TW201206348A

TW201206348A - Pesticidal composition and its use

Info

Publication number: TW201206348A
Application number: TW100114310A
Authority: TW
Inventors: Yuichi Matsuzaki
Original assignee: Sumitomo Chemical Co
Priority date: 2010-04-27
Filing date: 2011-04-25
Publication date: 2012-02-16
Also published as: AR083145A1; CA2797218A1; KR101811898B1; JP5782678B2; US20130045970A1; BR112012027384B1; WO2011135830A1; RU2556402C2; US8691812B2; UA107830C2; NZ603840A; EP2563132A1; CL2012002972A1; CO6571877A2; EP2563132B1; JP2011231041A; CN102858166B; AU2011246795A1; BR112012027384A2; CA2797218C

Abstract

A composition comprising a carboxamide compound represented by formula (I): wherein R1 represents a hydrogen atom or a methyl group, and R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group, and one or more neonicotinoid compound selected from group (A) consisting of acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram thiacloprid and thiamethoxam possesses an excellent pesticidal effect.

Description

201206348 六、發明說明：【發明所屬之技術領域】本發明係關於一種殺蟲組成物及其用途。【先前技術】已發展許多用於防制害蟲且實際使用之化合物（參見，例如，PTL1 和 PTL2)。 [弓丨用名單] [專利文獻] [PTL 1] ： WO86/02641 [PTL2] ： WO92/ 1 2970 【發明內容】 [發明槪述] [技術問題] 本發明之一目的爲提供一種具有極佳殺蟲效果之組成物》 [解決問題的方法] 本發明之發明人爲了尋求具有極佳殺蟲效果之組成物而進行硏究並發現一種包含以下式（I)表示之甲醯胺化合物和一或多種選自下列（A)組之新菸鹼類化合物的組成物具有極佳殺蟲效果且然後完成本發明。 201206348 本發明提供下列[1 ]至[7]項。 [1] 一種殺蟲組成物，其包含以式（I)表示之甲醯胺化合物：201206348 VI. Description of the Invention: [Technical Field to Which the Invention Is Ascribed] The present invention relates to an insecticidal composition and use thereof. [Prior Art] A number of compounds have been developed for the prevention and control of pests (see, for example, PTL1 and PTL2). [Brief list] [Patent Document] [PTL 1] : WO86/02641 [PTL2] : WO92/ 1 2970 [Description of the Invention] [Technical Problem] [Technical Problem] An object of the present invention is to provide an excellent [Composition of the insecticidal effect] [Method for Solving the Problem] The inventors of the present invention conducted an investigation to find a composition having an excellent insecticidal effect and found a formamide compound represented by the following formula (I) and a The composition of a plurality of neonicotinoid compounds selected from the group (A) below has an excellent insecticidal effect and then the present invention has been completed. 201206348 The present invention provides the following items [1] to [7]. [1] A pesticidal composition comprising a formamidine compound represented by the formula (I):

其中 R1表示氫原子或甲基，及 R2表示甲基、二氟甲基或三氟甲基，及一或多種選自由亞滅培（acetamiprid)、可尼丁（ clothianidin )、達特南（dinotefuran)、益達胺（ imidacloprid )、嫌卩定蟲胺（nitenpyram)、賽果培（ thiacloprid)和賽速安（thiamethoxam)所組成之（A) 組的新菸鹼類化合物。 [2] 根據上述[1 ]之殺蟲組成物，其中甲醯胺化合物對新菸鹼類化合物之重量比（甲醯胺化合物/新菸鹼類化合物）係從0.01/1至4/1。 [3] 根據上述[1]或[2]之殺蟲組成物，其中該新菸鹼類化合物爲可尼丁。 [4] 一種防制害蟲之方法，其包含用有效量的以式（ I)表示之甲醯胺化合物： 201206348Wherein R1 represents a hydrogen atom or a methyl group, and R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group, and one or more selected from the group consisting of acetamiprid, clothianidin, and dinotefuran , neonicotinoids of group (A) consisting of imidacloprid, nitenpyram, thiacloprid, and thiamethoxam. [2] The insecticidal composition according to the above [1], wherein the weight ratio of the formamide compound to the neonicotinoid compound (formamide compound/neonicotinoid compound) is from 0.01/1 to 4/1. [3] The insecticidal composition according to the above [1] or [2] wherein the neonicotinoid compound is cotinine. [4] A method for controlling pests comprising an effective amount of a formamide compound represented by formula (I): 201206348

其中 R1表示氫原子或甲基，及 R2表示甲基、二氟甲基或三氟甲基，及一或多種選自由亞滅培、可尼丁、達特南、益達胺、烯啶蟲胺、賽果培和賽速安組成之（A)組的新菸鹼類化合物，處理植物或其中生長植物的土壤之步驟。 [5] 根據根據上述[4]之防制害蟲之方法，其中甲醯胺化合物對新菸鹼類化合物之重量比（甲醯胺化合物/新菸鹼類化合物）係從0.01/1至4/1。 [6] 根據根據上述[4]或[5]之防制害蟲之方法，其中該新菸鹼類化合物爲可尼丁。 [7] 根據根據上述[4]至[6]中任一項之防制害蟲之方法，其中植物或其中生長植物的土壤分別爲大豆或或其中生長大豆的土壤" [本發明之有利效果] 根據本發明，可防制各種害蟲。 [具體例之說明] 本發明之殺蟲組成物（下文稱爲“組成物，，）包含以式 (I)表示之甲醯胺化合物： 201206348Wherein R1 represents a hydrogen atom or a methyl group, and R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group, and one or more selected from the group consisting of arsenic, cotinine, dardon, edamine, acetamiprid A step of treating a plant or a soil in which a plant is grown by a neonicotinoid compound of the group (A) consisting of an amine, a racepiper and a acesulfame. [5] The method according to the above [4] for controlling pests, wherein the weight ratio of the methotrexate compound to the neonicotinoid compound (formamide compound/neoxotine compound) is from 0.01/1 to 4/ 1. [6] The method according to the above [4] or [5], wherein the neonicotinoid compound is cotinine. [7] The method for controlling pests according to any one of the above [4] to [6] wherein the plant or the soil in which the plant is grown is soybean or the soil in which the soybean is grown respectively " [Advantageous Effects of the Invention] According to the present invention, various pests can be prevented. [Description of Specific Example] The insecticidal composition of the present invention (hereinafter referred to as "composition,") contains a formamide compound represented by the formula (I): 201206348

其中 R1和R2表示如上述中所定義之相同意義（下文稱爲“甲醯胺化合物”），及一或多種選自由亞滅培、可尼丁、達特南、益達胺、烯啶蟲胺、賽果培和賽速安組成之（A )組的新菸鹼類化合物（下文稱爲“新菸鹼類化合物”）。 “甲醯胺化合物”爲該等例如 WO86/02641 或 W092/1 2 970中所者，且可藉由其中所述之方法製備。 “甲醯胺化合物”之特殊例子如下：以式（1 )表示之甲醯胺化合物：Wherein R1 and R2 represent the same meaning as defined in the above (hereinafter referred to as "methionine compound"), and one or more selected from the group consisting of sub-cyanide, cotinine, dardon, edamine, acetamiprid A neonicotinoid compound (hereinafter referred to as "neoxotine compound") of the group (A) composed of an amine, a racepiper and a acesulfame. "Protonamine compounds" are those such as those described in WO 86/02641 or W092/1 2 970, and can be prepared by the methods described therein. A specific example of "formamide compound" is as follows: a formamide compound represented by formula (1):

(下文稱爲“甲醯胺化合物（i ) ”）以式（2 )表示之甲醯胺化合物：(hereinafter referred to as "formamide compound (i)") a formamide compound represented by formula (2):

(下文稱爲“甲醯胺化合物（2 ) ”）以式（3 )表示之甲醯胺化合物： 201206348(hereinafter referred to as "formamide compound (2)") a formamide compound represented by formula (3): 201206348

H3C 〇H3C 〇

VV

/N h3c (下文稱爲“甲醯胺化合物（3 )，，）：以式（4)表示之甲醯胺化合物：/N h3c (hereinafter referred to as "formamide compound (3),,): a formamide compound represented by the formula (4):

(下文稱爲“甲醯胺化合物（4 ) ”）以式（5 )表示之甲醯胺化合物：(hereinafter referred to as "formamide compound (4)") a formamide compound represented by formula (5):

(下文稱爲“甲醯胺化合物（5 ) ”）。 “新菸鹼類化合物”爲已知化合物且描述於例如“the PESTICIDE MANUAL -第 14 版（BCPC 出版）ISBN 1901396142中。這些化合物可得自市場上包含該“新菸鹸類化合物”之產物或可藉由公認方法合成。在“組成物”中“甲醯胺化合物”對“新菸鹼類化合物”之重量比（甲醯胺化合物新菸鹼類化合物”）通常從 0.01/1 至 500/ 1，和較佳從 0.0 1/1 至 4/1。雖然“組成物”可爲“甲醯胺化合物，，和“新菸鹼類化合物”之混合物本身’但“組成物”，但通常藉由混合“甲醯胺 -9- 201206348 化合物”、“新菸鹼類化合物”和情性載體，及如果需要加入界面活性劑及/或另一用於調配之助劑，及將混合物調配成例如油調配物、可乳化濃縮物、流動性調配物、可濕性粉劑、水分散性粒劑、粉劑、粒劑或類似者而製得。調配物（其單獨使用或藉由添加另一惰性成分使用）可當作殺蟲劑使用。在“組成物”中“甲醯胺化合物”和“新菸鹼類化合物”之總含量通常係從0.1至99重量％，較佳從0.2至90重量 %，且更較佳從1至80重量％。用於調配物之固體載體的例子包括（例如）礦物材料諸如高嶺土、鎂鋁海泡石黏土、膨土、蒙脫石、酸性白黏土、葉蠟石、滑石、矽藻土和方解石；天然有機材料諸如玉米軸粉和胡桃殼粉；合成有機材料諸如尿素；鹽類諸如碳酸鉀及硫酸銨；合成無機材料諸如合成水合氧化矽之細粉和顆粒。液態載體的例子包括芳族烴類諸如二甲苯、烷苯和甲基萘；醇類諸如2-丙醇、乙二醇、丙二醇和乙二醇單乙基醚；酮類諸如丙酮、環己酮和異佛酮；植物油諸如大豆油或棉籽油；石油脂族烴類；酯類；二甲亞颯；乙腈；及水。界面活性劑的例子包括陰離子界面活性劑諸如硫酸烷酯鹽類、烷基芳基磺酸鹽類、二烷基磺酸基琥珀酸鹽、聚氧乙烯烷基芳基醚磷酸酯鹽、磺酸木質素和萘磺酸鹽甲醛聚縮合產物；非離子界面活性劑諸如聚氧乙烯烷基芳基醚 -10- 201206348 、聚氧乙烯烷基聚氧丙烯嵌段共聚物和山梨醇酐脂肪酸酯 :及陽離子界面活性劑諸如烷基三甲基銨鹽。用於調配物之其他助劑的例子包括水溶性聚合物諸如聚乙烯醇和聚乙烯吡咯啶酮；多醣類諸如阿拉伯膠、藻酸及其鹽、CMC (羧甲基纖維素）或三仙膠；無機物質諸如矽酸鎂鋁或氧化鋁溶膠；防腐劑；著色劑；及穩定劑例如 PAP (酸性磷酸異丙酯）和BHT。 “組成物”也可藉由根據如上所述之方法調配“甲醯胺化合物”和“新菸鹼類化合物”而製備，且然後製造該調配物或其稀釋物。 “組成物”可用於防止植物受到害蟲（例如，昆蟲害蟲和植物病害）的損害，該等害蟲以進食、吸吮或類似者對植物產生損害。可被“組成物”防制之昆蟲害蟲的例子包括下列。半翅目（Hemiptera):飛蟲（飛 1¾ 科（Delphacidae ))諸如小褐飛蟲（斑飛蟲（Laodelphax striatellus)) 、褐稻飛蟲（褐飛蟲（Nilaparvata lugens))及白背稻飛蟲（白背飛蟲（Sogatella furcifera )):葉禪（ leafhopper)(角頂葉蟬科（Deltocephalidae))諸如青稻葉蟬（黑尾葉蟬（Nephotettix cincticeps ))、青稻葉禪（二點黑尾葉蟬（Nephotettix virescens)):既蟲（贬科（Aphididae))諸如棉呀（棉呀（Aphis gossypii) )、綠桃呀（桃蚜（Myzus persicae ))、甘藍蚜（甘藍赔（Brevicoryne brassicae))、馬鈴薯讶（馬鈴薯贬（ -11 - 201206348(hereinafter referred to as "methionine compound (5)"). "Niconicotinoids" are known compounds and are described, for example, in "The PESTICIDE MANUAL - 14th Edition (BCPC) ISBN 1901396142. These compounds may be obtained from products comprising the "new soot compound" on the market or It can be synthesized by an accepted method. In the "composition", the weight ratio of "formamide compound" to "neoxotine compound" (formamide compound neonicotinoid compound) is usually from 0.01/1 to 500/. 1, and preferably from 0.01/1 to 4/1. Although the "composition" may be a mixture of "methionine compound," and "neoxotine compound" itself, but "composition", usually by mixing "formamide-9-201206348 compound", "new" a nicotinic compound" and an esthetic carrier, and if necessary, a surfactant and/or another auxiliaries for formulation, and the mixture is formulated into, for example, an oil formulation, an emulsifiable concentrate, a fluid formulation, Prepared as a pesticide by using a wet powder, a water-dispersible granule, a powder, a granule or the like. The formulation can be used as an insecticide either alone or by adding another inert ingredient. The total content of "formamide compound" and "neoxotine compound" is usually from 0.1 to 99% by weight, preferably from 0.2 to 90% by weight, and more preferably from 1 to 80% by weight. Examples of the solid carrier of the substance include, for example, mineral materials such as kaolin, magnesium aluminum sepiolite clay, bentonite, montmorillonite, acid white clay, pyrophyllite, talc, diatomaceous earth and calcite; natural organic materials such as corn Shaft powder and walnut Shell powder; synthetic organic materials such as urea; salts such as potassium carbonate and ammonium sulfate; synthetic inorganic materials such as fine powders and granules of synthetic hydrated cerium oxide. Examples of liquid carriers include aromatic hydrocarbons such as xylene, alkylbenzene and methyl Naphthalene; alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether; ketones such as acetone, cyclohexanone and isophorone; vegetable oils such as soybean oil or cottonseed oil; petroleum aliphatic hydrocarbons ; esters; dimethyl hydrazine; acetonitrile; and water. Examples of surfactants include anionic surfactants such as alkyl sulfate salts, alkyl aryl sulfonates, dialkyl sulfosuccinates, Polyoxyethylene alkyl aryl ether phosphate salt, sulfonic acid lignin and naphthalene sulfonate formaldehyde polycondensation product; nonionic surfactant such as polyoxyethylene alkyl aryl ether-10-201206348, polyoxyethylene alkyl Polyoxypropylene block copolymers and sorbitan fatty acid esters: and cationic surfactants such as alkyltrimethylammonium salts. Examples of other adjuvants for formulations include water soluble polymers such as polyvinyl alcohol and polyethylene. Pyrrolidine Polysaccharides such as acacia, alginic acid and its salts, CMC (carboxymethylcellulose) or trisin; inorganic substances such as magnesium aluminum silicate or alumina sol; preservatives; colorants; and stabilizers such as PAP; (Acid isopropyl phosphate) and BHT. "Composition" can also be prepared by formulating "formamide compound" and "neoxotine compound" according to the method as described above, and then manufacturing the formulation or Dilutions. "Compositions" can be used to protect plants from damage by pests (eg, insect pests and plant diseases) that cause damage to plants by eating, sucking, or the like. Insects that can be protected by "compositions" Examples of pests include the following: Hemiptera: Flying insects (Delphacidae) such as the small brown fly (Laodelphax striatellus), brown rice flying insect (Nilaparvata lugens) And white-backed rice worm (Sogatella furcifera): leafhopper (Deltocephalidae), such as the green leafhopper (Nephotettix cincticeps), green rice leaf Zen (Nephotettix virescens): worm (Aphididae) such as cotton (Aphis gossypii), green peach (Myzus persicae), cabbage ( Bravicoryne brassicae), potato surprised (potato 贬 ( -11 - 201206348

Macrosiphum euphorbi ae ))、毛地黃呀(foxglove aphid )(節溝無網呀（Aulacorthum solani ))、燕麥黍縊呀 (oat bird-cherry aphid )(禾穀溢管讶(Rhopalosiphum padi ))、大洁赔（tropical citrus aphid )(桔极（ Toxoptera citricidus ))；椿象（樁象科（Pentatomidae ))諸如綠臭蟲（稻綠椿象（Nezara antennata))、豆綠蝽（點蜂緣棒象（Riptortus clavatus))、稻椿象（中華稻緣婚（Leptocorisa chinensis))、白斑黑棒象（白星嬉（Eysarcoris parvus ))和茶翅椿（Brown marmorated stink bug)(大綠椿（H a 1 y o m o r p h a m i s t a ) )、牧草盲椿（tarnished plant bug)(牧草盲椿（Lygus lineolaris)):粉 1¾ (粉 1¾ 科（Aleyrodidae))諸如溫室白粉蟲（溫室粉 1¾ (Trialeurodes vaporariorum))、銀葉粉蟲（銀葉粉蟲（Bemisia argentifolii)):介殼蟲 (介殼蟲科（Coccidae ))諸如桔紅腎圓盾介殼蟲（ Calfornia red scale)(紅圓介殼蟲（Aonidiella aurantii ))、梨圓介殼蟲（S an Jose scale )(梨圓介殼蟲（Macrosiphum euphorbi ae )), foxglove aphid (Aulacorthum solani), oat bird-cherry aphid (Rhopalosiphum padi), large Tropical citrus aphid (Toxoptera citricidus); 椿象 (Pentatomidae) such as green bed bug (Nezara antennata), bean green 蝽 (Riptortus clavatus) )), rice locust (Leptocorisa chinensis), white spot black elephant (Eysarcoris parvus) and brown marmorated stink bug (H a 1 yomorphamista ), Tarnished plant bug (Lygus lineolaris): powder 13⁄4 (Aleyrodidae) such as greenhouse white mealworm (Trialeurodes vaporariorum), silver leaf mealworm (silver leaf meal) Bemisia argentifolii): scale insect (Coccidae) such as Calfornia red scale (Aonidiella aurantii), S an Jose scale ) Pear round scale insect (

Comstockaspis perniciosa))、北柑介殼蟲（citrUs north scale)(桔矢尖介殼蟲（Unaspis citri))、紅臘介殼蟲 (紅臘介殼蟲（Ceroplastes rubens ))、吹綿介殼蟲（吹綿介殼蟲（Icerya purchasi )):網蝽科（Tingidae )、木蝨科（Psyllidae));等等。鱗翅目（Lepidoptera):螟蛾（螟蛾科（Pyralidae) )諸如水稻螺蟲（二化螟蛾（Chilo suppressalis)) '稻 -12- 201206348 黃鎮蟲（二化螺蛾（Tryporyza incertulas))、稻大卷葉螺（稻縱捲葉野螺蛾（Cnaphalocrocis medinalis))、棉大卷葉螟（棉捲葉野蟆（Notarcha derogata))、印度粉螺（印度榖粉螺蛾（Plodia interpunctella))、亞洲玉米虫冥（亞洲玉米膜（Ostrinia furnacalis))、甘藍螺（ cabbage webworm)(菜螟（Hellula undalis))及早熟禾草螟（bluegrass webworm )(早熟禾草螺（P e d i a s i a teterrellus));夜蛾（夜蛾科（Noctuidae))諸如普通夜盜蟲（斜紋夜蛾（Spodoptera litura))、甜菜夜蛾（ beet armyworm)(甜菜葉蛾（Spodoptera exigua ))、黏蟲（東方黏蟲（Pseudaletia separata))、甘藍夜蛾（甘藍夜蛾（Mamestra brassicae))、切根蟲（black cutworm)(小地老虎（Agrotis ipsilon))、甜菜斜紋夜蛾（beet semi-looper )(黑點銀紋夜蛾（P1 usia nigrisigna))、粉紋夜蛾屬（Thoricoplusia spp.)、棉花實夜蛾屬（Heliothis spp.)及實夜蛾屬（Helicoverpa spp.);紋白蝶（粉蝶科（Pieridae ))諸如普通菜粉蝶 (紋白蝶（Pieris rapae )):捲蛾（捲蛾科（Tortricidae ))諸如小捲葉蛾屬（Adoxophyes spp·)、東方果蛾（ oriental fruit moth )(梨小食心蟲（Grapholita molesta ) )、大豆食心蟲（豆捲葉螟（Leguminivora glycinivorella ))、紅豆豆蟲（azuki bean podworm)(豆小捲葉蛾（ Matsumuraeses azukivora))、夏果捲葉蛾（小角紋捲葉蛾（Adoxophyes orana fasciata ))、茶姬捲葉蛾（ -13- 201206348Comstockaspis perniciosa)), citrUs north scale (Unaspis citri), red wax scale insect (Ceroplastes rubens), blown scale insect (Blowing scale insect) (Icerya purchasi)): Tingidae, Psyllidae; and so on. Lepidoptera: Pyralidae (Pyralidae) such as rice snail (Chilo suppressalis) 'Rice-12- 201206348 Yellow worm (Tryporyza incertulas), Rice leaf snail (Cnaphalocrocis medinalis), cotton leafhopper (Notarcha derogata), Indian snail (Plodia interpunctella) , Asian corn worm (Ostrinia furnacalis), cabbage webworm (Hellula undalis) and bluegrass webworm (P ediasia teterrellus); night Moth (Noctuidae) such as the common night worm (Spodoptera litura), beet armyworm (Spodoptera exigua), armyworm (Pseudaletia separata) )), Brassica chinensis (Mamestra brassicae), black cutworm (Agrotis ipsilon), beet semi-looper (Black Spotted Spodoptera) (P1 usia nigrisigna )), Thoricoplusia spp., Heliothis spp. and Helicoverpa spp.; Pieridae (Pieridae) such as common cabbage butterfly (Butterfly butterfly) Pieris rapae )): Moth (Tortricidae) such as Adoxophyes spp., oriental fruit moth (Grapholita molesta), Soybean (Aphis gossypii) (Leguminivora glycinivorella )), azuki bean podworm (Matsumuraeses azukivora), Adoxophyes orana fasciata, and Aphis gossypii ( -13- 201206348)

Smaller tea tortrix)茶小捲葉蛾（Adoxophyes honmai) 、東方茶小捲葉蛾（oriental tea tortrix )(東方茶卷葉蛾 (Homona magnanima )))、蘋果捲葉蛾（亂紋蘋果捲葉蛾（Archips fuscocupreanus ))及蠢蛾（蘋果蠢蛾（ Cydia pomonella)):細蛾（細蛾科（Gracillariidae)) 諸如茶捲葉蛾（茶細蛾（Caloptilia theivora))、及蘋果潛葉蛾（潛葉蛾（Phyllonory cter ringoniell a )):蛀果蛾科（Carposinidae )諸如桃果蛀蛾（桃小食心蟲（ Carposina niponensis));潛蛾（潛蛾科（Lyonetiidae) )諸如潛蛾屬（Lyonetia spp.);毒蛾（毒蛾科（ Lymantriidae))諸如毒蛾屬（Lymantria spp.)及黃毒蛾屬（Euproctis spp.):巢蛾（巢蛾科（Yponomeutidae) )諸如鑽石背蛾（diamondback moths )(小菜蛾（ Plutella xylostella));麥蛾（麥蛾科（Gelechiidae)) 諸如棉紅鈴蟲（pink bo 11 worm )(棉紅鈴蟲（ Pectinophora gossypiella))及馬鈴薯管蟲（馬鈴薯塊莖蛾（Phthorimaea operculella));老虎蛾及燈蛾（燈蛾科（Arctiidae ))諸如秋幕蛾（美國白娥（H yphantri a cunea));谷蛾（谷蛾科（Tineidae))諸如製袋衣蛾（ casemaking clothes moth)(衣蛾（Tinea translucens)) 及織網衣蛾（webbing clothes moth)(幕衣蛾（Tineola bisselliella ));等等，纓翅目（Thysanoptera ):薊馬（Thripidae )諸如西方花薊馬（西方花薊馬（Frankliniella occidentals))、 -14- 201206348 南黃薊馬（南黃萷馬（Thrips palmi ))、茶黃薊馬（ Yellow tea thrip )(小黃薊馬（Scirtothrips dorsalis)) 、蔥薊馬（蔥薊馬（Thrips tabaci ))、花萷馬（花薊馬 (Frank liniella intonsa )、煙草蔚馬（煙草顯馬（ Frankliniella fusca)) ；雙翅目（Diptera):蒼蠅（家蠅（Musca domestica ))、普通蚊子（淡色庫蚊（Culex pipiens pallens)) 、三角虫亡（Tabanus trigonus)、菌蠅（菌蠅（Hylemya antiqua))、種蠅（種蠅（Hylemyaplatura))、中國瘧蚊（中華瘧蚊（Anopheles sinensis))、日本潛葉蠅（稻潛繩（Agromyza oryzae ))、稻潛葉繩（稻潛葉蠅（ Hydrellia griseola))、稻杆潛蠅（稻杆潛蠅（Chlorops oryzae))、瓜實蠅（瓜實蠅（Dacus cucurbitae))、地中海實蠅（地中海實蠅（Ceratitis capitata))和三葉斑潛蠅（L i r i 〇 m y z a t r i f ο 1 i i ); 鞘翅目（Coleoptera) : 28-星瓢蟲茄（二十八星瓢蟲 (Epilachna vigintioctopunctata )) 、黃守瓜（cucurbit leaf beetle )(黃守瓜（Aulacophora femoralis))、黃條葉蚤（Phyllotreta striolata )、稻葉甲（負泥蟲（ Oulema oryzae ))、水稻象甲（稻象鼻蟲（ Echinocnemus squameus ))、稻水象甲（稻象甲（ Lissorhoptrus oryzophilus))、棉鈴象甲（棉鈴象甲（ Anthonomus grandis ))、小豆象鼻蟲（綠豆象（ Callosobruchus chinensis ))、結縷草象鼻蟲（zoysia 201206348 billbug)(黑楔象鼻蟲（Sphenophorus venatus))、日本麗金龜（日本金龜（Popillia japonica))、銅金龜子 (金銅金龜（Anomala cuprea))、玉米根蟲科（ Diabrotica spp.)、科羅拉多馬鈴薯葉甲（Letinotarsa decemlineata)、叩甲科甲蟲（叩甲属（Agriotes spp.) )、煙草甲蟲（煙甲蟲（Lasioderma serricorne))、經節蟲（姬圓鰹節蟲（Anthrenus verbasci))、銹紅色粉甲蟲（赤擬穀盜（Tribolium castaneum))、留粉甲蟲（ power post beetle )(褐粉蠹(Lyctus brunneus))、白斑天牛蟲（星天牛（Anoplophora malasiaca))、一般松樹甲蟲（縱坑切梢小蠹（Tomicuspiniperda))、等等；直翅目（Orthoptera):煌蟲（飛幢（Locusta migratoria))、螻蛄（非洲螻蛄（Gryllotalpa Africana ))、小翅稻螳（Oxya yezoensis))、日本稻禮（Oxya japonica))、等等；膜翅目（Hymenoptera):蕪菁葉蜂（菜葉蜂（ Athaliarosae))、切葉犠（切葉蟻屬（ Acromyrmex spp. ))、火蟻（火犠屬（Solenopsisspp))、等等；蜚蠊目（Blattaria ):德國蜚蠊（德國小蠊（Smaller tea tortrix) Adoxophyes honmai, oriental tea tortrix (Homona magnanima), apple leaf moth (Archips fuscocupreanus) and stupid moth ( Cydia pomonella: A fine moth (Gracillariidae) such as the tea leaf moth (Caloptilia theivora) and the apple leaf moth (Phyllonory cter ringoniell a): 蛀Carposinidae such as Carposina niponensis; Lyothiidae such as Lyonetia spp.; Lymomito (Lymantriidae) such as venomous moth Genus (Symphaea spp Gelechiidae)) such as cotton bo 11 worm (Pectinophora gossypiella) and potato tuber (Phthorimaea operculella); tiger moth The hawk moth (Arctiidae) such as the autumn moth (Hyphantri a cunea); the moth (Tineidae) such as the casemaking clothes moth (cloth moth) Tinea translucens)) and webbing clothes moth (Tineola bisselliella); etc., Thysanoptera: Thripidae such as Western flower hummer (Western flower hummer ( Frankliniella occidentals)), -14- 201206348 Southern Yellow Horse (Thrips palmi), Yellow Tea thrip (Scirtothrips dorsalis), Green Onion Horse (Green Onion) Thrips tabaci), Frank liniella intonsa, Frankliniella fusca, Diptera: flies (Musca domestica), Ordinary mosquitoes (Culex pipiens pallens), tribes (Tabanus trigonus), fly (Hylemya antiqua), fly (Hylemyaplatura), Chinese malaria (Chinese malaria) Anopheles sinensis)), Japanese leaf miner (rice dive) Agromyza oryzae), rice paddy larvae (Hydrellia griseola), rice larvae (Chlorops oryzae), cucurbita (Dacus cucurbitae), Mediterranean fruit fly (Ceratitis capitata) and Liriomyza trifolii (L iri 〇myzatrif ο 1 ii ); Coleoptera: 28-star ladybug (Epilachna vigintioctopunctata) )), cucurbit leaf beetle (Aulacophora femoralis), Phyllotreta striolata, Oleema oryzae (Oulema oryzae), rice weevil (rice weevil) (Echinocnemus squameus)), rice water weevil (Lissorhoptrus oryzophilus), cotton boll weevil (Anthonymus grandis), weevil weevil (Cartodon elephant ( Callosobruchus chinensis)), scar weed Snake (zoysia 201206348 billbug) (Sphenophorus venatus), Japanese golden tortoise (Popillia japonica), copper chafer (Anomala cuprea), corn rootworm ( Diabrotica spp.), Colorado potato leaf (Letinotarsa decemlineata), armoridae (Agriotes spp.), tobacco beetle (Lasioderma serricorne), stag beetle (Anthrenus) Verbasci)), rust red powder beetle (Tribolium castaneum), power post beetle (Lyctus brunneus), white spotted beetle (Anoplophora malasiaca) , general pine beetle (Tincus piniperda), etc.; Orthoptera: Locusta migratoria, ry (Gryllotalpa Africana), small winged rice O(Oxya yezoensis), Oxya japonica, etc.; Hymenoptera: Aphididae (Athaliarosae), Aphididae (Acromyrmex spp. )), fire ants (Solenopsis spp), etc.; Blattaria: German 蜚蠊 (German 蠊 (

Blattella germanica ))、煙褐蟑螂（黑胸大蠊（ Periplaneta fuliginosa ))、美洲蟑螂（美洲蜚蠊（ Periplaneta americana))、黑密西西比蟑螂（棕色蜚蠊 (Periplaneta brunnea))、東方蟑螂（東方蜚蠊（Blatta orientalis))、等等 ° -16- 201206348 可被“組成物”防制之植物病害的例子包括下列》稻穀病害：稻瘟病（Magnaporthe grisea )、稻胡麻葉枯病菌（Cochliobolus miyabeanus )、立枯絲核菌（ Rhizoctonia solani)、藤倉赤黴菌（Gibberella fujikuroi )；小麥病害：麥類白粉病（Erysiphe graminis )、禾穀鐮刀菌（Fusarium graminearum )、燕麥鐮刀菌（F. avenaceum)、黃色鐮刀菌（F_ culmorum)、雪黴葉枯菌 (Microdochium nivale ) 、條鏽病菌（Puccinia striiformis ) 、稈鏡病（P.graminis)、小麥隱匿柄鏽菌 (p. recondite ) ) 、Micronectriella nivale ' Typhula sp. 、散黑穗病（Ustilago tritici )、小麥腥黑粉菌（Tilletia caries ) 、小麥基腐病菌（Pseudocercosporella herpotrichoides ) 、禾生球腔菌（Mycosphaerella graminicola)、穎枯殼多孢（Stagonospora nodorum)、小麥黃斑葉枯病菌（Pyrenophora tritici-repentis); 大麥病害：麥類白粉病（Erysiphe graminis)、禾穀鐮刀菌（Fusarium graminearum )、燕麥鐮刀菌（F. avenaceum)、黃色鐮刀菌（F. culmorum)、雪黴葉枯菌 (Microdochium nivale ))、條鏽病菌（Puccinia striiformis)、桿錄病（P. graminis)、葉绣病（P. hordei)、麥散黑粉菌（Ustilago nuda)、大麥雲紋病菌 (Rhynchosporium secalis )、大麥網斑（Pyreno'phora teres)、禾旋孢腔菌（Cochliobolus sativus)、麥類核腔 -17- 201206348 菌(Pyrenophora graminea )、立枯絲核菌(Rhizoctonia solani) ; 玉米病害：玉米黑穗菌（Ustilago maydis )、異旋孢腔菌（Cochliobolus heterostrophus)、高粱膠尾孢菌（ Gloeocercospora sorghi )、玉米錄菌（Puccinia polysora )、玉米尾孢菌（Cercospora zeaemaydis)、立枯絲核菌 (Rhizoctonia solani) ；柑橘病害：柑橘黑點病菌（Diaporthe citri)、相桔瘡痴病菌（Elsinoe fawcetti )、指狀青黴（Penicillium digitatum )、義大利青黴菌（P. i tali cum )、柑桔脚腐病菌（Phytophthora parasitica )、相拮褐腐疫黴（ Phytophthora citrophthora )；蘋果病害：蘋果鏈核盤菌（Monilinia mali )、蘋果樹腐爛病菌（Valsa ceratosperma )、白叉絲單囊殼（ Podosphaera leucotricha )、鑛果病變型鏈格孢菌（ Alternaria alternata apple pathotype ) 、瘡痂病（ Venturia inaequalis )、尖孢炭痕菌（Colletotrichum acutatum ) 、Phytophtora cactorum ；梨病害：梨黑星病菌（Venturi a nashi cola)(梨黒星病菌（V. pirina))、梨黑斑病菌（Alternaria alternata Japanese pear pathotype ) 、梨赤星病菌（ Gymnosporangium haraeanum ) 、惡疫黴（Phytophtora cactorum ) ; 桃子病害：褐腐病菌（Monilinia fructicola)、黑星 -18- 201206348 病（Cladosporium carpophilum )、擬睫點黴屬（ Phomopsis sp.); 葡萄病害：黑豆病（Elsinoe ampelina)、炭疽病菌 (Glomerella cingulata )、葡萄鉤絲殼（Uncinula necator )、葡萄層銹菌(Phakopsora ampelopsidis )、葡萄黑腐病菌（Guignardia bidwellii ) '葡萄露菌病菌（Blattella germanica )), brown cockroach (Periplaneta fuliginosa), American lynx (Periplaneta americana), black sissibe (Periplaneta brunnea), oriental 蟑螂 (Oriental 蜚蠊(Blatta orientalis), etc. ° -16- 201206348 Examples of plant diseases that can be prevented by "compositions" include the following: Rice diseases: Magnaporthe grisea, Cochliobolus miyabeanus, Li Rhizoctonia solani, Gibberella fujikuroi; wheat disease: Erysiphe graminis, Fusarium graminearum, F. avenaceum, Fusarium oxysporum (F_ culmorum), Microdochium nivale, Puccinia striiformis, P. graminis, p. recondite, Micronectriella nivale ' Typhula sp. , Ustilago tritici, Tilletia caries, wheat-based rot (Pseudoce) Rcosporella herpotrichoides ), Mycosphaerella graminicola, Stagonospora nodorum, Pyrenophora tritici-repentis; Barley disease: Erysiphe graminis, cereal trowel Fusarium graminearum, F. avenaceum, F. culmorum, Microdochium nivale, Puccinia striiformis, P. graminis ), P. hordei, Ustilago nuda, Rhynchosporium secalis, Pyreno'phora teres, Cochliobolus sativus, Wheat nucleus -17- 201206348 bacteria (Pyrenophora graminea), Rhizoctonia solani; corn disease: Ustilago maydis, Cochliobolus heterostrophus, sorghum Gloeocercospora sorghi, Puccinia polysora, Cercospora zeaemaydis, Rhizoctonia sol Ani) ; citrus diseases: Diaporthe citri, Elsinoe fawcetti, Penicillium digitatum, P. i tali cum, citrus foot rot (Phytophthora parasitica), Phytophthora citrophthora; Apple disease: Monilinia mali, Valsa ceratosperma, Podosphaera leucotricha, ore Alternaria alternata apple pathotype, Venturia inaequalis, Colletotrichum acutatum, Phytophtora cactorum; Pear disease: Venturi a nashi cola (Pear Star) V. pirina), Alternaria alternata Japanese pear pathotype, Gymnosporangium haraeanum, Phytophtora cactorum; Peach disease: Monilinia fructicola, black star - 18- 201206348 Disease (Cladosporium carpophilum ), Pseudomonas genus ( Pho Mopsis sp.); grape disease: Elsinoe ampelina, Glomerella cingulata, Uncinula necator, Phakopsora ampelopsidis, Guignardia bidwellii 'grape Phytophthora

Plasmopara viticola ) ; 柿子病害：柿盤長孢（Gloeosporium kaki)、柿角斑病（Cercospora kaki )(柿圓斑病（Mycosphaerella nawae)) ；葫蘆病害：瓜類炭疽病菌（Colletotrichum lagenarium)、瓜類白漉病菌（Sphaerotheca fuliginea) 、甜瓜球腔菌（Mycosphaerella melonis)、錘形黴菌（ *Plasmopara viticola ) ; Persimmon disease: Gloeosporium kaki, Cercospora kaki (Mycosphaerella nawae); Cucurbita disease: Colletotrichum lagenarium, melon white Sphaerotheca fuliginea, Mycosphaerella melonis, Hammer mold (*

Fusarium oxysporum ) 、古巴假霜霉病菌（ Pseudoperonospora cubensis)、疫黴菌屬(Phytophthora sp.)、腐黴屬（Pythiumsp.)；蕃前病害：交鏈孢菌（Alternaria solani)、蕃苑葉黴病菌（Cladosporium fulvum )、蕃前疫菌（ Phytophthora infestans) ；前子病害：節褐紋病菌（Phomopsis vexans)、二孢白粉菌(Erysiphe cichoracearum )；十字花科蔬菜病害：蘿菔黑斑病菌（Alternaria japonica)、白壯小尾孢（Cercosporella brassicae)、根瘤菌（Plasmodiophora brassicae )、寄生霜黴（ -19- 201206348Fusarium oxysporum ), Pseudoperonospora cubensis, Phytophthora sp., Pythium sp.; pre-carial disease: Alternaria solani, Fan Ye fungus Cladosporium fulvum), Phytophthora infestans; anterior disease: Phomopsis vexans, Erysiphe cichoracearum; Cruciferous vegetable disease: Alternaria japonica , Cercosporella brassicae, Plasmodiophora brassicae, parasitic mildew ( -19- 201206348

Peronospora parasitica ) ；大蔥病害：蔥柄銹菌（Puccinia allii )、毀壞霜黴（ Peronospora destructor ) ；大豆病害：大豆紫斑病菌（Cercospora kikuchii)、大豆黑痘病菌（Elsinoe glycines )、大豆黑點病菌（ Diaporthe phaseolorum var. sojae)、褐紋病菌(Septoria glycines)、灰斑病菌（Cercospora sojina)、大豆銹病 (Phakopsora pachyrhizi )、大豆疫霉菌（phytophthora sojae)、立枯絲核菌（Rhizoctonia solani)、莖枯菌（ Corynespora casiicola ) 、菌核病（ Sclerotinia sclerotiorum ) ；菜豆病害：豆刺盤孢（Colletotrichum 1 indemuthi anum ) ；花生病害：球座尾孢菌（Cercospora personata)、花生尾孢菌（Cercospora arachidicola)、白絹病菌（ Sclerotium rolfsii ) ；豌豆病害：豌豆白粉菌（Erysiphe pisi); 馬鈴薯病害：馬鈴薯夏疫病菌（Alternaria solani) 、馬鈴薯腐疫病菌（Phytophthora infestans)、馬鈴薯緋腐病菌(Phytophthora erythroseptica ) 、 Spongospora subterranean f. sp. Subterranea : 草莓病害：草莓白粉病（Sphaerotheca humuli)、炭疽病菌（Glomerella cingulata ); 茶病害：網狀外擔菌（Exobasidium reticulatum)、 -20- 201206348 茶瘡痂病菌（Elsinoe leucospila )、輪斑病（ Pestalotlopsis sp.)、炭疽病（Cο 11 etotrichum theae-sinensis ) ；煙草病害：煙草赤星病菌（Alternaria longipes)、二孢白粉菌（Erysiphe cichoracearum)、烟草刺盤孢（ Colletotrichum tabacum )、煙草霜霉菌（Peronospora tabacina)、煙草疫黴（Phytophthora nicotianae); 油菜好病害：菌核病菌（Sclerotinia sclerotiorum) 、立枯絲核菌（Rhizoctonia solani)；棉花病害：立枯絲核菌（Rhizoctoniasolani); 甜菜病害：甜菜生尾孢（Cercospora beticola)、瓜亡革菌（Thanatephorus cucumeris )、瓜亡革菌（ Thanatephorus cucumeris )、糸糸囊黴菌(Aphanomyces cochlioides) ; 玫瑰病害：薔薇雙殼菌（Diplocarpon rosae)、薔薇單囊殻菌（S p h a e r 〇 t h e c a p a η η 〇 s a )、薔薇露菌病菌（ Peronospora sparsa) ；菊花及菊科之病害：萵苣盤梗黴（Bremia lactucae) 、野菊殼針孢（Septoria chrysanthemi-indiei)、菊花白錄病(Puccinia horiana); 各種植物之病害：瓜果腐黴菌（Pythium aphanidermatum ) 、Pythium debarianum、禾生腐黴（Peronospora parasitica ); Scallion disease: Puccinia allii, Peronospora destructor; Soybean disease: Cercospora kikuchii, Elsinoe glycines, Diaporthe Phaseolorum var. sojae), Septoria glycines, Cercospora sojina, Phakopsora pachyrhizi, phytophthora sojae, Rhizoctonia solani, stem blight (Corynespora casiicola), Sclerotinia sclerotiorum; Bean disease: Colletotrichum 1 indemuthi anum; Peanut disease: Cercospora personata, Cercospora arachidicola, white Sclerotium rolfsii; pea disease: Erysiphe pisi; potato disease: Alternaria solani, Phytophthora infestans, Phytophthora erythroseptica, Spongospo Ra subterranean f. sp. Subterranea : Strawberry disease: Sphaerotheca humuli, Glomerella cingulata; Tea disease: Exobasidium reticulatum, -20- 201206348 Elsinoe leucospila , Pestalotlopsis sp., anthrax (Cο 11 etotrichum theae-sinensis); tobacco diseases: Alternaria longipes, Erysiphe cichoracearum, Colletotrichum tabacum, Peronospora tabacina, Phytophthora nicotianae; Rape good disease: Sclerotinia sclerotiorum, Rhizoctonia solani; Cotton disease: Rhizoctonia solani; Rhizoctonia solani; Beet diseases: Cercospora beticola, Thanatephorus cucumeris, Thanatephorus cucumeris, Aphanomyces cochlioides; Rose disease: Diplocarpon rosae , S. phaer Thecapa η η 〇sa ), Peronospora sparsa; Chrysanthemum and Compositae diseases: Bremia lactucae, Septoria chrysanthemi-indiei, Puccinia horiana ); diseases of various plants: Pythium aphanidermatum, Pythium debarianum, Pythium

Pythium graminicola)、畸雌腐黴菌（Pythium irregulare )、終極腐黴菌（Pythium ultimum )、灰黴菌（Botrytis -21 - 201206348 cinerea)、菌核菌（Sclerotinia sclerotiorum); 蘿蔔病害：芸苔鏈格孢（Alternariabrassicicola); 結縷草（Zoysia.) 病害：錢斑病（Sclerotinia homeocarpa)、立枯絲核菌（Rhizoctoniasolani); 香蕉病害：香蕉黑條葉斑病（Mycosphaerella fijiensis )、香蕉黃條葉斑病菌（Mycosphaerella mus i cο 1 a ) ；向日葵病害：霍爾斯軸霜黴（Plasmopara halstedii) » 種子病害或在各種植物生長的起始階段中由下列引起之病害：麴黴屬（Aspergillus spp.)、青黴屬（ Penicillium spp.)、鐮孢屬（Fusarium spp.)、赤黴菌屬 (Gibberella spp.)、木黴屬（Tricoderma spp.)、根串珠黴屬（Thielaviopsis spp.)、酒麴菌屬（Rhizopus spp· )、毛菌屬（Mucor spp·)、絲核菌屬（Corticium spp·) 、莖點黴屬（Phoma spp.)、絲核菌屬（Rhizoct oni a spp . )或色二孢菌（Diplodiaspp.); 由Polymixa屬及Olpidium屬或類似者媒介之各種植物的病毒病害。 “組成物”可用於其之植物的例子如下：農作物：玉米、稻穀、小麥、大麥、裸麥、燕麥、高梁、棉花、大豆、花生、蔷麥、甜菜、油菜子、向臼葵、甘蔗、菸草、等等：蔬菜：茄科植物（茄子、蕃茄、青椒、辣椒、馬鈴薯 -22- 201206348 、等等）、葫蘆科植物（黃瓜、南瓜、節瓜、西瓜、香瓜、西萌蘆、等等）；十字花科植物（日本蘿蔔、蕪菁、辣根、大頭菜、大白菜、甘藍菜、芥菜、青花菜、花椰菜、等等）、紫菀科植物（牛蒡、茼蒿、朝鮮薊、西生菜、等等）、百合科植物（韭菜、洋蔥、蒜、蘆筍、等等）、饊狀化科植物（胡蘿蔔、荷蘭芹、芹菜、野防風、等等）、黎科植物（菠菜、葉甜菜、等等）、唇形科植物（紫蘇、薄何、羅勒、等等）'草每、甘薯、日本山藥、天南星、等等；開花植物：觀葉植物草地；果樹：仁果類（蘋果、西洋梨、日本梨、木瓜、榲悖、等等）、核果類（桃、梅'油桃、日本李、櫻桃、杏、蜜棗 '等等）、柑橘類（溫州蜜柑、柳橙、萊姆、檸檬、葡萄柚、等等）、堅果類（栗子、胡桃、榛子、杏仁、開心果、腰果、夏威夷豆、等等）、漿果類（藍莓、蔓越莓、黑莓、樹莓、等等）、葡萄、柿子、橄欖、枇杷、香蕉、咖啡、海棗、椰子、等等；非果樹之樹木；茶樹、桑樹、開花樹、行道樹（白千廢、樺樹、山茱萸、桉樹、銀杏、紫丁香、楓、橡樹、白揚、紫荆、楓香、懸鈴木、櫸樹、日本冷杉、鐵杉、杜松、松樹、雲杉、紫杉）'等等。上述植物可爲該等藉由遺傳基因工程技術賦予抵抗性 -23- 201206348 者。在上述植物之中，“組成物”被預期特別是對在大豆中所引起之植物病害具有極佳防制效果。在上述植物病害之中，可預期“組成物”對其具有尤佳效果之大豆病害爲立枯絲核菌（Rhizoctonia solani)、大豆紫斑病菌（Cercospora kikuchii)、褐紋病菌（Septoria glycines )、莖枯菌(Corynespora casiicola )、大豆錄病 (Phakopsora pachyrizi )、菌核病菌（S c 1 erotini a sclerotiorum )、灰斑病菌(Cercospora sojina)、等等〇下列組成物舉例說明“組成物”之具體例：一種組成物，其包含“甲醯胺化合物（1 ) ”及可尼丁 t —種組成物，其包含“甲醯胺化合物（1 ) ”及益達胺 » 一種組成物，其包含“甲醯胺化合物（1) ”及賽速安 » —種組成物，其包含“甲醯胺化合物（2 ) ”及可尼丁 » —種組成物，其包含“甲醯胺化合物（2 ) ”及益達胺 * 一種組成物，其包含“甲醯胺化合物（2 ) ”及賽速安 f —種組成物，其包含“甲醯胺化合物（3 ) ”及可尼丁 -24- 201206348 —種組成物，其包含“甲醯胺化合物（3 ) ”及益達胺 t 一種組成物，其包含“甲醯胺化合物（3 ) ”及賽速安 » 一種組成物，其包含“甲醯胺化合物（4 ) ”及可尼丁 * 一種組成物，其包含“甲醯胺化合物（4 ) ”及益達胺 » 一種組成物，其包含“甲醯胺化合物（4 ) ”及賽速安 » 一種組成物，其包含“甲醯胺化合物（’5 ) ”及可尼丁 » 一種組成物，其包含“甲醯胺化合物（5 ) ”及益達胺一種組成物，其包含“甲醯胺化合物（5 ) ”及賽速安 * 一種組成物，其包含“甲醯胺化合物（1 ) ”及可尼丁，其中“甲醯胺化合物（1 ) ”對可尼丁的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（1 ) ”及益達胺，其中“甲醯胺化合物（1 ) ”對益達胺的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（1 ) ”及賽速安，其中“甲醯胺化合物（1 ) ”對賽速安的重量比爲0.01/1 -25- 201206348 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（2 ) ”及可尼丁，其中“甲醯胺化合物（2) ”對可尼丁的重量比爲0.01/1 至 4/1 ; —種組成物，其包含“甲醯胺化合物（2 ) ”及益達胺，其中“甲醯胺化合物（2 ) ”對益達胺的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（2 ) ”及賽速安，其中“甲醯胺化合物（2) ”對賽速安的重量比爲0.01/1 至 4/1 ; —種組成物，其包含“甲醯胺化合物（3 ) ”及可尼丁，其中“甲醯胺化合物（3) ”對可尼丁的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（3 ) ”及益達胺，其中“甲醯胺化合物（3 ) ”對益達胺的重量比爲0.01/1 至 4/1 ；一種組成物，其包含“甲醯胺化合物（3) ”及賽速安，其中“甲醯胺化合物（3) ”對賽速安的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（4 ) ”及可尼丁，其中“甲醯胺化合物（4) ”對可尼丁的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（4 ) ”及益達胺，其中“甲醯胺化合物（4 ) ”對益達胺的重量比爲0.01/1 -26- 201206348 至 4/1 ; —種組成物，其包含“甲醯胺化合物（4 ) ’，及賽速安，其中“甲醯胺化合物（4)，’對賽速安的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（5 )，’及可尼丁，其中“甲醯胺化合物（5)，’對可尼丁的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（5 )，，及益達胺 ’其中“甲醯胺化合物（5)，，對益達胺的重量比爲0.01/1 至 4/1 ; 一種組成物，其包含“甲醯胺化合物（5 )’，及賽速安 ’其中“甲醯胺化合物（5) ”對賽速安的重量比爲0.01/1 至 4/1。防制害蟲之方法（下文稱爲“防制方法”）可藉由用有效量之“甲醯胺化合物，，和“新菸鹼類化合物”處理植物或其中生長植物之土壤進行。欲處理之植物部份爲植物之莖和葉、植物之種子或鱗莖，且鱗莖表示鱗莖、球莖、根莖、塊莖、塊根及根托（ rhizophore)。在“防制方法”中，植物或其中生長植物之土壤用“甲酿胺化合物”和“新菸鹼類化合物”之處理可在同一時間分開地進行’但鑒於方便性，處理通常是藉由使用“組成物” 進行8 在“防制方法”中，用甲醯胺化合物”和“新菸鹼類化合 -27- 201206348 物”處理爲例如莖和葉施用、土壤施用、根施用或種子施用。莖和葉施用之例子包括藉由莖和葉噴霧或莖和樹噴霧的栽培植物之表面的處理。根施用之例子包括一種將整株植物或植物的根浸進包含“甲醯胺化合物”和“新菸鹼類化合物”之液體的方法和一種將包含“甲醯胺化合物”、“新菸鹼類化合物”和固體載體之固體製劑放置植物之根上的方法》土壤施用之例子包括一種將“組成物”噴霧在土壤上之方法、一種混合“組成物”與土壤之方法及一種將“組成物” 灌槪於土壤之方法。種子施用之例子包括一種用“組成物”處理欲防制植物病害的植物之種子或鱗莖的方法。特別地，施用可藉由將 “組成物”的懸浮液噴灑在種子或鱗莖的表面上，或藉由將可濕性粉劑、可乳化濃縮物或流動性調配物本身或其與小量水之混合物散佈在種子或鱗莖上，或藉由將種子浸在“ 組成物”之溶液中經規定時間，藉由薄膜塗布施用或顆粒塗布施用進行。 “防制方法”中所使用之“甲醯胺化合物”和“新菸鹼類化合物”的量視欲處理之植物的種類、欲防制之植物病害的種類和其頻率、調配物的種類、處理的時序、處理的方法、處理的地方、天氣條件、等等而不同。當“組成物”施用至植物之莖及/或葉或其中生長植物之土壤時，“甲醯胺化合物”和“新菸鹼類化合物”之總量通 -28- 201206348 常從1克至500克/1 000米2，較佳從2克至米2和更佳從10克/1000米2。當“組成物”施用至植物之種子時，“甲 “新菸鹼類化合物”之總量通常從0.001克3 之種子，和較佳從0.01克至1克/1公斤之可乳化濃縮物、可濕性粉劑或可流動I 量水稀釋調配物及噴灑稀釋之調配物。在It 釋調配物之總和中“甲醯胺化合物”和“新菸濃度通常在0.0 00 5%至2重量％，且較佳量％。粉末調配物或顆粒調配物等等常通常名用。【實施方式】 [實例] 本發明將以調配例及試驗例進一步詳箱 ’本發明不被下列實例限制。在下列實例中，“份”表示“重量份”，除調配例1 混合“甲醯胺化合物”（1 )至（5 )之-可尼丁（8份）、白碳和聚氧乙烯烷基醚® 物（重量比1 : 1 )( 3 5份）及水（5 5份）磨法將混合物粉碎以分別地產生各流動性靜 200 克 /1 000 醯胺化合物”和 i 1〇克/1公斤種子。 I配物通常用小匕情形中，在稀鹼類化合物”之 0.005% 至 1 重 Ξ沒有稀釋下使地說明。然而非另有提供。者（2份）、酸銨鹽的混合並藉由濕式硏配物。 -29 - 201206348 調配例2 混合“甲醯胺化合物”（1 )至（5 )之一者可尼丁（10份）、山梨醇酐三油酸酯（1.5 聚乙烯醇（2份）之水溶液（2 8.5份）並藉由將混合物粉碎。將包含三仙膠（0.05份）和〇· 1份）之水溶液（45份）加至粉碎混合物。 10份）加至混合物且藉由攪拌混合所得混合產生各流動性調配物。 (5 份）、 )、及包含濕式硏磨法矽酸鎂鋁（將丙二醇（物以分別地調配例3 將“甲醯胺化合物”（1 )至（5 )之一者（尼丁（ 4份）、合成含水氧化矽（1份）、木 (3份）、膨土（ 30份）和高嶺土（ 62份）及磨碎。將水加至混合物並將混合物充分地捏然後乾燥以分別地產生各顆粒調配物。 1份）、可質素磺酸鈣徹底地混合合，粒化且調配例4 將“甲醯胺化合物”（1 )至（5 )之一者（可尼丁（37.5份）、木質素磺酸鈣（3份）、鈉（2份）和合成含水氧化矽（45份）徹底地以分別地產生各可濕性調配物。 12.5 份）、硫酸月桂酯混合及磨碎調配例5 -30- 201206348 將“甲醯胺化合物”（1 )至（5 )之一者（3份）、可尼丁（ 2份）、高嶺土（ 85份）和滑石（1 0份）徹底地混合及磨碎以分別地產生各粉末調配物。調配例6 混合“甲醯胺化合物”（1 )至（5 )之一者（2份）、賽速安（8份）、白碳和聚氧乙烯烷基醚硫酸銨鹽的混合物（重量比1 : 1 ) ( 35份）及水（55份）並藉由濕式硏磨法將混合物粉碎以分別地產生各流動性調配物。調配例7 混合“甲醯胺化合物”（1 )至（5 )之一者（5份）、賽速安（10份）、山梨醇酐三油酸酯（1.5份）、及包含聚乙烯醇（2份）之水（28.5份）並藉由濕式硏磨法將混合物粉碎。將包含三仙膠（0.05份）和矽酸鎂鋁（0.1份 )之水溶液（45份）加至粉碎混合物。將丙二醇（10份 )加至混合物且藉由攪拌混合所得混合物以分別地產生各流動性調配物。調配例8 將“甲醯胺化合物”（1 )至（5 )之一者（1份）、賽速安（4份）、合成含水氧化矽（1份）、木質素磺酸鈣 (3份）、膨土（ 3 0份）和高嶺土（ 62份）徹底地混合及磨碎。將水加至混合物並將混合物充分地捏合且然後粒 -31 - 201206348 化及乾燥以分別地產生各顆粒調配物。調配例9 將“甲醯胺化合物”（1 )至（5 )之一者（12 · 5份）、賽速安（37.5份）、木質素磺酸鈣（3份）、硫酸月桂酯鈉（2份）和合成含水氧化矽（45份）徹底地混合和磨碎以分別地產生各可濕性調配物。調配例1 〇將“甲醯胺化合物”（1 )至（5 )之一者（3份）、賽速安（2份）、高嶺土（85份）和滑石（10份）徹底地混合和磨碎以分別地產生各粉末調配物。調配例11 混合“甲醯胺化合物”（1 )至（5 )之一者（2份）、益達胺（8份）、白碳和聚氧乙烯烷基醚硫酸銨鹽的混合物（重量比1 : 1 ) ( 3 5份）及水（5 5份）並藉由濕式硏磨法將混合物粉碎以分別地產生各流動性調配物。調配例12 混合“甲醯胺化合物”（1 )至（5 )之一者（5份）、益達胺（10份）、山梨醇酐三油酸酯（1.5份）、及包含聚乙烯醇（2份）之水（28.5份）並藉由濕式硏磨法將混合物粉碎。將包含三仙膠（〇.〇5份）和矽酸鎂鋁（0.1份 -32- 201206348 )之水溶液（45份）加至粉碎混合物。將丙二醇（i〇份 )加至混合物且藉由攪拌混合所得混合物以分別地產生各流動性調配物。調配例13 將“甲醯胺化合物”（1 )至（5 )之一者（1份）、益達胺（4份）、合成含水氧化矽（1份）、木質素磺酸鈣 (3份）、膨土（ 3 0份）和高嶺土（ 62份）徹底地混合及磨碎。將水加至混合物並將混合物充分地捏合且然後粒化及乾燥以分別地產生各顆粒調配物。調配例1 4 將“甲醯胺化合物”（1 )至（5 )之一者（12 · 5份）、益達胺（37·5份）、木質素磺酸鈣（3份）、硫酸月桂酯鈉（2份）和合成含水氧化矽（45份）徹底地混合和磨碎以分別地產生各可濕性調配物。調配例1 5 將“甲醯胺化合物”（1 )至（5 )之一者（3份）、益達胺（2份）、高嶺土（ 8 5份）和滑石（1 〇份）徹底地混合和磨碎以分別地產生各粉末調配物。下文中顯示使用各“組成物”之試驗例。試驗例 -33- 201206348 藉由使用種子處理用旋轉裝置（拌種機，由Hans-Ulrich Hege GmbH製造）將包含規定量（重量）之試驗化合物的環己酮溶液（100微升）施用於大豆種子（品種 :Natto shoryu) ( 1〇克）。在處理一天之後，將塑膠盆裝滿被立枯絲核菌（ Rhizoctonia solani)污染的土壤，並將用試驗化合物處理之種子播種在土壤中且在玻璃溫室中栽培長達20天（下文稱爲“處理土地》其後，觀察在從各種子發芽的幼苗中由立枯絲核菌（' Rhizoctonia solani)引起之病害的出現及根據下列計算式 (1 )計算病害嚴重性。另一方面，以如上述相同方式栽培沒有如上述處理之大豆種子（下文稱爲“非處理土地”）且以如上述“處理土地”相同之方式計算“非處理土地”中之病害嚴重性。根據上述“處理土地”和“非處理土地”中的病害嚴重性，根據下列計算式（2 )計算“處理土地"中之效力。結果顯不在表1至表6中。計算式（1 ): 病害嚴重性（％) =(感染幼苗數/幼苗總數）X 100 計算式（2 ): 效力（％) =[1 -(“處理土地”中之病害嚴重性/ “非處理土地”中之病害嚴重性）]x 100 -34- 201206348 [表l] “甲醯胺化合物(1)” [克"〇〇公斤之種子] “可尼丁” [克/100公斤之種子] 效力(％) 0.2 5 68.4 0.2 ——— 42.1 [表2] “甲醯胺化合物(V)，， [克/100公斤之種子] “可尼丁” [克/100公斤之種子] 效力(％) 0.2 5 57.9 0.2 ——_ 21.1 [表3] “甲醯胺化合物(1)” [克A 〇〇公斤之種子] “益達胺” [克/100公斤之種子] 效力(％) 0.2 5 63.2 0.2 42.1 [表4] “甲醯胺化合物(V)” [克/100公斤之種子] “益達胺” [克/100公斤之種子] 效力(％) 0.2 5 63.2 0.2 ——· 21.1 [表5] “甲醯胺化合物(1)” [克A 00公斤之種子] “賽速安” [克/100公斤之種子] 效力(％) 0.2 5 68.4 0.2 ——— 42.1 -35- 201206348 [表6] “甲醯胺化合物(V)” [克/100公斤之種子] “賽速安” [克/100公斤之種子] 效力(％) 0.2 5 63.2 0.2 21.1 工業應用性一種包含以式（I)表示之“甲醯胺化合物”及選自（A )組之新菸鹼類化合物的殺蟲組成物係可用於防制害蟲。 -36-Pythium graminicola), Pythium irregulare, Pythium ultimum, Botrytis -21 - 201206348 cinerea, Sclerotinia sclerotiorum; Radish disease: Alternariabrassicicola Zoysia. Disease: Sclerotinia homeocarpa, Rhizoctoniasolani; Banana disease: Mycosphaerella fijiensis, Mycosphaerella Mus i cο 1 a ) ; Sunflower disease: Plasmopara halstedii » Seed diseases or diseases caused by the following stages in the growth stages of various plants: Aspergillus spp., Penicillium (Picicillium spp.), Fusarium spp., Gibberella spp., Tricoderma spp., Thielaviopsis spp., Rhizopus spp ·), Mucor spp., Corticium spp., Phoma spp., Rhizoct oni a spp. or color II Diplodiaspp.; a viral disease of each plant that is mediated by the Polymixa genus and the Olpidium genus or the like. Examples of plants in which the "composition" can be used are as follows: Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, peanuts, buckwheat, beets, rapeseed, hollyhock, sugar cane, Tobacco, etc.: Vegetables: Solanaceae (eggplant, tomato, green pepper, pepper, potato-22-201206348, etc.), Cucurbitaceae (cucumber, pumpkin, melon, watermelon, melon, sage, etc. ); cruciferous plants (Japanese radish, turnip, horseradish, kohlrabi, Chinese cabbage, kale, mustard, broccoli, broccoli, etc.), Asteraceae (Burdock, Artemisia, Artichoke, Western lettuce, etc.) ), lily plants (chives, onions, garlic, asparagus, etc.), scorpion plants (carrots, parsley, celery, wild wind, etc.), Rico plants (spinach, leaf beets, etc.) , Labiatae (Perilla, Boho, Basil, etc.) 'grass, sweet potato, Japanese yam, Araceae, etc.; Flowering plants: foliage plants; fruit trees: pome fruits (apples, Pear, Japanese pear, papaya, medlar, etc.), stone fruit (peach, plum 'nectar, Japanese plum, cherry, apricot, candied dates', etc.), citrus (Wenzhou mandarin orange, orange, lime, lemon, Grapefruit, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, hawaiian beans, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, Persimmons, olives, alfalfa, bananas, coffee, dates, coconuts, etc.; non-fruit trees; tea trees, mulberry trees, flowering trees, street trees (white thousand waste, birch, hawthorn, eucalyptus, ginkgo, lilac, maple, Oak, Baiyang, Bauhinia, Liquidambar, Platanus, Eucalyptus, Japanese fir, hemlock, juniper, pine, spruce, yew) and so on. The above plants may be those which are rendered resistant by genetic engineering techniques -23-201206348. Among the above plants, the "composition" is expected to have an excellent control effect particularly on plant diseases caused in soybeans. Among the above plant diseases, the soybean diseases which can be expected to have a particularly good effect on the "composition" are Rhizoctonia solani, Cercospora kikuchii, Septoria glycines, stems. Specific examples of "composition" are exemplified by the following compositions of Corynespora casiicola, Phakopsora pachyrizi, S c 1 erotini a sclerotiorum, Cercospora sojina, and the like. A composition comprising "formamide compound (1)" and a nicotine t-type composition comprising "formammine compound (1)" and edaramin» a composition comprising "a a composition of a guanamine compound (1)" and a sylvestre" comprising a "formamide compound (2)" and a composition of konidin, which comprises "formamide compound (2)" and达达amine* A composition comprising "formamide compound (2)" and a serotonin composition comprising "formamide compound (3)" and cotinine-24-201206348 Composition comprising a composition of the carbamide compound (3)" and idacaine t, which comprises "formamide compound (3)" and a composition of "Synthesis", which comprises "formamide compound (4)" and Nitin* A composition comprising "formammine compound (4)" and edetamine» a composition comprising "formammine compound (4)" and Sai'an» a composition comprising " A composition of a carbamide compound ('5)" and a nicidine, which comprises a composition of "formamide compound (5)" and edetamine, which comprises "formamide compound (5)" and race A composition comprising "formamide compound (1)" and cotinine, wherein the weight ratio of "formamide compound (1)" to cotinine is from 0.01/1 to 4/1; a composition comprising "formamide compound (1)" and edaramin, wherein the weight ratio of "formamide compound (1)" to edaramin is from 0.01/1 to 4/1; a composition Contains "carbamamine compound (1)" and Sai Su'an, where "carbamamine compound (1)" is heavy on Sai Su'an The ratio is 0.01/1 -25 - 201206348 to 4/1 ; a composition comprising "formamide compound (2)" and cotinine, wherein "carbamamine compound (2)" has a weight of konidine The ratio is from 0.01/1 to 4/1; a composition comprising "formamide compound (2)" and idalide, wherein the weight ratio of "formamide compound (2)" to edaramin is 0.01 /1 to 4/1 ; a composition comprising "formamide compound (2)" and Sai Suan, wherein the weight ratio of "methionine compound (2)" to Sai Suan is 0.01/1 to 4 a composition comprising "formamide compound (3)" and cotinine, wherein the weight ratio of "formamide compound (3)" to cotinine is from 0.01/1 to 4/1; A composition comprising "formamide compound (3)" and edaramin, wherein the weight ratio of "formamide compound (3)" to edaramin is from 0.01/1 to 4/1; a composition, It comprises "formamide compound (3)" and Sai Suan, wherein the weight ratio of "formamide compound (3)" to Sai Suan is 0.01/1 to 4/1; a composition comprising "A a guanamine compound (4)" and a nicotine, wherein the weight ratio of "formamide compound (4)" to cotinine is from 0.01/1 to 4/1; a composition comprising "formamide compound ( 4) "and etalide, wherein the weight ratio of "methionine compound (4)" to edaramin is 0.01/1 -26 - 201206348 to 4/1; a composition comprising "formamide compound" (4) ', and Sai Su'an, wherein "carbamamine compound (4), 'weight ratio to Sai Sai'an is 0.01/1 to 4/1; a composition comprising "formamide compound (5 And 'codonine, wherein the "carbamamine compound (5), the weight ratio of 'n-codonine is 0.01/1 to 4/1; a composition comprising "formamide compound (5), And etalide 'wherein the weight ratio of the meglumine compound (5) to the idadamine is from 0.01/1 to 4/1; a composition comprising the "formamide compound (5)", and Sai Su'an's "carbamamine compound (5)" has a weight ratio of 0.01/1 to 4/1. The method for controlling pests (hereinafter referred to as "prevention method") can be carried out by treating the plants or the soil in which the plants are grown with an effective amount of "mercaptoamine compound, and "neoxotine compound". The plant parts are the stems and leaves of the plants, the seeds or bulbs of the plants, and the bulbs represent the bulbs, bulbs, rhizomes, tubers, roots and rhizophores. In the "prevention method", the plants or the soil in which the plants are grown The treatment with "mercaptoamine compound" and "neoxotine compound" can be carried out separately at the same time 'but for convenience, the treatment is usually carried out by using "composition" 8 in the "prevention method" Treatment with formazan compound and neonicotinoid compound -27-201206348 is, for example, stem and leaf application, soil application, root application or seed application. Examples of stem and leaf application include the treatment of the surface of cultivated plants sprayed by stems and leaves or by stems and trees. Examples of root application include a method of immersing the roots of whole plants or plants into a liquid containing "formamide compound" and "neoxotine compound" and a method comprising "mercaptoamine compound" and "neoxotine" Method for placing a solid compound in a solid preparation on a root of a plant. Examples of soil application include a method of spraying a "composition" on soil, a method of mixing a "composition" with soil, and a method of "constructing" The method of filling the soil. Examples of seed application include a method of treating a seed or bulb of a plant to be treated with a "composition" to prevent plant diseases. In particular, the application can be carried out by spraying a suspension of "composition" onto the surface of the seed or bulb, or by using a wettable powder, an emulsifiable concentrate or a fluid formulation itself or with a small amount of water. The mixture is spread over the seed or bulb, or by dipping the seed in a solution of the "composition" for a specified period of time, by film coating application or particle coating application. The amount of "formamide compound" and "neoxotine compound" used in the "prevention method" depends on the kind of the plant to be treated, the type and frequency of the plant disease to be prevented, the type of the formulation, The timing of the processing, the method of processing, the place of processing, the weather conditions, and the like are different. When the "composition" is applied to the stems and / or leaves of plants or the soil in which the plants are grown, the total amount of "formamide compound" and "neoxotine compound" is from -28 to 201206348 often from 1 to 500. Gram / 1 000 m 2 , preferably from 2 g to m 2 and more preferably from 10 g / 1000 m 2 . When the "composition" is applied to the seed of the plant, the total amount of "a neonicotinoid compound" is usually from 0.001 g of the seed of 3, and preferably from 0.01 g to 1 g / 1 kg of the emulsifiable concentrate, Dilute the formulation with a wettable powder or a flowable amount of water and spray the diluted formulation. The "formamide compound" and "new smoke concentration are usually between 0.000% and 2% by weight in the sum of the It's release formulation. And the preferred amount is %. Powder formulations or granule formulations and the like are often used. [Embodiment] [Examples] The present invention will be further described in terms of formulation examples and test examples. The present invention is not limited by the following examples. In the following examples, "parts" means "parts by weight", except for blending Example 1, mixing "formamide compound" (1) to (5) - cotinine (8 parts), white carbon and polyoxyethylene alkyl group Ether® (weight ratio 1:1) (35 parts) and water (5 5 parts) The mixture was pulverized by grinding to produce each fluidity static 200 g / 1 000 guanamine compound" and i 1 gram / 1 kg of seed. I formulation is usually described in the case of small sputum, 0.005% to 1 Ξ of the dilute alkali compound, without dilution. However, it is not provided separately. (2 parts), a mixture of ammonium salts and a wet hydrazine formulation. -29 - 201206348 Formulation Example 2 An aqueous solution of nicotine (10 parts) and sorbitan trioleate (1.5 parts of polyvinyl alcohol (2 parts)) in which one of the "formamide compounds" (1) to (5) is mixed. (2 8.5 parts) and by pulverizing the mixture, an aqueous solution (45 parts) containing celestial gum (0.05 parts) and 〇·1 part) was added to the pulverized mixture. Each of the fluid formulations was prepared by adding to the mixture and mixing by stirring. (5 parts), ), and containing the wet honing method of magnesium aluminum silicate (the propylene glycol (the substance is separately formulated in Example 3, one of the "formamide compounds" (1) to (5) (Nitin ( 4 parts), synthetic aqueous cerium oxide (1 part), wood (3 parts), bentonite (30 parts) and kaolin (62 parts) and ground. Water is added to the mixture and the mixture is fully kneaded and then dried to separate Each particle preparation is produced. 1 part), calcium sulfonate sulfonate is thoroughly mixed, granulated and formulated. Example 4 "Metamine compound" (1) to (5) (Knidding (37.5) (Parts), calcium lignin sulfonate (3 parts), sodium (2 parts) and synthetic aqueous cerium oxide (45 parts) thoroughly to produce each wettable formulation separately. 12.5 parts), lauryl sulfate mixture and grinding Fine Formulation 5 -30- 201206348 One of the "formamide compounds" (1) to (5) (3 parts), cotinine (2 parts), kaolin (85 parts) and talc (10 parts) Thoroughly mix and grind to separately produce each powder formulation. Formulation Example 6 Mix one of the "formamide compounds" (1) to (5) (2 parts), Sai Su An (8 parts), a mixture of white carbon and polyoxyethylene alkyl ether ammonium sulfate (weight ratio 1:1) (35 parts) and water (55 parts) and by wet 硏The mixture was pulverized to separately produce each of the fluidity formulations. Formulation Example 7 Mixing one of the "formamide compounds" (1) to (5) (5 parts), Sai Su'an (10 parts), sorbitol An anhydride trioleate (1.5 parts), and water (28.5 parts) containing polyvinyl alcohol (2 parts) and pulverizing the mixture by wet honing. It contains celery (0.05 parts) and magnesium citrate. An aqueous solution of aluminum (0.1 part) (45 parts) was added to the pulverized mixture. Propylene glycol (10 parts) was added to the mixture and the resulting mixture was mixed by stirring to separately produce each of the fluidity formulations. One of the compounds "(1) to (5) (1 part), Sai Su'an (4 parts), synthetic aqueous cerium oxide (1 part), calcium lignosulfonate (3 parts), bentonite (30 parts) ) thoroughly mixed and ground with kaolin (62 parts). Water is added to the mixture and the mixture is fully kneaded and then granulated -31 - 201206348 And drying to separately produce each particle formulation. Formulation Example 9 "Metamine compound" (1) to (5) (12 · 5 parts), Sai Suan (37.5 parts), lignosulfonic acid Calcium (3 parts), sodium lauryl sulfate (2 parts) and synthetic aqueous cerium oxide (45 parts) were thoroughly mixed and ground to separately produce each wettable formulation. Formulation Example 1 〇 "Metamine compound" One of (1) to (5) (3 parts), Sai Su An (2 parts), kaolin (85 parts), and talc (10 parts) were thoroughly mixed and ground to separately produce each powder formulation. Formulation Example 11 Mixture of one of "formamide compound" (1) to (5) (2 parts), edamine (8 parts), white carbon and polyoxyethylene alkyl ether ammonium sulfate (weight ratio) 1 : 1 ) (35 parts) and water (5 5 parts) and the mixture was pulverized by wet honing to separately produce each fluidity formulation. Formulation Example 12 Mixing one of "formamide compounds" (1) to (5) (5 parts), idalide (10 parts), sorbitan trioleate (1.5 parts), and polyvinyl alcohol (2 parts) of water (28.5 parts) and the mixture was pulverized by wet honing. An aqueous solution (45 parts) containing Sanxian gum (5 parts by weight) and magnesium aluminum silicate (0.1 part -32 to 201206348) was added to the pulverized mixture. Propylene glycol (i) was added to the mixture and the resulting mixture was mixed by stirring to separately produce each of the fluidity formulations. Formulation Example 13 "Metformamide compound" (1) to (5) (1 part), edodamin (4 parts), synthetic aqueous cerium oxide (1 part), calcium lignosulfonate (3 parts) ), benton (30 parts) and kaolin (62 parts) thoroughly mixed and ground. Water was added to the mixture and the mixture was sufficiently kneaded and then granulated and dried to separately produce each particle formulation. Formulation Example 1 4 "Metformamide compound" (1) to (5) one (12 · 5 parts), idalide (37. 5 parts), calcium lignosulfonate (3 parts), sulfuric acid laurel Sodium ester (2 parts) and synthetic aqueous cerium oxide (45 parts) were thoroughly mixed and ground to separately produce each wettable formulation. Formulation Example 1 5 Thoroughly mix one of the "methionine compounds" (1) to (5) (3 parts), eddaramine (2 parts), kaolin (85 parts) and talc (1 part) And grinding to produce each powder formulation separately. Test examples using the respective "compositions" are shown below. Test Example-33-201206348 A cyclohexanone solution (100 μL) containing a predetermined amount (by weight) of a test compound was applied to soybean by using a seed treatment rotary device (seed dresser, manufactured by Hans-Ulrich Hege GmbH) Seed (variety: Natto shoryu) (1 gram). After one day of treatment, the plastic pots were filled with soil contaminated with Rhizoctonia solani, and the seeds treated with the test compound were sown in the soil and cultivated in a glass greenhouse for up to 20 days (hereinafter referred to as "Treatment of the land" Thereafter, the occurrence of the disease caused by Rhizoctonia solani in the seedlings germinated from various seeds was observed and the severity of the disease was calculated according to the following formula (1). The soybean seed which is not treated as described above (hereinafter referred to as "non-treated land") is cultivated in the same manner as described above and the disease severity in "non-treated land" is calculated in the same manner as the "treatment of land" as described above. The severity of the disease in "and non-treated land" is calculated according to the following formula (2). The results are shown in Tables 1 to 6. The calculation formula (1): disease severity ( %) = (number of infected seedlings / total number of seedlings) X 100 Calculation formula (2): Efficacy (%) = [1 - (Severity of disease in "treated land" / serious disease in "non-treated land" Sex))x 100 -34- 201206348 [Table l] "Propylamine compound (1)" [g" & 〇〇〇〇 kg seed] "Knitidine" [g / 100 kg of seed] Efficacy (%) 0.2 5 68.4 0.2 ——— 42.1 [Table 2] “Proline compound (V), [[g/100 kg of seed] “Knitidine” [g/100 kg of seed] Efficacy (%) 0.2 5 57.9 0.2 ——_ 21.1 [Table 3] “Proline compound (1)” [K A 〇〇 kg of seed] “IDA amide” [g / 100 kg of seed] Efficacy (%) 0.2 5 63.2 0.2 42.1 [Table 4] "Proline compound (V)" [g / 100 kg of seed] "IDA" [g / 100 kg of seed] Efficacy (%) 0.2 5 63.2 0.2 ——· 21.1 [Table 5] “A Indoleamine compound (1)" [K A 00 kg seed] "Sai Su An" [g / 100 kg of seed] Efficacy (%) 0.2 5 68.4 0.2 ——— 42.1 -35- 201206348 [Table 6] “A Indoleamine compound (V)" [g / 100 kg of seed] "Sai Su An" [g / 100 kg of seed] Efficacy (%) 0.2 5 63.2 0.2 21.1 Industrial applicability contains a formula (I) Methionine compound" and selected from group (A) The insecticidal composition of neonicotinoid compounds can be used to control pests.

Claims

201206348 VII. Patent application scope: 1. A pesticidal composition comprising a methotrexate compound represented by formula (I):

Wherein R1 represents a hydrogen atom or a methyl group, and R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group, and one or more selected from the group consisting of acetamiprid, clothi anidin, and tainnan ( Neonicotinoids of group (A) consisting of dinotefuran), imidacloprid, nitenpyram, thiacloprid and thiamethoxam. 2. The insecticidal composition according to claim 1, wherein the weight ratio of the methotrexate compound to the neonicotinoid compound (formamide compound/neoxotine compound) is from 0.01/1 to 4 /1. 3. The insecticidal composition according to claim 1 or 2, wherein the neonicotinoid compound is cotinine. 4. A method for controlling pests comprising an effective amount of a formamide compound represented by formula (I): -37- 201206348

Wherein R1 represents a hydrogen atom or a methyl group* and R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group, and one or more selected from the group consisting of sub-cyanide, cotinidine, dardon, edamine, acetamiprid A step of treating a plant or a soil in which a plant is grown by a neonicotinoid compound of the group (A) consisting of an amine, a sage, and a sylvestre. 5. The method for controlling pests according to item 4 of the patent application, wherein the The weight ratio of the guanamine compound to the neonicotinoid compound (formamide compound/neoxotine compound) is from 0.01/1 to 4/1. 6. The method for controlling pests according to claim 4 or 5, wherein the neonicotinoid compound is cotinine. 7. The method for controlling pests according to claim 4 or 5, wherein the plant or the soil in which the plant is grown is soybean or soil in which the soybean is grown. -38- 201206348 IV. Designated representative map: (1) The designated representative circle of this case is: None (2) The symbol of the symbol of this representative is simple: No 201206348 V. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: formula (I)

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