201109397 六、發明說明： 【發明所屬之技術領域】 本發明是涉及一種塗料組成。 【先前技術】 隨著電子工業的迅速發展，各種家用電器、辦公微機、儀 器設備等電子產品得到了廣泛的普及與應用。然而它們的工作 給人們帶來極大便利的同時也釋放出大量的電磁輕射危 人們的健康》 ° 此外，電磁輕射對電子產品本身，也存在著極大的危害。 -方面’塑勝以其價廉、質輕、易加工的優點，被廣泛用作電 子產品的外殼，但其對電磁波幾乎是完全透明的，對電磁干擾 毫無屏蔽作用。 另一方面’電子產品内部微電流控制信號的功率，與外部 之電磁波噪音的功率相近，極易受到干擾而出現操作失誤、系 統癍瘓等嚴f後果，同時這些電子產品本身料發射的電磁 波’也會對鄰近的電子設備產生干擾。 還有，在半導體產業中，有超過50%的產品失效原因，被 歸咎於E0S/ESD影響’產品被靜電打穿、燒毁、劣化、破壞的 情況，時常是產品發生問題的原因，近年來靜電防護麵已成 為全球各大廠的主要課題。 導電塗料便是在此種狀態下，因應而生，導電塗料最早應 用於20世紀初，導電塗料的使用目的，一般分為靜電防護(esw 及抗電磁干擾(EMI)兩種。 靜電（ESD/Electrical Static Discharge)防護漆，主要 201109397 應用在電子業，能避免靜電損害產品、及提高產品良率，能讓 生產作業環境符合ESDA的規範。 電磁干擾（EMI/Electromagnetic Interference)防護 漆，主要的應用是電磁波遮蔽，可以有效降低電磁波對人體健 康的危害與對電子產品的影響。 【發明内容】 一、所欲解決的問題點： 前述習知導電塗料存在著下列問題點： 1·目則習知導電塗料的色彩，受到其内導電原料的影響， 如·銀(Ag)與導電炭黑(carbonblack)，多為金屬色澤和石墨 暗黑色系，色彩單一、單調，不明亮。 有鑑於此，如何有效的解決，因為導電塗料原料，所帶來 的色彩單一、單調問題，便成為本發明欲改進的目的之一。 2·目前習知導電塗料所使用的導電材料，為了達到足夠的 靜電、電磁波防護效果’導電性要好，而導電性好的材料，一 般多為貴金屬，如：銀(Ag)、銅(cu )、銘(A1)、錄⑽）、鋅 (Zn)等，其價格高，連帶的會提高導電塗料的成本，使導電塗 料無法大量的使用，讓使用範圍受的限制。 有鑑於此，如何使用低價的導電材料，達到足夠的靜電、 電磁波防護效果’便成為本發明欲改進的目的之二。 3.目前習知導電塗料所使用的填料，為碳酸鈣(Calcium carbonate) ’其所提供的硬度，只有摩氏硬度3的耐磨硬度， 非常不耐磨。 有鑑於此’如何提高導電材料的耐磨硬性，便成為本發明 欲改進的目的之三。 201109397 二、本發明的技術手段： 本發明目的在於提供一種色彩多樣化、成本低、硬度高、 能抗菌、光澤和透明性佳、能靜電防護及抗電磁干擾的塗料組 成。 、、 為解決前述問題及達到本發明的目的，本發明的技術手 段，有以下兩種應用實施型態： 本發明的第一實施型態： 其技術手段’為一種塗料組成，其特徵在於： φ 該塗料（100)主要是由樹脂（1)加上二氧化鈦粉末(2)、球 狀的氧化辞半導體粉末(3)、硫化鋅粉末(4)、二氧化矽粉末 (5)、添加劑(6)、以及有機溶劑（7),予以調和而成； 而該添加劑（6)是由工業蠟助劑(61)、搖變性控制劑 (62)、消泡劑(63)、以及分散劑(64)所組成。 根據上述的塗料組成，所述塗料（1〇0)中，該樹脂（1)為主 要原料，重量百分比為20% ;該二氧化鈦粉末(2)，重量百分 比為14% ;該球狀氧化辞半導體粉末⑶，重量百分比為14 • % ;該硫化鋅粉末(4)，重量百分比為8% ;該二氧化矽粉末 (5)，重量百分比為8% ;該工業蠟助劑(61)，重量百分比為5 %，該搖變性控制劑(62)，重量百分比為1% ;該消泡劑(63)， 重量百分比為1% ;該分散劑(64)，重量百分比為1% ;該有 機溶劑（7)，重量百分比為28%。 根據上述的塗料組成，所述樹脂（1)為下列之一：長油型 醇酸樹脂、中油型醇酸樹脂、短油型醇酸樹脂與確化纖維素混 合樹脂、短油型醇酸樹脂與三聚氰胺尿素混合樹脂、短油型醇 酸樹脂與三聚氰胺混合樹脂、苯乙稀樹脂、苯乙烯與丙烯酸酯 聚合樹脂、熱塑型丙烯酸樹脂、飽和聚酯與異氰酸酯混合樹 201109397 脂、飽和聚酯與硝化纖維素混合樹脂、醇酸多元醇與異氰酸醋 混合樹脂、醇酸多元醇與磷化纖維素混合樹脂、丙烯酸多元醇 與異氰酸酯混合樹脂、丙烯酸多元醇與硝化纖維素混合樹脂、 濕氣硬化型聚氨酯樹醋、環氧樹脂與變性胺混合樹脂、環氧樹 脂與聚醯胺混合樹脂、環氧樹脂與多胺聚醯胺混合樹脂、環氧 樹脂與變性環狀脂肪族胺混合樹脂、環氡樹脂與變性芳香族胺 混合樹脂、有機矽樹脂、矽變性醇酸樹脂、矽變性環氧樹脂、 梦變性二氧化矽樹脂、矽變性橡膠樹脂、矽變性丙烯基樹脂、 氯化橡膠樹脂、氟素樹脂與不變黃聚異氰酸混合樹酯、聚偏二 氟乙婦樹酯。 根據上述的塗料組成’所述氧化鋅半導體粉末(3)的粉體 電阻係數$300(〇*〇1〇，而平均粒徑為〇.18(/^111)。 根據上述的塗料組成，所述工業蠟助劑（61)的主要成分為 合成蠟’主要溶劑為油漆溶劑1〇〇號。 根據上述的塗料組成，所述搖變性控制劑（62)的主要成分 是為改性脲溶液’主要溶劑是為N_甲基砒咯烷酮(NMp)。 根據上述的塗料組成，所述消泡劑(63)是為下列之一：有 機碴、聚合物。 根據上述的塗料組成，所述分散劑(64)是為下列之一：不 餘和聚胺鉄與低分子酸性聚酯、高分子聚胺酸與烷胺、高分子 聚胺酸與聚胺烧胺、長鏈多胺鉄胺和極性酸性g旨、含酸性基團 聚合物、具有顏料親合基團的共聚酯、羥基官能羧酸酯、高分 子烷基醇氨基鉄胺、含酸性顏料親合基團高分子共聚體、含鹼 性顏料親合基團高分子共聚體、含顏料親合基團高分子共聚 體、丙婦酸共聚體、不飽和聚胺酸的聚鉄胺、酸性共聚體烷基 胺鹽、高分子量共聚體磷酸酯、帶酸性顏料親合基團之共聚酯 6 201109397 的烷醇胺、改性丙烯酸高分子共聚體、星型結構_含酸性顏料 親合基團的聚烷基酯、星型結構-含中性顏料親合基團的聚烷 基酯、極性-酸性聚酯及高分子量醇複合體、不溶性顏料溶合 物、不飽和聚胺酸均聚體、不飽和聚胺酸均聚體和有機硅、不 飽和聚胺酸與胺-含有機硅。 本發明的第二實施型態： 其技術手段，為一種塗料組成，其特徵在於： 該塗料(200)主要是由樹脂（1)加上二氧化鈦粉末(2)、球 狀的氧化鋅半導體粉末(3)、硫化鋅粉末(4)、二氧化矽粉末 (5)、添加劑(6)、以及水(8) ’予以調和而成； 而該添加劑(6)是由工業蠟助劑（61)、搖變性控制劑 (62)、消泡劑（63)、以及分散劑(64)所組成。 根據上述的塗料組成，所述塗料(200)中，該樹脂（1)為主 要原料，重量百分比為20% ;該二氧化鈦粉末(2)，重量百分 比為14% ;該球狀氧化辞半導體粉末(3)，重量百分比為 % ’該硫化鋅粉末(4) ’重量百分比為8% ;該二氧化矽粉末 (5)，重量百分比為8% ;該工業蠟助劑(61)，重量百分比為5 %，該搖變性控制劑(62)，重量百分比為1% ;該消泡劑(63)， 重量百分比為1% ;該分散劑（64)，重量百分比為丨％ ;該水 (8)，重量百分比為28%。 根據上述的塗料組成，所述樹脂（1)為下列之一：丙烯酸 醋樹脂、苯乙烯酯樹脂、水性矽素與丙烯酸酯聚合樹脂、苯乙 稀與丙烯酸酯聚合樹脂、水性聚酯樹脂'水性壓克力聚酯樹 脂、水性聚醯胺與泛用液狀環氧混合樹脂。 根據上述的塗料組成，所述氧化鋅半導體粉末(3)的粉體 電阻係數$300(Ω · cm)，而平均粒徑為〇· i8(；am)。 201109397 根據上述的塗料組成’所述工業蠟助劑（6丨）的主要成分為 石蠟與氧化高密度聚乙烯混合蠟，主要溶劑為水。 根據上述的塗料組成，所述搖變性控制劑(62)的主要成分 是為改性脲溶液，主要溶劑是為N-甲基础咯烷酮(蘭p)。 根據上述的塗料組成，所述消泡劑(63)是為下列之一：有 機娃、聚合物、礦物油、疏水性粒子。 根據上述的塗料組成，所述分散劑(64)是為下列之一：聚 胺酸與烷醇胺、丙烯酸聚合體、帶酸性基團之高分子共聚酯的 烷醇胺、多官能基聚合體的烷醇胺、含顏料親合基團高分子共 聚體、含顏料親合星團高分子共聚體、多官能基聚合體的烷基 胺鹽。 二、對照先前技術之功效： 1. 本發明的重點一’塗料中所使用之球狀的氧化鋅半導體 粉末(3)，讓塗料(100、200)不但有很好的靜電防護及抗電磁 干擾特性，其透明的性質，讓本發明能克服導電塗料，只有單 一顏色的單調性問題，可實現導電塗料的色彩多樣性，製作明 焭色調，大大滿足眾多用戶對導電塗料顏色、日趨豐富的個性 化、明快化、效率化之色彩選擇的國際潮流。 2. 本發明的重點二，塗料中所使用之球狀的氧化鋅半導體 粉末(3)，除了能克服塗料（1〇〇、2〇〇)其顏色單一的問題外， 更不含有-般導電粉體t，娣、錫、銦等對人體有害的物質， 安全性尚，本身無毒、無味、對皮膚無刺激性、不變質、熱穩 定性極佳，抗菌、消毒、除臭、自潔等功能皆很強；此外盥 一般導電粉體中所使用的貴金屬相比，有更高的價性比，能^ 低塗料(100、200)的成本。 3·本發明的重點三’塗料⑽、_中再加上配入一硫化 201109397 辞粉末(4)後’進而使塗層具有艷麗的外觀，並有著長效殺菌 的作用’硫鱗粉末⑷本身無毒，和其它殺細、殺菌劑、 抗菌劑相比，在安全性質上，硫化辞粉末(4)更可取，再者氧 化鋅半導體粉末⑶亦具有—定的抗g、除臭性，塗層抗菌性 由氧化辞半導體粉末(3)及硫化辞粉末(4)，提供相辅相成的雙 重效果’其抗菌性，屬於結構長效型和高度的安全性，因而塗 料在其施工作業時’無損職工及使用者的健康，亦更具環境保 護性。 • 4.本發明的重點四，本發明塗料（100、200)其塗層的耐磨 性，有別於習知導電塗料，以碳酸詞所提供之摩氏硬度3的 耐磨硬度，本發明塗料(100、200)的耐磨性，分為兩個階段來 作用，首先，當產生磨損時，會先磨損漂浮於漆膜表面的工業 壤助劑，其所提供之滑度、抗劃傷性(scratch resistance)、 耐摩擦性後，之後再磨耗以二氧化矽粉末(5)所提供之摩氏硬 度7的耐磨硬度，藉由雙重的保護，加上更高的硬度，能讓 本發明的使用壽命，比習知導電塗料更長。 • 5.本發明的重點五’本發明塗料(1〇〇、2〇〇)中，所採用的 搖變性控制劑（62)，其主要成分中的改性脲溶液，它的作用方 式是基于其有效物質，在大部分塗料溶劑[有機溶劑(7)、水(8)] 中的不溶解性，助劑添加入進塗料(1〇〇、200)中，析出產生很 細的針狀結晶（cement bacillu)，形成三維網絡結構，更優化 調整流變的特性，大大改進儲存時的抗沉降，和施工時的抗流 掛性’這些網絡結構在很低的煎切力下，就足以可逆地被破 壞，因此使塗料(100、200)具假塑、觸變流動的特性，在施工 時，處於低黏度之封閉循環管道中，塗料(100、2〇〇)具有很有 效的防沉澱流變效應作用；亦能改良習知導電塗料，其所使用 201109397 的傳統型蠟漿及有機膨脹土型流變助劑，對於塗料會降低光澤 和影響透明性的問題。 6.本發明的重點六，本發明塗料（1〇〇、2〇〇)中，透過調整 樹脂（1)及添加劑(6)後’便能以有機溶劑（7)或是水(8),作為 本發明的塗料溶劑使用，可以在不影響主要功能的狀況下，將 本發明區分為油性的塗料（1〇〇)，或是水性的塗料(2〇〇)，讓本 發明的應用範圍更廣、 【實施方式】 以下依據圖面所示的實施例詳細說明如後： 第一實施型態： 如圖1所示為本發明第一實施例的方塊組成示意圖。圖式 中揭示出，一種塗料組成，其特徵在於： 該塗料（100)主要是由樹脂（1)加上二氧化欽粉末⑵、球 狀的氧化鋅半導體粉末(3)、硫化鋅粉末(4)、二氧化矽粉末 (5)、添加劑（6)、以及有機溶劑（7)，予以調和而成； 而該添加劑（6)是由工業蠟助劑（61) (Wax-Auxilliaries)、搖變性控制劑（62)(Thixotropic Agent & Anti settling)、消泡劑（63)(Defoamer)、以及分散劑 (64)(Dispersant)所組成。 又上述中，所述塗料（100)中，該樹脂（1)為主要原料，重 量百分比為20% ;該二氧化鈦粉末(2)，重量百分比為14% ; 該球狀氧化辞半導體粉末(3)，重量百分比為14% ;該硫化鋅 粉末(4)，重量百分比為8% ;該二氧化矽粉末(5)，重量百分 比為8% ;該工業蠟助劑（61) ’重量百分比為5% ;該搖變性 控制劑(62)，重量百分比為1% ;該消泡劑（63)，重量百分比 為1% ;該分散劑(64)，重量百分比為1% ;該有機溶劑（7)， 201109397 重量百分比為28%。 其中，透過添加的各種材料，發揮出其各自的優點與用 途，並以最適當且經濟的比例混合，以達到本發明的目的 優點如以下所示： 、 [1] 樹脂a)，供塗膜型成用。 [2] 二氧化鈦粉末（2)，也就是一般所俗稱的鈦白粉 (Titaninm dioxide)，能提供-塗臈遮蓋力（hiding歸的二 與有機接合劑(organic binders)，有較高的安定度，不起化 學反應’具有較好的白色鮮亮度(brightness)，另外一個重要 原因，二氧化鈦可以吸收紫外光，作為塗料用途時可以有大 的財用度(durability)。 [3] 球狀的氧化鋅半導體粉末(3),活性高、具有遮蔽紅外 線、紫外線的功能，並能提供一導電能力、與殺菌能力，更能 能明顯提高產品遮蓋力（hidingpower)和著色力，且其為透明 的粉末，無原色，故能配合其他的上色顏料來使用，可實現導 電塗料的色彩多樣性，製作多樣化的明亮色調，大大滿足眾多 用戶對導電塗料顏色、日趨豐富的個性化、明快化、效率化之 色彩選擇的國際潮流》 [4] 硫化辞粉末（4)，摩氏硬度為3，能提供一抗菌 (anti-bacteria)、殺菌（sterilize)能力，有著長效殺菌的作 用，無毋，和其它殺蟲劑、殺菌劑、抗菌劑相比，在安全性質 上，硫化辞粉末(4)更可取，並能配合氧化辞半導體粉末(3)， 提供相辅相成的雙重抗菌效果。 [5] 二氧化發粉末(5)( Silicon dioxide)，Si〇2 的含量為 99· 2%左右、PH值=7、摩氏硬度為7、分子形狀為六方顯晶組 系’可提供防結塊、防流掛(protect sag)、乳化、流化性、 201109397 消光(extinction)性、支持性、懸浮、增稠、觸變性等功能， 在塗料中成功地應用，一改過去產品的不足，其主要性能指標 均大幅提高，如、外牆塗料的耐洗刷性，能由原來的1〇⑽多 次’提高到1萬多次以上，人工加速氣候老化(aging)和人工 輻射暴露老化時間’由原來的250小時(粉化1級、變色2級）， 提高到600小時以上（無粉化，漆膜無變色，色差值4 8)，此 外塗膜與牆體結合強度’大幅提高，塗膜硬度顯著增加，能提 供一更高的耐磨性，表面自潔能力也獲得改善。 [6] 添加劑（6)中的工業蠟助劑（61)，使塗料具有撥水性 (water repel lency)、耐摩擦性(rub resistance)、耐防黏性 (anti blocking)、並能增加表面滑爽性（slip)。 [7] 添加劑（6)中的搖變性控制劑（62)，使塗料能防沉 (anti settling)、抗流掛(protect sag) » [8] 添加劑(6)中的消泡劑（63)，供塗料的消泡、脫泡用。 [9] 添加劑（6)中的分散劑（64)，供分散塗料用》 [10] 有機溶劑（7)(organic solvent)、供混合各種原料 用。 上述中，所述樹脂（1)為下列之一：長油型醇酸樹脂、中 油型醇酸樹脂、短油型醇酸樹脂與硝化纖維素混合樹脂、短油 型醇酸樹脂與三聚氰胺尿素混合樹脂、短油型醇酸樹脂與三聚 氛胺混合樹月曰、本乙稀樹脂、苯乙稀與丙稀酸醋聚合樹脂、熱 塑型丙烯酸樹脂、飽和聚酯與異氰酸酯混合樹脂、飽和聚酯與 硝化纖維素混合樹脂、醇酸多元醇與異氰酸酯混合樹脂、醇釀 多元醇與磷化纖維素混合樹脂、丙烯酸多元醇與異氰酸酯混合 樹脂、丙烯酸多元醇與硝化纖維素混合樹脂、濕氣硬化型聚氨 酯樹酯、環氧樹脂與變性胺混合樹脂、環氧樹脂與聚醯胺混合 12 201109397 樹脂、環氧樹脂與多胺聚醯胺混合樹脂、環氧樹脂與變性環狀 脂肪族胺混合樹脂、環氧樹脂與變性芳香族胺混合樹脂、有機 矽樹脂、梦變性醇酸樹脂、矽變性環氧樹脂、發變性二氧化石夕 樹脂、矽變性橡膠樹脂、矽變性丙烯基樹脂、氯化橡膠樹脂、 氟素樹脂與不變黃聚異氰酸混合樹酯、聚偏二氟乙稀樹酯。 其中，透過使用不同的樹脂（1)原料，讓本發明塗料 (100)，能配合其它的原料，符合油性塗料的規範，並能增加 應用範圍，並讓消費者有更多的選擇。. 上述中，所述工業蠟助劑（61)的主要成分為合成蠟，主要 溶劑為油漆溶劑100號。 又上述中’所述消泡劑（63)是為下列之一：有機硅、聚合 物。 其中，因為塗料（100)的組成方式，是一種油性塗料的組 成，故能使用以上所述的各種工業蠟助劑（61)與消泡劑（63) 的配合’以符合塗料（1〇〇)的用途與使用場所。 上述中，所述分散劑（64)是為下列之一：不飽和聚胺鉄與 低分子酸性聚酯、高分子聚胺酸與烷胺、高分子聚胺酸與聚胺 烧胺、長鍵多胺鉄胺和極性酸性酯、含酸性基團聚合物、具有 顏料親合基團的共聚酯、羥基官能羧酸酯、高分子烷基醇氨基 鉄胺、含酸性顏料親合基團高分子共聚體、含鹼性顏料親合基 團高分子共聚體、含顏料親合基團高分子共聚體、丙烯酸共聚 體、不飽和聚胺酸的聚鉄胺、酸性共聚體院基胺鹽、高分子量 共聚體鱗酸酯、帶酸性顏料親合基團之共聚酯的烧醇胺、改性 丙烯酸高分子共聚體、星型結構-含酸性顏料親合基團的聚院 基酯、星型結構-含中性顏料親合基團的聚烷基酯、極性-酸性 聚酿及高分子量醇複合體、不溶性顏料溶合物、不飽和聚胺酸 201109397 均聚體、不飽和聚胺酸均聚體和有機硅、不飽和聚胺酸與胺— 含有機娃。 其中，因為塗料（1〇〇)的組成方式，是一種油性塗料的組 成，故能使用以上所述的各種分散劑（64)，以符合塗料（1〇〇) 的用途與使用場所’並增加本發明的適用範圍。 第二實施型態： 如圖2所示為本發明第二實施例的方塊組成示意圖。圖式 中揭示出’ 一種塗料組成，其特徵在於： 該塗料(200)主要是由樹脂（1)加上二氧化鈦粉末、球 狀的氧化鋅半導體粉末(3)、硫化鋅粉末(4)、二氧化矽粉末 (5)、添加劑（6)、以及水(8)，予以調和而成； 而該添加劑（6)是由工業蠟助劑（61)、搖變性控制劑 (62)、消泡劑（63)、以及分散劑（64)所組成。 又上述中’所述塗料(200)中，該樹脂（1)為主要原料，重 量百分比為20% ;該二氧化鈦粉末(2)，重量百分比為14% ; 該球狀氧化鋅半導體粉末(3) ’重量百分比為14% ;該硫化鋅 粉末(4) ’重量百分比為8% ;該二氧化梦粉末(5)，重量百分 比為8% ;該工業壤助劑（61)，重量百分比為5% ;該搖變性 控制劑（62)，重量百分比為1% ;該消泡劑（63)，重量百分比 為1% ;該分散劑（64)，重量百分比為1% ;該水(8)，重量百 分比為28% 〇 其中，透過添加的各種材料，發揮出其各自的優點與用 途’並以最適當且經濟的比例混合，以達到本發明的目的，其 優點如以下所示： [1]而上述之樹脂（1)、二氧化鈦粉末（2)、氧化鋅半導體 粉末（3)、硫化鋅粉末(4)、二氧化矽粉末（5)、與添加劑（6) 201109397 中的搖變性控制劑(62)、消泡劑(63)、分散劑(64)的優點，與 前述第一實施例所述的優點内容相同。 [2] 添加劑（6)中的工業蠟助劑(61)，使塗料具有撥水性 (water repellency)、耐摩擦性(rub resistance)、对鞋跟劃 痕(black heel resistance)、耐防黏性(anti blocking)、並 能增加表面滑爽性(slip)。 [3] 水(8)、供混合各種原料用。 上述中’所述樹脂（1)為下列之一：丙烯酸酯樹脂、苯乙 烯酯樹脂、水性矽素與丙烯酸酯聚合樹脂、苯乙烯與丙烯酸酯 聚合樹脂、水性聚酯樹脂、水性壓克力聚酯樹脂、水性聚醯胺 與泛用液狀環氧混合樹脂。 其中，透過使用不同的樹脂（1)原料，讓本發明塗料 (200)，能配合其它的原料，符合水性塗料的規範，並能增加 應用範圍，並讓消費者有更多的選擇。 上述中，所述工業蠟助劑（61)的主要成分為石蠟與氧化高 密度聚乙烯混合蠟，主要溶劑為水。 又上述中，所述消泡劑(63)是為下列之一：有機硅、聚合 物、礦物油、疏水性粒子。 其中’因為塗料(200)的組成方式，是一種水性塗料的組 成，故能使用以上所述的各種工業蠟助劑（61)與消泡劑（63) 的配合’以符合塗料(200)的用途與使用場所。 上述中，所述分散劑（64)是為下列之一：聚胺酸與烷醇 胺、丙烯酸聚合體、帶酸性基團之高分子共聚酯的烷醇胺、多 官能基聚合體的烷醇胺、含顏料親合基團高分子共聚體、含顏 料親合星團高分子共聚體、多官能基聚合體的燒/基胺鹽。' 其中，因為塗料(200)的組成方式，是一種水性塗料的組 15 201109397 成，故能使用以上所述的各種分散劑（64) ’以符合塗料(200) 的用途與使用場所，並增加本發明的適用範圍。 上述兩實施例中，所述搖變性控制劑（62)的主要成分是為 改性脲溶液，主要溶劑是為N-甲基砒洛垸酮(顺p)。 其中，具有用量小、穩定性好、對塗層其它影響小的特點， 它的作用方式是基于其有效物質，在大部分塗料溶劑[有機溶 劑（Ό、水(8)]中的不溶解特性，當搖變性控制劑（62)，做為 助劑添加入進塗料（1〇〇、2〇〇)中後，會析出產生很細小的針狀 結晶（needlecrystal)，形成一三維網絡結構，這樣就可產生 觸變流動性能，以防止沉降並改善防流掛性。 其久，這些網絡結構，在很低的剪切力下，就足以可逆地 被破壞，因此使塗料（100、200)具有假塑、觸變流動的特性， 在施工時，就算是處於低黏度之封閉循環管道中，塗料（100、 200)仍具有非常好的防沉澱流變效應作用。 再者，亦能改良習知導電塗料，其所使用的傳統型蠟漿及 有機膨脹土型流變助劑，對於塗料(1〇〇、2〇〇)，會降低其光澤 和影響其透明性的問題。 、 上述兩實施例中，所述氧化辞半導醴粉末(3)的粉體電阻 係數S300(Q · cm)，而平均粒徑為〇 。 其中，氧化鋅半導體粉末(3)，由於晶粒的細微化，其表 面電子結構和晶赌紐生變化，產生了宏麟體所不具有的 ，面效，、體積效應、量子尺寸效應和魏贼效應以及高透 月度n分散性等特點，更因為氧化鋅雜的細微化，具有半 ^體的雜m下具有比塊材氧化鋅更高的導電性，因而 ^靜ί遮罩作用，製成抗靜電、抗電磁干擾用的塗料(100、 月匕發揮出不遜於使用貴金屬之習知導電塗料的防護效 16 201109397 果’同時其調色優於常用的導電材料碳黑，故應用能更為廣泛。 其次，氧化鋅半導體粉末(3)，除具有傳統氧化鋅的抗菌 作用’由於粒子粒徑的細微化，故具有細微粒子特有的小尺寸 效應、表面介面效應、及量子尺寸效應； 氧化鋅半導體粉末(3)，在抗菌效果方面有： [A] 比表面積大，與傳統無機抗菌劑相比，可大大減少用 量’是傳統無機抗菌劑用量的10%〜20%。 [B] 氧化鋅半導體粉末(3)的表面原子數量，大大多於傳 統粒子’表面原子由於缺少鄰近的配位原子，而具備很高能 量’可增強氧化鋅與細菌的親和力，提高殺菌的效率。 [C] 對氧化鋅半導體粉末(3)而言，顆粒細微化，可大大提 高光催化效應，在光照條件下產生電子躍遷，並將能量傳遞， 在離子表面產生電子和空穴，與環境中的水和氧接觸時，生成 負氧離子和OH—離子，負氧離子具有很強殺菌力’而〇H-離子 可與大多數有機物反應，促使其分解，可增強殺菌力，用於塗 料（100、200)時，可使其產品具有自潔力。 再者，氧化辞半導體粉末⑶，也是一種半導體催化劑的 電子結構’在光騎下’當—個具有_定能量的光子，或者具 有超過14辦導體帶雜量Eg的光子，射人半導體時，一個 ==價_激發料帶.而留下了—個空穴；激發態的 導帶電子和條以，_重新結合，齡輸人的能量和熱， 電子在材料的表面態被捕捉，價態電子躍遷_帶，價帶 mu境巾贿基料，搶奪過來，使祕魏自由基， =強氧化劑，而完成對有機物(或含氣)的降解，將病菌和病 每殺死。 由此能得知，本發明的塗料⑽、_，透過添加、球狀 201109397 的氧化鋅半導體粉末(3)、硫化鋅粉末(4)、二氧化矽粉末(5)， 讓塗料(100、200)具有靜電防護及抗電磁干擾性能，擁有足夠 的全方位安全性，並能降低成本、提高硬度、增加抗菌效果， 亦解決了色調單一的問題，而配合使用的工業蠟助劑（61)和搖 變性控制劑(62)，更進一步的提升了塗料（1〇〇、2〇〇)的滑度、 耐刮傷、耐摩擦性、抗沉降、抗流掛性、防沉澱等優點，相較 於現今的習知導電塗料，更具功效性、實用性與產業利用性。 以上依據圖式所示的實施例詳細說明了本發明的構造、特 徵及作用效果’由於符合新穎及進步性要件，遂爰依法提出發 明專利申請，惟以上所述僅為本發明之較佳實施例，但本發明 不以圖面所示限定實施範圍，因此舉凡與本發明意旨相符的修 飾性變化，只要在均等範圍内都應涵屬於本發明專利範圍内。 18 201109397 【圖式簡單說明】 圖1 :本發明第一實施例的方塊組成示意圖。 圖2:本發明第二實施例的方塊組成示意圖。 【主要元件符號說明】 1 樹脂 2 二氧化鈦粉末 3 氧化鋅半導體粉末 4 硫化鋅粉末 5 二氧化矽粉末 6 添加劑 61 工業蠟助劑 62 搖變性控制劑 63 消泡劑 64 分散劑 7 有機溶劑 8 水 100 塗料 200 塗料201109397 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a coating composition. [Prior Art] With the rapid development of the electronics industry, various electronic products such as household appliances, office microcomputers, and instrumentation equipment have been widely used and applied. However, their work has brought great convenience to people and also released a large number of people with electromagnetic light and danger. ° In addition, electromagnetic light is also a great hazard to the electronic products themselves. - Aspect's plastic is widely used as the outer casing of electronic products because of its advantages of low cost, light weight and easy processing. However, it is almost completely transparent to electromagnetic waves and has no shielding effect on electromagnetic interference. On the other hand, the power of the internal micro-current control signal of the electronic product is close to the power of the external electromagnetic wave noise, and it is highly susceptible to interference and operational errors, system defects, etc., and the electromagnetic waves emitted by these electronic products themselves. It can also cause interference to nearby electronic devices. In addition, in the semiconductor industry, more than 50% of product failures are attributed to E0S/ESD impacts. 'Products are electrostatically broken, burned, deteriorated, damaged, and often cause product problems. Electrostatic protection has become a major issue for major manufacturers around the world. Conductive coatings are produced in this state, and conductive coatings were first used in the early 20th century. The purpose of conductive coatings is generally divided into electrostatic protection (esw and anti-electromagnetic interference (EMI). Static electricity (ESD/ Electrical Static Discharge), mainly used in the electronics industry, can avoid static damage to products and improve product yield, and can make the production environment comply with ESDA specifications. Electromagnetic interference (EMI/Electromagnetic Interference) protective paint, main application It is electromagnetic wave shielding, which can effectively reduce the harm of electromagnetic waves to human health and the influence on electronic products. [Summary] 1. Problems to be solved: The above-mentioned conventional conductive coatings have the following problems: The color of the conductive paint is affected by the conductive materials inside, such as silver (Ag) and conductive carbon black, mostly metallic color and graphite dark black, the color is single, monotonous, not bright. In view of this, how Effectively solved, because the conductive paint raw materials, the single color, monotonous problem, has become the invention One of the purposes. 2. The conductive materials used in the current conductive coatings, in order to achieve sufficient static electricity, electromagnetic wave protection effect 'electrical conductivity is good, and conductive materials, generally more precious metals, such as: silver (Ag) , copper (cu), Ming (A1), recorded (10), zinc (Zn), etc., its high price, associated with the cost of conductive coatings, so that conductive coatings can not be used in large quantities, so that the scope of use is limited. In view of this, how to use a low-cost conductive material to achieve sufficient static electricity and electromagnetic wave protection effect has become the second object of the present invention. 3. The filler used in conventional conductive coatings is calcium carbonate (Calcium carbonate) which provides a hardness of only Mohs hardness of 3 and is very resistant to abrasion. In view of this, how to improve the wear resistance of the conductive material has become the third object of the present invention to be improved. 201109397 2. Technical means of the present invention: The object of the present invention is to provide a coating composition which is diversified in color, low in cost, high in hardness, excellent in antibacterial, gloss and transparency, capable of electrostatic protection and anti-electromagnetic interference. In order to solve the foregoing problems and achieve the object of the present invention, the technical means of the present invention have the following two application embodiments: The first embodiment of the present invention: The technical means 'is a coating composition, and is characterized by: φ The coating (100) is mainly composed of a resin (1) plus titanium dioxide powder (2), a spherical oxide semiconductor powder (3), a zinc sulfide powder (4), a cerium oxide powder (5), and an additive (6). And the organic solvent (7) is blended; and the additive (6) is composed of an industrial wax auxiliary (61), a shake control agent (62), an antifoaming agent (63), and a dispersing agent (64). ) composed of. According to the above coating composition, in the coating material (1〇0), the resin (1) is a main raw material, and the weight percentage is 20%; the titanium dioxide powder (2) is 14% by weight; the spherical oxide semiconductor Powder (3), weight percentage is 14%; the zinc sulfide powder (4) is 8% by weight; the cerium oxide powder (5) is 8% by weight; the industrial wax auxiliary (61), weight percentage 5 %, the shake control agent (62) is 1% by weight; the antifoaming agent (63) is 1% by weight; the dispersant (64) is 1% by weight; the organic solvent ( 7), the weight percentage is 28%. According to the above coating composition, the resin (1) is one of the following: a long oil type alkyd resin, a medium oil type alkyd resin, a short oil type alkyd resin and a deified cellulose mixed resin, a short oil type alkyd resin and Melamine urea mixed resin, short oil type alkyd resin and melamine mixed resin, styrene resin, styrene and acrylate polymer resin, thermoplastic acrylic resin, saturated polyester and isocyanate mixed tree 201109397 Fat, saturated polyester and nitrification Cellulose mixed resin, alkyd polyol and isocyanate vinegar mixed resin, alkyd polyol and phosphating cellulose mixed resin, acrylic polyol and isocyanate mixed resin, acrylic polyol and nitrocellulose mixed resin, moisture hardening Polyurethane vinegar, epoxy resin and denatured amine mixed resin, epoxy resin and polyamide resin, epoxy resin and polyamine polyamide resin, epoxy resin and denatured cyclic aliphatic amine mixed resin, ring Resin and denaturing aromatic amine mixed resin, organic antimony resin, deuterated alkyd resin, deuterated epoxy resin, dream denatured dioxygen Silicone, modified silicone rubber resin, silicon denatured acrylic resin, chlorinated rubber resin, a fluorocarbon resin and non-yellowing polyisocyanate mixed resin, polyvinylidene fluoride resin B women. According to the above coating composition, the zinc oxide semiconductor powder (3) has a powder resistivity of $300 (〇*〇1〇, and an average particle diameter of 〇.18 (/^111). According to the coating composition described above, The main component of the industrial wax auxiliaries (61) is synthetic wax. The main solvent is the paint solvent No. 1 。. According to the above coating composition, the main component of the thixotropy control agent (62) is a modified urea solution. The solvent is N-methylpyrrolidone (NMp). According to the above coating composition, the antifoaming agent (63) is one of the following: an organic hydrazine, a polymer. According to the above coating composition, the dispersion Agent (64) is one of the following: no residue and polyamine oxime and low molecular weight acid polyester, high molecular weight polyamine and alkylamine, high molecular polyamine and polyamine amine, long chain polyamine amide and Polar acid acid, acid group-containing polymer, pigment-affinity group-containing copolyester, hydroxy-functional carboxylic acid ester, polymer alkyl alcohol aminoguanamine, acid-containing pigment affinity group polymer copolymer, Basic pigment affinity group polymer copolymer, pigment-containing affinity group polymer copolymer, Glycolate copolymer, polyamine of unsaturated polyamine, acid copolymer alkylamine salt, high molecular weight interpolymer phosphate, copolyester with acidic pigment affinity group 6 Alkanolamine of 201109397, modification Acrylic polymer interpolymer, star structure_Polyalkyl ester containing acid pigment affinity group, star structure - polyalkyl ester containing neutral pigment affinity group, polar-acid polyester and high molecular weight alcohol Complex, insoluble pigment solvate, unsaturated polyamine homopolymer, unsaturated polyamic acid homopolymer and silicone, unsaturated polyamine and amine-containing silicone. Second embodiment of the present invention The technical means is a coating composition characterized in that: the coating (200) is mainly composed of a resin (1) plus titanium dioxide powder (2), a spherical zinc oxide semiconductor powder (3), and a zinc sulfide powder (4). ), the cerium oxide powder (5), the additive (6), and the water (8)' are blended; and the additive (6) is an industrial wax auxiliary (61), a shake control agent (62), The antifoaming agent (63) and the dispersing agent (64) are composed. According to the above coating composition, the coating (200) The resin (1) is a main raw material, the weight percentage is 20%; the titanium dioxide powder (2) is 14% by weight; the spherical oxidized semiconductor powder (3), the weight percentage is % 'the zinc sulfide Powder (4) '% by weight is 8%; the cerium oxide powder (5) is 8% by weight; the industrial wax auxiliary (61) is 5% by weight, the shake control agent (62), The weight percentage is 1%; the antifoaming agent (63) is 1% by weight; the dispersing agent (64) is 丨% by weight; the water (8) is 28% by weight. The resin (1) is one of the following: acrylic vinegar resin, styrene ester resin, aqueous halogen and acrylate polymer resin, styrene and acrylate polymer resin, water-based polyester resin 'aqueous acrylic polyester Resin, water-based polyamide and a general-purpose liquid epoxy resin. According to the above coating composition, the zinc oxide semiconductor powder (3) has a powder resistivity of 300 (Ω · cm) and an average particle diameter of 〇 · i8 (; am). 201109397 According to the above coating composition, the main component of the industrial wax auxiliary (6丨) is a mixed wax of paraffin wax and oxidized high density polyethylene, and the main solvent is water. According to the above coating composition, the main component of the shake control agent (62) is a modified urea solution, and the main solvent is N-methylrrolidone (lane p). According to the above coating composition, the antifoaming agent (63) is one of the following: an organic silicone, a polymer, a mineral oil, and a hydrophobic particle. According to the above coating composition, the dispersing agent (64) is one of the following: polyamine and alkanolamine, acrylic polymer, alkanolamine of a polymer copolyester having an acidic group, polyfunctional polymerization The alkanolamine, the pigment-containing affinity group polymer copolymer, the pigment-containing affinity cluster polymer interpolymer, and the alkylamine salt of the polyfunctional polymer. Second, according to the efficacy of the prior art: 1. The focus of the present invention - the spherical zinc oxide semiconductor powder (3) used in the coating, so that the coating (100, 200) not only has good electrostatic protection and anti-electromagnetic interference The characteristics, its transparent nature, enable the invention to overcome the conductive paint, only the monotonicity of a single color, can realize the color diversity of the conductive paint, and make the alum color, which greatly satisfies the color of the conductive paint and the increasingly rich personality of many users. The international trend of color selection, speed, and efficiency. 2. The second aspect of the present invention is that the spherical zinc oxide semiconductor powder (3) used in the coating has no problem of being able to overcome the single color problem of the coating (1〇〇, 2〇〇), and is not particularly conductive. Powder t, antimony, tin, indium and other substances harmful to the human body, safety, non-toxic, odorless, non-irritating to the skin, non-deteriorating, excellent thermal stability, antibacterial, disinfection, deodorization, self-cleaning, etc. The functions are very strong; in addition, compared with the precious metals used in general conductive powders, there is a higher price ratio, which can lower the cost of paint (100, 200). 3. The key three of the present invention is the coating (10), _ plus the addition of the first vulcanization 201109397. After the powder (4), the coating has a glamorous appearance and has a long-lasting bactericidal effect. The sulfur scale powder (4) itself Non-toxic, compared with other fine-killing, fungicides, antibacterial agents, in terms of safety properties, vulcanized powder (4) is preferable, and zinc oxide semiconductor powder (3) also has a certain anti-g, deodorizing, coating The antibacterial property is provided by the oxidized semiconductor powder (3) and the sulphide powder (4), which provide a complementary effect of double antibacterial property, which is a long-lasting structure and a high degree of safety, so that the coating is not damaged during the construction operation. The health of the user is also more environmentally friendly. 4. The focus of the present invention is that the coating of the present invention (100, 200) has a wear resistance different from that of the conventional conductive coating, and the wear resistance of the Mohs hardness of 3 provided by the carbonic acid word, the present invention The wear resistance of the coating (100, 200) is divided into two stages. Firstly, when wear occurs, the industrial soil auxiliaries floating on the surface of the paint film are first worn, which provides the slip and scratch resistance. After the scratch resistance and the friction resistance, the abrasion resistance of the Mohs hardness of 7 provided by the cerium oxide powder (5) is then abraded, and the double protection and the higher hardness allow the present The service life of the invention is longer than conventional conductive coatings. • 5. The focus of the present invention is as follows: in the coating of the invention (1〇〇, 2〇〇), the shake control agent (62) used, the modified urea solution in the main component, the mode of action is based on Its effective substance, insoluble in most coating solvents [organic solvent (7), water (8)], additives added to the coating (1〇〇, 200), precipitated to produce very fine needle crystals (cement bacillu), forming a three-dimensional network structure, optimizing the rheological characteristics, greatly improving the anti-settling during storage, and the sag resistance during construction. These network structures are reversible under very low frying force. The ground is destroyed, so that the paint (100, 200) has the characteristics of pseudoplasticity and thixotropic flow. In the closed loop pipeline with low viscosity during construction, the coating (100, 2〇〇) has a very effective anti-sedimentation flow. It also improves the conventional conductive coatings, which use the traditional type of wax paste and organic expansive soil rheological additives of 201109397, which will reduce the gloss and affect the transparency of the coating. 6. In the sixth aspect of the present invention, in the coating material (1〇〇, 2〇〇) of the present invention, by adjusting the resin (1) and the additive (6), the organic solvent (7) or water (8) can be used. As the coating solvent of the present invention, the present invention can be classified into an oily coating (1〇〇) or an aqueous coating (2〇〇) without affecting the main function, so that the application range of the present invention is further improved. [Embodiment] The following is a detailed description of the following embodiments according to the embodiments shown in the drawings: First Embodiment: FIG. 1 is a block diagram showing the first embodiment of the present invention. The figure discloses a coating composition characterized in that: the coating (100) is mainly composed of a resin (1) plus a dioxide powder (2), a spherical zinc oxide semiconductor powder (3), and a zinc sulfide powder (4). ), cerium oxide powder (5), additive (6), and organic solvent (7) are blended; and the additive (6) is made of industrial wax auxiliaries (61) (Wax-Auxilliaries), shaken Control agent (62) (Thixotropic Agent & Anti settling), defoamer (63) (Defoamer), and dispersant (64) (Dispersant). In the above, in the coating material (100), the resin (1) is a main raw material, and the weight percentage is 20%; the titanium oxide powder (2) is 14% by weight; the spherical oxidized semiconductor powder (3) , the weight percentage is 14%; the zinc sulfide powder (4) is 8% by weight; the cerium oxide powder (5) is 8% by weight; the industrial wax auxiliary (61) is 5% by weight The shake control agent (62) is 1% by weight; the antifoaming agent (63) is 1% by weight; the dispersant (64) is 1% by weight; the organic solvent (7), 201109397 weight percentage is 28%. Among them, through the addition of various materials, exerting their respective advantages and uses, and mixing in the most appropriate and economical ratio, to achieve the object of the present invention, the advantages are as follows: [1] Resin a), coating film Type is used. [2] Titanium dioxide powder (2), also known as titanium dioxide (Titaninm dioxide), can provide - coating opacity (hiding two and organic binders, with higher stability, There is no good chemical reaction 'with good white brightness. Another important reason is that titanium dioxide can absorb ultraviolet light and can have a large degree of durability as a coating. [3] Spherical zinc oxide The semiconductor powder (3) has high activity, has the function of shielding infrared rays and ultraviolet rays, and can provide a conductive ability and a sterilizing ability, and can more obviously improve the hiding power and the coloring power of the product, and is a transparent powder. It has no primary color, so it can be used together with other pigments. It can realize the color diversity of conductive coatings and produce a variety of bright colors. It can meet the needs of many users for the color of conductive coatings, and become more and more personalized, bright and efficient. The international trend of color selection [4] vulcanized powder (4), Mohs hardness of 3, can provide an anti-bacteria, sterilization (sterilize) energy It has a long-acting bactericidal effect and is flawless. Compared with other insecticides, fungicides and antibacterial agents, in terms of safety properties, the vulcanized powder (4) is preferable and can be combined with the oxidized semiconductor powder (3). Provides a complementary double antibacterial effect. [5] Silicon dioxide, silicon dioxide, Si〇2 content of about 99. 2%, pH = 7, Mohs hardness of 7, molecular shape is hexagonal The crystal system ' provides anti-caking, anti-sagging (protect sag), emulsification, fluidization, 201109397 extinction, support, suspension, thickening, thixotropic and other functions, successfully applied in coatings The main performance indicators of the exterior paints have been greatly improved. For example, the scrub resistance of exterior paints can be increased from the original 1〇(10) to more than 10,000 times, artificially accelerating weather aging (aging ) and artificial radiation exposure aging time 'from the original 250 hours (pulverized grade 1, color change 2), increased to more than 600 hours (no powder, no change in paint film, color difference 4 8), in addition to the film and The wall joint strength 'is greatly increased, and the film hardness is significantly increased. It can provide a higher wear resistance and improve the self-cleaning ability of the surface. [6] The industrial wax additive (61) in the additive (6) makes the water repel lency and abrasion resistance of the coating. (rub resistance), anti-blocking (anti-blocking), and can increase the slip of the surface. [7] The shake modifier (62) in the additive (6) enables the paint to resist settling (anti settling) ), anti-sagging (protect sag) [8] Defoamer (63) in additive (6) for defoaming and defoaming of paint. [9] The dispersant (64) in the additive (6) is used for dispersing the coating [10] organic solvent (7) (organic solvent) for mixing various raw materials. In the above, the resin (1) is one of the following: a long oil type alkyd resin, a medium oil type alkyd resin, a short oil type alkyd resin and a nitrocellulose mixed resin, a short oil type alkyd resin and a melamine urea mixed. Resin, short oil type alkyd resin and trimeric amine mixed tree sap, this ethylene resin, styrene and acetoacetate polymer resin, thermoplastic acrylic resin, saturated polyester and isocyanate mixed resin, saturated poly Ester and nitrocellulose mixed resin, alkyd polyol and isocyanate mixed resin, alcohol blended polyol and phosphatized cellulose mixed resin, acrylic polyol and isocyanate mixed resin, acrylic polyol and nitrocellulose mixed resin, moisture hardening Polyurethane resin, epoxy resin and denatured amine mixed resin, epoxy resin and polyamine blending 12 201109397 Resin, epoxy resin and polyamine polyamide resin, epoxy resin and denatured cyclic aliphatic amine mixed resin , epoxy resin and modified aromatic amine mixed resin, organic resin, dream modified alkyd resin, enamel modified epoxy resin, denatured dioxide stone , Denatured silicone rubber resin, silicon denatured acrylic resin, chlorinated rubber resin, a fluorocarbon resin and non-yellowing polyisocyanate mixed resin, polyvinylidene fluoride resin ethylene. Among them, by using different resin (1) raw materials, the coating material (100) of the present invention can be matched with other raw materials, conforms to the specifications of the oily coating, and can increase the application range, and allows consumers to have more choices. In the above, the main component of the industrial wax auxiliary (61) is a synthetic wax, and the main solvent is the paint solvent No. 100. Further, the above-mentioned antifoaming agent (63) is one of the following: silicone, polymer. Among them, because the composition of the coating (100) is a composition of an oily coating, the combination of various industrial wax auxiliaries (61) and antifoaming agent (63) described above can be used to conform to the coating (1〇〇). ) Use and use. In the above, the dispersing agent (64) is one of the following: unsaturated polyamine hydrazine and low molecular acid polyester, high molecular polyamine and alkylamine, high molecular polyamine and polyamine amine, long bond Polyamine amides and polar acid esters, acid group-containing polymers, copolyesters having pigment affinity groups, hydroxy-functional carboxylic acid esters, high molecular weight alkyl alcohol aminoguanamines, high acid-containing pigment affinity groups Molecular copolymer, basic pigment affinity group polymer copolymer, pigment-containing affinity group polymer copolymer, acrylic acid copolymer, polyamine of unsaturated polyamine, acid copolymer compound amine salt, High molecular weight copolymer carboxylic acid silicate, cocopolyester with acid pigment affinity group, alcoholic amine copolymer, modified acrylic polymer copolymer, star structure - polyglycol ester containing acid pigment affinity group, star Type structure - polyalkyl ester containing neutral pigment affinity group, polar-acidic poly-broth and high molecular weight alcohol complex, insoluble pigment solvate, unsaturated polyamine 201109397 homopolymer, unsaturated polyamine Homopolymers and silicones, unsaturated polyamines and amines - contain organic silicon. Among them, because the composition of the coating (1〇〇) is a composition of an oily coating, the various dispersing agents (64) described above can be used to meet the use and use of the coating (1〇〇) and increase The scope of application of the present invention. Second Embodiment: FIG. 2 is a block diagram showing a second embodiment of the present invention. The figure discloses a coating composition characterized in that: the coating (200) is mainly composed of a resin (1) plus titanium dioxide powder, a spherical zinc oxide semiconductor powder (3), a zinc sulfide powder (4), two The cerium oxide powder (5), the additive (6), and the water (8) are blended; and the additive (6) is an industrial wax auxiliary (61), a shake control agent (62), and an antifoaming agent. (63), and a dispersant (64). Further, in the above coating (200), the resin (1) is a main raw material, and the weight percentage is 20%; the titanium oxide powder (2) is 14% by weight; the spherical zinc oxide semiconductor powder (3) 'The weight percentage is 14%; the zinc sulfide powder (4) '% by weight is 8%; the dioxide dream powder (5), the weight percentage is 8%; the industrial soil adjuvant (61), the weight percentage is 5% The shake control agent (62) is 1% by weight; the antifoaming agent (63) is 1% by weight; the dispersant (64) is 1% by weight; the water (8), weight The percentage is 28%, among which, by adding various materials, exerting their respective advantages and uses' and mixing them in the most appropriate and economical ratio to achieve the object of the present invention, the advantages of which are as follows: [1] The above-mentioned resin (1), titanium dioxide powder (2), zinc oxide semiconductor powder (3), zinc sulfide powder (4), cerium oxide powder (5), and additives (6) 201109397, a shake control agent (62) ), the advantages of the antifoaming agent (63) and the dispersing agent (64), and the advantages and contents described in the foregoing first embodiment . [2] The industrial wax auxiliaries (61) in the additive (6), the coating has water repellency, rub resistance, black heel resistance, and anti-sticking resistance. (anti blocking), and can increase the surface slip (slip). [3] Water (8), for mixing various raw materials. The above-mentioned resin (1) is one of the following: acrylate resin, styrene ester resin, aqueous halogen and acrylate polymer resin, styrene and acrylate polymer resin, water-based polyester resin, water-based acrylic polymerization Ester resin, water-based polyamide and general-purpose liquid epoxy mixed resin. Among them, by using different resin (1) raw materials, the coating (200) of the present invention can be combined with other raw materials, conforms to the specifications of water-based coatings, and can increase the application range, and allows consumers to have more choices. In the above, the main component of the industrial wax auxiliary (61) is a mixed wax of paraffin wax and oxidized high density polyethylene, and the main solvent is water. Further, in the above, the antifoaming agent (63) is one of the following: silicone, polymer, mineral oil, and hydrophobic particles. Among them, because the composition of the coating (200) is a composition of an aqueous coating, the combination of various industrial wax additives (61) and antifoaming agent (63) described above can be used to conform to the coating (200). Use and place of use. In the above, the dispersing agent (64) is one of the following: a polyamine and an alkanolamine, an acrylic polymer, an alkanolamine of a polymer copolyester having an acidic group, and an alkane of a polyfunctional polymer. An alcohol amine, a pigment-containing affinity group polymer copolymer, a pigment-containing affinity cluster polymer interpolymer, and a pyro- and amine-based salt of a polyfunctional polymer. ' Among them, because the composition of the coating (200) is a group of water-based coatings 15 201109397, it is possible to use the various dispersing agents (64) described above to meet the use and use of the coating (200) and increase The scope of application of the present invention. In the above two embodiments, the main component of the shake control agent (62) is a modified urea solution, and the main solvent is N-methyl valerone (cis p). Among them, it has the characteristics of small dosage, good stability and other influence on the coating. Its action mode is based on its effective substance, and it is insoluble in most coating solvents [organic solvent (Ό, water (8)]. When the shake control agent (62) is added as an auxiliary agent into the paint (1〇〇, 2〇〇), it will precipitate to produce very fine needle crystals to form a three-dimensional network structure. Thixotropy flow properties can be produced to prevent settling and improve sag resistance. For a long time, these network structures, under very low shear forces, are sufficiently reversibly destroyed, thus giving the coating (100, 200) The characteristics of pseudoplastic and thixotropic flow, even in the closed loop pipeline with low viscosity during construction, the coating (100, 200) still has a very good anti-sediment rheological effect. Furthermore, it can improve the conventional knowledge. Conductive coatings, which use conventional wax pastes and organic expansive soil rheological additives, which reduce the gloss and affect the transparency of the coatings (1〇〇, 2〇〇). In the middle of the oxidation The powder has a powder resistivity of S300 (Q · cm) and an average particle diameter of 〇. Among them, the zinc oxide semiconductor powder (3), due to the grain refinement, its surface electronic structure and crystal gambling The change has the characteristics that the macro-narrow body does not have, the surface effect, the volume effect, the quantum size effect and the Wei thief effect, and the high permeability of the monthly n-dispersion, but also because of the fineness of the zinc oxide impurities, and the half-body Under the m, it has higher conductivity than the bulk zinc oxide, so it can be used as a coating for antistatic and anti-electromagnetic interference (100, the moon 匕 is not inferior to the conventional conductive coating using precious metals) The protective effect 16 201109397 'At the same time its color is better than the commonly used conductive material carbon black, so the application can be more extensive. Secondly, zinc oxide semiconductor powder (3), in addition to the antibacterial effect of traditional zinc oxide ' due to particle size The fineness, so it has the small size effect, surface interface effect and quantum size effect unique to fine particles; zinc oxide semiconductor powder (3), in terms of antibacterial effect: [A] large specific surface area, and traditional inorganic antibacterial agent The ratio can be greatly reduced by 10% to 20% of the amount of the conventional inorganic antibacterial agent. [B] The number of surface atoms of the zinc oxide semiconductor powder (3) is much larger than that of the conventional particle 'surface atom due to the lack of adjacent coordination atom With high energy', it can enhance the affinity of zinc oxide and bacteria to improve the efficiency of sterilization. [C] For zinc oxide semiconductor powder (3), the particle is fine, which can greatly improve the photocatalytic effect under light conditions. Generates electronic transitions and transfers energy to generate electrons and holes on the surface of the ions. When contacted with water and oxygen in the environment, negative oxygen ions and OH-ions are generated. Negative oxygen ions have strong bactericidal power' while 〇H- Ions react with most organic substances, causing them to decompose and enhance bactericidal power. When used in coatings (100, 200), they can make their products self-cleaning. Furthermore, the oxidized semiconductor powder (3) is also an electronic structure of a semiconductor catalyst 'under light riding' as a photon having a certain energy, or a photon having more than 14 conductors with a quantity of Eg, when injecting a semiconductor, A == price_excitation band. Leave a hole; the excited state of the conduction band electrons and strips, _recombination, age input energy and heat, electrons are captured in the surface state of the material, the price State electronic transition _ belt, price belt mu environment towel bribe base, grabbed over, make secret Wei radicals, = strong oxidants, and complete the degradation of organic matter (or gas), killing germs and diseases. From this, it can be seen that the coating material (10), _ of the present invention, through the addition, the spherical zinc oxide semiconductor powder (3) of the 201109397, the zinc sulfide powder (4), the cerium oxide powder (5), and the coating (100, 200) With electrostatic protection and anti-electromagnetic interference performance, it has sufficient all-round safety, can reduce cost, improve hardness, increase antibacterial effect, and solve the problem of single color tone, and cooperate with industrial wax additive (61) and The shake control agent (62) further improves the slip (scratch, scratch resistance, abrasion resistance, anti-settling, sag resistance, anti-precipitation, etc. of the coating (1〇〇, 2〇〇), compared with In today's conventional conductive coatings, it is more effective, practical and industrially usable. The structure, features and effects of the present invention have been described in detail above based on the embodiments shown in the drawings. 'Because of the novelty and progressive requirements, the invention patent application is filed according to law, but the above description is only a preferred embodiment of the present invention. For example, the present invention is not limited by the scope of the invention, and modifications that are in accordance with the meaning of the present invention are intended to be within the scope of the invention as long as they are within the scope of the invention. 18 201109397 [Simple description of the drawings] Fig. 1 is a block diagram showing the composition of the first embodiment of the present invention. Figure 2 is a block diagram showing the composition of a second embodiment of the present invention. [Explanation of main components] 1 Resin 2 Titanium dioxide powder 3 Zinc oxide semiconductor powder 4 Zinc sulphide powder 5 Ceria powder 6 Additive 61 Industrial wax auxiliaries 62 Shake control agent 63 Defoamer 64 Dispersant 7 Organic solvent 8 Water 100 Paint 200 coating