201217305 六、發明說明： 【發明所屬之技術領域】 本發明係無音材料有關，更詳而言之是彳卜種無機發泡 聚合物隔音材料製作方法。 【先前技術】 現今的工商料勃發展賴提升了人義生活水準，卻也 因此造就了許多的噪音問題，不僅干擾人民生活安寧，亦影響 工作環境品質’嚴鱗更將造顏覺的受損，為確保生活與工 作環境不被噪音軒擾，隔音材料的顧便因此因應而生。 而已知的隔音材料於製作過程中大多使用水泥當成主要 原料’但水^^製程的所需耗能高又會產生大量的二氧化碳，不 僅使得加工成本較為昂#又會造成溫室效應及熱島現象等環 境問題。 < 且已知的製作過程中顧之混凝方式，常使得製作完成之 隔音材料比重過大，而建築物皆有一定限制的最大乘載重量， 過大的比重常使得隔音材料在縣與裝_上而有所受 限。 、是故’在環保意識抬頭的現代，隔音材料的製程勢必順應 潮流，發展低污較低耗能的環保㈣以取代水泥作為隔音材 料的主要原料，以及能使隔音材料比重降低的混凝方式，除能 確保生活安寧與工作環境不被噪音所干擾外，亦能保障後代子 201217305 孫能擁有美好的生活環境，更能讓隔音材料的運用不再因比重 而有所限制。 f發明内容】 有鑑於此，本發明在於提供一種無機發泡聚合物隔音材料 製作方法’其主要目的為湘低污染及絲㈣無機聚合物為 主要原料’次要目的為利舰沫混凝方式，使隔音材料製成後 不僅隔音效果佳還具有比重小的特性。 緣以達成上述目的，本發明所提供之無機發泡聚合物隔音 材料製作方法包含下列步驟：先將—無機膠結材料與一無機卜 作凰材料混合且充分響後，再以—齡化液聽且均勾擾 拌’以製成-漿體’其中’該驗活化液係由驗金屬氫氧化物、 驗金屬魏驗與水齡且羽勝所製成；縣鄕體與一 經泡沐化之發泡劑混合，均勻赫後倒入模具内成型；型後由 模具内取出’以形成-無機發泡聚合物隔音材料，且其内部具 有複數個氣泡體。 【實施方式】 為能更清楚地說明本發明，兹舉較佳實施例並配合圖示詳 細說明如后。 請參閱第-圖’為本發明—較佳實_之無機發泡聚合物 201217305 隔音材料製作方法，包含下列步驟： 先將皆呈乾粉狀的無機膠結材料與無機卜域材料混合 且擾拌均勻。 σ 上述之無機膠結材料重量百分比可為％〜4〇糾％。於本發 明中，無機膠結材料係使用高嶺土，為產生聚合反應之主· 料，高嶺土更可於與無機卜作風材料混合前，先以6〇〇〜卿。c 加熱’以增加高駐於聚合反射辟性缝無機發泡聚合物 隔音材料之成品強度’除使用高嶺土外，亦可使用玻璃或石膏 等了產生^^合反應之無機膠結材料代替。 該無機卜作嵐材料的重量百分比可為1〇〜2〇wt%。於本發 明中’無機卜作風材料係使用爐石粉，於聚合反應中可產生枯 性，主要是时取代部分無機騎材料以及使無機發泡聚合物 隔音材料之成品強度上升，除使用爐石粉外，亦可使用飛灰或 石夕灰等…於聚合反應中亦可產生黏性之無機卜作風材料代替。 接著，將勝均勻的無機膠結材料與無機卜作·料用一 鹼活化液澆淋並均勻攪拌，藉以製成一漿體。 該驗活化液的重量百分比可為4〇〜6〇wt%。在本發明中， 鹼活化液係由H)〜3〇wt%的驗金屬氫氧化物、4〇〜6_%的驗金 屬石夕酸溶液以及2〇〜婉％的水混合且均勾·所製成’用以 產生聚合反應所需之_子’該雜子係與域雜材料及益 機卜作嵐材反應’以產生凝結鏈與膠體，使該漿體得以凝結成 型。上述之鹼金屬氫氧化物與鹼金屬矽酸溶液於本實施例中係 201217305 使用氫氧化域㈣娜液，除氫氧化倾魏納溶液 外’亦可使用氫氧化鉀與石夕酸鉀溶液，或氫氧化鐘與石夕酸經溶 液代替。 最後’將賴體触齡化之發泡舰合， 倒入模具内成型。該發泡劑的重量百分比約為5〜驗，係由 界面活性趣錢合製成’並彻加敎魏M、管路使其泡 沬化。 、 最後打開模具即可得到如第二圖所示之無機發泡聚合物 隔音材料20。 〇無機發泡聚合物隔音材料2G具有—表面21幼部具有 複數個氣泡體22 ’該複數個氣泡體22係藉由該泡沫化之發泡 劑固結後所形成，當聲波丨，如第二騎示，料至該無機發 泡聚合物隔音材料2〇時驾分職絲面2ι反射形成聲波 2 ’而少部分進入該無機發泡聚合物隔音材料的聲波3，則受 該複數織顏22制，導鱗波3德量鋪，而無法完 整穿透該無機發泡聚合物隔音材料1〇，藉以形成隔音效果。 茲以上述配比關係為基礎下，本發明較佳實施例之無機發 泡聚合無音㈣，其補配比麵纽果如下所示： 【範例一】 原料 高嶺土 爐石粉 _比<歹4 32.4wt% 13.9wt% 201217305 8.2wt% 24.2wt% 18.4wt% 2.8wt% 0.1 wt% 氫氧化鈉 矽酸鈉溶液 水 發泡劑 其他成分 將高嶺土緞燒後混合爐石粉乾拌5分鐘，再以氫氧化納、 矽酸鈉溶液及水製成之鹼活化液澆淋並攪拌1〇分鐘，再將泡 沫化之發泡劑加入，且攪拌均勻後倒入模具中成型，製成無機 發泡聚合物隔音材料後，利用1〇〇〜5〇〇〇Hz之聲波進行二4隔 音測試’測試結果說明如下： 聲波頻率 聲波指耗能景 100 〜200Hz ^ 大約30dB，但部分小於3〇dB 200〜300 Hz 35dB〜42dB之間 300-500 Hz 35dB〜45dB之間 500〜1000 Hz 40dB〜45dB之間 1000〜2000 Hz 4(MB〜47dB之間 2000-3000 Hz 40dB〜45dB之間 3000〜5000 Hz 40dB〜45dB之間 【範例二】 7 201217305 改變水與發泡劑之比例，其原料配比如下： 原料 比例 面嶺土 32.4wt% 爐石粉 13.9wt% 氫氧化鈉 8.2wt% 矽酸鈉溶液 24.2wt% 水 17.3wt% 發泡劑 4wt% 同樣步驟及混合時間製作成型後，三次隔音測試結果如 下： 聲波頻率_聲波損耗能量_ 100〜200Hz 35dB〜47dB之間 200〜300 Hz 45dB〜52dB之間 300-500 Hz 45dB〜55dB之間 500〜1000 Hz 45dB〜50dB之間 1000〜2000 Hz 43dB〜50dB之間 2000〜3000 Hz 44dB〜48dB之間 3000〜5000 Hz 43dB〜48dB之間 【範例三】 201217305 改變各原料之比例，其原料配比如下： 原料 比例 高嶺土 32wt% 爐石粉 14wt% 氫氧化鈉 8wt% 矽酸鈉溶液 24wt% 水 16wt% 發泡劑 5wt% 其他成分 lwt% 同樣步驟及混合時間製作成型後，三次隔音測試結果如 下： 聲波頻率_聲波損耗能量_ 100〜200Hz 35dB〜45dB之間 200〜300 Hz 45dB〜50dB之間 300〜500 Hz 48dB〜53dB之間 500-1000 Hz 46dB〜50dB之間 1000〜2000 Hz 44dB〜51dB之間 2000〜3000 Hz 44dB〜47dB之間 3000〜5000 Hz 43dB〜47dB之間 201217305 ^ 至範例二之隔音測試結果曲線圖如第四至六圖所 丁 /曰、中之dB值為聲波在進入該無機發泡聚合物隔音材料時 的月匕里她大小(能量損耗:斯娜⑹dB，其中L為入射聲波 強度’ L為穿透聲波強度），犯值越高則表示能量損耗越大， 7值與隔音效果說明如下：當dB值於小於30時：正常交談 易被5隔音效果不良。當dB值於30〜35時：正常交談 不易被隔音效果尚可。當犯值於％〜45時：正常交談 ’、大聲交4自不易被聽到，隔音絲良好。當册值於大於Μ 時：正常交軸大聲交談皆轉被_，隔姐果極佳。 …由第四圖可看出，範例一之無機發泡聚合物隔音材料’其 、’J試:果大。p刀皆於3〇dB以上，表示具有不錯的隔音效果。 範例之無機發缝合物隔音材料，其隔音測試結果之曲 相如第五圖所不’可看出測試結果皆大於％犯且大部分大 於45dB ’具有良好的隔音效果。 範例一之無機發泡聚合物隔音材料，其隔音測試結果之曲 相如第，、圖所不’測試結果與數據二相似，皆大於3娜且 大部分从45犯，同樣具有良好的隔音效果。 由範例―、三可得知，在不影響整體強度的條件下，增加 泡沐化之發_的_，將使得隔音效果提升。 以上所述僅為本發明數個較佳可行實施例而已，舉凡應用 本&月說明書及申睛專利範圍所為之等效結構及製作方法變 化’ _包含在本發明之專利範圍内。 201217305 【圖式簡單說明】 第一圖為本發明一較佳實施例之流程圖。 第二圖為上述本發明較佳實施例之隔音示意圖。 第三圖為上述本發明較佳實施例範例一的測試曲線圖。 第四圖為上述本發明較佳實施例範例二的測試曲線圖。 第五圖為上述本發明較佳實施例範例三的測試曲線圖。 【主要元件符號說明】 1〜3聲波 20無機發泡聚合物隔音材料 21表面 22氣泡體201217305 VI. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a silent material, and more particularly to a method for producing an inorganic foamed polymer sound insulating material. [Prior Art] Today's industrial and commercial development has improved the standard of human life, but it has created a lot of noise problems, which not only interferes with the peace of life of the people, but also affects the quality of the work environment. In order to ensure that the living and working environment is not disturbed by noise, the sound insulation material will be born accordingly. However, the known soundproofing materials mostly use cement as the main raw material in the production process. However, the high energy consumption required for the water treatment process will generate a large amount of carbon dioxide, which not only makes the processing cost more expensive, but also causes the greenhouse effect and the heat island phenomenon. Environmental issues. < And the known coagulation method in the production process often makes the proportion of the sound-insulating material produced too large, and the building has a certain maximum load weight, and the excessive proportion often makes the sound-proof material in the county and equipment_ It is limited. Therefore, in the modernization of environmental awareness, the process of sound-insulating materials is bound to follow the trend, develop low-pollution and low-energy environmental protection. (4) Replace cement as the main raw material for sound-insulating materials, and the coagulation method that can reduce the specific gravity of sound-insulating materials. In addition to ensuring that the peace of life and the working environment are not disturbed by noise, it can also protect future generations. 201217305 Sun can have a beautiful living environment, and the use of soundproofing materials can no longer be limited by the proportion. In view of this, the present invention provides a method for producing an inorganic foamed polymer sound-insulating material, whose main purpose is to reduce pollution and silk (4) inorganic polymers as main raw materials. After the soundproof material is made, not only the sound insulation effect but also the small specific gravity is obtained. In order to achieve the above object, the method for preparing an inorganic foamed polymer sound-insulating material provided by the present invention comprises the steps of: first mixing an inorganic cement material with an inorganic material, and then fully ringing, and then listening to the aging liquid. And all of them are disturbed by mixing 'to make-slurry'. 'The test activation liquid is made of metal hydroxide, metal test and water age and Yusheng; county body and one bubble The foaming agent is mixed, uniformly poured into the mold, and then taken out from the mold to form an inorganic foamed polymer sound-insulating material, and has a plurality of bubble bodies inside. [Embodiment] In order to explain the present invention more clearly, the preferred embodiment will be described in detail with reference to the accompanying drawings. Please refer to the drawing of the present invention as a preferred embodiment of the inorganic foaming polymer 201217305 sound insulating material, comprising the following steps: first mixing the inorganic cement material which is dry powdered with the inorganic material and disturbing Evenly. σ The above inorganic cement material may have a weight percentage of % to 4%. In the present invention, the inorganic cementing material is kaolin, which is the main material for the polymerization reaction, and the kaolin can be used in the first place before mixing with the inorganic material. c Heating 'to increase the strength of the finished product of the inorganic foamed polymer sound-insulating material in the polymeric reflective crack'. In addition to the kaolin, an inorganic cementing material such as glass or gypsum may be used instead. The inorganic silicon material may have a weight percentage of 1 〇 to 2 〇 wt%. In the present invention, the use of hearth powder in the inorganic-inorganic material can produce a stagnation in the polymerization reaction, mainly replacing a part of the inorganic riding material and increasing the strength of the finished product of the inorganic foaming polymer sound-insulating material, except for using whetstone powder. It is also possible to use fly ash or Shixia ash, etc., in which a viscous inorganic cloth material can also be used in the polymerization reaction. Next, the uniform inorganic binder material and the inorganic material are poured with an alkali activation liquid and uniformly stirred to prepare a slurry. The test solution may have a weight percentage of 4 〇 to 6 〇 wt%. In the present invention, the alkali activation liquid is mixed with H) 〜3〇wt% of the metal hydroxide, 4〇~6_% of the metallurgical acid solution, and 2〇%婉% of the water and mixed with The preparation is carried out to produce a coagulation chain and a colloid to form a coagulation chain and a colloid to form a coagulation chain. In the present embodiment, the alkali metal hydroxide and the alkali metal ruthenic acid solution are used in 201217305, and the hydroxide field (tetra) liquid is used, and the potassium hydroxide and potassium oxalate solution may be used in addition to the fluoridation Weiner solution. Or the oxidation clock and the oxalic acid are replaced by a solution. Finally, the foaming ship that has been aged to the body is poured into a mold for molding. The weight percentage of the foaming agent is about 5 to 1 test, which is made up of the interface active fun and made by the addition of Wei M and the tube to make it bubble. Finally, the mold is opened to obtain the inorganic foamed polymer sound insulating material 20 as shown in the second figure. 〇Inorganic foamed polymer sound-insulating material 2G has a surface 21 having a plurality of bubble bodies 22', and the plurality of bubble bodies 22 are formed by consolidation of the foaming foaming agent, when the sound waves are smashed, such as The second ride shows that the inorganic foamed polymer sound-insulating material is 2 〇 驾 分 丝 2 2 2 2 ι ι ι ι ι ι ι ι ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' The 22 system, the guide scale wave 3 German shop, and can not completely penetrate the inorganic foam polymer sound insulation material 1 〇, in order to form a sound insulation effect. Based on the above ratio relationship, the inorganic foaming polymerization of the preferred embodiment of the present invention is silent (4), and the compounding ratio of the noodles is as follows: [Example 1] Kaolinite powder of raw material _ ratio < 歹 4 32.4 Wt% 13.9wt% 201217305 8.2wt% 24.2wt% 18.4wt% 2.8wt% 0.1 wt% sodium hydroxide sodium citrate solution water foaming agent other ingredients dry kaolin satin-fired mixed hearth powder for 5 minutes, then hydrogen The sodium oxide solution, the sodium citrate solution and the alkali activation solution made of water are poured and stirred for 1 minute, and then the foaming foaming agent is added, stirred uniformly, and poured into a mold to form an inorganic foaming polymer. After the sound insulation material, use the sound wave of 1〇〇~5〇〇〇Hz for the 2 4 sound insulation test' test results are as follows: Acoustic frequency sound wave refers to the energy consumption scene 100 ~ 200Hz ^ about 30dB, but part is less than 3〇dB 200~300 Hz 35dB~42dB between 300-500 Hz 35dB~45dB between 500~1000 Hz 40dB~45dB between 1000~2000 Hz 4(MB~47dB between 2000-3000 Hz 40dB~45dB between 3000~5000 Hz 40dB~ 45dB [Example 2] 7 201217305 Change water and foaming agent Proportion, the raw materials are as follows: Raw material ratio kaolin soil 32.4wt% Hearth powder 13.9wt% Sodium hydroxide 8.2wt% Sodium citrate solution 24.2wt% Water 17.3wt% Foaming agent 4wt% The same step and mixing time to make the molding After three sound insulation test results are as follows: Acoustic frequency _ Acoustic wave loss energy _ 100~200Hz 35dB~47dB between 200~300 Hz 45dB~52dB between 300-500 Hz 45dB~55dB between 500~1000 Hz 45dB~50dB 1000~2000 Hz 43dB~50dB between 2000~3000 Hz 44dB~48dB between 3000~5000 Hz 43dB~48dB [Example 3] 201217305 Change the ratio of each raw material, the raw materials are as follows: Raw material ratio kaolin 32wt% furnace Stone powder 14wt% sodium hydroxide 8wt% sodium citrate solution 24wt% water 16wt% foaming agent 5wt% other components lwt% After the same step and mixing time to make the molding, the three sound insulation test results are as follows: Acoustic frequency _ acoustic loss energy _ 100~ 200Hz 35dB~45dB between 200~300 Hz 45dB~50dB between 300~500 Hz 48dB~53dB between 500-1000 Hz 46dB~50dB between 1000~2000 Hz 44dB~51dB between 2000~3 000 Hz 44dB~47dB between 3000~5000 Hz 43dB~47dB between 201217305 ^ To the second example of the sound insulation test result graph, as shown in the fourth to sixth figures, the dB value is the sound wave entering the inorganic foam Polymer sound insulation material in the moonlight her size (energy loss: Sna (6) dB, where L is the incident sound wave intensity 'L is the penetrating sound wave intensity), the higher the value indicates the greater energy loss, 7 value and sound insulation effect The description is as follows: When the dB value is less than 30: normal conversation is easily caused by 5 sound insulation effects. When the dB value is between 30 and 35: normal conversation is not easy to be soundproofed. When the value is between % and 45: normal conversation ‘, loudly 4 is not easy to be heard, the sound insulation is good. When the book value is greater than Μ: the normal cross-talking voice is turned to _, the sister is very good. As can be seen from the fourth figure, the inorganic foamed polymer sound-insulating material of the first example is as follows. The p-knife is above 3〇dB, indicating good sound insulation. For example, the inorganic hair suture sound-insulating material has a sound-proof test result as shown in the fifth figure. It can be seen that the test results are greater than % and most of them are greater than 45 dB. Example 1 of the inorganic foamed polymer sound-insulating material, the sound-damping test results are as follows, and the test results are similar to the data 2, all of which are larger than 3 Na and most of which are from 45, also have good sound insulation effect. . It can be seen from the examples - and three that, under the condition that the overall strength is not affected, increasing the _ of the foaming hair will increase the sound insulation effect. The above description is only a few preferred embodiments of the present invention, and the equivalent structure and manufacturing method variations of the present invention and the scope of the patent application are included in the patent scope of the present invention. 201217305 [Simple Description of the Drawings] The first figure is a flow chart of a preferred embodiment of the present invention. The second figure is a schematic view of the sound insulation of the above preferred embodiment of the present invention. The third figure is a test graph of the first preferred embodiment of the present invention. The fourth figure is a test graph of the second embodiment of the preferred embodiment of the present invention. Figure 5 is a test graph of Example 3 of the preferred embodiment of the present invention described above. [Main component symbol description] 1~3 sound wave 20 inorganic foaming polymer soundproof material 21 surface 22 bubble body