TW201209496A - Electrochromic module combined with organic and inorganic materials and display device combined with the module - Google Patents

Abstract

The invention provides an electrochromic module combined with organic and inorganic materials and a display device combined with the module. The display device has the electrochromic module installed on a surface of an image display module. The electrochromic module includes a first transparent substrate and a second transparent substrate, and a transparent conductive element and an electrochromic layer disposed between the substrates, and the electrochromic layer is made by mixing an organic material and an inorganic material in a solvent. With the transfer of electrons between the organic and inorganic materials, the valence of ions of the materials is changed. By gaining electrons for a reduction, and losing electrons for an oxidation, a color change is achieved, so as to have the advantages of high speed and uniformity in color change, and a relatively low driving voltage. In addition, the organic material is a redox indicator or an acid-base indicator, and the inorganic material is an oxide, sulfide, chloride or hydroxide of a transition element. The electrochromic layer further includes at least one inert conductive salt, and the inert conductive salt is a lithium, sodium, or tetra-alkylamine salt. The first transparent substrate further includes a plurality of first transparent conductive elements arranged with an interval apart from each other and disposed on the first transparent substrate. The second transparent substrate further includes a second transparent conductive element disposed on a surface of the second transparent substrate.

Description

201209496 VI. Description of the Invention: [Technical Field of the Invention] An electrochromic module, in particular, an electrochromic module incorporating organic and inorganic materials and a display device using the electrochromic module. [Prior Art] According to the electrochromic (EC) material, it means that the electrochromic material undergoes light absorption or light scattering under the action of electric current or electric field, thereby causing a reversible change in color. The electrochromic module of the prior art, as shown in FIG. 1 , is provided between the two transparent substrates ® 31 and 32 respectively with first and second transparent conductive elements 311 and 321 between the substrates 31 and 32. An electrolyte layer 34 and an electrochromic layer 33 are interposed, or as shown in FIG. 2, another electrochromic layer 33 is further added as an ion storage layer and an auxiliary color changing layer, and the electrochromic material is The material types can be divided into inorganic electrochromic materials and organic electrochromic materials. In practical applications, the following characteristics are required: (1) good electrochemical redox reversibility, (2) fast color response time, and (3) color change. Reversible, (4) high color sensitivity sensitivity (3) long cycle life, (6) a certain storage memory function and (7) good chemical stability. _ f know the structure of the electrochromic module, its material (4) (10) to do elemental oxide or hydroxide or its organism to make an inorganic solid film or mixed with organic compounds / electrolyte materials into a composite material, through the electrons and additional ions Source (such as electrolyte or second electrochromic material) to make ions into the effect of the lattice towel, the force WQ3, μ (〇η) 2, Prussian blue and so on. In addition to the above-mentioned & some electrochromic materials, the inorganic electrochromic material has an energy-detecting enthalpy, and its light absorption change is caused by the recording and electron double-shaped and cooked "caused, there is _ electric ray color material, including poly-amine, violet Fine and rare earth ugly cyanine, its color has a variety of richness, is also 201209496 using organic matter itself redox reaction, although the speed is faster than inorganic materials, but also has environmental and toxicity problems; and the above-mentioned conventional electric The patents for the discoloration mechanism and structure are as follows: "Electrochromic film" of the Republic of China Bulletin No. 73131, "Electrochromic display device" of No. 1289236, and the like. The general stereoscopic image display technology uses the binocular disparity to receive different images through the left and right eyes, and finally merges into a stereo image in the brain. In the naked-eye stereoscopic display technology, the structure can be roughly divided into a columnar lens (Lenticular) and a light barrier type (Barrier), and an electrochromic material is used to achieve a light barrier (Barrier), and has a switching display stereoscopic image or The three-dimensional image display device of the flat image, such as: the Republic of China Patent Gazette, the bulletin No.] No. VI368088, "Integrated Electrochromic 2D/3D Display", No. M371902, "Switching 2D Plane Image / "Display device for 3D stereoscopic image display screen", Bulletin No. 1296723, "Color filter for liquid crystal panel capable of forming a stereo image and its manufacturing method" and U.S. Patent Gazette, No. 2〇〇6〇87499 "Autostereoscopic 3D display device and fabrication method thereof" and the like 'all of the above patents use electrochromic materials as parallax barrier devices for displaying stereoscopic images', but the common defects in the structure of M368088 and M371902 are lack of electrochromic devices. Necessary electrolyte layer, electrochromic device will not be able to provide ions to the electrolyte layer of the electrochromic layer The oxidation or color reversal of the reversible anti-lying silk coloring or color change, so these patents should not be practically implemented; in addition, the transparent electrode layer and the electrochromic material layer of the parallax barrier device are set as a fence pattern, and the manufacturing process thereof The layer coating of the towel, the reduction of the key or the surname of the towel, even the stack must be accurately aligned, the process is quite complicated, and all the layers of the 201209496 layer are set as the barrier pattern, resulting in the formation of each gate barrier and the barrier The hollow area will affect the overall light penetration, refraction or reflection, even if it is a general 2D display, it may also affect the image of the display f 'causes the brightness problem of color money; and 1296723 is - embedded in the liquid crystal display and formed In the structure of the color light-receiving sheet, and the electrochromic layers in all of the above patents are applied to the conventional electrochromic material and the color-changing mechanism, a large driving voltage is required, so that material defects and short service life are easily caused. problem. SUMMARY OF THE INVENTION In view of the above needs, the inventors have carefully studied and accumulated many years of experience in the business, and finally designed the electrochromic module and combination of the "he-he" Display device of the module". The object of the present invention is to provide an electro-deformation module which reduces the freshness and simplifies the remainder. SUMMARY OF THE INVENTION It is an object of the present invention to provide an electrochromic module that does not require an electrolyte. SUMMARY OF THE INVENTION The object of the present invention is to provide an electrochromic module having a fast (four) color, a high cycle life and a low driving voltage. The objective is to provide an electrochromic module that has the advantages of an organic/inorganic electrochromic material but has no disadvantages. The object of the invention is that the color-changing material of the electrochromic module of the present invention is in a solvent-mixed organic compound and the domain (4) (4), and the (four) material contains a redox indicator, and the inorganic material contains a transition element. (including 铳 sub-group _), Qin sub-group 201209496 (IVB), Syrian sub-family (VB), chrome sub-family (VIB), manganese sub-family (νπΒ), iron system (VIII), copper sub-family (IB), An inorganic derivative such as an oxide, a sulfide, a vapor, or a hydroxide of a subgroup (IIB) or a platinum group (vm), and a halogen (VIIA), an oxygen group (VIA), or a nitrogen group (VA) One of the inorganic derivatives such as carbon (IVA), boron (IIIA), alkaline earth (ΠΑ), alkali metal (IA), etc., the color change mechanism is formed by organic and inorganic materials to form a complementary system. In this system, the conductive element extracts electrons to cause a reduction reaction of the organic material in the electrochromic material, and the potential energy of the radical or ionic state after the reduction is different from the potential energy of the ions of the inorganic material. The ions are transferred to the inorganic ions, and the valence of the material is changed to change color, and the valence is reduced by electrons to produce reduction and electron elimination. The concept of oxidization is lost, so that the rate of electrochromism is fast, uniform, and the driving voltage is small and the life is high. In order to achieve the above object, the present invention relates to an electrochromic module comprising a combination of an organic and an inorganic material, a third transparent substrate, a second transparent substrate, and an electrochromic layer disposed between the transparent substrates. And at least a transparent conductive element, wherein the transparent conductive element can be disposed on the surface of the first transparent substrate, or can be disposed on the surface of the second substrate, or simultaneously disposed on the first transparent substrate and the second transparent substrate The surface of the electrochromic layer undergoes a color change by changing the ion valence by the electrons provided by the transparent germanium conductive element and the complementary mechanism of the electrochromic material itself. Another object of the present invention is to provide a display device that switches between 2D image and 3D image display state. Another object of the present invention is to provide a display device which increases the contact area of an electrochromic module with an electrode and increases the rate of discoloration. In order to achieve the above object, the present invention combines the electrochromic module described above with an image display module 6 201209496 to form the display device. When the display device is converted from a planar image to a stereoscopic image, the image is divided into The left eye image and the right eye image, at this time, the transparent conductive element is turned on, so that the color of the electrochromic layer is transparent, and the light shielding area is dark and arranged according to the interval of the electrochromic module. The color-changing module generates a plurality of light-shielding regions arranged at intervals, and the images of the light-shielding regions are divided into three-dimensional images of the left-eye image and the right-eye image, and the partial image of the image is removed through the light-shielding region, and after receiving by the naked eye, No creases are formed and a stereoscopic image is formed. • For the above purpose, when the electrochromic module is used as a mask for a stereoscopic image display, the electrochromic layer is disposed in a plurality of spaced-apart arrays, and the electrochromic modules can have three settings. In the first mode, the conductive polymer is mixed in a screen printing manner, and the first method is to block the electro-chemical layers into a plurality of strips, and the second method is directly The transparent conductive element acts as a blocking unit; the light-shielding region of the grating is generated by the above three methods to form a light-shielding region (Ban> ier). In general, the three-dimensional image display is additionally provided with a Lenticular lens or a Barrier device on the display, but by the invention, an electrochromic module combining organic and inorganic materials is combined with the device. The display device of the module can display a stereoscopic image that has been divided into a left eye image and a right eye image directly by the display device when the stereoscopic image is displayed. [Embodiment] In order to make the reviewer understand the contents of the present invention, please refer to the following description. Please refer to FIG. 3 for a perspective view of a first embodiment of the present invention. The electrochromic module 1 of the present invention includes a first transparent substrate 11 as shown in the figure. a second transparent substrate 12 and an electrochromic layer 13, wherein: the first transparent substrate 11 is provided with a first transparent conductive element 111, and the first transparent substrate 11 and the second transparent substrate 12 are The material is plastic, polymer plastic, glass or is selected from the group consisting of resin, polyethylene terephthalate (PET), polycarbonate (Poly Carbonate, PC), polyethylene (PE), Polymerization of Poly Vinyl Chloride (PVC), Polypropylene (PP), Poly Styrene (PS), Polymethylmethacrylate (PMMA) or a mixture thereof One of the materials; and the material of the first transparent conductive element 111 is selected from indium tin oxide (IndiumTin)

Oxide, ΙΤ0), Indium Zinc Oxide (ΙΖ0), zinc oxide aluminum (A1-doped ZnO 'ΑΖ0) or antimony tin Oxide (Antimony Tin Oxide, ΑΤΟ) is a doped oxide (Impurity-Doped Oxides) One of the groups is either a carb〇n nanotube. The electrochromic layer 13 is disposed between the first transparent substrate 11 and the second transparent substrate 12 to cover the first transparent layer. The surface of the conductive element 111, and the material of the electrochromic layer 13 is made of a mixed organic material and an inorganic material in a solvent. The electrochromic layer 13 utilizes the effect of complementing the organic material and the inorganic material, so that it has both The characteristics of oxidation and reduction reaction, the original cost of discoloration is provided by conduction, so that the electric-color material cap is transferred and transmitted by electrons, so that the valence of the ion is changed and discolored, and the valence is reduced by the electron supply, and the electron disappears. Oxidation concept, the color change mechanism is achieved compared with the migration and migration of electrons and ions in the conventional electrochromic system. The electrochromic speed of the present invention is fast and uniform, and the driving voltage is small and the life is 201209496. Organic material comprises a redox indicator (Red0X Indicat〇r), pH indicator (acid-base indicator) and the like. Among them, redox indicator (Red〇x indicat〇r) is an indicator used in redox titration, which can produce significant color change at a specific electrode potential, and is generally an organic reagent having redox properties. Oxidation and reduction have different colors, there are two kinds of oxygen decompression readings: metal organic complexes, organic redox systems, all redox indicators and organic redox systems involve protons ( That is, H+) is a participant in the electrochemical reaction. Therefore, depending on the characteristics, the oxidation can be further divided into two pH-dependent redox indicators and a pH-independent redox indicator. The pH-independent redox indicator comprises: 2, 2,-bipyridinium complex ion '5-nitro-phenanthroline argon ion, N-phenyl anthranilic acid, hydrazine, 1 ()_ Erlin ferrous tin, wool red, paraquat, 2, 2'-bipyridyl ferrous ion, 5, 6-dimercapto phenanthroline complex ion, 3' 3' ~ didecyloxy Benzidine, sodium diphenylamine sulfonate, N, N, _ bis phenylamine, diphenylamine, viologen, etc., but some of the indicators are toxic; and the pH-dependent redox indicator comprises: Phenol sodium, o-cresol sodium, sulphur, indigo, indigo tetrasulfonic acid, indigo trisulfonic acid, indigo carmine, indigo monosulfonic acid, phenol red, safranin T, neutral red, and the like. Among them, the acid-base indicator is a chemical reagent used to test the pH value. It is a collision or a pigment. In the case of a human solution, the pigment is combined with hydrogen ions or nitrogen oxide ions to be converted into corresponding Acidic or test, thus showing different shades, because Qiu 俨 shows a reversible color change in solution at different pH values, so in the neutralization analysis, the end point of the reaction is indicated, and the pH of the test solution can be determined in the laboratory. Commonly used Qiu indicator package 201209496 contains: phenol red, Congo red, methyl orange, phenolphthalein, thymol blue, litmus, methyl violet, malachite green, methyl yellow, bromophenol blue, bromocresol green, Methyl red, bromocresol purple, bromothymol blue, Thymolphthalein, alizarin yellow R and the like. Preferred embodiments of the electrochromic layer of the present invention are Methylene blue (CieHieClNaS-SHzO), Dichlorophenolindophenol sodium (dCMNaO), and a pH indicator using the above redox indicator. Variamine Blue B Diazonium salt (C13Hi£1N3〇). The material of the solvent may be one of dimethyl sulfoxide (CHASO), propylene carbonate (C4H6〇3) or water (H2〇). The inorganic material is an oxide or sulfide of a transition metal. One of inorganic derivatives such as vapors and hydroxides; or may be halogen (VIIA), oxygen (VIA), nitrogen (VA), carbon (IVA), alkali (ΙΠΑ), social mail A One of the money touches of the age group (IA). Among them, the transition metal element includes, sub-group (IB), zinc sub-group (ΠΒ), sharp sub-group (ΠΙΒ), titanium sub-group (IVB), hung subfamily (VB), chrome sub-family (VIB), fierce Subfamilies (νι(8), Iron (VIIIB) and the beginning (fifth and sixth cycle vjiib), etc. The above various families are exemplified as follows: Halogen (British VIIA): s〇hd: h Charm; IC1 Charm·' iBr charm; IF3 yellow; ICh orange; l2〇5 white; geosteam (ion crystal); 〖4〇9 yellow (ion crystal) oxygen group (英VIA):

Solid ’· S ϋ child; Se ash, brown; Te colorless metallic luster; Na2S, (10) 4) 2S, KzS, secret white 201209496 soluble; ZnS white! MnS meat red i; FeS black j; PbS black j; CdS yellow j; ShSa orange red 1; SnS brown 4; HgS black (precipitate), red (cinnabar); Ag2S black j; CuS black j; like 2&White;Na2&〇4white; Se〇2 white, volatile; SeBr2 red; SeBr4 yellow; Te〇2 white heating yellowing; MeCb white; TeBn brown; TeBn orange; Teh gray black; P〇〇2 low temperature yellow ( Face-centered cubic), high-temperature red (quartet); S〇3 colorless; Se〇3 colorless and easy to deliquesce; Te〇3 orange; H6Te〇6 colorless nitrogen group (English VA):

Solid salt colorless crystal 'nitride metal white; 〇 3 blue (low temperature); n2 〇 5 white; p white red, black; white; P2 〇 5 white; PBr3. yellow; PI3 red; pCl5 colorless; p4Sx yellow; secret gray yellow; secret yellowish; · Ο colorless glass; Μ〇 2 white; As ash; As2 〇 3 white; As2 〇 5 white; Ash red; AsA red (realgar); As4S6 yellow (girl); As2Ss yellowish; Sb silver white; Sb(0H)3 white i; Sb2〇3 white (white, pigment); Sb2〇5 yellowish; SbX3(X<>I) white; sbl3 red; Sb2S3 orange red i; SbA Orange yellow; Bi silver white slightly red; Bh〇3 light yellow; Η · red brown; BiF3 gray white; BiCla white; BiBn yellow; Bih black i; Bi2S3 brown black. Carbon family (English IVA):

Solid : C (diamond) colorless and transparent; C (graphite) black metal luster; Si gray black metal luster; Ge gray white; Sn silver white; Pb dark gray; Si〇 2 colorless and transparent; H2Si〇3 colorless transparent colloidal enamel;

Na2SiF6 white crystal, GeO black; Ge〇2 white; SnO black; Sn〇2 white; Sn(0H)2 white i; Pb yellow or yellow red; Pb crystal inspection; Pb must be red; Pb〇2 sweep; CBn light Yellow; Cl4 reddish; Geh dial; yellow, GeF4 white; GeBn gray; Geh yellow; SnF2 white; SnCl2 white; SnBn yellow; Snh orange; SnF4 white; SnBn colorless; Snl4 red; PbF2 colorless | ; pbCh white i; pbBr2 White; PbL·Golden; PbF4 colorless; GeS red; GeS2 white; SnS brown i; secret golden (commonly known as "golden powder")! ' PbS black i ; PbS2 reddish brown; Pb (N〇3) 2 colorless; Pb (Ac) 2 · lion colorless crystal; 11 201209496

PbS〇4 white i; PbC〇3 white i; Pb(0H> white i; Pb3(C〇3)2(OH)2 lead white i; PbCr〇4 bright yellow 4 . . , boron family (English): 3〇1丨 (1:6 (amorphous) brown powder; 8 (crystal) black ash; human 1 silver white; (; 3 silver white (easy to liquefy);

In silver ash; T1 silver ash; B2 〇 3 glass; H3B 〇 3 colorless flake; BN white; Na2B4 〇 7 · 10H2 〇 white crystal; Cu (B 〇 2) 2 blue! Ni(B〇2)2 Green 4; NaB〇2 · Co(B〇2)2 Blue 4; NaB〇2 · 4M) Colorless crystal; anhydrous NaB〇2 yellow crystal; Ah〇3 white crystal; A1F3 colorless; AlCh white; AIBn white; A1L· standard; A1(0H)3 white i; Ga2〇3 white i Ga(0H)3 white i; GaBn white; Gah yellow; Ιπ2〇3 yellow; InBr3 white; Inl3 yellow; T10H yellow ; Tl2 〇 black; Tl2 〇 3 brown black; T1C1 white i; TIBr light yellow i; Til yellow i (similar to silver); TlBn yellow; T1I3 black. Alkaline soil (English): Elemental: Silver white flame: Ca brick red ;Sr magenta; Ba green. Oxide: all white solid. Hydroxide: white solid Be(〇H)2 j,MgCOIOd . ^ Salt: mostly colorless or white crystal; BeCL·light yellow; BaCr〇4 yellow I; CaF2 white I. Alkali metal (English): Elemental: silver white flame color: Li red; Na yellow; Κ purple; Rb purple red; Cs purple red. Oxide, peroxide, superoxide, ozonide: Llo white ; like 2 white; K2O yellowish;

RhO bright yellow; Cs2〇 orange red; Μ-light yellow; K〇2 orange yellow; Rb〇2 deep sweep; Cs〇2 dark yellow; K〇3 orange red. hydroxide: white, Li〇H white I. 12 201209496 salt : mostly colorless or white crystals and soluble in water. Insoluble salts! (Not specified are white crystals): LiFLi2C〇3Li3P〇4LiKFeI〇6Na[Sb(OH)6] - NaZn(U〇2)3(Ac)9 · 6H2〇 Yellow green; M=K, Rb, Cs M3 [Co(N〇2)6] bright yellow; MBPh4 MCl〇4 ifcPtCle yellowish; CsAuCh. copper subfamily (English IB): elemental: Cu purplish red or dark red; Ag silver white; Au golden. Copper compound: flame green; CuF red; CuCl white j; CuBr yellow j; Cul brown yellow I; CuCN 0 white enamel; Cu2 〇 dark red; Cu2S black; CuF2 white; CuCh brown yellow. (solution yellow green); CuBn brown; Cu (CN) 2 brown Yellow; CuO black i; CuS black I; CuS〇4 colorless; CuS〇4 · 5H2 indigo; Cu(0H)2 pale blue 4; Cu(0H)2 · CuC〇3. dark green; [Cu(H2〇) 4] 2+ blue; [Cu(0H)4] 2_ blue purple; [Cu(NH3)4]2+ dark blue; [CuClJ 2 - yellow; [Cu(en)2] 2+ dark blue purple; Cu2 [Fe (CN)6] brown red; alkyne copper red i. Silver compound: AgOH white (normal temperature decomposition); Ag2 black; new AgOH brown yellow (mixed with Ag2〇); protein silver (AgN〇3 drops on hand) black j AgF white; AgCl white j; AgBr light yellow | ; Agl yellow I (colloid); Ag2S black! Ag4[Fe(CN)6] white j; Ag3[Fe(CN)6] white j; Ag+, [Ag(NH3)2] φ +, [Ag(S2〇3)2]%[Ag(CN) 2] - colorless. Gold compound: HAuCL · · 2 bright yellow crystal; KAuCl4 · 1 · 5H2 〇 colorless flaky crystal; Au2 〇 3 black, H [Au (N 〇 3) 4] · 3H2 〇 yellow crystal; AuBr gray yellow j; Aul #檬黄j. The subfamily (I Ying IB): Elemental: all silver, the precipitation in aqueous solution is black. Zinc compound. ZnO white (white pigment) 丨; zni2 colorless; zns White 4; ZnCl2 white crystal (very soluble, acidic in aqueous solution); KaZm [Fe(CN)6] white; Zn3 [Fe(CN)6]2 yellow brown · Recorded compound: cd ash ash i; (four) yellow; CdS yellow (mine yellow pigment) n HgCh (mercury) white 13 201209496 color; HgNHzCl white 1; Hg£l2 (calomel) white i _ Zhu compound: Hg blush (large grain) or yellow (small grain) 丨; HgI2 Red or yellow (slightly soluble); HgS black or red sputum; Hg2NI · H2 〇 red 丨; Hg2 (N 〇 3) 2 colorless crystals.

ZnS glory powder: Ag blue; Cu yellow green; Μη orange. Titanium subfamily (British IVB): Qinhua. Titanium red; [TiOOM) 2) 2] 2+ orange; Mi 〇 3 white j; Ti 〇 2 white (titanium white pigment) or peach red (rutile) 丨; (NH 4 ) 2 TiC16 yellow crystal; [Ti (H2 〇)6]cl3 purple crystal; [Ti(H2〇)5Cl]Cl2 · H2〇 green crystal; TiCl4 colorless fuming liquid. Lead, antimony: M〇2, MCl4 white. Vanadium subfamily (British VB): vanadium compound :r purple; v3+green; vo: blue; V(0H)4 yellow; V〇43 yellow; V0 black; V2O3 gray black, V2S3 brown black; ν〇2 blue solid; vf4 green solid; vcl4 dark grazing liquid ;νβΓ4 magenta liquid; V, 〇5 yellow or brick red; hydrated threat brownish red; saturated m solution (slightly soluble) yellowish; [V〇2(〇2)2]3_黄; [ν(〇2) 3]3-Red-brown. Hunger root polycondensation: With the decrease of the ratio of the number of hens and oxygen atoms, from light yellow to dark red to light yellow. Sharp, group: slightly. Chromium sub-family (British VIB): Chromium compound: Cr2+ Blue; Cr: purple; Cr2072· orange red; 〇042-yellow; Cr(OH)4-bright green; Cr(0H)3 gray-blue; Cr2〇3 green; Cr〇3 dark red needle; [Cr〇(〇 2) 2] 〇 Eb blue; c ritual 2 dark red liquid; Ag2Cr 〇! monument red I; BaCr 〇 4 yellow I; PbCr 〇 4 yellow i.

Body; %2Cn〇7, LCrCh orange red; purple red Cn(S〇4)3 · 18H2〇—201209496 light green [Cr(H2〇>Cl]Cl2, [Cr(H2〇)6]3+ purple; tCr( H2〇XNH3)2]3+ purple red; [Cr(H2〇)3(NH3)3]3+ light red; - [Cr(H2〇)2(NH3)4]3+ orange red; [Cr (chaos) pool 0]3+ orange yellow; [Cr(NH3)6]3+ yellow. Molybdenum, tungsten: Mo〇3 white; brown MoCh; green MoCh; M0S3 brown!; (intestine) 3 [Ρ(Μοΐ2〇4〇)]· 6H2〇 yellow crystal form j; w〇3 deep yellow; leg 〇4 · xH2〇 white colloid. Shovel subfamily (British VIIB): Manganese compound: Mn2+ meat red; Mn3+ purple red; ΜηΟΛ green; MnO4- violet; Μη03+ bright green ;Mn(0H)2 φ white I; MnO(OH)2 brown!; Mn〇2 black I; anhydrous manganese salt (MnS〇4) white crystal; manganese hexahydrate salt (ΜηΧ2 · 6H2〇, X=halogen, N 〇3, Cl〇4) pink; MnS · nH2 〇 meat red I; anhydrous MnS dark green; MnCCb white i; Mm(P〇4)2 white I; KMn〇4 purple red; K2Mn〇4 green; K2 [MnFe] Gold yellow crystal; MmO? brown oily liquid. 鍀, 铢: slightly · iron system (fourth cycle VIII): iron compound: Fe2+ light green; [Fe(H2〇)6]3+ light purple; [Fe( OH) (H2 〇)5]2+ yellow; FeO, purple φ red; FeO black; Fe2〇3 dark red; Fe(0H)2 chalk; Fe(0H)3 brown red enamel; FeCh or FeCl2 crystal brown red blue; anhydrous FeS〇 4 white; FeS〇4 · 7H2〇 green; L[Fe(CN)6] (yellow blood salt) yellow crystal; K3 [Fe(CN)6] (red blood salt) red crystal; Fe2 [Fe(CN)6 】Prussian blue | ; Fe [Fe(CN)6] black | ; Fe(C5H5)2 (ferrocene) orange-yellow crystal; M2Fe6(S〇4)4(OH)12 (yellow iron, M=NH4, Na, K) light yellow crystal; Fe(C0)5 yellow liquid. Cobalt compound: Co2+ pink; C〇0 gray green; C〇3〇4 black; Co(0H)3 brown | ; (:〇(01〇2 Pink 4; Co(CN)2 red; K4[Co(CN)6] purple crystal; C〇2(C0)8 yellow crystal; [Co(SCN)6] violet; vaporized cobalt dehydration discoloration: pink CoCh · 6H2 〇—325K—> purple red CoCh · 2H2〇—313K—> 15 201209496 blue purple CoCl2 · H2〇—393K—>blue CoCl2. Nickel compound: Ni2+ bright green; [Ni(NH3)6]2+ violet; Ni( 0H)2 green i; Ni(0H)3 black 4; anhydrous, Ni(II) salt yellow; Na2[Ni(CN)4] yellow; K2[Ni(CN)4] orange; Ni(C0)4 colorless liquid .-Platinum elements (fifth and sixth cycle VIII): 〇s blue Color volatile solid; Pd^(aq) black; 〇s〇4 colorless with special odor gas; HetCl6 red crystal; NaftCh orange yellow crystal; M2PtCl6 (M=K, Rb, Cs, NH4) yellow I. Among the compounds, the inorganic material of the present invention is preferably one of vaporized ferrous iron (FeCh), iron trioxide (FeCl3), titanium trioxide (TiCl3) or titanium tetrahydrate (Ticl4). The color change mechanism is as follows: dissolving iron σβ1〇 and yttrium blue in dimethyl hydrazine (DMS0) to form a complementary age electrochromic solution, and the color of the second liquefied iron crystal is blue (Fe2+ is blue) Color), the surface oxidation will form a reddish brown color (Fe3+ is light yellow), and the secondary iron is dissolved in the solvent 'that is, because the oxidation changes from Fe2+ to Fe3+, the solvent becomes pale yellow, and the first transparent conductive element 111 supplies electrons. When the indigo blue molecule Luin close to the first turn-on conductive element i n obtains electrons and produces a county reaction, the indigo blue becomes self (four), and the potential energy of 'Fe3+ and methylene blue free radicals' is different when the external voltage is removed. Will spontaneously pass from the methylene blue free radical to Fe+, then the pale yellow Fe3+ is reduced to blue Fe2+, p. 'The entire electrochromic layer 13

In addition, the electrochromic layer 13 prepared as described above has a multi-dead state, and can also be mixed with electricity by a high conductivity of 1.1 Ι?λ3+ _ 〇, · Α4- ^ τι 3+ ^ a . . . . 201209496 Color-changing inks, used in conjunction with screen printing. Referring to the "4th, 5th, and 6th drawings", the transparent conductive element structure shown in the first preferred embodiment of the present invention is _-~3, which is the setting of the conductive element in the electrochromic module. When the method has a transparent conductive member on the substrate (as shown in FIG. 4), it is preferred to arrange the transparent conductive member in a plurality of spaced intervals and interleavely give electric potentials of different potentials to a voltage difference between the electrodes to provide electrons required for discoloration of the electrochromic layer, and also for the first and second substrates u, 12

The electrical components m, 121 are disposed in such a manner as to sandwich the electrochromic layer 13 (as shown in FIG. 5), or the transparent conductive elements (1) and 121 may be disposed on the first and second transparent substrates at a plurality of intervals ( As shown in Figure 6). The above-mentioned electrochromic display can be regarded as a display, an e-book, a thin D display device, a rear view mirror and a smart glass. The frequency is shown in Fig. 7, which is the second preferred embodiment. The application of the invention is based on the application of the flat/vertical display device. The display device of the present invention combines the electrochromic module into an image display module 2, The image display module 2 is configured to display a planar image and a stereoscopic image, and the displayed stereoscopic image can be generated by using a software, an I body or a hardware technology, for example, converting the planar image into a software or a body. The image display device 2 can be a liquid crystal display (LCD), a plasma display (PDP), or a surface conduction electron emission display (Surface c〇nducti). 〇n

Electron-emitter Display, Sf: D), Field Emission Display (Field Emission)

Display ' FED) 'yacuum Flu〇rescent Display (VFt)), 17 201209496 Organic Illumination · One-pole Display. (f) r£rjimV T ; rrh+ P .· w "Organic Light-Emitting The electrochromic module 1 is coupled to the surface of the image display module 2, and includes a first transparent substrate 12 and a second transparent substrate 12 And the plurality of electrochromic layers 13, wherein: the first transparent substrate 11 is provided with a first transparent conductive element 111, and the second transparent substrate 12 is provided with a second transparent conductive element 121, the electrochromic layer 13 is caused by the electrical conduction of the first and second transparent conductive elements (1), 121 to produce a color change, but for the sake of illustration, for example, a plurality of transparent conductive elements may be disposed on the single substrate, as long as each _ - The electrochromic layer 13 is simultaneously contacted with transparent conductive elements having different potentials, so that the electrons can be injected and transferred in the electrochromic layer when discolored. The materials of the first transparent substrate 11 and the second transparent substrate 12 And the first transparent conductive member 111 The material is as described above and will not be described here. The electrochromic layer 13 is made of a solvent-dissolving organic compound (IV) and an inorganic material. The organic material may be a redox indicator (Red〇x Indicat〇). r) A pH-indicator, etc., the present invention preferably uses methylene blue _ blue, C16H18C1N3S.3_, sodium diphenol phenolate sodium (Dichl〇r〇phen〇lind〇phen〇1 sodium ' Ci2H6Cl2NNa〇2) and Variamine Blue b Diaz〇nium salt (CuibClfU), etc., and the inorganic material may be selected from transition elements (including bismuth subgroup (IIIB), titanium subgroup (IVB) ), vanadium subgroup (VB), chromium subgroup (VIB), manganese subgroup (VIIB), iron system (vm), copper subgroup (IB), zinc subgroup (ΠΒ) or platinum (VIII), etc.) An inorganic derivative such as an oxide, a sulfide, a vapor, or a hydroxide may be selected from the group consisting of a halogen (VIIA), an oxygen group (VIA), a nitrogen group (VA), a carbon group (IVA), and a boron group (ΠΙΑ). Inorganic derivative such as alkaline earth (ΠΑ), alkali metal (IA), etc. 201209496 One of the preferred embodiments of the invention uses ferrous ferrous (FeClz), ferric chloride (FeC丨3) Three gas One of titanium (TiCL·) and titanium tetrachloride (TiCh); and the solvent may be selected from dimethyl sulfoxide ((CH3)2S0), propylene carbonate (C4·) or water (out of 0). Compared with the general inorganic electrochromic layer, the inorganic electrochromic layer of the present invention requires ion and electron double loading into the crystal lattice, and requires a large driving voltage, so the solution causes defects in the material, and the lifetime is only about one or two thousand. Secondly, the concept of the present invention can be changed only by the valence of ions in the electrochromic material, not only the driving voltage is small, but the material does not produce defects, and the lifetime can reach 30,000 times. Combined with the image display module, as a mask for 2D/3D image display, the image display requires higher resolution and light transmittance, and the electrochromic layer of the present invention does not compare with the conventional electrochromic multilayer structure. It is necessary to combine an electrolyte or other auxiliary color-changing layer, thereby greatly reducing the thickness thereof and thereby increasing the light-emitting rate. Please refer to FIG. 8 and FIG. 9 for a schematic structural view of a transparent conductive member according to a second preferred embodiment of the present invention. Second, the transparent conductive members (1) and (2) may be integrally disposed on the transparent substrate U. And the surface may also be arranged according to the position and the number of the electrochromic layers η arranged at the plurality of intervals, and the corresponding transparent conductive elements % w color-changing ink are arranged correspondingly at a plurality of intervals, and are matched with the net a plurality of blocking units 15 are disposed between the electrochromic layers 13 of the third preferred embodiment of the navigation device structure, and the second embodiment of the invention The barrier sheets divide the electrochromic layer 13 into strips _, the blocking unit U __ η is in the ridge area formed by the blocking unit 5, and the stray unit can be - photoresist. 201209496 凊Reviewed in Figure 12, the fourth structure of the present invention is a fine-transparent conductive such as ruthenium as a barrier sheet =:== the function of the gray layer 13, and the electrochromic layer can also be added! :_' As shown in Figure 13, it is _-transparent conductive =: 彳上^图, as shown in the figure, on the substrate u, two sets of conductive elements arranged in the outline are arranged, and the structure is a three-dimensional structure - Secondly, the turned conductive elements may form a state like a spacer (as shown in FIG. 14), or a plurality of receiving grooves may be formed (such as the 15th pain, and the electrochromic layer 13 is disposed in each receiving groove). It should be noted that the transparent conductive elements of different potentials are not in contact with each other and are arranged at intervals in a staggered manner. As shown in Fig. 16, a cross-sectional view of a fifth preferred embodiment of the present invention will be 1. The first and the first transparent conductive elements 1U and 121 are disposed on the surface of the first and first substrates 11 12 at a plurality of intervals, and a plurality of spatial regions are generated between the transparent substrates. The color changing layer 13 is respectively disposed in the plurality of spatial regions, and the above-mentioned device (4) is simultaneously used as the blocking unit by the first and second transparent conductive elements u and (2): as shown in Figs. No, it is a structural view of the conductive element of the fifth preferred embodiment and 'that is, the first transparent conductive element (1) and the second transparent conductive elements (2) are arranged at a staggered interval, and the first transparent conductive elements m give a positive voltage, and the second transparent conductive elements 121 give a negative voltage. And vice versa, so that a voltage difference is formed between each of the electrically conductive 7G members arranged in a strip shape, but this arrangement is merely exemplary, and other corresponding various modifications and variations are included in the patent scope of the present invention. In summary, in the display device of the present invention, the electrochromic module i is matched with the shadow 201209496 image display module 2', that is, the image of the electrochromic module 1 disposed in the image display module 2 On the projection surface, when the image display mode 2 is displayed after the processing of the multiple images (different into the left eye image 1 and the right eye image R), the light-receiving layer of the gamma lining is repeated. After being received by the naked eye, the mosquitoes will not be generated to form a stereoscopic image. However, the above description is only for the preferred embodiment of the present invention and is not intended to limit the implementation of the present month. Anyone skilled in the art will be Without departing from the spirit and scope of the invention Changes made to the scales and modifications are specifically intended to be included within the present invention follow around. In summary, the present invention in conjunction with the display module Sang-home "applicant Yuan Yi predetermined Patent Law

"An electrochromic module and system combining organic and inorganic materials has a patented origin and its use value to the industry; 1 an application for invention patents to the bureau.

21 201209496 [Simple description of the drawings] Fig. 1 is a cross-sectional view 1 of a conventional electrochromic module. Figure 2 is a cross-sectional view 2 of a conventional electrochromic module. Fig. 3 is a perspective exploded view of the first preferred embodiment of the present invention. Fig. 4 is a first schematic view showing the structure of a transparent conductive member according to a first preferred embodiment of the present invention. Fig. 5 is a second schematic view showing the structure of a transparent conductive member according to a first preferred embodiment of the present invention. Figure 6 is a third schematic view showing the structure of a transparent conductive member according to a first preferred embodiment of the present invention. Figure 7 'Linfa two health _ three-dimensional distinction. Fig. 8 is a first schematic view showing the structure of a transparent conductive member according to a second preferred embodiment of the present invention. Figure 9 is a second schematic view showing the structure of a transparent conductive member according to a second preferred embodiment of the present invention. FIG. 1 is a first schematic structural view of a transparent conductive member according to a third preferred embodiment of the present invention. Figure U is a second schematic view of a transparent conductive element according to a third preferred embodiment of the present invention. Figure 12 is a cross-sectional view showing a fourth preferred embodiment of the present invention. Figure 13 is a top plan view showing the structure of a transparent conductive member in accordance with a fourth preferred embodiment of the present invention. Fig. 14 is a perspective view showing the structure of a transparent conductive member according to a fourth preferred embodiment of the present invention. Fig. 15 is a perspective view showing the structure of a transparent conductive tree according to a ton preferred embodiment of the present invention. Figure 16 is a cross-sectional view showing a fifth preferred embodiment of the present invention. Fig. 17 is a top plan view showing the structure of a conductive member according to a fifth preferred embodiment. The lap 18 is a perspective view showing the structure of the transparent conductive tree of the fifth preferred embodiment of the present invention. 22 201209496 f

[Description of main components] Electrochromic module 1 First transparent substrate 11 First transparent conductive element 111 Second transparent substrate 12 Second transparent conductive element 121 Electrochromic layer 13 Electrolyte layer 14 Barrier unit 15 Image display module 2 Electrochromic module 3 first transparent substrate 31 first transparent conductive element 311 second transparent substrate 32 second transparent conductive element 321 electrochromic layer 33 electrolyte layer 34

Claims (1)

201209496 VII. Patent Application Range: 1. An electrochromic module combining organic and inorganic materials, comprising: a first transparent substrate having at least one first transparent conductive element on an upper surface thereof; a transparent substrate; and an electrochromic layer disposed between the first transparent substrate and the second transparent substrate, wherein the electrochromic layer is made by mixing a mixed organic material and an inorganic material in a solvent. 2. The "electrochromic module incorporating organic and inorganic materials" as described in item 1 of the patent scope, wherein the materials of the transparent substrates are plastic, polymer plastic, glass or selected from resin, poly P〇丨yethylene Terephthalate (pET), polycarbonate Carbonate 'PC), polyethylene (p〇iyethyiene, pE), polyethylene (p〇ly 乂 (4) Chloride, PVC) One of the plastic polymer groups consisting of polypropylene (p〇iy Propylene, pp) and polystyrene (PS) polymethyl methacrylate (丨methacry late). 3. The electrochromic module according to the first aspect of the invention, wherein the material of the first transparent conductive element is selected from the group consisting of indium tin oxide (Indium Tin 0xide, ιτο), Impurity-Doped consisting of indium zinc oxide (IndiumZinc〇xide, IZ〇), zinc oxide (Ai d^edZn〇, AZO) and tin oxide (Amim〇ny Ή 〇 〇, at〇) One of the Oxides) groups. 4. For the “Electrochromic Modules Combining Organic and Inorganic Materials” as described in the application for patents (4), The material of the first transparent conductive element is a carb〇n nanotube. 5. The "electrochromic module incorporating organic and inorganic materials" as described in the scope of the patent application, wherein the organic material is a redox indicator (Red〇x indicat〇r) or a pH indicator 24 201209496 ( Acid-base indicator). - 6. "Electrochromic module incorporating organic and inorganic materials" as described in item 5 of the patent application, - where 'the redox indicator is methylene blue (C6H18CIN3S.3H2O) or two Dichlorophenolindophenol sodium (〇7. The electrochromic module incorporating organic and inorganic materials as described in claim 5, wherein the pH indicator is vanazin blue salt B (Variamine Blue BDiazonium salt, C丨3Hi2C1N3〇). 8. The "electrochromic module incorporating organic and inorganic materials" as described in the scope of claim i, wherein the inorganic material is an inorganic derivative. 9. The "electrochromic module incorporating organic and inorganic materials" as described in claim 8 wherein the inorganic derivative is an oxide, sulfide, vapor or hydroxide of a transition element. 10. The "electrochromic module incorporating organic and inorganic materials" as described in claim 8 wherein the inorganic derivative is a halogen (VIIA), an oxygen group (VIA), a nitrogen group (VA). ), carbon family (IVA), deleted family (ΠΙΑ ), Alkaline Earth (IIA) or Alkali Gold (IA). U. The "electrochromic module incorporating organic and inorganic materials" as described in claim 9 of the patent application, wherein 'the transition element is sharp Family (IIIB), Titanium Subgroup (IVB), Hungry Subfamily (VB), Chromium Subgroup (VIB), Meng Subgroup (VIIB), Iron 'Series (VIII), Copper Subgroup (IB), Zinc Subgroup _ or platinum system (VIII). 1Z is the "electrochromic module combining organic and inorganic materials" as described in the scope of claim i, wherein the inorganic material is gasified ferrous iron (FeCl2), three gas Iron (FeCb), titanium trichloride (TiCl3) or titanium tetrachloride (TiCh). I3. "Electrochromic module combined with organic and inorganic materials" as described in claim i of the patent application, The material of the medium u solvent is dimethyl-hard ((chaso), propylene carbonate (10) 6〇3) or water 25 201209496 (h2〇). 14. As described in the patent application, the combination of organic and inorganic The "color changing module" of the material, wherein, when the plurality of first transparent conductive elements are plural, they are arranged on the first transparent substrate at intervals. 15. - "Combining organic and inorganic materials a color changing module, comprising: a transparent substrate having at least one first transparent conductive element on an upper surface thereof; a second transparent substrate 'having at least a second transparent conductive element on a lower surface thereof; and - electrochromic The layer ' is disposed between the first-turn substrate and the second transparent substrate, and the electrochromic layer is made by mixing the organic material and the inorganic material in a solvent. 16. For example, the “Electrochromic Modules Combining Organic and Inorganic Materials” as described in Item 15 of the 凊 凊 丨 其 其 其 其 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该Luna, polyethylene, p〇lyethyiene Terephthalate (pET), polycarbonate (Carbonate 'PC), polyethylene (p〇iyethyiene, PE), polystyrene (PVC) One of the group of plastic rug polymers composed of polypropylene (p〇iy propyiene 'pP) and polystyrene (PS) and polymethylmethacrylate 'pmmA. 17. The "electrochromic module incorporating organic and inorganic materials" as described in claim 15 wherein the material of the first transparent conductive member is selected from the group consisting of indium tin oxide (ndium tin Oxide 'ITO), Among the groups of indium Zinc Oxide (IZO), zinc oxide (Al-doped ZnO 'AZO) and Antimony Tin Oxide (Antimony Tin Oxide), among them are the Impurity-Doped Oxides group. One. 18. The "electrochromic mold combined with organic and inorganic materials 26 201209496" as described in claim 15 of the patent application, wherein the material of the first-transmissive electrical component is a neat tube. 19. The "Electrochromic Module Combined with Organic and Inorganic Materials" as described in the Patent No. 15 [Where the 'organic material is a redox indicator (Red〇x Indica1; 〇r) or ρΗ An acid-base indicator. 20♦ As described in the sf patent model, the "electrochromic mode combined with organic and inorganic materials," and "eight zhonghai" redox indicator is Methylene blue (C6H18CIN3S 3H2O) or "Dichi〇r〇phen〇iind〇phen〇i sodium, Ci2HeCl2NNa〇2) ° 21. "The electrochromic module combining organic and inorganic materials" as stated in the patent patent '19, Wherein the pH indicator is vanazin blue salt B (Variamine is B Diaz〇nium salt » C13H12CIN3O) ° 22. The electrochromic combination of organic and inorganic materials as described in claim 4 Module "" wherein the inorganic material is an inorganic derivative. 23. The "electrochromic module incorporating organic and inorganic materials" as described in Item 22 of the 4th patent (4), wherein the inorganic derivative is an oxide, sulfide, vapor or oxynitride of a transition element. . 24. The “Electrochromic Module Combining Organic and Inorganic Materials” as described in the 22nd paragraph of the patent scope, wherein the inorganic derivative is a group (νΠΑ), an oxygen group (VIA), a nitrogen group ( Va), carbon group (IVA), boron group (ΙΠΑ), alkaline earth group (πα) or alkali gold group (ία). 25. For the purpose of item 23 of the scope of application, the "electrochromic module combining organic and money materials" 'where' the transition element is the mirror subfamily (wide, titanium subfamily (IVB), Kay subfamily (vb) ), the sub-family (VIB), the manganese sub-group (γΠΒ), the iron system (vm), the copper sub-group (IB), the zinc sub-group _ or the sales system 27 201209496 (VIII). 26. If the scope of patent application is 23 "Electrochromic mode combined with organic and inorganic materials, non-Sna Wei S iron (FeCI2), three gas iron (FeCl3), three gasification (τια3) or titanium tetrachloride (Tia) 27. The "electrochromic mold combined with organic and inorganic materials" as described in item [i] of the U profit range, the material of the refrigerant is dimethyl sulfoxide (10) 3) but) Q secret) or water (H2〇:). 28. In the case of the "electrochromic mold combined with organic and inorganic materials" as described in the fifteenth paragraph of the patent application, and the plurality of first and second transparent conductive elements of the towel, the plurality of conductive elements are arranged at intervals On the first and second transparent substrates. 29. A "display device" comprising: - an image display module - for displaying - a planar image and a - stereo image; - an electrochromic module - being disposed on the surface of the image display module, comprising: a first transparent substrate having at least one first transparent conductive element on its surface; a first transparent substrate; and a plurality of electrochromic layers spaced apart between the first transparent substrate and the second transparent substrate The materials of the electrochromic layers are made by mixing a mixed organic material and an inorganic material in a solvent. 30. The "display device" as claimed in claim 29, wherein the transparent substrate is made of plastic, polymer plastic, glass or selected from the group consisting of resin and polyethylene terephthalate (PET). ), polycarbonate (P〇lyCarb〇nate, pc), polyethylene (Polyethylene 'PE), polystyrene (P〇ly Vinyl Chl〇ride, pvc), polyacryl 28 201209496 (Polypropylene, PP) and polystyrene One of the group of plastic polymers composed of Polystyrene (PS) and Polymethylmethacrylate (PMMA). The "display device" according to claim 29, wherein the first transparent conductive member is made of Indium Tin Oxide (ITO) or Indium Zinc Oxide (IZO). One of the group of Impurity-Doped Oxides consisting of Al-doped ZnO (AZO) and Antimony Tin Oxide 'ATO. 32. The "display device" of claim 29, wherein the first transparent conductive member is made of a carbon nanotube. 33. The "display device" of claim 29, wherein the organic material is a redox indicator or an acid-base indicator. 34. The "display device" according to claim 33, wherein the redox indicator is methylene blue, (ΛαΜ.3Η2〇) or dichlorophenolindophenol sodium (Dichlorophenolindophenol sodium, Ci2HeCl2NNa〇2) 35. The "display device" according to claim 33, wherein the pH indicator is BCVariamine Blue B Diazonium salt, C丨3H丨£1Ν3〇). 36. The "display device" of claim 29, wherein the inorganic material is an inorganic derivative. 37. The "device" of claim 36, wherein the inorganic derivative is an oxide, sulfide, vapor or hydroxide of a transition element. 38. The "display device" of claim 36, wherein the inorganic derivative is 29 201209496 halogen (VIIA), oxygen (VIA), nitrogen (VA), carbon (IVA) 'Borzo (ΙΙΙΑ), alkaline earth (ΠΑ) or gold test (ΙΑ). 39. The "display device" of claim 37, wherein the transition element is a sharp subgroup (ΙΙΙΒ), a titanium subgroup (IVB), a vanadium subgroup (VB), a chromium subgroup (VIB). , manganese subgroup (VIIB), iron system (VIII), copper subgroup (IB), zinc subgroup (IIB) or platinum system (VIII). 4. The "display device" according to claim 29, wherein the inorganic material may be gasified ferrous iron (FeCl2), triironated iron (FeCi3), trigastric (Ticl3) or four. Gasification Qin (7) (1). 4h, the "display device" as described in claim 29, wherein the solvent is made of bismuthylene ((CH3)2S0), propylene carbonate (c4H6〇3) or water (10). The "display device" according to claim 29, wherein the electrochromic layer is further mixed with a conductive polymer to form an electrochromic ink. The "display device" according to claim 29, wherein when the plurality of first transparent conductive elements are plural, they are arranged on the first transparent substrate at intervals. 44. The "display device" of claim 43, wherein the electrochromic sound system is disposed between the first transparent conductive elements, and the first transparent conductive elements are used to separate the same The discoloration layer. </ RTI> 45. The "display device" of claim 43, wherein the first transparent conductive element is more brittle, and the electro-acoustic layer is disposed in the slot. 46. The "display device" as described in claim 29, wherein the transparent substrate is provided with a Wei-Xian-transfer unit, and the blocking unit is located between the transparent units. The "display device" described in claim 46, wherein the blocking units are 201209496-resistance. - 48. A "display device" comprising: - a display module for display - a flat image and a stereo image; an electrochromic module mounted on the surface of the image display module The first transparent substrate is provided with at least a first transparent conductive member; the second transparent substrate has at least one second transparent conductive member on a lower surface thereof; and a plurality of electrochromic layers The material is formed between the first transparent conductive element and the second transparent substrate #, and the material of the electrochromic layer is prepared by dissolving the mixed organic material and the inorganic material in a solvent. 49. The "display device" of claim 48, wherein the transparent substrate is made of plastic, polymer plastic, glass or selected from the group consisting of resin and polyethylene terephthalate. 'PET), polycarbonate (PC), polyethylene (PE), P〇ly Vinyl Chloride (PVC), polypropylene (PP) and polystyrene (p) One of the plastic polymer groups consisting of 〇ly Styrene 'PS) and polymethylmethacrylate (PMMA). 50. The "display device" according to claim 48, wherein the first transparent conductive member is made of Indium Tin Oxide (ITO) or Indium Zinc Oxide (IZO). One of the group of Impurity-Doped Oxides consisting of Al-doped ZnO (AZO) and Antimony Tin Oxide (ATO). 51. The "display device" of claim 48, wherein the material of the first transparent conductive element 31 201209496 is a carbon nanotube. 52. The "display device" as described in claim 48, wherein the organic material is a redox indicator or an acid-base indicator. 53. The "display device" of claim 52, wherein the redox indicator is methylene blue (CieHieClNaSJHzO) or Dichlorophenolindophenol sodium (C^HeClaNNaOa) 〇54. The "display device" of claim 52, wherein the pH indicator is Variamine Blue B Diazonium salt (C13H12CIN3O) 〇 55. The "display device" according to the item, wherein the inorganic material is an inorganic derivative. 56. The "display device" according to claim 55, wherein the inorganic derivative is an oxide, a sulfide, a chloride or a hydroxide of a transition element. 57. The "display device" according to claim 55, wherein the inorganic derivative is a halogen (VIIA), an oxygen group (VIA), a nitrogen group (VA), a carbon group (IVA), or boron. Family (ΙΠΑ), soil tester (ΠΑ) or gold tester (ΙΑ). 58. The "display device" according to claim 56, wherein the transition element is a sub-group (ΙΙΙΒ), a titanium sub-group (IVB), a vanadium sub-family (VB), and a chromium sub-family (VIB). , manganese subgroup (VIIB), iron system (VIII), copper subgroup (IB), zinc subgroup (IIB) or platinum system (VIII). 59. The "display device" according to claim 48, wherein the inorganic material is gas ferrous iron (FeCl2), three gas iron (FeCh), three gasification (TiCl〇 or four gas). Huaqin (TjQ4) 60. The "display device" as described in claim 48, wherein the solvent is made of dimethyl sulfoxide ((CH3)2S0), propylene carbonate (C4H6〇3). Or water (H2〇). 32 201209496 61. The “display device” as described in the scope of the patent application section, wherein when the first and second moon-transparent 7C pieces are plural, they are spaced apart. And a surface corresponding to the first and second transparent substrates, and each of the electrochromic layers undergoes a color change according to electrical conduction of each group and the first transparent conductive element. 62. The "display device" of the present invention, wherein the first transparent conductive element is placed between the transparent substrates and the electro-chromic layer is disposed in the conductive layer Between the first transparent conductive element and the second transparent conductive element. 63. In the "display shake" described in item 61, wherein the transparent substrates are provided with a plurality of spaced-apart blocking units, and the electro-transformation (four) is respectively disposed between the blocking units. The "display device" of claim 62, wherein the blocking unit is a photoresist. The "display device" of claim 48, wherein the electrochromic layers are further mixed. A conductive polymer is formed to form an electrochromic ink.