201111587 六、發明說明: 【發明所屬之技術領域】 本發明為一種可生物分解保鮮殺菌紙包材内膜層之製法,係 在紙包材如紙杯、碗、紙便當盒、保鮮紙等内緣表層披附一聚乳 酸奈米銀薄膜,應用奈米銀對盛裝物具有殺菌保鮮效果,且可在 使用一段時間,藉該聚乳酸可生物分解特性而自然分解自紙匹上 剝離,並能與土壤結合,達到環保要求及紙張本身可回收再利用 之效益的技術領域。 【先前技術】201111587 VI. Description of the Invention: [Technical Field] The invention is a method for preparing an inner membrane layer of a biodegradable fresh-keeping sterilized paper packaging material, which is in the inner edge of paper packaging materials such as paper cups, bowls, paper lunch boxes, and wrap paper The surface layer is coated with a polylactic acid nano silver film, and the nano silver is used for sterilizing and preserving effect on the contents, and can be used for a period of time, and the polylactic acid can be biodegraded and naturally decomposed from the paper, and can be separated from The technical field of combining soils to meet the environmental requirements and the benefits of recycling the paper itself. [Prior Art]
按一般紙製產品(如:紙杯、紙碗、紙盤、紙盒及紙製便當盒、 飲料、’氏i、不織布、紙容盗..等),為使承裝食物時不致發生參 漏情形,通常會在紙製產品之紙片内面,披附一層PE或pp ^ 淋膜層,然該牀膜層因無法自然分解,而產生環境二次公宝。 前述的問題,目前已能獲得突破性的發展,其原料已二可 PLA(聚乳酸)_於_表層,而產生自齡解之效果;然該 僅能提供自然分解效果,但仍無法達成可為保鮮殺菌之功能。 而要達成保鮮殺菌效果,又能達成自然分解之環保效果, =淋膜技術披附祕上製成紙製容器魄啸有耐米銀混合ς ^膜内,#能達成殺菌保鮮作用,然此為非一般淋膜技術即能達 【發明内容】 八站一f可生齡解簡殺眺包材_層之製法,係以生物可 二=之聚礼酸原料添加奈米銀,其重量比為聚乳酸8〇〜 太 ,量比為5〜20% ’ _拌混合後,透過融雜絲裝置‘= j酸奈米銀複合絲,再將聚乳酸奈米銀複合絲逐 成‘ 酸,銀顆粒’並透過淋膜機將該聚乳酸奈米銀顆粒熔== 二礼酸奈練賴’該聚該奈米銀薄朗時 ,處理機(CORONA)以5K〜50KW功率電擊紙匹表 士=一橡_5〜28。⑽冷卻輪麵 = 與紙匹而相互_結合為-體,使其披附於紙匹 3 201111587 銀薄膜層’以形成保鮮殺菌紙包材,再經裁切製成 碗、紙便當盒、保鮮紙等,其内緣表層即應 #氏杯、 及紙張本身可回收再利用之效益者。 、保要求 【實施方式】 第-、二騎示’係以生物可分解之聚魏 加不米銀2,其重量比為聚乳酸8〇〜95%,奈米銀 氐、/添 %,經攪拌混合成聚乳酸奈米銀複合材料3後,’透:〜2〇 ί ί聚ί酸奈米銀複合絲5,再將聚乳酸奈米銀複 ===解而押出一聚乳酸奈米銀薄膜:該 ί率電擊表面處理機8(C〇R〇NA)以5K〜5“ 表產生毛細孔上’隨後經-橡膠輪91與15〜28 產生=卩^2輾壓該聚乳酸奈米銀細6與紙匹7,應用該電擊 由:捲收’以製成保_紙= ㈣所示,該披附有聚乳酸奈米銀薄膜61之 ㈣舍ί成紙容11如紙杯Α(第_·々、紙碗稱四圖七)、 f膜ΙΓ*座(第Γ、圖等紙包材之内、缘表層即具有聚乳酸奈米銀 1B ci_銀對盛裝物具有賴保鮮效果;請參閱第三圖 而白钟八站所不’可在使用一段時間’藉該聚乳酸可生物分解特性 能與土壤結合,達到‘ 前法所製成之鱗殺賊包材,其中該紙匹7可為 , ”披附之表層亦為聚乳酸奈米銀薄膜61,即可直接提供 〇材之應用,作為保鮮膜或保鮮包覆食物、水果用途者。’、 201111587 【圖式簡單說明】 第一圖為本發明之製造流程方塊圖。 第二圖為本發明之設備流程圖。 第三圖-A〜C為本發明之淋膜層於紙匹上自然分解示意圖。 第四圖-A〜C為本發明可製成成品實施例圖。 【主要元件符號說明】 聚乳酸1 奈米銀2 聚乳酸奈米銀複合材料3 _ 融熔紡絲裝置4 聚乳酸奈米銀複合絲5 聚乳酸奈米銀顆粒51 淋膜機6 聚乳酸奈求銀薄膜61 紙匹7According to general paper products (such as paper cups, paper bowls, paper trays, paper boxes and paper lunch boxes, beverages, 'I', non-woven fabrics, paper pirates, etc.), so as not to cause leakage when loading food In the case, usually a layer of PE or pp ^ is coated on the inner surface of the paper of the paper product, and the film layer of the bed is naturally unresolved, resulting in an environmental secondary treasure. The above-mentioned problems have now achieved a breakthrough development. The raw materials have been able to produce PLA (polylactic acid) _ on the surface layer, which produces the effect of self-digestion; however, it can only provide natural decomposition effects, but it still cannot be achieved. For the preservation of the function of sterilization. In order to achieve the effect of fresh-keeping and sterilizing, and to achieve the natural decomposition effect of natural decomposition, the coating technology is made into a paper container, and the screaming has a resistance to rice and silver mixed ς ^ film, # can achieve sterilization and preservation, but this For non-general laminating technology, it can reach [invention content] Eight stations and one f can be used to solve the problem of 眺 眺 眺 _ _ _ _ , , , , , , , , 层 层 层 层 层 层 层 层 层 层 层 层 层For polylactic acid 8〇~ too, the ratio is 5~20% ' _ mix and mix, through the melt wire device '= j acid nano silver composite wire, and then the polylactic acid nano silver composite wire into 'acid, The silver particles 'and the polylactic acid nano silver particles are melted through the laminating machine==Bai Lishui Nai Lai', when the silver is thin, the processor (CORONA) is electrically shocked at 5K~50KW士=一橡_5~28. (10) Cooling the tread = with the paper and _ together with the body, so that it is attached to the paper 3 201111587 silver film layer 'to form a fresh-keeping sterilized paper package, and then cut into a bowl, a paper lunch box, fresh Paper, etc., the inner edge of the surface is the #氏氏, and the paper itself can be recycled and reused. , insurance requirements [embodiment] The first - and second riding shows 'biodegradable poly-weijia not silver 2, the weight ratio of polylactic acid 8 ~ 95%, nano silver, /%%, by After stirring and mixing into polylactic acid nano silver composite material 3, 'transparent: ~2〇ί ί polylactic acid nano silver composite wire 5, and then polylactic acid nano silver complex === solution and a polylactic acid nano Silver film: The 电 rate electric shock surface treatment machine 8 (C〇R〇NA) is 5K~5" on the surface of the capillary hole' and then the rubber wheel 91 and 15~28 are produced = 卩^2 The rice silver thin 6 and the paper 7, the electric shock is applied by: winding the 'made to protect paper _ paper = (4), which is coated with the polylactic acid nano silver film 61 (four) ί 成 into a paper capacity 11 such as a paper cup Α (Article _·々, paper bowl called four figure seven), f film ΙΓ* seat (the inside of the paper, such as Γ, 图, etc., the surface layer of the layer has polylactic acid nano silver 1B ci_ silver has a fresh on the contents The effect; please refer to the third picture and the white clock eight station does not 'can be used for a period of time' by the polylactic acid biodegradable characteristics combined with the soil, to achieve the 'pre-method made scales thieves package materials, which Paper 7 can be , "The surface layer of the drapes is also a polylactic acid nano silver film 61, which can directly provide the application of coffin, as a plastic wrap or fresh-keeping food and fruit use.", 201111587 [Simple description of the picture] The block diagram of the manufacturing process of the present invention. The second figure is a flow chart of the device of the present invention. The third figure -A~C is a schematic diagram of the natural decomposition of the coating layer on the paper of the present invention. The fourth figure -A~C is The invention can be made into a diagram of the finished product. [Description of main component symbols] Polylactic acid 1 Nano silver 2 Polylactic acid nano silver composite material 3 _ Melt spinning device 4 Polylactic acid nano silver composite wire 5 Polylactic acid nano Silver Particles 51 Laminating Machine 6 Polylactic Acid Naim Silver Film 61 Paper 7
表面處理機8 橡膠輪91 冷卻輪92 羅拉R 紙杯A 紙碗B 紙便當盒CSurface treatment machine 8 Rubber wheel 91 Cooling wheel 92 Roller R Paper cup A Paper bowl B Paper lunch box C