201120280 四、 指定代表圖： (一) 本案指定代表圖為：第（〇)圖。 (二) 本代表圖之元件符號簡單說明： 鉦 五、 本案若有化學式時’請揭示最能顯示發明特徵的化學式： 六、 發明說明：· 【發明所屬之技術領域】 本發明係-種錢餘油紙及其製造方法，_是塗布天然聚合 物及/或合«合物找合物魏社㈣叙防油紙。 【先前技術】 防油隔離（grease barrier) &裝容器在紙與紙板及紙模領域的主要 應用有· 1)紙模.紙盤、湯碗、便當盒、速食容器；2)祿面紙板： 比薩餅、肉類、肥皂、零配件、繩子；3)指式紙盒：點心、外帶速 •食、糕餅粉、清潔劑、清新劑；4)多層袋：點心、糕餅粉、寵物食 物、木炭；5)軟式包裝：速食、糖果、巧克力、人造奶油、奶油、 烘培食物、寵物食物、肥皂；6)特殊紙：非碳複寫紙、標藏紙、裝 飾紙、藝術紙等六大方面。 防油隔離可藉由：1)多種聚烯烴類㈣制咖，例如：pE、仲 等）貼合；2)鮮氟素化合物（flor〇chemicals) ;3)熱織處理；句喷 銘貼合等四種方式來達成，其中贿兩種方式為目前市面上的主流。、 近年來，氟素化合物逐漸被廣泛觀，不僅因其成膜的可挽性、疏水 201120280 及撥油的雙效功能，·最重要的是，與聚稀烴類貼合方式比較，具有相 當低成本競爭優勢。 ~ 目前中華民國專利號，1266797、591055及5〇6979等，據以完全 揭露氟素化合物顧於防域之方法及功效，然而，氟素化合物於製 造過程中所產生财毒巾間產物將影響㈣環境；亦有文獻指出，含 軋素化合物產品經高溫加熱後釋放出的有毒物質，可經由食物進入人 體’造成身體機能產生錢，A幅提高朗風險；·，開發非氣素 防油劑實為當務之急。 【發明内容】 · 本發日⑽-㈣氣細域及鄕造方法，魏錢"纖維素溶 液及/或聚乙_雜之齡物、_衍生物驗及/歧乙烯醇溶液 之混絲’其混合之重量比為1:1〜1:1〇，將此混合溶液塗布於紙張表 面，每面塗布量約為0.5〜，依ΤΑρρι 丁559师_96方法檢測 魯其紙張防油度可達kit >6之標準。 ^據TAPPI T559 ριη·96標準制方法，混合不同比例之祕油、 I笨及正庚燒等三種藥品，會產生不同的表面張力之溶液（如表1所 不之12種不同表面張力之測試溶夜），來檢測防油紙之防油程度。試 驗的步驟為把紙樣職平面狀，測試面朝上(勿时接綱試面），在 距離紙樣高30mm錢下丨滴已知Kit龍之，朗_下碼錶， 十時I5秒’隨後利用清潔之衛生紙吸除紙樣上殘餘的試劑，立即觀 ’、、我樣肖面是碰油滴所滲透而變為透赚；如紙面被渗透，則更 、號數較小之Klt號數之試劑，測試到紙面不被油滴滲透為止，測試 201120280 結果，所使用之Kit號數之試劑，則為此紙樣之防油度。 表 1 Oil Kit Test 溶液配製表（TAPPIT559 pm-96 )201120280 IV. Designation of the representative representative: (1) The representative representative of the case is: (第). (2) A brief description of the symbol of the representative figure: 钲5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 6. Description of the invention: · Technical field of the invention The invention is a kind of money Residual oil paper and its manufacturing method, _ is coated with natural polymer and / or combined with the compound to find the compound Weishe (four) anti-oil paper. [Prior Art] Grease barrier & The main applications of containers in paper and cardboard and paper molds are: 1) paper molds, paper trays, soup bowls, lunch boxes, instant food containers; 2) Cardboard: pizza, meat, soap, spare parts, rope; 3) finger tray: snacks, take-away speed, food, cake powder, detergent, freshener; 4) multi-layer bag: snack, cake powder, pet food, charcoal 5) Flexible packaging: instant food, candy, chocolate, margarine, cream, baked goods, pet food, soap; 6) special paper: non-carbon carbon paper, standard paper, decorative paper, art paper and other six aspects. Oil-proof isolation can be achieved by: 1) a variety of polyolefins (four) coffee, such as: pE, secondary, etc.; 2) fresh fluorinated compounds (flor〇chemicals); 3) thermal weaving; There are four ways to achieve this, and the two ways of bribery are currently the mainstream in the market. In recent years, fluorinated compounds have been widely observed, not only because of their film-forming property, hydrophobic 201120280 and double-effect of oil-repellent, and most importantly, compared with poly-hydrocarbons. Low cost competitive advantage. ~ At present, the Republic of China patent number, 1266797, 591055 and 5〇6979, etc., according to the method and effect of completely preventing the disclosure of fluorocarbon compounds, however, the production of fluorocarbon compounds in the manufacturing process will affect (4) Environment; also some literatures indicate that toxic substances released by heating products containing high-temperature products can enter the human body through foods, causing body functions to generate money, and A increases the risk of Lang; and develops non-gas-based oil-repellent agents. It is a matter of urgency. [Summary of the Invention] · The first day (10)-(four) gas fine domain and manufacturing method, Wei Qian " cellulose solution and / or poly- _ mixed age, _ derivative test and / vinyl alcohol solution mixed wire 'The weight ratio of the mixture is 1:1~1:1〇, and the mixed solution is applied to the surface of the paper, and the coating amount per surface is about 0.5~, according to the method of 559ρρι丁 559 division _96, the paper oil resistance can be detected. Up to the standard of kit > 6. According to TAPPI T559 ριη·96 standard method, mixing different ratios of Mi secret oil, I stupid and Zheng Geng burning, etc., will produce different surface tension solutions (such as 12 different surface tension tests in Table 1) Solve the night) to check the oil resistance of the greaseproof paper. The test procedure is to put the paper sample in the plane shape, the test surface is facing up (do not touch the test surface), and the known Kit Dragon is smashed at a distance of 30mm from the paper sample. The lang_down code table, ten o'clock I5 seconds' Use clean toilet paper to remove the residual reagents on the paper, and immediately observe ',, my face is penetrated by the oil droplets and becomes transparent. If the paper is penetrated, the Klt number is smaller. Reagent, test until the paper surface is not infiltrated by oil droplets, test 201120280 results, the reagent number of the kit used, the oil resistance of the paper sample. Table 1 Oil Kit Test Solution Preparation Table (TAPPIT559 pm-96)
Kit No.Kit No.
Castor Oil Toluene Heptane Surface Tension (g)_(mL) (mL) (dynes/cm) 1 2 3 4 5 6 7 8 9 10 11II 實施方式 969.0 872.1 775.2 678.3 581.4 484.5 387.6 290.7 193.8 96.9 0.0 0.0 0 50 100 150 200 250 300 350 400 450 500 450 0 50 100 150 200 250 300 350 400 450 500 550 34.5 32.7 29.3 25.4 25.0 24.1 23.222.8 22.5 22.5 22.4 22.0 本發明實施方式係包含非氟素防油劑之配製、混合及塗布於紙張 等步驟，本發社非·防油舰包錢甲基_素絲、殿粉^ 物溶液及聚乙烯醇溶液等，各步驟說明如下： '丁生 1.配製步驟： ⑴敌甲基纖維素溶液：係每100重量份的水中，包含$七％童 份賴甲基纖維素；配製時，需贿ψ基纖維素緩慢加入^ 201120280 避免絮凝現象產生’並充份攪拌約1小時後備用； (2) 澱粉衍生物溶液：係每1〇0重量份的水中，包含5_15%重量 份的殿粉衍生物’以隔水加熱方式蒸煮，待加熱溫度達95χ：時， 再持續加熱約20分鐘，使其完全糊化後，冷卻至室溫備用； (3) 聚乙烯醇溶液：係每1〇〇重量份的水中，包含5_15%重量份 的聚乙嫦醇’以90-951熱水使其完全溶解後，冷卻至室溫備用； 2. 混合步驟：麟素溶肢/或聚乙鱗溶液之混合物、澱粉Castor Oil Toluene Heptane Surface Tension (g)_(mL) (mL) (dynes/cm) 1 2 3 4 5 6 7 8 9 10 11II Embodiment 969.0 872.1 775.2 678.3 581.4 484.5 387.6 290.7 193.8 96.9 0.0 0.0 0 50 100 150 200 250 300 350 400 450 500 450 0 50 100 150 200 250 300 350 400 450 500 550 34.5 32.7 29.3 25.4 25.0 24.1 23.222.8 22.5 22.5 22.4 22.0 Embodiments of the invention comprise the formulation, mixing and non-fluorinated oil repellents In the steps of coating on paper, etc., the hair non-oil tanker of the hairdressing company is covered with methyl _ silk, temple powder solution and polyvinyl alcohol solution. The steps are as follows: 'Ding Sheng 1. Preparation steps: (1) Enemy Cellulose solution: containing 7% of children's lysine methylcellulose per 100 parts by weight of water; when preparing, it is necessary to slowly add the cellulose to the base of 201120280 to avoid flocculation and to fully stir for about 1 hour. (2) Starch derivative solution: every 1 〇 0 parts by weight of water, containing 5_15% by weight of the temple powder derivative 'cooked by water heating, when the heating temperature reaches 95 χ:, then continue to heat about 20 Minutes, after making it completely gelatinized, But to room temperature for standby; (3) Polyvinyl alcohol solution: containing 5_15% by weight of polyethylene glycol per 1 part by weight of water 'completely dissolved in 90-951 hot water, then cooled to room Warm standby; 2. Mixing step: mixture of lysine dissolving limbs or polystyrene solution, starch
衍生物溶液及/或聚乙烯醇溶液之混合物，其混合之重量比為 1:1〜1:10，充份攪拌均勻； 3. 塗布步驟：將此混合溶液以含浸設備、機上上膠轆(也p㈣或機 下塗布機(刀式塗布機、棒式塗布機)等塗布於紙張表面，每面塗布 量約為G.5〜1.5g/m2，經乾驗即可製得如6之素防油紙。 七、申請專利範圍： 1· 一種非氟素防油紙及其製造方法，包括： 塗布天錢合物及/或合絲合物之混合物於賴上所製 防油嫉。 2. 如申μ專利範_第i項所述之—種非氟素防油紙及其製造方 法，其中係包含鮮基纖維素歸及/絲乙鱗溶液之混人 物、澱粉衍生物溶液及/或翏乙烯醇溶液之混合物。 〇 3. 如申請專娜_第1項所述之—種魏素防油紙及其製造方 法，其混合物之混合重量比為1.1〜1:1〇。 4. 如申請專利制的第β所述之—種魏素防油紙及1製造 法j塗布方式包含以含浸設備、機上上膠轆(如卿s)或機 下塗布機(刀式塗布機、棒式塗布機)等實施。a mixture of a derivative solution and/or a polyvinyl alcohol solution, which is mixed in a weight ratio of 1:1 to 1:10, and uniformly stirred uniformly; 3. Coating step: the mixed solution is impregnated with equipment, and the capsule is coated on the machine. (Also p (four) or under-machine coater (knife coater, bar coater), etc. are applied to the surface of the paper, and the coating amount per side is about G.5~1.5g/m2, and after drying, it can be obtained as 6 Plain oil-proof paper. VII. Patent application scope: 1. A non-fluorine oil-proof paper and a manufacturing method thereof, comprising: a mixture of a coating of a daily clathrate and/or a compound of a silk compound, and an anti-oil sputum. A non-fluorinated greaseproof paper and a method for producing the same according to the invention, wherein the method comprises a fresh-base cellulose-retributed/silk-stained solution, a starch derivative solution and/or a crucible. Mixture of vinyl alcohol solution. 〇3. If applying for the application of 娜娜_, the type of Weisu greaseproof paper and the method for producing the same, the mixture weight ratio of the mixture is 1.1 to 1:1. The method described in the above-mentioned β-type Weisu greaseproof paper and 1 manufacturing method includes the impregnation device and the upper glue on the machine (such as Qings) Under coater (blade coater, bar coater) or the like machine embodiment.