201205238 六、發明說明： 【發明所屬之技術領域】 本發明大體上是有關用於電子裝置的保護套件，且特 別是關於整合太陽能電池以對電子裝置進行充電的保護 套件。 【先前技術】 籲 隨者半導體技術不斷提升、加上消費者對電子裝置的 倚賴漸深，可攜式電子裝置有取代傳統消費性電子產品 的趨勢，例如手機、媒體播放器、筆記型電腦等。但可 攜式電子裝置的功能越多，耗電量越大，如何延長其使 用時間已成為開發關鍵。 可攜式電子裝置主要仰賴電池供電。然使用諸如錄氣 電池、鎳鎘電池等一次電池會破壞環境，即便使用二次 電池（如鐘電池）’也因電量有限而需時常充電，以致相 當不便。 【發明内容】 有鑑於此，本發明之一目的為提出兼具保護與充電功 -的套件，如此不但可簡化電子裝置的配備，又因隨時 可對電子裝置進行充電而延長其使用時間。 根據本發明之一態樣， 件。保護套件包含主體、 提出整合太陽能電池的保護套 和樞接主體一側且可覆蓋主體 201205238 之内p工pBi的蓋體。由至少—個染料敏化太陽能電池組 成的太陽能電池模組内嵌於蓋體的中空部。直流(Ο。)，。。 轉換器電眭連接太陽能電池模組和連接器。當電子裝置 _接連接器時’太陽能電池模組將透過轉換器對 電子裝置進行充電β其中，染料敏化太陽能電池包含第 -電極基板及第二電極基板。第一電極基板可接收從蓋 體之第表面進入的入射光，第二電極基板可接收從蓋 體之第一表面進入的入射光，使得太陽能電池模組可利 用從第表面進入之入射光或者可利用從第二表面進入 之入射光對該電子裝置進行充電。 根據本發明之另—態樣，提出整合太陽能電池的保護 套件。保護套件包含具内部空間之主體，用以容納電子 裝置、和樞接主體一側且可覆蓋主體之内部空間的蓋 體。第一太陽能電池模組設於蓋體的第一表面，第二太 陽能電池模組設於蓋體的第二表面，第一和第二太陽能 電池模組各包括至少一個染料敏化太陽能電池。直流 (DC)/DC轉換器電性連接第一與第二太陽能電池模組和 連接器。第一太陽能電池模組及/或第二太陽能電池模組 將透過DC/DC轉換器對電子裝置進行充電。 上述保護套件配有染料敏化太陽能電池模組，其可雙 面照光發電，因此無論是打開或闔上保護套件皆可對同 一染料敏化太陽能電池進行充電動作、此外由於使用染 料敏化太陽能電池故在戶外或室内皆可充電使用電子裝 201205238 【實施方式】 為讓本發明之上述與其他目的、特徵和優點變得更明 顯易懂，現將配合參照所附圖式詳加說明於下。然須注 意的是，所述實施例僅為舉例說明本發明，而非限定本 發明之精神與範圍，熟諳此技藝者當可進行修改而得等 效實施例。 參照第1及2圖，其分別繪示打開及蓋闔狀態下的保 護套件實施例。如第1圖所示，保護套件包括内含容納 空間11 5的主體11 〇、和可覆蓋及封閉空間i丨5的蓋體 120。蓋體120樞接主體110的一側，以便於繞著樞軸R 打開或闔上蓋體120。主體11〇及/或蓋體12〇可為硬性 殼體或軟性套體。在一實例中，主體11〇和蓋體12〇為 結合成一體的套體。 根據一實施例，第一太陽能電池模組WOq配置在蓋 體120的第一表面19〇 (第2圖），第二太陽能電池模組 160-2則配置在蓋體12〇的第二表面2〇〇 (第1圖在一 實例中，太陽能電池模組160]、16〇·2各自包括至少_ 個染料敏化太陽能電池（DSSC)。個別太陽能電池模組之 染料敏化太陽能電池為複數個時，其可為串聯或並聯配 置，但串聯易因遮蔽效應導致整個模組失效，故較佳採 用並聯方式。第4圖繪示根據一實施例之太陽能電池模 組的截面，其包括複數個並聯的染料敏化太陽能電池。 201205238 染料敏化太陽能電池一般包括陰極（第一電極基板 170)、陽極（第二電極基板18〇)和介於二者間的電解質。 如第4圖所示，第一電極基板17〇包括設於第一基板21〇 上的對電極240，第二電極基板18〇包括設於第二基板 310上的光電極340，其中對電極24〇配置對應光電極 340。第一基板210及/或第二基板31〇可為撓性基板（如 塑膠基板）或硬性基板（如玻璃基板）。第一基板21〇及第 二基板310為透明或半透明基板（高穿透率的基板較 佳）。第一電極基板1 70和第二電極基板丨8〇的表面分別 具有導電層220和導電層320。導電層通常為透明導電 氧化物（tco)膜，例如銦錫氧化物（IT〇)、氟錫氧化物 (FTO)、摻銻氧化錫（ΑΤΟ)、摻鋁氧化鋅（ΑΖ〇)、摻鎵氧 化鋅（GZ0)或摻銦氧化鋅（ΙΖ〇) ^導電層亦可為金屬材 料’例如H、銘、銀、金、銅、鋅、鈦或金卜對電極24〇 配置在導電層220上，並可包括鉑（pt)或碳（c)等電極 • &。在一實例中’對電極還包括高分子包覆之貴金屬粒 子做為觸媒層，導電層上則有界面活性層連結高分子包 覆之貴金屬粒子。高分子可為聚乙烯吡咯烷酮（pvp)、聚 丙烯醯胺（PAM)、聚乙烯醇（PVAL)、聚丙烯酸（pAA)或聚 次乙亞胺（PEI);被高分子包覆之責金屬可為鈀（pd)、鉑 (Pt)、釕（Ru)、銀（Ag)或金（Au)等。此種對電極其穿透率 較一般以濺鍍法形成之鉑電極層為佳。光電極34〇配置 在導電層320上，且可包括含光敏染料之金屬半導體氧 化物（如Ti〇2層）。電解質層450配置在對電極24〇與201205238 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention generally relates to a protection kit for an electronic device, and more particularly to a protection kit for integrating a solar cell to charge an electronic device. [Prior Art] With the continuous improvement of semiconductor technology and consumer reliance on electronic devices, portable electronic devices have the tendency to replace traditional consumer electronic products, such as mobile phones, media players, notebook computers, etc. . However, the more functions of portable electronic devices, the greater the power consumption, and how to extend their use time has become the key to development. Portable electronic devices rely mainly on battery power. However, the use of a primary battery such as a gas battery or a nickel-cadmium battery can damage the environment, even if a secondary battery (such as a clock battery) is used, it is often charged due to limited power, which is quite inconvenient. SUMMARY OF THE INVENTION In view of the above, it is an object of the present invention to provide a kit that combines protection and charging work, which not only simplifies the arrangement of the electronic device, but also prolongs the use time of the electronic device by charging it at any time. According to one aspect of the invention, the piece. The protection kit includes a main body, a protective cover that proposes an integrated solar cell, and a cover body that is on one side of the pivoting body and can cover the p-work pBi in the main body 201205238. A solar cell module composed of at least one dye-sensitized solar cell is embedded in a hollow portion of the cover. DC (Ο.),. . The converter is electrically connected to the solar cell module and the connector. When the electronic device is connected to the connector, the solar cell module charges the electronic device through the converter. The dye-sensitized solar cell includes a first electrode substrate and a second electrode substrate. The first electrode substrate can receive incident light entering from the first surface of the cover body, and the second electrode substrate can receive incident light entering from the first surface of the cover body, so that the solar cell module can utilize incident light entering from the first surface or The electronic device can be charged using incident light entering from the second surface. According to another aspect of the present invention, a protective kit for integrating a solar cell is proposed. The protection kit includes a body having an internal space for accommodating the electronic device, and a cover that pivots one side of the main body and covers the internal space of the main body. The first solar cell module is disposed on the first surface of the cover body, the second solar cell module is disposed on the second surface of the cover body, and the first and second solar cell modules each include at least one dye-sensitized solar cell. A direct current (DC)/DC converter electrically connects the first and second solar cell modules and connectors. The first solar cell module and/or the second solar cell module will charge the electronic device through the DC/DC converter. The above protection kit is equipped with a dye-sensitized solar cell module, which can generate electricity by double-sided illumination, so that the same dye-sensitized solar cell can be charged by opening or slamming the protection kit, and also by using dye-sensitized solar cells. Therefore, the above-mentioned and other objects, features and advantages of the present invention will become more apparent from the accompanying drawings. It is to be understood that the embodiments are merely illustrative of the invention, and are not intended to Referring to Figures 1 and 2, there are shown embodiments of the sheath retaining member in the open and closed state, respectively. As shown in Fig. 1, the protection kit includes a main body 11 that houses the accommodation space 115, and a cover 120 that covers and closes the space i丨5. The cover 120 is pivoted to one side of the body 110 to facilitate opening or closing the cover 120 about the pivot R. The body 11 〇 and/or the cover 12 〇 may be a rigid casing or a flexible casing. In one example, the body 11 〇 and the cover 12 〇 are integrated into a casing. According to an embodiment, the first solar cell module WOq is disposed on the first surface 19 of the cover 120 (Fig. 2), and the second solar module 160-2 is disposed on the second surface 2 of the cover 12第 (In the first embodiment, the solar cell module 160], 16〇·2 each include at least _ dye-sensitized solar cells (DSSC). The dye-sensitized solar cells of the individual solar cell modules are plural When it is arranged in series or in parallel, but the series is easy to cause the entire module to fail due to the shadowing effect, it is preferably in parallel mode. FIG. 4 is a cross section of the solar cell module according to an embodiment, which includes a plurality of Dye-sensitized solar cells in parallel. 201205238 Dye-sensitized solar cells generally include a cathode (first electrode substrate 170), an anode (second electrode substrate 18A), and an electrolyte interposed therebetween. As shown in FIG. The first electrode substrate 17 includes a counter electrode 240 disposed on the first substrate 21 , and the second electrode substrate 18 includes a photo electrode 340 disposed on the second substrate 310 , wherein the counter electrode 24 is disposed with a corresponding photo electrode 340 . the first The board 210 and/or the second substrate 31 can be a flexible substrate (such as a plastic substrate) or a rigid substrate (such as a glass substrate). The first substrate 21 and the second substrate 310 are transparent or translucent substrates (high transmittance) The substrate is preferably. The surfaces of the first electrode substrate 170 and the second electrode substrate 丨8〇 respectively have a conductive layer 220 and a conductive layer 320. The conductive layer is usually a transparent conductive oxide (tco) film, such as indium tin oxide. (IT〇), fluorine tin oxide (FTO), antimony-doped tin oxide (ΑΤΟ), aluminum-doped zinc oxide (ΑΖ〇), gallium-doped zinc oxide (GZ0) or indium-doped zinc oxide (ΙΖ〇) ^ conductive layer The electrode material 24 such as H, Ming, silver, gold, copper, zinc, titanium or gold may be disposed on the conductive layer 220 and may include electrodes such as platinum (pt) or carbon (c). In an example, the counter electrode further includes a polymer-coated noble metal particle as a catalyst layer, and the conductive layer has an interface layer bonded to the polymer-coated noble metal particle. The polymer may be polyvinylpyrrolidone (pvp). , polyacrylamide (PAM), polyvinyl alcohol (PVAL), polyacrylic acid (pAA) or poly Ethyleneimine (PEI); the metal coated with the polymer may be palladium (pd), platinum (Pt), ruthenium (Ru), silver (Ag) or gold (Au), etc. The transmittance is preferably higher than that of the platinum electrode layer formed by sputtering. The photoelectrode 34 is disposed on the conductive layer 320 and may include a metal semiconductor oxide (such as a Ti 2 layer) containing a photosensitizing dye. At the counter electrode 24
f SJ 6 201205238 電極340之間。 至少一導線410置於導電層22〇上且電性連接至少一 個對電極240而構成第一電極基板17〇 (陰極），另一導 線41 0置於導電層320上且電性連接至少一個光電極34〇 而構成第二電極基板18〇(陽極）。導線41〇例如為銅 (Cu)、銀（Ag)或金（An)等金屬線。封裝層43〇配置在陰 極組件與陽極之間。 回溯第1圖，保護套件還包括直流（DC)/DC轉換器 130 ’其配置於蓋體12〇的一側且電性連接太陽能電池模 組160-1和160-2»DC/DC轉換器13〇將太陽能電池模組 160-卜160-2產生的電能轉換成預定電壓。在一實例中， DC/DC轉換器130為升壓器。在另一實例中，dc/Dc轉 換器130内設至少一嵌入式電感。在又一實例中，Dc/Dc 轉換器130埋設在蓋體120内。連接器140配置在主體 110的一側且電性連接DC/DC轉換器130。當可攜式電 子裝置（未繪示）放在主體110的容納空間U5内並耦接連 接器140時’太陽能電池模組丄⑼]及/或i6〇_2將可透 過DC/DC轉換器130和連接器140直接對可攜式電子裝 置進行充電。 由於上述保護套件的蓋體第一表面19〇(正面）和第二 表面200(背面）均可接受入射光使得太陽能電池模組發 電’甚至可使得同一太陽能電池模組發電，因此在打開 或蓋闔保護套件時，皆可持續進行充電動作。 參照第3圖’其繪示保護套件之另一實施例。第3圖 201205238 保護套件的構造大致與第丨圖保護套件相同，除了蓋體 120設計成為中空部125的部份僅設置一個太陽能電池 模組160,蓋體丨20闔上的外觀類似第2圖。在此實施 例中，太陽能電池模組160為染料敏化太陽能電池模 組，其雙面皆可吸光，故打開或蓋闔保護套件時，太陽 能電池模組160均可發電而對電子裝置進行充電。在一 實例中，太陽能電池模組1 60由至少一個染料敏化太陽 能電池組成，其構造和設計類似前述太陽能電池模組 160-1、160-2，故於此不再贅述。在另一實例中，染料 敏化太陽能電池由第一電極基板17〇與第二電極基板 180組成，其中第一電極基板可接收從蓋體之第一表面 190(如蓋體表面）進入的入射光，第二電極基板可接收從 蓋體之第二表面200(如蓋體背面）進入的入射光。染料敏 化太％ flb電池模組利用從第一表面190進入之入射光產 生的光電轉換效率例如為利用從第二表面2〇〇進入之入 射光的70%-130%。 保護套件還配設DC/DC轉換器130和連接器14〇，使 得太陽能電池模組1 60可直接對電子裝置進行充電。 由於一般染料敏化太陽能電池是靠光敏染料將光能轉 換成電能’其不侷限於太陽光、而是包括室内燈源之任 何光源都能產生作用，加上其不受照射角度影響，因此 更適合做為電子裝置的充電應用。 在此所述之保護套件具有可雙面照光發電的太陽能電 池模組，或者保護套件的蓋體正面和背面分別設有太陽f SJ 6 201205238 Between electrodes 340. The at least one wire 410 is disposed on the conductive layer 22〇 and electrically connected to the at least one opposite electrode 240 to form the first electrode substrate 17〇 (cathode), and the other wire 41 0 is disposed on the conductive layer 320 and electrically connected to the at least one light. The electrode 34 is formed to constitute a second electrode substrate 18 (anode). The wire 41 is, for example, a metal wire such as copper (Cu), silver (Ag) or gold (An). The encapsulation layer 43 is disposed between the cathode assembly and the anode. Referring back to FIG. 1, the protection kit further includes a direct current (DC)/DC converter 130' disposed on one side of the cover 12 且 and electrically connected to the solar battery modules 160-1 and 160-2 » DC/DC converter 13〇 Converts the electric energy generated by the solar cell module 160-Bu 160-2 into a predetermined voltage. In an example, DC/DC converter 130 is a booster. In another example, at least one embedded inductor is provided in the dc/Dc converter 130. In yet another example, the Dc/Dc converter 130 is embedded within the cover 120. The connector 140 is disposed at one side of the body 110 and electrically connected to the DC/DC converter 130. When the portable electronic device (not shown) is placed in the receiving space U5 of the main body 110 and coupled to the connector 140, the 'solar battery module 丄(9)] and/or i6〇_2 will be permeable to the DC/DC converter. The 130 and the connector 140 directly charge the portable electronic device. Since the first surface 19 〇 (front side) and the second surface 200 (back side) of the cover of the above protective cover can receive incident light so that the solar cell module generates power, the same solar battery module can even generate electricity, so that the cover or the cover is opened or covered. When the protection kit is used, the charging operation can be continued. Referring to Figure 3, another embodiment of a protective kit is illustrated. Figure 3 201205238 The structure of the protection kit is substantially the same as that of the first protection package. Except that the cover 120 is designed as a part of the hollow portion 125, only one solar cell module 160 is provided, and the appearance of the cover body 20 is similar to that of the second figure. . In this embodiment, the solar cell module 160 is a dye-sensitized solar cell module, and both sides thereof can absorb light, so when the cover or the protection kit is opened or closed, the solar cell module 160 can generate electricity to charge the electronic device. . In one example, the solar cell module 160 is composed of at least one dye-sensitized solar cell, and is constructed and designed similarly to the solar cell modules 160-1, 160-2 described above, and thus will not be described again. In another example, the dye-sensitized solar cell is composed of a first electrode substrate 17A and a second electrode substrate 180, wherein the first electrode substrate can receive an incident from the first surface 190 of the cover (such as the surface of the cover) Light, the second electrode substrate can receive incident light entering from the second surface 200 of the cover, such as the back of the cover. The dye sensitization too% flb battery module utilizes photoelectric conversion efficiency generated by incident light entering from the first surface 190, for example, by 70% to 130% of the incident light entering from the second surface 2〇〇. The protection kit is also provided with a DC/DC converter 130 and a connector 14A so that the solar module 160 can directly charge the electronic device. Since a typical dye-sensitized solar cell converts light energy into electrical energy by a photosensitive dye, it is not limited to sunlight, but any light source including an indoor light source can function, and it is not affected by the angle of illumination, and thus Suitable for charging applications of electronic devices. The protection kit described herein has a solar battery module that can generate electricity by double-sided illumination, or a solar panel on the front and back of the cover of the protection kit.
[SJ 8 201205238 能電池模組，另並配合使用dc/dc轉換器，是以保護套 件無論是在打開或蓋闔狀態，均可產生電能供電子裝置 使用。 應注意為便於說明’圖式並未按比例繪製，熟諳此技 藝者當可依需求更改各元件的配設位置、相對關係和尺 寸，本發明不以此為限。 雖然本發明已以較佳實施例揭露如上，然其並非用以 限定本發明，任何熟習此技藝者，在不脫離本發明之精 神和範圍内，當可作各種之更動與潤飾，因此本發明之 保護範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 第1圖為根據本發明-實施例之保護套件的示意圖； 第2圖為第1圖所示之保護套件蓋闔時的示意圖； 第3圖為根據本發明另一實施例之保護套件的示意 圖；以及 ~ 第4圖為根據本發明一實施例，由並聯染料敏化太陽 能電池組成之電池模組的截面圖。 【主要元件符號說明】 110 主體 115 空間 120 μα 盖體 125 中空 部 130 DC/DC轉換器 140 連接 器 201205238 160、 160-1 、 160-2 太陽能電池模組 170 第一電極基板 180 第二電極基板 190 第一表面 200 第二表面 210 第一基板 220 導電層 240 對電極 310 第二基板 320 導電層 340 光電極 410 導線 430 封裝層 450 電解質層 R 柩軸[SJ 8 201205238 The battery module can be used together with the dc/dc converter to generate power for the electronic device whether it is in the open or closed state. It should be noted that the drawings are not drawn to scale, and the skilled artisan can change the arrangement position, relative relationship and size of each component as needed, and the invention is not limited thereto. While the present invention has been described above by way of a preferred embodiment, it is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of a protection kit according to an embodiment of the present invention; FIG. 2 is a schematic view of the protection kit shown in FIG. 1; FIG. 3 is another embodiment of the present invention. A schematic diagram of a protective kit of the example; and FIG. 4 is a cross-sectional view of a battery module composed of parallel dye-sensitized solar cells, in accordance with an embodiment of the present invention. [Description of main components] 110 Main body 115 Space 120 μα Cover 125 Hollow 130 DC/DC converter 140 Connector 201205238 160, 160-1, 160-2 Solar battery module 170 First electrode substrate 180 Second electrode substrate 190 first surface 200 second surface 210 first substrate 220 conductive layer 240 counter electrode 310 second substrate 320 conductive layer 340 photo electrode 410 wire 430 encapsulation layer 450 electrolyte layer R 柩 axis
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