201122676 I w*+^ /υ「/·ν 六、發明說明： 【發明所屬之技術領域】 本發明是有關於一種多象限垂直配向型之液晶顯示 面板及其製造方法，且特別是有關於一種暗態低漏光之 多象限垂直配向型之液晶顯示面板及其製造方法。 【先前技術】 液晶顯示面板（Liquid Crystal Display Panel)具 備輕薄、省電、低輻射的特性，在商業及消費性電子產 品上應用廣泛，逐步取代傳統陰極射線管螢幕成為熱門 的光電產品。目前液晶顯示面板在耗電力、全面輝度及 明室對比效果已經優於傳統陰極射線管螢幕。 一般來#兒，為了增加液晶分子的反應時間，會使液 晶分子先傾倒一預傾角。請參照第丨圖，其繪示習知之 具有配向聚合層之液晶顯示面板之示意圖。⑯晶顯示面 板100具有一上基板102、一下基板104、—第一電極 101、一第二電極1〇3、一配向聚合層1〇6、配向膜 及數個液晶分子108。配向聚合層106係由數個可聚合單 體（monomer)聚合形成。透過聚合高分子辅助配向^術 (Polymer-Stabilizing Alignment’ PSA)形成於上基板 102或下基板1〇4之表面’用以引導液晶分子1〇8排列及 與基板間產生-預傾以。如此，可縮短電場通過時液 晶分子108時液晶分子1 〇8的反應時間。 然而，液晶分子1G8 -起往同-方向傾倒，雖缺可 縮短液晶分子1G8之反應時fa卜但是在不加電場的情況 201122676 1 1 /υτ/Λ 下，卻會有更嚴重的暗態漏光問題發生。 【發明内容】 本發明係有關於-種多象限垂直配向型之液晶顯示 面板及應用其之液晶顯示裝置與其製造方法，於液晶顯 不面板内配置至少二種不同之預傾角的液晶分子，兼顧 縮短反應時間及降低暗態漏光之效果。 根據本發明之第—方面，提出—種多象限垂直配向 籲型之液晶顯示面板，液晶顯示面板係設置於一液晶顯示 裝置。液晶顯示面板包括一上基板、一下基板、一液晶 層及-配向聚合層4基板具有—上基板表面，下基= 具有一下基板表面。液晶層填充於上基板表面與下基板 表面之間液層包括數個液晶分子。配向聚合層係形 成於上基板表面與下基板表面中至少一者，用以引導液 晶分子之一第一部份以一第一預傾角排列，及引導液晶 分子之一第一部份以一第二預傾角排列。其中，第一預 • 傾角係大於第二預傾角。 根據本發明之第一方面，提出一種液晶顯示裝置。 液晶顯示裝置包括一多象限垂直配向型之液晶顯示面板 及一背光模組。液晶顯示面板包括一上基板'一下基板、 一液晶層及一配向聚合層。上基板具有一上基板表面。 下基板具有一下基板表面。液晶層係填充於上基板表面 與下基板表面之間。液晶層包括數個液晶分子。配向聚 合層形成於上基板表面與下基板表面中至少一者，用以 引導液晶分子之一第一部份以一第一預傾角排列，及引 201122676 1 vv '•ty I \ji γλ 導液晶分子之一第二部份以一第二預傾角排列。其中， 第一預傾角係大於第二預傾角。背光模組用以提供光線 至液晶顯不面板以顯不晝面。 根據本發明之第三方面，提出一種液晶顯示面板之 製造方法。製造方法包括以下步驟。提供一上基板、一 下基板及一液晶層。液晶層係填充於上基板之一上基板 表面與下基板之一下基板表面之間，液晶層包括數個液 晶分子及數個可聚合單體；提供一第一電壓於上基板與 下基板之間，使液晶分子以一第一預傾角排列；提供一 第一光罩。第一光罩具有一第一透光區，第一透光區係 對應至液晶分子之一第一部份；以一光線，透過第一光 罩照射液晶分子之第一部份，使可聚合單體中被照射之 可聚合單體於上基板表面與下基板表面中至少一者形成 一配向聚合層之第一部份；提供一第二電壓於上基板與 下基板之間，以使液晶分子以一第二預傾角排列；以光 線照射液晶分子之一第二部份，使可聚合單體中被照射 之可聚合單體於上基板表面與下基板表面中至少一者形 成配向聚合層之第二部份。 根據本發明之第四方面，提出一種液晶顯示面板之 製造方法。製造方法包括以下步驟。提供一上基板、一 下基板及一液晶層。液晶層係填充於上基板之一上基板 表面與下基板之一下基板表面之間，液晶層包括數個液 晶分子及數個可聚合單體；提供一電壓於上基板與下基 板之間；提供一第一光罩，第一光罩具有一第一透光區， 第一透光區係對應於液晶分子之一第一部份；以一第一 201122676 I νν*+7/〇Γ/Λ 光線，透過第一光罩照射液晶分子之第一部份，以使液 曰日刀子之第一部份以一第一預傾角排列並使可聚合單體 中被照射之可聚合單體於上基板表面與下基板表面中至 少一者形成一配向聚合層之第一部份；以一第二光線， 照射液晶分子之一第二部份，以使液晶分子之第二部份 ^一第二預傾角排列並使可聚合單體中被照射之可聚合 單體於上基板表面與下基板表面巾至少—者形成配向聚 合層之第二部份。其中，第一光線具有一第一能量，第 •二光線具有一第二能量，第一能量係不同於第二能量。 ，根據本發明之第五方面，提出—種液晶顯示面板之 製造方法。製造方法包括訂步驟。提供—上基板、一 下基板及一液晶層。液晶層係填充於上基板之一上基板 =與下基板之-下基板表面之間，液晶層包括數個液 Β曰分子及數個可聚合單體；提供一電壓於上基板與下美 板之間；提供—光罩’光罩具有—第-透光區及一第1 透光區。第—透光區對應於液晶之-帛1份且第二透 光區對應於液晶之1二部份，該第—透光區具有一第 =透比例’使—光線以該第—穿透比例通過該第一透 :第-ΐϊτ透光區具有一第二穿透比例’使該光線以 二：=例通過該第二透光區;提供光線，透過光 罩础液曰曰層’以使可聚合單體中被照射之 ^上基板表面與下基板表面中至少—者形成—配:聚人 層。配向聚合層用以引導液晶之—第—部份係 二 預傾角排列及引導液晶之一第二部 排列。 丨物係以一第二預傾角 201122676 i wny/υτ/Λ 為讓本發明之上述内容能更明顯易懂，下文特舉較 佳實施例，並配合所附圖式，作詳細說明如下： 【實施方式】 以下係提出較佳實施例作為本發明之說明，然而實 施例所提出的内容，僅為舉例說明之用，而繪製之圖式 係為配合說明，並非作為限縮本發明保護範圍之用。再 者，實施例之圖示亦省略不必要之元件，以利清楚顯示 本發明之技術特點。 第一實施例 請參照第2圖，其繪示依照本發明第一實施例之液 晶顯示裝置之示意圖。液晶顯示裝置200包括一液晶顯示 面板202、一背光模組204及一外框203。背光模組204 用以提供光線至液晶顯示面板202以顯示晝面。其中，液 晶顯示裝置200例如是多顯示域垂直配向（Multi-domain Vertical Alignment, MVA)型之顯示面板。 請參照第3圆，其繪示第2圖之液晶顯示面板之示 意圖。液晶顯示面板202包括一上基板206、一下基板 208、一液晶層210及一配向聚合層218。 上基板2 0 6，例如是一彩色濾、光片基板，其具有一上 基板表面212、一配向膜264及一透明電極223。下基板 208,例如是一薄膜電晶體矩陣基板具有一下基板表面214 並包括一配向膜264及一顯示電極，該顯示電極例如是圖 案化透明電極224，其具有數個溝槽226，第3圖係以繪 201122676 里▼▼ -ry /、_/里 示 個溝槽為例作說明。 日層21〇填充於上基板表面212與下基极表面214 之間。液曰曰層210包括數個液晶分子216。配向聚合 形成於上基板表面212與下基板表面214，用以引^ 分子216之—第一部份22〇以一第一預傾角Θ1排列及^曰 導液晶分子216之-第二部份222份以一第二預傾角的 排列。第-預傾角Θ1可介於6。〜3〇。之間，第—預傾 大於第二預傾角02，第二預傾角02可小於3。。如此— 由較大預傾角之液晶’即液晶分子216之第-部份22〇 I 縮短反應時間’同時藉由預傾角較小的液晶 91 c ^ ^ 1饮日日分子 16之第一。卩份222來降低暗態漏光，使整體液晶顯示面 板202可以兼顧縮短反應時間及降低暗態漏光的效果。其 中，暗態，係液晶分子未受電場作用的狀態。較 ^ 限定地，第-預傾角Θ1介於6。〜10。之間更可有效地降低 暗態漏光。 - 雖然本實施例之配向聚合層係以形成於上基板與下 基板為例作說明，然於其它實施態樣中，配向聚八士 以只形成於上基板與下基板之其中一者。 Q θ也可 雖然本實施例之圖案化透明電極係以設置於下某板 表面214為例作說明，然於其它實施態樣中，圖案化透明 電極也可以形成於上基板表面212。或者，上基板表面212 與下基板表面214也可以同時形成有圖案化透明電極。 此外，雖然本實施例之上基板2〇6以彩色濾光片基 板而下基板208以薄膜電晶體矩陣基板（即c〇T (c〇l〇r filter on TFT)形式之顯示面板）為例作說明，然於其 201122676 1 »» ^y I \j\ rx 它實施態樣中，下基板208可以同時形成有薄膜電晶體矩 陣及彩色遽光片且彩色濾光片可形成於薄膜電晶體矩陣 上，即為COA ( Co 1 or f i 1 ter on Array)形式之顯示面 板。或者，下基板208可以同時形成有薄膜電晶體矩陣及 彩色濾光片且薄膜電晶體矩陣可形成於彩色濾、光片上，即 為AOC (Array on Color filter )形式之顯示面板。 請參照第4圖，其繪示往第3圖之方向])1觀看到之 圖案化透明電極之第一種實施態樣示意圖。溝槽226係與 圖案化透明電極224之一邊228夾有一銳角a。具有第一 預傾角Θ1之液晶分子216，即液晶分子216之第一部份 2 2 0 ’係位於二個溝:槽2 2 6之間’較佳地但非限定地位於 二個溝槽226之中間部位232。而具有第二預傾角Θ2之 液晶分子216 ’即液晶分子216之第二部份222，係位於 圖案化透明電極224之其它部位234。 此外，雖然本實施例之圖案化透明電極224之溝槽 226係以與圖案化透明電極224之一邊228夾有銳角A為 例作說明，然於另一實施例中，請參照第5圖，其繪示 依照本發明之溝槽之第二種實施態樣示意圖。溝槽230 的延伸方向係實質上垂直於圖案化透明電極244之一邊 242，而具有第一預傾角仍之液晶分子216，即液晶分子 216之第一部份220，係位於二個溝槽230之間的部位 260，較佳地但非限定地位於二個溝槽23〇之中間部位。 或者，請參照第6圖，其繪示依照本發明之溝槽之 第一種實施態樣示意圖。溝槽236的延伸方向實質上平行 於圖案化透明電極2 5 0之一邊2 4 8，而具有第一預傾角θ 1 201122676 1 yy *tj/ / ui 之液晶分子216,即液晶分子216之第一部份22〇，係位 於二個溝槽236之間的部位262。 或者’請參照第7圖及第8圖，料示依照本發明 之溝槽之第四種實施態樣示意圖。如第7圖所示，圖案 化透明電極246具有-幾何對稱之圖案化溝槽挪。液晶 ^子216之第一部份220位於圖案化溝槽2邡之幾何對 柄中心240’而液晶分子216之第二部份222位於圖案化 溝槽238之幾何對稱中心24〇以外的部位2如。如第8圖 _所* ’圖案化透明電極252 #有一幾何對稱之圖案化溝 槽310。液晶分子216之第一部份220位於圖案化溝槽 310之幾何對稱中心312,而液晶分子216之第二部份 位於圖案化溝槽31〇之幾何對稱中心312以外之部位 31卜 此外，雖然本實施例之圖案化透明電極，例如是圖 案化透明電極224、244、246、250及252係以具有溝槽 為例作說明，然於其它實施態樣中，顯示電極也可以不曰 ♦具有溝槽。請參照第9圖及第1〇圖，其繪示依照本發明 之第五種實施態樣示意圖。液晶分子216之第一部份22〇 位於顯示電極254的幾何對稱中心256,例如是長方形之 中心處。此外，雖然液晶分子216之第一部份22〇的^ 佈形狀以第9圖的圓形為例作說明，然此非用以限制本 ^明，液晶分子216之第一部份22〇的分佈形狀也可以 是其它形狀’例如是第10圖所示之矩形314。 此外，雖然圖案化透明電極之溝槽形式係以第4圖 至第8圖為例各別作說明，然於其它實施態樣中也可 201122676 第8圖之溝槽形式混搭於同-圖案化透明 亦即，只要二溝槽之間的液晶分子具有第一預 =即可。或者’呈幾何對稱之溝槽化圖案，其位於 分子具有第一預傾角亦可。也就是說，、圖 案化透明電極之溝槽形式並不受本實施例之限制。 此:’雖然本實施例之預傾角係以二種為例作說 月。…、之它貫施例中，也可以是三種以上之預傾角。以 下係說明三種預傾角的實施態樣。請參照第u圖及第12 圖，第11圖繪示具有三種預傾角之液晶顯示面板之示意 圖’第12圖繪不液晶分子之第三部份之設置部位圖。 如第U圖所示，液晶顯示面板280之液晶分子216 之一第二部份282以一第三預傾角<93排列並位於第以圖 所不之圖案化透明電極2犯之邊緣區域266。此邊緣區域 266的位置對應於黑色矩|j車（Biack Matrix，bm ) 284 (專、 色矩陣284繪示於第π圖）的位置。由於邊緣區域挪 為非顯示區，所以即使發生暗態漏光以致影響顯示品 質。因此，設置於邊緣區域266之液晶分子（即液晶分 子216之第二部份）之預傾角可大於第一預傾角钒與第 二預傾角Θ2 ’以大幅縮短反應時間。進—步地說，透過 大預傾角的液晶可帶動週遭液晶加速傾倒，週遭液晶在 互相影響下，加速了整體液晶的傾倒速度，因此可大幅 縮短反應時間。 此外，液晶分子216之第一部份220之分佈面積約 占顯示電極之透光區域之面積，即開口率之面積約⑽至 90%之間並且以10%至30%之間為較佳。舉例來說，第4 201122676 1 VVH：7 /υΓ/Λ 圖至第10圖及第12圖之液晶分子之第一部份的分佈範 圍可占顯示電極之開口率約5%至90%。 以下將以第11圖之液晶顯示面板280為例說明本發 明之液晶顯示面板的製造方法。請參照第13圖，其繪示 依照本發明第一實施例之液晶顯示面板之製造方法流程 圖。製造方法包括以下步驟。 於步驟S402中，請同時參照第14圖，其繪示上基 板、下基板及液晶層之示意圖。提供上基板2 0 6、下基板 φ 208及液晶層210。液晶層210包括數個液晶分子及數個 可聚合單體272。液晶分子216實質上垂直於上基板206 之上基板表面212與下基板208之下基板表面214。其 中’液晶分子216藉由上基板206與下基板208之配向 膜264來達成與上基板表面212與下基板表面214垂直。 下基板208包括顯示電極，例如是圖案化透明電極224、 244、246、250、252。本實施例之製造方法係以圖案化 透明電極224為例作說明。 • 再來，於步驟S404中，請同時參照第15Α圖及第 15Β圖’第15Α圖繪示本實施例之製造方法之第一光罩之 示意圖，第15Β圖繪示第15Α圖之方向15Β-15Β，的剖視 圖。提供一第一光罩268,第一光罩268具有一第一透光 區270。為了對液晶分子216之第一部份220進行曝光， 第一透光區270對應至液晶分子216之第一部份220(第 一部份220繪示於第11圖）的位置，液晶分子216之第 一部份220位於第4圖之溝槽226之中間部位232。也就 是說，第一透光區270對應於第4圖之溝槽226之中間 13 201122676 I VT T / i IF1 厂1 部位232。 接著，於步驟S406中，請參照第16圖，其繪示提 供電壓於上基板與下基板之間之示意圖。提供一第一電 壓VI於上基板206的透明電極223與下基板208的圖案 化透明電極224之間，以使液晶分子216以第一預傾角Θ1 排列。此外，第一電壓V1例如是介於5伏特（V)至5 0 V 之間。 由於溝槽226之設置，使液晶分子的排列可呈現多 維度。如此，在後續的曝光製程後，可聚合單體在液晶 分子呈多維度之排列方式下所聚合成的聚合配向膜將使 液晶分子在未受電場作用的情況下仍以多維度的方式排 列。 然後，請參照第17圖，其繪示對第16圖之液晶層 進行曝光之示意圖。於步驟S408中，將第一光罩268設 於下基板208之下方，並以一光線L，例如是紫外光，透 過第一光罩268照射液晶分子216之第一部份220,以使 可聚合單體272中被照射之可聚合單體於上基板表面212 與下基板表面214形成配向聚合層218之第一部份294。 此外，雖然本實施例的第一光罩將以設於下基板208 之下方為例作說明，然於其它實施態樣中，第一光罩268 可設於上基板206的上方，例如，當液晶顯示面板202 為COA型或AOC型的顯示面板時，第一光罩268可設於 上基板206的上方，使光線L由第一光罩268之上方往 上基板206之方向照射。 然後，於步驟S410中，請同時參照第18A圖及第 201122676 1 TT-T//V 羼厂1 18B圖，第18A圖繪示本實施例之製造方法之第二光罩示 意圖，第18B圖繪示第18A圖之方向18B-18B’的剖視 圖。提供一第二光罩274。第二光罩274具有一第二透光 區276、一第一遮光區278及一邊緣遮光區300。第一遮 光區278對應於第一光罩268之第一透光區270的位置， 以避免已設定好第一預傾角Θ1之配向聚合層218之第一 部份294受到光照影響。 由於本實施例要製作出三種預傾角，故以邊緣遮光 φ 區300對位於圖案化透明電極224之邊緣區域266之液 晶，即液晶分子216之第三部份282進行遮光，以避免 位於液晶分子216之第三部份282之可聚合單體發生聚 合反應。進一步地說，第二透光區276對應於液晶分子 216之第二部份222的位置。 然後，請參照第19圖，其繪示提供第二電壓於上基 板與下基板之間之示意圖。於步驟S412中，提供一第二 電壓V2於上基板206與下基板208之間，使液晶分子216 • 以第二預傾角Θ2排列。其中，第一電壓VI係大於第二 電壓V2，因此，第一預傾角Θ1大於第二預傾角Θ2。 然後，請參照第20圖，其繪示對第19圖之液晶層 進行曝光之示意圖。於步驟S414中，以光線L透過第二 光罩274照射液晶分子216之第二部份222,使可聚合單 體272中被照射之可聚合單體於上基板表面212與下基 板表面214形成配向聚合層218之第二部份296。 然後，於步驟S416中，請同時參照第21A圖及第 21B圖，第21A圖繪示本實施例之製造方法之第三光罩示 15 201122676 意圖’第m圖㈣第m圖之方向21B_21B，的剖視 圖。提供一第三光罩286。第三光罩286具有一第三透光 =288及=第二遮光區292。第三透光區288對應於液晶 分子之第三部份282 (第三部份282㈣於帛U圖）的 位置亦即第二透光區係對應於圖案化透明電極224 之邊緣區域266(邊緣區域266繪示於第12圖）的位置。 然後，於步驟S418中，請同時參照第22圖，其繪 示提供第三電壓V3於上基板與下基板之間之示意圖二提 供一第二電壓V3於上基板206與下基板208之間，以使 液晶分子216以第三預傾角Θ3排列。其中，第三電壓V3 係大於第一電壓VI與第二電壓V2。 然後，於步驟S420中，請參照第23圖，其繪示對 第22圖之液晶層進行曝光之示意圖。以光線L·照射液晶 分子216之第三部份282’使可聚合單體272中被照射之 可聚合單體於上基板表面212與下基板表面214形成配 向聚合層218之第三部份298。由於第三電壓V3係大於 第一電壓VI及第二電壓V2，所以，第三預傾角03係大 於第一預傾角Θ1及第二預傾角02。 至此’完成具有三種不同預傾角，即第一預傾角 Θ1、第二預傾角<92及第三預傾角的之液晶分子的液晶 顯示面板280。 配向聚合層218至少由第一部份294、第二部份296 及第二部份298所組成，也就是說，配向聚合層gig使 液晶分子216分成二部份，該三部份的液晶分子在未受 電場作用的情況下即具有不同之預傾角。 16 201122676 I W*+，,ϋΓ/\ 此外，雖然第一實施例之製造方法係以三道光罩為 例作說明，然亦可只有兩道光罩。進一步地說，由於最 後一道曝光是要讓其它未反應的可聚合單體聚合，而已 聚合的可聚合單體若再此受到光線L之照射，雖亦會有 反應，但反應卻甚小。因此，若省略最後一道曝光製程 中之光罩，對已設定完成之預傾角影響也不大，故可省 略最後一道曝光製程中之光罩。舉例來說，於另一實施 態樣之製造方法中，可省略第13圖之步驟S416，並於步 φ 驟S420中，以光線L照射所有的液晶分子216。如此， 可節省一道光罩的成本。 第二實施例 請參照第24圖，其繪示依照本發明第二實施例之液 晶顯示面板之製造方法流程圖。第二實施例與第一實施 例不同之處在於，第二實施例係以曝光能量控制預傾角 之方式製作液晶顯示面板280,有別於第一實施例以電壓 • 控制預傾角之方式製作液晶顯示面板280。由於步驟S502 及步驟S504相似於第一實施例之步驟S402及步驟 S404，在此不再重複贅述，以下從步驟S506開始說明。 於步驟S506中，請同時參照第25圖，其繪示提供 電壓於上基板與下基板之間之示意圖。提供一電壓V於 上基板206與下基板208之間。 然後，於步驟S508中，請同時參照第26圖，其繪 示以第一光罩對第25圖之液晶層進行曝光之示意圖。以 一第一光線L1，透過第一光罩268照射液晶分子216之 17 201122676 I » T -Γ I \J k 1 ft 第一部份220 ’使液晶分子216之第一部份220以一第一 預傾角Θ1排列並使可聚合單體272中被照射之可聚合單 體於上基板表面212與下基板表面214形成配向聚合層 218之第一部份294。其中’第一光線L1具有一第一能 量（未繪示）。 然後，於步驟S510中’如第18A圖及第18B圖所示。 提供第二光罩274。第二光罩274已於第一實施例中作說 明，在此不再重複贅述。 然後，於步驟S512中，請同時參照第27圖，其繪 示以第二光罩對第25圖之液晶層進行曝光之示意圖^以 一第二光線L2，透過第二光罩274照射液晶分子216之 第一部份222’使液晶分子216之第二部份222以一第二 預傾角Θ2排列並使可聚合單體272中被照射之可聚合單 體於上基板表面212與下基板表面214形成配向聚合層 2曰 18之第二部份296。其中，第二光線L2具有一第二能 量（未綠示），上述之第一能量係大於第二能量。由於對 可聚合早體272曝光的能量愈大’則形成之聚合配向膜 對二晶分子216所引導之預傾角愈大。因此，第一預傾 角Θ1大於第二預傾角Θ2。 ' ^後，於步驟S514中，如第2U圖及第2ΐβ圖所示， 光罩286。第三光罩286已於第—實施例 明，在此不再重複贅述。 _ |後，於步驟S516中，請同時參照第 ==對第25圖之液晶層進行曝光之示意圖二 第二先線L3,透過第三光罩_照射液晶分子216之 201122676 ' I WH^/〇r/\ 第三部份282,使液晶分子216之第三部份282以一第三 預傾角<93排列並使可聚合單體272中被照射之可聚合單 體於上基板表面212與下基板表面214形成配向聚合層 218之第三部份298。其中，第三光線L3具有一第三能 量（未繪示），第三能量大於第一能量與第二能量。由於 第三能量大於第一能量與第二能量，所以，液晶分子216 之第三部份282之第三預傾角Θ3係大於液晶分子216之 第一部份220之第一預傾角<91及液晶分子216之第二部 鲁份222之第二預傾角Θ2。至此，完成具有三種不同預傾 角之液晶分子的液晶顯示面板280。 雖然第二實施例之製造方法係以三道光罩為例作說 明，然亦可只有兩道光罩。進一步地說，由於最後一道 曝光是要讓其它未反應的可聚合單體聚合，而已聚合的 可聚合單體若再此受到光線L之照射，雖亦會有反應， 但反應卻甚小。因此，若省略最後一道曝光製程中:光 罩，對已設定完成之預傾角影響也不大。因此，可省略 魯最後-道曝光製程中之光罩。舉例來說，可省略第圖 之步驟S514,並於步驟咖中，以第三光線L3對所有 的液晶分子216作照射。如此，可節省一道光罩的成本。 第三實施例 請參照第29圖’料示依照本發明第三實施例之液 晶顯示面板之製造方法流程圖。第三實施例與第一實施 :及第二實施例不同之處在於，第三實施例只需要一道 光罩就能完成具有三種不同預傾角之液晶分子之液晶顯 19 201122676 里 wny /or/\ 示面板2 8 0。 由於步驟S602相似於第一實施例之步驟S402，在 此不再重複贅述，以下從步驟S604開始說明。 於步驟S604中，請同時參照第30A圖及第30B圖， 第30A圖繪示本實施例之製造方法之光罩之示意圖，第 30B圖繪示第30A圖之方向30B-30B’的剖視圖。提供一 光罩302，例如是半透式光罩（Half-tone Mask)或狹縫 式光罩（SI it Mask)。 光罩302具有一第一透光區304、一第二透光區306 及一第三透光區308。進一步地說，當光線L照射光罩 302時，光線L以一第一穿透比例，例如是50%通過第一 透光區304、以一第二穿透比例，例如是20%通過第二透 光區306，及以一第三穿透比例，例如是100%通過第三 透光區308。液晶分子216之第一部份對應於第一透光區 304的位置、液晶分子216之第二部份222對應於第二透 光區306的位置且液晶分子216之第三部份282對應於 第三透光區308的位置。第三透光區308的位置對應於 圖案化透明電極224之邊緣區域266(邊緣區域266繪示 於第12圖）。其中，第三穿透比例係大於第一穿透比例 與第二穿透比例。 再來，於步驟S606中，請同時參照第31圖，其繪 示提供電壓於上基板與下基板之間之示意圖。提供一電 壓V於上基板206與下基板208之間。 然後，於步驟S608中，請同時參照第32圖，其繪 示對第31圖之液晶層進行曝光之示意圖。提供光線L， 20 201122676 1 υύ / ui r\ 透過光罩302照射液晶層210,使可聚合單體272中被照 射之可聚合卓體於上基板表面212與下基板表面214形 成配向聚合層218,以使液晶分子216之第一部份220係 以第一預傾角（91排列、液晶分子216之第二部份222以 第二預傾角<92排列，及液晶分子216之第三部份282以 第三預傾角Θ3排列。由於液晶分子216之預傾角與液晶 分子216所承受的照光量呈正比，即，穿透比例愈大者， 照光量愈大’故第三預傾角Θ3大於第二預傾角02、而第 • 一預傾角Θ1大於第二預傾角Θ2。至此，完成具有三種不 同預傾角之液晶分子之液晶顯示面板280。 此外’亦可將第一預傾角Θ1、第二預傾角Θ2與第 三預傾角Θ3，分別設置對應於彩色濾光片基板的不同顏 色，例如疋紅色、藍色及綠色之區域分別對應不同的預傾 角。 、 本發明上述實施例所揭露之液晶顯示面板及應用其 之液晶顯示裝置與其製造方法，藉由較大預傾角之液晶， 例如是液晶分子216之第一部份2 2 0及液晶分子2丨6之第 三部份282來縮短反應時間，且藉由其它預傾角較小的液 晶，例如是液晶分子216之第二部份222來降低暗態漏 光。使得整體液晶顯示面板2〇2可以兼顧縮短反應時間及 降低暗態漏光的效果。 綜上所述，雖財發明已以較佳實施·露如上， 然其並非㈣限定本發明。本發明所屬技術領域中具有 通常知識者，在不脫離本發明之精神和範_，#可作 各種之更動與潤飾。因此，本發昍♦, 發月之保濩乾圍當視後附 21 201122676 之申請專利範圍所界定者為準。 【圖式簡單說明】 之示意第圖㈣示習知之具有配向聚合層之液晶顯示面板 之示=輯讀照轉㈣—實施狀液晶顯示裝置 第3圖緣示第2圖之液晶顯示面板之示意圖。 電極之第第4 ^摊第3圖之方向D1觀相之圖案化透明 電極之第一種貫施態樣示意圖。 意圖第5輯讀照本發明之溝叙第二種實施態樣示 意圖第6騎示依照本發明之溝槽之第三種實施態樣示 施態US第8輯示錢本發明之溝槽之第四種實 施態㈣圖繪示依照本發明之溝槽之第五種實 圖第11圖繪示具有三種預傾角之液晶顯示面板之示意 圖。 第12圖繪示液晶分子之第三部份之設置部位圖。 第13輯示依照本發明第—實施例之液晶顯示面 板之製造方法流程圖。 第14圖繪TF上基板、下基板及液晶層之示意圖。 第15A圖繪示本實施例之製造方法之第一光罩之示 22 201122676 i wny /ur/\ 意圖 第15B圖繪示第15A圖之方向⑽ 意圖 第16圖㈣提供電壓於上基板與下基板 圖201122676 I w*+^ /υ"/·ν VI. Description of the Invention: [Technical Field] The present invention relates to a multi-quadrant vertical alignment type liquid crystal display panel and a method of fabricating the same, and in particular to a A dark-state, low-leakage, multi-quadrant, vertical alignment type liquid crystal display panel and a method of manufacturing the same. [Prior Art] A liquid crystal display panel (Liquid Crystal Display Panel) is characterized by lightness, power saving, and low radiation, in commercial and consumer electronic products. It has become a popular optoelectronic product by gradually replacing the traditional cathode ray tube screen. At present, the liquid crystal display panel has better power consumption, overall brightness and bright room contrast than the traditional cathode ray tube screen. Generally, in order to increase liquid crystal molecules The reaction time causes the liquid crystal molecules to be tilted by a pretilt angle first. Referring to the figure, a schematic diagram of a conventional liquid crystal display panel having an alignment polymer layer is shown. The 16 crystal display panel 100 has an upper substrate 102 and a lower substrate 104. - a first electrode 101, a second electrode 1 〇 3, an alignment polymer layer 1 〇 6, an alignment film and a plurality of liquids The crystallized molecule 108. The alignment polymerization layer 106 is formed by polymerizing a plurality of polymerizable monomers, and is formed on the upper substrate 102 or the lower substrate 1〇4 by a polymer-stabilizing alignment (PSA). The surface 'is used to guide the alignment of the liquid crystal molecules 1 〇 8 and the pre-tilt between the substrates. Thus, the reaction time of the liquid crystal molecules 1 〇 8 when the liquid crystal molecules 108 pass through the electric field can be shortened. However, the liquid crystal molecules 1G8 - the same - The direction is tilted, although the lack of liquid crystal molecules 1G8 can be shortened, but without the electric field, 201122676 1 1 / υτ / ,, there will be more serious dark state light leakage problems. The invention relates to a multi-quadrant vertical alignment type liquid crystal display panel and a liquid crystal display device using the same, and a method for manufacturing the same, and disposing at least two different pretilt angle liquid crystal molecules in the liquid crystal display panel, thereby reducing the reaction time and reducing the darkness. According to the first aspect of the present invention, a multi-quadrant vertical alignment type liquid crystal display panel is proposed, and the liquid crystal display panel is disposed on a liquid crystal The liquid crystal display panel comprises an upper substrate, a lower substrate, a liquid crystal layer and an alignment polymer layer 4. The substrate has an upper substrate surface, and the lower substrate has a lower substrate surface. The liquid crystal layer is filled on the upper substrate surface and the lower substrate surface. The inter-liquid layer comprises a plurality of liquid crystal molecules. The alignment polymer layer is formed on at least one of the surface of the upper substrate and the surface of the lower substrate for guiding the first portion of the liquid crystal molecules to be aligned at a first pretilt angle, and guiding the liquid crystal molecules One of the first portions is arranged at a second pretilt angle, wherein the first pretilt angle is greater than the second pretilt angle. According to a first aspect of the invention, a liquid crystal display device is provided. The liquid crystal display device comprises a multi-quadrant vertical alignment type liquid crystal display panel and a backlight module. The liquid crystal display panel includes an upper substrate 'the lower substrate, a liquid crystal layer and an alignment polymer layer. The upper substrate has an upper substrate surface. The lower substrate has a lower substrate surface. The liquid crystal layer is filled between the surface of the upper substrate and the surface of the lower substrate. The liquid crystal layer includes a plurality of liquid crystal molecules. The alignment polymer layer is formed on at least one of the surface of the upper substrate and the surface of the lower substrate for guiding the first portion of the liquid crystal molecules to be arranged at a first pretilt angle, and the reference 201122676 1 vv '•ty I \ji γλ liquid crystal The second portion of one of the molecules is arranged at a second pretilt angle. Wherein, the first pretilt angle is greater than the second pretilt angle. The backlight module is used to provide light to the LCD display panel to show off. According to a third aspect of the invention, a method of manufacturing a liquid crystal display panel is provided. The manufacturing method includes the following steps. An upper substrate, a lower substrate and a liquid crystal layer are provided. The liquid crystal layer is filled between the upper substrate surface of one of the upper substrate and the lower substrate surface of the lower substrate, the liquid crystal layer includes a plurality of liquid crystal molecules and a plurality of polymerizable monomers; and a first voltage is provided between the upper substrate and the lower substrate The liquid crystal molecules are arranged at a first pretilt angle; a first photomask is provided. The first mask has a first light transmissive region, and the first light transmissive region corresponds to a first portion of the liquid crystal molecules; and the first portion of the liquid crystal molecules is irradiated with the light through the first mask to make the polymerizable The irradiated polymerizable monomer in the monomer forms a first portion of an alignment polymer layer on at least one of the surface of the upper substrate and the surface of the lower substrate; and provides a second voltage between the upper substrate and the lower substrate to enable liquid crystal The molecules are arranged at a second pretilt angle; the second portion of the liquid crystal molecules is irradiated with light, and the irradiated polymerizable monomer in the polymerizable monomer forms an alignment polymerization layer on at least one of the surface of the upper substrate and the surface of the lower substrate. The second part. According to a fourth aspect of the present invention, a method of manufacturing a liquid crystal display panel is proposed. The manufacturing method includes the following steps. An upper substrate, a lower substrate and a liquid crystal layer are provided. The liquid crystal layer is filled between the upper substrate surface of one of the upper substrate and the lower substrate surface of the lower substrate, the liquid crystal layer includes a plurality of liquid crystal molecules and a plurality of polymerizable monomers; and a voltage is provided between the upper substrate and the lower substrate; a first photomask, the first photomask has a first light transmissive region, and the first light transmissive region corresponds to a first portion of the liquid crystal molecules; and a first 201122676 I νν*+7/〇Γ/Λ Light, illuminating the first portion of the liquid crystal molecules through the first mask such that the first portion of the liquid knives is aligned at a first pretilt angle and the polymerizable monomer in the polymerizable monomer is irradiated thereon Forming a first portion of the alignment polymer layer on at least one of the surface of the substrate and the surface of the lower substrate; illuminating a second portion of the liquid crystal molecules with a second light to make the second portion of the liquid crystal molecules The pretilt angle arrangement causes the irradiated polymerizable monomer in the polymerizable monomer to form at least a second portion of the alignment polymer layer on the upper substrate surface and the lower substrate surface. The first light has a first energy, and the second light has a second energy, the first energy being different from the second energy. According to a fifth aspect of the invention, a method of manufacturing a liquid crystal display panel is proposed. The manufacturing method includes a step of ordering. An upper substrate, a lower substrate, and a liquid crystal layer are provided. The liquid crystal layer is filled on one of the upper substrate and between the lower substrate and the lower substrate surface, the liquid crystal layer includes a plurality of liquid helium molecules and a plurality of polymerizable monomers; and a voltage is applied to the upper substrate and the lower substrate Provided—the reticle reticle has a first-light transmitting region and a first light transmitting region. The first light-transmitting region corresponds to -1 part of the liquid crystal and the second light-transmitting region corresponds to the first part of the liquid crystal, and the first light-transmitting region has a ratio of 'transmission' to enable the light to penetrate through the first Proportion through the first through: the first - ΐϊτ light transmissive region has a second penetration ratio 'the light is passed through the second light transmissive region by two: = the light is transmitted through the reticle The at least one of the surface of the substrate that is irradiated in the polymerizable monomer and the surface of the lower substrate is formed: a poly layer. The alignment polymer layer is used to guide the liquid crystal to the first portion of the pre-tilt arrangement and to guide the second portion of the liquid crystal. The above-mentioned contents of the present invention can be more clearly understood by a second pre-tilt angle 201122676 i wny/υτ/Λ. The following is a detailed description of the preferred embodiment, and is described in detail below with reference to the following drawings: The following is a description of the preferred embodiments of the present invention, but the description of the embodiments is for illustrative purposes only, and the drawings are for illustrative purposes only and are not intended to limit the scope of the present invention. use. Further, the illustration of the embodiments also omits unnecessary elements to clearly show the technical features of the present invention. First Embodiment Referring to Figure 2, there is shown a schematic view of a liquid crystal display device in accordance with a first embodiment of the present invention. The liquid crystal display device 200 includes a liquid crystal display panel 202, a backlight module 204, and an outer frame 203. The backlight module 204 is configured to provide light to the liquid crystal display panel 202 to display the surface. Among them, the liquid crystal display device 200 is, for example, a multi-domain vertical alignment (MVA) type display panel. Please refer to the third circle, which shows the schematic of the liquid crystal display panel of Fig. 2. The liquid crystal display panel 202 includes an upper substrate 206, a lower substrate 208, a liquid crystal layer 210, and an alignment polymer layer 218. The upper substrate 206 is, for example, a color filter, a light substrate having an upper substrate surface 212, an alignment film 264, and a transparent electrode 223. The lower substrate 208, for example, a thin film transistor matrix substrate having a lower substrate surface 214 and including an alignment film 264 and a display electrode, such as a patterned transparent electrode 224 having a plurality of trenches 226, FIG. Take the example of drawing a channel in ▼22-ry /, _/ in 201122676 as an example. The day layer 21 is filled between the upper substrate surface 212 and the lower base surface 214. The liquid helium layer 210 includes a plurality of liquid crystal molecules 216. The alignment polymerization is formed on the upper substrate surface 212 and the lower substrate surface 214 for aligning the first portion 22 of the molecules 216 with a first pretilt angle Θ1 and guiding the second portion 222 of the liquid crystal molecules 216. The parts are arranged in a second pretilt angle. The first pretilt angle Θ1 may be between 6. ~3〇. Between, the first pretilt angle is greater than the second pretilt angle 02, and the second pretilt angle 02 may be less than 3. . Thus, the liquid crystal of the larger pretilt angle ‘that is, the first portion 22 〇 I of the liquid crystal molecules 216 shortens the reaction time ′ while the first of the solar molecules 16 is consumed by the liquid crystal 91 c ^ ^ 1 having a small pretilt angle. The 222 is used to reduce the dark state light leakage, so that the overall liquid crystal display panel 202 can achieve the effects of shortening the reaction time and reducing the dark state light leakage. Among them, the dark state is a state in which liquid crystal molecules are not subjected to an electric field. The first pretilt angle Θ1 is between 6 and more limited. ~10. It is more effective in reducing dark light leakage. - Although the alignment polymerization layer of this embodiment is exemplified by being formed on the upper substrate and the lower substrate, in other embodiments, the alignment poly octa is formed only on one of the upper substrate and the lower substrate. The Q θ may be described as an example in which the patterned transparent electrode of the present embodiment is disposed on the lower surface 214. However, in other embodiments, the patterned transparent electrode may be formed on the upper substrate surface 212. Alternatively, the upper substrate surface 212 and the lower substrate surface 214 may be simultaneously formed with a patterned transparent electrode. In addition, although the upper substrate 2〇6 of the present embodiment is a color filter substrate and the lower substrate 208 is a thin film transistor matrix substrate (ie, a display panel in the form of c〇l〇r filter on TFT) For example, in the embodiment, the lower substrate 208 can simultaneously form a thin film transistor matrix and a color light-emitting sheet, and the color filter can be formed on the thin film transistor. On the matrix, it is a display panel in the form of COA (Co 1 or fi 1 ter on Array). Alternatively, the lower substrate 208 may be formed with a thin film transistor matrix and a color filter at the same time, and the thin film transistor matrix may be formed on a color filter or a light sheet, that is, a display panel in the form of an AOC (Array on Color filter). Referring to Fig. 4, there is shown a first embodiment of a patterned transparent electrode viewed in the direction of Fig. 3). The trench 226 is sandwiched by an edge 228 of the patterned transparent electrode 224 with an acute angle a. The liquid crystal molecules 216 having the first pretilt angle ,1, that is, the first portion 2 2 0 ' of the liquid crystal molecules 216 are located between the two grooves: the grooves 2 26 ' preferably, but not limited to, the two grooves 226 The middle portion 232. The liquid crystal molecules 216' having the second pretilt angle 即2, i.e., the second portion 222 of the liquid crystal molecules 216, are located at other portions 234 of the patterned transparent electrode 224. In addition, although the trench 226 of the patterned transparent electrode 224 of the present embodiment is exemplified by an acute angle A with one side 228 of the patterned transparent electrode 224, in another embodiment, please refer to FIG. A schematic view of a second embodiment of a trench in accordance with the present invention is shown. The extending direction of the trench 230 is substantially perpendicular to one side 242 of the patterned transparent electrode 244, and the liquid crystal molecules 216 having the first pretilt angle, that is, the first portion 220 of the liquid crystal molecules 216 are located in the two trenches 230. The portion 260 between, preferably but not limited to, is located intermediate the two grooves 23〇. Alternatively, please refer to Fig. 6, which shows a schematic view of a first embodiment of a trench in accordance with the present invention. The extending direction of the trench 236 is substantially parallel to one side of the patterned transparent electrode 250, and the liquid crystal molecule 216 having the first pretilt angle θ 1 201122676 1 yy *tj / / ui, that is, the liquid crystal molecule 216 A portion 22 〇 is located at a location 262 between the two grooves 236. Or, please refer to Figures 7 and 8, for a schematic view of a fourth embodiment of a trench in accordance with the present invention. As shown in Fig. 7, the patterned transparent electrode 246 has a geometrically symmetric patterned groove shift. The first portion 220 of the liquid crystal cell 216 is located at the geometric center of the patterned trench 2, and the second portion 222 of the liquid crystal molecule 216 is located at a portion other than the geometrically symmetric center 24 of the patterned trench 238. Such as. As shown in Fig. 8, the patterned transparent electrode 252 # has a geometrically symmetrical patterned groove 310. The first portion 220 of the liquid crystal molecules 216 is located at the geometrically symmetric center 312 of the patterned trench 310, and the second portion of the liquid crystal molecules 216 is located at a location other than the geometrically symmetric center 312 of the patterned trench 31〇. The patterned transparent electrodes of the present embodiment, for example, the patterned transparent electrodes 224, 244, 246, 250, and 252 are exemplified by having grooves. However, in other embodiments, the display electrodes may not have Groove. Referring to Figure 9 and Figure 1, a schematic view of a fifth embodiment of the present invention is shown. The first portion 22 of the liquid crystal molecules 216 is located at the geometrically symmetric center 256 of the display electrode 254, such as at the center of the rectangle. In addition, although the shape of the first portion 22 of the liquid crystal molecule 216 is illustrated by the circular shape of FIG. 9, it is not intended to limit the first portion of the liquid crystal molecule 216. The distribution shape may also be other shapes 'for example, the rectangle 314 shown in FIG. In addition, although the groove pattern of the patterned transparent electrode is illustrated by using FIG. 4 to FIG. 8 as an example, in other embodiments, the groove pattern of the 201122676 FIG. 8 may be mixed and patterned in the same pattern. Transparent, that is, as long as the liquid crystal molecules between the two trenches have the first pre-=. Alternatively, the geometrically symmetrical grooved pattern may be located at a first pretilt angle of the molecule. That is, the groove form of the patterned transparent electrode is not limited by this embodiment. Here: 'Although the pretilt angle of this embodiment is two examples, it is said to be a month. ..., in its example, it can also be more than three kinds of pretilt angles. The following describes the implementation of the three pretilt angles. Referring to FIG. 9 and FIG. 12, FIG. 11 is a schematic view showing a liquid crystal display panel having three pretilt angles. FIG. 12 is a view showing a setting portion of a third portion of liquid crystal molecules. As shown in FIG. U, the second portion 282 of one of the liquid crystal molecules 216 of the liquid crystal display panel 280 is arranged at a third pretilt angle <93 and is located at the edge region 266 where the patterned transparent electrode 2 is not shown. . The position of this edge region 266 corresponds to the position of the black moment |j car (Biack Matrix, bm) 284 (the special color matrix 284 is shown in the πth image). Since the edge area is shifted to the non-display area, even if dark light leakage occurs, the quality of the display is affected. Therefore, the pretilt angle of the liquid crystal molecules disposed at the edge region 266 (i.e., the second portion of the liquid crystal molecules 216) may be greater than the first pretilt vanadium and the second pretilt angle Θ2' to substantially shorten the reaction time. Further speaking, the liquid crystal through the large pretilt angle can drive the surrounding liquid crystal to accelerate and pour, and the surrounding liquid crystals under the influence of each other accelerates the pouring speed of the whole liquid crystal, thereby greatly shortening the reaction time. Further, the distribution area of the first portion 220 of the liquid crystal molecules 216 is about the area of the light-transmitting region of the display electrode, that is, the area of the aperture ratio is between about (10) and 90% and preferably between 10% and 30%. For example, the distribution of the first portion of the liquid crystal molecules of the fourth to the second and second graphs of the fourth to the fourth and fourth and fourth and fourth graphs may be about 5% to 90% of the aperture ratio of the display electrodes. Hereinafter, a method of manufacturing the liquid crystal display panel of the present invention will be described by taking the liquid crystal display panel 280 of Fig. 11 as an example. Referring to Figure 13, there is shown a flow chart of a method of fabricating a liquid crystal display panel in accordance with a first embodiment of the present invention. The manufacturing method includes the following steps. In step S402, please refer to FIG. 14 at the same time, which shows a schematic diagram of the upper substrate, the lower substrate and the liquid crystal layer. The upper substrate 206, the lower substrate φ 208, and the liquid crystal layer 210 are provided. The liquid crystal layer 210 includes a plurality of liquid crystal molecules and a plurality of polymerizable monomers 272. The liquid crystal molecules 216 are substantially perpendicular to the substrate surface 212 above the upper substrate 206 and the substrate surface 214 below the lower substrate 208. The liquid crystal molecules 216 are perpendicular to the upper substrate surface 212 and the lower substrate surface 214 by the alignment film 264 of the upper substrate 206 and the lower substrate 208. The lower substrate 208 includes display electrodes, such as patterned transparent electrodes 224, 244, 246, 250, 252. The manufacturing method of this embodiment is described by taking the patterned transparent electrode 224 as an example. • In step S404, please refer to FIG. 15 and FIG. 15 'figure 15' to illustrate a schematic diagram of the first mask of the manufacturing method of the embodiment, and FIG. 15 is a diagram showing the direction of the 15th panel. -15 Β, a cross-sectional view. A first mask 268 is provided, the first mask 268 having a first light transmissive region 270. In order to expose the first portion 220 of the liquid crystal molecules 216, the first light-transmissive region 270 corresponds to the position of the first portion 220 of the liquid crystal molecules 216 (the first portion 220 is shown in FIG. 11), and the liquid crystal molecules 216 The first portion 220 is located at an intermediate portion 232 of the trench 226 of FIG. That is, the first light transmitting region 270 corresponds to the middle portion of the groove 226 of Fig. 4 201122676 I VT T / i IF1 Plant 1 portion 232. Next, in step S406, please refer to FIG. 16, which shows a schematic diagram of providing a voltage between the upper substrate and the lower substrate. A first voltage VI is provided between the transparent electrode 223 of the upper substrate 206 and the patterned transparent electrode 224 of the lower substrate 208 such that the liquid crystal molecules 216 are aligned at a first pretilt angle Θ1. Further, the first voltage V1 is, for example, between 5 volts (V) and 50 volts. Due to the arrangement of the trenches 226, the alignment of the liquid crystal molecules can be multi-dimensional. Thus, after the subsequent exposure process, the polymerizable alignment film in which the polymerizable monomers are polymerized in a multi-dimensional arrangement of liquid crystal molecules will cause the liquid crystal molecules to be arranged in a multi-dimensional manner without being subjected to an electric field. Next, please refer to Fig. 17, which is a schematic view showing exposure of the liquid crystal layer of Fig. 16. In step S408, the first mask 268 is disposed under the lower substrate 208, and irradiates the first portion 220 of the liquid crystal molecules 216 through the first mask 268 with a light L, such as ultraviolet light. The irradiated polymerizable monomer in the polymerized monomer 272 forms a first portion 294 of the alignment polymeric layer 218 on the upper substrate surface 212 and the lower substrate surface 214. In addition, although the first mask of the present embodiment will be described as being disposed below the lower substrate 208, in other embodiments, the first mask 268 may be disposed above the upper substrate 206, for example, when When the liquid crystal display panel 202 is a COA type or AOC type display panel, the first mask 268 may be disposed above the upper substrate 206 to illuminate the light L from the upper side of the first mask 268 toward the upper substrate 206. Then, in step S410, please refer to FIG. 18A and 201122676 1 TT-T//V 羼 factory 1 18B, and FIG. 18A is a schematic view of the second reticle of the manufacturing method of the embodiment, FIG. 18B A cross-sectional view of the direction 18B-18B' of Fig. 18A is shown. A second mask 274 is provided. The second mask 274 has a second light transmissive region 276, a first light blocking region 278 and an edge light blocking region 300. The first opaque region 278 corresponds to the position of the first light transmissive region 270 of the first mask 268 to prevent the first portion 294 of the alignment polymer layer 218 having the first pretilt angle 设定1 from being affected by illumination. Since three pretilt angles are to be produced in this embodiment, the liquid crystal at the edge region 266 of the patterned transparent electrode 224, that is, the third portion 282 of the liquid crystal molecules 216 is shielded by the edge shading φ region 300 to avoid liquid crystal molecules. The polymerizable monomer of the third portion 282 of 216 is polymerized. Further, the second light transmitting region 276 corresponds to the position of the second portion 222 of the liquid crystal molecules 216. Then, referring to Fig. 19, a schematic diagram of providing a second voltage between the upper substrate and the lower substrate is shown. In step S412, a second voltage V2 is provided between the upper substrate 206 and the lower substrate 208 to align the liquid crystal molecules 216 with the second pretilt angle Θ2. The first voltage VI is greater than the second voltage V2, and therefore, the first pretilt angle Θ1 is greater than the second pretilt angle Θ2. Next, please refer to Fig. 20, which is a schematic view showing exposure of the liquid crystal layer of Fig. 19. In step S414, the second portion 222 of the liquid crystal molecules 216 is irradiated with the light L through the second mask 274, so that the irradiated polymerizable monomer in the polymerizable monomer 272 is formed on the upper substrate surface 212 and the lower substrate surface 214. The second portion 296 of the alignment layer 218 is aligned. Then, in step S416, please refer to FIG. 21A and FIG. 21B at the same time, and FIG. 21A shows the third reticle of the manufacturing method of the embodiment 15 201122676, which is intended to be the 'mth picture (four) direction m 21B_21B, Cutaway view. A third mask 286 is provided. The third mask 286 has a third light transmission = 288 and a second light blocking area 292. The third light-transmissive region 288 corresponds to the position of the third portion 282 of the liquid crystal molecules (the third portion 282 (four) is in the U-picture), that is, the second light-transmitting region corresponds to the edge region 266 of the patterned transparent electrode 224 (edge Area 266 is shown at the position of Figure 12). Then, in step S418, please refer to FIG. 22, which shows a second voltage V3 between the upper substrate and the lower substrate, and a second voltage V3 between the upper substrate 206 and the lower substrate 208. The liquid crystal molecules 216 are arranged at a third pretilt angle Θ3. The third voltage V3 is greater than the first voltage VI and the second voltage V2. Then, in step S420, please refer to Fig. 23, which is a schematic view showing exposure of the liquid crystal layer of Fig. 22. The third portion 282' of the liquid crystal molecules 216 is irradiated with light L. The irradiated polymerizable monomer in the polymerizable monomer 272 forms a third portion of the alignment polymer layer 218 on the upper substrate surface 212 and the lower substrate surface 214. . Since the third voltage V3 is greater than the first voltage VI and the second voltage V2, the third pretilt angle 03 is greater than the first pretilt angle Θ1 and the second pretilt angle 02. Heretofore, the liquid crystal display panel 280 of liquid crystal molecules having three different pretilt angles, that is, a first pretilt angle Θ1, a second pretilt angle <92 and a third pretilt angle is completed. The alignment polymer layer 218 is composed of at least a first portion 294, a second portion 296 and a second portion 298, that is, the alignment polymerization layer gig divides the liquid crystal molecules 216 into two parts, and the three liquid crystal molecules There is a different pretilt angle without being affected by the electric field. 16 201122676 I W*+,,ϋΓ/\ In addition, although the manufacturing method of the first embodiment is described by taking three masks as an example, there may be only two masks. Further, since the last exposure is to polymerize other unreacted polymerizable monomers, and the polymerizable polymerizable monomers are further irradiated with the light L, there is a reaction, but the reaction is small. Therefore, if the mask in the last exposure process is omitted, the pretilt angle of the set completion is not greatly affected, so that the mask in the last exposure process can be omitted. For example, in another manufacturing method of the embodiment, the step S416 of Fig. 13 may be omitted, and in the step S420, all the liquid crystal molecules 216 are irradiated with the light L. In this way, the cost of a mask can be saved. SECOND EMBODIMENT Referring to Figure 24, there is shown a flow chart of a method of fabricating a liquid crystal display panel in accordance with a second embodiment of the present invention. The second embodiment is different from the first embodiment in that the second embodiment fabricates the liquid crystal display panel 280 in such a manner that the exposure energy is controlled by the pretilt angle, which is different from the first embodiment in that the liquid crystal is formed by the voltage control pretilt angle. The display panel 280. Since step S502 and step S504 are similar to step S402 and step S404 of the first embodiment, the description thereof will not be repeated here, and the description will be started from step S506. In step S506, please refer to FIG. 25 at the same time, which shows a schematic diagram of providing a voltage between the upper substrate and the lower substrate. A voltage V is provided between the upper substrate 206 and the lower substrate 208. Then, in step S508, please refer to FIG. 26 at the same time, which shows a schematic diagram of exposing the liquid crystal layer of FIG. 25 with the first mask. Passing the first light ray L1 through the first mask 268 to illuminate the liquid crystal molecules 216 17 201122676 I » T - Γ I \ J k 1 ft the first portion 220 ' makes the first portion 220 of the liquid crystal molecules 216 A pretilt angle Θ1 is aligned and the irradiated polymerizable monomer in the polymerizable monomer 272 forms a first portion 294 of the alignment polymer layer 218 on the upper substrate surface 212 and the lower substrate surface 214. Wherein the first light L1 has a first energy (not shown). Then, in step S510, as shown in Figs. 18A and 18B. A second mask 274 is provided. The second mask 274 has been described in the first embodiment, and the detailed description thereof will not be repeated here. Then, in step S512, please refer to FIG. 27 at the same time, which shows a schematic diagram of exposing the liquid crystal layer of FIG. 25 with the second mask to a second light L2, and irradiating the liquid crystal molecules through the second mask 274. The first portion 222' of the second portion 222 of the liquid crystal molecules 216 is aligned at a second pretilt angle Θ2 and the irradiated polymerizable monomer in the polymerizable monomer 272 is applied to the upper substrate surface 212 and the lower substrate surface. 214 forms a second portion 296 of the alignment polymeric layer 2曰18. The second light L2 has a second energy (not shown in green), and the first energy system is greater than the second energy. The greater the energy exposure to the polymerizable precursor 272, the greater the pretilt angle that the formed polymeric alignment film directs to the dicrystalline molecules 216. Therefore, the first pretilt angle Θ1 is larger than the second pretilt angle Θ2. After ^ ^, in step S514, the photomask 286 is as shown in the 2Uth and 2nd ΐβ diagrams. The third mask 286 has been described in the first embodiment, and the detailed description thereof will not be repeated here. After the _ |, in step S516, please refer to the second = the first line L3 of the liquid crystal layer of the 25th picture, and the second mask _ irradiated the liquid crystal molecules 216 of 201122676 'I WH^/第三r/\ third portion 282, aligning third portion 282 of liquid crystal molecules 216 at a third pretilt angle <93 and causing the polymerizable monomer in the polymerizable monomer 272 to be irradiated onto the upper substrate surface 212 A third portion 298 of the alignment polymeric layer 218 is formed with the lower substrate surface 214. The third light L3 has a third energy (not shown), and the third energy is greater than the first energy and the second energy. Since the third energy is greater than the first energy and the second energy, the third pretilt angle Θ3 of the third portion 282 of the liquid crystal molecules 216 is greater than the first pretilt angle <91 of the first portion 220 of the liquid crystal molecules 216. The second pretilt angle 222 of the second portion 222 of the liquid crystal molecules 216. So far, the liquid crystal display panel 280 having liquid crystal molecules of three different pretilt angles is completed. Although the manufacturing method of the second embodiment is exemplified by three masks, there are only two masks. Further, since the last exposure is to polymerize other unreacted polymerizable monomers, and the polymerizable polymerizable monomers are further irradiated with the light L, there is a reaction, but the reaction is small. Therefore, if the last exposure process is omitted: the reticle has little effect on the pre-tilt angle that has been set. Therefore, the mask in the final-channel exposure process can be omitted. For example, step S514 of the figure may be omitted, and in the step coffee, all of the liquid crystal molecules 216 are irradiated with the third light L3. In this way, the cost of a reticle can be saved. THIRD EMBODIMENT Referring to Figure 29, a flow chart showing a method of manufacturing a liquid crystal display panel in accordance with a third embodiment of the present invention is shown. The third embodiment is different from the first embodiment: and the second embodiment in that the third embodiment only needs a mask to complete the liquid crystal display of liquid crystal molecules having three different pretilt angles. 19 wnd /or/\ Display panel 2 800. Since step S602 is similar to step S402 of the first embodiment, the description thereof will not be repeated here, and the following description will be made from step S604. In step S604, please refer to FIG. 30A and FIG. 30B simultaneously. FIG. 30A is a schematic view of the photomask of the manufacturing method of the embodiment, and FIG. 30B is a cross-sectional view of the direction 30B-30B' of the 30A. A photomask 302 is provided, such as a half-tone mask or a SI it mask. The mask 302 has a first light transmissive area 304, a second light transmissive area 306 and a third light transmissive area 308. Further, when the light L is irradiated to the reticle 302, the light ray L passes through the first light transmitting area 304 at a first penetration ratio, for example, 50%, and passes through the second light transmission ratio, for example, 20% through the second. The light transmitting region 306 passes through the third light transmitting region 308 at a third penetration ratio, for example, 100%. The first portion of the liquid crystal molecules 216 corresponds to the position of the first light transmissive region 304, the second portion 222 of the liquid crystal molecules 216 corresponds to the position of the second light transmissive region 306, and the third portion 282 of the liquid crystal molecules 216 corresponds to The position of the third light transmitting region 308. The position of the third light transmissive region 308 corresponds to the edge region 266 of the patterned transparent electrode 224 (the edge region 266 is shown in Fig. 12). Wherein, the third penetration ratio is greater than the first penetration ratio and the second penetration ratio. Further, in step S606, please refer to FIG. 31 at the same time, which shows a schematic diagram of providing a voltage between the upper substrate and the lower substrate. A voltage V is provided between the upper substrate 206 and the lower substrate 208. Then, in step S608, please refer to Fig. 32 at the same time, which shows a schematic diagram of exposing the liquid crystal layer of Fig. 31. Providing light L, 20 201122676 1 υύ / ui r\ illuminating the liquid crystal layer 210 through the reticle 302 to form the alignable polymerizable layer in the polymerizable monomer 272 to form the alignment polymer layer 218 on the upper substrate surface 212 and the lower substrate surface 214. So that the first portion 220 of the liquid crystal molecules 216 is at a first pretilt angle (91 arrangement, the second portion 222 of the liquid crystal molecules 216 is arranged at a second pretilt angle < 92, and the third portion of the liquid crystal molecules 216 282 is arranged at a third pretilt angle 。 3. Since the pretilt angle of the liquid crystal molecules 216 is proportional to the amount of illumination of the liquid crystal molecules 216, that is, the larger the penetration ratio, the larger the amount of illumination is, so the third pretilt angle Θ 3 is larger than the first Two pretilt angles 02, and the first pretilt angle Θ1 is greater than the second pretilt angle Θ2. Thus, the liquid crystal display panel 280 having liquid crystal molecules of three different pretilt angles is completed. Further, the first pretilt angle Θ1, the second pre- The dip angle Θ2 and the third pretilt angle Θ3 respectively set different colors corresponding to the color filter substrate, for example, the areas of magenta, blue, and green respectively correspond to different pretilt angles. The liquid crystal display disclosed in the above embodiment of the present invention The panel and the liquid crystal display device using the same, and the manufacturing method thereof, shorten the reaction time by a liquid crystal having a large pretilt angle, for example, a first portion of the liquid crystal molecules 216, and a third portion 282 of the liquid crystal molecules 2? And by other liquid crystals having a small pretilt angle, for example, the second portion 222 of the liquid crystal molecules 216, the dark state light leakage is reduced, so that the overall liquid crystal display panel 2〇2 can achieve the effects of shortening the reaction time and reducing the dark state light leakage. In view of the above, although the invention has been described in a preferred embodiment, it is not intended to limit the invention. Those skilled in the art to which the present invention pertains can be made without departing from the spirit and scope of the invention. The change and refinement. Therefore, the hairpin ♦ ♦ 发 之 濩 濩 当 当 21 21 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 The display of the liquid crystal display panel of the alignment layer (4) - the schematic diagram of the liquid crystal display panel of the second embodiment of the liquid crystal display device of the embodiment. The fourth direction of the electrode is the direction D1 of the third figure. A schematic diagram of a first embodiment of a patterned transparent electrode. Intent of the fifth embodiment of the present invention is a schematic diagram of a second embodiment of the present invention. The sixth embodiment shows a third embodiment of the trench according to the present invention. The fourth embodiment of the present invention shows a fourth embodiment of the trench of the present invention. The fourth embodiment of the trench according to the present invention shows a liquid crystal display panel having three pretilt angles. Fig. 12 is a view showing a portion of a liquid crystal display panel according to a first embodiment of the present invention. Fig. 14 is a flow chart showing a method of manufacturing a liquid crystal display panel according to a first embodiment of the present invention. FIG. 15A is a diagram showing the first mask of the manufacturing method of the present embodiment. 22 201122676 i wny /ur/\ Intent 15B shows the direction of FIG. 15A (10). FIG. 16 (4) is provided. Voltage on the upper and lower substrate
第18B圖繪示第18A圖之方 ^ 1 Ο ^ B 188 的剖視圖 第19圖，外供第二電壓於上基板與下基 之示意圖。 第20圖繪示對第19圖之液晶層進行曝光之示意圖。 第21A圖繪示本實施例之製造方法之第三光罩示音 圖。 第21B圖繚示第21八圖之方向21B 21B，的剖視圖。 第22圖繪示提供第三電壓V3於上基板與下基板之 間之示意圖。 第23圖繪示對第22圖之液晶層進行曝光之示意圖。 第24圖繪示依照本發明第二實施例之液晶顯示面 板之製造方法流程圖。 第25圖繪示提供電壓於上基板與下基板之間之示 意圖。 第26圖繪示以第一光罩對第25圖之液晶層進行曝 光之示意圖。 第27圖繪示以第二光罩對第25圖之液晶層進行曝 光之示意圖。 23 201122676 I w*+7 /υτ/Λ ' 第28圖繪示以第三光罩對第25圖之液晶層進行曝 光之示意圖。 第29圖繪示依照本發明第三實施例之液晶顯示面 板之製造方法流程圖。 第30Α圖繪示本實施例之製造方法之光罩之示意 圖。 第30Β圖繪示第30Α圖之方向30Β-30Β’的剖視圖。 第31圖繪示提供電壓於上基板與下基板之間之示 意圖。 g 第32圖繪示對第31圖之液晶層進行曝光之示意圖。 【主要元件符號說明】 100、202、280 :液晶顯示面板 101 :第一電極 102、206 :上基板 103 :第二電極 104、 208 :下基板 φ 105、 264 :配向膜 106、 218 :配向聚合層 108 :液晶分子 200 :液晶顯示裝置 203 :外框 204 :背光模組 210 :液晶層 212 :上基板表面 24 201122676 1 vvh·，,υ「Α\ 214 :下基板表面 216 :液晶分子 220 :液晶分子之第一部份 222 :液晶分子之第二部份 223 :透明電極 224、244、246、250、252、254 :圖案化透明電極 226、230、236 :溝槽 228、242、248 :圖案化透明電極之一邊 φ 232:溝槽之中間部位 234 :其它部位 238、 310 :圖案化溝槽 239、 311 :部位 240、 256、312 :幾何對稱中心 260、262 :溝槽之間的部位 266 :邊緣區域 268 :第一光罩 • 270、304 :第一透光區 272 :可聚合單體 274 :第二光罩 276、306 :第二透光區 278 :第一遮光區 282 :液晶分子之第三部份 284 :黑色矩陣 286 :第三光罩 288、308 :第三透光區 25 201122676 i WH7 /υΓ/Λ ' 292 :第三遮光區 294 :配向聚合層之第一部份 296 :配向聚合層之第二部份 298 :配向聚合層之第三部份 300 :邊緣遮光區 302 :光罩 314 :矩形 VI :第一電壓 V2 :第二電壓 _ V :電壓 Θ1 :第一預傾角 <92 :第二預傾角 Θ3 :第三預傾角 D1 :方向 L :光線 L1 :第一光線 L2 :第二光線 鲁 26Fig. 18B is a cross-sectional view showing the square of Fig. 18A ^ 1 Ο ^ B 188 Fig. 19 is a schematic view showing the external voltage applied to the upper substrate and the lower substrate. Fig. 20 is a view showing the exposure of the liquid crystal layer of Fig. 19. Fig. 21A is a view showing a third mask of the manufacturing method of the embodiment. Fig. 21B is a cross-sectional view showing the direction 21B 21B of Fig. 21; Figure 22 is a schematic diagram showing the provision of a third voltage V3 between the upper substrate and the lower substrate. Fig. 23 is a view showing the exposure of the liquid crystal layer of Fig. 22. Figure 24 is a flow chart showing a method of manufacturing a liquid crystal display panel in accordance with a second embodiment of the present invention. Fig. 25 is a view showing the supply of voltage between the upper substrate and the lower substrate. Fig. 26 is a view showing the exposure of the liquid crystal layer of Fig. 25 by the first mask. Fig. 27 is a view showing the exposure of the liquid crystal layer of Fig. 25 by the second mask. 23 201122676 I w*+7 /υτ/Λ ' Figure 28 is a schematic view showing the exposure of the liquid crystal layer of Fig. 25 with a third mask. Figure 29 is a flow chart showing a method of manufacturing a liquid crystal display panel in accordance with a third embodiment of the present invention. Fig. 30 is a schematic view showing a reticle of the manufacturing method of the embodiment. Figure 30 is a cross-sectional view showing the direction 30Β-30Β' of the 30th drawing. Fig. 31 is a view showing the supply of voltage between the upper substrate and the lower substrate. g Fig. 32 is a view showing the exposure of the liquid crystal layer of Fig. 31. [Description of main component symbols] 100, 202, 280: liquid crystal display panel 101: first electrodes 102, 206: upper substrate 103: second electrodes 104, 208: lower substrate φ 105, 264: alignment films 106, 218: alignment polymerization Layer 108: liquid crystal molecule 200: liquid crystal display device 203: outer frame 204: backlight module 210: liquid crystal layer 212: upper substrate surface 24 201122676 1 vvh·,, υ "Α \ 214: lower substrate surface 216: liquid crystal molecule 220: The first portion 222 of the liquid crystal molecules: the second portion 223 of the liquid crystal molecules: transparent electrodes 224, 244, 246, 250, 252, 254: patterned transparent electrodes 226, 230, 236: trenches 228, 242, 248: One side of the patterned transparent electrode φ 232: the middle portion of the groove 234: other portions 238, 310: patterned grooves 239, 311: portions 240, 256, 312: geometrically symmetric centers 260, 262: between the grooves 266: edge region 268: first mask 270, 304: first light transmitting region 272: polymerizable monomer 274: second mask 276, 306: second light transmitting region 278: first light blocking region 282: liquid crystal The third part of the molecule 284: black matrix 286: third mask 288, 308: the third through Zone 25 201122676 i WH7 /υΓ/Λ ' 292 : third opaque zone 294 : first portion of the alignment polymer layer 296 : second portion of the alignment polymer layer 298 : third portion of the alignment polymer layer 300 : edge shading Zone 302: reticle 314: rectangle VI: first voltage V2: second voltage _V: voltage Θ1: first pretilt angle <92: second pretilt angle Θ3: third pretilt angle D1: direction L: ray L1: First light L2: second light Lu 26