferably dicamba Glyphosate and (B1·1), dicamba, glyphosate and (B 1.2), dicamba, glyphosate and (B1.3), dicamba 'glyphosate and (B1 (one), dicamba glyphosate and (B1·5), dicamba, glyphosate and (B 1.6), wheat straw glyphosate and (B1·7), dicamba, glyphosate and (Β1·8), dicamba glyphosate and Β 1.9), dicamba, glyphosate and (Β1.10), dicamba, glyphosate and (Bl.ll), or dicamba, glyphosate and (B1 12)], of which all components The amount is up to i 〇〇wt〇/. d) granules 0^-20 wt% salt and optionally at least one other pesticide, 〇52〇%2 (eg diol), 4〇_99 wt% a solid carrier and optionally an additive comprising dicamba (as A1) and glyphosate (as A2) and (bi), dicamba glyphosate and (B2), or dicamba, glyphosate and (B4) [preferably dicamba 'glyphosate and (B1.1), dicamba, glyphosate And (B12), dicamba, glyphosate and (B1.3), dicamba, glyphosate and (B1 4), dicamba, glyphosate and (B1.5), wheat #畏, glyphosate And (B1 6), dicamba, glyphosate and (B1.7), dicamba, glyphosate and (B1 8), dicamba, glyphosate and (B1.9), dicamba, glyphosate And (B1 1〇 畏 glyphosate and (BM1), or dicamba, glyphosate and (B 1.12)] 'the amount of all the components added up to (10) corrected %. 159869.doc

S-56·201225840 In another embodiment, a particularly suitable agrochemical composition of the salt of the invention is a water-soluble concentrate comprising 2〇_6〇wt% of a salt comprising dicamba, glyphosate and (BM) (the sum of the first salt and the second salt), and optionally at least one other pesticide, 80-40 wt% water, and optionally up to 1% by weight of an auxiliary agent (eg, a surfactant (eg, ethoxylation) Tallow amine), thickener or colorant), wherein the amount of all components is added up to 〇〇wt〇/〇. In another embodiment, particularly suitable agrochemical compositions of the present invention are water-soluble concentrates comprising from 20 to 60% by weight of a salt comprising dicamba, glyphosate and (B 1.2) (first salt and The sum of the two salts;), and optionally at least one other pesticide, 80-40% by weight of water, and optionally up to 10% by weight of auxiliaries (eg surfactants (eg ethoxylated tallow amine), thickeners) Or colorant), wherein the amount of all components is added up to 1 〇〇 wt%. In another embodiment, the salt of the invention is particularly suitable for agrochemical compositions: a) water soluble concentrate 20-60 wt% salt and optionally at least one other pesticide, 80-40 wt%. Water, and optionally up to 10 wt ° / 〇 auxiliaries (such as surfactants (eg, ethoxylated tallow amine), thickeners or colorants), these salts contain dicamba (as A1) glyphosate (as A2) and (B 1.2), dicamba, licorice and (B1.5), or dicamba, glyphosate and (B2) [preferably containing dicamba, glyphosate and (B 1,2) ) ' dicamba, glyphosate and (B 1.5), dicamba, glyphosate and (B 1.10 ' dicamba, glyphosate and (B 1.11), or dicamba, glyphosate and (B1.12) ] 'The amount of all components added up to 1〇〇wt% 〇159869.doc -57- 201225840 b) Wettable powder 1 0-90 wt. /. Salt (sum of first salt and second salt) and optionally at least one additional pesticide, 9-80 wt% solid carrier, 1_1 〇wty0 surfactant (eg ethoxylated tallow amine) and optionally Agents, the salts comprising dicamba, glyphosate and (B1.2), dicamba, glyphosate and (B1.5), or dicamba, glyphosate and (B2) [preferably dicamba, grass Glyphosate and (B1 2), dicamba 'glyphosate and (B1_5), dicamba 'glyphosate and (B11〇), dicamba, glyphosate and (B1.11), or dicamba, grass Phosphine and (B 1 · 1 2)] 'The amount of all components is added up to i 〇〇wt〇/〇. c) water-dispersible granules 10-90 wt% salt (sum of first salt and second salt) and optionally at least one additional pesticide, 9-80 wt% solid carrier, i_i〇wt〇/〇 surfactant ( For example, 'ethoxylated tallow amines' and optionally additives, including dicamba, glyphosate and (B1.2), dicamba, glyphosate and (B1.5), or dicamba, grass Glyphosate and (B2) [preferably dicamba, glyphosate and (Bi 2), dicamba, glyphosate and (B1.5), dicamba, glyphosate and (B1 1〇), dicamba, Glyphosate and (B1.U), or dicamba, glyphosate and (Bl·12)], wherein all components are added up to 100 wt%. d) particles 0.5-20 wt% salt (sum of first salt and second salt) and optionally at least one other pesticide, 0.5-20 wt% solvent (eg diol), 4 〇·99 wt〇/〇 a solid carrier, and optionally an auxiliary (for example, ethoxylated tallow amine), the salts comprising dicamba, glyphosate and (Β1·2), dicamba, glyphosate and (Β1.5), Or dicamba, glyphosate and (Β2) [preferably dicamba, glyphosate]59869.doc

S • 58 - 201225840 and (B 1.2), dicamba, glyphosate and (βι·5), dicamba, glyphosate and (Β1.10), dicamba, glyphosate and (Β111), or wheat straw Awesome, glyphosate and (Β 1.12)] 'The amount of all the components added to the correction%. In still another preferred embodiment, the agrochemical composition is a water dispersible granule comprising a first salt dicamba, a second salt glyphosate and selected from the group consisting of (βι, (m.3), (Β1·4) , (B1.5), (B16), (Bi7), (8).8), (8)_8), (B1.9), (Bl.1()), (Bl ll)siUBi i2)u ionic polyamine (8), Baikemin is used as another pesticide and as an adjuvant. In another embodiment, the agrochemical composition may be present in the form of a suspension concentrate. 0 八 A 1 main ear 'eight π 驵 驵 系 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Salt 2,4-D and selected from (Β1.1), (B1.2), (Bi.3), (B1 4) (B1.5), (Bi.6), (Bi 7), (B1 .8), (B1.8), (Β1·9), ΓΒ1 '0), (Β1·11) or (Βΐ·ΐ2) cationic polyamines (Β), MCPA as again - farm music and as appropriate Agent. In another example, 'this agrochemical group is. The σ substance may be stored in a water-soluble concentrate in a particularly preferred embodiment, the granule comprising the first salt dicamba, the chemical composition water dispersible granules (8). 2), (m.3), (8). ;, (4) (10) and selected from (BU), (8).8), (8).8), (Β1·9), (8)(8).5), (B1.6), (B1·7), ionic polyamine, MCPA As a further example of /), (B1.n) or (B1.12), this agricultural chemical group and the appropriate adjuvant. In another embodiment, in another embodiment t, this fee: may be present in the form of a water soluble concentrate. The chemical composition may be present in soluble particulate form I59869.doc -59. 201225840. In yet another preferred embodiment, the agrochemical composition is a water dispersible granule comprising a first salt dicamba, a second salt Mcpp and a selection From (bii), (B1·2), (B1·3), (B1·4), (8)·5), (m.6), (B17), (8)·8), (Β1.8), (8) · 9), (β1.1 ()), (β11ι) ^ βι ι2) 1 ionic polyamine (B), 2, 4-D as a further pesticide and optionally adjuvant. In another embodiment, this The agrochemical composition may be in the form of a water soluble concentrate. In another embodiment, the agrochemical composition may be in the form of soluble granules. The second inventive composition preferably comprises water, wherein the first salt and the second salt are in dissolved form. Stored in water [suitable examples are the above water-soluble concentrates. They can be applied before or during sowing. Methods for applying or treating agrochemical compounds and compositions thereof to plant propagation material (10), respectively, are known in the art and include propagation material. Seed dressing, coating, pelletizing, dusting, foaming, and application in a ditch. In a preferred embodiment, by not inducing hair Two:: methods (for example, by seed dressing, pelletizing, coating and dusting) respectively applying the compounds and their compositions to the plant hoppers. In the preferred embodiment, the suspension type (four) composition is used. For seed treatment. Usually, the FS combination can be wide, the active substance f, lg/1 to the g/i surface activity is 〇g/Ι to 200 g/l; Dongjian, Λ, g/丨Up to 400 g / ι of binder, 〇 g / 1 to g 丨 pigment and up to 1 liter of solvent (preferably water). The composition of the present invention can be used as it is or in the form of its agrochemical composition in the following form: Directly sprayed solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, spreadable products 'dispersed 159869.doc 201225840 materials or granules, which are sprayed, atomized, spread Applying, immersing or pouring. The application form depends entirely on the intended purpose to ensure that the active substance of the present invention reaches the most uniform knives in each case. It can be applied by emulsion concentrate, paste or emollient. Wet powder (may, 柘, from the dispersion) is added with water to form an aqueous application form. For the preparation of milk-paste or oil dispersion It can be homogenized in water by means of a wetting agent, a tackifier, a diluent or an emulsifier, and the substance can be homogenized as it is or dissolved in an oil or solvent. Alternatively, it can be prepared from an active substance or a wetting agent. a thickening agent, a powder or an emulsifier and, if appropriate, a concentrate of a solvent or an oil, and the concentrates are suitable for dilution with water. The concentration of the active substance in the preparation can vary within a wide range of f... Generally, it is Q. 丨 丨 丨 至 至 较佳 较佳 较佳 较佳 较佳 较佳 较佳 较佳 较佳 较佳 较佳 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 % by weight or more of the active substance composition, or even an additive-free active substance. Depending on the type of effect desired, when applied to plant protection, the amount of active substance applied is 0.001 kg/hd2 kg/ha, preferably 〇〇〇5 4 to 2 kg/ha, more preferably 05.05 kg/ Iu〇9 kg/ha, especially 〇i kg/ha to 〇75 kg/ha. When the plant propagation material (for example, seed) is treated by, for example, dusting, coating or infiltrating the seed, the amount of the active substance usually required is from 〇ig to _〇g' preferably from 1 § to 1000 g, more preferably ! 8 to 1 g, and preferably 5 § to g/100 kg of plant propagation material (preferably when seed t is used to protect the material or stored product, the amount of active substance applied depends on the type of application area and Desirable effect. In material protection, the amount is usually applied (eg 159869.doc •61 · 201225840) 〇·001 g to 2 kg, preferably 0.005 g to 1 kg of active substance/cubic meter of treated material. Tian Ke may add various oils, wetting agents, adjuvants, herbicides, bactericides, other fungicides and/or pesticides to the active substance or compositions containing it just prior to use (large tank mixing). The reagent may be mixed with the composition of the present invention in a weight ratio of 1.100 to 100:1, preferably 1:1 〇 to 〇. The azole may be used, specifically, an organic modified polyoxetane, for example Break Thru s 240®; alcohol alkoxylates such as Atpius 2458,

AtplUS MBA 1303® ' P1 (10) ~ LF 300® and Lutensol (10) 3〇8; E^/P〇 segmented polymers (eg Plur〇nic RPE 2035 <8> and GenaP〇i B ) 'alcohol ethoxylates ( For example, Lutens〇i χρ 8〇®); and dioctyl sulfonate, such as Le〇phen ra®. The salts may also be present together with other active substances, for example with herbicides, insecticides, growth regulators, fungicides or additionally with chemical fertilizers as premixed mash, or (if appropriate) at the end of use (large The tanks are mixed before they exist together. The invention also relates to the control of harmful insects and/or phytopathogenic fungi, including plants, seeds, soil or plant habitats in which harmful insects and/or phytopathogenic fungi are grown or growable, Protection is free. Plants, seeds or soil attacked or infested by harmful insects and/or phytopathogenic fungi such as hai are contacted with an effective amount of the composition of the present invention. Anionic pesticides typically contain insecticides and/or fungicides. For example, t, for the control of harmful insects, the agrochemical formulation contains an insecticide. For example, to prevent phytopathogenic fungi, agrochemical formulations comprise a fungicide. 159869.doc

S•62· 201225840 The invention further relates to a method of controlling undesired vegetation comprising applying a herbicidally effective amount of a composition of the invention to a plant, to its habitat or to seeds of such plants. In a preferred embodiment, The method can also include plants that have been rendered tolerant to the applied agrochemical formulation, wherein the anionic pesticide is a herbicide. Such methods generally involve applying an effective amount of an agrochemical formulation of the invention comprising a selected herbicide to a cultivation area or crop field containing one or more crop plants that are tolerant to the herbicide. While any undesired vegetation can be controlled by such methods, in some embodiments, the methods can involve first determining undesired vegetation in the Gotland area that is sensitive to the selected herbicide. Methods are provided for controlling undesired vegetation in the cultivation area, preventing the formation or occurrence of undesirable vegetation in the cultivation area, producing crops, and improving crop safety. Undesirable vegetation is to be understood in the broadest sense to mean all plants that grow at undesired locations, including but not limited to plant species commonly referred to as weeds. In addition, it is undesirable for the vegetation to include undesirable crop plants that are growing at the determined location. For example, a authigenic corn plant in a field that primarily comprises soybean plants may be considered undesirable. Unwanted plants which can be controlled by the method of the invention include plants which have been planted in a particular field in the pre-season or have been planted in adjacent areas, i including crop plants, including soybeans, corn, canola, cotton, sunflowers And so on. In some aspects, crop plants are tolerant to herbicides, such as licorice scales, als-inhibitors or glufosinate herbicides. The # method comprises planting a crop plant that is financially acceptable to the herbicide in the cultivation area' and in some embodiments, for crops, seeds, weeds, undesirable plants, soil damage, or cultivated areas thereof 159869.doc -63 - 201225840 Focus on herbicides. Herbicides can be applied between plants that are tolerant to plants. The herbicide can be applied after the crop has been planted in the cultivation area or after. Also provided is a method of controlling glyphosate-tolerant weeds or crop plants in a cultivation area, comprising, wherein the herbicide is applied to a cultivation area having a ❹ == amount of glyphosate. The term "herbicidally effective amount" which is tolerant to another herbicide means that the amount of the active ingredient of the pesticide (for example, salt or another agricultural music) is sufficient to control the undesired vegetation and it does not cause substantial effects on the treated plant. Sexual damage. This amount can vary within the silk circumference and depends on various factors such as the species to be controlled, the cultivated plant or material being treated, the climatic conditions and the particular pesticide active ingredient used. The term "control weeds" means one or more of the following: inhibiting the growth of weeds and/or plants 'germination' and/or proliferation; and/or killing, removing, destroying, or otherwise Reduce its production and / or activity. The compositions of the present invention have excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants (e.g., broadleaf weeds, grass weeds, or cyperaceae). These active compounds also act effectively on perennial weeds which produce shoots from rhizomes, rhizomes and other perennial organs and are difficult to control. Particular examples which may be mentioned are some representatives of monocotyledonous and dicotyledonous weedy weed flora which may be controlled by the compositions of the present invention, and the enumeration is not limited to certain species. Examples of weed species in which herbicidal compositions are effective are in particular monocotyledonous weed species: Avena spp., Aurora, Apollo (Apera 159869.doc •64·

S 201225840 SPP·), Brachiaria spp., Bromus spp., Digitaria spp., Lolium spp., Echinochloa spp. , Leptochloa spp., Fimbristylis spp., panicum spp., Phalaris spp., Poa spp., genus Filaria Setaria spp.) and the genus Cyperus from the annual group, and the genus Agropyron, Cynodon, Imperata and Sorghum, and the perennial sedge . In the case of dicotyledonous weed species, the range extends to the genus 'Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum (for example) belonging to the annual weeds. Chrysanthemum spp.), Galium spp., Ipomoea (ip0moea Spp_), Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., p〇lyg0nurn spp., Sida spp., Sinapis spp., Solanum spp., Stellada spp. , Ver〇nica spp, Eclipta spp., Sesbania spp., Aeschynomene spp., Vi〇la spp, Xanthium Genus (Xanthium spp.), and in the case of perennial weeds, Convolvulus, Cirsium, Rumex, and Artemisia. The invention further relates to seeds comprising the compositions of the invention. Preferably, the seed is coated with an agrochemical formulation comprising a composition of the invention. The present invention provides various advantages: the compositions of the present invention exhibit low volatility. Was 159869.doc -65- 201225840 Hair is also lower than the commercially available composition. Moreover, the compositions of the present invention are readily prepared starting from inexpensive, industrially available and readily processable compounds. The activity of the pesticide is maintained to the extent equivalent to the known salt or free acid of the pesticide. The invention reduces off-target crop damage caused by low volatility, and does not even adversely affect the pesticide/tongue life. Low volatility properties are maintained whether delivered in large tank mixing or premixed formulations. Moreover, the present invention increases the physical stability of the composition, for example by reducing the tendency to crystallize or phase separation. The compositions of the invention exhibit high solubility in water. The invention is further illustrated by the following examples, but the invention is not limited to the examples of the examples 0

Clarity®: Agrochemical formulation of dicamba salt of 2-(-aminoethoxy)ethanol (water soluble concentrate SL, 48 〇g/b from Basf). Touchdown® HiTech: An agrochemical formulation of glyphosate potassium salt (water-soluble Chinese shrinkage SL, 500 g/Ι, purchased from Syngenta).

Accord9 Concentrate 'condensate: agrochemical formulation of glyphosate isopropylamine (IpA) salt (water soluble concentrate SL, 480 g / bu pH 48_5 〇, available from Dow AgroScience) ° Example 1 Preparation of a single salt preparation Dicamba or glyphosate is used as an anionic pesticide and a salt of various polyamine cations. A known amount of dicamba (3,6 dioxo-2-methoxybenzoic acid or glyphosate acid (N-(phosphoninodecyl)glycine) is suspended in water while being stirred. The amine is titrated to a pH of 7 〇 to 8 〇 (for wheat straw) or a pH of about 5 (for glyphosate) until all solids are dissolved and 159,869.doc •66·

S 201225840 Salt. Additional water is added to adjust the desired concentration of dicamba or glyphosate. Tables 1 through 4 list the details of the final composition. In each case, add water concentration totaling 100 wt%. All test salts have been shown to have excellent solubility in water, i.e., dicamba salt is soluble up to at least 527 g/stroke and glyphosate salt is soluble up to at least 521 g/stroke. Table 1: Solution 1 containing 527 g/l dicamba. Concentration (w/w%) dicamba 42.29 Ν, Ν-bis-(3-aminopropyl) decylamine (BAPMA) 10.9 Water 46.80 Table 2: Solution containing 509 g / buckwheat grass 2 . Concentration (w/w%) dicamba 42.06 diethyltriamine (DETA) 9.95 water 47.99 Table 3: Solution containing 509 g/glyphosate 3 . Concentration (w/w%) Glyphosate 39.68 Ν, Ν-bis-(3-aminopropyl)methylamine (BAPMA) 15.65 Water 44.67 Table 4: Solution 4 containing 521 g/glyphosate. Concentration (w/w%) Glyphosate 39.68 Diethyltriamine (DETA) 13.05 Water 47.27 Example 2: Preparation of glyphosate and dicamba mixture The following grasses were prepared by mixing at room temperature with stirring. Mixture of phosphine and dicamba salt (glyphosate/dicamba ratio = 2:1). 159869.doc •67- 201225840 Table 5: Composition Concentration (w/w%) Aa) Touchdown® HiTech (Glyphosate K Salt) Solution 2 (Drosophila DETA Salt) 62.93 37.07 Ba) Touchdown® HiTech (Glyphosate) K salt) Solution 1 (grass salt) 62.71 36.29 ca) Touchdown® HiTech (glyphosate strontium salt) Clarity® ( dicamba DGA salt) 61.53 38.47 Da) Accord® concentrate (glyphosate IPA salt) solution 2 (Drosophila DETA salt) 67.95 32.05 Ea) Accord® concentrate (glyphosate IPA salt) Solution 3 (glyphosate BAPMA salt) 68.67 31.33 pa) Accord® concentrate (glyphosate IPA salt) Clarity® (dicamba) DGA salt) 66.64 33.36 G solution 4 (glyphosate DETA salt) solution 2 ( dicamba DETA salt) 66.15 33.85 H solution 3 (glyphosate BAPMA salt) solution 1 ( dicamba BAPMA salt) 67.41 32.59 a) Comparative, Not according to the invention. Example 3: Stability after storage The composition A-Η of Example 2 was kept at 25 ° C for one month. Table 6 summarizes the results of macroscopic observation of the stability of the mixture formulation. It has been found that the physical stability of the mixture of G glyphosate and dicamba salt formulations G and hydrazine (according to the present invention) is stable, while the other mixture formulations Α to F are crystallized or phase separated from the solution. Table 6: Formulation observations Aa) Two liquid phases separated Ba) Two liquid phases separated ca) Two liquid phases separated D aJ Crystal EaJ Crystal F a) Crystal G Stable H Stabilized a) Comparative, not According to the invention.

159869.doc -68- S 201225840 Example 4: Volatile Field Testing Field test plots were established in existing soybean fields in some locations in the United States at intervals of 300 ft to avoid possible movement into adjacent test areas. At the center of each test zone (300 x 300 ft), the 40 M0 ft area was treated with the composition dsg from Example 2. The treatment is applied when the soybean is in the growth period of ¥5 to 111. Applying on a day with a lower wind speed to minimize particle drift, a manual boom with air-introducing (10) nozzles is used and the boom height is 12 inches above the soybean canopy height. After 5 minutes of application, four air sample pumps equidistant from each other were placed in the spray area. Use a stake to raise the air pump to a height of about 0 to 3 inches above the soybean canopy. Depending on the position, the air sample was collected by pumping air through the sample collection box containing the adsorption filter paper at 4 L/min for 8 hours. The sample collection box consists of a 丨.〇μηι glass fiber filter paper and a mixed ester cellulose support pad stored in a plastic collection box connected to a low volume pump by tygon tubing. Air samples were continuously collected over 8 hours. Immediately after removing the collection box from the air pump, all openings in the collection box were closed and each collection box was placed in a separate ziplock bag and transported on dry ice. The filter paper and the support of the collection box were extracted by heating to 60 ° C with 0.5 N K0H and 10% KC1 in a water bath for 15 minutes. A 1 mL aliquot of the sample was acidified to pH 1-2 with HCI and then dispensed by vortexing with 4 mL of ethyl acetate and then centrifuged. Then 2 mL of the ethyl acetate phase was evaporated under nitrogen. The samples were then reconstituted in 2 mL 10/90 Me0H/H20 and analyzed on LC/MS/MS. 159869.doc • 69- 201225840 DGA- dicamba volatiles are summarized in Table 7, which is measured as dicamba concentration (ng/m3) in the air treated soybean plants above. Compared with the composition d, the volatility of the composition of the present invention (3, dicamba is greatly reduced. Table 2, woven straw volatility (all values are in ng/m3^(10)) gras gras _ dicamba 34 43 38 a) Comparative, not in accordance with the invention. Example 5: Greenhouse test A greenhouse test was conducted to confirm high pesticide activity (biological potency). The evaluators included corn that is intolerant to glyphosate (c〇rn, noisy ", glyphosate-tolerant (soybean, w), common gray (Chenopodium aibumy, green carp) (veh/etleaf, heart (1) (10) Chuan), spring wheat (wheat (said aewv_)) and mixed morning glory (Ipomoea spp.)) e plant growth period in the range of 2 to 5 leaves 'this depends on the target Species: Two treatments of dicamba + glyphosate were applied at 280 + 560 g ai/ha, respectively, with a closed track sprayer delivering 187 1/ha. 0.25% (v/v) non-ion was included in all treatments. Surfactant. Control at % (no control) to 1 〇〇 (plant complete death) % scale was evaluated 14 days after treatment. The average values are summarized in Table 8. The two herbicide treatments were shown for all species. Pesticide activity (biological potency) 159869.doc 201225840 Table 8: Efficacy [value from 0 (no control) to 100 (complete plant death)] glyphosate BAPMA salt + dicamba BAPMA salt glyphosate DETA salt + wheat straw Fear DETA salt corn 94 95 乂95 98 wheat 96 95 green hemp 95 91 leafy gray dish 100 100 Ipomoea 96 98 159869.doc -71 -

Claims (1)

201225840 VII. Patent application scope: 1. A composition comprising: a salt comprising 'the first anionic pesticide (A1) and a cationic polyamine (B), and b) a second salt, the winter ancient & There is a second anionic pesticide (A2) and a cationic polyamine. (8), wherein both salts contain the same cationic polyamine (8), and wherein the cationic polyamine comprises at least two amine groups. a composition wherein the cationic polyamine (7)) is a compound of the formula R1, n+W, x ^ y R (Bl) wherein R, R, R, R6 and R7 are independently H or optionally substituted by 〇H -C6-alkyl, R3 and R5 are independently (: 2-(:1()-alkylene, X- or NR6R7, and η- 1 to 20; or a compound of formula (Β2)) R11 (Β2) wherein R10 and R11 are independently hydrazine or Ci-C6-alkyl, R12 is a (VCu-alkylene group, and R13 is an aliphatic Cs-C:8 ring system which contains nitrogen in the ring or Its 159869.doc 201225840 is replaced by at least one unit NRi〇Rii. 3. 4. 5. 6. 7. 8. 9. 10 The composition of claim 1 or 2, where R1, R2, R4 'R6 and R7 Independently, hydrazine or methyl, R3 and R5 are independently c2-c3-alkylene, X-based OH or nr6r7, and η is 1 to 1 Å. For example, a composition of the above items 1 to 3, wherein Ri 〇 &Rii is independently a hydrazine or a methyl group, Ri2 is a C2-C3-alkylene group, and Ru is an aliphatic C5_C8 ring system containing nitrogen in the ring. The composition of claims 1 to 4, wherein Cationic polyamines, compounds of formula 2), (B1.5) (Β1.2) (Β1.5) or a compound of formula (Β2). The composition of claims 1 to 5, wherein the first anionic pesticide comprises a carboxy group and the second anionic pesticide contains a phosphonate group. The composition of claim 1 to 6, wherein the first anionic pesticide is an aromatic acid herbicide or a phenoxycarboxylic acid herbicide, and the second anionic pesticide comprises an organophosphorus herbicide of a decanoic acid group. The composition of claim 1 to 7, wherein the first anionic pesticide and the first anionic pesticide are selected from the group consisting of dicamba, pinclorac, glyphosate, 2, 4 d A composition of the present invention, wherein the first anionic pesticide and the second anionic pesticide are selected from the group consisting of dicamba and glyphosate, wherein the composition of the first anionic pesticide and the second anionic pesticide is selected from the group consisting of aminopyraiid and MCPP. The composition of claim 1 to 9, the first anionic pesticide in the sputum and the No. I59869.doc 201225840 - anionic farmer less in the molar ratio of (1) to Fan 2 and the sum of the cationic polyamines]. A composition according to claim 1 to 1 , 4, which comprises water, wherein the nightmare one of the second salt is stored in water in dissolved form. "^ A method of preparing a composition of any one of items 1 to 11, and a step of contacting the first salt with the second salt. A method of preventing harmful insects and/or phytopathogenic fungi comprising causing, in or on, such harmful insects and/or plant pathogens to grow or: plants, seeds, soil or plant habitats, Plants, seeds or soils intended to protect against attack or infestation by such harmful insects and/or phytopathogenic fungi are contacted with an effective amount of a composition as claimed in the claims. 14. A method of controlling undesired vegetation comprising applying a herbicidally effective amount of the composition of claims 1 to U to plants, their habitat or seeds of such plants. 15. A seed comprising the composition of claims 1 to 131. 159869.doc 201225840 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: ' (none) 159869.doc