TW201139461A - Cellulose acylate film, polarizing plate and liquid crystal display - Google Patents

Abstract

This invention provides a cellulose acylate film good in transparency, moisture permeability and optical property, and can improve durability of a polarizing plate at high temperature and high humidity when be combined with a polarizer. The cellulose acylate film is characterized by including a plurality of sugar ester compounds with different ester substitution degrees and cellulose acylate. Sugar constituting the sugar ester compound is disaccharide to tetrasaccharide. The average ester substitution degree of the sugar ester compounds is in a range of 62% to 94%. In the sugar ester compounds with different ester substitution degrees contained by the cellulose acylate film, the content of sugar ester compound having an ester substitution degree of 75% or above is 80% or below, and the content of sugar ester compound having an ester substitution degree of 35% to 50% is 5% to 30%.

Description

[Technical Field] The present invention relates to a deuterated cellulose film, a polarizing plate using the deuterated cellulose film, and a liquid crystal display device. In particular, the present invention relates to a deuterated cellulose film which is used as a polarizing plate protective film which can improve the durability of a polarizing plate under high temperature and high humidity in combination with a polarizing plate, and the use of the deuterated cellulose film. Polarizer and liquid crystal display device. [Prior Art] The use of a liquid crystal display device as an image display device that consumes less power and saves space has been expanding year by year. Previously, the liquid crystal display device has a large disadvantage that the viewing angle of the display image is large, but a wide viewing angle liquid crystal mode such as a Vertical Alignment (VA) mode has been put into practical use, thereby requiring a high-quality picture such as a television. Demand for liquid crystal display devices is rapidly expanding, such as the market or the market where outdoor lighting is required. The basic configuration of the liquid crystal display device is such that a polarizing plate is provided on both sides of the liquid crystal cell. The polarizing plate is responsible for the passage of only the light of the polarizing surface in the fixed direction. The performance of the liquid crystal display device is greatly affected by the performance of the polarizing plate. The polarizing plate generally comprises a polarizer and a transparent protective film. The polarizer comprises a polyvinyl alcohol film or the like which adsorbs iodine or a dye, and the transparent protective film is bonded to both sides of the front and back of the polarizer. The cellulose-deposited cellulose film represented by cellulose acetate is widely used as a polarizing plate protective film because it has high transparency and can easily ensure adhesion to polyethylene glycol used in a polarizer. In recent years, the actual situation is that high-quality images are required when the liquid crystal display device is placed outdoors under high temperature and high humidity, and polarized light is required. 4 201139461 Protective film is improved to polarize under high temperature and high humidity when combined with a polarizer. Board durability. First, from the above viewpoint, the cellulose-coated cellulose film which is generally used as a protective film for a polarizing plate requires high transparency (low haze), good moisture permeability (although high but not too low), and good optical properties. Previously it was adjusted to meet performance by adding a specific plasticizer. However, as a representative plasticizer, a carboxylic acid such as a diphenyl phosphate (Triphenyl Phosphate) is sublimed in a drying step during film formation of a deuterated cellulose film, and is attached to a manufacturing line. Contaminants fall onto the membrane causing problems such as planar failure. Further, in addition to this problem, from the viewpoint of providing an environmentally-friendly polarizing plate protective film and a method for producing the same, it is also required to use no ester as a plasticizer for the bismuth fiber octane film. On the other hand, various compounds are known as plasticizers which can be added to other modifiers other than deuterated cellulose, and it has been known from the past that saccharides and derivatives thereof can be added as a plasticizer. . For example, in the patent text = Zhong Kee, by adding galactose as a plasticizer to a plastic containing the powder and the cellulose, it is excellent in environmental properties and environmentally friendly. Rotation and machine = in the use of plasticizers for cellulose enamels for optical films, sugars and "hess are also suitable. Among the bribes and their targets, sugar and vinegar compounds are known. For example, In the special dispersion 2, the degree of substitution is 59.5% (the total thiol substitution degree is about the vinegar plasticizer derived from the hexa gamma (ice _ lose less 5__^= = In Patent Document 3, phase two = 201139461 cellulose acetate having an ethyl ketone substitution degree of 2.5, and a plasticizer obtained by esterification of a hydroxyl group of a saccharide of 8 〇 0 / 〇 to 99% (refer to the literature) [〇〇32], [〇115], [0134]). In Patent Document 4, a cellulose having a total thiol substitution degree of 2.1 to 2.7 is used, and all of the hydroxyl groups of the saccharide are used. A plasticizer which is partially esterified' is understood to be a plasticizer obtained by 100% esterification of a hydroxyl group of a sugar ester compound actually used (refer to the exemplified compound 1 to the exemplified compound 1). In Patent Document 5, several kinds of sugar ester compounds having different degrees of substitution are mixed for use as plasticization with respect to deuterated cellulose having a total thiol substitution degree of 2.7 to 2.95. The sugar ester compound is a sweet and sour compound obtained by partially acetating a monosaccharide to a disaccharide group (refer to the document [0393], exemplified by the compound 3 to the exemplified compound 6, the exemplified compound 9, and the exemplified compound 18, [Table 3] to [Table 6] and the like. However, in these documents, only the use examples of the sugar ester compound having a relatively high degree of ester substitution are disclosed, particularly in the case of mixing and using several sugar esters having different degrees of substitution. In Patent Document 5 of the compound, only a form in which the addition ratio of the low-substituted sugar ester compound is extremely small is disclosed. Further, in any of the documents, the total thiol substitution degree of the cellulose-deuterated cellulose is not described (especially An example of the relationship between the range of the ethyl thiol substitution degree and the degree of ester substitution of a sugar ester compound has been studied. That is, the degree of substitution and sugar ester of the deuterated cellulose (especially cellulose acetate) has not been revealed. The optimum combination of the degree of ester substitution of the compound. In addition, in these documents, the durability of the polarizing plate under high temperature and high humidity when the obtained polarizing plate protective film and the polarizing plate are combined is not studied. Literature 1] [Patent Document 2] Japanese Patent Laid-Open Publication No. 2005-515285 [Patent Document 4] WO2007/125764 [Publication No. WO2007/125764] [Patent Document 5JW02009/031464] SUMMARY OF THE INVENTION In view of the above, the inventors of the present invention have directed the above-mentioned Patent Document 2 from the viewpoint of replacing or improving a previously used plasticizer such as triphenyl phosphate (TPP). In the compound described in Patent Document 5, the physical properties of the film obtained when the compound was combined with a fluorinated cellulose film having an ethyl ketone group substitution degree of 2.7 or more and less than 2.95 was examined. However, when the sweet and sour compound having a south degree of substitution contained in Patent Documents 2 to 5 is used, it is not possible to obtain desired film properties such as transparency, moisture permeability, and optical properties, and when combined with a polarizer, The polarizing plates under the two warm south wetness are not sufficient, and further improvement is required. An object of the present invention is to provide a cellulose acetate film which is excellent in transparency, moisture permeability and optical performance and which can improve the durability of a polarizing plate under high temperature and high humidity when combined with a polarizing plate. Further, it is an object of the invention to provide a polarizing plate using the deuterated cellulose film and a liquid crystal display device using the same. As a result of intensive studies to solve the above problems, the present inventors have found that a sugar ester compound having a specific degree of ester substitution as a plasticizer is made into a mixture having a different degree of substitution, and a specific B When a combination of deuterated cellulose in the range of thiol substitution degree is used, transparency, moisture permeability, and optical performance can be obtained, and the high temperature at the time of combination with the polarizer can be improved. 7 201139461 The durability of the polarizing plate under wetness is brewed. Cellulose film. That is, the above problem is solved by the present invention having the following configuration. [1] A cellulose-deposited film comprising: a plurality of sugar ester compounds having different degrees of ester substitution, and deuterated cellulose, wherein the deuterated cellulose has an ethylidene group substitution degree of 2.70 or more and less than 2.95. Further, the sugar constituting the sugar ester compound is a disaccharide to a tetrasaccharide, and the average ester substitution degree of the plurality of sugar ester compounds having different degrees of ester substitution is 62% to 94%, and the ester contained in the cellulose film of the above-mentioned cellulose oxide film Among the various sugar ester compounds having different degrees of substitution, the content of the sugar-containing compound having an ester substitution degree of 75% or more is 8% by weight or less, and the content of the sugar ester compound having an ester substitution degree of 35% to 50% is 5 %~ 30%. [2] The cellulose-deposited film according to [1], wherein the sugar ester compound contains at least a sugar ring or an η-pyranose ring. [3] The cellulose-deposited film according to [1] or [2] wherein the sugar which becomes the mother nucleus of the above-mentioned sugar ester compound is a disaccharide. [4] The cellulose-deposited film according to any one of [1] to [3] wherein the above-mentioned sweet and sour compound has at least one of a benzoinyl group and an ethyl fluorenyl group as an ester group. [5] The cellulose-deposited film according to any one of [1] to [4] wherein the cellulose deuterated cellulose is cellulose acetate. [6] The cellulose-deposited film according to any one of [1] to [5] which has a phase difference. [7] The cellulose-deposited film according to any one of [1] to [6] which further has a functional layer. [8] The cellulose film according to [7], wherein the functional layer is a hard coat layer. [9] A polarizing plate comprising: a polarizer, and at least one film of the cellulose according to any one of [1] to [8]. [10] A liquid crystal display device comprising at least one sheet of a cellulose oxide film according to any one of (1) to m, or a polarizing plate according to [9]. According to the present invention, it is possible to provide transparency, moisture permeability, and optical performance, and it is possible to improve the polarizing plate under ten temperature and high humidity in combination with the polarized light. Further, by producing the cellulose film of the invention (IV), it is possible to provide a high-quality image when the film is placed outside the high-temperature nail, a polarizing plate of the local moon, and a liquid crystal display of the present invention using the same. [Embodiment] Hereinafter, the inner valley of the present invention will be described in detail. The components of the components described below are based on the embodiment of the present invention, but the present invention is not limited to such an embodiment. Further, in the present specification, "~" is used in the sense that the value of _ before and after the _ value is used as the lower limit and the upper limit. [Deuterated cellulose film] The cellulose-deposited cellulose film of the present invention (hereinafter also referred to as the film of the present invention) is characterized in that it contains a plurality of kinds of sweet and sour compounds having different degrees of substitution, and deuterated cellulose. The degree of substitution of the acetyl group of the cellulose is 27 〇 or more and less than 2.95, and the saccharide constituting the above-mentioned _ compound is a _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 62% to 94%, the content of the sugar ester compound having a degree of ester substitution of 75 Å/〇 or more in the various sugar ester compounds having different degrees of ester substitution in the above-described fluorinated cellulose film is 80% or less, and the ester The content of the sugar ester compound having a degree of substitution of 35% to 50% is 5°/. ~30〇/〇. Hereinafter, the film of the present invention will be described. <Deuterated cellulose> In the present invention, deuterated cellulose having an ethyl ketone group substitution degree of 2.70 or more and less than 2.95 is used. When the degree of substitution of the ethyl group is 27 or more, compatibility with a sugar ester compound (e.g., sucrose benzoate having a specific degree of substitution) which satisfies the conditions described later is good, and the film is not easily whitened, which is preferable. Further, in addition to the transparency, the moisture permeability or the water content is also good, which is preferable. Further, the durability of the polarizing plate or the wet heat durability of the film itself is also good, so that it is preferable. On the other hand, if the degree of substitution is less than 2.95, the optical performance is remarkably improved, which is preferable. The degree of substitution of the above-mentioned deuterated cellulose is more preferably 2 75 to 2 9 Å, particularly preferably 2.82 to 2.87. Further, the preferred range of the total thiol substitution is also the same as the preferred range of the above-mentioned oxime. a Further, the degree of substitution of the thiol group can be determined according to the method of a in ASTM_D817 96. The moiety which is not substituted by a thiol group is usually an hydroxy group and is substituted with a fluorenyl group having a carbon number of 2 to 22 and a carbon number of 2 to 22, which may be an aliphatic group. ▲ 醯 propyl group is not particularly limited and may be a single compound or a mixture of two = olefins 201139461. These may be, for example, a pyridyl ester of cellulose, an alkenylcarbonyl ester or an aromatic carbonyl ester, an aromatic alkylcarbonyl ester or the like, and each may have a group which is further substituted. Preferred examples of the sulfhydryl group include an ethyl fluorenyl group, a propyl fluorenyl group, a butyl fluorenyl group, a fluorenyl group, a hexyl fluorenyl group, a decyl group, a fluorenyl group, a fluorenyl group, a thirteenth fluorenyl group, and a fourteenth Base, hexadecanyl, octadecyl, isobutyl sulfhydryl, tert-butyl fluorenyl, cyclohexanecarbonyl, oleoyl, benzoinyl, naphthylcarbonyl, cinnamyl, and the like. Among these, preferred are an ethyl group, a propyl group, a butyl group, a fluorenyl group, a decyl group, an octadecyl group, a third butyl group, an oil fluorenyl group, a fluorenyl group, a naphthyl group, a cinnamyl group, and the like. More preferably, it is an ethylene base, a propyl group, and a butyl group. The cellulose-defluorated cellulose film used in the present invention imparts hydrophilicity from the viewpoint of adjusting moisture permeability or water content, and therefore the substituent is preferably a substituent containing an ethyl fluorenyl group. Further, as the mixed fatty acid deuterated cellulose, a mixed fatty acid deuterated cellulose may be used, and specific examples thereof include cellulose acetate propionate and cellulose acetate butyrate. The basic principle of the method for synthesizing deuterated cellulose is described in the Wood Chemistry, ed., vol. 180-190 (Kyoritsu, 1968). A representative synthetic method is liquid phase acetylation using a tarenic acid-acetic acid-sulfuric acid catalyst. When the above-mentioned deuterated cellulose is obtained, specifically, a cellulose raw material such as cotton linters or wood pulp is pretreated with an appropriate amount of acetic acid, and then poured into a pre-cooled acidified mixed solution for acetification to synthesize complete hydrazine. The cellulose (the total of the thiol substitution degrees at the 2, 3, and 6 positions is approximately 3 〇〇). 11 201139461 The above (4) mixed solution generally contains acetic acid as a solvent, a tickic acid if as a hydrazine, and a sulfur as a thief. It is usually used in an amount that is chemically more than the amount of moisture present in the anti-Brown fiber system (10). After the end of the reaction, the neutralizing agent (for example, lanthanum, 35, iron, and zinc in the zinc) is added to carry out the hydrolysis of the excess surface if and the neutralization of the partial catalyst. An aqueous solution of a salt, acetate or oxide. Then, the obtained fully deuterated cellulose is saponified and matured by maintaining it at 5 〇t to 9 Torr in the presence of a small amount of an oxime reaction catalyst (generally residual sulfuric acid), and is changed to have The desired degree of substitution of the base and the degree of polymerization of the brewed cellulose. At the point of time when the desired cellulose deuterated cellulose is obtained, the catalyst remaining in the system is completely neutralized using the neutralizing agent as described above, or the deuterated cellulose solution is poured into water or diluted without neutralization. The specific deuterated cellulose described above can be obtained by separating the deuterated cellulose in sulfuric acid (or by introducing water or dilute sulfuric acid into the deuterated cellulose solution), washing, stabilizing, and the like. The molecular weight of the above deuterated cellulose is preferably from 40,000 to 200,000, more preferably from 1,000,000 to 200,000, in terms of number average molecular weight (Mn). The Mw/Mn of the brewed cellulose used in the present invention is preferably 4.0 or less, more preferably 1.4 to 2.3. In the present invention, the average molecular weight and molecular weight distribution of 'deuterated cellulose and the like can be calculated by gel permeation chromatography (GPC) to calculate the number average molecular weight (Mn) and the weight average molecular weight (Mw), and The method described in the publication WO 2008-126535 calculates the ratio of the two. 12 201139461 <Sugar ester compound> The film of the present invention contains a plurality of sugar ester compounds having different degrees of ester substitution, and the sugar constituting the sugar ester compound is a disaccharide to a tetrasaccharide, and the plurality of sugar ester compounds having different degrees of ester substitution are used. The average ester substitution degree is 62% to 94%, and the content of the sugar ester compound having an ester substitution degree of 75% or more in the plurality of sugar ester compounds having different degrees of ester substitution in the above-described cellulose-deuterated film is 80%. In the following, the content of the oxime ester compound having an ester substitution degree of 35% to 50% is 5% to 30%. By adding the above-mentioned sugar ester compound to the cellulose fluorite film, the visibility of optical characteristics can be prevented. Even if the heat treatment is not performed before the stretching step, the total turbidity and the internal turbidity can be reduced. Further, by using the cellulose telluride film of the present invention in a liquid crystal display device, the front contrast can be greatly improved. - Sugar residue - The above-mentioned sugar ester compound means a compound in which at least one of a substitutable group (e.g., a hydroxyl group or a carboxyl group) in the polysaccharide constituting the compound is ester-bonded to at least one substituent. Namely, the sugar ester compound herein also includes a broadly sucrose-like organism, for example, a compound containing a sugar residue such as gluconic acid as a structure. Namely, the above sugar ester compound includes an ester of glucose and a carboxylic acid, and also includes an ester of gluconic acid and an alcohol. The substitutable group in the polysaccharide constituting the above sugar ester compound is preferably a trans group. In the above sugar ester compound, 'the structure derived from polyterpenes constituting the sugar ester compound (hereinafter also referred to as a sugar residue) is contained. Each single saccharide residue 13 201139461 is referred to as a structural unit of a compound. Difficult to be the above-mentioned sugar and vinegar: 2 structural unit contains π (four) county fresh domain material county unit, -:, some sugar residues light structural unit or seven practice structure ί = ί constitute the above sugar ester, preferably - and Contains 吼 two, 〇 〇 兀 or furanose structural unit. The sugar residue of the vine vinegar compound may be derived from a five-carbon sugar or may be derived from a hexose anti-sugar, but is preferably derived from a six-carbon sugar. The number of structural units contained in the 〜4, upper=^ conjugate is preferably 2 sugars above ^3, particularly preferably 2. That is, the above-mentioned sweet and sour compound is ϋ 四 to tetrasaccharide, more preferably bis to trisaccharide, and particularly preferably, the above-mentioned sweet and sour compound preferably contains 2 to 4 units. Between the two or more than the singular structure unit or the butterfly structure, there are at least one via the substrate. The (four) I structure is early or the saccharide structure unit is saccharified to form the above monosaccharide or contains 2 to 4 subunits. For example, it can be mentioned: red peony, threose, ribose sugar, f example, sugar, alu, azhuo sugar, (four) sugar, fructose, sweet = idose, galactose, tower miscellaneous, sea test t: bud rr, Disaccharide, Aspergillus niger, malt-lactosamine, lactitol, lactulose, melibiose, onion disaccharide, sucrose, sucrose, sucrose, = grass =, syrup, sea Human and sugar, cellotriose, 201139461 disaccharide, gentian disaccharide, isomaltose, isoglucosyl maltose, maltotriose, mannotriose, pine triose, panaxose, psyllium , raffinose, eugenose: umbrella sugar, lycopene, maltotetraose, stachyose, maltopentaose, hairy sugar, maltohexaose, xylitol, sorbitol, etc. More Good ribose, arabinose, xylose, lyxose, raisin, fructose, mannose, galactose, trehalose, maltose, cellobiose, lactose, sucrose, xylitol, sorbitol, etc. Good for arabinose, xylose, glucose, fructose, mannose, galactose, maltose, fiber double hearing, sugar, especially for xylose, glucosamine, silk, chloroplast, galactose, maltose, cellobiose, sucrose , Xylitol, Sorbitol - Structure of Substituent - The above-mentioned sugar s-used compound used in the present invention preferably contains a usable substituent and has a structure which is fine by the following formula (1). Formula (1) (〇^VG<^\(〇^2)r In the formula (1), G represents a sugar residue, and L! represents _〇·, _c〇... clothes 13 ==1 represents a hydrogen atom or a monovalent a substituent, Rl2 represents a substituent having a valence of =. " and r each independently represent an integer above 〇, p + q + 1• is equal to the number of bases assuming the above substituted _. The preferred range of the above G is preferably in the range of the above-mentioned saccharide residue, and the above L is preferably _〇_ or _c〇_, more preferably. When the above-mentioned l丨 is 15 201139461, it is particularly preferably a linking group derived from a bond or a vinegar bond, and particularly preferably a linking group derived from a vinegar bond. Further, when there are a plurality of L1s, the same can be used. Preferably, at least one of R11 and R12 has an aromatic ring. In particular, when L1 is (i.e., when R", Ru is substituted on a hydroxyl group in the above sugar ester compound), Rn, Rlz and Preferably, RU is selected from a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted aryl group, a substituted substituted silk, a substituted or unsubstituted amine group, more preferably a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted silk, or a substituted silk substituted aryl group, particularly preferably an unsubstituted fluorenyl group, a substituted or unsubstituted alkyl group, or Unsubstituted aryl. Further, when there are a plurality of R", RU, and Ri3, respectively, they may be the same or different. . . The P table is not limited to the above integer, and the preferred range is the same as the preferred range of the number of hydroxyl groups per monosaccharide unit to be described later. Preferably, the above r represents a number larger than the number of pyranose structural units or the number of gurdose structural units contained in the above G. The above q is preferably 0. Further, since P + q + r is equal to the number of hydroxyl groups when the above-mentioned G is an unsubstituted saccharide having a cyclic acetal structure, the upper limit of the above p, q & r is a structure corresponding to the above G. Determine consistently. Preferred examples of the substituent of the above-mentioned sugar ester compound include a hospital base (preferably having a carbon number of 1 to 22, more preferably a carbon number of 丨~12, and particularly preferably a carbon 201139461 number of 1 to 8). a base such as a mercapto group, an ethyl group, a propyl group, an ethyl group, a propyl 2 cyanoethyl group, a benzyl group or the like, an aryl group (preferably having a carbon number of 6 to 24, more preferably 6 to 18, Particularly preferred is an aryl group of 6 to 12, such as a phenyl group, a naphthyl group, or a fluorenyl group (preferably having a carbon number of 1 to 22, more preferably a carbon number of 2 to 12, particularly preferably a carbon number of 2 to 8). Alkyl groups such as ethyl, propyl, butyl, pentylene, hexyl, octyl, phenyl, phenyl, phthalic acid, etc. Preferably, the carbon number is i~22, more preferably the carbon number is 2~12, particularly preferably the decylamine having a carbon number of 2~8, such as amidino group, an etidamine group, etc.) Preferably, the carbon number is 4 to 22, more preferably 4 to 12 carbon atoms, particularly preferably an amidino group having a carbon number of 4 to 8, such as amber quinone imine group, quinone imine group, etc.) Jia is a hospital base or a base, and thus better as a base, a base, a stupid base, a special B is a benzoyl group, and mince at least one group, and further particularly preferably benzoyl group. As a method for obtaining the above-mentioned sugar ester compound, commercially available products such as jin, Huacheng (share), and Aldrich may be commercially obtained, or a known S-derivative method may be used for commercially available carbohydrates. It is preferable that the number average molecular weight is more preferably from 200 to 3,000, particularly preferably from 250 to 2,000, in the method of 200 〜 〜 。 。 。 。 。 。 。 。 。 。 。 。 。. Specific examples of the above-mentioned sugar-combination compound which can be preferably used in the present invention are listed, but the present invention is not limited to the following embodiments. More than two of two independently represent an arbitrary substituent, and may be different. The ClogP value is a value obtained by calculating a common logarithm logP of the partition coefficient P of alcohol and water for sim 17 201139461. For the calculation of ClogP values, use the Daylight Chemical Information Systems system: Group CLOGP programs in PCModels. [Chemical 1] ch2or ten μ m C〇R ^ OR ] I Τ I ch2or H OR OR Η [Table 1] Compound substituent 1 Substituent 2 Molecular weight species Substitution degree Substitution degree 101 Ethyl 7 benzyl 1 727 102 Ethyl 6 benzyl 2 775 103 Ethyl 7 Benzopyridin 1 741 104 Ethyl 6 Benzopyridin 2 802 105 Benzyl 2 No 0 523 106 Benzyl 3 No 0 613 107 Benzyl 4 No 0 702 108 Ethyl 7 phenylacetamyl 1 771 109 Ethyl 6 Phenyl Erylate 2 847 110 Benzopyridinyl 1 - 446 111 Phenylhydrazine 2 Nil - 550 112 Phenylhydrazyl 3 • 654 113 awkward base 4 none - 758 114 benzamidine 5 no - 862 115 benzamyl 6 not - 966 116 phenyl sulfonyl 7 no - 1070 117 benzamidine 8 no - 1174 18 201139461 [ 2]

[Table 2] Compound Substituent 1 Substituent 2 Molecular Weight Species Degree of Substitution Degree of Substitution Degree 301 Ethylene 6 Phenylhydrazyl 2 803 302 Ethylene 6 Benzyl 2 775 303 Ethyl 6 Phenyl Ethyl 2 831 304 phenylhydrazine 2 no 0 551 305 benzyl 2 no 0 522 306 phenyl ethyl 2 without 0 579 [Chemical 3]

19 201139461 [Table 3] Compound Substituting a certain 1 401 'type Ethylene group _ Substitution degree 402 Ethyl group 6 403 Ethyl group 6 404 Bismuthyl group 2 405 Benzyl 2 406 Phenyl ester 2

The sugar ester compound is contained in an amount of 3% by mass to 3% by mass based on the amount of the fluorinated cellulose, and more preferably, the saponin 3 has a sufficiency of 2, and the content of the sugar ester compound is ～2G% by mass, particularly preferably 5% by mass to 15% by mass. In addition, it is preferable that the amount of the above-mentioned sugar gargle is added to the amount of the plasticizer added (the amount of the plasticizer). To add 2 times to 1 〇 times (mass weight ratio), it is more preferable to add 3 times to 8 times (mass ratio). (The content ratio of the sugar ester compound having a different degree of ester substitution) is rich in the degree of substitution with respect to the present invention, and the average degree of ester substitution of the plurality of sugar ester compounds having different degrees of substitution of S曰 is 62/. 94/. . By controlling the average degree of ester substitution of the above-mentioned sugar ester compound to such a range, the moisture content or moisture permeability of the present invention can be reduced, and the durability of the polarizing plate or the wet heat durability of the film itself tends to be good. Further, it is preferred that the film having the average degree of ester substitution of the above-mentioned sugar ester compound controlled within such a range has a large optical display property (Rtil). In the present invention, the degree of substitution of the ester contained in the sterilized cellulose film is different from that of the various sugar ester compounds of the above-mentioned 20, 2011, 461, the content of the sugar ester compound having an ester substitution degree of 75 Å/〇 or more is 80% or less, and the ester is substituted. The content of the sugar ester compound having a degree of 35% to 50% is 5% to 30%. By controlling the content of each of the above-mentioned sugar ester compounds to such a range, the transparency of the film of the present invention can be maintained. The inventors of the present invention have found that a plurality of sugar ester compounds having different degrees of ester substitution in the cellulose-deposited cellulose film having a high degree of substitution with respect to an acetyl group have a sugar having a high degree of substitution with an ester substitution degree of 75% or more. When the content of the ester compound is 80% or more, the sugar ester compound tends to be incompatible with the deuterated cellulose and oozes out. Further, the inventors of the present invention have not been bound by any theory, and found that a plurality of sugar ester compounds having a different degree of ester substitution in the above range have a degree of substitution of the ester of 35% to 5% by weight. The low-yield sweet and sour compound has good compatibility with the cellulose acetate having a high degree of substitution with the ethylenic acid by the low-substrate_capacitability, thereby preventing the film from being formed. The sugar ester compound bleeds out during film formation. Further, when the sugar ester compound is a disaccharide, the average number of the esterified substituents is 5 to 75 Å, and the (4) substituent is 6 to 8 high substitution contents. The rate of substitution of the substituents of 3 to 4 is 5% to 3% by weight. The average vinegar substitution degree of the above various sweet and sour compounds having different degrees of ester substitution is preferably from 6 g to 95% by weight, more preferably from 65 to 85%. The average g of the various sugar S compounds having different degrees of ester substitution is controlled within the above range, which means that each of the plurality of sugar S compounds having different degrees of vinegar substitution has an average of 21 201139461 units. The quantity is controlled by the phase _ of the phase. By controlling the above, the average number of reductions of each structural unit of the hydration can suppress the movement of the toner toward the polarizer layer under high temperature and high humidity with time, and polyvinyl alcohol (polyvinyl Alc〇h〇) 1, PVA) The destruction of the disc-compounding compound can suppress the deterioration of the performance of the polarizer under high temperature and high humidity with time. In the present invention, the content of the sugar ester compound having an ester substitution degree of 75% or more is preferably 40% to 80%, more preferably, in the plurality of sugar ester compounds having different degrees of ester substitution in the cellulose film. It is 55°/. ~75°/. . In particular, in the case of optical properties, water content, or moisture permeability, the content of the sugar ester compound having a degree of ester substitution of 75% or more among the various sugar ester compounds having different degrees of ester substitution in the cellulose film for deuteration To some extent, the higher the better. In the present invention, the content of the sugar ester compound having a degree of ester substitution of 35% to 50% in the plurality of sugar ester compounds having different degrees of ester substitution in the cellulose film for deuteration is preferably 5% to 40%. More preferably, it is 10%~3〇〇/0. A plurality of sugar ester compounds having different degrees of ester substitution satisfying the above conditions are combined with deuterated cellulose satisfying the above-described degree of substitution of the ethyl thiol group, whereby physical properties or optical properties of the film can be obtained, and durability of the polarizing plate can be obtained. It is improved to be superior to known phosphate ester plasticizers such as the so-called Triphenyl phosphate (TPP) / Bisphenol-A bis (diphenyl phosphate) BDP. . Further, when laminating with the hard coat layer, a film excellent in adhesion and excellent in pencil hardness can be obtained. 22 201139461 (Method of preparing various sugar ester compounds having different degrees of ester substitution) The method of mixing a plurality of sugar ester compounds having different degrees of ester substitution is not particularly limited, and a known method can be used. In addition, a plurality of times of mixing the above-mentioned sugar ester compounds having different degrees of ester substitution may be, for example, in the case of using a solution film forming method, or may be added to the cellulose halide dopant before the addition of the cellulose halide dopant. After the inclusion of a plurality of sugar ester compounds individually. <Additives other than the sugar ester compound> (1) Plasticizer other than the sugar ester compound The cellulose telluride film of the present invention preferably contains a polyol ester-based hydrophobizing agent and a polycondensed ester-based hydrophobicizer. The agent and the carbohydrate derivative are at least one type of hydrophobizing agent in the hydrophobizing agent, and are two plastic agents other than the compound (4). As the hydrating agent for the money, it is preferable to reduce the glass of the film as much as possible, and to reduce the water content. By using such a hydrophobizing agent, it is possible to diffuse an additive into the polarizing plate layer in the cellulose film at a south temperature and high humidity, and to improve the deterioration of the performance of the polarizing plate. (Polyol ester-based hydrophobizing agent) The above polyol is represented by the following formula (A). General formula (A) R31-(〇H)n integer) (wherein R31 represents an organic group of η valence, and n represents a positive ternary m hydrating agent of 2 or more, which is preferably a ruthenium, for example, 23 2011 39461 = B3 is not limited = in: some: can be listed as alcohol, sedative, two-same, h, one, one, two, one, four ethylene glycol, one, one, three, propylene glycol, dipropylene glycol, three Propylene glycol, 12_ 1,3-butanediol, ! 4 _ _ # > 〆 一 a private, A - st u dibutyl, leave, 2,4 · butyl triol, hexane diol, hexane , galactitol, mannitol, 3·mercaptopyrene-1,3,5·triol, pinacol, sorbitol, tris(4): thiopurine, xylitol, etc. Ethylene glycol, tetraethylene glycol, dipropylene mono-2-diol, sorbitol, tri-propyl mercapto, xylitol. The number of polyols of 5 or more is more than _. The (4) monocarboxylic acid is not particularly limited as long as it is used, and a known aliphatic monocarboxylic acid, alicyclic monocarboxylic acid, early acid, or the like can be used. (4) It is better to pick up the moisture permeability and retention. The monomer used in the above-mentioned polyol vinegar is preferably as follows. However, the present invention is not limited thereto. The example is preferably used as the above aliphatic monorexic acid, and the carbon number is preferably from 1 to 32. A fatty acid having a bond or a side chain. More preferably, the carbon number is (9), particularly preferably 0 to 10. If acetamidine is contained, the compatibility with the cellulose derivative is increased, so it is preferred to mix acetic acid with other single bonds. Further preferred is the above aliphatic monocarboxylic acid: acid, caproic acid, heptanoic acid, caprylic acid, capric acid, capric acid, 2 ethyl acetate; _ decanoic acid, lauric acid, ten Triacid, mezzanine acid, pentadecanoic acid, brown gene, heptadecanoic acid, stearic acid, nineteen acid, arachidic acid, behenic acid, 24 201139461, fourteen I, soil acid, twenty-seven acid, Twenty people of acid, candied acid, fatty acid, undecylenic acid, oleic acid, sorbic acid, linoleic acid, human linoleic acid, peanut oleic acid and other unsaturated fatty acids, etc. Examples of the carboxylic acid include an example of producing the above-mentioned aromatic single ship, which is a preferred transgenic acid, cyclohexanoic acid, a ring-seeking ship, or a charm. Listed = acid-toluic acid, etc., which are introduced into the benzene ring of benzoyl g, such as benzene carboxylic acid, naphthalene carboxylic acid, tetrahydronaphthalene carboxylic acid, etc. 'or a derivative thereof, but particularly preferably benzoic acid. The molecular weight of the above-mentioned polyol-based hydrophobizing agent is not particularly limited, and is 300 to 3,000, more preferably 350 to 1,500. The larger the molecular weight, the more difficult it is to produce. Therefore, in terms of moisture permeability and compatibility with a cellulose derivative, the carboxylic acid used in the above polyol ester may be one type or a mixture of two or more. Further, all of the hydroxyl groups in the above polyol may be two, and a part of the hydroxyl group may remain in the form of a hydroxyl group. 3, ^ The following 'is a specific compound of the above polyol ester. 25 201139461 [Chemical 4] 1 C4H3-C-0*-(CH2}2-〇-<CH^2~0-*(CH2)a-〇-C~C4H9 ο ο 2 Ο" Poor*·〇— (CH2)2—〇—{CHah—O—<CHa)2 A V==ZQ Ο 3 〈—(CH2)2—Ο—<CH山一〇一 (CHdf 〇一〉 ^~f 〇0 ^~f 4》—C~Q'~^,CH2-CHg—-Q^'*G~-^” 5 C4H9-C-〇-^CH2-CHt-〇-^-C-C4H9 〇〇6 CRH17 -C-〇-(cH2-CH2-〇^C-CBHt7 0 o 7 〇-S~. 十叫-CHr〇^-5-〇8"\~C-0-^CH2CH2CH2-0^-C~/ y

, q q \sssssJ 9 C4He_C-0~[*CH2CH2CH2—〇^~C_C4H9 o 3 0 10 CBHi7-C-0-^CH2CH2CH2-0^-C-C8H17

OO 11 {_Vc-〇^ch2ch2ch2-o^ch^\ v-yqq 12 f, one c-〇*"f~CH2CH*^〇V~C7 〇ch3 〇13 C4He-c-o-^ch2ch-o ^~-c~c4h» ooa

CH 14 15

CeH^-C-O^C^CH-O^-C-CaHiT. CHS 〇 〇~ir〇*{CH2?H—(=) 26 201139461

18 ch2-o-c-c8h17

CHaCHjf-C~CH2-〇_C-C8H17 I O 13 O \广""〇 Ct^CH3-C-CH2-〇-C—/ \ 〇

Ch2-o-c-c8h1t O CHa-0-C-CH3 20 21 ch2 CHaCHj-C-CH*—O-C-CH, I ° CH2-〇-C-CHso ch2-o ch3ch2-c-ch2-

Ch2

•0-rO 22 o 2^0-C—/ \ CH3CH2"C-CH2-〇-C—/ ) 23 oo Factory “-〇 CH3CH2—C-CHa—O-C—^>

CHa—OH 27 201139461 6]化 24 ΓΕό ^ CIO— \^/oss o-rL \sssX %/ 25 r“-o ri

26 ο h cl^lo °~ f— o 28 o 29 6

o View CHO

-τό 9rf I

Hz cw H3I CICIOICI c wo=27 rc=-o rvc- 八丫? Ο- °· ο —0.^10 OT^i OIC I Ha c

* o 1 T"~O

Ha CH

c - H2 OIC 9 c=o χό 0.1 OICΗ2 - ίΗ?5-^^> ο 丨CHOCH, 28 201139461 [化η 30

31 Ο CH2—〇_c—^> ch3-ch2—c-ch2—o-c—^ \ CH-

n dc-o such as H2-civ>ctv-o

Take seven 2:--〇Γ〇

(polycondensation ester-based hydrophobizing agent) The polycondensation ester-based hydrophobizing agent is preferably from at least one dicarboxylic acid having an aromatic ring (also referred to as an aromatic dicarboxylic acid) and at least one average carbon number of 29 201139461 is 2.5. Obtained from ~8.0 aliphatic diol. Further, it is also preferably obtained from a mixture of an aromatic dicarboxylic acid and at least one aliphatic dicarboxylic acid, and at least one aliphatic diol having an average carbon number of from 2.5 to 8.0. The calculation of the average carbon number of the dicarboxylic acid residue and the above dicarboxylic acid residue is carried out individually as a monohydric alcohol residue. The value calculated by multiplying the composition ratio (mole fraction) of the above dicarboxylic acid residue by a number is set as an average carbon number, for example, #% Mohr/^ adipic acid residue and orthobenzene When the diterpene acid residue is composed, the average carbon number becomes. Further, in the case of the above diol residue, the average carbon number of the diol residue is set such that the composition ratio of the diol residue (the molar fraction is multiplied by the calculated value, such as 'when by 5 〇 mole When the % ethylene glycol 5 〇 mol% of the 1,2-propanediol residue is constituted, the average carbon number of the poly-carbon condensed ester is preferably 5 (^, more preferably 700 to 1200). If the polycondensation vinegar is above _, the volatility becomes low, and it is not easy to produce a cataract or step (4) when the extension is caused by sublimation under high temperature conditions, and if it is below the test, then It is not easy to produce bleed out during film formation and during heating and extension. The number average molecular weight of the method can be reduced by gel permeation chromatography, and the broach is not at the end. The end of the polystyrene polyol Μ book t, it is difficult to measure the excess acetic acid and the amount of potassium hydroxide (mg) after the polyacetate acetonitrile. 201139461 10.0 The mixture of no-two thieves is preferably used as a di-decanoic acid of more than 5, preferably a dicarboxylic acid component, having a carbon number of 5 5 or more preferably 5.6 to 8. If the plates are both 5.5 or more, the average yield of the (4) long-lasting right-key is 1 G or less, and the compatibility of the cis-cellulose is excellent, and it can be prevented from being escaping in the riding process. The aromatic dicarboxylic acid residue is contained in the polycondensed 5-anthracene obtained from the octa- i-alcohol and the tri-alcoholic acid. The term 'residue' in the present specification means polycondensation S. The partial structure of the present invention is a partial structure having a single-frequency of (4) silk condensation. For example, the di(tetra) residue formed by a Wei HOOC-R-COOH is -OC-R-CO- The ratio of the aromatic dicarboxylic acid residue of the condensed ester is preferably 40 mol% or more, more preferably 4 〇 mol% to 95 mol%, and the ratio of the aromatic dicarboxylic acid residue is set to 4 〇 m 〇. 1% or more, a bismuth-based film which exhibits sufficient optical anisotropy can be obtained, and a polarizing plate excellent in durability can be obtained. When the % curry% or less is satisfied, the compatibility of the cellulose ester is excellent. It is also difficult to cause bleed out during film formation and heating extension of the fluorinated cellulose film. As an aromatic urethane which can be used for the formation of the above polycondensation ester-based hydrophobizing agent Examples of the acid include phthalic acid, terephthalic acid, m-dicarboxylic acid, 1,5-naphthoic acid, iota-4-naphthoic acid, naphthalene dicarboxylic acid, and 2-naphthalene dicarboxylic acid. Acid or 2,6-naphthalenedicarboxylic acid, etc. Among them, preferred is phthalic acid, p-dicarboxylic acid, 2,6-naphthalene dicarboxylic acid, more preferably phthalic acid, and puppet 31 201139461 曱More preferably, the acid is more preferably terephthalic acid. In the above polycondensation ester, an aromatic dicarboxylic acid residue derived from an aromatic acid used for mixing is formed. Preferably, at least one of the anthracene dioxime group, the p-dibenzoic acid residue, and the isophthalic acid residue is preferably an phthalic acid residue or a terephthalic acid residue. At least one of the compounds, and more preferably a terephthalic acid residue. In the case of mixing in the formation of the above-mentioned polycondensation ester, the use of the aromatic dicarboxylic acid as the aromatic dicarboxylic acid can be used to form a film with a deuterated cellulose. It is also difficult to produce a deuterated cellulose film at the time of heating and elongation. Further, the aromatic dicarboxylic acid may be used singly or in combination of two or more kinds. When two types are used, it is preferred to use 'acid and p-dicarboxylic acid. It is preferable to use a combination of two kinds of aromatic diacids of phthalic acid and terephthalic acid to soften the polycondensed vinegar at normal temperature. The amount of the terephthalic acid residue in the dicarboxylic acid residue of the above polycondensation ester is preferably 40 mol% to 1 〇〇 m〇i%. 3 ^ By setting the terephthalic acid residue ratio to 4 〇 m 〇 1% or more, a cellulose optical film having a sufficient optical anisotropy of '4 is obtained. An aliphatic diterpene acid residue is contained in the ester obtained from the diol and the diremediate acid containing an aliphatic diremediate acid. As the aliphatic & '', which can form the above-mentioned polycondensation ester-based hydrophobizing agent, for example, oxalic acid m-lan, cis-butan ^ 32 201139461 anti-butadiate = diacid, glutaric acid, adipic acid, pimelic acid And suberic acid, azelaic acid, decanoic acid, dodecanedicarboxylic acid or 1> 4-cyclohexanedicarboxylic acid. In the polycondensation ester, a fatty aliphatic dicarboxylic acid residue derived from the mixture is formed. The average carbon number of the post-aliphatic dicarboxylic acid residue is preferably from 5.5 to 10.0, more preferably 5.5 8.0, still more preferably from 55 to 7 Å. If the average carbon number of the aliphatic di-retensive acid residue is less than the cut, the heating reduction of the compound can be reduced and the step caused by the bleeding during the drying of the cellulose network can be prevented from being the cause of the failure. produce. Further, when the number of carbon residues of the lipid-bis-acid retardation is 5.5 or more, the compatibility is excellent, and precipitation of the polycondensation ester is less likely to occur, which is preferable. In the case of the second Xiangsa 'i ^ silk condensation S, it is possible to use two kinds of aliphatic amber shafts. When two types are used, it is preferred to use an acid. It is preferred to use an acid in the mixing at the time of forming the polycondensation. The idea of an aliphatic two-passibility can be preferred to the desired value 'in the second phase of the brewing cellulose: two or three acids and aromatics - preferably using the two aliphatics of each species 33 201139461 = Family second. The value of 1 in the average = number of the dicarboxylic acid residue of the organic dicarboxylic acid residue can make the content of the aromatic dinuclear residue become more uniform and improve the durability of the polarizer. The diol residue is contained in the diol and the diNide containing the ruthenium. Θ θ In the present specification, the diol residue formed by the diol ΗΟ κ κ 〇Η -0 is -0-R-0-. The diol which forms the polycondensation ester is exemplified by an aromatic diol and an aliphatic monool, and the polycondensation ester used in the above hydrophobizing agent is preferably formed of at least an aliphatic diol. The above-mentioned polycondensation ester is preferably a fatty alcohol residue having an average carbon number of 2.5 to 7.0, more preferably an aliphatic diol residue having an average carbon number of 2.5 to 4.0. When the average carbon number of the aliphatic diol residue is less than 7 〇, the compatibility with the cellulose is improved, and the amount of heat loss of the β substance is hardly increased, and the brewing is hard to occur. The step of drying the cellulose network is considered to be the cause of the problem. Further, when the average carbon number of the aliphatic-alcohol residue is 25 or more, the synthesis is easy. The aliphatic diol which can form the above-mentioned polycondensation ester-based hydrophobizing agent may, for example, be an alkyl diol or an alicyclic diol, and is preferably, for example, a diol or a 1,2-propanediol. 1,3-propanediol, 1,2-butanediol, υ-butanediol, 2-hydrazino-1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 2,2_ Methyl propanol (neopentyl glycol), 2,2-diethyl-1,3-propanediol (3,3-di-methylpentane), 2-n-butyl-2-ethyl-1 , 3-propanediol (3,3_-light methyl heptane), 3-mercapto-1,5-pentanediol, 1,6-hexanediol, 2,2,4-34 201139461 monomethyl-1 , 3-pentanediol, 2-ethyl_ι, 3-hexanediol, 2_, its alcoholic decanediol, U0-decanediol, (3)·Eight-fired _^=octane=alcohol, cyclohexane Two p alcohol and the like. These are preferably mixtures with two or more than two or more. More preferably, the above aliphatic diol is at least one of ethylene glycol, u-propylene glycol, and η alcohol, particularly preferably ethylene glycol, and 2, _, preferably ethylene glycol. 1,2-propanol or U_propanediol, can prevent the condensation of the purpose;

Γ = Γ, from the diol form = alcohol residue used for mixing. That is, the above polycondensation is preferably composed of an ethylene glycol residue, a U alcohol residue, and a U-propanediol residue, a:: group, more preferably an ethylene glycol residue or an H-propylene glycol residue. . (4) The alcohol remains in the aliphatic diol residue contained in the polycondensed vinegar, preferably an ethylene glycol residue containing 3 1 G m 1% to just %, more preferably containing mol% 〜 100 mol%. The above polycondensation _ terminal can be directly used as a diol or a vessel = a further acid or a monool to carry out so-called end capping. As the monolin for capping, acetic acid, propionic acid, butyric acid, benzoic acid or the like is preferred. As the monool to be blocked, decyl alcohol, ethanol, propanol, isopropanol, butanol, isobutanol or the like is preferred as methanol. If the end of the polycondensed vinegar is used, the single __ carbon number is 7 and the heating loss does not increase and does not occur. 35 201139461 The end of the above polycondensed vinegar is more preferably a state in which the diol residue is maintained without capping, or is blocked by acetic acid or propionic acid or benzoic acid. The presence or absence of the end of the above-mentioned polycondensed vinegar is not limited to the same case I. When the both ends of the condensate are not blocked, the polycondensation is preferably a polyester polyol. One of the forms of the above polycondensed vinegar is a polycondensed vinegar having an aliphatic diol residue having a carbon number of 2.5 to 8.0 and a (tetra) conjugated end which is not blocked. When the both ends of the polycondensed vinegar are blocked, it is preferred to carry out the reaction of the transesterification reaction to carry out the end-capping. The 13⁄4 financial scarf, the single _ R_(10)H formed a single residue of R-ca. When the two ends of the polycondensation g are blocked by the single Wei, the above single ship is preferably a residue of a single bond, and the single residue is preferably a lipid residue having a carbon number of 22 or less. And, more preferably, the carbon number is 3 or less. Further, it is preferred that the carbon number is 2 or more. One of the forms of the above-mentioned polycondensed vinegar is a polycondensation ester in which the aliphatic diol residue has a carbon number of more than 2.5 and 7.0 to f, and the polycondensation (tetra) terminal is blocked by a monocarboxylic acid residue. When the carbon number of the single-nuclear residue which is blocked at both ends of the polycondensation is 3 or less, the volatility is lowered, the reduction of the polycondensation _ by heating does not increase, and the occurrence or recording of the recording contamination can be reduced. The production. 36 201139461 几 ί 纽 纽 纽 纽 纽 纽 纽 纽 纽 _ _ _ _ _ _ _ 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的The derivative is, for example, preferably acetic acid, propionic acid, butyric acid or the like, more preferably acetic acid or propionic acid, and most preferably acetic acid. The monocarboxylic acid used for blocking may be mixed in two or more types. Preferably, the two ends of the above heterozygous are terminated by acetic acid or (iv), and the ends are made of acetic acid and the two ends are (tetra)yl residues. When both ends of the above-mentioned polycondensed vinegar are capped, it is difficult to obtain a S1 body shape in a state of being warm, and the operation is good, and the stability of the rabbit and the durability of the polarizing plate are excellent. The above polycondensation _ specific example = = film is shown in Table 4 below, but is not limited thereto. 37 201139461 [Table 4] Dicarboxylic acid diol terminal aromatic dicarboxylic acid aliphatic dicarboxylic acid dicarboxylic acid (Morby) diol 1 diol 2 diol ratio (Mohr ratio) A-1 TPA SA 45 /55 ethylene glycol propylene glycol 45/55 ethyl decyl ester A-2 TPA SA 50/50 ethylene glycol propylene glycol 45/55 acetoxy ester group A-3 TPA SA 55/45 ethylene glycol propylene glycol 45/55 B Mercaptoester A-4 TPA SA 65/35 Ethylene Glycol Propylene Glycol 45/55 Ethyl Ester A-5 TPA SA 55/45 Ethylene Glycol Propylene Glycol 25/75 Ethyl Ester A-6 TPA SA 55 /45 Glycol propylene glycol 10/90 Ethyl sulphate A-7 2,6-NPA SA 50/50 Ethylene glycol propylene glycol 45/55 Ethyl sulphate A-8 2,6-NPA SA 50/50 Ethylene glycol propylene glycol 45/55 Ethyl ester base A-9 TPA/PA SA 45/5/50 Ethylene glycol propylene glycol 45/55 Ethyl ester base A-10 TPA7PA SA 40/10/50 Ethylene glycol propylene glycol 45/55 Ethyl Ester A-11 TPA SA/AA 50/30/20 Ethylene Glycol Propylene Glycol 45/55 Ethyl Ester A-12 TPA SA/AA 50/20/30 Ethylene Glycol Propylene Glycol 45/ 55 ethyl decyl ester A-13 TPA SA 50/50 ethylene glycol propylene glycol 25/75 ethyl decyl ester A-14 TPA SA 55/45 ethylene glycol propylene 45/55 Ethyl decyl hydrazide · 15 TPA SA 55/45 Ethylene glycol cyclohexane dimethanol 45/55 Ethyl decyl hydrazine - 16 TPA SA 45/55 Ethylene glycol propylene glycol 45/55 Hydroxyl hydrazine - 17 TPA SA 50/50 ethylene glycol propylene glycol 45/55 hydroxy hydrazine-18 TPA SA 55/45 ethylene glycol propylene glycol 45/55 hydroxy hydrazine-19 TPA SA 65/35 ethylene glycol propylene glycol 45/55 hydroxy hydrazine-20 TPA SA 55/45 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-21 TPA SA 55/45 ethylene glycol propylene glycol 10/90 hydroxy hydrazine-22 2,6-NPA SA 50/50 ethylene glycol propylene glycol 25/75 hydroxy hydrazine 23 2,6-NPA SA 50/50 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-24 2,6-NPA SA 45/5/50 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-25 2,6-NPA SA 40 /10/50 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-26 TPA SA/AA 50/30/20 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-27 TPA SA/AA 50/20/30 ethylene glycol propylene glycol 25/ 75 hydroxyindole-28 TPA SA 50/50 ethylene glycol propylene glycol 25/75 via Α-29 TPA SA 55/45 ethylene glycol propylene glycol 25/75 hydroxy hydrazine-30 TPA SA 55/45 ethylene glycol cyclohexane Sterol 25/75 hydroxy hydrazine-31 TPA SA 55/45 ethylene glycol propylene glycol 45/55 propyl decyl hydrazide -32 TPA - 100/0 ethylene glycol propylene glycol 50/50 hydroxy hydrazine-33 TPA - 100/0 ethylene glycol propylene glycol 40/60 ethoxylated hydrazine-34 TPA SA 50/50 ethylene glycol propylene glycol 45/55 The abbreviated group of the above-mentioned Table 4 represents the following compounds, respectively. PA: o-bromic acid, TPA: terephthalic acid, AA: adipic acid, SA: succinic acid, 38 201139461 2,6-NPA: 2,6-naphthalenediic acid. The above polycondensation can be synthesized by any one of the following methods: === a hot melt condensation method of a diol and a dibasic acid lysate by a usual method, or a hydrazine condensation method of the acid. In addition, regarding the above-mentioned polycondensed vinegar, in = and: in March of the year, the first version of the 曰 first edition is issued t; In addition, you can also use the patent special opening 〇5_ patent special Kaiping 〇5-155810, 曰本专利特本姻94号, 曰本专利特开平= 旒本专利特开200«42227号, Japan's special 〇 The material described in each of the publications No. 3679 and the like. The cellulose of this patent having a mass == is preferably a broad improvement effect, and oozing occurs. A better 涞 θθθ r is also difficult for 5 mass (four) i. , ^ Time point can be produced in two: (2) delayed development agent, show:: r using delayed development (prepared. Sheep obtained pure 〒 Re manifestation. Delayed appearance 39 201139461 The type of agent is not particularly limited, In the case of a rod-like or disc-shaped compound or a compound of the above-mentioned non-phosphate-based compound, a compound having a delayed developability is exemplified. As the rod-like or cryptic compound, at least two aromatic rings may be used. The compound is preferably used as a retardation-developing agent. It is also possible to use more than 13⁄4 kinds of retardation-developing agents in combination. The =k-delay agent preferably has a maximum absorption in a wavelength region of 250 nm to 4 〇〇 nm, and It is preferable that the compound which is carried out in the leg leg region is not absorbed. As the retardation-appearing material, for example, a compound described in Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. However, it is not limited to these. As the disc-shaped compound, for example, a compound described in the specification of European Patent Application No. 0911656A2, and Japanese Patent Laid-Open No. Hei 2-344655 The three-calling compound recorded in Japan The open disc-shaped compound described in Japanese Laid-Open Patent Publication No. 592- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ It is synthesized by a known method such as the method described in the Japanese Patent Application. In addition to the above-mentioned disc-shaped compound, a rod-like compound having a linear = molecule can be preferably used, for example, it is difficult to (4) Japanese Patent = 2_ In the fermented cellulose film of the present invention, the weight average of 201139461 may be further added to a molecular weight of 500 to 1 〇, 〇〇〇 92 92 92 92 92 92 92 92 92 92 92 92 92 92 92 92 92 92 92 3 3 3 3 3 3 3 3 3 The acrylic polymer preferably has a weight average molecular weight of 500 to 5000. When the acrylic polymer is added to the right, the cellulose-deposited cellulose film after the film formation is excellent in transparency, and the moisture permeability is low, and it is used as a polarizing plate. The film exhibits excellent performance. The compound described in the publication No. WO 02__126535 is preferably used in the above-mentioned gamma-stretching compound. (4) An antioxidant and a heat-resistant deterioration agent are used in the present invention as an anti-oxidation agent. Oxidant, heat resistance An antioxidant or a heat-resistant deterioration agent known in the art can be used. In particular, an internal vinegar system, a sulfur system, a I system, a double bond system, a hindered amine system, or a squamous compound can be preferably used. The heat-deteriorating agent can be preferably a compound described in WO 2008-126535. (5) Coloring agent In the present invention, a coloring agent can also be used. The coloring agent means a dye or a pigment, but In the present invention, it means that the color tone of the liquid crystal screen is changed to a blue hue, and the effect of adjusting the yellow index and reducing the haze is considered. The above-mentioned coloring agent 'is preferably used in the international publication WO2008-126535. The compound described. (6) Microparticles As the fine particles used in the present invention, examples of the inorganic compound include cerium oxide, titanium oxide, aluminum oxide, cerium oxide, acid, clay, calcined kaolin, calcined calcium citrate, and hydrated citric acid. Bismuth, aluminum citrate, magnesium citrate and calcium phosphate. The ruthenium particles are preferred from the viewpoint of reducing the turbidity in the case of the stone shovel, and the particularly good 201139461 is ruthenium dioxide. The average particle diameter of one person is preferably 5 nm to 5 Å, and more preferably 7 nm to 2 G nm. The fine particles are preferably mainly contained as secondary aggregates having a particle diameter of 0.05 μm to 0.3 μm. The content of the recorded particles of a fibrous material of the microparticles is preferably 〇〇5 mass%, which is called mass%, and particularly preferably, the mass%~〇5f amount is a cellulose derivative composed of a multilayer of a co-washing method. In this case, it is preferred that the surface contains the added amount of fine particles. As the oxidized particles of the oxidized stone, for example, the sigma of the Aerosii milk 72, R972V, R974, R812, 200, 200V, 300, R202, 0X50, ΊΤ _ &gt; NAX50 (the above is manufactured by Sakamoto Aerosil (share)) Microparticles for sale. For example, an example of a polymer which is commercially available as a polymer, such as Aerosii R976 and R811 (the above is manufactured by Japan Aerosil Co., Ltd.), is used as an example of a polymer. Examples thereof include an anthracene resin, a fluororesin, and an acrylic resin. It is preferably an anthracene resin, particularly preferably a three-dimensional network structure, and can be used, for example, in Tospearl 103, Tospearl 105, Tospearl 108, Tospearl 120, Tospearl 145, Tospearl 3120 and Tospearl 240 (above, Toshiba Silicones) The trade name of the marketer. Among these, Aerosil 200V and Aerosil R972V are particularly preferably used because the turbidity of the cellulose derivative film is kept low and the friction coefficient is lowered. (ΌOther additives 42 201139461 used in the present invention. In addition to the above, the additive can be added to a normal brewing cellulose film. Examples of the two additives include ultraviolet absorbers and the like. Other additions, the method of producing a compound of the sulphated cellulose film can be purchased as follows. &lt;Manufacturing method of bismuth cellulose film&gt; The method of tilting the locust fiber is not limited, and the method can be used for film formation. Specifically, the film of the present invention can be easily produced by the method of lysing the solution y or by melting to obtain the surface of the film containing the lysine lysate and the film. The film Ϊ ΐ method of the present invention is described by taking the case of using a film containing lyopoietin to carry out the method of using the solvent-casting film method. However, the present invention is not limited to the solution washing process. Film forming method As a method of the film of the present invention, a known method can be used. (Polymer solution) In the solution washing and film forming method, the above-mentioned deuterated fiber is used to contain each age plus polymer solution (醯化_纽液) form $ Hereinafter, a polymer solution (which may be sometimes referred to as a deuterated cellulose solution) which can be used in a solution washing and film forming method will be described. (Solvent) The cellulose deuterated cellulose used in the present invention is dissolved in Forming / miscellaneous in the solvent' and then casting the money on the substrate (4). Since it is necessary to extrude the solvent at this time, or to evaporate after the flooding, it is preferred to use a volatile solvent. A solvent which reacts with a reactive metal compound or a catalyst, and does not dissolve the substrate for casting. Further, two or more solvents may be used in combination. Further, a reaction capable of undergoing hydrolysis and polycondensation with deuterated cellulose may be employed. The organic metal compound is dissolved in another solvent and mixed. Here, the organic solvent having good solubility to the above-described deuterated cellulose is referred to as a good solvent, and in addition, a main effect is exhibited in the dissolution, and a large amount thereof is present therein. The organic solvent used is referred to as a main (organic) solvent or a main (organic) solvent. As an example of the above good solvent, 'except acetone, methyl ethyl ketone, cyclohexanone, cyclohexyl _ et al _, Qian Jing (shirt mail - cut, thf), 1,4-Yao, 1,3 dioxin, m oxy ethene, etc., ^ acid vinegar, vinegar vinegar, acetic acid Methyl vinegar, ethyl acetate, acetic acid pentane: internal self-purpose, etc. 'Methyl soluble _, dimercapto ♦ sitting side:::: decylamine suffers from monomethyl acetamide, acetonitrile, disulfoxide, Sulfolane, acetamidine acetate, etc., preferably, tert-ethyl ketone, acetone, decyl acetate and dioxane. New Zealand is a gift of miscellaneous wealth, red money machine quality. / 40% by mass of carbon atoms The number of alcohols is 4. The gelation of the agent = "===== agent' _ ratio W Ϊ after the solvent begins to evaporate and the alcohol white θ, * doping the cellulose on the support 4 44 201139461 The title of the film is set to gel), so that the peeling from the gold body is allowed to become (4) gelling solvent, #The proportion of these alcohols is small and also promotes the non-(four) organic solvent riding fiber The action of the dissolution of the element also has the effect of suppressing the increase in the oxidization of the reactive metal compound. Examples of the alcohol having 1 to 4 carbon atoms include methanol, ethanol, positive =, isopropanol, n-butanol, second butanol, third butanol, and propylene glycol. It is excellent in stability, low in boiling point, good in toxicity, and non-toxic, etc., preferably (10). These organic agents have not been reversible in the early days, but are called poor solvents. In the present invention, the brewing cellulose constituting the cellulose-deposited cellulose film contains a hydrogen-bonding functional group such as vinegar or ketone. Therefore, from the viewpoint of reducing the peeling load of the self-washing town, it is preferable to The solvent contains = 30% by mass, more preferably 7% by mass to 25% by mass, still more preferably 10% by mass to 20% by mass of hydrazine. By the difficult alcohol content, the reproducibility of Re or Rth of the deuterated cellulose film of the manufacturing method of the present invention can be accommodated. Specifically, the alcohol content is increased, or the drying temperature (heat treatment temperature) in the later-described production method of the present invention is set to be low, and the reach of Re or Rth can be further increased. Correction, Yu Shucai, 対 a small amount of water to improve the viscosity of the solution when drying the wet film (4), or to improve the short-term secret / debris strength is also effective, for example, can be 01 mass 45 relative to the entire solution 2011387461 %〜5质量%, more preferably 〇j is contained in an amount of 0.2% by mass to 2% by mass. 〇 〇 〇 特 特 特 特 特 特 特 特 特 特 特 特 特 特 特 特 本 本 本 本 本 本 本 本 本 本 本 本 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 2001 Numbered in the polymer solution of the invention, fiber = two). Quantity %~4〇 quality. More preferably, 1 〇 f is preferably 5 mass% to 30 mass%. In the mass / 〇, the best is 15 dissolved on the i«化_素 concentration energy _, the stage becomes the specified concentration of the dimension = by evaporation of the solvent, etc.; ~ and 14 mass /%) of the solution, the , Rongrong De, 隹 &gt; = agricultural shrinkage, can also be prepared in advance to prepare high concentration of bismuth cellulose. . Further, the period of the additive may be appropriately determined depending on the kind of the additive by adding an additive. The vitamin, the solution is made into it, and the preferred polymer compound, that is, the solvent for the deuterated fibril, is a gas of ethylene. Alternatively, it is also preferable to rape the horse 60. 40~95: 5 mixed solvent. (1) Dissolution step The bathing step is a step of forming a dopant by dissolving the wipes, the age-old sputum, and adding 46 201139461 solution to add a ship fluid. ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Dissolution method and other various dissolution:: No.; = household: The main solvent (four) points above the pressure to carry out the dissolution method. ή The concentration of the dopant t_cellulose is lower than the second =: rr additive to the lower H material into the shout, and after listening to the liquid <use, ζ> Η stone. (2) Casting step The casting step is a step of feeding the dopant to a metal cutting body such as a metal roller with a ' or ^ in a press mold by a liquid feeding fruit (for example, a press type = gear pump) Lai position. The shape of the slit of the metal mouth portion of the mold is adjusted, and it is easy to change the thickness of the mold. Any of the domain mode τ fonts and the like can be preferably used. Metal support 201139461 is a mirror surface. In order to increase the film forming speed, two or more press molds may be provided on the metal ship, and the amount of the dopant may be divided to form a plurality of layers. Alternatively, it is preferred to obtain a laminate by the Wei cast wire of the simultaneous secret dopant. ~ (3) Solvent evaporation step The solvent evaporation step is to heat and dissolve the mesh on the metal slab (the state before the finished product of the cellulose film, and still contains many solvents) • Send to a step that can be taken from = stripping. In the case of the job, the financial system has a self-rewarding method, or a method of heat transfer by liquid on the back side, and a method of heat transfer from the back surface of the surface. Good, the method of combining these methods is also preferred. In the back liquid ====== (4) Stripping step ... , = is in the _ position _ on the metal dragon has been steamed ===. The separated net is sent to the next step. In addition, if the amount of residual solvent (the following formula) of := is too large, if the detachment is too sufficiently dried on the metal support and then peeled off, the portion of the mesh will peel off in the middle. The method of increasing the film forming speed (as much as possible with the residual solvent 忒ί %el '11 can increase the film forming speed), and has a gel casing. For example, a method of gelling a dopant after casting a dopant with respect to the poor solvent of the brewing 48 201139461 cellulose, and a method of reducing the degree of the metal branching to gelation are added to the dopant. . Gelation is carried out on the metal support to increase the strength of the film at the time of peeling, whereby the peeling can be accelerated and the film forming speed can be increased. The amount of residual solvent in the peeling of the mesh on the metal support is preferably in the range of 5 mass% to 15 mass% depending on the strength of the drying conditions, the length of the metal branch body, etc., but the amount of residual solvent is more In the case of a lot of time peeling, the amount of residual solvent at the time of peeling is determined by the balance between the economic rate and the quality. Preferably, the temperature at the peeling position on the metal support is set to -5 (TC~4〇t, more preferably 10°c~4 (rc, optimally set to 15 °C~ 30. Further, it is preferable to set the residual solvent amount of the mesh at the s-black peeling position to 1% by mass to 150% by mass, more preferably 1% by mass to 12% by mass. The amount can be expressed by the following formula: The amount of residual solvent (% by mass) = [(MN) /N]xl〇〇 The amount of f at any time point of the M疋 network, and N is the mass of M at 110 C for 3 hours. Quality during drying. (5) Drying or heat treatment step, extension step

The tenter holding the both ends of the net to carry the web is dried by a tenter device. Drying device 49 201139461

When TgXdr is heat-treated, the heat treatment temperature is less than the time of the bell 4 and the right clock is right/right. 3° minutes or less 'better 2 points are available in the film transport direction (hereinafter, also referred to as: direction: the direction of the intersection (hereinafter, also referred to as the horizontal direction of the heart =: Shen's but the delay of the charm) The point is extended in the direction of the intersection. It is more preferable that the two-axis extension in the longitudinal and lateral directions can be implemented in one stage, and can also be carried out in multiple stages. The application of the film transfer method is extended. The wheel i is preferably 1515%, especially good for 卜·. The extension ratio (elongation ratio) of the _= weisu net can be achieved by the circumferential speed difference of the gold _ running speed when the above extension is extended. Example == 2 In the case of the nip roller device, the squeezing direction (longitudinal direction) is preferably extended by the rotation speed of the nip roller on the side of the nip by the squeezing roller on the outlet side. By borrowing, the whole delay is manifested. By extending this extension, the "extension ratio (%)" here is determined by the following formula: • &quot;&quot;β 50 201139461 Length == Long T "Extended Length) - (the extension ratio in the direction in which the direction of the feed direction is orthogonal before stretching is preferably *', and °' is preferably 10% to 50 ° / 〇, particularly preferably 20% to 40%. It is preferable to use a tenter to extend in the direction orthogonal to the direction in which the female is fed. Pulling is performed in the longitudinal direction and can be relaxed to, for example, 〇. 8 a 4» I to obtain the desired retardation value. The stretch ratio is corresponding to the optical (4) setting. Correction, when manufacturing the cellulose-deposited cellulose film of the present invention, can also be uniaxially extended in the longitudinal direction. The temperature at the time of stretching is preferably Tg_5t~Tg+(1). C, more preferably two or two Tg + 5°C 'excellently Tg.-5°C~Tg + 3t. The ruthenium film extension can reduce the turbidity of the present invention, and is preferably further dried after the stretching step. When the drying step is followed by drying, the drying temperature is The air volume and the aging time may be selected according to the type of the solvent used, and the drying condition may be selected as long as it corresponds to the type and combination of the solvent to be used. In the invention, the film of the present invention is assembled into the liquid crystal display. The viewpoint of the front contrast ratio at the time of setting is preferably that the drying temperature after the step is lower than the stretching temperature of the stretching step. (6) The winding is preferably such that the length of the film obtained as described above is 1 roller per roll. The winding is carried out in a manner of 100 m to 10000 m, more preferably 500 m to 7000 51 2011 39461 m, and further preferably looo m to 6000 m. The width of the film is preferably 〇 5 m to 5.0 m, more preferably 10^^3.0 m, and more preferably 1〇m~25m. When winding, it is preferred to impart knurling to at least one end, and the width of the knurling is preferably 3 mm to 50 mm, more preferably 5 mm to 30 mm. The mm' height is preferably 〇5 Å to 500 μηι, more preferably 1 μm 〜2 〇〇μιη. It may be single-sided pressing or double-sided pressing. The film of the invention is particularly suitable for large-surface liquid crystal display. When used as an optical compensation film for a liquid crystal display device for a large facet, it is preferred to Further, the film of the present invention includes not only a crucible which is cut into a film form which can be directly incorporated into a liquid crystal display device, but also a form in which a strip is formed by continuous production and rolled into a roll. The film of the latter form is stored and transported in this state, and when it is actually incorporated in a liquid crystal display device or bonded to a polarizer or the like, it is cut into a desired size and used. The strip-shaped state is bonded to a polarizer such as a polyvinyl alcohol film which is formed into a strip shape in the same manner, and 'when the liquid crystal display device is actually assembled' is cut into a desired size. The form of the film wound into a roll shape is a roll form having a roll length of 500 m or more. A deuterated cellulose film as a final event can be obtained by the above-mentioned material. &lt;Characteristics of the brewed cellulose film&gt; (Thirst) The cellulose of the present day is difficult to be a film of the enamel film (four) degree is (10) or more preferably 〇·4% or less, and particularly preferably 〇~〇 buckle%. 52 201139461 (The glass transition temperature Tg of the deuterated cellulose crucible) The cellulose produced by the (4) book towel's is a glass transition temperature of the entire film containing the brewing cellulose which constitutes the film (hereinafter _ is! ^, other additives (delay) (55 ί) wavelength 55G η &quot; 1 赖 厚 厚 (4) retardation value Rth = 〇 better, 〇 nm ~ 50 nm, more preferably 2. nm ~ 4. M, especially good 25 nm ~ More preferably, the film of the present invention is preferably a biaxial film, an optical compensation film. Here, the film is biaxial, which means a slow axis direction in the film. The refractive index, ny represents the refractive index in the in-plane and the ηχ-positive direction, and ηζ represents the refractive index in the direction orthogonal to the shape and the ridge.) In the case of the present invention, it is more preferable. The invention of the present invention is advantageous in that it reduces the color shift of the liquid crystal display device, particularly in the VA mode liquid crystal display device, when viewed from the oblique direction. In the present specification, ReU) and Rth(1) respectively indicate the in-plane retardation and the retardation in the thickness direction of the wavelength person. In the description # in this case, when there is no special description, the wavelength is set to 59 〇 nm &lt;&gt; ReU) to make the wavelength in ^ 21 ADH (manufactured by the prince measuring machine (〇ji Sdentific fine axis coffee) (share)) The light of λ nm was incident on the normal direction of the film and measured. Regarding Rth (λ), the slow axis (determined by KOBRA 21ADH) is used as the tilt axis (rotation axis) (when there is no slow axis, the arbitrary direction of 53 201139461 in the film plane is set to be pure) _u degrees until every 1G degree of light from the two legs, measuring all 6 points / (10) into the wavelength λ according to the measured delay value ^ flat ^ ^ / 6 (λ), κο · 21 削 (when there is no丄 抽 抽 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Bribe Handbook (JOHNwiley &amp; s〇ns, Satoshi), the value of the catalogue of various optical films. For the unknown value of the average refractive index, it can be measured by an Abbe refractometer. The average refractive index of the main optical film is exemplified below. Values: deuterated cellulose (1.48), cycloolefin polymer (152), polycarbonate 〇 59), polymethyl methacrylate (1.49), polystyrene (159). By inputting these average refractions The assumed value of the rate and the film thickness, K〇BRA 21ADH calculates nx, ny, nz. According to the calculated nx, Ny = (nx - nz ) / ( nx - ny ) is further calculated by ny and nz. [Equation 1] Formula (A)

Re(4)=

‘sin(-0)

Here, the above Re (Θ) represents the angle of inclination θ from the normal direction. 54 201139461 represents the principal axis orientation of the index ellipsoid

Rth= C(nx + ny) /2-nz) xd Formula (B) is required, and its "Abbe fold, at this time, the average refractive index n is used as a parameter by using the Abbe refractometer (AtagG (share The value measured by the company's luminometer 2-T"). (Moisture content) The balance of the invention is low, and the balance under (4) minus 8G% is low. When the ship crystal display panel is large, the change with respect to the environmental humidity is made into a buffer body, and the polarized light can be made. It is preferable to homogenize the central portion of the humidification and the end portion. (Moisture Permeability) From the viewpoint of durability of the polarizing plate and drying during processing of the polarizing plate, the film of the present invention is converted into a pit having a film thickness of 4 G μm, a relative humidity of 8 〇 ^, a volume of 1 24 /j, and a time after The moisture permeability is preferably A 150. g/m2.day~35〇〇 g/m day, more preferably 1500 g/m2.day~3〇〇〇 g/m2 such as 2000 g/m2.day~2500 g/m2.day. When the moisture permeability and water content are too high, the polarizer has a tendency to be poor in wet heat and long life, and thus it is likely to cause light leakage in a high-humidity environment. Therefore, it is more preferable to control the moisture permeability and the water content of the polarizing plate protective film in an optimum range. (Thickness) 55 201139461 The read film thickness of the present invention is preferably 2 μm, more preferably 2 〇 pm to g5, and is 进 臌; i, the soil is μ 疋叨 and the horse is 25 μηι to 65 μιη. When the right film thickness is less than 20 μm, the mechanical strength is insufficient and the film is broken, and the film surface is likely to be deteriorated. The film thickness of the present invention is adjusted as long as it is a desired thickness component concentration, the metal of the mold is called the narrow dust, the extrusion dust force of the mold, and the metal branch body speed (film width). The film width is preferably 1 〇〇〇 or more and 1500 mm or more, and particularly preferably 18 〇〇 mm or more. ", (functional layer) The film of the film may be a single layer film' or may have a layer structure of 2 or more layers. Here, the hair of the present invention is higher than that of the film of the present invention. The film group of the form of the functional layer is incorporated in the polarizing film (4) of the present invention, and other functions may be superimposed. The functional layer as the functional layer is not particularly limited as long as it does not violate the gist of the present invention, and for example, the following functions can be cited. Substrate film / hard coat / medium refractive index layer / low refractive index layer base film / hard coat / medium refractive index layer / high refractive index i / low refractive index layer substrate / hard coat / Low refractive index layer base film / hard coat layer / conductive layer / low refractive index layer f material film / hard coat layer / high refractive index layer (conductive layer) / low refractive index layer base film / hard coat / Anti-glare layer/low-refractive-index layer [polarizing plate] 56 201139461 The polarizing plate of the present invention contains at least a sheet of the present invention. The polarizing plate of the present invention can be obtained by a general method. 1 B_Aqueous solution is attached to the polarizer, which means that the water system is smashed at a high temperature. Liquid, as the polarizer used in the polarizing plate of the present invention, a previously known polarizer can be used. For example, a content such as a polyvinyl alcohol or an ethylene unit is used as a molybdenum-based dichroic dye pair. Ear %~4 mol. /0, degree of polymerization 2000~4000, saponification degree 99 〇mol %~99 99 mol% of acetaminophen-modified polyethylene glycol-like hydrophilic polymer film And extending it, or processing and aligning the plastic film like vinyl. As the film thickness of the polarizer, it is preferable to use a film thickness of 5 μm to 30 μm. The polarizer obtained in the above manner is bonded to the polarizing plate protective film. At this time, at least one of the polarizing plate protective films uses the film of the present invention. On the other hand, other polarizing plate protective film (preferably cellulose) can be used. Derivative film) As the polarizing plate protective film of the other surface, a cellulose acetate film of the present invention can be used. A commercially available cellulose ester film can also be used. The polarizing plate used for the surface side of the display device is used. Protective film 57 201139461 The anti-glare layer or the transparent hard coat layer also has an anti-reflection layer, an antistatic layer, and an anti-staining layer. Further, when the polarizing plate is formed, it is preferable to make the in-plane slow axis and the polarized light of the retardation film of the present invention. The liquid crystal display device of the present invention comprises at least one film of the present invention or a polarizing plate of the present invention. The liquid crystal display device of the present invention can be bonded. The liquid crystal display device of the present invention is produced by arranging and bonding the polarizing plate of the present invention obtained in the above manner to both surfaces of the liquid crystal cell. The liquid crystal display device of the present invention is a liquid crystal display using at least i of the polarizing plate of the present invention. The polarizing plate of the present invention can be used for liquid crystal cells of various display modes, and can be combined with, for example, Twisted Nematic (TN), In-Plane Switching (IPS), and Ferroelectric Liquid Crystal (Ferroelectric Liquid Crystal, FLC), Anti-ferroelectric Liquid Crystal (AFLC), Optically Compensatory Bend (OCB), Super-twisted nematic (Supper Twisted) Nematic, STN), Vertically Aligned (VA), and Hybrid Aligned Nematic (HAN) units of various display modes are used in combination. [Examples] Hereinafter, the features of the present invention will be more specifically described by way of examples and comparative examples. The materials, the amounts used, the ratios, the contents of the treatments, the processing order of 58 201139461, and the like, which are shown in the following examples, may be appropriately changed as long as they are not in accordance with the gist of the present invention. Therefore, the scope of the present invention should not be construed as being limited by the specific examples shown below. [Examples 1 to 3 and Comparative Examples 1 to 7] Preparation of Raw Materials (Preparation of 1-Deuterated Cellulose Resin and Preparation of Deuterated Cellulose of Degree of Substituted Ethyl Substrate as Illustrated in the Table below Sulfuric acid as a catalyst (7.8 parts by mass relative to 100 parts by mass of cellulose), and each carboxylic acid is added, followed by thiolation at 4 Torr. Thereafter, by adjusting the sulfuric acid catalyst The amount of water, the amount of water and the time of ripening to adjust the total degree of substitution and the degree of substitution of 6 are carried out at the ripening temperature of the thief. Further, the low molecular weight component of the deuterated cellulose is washed and removed by acetone. Preparation of a plurality of different sugar ester compounds A plurality of sugar ester compounds described in the following Tables were prepared by the following method: 1. First, 'synthesized by the method described in WO2009/03164 [0054] exemplified by the compound 3 Further, the compound (1) was synthesized in the same manner as in the above-mentioned table. Further, other compounds were synthesized in the same manner. Thereafter, the sugar ester compound was adjusted in combination. Preparation of the dopant (2) The following group was mixed. Shoot, feed and dissolve to dissolve, and then last about 10 After heating to 9〇〇c clock, using the average knock holes 34 of sintered metal and paper suddenly 1〇 average pore County State = 59201139461 is suddenly through filtration.

100.0 parts by mass, 8.0 parts by mass, 365.8 parts by mass, 92.6 parts by mass, 4.6 parts by mass of the solution of the deuterated oryzanol solution of the first example, the deuterated cellulose described in the following table, and various sugars having different degrees of ester substitution as described in the following table Ester compound - gas methylcholine" Methanol butanol Further, in the following table, AC represents an ethyl group and pr represents a propyl group. &lt;1-2&gt; Matting agent dispersion 4 ° Next, the deuterated cellulose solution prepared by the above method was placed in a dispersing machine to prepare a matting agent dispersion.

0.2 parts by mass 65.7 parts by mass 16.6 parts by mass 0.8 parts by mass 10.3 parts by mass Example 1 matting bismuth mash liquid Matting agent (AerosnR972) dichloromethane methanol butyl alcohol as cellulose solution 100 parts by mass of the above examples! The deuterated cellulose solution and the inorganic fine particles are mixed with the defoaming agent dispersion of Example 1 and the deuterated cellulose resin to obtain a film-forming ride amount. In addition, the examples used in the examples and comparative examples are used. The benzoic acid s is intended to be used as a reaction solvent for dehydration of toluene as a reaction solvent. #f = used and less than just ppm. The dry medium (1) was taken as follows: The type of the cellulose-based cellulose-forming agent was changed as shown in the following table, and the other examples and comparative examples were replaced with the soil-substituted degree of Example 1, plastic preparation, and the comparative example. . . Turn the same way 201139461 (3) Washing and casting The above blending is carried out by flood casting. Further, the drum using the drum film forming machine is made of SUS. (4) Drying At a temperature as noted in the following table, the net (film) obtained by washing was dried. In the minute, another J, = is a two-shaped S, and the tenter device that carries the _ after the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Further, the drying temperature herein means the film surface temperature of the film. (5) Extension The strip (film) obtained is peeled off from the drum, and then clamped in the jig 'When the residue relative to the difficult mass is dissolved to the brain ~ 5% state" at the end of the uniaxial axis Under the extended conditions, the net (film) was stretched in a direction (lateral direction) orthogonal to the film transport direction by the extension temperature and the stretching ratio of δ carried in the following. /, and thereafter, the jig was removed from the film and dried at 110 ° C for 30 minutes. At this time, the cast film thickness was adjusted so that the film thickness after the extension reached 4 pm. (6) Winding A film having the composition shown in the following table was produced, and in order to judge the manufacturing suitability, a minimum of 24 rolls having a roll width of 1280 mm and a roll length of 2600 mm were produced under the above conditions. For each of the 24 rolls continuously manufactured, a sample having a length of lm (width: 1280 mm) was cut at intervals of 100 melons and each measurement was performed. 201139461 (Production of polarizing plate) A polarizer is produced by adsorbing iodine on an extended polyvinyl alcohol film. The film of each of the produced examples and the comparative examples was attached to one side of the polarizer using a polyvinyl alcohol-based adhesive. Further, the saponification treatment was carried out under the following conditions. A 1.5 mol/L sodium hydroxide aqueous solution was prepared and kept at a temperature of 匚. A 0.005 mol/L aqueous solution of dilute sulfuric acid was prepared and kept at 35 〇c. The films prepared in each of the examples and comparative examples were subjected to the above-mentioned hydration. After immersing in the sodium aqueous solution for 2 minutes, the aqueous sodium hydroxide solution was sufficiently washed away by immersing in water, and then immersed in the above-mentioned dilute sulfuric acid aqueous solution for a minute, and then immersed in water to sufficiently wash away the dilute sulfuric acid aqueous solution. Finally, the sample was sufficiently dried under a helium addition. A commercially available cellulose triacetate film (FUJITAC TD80UF, manufactured by Fujifilm Co., Ltd.) was saponified and attached to it using a polyvinyl alcohol-based adhesive. The opposite side of the polarizer was then dried at 7 ° C for more than 1 minute. The alignment axis of the polarizer was arranged in parallel with the slow axis of the films of the respective examples and the comparative examples to allow the polarizer to be worn. The transmission axis is disposed so as to be orthogonal to the slow axis of the commercially available film. <Measurement method> (Measurement method of average degree of substitution of sucrose benzoate) The peak having a retention time of around 31.5 min is set to eight substitution Object, will protect The peak group with time between 27 min and 29 min is set as a seven-substrate, and the peak group with a hold time of 22 min to 25 min is set as a six-substitute'. The hold time is around 15 min~20 min. 62 201139461 Crest The group was set as a penta-substrate, and the peak group near the retention time of 8.5 min to 13 mil1 was set as a tetra-substrate, and the peak group having a retention time of 3 min to 6 min was set as a tri-substrate by the following HPLC. Under the conditions, the average degree of substitution with respect to the total value of the area ratio of each of the substituents was calculated. "HPLC measurement conditions" Column: TSK-gel ODS-100Z (Tosoh), 4.6* 150 mm, Batch No. (P0014) Eluent A: H20=100, Eluent B: AR=100. Add 0.1% AcOH and NEt3 in both A and B. Flow rate: 1 ml/min, column temperature: 4 (TC) , Wavelength: 254 nm, Sensitivity: AUX2, Injection amount: 1 〇μ Bu Eluent: THF/H20 = 9A (vol ratio) Sample concentration: 5 mg/10 ml (THF) (turbidity) The turbidity is determined by At 25 ° C, 60% relative humidity, use a haze meter (HGM-2DP, Suga Test Instrument) and according to J IS Κ·6714 A film sample of 40 mm &gt;&lt; 80 mm was measured. The results are shown in the following table. (Optical properties) The optical properties were comprehensively evaluated. The results are shown in the following table. (Optical display) Using KOBRA 21ADH (Prince Measurement Machine (〇ji Scientific 63 201139461

Instruments) (manufactured by the company), and the determination of Re and IUh at a wavelength of 590 nm by the above method. The results are shown in the following table. (Tg) The measurement of the glass transition temperature was carried out by the following method. After adjusting the sample of 24 mm>&lt;36 mm of deuterated cellulose film at 25 ° C and 60% relative humidity for 2 hours or more, 'Using dynamic viscoelasticity measuring device (Vibron : DVA-225 (IT Keisoku Seigyo shares) Co., Ltd.)), the distance between the clamps is 20 mm, the heating rate is 2〇c/min, and the measurement temperature range is 30°C~20 (TC, frequency 1 Hz. The vertical axis does not store the elasticity on the logarithmic axis. Modulus, the temperature is represented by a linear axis on the horizontal axis, and the rapid decrease in the storage elastic modulus observed when the storage elastic modulus moves from the solid region toward the glass transition region is recorded in Fig. 3 of JIS K71211987 The method of loading is used to determine the glass transition temperature of Ding Lu. (Water content) 3 The water rate is measured by using a moisture analyzer, a sample drying device, and VA-〇5' are all Mitsubishi Chemicals. A sample of deuterated cellulose film with a width of mm×35 mm was measured. The moisture content was calculated by dividing the water by the weight (g) of the sample. (Exudation) 9〇%, and the temperature was crystallized/cast, dried at a temperature of 6吖, wet or not, after 1〇〇〇h (closely evaluation) The thief is placed in Table 5 according to the grid test of the IISK56GG. Specifically, the grading of the film is formed on the surface of the sample after ultraviolet (Ultraviolet, UV) hardening at intervals of 1 mm. Cut into one square of 1 mm square. Attach cellophane tape and mylar tape to it, then peel off quickly and peel off by visual inspection. The adhesion evaluation was performed on the part. The result of Xe irradiation for 24 h before the formation of the incision was set to be light-tight, and the non-irradiation of Xe was set as the initial adhesion. Adhesion 〇: The peeled portion was 0 mass to 10 mass. △. The peeling site is 11 mass to 50 mass °. The splicing property x · The peeling site is more than 50 mass and 99 mass or less. Adhesiveness xx: 100 mass of the peeling part (all parts with tape attached) When irradiating Xe, use suga Super Xenon Weather Meter SX75 manufactured by Test Instruments, Inc. (Pencil hardness evaluation method) Hard coating is applied to the UV-cured sample at 25 ° C and 6 G% relative humidity for 2 hours. n The test ship stipulated by ss _6 'according to the wrong pen hardness evaluation method stipulated in JIS K 5, and the sample of g hardness is repeated five times with the code of g to load the sample of 10 CTC for seven hours. In the middle of 5 minutes, the evaluation was performed after taking out 'the hardness of 4 times or more without damage was set to the hardness of the sample. In addition, the damage defined in JIS K 5400 is the rupture of the coating film and the scratch of the coating film. Although it is described that the coating film is not targeted, the depression of the coating film is also included in the damage of the celery. The higher the number, the higher the wire hardness. 65 201139461 (Performance of polarizing plate) The durability of the polarizing plate obtained under the moist heat condition was obtained by the following method. Observed at the temperature 6 (TC, humidity 90%, and temperature 80%, thirst yield 1 〇 0 / 〇 under the damp heat condition of the positive = sucrose alumite ester bias #柘mam &lt; Drinking thousands to cross, can be sure of long-lasting. (4) Partial planting durability is better than TPP_ polarizing plate resistant 66 201139461 [ln&lt;]J-aIoo Bub ε

〇0 〇X ο X ο安ffi cn Ε m 安〇ο Ο &lt;1 X 〇ο 〇ο Ο X 〇ο 飧ή XX &lt;1 ο &lt;1 &lt; ο 〇) m 00 cn Η Η σ\ η m 5 ton £5 s Ρ ηϊ a οο Ο 0 ο ¢4 •CI ^ 〇随刼gs 2 Ο 3 3 «DI ^ ο 璨谱嵩 制 制 - 制 00 00 Η Η ol ol ol Η i ώ ^ ^ ^ ^ ^ 甸 甸uS 00 vS Substitution degree is 75% iXL replacement ^ι¥] Total VO 忒R 00 νη οό ^Η 00 f Substitution with a degree of substitution of 12 % o Ο Ο Ο ο ο \J/ so Ο Ο ο ο ο储j 4jp Umbrella-s tear iS Rong'Ο ο a 1 ί为义中§ »~Η CO νο CO Ό cn ψ i S Shao Rong Rong Oj Bu Ho I Substitute with 75% substitution jn οο CO οο m Οο m Ό inch?3 η F5 Ι5§ίΙ^ pj Ον ΐ&quot;Η η ιη η »〇η s beam 1 sucrose awkward sour sucrose sucrose stupid formic acid vinegar benzoic acid deer TPP/BD Ρ cheap sugar醆 醆 醆 苯 苯 苯 苯 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ° ° ° ° ° ° ° ° ° ° ° m - - § In is Ο m•m ^ s Η Η S3 NS ο 〇§ 12 N 〇 \ S 2 | ® 00 5S $ Ο 〇〇ο 〇〇Η S η 00 00 η 00 卜 00 ν 〇 S § vp 2 νρ Curtain benzoic acid vinegar succinct sugar stupid formic acid cool vegetable sugar benzoic acid vinegar 3 ^ 201139461 According to Table 5, the fluorinated cellulose film obtained in the example has good transparency, moisture permeability and optical properties. Moreover, the durability of the polarizing plate under the south temperature and the south humidity when combined with the polarizer can be improved. On the other hand, according to Comparative Example 1 and Comparative Example 2, when a mixture of sugar and vinegar compounds having different degrees of substitution is used, if the content of the sugar ester compound having a degree of vinegar substitution of more than % is more than the range of the present invention, the ester is substituted. When the content of the sugar ester compound having a degree of 35% to 50% is less than the range of the present invention, the sugar ester compound bleeds out, and transparency and optical properties are deteriorated. Example 4 is to facilitate the adhesion of the sugar ester compound of Example 3 in Table 5, that is, sucrose phthalic acid vinegar, to sucrose octaacetate as the sugar ester compound of the disaccharide. The pencil hardness and the durability of the polarizing plate were also good as in the case of Example 3. (Production of Liquid Crystal Display Device) The result of evaluation by attaching a polarizing plate using the film of the present invention to a liquid crystal panel was confirmed to be no difference from the Tpp film, and there was no problem in performance. It is understood that the obtained liquid crystal display device has excellent durability under high temperature and high humidity. [Simple diagram description] 〇 [Main component symbol description] None 0 69

Claims (1)

201139461 VII. Patent application scope: 1. A deuterated cellulose film, comprising: a plurality of sugar ester compounds having different degrees of vinegar substitution; and deuterated cellulose, wherein the above-mentioned deuterated cellulose has an ethyl sulfhydryl substitution degree of 27〇 or more and less than 2.95, and the sugar constituting the sugar ester compound is a disaccharide to a tetrasaccharide, and the average ester substitution degree of the above-mentioned sugar ester compound having a different degree of ester substitution is 62% to 94%, and the above-mentioned deuterated fiber In the above-mentioned sugar ester compound having a different degree of ester substitution in the film, the content of the sugar ester compound having an ester substitution degree of 75% or more is 80% or less, and the ester degree of ester is 35% to 5% by weight. The content of the compound is 5% to 30%. 2. The fluorinated cellulose film according to claim 1, wherein the sugar ester compound contains at least a fluorene ring or a hally sugar ring. 3. The cellulose-degraded cellulose film according to claim 1, wherein the sugar constituting the sugar ester compound is a disaccharide. 4. The cellulose-deposited cellulose film according to the invention of claim 1, wherein the sugar ester compound has at least one of a benzoyl group and an acetamyl group as 5, as in the patents _1 to 4 The deuterated cellulose film according to any one of the preceding claims, wherein the deuterated cellulose is cellulose acetate. 6. If you apply for a patent range! The brewing cellulose film as described in any one of item 4 has a phase difference. In the case of the bismuth fiber phase described in any one of claims 1 to 4, it is further prepared with Wei (4). 8. The fluorinated cellulose film according to claim 7, wherein the functional layer is a hard coat layer. 9_ A polarizing plate characterized by: a flute s if polarizer, and at least one bismuth cellulose film according to any one of claims 1 to 22. Οο — — — — 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶 液晶201139461 mentioned in the item IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the component symbols of this representative figure: None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None. 201139461 Revision date: July 18, 100 is the Chinese manual of 苐100112643. There is no scribe correction. Patent description of the invention (The format and order of this manual should not be changed at any time.] Please do not fill in the mark) ※Application number: j ※Application曰: id孓, I y ※Working PC classification: 1. Invention name: (Chinese/English) 醯化cellulose film, polarizing plate and liquid crystal display device/CELLULOSE ACYLATE FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY 2. Abstract: The present invention provides a transparency, moisture permeability and optical performance, and can improve the long-term stability of a polarizing plate under high temperature and high humidity when combined with a polarizer. Brewing cellulose film. The deuterated cellulose film is characterized by comprising a plurality of sugar ester compounds having different degrees of substitution, and deuterated cellulose, wherein the deuterated cellulose has a degree of substitution of 2.70 or more and less than 2.95, and constitutes the above. The sugar of the sugar ester compound is a disaccharide to a tetracool, and the average ester substitution degree of the polysaccharide derivative having different degrees of ester substitution is 62% to 94%, and the degree of ester substitution in the above-mentioned brewed cellulose film is Among the various sugar ester compounds, the degree of ester substitution is 75 ° /. The content of the above sugar ester compound is not more than 5, and the content of the sugar ester compound having an ester substitution degree of 35% to 50% is 5. /〇~ 30%. 201139461 Revision period: July 18, 100 is the Chinese manual No. 100112643. There is no underline correction. 6. Description of the Invention: [Technical Field] The present invention relates to a deuterated cellulose crucible, using the deuterated A polarizing plate of a cellulose film and a liquid crystal display device. In particular, the present invention relates to a deuterated cellulose film which is used as a polarizing plate protective film which can improve the durability of a polarizing plate under high temperature and high humidity in combination with a polarizing plate, and a polarizing film using the deuterated cellulose film. Board and liquid crystal display device. [Prior Art] The liquid crystal display device is an image display device that consumes less power and is space-saving, and its saturation is expanding year by year. Previously, the disadvantage of the liquid crystal display translocation is that the viewing angle of the display image is large, but the wide viewing angle liquid crystal mode such as the vertical alignment (... Alignment, VA) mode has been put into practical use, thereby requiring high quality such as television. The market for images or the market that is required to be installed in the outdoor market's demand for liquid crystal display devices is rapidly expanding. The basic configuration of the liquid crystal display device is such that a polarizing plate is provided on both sides of the liquid crystal cell. The polarizing plate is responsible for passing only the light of the deflecting surface in the fixed direction, and the performance of the liquid crystal display device is greatly affected by the performance of the polarizing plate. The polarizing plate generally comprises a polarizer and a transparent protective film. The polarizer comprises a polyvinyl alcohol film or the like which adsorbs iodine or a dye, and the transparent protective film is bonded to both sides of the front and back of the polarizer. The cellulose-deposited cellulose film represented by cellulose acetate is widely used as a protective film for a polarizing plate because it has high transparency and can easily ensure adhesion to polyvinyl alcohol used in a polarizer. In recent years, the actual situation is that when the liquid crystal display device is installed outdoors under high temperature and high humidity, the image of the high product f is also required, and the polarized light is required for the 201139461 correction period: July 18, 100 is the Chinese manual No. 100112643 The scratch-free correction of the protective film of the board improves the durability of the polarizing plate under high temperature and high humidity when combined with the polarizer. First, from the above viewpoints, the 醯$cellulose film generally used as a protective film for a polarizing plate requires high transparency (low turbidity), good moisture permeability (although high but not too low), and good optical properties. Previously it was adjusted to meet performance by adding a specific plasticizer. However, phosphates such as Triphenyl PhGsphate (TPP), which is a typical plasticizer, are sublimed in a drying step when filming a cellulose-coated cellulose film, and are attached to a manufacturing line. In addition to this problem, it is also required to use a plasticizer which does not use a phosphoric acid film, from the viewpoint of providing an environmentally-friendly polarizing plate protective film and a manufacturing method. In the case of the plasticizer which can be added to the cellulose fiber, various compounds are known, and the sugar and its derivative can be added as a plasticizer. For example, it is described in 2 that by providing galactose containing starch and carboxymethylcellulose = 2; a plasticizer, it is excellent in biodegradable physicochemical properties and the ring is simple. Jobs and Machines It is also known that plasticizers and derivatives thereof for use in cellulose membranes for optical films are suitable for the production of sweet and sour compounds in sugars and their derivatives. For example, in the patent document, the degree of use is 59.5% (the total thiol group is substituted with an ester of a sugar alcohol derived from a hexacarbase (a total of at least 5 sucrose of a sugar alcohol). Plasticizer. On 5 201139461 Revised flood season: July 18th, 2001, No. 100112643 Chinese manual, no underline correction, cellulose acetate with a degree of substitution of 2.5, using enzyme base 8% to 99% of the plasticizer obtained by S (refer to the literature [0032], [〇115], [0134]). In Patent Document 4, the degree of substitution with respect to the total base is described. For the deuterated cellulose of 2.1 to 2.7, a plasticizer obtained by esterifying all or part of the hydroxyl group of the saccharide is used, but it can be understood that the hydroxyl group of the sugar ester compound actually used is 100% esterified. Plasticizer (refer to the literature exemplifying compound 1 to exemplified compound 10, etc.). In Patent Document 5, several kinds of sugar ester compounds having different degrees of substitution are used for deuterated cellulose having a total thiol substitution degree of 2.7 to 2.95. Mixed to be used as a plasticizer, the above sugar ester compound is a partial esterification of a hydroxyl group of a monosaccharide to a trisaccharide A sugar ester compound (refer to the document [0393], exemplified by the compound 3 to the exemplified compound 6, the exemplified compound 9, and the exemplified compound 18' [Table 3] to [Table 6], etc. However, in these documents, substantially Only the use examples of the sugar ester compound having a relatively high degree of ester substitution are disclosed, and in particular, in Patent Document 5 in which several sugar ester compounds having different degrees of substitution are mixed, only the addition ratio of the sugar ester compound having a low degree of substitution is revealed to be very small. Further, in any of the literatures, there is no description of the relationship between the degree of total thiol substitution (particularly the degree of substitution of acetylation) of deuterated cellulose and the degree of ester substitution of sugar ester compounds. The example, that is, does not reveal the optimum combination of the degree of substitution of the thiol group of cellulose (especially cellulose acetate) with the degree of ester substitution of the sugar ester compound. In addition, in these documents, The durability of the polarizing plate under high temperature and high humidity when the obtained polarizing plate protective film and the polarizing plate are combined is studied. [Patent Document 1] Japanese Patent Laid-Open No. Hei 5-320418 No. 201139461 Date of revision: July, 100 Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. 2001-515285. [Patent Document 5] WO2009/031464, SUMMARY OF THE INVENTION [In the case of the present invention, the inventors of the present invention have been aiming at replacing or improving a plasticizer previously used such as triphenyl phosphate (TPP). In the compounds described in the above Patent Documents 2 to 5, the physical properties of the films obtained by combining these compounds with the degree of substitution of the ethyl acetate group of 2.7 or more and less than 2, 95 of the spinel fiber and the film of the film were examined. However, when the highly-substituted sugar ester compound described in Patent Document 2 to Patent Document 5 is used, it is not possible to obtain desired film physical properties such as transparency, moisture permeability, and optical performance, and high temperatures when combined with a polarizing plate. The polarizing plate under high humidity is also insufficient in durability, and further improvement is required. The purpose of the invention is to provide a cellulose acetate film which is excellent in transparency, moisture permeability and opticalness, and which can improve the high temperature enthalpy when combined with a polarizer. In addition, in order to solve the above problems, the inventors of the present invention have found that the polarizing plate of the cellulose-degraded cellulose film and the liquid crystal display device using the same have been found to be When the mixture of different degrees of substitution is made ============================================================================================== On the 18th of the month, the Chinese patent specification No. 100112643 has no scribe line to correct the durability of the polarized plate under wet. That is, the above problem is solved by the present invention having the following configuration. [1] A cellulose-deposited film comprising: a plurality of sweet and sour compounds having different degrees of ester substitution, and deuterated cellulose, wherein the above-mentioned deuterated cellulose has an ethylidene substitution degree of 2.7 G or more and less than 2 95. The sugar constituting the sugar ester compound is a disaccharide to a tetrasaccharide, and the average ester substitution degree of the plurality of sugar ester compounds having different degrees of ester substitution is 62% to 94%, and the cellulose film is contained in the cellulose oxide film. Among the various sugar ester compounds having different degrees of ester substitution, the content of the sugar ester compound having a degree of ester substitution of 75% or more is 8% by weight or less, and the content of the sugar ester compound having an ester substitution degree of 35% to 50% is 5% to 30%. [2] The cellulose-deposited film according to [1], wherein the sugar ester compound contains at least a sugar ring or a D-halose ring. [3] The cellulose-deposited film according to [1] or [2] wherein the sugar which becomes the mother nucleus of the above-mentioned sugar ester compound is a disaccharide. [4] The cellulose-degraded film according to any one of [1] to [3] wherein the above-mentioned sugar ester compound has at least one of a benzamidine group and an ethenyl group as an ester group. [5] The cellulose-deposited film according to any one of [1] to [4] wherein the deuterated cellulose is cellulose acetate. [8] The cellulose-deposited film according to any one of [1] to [5] which has a phase difference. [7] The cellulose-deposited film according to any one of [1] to [6] which further has a functional layer. ' ~ 201139461 is the first 〇〇m643 Chinese _ book without a line correction this revision date side of the year July 18 [8] such as [7] described in the cellulose film, wherein the above functional layer is hard coated Floor. [9] A polarizing plate is characterized in that it has a polarizing plate, and at least one film of the cellulose-deposited film according to any one of [1] to [8]. [10] A liquid crystal display device, comprising: a bismuth cellulose film according to any one of [1] to [8], or a polarizing plate according to [9]. According to the present invention, it is possible to provide a fluorinated cellulose film which is excellent in transparency, moisture permeability and optical performance, and which can improve the durability of a polarizing plate under high temperature and high humidity when combined with a polarizing plate. Further, by using the cellulose-degraded cellulose film of the present invention, it is possible to provide a polarizing plate of the present invention which can obtain a high-quality image even when placed outdoors under high temperature and high humidity, and a liquid crystal display of the present invention using the same [Embodiment] Hereinafter, the contents of the present invention will be described in detail. The description of the constituent elements described below may be performed based on a representative embodiment of the present invention, but the present invention is not limited to such an embodiment. In addition, in the present specification, "~" is used in the sense that the numerical values described before and after are included as the lower limit and the upper limit. [Sulphide cellulose film] The cellulose fluorite film of the present invention (hereinafter also referred to as the film of the present invention) is characterized by comprising a plurality of sugar ester compounds having different degrees of ester substitution, and deuterated cellulose, and the above-described deuteration The degree of substitution of the cellulose acetyl group is more than 2.95, and the sugar constituting the above sugar ester compound is a disaccharide to a tetradomain, and the average ester substitution of the plurality of sugar ester compounds having different degrees of ester substitution is 9 201139461. :1 July 18th, the Chinese manual of No. 100112643 has no underline correction, and the degree is 62% to 94%. Among the various sugar ester compounds having different degrees of ester substitution in the above deuterated cellulose film, the ester The content of the sugar ester compound having a degree of substitution of 75% or more is 80% or less, and the content of the sugar ester compound having an ester substitution degree of 35% to 50% is 5% to 30%. Hereinafter, the film of the present invention will be described. &lt;Deuterated cellulose&gt; In the present invention, deuterated cellulose having an ethyl ketone group substitution degree of 2.70 or more and less than 2.95 is used. When the degree of substitution of the ethyl group is 27 or more, compatibility with a sugar ester compound (e.g., sucrose benzoate having a specific degree of substitution) which satisfies the conditions described later is good, and the film is not easily whitened, which is preferable. Further, in addition to the transparency, the moisture permeability or the water content is also good, which is preferable. Further, the durability of the polarizing plate or the wet heat durability of the film itself is also good, so that it is preferable. On the other hand, if the degree of substitution is less than 2,95, the optical performance is remarkably improved, which is preferable. ‘ The above-mentioned deuterated cellulose has a degree of substitution of acetylation of 2 to 75 Å, particularly preferably 2.82 to 2.87. ‘Further, the preferred range of the degree of substitution of the total brewing base is also the same as the preferred range of the above-mentioned acetaminophen. Further, the degree of substitution of the thiol group can be determined according to the method of the method of ASTM_D817_96. The unsubstituted group is usually used as an auditory group and is substituted with a carbon number of 2 to 9 on the hydroxyl group of the cellulose, and a carbon number of 2 to 22, which may be an aliphatic group or a rabbit. Propyl, there is no special sputum, can be a single compound, can also be two kinds of 2 201139461 for the first measurement of the god Zhao Ridan _ 镰 赃 赃 赃 _ _ July 18th mixture. These may be, for example, an alkylcarbonyl ester, an alkenylcarbonyl ester or an aromatic carbonyl ester of cellulose, an aromatic alkylcarbonyl ester or the like, and each may have a group which is further substituted. Preferred examples of such a brewing group include an ethyl fluorenyl group, a propyl fluorenyl group, a butyl group, a fluorenyl group, a hexyl group, a decyl group, a fluorenyl group, a fluorenyl group, a thirteenth fluorenyl group, and a tetradecyl group. Base, hexadecanyl, octadecyl, isobutyl decyl, tributyl sulfhydryl, cyclohexyl carbonyl, oleoreyl, benzoyl, naphthylcarbonyl, cinnamyl and the like. Among these, preferred are an ethyl group, a propyl group, a butyl group, a decyl group, an octadecyl group, a tributyl sulfonyl group, an oil fluorenyl group, a benzamidine group, a naphthyl group, a cinnamyl group, and the like. More preferably, it is an ethyl acetate base, a glycerin base, and a butyl base. The cellulose fluorite film used in the present invention imparts hydrophilicity from the viewpoint of adjusting moisture permeability or water content, and therefore the substituent is preferably a substituent containing an ethyl aryl group. Further, as the mixed fatty acid-dyed cellulose, cellulose mixed with a fatty acid may be used, and specific examples thereof include cellulose acetate propionate and cellulose acetate butyrate. ” [4] (4) Basics of fiber surface synthesis method _ Residing in the wood chemistry compiled by Wada et al., 180 pages ~ 190 pages (Kyoritsu Publishing, 1968). A representative synthesis method is the use of several acid liver. Acetic acid _ sulfuric acid touch B When the above-mentioned deuterated cellulose is obtained, specifically, a cellulose raw material such as cotton linters or wood pulp is pretreated with an appropriate amount of acetic acid, and then poured into a pre-cooled lysified mixed solution for vinegarization. Synthetic fully brewed cellulose (the total base substitution degree of 2, 3 and 6 positions is approximately 3 〇〇). 201139461 Revision date: July 18, 100 is the revised version of the duck thin line in the number 〇0112643 The above-mentioned slow Ht* solution generally contains acetic acid as a solvent, a tickic acid if as a vinegar = and sulfuric acid as a catalyst. Fine (4) is usually used in an amount that exceeds the total amount of water present in the chemistry and the amount of cellulose and hydrazine reacted with it. The purpose of the S-reaction is to add money, in order to carry out the excess ship-hydrolysis and partial trades in (10), and add neutralizing agents (such as carbonate, acetate or per-, town, iron, or Oxide) water solution. Then, by saponification of the obtained whole sulphurized cellulose by the presence of a small amount of an oxime reaction catalyst (generally residual sulfuric acid), the saponification of the obtained whole saponified cellulose is saponified and changed to have the desired The degree of substitution of thiol and the degree of polymerization of deuterated cellulose. When the desired cellulose deuterated cellulose is obtained, the catalyst remaining in the system is completely neutralized by using the neutralizing agent as described above, or the deuterated cellulose liquid is put into water or without neutralization. Diluted sulfuric acid (or water or dilute sulfuric acid is put into the deuterated cellulose &gt; trough liquid) to separate the deuterated cellulose, and is washed, stabilized, etc., thereby obtaining the above specific deuterated cellulose. . The molecular weight of the above deuterated cellulose is preferably from 40,000 to 200,000, more preferably from 1,000,000 to 2,000,000, in terms of number average molecular weight (??). The Mw/Mn of the deuterated cellulose used in the present invention is preferably 4.0 or less, more preferably 1.4 to 2.3. In the present invention, the average molecular weight and molecular weight distribution of deuterated cellulose and the like are used to calculate the number average molecular weight (Mn) and the weight average molecular weight (Mw), and the weight average molecular weight (Mw) is determined by using G permeation Chromatography (GPC). The ratio of the two is calculated by the method described in International Publication WO2008-126535. 12 201139461 Date of revision: July 18, 100, stomach m 100112643 Chinese manual without sizing correction &lt;saccharide ester compound&gt; The film of the present invention contains a plurality of sugar ester compounds having different degrees of ester substitution, and constitutes the above-mentioned sugar ester compound The sugar is a disaccharide to a tetrasaccharide, and the average ester substitution degree of the plurality of sugar ester compounds having different degrees of ester substitution is ～, and the saccharide ester compound having a different degree of ester substitution in the fluorinated cellulose film is 酗The content of the sugar ester compound having a degree of substitution of 75% or more is the following, and the degree of ester substitution is from 35% to 50%. /. The content of the sugar ester compound is 5°/〇30〇/〇〇〇+. By adding the above sugar ester compound to the cellulose fluorite film, the optical properties of the crystal can be exhibited, and even if not In the case of heat treatment before the stretching step, the total turbidity and internal turbidity can also be reduced. Further, by using the brewed cellulose film of the present invention in a liquid crystal display device, the front contrast can be greatly improved. - Sugar residue - The above-mentioned sweet and sour compound means a compound in which at least one of a substitutable group (e.g., a hydroxyl group or a carboxyl group) in the polyacetate constituting the compound is ester-bonded to at least one substituent. Namely, the sugar ester compound herein also includes a broadly defined sugar derivative, and for example, a compound containing a sugar residue such as gluconic acid as a structure. Namely, the above sugar ester compound includes an ester body of glucose and a carboxylic acid, and also includes an ester of gluconic acid and an alcohol. The substitutable group in the polysaccharide constituting the above sugar ester compound is preferably a hydroxyl group. Among the above-mentioned sugar ester compounds, 'containing a structure derived from a polysaccharide constituting a sugar ester compound (hereinafter also referred to as a sugar residue). Each of the above-mentioned sugar residues 13 201139461 is the 100112112 Chinese manual without a slash correction. Date of revision: July 18, 100 The structure of the sugar is reduced to the composition of the (4) structural unit. Preferably, the fresh-keeping element of the above-mentioned sweet and sour compound comprises t-green nodule and no structural unit, and more preferably, the (four)-based is a material or a sugar element. Further, when the above sweet and sour vinegar is composed of a polysaccharide, it is preferred to contain a sucrose moiety or a furanose structural unit. The sugar residue of the above sweet and sour compound may be derived from a five-carbon vinegar, also a carbon sugar, but is preferably derived from a six-carbon sugar. ‘,’, 2 (II) The structural unit of the above-mentioned saccharide hybrid contains 2 to 3, particularly preferably 2. That is, the above-mentioned sweet and sour saccharide carcass is preferably a disaccharide to a tetrasaccharide, and more preferably a disaccharide. U is - axis to three laps, particularly preferably to f 'the above fine 1 compound is more preferably contained in 2 to 4 = (10): a pyranose structural unit or a furanose structural unit: sugar = 2 , ~ 4 monosaccharide units of sugar, such as threose, allose, A turn,, sugar, candy, arabinose, xylose, sugar, sucrose, galactose, t-mannose, Guluose, Hess n: Rosin, Hainan, Iso-trehalose, New Sea Isomalt, 16, Glucose, Aspergillus, Maltose, Maltitol, Lactoseamine, Gambling..s Fiber Double Sugar , bile disaccharide, lactose, onion disaccharide, melibiose, primrose, rutose, jellyfish, sucralose, sputum, sputum, gan-^ private sugar, ugly disaccharide, fiber trisaccharide, 14 201139461 is the Chinese manual No. 100112643 without a slash correction. Amendment date: July 18, 100, potato trisaccharide, gentian trisaccharide, isomaltotriose, isoglucosyl maltose, maltotriose, mannotriose , pine triose, pannoose, psyllium, raffinose, disaccharide, umbelliferous, lycopene, maltotetraose, stachyose, malt Sugar, sugar flowers Mao Ning, maltohexaose, xylitol, sorbitol and so on. Preferred are ribose, arabinose, xylose, lyxose, glucose, fructose, mannose, galactose, trehalose, maltose, cellobiose, lactose, sucrose, sucralose, xylitol, sorbitol, etc. Good arabinose, xylose, glucose, fructose, mannose, galactose, maltose, cellobiose, sucrose, especially xylose, glucose, fructose, mannose, galactose, maltose, cellobiose, sucrose, Xylitol, sorbitol. - Structure of Substituent - The above-mentioned sweet and sour compound used in the present invention more preferably contains a usable substituent and has a structure represented by the following formula (〇). Formula (1) (OH)pG-(L1-R11)q(〇-Ri2)r In the formula (1), G represents a sugar residue, and L1 represents -〇-, _c〇-, -NR13- Any one, R11 represents a hydrogen atom or a valence substituent, and r12 represents a valence substituent bonded by a hydrazone bond. p, q and r each independently represent an integer of 0 or more, and p + q + r is equal to the number of hydroxyl groups when the unsubstituted saccharide in which G is a cyclic acetal structure is assumed. The above-mentioned G Chen Jia's model has the same range as the above. The above L1 is preferably _〇_ or ·c〇_, more preferably _〇_. When the above l1 is VII·15 201139461 Revision date: July 18th of the following year is the 10011; Chinese manual No. 2643 is not drawn [[Line correction, especially the linkage derived from ether bond or ester bond] Further, it is particularly preferably a linking group derived from a vinegar bond. Further, when there are a plurality of L1's, they may be the same or different. It is preferred that at least one of R11 and R12 has an aromatic ring. In particular, when L1 is -0- (i.e., when R11 and R12 are substituted on the hydroxyl group in the above sugar ester compound), the above R11, R12 and R13 are preferably a self-substituted or unsubstituted fluorenyl group. The substituted or unsubstituted aryl group, or the substituted or unsubstituted alkyl group, the substituted or unsubstituted amine group, is selected to be more preferably substituted or unsubstituted perylene, substituted or unsubstituted. a substituted alkyl group, or a substituted or unsubstituted aryl group, particularly preferably an unsubstituted imidyl group, a substituted or unsubstituted alkyl group, or an unsubstituted aryl group. In addition, when R11, When there are a plurality of R12 and R13, respectively, they may be the same or different. The above p represents an integer of 〇 or more, and a preferred range is the same as the preferred range of the number of bases of each monosaccharide unit to be described later. Preferably, the above r represents a number larger than the number of n-the 晦 兀 or the number of the furanose structural units contained in the above G. Drying q is preferably 〇. Ϊ ' Since P + q + 1: is assumed to be a heterogeneous structure, the number of hydroxyl groups in the saccharide is equal, so the above p, q and ^ 2 limits 疋 correspond to the structure of G described above. Ground decision, base 16 2U1139461 Revision date: July 18th, 1st year is the first ______, ----^ 18 y number of alkyl groups 1~8, γ base, 2 · cyanoethyl, segment base Etc.), ^美3, two bases, ethyl, and propylene are 6~18, especially good for μ. The latter is 6~24, more base (preferably carbon number is phenyl, naphthalene) Base), 醯 = ~ _ base, for example, two are two numbers = particularly good for breaking hexyl group, octyl group, stupid base, = butyl group, aryl group, hydrazine, etc.), guanamine group (preferably The number of charcoal is 卜22, and the dimethyl dimethyl hydrazine group is preferably a carbon number of 2 to 8 and the number of 醯骇 彳 彳 41⁄4 is 2 to 12, etc., 醯 丝 (preferably carbon "4 to 22 m = amine Base 12, particularly preferably a carbon number of 4 to 8 is read as 4 to = imino group, etc.), wherein more preferably is a burnt base or = and = a = = is a benzoic heart = ❹ :咐#_平8:24=二=:=)(:2〇. Two=two comparison=the number average molecular weight is preferably more preferably 200~3000, It is preferably in the range of 250 to 2 Å. The specific examples of the above-mentioned sugar ester compound which can be preferably used in the present invention are listed. However, the present invention is not limited to the form of the town. The substituents of any of them can be independently represented, and the R can be (iv) or different. The value of clGgP is calculated by the calculation for the Chinese version of the Chinese version of the 2011. The value obtained by the common logarithm logP of the partition coefficient of alcohol and water on the 18th of the month. In the calculation of the ClogP value, the system of Daylight Chemical Information Systems is used: the CLOGP program in the PCModels is assembled. [Table 1] Compound Substituent 1 Substituent 2 Molecular Weight Species Degree of Substitution Degree Substitution Degree 101 Ethyl 7 Benzyl 1 727 102 Ethyl 6 Benzyl 2 775 103 Ethyl 7 Chamoryl 1 741 104 Ethylene Base 6 Stupid thiol 2 802 105 Benzyl 2 No 0 523 106 Benzyl 3 No 0 613 107 Benzyl 4 No 0 702 108 Ethyl 7 Phenylethyl 1 771 109 Ethyl 6 Styrene Base 2 847 110 Benzopyridinyl 1 None - 446 111 Stupid Amaranthin 2 No - 550 112 Stupid Amaranthin 3 No - 654 113 Benzoyl Brewing 4 None - 758 114 Benzopyridyl 5 None - 862 115 Benzene曱醯基6无- 966 116 Benzyl sulfhydryl 7 - - 1070 117 笨甲甲基8 No - 1174 18 201139461 For the 100112643 Chinese manual no underline correction This revision date: 1 July 18th [ 2] [Table 2] 化合物 Compound Substituent 1 Substituent 2 Molecular Weight Species Degree of Substitution Degree of Substitution Degree 301 Ethylene 6 Phenylhydrazyl 2 803 302 Ethylene 6 Benzyl 2 775 303 Ethyl 6 Phenyl Ethyl 2 831 304 笨甲醯基2 No 0 551 305 Benzyl 2 No 0 522 306 Phenyl Ethylene 2 No 0 579 [Chemical 3] 〇 19 201139461 Revision date: July 18, 100 is the Chinese manual No. 100112643 without a slash correction [Table 3] The sugar ester compound is preferably contained in an amount of 2% by mass to 30% by mass, more preferably 5% by mass to 2% by mass, and particularly preferably 5% by mass to 1% by mass to 5% by mass. . In addition, when the polyester-based plasticizer to be described later is used in combination with the above-mentioned sugar ester compound, the amount (parts by mass) of the sugar ester compound added to the amount (parts by mass) of the polyester-based plasticizer is preferably Add 2 times to 1 times (mass ratio), more preferably 3 times to 8 times (mass ratio). (Content ratio of sugar ester compound having different degree of ester substitution) In the present invention, 'containing a plurality of sweet and sour compounds having different degrees of substitution with vinegar, the degree of substitution of the above vinegar is not _ the average (four) degree of the compound of the compound is 62/〇 94/〇. By controlling the average ester substitution degree of the above sugar ester compound to such a range, the moisture content or moisture permeability of the hair __ can be reduced, and the durability of the polarizing plate durability of the cedar can be obtained. Further, it is preferable to control the degree of substitution of the sugar track _ average degree of substitution in such a range to be large. In the present invention, the degree of substitution of the ester contained in the cellulose-deposited cellulose film is different. 20 201139461 is the first sugar-ester compound of the first date of the revised date of July 18th. The content of the sweet and sour compound having an ester substitution degree of 75% or more is 80. /. The content of the sugar compound having the following ester substitution degree of 35% to 5% by weight is 5% to 30%. By controlling the content of each of the above-mentioned sugar ester compounds to such a range, the transparency of the film of the present invention can be maintained. The inventors of the present invention have found that a plurality of sugar ester compounds having different degrees of ester substitution contained in a cellulose phthalocyanine film having a high degree of substitution with respect to an acetyl group are found. When the content of the sugar ester compound having a high substitution ratio of Sa of 75% or more is 80% or more, the sugar ester compound tends to be incompatible with the deuterated cellulose and oozes out. In addition, the inventors of the present invention have not adhered to any theory, and found that if the average degree of vinegar substitution is in the above range, the degree of substitution is not _ a variety of sweet and sour compounds, 'quantity of money (four) is the degree of abdomen The low-substituent sugar S is a compound which has a compatibilizing ability of a low-substance, and the degree of substitution of the sweet and sour compound with the ethyl thiol group is high, and the capacity is improved, and the film can be prevented from being formed into a film. The ester compound oozes out. Further, when the sweet and sour compound is a diacetate, the average of the number 2 of the acetalized substituted two is 5 to 75 (five), and the content of the substituted substituent is 6 = 8 of the high-substituted product. The ratio is 8 (%) or less, and the content of the acetalized substituted soil and the ～4 substituents is 50/〇 to 30%. ^ (4) The degree of substitution of the compound is not _ recorded _ the average degree of substitution of the compound: broadcast two 95% ‘more preferably 65 to 85%. The average degree of substitution of the above-mentioned ester substitution degree is controlled within the above range, and each of the structures of the various types of sugars having different degree of substitution is used. 21 201139461 Revision period: July, 100 days For the Chinese specification No. 100112643, the average number of hydroxyl groups of the present invention 70 is controlled within a corresponding range. By controlling the average number of hydroxyl groups of each structural unit in the above-mentioned sugar ester compound, the movement of the sugar ester compound toward the polarizing plate layer under high temperature and high humidity with time, and polyvinyl alcohol (p〇lyVinyl Alc〇) can be suppressed. H〇卜pvA) The %L of the magnetic complex is bad, and it is preferable to suppress the performance of the polarizer under high temperature and high humidity with time. In the present invention, the content of the sugar ester compound having an ester substitution degree of 75% or more is preferably 40% to 80%, more preferably, in the plurality of sugar ester compounds having different degrees of ester substitution in the cellulose film. It is 55% to 75%. In particular, in the case of optical properties, water content, or moisture permeability, the content of the sugar ester compound having a degree of ester substitution of 75% or more among the various sugar ester compounds having different degrees of ester substitution in the cellulose film for deuteration To some extent, the higher the better. In the present invention, the content of the sweet and sour compound having a degree of ester substitution of 35% to 50% in the plurality of sugar ester compounds having different degrees of ester substitution in the cellulose film for deuteration is preferably 5% to 40%. More preferably, it is 1〇%~3〇〇/〇. A plurality of sugar ester compounds having different degrees of ester substitution satisfying the above conditions are combined with deuterated cellulose satisfying the above-described degree of substitution of the ethyl thiol group, whereby physical properties or optical properties of the film can be obtained, and durability of the polarizing plate can be obtained. A known phosphate ester compound such as Triphenyl phosphate (TPP) / Bisphenol-A bis (diphenyl phosphate) (BDP) is improved in comparison with the stomach of the stomach. The agent is more excellent. Further, when laminating with the hard coat layer, a film excellent in adhesion and excellent in pencil hardness can be obtained. 22 201139461 ϋΐΕ曰期: July 18th, 1st, is the Chinese manual of No. 100112643. There is no slash correction (method of preparing various sugar ester compounds with different degrees of ester substitution) as a mixture of various sugars with different degrees of ester substitution. The method of the ester compound is not particularly limited, and a known method can be used. In addition, the mixing time of a plurality of the above-mentioned sugar ester compounds having different degrees of vinegar substitution may be, for example, in the case of using a solution film forming method, or may be added to the cellulose halide dopant before the addition of the cellulose halide dopant. After the addition of various sweet and sour compounds individually. σ 〇〇 &lt;Other additives other than the sugar ester compound&gt; (1) Plasticizer other than the sugar ester compound The brewed cellulose film of the present invention preferably contains a polycondensation agent selected from the group consisting of polyhydric alcohols and polycondensation agents. At least one type of hydrophobizing agent in the ester-based hydrophobizing agent and the carbohydrate-derivative agent is used as the above-mentioned water-salt compound, and 17 Hr is hydrophobic as described above, and it is preferable to reduce the glass of the film as much as possible to reduce the rotation. By. By making the limb hydrophobizing agent, the phenomenon of polarization of the added axis of the towel can be improved under the condition of high temperature and high humidity, and the deterioration of the performance of the polarizer can be improved. Erkiwen (Polyol ester-based hydrophobizing agent) The above polyol is represented by the following formula (A). R31-(OH)n of the formula (A) (wherein R31 represents an n-valent organic group, and η is bombarded with 7^μμ of an integer) η represents a positive of 2 or more as a preferred polyol-based hydrophobizing agent For example, it can be listed as 23 201139461. The revised period: July 18, 2010 is the 100112643 Chinese manual without the following lines, but is not limited to these. For example, fumarin, arabitol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, 1,3-propanediol, dipropylene glycol, tripropylene glycol, butylene glycol, 1,3-butanediol, 1,4-butanediol, dibutylene glycol, hydrazine and butyl tributol, 0 pentanediol, 1,6-hexanediol, hexanetriol, galactitol , mannitol, 3-methylpentane-1,3,5-diol, pinacol, sorbitol, trimethylolpropane, triterpene, xylitol, and the like. Particularly preferred are triethylene glycol, tetraethylene glycol, dipropanol, dipropylene glycol, sorbitol, tris-propylpropanol, xylitol. As the above-mentioned polyol "hydrophobizing agent, it is preferred to use a polyhydric alcohol having a carbon:' or a polyhydric alcohol of 5 or more. Particularly preferred is a carbon number of 5 to 20. There is no particular limitation on the use of #单叛酸in the above-mentioned alcoholic vinegar, and it is not limited to the single-use ri, the alicyclic single ah, the aromatic aliquot, and the aromatic moisture permeability. A good aromatic single-acid acid 'is a list of the two _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ , ~Η) =1 chain fatty acids. More preferably, the carbon number is 1~, and the special 3 has acetic acid, and the compatibility with the cellulose derivative is added. Therefore, the acetic acid is mixed with other monocarboxylic acids to be used. Family single button, can be listed as: acetic acid, propionic acid 'burned citric acid, ten acid, moon acid, tannic acid, citric acid, 2-ethyl _ palmitic acid, ten + cabin lauric acid, tridecanoic acid , myristic acid, pentadecanoic acid, heptadecanoic acid, stearic acid, nineteen acid, arachidic acid, two 24 201139461 Revision date: July 18, 1st, the Chinese manual for the 1001丨2643 no line correction Saturated fatty acids such as tetradecanoic acid, citric acid, twenty-seven acid, octadecanoic acid, honey, and myric acid, undecylenic acid, oleic acid, sorbic acid, linoleic acid, linoleic acid, peanut oil Unsaturated fatty acids such as acids. Preferred examples of the above alicyclic monocarboxylic acid include calcined acid, cyclohexanol, cyclooctene, or derivatives thereof, and preferred aromatic monocarboxylic acids. In the case of the benzene ring of benzoic acid, such as acid benzoic acid, it is exemplified: acid, naphthalene, tetrahydronaphthalene or the like having two or more monocarboxylic acids, Or derivatives of these, but particularly preferred is benzoic acid. The molecular weight of the above polyhydric alcohol-based hydrophobizing agent is not particularly limited, and is preferably 300 to 3 Å'. The larger the molecular weight, the harder it is: hair, so it is preferable, as far as the moisture permeability and the compatibility with the cellulose derivative are concerned, the smaller the better. The carboxylic acid used in the above polyol vinegar may be one type or a mixture of the above. Further, all of the above-mentioned polyols may be subjected to two kinds of groups, and a part of them may be left in a state of a hydroxyl group. 9' Also, the specific compound of the above polyol ester is shown below. 25 201139461 Revision period: July 18th, the first paragraph of the Fool 12643 Chinese manual without a slash correction [4] C4H9 -C - 0 - (CHj-h - Ο - {CKs] f2**- 〇M (CHsJg ~ C-C4H9 Ο Ο C-〇-(CH2)2-〇--{CH2b*-CI-*(€H2)2-〇-0 δ ο 0*0—(CHa)2~〇 —(CH2b~*〇~(^Hl232~&quot;C&gt;-C·-/ 〉 Ο Ο ^一^' 3 / \ 5. continent 1-. inch €^叫-.沄5_(:义0 〇5 C^7-CQ^CHt-CHt-a^-CC%Hn Ο 〈7< /~ loan &quot;TM〇--CH Guang 0): It-<> Ο Ο X~/ S / \~C^〇 4^CH2CH2CH2-〇*Vc~4 \ \ / it V Λ /3 ΙΪ \ / Ο Ο 9 - O^CHjCHaCH^-'O^-'-C- Ο 3 ο 1〇 caH17-r〇4cH2〇H2CH2^〇)rC-C8Hl7 Ο 11 ( V-c -〇~^CH2CH2CH2-〇 \-f 〇 Ch3 οOf C_ο ten ch2ch—ο 0 Λ I «&gt; ch3 26 15 201139461 For the Chinese manual No. 100112643, there is no slash correction. The date of this amendment is: July 18, 1 [5] 16 17 ch2~oou CHt-〇-C-C4H9 -〇_/Λ CH3CH2_ Let a GHjj ^OC—g4h$ I 〇ch2 Leak o-c-*c4h&amp; o 18 O CH2-〇-C-C8H17 CHaCH2-C*-C«2-〇-C-(3⁄4)1⁄2I 〇CH^*-*〇 -C—CeHir O 19 O y,(HX CHsCHj-C-CHz-OC—/ \ 0 ch2-o- 20 CHaCHi-C-CHi^O -C * CH3 O 21 GHg O ch2-o-c-( y CI^CH2-C-CH2 CH^-O-C-CHa II o ch2-o-c II o .-r〇-o twenty three CHa-OH 27 201139461 is the Chinese manual of the fool 12643 without a slash correction. Date of revision: July 18, 1 [Chem. 6] 28 201139461 Revision period: July 18th, 1st, July, 100112643 Chinese manual, no underline correction [Chemistry 7] 30 <^&gt;-co-{ch2-〒 H-CH2«O 沴c»o ό 〇 32 ο c-o-(ch2-ch2-chz*-o^— 34 仏―2trK) 〇 35 C-〇&quot;(cH2-CH~CH2-〇^~-C--/^\ Ο 〇«aas/co ο (polycondensation ester-based hydrophobizing agent) The above polycondensation ester-based hydrophobizing agent And the at least one average carbon number of the dicarboxylic acid (also known as the aromatic is obtained from at least one of the aromatics 29 201139461 revised date: July 18, 100 for the 1st GG112643 lion Wenshu book fine line corrected for the diol In addition, from the mixture of aromatic dibenzoic acid to &gt; - a kind of secret group, t is 2.5~8.0_difficult to obtain the calculated residue of the average of the diols The value calculated by multiplying the composition ratio of the dicarboxylic acid residue by two is an average carbon number. For example, when the leather is composed of a ruthenium ruthenium residue and a phthalic acid residue, the average carbon is used. The number is changed to °, and the diol residue is also the same. The number of char carbons is set to a value obtained by multiplying the composition ratio of the diol residues (the molar fraction is multiplied. For example, when 50:$ constitutes 50 mils of carbon) When the % u propylene glycol residue is composed, the number average molecular weight of the condensed condensed vinegar is preferably 5 〇 ^ = 〇, 2 is 6 G0 丨鄕 丨鄕, More preferably, it is 7 (9) ~ 'clearing low-yield cellulose _ when extended, under high temperature conditions =, barrier or step contamination. In addition, if the film is caused by 2, the compatibility becomes high: Membrane time and heating extension 2: The normal molecular weight of the vitamin can be obtained by gel permeation chromatography; the w′ of the flat end unblocked polyphenol polyol is calculated from the amount of the hydroxyl group of the average weight of 1) In the book towel, the amount of potassium hydroxide required for the neutralization of the acetic acid after the addition of the polyol:) base 30 201139461 is the first face 2643 __ 赃 赃Fine-acting year 7 ribs acid formation: a mixture of aliphatic and diacids is used as the second nucleus of diterpene, and the average carbon number of the ίίί component is 5.5 to 1 〇.0 Α, and the average of the number is 5 5 or more. Then, an average of 10 or less can be obtained, and the production of bleed out can be suppressed during the process of forming a film with a whitened cellulose. ο _, ===: The second of the acid is obtained. 'The so-called residue refers to the partial structure of the characteristic of the monomer of the polycondensed vinegar such as 疋2' into vinegar. Example-OC-R-CO- 〇...(2)H The residue is an aromatic dicarboxylic acid residue of the above polycondensation ester having a ratio of m〇1/° or more, more preferably 40 m〇1% to 95 m〇1%. Η 40 is set to 40, and is durable. Excellent partiality = each = sex = = film 'and can be obtained when heat is extended:; = can be made into a brewing cellulose film · Carboxy:::: upper condensed condensed vinegar-based hydrophobizing agent Examples of the formation of aromatic j can be exemplified by: phthalic acid, terephthalic acid, phthalocyanine, quinone, 1,5-naphthalene diwei, hinsai 曰ben~, Ben-曱qi, 2,6-naphthalene Diterpenic acid, more preferably as stearic dicarboxylic acid, on stupid two 31 201139461 Amendment date: July 18, 100 is the 100112643 Chinese manual without a slash correction of this tannic acid, and thus more preferably terephthalic acid. Acid: Forms a scented diterpene acid residue derived from the aromatic dibenzoic acid used for mixing. The above-mentioned aromatic di-nucleus residue preferably contains at least one of an ortho-dicarboxylic acid residue basic dicarboxylic acid residue and an isophthalic acid residue, and j is preferably. One of the phthalic acid-containing residue, the p-dicarboxylic acid residue, and more preferably the terephthalic acid residue. By the formation of the above-mentioned polycondensed vinegar, the ruthenium can be made into phase with the brewed cellulose, and the cellulose can be used as the heating material, and the raw material can be used. The two kinds of aromatic diterpenoids of dicarboxylic acid and terephthalic acid are softened by the polycondensation vinegar at room temperature, and it is preferable from the viewpoint of easy handling. The content of the terephthalic acid residue in the dicarboxylic acid residue of the above polycondensation ester is preferably 40 mol% to 1 〇〇 mQl%. By setting the terephthalic acid residue ratio to 4 〇 mol% or more, a cellulose film exhibiting sufficient optical anisotropy can be obtained. The polycondensate t obtained from the diol and the dicarboxylic acid containing an aliphatic dicarboxylic acid contains an aliphatic dicarboxylic acid residue. The aliphatic dimer & ', which is formed by the above-mentioned polycondensation ester-based hydrophobizing agent, for example, oxalic acid, malonic acid, succinic acid, maleic acid, 32 201139461 Revision date: July 1st On the 18th, the 1st GG112643 towel textbook revised the reverse line: enedic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecane dicarboxylic acid or 1,4-cyclohexanedicarboxylic acid or the like. The aliphatic dicarboxylic acid residue derived from the aliphatic dicarboxylic acid used for mixing is formed in the polycondensation ester. The average carbon number of the aliphatic diterpenic acid residue is preferably 5.5 to 1 〇. 〇, more preferably y. 5 8.0, and still more preferably 5 5 to 7 〇. When the average carbon number of the aliphatic dibenzoic acid residue Ο 为 is 1 〇. () or less, the heating loss of the compound can be reduced, and the occurrence of the planar failure due to the bleed out when the brewing cellulose web is dried can be prevented. . Further, when the aliphatic group 2 = ^ is not more than 5.5, the compatibility is excellent, and precipitation of the polycondensed vinegar is less likely to occur, which is preferable. The residue has two 3 groups of lipids: the group of two groups of fibers preferably contains an acid group. In the case of seeding, it is preferable to use a mixture of a succinic residue and adipic acid residue P in the case of forming a polycondensation S, and it is also possible to use two or more types in one broadcast, and when two types are used, In the mixing, the use of two kinds of acid and the second is equal to the desired value. In the mixture of the two phases of the deuterated cellulose ==:!, it is preferred to use two or three kinds of acids and aromatics. Acid, using each type of aliphatic dicarboxylic acid and two aromatic two = use;; two can use - an aliphatic two (four), or _ aliphatic two Wei and one 33 201139461 Revision date: 100 years 7 On the 18th of the month, the 1st GG112643 towel textbook fine line revised the 1 fragrant dicarboxylic acid. The reason for this is that it is easy to adjust the value of the average number of slaves of the dicarboxylic acid residue, and the content of the aromatic dicarboxylic acid residue can be made into a preferable range and the durability of the polarizer can be increased. In the polycondensation obtained from the diol and the dicarboxylic acid containing a dicarboxylic acid, a diol residue is contained. In the present specification, the diol residue formed by the diol HO-R-OH is a diol which forms a polycondensation, and examples thereof include an aromatic diol and an aliphatic diol, and the above hydrophobizing agent is used. The polycondensation ester used is preferably formed of at least an aliphatic diol. Preferably, the polycondensation ester of the p-heteropoly is a fat residue comprising an average carbon number of 2·5 to 7·〇, and more preferably an aliphatic second earth having an average carbon number of 2.5 to 4·°. The average carbon number of the above aliphatic diol residue is less than 7 〇, the compatibility of the j-cellulose is improved, and it is less likely to cause bleed out. Further, the average carbon number of the alcohol residue is 25 or more, and the synthesis is easier. . As an aliphatic diol which can form the above-mentioned polycondensation ester-based hydrophobizing agent, a mercapto diol or a trans diol is exemplified as a preferred example, for example: Glycol, propylene glycol, u-propylene glycol, butanediol, 13-I-alcohol, 2-methyl-1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 2'2_^ Mercaptopropanediol (neopentyl glycol), 2,2-diethyl-u-propanediol 〇'3_dimethylpentyl, 2-n-butyl-2-ethyl-U-propanediol (3『1 Red methyl ketone), 3-methyl], 5 pentanediol, i, 6 hexanediol, ^ from 34 201139461 is the 100112643 Chinese manual without scribe correction # Revision date: 1 year 7 On March 18, tridecyl-1,3-pentanediol, 2-ethyld-tris-hexanediol, 2-methylglycol, 1:9-nonanediol, U0-decanediol, U2^8 Alkanediol, 'diethylene glycol, hexane hexane dimethanol, and the like. These are preferably a mixture of two or more kinds. Further, the above-mentioned aliphatic diol is preferably ethylene glycol, and propylene glycol, at least one of the alcohols, particularly preferably ethylene glycol, and two kinds of the above aliphatic diols formed of propylene glycol. The above polycondensation iV C - if ] Λ ; yeast, and diol. The crystallization of the polycondensation vinegar is prevented by using 1, alcohol or propylene glycol. In the above polycondensation I, the above-mentioned polycondensation is preferably carried out as a diol residue including at least one of an ethylene glycol residue, a propylene terephthalate and an upper 3-propanediol residue. More preferably, it is an ethyl alcohol residue or a 1,2-propanediol residue. 2, preferably, in the above-mentioned heterozygous g, the aliphatic group II group is preferably K K1 m % 1% to 100 mol % of the ethylene glycol residue, more preferably 2 〇 mol% to 1 〇〇 mol %. The terminal of the above polycondensation ester may be directly blocked as a diol or a tracing acid, or may be blocked by a single sand or a single yarn. + as a single type of the end of the seal, preferably acetic acid, propionic acid, butyric acid, orthoformic acid or the like. As the monomer for blocking, it is preferably a material, ethanol, butanol, isobutanol or the like, and most preferably methanol. If the carbon number of the mono-type of the polycondensation St Γ is 7 or less, the heating minus 1 of the compound does not increase, and no planar failure occurs. 35 201139461 For the Chinese manual No. 112643, there is no slash correction. 1 ϋϊΕ曰 :: July 18, 1 ,, 〆丄. i W flat / month _! δ mouth f-acetic acid or propionic acid at the end of the above polycondensation ester or stupid = seal: the same = the end of each end is not limited to the end of the implementation of the presence or absence of vinegar = _ both ends are not carried out At the end of the capping, the polycondensation (four) is polycondensed as the above-mentioned polycondensation cool & base carbon number = = f diol diol residual condensed ester. And it is preferred to make it with a monocarboxylic acid residue when the end of the poly (4) end of the silk is capped.于:丁说f:金: When the two ends of the polycondensate ester become a monocarboxylic acid residue, H i is blocked by a single row formed by the acid R-C00H, the above mono-! The two ends are in the form of two == two aliphatic aliphatic acid groups, and furthermore: 2" on the aliphatic monoterpenes two nj I additionally 'preferably a carbon number monocarboxylic acid residue. ^ Particularly preferred is an aliphatic group having a carbon number of 2 as a polycondensation-based group having a carbon number of more than 2.5 and a ninth, which may be exemplified by a polycondensation ester of an aliphatic diol residual monocarboxylic acid residue. The number of carbons of the mono-group terminated by the end of the polycondensation ester from the end of 3 Ϊ = = 不会 is not caused by the heating of the step (4) or the occurrence of a planar failure. 36 201139461 For the first time] No. 2643 Chinese manual without line correction This revision date: July 18, 100 is 'as a monocarboxylic acid for capping, == is:, :: 22_family === Carboxylic acid residue. It is known that the early New Year's is a vine with a carbon number of 2: two are acetic acid, propionic acid, butyric acid, benzoic acid and its derivatives, etc., and more preferably acetic acid or propionic acid, preferably acetic acid. . The monocarboxylic acid used for blocking may be mixed in two or more types. Preferably, the ends of the condensed condensed vinegar are capped with acetic acid or propionic acid, and the most acetic acid is capped such that the two ends become ethyl acetonitrile residues (sometimes referred to as ethylenic residues). When the both ends of the above-mentioned polycondensed vinegar are blocked, it is possible to obtain a cellulose-deposited cellulose film which is less likely to be in a solid shape and has a good operation, and which is excellent in moisture stability and durability of a polarizing plate. The specific example of the above polycondensation is described in Table 4 below, but is not limited thereto. 〇37 201139461 is the Chinese manual No. 100112643 without a slash correction. Amendment date: July 18, 1 [Table 4] Dicarboxylic acid diol terminal aromatic dicarboxylic acid aliphatic dicarboxylic acid dicarboxylic acid (Mo Ear ratio) diol 1 diol 2 diol ratio (mole ratio) A-1 TPA SA 45/55 ethylene glycol propylene glycol 45/55 ethoxylated ester group A-2 TPA SA 50/50 ethylene glycol propylene glycol 45 /55 Ethyl ester group A-3 TPA SA 55/45 Glycol propylene glycol 45/55 Ethyl ester group A-4 TPA SA 65/35 Ethylene glycol propylene glycol 45/55 Ethyl ester group A-5 TPA SA 55/45 Glycol Propylene Glycol 25/75 Ethyl Ester A-6 TPA SA 55/45 Glycol Propylene Glycol 10/90 Ethyl Ester A-7 2,6-NPA SA 50/50 B Glycol Propylene Glycol 45/55 Ethyl Ester A-8 2,6-NPA SA 50/50 Ethylene Glycol Propylene Glycol 45/55 Ethyl Ester A-9 ΤΡΑ/ΡΑ SA 45/5/50 Ethylene Glycol Propylene glycol 45/55 Ethyl acetate A-10 ΤΡΑ/ΡΑ SA 40/10/50 Ethylene glycol propylene glycol 45/55 Ethyl thiol A-11 TPA SA/AA 50/30/20 Ethylene glycol propylene glycol 45 /55 Ethyl decyl ester A-12 TPA SA/AA 50/20/30 Glycol propylene glycol 45/55 Ethyl amide Ester A-13 TPA SA 50/50 Ethylene Glycol Propylene Glycol 25/75 Ethyl Ester A-14 TPA SA 55/45 Ethylene Glycol Propylene Glycol 45/55 Ethyl Ester A-15 TPA SA 55/45 Ethylene glycol cyclohexane dimethanol 45/55 Ethyl ester group A-16 TPA SA 45/55 Ethylene glycol propylene glycol 45/55 Hydroxy A-17 TPA SA 50/50 Ethylene glycol propylene glycol 45/55 Hydroxy A- 18 TPA SA 55/45 ethylene glycol propylene glycol 45/55 hydroxyl A-19 TPA SA 65/35 ethylene glycol propylene glycol 45/55 hydroxyl A-20 TPA SA 55/45 ethylene glycol propylene glycol 25/75 hydroxyl A-21 TPA SA 55/45 Glycol propylene glycol 10/90 Hydroxy A-22 2,6-NPA SA 50/50 Ethylene glycol propylene glycol 25/75 Hydroxy A-23 2,6-NPA SA 50/50 Ethylene glycol propylene glycol 25/ 75 Hydroxy A-24 2,6-NPA SA/AA 45/5/50 Ethylene Glycol Propylene Glycol 25/75 Hydroxy A-25 2,6-NPA SA/AA 40/10/50 Ethylene Glycol Propylene Glycol 25/75 Hydroxyl A-26 TPA SA/AA 50/30/20 Ethylene glycol propylene glycol 25/75 Hydroxy A-27 TPA SA/AA 50/20/30 Ethylene glycol propylene glycol 25/75 Hydroxy A-28 TPA SA 50/50 Ethylene Alcohol propylene glycol 25/75 Hydroxy A-29 TPA SA 55/45 Ethylene glycol propylene glycol 25/75 Hydroxy A-30 TPA SA 55/45 Ethylene glycol ring Alkanediethanol 25/75 Hydroxy A-31 TPA SA 55/45 Glycol Propylene Glycol 45/55 Propyl Ester A-32 TPA - 100/0 Ethylene Glycol Propylene Glycol 50/50 Hydroxy A-33 TPA - 100/ 0 ethylene glycol propylene glycol 40/60 ethyl decyl ester group A-34 TPA SA 50/50 ethylene glycol propylene glycol 45/55 benzhydryl ester group PA: o-benzene succinic acid, the abbreviations in Table 4 above indicate the following compound of. Diterpenic acid, TPA: terephthalic acid, AA: adipic acid, SA 38 201139461 Revision date: 1 (five) July 18th is the 1001Π643 Chinese manual without a slash correction 2,6 to break into .2, 6-Cai II is rebel.合成 The synthesis of the above polycondensation ester can be easily synthesized by any one of the following methods: a polyesterification reaction of a diol with a dicarboxylic acid by a usual method or a thermal fusion condensation method using a transesterification reaction Or an interfacial condensation method of the acid gas and the glycol. In addition, the above-mentioned polycondensed vinegar is detailed in Yuki Takashi, editor of "The Theory and Application of Plasticizers" (Kyosuke Co., Ltd., published on the first edition of March 1, 2008). In addition, Japanese Patent Laid-Open No. 5_1558〇9, Japanese Patent Laid-Open No. Hei 05.155810, Japanese Patent Laid-Open No. Hei No. 5_197〇73, Japanese Patent Laid-Open No. 2006-259494, Japanese Patent Laid-Open No. Hei 7_33素材67〇, Japanese Patent Laid-Open No. Hei 2-6-342227, and Japanese Patent Laid-Open Publication No. 2007-003679, etc. The amount of the hydrophobizing agent added is preferably from 5% by mass to 2% by mass based on the amount of the deuterated cellulose. When the content is 1% by mass or more, the effect of improving the durability of the polarizer is easily obtained. Further, if it is 2% by mass or less, bleeding is hard to occur. A more preferable addition amount is 2% by mass to 15% by mass, and 5 parts by mass / 〇 to 15% by mass. There is no particular limitation on the time at which the hydrophobizing agent is added to the cellulose fluorite film at the time of film formation. For example, when the cellulose is synthesized at the time of synthesis, it is also possible to prepare a mixture of the dopant 睥 and the brewed cellulose. (2) The film of the invention may also contain a retardation agent. A higher Re reproducibility is obtained with a low stretch ratio by using a delayed developer. Delayed appearance 39 201139461 is the Chinese manual of No. 100112643. There is no underline correction. The date of this correction is not limited to the type of the agent on July 18, 1 (8). The inclusion of a rod-shaped or disc-shaped compound or the above-mentioned non-filled acid ester is not particularly limited. Among the compounds of the system, compounds exhibiting delayed development are exhibited. As the rod-like or disc-shaped compound, a compound having at least two aromatic rings can be preferably used as the retardation-developing agent. Two or more kinds of delayed development agents may also be used in combination. The I late development agent preferably has a maximum absorption in a wavelength region of from 250 nm to 400 nm, and preferably has substantially no absorption in the visible region. As the retardation-developing agent, for example, the compounds described in JP-A-2002-50516 and JP-A-H07-86748 can be used, but are not limited thereto. And the compound described in the specification of the European Patent Application No. G911656A2, and the triazine compound described in Japanese Patent Laid-Open No. 3-344655, Japan No. 8 ff-like compound can be used, for example, in the form of a rod as described in Japanese Patent No. 3,344,655, No.: _ _ _ __7: (3) Acrylic polymer in the present invention _ chemical fiber Yucai, the village into the weight plus average 40 201139461 for the 100112643 Chinese said the sun and the moon book without a slash correction this revision period: turn July 18 molecular weight is 500~1 〇, 〇〇〇 acrylic polymer. Preferably, the weight average molecular weight is from 500 to 5,000. When the acrylic polymer is added, the cellulose-deposited cellulose film after the film formation is excellent in transparency and extremely low in moisture permeability, and exhibits excellent performance as a protective film for a polarizing plate. As the acrylic polymer, a compound described in WO 2008-126535 can be preferably used. (4) Antioxidant and heat deterioration inhibitor ❹ a In the present invention, as the antioxidant and the heat deterioration inhibitor, a known antioxidant or a heat deterioration inhibitor can be used. In particular, an internal vinegar, a sulfur, a phenol, a double bond, a hindered amine or a phosphorus compound can be preferably used. As the above-mentioned antioxidant and heat-resistant deterioration agent, the compound described in International Publication WO2008-126535 can be preferably used. (5) Colorant In the present invention, a colorant can also be used. The coloring agent means a dye or a color. In the present invention, it means an effect of changing the color tone of the liquid crystal surface to a blue color, or having an effect of adjusting the yellowness index and reducing the haze. Regarding the above-mentioned coloring agent', the compound described in the publication of International Publication No. WO 〇8_丨26535 can be preferably used. (6) Microparticles, as the microparticles used in the present invention, examples of the inorganic compound may be: cerium oxide, titanium dioxide, aluminum oxide, zirconium oxide, calcium carbonate, stone, clay, calcined kaolin, calcined tannic acid Calcium, hydrated calcium citrate, bismuth aluminum, magnesium citrate and calcium phosphate. The microparticles are preferred for the purpose of reducing turbidity, and are particularly good. 201139461 Revision date: July 1st, July j8 is the Chinese manual of No. 100112643. The average particle diameter of the primary particles of the microparticles is preferably from 5 nm to 5 Å, more preferably from 7 nm to 20 nm. These fine particles are preferably mainly contained as secondary aggregates having a particle diameter of 0.05 μm to 0.3 μm. The content of the fine particles in the cellulose derivative film is preferably 〇% by mass to 1% by mass, particularly preferably (U% by mass to 5% by mass). The cellulose derivative film of the multilayer structure by the co-casting method is used. In the case, it is preferred that the surface contains the added amount of fine particles. For the fine particles of the dioxide, for example, Aerosil R972, R972V, R974, R812, 200, 200V, 300, R202, 〇Χ5〇, TT600, NAX50 (above) Microparticles which are commercially available under the trade name of Japan Aer〇sil (share). For the oxidized microparticles, for example, commercially available microparticles under the trade names of Aerosii R976 and R811 (above, manufactured by Japan Aerosil Co., Ltd.) can be used. Examples of the polymer include an anthracene resin, a fluororesin, and an acrylic resin. Preferred are an anthracene resin, particularly preferably a three-dimensional network structure, and for example, Tospearl 103, Tospearl 105, Tospearl 108, Tospearl 120, Tospearl 145, Tospearl 3120 and Tospearl 240 (above the trade name of Toshiba Silicones (share)). Among them, Aerosil 200V, Aerosi l R972V is particularly good for keeping the turbidity of the cellulose street biofilm low and reducing the friction coefficient. (7) Other additives 42 201139461 Correction period for the first leg 3: 100 In addition to the above-mentioned compounds, the brewing cellulose film used in the present invention may contain an additive which can be added to a normal fluorinated cellulose film. Examples of the additives include ultraviolet rays. An absorbent or the like. For the other additives described above, a compound described in WO-A-2-8536535 can be preferably used. &lt;Manufacturing Method of Deuterated Cellulose Membrane&gt; The method for producing the cellulose-deposited cellulose film of the present invention is not particularly limited, and a known method can be used to prepare a specific method. The molten film is formed into a film containing the upper lysine. In view of improving the planar shape of the film, the method for producing a film of the present invention preferably comprises the step of coating a film of the above-mentioned cellulose-dyed film with a smear-casting method. Hereinafter, a method for producing a film of the present invention will be described by taking a case where a solution washing and film forming method is used as an example. However, the present invention is not limited to the solution washing film forming method. Further, a known method can be used as the method of producing the film of the present invention by using the above-described melt film forming method. 〇 (Polymer solution) In the solution washing and film forming method, the above-mentioned brewed cellulose or, if necessary, each of the _plus-polymer solution (cellulose solution) is used to form a net. Hereinafter, a polymer solution (hereinafter, sometimes referred to as a deuterated cellulose solution) which can be used in a solution washing and film forming method will be described. (Solvent) The deuterated cellulose used in the present invention is dissolved in a solvent to form a dopant, and then it is washed and cast on a substrate to form a film. Since it is necessary to be here 43 201139461 Amendment date: July of the 100th! 8th The Chinese manual No. 100112643 is not slashed to correct the % extrusion or evaporation of the solvent after casting, so it is preferable to use a volatile solution sword. Further, it is a solvent which does not react with a reactive metal compound or a catalyst, and does not dissolve the washing substrate. Further, two or more solvents may be used in combination. Further, the reactive metal compound capable of undergoing hydrolysis and polycondensation with deuterated cellulose may be dissolved in another solvent and mixed. Here, the organic solvent having good solubility to the above-described deuterated cellulose is referred to as a good one. In addition, the main effect will be exhibited in the dissolution towel, and a large amount of (4) money-soluble surface-based (money) solvent is used therein. Or (organic) solvent. (4) Examples of good solvents, except for _, methyl meth, ring oxime, cyclohexanone, etc., Tetrahydr〇furan, 1'4_ chew, 1'3_ Dioxyl oxime, bismuth dimethoxy bromide, etc., such as methyl vinegar, formic acid, acetic acid, acetonitrile, gamma, etc., may be exemplified by methyl cellosolve, dimethyl _ , Amine dimethyl ethanoamine, acetonitrile, dimethyl sulphate, cyclodnaze, sulphur, m, acetonitrile, pentyl / HF, methyl ethyl ketone, _, acetic acid Base red chloroform = preferably in the dopant, in addition to the above organic ft 〇 / 〇 ^ 40 ^ = some alcohol is the following sizing agent, after the doping is reduced on the metal support, dissolved比革〇叫网(The pusher of the cellulose on the dragon's stalks will be used. 44 201139461 is the Chinese manual of the 100112643. There is no slash correction. The revised period: 100 years July 18 曰 古二4 film definition Gelling the gel, so that the gelation solvent which becomes easy to peel off from the metal is used when the proportion of the alcohol is small, and the dissolution of the deuterated cellulose which promotes the non-gasochemical organic solvent is used. The gelation, precipitation, and viscosity of the inhibiting reactive metal compound are increased. ▲ As the alcohol having the atomic number, decyl alcohol, ethanol, n-isopropanol, n-butanol, second tau alcohol, and third Among the butanol and propylene glycol, it is preferred that the dopant is excellent in stability, the point of the Buddha is relatively low, and the ratio is good and non-toxic. These organic fissures have no solubility and are called poor solvents. In the present invention, the deuterated cellulose constituting the deuterated cellulose film contains a hydroxylLti-containing fluorene-functional group', thus reducing the amount of the self-cleaning building from the viewpoint of %2, preferably in the total solvent. The alcohol contains 5 masses of 〇1°〇皙', more preferably 7 mass% to 25% by mass, still more preferably 10% by mass to 20% by mass.勹 (4) The content of the whole alcohol can be easily adjusted by the production method of the present invention θ. The reproducibility of Re4Rth of the cellulose film. Specifically, the enthalpy of this or the temperature of the dry 26 (heat treatment temperature) in the production method of the present invention to be described later is set to be relatively low, and the reach of Re or Rth can be further increased. In the present invention, the presence of a small amount of water is also effective for increasing the film strength of the solution viscosity state or for increasing the dopant strength during the drum method, for example, it may contain 〇ι mass 45 2011 39461 for the whole solution. 126« Chinese manual without line correction This revision date: 100 years July day % ~ 5 quality. /. More preferably, it may contain G.lf4%~ which may contain 0.2% by mass to 2% by mass. The examples of the combination which can be preferably used as the solvent of the polymerizer in the present invention are listed in the report of Japanese Patent Laid-Open. This patent special open 2_ No. 2 (No.) is more than the base solvent as the main solvent, the finest S has been contained in the Invention Association 2001-1745, March 15, 2001 Needle Technology Report The day of the month, the invention association). The concentration of the deuterated fiber f in the polymer solution of the present invention is from % to 40% by mass, more preferably 1 〇 Zeng Jin. / The jing / Chen degree is preferably 5 mass% to 30% by mass. The mass / 〇 ~ 3 〇 mass%, the best is Μ (4) The concentration of the brewed cellulose can be in the 将 which dissolves the brewed cellulose in the solvent. The white segment is adjusted to a predetermined concentration. Alternatively, it may be prepared by previously preparing a low concentration (for example, a solution of 4% by mass to a concentration). Alternatively, it may be prepared by previously preparing a concentration of two deuterated cellulose. It may also be added by adding an additive. The period of the additive may be based on the addition and the preferred high score == lyotropic ir is dissolved in two gas: the ethyl is methyl acetate: ethanol is 6 。 ^ t. or 'may also be preferred (1) Dissolving the mixed solvent of step 95: 5. The prototyping step is to dissolve (four) mixed with cellulose, and added 46 201139461 to the Chinese manual No. 100112643 No painting dirty ^# Revision date: July 18, 100, agent The steps of dissolving the dopants in the organic solvent relative to the brewed organic solvent, or the solution of the mixed additive solution to form the dopants in the dissolution of the deuterated cellulose in the deuterated cellulose can be used. In the case where ~= method 'dissolved below the boiling point of the main solvent=The method of adding more than the point of the monument to the dissolution of the point of interest. 9 9 marriage No. 4 bulletin, Japanese patent special Kaiping 9_95 ^ special ^ Kaiping patent special Kaiping 9-95538 "Report, or transcript" in the communique The method of dissolving and dissolving in the method of cooling and dissolving, as described in the Japanese Patent Laid-Open No. 3, the method of dissolving the same method as the main solvent, etc. The method of pressurizing to dissolve. It is difficult to make the concentration of the tilting surface of the sundries (4), and the step of casting the step by the liquid feeding (2) by means of the liquid feeding (2): (for example, a pressurized type of belt, or a ring-shaped metal belt that is limitedly conveyed by Hi, for example, a casting position on a metal support such as a non-mineral steel=twisted metal drum. Shape, and easy to T-shaped mold = uniform pressure mold. Pressurized molds include hanger-type molds or products, any of which can be preferably used. The surface of the metal support is ... see. In order to increase the film speed Can also be placed on the metal trap 2 47 201139461 _ Correction period: July 18th, 100th is the "00112643 Chinese manual" without the scribe line correction of the above-mentioned calendar mold, the amount of dopants divided to form a multilayer Or, by simultaneously casting a variety of dopants It is also preferable to cast a film to obtain a laminated structure. (3) Solvent evaporation step The solvent evaporation step is a state in which the mesh is placed on the metal support (the state is before the finished product of the cellulose-deposited cellulose film, and still contains many The solvent is referred to as a web) to heat and evaporate the solvent until the web can be peeled off from the metal support. When the solvent is evaporated, there is a method of blowing from the net side and/or from the back of the metal baffle. The method of transferring heat by means of _ method, self-existing _ pure radiant heat, etc., but the method of heat transfer of the back Φ liquid is preferable because of good drying efficiency. In addition, the method of combining the shaft method is good. . In the case of heat transfer of the backside liquid, it is preferable to add it below the boiling point of the main solvent of the organic solvent used for the dopant or the organic solvent having the lowest point. (4) Peeling step" The stripping step is a step of peeling off the web on which the solvent has evaporated on the metal support at the peeling position. The stripped web is sent to the next step. Further, if the web is peeled off If the residual swell (the following formula) is too large, if it is too dry on the metal support and then peeled off, the _ part will peel off on the towel. As far as possible, the residual solvent is washed by R. 仃^, which can increase the film forming speed. There is a gel fiber, such as a directional dopant, which is added with respect to the deuterated cellulose (tetra) solvent. The method of gelation after the object and the scale is as follows: 48 201139461 Revised date: July 18, 100 is the Chinese manual No. 100112643, and the method of reducing the temperature of the metal support to reduce the temperature of the metal support is used. Gelation on the metal support to increase the strength of the film at the time of peeling, thereby speeding up the peeling and increasing the film forming speed. The amount of residual solvent at the time of peeling of the mesh on the metal support is preferably according to the strength of the drying condition, Length of metal support In the range of 5% by mass to 15% by mass, the amount of residual solvent at the time of peeling is determined by the combination of the economic rate and the quality. Preferably, the temperature at the peeling position on the metal support is set to -50 ° C to 40 ° C, more preferably 1 〇. (: ~ 4 (TC, preferably set to 15 ° C ~ Further, it is preferable to set the residual solvent amount of the mesh at the peeling position to 10% by mass to 150% by mass, more preferably 10% by mass to 5% by mass. The amount of residual solvent can be expressed by the following formula. The amount of residual solvent (% by mass) = [ (MN) / Ν] χ 1 于 : : : : : : : : 二 二 二 于 于 于 于 于 于 于 于 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( The drying or heat treatment step, the stretching step, the loading and unloading of the jig, and the end of the work are carried out in the present invention. When the heat treatment is performed, the heat treatment is carried out in the 49 201139461 revision period: July 18, 100 is the first surface Qing Tg-5 C, preferably Tg-2 〇 °c or more, go above, less than Tg_5t. 5°(:, more preferably Tg-l5°C In addition, the heat treatment time is preferably less than the clock, especially preferably about 10 minutes. Below the knife buckle, more preferably 20 minutes drying and heat treatment method = Γ Γ 的 microwave In the direction of the film transport direction fu direction (in the T), it is appropriate to select the conditions according to the solvent used. t 'also referred to as the longitudinal direction) and the film-transferring, but in the case of the extension = the lateral direction, the extension in the direction of the direction is extended upwards. More preferably: == can be implemented in the f 1 segment, When the extension is extended to the film transport side (four), the special one is 〇~10%. The upper == 〇 = dimension length can be achieved by the speed difference between the metal branch body and the peeling $ (peeling roll pulling speed). For example, the pinch Lm of the inlet side is faster than the direction of the rotation speed of the roller (the longitudinal direction: the appearance of the brewing cellulose film in the transfer delay). The adjustable one is the 'extension ratio here' (%)" is calculated by the following formula: 50 201139461 Revised period: 100 years July 18曰 is 100112643 Chinese _ book _ line correction extension ratio (%) (length after extension) - (Extension The length of the front length)}/the length before the extension 帛 is extended in the direction orthogonal to the film transport direction. The stretch ratio is preferably 〇50/〇' more preferably 10% to 5〇%, and is particularly good for leisure/dissipation. Further, in the present invention, the method of "application" is preferably carried out by using a tenter device in a direction orthogonal to the film transport direction. Ο &amp;纟 is biaxially extended in the longitudinal direction. It is also possible to relax to, for example, 〇8:~1.0 times to obtain a desired retardation value. The stretching ratio is corresponding to the light, and the other is also used in the length direction when manufacturing the brewing cellulose film of the present invention. Uniaxial extension. The temperature at the time of extension is preferably Tg_5t~Tg+1(rc, more: Tg+5°c It is particularly preferably Tg-5°c~Tg+3°c. By such a film stretching, the film of the present invention can be reduced in turbidity, and can be dried after the stretching step. When the stretching step is followed by correction, the drying temperature, the amount of drying, and the drying _ are different depending on the use, as long as the drying conditions are appropriately selected depending on the type and combination of the solvent to be used. In the present invention, the lifting will be carried out. From the viewpoint of the front contrast when the film of the present invention is applied to the liquid crystal display device, it is preferable that the dry n degree after the stretching step is lower than the stretching step_extension temperature. (6) The winding is preferably such that The length of the film obtained as described above is taken up in a manner of 10000m 〇 0 '10000 m, more preferably 500 m to 7 mm, and even more preferably m to 6 m. The width of the film is preferably 〇5 melon. 51 201139461 For the Chinese manual No. 100112643, there is no slash correction. This revision period: July 18, 100: 5.0 m 'More preferably L〇m~3.〇m, and more preferably i 〇m~2 5 melon When picking up, the best is to give at least the end-end knurling, and the width of the knurling is preferably 3:~50 mm 'better 5 _~3 〇 coffee, The height is preferably 〇5 _ 钱 Γ 更 更 1 1 1 1 1 1 1 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 In the case of the optical compensation film for a crystal display device, for example, the film width is preferably 1470 mm or more. The film of the present invention is not only cut into a film form which can be directly incorporated into a liquid crystal display device. It also includes a film that is produced by (4) continuous production (4) as a growing strip and rolled into a shape of a parent. The film of the latter form is stored and transported in this state. When the human liquid (4) device is actually assembled, or when it is attached to the polarizer #, it is used to a desired size. In addition, a polarizer such as a polyvinyl alcohol film which is formed into a strip shape in the same manner as in the case of a long strip is attached, and when it is actually incorporated in a liquid crystal display device, it is cut into two. The form of the film of the wound sheet is in the form of a roll of 2,500 m or more. I can take the web obtained in the above manner and obtain the deuterated cellulose film as the final finished product. &lt;Characteristics of the fluoridation cellulose film&gt; (turbidity) The bismuth cellulose film of the present invention preferably has a turbidity of the ruthenium film of 1% or less, more preferably 0.4% or less, and particularly preferably 〇~ 0.30%. (Glass transfer temperature Tg of deuterated cellulose film) 52 201139461 Revised flood season: July 18, 100 is the first Chinese version of No. 12643 No underline correction. In this specification, TB at - , the clear cellulose The glass transition temperature of the film is the glass transition temperature (hereinafter abbreviated as Tg) of the entire film of the deuterated cellulose or the plastic film constituting the film. The additive (delay) (the retardation value of the film thickness direction under the leg of 55G at 55G is 550) is relatively high. Nm~5. Legs, more preferably 2. Nm~4. (10) Special 4 soil is 25 nm to 35 nm. Further, the film of the present invention is preferably an optical compensation film of a biaxial film. More preferably, it is biaxial. Here, the so-called film is biaxial, which means that the film is nx, ny, and taken (the refractive index of the slow axis in the plane of the rainbow is 'ny), which means that the in-plane is orthogonal to μ. In the case of the present invention, the refractive index 'η ζ indicates a refractive index in a direction orthogonal to η χ and W) is more preferably nx &gt; ny &gt; nz. The film of the present invention exhibits biaxial optical characteristics and is preferable in that it reduces the problem of color shift when viewed from a diagonal direction in a liquid crystal display device, particularly a VA mode liquid crystal display device. In the present specification, Re(1) and Rth(λ) respectively indicate the in-plane retardation at the wavelength λ and the retardation in the thickness direction. In the present specification, when not specified, the wavelength λ is set to 590 nmaRe(), which is the wavelength λ in K〇BRA '1Α]〇Η (manufactured by Qji Scientific Instruments) The light of nm is incident in the normal direction of the film to measure. Regarding Rth ( λ) ' with respect to the slow axis in the plane (determined by K〇BRA 2丨ADH 1_ as the tilt axis (rotation axis) (when there is no slow axis, the arbitrary direction in the film plane is set to The normal direction of the film of the rotating shaft), from the normal direction to 53 201139461 is the Chinese manual of the No. 100112643. There is no scribe line correction. This correction date: every 1G degree from the direction of the inclination of July 1st, 100 degrees. Into the light of nm, the above six points are measured as (1), the assumed value of the 21 calendar value and the average refractive index, and the input film ιϊν /· ( ) ° and then the slow sleeve can also be used as the oblique pumping ( The arbitrary direction of the rotation is set to the rotation =) 'The delay value is measured from any two directions, and based on the value and the assumed value of the average refractive index and the input film thickness value, Rth is calculated by the following formula (8). The assumed value of the average refractive index can be used to earn values of X) HN WILEY &amp; s NS, jump), catalogues of various optical films. For those whose average refractive index value is unknown, the measurement can be made by an Abbe refractometer. The following is an example of a flattened cellulose (1_complementary dilute hydrocarbon polymer ((9), polycarbonate (Γ59), polymethyl methacrylate (1.49), polystyrene (1.59)) of the main optical film. The assumed value of the average refractive index and the film thickness, k 〇 BRa 2iadh nx, ny, nz are input. Further, Nz = (nx - nz ) / ( nx - ny ) 〇 is calculated based on the calculated nx, ny, nz [ Number l] Equation (A) Re(6&gt;): ny'Knz / • -1 sin , nx , 夕) l2 rfj +|«zcos sin'1 r 8ΐη(-^η k nx , / F cos ^ sin* Here, 'Re (Θ) denotes a delay value in the direction from the inclination angle one of the normal direction, nX, ny, ηζ denotes the refractive index ellipse _ each spindle orientation sin (-^) 54 201139461 Revision period: 100 years 7 On the 18th, the Chinese manual No. 100112643 has no reticle correction of the refractive index, and d represents the film thickness. Rth = ((nx + ny) / 2-nz) xd (B) Furthermore, at this time, the average refractive index n is required as a parameter, and the value measured by the Abbe refractometer (Abbé refractometer 2-T manufactured by AtagG Co., Ltd.) is used. 〇 (water content) The film of the present invention is 25. (: The equilibrium moisture content at a relative humidity of 80% is low.) When the liquid crystal display panel is greatly surfaced, the humidity is changed to the buffer body with respect to the environmental humidity, and the humidity inside the partial filament is changed in the center portion. It is preferable to homogenize the end portion. (Moisture Permeability) From the viewpoint of the durability of the light plate and the drying during the processing of the offset, (4) the film thickness is 40 μm #25t: relative humidity 80%, ,, '乂The moisture permeability after hours is preferably 1500 g/m2.day~3500 1500 g/m2*da-3〇〇〇g/m2.day, 2000g/m2.day~2500g/m2.day. The polarized light, moist heat, and long-lasting property are more likely to cause light leakage in a wet environment. Therefore, the inner moisture: ', the moisture permeability and moisture content of the shin guard are controlled to the optimum range (film thickness). The thickness of the cellulose film is preferably 20 μm η~200 55 201139461 Revision date: July 18th of the following year is the _12643 Chinese reward book _! (_正本2〇^85 μΠ15 25 μ^65 μιη ° If the right film is less than 20 divisions, the mechanical strength is insufficient to break, and the film surface is likely to be deteriorated. The concentration of the solid component contained in the square worm of the desired thickness, the narrowness of the metal π of the mold, the extrusion pressure from the mold, the metal branch speed, and the like may be used." (Film width) The film width of the film of the invention is preferably 1 〇〇〇 15 〇〇 or more, particularly preferably _ _ or more. More preferably (functional layer), the ruthenium film may be a single layer film, or may have 2 The polarizing plate of the present invention preferably has a functional layer, and the film of the present invention has a functional layer form, and when the polarizing plate of the film of the present invention is used, Other functional films may be superimposed. No special, for example, the following _ wei Wei and base film / hard coat / medium refractive index layer / low refractive index layer base film / hard coat / medium refraction Rate layer / substrate film / hard coat layer / low refractive index layer + 曰 / low refractive leather layer base film / hard coat layer / conductive layer / low refractive index layer lamination layer [polarizing plate] 偏 polarizing plate of the present invention Containing at least one film of the present invention. Hereinafter, the pair of 56 201139461 Amendment date: July 18, 100 is the Chinese specification of No. 100112643 The polarizing plate of the present invention is described by the scribe line correction. The polarizing plate of the present invention can be produced by a general method. For example, the following method can be used. After the saponification treatment of the II cellulose film of the present invention, the fully saponified polyethylene is used. The aqueous alcohol solution is applied to both sides of the polarizer. 7 The saponification treatment refers to the improvement of the adhesion in order to improve the adhesion of the leeches, and the ionic pigment is not impregnated into the high temperature test liquid. Processing. As the polarizer used in the polarizing plate of the present invention, a polarizer of the prior art can be used. For example, a dichroic dye pair such as ruthenium containing, for example, a polyvinyl alcohol or an ethylene unit is contained in an amount of i mol% to 4 mol%, a degree of polymerization of 2000 to 4000, and a degree of saponification of 99.0 mol%. 99.99% of the ethylene-modified polyvinyl alcohol-like hydrophilic polymer film is processed and stretched, or a vinyl chloride-like plastic film is processed and aligned. As the film thickness of the polarizer, a film thickness of 5 μm to 3 μm is preferably used. The polarizer obtained in the above manner was bonded to the polarizing plate protective film. At this time, at least one of the polarizing plate protective films is a film using the present invention. On the other hand, other polarizing plate protective films (preferably cellulose derivative films) can be used. As the polarizing plate protective film of the other surface, the deuterated cellulose film of the present invention can be used. A commercially available cellulose ester film can also be used. The polarizer protective film used on the surface side of the display device has an antireflection layer, an antistatic layer, and an antifouling layer in addition to an antiglare layer or a transparent hard coat layer. 57 201139461 is the "Thank _ Chinese manual without a slash correction. This correction date: July 18, 100. In addition, when making a polarizing plate, it is preferable to make the in-plane slow axis and polarized light of the retardation film of the present invention. The liquid crystal display device of the present invention comprises at least one film of the present invention or the polarizing plate of the present invention. The liquid crystal display device of the present invention is characterized in that the liquid crystal display device of the present invention is bonded to the liquid crystal display device of the present invention. The liquid crystal display device of the present invention can be produced by arranging and bonding the polarizing plate of the present invention obtained in the above manner to both surfaces of the liquid crystal cell. The liquid crystal display device of the present invention uses at least one polarizing plate of the present invention. Liquid crystal display device. The polarizing plate of the present invention can be used for liquid crystal cells of various display modes' and can be used with, for example, Twisted Nematic (TN), In-Plane Switching (IPS), Ferroelectric Liquid (Ferroelectric Liquid) Crystal, FLC), Anti-ferroelectric Liquid Crystal (AFLC), Optically Compensatory Bend (OCB), Hypertwisted Nematic (Supper Twisted Nematic, STN), Vertically Aligned 'VA' and Hybrid Aligned Nematic (HAN) are used in combination with various display modes. [Examples] The following 'exemplary examples and comparative examples are more specifically The features, the amounts, the ratios, the processing contents, the processing order, and the like shown in the following examples can be appropriately changed without departing from the gist of the present invention. Therefore, the scope of the present invention should not be construed as follows. Specific examples shown are limited to 58 201139461 mm 100112643 Revised date: July 18, 100. [Example 1 to Example 3 and Comparative Example 1 to Comparative Example 7] (1) Preparation of raw materials (M) Deuterated fibers Preparation of a resin, preparation of a cellulose derivative having an ethylene thiol substitution degree as described in the following table, and addition of sulfuric acid as a catalyst (7.8 parts by mass relative to cellulose 1 part by mass) Each carboxylic acid is then subjected to a thiolation reaction under 4 Torr. Thereafter, the total substitution degree and the degree of substitution at the 6-position are adjusted by adjusting the amount of the sulfuric acid catalyst, the amount of water, and the ripening time. The aging temperature of C is carried out. Further, the low molecular weight component of the deuterated cellulose is washed and removed with acetone. /1-2) Preparation of various sugar ester compounds having different degrees of ester substitution is prepared by the following method. A plurality of sugar ester compounds having different degrees of ester substitution are described. First, the compound U1 to 117 described in the above formula is synthesized by the method described in the synthesis of the compound 3 by W02009/03164 [0054]. 0 In addition, other compounds were synthesized in the same manner. Thereafter, mixing is carried out to prepare a sugar ester compound. (2) Preparation of a dopant, putting the following composition into a mixing tank, stirring to dissolve each component, and heating to 9 after about 10 minutes (after TC, using a filter paper having an average pore diameter of 34 μηι and an average pore diameter of The 10 μιη sintered metal filter was over-etched. 59 201139461 Revision date: July, 100, 18, 100.0 parts by mass, 8.0 parts by mass, 365.8 parts by mass, 92.6 parts by mass, 4.6 parts by mass, No. 100112643, Chinese manual, no underline correction, the following cellulose oxides described in the following table In the following table, Ac represents an ethyl hydrazide group, and Pr represents a glyceryl group, and a plurality of sugar ester compounds having different degree of ester substitution described in the table. &lt;1 -2 &gt; Matting agent dispersion liquid Next, the following composition containing the deuterated cellulose solution prepared by the above method was placed in a dispersing machine to prepare a matting agent dispersion liquid. • matting agent (Aerosil R972) • two gas aeration • methylation • butanol • deuterated cellulose solution 〇 2 parts by mass 65.7 parts by mass 16.6 parts by mass 〇 8 parts by mass 10-3 parts by mass 100 parts by mass of the above The inorganic microparticles of the brewing cellulose solution of Example i were mixed with the example 1 (4) of the turtle fiber fat-prepared M f, and the races and the replacement materials used in the examples and the comparative examples were prepared. It is used as a reaction to remove benzene by vacuum drying (1) and less than 100 ppm. g))) The type of the brewing agent was changed as shown in the following table, and the dopants of the other examples and the comparative examples were prepared by the degree of substitution with the examples. ~ The same method as the foreign matter (3) Washing and casting The above dopant is made of SUS using a roll forming machine.仃% cast. Furthermore, the drum 201139461 repair period: July 18th, 1st year is the 100112112 Chinese manual without a slash correction (4) Dry. At the temperature indicated in the following table towel, the slab was sprayed with a drying device to obtain a lye (film) for 2 minutes. Further, as another form, after the film was peeled off from the drum, the domain device that carried the two ends of the net by the jig was transported, and the machine was squirted for 2 G minutes in the tenter device. The results obtained from the above two lion states are the same. Further, the drying temperature herein means the film surface temperature of the film. (5) Extending the obtained net (film) from the roller and then clamping it to the jig, when the amount of residual solvent relative to the mass of the film as a whole is 3〇% to 5%, in the state of being fixed Under the condition that the end is uniaxially stretched, the net (film) is stretched in the direction (lateral direction) which is the father of the film transport direction by using a tenter at the extension temperature and the stretching ratio of the carrier. Thereafter, the jig was removed from the film and dried at 11 (rc) for 3 minutes. On this day, the thickness of the cast film was adjusted so that the film thickness after stretching reached 4 〇 111. (6) In order to judge the manufacture of the film of the composition shown in the above table, it is suitable to produce a roll having a minimum of 24 roll widths as a professional and a pro-length of 2 mm in the above-mentioned conditions. For 1 of 24 rolls continuously manufactured. The root roll was cut at intervals of lm (the width was i28 〇mm Di.) (Preparation of polarizing plate) The yttrium was adsorbed on the stretched polyhedral film to prepare a polarizer. The following agent's film of each of the produced examples and comparative examples is attached to the side of the polarizer. The saponification treatment is on the side of the polarized film on July 18th. The following conditions were carried out: 1.5 mol/L aqueous sodium hydroxide solution was prepared and kept at a temperature. A 0.005 mol/L aqueous solution of dilute sulfuric acid was prepared and kept at 351. The film prepared in each of the examples and the comparative examples was subjected to the above hydrogen. After immersing in an aqueous solution of sodium oxide for 2 minutes, it is immersed in water to fully wash away hydrogen. The sodium aqueous solution was then immersed in the above dilute sulfuric acid aqueous solution for 1 minute, and then immersed in water to sufficiently wash away the dilute sulfuric acid aqueous solution. Finally, the sample was sufficiently dried at 120 ° C. Commercially available triacetic acid The cellulose film (FUJITAC TD80UF, manufactured by Fujifilm Co., Ltd.) was subjected to saponification treatment, and adhered to the opposite side of the polarizing plate using a polyvinyl alcohol-based adhesive, and then dried at 70°. The transmission axis of the polarizer was arranged in parallel with the slow axis of the film of each of the examples and the comparative examples, and the transmission axis of the polarizer was arranged to be orthogonal to the slow axis of the commercially available film. Measurement method&gt; (Measurement method of average degree of substitution of sucrose benzoate) A peak having a retention time of about 31.5 min was set as an octasubstituted product, and a peak group having a retention time of about 27 min to 29 min was set as a seven substitution. The peak group with the hold time of 22 min~25 min is set as a six-substitute, and the peak group with the hold time of 15 min~20 min is set as a five-substitment'. The hold time is at 8.5 mi. The peak group near n~13 min is set as a tetra-substrate, and the peak group with a retention time of 3 min~6 min is set as a tri-substitture'. By the following HPLC strip 62 201139461 * No Chinese patent specification No. 100112643 Correction of the line correction date: The average degree of substitution with respect to the value obtained by totaling the area ratio of each of the substitutes was measured by the measurement on July 18, 100. "HPLC measurement conditions" Column: TSK-gel ODS -100Z (Dongcao), 4.6* 150 mm, batch number (P0014) Eluent A: H20 = 1 〇〇, eluent b: AR = 1 〇〇. Add 0.1% of each of A and 6 to &lt;:〇11,\£13 Flow rate: 1 ml/min, column temperature: 4 (TC, wavelength: 254 nm, sensitivity: AUX2, injection amount: 1 〇μΐ, eluent: THF/H2〇= 9d (vol ratio) Sample concentration: 5 mg/10 ml (THF) (turbidity) Turbidity is measured at 25 ° C, relative humidity 60%, using turbidity A meter (HGM-2DP 'Suga Test Instrument) and a 40 mm x 80 mm film sample were measured according to Jis K-6714. The results are shown in the following table (optical properties). The results are shown in the following table. (Optical displayability) Re and Rth were measured at a wavelength of 59 〇 nm by the above method using KOBRA 21ADH (manufactured by Otsuka Instruments). The results are shown in the following table. (Tg) 63 201139461 is the Chinese manual No. 100112643. There is no slash correction. The date of this correction: the measurement of the glass transition temperature on July 1008, 100 is determined by the following method. Adjusting the brewing cellulose film sample of 24 mm&gt;&lt;36 mm at 25 C and 60% relative humidity After being wet for 2 hours or more, a dynamic viscoelasticity measuring device (Vibron: DVA-225 (manufactured by IT Keisoku Seigyo Co., Ltd.)) was used, and the distance between the jigs was 20 mm, the temperature increase rate was 2 ° C / min, and the measurement temperature range was 30 ° C. Measured at ~20 (TC, frequency 1 Hz. The storage elastic modulus is represented by the logarithmic axis on the vertical axis, the temperature is represented by the linear axis on the horizontal axis, and the storage elastic modulus is transferred from the solid region to the glass transfer region. The observed rapid decrease in the storage elastic modulus was determined by the method described in Figure 3 of JIS K7121 1987. The water content was determined by using a moisture analyzer. The sample (cmG5, all of which is Mitsubishi Chemical (share)) was measured by Karl; = 7 mm x 35 mm sample of deuterated cellulose film. The water content was calculated by dividing the moisture content (g) by the weight (g) of the sample. (Exudation) 9 〇. / 渗 and ^ will be mixed with the scales, the temperature of the thief, the humidity ^ 1 degree humidity 1%% under the damp heat condition of the precipitation (10) precipitation evaluation. The results are shown in Table 5. (岔 评价 评价 评价 ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) The square test of K56iK). Specifically, the surface of the sample hardened by hardening with 1 mm outer line and wire (UUraVi〇let, W) is attached with cellophane tape and 64 201139461曰期: On July 18th, 100th, the Chinese manual No. 0112643 was used to correct the mylar tape, and then quickly peeled off, and the peeling site was closely evaluated by visual observation. The result of Xe irradiated for 24 h before the formation of the incision was set to be light-resistant, and the non-irradiated Xe was set as the initial adhesion. Adhesion 〇: The peeling part is 0 mass~10 mass. Adhesion Δ: The peeling site is 11 mass to 50 mass 〇 Adhesiveness χ : The peeling site is more than 50 mass and 99 mass or less. 密 Adhesion XX: The peeling site is 1 〇〇 mass (all parts with tape attached). When Xe is irradiated, the Super Xenon Weather Meter SX75 manufactured by Suga Test Instruments Co., Ltd. is used. (Pencil hardness evaluation method) Hard coating was carried out at 25 ° C and a relative humidity of 60. /. After the UV-cured sample was conditioned for 2 hours, the test pencil specified in JIS s 6〇〇6 was used, and the pencil hardness evaluation method according to JIS K54〇〇 was used, and the 500 g code was used. The sample in which the pencils of the respective hardness were repeated five times was placed in a room (eell) of the uktc for 5 minutes, and was taken out and evaluated. The hardness of the sample was set to 4 times or more without damage. Furthermore, 'IS K 54GG towel's (4) damage is the rupture of the thief and the scratch of the film. Although the air carrier forest will be Tu County sag as a county, the sag of the film is also included as damage. The higher the number, the higher the hardness. 0 (Polarizer durability) The polarizing plate obtained by the method of the next method is under the hot and humid conditions of 65 201139461. The Chinese manual has no underline correction. On July 18, 1st, it was a long time. Observed the change in the orthogonal transmittance of the sucrose benzoate-based polarizing plate at a temperature of 60 ° C, a humidity of 90%, a temperature of 80 ° C, and a humidity of 10% under a moist heat condition of 1000 h. Better than the durability of the TPP-based polarizer. 66 201139461 BooIIICi 001 : sm 3!s HI 遒 细 细 匪 匪 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi fi 〇〇0 ο &lt; X 0 0 骖Ή XX &lt;〇&lt; 〇Φ m 00 cn $ - - 5 芦 S δ ΐΓ·Η sgg H Room 1 R 00 ^ # si ^ 〇〇sw O •® ^ 〇 ^ ^ ν 〇 &&gt; £J o 2 ΓΟ • m ^ 2 f? 婳硪嵩 甸 r r4 s HH S3 r4 ϊ οϊ Η IS i & & 〇 〇 〇 Ο o Ο ο S 接 甸 r r4 s HH S3 cs c4 c4 r4 + ίΓΓ&lt; target g CO 00 00 00 v〇oo P&gt; 00 00 ίί ϋΐ in in oo wS 1—H 00 in 00 JO Substitute substitution of 75% or more Total 〇· 5; R *-H OO 妄f Substitution with a substitution of 125% o 〇o 〇\_x 取代 Substitution with a substitution of 25% o 〇o 〇oo Plasticizer Ψ *4〇蒌 Substitution 37.5 % of the substituents o fS I ίί_« 客 o Ό rn Ό cn Ό cn i Substitution with a degree of substitution of 67.5 % O) iH 绔涔1m ί 75% substitution oo cn OO m 00 CO Substitution degree 87i % substitution t-H inch fs A Substitution degree 100% substitution ON m 3 wS m infant sucrose benzoate succinic acid benzoquinone Sour and vinegar cheap benzoic acid vinegar TPP/BD P Strict benzoic acid vinegar sucrose benzoic acid vinegar vegetable benzoic acid vinegar Si SI ^ cn 5 5 怒寸ΤΓ ¢: • u令怒η 5 5 201139461 BooIgl 壮001 :s&gt ;[n3I_ 许31乐璩«毁_器饀«-&amp;-------------------------------------------------------------------------------------------------------------------------------------------------------------------- CN r5 〇〇•® ^ i2 〇y-^ r &lt; H CN oo N CN in H ON 聋〇\ o (D 2 $ oo !B soooooo N ° H m od oo m oo 卜 On § 00 00 ri \q 2 Ϊ4 窭I ift| ®- i4 ® 窭i itt| B- 严糖苯甲_ 201139461 Amendment date: (10) The data of the deuterated cellulose crucible obtained in the example of IS on July can be improved and combined with the polarizer. According to Table 5, the example has good properties, moisture permeability and optical properties. Durability of polarizing plates under wet conditions. On the other hand, according to Comparative Example 比较 and Comparative Example 2, when a mixture of sugar ester compounds having different degrees of substitution is used, if the content of the sugar ester compound having an ester substitution degree of 75% or more exceeds the range of the present invention, the ester is substituted. When the content of the sugar ester compound having a degree of 35% to 50% is less than the range of the present invention, the bleeding property of the sweet and sour compound is deteriorated and the optical properties are deteriorated. Example 4 is to facilitate the adhesion of the sugar ester compound of Example 3 in Table 5, that is, 25% of the sucrose alum vinegar, to the sucrose octaacetate as the sweet and sour compound of the disaccharide, and the adhesion property to the hard coat layer, The pencil hardness and the durability of the polarizing plate were also good as in the case of Example 3. (Production of Liquid Crystal Display Device) The polarizing plate using the film of the present invention was mounted on a liquid crystal panel and evaluated. As a result, it was confirmed that there was no difference from the Tpp film, and there was no problem in performance. It is understood that the obtained liquid crystal display device has excellent durability under high temperature and high humidity. [Simple description of the diagram] None. [Major component symbol description] 69 201139461 Revision date: July 18, 100 is 苐100112643 Chinese manual without slash correction The invention patent description painting (this manual format, order 'Do not change any more' ※Do not fill in the mark ) ※Application number: j ※Application曰: id孓, I y ※Working PC classification: 1. Invention name: (Chinese/English) 醯化cellulose film, polarizing plate and liquid crystal display device/CELLULOSE ACYLATE FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY 2. Abstract: The present invention provides a transparency, moisture permeability and optical performance, and can improve the long-term stability of a polarizing plate under high temperature and high humidity when combined with a polarizer. Brewing cellulose film. The deuterated cellulose film is characterized by comprising a plurality of sugar ester compounds having different degrees of substitution, and deuterated cellulose, wherein the deuterated cellulose has a degree of substitution of 2.70 or more and less than 2.95, and constitutes the above. The sugar of the sugar ester compound is a disaccharide to a tetracool, and the average ester substitution degree of the polysaccharide derivative having different degrees of ester substitution is 62% to 94%, and the degree of ester substitution in the above-mentioned brewed cellulose film is Among the various sugar ester compounds, the degree of ester substitution is 75 ° /. The content of the above sugar ester compound is not more than 5, and the content of the sugar ester compound having an ester substitution degree of 35% to 50% is 5. /〇~ 30%. 201139461 is the Chinese version of the ίοο 112643 without a slash correction. This amendment date: July 18th, the third year of the invention, the invention summary: this invention provides a cellulose acylate film good in transparency, moisture permeability and optical property, and can improve The cellulose acylate film is characterized by including a plurality of sugar ester compounds with different ester substitution degrees and cellulose acylate. The sugar constituting the sugar ester compound is disaccharide to The average ester substitution degree of the sugar ester compounds is in a range of 62% to 94%. In the sugar ester compounds with different ester substitution degrees contained by the cellulose acylate film, the content of sugar ester compound having an ester substitution Degree of 75% or above is 80% or below, and the content of sugar ester compound having an ester substitution degree of 35% to 50% is 5% to 30%. 201139461 Revision period: July 18th of the following year is the 100112643 Chinese manual without a slash correction. 7. Patent scope: 1. A bismuth cellulose film And characterized in that it comprises: a plurality of sugar ester compounds having different degrees of vinegar substitution; and a brewing cellulose, wherein the cellulose halide has a degree of substitution of 2.70 or more and less than 2.95, and the sugar constituting the above sweet and sour compound In the disaccharide-to-tetrasaccharide, the average g of the above-mentioned sugar-glysing compound having a different degree of substitution is 62% to 94%, and the degree of substitution of the ester contained in the cellulose-deuterated film is different. In the sugar ester compound, the content of the sugar ester compound having a 'ester substitution degree of 75% or more is 80% or less' and the ester substitution degree is 35% to 50%. The content of the sugar ester compound is 5% to 30%. 2. The fluorinated cellulose film according to claim 1, wherein the sugar ester compound contains at least a furanose ring or a urethane ring. 3. The cellulose-deposited film according to item 1, wherein the hydrazine constituting the sugar ester compound is a disaccharide. 4. The cellulose-deposited film according to claim 1, wherein the sugar ester compound has at least one of a phenylhydrazine group and an ethylidene group as an S group. 5. The cellulose film according to any one of claims 1 to 4, wherein the cellulose deuterated cellulose is cellulose acetate. 6. The cellulose film according to any one of claims 1 to 4, which has a phase difference. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; More layers have a functional layer. 8. The fluorinated cellulose film of claim 7, wherein the functional layer is a hard coat layer. A polarizing plate is characterized in that it has a polarizing plate, and at least one film of a cellulose-degraded film according to any one of the above claims. A liquid crystal display device, comprising: at least one of the cellulose-deposited cellulose film according to any one of claims 1 to 8 or as claimed in claim 9 The polarizing plate described. 71 201139461 For the Chinese manual No. 100112643, there is no slash correction. The revised period: July 18, 2010. IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the component symbols of this representative figure·· None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None.