201137199 六、發明說明： 【發明所屬之技術領域】 本發明係有關橡膠共聚物塗敷在聚酯織物上及其製 法。本發明橡膠共聚物塗敷纖維織物是將纖維_在^ 溫度及常壓下，經溶劑處理降解可形成水溶性溶液可塗 佈在織物上或將橡膠共聚物以埶熔 ·、、、络及貼合的方式附著在織 物。 【先前技術】201137199 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to the application of a rubber copolymer to a polyester fabric and a process for the same. The rubber copolymer coated fiber fabric of the present invention is formed by dissolving the fiber at a temperature and a normal pressure by solvent treatment to form a water-soluble solution, or coating the rubber copolymer with a smelting, melting, and the like. Attached to the fabric in a conforming manner. [Prior Art]
纖維複合布膜材基本構成是一層織物’以及在織物上 黏貼-層軟性塑膠皮膜。其中的織物可以是棉、麻、嫘繁 尼龍、聚醋、聚乙烯、聚丙烯、壓克力等其中之一所製成 的’而軟性塑膠則可以是任何有柔軟觸感、經塑化或未經 塑化的詩材料。有時為獲得更好的觸感及保溫、防震等 目的 製造纖維複合布膜產品的製程有以下三種： Π)糊料加工·· pu是製造纖維複合布膜最常用的材料之一， 係將pu樹脂與塑化劑共混成糊狀後，均勻塗佈於纖維織物 材料上，經高溫使樹脂膠化熟成而得纖維複合布膜產品。 (2)壓延加工：這是聚氣乙烯（pvc)纖維複合布膜產品最常 用的製程，係將PVC樹脂與塑化劑預混拌後，經捏合裳置 201137199 膠化後以多報㈣延機擠壓成片&，再與織物在高溫下貼 合而成。 (3)押出成型加工：這是熱可塑性聚胺醋(τρυ)是纖維複合 布膜產品最常用的製程，縣ΤΡϋ以單螺桿或雙螺桿押出 機膠化，經一Τ型模形成皮膜再與織物貼合而成。 纖維複合布膜產品的應用十分廣泛，舉凡汽車内裝、 廣告旗幟、皮包、皮箱、皮袋、衣物、鞋等製品均可見纖 維複合布膜。纖維複合布膜在加工成製品時會應用到縫、 黏、貼及局週波炫接等加工方法，其中尤以高週波溶接加 工時間短、可接著及可同時成型為特定形狀等優點。欲行 高週波熔接必須是被熔接材料帶有某種程度的極性，極性 分子在高頻週波的誘導下快速轉動，從而引發分子内的摩 擦熱而使材料軟化甚至熔融。帶有極性的合成材料以ρυ、 PVC及TPU最常見，也大量應用於纖維複合布膜產品之上。 然而PU纖維複合布膜的耐水解性較差，遇水易起反應 造成分子鏈斷裂，進而產生黃變現象，造成應用上的困擾； 此外PU纖維複合布膜係經交聯反應製成，其產品不利於回 收再利用。TPU纖維複合布膜雖無交聯反應，其耐水解性也 較PU纖維複合布膜有改善，但由於TPU價格昂貴，基於成 本考量，市場的接受度較低。PVC纖維複合布膜被使用的歷 201137199 史固然悠久，但由於添加塑化劑（如鄰苯二曱酸鹽類）及含 . 重金屬之安定劑，不但在製程中有粉塵及廢氣的環境污染 問題，pvc纖維複合布膜用完後進行垃圾焚化時亦會產生世 之毒戴奥辛’ I盟之法規REACH (Registration， valuation and Authorization of Chemicals)便明文規 疋不止使用pvc類的製品，此外，目前世界級大廠如Nike、 • MatSUShlta、GM 及 Sony 分別於 2000、2000、2002 及 2004 年禁用PVC。 壓延製程在PVC纖維複合布膜產品的場合有粉塵及廢 氣污染的問題，那是因為pvc樹脂為粉狀，且其卡又添加 大量塑化劑之故。另一方面，壓延加工更有產量高容易 控制及厚度均勾性佳的優點，適合於大量生產以降低成 鲁本。近冑國内外有許多使用# pvc材質之專利發明用途 亦不僅限於纖維複合布膜的範疇，且絕大多數均利用^塑 ㈣烯烴（TPG)為主體。由於|延製程須長時間曝露於高溫 且開放的環境中，熱塑性聚烯烴的熱穩定性不足，易於加 ,發生熱裂解而影響製品品質，而且熱塑性聚烯烴易於 中發生黏輪現*象，影響其成形性。即使以添加改質劑 的方式加以克服，熱塑性聚烯烴還有熔融強度不足，易於 熱成型時造成抽拉斷裂。縱使克服了上述的問題之後，熱 201137199 塑性聚烯烴還須面臨其缺乏極性的本質，結果是難以與織 物或異種材料接著，以及無法以高週波熔接法進行加工。 傳統高壓法製成的聚乙烯如LDPE等，因分子量分佈較廣， 分枝較多’融點低’易於衰弱點（weak point)發生斷裂· 反之’艾克森美孚公司（Exxon)的双茂金屬聚乙稀 (metal locene PE ’ m - PE)則因分子大小均一且分佈集中， 和共聚早體共聚合所得之分枝頻率亦均勻，故其衝擊強产 為傳統低密度聚乙烯LDPE的4倍好，惟其尚缺長鍵分枝 (long chain branch，簡稱LCB)，故熔融強度差。陶氏化 學公司（Dow)的單茂金屬聚乙烯則稍有LCB使得熔融強度有 改良’衝擊強度仍有傳統低密度聚乙烯LDPE的3倍好。 陶氏化學公司的Ρ0Ε係一種茂金屬一超低密度聚乙稀（^_ ultra low density polyethylene，m_ULDPE)，其乃乙烯 與丁烯或辛烯共聚合的聚烯烴彈性體，因分子量分佈集中 且具有LCB的分子結構’適合於行壓延加工。Tarkett Aktiengsellschaft公司（美國專利5,763,501 )所揭示的 「有發泡中間層的聚烯烴多層結構地磚之製法」，便是以 Ρ0Ε或聚稀烴塑性體（p〇iy〇ieHn plastomer’簡稱pop)為 主體’利用重覆的壓延製程生產出有中間發泡層的地磚。 然而該專利未揭示配合任何滑劑組成，而在壓延製程中易 201137199 生黏輪的問題；而且該專利在1〇〇份的聚烯烴主體中添加 2 0 — 5 0份的碳酸鈣，會對發泡過程產生不利的影響。此外， 該發明仍未解決對異質材料的接著問題，因此其產品未有 織物層而無法適用於纖維複合布膜上。 疋以’針對上述習知結構所存在之問題點，如何開發 一種更具理想實用性之創新結構，實消費者所殷切企盼， 亦係相關業者須努力研發突破之目標及方向。 有鑑於此，發明人本於多年從事相關產品之製造開發 與設計經驗，針對上述之目標，詳加設計與審慎評估後， 終得一確具實用性之本發明。 【發明内容】 有鑑於此，本發明之目的是提供以橡膠共聚物塗層的 織物，其特徵為以橡膠共聚物為原料塗敷在織物上，使具 有提高織物的車縫牢度、撕裂強度及綁紗牢度。此橡膠共 聚物可以為熔點（704 9(rc )粒子、橡膠共聚物薄膜或是橡 膠乳液共聚物。 本發明之另一目的是提供一種以橡膠共聚物為樹脂塗 敷織物的方法，將橡膠共聚物以塗佈透過含浸或熱壓合 塗敷在織物。在塗敷加工過程中可同步回收樹脂此外纖 維複合布膜也可回收再製利用。 201137199 依本發明提供一種以橡膠共聚物為樹脂塗敷織物，其 包含利用熔點（70〜190°C)橡膠共聚物在溫度200°C及常壓 力下’經由溶劑處理可變成水溶性溶液，此水溶性樹脂可 以塗佈或透過浸染方式附著在織物上。 此外本發明提供另一項以橡膠共聚物為樹脂塗敷織物 的方法’其特徵為將橡膠共聚物藉由熱熔及淋膜的方式， 附著在織物上。除此之外’亦可將薄膜藉由熱壓合方式， 將薄膜附著在織物上。 本發明之以橡膠共聚物為樹脂的塗敷織物，係以橡膠 共聚物在200C溫度及常壓下，經由溶劑處理可變成水溶性 溶液’可塗佈在織物上使附著織物上，以進一步製得本發 明之以橡膠共聚物為樹脂的塗敷織物。其具有撕裂強度經 向為5-30 lbf、緯向為5-30 lbf，耐磨性可達2〇〇1〇〇〇 rev ’車縫強度50-140 lbf的塗敷織物。 有關本發明所採用之技術、手段及其功效，茲舉較佳 實施例並配合圖式詳細說明於后’相信本發明上述之目 的、構造及特徵，當可由之得一深入而具體的瞭解。 【實施方式】 本發月的橡膠共聚物為融點的樹脂塗敷織 物，係以橡膠共聚物為塗敷樹脂原料，包括熔點701901 201137199 橡謬共聚物在200 C溫度及常壓力下，經由溶劑處理可變成 水溶性溶液，亦即為一種高分子溶液，而高分子溶液簡單 地說就是指將一種高分子單體溶於某溶劑中此處的高分 子單體則是指橡膠共聚物；黏度15〇~3〇〇〇〇cps以下，以塗 佈或透過浸染方式附著在織物上，塗布量範圍2〇2〇〇g/m2。 適用於本發明的樹脂為橡膠共聚物，可為橡膠乳液共 φ 聚、熔點70〜190°C橡膠共聚物子粒（粒徑5-40/zm)或薄膜 (厚度為 0. 01-0. 20 mm) ° 於本發明的另一型態，是一種製造以橡膠共聚物塗敷 織物的方法，包含下列步驟： 參閱第一圖所示，首先使用熔點7〇〜l9(rc橡膠共聚物 放入反應爸裏與溶劑一起反應（10)，其中該溶劑為丙酮、 乙醇與水混合而成。反應溫度為2〇〇。(：及常壓力下即高溫常 鲁廢（11)，反應完成後形成水溶性溶液（20)，再加增桐劑調 整黏度使易於塗敷在織物（30)上。經本發明所製得的以聚 酯為樹脂的塗敷織物，其具有撕裂強度經向為、 緯向為5-30 lbf，耐磨性可達2004〇〇〇rev， 早縫強度 50-140 lbf的塗敷織物，得以提高車縫牢度、 干反撕裂強度及 綁紗牢度（40)。 參閱第二圖所示’本發明以熔點 9The fiber composite cloth film is basically composed of a layer of fabric 'and a layer of soft plastic film adhered to the fabric. The fabric may be made of cotton, hemp, nylon, polyester, polyethylene, polypropylene, acrylic, etc. and the soft plastic may be any soft touch, plasticized or Unplasticized poetry material. Sometimes there are three processes for manufacturing fiber composite film products for better touch, heat preservation, shockproof, etc.: Π) Paste processing·· pu is one of the most commonly used materials for making fiber composite cloth films. After blending the pu resin and the plasticizer into a paste, the resin is uniformly coated on the fiber woven material, and the resin is gelatinized at a high temperature to obtain a fiber composite cloth film product. (2) Calendering processing: This is the most commonly used process for polystyrene (pvc) fiber composite cloth film products. After premixing PVC resin and plasticizer, it is kneaded by kneading and will be over-reported (4). The machine is extruded into a sheet & and then bonded to the fabric at a high temperature. (3) Extrusion molding processing: This is the most common process for thermoplastic polyamine vinegar (τρυ), which is the most commonly used process for fiber composite cloth film products. The county is glued by single-screw or twin-screw extruder, and formed into a film through a mold. The fabric is laminated. The application of fiber composite cloth film products is very extensive, and the fiber composite cloth film can be seen in automobile interiors, advertising flags, leather bags, leather cases, leather bags, clothing, shoes and the like. When the fiber composite cloth film is processed into a product, it will be applied to the processing methods such as seaming, sticking, sticking, and peripheral splicing. Among them, the high cycle welding processing time is short, and the film can be formed into a specific shape at the same time. To be high-frequency welding, the welded material must have a certain degree of polarity, and the polar molecules rapidly rotate under the induction of high-frequency waves, thereby inducing frictional heat in the molecules to soften or even melt the material. Synthetic materials with polarity are most common with ρυ, PVC and TPU, and are also widely used on fiber composite film products. However, the PU fiber composite cloth film has poor hydrolysis resistance, and the water chain is liable to react to cause molecular chain breakage, which causes yellowing, which causes troubles in application; in addition, the PU fiber composite cloth film is made by cross-linking reaction, and its product Not conducive to recycling and reuse. Although the TPU fiber composite film has no crosslinking reaction, its hydrolysis resistance is improved compared with the PU fiber composite film. However, due to the high cost of the TPU, the market acceptance is low based on cost considerations. The PVC fiber composite cloth film has been used for a long history of 201137199, but due to the addition of plasticizers (such as phthalic acid salts) and stabilizers containing heavy metals, there are environmental pollution problems of dust and exhaust gas in the process. When the pvc fiber composite cloth film is used up, it will also produce the poison of the world. The Registration, valuation and authorization of Chemicals will clearly not only use pvc products, but also the world. Major manufacturers such as Nike, • MatSUShlta, GM and Sony banned PVC in 2000, 2000, 2002 and 2004 respectively. The calendering process has the problem of dust and waste gas pollution in the case of PVC fiber composite cloth film products, because the pvc resin is powdery, and the card is added with a large amount of plasticizer. On the other hand, the calendering process has the advantages of high yield, easy control, and good thickness, and is suitable for mass production to reduce the cost. Recently, there are many patented inventions using # pvc material at home and abroad. It is not limited to the category of fiber composite cloth film, and most of them use the chemical (tetra) olefin (TPG) as the main body. Due to the long-term exposure of the extended process to high temperature and open environment, the thermal stability of the thermoplastic polyolefin is insufficient, it is easy to add, thermal cracking affects the quality of the product, and the thermoplastic polyolefin is prone to occur in the sticky wheel. Formability. Even if it is overcome by adding a modifier, the thermoplastic polyolefin has insufficient melt strength and is liable to cause drawing breakage during thermoforming. Even after overcoming the above problems, thermal 201137199 plastic polyolefins must face the nature of their lack of polarity, with the result that it is difficult to work with fabrics or dissimilar materials, and cannot be processed by high-frequency welding. Polyethylene made by traditional high pressure method, such as LDPE, has a wide molecular weight distribution, and more branches have a low melting point, which is easy to break at the weak point. Conversely, Exxon's Shuangmao Metal locene PE ' m - PE) is uniform in molecular size and concentrated in distribution, and the branching frequency obtained by co-polymerization of copolyester is also uniform, so its impact strength is the traditional low-density polyethylene LDPE 4 It is better, but it still lacks long chain branch (LCB), so the melting strength is poor. Dow's single metallocene polyethylene has a slightly LCB to improve the melt strength. The impact strength is still three times better than conventional low density polyethylene LDPE. Dow Chemical Company's Ρ0Ε is a metallocene- ultra low density polyethylene (m_ULDPE), which is a polyolefin elastomer copolymerized with butene or octene. The molecular structure with LCB is suitable for row calendering. The method for preparing a polyolefin multi-layered floor tile with a foamed intermediate layer disclosed by Tarkett Aktiengsellschaft (U.S. Patent No. 5,763,501) is based on a Ρ0Ε or a benzophene (ppopiy〇ieHn plastomer') 'The use of a repeated calendering process produces a floor tile with an intermediate foam layer. However, this patent does not disclose the problem of blending any slip agent, but it is easy to make a sticky wheel in the calendering process; and the patent adds 20-50 parts of calcium carbonate to a polyolefin body of 1 part, which will The foaming process has an adverse effect. Further, the invention has not solved the problem of the subsequent problem with the foreign material, and therefore the product has no fabric layer and cannot be applied to the fiber composite cloth film. In view of the problems existing in the above-mentioned conventional structure, how to develop an innovative structure with more ideal and practicality, the consumers are eagerly awaiting, and the relevant industry must strive to develop the goal and direction of breakthrough. In view of this, the inventor has been engaged in the manufacturing development and design experience of related products for many years. After detailed design and careful evaluation of the above objectives, the inventor has finally obtained the practical invention. SUMMARY OF THE INVENTION In view of the above, an object of the present invention is to provide a fabric coated with a rubber copolymer, which is characterized in that a rubber copolymer is used as a raw material to be coated on a fabric to improve the sewing fastness and tear of the fabric. Strength and fastness to the yarn. The rubber copolymer may be a melting point (704 9 (rc) particles, a rubber copolymer film or a rubber emulsion copolymer. Another object of the present invention is to provide a method for coating a fabric with a rubber copolymer as a resin, copolymerizing the rubber The coating is applied to the fabric by impregnation or thermocompression coating. The resin can be recovered synchronously during the coating process, and the fiber composite fabric film can also be recycled and reused. 201137199 According to the invention, a rubber copolymer is used as a resin coating. a fabric comprising a rubber copolymer having a melting point (70 to 190 ° C) at a temperature of 200 ° C and a normal pressure, which can be converted into a water-soluble solution by solvent treatment, and the water-soluble resin can be coated or impregnated onto the fabric. In addition, the present invention provides another method for coating a fabric with a rubber copolymer as a resin, which is characterized in that the rubber copolymer is attached to the fabric by means of hot melt and lamination. The film is attached to the fabric by thermocompression bonding. The coated fabric of the rubber copolymer of the present invention is a rubber copolymer at a temperature of 200 C and often Pressed, can be turned into a water-soluble solution by solvent treatment, and can be coated on the fabric to adhere to the fabric to further obtain the coated fabric of the rubber copolymer of the present invention. The tear strength is 5 -30 lbf, latitudinal 5-30 lbf, abrasion resistance up to 2〇〇1〇〇〇rev 'coated fabric with a seam strength of 50-140 lbf. Techniques, means and effects of the invention DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The above-mentioned objects, structures and features of the present invention will be described in detail with reference to the accompanying drawings. The resin coated fabric of the melting point is a rubber resin as a coating resin raw material, including a melting point of 701901 201137199. The rubber copolymer can be converted into a water-soluble solution by a solvent treatment at a temperature of 200 C and a normal pressure, that is, a high temperature. Molecular solution, and the polymer solution simply means that a polymer monomer is dissolved in a solvent. The polymer monomer here refers to a rubber copolymer; the viscosity is 15 〇 to 3 〇〇〇〇 cps or less, Coated or transmitted The dyeing method is attached to the fabric, and the coating amount is in the range of 2〇2〇〇g/m2. The resin suitable for the present invention is a rubber copolymer, which may be a rubber emulsion, a φ poly, a melting point of 70 to 190 ° C rubber copolymer particles (granules) 5-40/zm) or film (thickness of 0.01 to 20.20 mm) ° Another form of the invention is a method of manufacturing a fabric coated with a rubber copolymer, comprising the following steps: As shown in the figure, the melting point of 7〇~l9 is first used (the rc rubber copolymer is placed in the reaction dad to react with the solvent (10), wherein the solvent is acetone, ethanol and water are mixed. The reaction temperature is 2〇〇. (: and under normal pressure, that is, high temperature and often waste (11), after the completion of the reaction, a water-soluble solution (20) is formed, and the addition of a tung fertilizer to adjust the viscosity makes it easy to apply on the fabric (30). The polyester-based coated fabric obtained by the invention has a tear strength warp direction, a weft direction of 5-30 lbf, an abrasion resistance of up to 2004 〇〇〇 rev, and an early seam strength of 50-140. The lbf coated fabric improves the sewn fastness, dry tear strength and fastness (40). Referring to the second figure, the present invention has a melting point of 9
70〜19〇°C橡膠共聚物 i S 201137199 (5〇) ’經融炫狀態（60) ’再塗佈或淋膜在織物（70)上，如 此得以提尚車縫牢度、撕裂強度及綁紗牢度（80)。 於本發明的另一型態，以橡膠共聚物薄膜以熱壓合方 式附著在織物上。經本發明所製得的以橡膠共聚物為樹脂 的壓合織物，其具有撕裂強度5-30 lbf，耐磨性可達 200-2000 rev ,車縫強度50-150 lbf的塗敷織物。 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易僅，下文特舉出較佳實施例，作詳細說明如下： 〔實施例〕 實施例1. 將70〜19〇。(：橡膠共聚物放入反應釜裏與溶劑一起在溫 度200 C及常壓下反應，可反應形成水溶性溶液15〇cps， 再加增稠劑調整黏度18〇〇〇 cps，以塗佈或透過浸染方式附 著在織物上，塗布量5〇g/m2。其中塗佈方式為將高分子溶 液直接塗佈至織物上；浸染方式為將織物浸泡於橡膠共聚 物咼分子溶液中，然後以滾壓將多餘的橡膠共聚物塗液去 除。 所製得纖維複合布膜依據ASTM _D〜2261測·試其撕裂強 度、依據ASTM -3884-92測試其耐磨檢驗及測試其車縫強 度。各數據如表1所示。 201137199 表1 撕裂強度（lbf) 耐磨強度 (rev) i縫強度 (lbf) 經向 緯向 實施例1 13.3 12.1 850 110 比較實施例1 7.3 7.2 900 97.5 實施例2. 將橡膠共聚物薄膜以熱壓合方式固著在織物上，膜厚 度0. 06mm。所製得壓合織物依實施例1的測試方法測得數 • 據如表2所示。其中熱壓合方式係將橡膠共聚物薄膜利用 高壓熱壓將橡膠共聚物薄膜貼合於織物。 表2 撕裂強度（lbf ) 耐磨強度 (rev) 車縫強度 (lbf) 實施例2 13. 3x12. 1 550 108 [^較實施例2 8.2x8.5 250 105 實施例3. 將橡膠共聚物以熱融淋膜方式附著在織物上，塗佈量 75 g/m2。所製得壓合織物依實施例1的測試方法測得數據 如表3所示。其中熱融淋膜方式係使用橡膠共聚物經由融 炫1形成融熔狀態，然後透過淋膜方式附著在織物上。 表3 撕裂強度（lbf) 耐磨強度 (rev) 車縫強度 (lbf) 施例3 23. 5 450 120 201137199 比較實施例1. 依實施例1的織物塗敷方法將樹脂附著在織物上所 不同是樹脂使用熱固型PU樹脂。所製得塗敷織物依實施例 1的測试方法測得各數據如表1所示。 比較實施例2. 依實施例2的織物以薄膜，膜厚度〇〇6mm ’壓合方式 將橡膠共聚物薄膜附著在織物上，所不同是樹脂使用一般 薄膜。所製得薄膜壓合織物依實施例丨的測試方法測得各 · 數據如表2所示。 雖然本發明已以較佳實施例揭露如上，然其並非用以 限定本發明。任何熟習此技藝者，在不脫離本發明之精神 和範圍内’當可作些許之更動與潤飾。因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 φ 第一圖：為橡膠共聚物水溶性溶液，塗敷在織物上的流程 圖。 第二圖：為橡膠共聚物藉由熱熔及淋膜的方式附著在織物 上的流程圖。 【主要元件符號說明】 (10)橡膠共聚物放入反應蚤裏與溶劑一起反應 12 201137199 (11)高溫常壓 (2 0 )水溶性溶液 (30)塗敷在織物 (40)提高車縫牢度、撕裂強度及綁紗牢度 (50)橡膠共聚物 (60)融熔狀態 φ (70)塗佈或淋膜在織物 (80)提高車缝牢度、撕裂強度及綁紗牢度70~19〇°C rubber copolymer i S 201137199 (5〇) 'The state of melting (60) 'Recoating or laminating on the fabric (70), so as to improve the sewing fastness and tear strength And the fastness of the yarn (80). In another form of the invention, the rubber copolymer film is attached to the fabric in a thermocompression bonding manner. The press fabric made of the rubber copolymer as a resin obtained by the present invention has a coated fabric having a tear strength of 5 to 30 lbf, an abrasion resistance of 200 to 2000 rev, and a sewn strength of 50 to 150 lbf. The above and other objects, features, and advantages of the present invention will become more apparent from the <RTIgt; <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; (: The rubber copolymer is placed in the reaction vessel and reacted with the solvent at a temperature of 200 C and normal pressure to form a water-soluble solution of 15 〇 cps, and a thickener is added to adjust the viscosity of 18 〇〇〇 cps to coat or Adhered to the fabric by dipping, the coating amount is 5〇g/m2, wherein the coating method is to directly apply the polymer solution to the fabric; the dip method is to soak the fabric in the rubber copolymer 咼 molecular solution, and then roll The excess rubber copolymer coating liquid is removed by pressing. The obtained fiber composite cloth film is tested for tear strength according to ASTM _D~2261, and its abrasion resistance test is tested according to ASTM -3884-92 and the joint strength is tested. The data is shown in Table 1. 201137199 Table 1 Tear strength (lbf) Abrasion resistance (rev) i-slit strength (lbf) Warp and weft Example 1 13.3 12.1 850 110 Comparative Example 1 7.3 7.2 900 97.5 Example 2 The rubber copolymer film is fixed to the fabric by thermocompression, and the film thickness is 0.06 mm. The obtained press fabric is measured according to the test method of Example 1. The data are as shown in Table 2. The method uses a high pressure of the rubber copolymer film The rubber copolymer film was bonded to the fabric by hot pressing. Table 2 Tear strength (lbf) Wear resistance (rev) Seam strength (lbf) Example 2 13. 3x12. 1 550 108 [^Comparative Example 2 8.2x8 .5 250 105 Example 3. The rubber copolymer was attached to the fabric by hot-melt coating, and the coating amount was 75 g/m 2 . The obtained press fabric was measured according to the test method of Example 1 as shown in Table 3. As shown in the figure, the hot-melt coating method uses a rubber copolymer to form a molten state through the melting, and then adheres to the fabric through a lamination method. Table 3 Tear strength (lbf) Wear resistance (rev) Seam strength (lbf) Example 3 23. 5 450 120 201137199 Comparative Example 1. The method of fabric coating according to Example 1 was carried out by attaching a resin to a fabric. The difference was that the resin was a thermosetting PU resin. The test method of Example 1 measured each data as shown in Table 1. Comparative Example 2. The woven fabric of Example 2 was adhered to the fabric by a film having a film thickness of 〇〇6 mm. The difference is that the resin is a general film. The film-bonded fabric produced is measured according to the example. The method of the present invention is as shown in Table 2. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention, and it is to be understood by those skilled in the art without departing from the spirit and scope of the invention. The scope of protection of the present invention is defined by the scope of the appended claims. [Simplified illustration] φ First: a water-soluble solution of a rubber copolymer, coated Flow chart on the fabric. Second: A flow chart for attaching a rubber copolymer to a fabric by means of hot melt and lamination. [Main component symbol description] (10) Rubber copolymer is placed in the reaction crucible and reacted with the solvent 12 201137199 (11) High temperature and normal pressure (20) Water-soluble solution (30) coated on the fabric (40) to improve the sewing Degree, tear strength and fastness to the yarn (50) rubber copolymer (60) melt state φ (70) coating or laminating on the fabric (80) to improve the sewing fastness, tear strength and fastness of the yarn
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