201113386 六、發明說明： 【發明所屬之技術領域】 本發明係有_-種貴金屬組件含錯真空法，此尤指一種具 有環保與提升成品附加價值之含鍺真空電鑛方法，藉此提供貴金屬具 有鍺及鈦元素讀職果，且該_鈦元权物理娜，促進使 用者身體健康’以及提升貴金屬之商業價值與適用範圍者。 【先前技術】 由於鍺元素具有游離及隔離、中和電磁波之物理特性，特別是 在3 2 C時會產生負電子麟離，醫學上已知糊此雛以平衡人體 體内之正負電子，藉此促進人體血液之鄕，更是廣為人知之事實， 因此近年來已有眼鏡框、項鍊、手鐲等貴金屬組件之業者，利用含錯 元素之錯粒13鑲嵌在貴金屬組件其成品i上（如第_、二圖所示）， 一方面可齡佩戴者的身分與„，另—方面更因具有養生效果，而 為各界所吾好：上述f式責金屬組件之成品i鑲嵌鍺粒丨3之結構， 主要係在該成品1的組件i i上設有一嵌入孔丄2，利用該嵌入孔工 2嵌入（絲著）該鍺粒！ 3，其製造方法2 (如第三圖所示）之步 驟為： (一）組件加工（步驟2 i )，利用模具將金屬線材裁切，並加以成 型成一成品1 (如項鍊、手鐲、眼鏡框等）之組件i工； (一）組裝（步驟2 2 )’將各組件1 1組合成一雛型加工件； (三）錯喊設處理（步驟2 3)，將鍺粒丨3欽於雜型加工件 其組件11之嵌入孔i 2，而完成一成品i。 201113386 上述ι式製&方法，雖可使成品i具有鍺元素之效果，侧錯元素 的價格十分昂貴’且鑲嵌作業耗費人工，不易大量生產；同時又因鍺 粒分布不均勾，往往會影響到使用效果，而廣為使用麵垢病；有鐘 於此本案發明人乃提出「飾品的製造方法」（即我國申請專利案號 第95149751號、中國專利中請案號第2 〇 〇71〇〇〇56 8 4 . 4號之專利案，以下簡稱前案），藉由上述方法所製成之成品， 不但成本似可大量快速生產’此前案料姐解決鍺粒鎮 喪作業上耗費人ji ’不易大量生產等缺失；但此製造方法係一種利用 液態（水）電鐘之方法，必需耗費大量用水，其電鑛過程會產生如c r、N i、Z r、S η及其合金之重金屬廢水與空氣污染問題，特別 疋’、價鉻、氰化物係為劇毒，即使經由昂貴廢水處理，仍會存有殘餘 物，長期累積也是-大毒害；再者，液態⑷電鍍之產品其附著度 的控制不易’常造成其成品鍺膜分布不均勻，以致浪費昂貴的錯原料。 如上所述，液態（水）電鐘存有環境污染缺失，要解決此問題以 現有技術只能仰賴金屬真空魏法，此綠俗觀漿減法，又稱I Ρ電鍍法’其工作原理係在一真空鍍膜機内，利用放電產生電漿作用， 以使金屬轉其金屬元素游離_在加功表面，而形成—金屬間化 合物膜；然此技街在其他單一金屬鍍膜處理上（如鈦膜），雖已被廣泛 使用，但有關鍺材料利用IΡ電鍍法，使用在貴金屬成品上，仍為無 法克服之問題，其原因除了將鍺製成錯乾材的技術無法突破外，現有 的I Ρ電鍍法仍存有鍍膜不均勻，以及不能在一次工作流程中做出多 層複合鍍膜之技術。此外，由於貴金屬組件之成品，已被要求製成各 201113386 種高雅色系的發展趨勢下，傳統的^ 色系，而廣為人所垢病。 【發明内容】 p電鍍法卻僅能提供有限的基本201113386 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a method for containing a wrong vacuum of a noble metal component, and more particularly to a method for containing an environmentally friendly and enhanced value of a finished product containing a vacuum, thereby providing a precious metal It has the ability to read the fruits of bismuth and titanium, and the _ titanium element is physical, to promote the health of users, and to enhance the commercial value and scope of precious metals. [Prior Art] Since the lanthanum element has the physical properties of freeing and isolating and neutralizing electromagnetic waves, especially at 3 2 C, it will produce a negative electron lining. It is known in medicine to balance the positive and negative electrons in the human body. This is a well-known fact that promotes the blood of the human body. Therefore, in recent years, the manufacturer of precious metal components such as eyeglass frames, necklaces, bracelets, etc., has been embedded in the finished metal component of the precious metal component by using the wrong element 13 containing the wrong element (such as the first On the one hand, the identity of the age-old wearer is „, and the other is because of the health effect, but it is good for all walks of life: the structure of the above-mentioned f-type metal component finished i-set 锗 丨3 Mainly, the component ii of the finished product 1 is provided with an insertion hole 2, and the embedded hole 2 is used to embed (wire) the particle! 3, the manufacturing method 2 (as shown in the third figure) is : (1) Component processing (step 2 i ), cutting the metal wire with a mold and forming it into a component of a finished product 1 (such as a necklace, a bracelet, a spectacle frame, etc.); (1) Assembling (step 2 2 ) 'Combining each component 1 1 into a prototype processing piece; (3) erroneous shouting processing (step 2 3), the 锗 丨 3 钦 钦 钦 钦 钦 钦 杂 杂 杂 杂 杂 杂 杂 杂 杂 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 The & method, although the finished product i has the effect of bismuth element, the price of the side-error element is very expensive' and the inlaying operation is labor-intensive, and it is not easy to mass-produce; at the same time, due to the uneven distribution of the granules, the effect is often affected. However, the inventor of this case has proposed the "manufacturing method of jewelry" (ie, China Patent Application No. 95,945,751, Chinese Patent Application No. 2, No. 71〇〇〇56 8 4. The patent case No. 4, hereinafter referred to as the previous case), the finished product made by the above method, not only cost can be produced in a large amount of rapid production, 'previously, the material is solved by the sister of the granules, and it is difficult to mass produce. Etc.; but this manufacturing method is a method using a liquid (water) electric clock, which requires a lot of water, and its electro-mineral process produces heavy metal wastewater and air pollution such as cr, N i, Z r, S η and its alloys. Problem, especially The price of chromium and cyanide are highly toxic. Even if it is treated by expensive wastewater, there will still be residues, and long-term accumulation is also - great poison; in addition, liquid (4) electroplated products are not easy to control the adhesion of their products. The film is not evenly distributed, so that expensive raw materials are wasted. As mentioned above, the liquid (water) electric clock has a lack of environmental pollution. To solve this problem, the prior art can only rely on the metal vacuum Weifa. This green customary pulping subtraction method, also known as the I Ρ electroplating method, In a vacuum coating machine, the plasma is generated by the discharge, so that the metal is transferred to the metal element to be freed on the surface of the work to form an intermetallic compound film; however, the technology is processed on other single metal coatings (such as titanium film). Although it has been widely used, the use of IΡ plating method for the use of tantalum materials is still an insurmountable problem in the finished precious metal products. The reason is that in addition to the technology that can be made into a wrong dry material, the existing IΡ plating The method still has uneven coating and the ability to make multi-layer composite coating in one workflow. In addition, due to the finished product of precious metal components, it has been required to make the traditional color system of the 201113386 elegant color system, which is widely used. SUMMARY OF THE INVENTION p plating method can only provide limited basic
有a ; b本發月之目的’乃在提供—種具有環保與提升成品 附加價值之觸轉含鍺真空電鍍法嚇法之步驟至少包括:㈠ 組件加工、（二）表層處理、（三）錢鍺膜處理、㈤雜膜處理、（五) 氣化處理、（六）_成品，勤上財法之步驟，雛大幅減低生產 時之環境污染’魏提供貴金屬具有财鈦元素之處微果，且利用 該錯與鈦讀之物理祕，促較用者身體難之提升，以及貴金屬 表面色澤變化，有效提升其附加價值與適用範圍者。 述本發月之方法，其中該鍍錯膜處理及鑛欽膜處理之步驟，更 透過-真空鐘膜機内之掛具的自轉配合—轉盤的公轉，在該真空鍛膜 機其真空艙四周環_複數讀設置下，能全面包圍X作物，而使鑛 、句勻且在不同材料的靶材（如鍺乾材、鈦乾材）配置下，以達到 人工作流程中做出多層次之複合鑛膜，實現成品之底層鑛鍺，表面 鑛鈦之目的。 上述本發明之方法，其中該氣化處理之步驟，更透過不同的氣體 進入該真空艘膜機内，使該鈦膜表面形成各種不同的表面色系之欽 膜’藉以符合市場的需求色系’例如加人氮氣可產生玫瑰金，加入二 氧化碳產生寶藍色，加人乙炔產生灰色等。 【實施方式】 本發明一種貴金屬組件含鍺真空電鍍法4(請參閱第四至七圖所 201113386 不）’其係糊-真空鍍賴3進行本發明之方法4各步驟之進行，其 中該真麵膜機3其殼體3 0内部設有—真鎌3 q q，其底部設有 -抽氣馬達31 ’而該殼體3 〇外接至少一供氣管3 2，該真空搶3 〇 0的周Μ設有複數㈣座3 7，縣-树座3 7係由-永久磁 鐵結合電磁鐵所組成之磁鐵3 7 3連結，材3 7 i所構成（該姆 3 7 1可健麟不同’ 各種不同金屬材制製狀姆，例如 鍺乾材、鈦材），各補材料之姆3 7 i可在該真空艙3 〇 〇的周 圍等分均勻分布’藉此以多綺3 7 i全面包圍各加工件5 〇 ;同時 為考慮每-红件5⑽表面_能夠均勻附著，該真空艙3 〇 〇的 底部設有’盤3 4 ’該轉盤3 4上置設有複數掛具3 5，該掛具3 5係提供該加功5 〇之掛設，且簡具3 5本身透過動力控制會定 時作正向自轉或反向自轉，並配合該轉盤3 4本身的公轉，如此將使 每-加工件5 0掛設在掛具3 5上時，會具有多方向容易達到全面性 錢膜處理效果’以獲取-均勻之賴層，藉由上述之真空顧機3， 本發明之方法4步驟（如第七圖所示）至少包括有： 组件加丄（.步驟4 i )，利用模具將金屬材料裁切，並加工成 型成為-離型之加工件5 〇 (如項鍊、手鐲、眼鏡枢等零植 件）； 、’ (二）表層處理（步驟4 2 )，將加工件5 〇進行酸洗、脫脂作業， 以去除該加辑5 〇上不必要之㈣，雜該加卫件5 〇放入 該真空電鍍膜機3中； 、三）鍵錯膜處理（步驟4 3)，加工件50置設在掛具^上， 6 201113386 動電源單疋3 3對具有鍺純之把材座3 7其磁鐵3 7 3通 電使其產生磁場與電子交互作用，在真空搶3〇〇内會產生 -電装作用區A (如第六騎示），在該賴作龍A作用下 乾材3 71 (指錯乾材）的乾面3 7 2從而濺射出鍺元素，並 附著於加工件5 〇之表s，而形成—鍺膜5 〇丨（如第八圖所 ’、）同時因該掛具3 5定時作正、反向自轉及配合轉盤3 4 的公轉’因此鍺膜5 01能更均勻披覆在加工件5 0表面； (四） It賴處理（步驟4 4 )，在完成繼贼趙，购電源單 元3 3對具有鈦妹之乾材座3 7其磁鐵3 7 3通電使其產 生磁場與電子交互作用，在真空搶3 0 0内會產生- 電漿作用 區A (如第六圖所示），在該電毁作用區a作用下乾材㈠旨鈦 把材）的le*面3 7 2從而濺射出鈦元素 ，並附著於該加工件5 0其鍺膜5 01之表面，而形成—鈦膜5 〇 2 (如第八圖所 示）； (五） 氣化處理（步驟4 5 )，在鍍鍺膜處理（步驟4 3 )的步驟中， 由至少一供氣管3 2釋出氣體（如氬氣）引發該磁鐵3 7 3在 通電後產生電浆作用，而在鍍鈦膜處理（步驟44)該供氣管 3 2除引發該磁鐵3 7 3產生電漿作用，更會依加工件5 0表 面需求顏色之不同，釋出不同種類之氣體，以使該氣體與鈦膜 5 0 2產生反應’生成各種不同顏色之鈦膜5 〇 2(例如供氣 管3 2釋出氮氣會產生玫瑰金之鈦膜，當然所添加氣體之比例 不同，也會產生不同色系之鈦膜）； 7 201113386 (六）組裝成品（步驟4 6)，將各鑛膜處理完成之加工件5 〇組裝成 一成品5 (如第九圖所示）。 綜上所述，本發明之製造方法，可使貴金屬組件（如項鍊、手竭、 眼鏡框）麵、鈦元素，又轉決雜雜之_，藉由其含錯元素 之物理特性，以翻人麵岐、貞電子之平衡，又可產生各種高雅 色系之表面，有效提升成品附加商業價值者。 在本發明内容中所提出之具體實施例僅用以方便說明本發明之 技術内容’ _將本發明狹義祕制於上述實補，林超出本發明 之精神與下述之申請專利範圍的情況下，所作的種種變化實施， 於本發明之範圍。 【圖式簡單說明】 第圖，係習式貴金屬組件之立體示意圖。 第-圖’係習式貴金屬組件之剖面示意圖。 第三圖，係習式貴金屬組件其製造方法之流程圖。 第四圖’係本發明其真空鍍膜機作動示意圖。 第五圖，縣發明其真线膜機平面示意圖。 第六圖’縣發·錄侧區作動示意圖。 第七圖’係本發明其方法之步驟流程圖。 第八圖’係本發明其加卫件剖面示意圖。 第九圖係'本發明其成品實施例之立體示意圖。 【主要元件符號說明】 201113386 〈習式〉 1.....成品 12.....嵌入孔 2......製造方法 步驟 1 1 ....組件 13 ....錄粒 2 1、2 2、2 3There are a; b the purpose of this month is to provide - a kind of environmental protection and enhance the added value of the finished product. The steps of the vacuum plating method include at least: (1) component processing, (2) surface treatment, (3) Qian 锗 film treatment, (5) miscellaneous membrane treatment, (5) gasification treatment, (6) _ finished product, step of diligent financial method, the chick significantly reduced the environmental pollution during production 'Wei provides precious metals with Titanium elements And the use of the fault and the physical secret of titanium reading, to promote the user's physical difficulty, as well as the change in the color of the precious metal surface, effectively enhance its added value and scope of application. The method of the present month, wherein the step of plating the wrong film treatment and the processing of the mineral film is further carried out by the rotation of the hanging device in the vacuum bell machine - the revolution of the turntable, in the vacuum chamber of the vacuum forging machine _Multiple reading settings, can fully encompass the X crop, and make the mine, sentence uniform and in the configuration of different materials (such as dry materials, titanium dry materials) to achieve a multi-level composite in the human workflow The mineral film realizes the purpose of the bottom layer of the finished product and the surface of the ore. In the above method of the present invention, the step of gasification treatment further enters the vacuum film machine through different gases, so that the surface of the titanium film forms a variety of different color shades of the film "to meet the market demand color system" For example, adding nitrogen can produce rose gold, adding carbon dioxide to produce royal blue, adding acetylene to produce gray. [Embodiment] A precious metal component of the present invention comprises a vacuum plating method 4 (refer to FIGS. 4 to 7 and 201113386). The paste-vacuum plating 3 performs the steps of the method 4 of the present invention, wherein the true The mask machine 3 has a casing 3 30 inside, a true 镰 3 qq, a suction motor 31 ′ at the bottom thereof, and an external air supply pipe 3 2 external to the casing 3 ,, the vacuum grabs a week of 3 〇 0 ΜThere are a plurality of (four) seats 3 7, the county-tree seat 3 7 series consists of a magnet consisting of a permanent magnet combined with an electromagnet 3 7 3, and the material is 3 7 i (the y 3 7 1 can be different) Different metal materials, such as dry materials, titanium materials, the material of each of the materials can be equally distributed around the vacuum chamber 3 ' 'by being surrounded by multiple 绮 3 7 i Each workpiece is 5 〇; at the same time, in order to consider that the surface of each of the red parts 5 (10) can be uniformly attached, the bottom of the vacuum chamber 3 设有 is provided with a 'disc 3 4 ' on which the plurality of rigging 3 5 is placed. The rigging 3 5 series provides the erection of the gong 5 ,, and the simplification 3 5 itself periodically rotates forward or reversely through the power control, and cooperates with The revolution of the turntable 34 itself, so that when each workpiece 50 is hung on the hanger 35, it will have a multi-directional easy to achieve a comprehensive money film treatment effect to obtain a uniform layer. The above-mentioned vacuum machine 3, the method of the method 4 of the present invention (as shown in the seventh figure) includes at least: assembly twisting (. step 4 i ), cutting the metal material by using a mold, and processing into a --release type Processing parts 5 〇 (such as necklaces, bracelets, glasses hinges and other parts); , ' (2) surface treatment (step 4 2), the workpiece 5 〇 pickling, degreasing operation to remove the add-on 5 It is unnecessary (4), the auxiliary fastener 5 is placed in the vacuum plating machine 3; 3) the key is processed by the wrong film (step 4 3), and the workpiece 50 is placed on the hanger ^ 6 201113386 The power supply unit 3 3 pairs of the pure metal holder 3 7 and its magnet 3 7 3 energize it to generate a magnetic field and electronic interaction, which will be generated within the vacuum grab 3 - the electric installation area A (such as the sixth ride) Show), under the action of the Lai Zuolong A, dry material 3 71 (refer to the wrong dry material) dry surface 3 7 2 to sputter the enamel element, and attached On the surface of the workpiece 5 而, and the formation of the 锗 film 5 〇丨 (as shown in the eighth figure), at the same time because the hanger 3 5 timing for positive and negative rotation and the rotation of the turntable 3 4 ' The enamel film 5 01 can be more evenly coated on the surface of the workpiece 50; (4) It Lai treatment (step 4 4), after completing the thief Zhao, purchase the power unit 3 3 pairs of dry material holders with titanium sisters 3 7 The magnet 3 7 3 is energized to generate a magnetic field and electron interaction, and a vacuum action zone A (as shown in the sixth figure) is generated in the vacuum grab 300, and the dry material is acted upon in the electric destructive action zone a (1) Ti* surface 3 7 2 of the titanium material is sputtered out of the titanium element, and adhered to the surface of the workpiece 50 of the workpiece 50 to form a titanium film 5 〇 2 (as shown in the eighth figure) (5) gasification treatment (step 4 5), in the step of the ruthenium plating treatment (step 43), the gas (such as argon) is released from at least one gas supply pipe 3 2 to initiate the magnet 373 After the plasma action is generated, in the titanium plating process (step 44), the gas supply pipe 3 2 causes the magnet 3 3 3 to generate a plasma effect, and the color of the surface of the workpiece 50 is different. , releasing different kinds of gases, so that the gas reacts with the titanium film 502 to generate titanium films of different colors 5 〇 2 (for example, the gas pipe 3 2 releases nitrogen to produce a titanium film of rose gold, of course The ratio of the added gas is different, and the titanium film of different color systems will also be produced. 7 201113386 (6) Assembling the finished product (step 4 6), assembling the processed parts of each film processing into 5 pieces (as shown in the ninth figure) Shown). In summary, the manufacturing method of the present invention can make precious metal components (such as necklaces, exhausted hands, glasses frames), titanium elements, and turn into impurities, by virtue of the physical characteristics of the wrong elements. The balance between the human face and the electronic, and the appearance of a variety of elegant color, effectively enhance the added value of the finished product. The specific embodiments set forth in the Summary of the Invention are merely used to facilitate the description of the technical contents of the present invention. _ The invention is narrowly defined in the above-mentioned embodiments, and the present invention is beyond the spirit of the present invention and the following claims. The various changes made are within the scope of the invention. [Simple description of the diagram] The figure is a three-dimensional diagram of a conventional precious metal component. Fig. 1 is a schematic cross-sectional view of a conventional precious metal component. The third figure is a flow chart of a method for manufacturing a conventional precious metal component. The fourth figure is a schematic diagram of the operation of the vacuum coater of the present invention. In the fifth figure, the county invented a schematic diagram of its true line film machine. The sixth picture shows the operation of the county and the recording area. The seventh diagram is a flow chart of the steps of the method of the present invention. The eighth figure is a schematic cross-sectional view of the fastener of the present invention. The ninth drawing is a perspective view of a finished product embodiment of the present invention. [Description of main component symbols] 201113386 <Formula> 1... Finished product 12... Embedding hole 2... Manufacturing method Step 1 1 .... Component 13 .... Recording 2 1, 2 2, 2 3
〈本發明〉 3.....真空鍍膜機 3 0 ....殼體 3 2 · · · ·供氣管 3 4 ....轉盤 3 7 · · · ·乾材座 4 .....方法 4 1、42、43、44 5 .....成品 5 0 . · . ·加工件 A · · .·.電漿作用區 3 0 0 •..真空艙 3 1· •••抽氣馬達 3 3· ..·電源單元 3 5 · • ••掛具 3 7 1 • · ·靶材 372 • ••乾面 3 7 3 • ••磁鐵 '45' 4 6步驟 5 0 1 • · ·鍺膜 5 0 2 • ••鈦膜<The present invention> 3.....Vacuum coating machine 3 0 .... Housing 3 2 · · · · Air supply pipe 3 4 .... Turntable 3 7 · · · · Dry material base 4 .... Method 4 1, 42, 43, 44 5 ..... Finished product 5 0 · · · Processed part A · · ... Plasma action zone 3 0 0 •.. Vacuum chamber 3 1 · ••• pumping Air motor 3 3· ..·Power unit 3 5 · • •• Hanger 3 7 1 • · · Target 372 • •• Dry surface 3 7 3 • •• Magnet '45' 4 6Step 5 0 1 • ·锗膜5 0 2 •••Titanium film