201108761 六、發明說明： 【發明所屬之技術領域】 [0001] 本發明涉及一種音圈骨架及使用該音圈骨架的揚聲器。 【先前技術】 [0002] 揚聲器係將電能轉化為機械能的電子元件，應用廣泛， . 如電話、移動通訊終端、電腦、電視機、盒式磁帶、聲 • 音設備和汽車等。 [0003] 先前技術中的揚聲器大部分採用電動式揚聲器。電動式 q 揚聲器通常包括一音圈、一音圈骨架（Bobbin)、一磁 場系統及一振動膜。所述音圈纏繞於音圈骨架一端的週 邊。所述音圈骨架與振動膜相連接。通過固定於音圈骨 架上的音圈於磁場系統產生的磁場下的運動，推動振動 膜振動並發出聲波。 [0004] 揚聲器的音量係評價揚聲器優劣的一個重要指標。揚聲 器的音量與輸入功率及電聲轉換效率相關。當輸入功率 越大，電聲轉換效率越高，揚聲器發出的音量越大。然 〇 而，當輸入功率增大時，揚聲器中的元件如音圈骨架及 與音圈骨架相連的振動膜易發生變形甚至破裂，從而使 發出的聲音產生失真。故，揚聲器中各元件的強度係決 定其額定功率的因素。額定功率即不使揚聲器產生失真 的輸入功率。另外，揚聲器的電聲轉換效率與揚聲器中 的元件的重量尤其係單位面積振動膜的重量及推動振動 膜振動的音圈骨架的重量有關。單位面積振動膜的重量 及推動振動膜振動的音圈骨架的重量越輕，則使振動膜 產生振動所消耗的能量越小，揚聲器的電聲轉換效率越 098127655 表單編號A0101 第3頁/共25頁 0982047431-0 201108761 高，進而相同輸入功率產生的音量越大。故，推動振動 膜振動發聲的音圈骨架的強度和重量係影響揚聲器的音 量的一重要因素。音圈骨架的重量與其厚度及密度相關 。故，音圈骨架的強度愈大，厚度及密度愈小，則揚聲 器的音量越大。一般來說，音圈骨架的比強度（強度和 密度之比）愈大，厚度愈小，則揚聲器的音量越大。 .201108761 VI. Description of the Invention: [Technical Field of the Invention] [0001] The present invention relates to a voice coil bobbin and a speaker using the voice coil bobbin. [Prior Art] [0002] A speaker is an electronic component that converts electrical energy into mechanical energy and is widely used, such as telephones, mobile communication terminals, computers, televisions, cassette tapes, sound and sound equipment, and automobiles. [0003] Most of the speakers in the prior art use electric speakers. The electric q-speaker usually includes a voice coil, a voice coil bobbin, a magnetic field system, and a diaphragm. The voice coil is wound around the circumference of one end of the voice coil bobbin. The voice coil bobbin is connected to the diaphragm. The vibration of the vibrating membrane and the sound waves are caused by the movement of the voice coil fixed on the voice coil skeleton under the magnetic field generated by the magnetic field system. [0004] The volume of the speaker is an important indicator for evaluating the pros and cons of the speaker. The volume of the speaker is related to the input power and the electroacoustic conversion efficiency. The higher the input power, the higher the electro-acoustic conversion efficiency and the louder the speaker emits. However, when the input power is increased, components in the speaker such as the voice coil bobbin and the diaphragm attached to the voice coil bobbin are liable to be deformed or even broken, thereby causing distortion of the emitted sound. Therefore, the strength of each component in the loudspeaker is a factor in determining its power rating. The rated power is the input power that does not distort the speaker. In addition, the electroacoustic conversion efficiency of the speaker is related to the weight of the components in the speaker, in particular, the weight of the diaphragm per unit area and the weight of the voice coil bobbin that urges the vibration of the diaphragm. The lighter the weight of the vibrating membrane per unit area and the weight of the voice coil bobbin that pushes the vibrating membrane vibrating, the smaller the energy consumed to vibrate the vibrating membrane, the more the electroacoustic conversion efficiency of the speaker is 098127655 Form No. A0101 Page 3 of 25 Page 0982047431-0 201108761 is high, and the volume produced by the same input power is greater. Therefore, the strength and weight of the voice coil bobbin that promotes the vibration of the vibrating membrane are an important factor affecting the volume of the speaker. The weight of the voice coil bobbin is related to its thickness and density. Therefore, the greater the strength of the voice coil skeleton, the smaller the thickness and density, and the louder the volume of the speaker. In general, the greater the specific intensity (intensity to density ratio) of the voice coil bobbin, the smaller the thickness, the louder the speaker. .
[0005] 先前的音圈骨架的材料通常採用紙、布、聚合物或者複 合材料等。然而，先前的音圈骨架受材料的比強度的限 制，其輸入功率無法進一步提高。一般的微型揚聲器的 〇 輸入功率僅為0.3 W~0.5W。另一方面，先前的音圈骨 架欲達到一定的比強度，在材料密度一定的情況下，必 然要求其具有較大的強度，從而使其具有較大的厚度， 進而導致音圈骨架的重量較大，使揚聲器的電聲轉換效 率無法進一步提高。故，為提高輸入功率及轉換效率， 進而提高揚聲器的音量，則需要進一步提高音圈骨架的 比強度及降低音圈骨架的重量。[0005] The material of the previous voice coil bobbin is usually made of paper, cloth, polymer or composite material or the like. However, the previous voice coil bobbin was limited by the specific strength of the material, and its input power could not be further improved. The input power of a typical micro speaker is only 0.3 W~0.5W. On the other hand, the previous voice coil skeleton is intended to achieve a certain specific strength. When the material density is constant, it is inevitably required to have a large strength, so that it has a large thickness, which in turn leads to a weight of the voice coil skeleton. Large, so the acoustic conversion efficiency of the speaker can not be further improved. Therefore, in order to increase the input power and conversion efficiency, and thereby increase the volume of the speaker, it is necessary to further increase the specific strength of the voice coil bobbin and reduce the weight of the voice coil bobbin.
【發明内容】 U[Summary of the Invention] U
[0006] 有鑒於此，確有必要提供一種具有較大的比強度且重量 較輕的音圈骨架及應用該音圈骨架的揚聲器。 [0007] 一種音圈骨架，其中，所述音圈骨架包括一紙基體及分 散於該紙基體中的複數個奈米碳管。 [0008] —種音圈骨架，其中，所述音圈骨架為一奈米碳管紙圍 成的一中空管狀結構。 [0009] 一種揚聲器，其包括：一音圈；一音圈骨架，所述音圈 0982047431-0 098127655 表單編號A0101 第4頁/共25頁 201108761 [0010] ο [0011] ο 設置於該音圈骨架上；一振動膜，該振動膜與所述音圈 骨架一端相連接；一定心支片，該定心支片套設於所述 音圈骨架上；及一磁場系統，該磁場系統具有一磁場間 隙，所述音圈設置於所述磁場間隙中；其中，所述音圈 骨架包括一紙基體及分散於該紙基體中的複數個奈米碳 管。 一種揚聲器，其包括：一音圈；一音圈骨架，所述音圈 設置於該音圈骨架上；一振動膜，該振動膜與所述音圈 骨架一端相連接；一定心支片，該定心支片套設於所述 音圈骨架上；及一磁場系統，該磁場系統具有一磁場間 隙，所述音圈設置於所述磁場間隙中；其中，所述音圈 骨架為一奈米碳管紙圍成的一中空管狀結構。 與先前技術相比較，本發明提供的音圈骨架及使用該音 圈骨架的揚聲器具有以下優點：第一，由於奈米碳管具 有優異的強度，故將奈米碳管均勻分散於音圈骨架的基 體中，可提高基體的比強度或在保持強度不變的條件下 可減小音圈骨架的厚度，從而減小音圈骨架的重量。第 二，由於奈米碳管具有較小的密度，將奈米碳管均勻分 散於音圈骨架的基體中，在維持甚至提高音圈骨架的強 度的同時減小音圈骨架的重量，從而減小揚聲器的重量 ，尤其在微型揚聲器中，該效果更加明顯。 [0012] 098127655 【實施方式】 下面將結合附圖對本發明實施例提供的音圈骨架及使用 該音圈骨架的揚聲器作進一步的詳細說明。 請參閱圖1及圖2，本發明實施例提供一種音圈骨架100。 表單編號Α0101 第5頁/共25頁 0982047431-0 [0013] 201108761 所述音圈骨架100為中空管狀結構。所述音圈骨架100的 直徑與長度不限，可根據實際需要製備。所述音圈骨架 100管壁的厚度可大於等於1微米且小於等於2毫米。所述 音圈骨架100採用奈米碳管紙製作，該奈米碳管紙包括一 紙基體106及分散於該紙基體106中的複數個奈米碳管 108。 [0014] 所述紙基體106包括各種纖維材料及添加材料。所述纖維 材料可包括木纖維、碳纖維、玻璃纖維、尼龍纖維、聚 丙烯纖維、棉纖維及竹纖維中的一種或多種。所述添加 0 材料可包括半纖維素、木素、樹脂、色素、果膠和灰分 等物質中的一種或多種。應當指出的係，其他任何雖未 記載於本申請的造紙用的纖維材料及添加材料，採用本 發明構思用於音圈骨架100的，皆應在本發明保護範圍之 内。 [0015] 所述奈米碳管108均勻分散於紙基體106申。進一步，所In view of the above, it is indeed necessary to provide a voice coil bobbin having a large specific strength and a light weight, and a speaker to which the voice coil bobbin is applied. [0007] A voice coil skeleton, wherein the voice coil bobbin includes a paper substrate and a plurality of carbon nanotubes dispersed in the paper substrate. [0008] A voice coil skeleton, wherein the voice coil bobbin is a hollow tubular structure surrounded by a carbon nanotube paper. [0009] A speaker comprising: a voice coil; a voice coil skeleton, the voice coil 0992047431-0 098127655 Form No. A0101 Page 4 / Total 25 pages 201108761 [0010] ο [0011] ο set in the voice coil a vibrating membrane, the vibrating membrane is connected to one end of the voice coil bobbin; a concentric segment, the centring segment is sleeved on the voice coil bobbin; and a magnetic field system, the magnetic field system has a a magnetic field gap, the voice coil is disposed in the magnetic field gap; wherein the voice coil bobbin comprises a paper substrate and a plurality of carbon nanotubes dispersed in the paper substrate. A speaker comprising: a voice coil; a voice coil bobbin, the voice coil is disposed on the voice coil bobbin; a vibrating membrane, the vibrating membrane is connected to one end of the voice coil bobbin; a centering piece is sleeved on the voice coil bobbin; and a magnetic field system, the magnetic field system has a magnetic field gap, and the voice coil is disposed in the magnetic field gap; wherein the voice coil skeleton is one nanometer A hollow tubular structure surrounded by carbon tube paper. Compared with the prior art, the voice coil bobbin provided by the present invention and the speaker using the voice coil bobbin have the following advantages: First, since the carbon nanotube has excellent strength, the carbon nanotube is uniformly dispersed in the voice coil bobbin. In the matrix, the specific strength of the substrate can be increased or the thickness of the voice coil bobbin can be reduced under the condition of maintaining the strength, thereby reducing the weight of the voice coil bobbin. Second, because the carbon nanotubes have a small density, the carbon nanotubes are uniformly dispersed in the matrix of the voice coil bobbin, and the weight of the voice coil bobbin is reduced while maintaining or even increasing the strength of the voice coil bobbin. The effect of the small speakers, especially in miniature speakers, is even more pronounced. [0012] 012127655 [Embodiment] A voice coil bobbin and a speaker using the voice coil bobbin provided by the embodiment of the present invention will be further described in detail below with reference to the accompanying drawings. Referring to FIG. 1 and FIG. 2 , an embodiment of the present invention provides a voice coil bobbin 100 . Form No. Α0101 Page 5 of 25 0982047431-0 [0013] 201108761 The voice coil bobbin 100 is a hollow tubular structure. The diameter and length of the voice coil bobbin 100 are not limited and can be prepared according to actual needs. The thickness of the wall of the voice coil bobbin 100 may be greater than or equal to 1 micrometer and less than or equal to 2 millimeters. The voice coil bobbin 100 is made of carbon nanotube paper, and the carbon nanotube paper comprises a paper substrate 106 and a plurality of carbon nanotubes 108 dispersed in the paper substrate 106. [0014] The paper substrate 106 includes various fibrous materials and additive materials. The fibrous material may include one or more of wood fiber, carbon fiber, glass fiber, nylon fiber, polypropylene fiber, cotton fiber, and bamboo fiber. The additive 0 material may include one or more of hemicellulose, lignin, resin, pigment, pectin, and ash. It should be noted that any other fibrous material and additive material for papermaking which is not described in the present application, which is intended for the voice coil bobbin 100, should be within the scope of the present invention. [0015] The carbon nanotubes 108 are uniformly dispersed in the paper substrate 106. Further,
述奈米碳管108表面可帶有功能團。該功能團包括羧基 (-COOH)、羥基（-OH)、醛基（-CHO)及氨基（-NH2)等中 1J 的一種或多種。該功能團可形成於奈米碳管108管壁上。 可理解，該功能團為親水性功能團，使奈米碳管108在泡 料過程中可更好地分散於紙漿中。所述奈米碳管108可為 單壁奈米碳管、雙壁奈米碳管及多壁奈米碳管中的一種 或其任意組合。其中，所述單壁奈米碳管的直徑為0. 5奈 米~50奈米，雙壁奈米碳管的直徑為1. 0奈米〜50奈米， 多壁奈米破管的直徑為1.5奈米〜50奈米。所述奈米碳管 108的長度不限。優選地，所述奈米碳管108的長度大於 098127655 表單編號A0101 第6頁/共25頁 0982047431-0 201108761 200微米。可理解，採用長度大於200微米奈米碳管108 可有效發揮奈米碳管108的增強作用，提高音圈骨架100 的強度。本實施例中，所述奈米碳管108的長度為200微 米〜900微米。 [0016] Ο ο 所述紙基體106在整個音圈骨架100中的質量百分比含量 為10%〜9 9. 9%，所述奈米碳管108在整個音圈骨架100中 的質量百分比含量為0. 1%〜90%。優選地，所述紙基體 106的質量百分比含量為60%~90%，所述奈米碳管108的 質量百分比含量為10%〜40%。例如：所述紙基體106可為 木纖維與果膠，在整個音圈骨架100中的質量百分比含量 可為70%，所述奈米碳管108在整個音圈骨架100中的質 量百分比含量可為30% ;所述紙基體106的材料為碳纖維 與樹脂，所述紙基體106在整個音圈骨架100中的質量百 分比含量可為80%，所述奈米碳管108在整個音圈骨架 100中的質量百分比含量可為20% ;所述紙基體106的材 料為聚丙烯纖維與果膠，所述紙基體106名整個音圈骨架 100中的質量百分比含量可為90%，所述奈米碳管108在 整個音圈骨架100申的質量百分比含量可為10%。本實施 例中，所述紙基體106為木纖維，所述紙基體106在整個 音圈骨架100中的質量百分比含量為85%，所述奈米碳管 108在整個音圈骨架100中的質量百分比含量可為15%。 [0017] 所述音圈骨架100可通過熱壓的方式直接形成或先製備一 奈米碳管紙，再將該奈米碳管紙卷成一中空管狀結構。 請參見圖3，本發明進一步提供一種所述音圈骨架100的 製備方法，其具體包括以下步驟： 098127655 表單編號Α0101 第7頁/共25頁 0982047431-0 [0018] 201108761 [0019] 步驟一：打漿。 [0020] 將造紙用的纖維材料放入盛有水的打漿機内，進行打漿 細化得到紙漿。所述打漿細化的時間可大於5小時。本實 施例中，將2 0克的木纖維與1 5 0 0克的水放入打漿機内打 漿細化10小時。可理解，打漿前還可採用氫氧化鈉和硫 化鈉混合液對纖維材料進行蒸煮。在蒸煮過程中，因為 藥液作用比較和緩，纖維不會受強烈侵蝕，故強韌有力 ，所製成的紙的耐折、耐破和耐撕裂強度極好。 [0021] 進一步，本實施例中還可將打漿細化後的紙漿放入一密 閉容器内施加一高壓，然後瞬間打開密閉容器使其降至 常壓，壓力急劇變化可促使紙漿内的纖維裂解細化。 [0022] 步驟二：泡料。 [0023] 將打漿細化後的紙漿放入一泡料池中，加入奈米碳管及 添加材料後，浸泡一段時間。 [0024] 所述奈米碳管可通過電弧放電法、鐳射蒸發法或者化學 氣相沈積法等方法製備。本實施例中，通過化學氣相沈 積法生長奈米碳管陣列，然後將該奈米碳管陣列中的奈 米碳管刮落。由於奈米碳管陣列中的奈米碳管定向排列 而沒有相互纏繞，故，有利於奈米碳管於溶液中分散。 本實施例中，將3. 53克的奈米碳管加入到打漿細化後的 紙漿中浸泡1天~ 3天。 [0025] 另外，將奈米碳管加入到漿料中之前，可進一步包括一 對上述奈米碳管提純的步驟。所述提純奈米碳管的方法 包括以下步驟：在空氣流中加熱奈米碳管以除去無定型 098127655 表單編號A0101 第8頁/共25頁 0982047431-0 201108761 [0026] Ο [0027] [0028] ❹ [0029] 碳；用濃酸浸泡該奈米碳管以除去金屬催化劑及反復洗 滌過濾得到提純的奈米碳管。 本實施例中，將奈米碳管放於350°C的爐中，在空氣流中 加熱2小時以除去奈米碳管中殘留的無定型碳；將奈米碳 管浸泡於36%的濃鹽酸中約1天，除去奈米碳管中殘留的 金屬催化劑；將鹽酸浸泡後的奈米碳管進行離心分離； 將分離所得的奈米碳管沉澱物用去離子水反復洗滌；再 將洗滌後的奈米碳管沉澱物經由0. 2 m m孔徑的聚四氟乙烯 膜過濾，得到提純的奈米碳管。 提純的目的主要係除去奈米碳管中殘留的無定型碳和金 屬催化劑等雜質。通過提純，可得到純淨的奈米碳管。 進一步，將奈米碳管提純之後，還包括一對奈米碳管功 能化處理的步驟。所述對奈米碳管功能化處理的方法包 括以下步驟：將提純的奈米碳管在強酸中回流及清洗過 濾得到帶有功能團的奈米碳管。 所述強酸包括濃硫酸、濃硝酸或濃鹽酸中的一種或幾種 。功能化處理的目的係使奈米碳管表面引入功能團。按 上述功能化方法處理後的奈米碳管，在管壁上引入親水 性的功能團。所述功能團包括羧基（-COOH)、羥基（-OH) 、醛基（-CHO)及氨基（-NH2)等中的一種或多種。在奈米 碳管管壁上引入親水性的功能團後的奈米碳管在泡料過 程中可更均勻地分散於紙漿中。 本實施例中，將提純後的奈米碳管放置於500ml圓底燒瓶 中，量取150ml濃硫酸和濃硝酸混合液（濃硫酸和濃硝酸 098127655 表單編號A0101 第9頁/共25頁 0982047431-0 [0030] 201108761 的體積為3:1)倒入圓底燒報内’回流反應4小時〜20小時 。該回流反應過程使奈米碳管表面帶有官能團。然後， 將反應後的液體倒入水中，再經濾紙過濾後得到一奈米 碳管濾餅。最後，用去離子水將該奈米碳管濾餅洗ipH 值為中性，得到羧基化的奈米碳管。 [0031] [0032] [0033] 步驟三：抄紙。 將浸泡後的紙漿通過抄紙工序打撈至金屬模具或配置於 金屬模具的篩網上，排除水分，堆積材料，形成奈米碳 管紙預製體。然後將該奈米破管紙預製體自然晾乾或供 乾，得到一奈米碳管紙。 請參見圖4，本實施例中，將浸泡後的紙漿2 〇 2裝入—抄 紙裝之20的計量槽200内。通過供給管204將紙聚202引 入一抄紙槽206内。通過第一控制閥2〇8可控制進入抄紙 槽206内紙襞202的量’從而控制奈米碳管紙預製體的厚 度。向抄紙槽206内加入適量的水稀釋紙槳202，並授摔 均勻。通過稀釋可使級^漿〗!^分散更均勻，並在之後的步 驟中均勻沈積於抄紙模具214上。打開第二控制閥21〇， 使水通過排列水管212排出抄紙槽2〇6，同時使紙漿2〇2 沈積於抄紙槽206内的抄紙模具214上。可理解，本實施 例中可將稀釋好的紙漿2〇2直接裝入一計量槽2〇〇内，然 後通過第一控制閥208控制，使一定量的紙漿2〇2進入抄 紙槽206内。 可理解，本實施例中還可將紙漿202用水稀釋後裝入一容 器（圖未示）中，將一抄紙網（圖未示）放入該容器中 098127655 表單編號A0101 第10頁/共25頁 0982047431-0 [0034] 201108761 再取出，從而使紙漿202沈積於該抄紙網上以形成奈米碳 管紙預製體。 [0035] 進一步，本實施例可通過熱壓工序將奈米碳管紙預製體 加熱加壓，使剩下的水分蒸發，得到一奈米碳管紙。本 實施例中，將奈米碳管紙預製體加熱至100°C~200°C範圍 内，並施加1 000牛頓〜6000牛頓的壓力保持10秒~100秒 ，得到一奈米碳管紙。 [0036] 步驟四：成型。 〇 Ο [0037] 將該奈米碳管紙卷成中空管狀結構。本實施例中，先提 供一圓柱體，然後將一奈米碳管紙環繞設置於該圓柱體 上。所述奈米碳管紙可多層環繞設置於該圓柱體上，此 時，可在相鄰兩層奈米碳管紙之間塗敷黏結劑以使相鄰 兩層奈米碳管紙牢固結合。可理解，本實施例中，也可 通過選擇抄紙模具214經過熱壓成型的工序直接製備音圈 骨架100。 [0038] [0039] 步驟五：後續處理 ；： 進一步，通過沖裁工序裁剪得到具有預定尺寸的音圈骨 架 100。 [0040] 請參見圖5及圖6，本發明實施例進一步提供一應用所述 音圈骨架100的揚聲器10。該揚聲器10包括一支架110、 一磁路系統120、一音圈130、一定心支片140、一振動 膜150及一音圈骨架100。所述支架110固定於所述磁路 系統120。所述振動膜150的一邊緣固定於所述支架110 ，中心固定於音圈骨架100上。所述定心支片140的邊緣 098127655 表單編號 Α0101 第 11 頁/共 25 頁 0982047431-0 201108761 固定於所述支架110，另通孔102套設於音圈骨架100上 。所述音圈130設置於音圈骨架100靠近所述磁路系統 120的一端之外表面，且收容於所述磁路系統120。 [0041] 所述支架110可為一錐體結構，其具有—中心孔111用於 套設所述磁路系統120，使該支架110與磁路系統120相 對固定。 [0042] 所述磁路系統120包括一導磁下板121、一導磁上板122 、一磁體123及一導磁芯枉124，所述磁體123相對的兩 端分別由同心設置的導磁下板121及導裤上板12 2所失持 。所述導磁上板122及磁體I23均為環狀结構’所述導磁 上板122及磁體123於所述磁路系統中圍成一柱形空間。 所述導磁芯柱124容置於所述柱形空間。該導磁芯柱124 與所述導磁下板121為一體，且由導磁下板121往導磁上 板122延伸。該導磁芯柱124與所述磁體123之間形成一 環形磁場間隙125用於容置:所述音圈130。所述該導磁芯 枉1 24延伸至所述中心孔111中。 [0043] 所述音圈130為揚聲器1〇的驅動單元，其設置於音圈骨架 100上。所述設置於音圈骨架1〇〇上的音圈130可容置於 所述磁場間隙125中，並於磁場間隙125中上下運動。該 音圈130為較細的導線於所述音圈骨架1〇〇上繞製而形成 ’優選地，所述導線可為漆包線。當所述音圈130接收到 音頻電信號時，該音圈130產生隨音頻電信號的強度變化 而變化的磁場’此變化的磁場與磁場間隙125中由磁路系 統120產生的磁場之間發生相互作用，迫使該音圈130產 生振動。 表單編號A0101 098127655 第12頁/共25頁 0982047431-0 201108761 [0044] 所述音圈骨架100為中空管形結構，其與所述導磁芯桎 1 24同心設置且間隔套設於所述導磁芯柱124上。所述音 圈骨架100可收容於所述磁場間隙125中。該音圈骨架 100與所述音圈130固定連接，且音圈骨架100遠離所述 磁路系統120的一端固定連接於所述振動膜150的中心位 置，從而當所述音圈骨架100隨音圈130振動時，帶動所 述振動膜150振動，從而使所述振動膜150周圍的空氣運 動，產生聲波。 [_5] 所述振動膜150為所述揚聲器1 〇的發聲單元。該振動膜 〇 150的形狀不限，與其具體應用有關，如當所述振動膜 150應用於大型揚聲器10時，該振動膜150可為一空心圓 錐體結構；當所述振動膜丨5〇應甩於微型揚聲器10時，該 振動膜150可為一圓片狀結構《所述振動膜150的頂端與 所述音圈骨架100通過黏結的方式固定連接’其另一端的 外緣與所述支架110活動連接。本實施例中，該振動骐 150為一空心圓錐體結構。 F i ）！,v' 爷‘ “， Ο [0〇46] 所述定心支片140藉#通孔102套設於所述音圈骨架100 上，該定心支片14〇的外緣固定於所述定心支架11〇靠近 所述中心孔111的一端，該定心支片140用於支持所述音 圈骨架100，且對該音圈骨架100起橫向限位的作用。該 定心支片140具有較大的彈性及強度，由於所述音圈13〇 纏繞於所述音圈骨架1〇〇，所以該音圈130於所述磁場間 隙125中可以自由地上下移動而不做橫向移動’避免該音 圈130與磁路系統120碰觸。由於所述定心支片140其設 置於磁路系統120與振動膜150之間’並將所述磁場間隙 098127655 表單編號A0101 第13頁/共25頁 0982047431-0 201108761 [0047] 1 2 5的覆蓋，妗# a 復盍故忒疋心支片140還具有防止灰塵進入該磁 場間隙12 5的作用。 =理解’應用所述音圈骨架1GG的揚聲器1G並不限於上述 、。構所述音圈骨架1GG也可應用於採用平面振動膜的微 [0048] =發明實施職供的音圈骨架及使用該音11骨架的揚！ '、有X下優點.第_，由於奈米碳管具有優異的強方 故將奈米碳★均勾分散於音圈骨架的基體中，可提違 體的比強度或在保持比強度不變的條件下可減小音匿 月架的厚度，從而減小音圈骨架的重量。第二，由於袭 米厌g具有較小的密度將奈来碳管均勻分散於音圈嘴 架的基體中，在_甚至提高音圈骨㈣鼓的同㈣ 小音圈骨架的重量’從而減小揚聲器的重量，尤其在樹 «聲器中，該效果更加明顯。第三，由於奈米碳管具 有良好㈣濕性及耐歸能，將奈料管均勻分散於音 圈骨架的基體中，使本發明實施例提供的音圈骨架也具 有良好的耐濕性及耐燃性The surface of the carbon nanotube 108 may have a functional group. The functional group includes one or more of 1J in a carboxyl group (-COOH), a hydroxyl group (-OH), an aldehyde group (-CHO), and an amino group (-NH2). The functional group can be formed on the wall of the carbon nanotube 108. It will be appreciated that the functional group is a hydrophilic functional group which allows the carbon nanotubes 108 to be better dispersed in the pulp during the soaking process. The carbon nanotubes 108 may be one of a single-walled carbon nanotube, a double-walled carbon nanotube, and a multi-walled carbon nanotube, or any combination thereof. Wherein, the single-walled carbon nanotube has a diameter of 0.5 nm to 50 nm, and the diameter of the double-walled carbon nanotube is 1.0 nm to 50 nm, and the diameter of the multi-walled nanotube is broken. For 1.5 nm ~ 50 nm. The length of the carbon nanotubes 108 is not limited. Preferably, the length of the carbon nanotubes 108 is greater than 098127655 Form No. A0101 Page 6 of 25 0982047431-0 201108761 200 microns. It can be understood that the use of the carbon nanotubes 108 having a length of more than 200 micrometers can effectively exert the reinforcing effect of the carbon nanotubes 108 and improve the strength of the voice coil bobbin 100. In this embodiment, the carbon nanotubes 108 have a length of from 200 micrometers to 900 micrometers. [0016] The mass percentage of the paper substrate 106 in the entire voice coil bobbin 100 is 10% to 9 9.9%, and the mass percentage of the carbon nanotubes 108 in the entire voice coil bobbin 100 is 0. 1%~90%. Preferably, the paper substrate 106 has a mass percentage of 60% to 90%, and the carbon nanotubes 108 has a mass percentage of 10% to 40%. For example, the paper substrate 106 may be wood fiber and pectin, and the mass percentage content in the entire voice coil bobbin 100 may be 70%, and the mass percentage of the carbon nanotube 108 in the entire voice coil bobbin 100 may be 30%; the material of the paper substrate 106 is carbon fiber and resin, the mass percentage of the paper substrate 106 in the entire voice coil skeleton 100 may be 80%, and the carbon nanotubes 108 are in the entire voice coil skeleton 100. The content of the mass percentage may be 20%; the material of the paper substrate 106 is polypropylene fiber and pectin, and the paper substrate 106 may have a mass percentage content of 90% in the whole voice coil skeleton 100, the nanometer. The carbon tube 108 may have a mass percentage of 10% throughout the voice coil bobbin 100. In this embodiment, the paper substrate 106 is wood fiber, the mass percentage of the paper substrate 106 in the entire voice coil bobbin 100 is 85%, and the mass of the carbon nanotube 108 in the entire voice coil bobbin 100 The percentage content can be 15%. [0017] The voice coil bobbin 100 may directly form or first prepare a carbon nanotube paper by hot pressing, and then roll the carbon nanotube paper into a hollow tubular structure. Referring to FIG. 3, the present invention further provides a method for manufacturing the voice coil bobbin 100, which specifically includes the following steps: 098127655 Form No. 1010101 Page 7 / Total 25 Page 0982047431-0 [0018] 201108761 [0019] Step 1: Beating. [0020] The fibrous material for papermaking is placed in a beater containing water and refined by beating to obtain a pulp. The beating refining time may be greater than 5 hours. In this embodiment, 20 grams of wood fiber and 1 500 grams of water were placed in a beater for slurry refining for 10 hours. It is understood that the fiber material can be cooked using a mixture of sodium hydroxide and sodium sulphide before beating. In the cooking process, the fiber is not strongly eroded because of the relatively gentle action of the liquid, so it is strong and strong, and the made paper has excellent folding resistance, breakage resistance and tear resistance. [0021] Further, in this embodiment, the pulp after refining and refining can be placed in a closed container to apply a high pressure, and then the closed container is instantly opened to a normal pressure, and the pressure changes rapidly to promote fiber cracking in the pulp. Refined. [0022] Step 2: Foam. [0023] The pulp after refining is placed in a bubble pool, and after adding the carbon nanotubes and adding materials, it is soaked for a while. [0024] The carbon nanotubes may be prepared by an arc discharge method, a laser evaporation method, or a chemical vapor deposition method. In this embodiment, the carbon nanotube array is grown by chemical vapor deposition, and then the carbon nanotubes in the carbon nanotube array are scraped off. Since the carbon nanotubes in the carbon nanotube array are aligned and are not entangled with each other, it is advantageous for the carbon nanotubes to be dispersed in the solution. In this embodiment, 3.53 g of carbon nanotubes are added to the pulp after pulping and refining for 1 day to 3 days. [0025] In addition, before the carbon nanotubes are added to the slurry, a step of purifying the above-mentioned carbon nanotubes may be further included. The method for purifying a carbon nanotube comprises the steps of: heating a carbon nanotube in an air stream to remove amorphous 098127655 Form No. A0101 Page 8 of 25 0982047431-0 201108761 [0026] Ο [0027] [0028 ❹ [0029] Carbon; the carbon nanotubes are soaked with concentrated acid to remove the metal catalyst and repeatedly washed and filtered to obtain a purified carbon nanotube. In this embodiment, the carbon nanotubes are placed in a furnace at 350 ° C, heated in an air stream for 2 hours to remove residual amorphous carbon in the carbon nanotubes; the carbon nanotubes are immersed in 36% thick In about 1 day in hydrochloric acid, the metal catalyst remaining in the carbon nanotubes is removed; the carbon nanotubes after the hydrochloric acid immersion are centrifuged; the separated carbon nanotube precipitates are repeatedly washed with deionized water; The resulting carbon nanotube precipitate was filtered through a 0.2 mm pore size polytetrafluoroethylene membrane to obtain a purified carbon nanotube. The purpose of purification is mainly to remove impurities such as amorphous carbon and metal catalyst remaining in the carbon nanotubes. By purifying, a pure carbon nanotube can be obtained. Further, after purifying the carbon nanotubes, a step of functionalizing a pair of carbon nanotubes is also included. The method for functionalizing the carbon nanotubes comprises the steps of: refluxing the purified carbon nanotubes in a strong acid and washing and filtering to obtain a carbon nanotube with a functional group. The strong acid includes one or more of concentrated sulfuric acid, concentrated nitric acid or concentrated hydrochloric acid. The purpose of the functionalization process is to introduce a functional group into the surface of the carbon nanotube. The carbon nanotubes treated by the above functionalization method introduce a hydrophilic functional group on the tube wall. The functional group includes one or more of a carboxyl group (-COOH), a hydroxyl group (-OH), an aldehyde group (-CHO), and an amino group (-NH2). The carbon nanotubes after introducing a hydrophilic functional group on the wall of the carbon nanotube tube can be more uniformly dispersed in the pulp during the foaming process. In this embodiment, the purified carbon nanotubes are placed in a 500 ml round bottom flask, and 150 ml of a concentrated sulfuric acid and concentrated nitric acid mixture (concentrated sulfuric acid and concentrated nitric acid 098127655) Form No. A0101 Page 9 of 25 0982047431- 0 [0030] 201108761 volume is 3:1) Pour into the bottom of the burnt report 'reflow reaction 4 hours ~ 20 hours. This refluxing reaction process imparts a functional group to the surface of the carbon nanotube. Then, the reacted liquid was poured into water, and then filtered through a filter paper to obtain a carbon nanotube filter cake. Finally, the carbon nanotube filter cake was washed with deionized water and the ipH value was neutral to obtain a carboxylated carbon nanotube. [0033] Step 3: Papermaking. The soaked pulp is salvaged to a metal mold or a screen placed on a metal mold by a papermaking process to remove moisture and deposit materials to form a carbon nanotube paper preform. The nanotube paper preform is then naturally dried or dried to obtain a carbon nanotube paper. Referring to Fig. 4, in the present embodiment, the soaked pulp 2 〇 2 is loaded into the metering tank 200 of the paper-making apparatus 20. The paper poly 202 is introduced into a papermaking slot 206 through a supply tube 204. The amount of the paper cassette 202 entering the papermaking tray 206 can be controlled by the first control valve 2〇8 to control the thickness of the carbon nanotube paper preform. An appropriate amount of water-diluted paper paddle 202 is added to the papermaking tank 206, and the drop is evenly distributed. By diluting, the dispersion can be more uniformly dispersed and uniformly deposited on the papermaking mold 214 in the subsequent steps. The second control valve 21 is opened, and the water is discharged through the arranging water pipe 212 to the papermaking tray 2〇6, while the pulp 2〇2 is deposited on the papermaking mold 214 in the papermaking tray 206. It can be understood that in the present embodiment, the diluted pulp 2〇2 can be directly loaded into a metering tank 2, and then controlled by the first control valve 208 to allow a certain amount of pulp 2〇2 to enter the papermaking tank 206. It can be understood that in this embodiment, the pulp 202 can be diluted with water and then placed in a container (not shown), and a paper net (not shown) is placed in the container. 098127655 Form No. A0101 Page 10 of 25 Page 0982047431-0 [0034] 201108761 is again removed so that pulp 202 is deposited on the papermaking web to form a carbon nanotube paper preform. [0035] Further, in this embodiment, the carbon nanotube paper preform can be heated and pressurized by a hot pressing process to evaporate the remaining water to obtain a carbon nanotube paper. In this embodiment, the carbon nanotube paper preform is heated to a temperature in the range of 100 ° C to 200 ° C, and a pressure of 1 000 Newtons to 6000 Newtons is applied for 10 seconds to 100 seconds to obtain a carbon nanotube paper. [0036] Step 4: Forming. 〇 Ο [0037] The carbon nanotube paper is rolled into a hollow tubular structure. In this embodiment, a cylinder is first provided, and then a carbon nanotube paper is placed around the cylinder. The carbon nanotube paper can be disposed on the cylinder in multiple layers. At this time, a bonding agent can be applied between two adjacent layers of carbon nanotube paper to firmly bond the adjacent two layers of carbon nanotube paper. . It can be understood that in the present embodiment, the voice coil bobbin 100 can also be directly prepared by selecting the papermaking mold 214 through the hot press forming process. [0039] Step 5: Subsequent processing; Further, a voice coil skeleton 100 having a predetermined size is obtained by a punching process. Referring to FIG. 5 and FIG. 6, an embodiment of the present invention further provides a speaker 10 to which the voice coil bobbin 100 is applied. The speaker 10 includes a bracket 110, a magnetic circuit system 120, a voice coil 130, a centering piece 140, a diaphragm 150, and a voice coil bobbin 100. The bracket 110 is fixed to the magnetic circuit system 120. An edge of the diaphragm 150 is fixed to the bracket 110 and is fixed to the voice coil bobbin 100 at the center. The edge of the centering piece 140 098127655 Form number Α0101 Page 11 of 25 0982047431-0 201108761 is fixed to the bracket 110, and the other through hole 102 is sleeved on the voice coil bobbin 100. The voice coil 130 is disposed on an outer surface of the voice coil bobbin 100 adjacent to one end of the magnetic circuit system 120 and is received in the magnetic circuit system 120. [0041] The bracket 110 can be a pyramid structure having a center hole 111 for arranging the magnetic circuit system 120 so that the bracket 110 is relatively fixed to the magnetic circuit system 120. [0042] The magnetic circuit system 120 includes a magnetically permeable lower plate 121, a magnetically conductive upper plate 122, a magnet 123, and a magnetic core 124. The opposite ends of the magnet 123 are respectively concentrically arranged. The lower plate 121 and the upper pants 12 2 are lost. The magnetically permeable upper plate 122 and the magnet I23 are both annular structures. The magnetically permeable upper plate 122 and the magnet 123 enclose a cylindrical space in the magnetic circuit system. The magnetic core stud 124 is received in the cylindrical space. The magnetic conductive core 124 is integral with the magnetic lower plate 121 and extends from the magnetic lower plate 121 to the magnetic conductive upper plate 122. An annular magnetic field gap 125 is formed between the magnetic core stud 124 and the magnet 123 for receiving: the voice coil 130. The magnetic core 枉1 24 extends into the central bore 111. [0043] The voice coil 130 is a driving unit of the speaker 1 ,, which is disposed on the voice coil bobbin 100. The voice coil 130 disposed on the voice coil bobbin 1 can be received in the magnetic field gap 125 and moved up and down in the magnetic field gap 125. The voice coil 130 is formed by winding a thinner wire on the voice coil bobbin 1'. Preferably, the wire may be an enameled wire. When the voice coil 130 receives an audio electrical signal, the voice coil 130 produces a magnetic field that varies with the intensity of the audio electrical signal. This magnetic field of the change occurs between the magnetic field generated by the magnetic circuit system 120 in the magnetic field gap 125. The interaction forces the voice coil 130 to vibrate. Form No. A0101 098127655 Page 12 of 25 0982047431-0 201108761 [0044] The voice coil bobbin 100 is a hollow tubular structure that is concentrically disposed with the magnetic core 桎 1 24 and spaced apart from the The magnetic core is 124. The voice coil bobbin 100 can be received in the magnetic field gap 125. The voice coil bobbin 100 is fixedly connected to the voice coil 130, and one end of the voice coil bobbin 100 away from the magnetic circuit system 120 is fixedly connected to a center position of the vibrating membrane 150, so that when the voice coil bobbin 100 is sounded When the ring 130 vibrates, the diaphragm 150 is driven to vibrate, thereby moving the air around the diaphragm 150 to generate sound waves. [_5] The diaphragm 150 is a sounding unit of the speaker 1 〇. The shape of the diaphragm 150 is not limited, and is related to its specific application. For example, when the diaphragm 150 is applied to the large speaker 10, the diaphragm 150 may be a hollow cone structure; when the diaphragm 丨5〇 When the micro-speaker 10 is used, the vibrating membrane 150 may be a disc-shaped structure. The top end of the vibrating membrane 150 is fixedly connected to the voice coil bobbin 100 by bonding. The outer edge of the other end and the bracket 110 are attached. Active connection. In this embodiment, the vibrating crucible 150 is a hollow cone structure. F i )! , v' 爷', Ο [0〇46] The centering piece 140 is sleeved on the voice coil bobbin 100 by the through hole 102, and the outer edge of the centering piece 14〇 is fixed to the The centering bracket 11 is adjacent to one end of the center hole 111, and the centering piece 140 is used to support the voice coil bobbin 100, and functions as a lateral limit on the voice coil bobbin 100. The centering piece 140 With greater elasticity and strength, since the voice coil 13 is wound around the voice coil bobbin 1 , the voice coil 130 can freely move up and down in the magnetic field gap 125 without lateral movement 'avoiding The voice coil 130 is in contact with the magnetic circuit system 120. Since the centering piece 140 is disposed between the magnetic circuit system 120 and the diaphragm 150, and the magnetic field gap 098127655 is shown in the form number A0101, page 13 of 25 Page 0982047431-0 201108761 [0047] The coverage of 1 2 5, 妗# a 盍 忒疋 忒疋 忒疋 支 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 140 The speaker 1G is not limited to the above, and the voice coil bobbin 1GG can also be applied to micro [0048] using a planar diaphragm. ] = Inductive implementation of the voice coil skeleton and the use of the sound 11 skeleton of the Yang! ', has X advantages. _, because the carbon nanotubes have excellent strength, so the nano carbon ★ is scattered in the sound In the matrix of the ring skeleton, the specific strength of the violation can be raised or the thickness of the moon frame can be reduced under the condition of maintaining the constant intensity, thereby reducing the weight of the voice coil skeleton. With a small density, the carbon nanotubes are evenly dispersed in the base of the voice coil holder, even increasing the weight of the same (four) small voice coil bobbin of the voice coil bone (four) drum, thereby reducing the weight of the speaker, especially in the tree In the sounder, the effect is more obvious. Thirdly, because the carbon nanotubes have good (four) wetness and resistance to resilience, the tube is evenly dispersed in the base of the voice coil bobbin, so that the sound provided by the embodiment of the present invention The ring skeleton also has good moisture resistance and flame resistance.
[0049] 綜上所述，本發财已符合發明專利之要件，遂依法提 出專利巾β $以上所述者僅為本發明之較佳實施例 ，自不能以此限制本案之巾請糊範圍。舉凡熟悉本案 技藝之人士援依本發明之精神所作之等效修飾或變化， 皆應涵蓋於以下申請專利範圍内。 【圖式簡單說明】 圖1為本發明實施例提供的音圈骨架的結構示意圖。 098127655 表單編號Α0101 第14頁/共25頁 0982047431-0 [0050] 201108761 [0051] 圖2為圖1的音圈骨架沿線I I - I I剖開的的剖面圖。 [0052] 圖3為本發明實施例提供的音圈骨架的製備方法流程圖。 [0053] 圖4為圖3中的抄紙步驟中採用的抄紙裝置的結構示意圖 [0054] 圖5為應用本發明實施例的音圈骨架的揚聲器的結構示意 圖。 [0055] 圖6為圖5所示的揚聲器的剖面圖。[0049] In summary, the present wealth has been in accordance with the requirements of the invention patent, and the above-mentioned patent towel β $ above is only a preferred embodiment of the present invention, and it is not possible to limit the scope of the case. . Equivalent modifications or variations made by those skilled in the art to the spirit of the invention are intended to be included within the scope of the following claims. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural view of a voice coil bobbin according to an embodiment of the present invention. 098127655 Form No. Α0101 Page 14 of 25 0982047431-0 [0050] FIG. 2 is a cross-sectional view of the voice coil bobbin of FIG. 1 taken along line I I - I I . 3 is a flow chart of a method for preparing a voice coil bobbin according to an embodiment of the present invention. 4 is a schematic structural view of a papermaking apparatus employed in the papermaking step of FIG. 3. [0054] FIG. 5 is a schematic structural view of a speaker to which a voice coil bobbin according to an embodiment of the present invention is applied. 6 is a cross-sectional view of the speaker shown in FIG. 5.
【主要元件符號說明】 [0056] 揚聲器 10 音圈骨架 100 紙基體 106 奈米碳管 108 支架 110 中心孔 111 磁路系統 120 導磁下板 121 導磁上板 122 磁體 123 導磁芯柱 124 磁場間隙 125 音圈 130 定心支片 140 振動膜 150 抄紙裝置 20 表單編號A0101 第15頁/共25頁 0982047431-0 098127655 201108761 計量槽 200 紙漿 202 供給管 204 抄紙槽 206 第一控制閥 208 第二控制閥 210 排水管 212 抄紙模具 214 098127655 表單編號A0101 第16頁/共25頁 0982047431-0[Main component symbol description] [0056] Speaker 10 Voice coil skeleton 100 Paper substrate 106 Carbon nanotube 108 Bracket 110 Center hole 111 Magnetic circuit system 120 Magnetic lower plate 121 Magnetic upper plate 122 Magnet 123 Magnetic core column 124 Magnetic field Clearance 125 Voice coil 130 Centering piece 140 Vibration film 150 Papermaking device 20 Form No. A0101 Page 15 / Total 25 pages 0992047431-0 098127655 201108761 Metering tank 200 Pulp 202 Supply pipe 204 Paper feed slot 206 First control valve 208 Second control Valve 210 Drain pipe 212 Papermaking die 214 098127655 Form No. A0101 Page 16 of 25 0982047431-0