TW201111587A - Manufacturing method of inner film layer of biodegradable freshness preservation and sterilization paper packing material - Google Patents

Manufacturing method of inner film layer of biodegradable freshness preservation and sterilization paper packing material Download PDF

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Publication number
TW201111587A
TW201111587A TW98132649A TW98132649A TW201111587A TW 201111587 A TW201111587 A TW 201111587A TW 98132649 A TW98132649 A TW 98132649A TW 98132649 A TW98132649 A TW 98132649A TW 201111587 A TW201111587 A TW 201111587A
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TW
Taiwan
Prior art keywords
paper
polylactic acid
silver
biodegradable
nano silver
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Application number
TW98132649A
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Chinese (zh)
Inventor
fu-zhi Xiao
Original Assignee
Home Round Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Home Round Paper Co Ltd filed Critical Home Round Paper Co Ltd
Priority to TW98132649A priority Critical patent/TW201111587A/en
Publication of TW201111587A publication Critical patent/TW201111587A/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/80Packaging reuse or recycling, e.g. of multilayer packaging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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  • Laminated Bodies (AREA)
  • Wrappers (AREA)

Abstract

Disclosed is a manufacturing method of inner film layer of biodegradable freshness preservation and sterilization paper packing material, which is formed by adding nano-silver into the raw material of biodegradable polylactic acid, its weight ratio is 80-95% polylactic acid, 5-20% nano-silver. After mixing and stiring, an extruder extrudes the conjugated yarn of polylactic acid nano-silver, then the conjugated yarn of polylactic acid nano-silver is cut into polylactic acid nano-silver granules one by one. A polylactic acid nano-silver film is extruded through the laminating machine by melting the polylactic acid nano-silver granules. At the same time, the polylactic acid nano-silver film is coated on a surface treatment machine (CORONA) and shock the paper surface with 5K-50KW electric power to generate the capillary pores. Afterwards, use a rubber wheel and a 15-28 DEG C cooling wheel to roll the polylactic acid nano-silver film and the paper (including paper board and non-woven fabric, etc. ) so as to adhere and associate them integrally and coated on the polylactic acid nano-silver film layer of the paper, thereby forming the freshness preservation and sterilization paper packing material. The paper material is further cut into packaging material such as paper cup, paper bowl, paper lunch box, freshness preservation paper, etc. Nano-silver has the effect of sterilization and freshness preservation. Also, after being used for a certain period of time, the polylactic acid is biodegradable to decompose naturally and peels off from the paper, and then associates with soil, thereby achieving the benefit of environmental protection and recycling the paper itself for reutilization.

Description

201111587 六、發明說明: 【發明所屬之技術領域】 本發明為一種可生物分解保鮮殺菌紙包材内膜層之製法,係 在紙包材如紙杯、碗、紙便當盒、保鮮紙等内緣表層披附一聚乳 酸奈米銀薄膜,應用奈米銀對盛裝物具有殺菌保鮮效果,且可在 使用一段時間,藉該聚乳酸可生物分解特性而自然分解自紙匹上 剝離,並能與土壤結合,達到環保要求及紙張本身可回收再利用 之效益的技術領域。 【先前技術】201111587 VI. Description of the Invention: [Technical Field] The invention is a method for preparing an inner membrane layer of a biodegradable fresh-keeping sterilized paper packaging material, which is in the inner edge of paper packaging materials such as paper cups, bowls, paper lunch boxes, and wrap paper The surface layer is coated with a polylactic acid nano silver film, and the nano silver is used for sterilizing and preserving effect on the contents, and can be used for a period of time, and the polylactic acid can be biodegraded and naturally decomposed from the paper, and can be separated from The technical field of combining soils to meet the environmental requirements and the benefits of recycling the paper itself. [Prior Art]

按一般紙製產品(如:紙杯、紙碗、紙盤、紙盒及紙製便當盒、 飲料、’氏i、不織布、紙容盗..等),為使承裝食物時不致發生參 漏情形,通常會在紙製產品之紙片内面,披附一層PE或pp ^ 淋膜層,然該牀膜層因無法自然分解,而產生環境二次公宝。 前述的問題,目前已能獲得突破性的發展,其原料已二可 PLA(聚乳酸)_於_表層,而產生自齡解之效果;然該 僅能提供自然分解效果,但仍無法達成可為保鮮殺菌之功能。 而要達成保鮮殺菌效果,又能達成自然分解之環保效果, =淋膜技術披附祕上製成紙製容器魄啸有耐米銀混合ς ^膜内,#能達成殺菌保鮮作用,然此為非一般淋膜技術即能達 【發明内容】 八站一f可生齡解簡殺眺包材_層之製法,係以生物可 二=之聚礼酸原料添加奈米銀,其重量比為聚乳酸8〇〜 太 ,量比為5〜20% ’ _拌混合後,透過融雜絲裝置‘= j酸奈米銀複合絲,再將聚乳酸奈米銀複合絲逐 成‘ 酸,銀顆粒’並透過淋膜機將該聚乳酸奈米銀顆粒熔== 二礼酸奈練賴’該聚該奈米銀薄朗時 ,處理機(CORONA)以5K〜50KW功率電擊紙匹表 士=一橡_5〜28。⑽冷卻輪麵 = 與紙匹而相互_結合為-體,使其披附於紙匹 3 201111587 銀薄膜層’以形成保鮮殺菌紙包材,再經裁切製成 碗、紙便當盒、保鮮紙等,其内緣表層即應 #氏杯、 及紙張本身可回收再利用之效益者。 、保要求 【實施方式】 第-、二騎示’係以生物可分解之聚魏 加不米銀2,其重量比為聚乳酸8〇〜95%,奈米銀 氐、/添 %,經攪拌混合成聚乳酸奈米銀複合材料3後,’透:〜2〇 ί ί聚ί酸奈米銀複合絲5,再將聚乳酸奈米銀複 ===解而押出一聚乳酸奈米銀薄膜:該 ί率電擊表面處理機8(C〇R〇NA)以5K〜5“ 表產生毛細孔上’隨後經-橡膠輪91與15〜28 產生=卩^2輾壓該聚乳酸奈米銀細6與紙匹7,應用該電擊 由:捲收’以製成保_紙= ㈣所示,該披附有聚乳酸奈米銀薄膜61之 ㈣舍ί成紙容11如紙杯Α(第_·々、紙碗稱四圖七)、 f膜ΙΓ*座(第Γ、圖等紙包材之内、缘表層即具有聚乳酸奈米銀 1B ci_銀對盛裝物具有賴保鮮效果;請參閱第三圖 而白钟八站所不’可在使用一段時間’藉該聚乳酸可生物分解特性 能與土壤結合,達到‘ 前法所製成之鱗殺賊包材,其中該紙匹7可為 , ”披附之表層亦為聚乳酸奈米銀薄膜61,即可直接提供 〇材之應用,作為保鮮膜或保鮮包覆食物、水果用途者。’、 201111587 【圖式簡單說明】 第一圖為本發明之製造流程方塊圖。 第二圖為本發明之設備流程圖。 第三圖-A〜C為本發明之淋膜層於紙匹上自然分解示意圖。 第四圖-A〜C為本發明可製成成品實施例圖。 【主要元件符號說明】 聚乳酸1 奈米銀2 聚乳酸奈米銀複合材料3 _ 融熔紡絲裝置4 聚乳酸奈米銀複合絲5 聚乳酸奈米銀顆粒51 淋膜機6 聚乳酸奈求銀薄膜61 紙匹7According to general paper products (such as paper cups, paper bowls, paper trays, paper boxes and paper lunch boxes, beverages, 'I', non-woven fabrics, paper pirates, etc.), so as not to cause leakage when loading food In the case, usually a layer of PE or pp ^ is coated on the inner surface of the paper of the paper product, and the film layer of the bed is naturally unresolved, resulting in an environmental secondary treasure. The above-mentioned problems have now achieved a breakthrough development. The raw materials have been able to produce PLA (polylactic acid) _ on the surface layer, which produces the effect of self-digestion; however, it can only provide natural decomposition effects, but it still cannot be achieved. For the preservation of the function of sterilization. In order to achieve the effect of fresh-keeping and sterilizing, and to achieve the natural decomposition effect of natural decomposition, the coating technology is made into a paper container, and the screaming has a resistance to rice and silver mixed ς ^ film, # can achieve sterilization and preservation, but this For non-general laminating technology, it can reach [invention content] Eight stations and one f can be used to solve the problem of 眺 眺 眺 _ _ _ _ , , , , , , , , 层 层 层 层 层 层 层 层 层 层 层 层 层For polylactic acid 8〇~ too, the ratio is 5~20% ' _ mix and mix, through the melt wire device '= j acid nano silver composite wire, and then the polylactic acid nano silver composite wire into 'acid, The silver particles 'and the polylactic acid nano silver particles are melted through the laminating machine==Bai Lishui Nai Lai', when the silver is thin, the processor (CORONA) is electrically shocked at 5K~50KW士=一橡_5~28. (10) Cooling the tread = with the paper and _ together with the body, so that it is attached to the paper 3 201111587 silver film layer 'to form a fresh-keeping sterilized paper package, and then cut into a bowl, a paper lunch box, fresh Paper, etc., the inner edge of the surface is the #氏氏, and the paper itself can be recycled and reused. , insurance requirements [embodiment] The first - and second riding shows 'biodegradable poly-weijia not silver 2, the weight ratio of polylactic acid 8 ~ 95%, nano silver, /%%, by After stirring and mixing into polylactic acid nano silver composite material 3, 'transparent: ~2〇ί ί polylactic acid nano silver composite wire 5, and then polylactic acid nano silver complex === solution and a polylactic acid nano Silver film: The 电 rate electric shock surface treatment machine 8 (C〇R〇NA) is 5K~5" on the surface of the capillary hole' and then the rubber wheel 91 and 15~28 are produced = 卩^2 The rice silver thin 6 and the paper 7, the electric shock is applied by: winding the 'made to protect paper _ paper = (4), which is coated with the polylactic acid nano silver film 61 (four) ί 成 into a paper capacity 11 such as a paper cup Α (Article _·々, paper bowl called four figure seven), f film ΙΓ* seat (the inside of the paper, such as Γ, 图, etc., the surface layer of the layer has polylactic acid nano silver 1B ci_ silver has a fresh on the contents The effect; please refer to the third picture and the white clock eight station does not 'can be used for a period of time' by the polylactic acid biodegradable characteristics combined with the soil, to achieve the 'pre-method made scales thieves package materials, which Paper 7 can be , "The surface layer of the drapes is also a polylactic acid nano silver film 61, which can directly provide the application of coffin, as a plastic wrap or fresh-keeping food and fruit use.", 201111587 [Simple description of the picture] The block diagram of the manufacturing process of the present invention. The second figure is a flow chart of the device of the present invention. The third figure -A~C is a schematic diagram of the natural decomposition of the coating layer on the paper of the present invention. The fourth figure -A~C is The invention can be made into a diagram of the finished product. [Description of main component symbols] Polylactic acid 1 Nano silver 2 Polylactic acid nano silver composite material 3 _ Melt spinning device 4 Polylactic acid nano silver composite wire 5 Polylactic acid nano Silver Particles 51 Laminating Machine 6 Polylactic Acid Naim Silver Film 61 Paper 7

表面處理機8 橡膠輪91 冷卻輪92 羅拉R 紙杯A 紙碗B 紙便當盒CSurface treatment machine 8 Rubber wheel 91 Cooling wheel 92 Roller R Paper cup A Paper bowl B Paper lunch box C

Claims (1)

2〇1111587 七、申請專利範圍: 1. 一種可生物分解保鮮殺菌紙包材内膜層之製法,其步驟係 包含: a. 將一生物可分解之聚乳酸原料添加奈米銀; b. 經撥拌混合後’透過融炼紡絲裝置抽絲形成聚乳酸奈米銀 複合絲; c•再將聚乳酸奈米銀複合絲逐一截斷成聚乳酸奈米銀顆粒; d. 再透過淋膜機將該聚乳酸奈米銀顆粒熔解而押出一聚乳酸 奈米銀薄膜;2〇1111587 VII. Patent application scope: 1. A method for preparing an inner membrane layer of biodegradable fresh-keeping sterilized paper packaging material, the steps comprising: a. adding a biodegradable polylactic acid raw material to nano silver; b. After mixing and mixing, 'filing the polylactic acid nano silver composite wire through the spinning spinning device; c• then cutting the polylactic acid nano silver composite wire one by one into polylactic acid nano silver particles; d. Melting the polylactic acid nano silver particles to extrude a polylactic acid nano silver film; e. 該聚乳酸奈米銀薄膜於披附於紙匹表面上之前,該紙匹表 面透過表面處理機(CORONA)電擊,以擴大紙匹毛細孔; f. 再將聚乳酸奈米銀薄膜淋膜於前述已被擴大毛細孔的紙匹 表面; g.隨後經一橡膠輪與冷卻輪輾壓該聚乳酸奈米銀薄臈與紙匹 而相互黏附結合為一體,以製成保鮮殺菌紙包材;、/、 ’該轉㈣紙包材即能提供製成紙包材如紙杯、碗、 菌伴保鮮轉,其内緣表層即應用奈綠對錄物具有殺 而自ϊϊϋ可在使用—段時間’藉該聚乳酸可生物分解特性 張本身^收能與均結合,達到環保要求及紙 膜層範圍第1項所述可生物分解保鮮殺菌紙包材内 ^佳者\、中聚乳酸重量比8G〜95%,奈米銀重量比為5〜20 膜層圍f1項所述可生齡解保鮮《紙包材内 紙匹表__(a>RQNA)_ 5K〜5QKw功率電擊 膜層ΐϋΐίίϊ圍第1項所述可生物分解保鮮殺菌紙包材内 佳者H其巾橡膠輪與冷卻魏壓之冷卻溫度為15〜28。^較 •如申4專利範圍第1項所述可生物分解保鮮殺_紙包材内 201111587 膜層之製法,其中該紙匹係可為不織布淋膜聚乳酸奈米銀薄膜, 供保鮮紙用途。e. Before the polylactic acid nano silver film is attached to the surface of the paper, the surface of the paper is shocked by a surface treatment machine (CORONA) to enlarge the pores of the paper; f. Membrane on the surface of the paper which has been enlarged by the capillary; g. Subsequently, the polylactic acid nano silver thin crucible and the paper are adhered and bonded together by a rubber wheel and a cooling wheel to form a fresh-keeping sterilization paper package Material;, /, 'The turn (four) paper packaging material can provide paper packaging materials such as paper cups, bowls, bacteria with fresh-keeping, the inner edge of the surface is applied to the green matter to kill the recorded objects and can be used - During the period of time, the biodegradable property of the polylactic acid can be combined with the energy, and the environmentally-friendly requirements and the range of the paper film layer can be biodegradable and fresh-keeping sterilized paper package materials. The weight ratio is 8G~95%, and the weight ratio of nano silver is 5~20. The film can be aged and preserved. The paper package material inside the paper table __(a>RQNA)_ 5K~5QKw power electric film Layer ΐϋΐίίϊThe first biodegradable fresh-keeping sterilized paper package material mentioned in item 1 Wei pressure of the cooling temperature is 15~28. ^ Compared with the method of manufacturing the membrane layer in the biodegradable fresh-keeping _ paper packaging material according to the first paragraph of the patent scope of claim 4, wherein the paper system can be a non-woven fabric coated polylactic acid nano silver film for use in fresh-keeping paper. .
TW98132649A 2009-09-28 2009-09-28 Manufacturing method of inner film layer of biodegradable freshness preservation and sterilization paper packing material TW201111587A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012035029A3 (en) * 2010-09-14 2012-10-04 L'oreal Cosmetic composition comprising a dyestuff, said dyestuff and cosmetic treatment process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012035029A3 (en) * 2010-09-14 2012-10-04 L'oreal Cosmetic composition comprising a dyestuff, said dyestuff and cosmetic treatment process

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