201140904 六、發明說明： 【發明所屬之技術領域】 本發明目的係在於透過用夾制& ^ ^ 幻用來製作鋰離子電池外蓋之社 構和處理方法的革新以製作高 盍之、，〇 用於制备 了久性鋰離子電池。所揭示 用於I作該外蓋之新型、结構和# 本人 ^ 友你延長合成電池的使用 -奸叩。本發明係提供用於諸如家 用 動車鲕廡田E 豕用敗*罝儲存應用或混和電 助早輛應用之長期應用的一電池。 【先前技術】 =密式（H_etie)密封係經常決定__子電池之使 的-關鍵問，，因為此電池的—高電墨會在假如水 等二，氣分子存在於電解質時提供水分解或氧氣降低。此 荨問仙經常引起不當的電池密封。傳統上，鐘離子電池 :尺寸和容量上係小型的。採取1865〇型圓柱型電池作為 -實例，此電池尺寸在直徑上係18公厘而高度上係“公 厘。此電池容量係依據正在使用之陰極材料的類型而約^ 2.8Ah到l.4Ah的範圍中。審於外蓋建構所利用的空間，於 該電池之集流柱處的金屬至聚合物介面通常係微小（僅透 ^形狀如-0型環之—絕緣層的支持），且此介面係因而 無法提供一長擴散路徑予穿透該金屬至聚合物介面的氧 氣、水氣分子或其它氣體或液體。因為該金屬至聚合物介 面的加速退解，所以前述情況一旦在對該等電池施加高溫 循環條件時（例如：諸如持續高功率運作的條件）係變為 更嚴重。相同問題係同樣發生在諸如稜柱型電池或甚=是 201140904 鋰聚合物型電池之其它類型的鋰離子電池。 【發明内容】 一種用於一鋰離子電池容器之外蓋組件係具有—用於 密封一電池容器之一頂部開口的外蓋，該外蓋係定義對於 集流柱之一個或更多開口。該外蓋組件係進一步包含：一 集流柱’該集流柱係延伸穿過各個開口且在該集流桎和該 外蓋之間係具有一間隙；一 柱、經佈置為相對且偏離自 集流柱向外徑向延伸超過開 圍繞各個集流柱、經佈置為 表面、和從該集流柱向外徑 及一第一聚合物主體，用於 體係連續及延伸以填入該外 和該底部凸緣中任一者之間 聚合物主體係被熔接至所接 和底部凸緣。 頂部凸緣，其係圍繞各個集流 該外蓋的一頂部表面、和從該 口的邊緣；一底部凸緣，其係 相對且偏離自該外蓋的一底部 向延伸超過該開口的邊緣；以 各個集流柱。該第一聚合物主 蓋、該等集流柱、該頂部凸緣 所形成的所有間隙，且該第一 觸的外蓋、集流柱、頂部凸緣 个赞明目的 爲了改善上述問題，所揭 結構係具有用於製造此外蓋的池容器外蓋之一新顆 器外蓋中所實施之適當結構和方法方法。错著在該電池容 所具有之延長使用壽命（目標為：久性的鐘離子電池 於在諸如電動車麵或混合電動上係能有所預期。對 和持續高功率能力）之大型能量（=要長時間使用壽命 子糸統及/或高功率應用 201140904 中所利用之大電池（超過1 〇 Ah的容量）來說，特別是於該 等集流枉處之良好密封係重要的。 【實施方式】 所應用在外蓋結構之關鍵概念係如下述： a. 增加氣體及/或液體進入或離開電池的一擴散路徑。 b. 加強該電池之集流柱處的一金屬至聚合物介面。 實例I ··本發明之基本形式 圖1 ( a )係顯示對於一電池容器之一頂部開口的一外 蓋1的一俯視圖。爲清楚敘述本發明之方法，該外蓋之逐 步組裝係以圖1 ( b )到圖1 ( f)之側視圖的形式來顯示。 圖1 ( b )係顯示用以製造該外蓋組件的第一步驟。— 第一聚合物主體2係透過一射出成型處理而被佈置在容器 外蓋1的一頂部表面和一底部表面。延伸穿過該外蓋丨中 之開口 4的集流柱3係透過該射出成型處理將聚合物填入 该外蓋和該等集流柱之間的一間隙而予以穩固。 圖1 ( c )係顯示傳導柱上所佈置之—頂部凸緣5和一 底部凸緣6。該等凸緣係被迫向彼此，而射出成型聚合物主 體係被夾層於兩者之間。該頂部凸緣和該底部凸緣係被熔 接至該射出成型聚合物。此步驟極為重要且以接近聚合物 之軟化點的-溫度來執行為佳。將該等凸緣係迫向彼此之 優勢（較佳為使用沖廢冑、使用一螺、絲機構將該頂部凸緣 和該底部凸緣一起栓緊在一螺栓上或類似物）係如下概述： 1·痛保該射出成型的聚合物及該頂部凸緣和該底部凸 6 201140904 緣之間的接觸與熔接。 2.確保該射出忐刑认奴人 成i的聚合物及該等集流枉之間的接觸 :::、丨糸非嗥重要，因為時常經歷高功率運作之電池 早凡可能導致該聚合物和該集流柱之間的退㈣f 圖1 U)所顯示-分離絕緣層7係至少被佈置在各個 底部凸緣之底部表而w " 上，以用於隔離該底部凸緣和該電池 的電極，同時亦阻隔氣體或液體在該等集流柱和該射 出成型的聚合物之間的介面處發生的可线漏8。 ▲圖1 U)係顯示所被銲接9 (例如：雷料接方法 及集机柱的頂部凸緣，以避免氣體或液體分子從該頂部凸 緣和該集流柱之間的介面處穿透之任何可能性。 最終如圖ICf)^ 所不，該頂部凸緣處之區域係被依第 ==體1〇所填入以確保在該頂部凸緣的邊緣和該射 纽的第一聚合物主體之間的介面處不會發生鴻漏。 =製作本發明實針所示外蓋上所涉及的關鍵因素和 方法係如下概述： a·射出成型以用於製作含有該等集流柱的外蓋單體。 b.藉將頂部凸緣和底部凸緣追向彼此塵縮外蓋單體。° C.將隔離材料塗佈在各個底部凸緣的底部表面上。 d·在該等頂部凸緣和該等集流柱之間進行雷射鲜接。 e.將—第二聚合物填入第一射出成型的第一 體來阻隔該頂部凸緣的邊緣和該第__ 能穿透。 刃主體之間的可 在製作前述外蓋上所涉及的關鍵因素和方法對解決如 201140904 下列表之問題係不可或缺·· 1.該射出成型處理係可仵 一外蓋單_ 本發明尹為優選，因為 之間第一聚合物主體和該容器外: 高壓處理，所以該容器：？乍。因為該射出成型處理為- 展示具有較佳I ^《頂部切佈置的聚合物係可 區分自將體取向之特徵「紋理」，其中係能 ㈣田 積在該容器外蓋之頂部上料它方式。 的射出成型處理和「外蓋/聚合物單體夕： 確保該介面整合性。一… 物早體」之一結構係 2 ^ 發明具新穎性係不可或缺。 的介面。Μ流柱和該射出成型的第-聚合物主體之間 ；1 。此係藉由在將該頂部凸緣和1广却 聚合物材料迫使兩者—起&卩凸緣熔接至該 所炫接至該射出成型的第一聚人亦傾向藉由 凸緣來增加擴散路控。沒有使 的頂部凸緣和底部 的悴、π /又有使用δ玄頂部凸緣和該底部凸緣 二，沒漏係能由於一較短擴散路經而更容易發生在 ㈣―射出成型的第—聚合物主體之間的介面處。 …所涉及用於阻隔在使用該頂部凸緣和該底部凸緣時 入…的任何新介面之其它步驟係不可或缺。該步驟係包 :耸ίί部凸緣之底部表面上所塗佈的絕緣㈣（將透過 漏的：机柱之”面而源自進入或離開該電池之可能雙向洩 :的穿透予以延遲’如圖i⑷所指示）；該等頂部凸緣 集流柱之間的雷射録接’（避免茂漏穿過該頂部凸 、’和该集流枚的介面’如圖1(e)所指示）；以及超過一 曰的聚合物塗佈以保護該頂部凸緣之邊緣（避免茂漏穿過 8 201140904 該頂部凸緣之邊緣處介面，如圖丨（ 該射出成型之聚合物声用 θ不 。 限於聚乙烯（ΡΕ)、聚 、擇係^^一不 聚對苯4酸乙二醋（ΡΕ= )、聚氣酉旨（叫、尼龍、 (娜）、氟化乙㈣丁二稀笨乙稀共聚物 (w^、聚㈣氰/i (FEP)、聚酿亞胺201140904 VI. Description of the Invention: [Technical Field of the Invention] The object of the present invention is to make a sorghum by using an innovation of a fabric and a processing method for fabricating a lithium ion battery cover using a sandwich & 〇 is used to prepare a long-lasting lithium ion battery. Revealed for the use of I as the cover of the new type, structure and # yourself ^ friends you extend the use of synthetic batteries - traitors. SUMMARY OF THE INVENTION The present invention provides a battery for long-term applications such as the use of home electric vehicles, storage applications, or hybrid electric applications. [Prior Art] = H_etie seal system often determines the key to the __ sub-cell, because the high-electro-ink of this battery will provide water decomposition when the gas molecules are present in the electrolyte. Or oxygen is reduced. This question often causes improper battery seals. Traditionally, the ion battery has been small in size and capacity. A 1865-inch cylindrical battery is used as an example. The size of the battery is 18 mm in diameter and "mm" in height. This battery capacity is about 2.8 Ah to 1.4 Ah depending on the type of cathode material being used. In the scope of the outer cover construction, the metal-to-polymer interface at the collector of the battery is usually small (only supported by a shape such as a -0-ring-insulation layer), and This interface thus does not provide a long diffusion path to penetrate the metal to the polymer interface of oxygen, water molecules or other gases or liquids. Because of the accelerated decompression of the metal to polymer interface, the foregoing is once When the battery is subjected to high temperature cycling conditions (for example, conditions such as continuous high power operation), the same problem occurs in other types of lithium ions such as prismatic batteries or even 201140904 lithium polymer type batteries. [Explanation] A cover assembly for a lithium ion battery container has an outer cover for sealing a top opening of a battery container, the outer cover is defined For one or more openings of the current collecting column, the outer cover assembly further comprises: a collecting column that extends through each opening and has a gap between the collecting raft and the outer cover a column, arranged to be opposite and offset from the current collecting column outwardly radially beyond the opening around each of the collecting columns, disposed as a surface, and from the collecting column to the outer diameter and a first polymer body, The polymer main system is spliced to the attached and bottom flanges between the outer and the bottom flanges. The top flange is wrapped around each of the outer covers. a top surface, and an edge from the port; a bottom flange that is opposite and offset from a bottom portion of the outer cover extending beyond the edge of the opening; for each current collecting column. The first polymer main cover, the first polymer The current collecting column, all the gaps formed by the top flange, and the outer cover, the collecting column and the top flange of the first contact are for the purpose of improving the above problem, and the disclosed structure has a cover for manufacturing One of the outer lids of the pool container Appropriate structure and methodologies implemented. Misplaced in the battery capacity has an extended service life (target: long-lasting clock ion battery can be expected on such as electric vehicle surface or hybrid electric system. Large power of high power capability (= large battery (capacity of more than 1 〇Ah) used in long-term service sub-systems and/or high-power applications 201140904, especially at these tributaries A good seal is important. [Embodiment] The key concepts applied to the outer cover structure are as follows: a. Increasing the diffusion path of gas and/or liquid into or out of the battery b. Strengthening the collector of the battery A metal to polymer interface. Example I · Basic Form of the Invention Figure 1 (a) shows a top view of an outer cover 1 open to the top of a battery container. To clearly illustrate the method of the present invention, the stepwise assembly of the outer cover is shown in the form of a side view of Figures 1(b) through 1(f). Figure 1 (b) shows the first step for making the outer cover assembly. - The first polymer body 2 is disposed on a top surface and a bottom surface of the container cover 1 through an injection molding process. The header 3 extending through the opening 4 in the outer lid is stabilized by the injection molding process by filling the polymer with a gap between the outer lid and the headers. Figure 1 (c) shows the top flange 5 and a bottom flange 6 disposed on the conductive column. The flanges are forced toward each other and the injection molding polymer master system is sandwiched between the two. The top flange and the bottom flange are welded to the injection molded polymer. This step is extremely important and is preferably performed at a temperature close to the softening point of the polymer. The advantages of the flanges being forced toward each other (preferably using a smashing smash, using a screw, a wire mechanism to bolt the top flange and the bottom flange together on a bolt or the like) are summarized as follows : 1. The contact between the injection molded polymer and the edge of the top flange and the bottom projection 6 201140904 is welded and welded. 2. Ensuring that the contact between the polymer and the collectors of the slain slain i:::, 丨糸 is not important, as batteries that are often subjected to high power operation may cause the polymer With the retreat (four) f between the current collecting columns, Figure 1 U) shows that the separating insulating layer 7 is at least arranged on the bottom table of each bottom flange and w " for isolating the bottom flange and the battery The electrodes also block the line leakage 8 that occurs at the interface between the current collecting column and the injection molded polymer. ▲ Figure 1 U) shows the welded 9 (for example: the lightning connection method and the top flange of the collecting column to prevent gas or liquid molecules from penetrating from the interface between the top flange and the collecting column) Any possibility. Finally, as shown in Figure ICf), the area at the top flange is filled with the == body 1〇 to ensure the first polymerization at the edge of the top flange and the injector. There is no leakage at the interface between the subjects. = The key factors and methods involved in making the outer cover shown in the actual needle of the present invention are summarized as follows: a. Injection molding for making the outer cover monomer containing the current collecting columns. b. By chasing the top and bottom flanges toward each other, the outer cover of the dust cover. ° C. Apply the insulation material to the bottom surface of each bottom flange. d. Laser splicing between the top flanges and the collectors. e. filling the second polymer into the first injection molded first body to block the edge of the top flange and the first permeable. The key factors and methods involved in making the aforementioned outer cover between the blade bodies are indispensable for solving the problems listed in the following list of 201140904. 1. The injection molding process can be used to cover a cover sheet. Preferably, because the first polymer body and the outside of the container: high pressure treatment, so the container:? first. Because the injection molding process is - showing that the polymer system having the preferred I ^ "top cut arrangement can distinguish the feature "texture" from the body orientation, wherein the system can (4) the field product is fed on the top of the container cover. . Injection molding process and "outer cover / polymer monomer evening: ensure the integration of the interface. One... early body" one structural system 2 ^ Invented novelty is indispensable. Interface. Between the turbulent column and the injection-molded first polymer body; This is also caused by the fact that the top flange and the 1 wide polymer material are forced to weld both the flange and the flange to the first gather of the injection molding. Diffusion road control. Without the top flange and the bottom of the 悴, π / and the use of the δ 玄 top flange and the bottom flange two, no leakage can be more likely to occur due to a shorter diffusion path in (four) - injection molding - at the interface between the polymer bodies. ...the other steps involved in blocking any new interface when using the top flange and the bottom flange are indispensable. This step is to wrap the insulation (4) coated on the bottom surface of the flange (which will pass through the leaked: the "column" surface and the possible two-way leakage from the entering or leaving the battery: the penetration is delayed" As indicated in Figure i(4); the laser recording between the top flange collectors' (to avoid leakage through the top convex, 'and the interface of the current collector'" as indicated in Figure 1(e) And more than one layer of polymer coating to protect the edge of the top flange (to avoid leakage through the interface of the edge of the top flange of 8 201140904, as shown in Figure 丨 (the polymer of the injection molding uses θ not Limited to polyethylene (ΡΕ), poly, select system ^ ^ a non-p-phenylene 4-acid vinegar (ΡΕ = ), poly gas 酉 (called, nylon, (na), fluorinated B (four) diced Ethylene copolymer (w^, poly(tetra)cyano/i (FEP), poly-imine
ResuO mi 州_〇、環氧樹脂（邱心ResuO mi _ 〇, epoxy resin (Qiu Xin
Res】n)或則述列舉材料的一組 物主體在該頂部凸緣和該底部凸緣：=的第：聚合 超過用以寄宿該隼法如' 、區域較佳係延伸 聚合物主體到所寄宿該集流纽㈣出成型的第一 佳係超過0_5公分。亦即、，口的邊緣之間的距離較 的邊緣至少〇·二:該聚合物係應該延伸超過該開口 為可接受則促使整:外、::一聚全合::重量:整體電池設計 物層之重量對==係… 性的較厚聚合物層又汁為可接受則促使具有較佳整合 物凸緣頂二凸:所利用的材料選擇係包含-金屬或-聚人 假如使用金屬，則扃吁π * 聚合 的-密封（例如：雷封;凸緣和該集流杜之間 覃。物頂部凸緣而非—金屬頂相 κ假如使用 和該集流杈< η ^ 。卩凸緣，則在該頂部凸％ 緣之尺十ΐ的…炫接係應該予以進行。，τ 尺寸較佳係大於用以寄宿坊隹ώ 4頂部凸 過該開Ο少鱼 伤該集k柱之開口。一 从 之邊緣0.5公分或更多 延伸超 °Λ底部凸緣所利用的材料胃 材抖選擇減該為擁有Μ" 201140904 之金屬，因為該底部凸緣被用連接至多個電極或電極小側 部。該底部凸緣之尺寸較佳係大於用以寄宿該集流柱之開 口。一延伸超過該開口之邊緣〇.5公分或更多係更好。 用於塗佈該底部凸緣之表面的材料選擇係能與該射出 成型的聚合物層所使用之材料相同或有所不同。該等選擇 係包含聚乙烯 '聚丙烯、聚氨酯、尼龍、 二，、丙稀睛丁二稀笨乙稀共聚物、氣化乙稀：稀:曱聚:乙 聚醯亞胺、聚丙烯氰、環氧樹脂或前述列舉材料的一組合。 該底部&緣中被連接至該等電極的一部分係不應被塗佈。 用於塗佈該射出成型的第一聚合物主體之頂部的材料 選擇係能與該射出成型的第一$合物主體相同或不同。再 次:該等選擇係包含聚乙稀、聚丙稀、聚氨醋、尼龍、聚 對笨二曱酸乙二酷、丙稀睛丁二稀苯乙烤共聚物、說化乙 烯丙婦共聚物、聚酿亞胺、聚丙稀氛、環氧樹脂或前述列 舉材料的一組合。 在本發明實例中，假如該射出_聚合物在介接該頂 部凸緣和該底部凸緣和該等集流柱以及在該外蓋表面上並 未展不充足炼接’則底層u係應該被用來溶接在該頂部巧 緣/該射出成型的第-聚合物主體、該底部凸緣/該射出成型 的第—聚合物主體、該集流柱/該射出成型的第—聚合物主 體、和該外蓋表面/該射出成型的第一聚合物主體之間的介 :(如圖1 ( g)所指示）。所用於底層之材料係苯乙烯 型、黏著劑、或對該金屬表面和該射出成 〜擁有出色附著性之任何其它材料。此外，該底層 10 201140904 係能為要被炫接之金屬表面上的—陽極極化層，其係增加 該金屬表面的粗操性以增強該金屬對該聚合物層的附著 性。-陽極極化金屬表面和利用一聚合物底層之一組合係 亦被涵蓋在本發明中。 實例II :本發明之一替代形式的組件 參考圖2 ( a)到2 ( c )，一集流柱、一頂部凸緣、— 底部凸緣和-外蓋係經由機械組裝或銲接而被先行組裝。 在如圖2(a)所示組態中，多個集流柱、頂部凸緣、和底 部凸緣係使用-鑄模而相對—外蓋進行組裝，1聚合物射 出成型係被進行在整個組件上。生成的外蓋係變為如圖2 jb)所示的H該等頂部凸緣接著係被密封至該等集 流柱’隨後如® 2 (c)所示在該射出成型的第一聚合物： 體之頂部上填入一第二聚合物主體。因為在該射出成型處 :期間使用高Μ，所以類似上述第一製造方法中將該頂部 =和該底Μ緣迫向彼此之—條件絲經由本發明的射 成5L處理來達成。應該要注意：在該頂部凸緣和該集产 主之間藉由例如雷射銲接的密封係能在該射出成型處理： 進仃。能藉由組裝兩個部# (其中前述組合的部件中一 件I集流柱/頂部凸緣的組件或-集流柱/底部凸緣的組 一」製作該集流柱、頂部凸緣、和底部凸緣的組件係進 壓今:仃其中兩個部件係經由加王_金屬塊、鑄造或擠 坠金屬而分別製成。 忒谷器外蓋係能以任何形狀來設計（例如：圓形、橢 "矩形等），而邊緣係被塑形為平坦除外的形狀（請 201140904 t見圖到3(e)之所有圖式）。在圖，"⑴ 中，所有谷益外蓋之邊緣係被 m ,,, m ^ ^ ^ 有唇狀」類型的結 構以用於進一步增加擴散長度和聚合物/外蓋介面整合性。 在將該外蓋銲接在-電池成品的電池容器電 解質係能透過注入埠12子以埴Λ 立 4…η、 最終密封係能藉由將 金屬球1 3或一小型蓋1 4錯接太方、+ —丄 蛊4銲接在该注入埠12的頂部上來 元成，如圖2(d)所示。 類似實例1中所要使用之底層材料，在本發明實例中， 請射出成型聚合物對該頂部凸緣和該底部凸緣及在該 外蓋表面並未屐示足夠的介面特性（附著或炫接），則-底層材料係係能被先行施用在凸緣表面的表面上。在該頂 部凸緣/該射出成型聚合物、該底部凸緣/該射出成型聚合 ^㈣g/該㈣0聚合物、和該外蓋表面/該射出成 型聚合物之間的介面處（如圖i ) 、g;所払不）在後續的射 出成型處理期間係發生炼接。所用於底層之材料係苯乙稀 丁一烯橡膠（SBR)、黏著劑、或對該金屬表面和該射出成 里聚合物擁有出色附著性之任何其它材料。此外，該底層 係能為要被熔接之金屬表面上的一陽極極化層，其係增加 該金屬表面的粗操性以增強該金屬對該聚合物層的J著 性。-陽極極化金屬表面和利用一聚合物底層之_組合係 亦被涵蓋在本發明中。 實例III·本發明之一延伸形式 -電池外蓋係可不僅含有正性集流柱和負性集流柱之 開口，還可含有用於電解質填入或安全進出的額外開口。 12 201140904 超過一個實施例係給定在本文中以供敘述用製作一電池外 蓋之設計和方法，其中係含有多個集流柱、一電解質填入 開口、及一安全通口（vent)。 為清楚起見，實例II所描述之方法係利用在本發明實 例中:圖3 ( a )所顯示—外蓋係在用於電解質填入之開口 β圍έ有缺口 15。具有一減少金屬厚度之缺口係被設計 成安王通口，其在内部電池壓力不正常增長時係向外斷 穸 集/;IL柱、一頂部凸緣和一底部凸緣係經由機械組裝 ^銲接而被先行組裝。在如圖3 (a)所示組態中，多個集 流柱、頂部凸緣、和底部凸緣係使用—鑄模而相對該外蓋 進行、、且裝，且接著射出成型係被進行在整個組件上。生成 的外蓋係變為如圖3 (b)所示的—單體18。在該射出成型 處理期間’藉由調整該鑄模的形狀，所射出的聚合物係能 被選擇以完全覆蓋該等缺口、部分覆蓋（以較淺深度）、 :’又有覆蓋該等缺口。在圖3 ( b )中，該射出聚合物係部 ^覆蓋該等缺口。部分覆蓋係較佳，原、因在於該等缺口由 聚合物層所保護、但是該聚合物層並未顯著地阻礙其正常 實仃。忒頂部凸緣接著係被密封至該集流柱，隨後如圖3 (c)所示在該射出成型的第一聚合物主體之頂部上提供一 :二：合物主體。應該要注意：該第二聚合物主體係能完 :覆蓋缺口區域、部分覆蓋（以-較淺深度）、或沒有覆 :-亥等缺口。在圖3 ( c ) t ’所示該第二聚合物主體】〇係 久有覆蓋該缺口（安全通口）區域。在目前實例中，該外 蓋結構係纟必被限制在圖$中所示該安全通口《該電解質 13 201140904 注入埠之配置和設計。額外實例係被給定在本文中以供該 安全通口和該電解質注入埠之配置和設計。例如：如圖3 (d )所示，一安全通口係能被設計成結合注入埠；或如圖 3( e )所示，該安全通口係可作為所安裝在該電池外蓋之一 分離位置1 7處的一獨立設計機構。 在上述給定的所有實例中，對一擴散路徑之一增加距 離和對該電池外蓋上存在之任何開口來增強該金屬對聚合 物介面係形成本發明基礎《集流柱、電解質注入埠和安全 通口之位置和形狀設計並未被限制成本發明實例中的給定 實例。聚合物層之結構和用於建構一電池外蓋之方法係2 用所要存在該電池外蓋之頂部上㈣流柱、電解 和安全通口中之任何組合和數量。本發明係亦施用在其中 容器和外蓋代替集流柱且僅需要—個m的配置。 L圓式間皁說明】 圖1 (a)係本發明中-容器外蓋的-頂部視圖； …=(b)到1 (g)係本發明中一外蓋叙件的側視圖， “不-第-製造方法的循序漸近步驟； 圖2 ( a)到2 ( c )係本發明令一 苴中伤骷_尬 ηΎ外盍組件的側視圖， ，〜、不一第二製造方法的循序漸近步驟； 圖2 ( d )係本發明中兮·冰絮 顯示電解質、主入π "卜盍，!件的-側視圖，其中係 丁电解資主入開口之各種密封的； 圖3 ( a )到3 ( d )係本發明中哕外 其中係顯示各種安全通口… 卜盍組件的側視圖， 女王通口和電解質注入孔洞及其密封方 201140904 法；以及 圖3 ( e )係本發明中該外蓋組件的側視圖，其中係顯 示一安全通口和一電解質注入孔洞之位置的另一變化。 【主要元件符號說明】 1 容器外蓋 2 第一聚合物主體 3 集流柱 4 集流柱之開口 5 頂部凸緣 6 底部凸緣 7 分離絕緣層 8 洩漏的可能路線 9 銲接埠 10 第二聚合物主體 11 底層 12 注入埠 13 金屬球 14 小型蓋 15 缺口 16 成型聚合物覆蓋的缺口 17 安全通口 18 單體 15Res] n) or a group of materials of the enumerated material at the top flange and the bottom flange: = the first: polymerization exceeds the host method used to board the 如 method, such as The first best line of boarding the collection (4) is more than 0_5 cm. That is, the distance between the edges of the mouth is at least 〇·2: the polymer system should extend beyond the opening to be acceptable to promote the whole: outer::: one-to-one:: weight: overall battery design The weight of the layer is ==. The thicker polymer layer of the sap is acceptable to promote the better integrator flange top bismuth: the material selection used includes -metal or -poly if metal is used , 扃 π 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合卩Flange, then the top of the convex edge of the edge of the ΐ ... ... 炫 炫 炫 炫 炫 炫 炫 炫 炫 炫 炫 炫 炫 , τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ The opening of the column. A material that extends from the edge of 0.5 cm or more. The material used for the bottom flange is selected as the metal that has the Μ" 201140904 because the bottom flange is used to connect to multiple electrodes or a small side of the electrode. The size of the bottom flange is preferably larger than that used to host the current collecting column. Preferably, the length of the opening is more than 5 cm or more. The material used to coat the surface of the bottom flange is selected to be the same as the material used for the injection molded polymer layer. The choices include polyethylene 'polypropylene, polyurethane, nylon, II, propylene dibutyl ethene copolymer, gasified ethylene: dilute: 曱 poly: ethoxylated imine, poly A combination of acrylonitrile, epoxy resin or the above listed materials. A portion of the bottom & edge to which the electrodes are attached should not be coated. For coating the top of the first polymer body of the injection molding The material selection can be the same as or different from the first molded body of the injection molding. Again: the selections include polyethylene, polypropylene, polyurethane, nylon, poly-p-benzoic acid, A combination of a propylene dibutyl benzene bromide copolymer, a vinylidene copolymer, a polystyrene, a polypropylene, an epoxy resin or the above listed materials. In the present example, if the injection _ a polymer interfacing the top flange and the bottom flange and The current collecting columns and the surface of the outer cover are not sufficiently spliced, and the bottom layer u should be used to melt the top polymer edge/the injection molded first polymer body, the bottom flange/ The injection molding of the first polymer body, the current collecting column / the injection molded first polymer body, and the outer cover surface / the injection molded first polymer body: (see Figure 1 ( g) as indicated. The material used for the bottom layer is styrene type, adhesive, or any other material that has excellent adhesion to the metal surface and the shot. In addition, the bottom layer 10 201140904 can be dazzled. An anodic polarization layer on the metal surface that increases the coarseness of the metal surface to enhance adhesion of the metal to the polymer layer. - Anodically polarized metal surface and combined with one of the polymer underlayers The system is also encompassed by the present invention. EXAMPLE II: Components of an Alternative Form of the Invention Referring to Figures 2(a) through 2(c), a header, a top flange, a bottom flange, and an outer cover are advanced via mechanical assembly or welding. Assembly. In the configuration shown in Fig. 2(a), a plurality of current collecting columns, a top flange, and a bottom flange are assembled using a mold-relative-outer cover, and a polymer injection molding system is carried out throughout the assembly. on. The resulting outer cover is changed to the H shown in Figure 2 jb). The top flanges are then sealed to the headers. The subsequent first injection of the first polymer as shown in Figure 2 (c) : The top of the body is filled with a second polymer body. Since the sorghum is used during the injection molding: the conditional filaments are subjected to the 5L treatment of the present invention in the first manufacturing method as described above in which the top = and the bottom rim are forced toward each other. It should be noted that a seal system such as laser welding can be used between the top flange and the collector to perform the injection molding process: The collector column, the top flange, can be made by assembling two sections # (in which one of the aforementioned combined components is a collector/top flange assembly or a collector/bottom flange group 1) The components of the bottom flange are pressed into the pressure: two of the components are made separately by adding a metal block, casting or squeezing the metal. The outer cover of the sifter can be designed in any shape (for example: round Shape, ellipses, rectangles, etc., and the edges are shaped to be flat except for the shape (see 201140904 t see all the patterns in 3(e)). In the figure, "(1), all the valley cover The edge is made of m,, m ^ ^ ^ having a lip-like structure for further increasing the diffusion length and polymer/cover interface integration. Soldering the cover to the battery container electrolyte of the finished battery The system can be inserted into the crucible 12 to stand 4...n, and the final sealing system can be welded to the top of the injection crucible 12 by misaligning the metal ball 13 or a small cover 1 4 to the square. The upper layer is shown in Fig. 2(d). Similar to the underlying material to be used in the example 1, in the example of the present invention, The injection molding polymer does not exhibit sufficient interfacial properties (attachment or splicing) to the top flange and the bottom flange and the surface of the outer cover, and the underlying material system can be applied to the surface of the flange first. On the surface, at the interface between the top flange / the injection molded polymer, the bottom flange / the injection molding polymer (4) g / the (tetra) 0 polymer, and the outer cover surface / the injection molded polymer (eg Figure i), g; does not) refining occurs during the subsequent injection molding process. The material used for the underlayer is styrene butadiene rubber (SBR), an adhesive, or any other material having excellent adhesion to the metal surface and the polymerized polymer. In addition, the underlayer can be an anodic polarization layer on the surface of the metal to be fused, which increases the roughness of the metal surface to enhance the metal's J properties to the polymer layer. The combination of an anodically polarized metal surface and a polymeric underlayer is also encompassed by the present invention. Example III. An extension of the invention - The battery cover may contain not only the openings of the positive and negative collector columns, but also additional openings for electrolyte filling or safe access. 12 201140904 More than one embodiment is provided herein for the design and method of making a battery cover, including a plurality of current collecting columns, an electrolyte filling opening, and a safety vent. For the sake of clarity, the method described in Example II is utilized in the practice of the present invention: Figure 3 (a) shows that the outer cover is notched 15 in the opening β for electrolyte filling. The gap having a reduced metal thickness is designed as an Anwang port, which is outwardly broken when the internal battery pressure is abnormally increased; the IL column, a top flange and a bottom flange are mechanically assembled. It was assembled first. In the configuration shown in FIG. 3(a), a plurality of current collecting columns, a top flange, and a bottom flange are made using a mold, and are mounted with respect to the outer cover, and then the injection molding system is carried out. On the entire component. The resulting outer cover is changed to a monomer 18 as shown in Fig. 3(b). By adjusting the shape of the mold during the injection molding process, the ejected polymer system can be selected to completely cover the indentations, partially cover (at a shallower depth), and to cover the indentations. In Fig. 3(b), the exiting polymer portion covers the gaps. Partial coverage is preferred, as the gap is protected by the polymer layer, but the polymer layer does not significantly impede its normal enthalpy. The top flange of the crucible is then sealed to the current collecting column, and then a second: compound body is provided on top of the injection molded first polymer body as shown in Figure 3 (c). It should be noted that the second polymer main system can be completed: covering the notched area, partially covering (with a shallow depth), or not covering the gap: The second polymer body shown in Fig. 3(c)t' has a region covering the gap (safety port) for a long time. In the present example, the outer cover structure must be limited to the configuration and design of the safety port "this electrolyte 13 201140904 injection" shown in Figure $. Additional examples are given herein for the configuration and design of the safety port and the electrolyte injection port. For example, as shown in FIG. 3(d), a safety port can be designed to be combined with the injection port; or as shown in FIG. 3(e), the safety port can be installed as one of the battery covers. Separate an independent design mechanism at position 17. In all of the examples given above, increasing the distance to one of the diffusion paths and any openings present on the outer cover of the battery to enhance the metal-on-polymer interface forms the basis of the present invention, "collector, electrolyte injection" The location and shape design of the safety port is not limited to the given example in the inventive example. The structure of the polymer layer and the method for constructing a battery cover 2 are any combination and number of (4) flow columns, electrolysis and safety ports on the top of the battery cover to be present. The present invention is also applied in a configuration in which the container and the outer cover replace the current collecting column and only require one m. L round soap description] Figure 1 (a) is a top view of the container cover of the present invention; ... = (b) to 1 (g) is a side view of a cover of the present invention, "No - a stepwise asymptotic step of the first manufacturing method; Fig. 2 (a) to 2 (c) are side views of the 苴 尬 尬 Ύ Ύ Ύ , , , , , , , , , , , , , , , 第二 第二 第二 第二Step 2; Figure 2 (d) shows the electrolyte in the present invention, the main π " 盍 盍 ! ! ! ! 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图 侧视图) to 3 (d) is a side view of the present invention showing various safety ports... a side view of the dip component, a queen port and an electrolyte injection hole and its sealing party 201140904 method; and FIG. 3(e) is the present invention A side view of the outer lid assembly showing another change in the position of a safety port and an electrolyte injection hole. [Main element symbol description] 1 container outer cover 2 first polymer body 3 collecting column 4 set Flow column opening 5 Top flange 6 Bottom flange 7 Separation insulation layer 8 Possible route for leakage 9 Weld 埠 10 Second polymer body 11 bottom layer 12 injection 埠 13 metal ball 14 small cover 15 notch 16 shaped polymer covered notch 17 safety port 18 monomer 15