201137112 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種在用以改盖 成纖維、以及該等之混合纖維製^然纖維及聚酷等合 等之效果的去除各種爽雜物之步：=、染色、整理 劑組合物。 斤使用的纖維用精練 【先前技術】 Ο 天然纖維例如植物纖維中，樹脂 中，脂肪、膠狀物質等，另夕卜，_人成刀4，動物纖維 卜聚酯合成纖維坯布中，於 纺絲階段添加的大量之石壤或丙稀酸醋系、聚乙烯醇系等 :上浆劑等作為夹雜物而存在，若在精練步驟中不將= 疋全去除’則會引起乾燥步驟中之發煙或漂白、 理不均勻。 宜 於該精練步驟中，先前主要使用非離子性界面活性劑、 陰離子性界面活性劑'該等之混合物作為精練劑。例如， 〇 料非離子性界面活性㈣之精練劑，已知找基盼或高 級醇之氧化丙烯（以下簡稱為Ρ〇)或氧化乙烯（以下簡稱為 ΕΟ)加成物，具體而言，於專利文獻！、2中，分別揭示有特 疋之芳香族及脂肪族醇之ΕΟ·Ρ〇·Ε〇三嵌段加成物，於專 利文獻3中，揭示有特定醇之ρ〇 ·Ε〇 · ρ〇三嵌段加成物。 該等均係以低泡性、高滲透性為目的。另外，於專利文獻4 中’揭示有一種以Ε〇、ρ〇對特定之醇進行無規加成後加成 所成的將非離子性界面活性劑與陰離子性界面活性劑 以特定比率併用的精練劑組合物，據記載其於高濃度或低 153874.doc 201137112 溫下之黏度較低。 上述中 ㈣文獻1為日本專利特公昭62-54840,專利文 獻2為日本專利特開昭47_9561 ^ ^ 寻W文獻3為日本專利公報 ，文獻4為曰本專利特開平8·6〇532。 【發明内容】 本發明係關於一種敏维用籍錄漁丨&入 纖、准用精練劑組合物，其係含有（Α) =通式0)所示之非離子性界面活性劑[以下，稱為（Α)成 刀]者，且⑷成分中’通式⑴中之R為碳數㈣之-級直鏈 飽和經基的非離子性界面活性劑之比例為轉耳％以上； R-〇-(PO)m-(E〇)n-H (1) [式中，R表示碳數6〜24之烴基，p〇表示丙稀氧基，聯示 乙稀氧基;m係丙婦氧基之平均加成莫耳數，為〇·5〜5之數； η係乙婦氧基之平均加成莫耳數，為3〜3〇之數；再者， (P〇)m、（ΕΟ)η係以此順序嵌段鍵結]。 進而’本發明係提供—種包括用上述組合物處理纖維的 纖維精練方法以及上述組合物的精練纖維之用途。 【實施方式】 f利文獻1中記載的院絲之的或阳加成物由於具有烧 基苯齡基，故而就原料之天然化之觀點而言並不佳，專利 文獻2或專利文獻3中記載的非離子性界面活性_ μ# 泡性’但高驗條件下之精練性較差。另外，專利文獻4之精 練劑組合物雖併用陰離子性界面活性劑而可高濃度化，但 高驗條件下之精練性仍不充分，期待進一步改良。 亦即，目前尚未獲得一種於高鹼條件下亦具有優異之精 153874.doc 201137112 練性、低起泡性，且併用陰離子性界面活性劑時可將有效 成分濃縮之精練劑組合物。 根據本發明，可提供一種於高鹼條件下亦具有優異之精 . 練性、低起泡性，且併用陰離子性界面活性劑時可將有效 成分濃縮之精練劑組合物。 本發明之（A)成分為上述通式（1)所示之聚氧化烯型非離 子性界面活性劑，於本發明中，（A)成分中的通式（1)中之r 為碳數8〜14之一級直鏈飽和烴基的非離子性界面活性劑之 比例為80莫耳％以上。通式（1)中，R表示碳數6〜24,較佳為 碳數8〜18之烴基。作為該烴基，可列舉直鏈或支鏈之烷基、 直鏈或支鏈之烯基、可經烷基或烯基取代之芳香族烴基 等，就高鹼條件下之精練性之觀點、及環境安全性之觀點 而言，較佳為選自直鏈或支鏈之烷基、以及直鏈或支鏈之 烯基中之基，更佳為選自直鏈烷基、及直鏈烯基中之基， 特佳為直鏈烷基。就環境安全性之觀點而言，較佳為來自 ◎ 於辛醇、癸醇、月桂醇、肉豆蔻醇等天然系高級醇之基。 (A)成分較佳為含有2種以上R之碳數不同的化合物。 於本發明中，（A)成分中的通式（1)中之R為碳數8〜14之一 •級直鏈飽和烴基的非離子性界面活性劑之比例為8〇莫耳％ 以上，就精練性之觀點而言，較佳為9〇莫耳％以上，更佳 為95莫耳％以上。 另外，於本發明中，就高鹼條件下之精練性之觀點而言， 較佳為（A)成分中的通式（1)中之R為碳數8〜1〇之一級直鏈 飽和烴基的非離子性界面活性劑之比例為5〜95莫耳％，更 153874.doc 201137112 佳為1〇〜9〇莫耳％，進而更佳為2〇〜80莫耳％，且R為碳數 11〜14之-級直鏈飽和烴基的非離子性界面活性劑之比例 。為5〜95莫耳％’更佳為1()〜9。莫耳％’進而更佳為2請莫耳 % 0 此外，於本發明巾’就高驗條件下之精練性以及提高作 為精練劑之濃度的觀點而言，較佳為㈧成分中的通式⑴ 中之R為正辛基的非離子性界面活性劑之比例為㈣莫耳 %，更佳為H)〜90莫耳％，更佳為25〜75莫耳％，進而更佳為 30〜70莫耳％。就同樣之觀點而言較佳為通式⑴中之r為 正十二院基的非離子性界面活性劑之比例為㈣莫耳％， 更佳為1〇〜90莫耳％，更佳為25〜75莫耳％，進而更佳為3"。 莫耳％。進而，於本發明中，就高驗條件下之精練性以及 提局作為精練劑之濃度的觀點而言，較佳為（A)成分包含通 式⑴中之R為正辛基的非離子性界面活性劑與㈣正十二 烷基的非離子性界面活性劑兩者，其等之合計量之比例較 佳為（A)成分中之10〜1〇〇莫耳％，更佳㈣〜⑽莫耳％，更 佳為5〇〜100莫耳％，進而更佳為60〜1〇〇莫耳％。 另外，於本發明中，就高鹼條件下之精練性以及提高作 為精練劑之濃度的觀點而言，較佳為⑷成分中的通式⑴ 中之R為碳數9〜10之烴基的非離子性界面活性劍之比例為 莫耳。/。，更佳為0〜20莫耳％，更佳為〇〜1〇莫耳％，進而 更佳為0〜5莫耳％。就同樣之觀點而言，較佳為通式⑴中之 R為碳數U〜14之烴基（其中，正十二烧基除外）的非離子性 界面活性劑之比例為〇〜30莫耳％，更佳為〇〜2〇莫耳％，更佳 153874.doc 201137112 為Ο〜10莫耳％，進而更佳為〇〜5莫耳％。 Ο Ο 構成⑷成分之聚氧化烯部係自通式⑴中之尺側起依序 後段加成以平均加成莫耳數計為G.5〜5莫耳之PQ、以平均加 成莫耳數計為3〜30莫耳之EO。若扣之平均加成莫耳數4 〇.5以上，則起泡性適度’若為5以下，則精練性良好。另 外，若E0之平均加成莫耳數„為3以上，則精練性良好，若 為25以下’則起泡性適度。對於m，就上述起泡性及精練性 之觀點而言，較佳為G.8〜4，更佳為卜3。對於n，就與_ 樣之觀點而言，較佳為4〜2〇，更佳為5〜15，進而更佳為 6〜U。又，藉由自尺側起形成（p〇)m、（E〇)n之嵌段結構，可 獲得精練性、低起泡性優異之精練劑組合物，且併用陰離 子性界面活性劑時容易將有效成分濃縮。⑷成分亦可：於 以R-OH(R為碳數6〜24之烴基）表示之醇之混合物上依序加 成特定量之氧化丙稀與氧化乙稀所成的非離子性界面活性 劑，且該醇之混合物中，R為碳數8〜14之直鏈飽和烴基的一 級醇之比例為80莫耳％以上。 通式（1)之非離子性界面活性劑例如可藉由下述製造方 法而獲得。除此之外，亦可應用以下方法而獲得：將利用 下述製造方法所製造之非離子性界面活性劑混合的方法； 依據下述製造方法製造通式（1)中之R為特定烴基的非離子 性界面活性劑後，將其與R為不同烴基之非離子性界面活性 劑混合的方法。 於可進行加熱、冷卻操作及減壓、加壓操作，具備原料 投入口、製品取出口、氧化烯及氮之導入管、攪拌裝置、 153874.doc 201137112 皿度计、麗力計的反靡 . 〜裔中’投入特定量的與本發明之通 式（1)中之R對應的醇、 幻如月曰肪族醇，繼而，投入固體狀 風氧化鉀或氫氧化鈉、或其等之水溶液等驗觸媒，或者 二知之酸觸媒後，進行氮置換，於常溫至⑽之溫度範圍 _ ，而’於80〜丨8〇。(：下依序導入特定量之 氣化丙烯與氧化乙稀，將其加纽上述醇上。 述加成反應操作中，更佳為在導人特定量之氧化丙稀 〆、氧化乙烯後’進行繼續反應直至壓力降低並達到一定壓 力為止的操作（熟成操作）。然後，向所獲得之反應粗產物中 、、’、'加適田里的公知之酸或鹼將觸媒中和藉此可獲得目標 、刀再者於中和操作中，亦可使用驗吸附劑或酸吸附 劑去除觸媒。 本發明之精練劑組合物較佳為含有陰離子性界面活性劑 作為（Β)成分。陰離子性界面活性劑有助於提昇高鹼條件下 之精練性。作為（Β)成分之具體例，可列舉：飽和或不飽和 脂肪酸、飽和或不飽和醇之硫酸酯，聚氧伸烷基烷基硫酸 酯（polyoxyalkylene alkyl sulfate)、聚氧伸烷基烷基單及二 磷酸酯（poly0xyalkylene alkyl mono/diphosphate)，以及該 等之鹽等。 s亥4之中，較佳為聚氧伸院基烧基_之磷酸酯、聚氧伸 烧基烧基醚之硫酸酯’具體而言聚氧伸烷基烷基硫酸酯、 聚氧伸烷基烷基單及二磷酸酯以及該等之鹼金屬、驗土金 屬等之無機鹽、有機鹼之鹽，其中更佳為鹼金屬之氫氧化 物、藉由有機鹼而部分或完全中和之鹽。 153874.doc 201137112 (A)成分可直接用作本發明之精練劑組合物。另外，本發 明之精練劑組合物亦可為含有（Α)成分10〜100質量％，更佳 為20〜100質量％，進而更佳為3〇〜1〇〇質量％之組合物。 於本發明之精練劑組合物含有（Α)成分與（Β)成分之情形 時，（Α)成分於組合物中之含量較佳為ι〇〜8〇質量％，更佳為 1 5〜70質量。/〇’另外，（Β)成分於組合物中之含量較佳為 0.5〜50質量°/。，更佳為3〜4〇質量％，進而更佳為5〜3〇質量％。 此’（Α)成分與（Β)成分之含量的合計量於組合物中較佳 為25〜100質量％ ’更佳為5〇〜1〇〇質量％，特佳為55〜1〇〇質量 %。 本發明之精練劑組合物亦可含有水。水之含量較佳為 0〜75質量％ °先前之精練劑係製成水以外之有效成分之濃 度為15〜50質量％左右的水溶液而流通，但於本發明中，由 於即便進一步提高有效成分之濃度，精練劑組合物之黏度 亦較低’因此可不損害操作性而濃縮。因此，水之含量較 ❹ 佳為50質量％以下，特佳為45質量％以下。 本發明之精練劑組合物由於為低起泡性，因此亦適用於 喷射染色機、高溫高壓染色機等需要當心產生氣泡之精練。 另外’本發明之精練劑組合物中，亦可視需要混合或併 用·聚氧乙稀燒基醚等其他非離子性界面活性劑，乙二胺 四醋酸（EDTA)、氮川三醋酸（NTA)、聚（甲基）丙烯酸、（曱 基）丙稀酸•順丁烯二酸共聚物等螯合分散劑，蘇打灰、苛 性納等驗輔助劑以及聚氧伸烷基醚系、矽油系、礦物油系 等之消泡劑等化學劑。 153874.doc 201137112 本發明之精練劑組合物係根據布料上所含之污潰，以有 效成分濃度、即（A)成分濃度或（A)成分與（B)成分之合計濃 度為0.1〜10 g/L，視需要添加之鹼輔助劑為〇_2〜5 g/L，螯合 劑為0.05〜5 g/L之方式用精練步驟通常使用之水及/或其他 溶劑稀釋後使用。 本發明之精練劑組合物可適用於棉、麻、羊毛等天然纖 維’聚酯、尼龍、嫘縈（rayon)、三醋酸纖維等化合纖維以 及該等之混紡交織纖維。精練方法為通常之批次處理、連 續處理之任一者均可’精練溫度亦根據纖維之種類而不 同，通常為室溫〜l4〇°C，較佳為50〜130。(：。 實施例 以下之實施例係就本發明之實施而進行說明。實施例僅 為說明本發明之示例者’並非用於限定本發明。 以下’揭示實施例、比較例中使用之非離子性界面活性 劑之製造例及比較製造例（為方便起見，「非離子性界面活 性劑（14)」及「聚氧乙烯（平均加成莫耳數為2 〇)月桂醚硫 酸· Na鹽」亦分別表示為比較製造例6、製造例9)。以下之 說明中，「Cp」表示碳數為p之直鏈一級飽和烴基，「Cp_〇H」 表示具有碳數為ρ之直鏈飽和烴基之一級醇。 製造例1 :非離子性界面活性劑（1)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中，投入碳數為8之直鏈飽和一級醇[商品名：Kaic〇i 0898，花王（股）製造]65.! [商品名：Kalcol 2098， g、與碳數為12之直鏈飽和一級醇 花王（股）製造]93.2 g之混合醇 153874.doc -10- 201137112 (08-011/0：12_011=5 0/50(莫耳比）），以及氫氧化鉀1.1§，於 110°C、1.3 kPa(絕對壓力）下脫水30分鐘後，進行氮置換。 氮置換後，升溫至125 °C，導入氧化丙稀145.2 g，進行加 成反應.熟成操作。繼而，升溫至150。(：，導入氧化乙烯308.4 §， 進行加成反應•熟成操作。反應結束後，冷卻至8〇。(：，然 後向高壓爸内添加乳酸1.8 g，於80 °C下授拌30分鐘後，進 行萃取’獲得本發明之非離子性界面活性劑（1)[通式 中 ’ R . C8/C12=50/50(莫耳比），^==2.5，n==7]。 製造例2 :非離子性界面活性劑（2)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 爸中’ ^又入$厌數為8之直鍵飽和一級醇[商品名：Kalcol 0898，花王（股）製造]65.1 g、與碳數為12之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93.2 g之混合醇 (C8-OH/C12-OH=50/50(莫耳比）），以及氫氧化鉀丨」g，於 110 C、1.3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後’升溫至125°C，導入氧化丙烯145.2 g，進行加 成反應•熟成操作。繼而，升溫至15〇它，導入氧化乙烯66〇8 g， 進行加成反應•熟成操作。反應結束後，冷卻至8〇c»c，然 後向尚壓爸内添加乳酸1 ·8 g，於80。〇下搜拌3〇分鐘後，進 打萃取’獲得本發明之非離子性界面活性劑（2)[通式（1) 中 ’ R : C8/C12=50/50(莫耳比），m=2 5，n=15]。 氩ie例3 .非離子性界面活性劑（3 )之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 爸中’投入碳數為8之直鏈飽和一級醇[商品名：Kalc〇1 153874.doc 201137112 0898，花王（股）製造]32.6 g、碳數為10之直鍵飽和一級醇[商 品名：Kalcol 1098 ’花王（股）製造]39.6 g、碳數為12之直鏈飽 和一級醇[商品名：Kalcol 2098，花王（股）製造]46.6 g、及碳 數為14之直鏈飽和一級醇[商品名：Kalcol 4098，花王（股）製 造]53.6 g 之混合醇（C8-OH/C10-OH/C12-OH/C14-OH=25/25/25/25 (莫耳比））’以及氫氧化If 1.1 g，於110°C、1 ·3 kPa(絕對壓 力）下脫水3 0分鐘後，進行氮置換。 氮置換後’升溫至125t，導入氧化丙烯145.2 g，進行加 成反應•熟成操作。繼而，升溫至150。(：，導入氧化乙烯440.5 g， 進行加成反應•熟成操作。反應結束後，冷卻至8〇°c，然 後向高壓釜内添加乳酸1.8 g，於80°C下攪拌30分鐘後，進 行萃取’獲得本發明之非離子性界面活性劑（3)[通式（1) 中 ’ R : C8/C10/C12/C14=25/25/25/25(莫耳比），m=2.5， n= 1 0]。 製造例4 :非離子性界面活性劑（4)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中，投入碳數為8之直鏈飽和一級醇[商品名·· Kalcol 0898’花王（股）製造]58.6g、碳數為12之直鏈飽和一級醇[商 品名：Kalcol 2098，花王（股）製造]83.8 g、碳數為16之直鏈飽 和一級醇[商品名：Kalcol 6098，花王（股）製造]12.1 g、及碳 數為18之直鏈飽和一級醇[商品名：Kalcol 8098，花王（股）製 造]13.5 g 之混合醇（C8-OH/C12-OH/C16-OH/C18-OH=45/45/5/5 (莫耳比）），以及氫氧化鉀1·1 g，於110°C、1·3 kPa(絕對壓 力）下脫水30分鐘後，進行氮置換。 153874.doc -12· 201137112 氮置換後，升溫至125°C，導入氧化丙烯145.2 g，進行加 成反應•熟成操作。繼而，升溫至丨⑽它，導入氧化乙烯3〇8 4 g， 進行加成反應•熟成操作。反應結束後，冷卻至8〇〇C，然 - 後向命壓爸内添加乳酸1.8 g，於80°C下擾拌30分鐘後，進 行萃取’獲得本發明之非離子性界面活性劑[通式 中，R: C8/C12/Cl6/C18=45/45/5/5(莫耳比），m=2.5，n=7]。 製造例5 :非離子性界面活性劑之製造 〇 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 爸中’投入碳數為8之直鏈飽和一級醇[商品名：Kalc〇1 0898,花王（股）製造]97.7 g、碳數為12之直鏈飽和一級醇[商 品名：Kalc〇1 2098，花王（股）製造]23.3 g、及碳數為14之直 鏈飽和一級醇[商品名：Kalcol 4098，花王（股）製造]26.8 g 之混合醇（08-〇出(：12-〇^1/(：14-011=75/12.5/12.5(莫耳比））， 以及氫氧化鉀1.1 g，於110它、1 3 kPa(絕對壓力）下脫水3〇 分鐘後，進行氮置換。 Q 氮置換後，升溫至125。(：，導入氧化丙烯145.2 g，進行加 成反應•熟成操作。繼而’升溫導入氧化乙稀 308.4 g，進行加成反應.熟成操作。反應結束後，冷卻至 8 0 C，然後向高壓爸内添加乳酸1.8 g，於8 〇 °c下授拌3 〇分 鐘後，進行萃取，獲得本發明之非離子性界面活性劑（5)[通 式⑴中 ’ R : C8/C12/C14=75A2.5/12.5(莫耳比），m=2.5， n=7]。 製造例6 :非離子性界面活性劑（6)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 153874.doc -13· 201137112 爸中’投入碳數為8之直鏈飽和一級醇[商品名：Kal col 0898 ’花王（股）製造]65.1 g、與碳數為12之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93.2 g之混合醇 (C8-OH/C12-OH=50/50(莫耳比）），以及氫氧化鉀u g，於 ll〇°C、1.3 kPa(絕對壓力）下脫水30分鐘後，進行氮置換。 氮置換後’升溫至125°C，導入氧化丙烯203.3 g ,進行加 成反應•熟成操作。繼而，升溫至150°C ,導入氧化乙烯3〇84g , 進行加成反應•熟成操作。反應結束後，冷卻至8 〇 ，然 後向高壓釜内添加乳酸1.8 g，於80°C下攪拌30分鐘後，進 行萃取’獲得本發明之非離子性界面活性劑（6)[通式（i) 中，R : C8/C12 = 50/50(莫耳比），m=3.5，n=7]。 製造例7 :非離子性界面活性劑（7)之製造 於包括授拌裝置、溫度控制裝置、自動導入裝置之高壓 蒼中’投入碳數為8之直鏈飽和一級醇[商品名：Kaic〇1 0898，花王（股）製造]65.1 g、與碳數為12之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93.2 g之混合醇 (C8-OH/C12-OH=50/50(莫耳比）），以及氫氧化鉀丨1 g，於 ll〇°C、1·3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後，升溫至125。(：，導入氧化丙烯l45.2g，進行加 成反應.熟成操作。繼而，升溫至150。(：，導入氧化乙烯22〇 3 g， 進行加成反應•熟成操作。反應結束後，冷卻至8 〇 ，然後 向高壓釜内添加乳酸1.8 g，於80。(：下攪拌30分鐘後，進行 萃取，獲得本發明之非離子性界面活性劑（7)[通式（1)中， R : C8/C12 = 50/50(莫耳比），m=2.5，n=5]。 153874.doc •14- 201137112 裝is·例8 .非離子性界面活性劑（8)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中，投入碳數為10之直鏈飽和一級醇[商品名：Kalc〇1 1098’ t王（股）製造]mjg、及氫氧化鉀jig，於削。c、 1.3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後，升溫至125。(：，導入氧化丙烯145 2 g，進行加 成反應•熟成操作。繼而，升温至15〇。〇，導入氧化乙烯3〇84g， 進行加成反應.熟成操作。反應結束後，冷卻至8 〇 ，然 後向高壓釜内添加乳酸1.8 g，於8(rC下攪拌3〇分鐘後，進 行萃取’獲得本發明之非離子性界面活性劑（8)[通式（1) 中 ’ R : CIO，m=2.5，n=7]。 比較製造例1 :非離子性界面活性劑（9)之製造 於包括授拌裝置、溫度控制裝置、自動導入裝置之高壓爸 中’投入碳數為8之直鏈飽和一級醇[商品名：Kalcol 0898， 花王（股）製造]45.6 g、碳數為12之直鏈飽和一級醇[商品名： Kalcol 2〇98’花王（股）製造]65,2g、碳數為16之直鏈飽和一 級醇[商品名：Kalcol 6098，花王（股）製造]36.4 g、及碳數為 18之直鍵飽和一級醇[商品名：Kalcol 8098，花王（股）製 造]40_6 g之混合醇（C8-OH/C12-OH/C16-OH/C18-OH=35/35/15/15 (莫耳比）），以及氫氧化鉀1.1 g，於ll〇°C、1,3 kPa(絕對壓 力）下脫水30分鐘後，進行氮置換。 氮置換後’升溫至125°C，導入氧化丙烯145_2g，進行加 成反應•熟成操作。繼而’升溫至150°C，導入氧化乙稀308.4 g， 進行加成反應•熟成操作。反應結束後，冷卻至8〇°C，然 153874.doc •15· 201137112 後向高壓爸内添加乳酸1.8 g，於8〇。(：下攪拌30分鐘後，進 行萃取’獲得比較用之非離子性界面活性劑（9)[通式（1) 中 ’ R: C8/C12/C16/C18=35/35/15/15(莫耳比），m=2.5，n=7]。 比較製造例2 :非離子性界面活性劑（丨〇)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中’投入碳數為8之直鏈飽和一級醇[商品名：Kalc〇1 0898，花王（股）製造]65.1 g、與碳數為丨2之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93」§之混合醇 (C16-OH/C18-OH=5 0/50(莫耳比）），以及氫氧化鉀丨」g，於 110 C、1.3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後，升溫至125。(：，導入氧化丙烯348.5 g，進行加 成反應•熟成操作。繼而，升溫至15〇°c，導入氧化乙烯308.4 g， 進行加成反應•熟成操作。反應結束後，冷卻至8〇它，然 後向咼壓爸内添加乳酸1.8 g，於8〇。〇下擾拌3〇分鐘後，進 行萃取，獲得比較用之非離子性界面活性劑（1〇^通式〇) 中，R : C8/C12=50/50(莫耳比），m=6，η=7]。 比較製造例3 .非離子性界面活性劑（11)之製造 於包括攪拌裝置、溫度控制裝置' 自動導入裝置之高壓 釜中，投入碳數為8之直鏈飽和一級酵[商品名：Kalc〇1 0898 ,彳匕王（股）製造]65.1 g、與碳數為12之直鏈飽和一級醇 [商品名.Kalcol 2098，花王（股）製造]93 ! 混合酵 (C16-OH/C18-OH=50/50(莫耳比）），以及氫氧化鉀i」g，於 ll〇°C、1.3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後，升溫至125°C，導入氧化丙烯145.2 g，進行加 153874.doc -16 - 201137112 成反應•熟成操作。繼而，升溫至15 0°c，導入氧化乙烯 1541.8g，進行加成反應•熟成操作。反應結束後’冷卻至 8〇°C，然後向高壓釜内添加乳酸1.8 g，於80°C下攪拌30分 鐘後’進行萃取，獲得比較用之非離子性界面活性劑（11)[通 式（1)中，R : C8/C12=50/50(莫耳比），m=2.5，n=35]。 比較製造例4 :非離子性界面活性劑（12)之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中，投入碳數為8之直鏈飽和一級醇[商品名：Kaleol 〇 0898，花王（股）製造]65.1 g、與碳數為之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93·ι g之混合醇 ((：16-011/(：18-011=5 0/50(莫耳比）），以及氫氧化鉀1.1§，於 110°C、1.3 kPa(絕對壓力）下脫水3〇分鐘後，進行氮置換。 氮置換後，升溫至125X：，導入氧化丙烯17.4 g，進行加 成反應.熟成操作。繼而，升溫至15〇。(：，導入氧化乙烯3〇84 g，進行加成反應•熟成操作。反應結束後，冷卻至8〇〇c， Q 然後向南壓爸内添加乳酸1,8 g，於8〇°C下攪拌30分鐘後， 進行萃取，獲得比較用之非離子性界面活性劑（12)[通式（1) 中 ’ R: C8/C12=50/50(莫耳比），m=〇 3，n=7]。 比較製造例5 .非離子性界面活性劑（13 )之製造 於包括攪拌裝置、溫度控制裝置、自動導入裝置之高壓 釜中，扠入奴數為8之直鏈飽和一級醇[商品名：Kaie〇i 0898’花王（股）製造]65.lg、與碳數為12之直鏈飽和一級醇 [商品名：KalC〇1 2098 ’花王（股）製造]93.1 g之混合醇 (C16-OH/C18_OH=50/50(莫耳比）），以及氫氧化卸ig，於 153874.doc 201137112 110°C、1.3 kPa(絕對壓力）下脫水30分鐘後，進行氮置換。 氮置換後，升溫至125°C，導入氧化丙烯145 2 g，進行加 成反應•熟成操作。繼而，升溫至i 5〇t：，導入氧化乙烯 88.1 g，進行加成反應•熟成操作。反應結束後，冷卻至 80C ’然後向咼壓爸内添加乳酸1.8 g，於8〇。〇下撥拌分 鐘後，進行萃取，獲得比較用之非離子性界面活性劑（13)[通 式（1)中，R: C8/C12=50/50(莫耳比），m=2.5 , n=2]。 比較製造例6 :非離子性界面活性劑（14) 使用日本觸媒（股）製造之S〇ftan〇l 7〇(直鏈型二級醇之氧 化乙烯加成物）作為非離子性界面活性劑（14)。 比較製造例7 .非離子性界面活性劑（15 )之製造 於包括攪拌裝置、溫度控制裝置' 自動導入裝置之高壓 蚤中，投入合成醇[商品名：8八戶0[23(8八801^公司製造）， 具有碳數12、13之支鏈烷基[碳數ι2/碳數13 = 55/45(莫耳 比）’分支率（分支型醇之質量組成）為5〇質量％]的飽和 醇]194 g、及氫氧化卸I」g，於"ο、I·] kp a(絕對壓力） 下脫水30分鐘後，進行氮置換。 氮置換後，升溫至125。(：，然後導入氧化丙烯丨45.2 g ,進 行加成反應•熟成操作。繼而，升溫至i5〇t，導入氧化乙 烯308.4 g，進行加成反應•熟成操作。反應結束後，冷卻 至80 C ’然後向高壓釜内添加乳酸丨8 g，於8〇°c下攪拌3〇 分鐘後’進行萃取’獲得比較用之非離子性界面活性劑 (15)[通式（1)中，r包含支鏈烷基（分支率為5〇質量％)， m=2.5，n=7]。 153874.doc -18- 201137112 比較製造例8 :非離子性界面活性劑（16)之製造 於包括攪拌裝置、溫度控制裝置、自動導入|置之高壓 釜中，投入碳數為8之直鏈飽和一級醇[商品名·· Kalc〇1 0898,花王（股）製造]65.1 g、與碳數為丨2之直鏈飽和一級醇 [商品名：Kalcol 2098，花王（股）製造]93·2 §之混合酵 (C8-OH/C12-OH=50/50(莫耳比）），以及氫氧化鉀i」g，於 110°C、1.3 kPa(絕對壓力）下脫水30分鐘後，進行氮置換。 〇 氮置換後，升溫至150°C，導入氧化丙烯145.2§及氧化乙 烯308.4 g，進行無規加成反應•熟成操作。反應結束後， 冷卻至80°C，然後向高壓釜内添加乳酸18 g,於8〇。〇下攪 拌30分鐘後，進行萃取，獲得比較用之非離子性界面活性 劑（16)[通式⑴中，R: C8/C12 = 5〇/5〇(莫耳比），m=2 5，n=7(但 係進行無規加成）]。 〈實施例1及比較例1 > 根據下述中所示之方法，評價包含製造例及比較製造例 〇 所得之非離子性界面活性劑（1)〜（16)的精練劑組合物之性 能:將結果歸納示於表！。再者，纟中，為方便起見，將並 不符u (A)成分之非離子性界面活性劑亦表示為（八）成分。 [精練性之評價（棉之殘脂率）] 以下述條件對棉坯布（殘脂率為1〇5質量％)進行精練處 理’自經精練處理之坯布切割出約3〜4g之試驗試樣，使用 2喊作為萃取溶劑，用索氏（s〇xhlet)萃取裝置（東海計器 製進订萃取操作。4小時之萃取操作後，於減壓下蒸餘 去除萃取洛劑，測定殘留物之質量，藉由以下之計算式求 153874.doc -19- 201137112 出殘脂率。 殘脂率（％)=(蒸餾去除萃取溶劑後之殘留物之質量/試驗 试樣之質量）X 100 *精練處理條件 精練劑組合物（非離子性界面活性劑）濃度：1〇 g/；L 苛性鈉濃度：1.0 g/L 精練時間：20分鐘 精練溫度：1 l〇°C 浴比：1/20 處理水：3°DH [精練性之評價（上吸高度）] 以上述條件對棉坯布進行精練處理，自處理後之布料上 取寬3 cm長15 cm之樣品布料，以樣品布料之—端浸沒 於盛滿冷解有染料之水溶液的缸上的方式，以無鬆弛之狀 態錯直地懸掛樣品布料’測定15分鐘後染料水溶液之上吸 同度（mm)，藉此檢查精練性。上吸高度越高，表示潤濕性 越優異，精練劑之精練性越優異。 [精練性之評價（滴下法）] 自經精練處理之^布切割出5咖5⑽之試驗試樣水平 放置用滴管自試樣述布上方約1 cm處滴落0.1 mL的上吸 间度之評 <貝中所使用之染料水溶液。自然乾燥後，根據染 料水洛液之擴展形狀而判定吸水性。評價基準如下所述。 〇木料擴展成較大之圓形，直徑1 cm之圓可收納於染 色之範圍中。 μ 153S74.doc •20· 201137112 △:染料之擴展不充分，或者染料之擴展形狀較扁，直 徑7 mm之圓可收納於染色之範圍中，但無法收納丨之圓。 X :直徑7 mm之圓無法納入於染色之範圍中。 [起泡性之評價] 於1 L之量茼中裝入試驗液（非離子性界面活性劑濃度： 2·00χ10_3 m〇l/L，剩餘部分為水）2〇〇社，藉由安裝有纖維 球過濾器（baU filter)之空氣泵，自量筒之底部以μ L/min 充送空氣’測定2分鐘後之起泡高度（mm)。 〇 153874.doc -21 - 201137112201137112 VI. Description of the Invention: [Technical Field] The present invention relates to a kind of removing various kinds of impurities in the effects of being used for changing the fibers, and the mixed fibers of the fibers and the like. Step: =, dyeing, finishing composition. The fiber used in the jin is refined [previous technique] 天然 natural fiber such as plant fiber, resin, fat, gelatinous substance, etc., in addition, _ human into a knife 4, animal fiber, polyester synthetic fiber fabric, in spinning a large amount of stone soil, acrylic acid vinegar, polyvinyl alcohol, etc. added in the silk stage: a sizing agent or the like exists as an inclusion, and if the 疋 is not removed in the scouring step, it may cause a drying step Smoke or bleach, uneven. Preferably, in the scouring step, a mixture of a nonionic surfactant, an anionic surfactant, and the like is used as a scouring agent. For example, a scouring agent for non-ionic interfacial activity (IV), which is known to be a propylene oxide (hereinafter abbreviated as ruthenium) or an ethylene oxide (hereinafter abbreviated as ruthenium) adduct of a ruthenium or higher alcohol, specifically, Patent literature! In 2 and 2, the triblock adducts of aromatic and aliphatic alcohols, which are characteristic of aromatics and aliphatic alcohols, are disclosed, and in Patent Document 3, ρ〇·Ε〇· ρ〇 of a specific alcohol is disclosed. Triblock adduct. These are all aimed at low foaming and high permeability. Further, Patent Document 4 discloses that a nonionic surfactant and an anionic surfactant are used in combination at a specific ratio by adding a specific alcohol to a specific alcohol and adding it to a specific ratio. The scouring composition is reported to have a low viscosity at a high concentration or a low temperature of 153874.doc 201137112. The above-mentioned (4) document 1 is Japanese Patent Publication No. Sho 62-54840, and Patent Document 2 is Japanese Patent Laid-Open No. 47_9561 ^ ^WW Document 3 is a Japanese Patent Gazette, and Document 4 is a Japanese Patent Laid-Open No. 8.6 532. SUMMARY OF THE INVENTION The present invention relates to a Minwei<RTI ID=0.0>&&&&&&&&&&&&&&&&&&&&&&& , in the component (4), the proportion of the nonionic surfactant in the formula (1) wherein R is a carbon number (four)-type linear saturated radical is more than or equal to the rotating ear; -〇-(PO)m-(E〇)nH (1) [wherein, R represents a hydrocarbon group having a carbon number of 6 to 24, p〇 represents an acryloxy group, and a ethyloxy group is bonded; The average addition mole number of the base is 〇·5~5; the average addition mole number of the η-type ethyl ethoxy group is 3~3〇; in addition, (P〇)m, ( ΕΟ) η is block bonded in this order]. Further, the present invention provides a fiber scouring method comprising treating a fiber with the above composition, and the use of the scouring fiber of the above composition. [Embodiment] The ortho-integrated product of the shovel described in the document 1 has a burnt-based benzene-based group, and therefore is not preferable from the viewpoint of naturalization of the raw material. Patent Document 2 or Patent Document 3 The described nonionic interfacial activity _ μ# bubbleability is poor in scouring under high test conditions. Further, the refining agent composition of Patent Document 4 can be made highly concentrated by using an anionic surfactant, but the refining property under high-test conditions is still insufficient, and further improvement is expected. Namely, there has not been obtained a scouring composition which is excellent in high alkali conditions and which is excellent in scouring, low foaming property, and which can concentrate an effective component when an anionic surfactant is used in combination. According to the present invention, it is possible to provide a scouring agent composition which has excellent refining properties under high alkali conditions, low foaming property, and can concentrate an effective component when an anionic surfactant is used in combination. The component (A) of the present invention is a polyoxyalkylene type nonionic surfactant represented by the above formula (1). In the present invention, r in the formula (1) in the component (A) is a carbon number. The ratio of the nonionic surfactant of the 8 to 14 one-stage linear saturated hydrocarbon group is 80 mol% or more. In the formula (1), R represents a hydrocarbon group having 6 to 24 carbon atoms, preferably 8 to 18 carbon atoms. Examples of the hydrocarbon group include a linear or branched alkyl group, a linear or branched alkenyl group, an aromatic hydrocarbon group which may be substituted by an alkyl group or an alkenyl group, and the like, and a viewpoint of scouring under high alkali conditions, and From the viewpoint of environmental safety, it is preferably a group selected from a linear or branched alkyl group and a linear or branched alkenyl group, more preferably selected from a linear alkyl group and a linear alkenyl group. The base of the group is particularly preferably a linear alkyl group. From the viewpoint of environmental safety, it is preferably a group derived from a natural higher alcohol such as octanol, decyl alcohol, lauryl alcohol or myristyl alcohol. The component (A) is preferably a compound containing two or more kinds of carbons having different R numbers. In the present invention, the proportion of the nonionic surfactant in the formula (1) in the component (1) in which R is a linear saturated hydrocarbon group having a carbon number of 8 to 14 is 8 〇 mol% or more. From the viewpoint of scouring, it is preferably 9% by mole or more, more preferably 95% by mole or more. Further, in the present invention, from the viewpoint of the scouring property under high alkali conditions, it is preferred that R in the formula (1) in the component (A) is a linear saturated hydrocarbon group having a carbon number of 8 to 1 Å. The ratio of nonionic surfactant is 5 to 95 mol%, more 153874.doc 201137112 is preferably 1〇~9〇mol%, more preferably 2〇~80mol%, and R is carbon number The ratio of the nonionic surfactant of the 11 to 14-stage linear saturated hydrocarbon group. It is preferably 5 to 95 mol%' more preferably 1 () to 9. Mohr%', more preferably 2, Momo% 0 In addition, in the viewpoint of the scouring property under the high-test condition and the concentration of the scouring agent, it is preferable that the formula (VIII) has a general formula (1) The proportion of the nonionic surfactant in which R is an n-octyl group is (iv) mol%, more preferably H) to 90 mol%, more preferably 25 to 75 mol%, and still more preferably 30~ 70% by mole. From the same viewpoint, it is preferred that the ratio of the nonionic surfactant in which the r in the formula (1) is a positive ortho-thoracic group is (four) mol%, more preferably from 1 to 90 mol%, more preferably 25 to 75 moles, and more preferably 3". Moer%. Further, in the present invention, from the viewpoint of the scouring property under high test conditions and the concentration of the scouring agent, it is preferred that the component (A) contains nonionicity in which R in the formula (1) is n-octyl group. The ratio of the surfactant to the (iv) n-dodecyl nonionic surfactant is preferably 10 to 1% of the component (A), more preferably (4) to (10). Mohr%, more preferably 5〇~100mol%, and even more preferably 60~1〇〇%. Further, in the present invention, in view of the scouring property under high alkali conditions and the improvement of the concentration as a scouring agent, it is preferred that R in the formula (1) in the component (4) is a hydrocarbon group having 9 to 10 carbon atoms. The ratio of the ionic interface active sword is Mohr. /. More preferably, it is 0 to 20% by mole, more preferably 〇~1〇% by mole, and further preferably 0 to 5% by mole. From the same viewpoint, it is preferred that the ratio of the nonionic surfactant in which the R in the formula (1) is a hydrocarbon group having a carbon number of U to 14 (excluding the n-dodecyl group) is 〇30 to 30 mol%. , better for 〇 ~ 2 〇 Moer %, better 153874.doc 201137112 for Ο ~ 10 Mo %, and thus better for 〇 ~ 5 Mo %. Ο Ο The polyoxyalkylene moiety constituting the component (4) is added sequentially from the flank of the formula (1) to the PQ of the G.5 to 5 molars in terms of the average addition mole number, and the average addition of the moir The number is 3 to 30 moles of EO. When the average molar amount of the buckle is 4 〇.5 or more, the foaming property is '5' or less, and the scouring property is good. In addition, when the average addition molar number of E0 is „3 or more, the scouring property is good, and if it is 25 or less, the foaming property is moderate. For m, from the viewpoints of the above foaming property and scouring property, it is preferable. It is G.8~4, more preferably it is 3. For n, it is preferably 4~2〇, more preferably 5~15, and even more preferably 6~U from the viewpoint of _. By forming a block structure of (p〇)m and (E〇)n from the flank side, a scouring agent composition excellent in scouring property and low foaming property can be obtained, and it is easy to be effective when an anionic surfactant is used in combination. The component is concentrated. The component (4) may also be a nonionic property of sequentially adding a specific amount of propylene oxide and ethylene oxide to a mixture of alcohols represented by R-OH (R is a hydrocarbon group having 6 to 24 carbon atoms). a surfactant, and a ratio of a primary alcohol having a linear saturated hydrocarbon group having 8 to 14 carbon atoms in the mixture of the alcohol is 80 mol% or more. The nonionic surfactant of the formula (1) can be borrowed, for example. It is obtained by the following production method. In addition, it can also be obtained by applying the following method: the non-ionic interface which is manufactured by the following manufacturing method is live. Method for mixing a mixture; a method of mixing a nonionic surfactant having a specific hydrocarbon group in the formula (1) with a specific hydrocarbon group in accordance with the following production method, and mixing the same with a nonionic surfactant having a different hydrocarbon group. It can be heated, cooled, decompressed, and pressurized. It has a raw material input port, a product take-out port, an introduction tube for oxyalkylene and nitrogen, a stirring device, and a reaction device for 153874.doc 201137112, a meter, and a caliper. A specific amount of an alcohol corresponding to R in the general formula (1) of the present invention, an imaginary aliphatic alcohol, and then a solid aqueous solution of potassium oxynitride or sodium hydroxide, or the like After the catalyst, or the acid catalyst of the second known, nitrogen substitution is carried out at a temperature ranging from room temperature to (10), and 'at 80 to 丨8〇. (:: a specific amount of vaporized propylene and ethylene oxide are sequentially introduced, It is added to the above-mentioned alcohol. In the addition reaction operation, it is more preferable to carry out the operation until the pressure is lowered and reaches a certain pressure after the specific amount of oxidized propylene oxide or ethylene oxide is introduced (cooking operation). Then, to the office In the reaction product, the known acid or base in the crude product is neutralized by the catalyst to obtain the target, and the knife can be used in the neutralization operation. The adsorbent or acid adsorption can also be used. The scouring agent composition of the present invention preferably contains an anionic surfactant as a (Β) component. The anionic surfactant helps to improve the scouring under high alkali conditions. Specific examples thereof include a saturated or unsaturated fatty acid, a sulfate of a saturated or unsaturated alcohol, a polyoxyalkylene alkyl sulfate, a polyoxyalkylene mono- and diphosphate (poly0xyalkylene). Alkyl mono/diphosphate), and the like. Among the shai 4, it is preferably a phosphate of a polyoxyl extension base, a sulfate of a polyoxyalkylene alkyl ether, specifically a polyalkylene alkyl sulfate, a polyoxyalkylene An alkyl group of mono- and di-phosphates, an inorganic salt of such an alkali metal, a soil-measuring metal, or a salt of an organic base, more preferably an alkali metal hydroxide, partially or completely neutralized by an organic base. salt. 153874.doc 201137112 The component (A) can be directly used as the scouring composition of the present invention. Further, the scouring composition of the present invention may be a composition containing 10 to 100% by mass, more preferably 20 to 100% by mass, still more preferably 3 to 1% by mass. In the case where the scouring agent composition of the present invention contains a (Α) component and a (Β) component, the content of the (Α) component in the composition is preferably ι 〇 8 〇 mass %, more preferably 1 5 〜 70 quality. Further, the content of the (Β) component in the composition is preferably from 0.5 to 50% by mass. More preferably, it is 3 to 4% by mass, and more preferably 5 to 3 % by mass. The total amount of the '(Α) component and the (Β) component is preferably from 25 to 100% by mass in the composition, more preferably from 5 to 1% by mass, particularly preferably from 55 to 1% by mass. %. The scouring composition of the present invention may also contain water. The content of the water is preferably from 0 to 75% by mass. The scouring agent is a solution in which the concentration of the active ingredient other than water is about 15 to 50% by mass, but in the present invention, even if the active ingredient is further increased The concentration of the scouring composition is also low, so that it can be concentrated without impairing handling. Therefore, the water content is preferably 50% by mass or less, and particularly preferably 45% by mass or less. Since the scouring composition of the present invention has low foaming property, it is also suitable for use in jet dyeing machines, high-temperature and high-pressure dyeing machines, and the like, which are required to be cautiously generated. In addition, in the scouring composition of the present invention, other nonionic surfactants such as polyoxyethylene alkyl ether, ethylenediaminetetraacetic acid (EDTA) and nitrogen triacetic acid (NTA) may be mixed or used as needed. , chelating dispersing agents such as poly(meth)acrylic acid, (mercapto)acrylic acid/maleic acid copolymer, soda ash, caustic soda, and polyoxyalkylene ether, eucalyptus oil, A chemical agent such as a defoamer such as mineral oil. 153874.doc 201137112 The scouring composition of the present invention is based on the stain contained in the fabric, and the concentration of the active ingredient, that is, the concentration of the component (A) or the total concentration of the components (A) and (B) is 0.1 to 10 g. /L, if necessary, the alkali adjuvant is 〇_2~5 g/L, and the chelating agent is 0.05~5 g/L, which is diluted with water and/or other solvent usually used in the scouring step. The scouring composition of the present invention can be applied to natural fibers such as cotton, hemp, and wool, such as polyester, nylon, rayon, triacetate, and the like, and the blended interwoven fibers. The scouring method can be any of the usual batch processing and continuous processing. The scouring temperature is also different depending on the type of the fiber, and is usually room temperature 〜14 ° C, preferably 50 to 130. The following examples are intended to illustrate the practice of the invention. The examples are merely illustrative of the invention and are not intended to limit the invention. The following is a description of the non-ionics used in the examples and comparative examples. Production examples of comparative surfactants and comparative production examples (for convenience, "nonionic surfactant (14)" and "polyoxyethylene (average addition mole number is 2 〇) lauryl ether sulfate · Na salt Also shown as Comparative Production Example 6 and Production Example 9). In the following description, "Cp" represents a linear first-order saturated hydrocarbon group having a carbon number of p, and "Cp_〇H" represents a linear chain having a carbon number of ρ. a saturated hydrocarbon group-based alcohol. Production Example 1: Production of a nonionic surfactant (1) In an autoclave including a stirring device, a temperature control device, and an automatic introduction device, a linear saturated primary alcohol having a carbon number of 8 is charged. Product name: Kaic〇i 0898, manufactured by Kao (share)] 65.! [Product name: Kalcol 2098, g, with a carbon number of 12 linear saturated primary alcohol Kao (stock)] 93.2 g of mixed alcohol 153874. Doc -10- 201137112 (08-011/0:12_011=5 0/50 (Mo Ear ratio)), and potassium hydroxide 1.1 §, dehydrated at 110 ° C, 1.3 kPa (absolute pressure) for 30 minutes, after nitrogen replacement. After nitrogen replacement, the temperature was raised to 125 ° C, introduced propylene oxide 145.2 g, The addition reaction is carried out, and the ripening operation is carried out. Then, the temperature is raised to 150. (:, introduction of ethylene oxide 308.4 §, addition reaction; ripening operation. After the reaction is completed, it is cooled to 8 Torr. (:, then lactic acid is added to the high pressure dad. 1.8 g, after 30 minutes of mixing at 80 ° C, extraction was carried out to obtain the nonionic surfactant (1) of the present invention [in the formula 'R. C8/C12=50/50 (mr ratio), ^==2.5, n==7]. Production Example 2: Non-ionic surfactant (2) was manufactured in a high-pressure dad including a stirring device, a temperature control device, and an automatic introduction device. 8 direct bond saturated primary alcohol [trade name: Kalcol 0898, manufactured by Kao (stock)] 65.1 g, with a carbon number of 12 linear saturated primary alcohol [trade name: Kalcol 2098, made by Kao (stock)] 93.2 g Mixed alcohol (C8-OH/C12-OH = 50/50 (mole ratio)), and potassium hydroxide 丨"g at 110 C, 1.3 kPa (absolute pressure) After dehydration for 3 minutes, nitrogen substitution was carried out. After nitrogen substitution, the temperature was raised to 125 ° C, 145.2 g of propylene oxide was introduced, and an addition reaction and a ripening operation were carried out. Then, the temperature was raised to 15 Torr, and ethylene oxide 66 〇 8 was introduced. g, Addition reaction and ripening operation. After the reaction is completed, cool to 8〇c»c, then add 1·8 g of lactic acid to 80. After mixing for 3 minutes, the extract is extracted to obtain the nonionic surfactant (2) of the present invention [in the formula (1), 'R: C8/C12=50/50 (mr ratio), m =2 5,n=15]. Argon Example 3. Non-ionic surfactant (3) Manufactured in a high-pressure dad including a stirring device, a temperature control device, and an automatic introduction device, a linear saturated primary alcohol having a carbon number of 8 is input [trade name: Kalc〇 1 153874.doc 201137112 0898, manufactured by Kao (stock)] 32.6 g, a direct carbon saturated primary alcohol with a carbon number of 10 [trade name: Kalcol 1098 'made by Kao (stock)) 39.6 g, linear saturation of carbon number 12 Primary alcohol [trade name: Kalcol 2098, manufactured by Kao (stock)] 46.6 g, and a linear saturated primary alcohol having a carbon number of 14 [trade name: Kalcol 4098, manufactured by Kao Co., Ltd.] 53.6 g of mixed alcohol (C8- OH/C10-OH/C12-OH/C14-OH=25/25/25/25 (Morby))' and hydroxide 1.1 g, dehydrated at 110 ° C, 1 · 3 kPa (absolute pressure) After 30 minutes, nitrogen substitution was performed. After the nitrogen substitution, the temperature was raised to 125 t, and 145.2 g of propylene oxide was introduced to carry out an addition reaction and a ripening operation. Then, the temperature is raised to 150. (:, introducing 440.5 g of ethylene oxide, performing an addition reaction and a ripening operation. After the completion of the reaction, the mixture was cooled to 8 ° C, and then 1.8 g of lactic acid was added to the autoclave, and the mixture was stirred at 80 ° C for 30 minutes, and then extracted. 'Obtaining the nonionic surfactant of the present invention (3) [in the formula (1) 'R : C8/C10/C12/C14=25/25/25/25 (mr ratio), m=2.5, n = 1 0]. Production Example 4: Production of a nonionic surfactant (4) In an autoclave including a stirring device, a temperature control device, and an automatic introduction device, a linear saturated primary alcohol having a carbon number of 8 was charged. Name ··················································································································· Alcohol [trade name: Kalcol 6098, manufactured by Kao (stock)] 12.1 g, and a linear saturated primary alcohol having a carbon number of 18 [trade name: Kalcol 8098, manufactured by Kao (stock)] 13.5 g of mixed alcohol (C8-OH) /C12-OH/C16-OH/C18-OH=45/45/5/5 (Morby)), and potassium hydroxide 1·1 g at 110 ° C, 1.3 kPa (absolute pressure) Dehydration 30 After a minute, nitrogen substitution was performed. 153874.doc -12· 201137112 After nitrogen substitution, the temperature was raised to 125 ° C, 145.2 g of propylene oxide was introduced, and an addition reaction and a ripening operation were carried out. Then, the temperature was raised to 丨 (10), and ethylene oxide 3 was introduced. 〇8 4 g, carry out the addition reaction and ripening operation. After the reaction is finished, cool to 8 ° C, then - add 1.8 g of lactic acid to the life pressure dad, and stir it at 80 ° C for 30 minutes, then extract 'The nonionic surfactant of the present invention is obtained [in the formula, R: C8/C12/Cl6/C18=45/45/5/5 (Morby ratio), m=2.5, n=7]. 5: The manufacture of non-ionic surfactants is based on a high-pressure dad including a stirring device, a temperature control device, and an automatic introduction device. A linear saturated primary alcohol having a carbon number of 8 is input [trade name: Kalc〇1 0898, Kao ( Manufactured] 97.7 g, a linear saturated primary alcohol having a carbon number of 12 [trade name: Kalc〇1 2098, manufactured by Kao), 23.3 g, and a linear saturated primary alcohol having a carbon number of 14 [product name: Kalcol 4098, manufactured by Kao (stock)] 26.8 g of mixed alcohol (08-〇出(:12-〇^1/(:14-011=75/12.5/12.5 (Morbi)) And 1.1 g of potassium hydroxide, which was dehydrated at 110 ° and 13 kPa (absolute pressure) for 3 minutes, and then subjected to nitrogen substitution. After the nitrogen substitution, the temperature is raised to 125. (:, 145.2 g of propylene oxide was introduced, and an addition reaction and a ripening operation were carried out. Then, 308.4 g of oxidized ethylene oxide was introduced at a temperature rise, and an addition reaction was carried out. After the completion of the reaction, it was cooled to 80 C, and then it was transferred to a high pressure dad. 1.8 g of lactic acid was added, and after mixing for 3 minutes at 8 ° C, extraction was carried out to obtain a nonionic surfactant (5) of the present invention [in the formula (1), 'R: C8/C12/C14=75A2. 5/12.5 (Morby ratio), m=2.5, n=7]. Production Example 6: Production of nonionic surfactant (6) in a high pressure 153874.doc including a stirring device, a temperature control device, and an automatic introduction device -13· 201137112 Dad's input of linear saturated primary alcohol with a carbon number of 8 [trade name: Kal col 0898 'made by Kao (stock)) 65.1 g, linear saturated alcohol with a carbon number of 12 [product name: Kalcol 2098, manufactured by Kao Co., Ltd.] 93.2 g of mixed alcohol (C8-OH/C12-OH=50/50 (Morby)), and potassium hydroxide ug at ll ° ° C, 1.3 kPa (absolute pressure) After dehydration for 30 minutes, nitrogen substitution was carried out. After nitrogen substitution, the temperature was raised to 125 ° C, and 203.3 g of propylene oxide was introduced to carry out an addition reaction. • Mature operation. Then, the temperature was raised to 150 ° C, and ethylene oxide 3 〇 84 g was introduced to carry out the addition reaction and the ripening operation. After the completion of the reaction, the mixture was cooled to 8 Torr, and then 1.8 g of lactic acid was added to the autoclave at 80 ° C. After stirring for 30 minutes, extraction was carried out to obtain the nonionic surfactant (6) of the present invention [in the formula (i), R: C8/C12 = 50/50 (mole ratio), m = 3.5, n =7]. Production Example 7: Production of a nonionic surfactant (7) in a high-pressure celestial medium containing a mixing device, a temperature control device, and an automatic introduction device, a linear saturated primary alcohol having a carbon number of 8 is input. Name: Kaic〇1 0898, manufactured by Kao (stock)] 65.1 g, linear saturated alcohol with a carbon number of 12 [trade name: Kalcol 2098, manufactured by Kao (stock)] 93.2 g of mixed alcohol (C8-OH/ C12-OH=50/50 (mole ratio)), and 1 g of potassium hydroxide ,, dehydrated at ll 〇 ° C, 1.3 kPa (absolute pressure) for 3 minutes, and then replaced with nitrogen. After nitrogen replacement The temperature was raised to 125. (:, 14.5 g of propylene oxide was introduced, and an addition reaction was carried out. The ripening operation was carried out. Then, the temperature was raised to 150. (:, introduction of ethylene oxide 22〇3 g After the completion of the reaction, the mixture was cooled to 8 Torr, and then 1.8 g of lactic acid was added to the autoclave at 80°. After stirring for 30 minutes, extraction was carried out to obtain a nonionic interface of the present invention. Active agent (7) [in the formula (1), R: C8/C12 = 50/50 (mole ratio), m = 2.5, n = 5]. 153874.doc •14- 201137112 Installation is Example 8. Non-ionic surfactant (8) is manufactured in an autoclave including a stirring device, a temperature control device, and an automatic introduction device, and is supplied with a linear saturation of 10 carbon atoms. Primary alcohol [trade name: manufactured by Kalc〇1 1098' t king (stock)] mjg, and potassium hydroxide jig, for cutting. c. After dehydration for 3 minutes at 1.3 kPa (absolute pressure), nitrogen substitution was performed. After nitrogen replacement, the temperature was raised to 125. (:, 145 2 g of propylene oxide was introduced, and an addition reaction and a ripening operation were carried out. Then, the temperature was raised to 15 Torr. Then, 84 g of ethylene oxide was introduced, and an addition reaction was carried out. After the completion of the reaction, the reaction was cooled to 8 Torr. Then, 1.8 g of lactic acid was added to the autoclave, and after 8 minutes of stirring at rC for 3 minutes, extraction was carried out to obtain the nonionic surfactant (8) of the present invention [in the formula (1), 'R: CIO, m=2.5, n=7]. Comparative Production Example 1: Production of Nonionic Surfactant (9) In a high-pressure dad including a mixing device, a temperature control device, and an automatic introduction device, the input carbon number is 8 Chain-saturated primary alcohol [trade name: Kalcol 0898, manufactured by Kao (stock)] 45.6 g, linear saturated alcohol with a carbon number of 12 [trade name: manufactured by Kalcol 2〇98' Kao (stock)] 65, 2g, carbon A straight-chain saturated primary alcohol of 16 (trade name: Kalcol 6098, manufactured by Kao), 36.4 g, and a direct-chain saturated primary alcohol having a carbon number of 18 [trade name: Kalcol 8098, manufactured by Kao (stock)] 40_6 a mixed alcohol of G (C8-OH/C12-OH/C16-OH/C18-OH=35/35/15/15 (Morbi)), and hydrogen and oxygen 1.1 g of potassium, dehydrated at ll ° ° C, 1,3 kPa (absolute pressure) for 30 minutes, and then replaced with nitrogen. After nitrogen replacement, 'heated to 125 ° C, introduced 145 _2 g of propylene oxide, and added reaction; Then, 'heat up to 150 ° C, introduce 308.4 g of ethylene oxide, carry out the addition reaction and ripening operation. After the reaction is finished, cool to 8 ° ° C, then 153874.doc •15· 201137112 after adding to the high pressure dad 1.8 g of lactic acid at 8 Torr. (: After stirring for 30 minutes, extracting was carried out to obtain a comparative nonionic surfactant (9) [in the formula (1) 'R: C8/C12/C16/C18= 35/35/15/15 (Morby ratio), m=2.5, n=7]. Comparative Production Example 2: Production of a nonionic surfactant (丨〇) including a stirring device, a temperature control device, and automatic introduction In the autoclave of the apparatus, a linear saturated primary alcohol having a carbon number of 8 is produced [trade name: Kalc〇1 0898, manufactured by Kao), 65.1 g, and a linear saturated primary alcohol having a carbon number of 丨2 [trade name] :Kalcol 2098, manufactured by Kao (share)] 93" § mixed alcohol (C16-OH / C18-OH = 5 0 / 50 (mr ratio)), and potassium hydroxide 丨"g After at 110 C, 1.3 kPa dehydrated (absolute pressure) 3〇 minutes, purged with nitrogen After nitrogen substitution was heated to 125. (:, propylene oxide was introduced 348.5 g, for addition reaction • maturing operations. Then, the temperature was raised to 15 ° C, and 308.4 g of ethylene oxide was introduced to carry out an addition reaction and a ripening operation. After the reaction was completed, it was cooled to 8 Torr, and then 1.8 g of lactic acid was added to the pressure dad to 8 g. After stirring for 3 minutes, the mixture was extracted to obtain a comparative nonionic surfactant (1〇^ formula), R: C8/C12=50/50 (mole ratio), m=6 , η=7]. Comparative Production Example 3. Production of a nonionic surfactant (11) In an autoclave including a stirring device and a temperature control device 'automatic introduction device, a linear saturated primary fermentation product having a carbon number of 8 was input [trade name: Kalc〇 1 0898 , manufactured by Yu Wang (stock)] 65.1 g, linear saturated alcohol with a carbon number of 12 [trade name. Kalcol 2098, manufactured by Kao) 9.93 Mixed yeast (C16-OH/C18-OH =50/50 (mole ratio)), and potassium hydroxide i"g, dehydrated at ll ° ° C, 1.3 kPa (absolute pressure) for 3 minutes, and then replaced with nitrogen. After nitrogen substitution, the temperature was raised to 125 ° C, 145.2 g of propylene oxide was introduced, and 153874.doc -16 - 201137112 was added to form a reaction and ripening operation. Then, the temperature was raised to 150 ° C, and 1541.8 g of ethylene oxide was introduced to carry out an addition reaction and a ripening operation. After the completion of the reaction, 'cooled to 8 ° C, and then 1.8 g of lactic acid was added to the autoclave, and the mixture was stirred at 80 ° C for 30 minutes, and then extracted to obtain a comparative nonionic surfactant (11). (1), R: C8/C12=50/50 (Morby ratio), m=2.5, n=35]. Comparative Production Example 4: Production of a nonionic surfactant (12) In an autoclave including a stirring device, a temperature control device, and an automatic introduction device, a linear saturated primary alcohol having a carbon number of 8 was charged [trade name: Kaleol® 0898, manufactured by Kao (stock)] 65.1 g, a linear saturated alcohol with a carbon number [trade name: Kalcol 2098, manufactured by Kao (stock)] mixed alcohol of 93·ι g ((:16-011/(: 18-011=5 0/50 (mole ratio)), and potassium hydroxide 1.1 §, after dehydration at 110 ° C, 1.3 kPa (absolute pressure) for 3 minutes, nitrogen substitution. After nitrogen replacement, the temperature is raised to 125X:, 17.4 g of propylene oxide was introduced, and an addition reaction was carried out. The aging operation was carried out. Then, the temperature was raised to 15 Torr. (:, ethylene oxide 3 〇 84 g was introduced, and an addition reaction and a ripening operation were carried out. After the reaction was completed, the mixture was cooled to 8 〇〇c, Q Then add 1,8 g of lactic acid to the south pressure dad, stir at 8 ° C for 30 minutes, and then extract to obtain a nonionic surfactant for comparison (12) [1 ) 'R: C8/C12=50/50 (Morby ratio), m=〇3, n=7]. Comparative Production Example 5. Nonionic surfactant ( 13) Manufactured in an autoclave including a stirring device, a temperature control device, and an automatic introduction device, a straight-chain saturated primary alcohol having a slave number of 8 [trade name: manufactured by Kaie〇i 0898 'King Co., Ltd.] 65. Lg, a linear saturated primary alcohol having a carbon number of 12 [trade name: manufactured by KalC〇1 2098 'Kao (stock)) 93.1 g of mixed alcohol (C16-OH/C18_OH=50/50 (Morby)), And KOH was dehydrated, and dehydrated for 30 minutes at 153874.doc 201137112 110 ° C and 1.3 kPa (absolute pressure), and then nitrogen substitution was performed. After nitrogen substitution, the temperature was raised to 125 ° C, and propylene oxide 145 2 g was introduced and added. Into the reaction and ripening operation. Then, the temperature was raised to i 5〇t:, 88.1 g of ethylene oxide was introduced, and the addition reaction and ripening operation were carried out. After the reaction was completed, the mixture was cooled to 80 C′, and then 1.8 g of lactic acid was added to the pressure dad. 8〇. After mixing for a few minutes, the extraction is carried out to obtain a comparative nonionic surfactant (13) [in the formula (1), R: C8/C12=50/50 (mr ratio), m =2.5, n=2]. Comparative Production Example 6: Nonionic surfactant (14) S〇ftan manufactured using Nippon Shokubai Co., Ltd. l 7 〇 (linear ethylene glycol adduct of secondary alcohol) as a nonionic surfactant (14). Comparative Production Example 7. Nonionic surfactant (15) manufactured by including stirring device, temperature The control device 'automatically introduces the high pressure crucible into the high-pressure crucible, and puts in the synthetic alcohol [trade name: 8 october 0 [23 (8 8 801 ^ company)), with a carbon number 12, 13 branched alkyl [carbon number ι / carbon The number 13 = 55/45 (Morby) 'branche rate (mass composition of branched alcohol) is 5 〇 mass%] saturated alcohol] 194 g, and hydrogen hydroxide unloading I"g, at "ο, I· After dehydration for 30 minutes at kp a (absolute pressure), nitrogen substitution was performed. After nitrogen replacement, the temperature was raised to 125. (:, then, 45.2 g of propylene oxide was introduced, and an addition reaction and a ripening operation were carried out. Then, the temperature was raised to i5〇t, and 308.4 g of ethylene oxide was introduced to carry out an addition reaction and a ripening operation. After the reaction was completed, it was cooled to 80 C ' Then, 8 g of lanthanum lactate was added to the autoclave, and the mixture was stirred at 8 ° C for 3 minutes, and then subjected to 'extraction' to obtain a nonionic surfactant (15) for comparison [in the formula (1), r contains a branch. Alkenyl group (branche rate: 5% by mass), m = 2.5, n = 7]. 153874.doc -18- 201137112 Comparative Production Example 8: The nonionic surfactant (16) is manufactured by including a stirring device, The temperature control device, the automatic introduction, and the autoclave placed in the autoclave were charged with a linear saturated primary alcohol having a carbon number of 8 [trade name·· Kalc〇1 0898, manufactured by Kao (stock)] 65.1 g, and the carbon number was 丨2. Linear saturated primary alcohol [trade name: Kalcol 2098, manufactured by Kao (stock)] 93·2 Mixed yeast (C8-OH/C12-OH=50/50 (Morbi)), and potassium hydroxide i" g, after dehydration at 110 ° C and 1.3 kPa (absolute pressure) for 30 minutes, nitrogen substitution was performed. After the nitrogen substitution, the temperature was raised to 150 ° C and introduced. Propylene 145.2 § and ethylene oxide 308.4 g were subjected to random addition reaction and ripening operation. After the reaction was completed, it was cooled to 80 ° C, and then 18 g of lactic acid was added to the autoclave at 8 ° C. After stirring for 30 minutes under the crucible , extraction is carried out to obtain a comparative nonionic surfactant (16) [in the formula (1), R: C8/C12 = 5〇/5〇 (mr ratio), m=2 5, n=7 (but <Example 1 and Comparative Example 1> <Example> The nonionic surfactant (1) to (including) obtained in the production example and the comparative production example was evaluated according to the method shown below. 16) Performance of the scouring composition: The results are summarized in the table! Furthermore, for the sake of convenience, the nonionic surfactant which does not conform to the u (A) component is also expressed as (eight) [Evaluation of scouring property (residual fat percentage of cotton)] The cotton fabric (residual fat ratio: 1〇5 mass%) was subjected to scouring treatment under the following conditions: A test of about 3 to 4 g was cut from the scoured grey fabric. For the sample, use 2 shouts as the extraction solvent, and use Soxhlet (s〇xhlet) extraction device (Donghai meter to make the extraction operation. 4 small After the extraction operation, the extracting agent is removed by evaporation under reduced pressure, and the mass of the residue is determined, and the residual fat ratio is obtained by the following formula: 153874.doc -19-201137112 Residual fat percentage (%) = (distillation The mass of the residue after removal of the extraction solvent / the mass of the test sample) X 100 * The scouring treatment condition The concentration of the scouring agent composition (nonionic surfactant): 1 〇 g / ; L The caustic soda concentration: 1.0 g / L Refining time: 20 minutes Refining temperature: 1 l〇°C Bath ratio: 1/20 Treatment water: 3°DH [Evaluation of scouring (upper suction height)] The cotton fabric is scoured under the above conditions, after self-treatment A sample fabric having a width of 3 cm and a length of 15 cm was taken on the fabric, and the sample cloth was suspended in a state of no slack without looseness by immersing the end of the sample cloth on the cylinder filled with the aqueous solution of the dye solution. The degree of suction (mm) above the dye aqueous solution is used to check the scouring property. The higher the suction height, the more excellent the wettability and the more excellent the scouring property of the scouring agent. [Evaluation of scouring (dropping method)] The test sample of 5 coffee 5 (10) was cut out from the scouring treatment. Horizontally placed with a dropper, the drop of 0.1 mL was dropped from the top of the sample about 1 cm above the cloth. Review of the aqueous dye solution used in the Bay. After naturally drying, the water absorption is judged based on the expanded shape of the dye water. The evaluation criteria are as follows. The eucalyptus wood expands into a larger circle, and a 1 cm diameter circle can be accommodated in the dyed range. μ 153S74.doc •20· 201137112 △: The dye is not sufficiently extended, or the dye has a flat shape. The circle with a diameter of 7 mm can be accommodated in the dyeing range, but it cannot accommodate the circle of enamel. X: A circle with a diameter of 7 mm cannot be included in the dyeing range. [Evaluation of foaming property] The test solution was placed in a quantity of 1 L (nonionic surfactant concentration: 2·00χ10_3 m〇l/L, and the remainder was water). The air pump of the fiber ball filter (baU filter) was charged with air at μ L/min from the bottom of the measuring cylinder' to determine the foaming height (mm) after 2 minutes. 〇 153874.doc -21 - 201137112
【II I 比較例 00 1—» ν〇 1 1 1 1 1 1 ο Τ—Η »r> ri 卜 無規 (Ν 00 X 0.140 S κη c^ I 1 27.5 22.5 1 1 1 普 κη (N 卜 嵌段 g X 0.132 〇 Ό m \〇 寸 1 1 1 1 1 1 1 1 ο 1 卜 1 r—Η 〇 0.099 370 206 m 幽 1 1 1 1 1 ο yn (N CS1 |嵌段| 宕 X 0.902 iTt 00 1—^ cn t 1 1 1 1 1 ο m o 卜 |嵌段| 〇 0.088 450 406 cn 1 1 1 1 1 1 ο CN m |嵌段| (S m X 0.861 312 230 fN ο 1 1 1 1 1 1 ο 卜 嵌段 X 0.964 cn VO T—" ΟΝ <T) m 1 in m 1 1 1 ο (N 卜 嵌段 1—^ X 0.987 ο (Ν (Ν 00 »—r 實施例 00 ^-Η 00 1 〇 1 1 1 1 1 1 ο (N 卜 |嵌段 os ON 〇 0.123 iT) 宕 卜 1 1 1 1 1 1 ο ^—Η <S <Ti 嵌段 g 〇 0.116 as νη (N 1 1 1 1 I 1 ο yn ΓΠ 卜 |嵌段| s 〇 0.113 00 IT) 1—^ 1 12.5 1 12.5 1 1 1 ο 1—^ oi 卜 |嵌段| r~< 〇 0.112 S 寸 < 4 1 1 *η 1 § ^T) r4 |嵌段| o 〇 0.121 oo 00 cn ΓΛ ^Ti CN (N 1 V) (N 1 1 1 ο (N 〇 嵌段 〇 0.091 卜 CN »—μ <Ν 1 1 1 1 1 1 ο 1—^ κη oi |嵌段| 〇 0.076 F—Ν 1 1 1 1 1 1 ο Η yn r4 卜 |喪段| (N| 1—ί 〇 0.079 in Ο 非離子性界面活性劑Νο. C10 C12 C13 C14 C16 C18 1其他i C8~C14之比例(莫耳％) PO之平均加成莫耳數(m) E0之平均加成莫耳數(η) ΡΟ·ΕΟ加成形態 上吸高度(mm) 滴下法 殘脂率(％) 2分鐘後 送氣結束2分鐘後 通式(1)中之R 之組成(莫耳％) (A)成分 精練性 起泡性 (mm) -22- 153874.doc 201137112 製造例9 :聚氧乙烯（平均加成莫耳數為2 〇)月桂醚硫酸 鹽之製造 使用花王（股）公司製造之Emal 270J。 製造例10 :聚氧乙烯（平均加成莫耳數為3.0)異癸基倍半磷 酸酯· Na鹽之製造 於2000 mL之反應容器中，裝入於協和醱酵化學（股）製造 之DecanoK化學名：異癸醇莫耳上加成氧化乙烯3莫耳= 得之有機羥基化合物（平均分子量=158.3)633.2 g(4.00莫 耳）、及85%之正磷酸93.7 g(若表示為ρ2〇5·ηΗ2〇 ,則p2〇5 : 0.41莫耳’私0: 2.00莫耳）並攪拌混合，一面將溫度保持為 5〇〜7〇°C，一面緩緩添加五氧化磷（有效成分為98.5。/。)229.6 g (1.59莫耳）’然後升溫至8〇〇c，反應12小時。之後，將其反 應產物供給至使用利用強制薄膜（f〇rced thin fUm)之水蒸氣 瘵餾裝置（傳熱面積：0.03 m3，玻璃製）的除臭處理。水蒸 氣蒸餾係於夾套溫度15(rc、2.7kpa(絕對壓力）之條件下’ 〇 分別以100 g/hr、75 g/hr之速度連續地供給反應產物與蒸氣 而進行獲彳于含有含量為〇.8 %之有機經基化合物及含量為 0.3%之水分的磷酸酯作為殘留物。然後，一面將該磷酸酯 添加於特定量之氫氧化鈉水溶液中並攪拌，一面進行中和， 獲传聚氧乙烯（平均加成莫耳數3 〇)異癸基倍半磷酸酯· Na 鹽。 <實施例2及比較例2> 根據表2之組成製備各種精練劑組合物，依據下述方法評 價各組合物之流動性。再者，表中為方便起見，將並不符 153874.doc -23· 201137112 合（A)成分之非離子性界面活性劑亦表示為（A)成分。 [流動性評價] 於内徑24.3 mm、高度46.5 mm之樣品管（Maru emu公司製 造之樣品瓶No.3)中裝入組合物3 mL，於3°C下靜置30分 鐘。然後，將裝有組合物之樣品管倒置，測定氣泡上升所 花費之時間（秒）。評價基準如下所述。 〇：未達1秒 △ : 1秒以上且未達20秒 X : 20秒以上 J'SJ*-. 153874.doc • 24· 201137112 ο ο 【(Nd 比較例 CN o X CN o X rn (N O X (N CN "〇 o X <N o X 實施例 Os (N % o 〇 00 <N % o 〇 卜 CN lz> o 〇 (N % o 〇 in CN o 〇 <N % o 〇 m (N "〇 o 〇 <N CN "〇 o 〇 CN % o 〇 非離子性界面活性劑(1) 非離子性界面活性劑P) 非離子性界面活性劑(3) 非離子性界面活性劑(4) 非離子性界面活性劑(5) 非離子性界面活性劑(6) 非離子性界面活性劑(7) 非離子性界面活性劑(8) 非離子性界面活性劑(10) 非離子性界面活性劑(11) 非離子性界面活性劑(12) 非離子性界面活性劑(13) 滅Jffld η ζ t奥 楚1¢: i)m |i Z 装你 〇 一 S' 流動性評價 < ^ Φ 落®廸噠(鉍®H%) 您斂聂戚4〇蓉 153874.doc -25-[II I Comparative Example 00 1—» ν〇1 1 1 1 1 1 ο Τ—Η »r> ri 卜 Random (Ν 00 X 0.140 S κη c^ I 1 27.5 22.5 1 1 1 普κη (N Bu Segment g X 0.132 〇Ό m \〇 inch 1 1 1 1 1 1 1 1 ο 1 Bu 1 r—Η 〇0.099 370 206 m 幽1 1 1 1 1 ο yn (N CS1 | Block | 宕X 0.902 iTt 00 1—^ cn t 1 1 1 1 1 ο mo 卜 | Block | 〇0.088 450 406 cn 1 1 1 1 1 1 ο CN m | Block | (S m X 0.861 312 230 fN ο 1 1 1 1 1 1 ο 卜 block X 0.964 cn VO T—" ΟΝ <T) m 1 in m 1 1 1 ο (N 卜 block 1—^ X 0.987 ο (Ν (Ν 00 »—r Example 00 ^-Η 00 1 〇1 1 1 1 1 1 ο (N 卜 | block os ON 〇 0.123 iT) 1卜 1 1 1 1 1 1 ο ^—Η <S <Ti block g 〇0.116 as νη (N 1 1 1 1 I 1 ο yn ΓΠ 卜 | block | s 〇 0.113 00 IT) 1—^ 1 12.5 1 12.5 1 1 1 ο 1—^ oi 卜 | block | r~< 〇0.112 S inch< 4 1 1 * η 1 § ^T) r4 | block | o 〇 0.121 oo 00 cn ΓΛ ^Ti CN (N 1 V) (N 1 1 1 ο (N 〇 block 〇 0.091 卜 CN »-μ <Ν1 1 1 1 1 1 ο 1—^ κη oi | Block | 〇0.076 F—Ν 1 1 1 1 1 1 ο Η yn r4 卜 | 丧 segment | (N| 1—ί 〇0.079 in Ο Non-ionic interface Active agent Νο. C10 C12 C13 C14 C16 C18 1 Other i C8~C14 ratio (mol%) PO average addition mole number (m) E0 average addition mole number (η) ΡΟ·ΕΟ addition Morphological suction height (mm) Dropping residual fat percentage (%) Composition of R in the general formula (1) after 2 minutes after the end of gas supply (% by mole) (A) Component scouring foamability (mm) -22- 153874.doc 201137112 Production Example 9: Polyoxyethylene (average addition molar number is 2 〇) The manufacture of lauryl ether sulfate was carried out using Emal 270J manufactured by Kao Corporation. Production Example 10: Polyoxyethylene (average addition molar number: 3.0) Isodecyl sesquiphosphate·Na salt was produced in a 2000 mL reaction vessel and charged in DecanoK manufactured by Kyowa Essence Chemical Co., Ltd. Chemical name: isodecyl alcohol on the molar addition of ethylene oxide 3 mole = organic hydroxy compound (average molecular weight = 158.3) 633.2 g (4.00 mol), and 85% orthophosphoric acid 93.7 g (if expressed as ρ2 〇 5·ηΗ2〇, then p2〇5: 0.41 Moer's private 0: 2.00 moles), while stirring and mixing, while maintaining the temperature at 5〇~7〇°C, slowly add phosphorus pentoxide (active ingredient is 98.5) /.) 229.6 g (1.59 mol) 'then warmed to 8 〇〇 c, reacted for 12 hours. Thereafter, the reaction product was supplied to a deodorization treatment using a steam distillation apparatus (heat transfer area: 0.03 m3, made of glass) using a forced film (f〇rced thin fUm). The steam distillation is carried out under the conditions of a jacket temperature of 15 (rc, 2.7 kPa (absolute pressure). 〇 The reaction product and the vapor are continuously supplied at a rate of 100 g/hr and 75 g/hr, respectively, and the content is contained in the content. 8. 8 % of an organic warp-based compound and a phosphate ester having a water content of 0.3% as a residue. Then, the phosphate ester is added to a specific amount of sodium hydroxide aqueous solution and stirred, and neutralized. Polyoxyethylene (average addition molar number 3 〇) isodecyl sesquiphosphate· Na salt. <Example 2 and Comparative Example 2> Various scouring compositions were prepared according to the composition of Table 2, according to the following The fluidity of each composition was evaluated by the method. Further, for the sake of convenience, the nonionic surfactant which does not conform to the component (A) of 153874.doc -23·201137112 is also represented as component (A). Evaluation of fluidity] A sample tube (bottle No. 3 manufactured by Maru emu Co., Ltd.) having an inner diameter of 24.3 mm and a height of 46.5 mm was charged with 3 mL of the composition, and allowed to stand at 3 ° C for 30 minutes. Then, it was loaded. The sample tube with the composition is inverted, and the time taken for the bubble to rise is measured (seconds) The evaluation criteria are as follows: 〇: less than 1 second △: 1 second or more and less than 20 seconds X: 20 seconds or more J'SJ*-. 153874.doc • 24· 201137112 ο ο [(Nd Comparative Example CN o X CN o X rn (NOX (N CN "〇o X <N o X Example Os (N % o 〇 00 < N % o CN CN CN lz> o 〇 (N % o 〇in CN o 〇 <N % o 〇m (N "〇o 〇<N CN "〇o 〇CN % o 〇Nonionic surfactant (1) Nonionic surfactant P) Nonionic surfactant (3) Nonionic surfactants (4) Nonionic surfactants (5) Nonionic surfactants (6) Nonionic surfactants (7) Nonionic surfactants (8) Nonionic Surfactant (10) Nonionic surfactant (11) Nonionic surfactant (12) Nonionic surfactant (13) Destroy Jffld η ζ t Ochu 1¢: i)m |i Z Load you a S' Liquidity Evaluation < ^ Φ 落 ®迪哒(铋®H%) You 戚聂戚4〇蓉 153874.doc -25-
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