TW201105510A - Composite with tack film for asphaltic paving, method of paving, and process for making a composite with tack film for asphaltic paving - Google Patents

Composite with tack film for asphaltic paving, method of paving, and process for making a composite with tack film for asphaltic paving Download PDF

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TW201105510A
TW201105510A TW98126240A TW98126240A TW201105510A TW 201105510 A TW201105510 A TW 201105510A TW 98126240 A TW98126240 A TW 98126240A TW 98126240 A TW98126240 A TW 98126240A TW 201105510 A TW201105510 A TW 201105510A
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Taiwan
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film
asphalt
major surface
layer
composite
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TW98126240A
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Chinese (zh)
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Sug-Joon Lee
Kerry Hook
Jon Woolstencroft
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Saint Gobain Technical Fabrics
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Priority to TW98126240A priority Critical patent/TW201105510A/en
Publication of TW201105510A publication Critical patent/TW201105510A/en

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Abstract

A composite comprises: an open grid comprising at least two sets of strands. Each set of strands has openings between adjacent strands. The sets are oriented at a substantial angle to one another. A tack film is laminated to the open grid. The tack film has first and second major surfaces, such that a material of the tack film at its first and second major surfaces includes an asphaltic component and about 50% or more of resinous non-asphaltic component of the material of the tack film.

Description

201105510 六、發明說明: 【發明所屬之技術領域】 本發明係關於用於鋪面修復之強化材料。 【先前技術】 已提出強化遞青道路及上覆層之各種方法及複合物。一 些人描述浸潰有樹脂之玻璃纖維格柵。為修復舊鋪面,一 般根據建設規範,隨玻璃纖維格柵一起塗覆瀝青黏性塗 料。黏性塗料係以液體形式塗覆(例如以乳液或熱瀝青水 泥黏合劑形式藉由喷霧來塗覆),且其後由液體變為固 體。黏性塗料係塗覆於所安裝格柵之上,且在格柵背面具 有用作使新瀝青鋪面與現有鋪築表面黏結之助劑的黏著塗 層。為在格柵背面無黏著塗層時安裝玻璃纖維格柵,首先 將黏性塗料塗覆於現有鋪面上。在黏性塗料完全固化之 前,將格柵舖設於黏性塗料上。隨著黏性塗料進一步固 化’其將格柵保持於下伏鋪面上之適當位置。當將熱瀝青 混凝土覆蓋於格柵之上時,黏性塗料部分熔化且與格柵中 之浸潰樹脂融合在一起。黏性塗料具有便於與該等強化物 一起使用的若干極其理想之特徵。詳言之,其與待用作上 覆層之瀝青混凝土或水泥完全相容,且其流體性質使其流 入粗糖舖築表面中並使該等表面平滑。 另一方面,黏性塗料帶來若干難題。黏性塗料特性對周 圍條件、尤其溫度及濕度極為敏感。此等條件可影響乳液 黏性塗料之固化溫度,且在嚴重狀況下可阻止固化。在不 太嚴重的情況下,鋪築上覆層之設備必須等到黏性塗料已 142390.doc 201105510 固化’從而導致不必要的延遲。舉例而言,黏性塗料通常 為遞青於水中之乳液,其常常由界面活性劑穩定化。為表 現乳液潛能’必須使乳液分解且移除水以鋪設瀝青膜。除 水過程基本上為蒸發過程,其受時間、環境之溫度及濕度 控制。環境條件時常不利,導致黏接無效或不可接受之延 遲。 JP 05-315732描述可代替噴霧型乳液黏性塗料使用之瀝 月膜。邏青膜覆蓋於基層上且鰹加熱之瀝青材料鋪設於該 膜之上。错由使瀝青乳液附著於網狀體兩側且使其凝固來 形成膜。將包含礫石、砂子等之下基層及碎石上基層置放 於路基上且壓實。將該膜置放於上基層上且將經加熱之瀝 青材料鋪設於該膜上。反覆鋪設額外膜及瀝青材料層於瀝 青層上。膜因瀝青材料之熱量而軟化且熔合成單一整體。 因此,仍需要改良鋪築層之間的層間層。 【發明内容】 一種複合物包含:包含至少兩組股線之開口式格柵。各 組股線在相鄰股線之間具有開口且該等組以彼此成實質角 定向。黏性膜層壓至該開口式格柵。該黏性膜具有第—主 表面及第二主表面,使得該黏性膜之第一主表面及第二主 表面之材料為樹脂性非瀝青材料或包括約5〇%或5〇%以上 樹脂性非瀝青組份及約50%或5〇%以下瀝青組份的材料。 一種鋪面結構包含遞青鋪面材料黏合層。複合物層鋪設 於該黏合層上,其包含:包含至少兩組股線之開口式格 柵,各組股線在相鄰股線之間具有開口且該等組以彼此成 142390.doc 201105510 實質角定向。黏性膜層壓至該開口式格栅。該黏性膜具有 第一主表面及第二主表面,使得該黏性膜之第一主表面及 第二主表面之材料為樹脂性非瀝青材料或包括約5〇%或 50%以上樹脂性非瀝青組份及約5〇%或5〇%以下瀝青組份 的材料。瀝青材料表面層係處於該複合材料上。 一種製備複合物之方法包含:提供包含至少兩組股線之 開口式格柵。各組股線在相鄰股線之間具有開口且該等組 以彼此成實質角定向。將黏性媒層壓至該開口式格拇。該 ㈣膜具有第—主表面及第二主表面,使得該黏性膜之第 主表面及第一主表面之材料為樹脂性非瀝青材料或包括 ㈣。/。或5〇%以上樹脂性非瀝青組份及約观或观以下歷 青組份的材料。 【實施方式】 ,附圖式說明本發明之較佳實施例以及與本揭示案有關 之其他資訊。 你卜性實施例之此描述欲結合隨附圖式—起閱讀,該 圖式被視為整個書面描述之一部分t y、f 厂 K 0丨刀。在忒描述中,諸如 。」、「上部」、「水平」、「垂 「」 丄万」、 相斜、向上」、「向下」、「頂部」及「底部」之 才「—吾以及其派生詞(例如「水平地」、「向下地」、 =地」等)應理解為指代彼時所描述或在所討論之圖 此等相對術語係為了便於描述且並不要 ",疋疋向來建構或操作。除非另外明確描述,$ 則與附接、耦桩芬甘姑 田it 否 耦接及其類似表述有關之術語(諸如「連接」 J42390.doc 201105510 及「互連」)係指結構彼此直接地或經由介入結構間接地 緊固或附接之關係,以及可移動式或剛性附接或關係。 以下實例描述供瀝青鋪面使用之自黏著黏性膜、製備該 膜之方法及形成鋪面之方法,其中第二鋪面層係置放於第 一鋪面層之上。如本文所用之以下術語定義如下: 周圍:四周環境條件,諸如壓力、溫度或相對濕度。 股線:以單元形式使用之連續長絲的撚合或未撚合絲束 或總成,包括棉條、缝頭(toe)、經紗 '紗線及其類似物。 有時單纖維或單長絲亦稱為股線。 樹月曰}·生·具有或屬於通常分子量較高之固體或假固體有 機材料,其在經受應力或溫度時展現流動趨勢。呈熱塑性 形式時,其通常具有軟化或熔融範圍。大多數樹脂為聚合 物。 詞「鋪面」、「道路」、「路面」及「表面」在本文中 以其廣泛含義使用以包括機場、人行道、車道、停車場及 所有其他該等舖築表面。 圖1展示鋪面區段150之一實例。在維護及修復鋪面15〇 期間,將瀝青黏合層135覆蓋於現有舊鋪面13〇之上,該舊 鋪面130可為混凝土、瀝青或其混合物。舊鋪面13〇通常由 碾輥(abrasive roll)(未圖示)紋理化或碾平,從而為黏合層 135提供良好唾合表面。預製樹脂性膜或浸潰有樹脂之膜 1〇〇置放於黏合層135上且增強與表面層! 4〇之黏結 。此確 保多層鋪築結構中之層間黏結,其為減少例如由汽車交通 施加於表面層的應力分布所必需。 142390.doc 201105510 黏性膜100具有第一主表面及第二主表面》黏性膜100之 第一主表面及第二主表面之材料為非瀝青樹脂材料,或具 有包括約50%或50%以上之樹脂及約50°/❶或50%以下之瀝青 材料的組合物。黏性膜表面之材料較佳為不超過25%之瀝 青材料’且黏性膜表面之材料更佳為不超過2〇%之瀝青材 料。在一些實施例中,黏性膜100包括載體基材,在其第 主表面及第二主表面上塗布有樹脂性非瀝青材料,或在 其第一主表面及第二主表面上塗布有包含約50。/。或50%以 上之樹脂性非瀝青材料及約5〇%或5〇%以下之瀝青材料的 材料。在其他實施例中,整個黏性膜1〇〇基本上由樹脂性201105510 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a reinforcing material for paving repair. [Prior Art] Various methods and composites for strengthening the greening road and the overlying layer have been proposed. Some people describe glass fiber grids impregnated with resin. In order to repair the old pavement, the asphalt viscous coating is applied along with the glass fiber grid, generally according to the construction specifications. The viscous coating is applied in liquid form (e.g., by spraying in the form of an emulsion or hot bituminous cement binder) and thereafter changed from a liquid to a solid. The viscous coating is applied to the installed grid and has an adhesive coating on the back of the grid for use as an additive to bond the new asphalt pavement to the existing paving surface. To install a fiberglass grid when there is no adhesive coating on the back of the grid, first apply a viscous coating to the existing decking. The grid is placed on the viscous coating before the viscous coating is fully cured. As the viscous coating is further cured, it holds the grid in place on the underlying surface. When the hot asphalt concrete is overlaid on the grid, the viscous coating partially melts and fuses with the impregnating resin in the grid. Adhesive coatings have several highly desirable features that facilitate their use with such reinforcements. In particular, it is completely compatible with the asphalt concrete or cement to be used as the overcoat layer, and its fluid properties allow it to flow into the rough sugar paving surface and smooth the surfaces. On the other hand, adhesive coatings present several challenges. Viscosity coating properties are extremely sensitive to ambient conditions, especially temperature and humidity. These conditions can affect the curing temperature of the emulsion viscous coating and can prevent curing under severe conditions. In less severe cases, the equipment for laying the overcoat must wait until the viscous coating has cured, resulting in unnecessary delays. For example, viscous coatings are typically emulsions that are condensed in water, which are often stabilized by surfactants. To demonstrate the emulsion potential, the emulsion must be decomposed and water removed to lay the asphalt film. The water removal process is essentially an evaporation process that is controlled by time, ambient temperature and humidity. Environmental conditions are often unfavorable, resulting in ineffective or unacceptable delays in bonding. JP 05-315732 describes a leaching film that can be used in place of a spray-type emulsion viscous coating. A logic film is applied over the substrate and a heated asphalt material is placed over the film. The error is caused by attaching the asphalt emulsion to both sides of the mesh body and solidifying it to form a film. The base layer containing gravel, sand, and the like and the base layer on the gravel are placed on the roadbed and compacted. The film is placed on the upper substrate and the heated asphalt material is laid on the film. An additional layer of film and asphalt material is applied over the asphalt layer. The membrane softens due to the heat of the asphalt material and fuses into a single unit. Therefore, there is still a need to improve the interlayer between the paving layers. SUMMARY OF THE INVENTION A composite comprises an open grid comprising at least two sets of strands. Each set of strands has an opening between adjacent strands and the sets are oriented at a substantial angle to each other. A viscous film is laminated to the open grid. The viscous film has a first major surface and a second major surface, such that the material of the first major surface and the second major surface of the viscous membrane is a resinous non-asphalt material or comprises about 5% or more 5% resin. A non-asphalt component and a material of about 50% or less of the asphalt component. A paving structure comprises a bonding layer of a gradual paving material. A composite layer is laid on the adhesive layer, comprising: an open grid comprising at least two sets of strands, each set of strands having an opening between adjacent strands and the groups being 142390.doc 201105510 Angle orientation. A viscous film is laminated to the open grid. The viscous film has a first major surface and a second major surface, such that the material of the first major surface and the second major surface of the viscous membrane is a resinous non-asphalt material or comprises about 5% or more resinity. Non-asphalt component and material of asphalt component of about 5% or less. The surface layer of the asphalt material is on the composite. A method of making a composite comprising: providing an open grid comprising at least two sets of strands. Each set of strands has an opening between adjacent strands and the sets are oriented at substantially a right angle to each other. A viscous medium is laminated to the open frame thumb. The film (4) has a first major surface and a second major surface such that the material of the first major surface and the first major surface of the adhesive film is a resinous non-asphalt material or comprises (4). /. Or more than 5% of the resinous non-asphalt component and the material of the aging or the following components. [Embodiment] The drawings illustrate preferred embodiments of the invention and other information related to the present disclosure. This description of the embodiments of the present invention is intended to be read in conjunction with the accompanying drawings, which are considered to be part of the entire written description t y, f factory K 0 knives. In the description, such as . """"""""""""""""""""""""""""""""""""""""""""""""""" , "downward", "ground", etc., are to be understood as referring to the figures described above or in the figures discussed. These relative terms are for convenience of description and do not construct or operate. Unless otherwise expressly stated, $ is a term relating to the attachment, coupling, and coupling of a similar type (such as "connection" J42390.doc 201105510 and "interconnection") means that the structures are directly or A relationship that is indirectly fastened or attached via an interventional structure, as well as a movable or rigid attachment or relationship. The following examples describe a self-adhesive viscous film for use in asphalt paving, a method of making the film, and a method of forming a surfacing, wherein a second surfacing layer is placed over the first surfacing layer. The following terms as used herein are defined as follows: Surrounding: ambient environmental conditions such as pressure, temperature or relative humidity. Strand: A twisted or untwisted tow or assembly of continuous filaments used in unit form, including slivers, toe, warp yarns and the like. Sometimes single fibers or single filaments are also known as strands. It has or belongs to a solid or pseudo-solid organic material of generally higher molecular weight, which exhibits a tendency to flow when subjected to stress or temperature. When in thermoplastic form, it typically has a softening or melting range. Most resins are polymers. The terms "paving", "road", "road" and "surface" are used herein in their broad sense to include airports, sidewalks, driveways, car parks and all such other paved surfaces. FIG. 1 shows an example of a paving section 150. During maintenance and repair of the pavement 15 沥青, the asphalt binder layer 135 is overlaid onto the existing old decking 13 ,, which may be concrete, asphalt or a mixture thereof. The old pavement 13 is typically textured or flattened by an abrasive roll (not shown) to provide a good salivation surface for the adhesive layer 135. A pre-formed resin film or a film impregnated with a resin is placed on the adhesive layer 135 and reinforced with the surface layer! 4〇 Bonding. This ensures interlayer bonding in the multi-layer paving structure, which is necessary to reduce the stress distribution applied to the surface layer by, for example, automobile traffic. 142390.doc 201105510 The adhesive film 100 has a first major surface and a second major surface. The first major surface and the second major surface of the adhesive film 100 are made of a non-asphalt resin material or have about 50% or 50%. A combination of the above resin and a bituminous material of about 50°/❶ or less. The material of the surface of the viscous film is preferably not more than 25% of the asphalt material' and the material of the surface of the viscous film is more preferably not more than 2% of the asphalt material. In some embodiments, the viscous film 100 includes a carrier substrate coated with a resinous non-asphalt material on the first major surface and the second major surface, or coated on the first major surface and the second major surface thereof. About 50. /. Or more than 50% of the resinous non-asphalt material and the material of the asphalt material of about 5% or less. In other embodiments, the entire viscous membrane 1 〇〇 is substantially resinous

一 Π „ Q方权A邵分或多數部分之 青材料及非零較小部分之遞青#料的材料组成 較大部分或多數部分之樹脂性非遞青材料及非 成;或整個黏 之樹脂性非瀝 ’或由包含 零較小部分 之遞青材料的材料組成。„ „Q Fangquan A Shao or a majority of the green material and the non-zero smaller part of the material of the material # constitute a larger part or a majority of the resinous non-cyan material and non-form; or the entire stick Resin non-leaching or consisting of a material containing zero minor parts of the greening material.

142390.doc 201105510 圖2展不黏性膜之第一實例,其可為複合膜1 ^在一些 實施例中’如圖丨及圖2中所示,聚合物薄膜11〇覆蓋於基 層135上且充當載體以便均勻地分布複合黏性膜丨〇〇之樹 脂(或包含約50%或50%以上之聚合樹脂及約5〇%或5〇%以 下之瀝月材料的材料口 2〇。經由塗布過程使樹脂12〇(或樹 脂與瀝青材料之組合物)完全覆蓋載體膜丨1〇之兩側以形成 黏性複合膜1〇〇。塗層之非黏性且平滑的表面性質提供在 建設現場操作之便利性。 製備複合黏性膜1 〇〇之例示性方法如下。第一步包括鋪 設樹脂性或浸潰有樹脂之聚合物薄膜作為載體膜110。隨 後例如藉由將薄膜110浸入樹脂或樹脂與瀝青材料之組合 物中而使該臈上塗布有聚合樹脂120(或樹脂與瀝青材料之 組合物)。隨後乾燥經塗布之膜丨00。可將黏著劑丨22(諸如 壓敏性黏著劑)塗覆於經塗布膜之背面(安裝後之底側)上。 隨後乾燥黏著劑122。在塗覆上覆表面層i40時,黏著劑 122將該膜保持於適當位置。 聚合樹脂(或樹脂與瀝青材料之组合物)丨2〇可具有與遞 月140類似之熱膨脹係數(CTE)。較佳地,聚合樹脂(或樹 脂與瀝青材料之組合物)具有優於瀝青14〇及135之穩定 性’以及在寬泛溫度範圍内之較高硬度。複合黏性膜1 〇〇 比基於瀝青之膜更具黏彈性。乾燥時,複合膜1〇〇具有平 滑非黏性表面。在使用中’當將表面層14〇之熱拌瀝青混 合物塗覆於黏性複合膜1 00上時,聚合樹脂(或樹脂與瀝青 材料之塗布組合物)120經活化以提供黏結力,且鋪面層 142390.doc 201105510 135、140之間的附接藉助於黏性複合膜1〇〇得到增強。 當在道路建財使用瀝青喷霧乳液時,安裝者必須設法 使遞青乳液塗層適當地薄且均一以獲得最佳效能。使用如 本文所述之黏性膜⑽提供狀厚度。可控制塗層⑵厚度 之均-性。可使塗層12G之厚度最優化至等效於渥青乳液 黏性塗層之最佳施用率的厚度。 黏性膜100去除瀝青乳液當場噴霧及固化之步驟。可縮 短鋪面建設工程之時間且降低其人工成本。此外,因為去 除當場固化步驟,所以完成既定鋪面面積所需之時間比使 用喷霧乳料更加可預測。藉由消除安裝時間的不可預測 性’有可能消除安裝時程中之鬆他時間,從而增加效率, 且進-步縮短工程持續時間。另夕卜,因為可最優化且控制 膜厚度]文可減少黏性膜消耗。使用預製且大量生產之複 合黏性膜的能力為可能降低材料成本提供機會。 在-些實施例令,在點性膜100背面添加黏著劑使得 現場安裝更牢固。為便於安裝,較佳使用M敏性黏著劑 122。 在-些實施例中’載體膜⑽可包含聚乙埽膜。該載體 可具有約G.5密耳(mil)至約1G密耳之厚度且更佳可使用 約〇.5密耳至約2密耳之載體。舉例而言,膜ug可為約〇5 密耳(〇.〇i毫米)之低密度聚乙稀膜,但亦可使用其他材料 及厚度,諸如約2密耳(0.05毫米)厚之聚乙婦聚丙歸共聚 物膜。聚乙烯為價廉材料。雖然在一些樹脂塗布材料之乾 燥溫度下聚乙烯可能收縮’但較佳樹脂保護膜ιι〇,心 142390.doc 201105510 該膜在乾燥過程中保持其形狀。與遞青相容之其他聚合物 膜可用於載體層I,例如PVC、耐綸(nylGn)(聚酿胺)、丙 婦^系物、HDPE及某些聚丙烯,其提供所要剛性、相容 &及耐腐#性)。在其他實施例+,載體層可&含由此等 材料中之兩者或兩者以上或此等材料之一與不同相容材料 之組合製成的多層片材。 膜U 〇可經穿孔。穿孔增加樹脂120浸潰入膜11 〇中之速 度。可在膜110之兩侧形成樹脂(或樹脂與瀝青材料之塗布 組合物)120之網狀物。來自表面層14〇之熱熔瀝青的熱量 經膜1 ίο之底部轉移至下部(黏合劑)瀝青混凝土層135。 在一些貫施例中’塗覆於膜1丨〇上之非瀝青樹脂性塗層 (或樹脂與瀝青材料之塗布組合物)12〇使得黏性膜1〇〇與周 圍遞青層135、140更相容。此係藉由謹慎地調整塗層12〇 之化學組成以使得樹脂在鋪築溫度 '鋪築壓力或兩者下塑 性流動來實現。塗層12〇之組成較佳具有高於68_77°F C20-25C)之玻璃轉移溫度,且較佳在約12〇_14〇。?(50-60。〇)以 上之溫度經歷塑性流動。一旦達到瀝青鋪面之溫度,亦即 約265-32〇°?(13〇-16〇°(:),塗層12〇甚至在極低壓力下仍可 能流動。實際上’建設壓實所施加之鋪築壓力及表面層 140之重量可實現一定程度之流動’從而至少局部與極緊 密接近之表面等形。在安裝期間,表面層140之典型溫度 始於約250-320°?(121-160。〇,且使得層間黏性膜100之溫 度為約140-150°F (60-66°C )。此足以加熱黏性膜1 〇〇及膜 110上之塗層120 ^此熱量使得塗層120流動且膜11〇鬆弛並 142390.doc -10· 201105510 被「熨平(iron out)」,以促進黏性膜1〇〇與鋪面15〇之黏合 層135及表面層140更好地機械黏結。 歸因於與任何暴露聚集體、瀝青或其類似物之凡得瓦爾 引力(Van der Waals attraction),塗層120之化學性質亦可 允許一定程度之物理及/或化學鍵結。物理過程與化學過 程均改良表面層與黏合層之間的剪切黏著力,從而改良剪 切強度。一般而言,塗層12〇愈厚,剪切效能愈好,直至 各塗布材料所特有之最大值。 在另一較佳實施例中,提供減小瀝青鋪面層中之彎曲力 矩的方法。該方法包括將較佳具有約〇75吋(19毫米)或 0.75吋(19毫米)以上之厚度的瀝青黏合層135塗覆於現有道 路表面130上,接著將複合黏性膜1〇〇塗覆於瀝青黏合層 135上。膜1〇〇可包含聚乙烯、乙烯乙酸乙烯酯(eva)或其142390.doc 201105510 FIG. 2 shows a first example of a non-adhesive film which may be a composite film 1 ^ In some embodiments, as shown in FIG. 2 and FIG. 2, a polymer film 11 is coated on the base layer 135 and A resin serving as a carrier for uniformly distributing the composite adhesive film (or a material port comprising about 50% or more of the polymer resin and about 5% or less by weight of the leaching material.) The process allows the resin 12 〇 (or a combination of resin and asphalt material) to completely cover the sides of the carrier film 丨 1 以 to form a viscous composite film 1 〇〇. The non-sticky and smooth surface properties of the coating are provided at the construction site. The convenience of the operation. An exemplary method of preparing the composite adhesive film 1 is as follows. The first step involves laying a resin film or a resin film impregnated with the resin as the carrier film 110. Then, for example, by dipping the film 110 into the resin or The crucible is coated with a polymeric resin 120 (or a combination of a resin and a bituminous material) in a composition of a resin and a bituminous material. The coated film 丨00 is then dried. The adhesive 丨 22 may be applied (such as pressure sensitive adhesive). Applied to the coated film On the surface (the bottom side after installation), the adhesive 122 is subsequently dried. When the surface layer i40 is coated, the adhesive 122 holds the film in place. Polymer resin (or a combination of resin and asphalt material) 2〇 may have a coefficient of thermal expansion (CTE) similar to that of the delivery month 140. Preferably, the polymeric resin (or combination of resin and asphalt material) has stability over asphalt 14 〇 and 135' and over a wide temperature range The higher hardness. The composite adhesive film 1 is more viscoelastic than the asphalt-based film. When dry, the composite film has a smooth non-stick surface. In use, when the surface layer 14 is hot mixed When the asphalt mixture is applied to the viscous composite film 100, the polymeric resin (or coating composition of resin and asphalt material) 120 is activated to provide a bonding force, and the attachment between the surfacing layers 142390.doc 201105510 135, 140 Enhancement is achieved by means of a viscous composite film. When using asphalt spray emulsions on roads, the installer must try to make the dip emulsion coatings suitably thin and uniform for optimum performance. It The film (10) provides a thickness which can control the uniformity of the thickness of the coating (2). The thickness of the coating 12G can be optimized to a thickness equivalent to the optimum application rate of the viscous coating of the phthalocyanine emulsion. The step of removing the asphalt emulsion on the spot spray and curing can shorten the time of paving construction work and reduce the labor cost. Moreover, because the on-site curing step is removed, the time required to complete the established paving area is more predictable than the use of sprayed milk. By eliminating the unpredictability of installation time, it is possible to eliminate the loose time in the installation schedule, thereby increasing efficiency and further shortening the project duration. In addition, because the film thickness can be optimized and controlled, the viscosity can be reduced. Sex film consumption. The ability to use prefabricated and mass produced composite viscous membranes provides an opportunity to reduce material costs. In some embodiments, the addition of an adhesive to the back of the dot film 100 results in a more secure field installation. For ease of installation, the M-sensitive adhesive 122 is preferably used. In some embodiments the carrier film (10) may comprise a polyethylene film. The carrier may have a thickness of from about G.5 mils to about 1 mil mils and more preferably from about 密5 mils to about 2 mils. For example, the film ug can be a low density polyethylene film of about 5 mils (〇.〇i mm), but other materials and thicknesses can be used, such as about 2 mils (0.05 mm) thick polyethylene. Polyacrylamide copolymer film. Polyethylene is a cheap material. Although polyethylene may shrink at the drying temperature of some resin coating materials, but a preferred resin protective film ιι, 142390.doc 201105510 The film retains its shape during drying. Other polymer films compatible with diqing can be used in carrier layer I, such as PVC, nylon (nylGn) (polyamide), propylene compound, HDPE and certain polypropylenes, which provide the desired rigidity and compatibility. & and anti-corruption #性). In other embodiments, the carrier layer can comprise a multilayer sheet of two or more of such materials or a combination of one of the materials and a different compatible material. The membrane U 〇 can be perforated. The perforations increase the speed at which the resin 120 is impregnated into the film 11 crucible. A mesh of resin (or a coating composition of resin and asphalt material) 120 may be formed on both sides of the film 110. The heat from the hot melt asphalt of the surface layer 14 is transferred to the lower (adhesive) asphalt concrete layer 135 through the bottom of the film 1 ίο. In some embodiments, the non-asphalt resin coating (or the coating composition of the resin and the asphalt material) coated on the film 1 is 12 〇 such that the viscous film 1 〇〇 and the surrounding greening layer 135, 140 More compatible. This is accomplished by carefully adjusting the chemical composition of the coating 12 to cause the resin to flow at the paving temperature 'paving pressure or both. The composition of the coating 12 较佳 preferably has a glass transition temperature higher than 68-77 ° F C20-25 C), and preferably about 12 〇 14 14 。. ? (50-60. 〇) The plastic flow is experienced at a temperature above. Once the temperature of the asphalt pavement is reached, that is, about 265-32 〇 ° (13 〇 -16 〇 ° (:), the coating 12 仍 may still flow even under very low pressure. Actually, the construction compaction is applied. The paving pressure and the weight of the surface layer 140 can achieve a degree of flow 'so that at least partially and closely close to the surface is equal. During installation, the typical temperature of the surface layer 140 begins at about 250-320°? (121-160 〇, and the temperature of the interlayer adhesive film 100 is about 140-150 ° F (60-66 ° C). This is enough to heat the viscous film 1 〇〇 and the coating on the film 110 120 ^ This heat makes the coating 120 flows and the film 11〇 relaxes and 142390.doc -10· 201105510 is "iron out" to promote better mechanical bonding of the adhesive film 1 and the adhesive layer 135 and the surface layer 140 of the pavement 15 Due to the Van der Waals attraction with any exposed aggregates, bitumen or the like, the chemistry of the coating 120 may also allow for some degree of physical and/or chemical bonding. Physical Process and Chemistry The process improves the shear adhesion between the surface layer and the adhesive layer, thereby improving the shear In general, the coating 12 is thicker and the shearing efficiency is better up to the maximum value peculiar to each coating material. In another preferred embodiment, a method of reducing the bending moment in the asphalt surfacing layer is provided. The method comprises applying an asphalt binder layer 135 having a thickness of preferably about 75 吋 (19 mm) or 0.75 吋 (19 mm) or more to the existing road surface 130, and then coating the composite viscous film 1 Covering the asphalt adhesive layer 135. The film may comprise polyethylene, ethylene vinyl acetate (eva) or

瀝青黏合層135與瀝青表面層14〇之間 1120塑性流動以改良 的層間黏結。層間黏 142390.doc 201105510 結可為黏著性黏結、熔融性黏結或化學(及/或凡得瓦爾)鍵 結或其組合。 在一些貫施例中,表面層120為丙烯酸系塗層。在一些 實施例中,表面層12〇可包含聚氣乙烯(pvc)乳膠乳液塗 層,其包含約1-8重量%蠟脫模劑,及約〇_1〇重量%選自由 以下組成之群的添加劑:可溶性聚合物、氨、稠化劑、碳 黑 '消泡劑及增塑劑。一種較佳之PVC:乳膠乳液為可購自1120 plastic flow between the asphalt binder layer 135 and the asphalt surface layer 14〇 for improved interlayer bonding. Interlayer adhesion 142390.doc 201105510 The junction can be an adhesive bond, a fusible bond or a chemical (and/or van der Waals) bond or a combination thereof. In some embodiments, surface layer 120 is an acrylic coating. In some embodiments, the surface layer 12A may comprise a polyethylene (PVC) latex emulsion coating comprising from about 1% to about 8% by weight of a wax release agent, and about 〇_1% by weight of the group selected from the group consisting of Additives: soluble polymers, ammonia, thickeners, carbon black's defoamers and plasticizers. A preferred PVC: latex emulsion is commercially available

Noveon,Inc.(Cleveland, OH)之 Vycar® 460x63乳膠(乙稀基 乳液)’其在高於約120-140卞(49-60。(:)之鋪築溫度下,在 塗布表面上提供極大程度之塑性流動。PVC乳膠聚合物與 瀝青亦可能存在固有程度之化學黏著。 在一些貫施例中’塗層包含40-60% Vycar® 460x63乳 膠,且在一些實施例中,塗層包含至少約40% Vycar⑫ 460x63乳膠及至多約20%遞青材料。在一些實施例中,塗 層包含45-50% Vycar® 460x63乳膠,且在一些實施例中, 塗層包含至少約45% Vycar® 460x63乳膠及至多約5%遞青 材料。 據知Vycar® 460x63自身頗具剛性,尤其在寒冷氣候 中。此可在經塗布之膜100在道路中沿曲線塗覆時產生安 裝問題。與其他樹脂性候選物相比,Vycar® 460x63亦對 液態水具有較小抗性。因為其固體含量相當低,故可能較 難得到所要吸取程度,且一旦被吸收,則可能較難充分乾 燥織物。 因此,在一些實施例中,含有Vycar® 460x63之塗層120 142390.doc 12 201105510 係以使該塗層較軟且增加其固體含量之方式來調配。 塗層120中之聚合物亦可由較軟單體製備。拒水性問題 可藉由併入含量佔乾燥塗層之約3·5重量%之蠟添加劑(諸 如Hydrocer丨45)來解決。此蠟脫模劑亦具有稍微軟化塗層 之趨勢。可改良塗層之固體含量至約5〇_6〇重量,理想地 為約55重量%或55重量%以上。除對pvc乳膠之此等改良 以外,可引入乾燥塗層之約5_9重量%之量的可溶性聚合物 (諸如Carboset 5 14W)以使軋輥(pad r〇u)上之塗層得到更多 凝固時間及再濕潤性。可使用其他水溶性聚合物,諸如 Michemprime聚合物。 為活化可溶性聚合物,可添加氨至約8或9之?11值。亦可 使用氨來活化組合物中所用之任何鹼溶性稠化劑。該等稠 化劑可包括通常可購得之稠化劑,且較佳在不能獲得吸取 目標時使用。來自 Rohm and Haas(Philadelphia,PA)之 ASE-60或6038A將適用於此應用。 約1重量%之量的著色劑(諸如碳黑)及達約〇 〇5重量%之 含量的消泡劑(諸如NXZ或DEFO)適用於此應用。 最後,可使用增塑劑以獲得塗層所要之軟度。因為 ADMEX 3 14為非揮發性聚合增塑劑且不會產生環境或健康 危害,故其合乎需要,且約2-5重量%之含量使塗層軟度產 生顯著變化。 許多替代類型之樹脂可用於表面層120,只要其在鋪築 溫度、鋪築壓力或兩者下塑性流動即可。主要實例為 PVC、耐綸、丙烯酸系物、HDPE及某些聚乙烯及聚丙烯 142390.doc 13 201105510 以及乙稀乙酸乙稀醋(EVA),其提供所要剛性、相容性及 对腐姓性。其可使用熱炫、乳液、溶劑、&固化或輕射固 化系統來塗覆。在一些實施例中,黏性膜1〇〇包括多層 膜。舉例而言,載體層110可為上面塗覆有表面層塗層12〇 之多層膜。在其他實施例中,整個黏性膜100為共擠出 物,且表面層120為與載體層110一起共擠出之樹脂膜。表 面層120之材料可與载體層110之材料相同,可包括與載體 層no相同之主要成份,或可具有與载體層110不同之主要 成份。 當任何此等替代性樹脂材料用於表面層120時,防黏劑 (例如蠟、合成聚合物、少量撒布之滑石粉)可包括於表面 層120中以防止黏性膜100在以螺旋輥形式儲存且在隨後展 開期間拉離格柵10時自身黏連。助滑劑亦可包括於載體層 110之一側或兩侧上之表面層丨20中。 上述組合物與瀝青表面140及黏合層135顯著相容。其容 許與埋置於瀝青混凝土中之黏性膜1〇〇強力黏結。鋪面層 之間的堅實黏著有效減少交通對表面層之應力分布。該種 解決方案寸防止因缺乏界面黏結而引起或促成之滑移、裂 縫及分層(稱為過早應力(premature stress))。 表面層120之熱膨脹係數近似於瀝青混合物之熱膨脹係 數。表面層120可能避免因複合瀝青混凝土中之離散熱行 為所致之膜100界面處不當脫離。增強之界面狀況使上覆 表面遞青層140免受顯著道路應力之影響而擁有延長的使 用壽命。 142390.doc 201105510 上文描述一實例,其中載體膜丨10包含第一材料(例如聚 合物,諸如聚乙烯),且膜110塗布有第二材料12〇(例如具 有添加劑之Vycar® 460x63,如上所述)。然而,涵蓋其他 實施例’其中膜110基本上由如上所述用作塗布材料12〇之 非瀝月树知性材料(例如具有添加劑之VyCar⑧460x63)組成 (或由其組成)。在該等實施例中,可省去塗布材料12〇之獨 立層。因此’黏性膜層可為複合膜1〇〇或均質樹脂性膜。 使用複合膜抑或均質膜之選擇及載體膜u〇材料之選擇可 視材料成本、製造簡易性及各材料之可購得性而定,此可 由一般熟習技術者在任何指定時間容易地評估。 當以樹脂性塗層浸潰及塗布或與樹脂性膜12〇一起共擠 出時’膜100較佳為半剛性的,且可捲於芯體上以便容易 地以預製連續組件之形式輸送至安裝地點,在此地點處其 可輕易地連續鋪開以便快速、經濟且簡易地併入路面中。 舉例而言,可將膜100置放於15呎(45公尺)寬之輥上該 等輥含有100公尺長或更長之單件結構。或者,黏合層135 可以膜100之若干較窄條帶覆蓋,通常各條帶約五呎(1.5公 尺)寬。因此,在黏合層135之所有或實質上所有表面上使 用此膜100為切實可行的,此因人工勞動減少而具有成本 效益。 在鋪築現場’將膜1〇〇以黏著劑122朝下而展開且鋪設於 下伏鋪面135上,在塗覆膜1〇〇時,該下伏鋪面135較佳為 約 40-140卞(4.4-60。〇。 將黏性膜100鋪開且黏著於厚度較佳約0.75吋(19毫米)或 142390.doc 201105510 〇·75寺(19毫米)以上之底襯層或瀝青黏合層η;。在一些實 施例中,在將任何上覆層或瀝青表面層14〇置放於膜丨⑽上 之前,可諸如由膜100製造期間所塗覆之黏著劑122(例如 壓敏性黏著劑)使膜100足夠穩定,以使膜1〇〇抵抗在其上 行走之工人、在其上驰越之施工車輛的作用以及尤其鋪築 機在其上之移動。 膜100雖然為半剛性的,但易於平置。在已展開之後, 其具有極小乃至無回捲趨勢。咸信此係歸因於黏合劑及/ 或表面層樹脂的適當選擇。 在一些實施例中,如圖丨_2中所示,經表面重整之鋪面 包括待表面重整之鋪面130、基層135、黏性複合膜100, 及表面層140’而無獨立強化層。 在其他實施例中,將黏性膜100塗覆於黏合層135上,獨 立強化層塗覆於黏性膜100上,且表面層14〇塗覆於強化層 上。舉例而言,強化層可為可購自Saint G〇bain Fabrics 之 GlasGdd® 產品(例如 8550、85〇1、85〇2、8511或 8512格柵)。 在其他實施例中,如圖3-6中所示,黏性膜丨〇〇包括於整 體複合強化間層200、300或400中。整體複合材料2〇〇、 300或400包括黏性膜層1〇〇及強化層〗〇。 在一些實施例中,複合強化間層為包含強化層1〇上方之 複合黏性膜層或樹脂性黏性膜層I 00的複合物2〇〇(圖3)。以 可為熱熔性黏著劑之黏著劑12使黏性膜層1〇〇與強化層1〇 黏結。熱熔性黏著劑可為壓敏性或永久性的。強化材料1〇 142390.doc -16- 201105510 之底表面(背對黏性膜層100)具有黏著劑11,諸如壓敏性黏 著劑’其在塗覆表面層時使複合材料200保持於適當位 置。在圖3之組態中’熱熔性黏著層丨2使黏性膜層1 〇〇與下 伏強化層10黏結,故黏性膜層i 〇〇不需要其自身黏著層 122。又,表面層14〇接觸膜層1〇〇之頂部,且在膜1〇〇之上 表面上不需要黏著層122。黏著層122可自待於圖3之複合 材料200中使用之黏性膜1 00中省去。 在一些實施例中,複合強化間層為包含複合黏性膜層或 樹脂性黏性膜層100上方之強化層10的複合物3〇〇(圖句。以 可為熱熔性黏著劑之黏著劑12使黏性膜層100與強化層10 黏結。為確保在塗覆表面層140時複合材料300保持於適當 位置,複合材料3GG中之黏性膜i⑽在其底表面上包括如圖 2中所示之黏著劑122(其接觸整平層135)。 在-些實施例中,複合強化間層為包含夾入一對複合黏 性膜層或樹脂性黏性膜層1〇〇之間的強化層1〇之複合物 400(圖5)應瞭解’在以下各描述中,黏性膜⑽可為具有 载體層U0及表面層⑵之複合物,或為具有適於在表面層 120之塗層中使用之材料的均f膜#中在該均質膜中不 具有各別載體層110。在複合物4咐,以可為熱炫性黏著 劑之黏著劑使黏性膜層i⑽與強化層_結。為續保在 塗覆表面層M0時複合材料保持於適#位置複合材料 權中之底部黏性膜⑽(其接觸整平層135)在其底表面上包 括如圖2中所示之黏著劑122。頂部黏性膜層刚(其接觸表 面層,在其表面上不需要黏著劑心黏著劑122可自頂 142390.doc 201105510 部黏性膜層100中省去。 強化層10可為多種強化材料中之任一者。在一些實施例 中,提供包含至少兩組實質上平行股線21(以橫截面展示 於圖7及圖8中)之開口式格柵(展示於圖9及圖1〇中)作為強 化層10。各組股線21在相鄰股線21之間包括開口 19(圖9), 且該等組以彼此成實質角(例如視情況成約90度)定向。在 一些實施例中,強化層可為來自Saint Gobain Technical FabriCS2GlasGrid ⑧產品(例如 855〇、85〇ι、85〇2、“η 或 85 12格柵)。 .在些實施例中,格栅ίο較佳包含襯緯經編(weft_ serted warp knit),其中股線2丨以彼此成約9〇〇角定向, 如圖9中所*。開口較佳具有約〇.5nfx 〇5忖〇2毫米X 12毫 米)或更大之尺寸,但開口亦可達約丨吋χ 1吋。雖然開口 19 可為正方形’但尺寸「a」及「b」可不同諸如在矩形之 狀況下。 凡在些實施例中,非瀝青塗層22安置於格栅1 〇上而不使 =21之間的開σ閉合’如圖8中最佳展*。塗層^在鋪 築'皿度冑築壓力或兩者下活化以形成與遞青鋪面相容之 黏結/層22在周圍溫度及壓力下無黏性’使得其可在施 見昜谷易地進行操作。在一些實施例中,股線2〗上之塗 層為與複合黏性膜1〇〇中塗覆於聚合膜110上之塗層12〇 相同之材料。 〜圖9中所不之大格柵開口 Η容許瀝青混合物。^及/或】4〇 封/線20或粗紗之各股線2〗,且容許黏性層1 〇〇與 142390.doc 201105510 黏合層135及表面層140兩者之間完全且實質性的接觸。黏 性層100實質上經由格柵10之開口 19來黏結層135及14〇以 容許來自鋪面135、140之應力實質上轉移至強化層1〇之玻 璃或類似纖維。所得複合格柵材料具有高模數及高強度與 成本比,其膨脹係數近似於道路建設材料之膨脹係數且 其抵抗用於道路建設及見於道路環境中之材料(諸如道路 用鹽)腐蝕。 格柵10可由連續長絲玻璃纖維之股線或紗線21形成,但 亦可使用其他高模數纖維,諸如聚(對苯二甲醯對苯二胺) 之聚醯胺纖維,稱為Kevlar®。2000特(tex)2ECR^E玻璃 組紗較佳,但吾人亦可使用約3〇〇特至約5〇〇〇特範圍内之 重量。當根據ASTM D6637量測時,較佳之玻璃纖維紗線 具有約 560 lb/in(100 kN/m)或 56〇 lb/in(1〇〇 kN/m)a上之股 線強度,以及5%或5%以下之斷裂伸長率。此等股線具有 車乂佳小於約 22 〇z/yd2(74〇 g/m2)且更佳約 u g/m2)之質量/單位面積。 使較佳具低撚度(亦即,每吋約一圈或一圈以下)之此等 叔線形成具有矩形或正方形開口 19之格栅,一邊(圖9中之 、a J 、「b」或兩者)之大小較佳在3/4吋至1吋範圍 内,但亦可使用一邊(「a」、「b」或兩者)在1/8吋至6吋 範圍内之格柵開口 19。 格柵1 〇較佳以圖】〇中所示之細線25綁結或以其他方式 在&向股線與縱向股線之交叉點處固定連接。此連接使格 拇1 〇保持其格柵樣式,防止在以非瀝青塗層22浸潰之前及 142390.doc •19· 201105510 期間股線2 1不當地散開,且保留開口丨9,其容許上覆層與 下伏層黏合且從而增加最終複合路面修復物1〇〇之強度。 格栅10交叉點處之固定連接亦有助於格柵1〇之強度,此 係由於其容許與一組股線21平行之力部分地轉移至另一組 平行股線21。同時,此開口式格柵構造使得每平方碼 (square yard)可能使用較少玻璃,且由此獲得例如比閉合 编織織物更經濟之產品。吾人青睞於使用每平方碼約8盎 司(ounce)之格柵1〇,但亦可使用每平方碼4至盘司。 雖然吾人青睞於在經編襯緯編織設備上使用7〇至1 5〇丹 尼爾(denier)聚酯細線25或等效物將格柵交又點綁結在一 起,但亦可利用形成交叉點經固定連接之格柵的其他方 法。舉例而言,以熱固性或熱塑性黏著劑製備之非編織格 拇可提供合適強度。 一旦形成格栅1 〇,且在使其接合至黏性膜! 〇〇之前,塗 覆树知、較佳熱塑性樹脂22。亦即,格柵1 〇以樹脂22「預 浸潰」。 選擇樹脂性塗層22之黏度以使其滲透至格栅丨〇之股線2 j 中。雖然樹脂性塗層22可能並不包裹玻璃纖維股線21中之 每條長絲20 ’但樹脂性塗層22—般在股線21之内部均一展 布,如圖8中所示。此浸漬賦予股線21較佳半剛性之性 質,且緩和及保護股線21及玻璃長絲免受路面環境中之 水鹽、油及其他要素腐姓。該浸漬亦減少玻璃股線2 1或 長絲20之間的磨蝕及一根玻璃股線21或長絲2〇受另一根玻 璃股線或長絲之切割。浸潰亦減少已鋪設格柵之後,但在 142390.doc •20- 201105510 塗覆上覆層140之前,玻璃纖維彼此切割之趨勢。 格柵在各纟且平行股線之方向上應較佳具有約25千牛頓/ 么尺(kN/m)、更佳約50 kN/m且最佳約1〇〇 kN/rn或1〇〇 kN/m以上之最小強度,及較佳小於約10。/。且更佳小於5% 之斷裂伸長率。 备乾燥或固化格柵1 〇上之較佳樹脂性塗層22時可使股 線21稍稍變平,但保持開口 19。舉例而言,在使用2〇〇〇特 粗紗之較佳實施例中,可形成具有約3/4吋χ丨吋(a = b = 0.75吋)之開口 19的矩形格栅1〇,且使粗紗變平至約丨/“吋 (1.6毫米)至1/8吋(3.2毫米)寬。塗布及乾燥後粗紗之厚度 可為約1/32吋(0.8毫米)或1/32吋(0.8毫米)以下。玻璃纖維 奴線之較佳格柵為可購自Saint_G〇bain Technical Fabrics之 未經塗布 GlasGrid®產品(例如 8550、8501、8502、8511 或 85 12格拇)。 許多樹脂可用於浸潰格柵10,只要其在鋪築溫度、舖築 廢力或兩者下塑性流動即可。主要實例為PVC、耐綸、丙 烯酸系物、HDPE及某些聚乙烯及聚丙烯,其提供所要剛 性、相容性及耐腐蝕性^其可使用熱熔 '乳液、溶劑、熱 固化或輻射固化系統塗覆,例如含有pvc乳液(諸如 Vycar® 460x63)之塗層。PVC乳液亦可包括約卜”量%蠟 脫模劑,及約0 -10重量%之一或多種選自由以下組成之群 的其他添加劑:可溶性聚合物、氨、稠化劑、碳黑、消泡 劑及增塑劑。適於用作複合聚合物膜100之塗層12〇之任何 材料(諸如以上所述之任一材料)可用作格柵1〇之塗層22。 142390.doc -21 201105510 在一些實施例中, 塗層120與22為相同材料。在 中,塗層120與22為不同材料,其中各塗層12〇 在其他實施 、22與瀝 青相容且可由熱量及/或壓力活化。 塗層120及22可由壓力、埶詈亦 、熱置或其他方式活化。當使塗Noveon, Inc. (Cleveland, OH) Vycar® 460x63 Latex (Ethyl-Based Emulsion)' provides maximum on coated surfaces at paving temperatures above about 120-140 Torr (49-60. (:)) Degree of plastic flow. PVC latex polymers and asphalt may also have an inherent degree of chemical adhesion. In some embodiments, the coating comprises 40-60% Vycar® 460x63 latex, and in some embodiments, the coating comprises at least About 40% Vycar 12 460x63 latex and up to about 20% greening material. In some embodiments, the coating comprises 45-50% Vycar® 460x63 latex, and in some embodiments, the coating comprises at least about 45% Vycar® 460x63 Latex and up to about 5% of the greening material. It is known that Vycar® 460x63 itself is quite rigid, especially in cold climates. This can cause mounting problems when the coated film 100 is coated along the curve in the road. Other resinous candidates Vycar® 460x63 is also less resistant to liquid water than it is. Because of its relatively low solids content, it may be difficult to obtain the desired degree of absorption, and once absorbed, it may be difficult to dry the fabric sufficiently. In the example, the coating containing Vycar® 460x63 120 142390.doc 12 201105510 is formulated in such a way that the coating is softer and increases its solids content. The polymer in coating 120 can also be prepared from softer monomers. The water repellency problem can be solved by incorporating a wax additive (such as Hydrocer(R) 45) in an amount of about 3% by weight of the dry coating. This wax release agent also has a tendency to slightly soften the coating. The solids content is up to about 5 -6 mm, preferably about 55% or more. In addition to such improvements to the pvc latex, soluble polymerization can be incorporated in an amount of about 5-19% by weight of the dried coating. (such as Carboset 5 14W) to give the coating on the roll (pad r〇u) more set time and rewet. Other water soluble polymers, such as Michemprime polymer, can be used. Ammonia is added to a value of about 8 or 9. The ammonia may also be used to activate any alkali soluble thickener used in the composition. The thickeners may include commonly available thickeners, and preferably Cannot be used when sucking targets. ASE-60 or 6038A from Rohm and Haas (Philadelphia, PA) will be suitable for this application. A coloring agent (such as carbon black) in an amount of about 1% by weight and an antifoaming agent in an amount of up to about 5% by weight (such as NXZ or DEFO) is suitable for this application. Finally, plasticizers can be used to achieve the desired softness of the coating. Because ADMEX 3 14 is a non-volatile polymeric plasticizer and does not pose an environmental or health hazard, it is desirable And a content of about 2-5 wt% causes a significant change in the softness of the coating. Many alternative types of resins can be used for the surface layer 120 as long as it plastically flows at the paving temperature, the paving pressure, or both. The main examples are PVC, nylon, acrylic, HDPE and some polyethylene and polypropylene 142390.doc 13 201105510 and ethyl acetate (EVA), which provide the rigidity, compatibility and resistance to corrosion. . It can be applied using a heat, emulsion, solvent, & cure or light shot curing system. In some embodiments, the viscous film 1 〇〇 comprises a multilayer film. For example, the carrier layer 110 can be a multilayer film having a surface layer coating 12〇 coated thereon. In other embodiments, the entire viscous film 100 is a coextrudate and the surface layer 120 is a resin film that is coextruded with the carrier layer 110. The material of the surface layer 120 may be the same as that of the carrier layer 110, may include the same main components as the carrier layer no, or may have a different main component than the carrier layer 110. When any such alternative resin material is used for the surface layer 120, an anti-sticking agent (for example, a wax, a synthetic polymer, a small amount of talc powder) may be included in the surface layer 120 to prevent the adhesive film 100 from being in the form of a spiral roll. It is stored and self-adhesive when pulled away from the grid 10 during subsequent deployment. The slip agent may also be included in the surface layer 20 on one or both sides of the carrier layer 110. The above composition is significantly compatible with the asphalt surface 140 and the adhesive layer 135. It is allowed to bond strongly to the viscous membrane embedded in asphalt concrete. The solid adhesion between the pavement layers effectively reduces the stress distribution of the traffic on the surface layer. This solution prevents slippage, cracking, and delamination (called premature stress) caused or caused by lack of interfacial bonding. The coefficient of thermal expansion of the surface layer 120 approximates the coefficient of thermal expansion of the asphalt mixture. The surface layer 120 may avoid improper detachment at the interface of the film 100 due to discrete thermal behavior in the composite asphalt concrete. The enhanced interface condition provides an extended service life for the overlying surface greening layer 140 from significant road stress. 142390.doc 201105510 An example is described above wherein the carrier film 10 comprises a first material (eg, a polymer such as polyethylene) and the film 110 is coated with a second material 12 (eg, Vycar® 460x63 with an additive, as above) Said). However, other embodiments are contemplated in which the film 110 consists essentially of (or consists of) a non-leak tree-aware material (e.g., VyCar 8460x63 with an additive) used as a coating material 12 as described above. In these embodiments, the separate layer of coating material 12 can be omitted. Therefore, the viscous film layer may be a composite film or a homogeneous resin film. The choice of composite film or homogenous film and the choice of carrier film u〇 material may depend on material cost, ease of manufacture, and availability of each material, which can be readily assessed by one of ordinary skill in the art at any given time. The film 100 is preferably semi-rigid when impregnated with a resinous coating and co-extruded with the resinous film 12A, and can be rolled onto the core for easy transport to the pre-formed continuous assembly. Installation location where it can be easily spread out continuously for quick, economical and easy integration into the road. For example, the film 100 can be placed on a 15 inch (45 meter) wide roll that has a one piece construction that is 100 meters long or longer. Alternatively, the adhesive layer 135 may be covered by a number of narrower strips of the film 100, typically about five feet (1.5 meters) wide. Therefore, it is practicable to use the film 100 on all or substantially all of the surface of the adhesive layer 135, which is cost effective due to reduced labor. At the paving site, the film 1 is unfolded with the adhesive 122 facing downward and laid on the underlying pavement 135. When the coating film is 1 ,, the underlying paving surface 135 is preferably about 40-140 卞 ( 4.4-60. 〇. Spreading the adhesive film 100 and adhering to a backing layer or asphalt bonding layer η having a thickness of preferably about 0.75 吋 (19 mm) or 142390.doc 201105510 〇·75 temple (19 mm) or more; In some embodiments, an adhesive 122 (eg, a pressure sensitive adhesive) that is applied during manufacture of the film 100 may be applied prior to placing any of the overlying layer or asphalt surface layer 14 on the film stack (10). The membrane 100 is sufficiently stable that the membrane 1 is resistant to the forces on which the worker walking, the construction vehicle over which it is driven, and in particular the movement of the paving machine thereon. Although the membrane 100 is semi-rigid, It is easy to flatten. After it has been unfolded, it has a very small or even no rewinding tendency. This is due to the proper selection of the adhesive and/or surface layer resin. In some embodiments, as shown in Figure _2 It is shown that the surface-reformed pavement comprises a pavement 130 to be surface-reformed, a base layer 135, and a viscous composite film 100. And the surface layer 140' without the independent strengthening layer. In other embodiments, the adhesive film 100 is coated on the adhesive layer 135, the independent reinforcing layer is coated on the adhesive film 100, and the surface layer 14 is coated on the adhesive layer On the reinforcement layer, for example, the reinforcement layer can be a GlasGdd® product (eg, 8550, 85〇1, 85〇2, 8511, or 8512 grid) available from Saint G〇bain Fabrics. In other embodiments, such as As shown in Figures 3-6, the viscous membrane raft is included in the integral composite reinforced interlayer 200, 300 or 400. The integral composite 2 〇〇, 300 or 400 includes the viscous membrane layer 1 and the reinforcement layer. In some embodiments, the composite reinforced interlayer is a composite 2 包含 (Fig. 3) comprising a composite viscous film layer or a resinous viscous film layer 00 above the reinforcing layer 1 。. The adhesive 12 of the adhesive binds the adhesive layer 1〇〇 to the reinforcing layer 1。. The hot-melt adhesive can be pressure-sensitive or permanent. The reinforcing material is the bottom of the material 〇 142390.doc -16- 201105510 The surface (back to the viscous film layer 100) has an adhesive 11, such as a pressure sensitive adhesive, which causes the composite material 20 when the surface layer is coated. 0 is kept in place. In the configuration of Fig. 3, 'the hot-melt adhesive layer 丨2 bonds the viscous film layer 1 〇〇 to the underlying reinforcing layer 10, so the viscous film layer 〇〇 does not need its own adhesion. Layer 122. Further, the surface layer 14 is in contact with the top of the film layer 1 and no adhesive layer 122 is required on the surface of the film 1 . The adhesive layer 122 can be used in the composite material 200 of FIG. The viscous film is omitted from the 00. In some embodiments, the composite reinforced interlayer is a composite containing the composite viscous film layer or the reinforcing layer 10 above the resinous viscous film layer 100 (Fig. The viscous film layer 100 and the reinforcing layer 10 are bonded by an adhesive 12 which is a hot-melt adhesive. To ensure that the composite material 300 remains in place when the surface layer 140 is applied, the viscous film i (10) in the composite material 3GG includes on its bottom surface an adhesive 122 (which contacts the leveling layer 135) as shown in FIG. . In some embodiments, the composite reinforcing interlayer is a composite 400 (Fig. 5) comprising a reinforcing layer 1 sandwiched between a pair of composite adhesive film layers or a resinous adhesive film layer 1 (Fig. 5) In the following description, the viscous film (10) may be a composite having a carrier layer U0 and a surface layer (2), or a homogeneous film having a material suitable for use in a coating of the surface layer 120. There are no individual carrier layers 110 in them. In the composite, the adhesive layer i (10) and the reinforcing layer are bonded by an adhesive which is a heat-sensitive adhesive. In order to renew the bottom adhesive film (10) (which contacts the leveling layer 135) in which the composite material is held in the right position of the composite material layer M0, the adhesive layer as shown in FIG. 2 is included on the bottom surface thereof. 122. The top adhesive film layer (which contacts the surface layer, does not require an adhesive agent on the surface of the adhesive layer 122 can be omitted from the top 142390.doc 201105510 part of the adhesive film layer 100. The strengthening layer 10 can be a variety of reinforcing materials Any of the embodiments, in some embodiments, an open grid comprising at least two sets of substantially parallel strands 21 (shown in cross-section in Figures 7 and 8) is provided (shown in Figures 9 and 1) As a strengthening layer 10. Each set of strands 21 includes an opening 19 (Fig. 9) between adjacent strands 21, and the sets are oriented at a substantial angle to each other (e.g., about 90 degrees as appropriate). In some embodiments The reinforcement layer may be from a Saint Gobain Technical Fabri CS2 GlasGrid 8 product (eg 855 〇, 85 〇, 85 〇 2, "η or 85 12 grids". In some embodiments, the grid ίο preferably comprises a weft insertion Warp (weft_serted warp knit), wherein the strands 2丨 are oriented at an angle of about 9 to each other, as shown in Figure 9. The opening preferably has about 〇5. 5nfx 〇5忖〇2 mm X 12 mm) or more. Large size, but the opening can reach about 吋 1 吋. Although the opening 19 can be square 'but Inch "a" and "b" may be different, such as in the case of rectangles. In some embodiments, the non-asphalt coating 22 is disposed on the grid 1 without closing the opening σ between = 21 as best seen in Figure 8. The coating ^ is activated in the paving 'degree of pressure build-up pressure or both to form a bond/layer 22 compatible with the greening pavement without viscosity at ambient temperature and pressure' so that it can be used in Shibuya Take action. In some embodiments, the coating on the strand 2 is the same material as the coating 12 涂覆 applied to the polymeric film 110 in the composite adhesive film 1 . ~ Large grid opening not shown in Figure 9 allows for asphalt mixture. ^ and / or 4 strands / line 20 or roving of each strand 2, and allow the adhesive layer 1 〇〇 and 142390.doc 201105510 adhesive layer 135 and surface layer 140 between the full and substantial contact . The adhesive layer 100 substantially bonds the layers 135 and 14 through the opening 19 of the grid 10 to permit the transfer of stress from the paving surfaces 135, 140 substantially to the glass or similar fibers of the reinforcing layer. The resulting composite grid material has a high modulus and high strength to cost ratio, the expansion coefficient of which approximates the coefficient of expansion of the road construction material and its resistance to corrosion of materials used in road construction and in road environments such as road salt. The grid 10 may be formed from strands or yarns 21 of continuous filament glass fibers, but other high modulus fibers such as poly(p-xylylene terephthalamide) polyamine fibers may be used, known as Kevlar. ®. The 2000 tex 2ECR^E glass yarn is preferred, but we can also use a weight in the range of about 3 〇〇 to about 5 。. Preferred glass fiber yarns have a strand strength of about 560 lb/in (100 kN/m) or 56 〇 lb/in (1 〇〇 kN/m) a, and 5% when measured according to ASTM D6637. Or an elongation at break of 5% or less. These strands have a mass/unit area of less than about 22 〇z/yd2 (74 〇 g/m2) and more preferably about u g/m2). Preferably, the tertiary lines having a low degree of twist (i.e., about one turn or less per turn) form a grid having a rectangular or square opening 19 on one side (in Fig. 9, a J , "b" or The size of the two is preferably in the range of 3/4 吋 to 1 ,, but it is also possible to use the grid opening 19 in the range of 1/8 吋 to 6 一边 on one side ("a", "b" or both). . The grid 1 〇 is preferably tied or otherwise fixed at the intersection of the strand and the longitudinal strand by the thin line 25 shown in the figure. This connection keeps the thumb 1 〇 in its grille pattern, preventing the strands 2 1 from spreading out before the immersion with the non-asphalt coating 22 and 142390.doc •19·201105510, and retaining the opening 丨9, which allows The coating adheres to the underlying layer and thereby increases the strength of the final composite pavement restoration. The fixed connection at the intersection of the grids 10 also contributes to the strength of the grid 1 due to its partial transfer of forces parallel to one set of strands 21 to another set of parallel strands 21. At the same time, this open grid construction makes it possible to use less glass per square yard and thereby obtain a product that is, for example, more economical than a closed woven fabric. I prefer to use a grid of about 8 ounces per square yard, but I can also use 4 to square yards per square yard. Although we prefer to use a 7〇 to 15〇denier polyester thread 25 or equivalent on a warp-knit weft-weaving equipment to tie the grids together, it can also be used to form intersections. Other methods of fixing the grille. For example, non-woven lattices prepared with thermosetting or thermoplastic adhesives provide suitable strength. Once the grid 1 is formed, and it is joined to the viscous membrane! Prior to the crucible, the thermoplastic resin 22 is preferably coated. That is, the grid 1 is "pre-impregnated" with the resin 22. The viscosity of the resinous coating 22 is selected such that it penetrates into the strand 2j of the grid. Although the resinous coating 22 may not wrap each of the filaments 20' of the fiberglass strands 21, the resinous coating 22 is uniformly spread inside the strands 21 as shown in Fig. 8. This impregnation imparts a preferred semi-rigid nature to the strands 21 and alleviates and protects the strands 21 and glass filaments from water, salt, oil and other elements in the road surface environment. The impregnation also reduces abrasion between the glass strands 21 or filaments 20 and the cutting of one glass strand 21 or filament 2 by another glass strand or filament. The impregnation also reduces the tendency of the glass fibers to cut each other after the grid has been laid, but before the coating 140 is applied at 142390.doc • 20-201105510. The grid should preferably have a range of about 25 kilonewtons per square foot (kN/m), more preferably about 50 kN/m, and most preferably about 1 〇〇 kN/rn or 1 方向 in the direction of the individual strands and parallel strands. The minimum strength above kN/m, and preferably less than about 10. /. More preferably, the elongation at break is less than 5%. Preparing to dry or cure the preferred resinous coating 22 on the grid 1 allows the strands 21 to flatten slightly but retain the opening 19. For example, in a preferred embodiment using a 2 roving, a rectangular grid 1 具有 having an opening 19 of about 3/4 吋χ丨吋 (a = b = 0.75 吋) can be formed and The roving is flattened to about 丨/“吋 (1.6 mm) to 1/8吋 (3.2 mm) wide. The thickness of the roving after coating and drying can be about 1/32 吋 (0.8 mm) or 1/32 吋 (0.8 mm). The following. The preferred grid for fiberglass slaves is uncoated GlasGrid® products available from Saint_G〇bain Technical Fabrics (eg 8550, 8501, 8502, 8511 or 85 12). Many resins can be used for impregnation. The grid 10 can be plastically flowed at the paving temperature, paving waste force or both. The main examples are PVC, nylon, acrylic, HDPE and some polyethylene and polypropylene, which provide the desired rigidity. Compatibility and corrosion resistance. It can be applied using a hot melt emulsion, solvent, heat cure or radiation curing system, such as a coating containing a pvc emulsion (such as Vycar® 460x63). PVC emulsions can also include A quantity of wax release agent, and one or more of about 0 to 10% by weight selected from the group consisting of Other additives: soluble polymer, ammonia, thickener, carbon black, defoaming agents and plasticizers. Any material suitable for use as the coating 12 of the composite polymer film 100, such as any of the materials described above, can be used as the coating 22 for the grid. 142390.doc -21 201105510 In some embodiments, coatings 120 and 22 are the same material. In the coatings 120 and 22 are different materials, wherein each coating 12 is compatible with other embodiments, 22 and leached and can be activated by heat and/or pressure. Coatings 120 and 22 can be activated by pressure, helium, heat, or other means. When making

可活化樹脂之表面與未經處理之表面接觸且 。當使塗布有熱 S*施加熱量時, 該熱可活化樹脂形成黏結。與在周圍溫度(例如約72卞)及 周圍壓力(例如約Η固大氣壓)下具黏性之其他黏著劑相比, 塗層120及22較佳在周圍溫度或周圍壓力下無黏性,且僅 在近似鋪築壓力或溫度下變黏。 在大多數使用中’塗層120及22直至達到約120-140 (49_60°C)之塗布溫度,或塗覆約^.5吋(2S_38毫米)或卜 1.5吋(25-3 8毫米)以上之鋪面層,或同時實現該兩者時方 塑性流動或黏連。電子級玻璃纖維(E_glass fiber)之炫點為 約1800-1832°?(約1000°(:),其確保在經受鋪築操作之過度 熱量時穩定。 表面層140與黏合層135之間的剪切強度需要儘可能高, 且在格柵10所經受之極寬泛溫度範圍内,剪切強度需要相 當大。可在低至約40°F之周圍溫度下將黏性膜-格柵複合 物200、300或400安裝於鋪築底襯層上,且可在約25〇-320°F(121-160°C )、一般約 300°F (149。(:)之溫度下塗覆瀝 青混凝土,從而使塗層22溫度上升至約150°F(66t:)。因 此,吾人青睞於塗層120及22具有約66-77卞(2〇-25。〇或 142390.doc -22- 201105510 66-77°F(20-25°C)以上之熔點或玻璃轉移溫度Tg,且其較 佳在約120-140卞(50-60。〇以上、在鋪築所施加之典型壓 力下塑性流動。 一旦達到約265-300T(130-15(TC)之溫度,甚至在極低 壓力下仍有可能流動,諸如在塗覆極薄瀝青層時。此使得 塗層120及22能夠塑性流動以改良格柵1〇中及格柵1〇周圍 之表面層140與黏合層135之間的剪切強度。 塗層120及22之黏度應具有足夠流動性以流至格柵上, 但較佳具有足夠黏性以使其在塗覆或儲存期間不會自格柵 流出或流動穿過格柵,而實際上保留在格栅上。 實例1 製備下表1中所述之塗層22且將其塗覆於來自SaintThe surface of the activatable resin is in contact with the untreated surface. The heat activatable resin forms a bond when heat is applied to the coating with heat S*. The coatings 120 and 22 are preferably non-tacky at ambient or ambient pressure, as compared to other adhesives that are viscous at ambient temperatures (e.g., about 72 Torr) and ambient pressure (e.g., about tamping atmospheric pressure), and It only becomes sticky under approximate paving pressure or temperature. In most applications, 'coatings 120 and 22 up to a coating temperature of about 120-140 (49-60 ° C), or coating about 1.5 吋 (2S_38 mm) or 1.5 吋 (25-3 8 mm) or more The pavement layer, or both plastic flow or adhesion when both are achieved. E-glass fiber has an illusion of about 1800-1832° (approximately 1000° (:), which ensures stability when subjected to excessive heat from the paving operation. Shear between surface layer 140 and adhesive layer 135 The shear strength needs to be as high as possible, and the shear strength needs to be quite large over the extremely wide temperature range experienced by the grid 10. The viscous membrane-grid composite 200 can be applied at ambient temperatures as low as about 40 °F. , 300 or 400 is mounted on the paving underlayer and may be coated with asphalt concrete at a temperature of about 25 〇 - 320 ° F (121-160 ° C), typically about 300 ° F (149 ° (:)) The temperature of the coating 22 is raised to about 150 °F (66 t:). Therefore, it is preferred that the coatings 120 and 22 have about 66-77 卞 (2 〇 - 25. 〇 or 142390. doc -22 - 201105510 66-77 a melting point or glass transition temperature Tg above °F (20-25 ° C), and preferably at about 120-140 卞 (50-60 〇 above, plastic flow under typical pressure applied by paving. Once reached About 265-300T (130-15 (TC) temperature, even under very low pressure, it is possible to flow, such as when coating an extremely thin asphalt layer. This makes the coatings 120 and 22 plastic The shear strength between the surface layer 140 and the adhesive layer 135 around the grid 1 改良 in the grid 1 is improved. The viscosity of the coatings 120 and 22 should have sufficient fluidity to flow onto the grid, but Preferably, it is sufficiently viscous that it does not flow out of the grid or flow through the grid during coating or storage, but actually remains on the grid. Example 1 The coating 22 described in Table 1 below was prepared and Apply it to Saint from

Gobain Technical Fabrics之未經塗布 GlasGrid®產品(8501 或8511格栅)上: 適用於塗層120及22之較佳樹脂系統包括為液體或可經 液化以便浸潰長絲20之間的一些或所有空間之樹脂系統。 树月曰系統應在鋪桌溫度、鋪築壓力或兩者下活化以形成與 遞青鋪面相容之黏結。該等系統可包括熱固性樹脂,諸如 B級環氧樹脂、聚矽氧樹脂或酚系樹脂;或熱塑性樹脂, 諸如耐綸、聚乙烯、聚丙烯、聚胺基甲酸酯或聚氯乙烯。 在存在或不存在添加劑下’包括樹脂及溶劑混合物或純樹 月曰之增塑溶膠(plastisol)為適用替換物。理想聚氯乙烯乳 膠乳液系統之較佳成份及範圍提供於下表1中: 142390.doc -23- 201105510 表1 :較佳PVC塗層範圍 乾重% 乾重% —般描述 商品名稱 之寬範圍 之窄範圍 基礎PVC-丙烯酸系乳膠 Vycar 460x63 40-60 45-50 内增塑之PVC乳膠 Vycar 578 0-20 7-14 苯乙烯-丙烯酸系乳膠 Rhoplex AC-103 5 5-25 15-20 乙烯-丙烯酸乳膠 Michemprime 4983-40R 5-25 12-18 有機油/二氧化矽消泡劑 DeeFo 97-3 0-1 0.1-0.3 碳黑分散液 Helzarin black 0-5 0.5-2 ros防黏蠟分散液 Hydrocer 145 0-5 1-3 丙烯酸系溶液聚合物 Carboset 514 0-10 1.5-3.5 非離子界面活性劑 Sryfynol 104 PA 0-1 0.05-0.15 非離子界面活性劑 Sryfynol 104 PG 50 0-1 0.05-0.15 氟界面活性劑 Zonyl FSO 0-1 0.05-0.15 飽和氨水 28%氨 0-1 WET% 0-0.1 WET% 聚丙烯酸稠化劑 ASE-6038A 0-5 0.25-1/0Gobain Technical Fabrics' uncoated GlasGrid® product (8501 or 8511 grid): Preferred resin systems for coatings 120 and 22 include some or all of the liquids or may be liquefied to impregnate the filaments 20 Space resin system. The tree raft system should be activated at the table temperature, the paving pressure, or both to form a bond that is compatible with the grading. Such systems may include thermosetting resins such as Class B epoxy resins, polyoxyxylene resins or phenolic resins; or thermoplastic resins such as nylon, polyethylene, polypropylene, polyurethane or polyvinyl chloride. A plastisol comprising a resin and a solvent mixture or a pure tree in the presence or absence of an additive is a suitable alternative. The preferred composition and range of the ideal polyvinyl chloride latex emulsion system are provided in Table 1 below: 142390.doc -23- 201105510 Table 1: Preferred PVC coating range Dry weight % Dry weight % General description of the wide range of trade names Narrow Range Foundation PVC-Acrylic Latex Vycar 460x63 40-60 45-50 Internal Plasticized PVC Latex Vycar 578 0-20 7-14 Styrene-Acrylic Latex Rhoplex AC-103 5 5-25 15-20 Ethylene - Acrylic Latex Michemprime 4983-40R 5-25 12-18 Organic Oil / Ceria Defoamer DeeFo 97-3 0-1 0.1-0.3 Carbon Black Dispersion Helzarin black 0-5 0.5-2 ros Anti-stick Wax Dispersion Hydrocer 145 0-5 1-3 Acrylic Solution Polymer Carboset 514 0-10 1.5-3.5 Nonionic Surfactant Sryfynol 104 PA 0-1 0.05-0.15 Nonionic Surfactant Sryfynol 104 PG 50 0-1 0.05-0.15 Fluorine Surfactant Zonyl FSO 0-1 0.05-0.15 Saturated ammonia 28% ammonia 0-1 WET% 0-0.1 WET% Polyacrylic acid thickener ASE-6038A 0-5 0.25-1/0

DeeFo 97-3 可以 Foam Blast或 Dow Corning 143 0 聚石夕氧消泡 劑替代DeeFo 97-3 can be replaced by Foam Blast or Dow Corning 143 0 Ju Shi Xi Oxygen Defoamer

Helzarin black可以 Octojet black 104替代 ASE-603 8A可以 ASE-60替代 當以樹脂性非瀝青塗層22浸潰及塗布(圖8)時,黏性膜-格柵複合物200、3 00或400(圖3-5)較佳為半剛性的,且可 捲於芯體上以便容易地以預製連續組件之形式輸送至安裝 地點,在此地點處其可輕易地連續鋪開以便快速、經濟且 簡易地併入路面中。舉例而言,可將其置放於5呎(1.5公 142390.doc -24- 201105510 尺)寬之輕上’該等輥含有1GG碼或更長之單件結構。黏性 膜-格柵複合物細、300或·之安裝程序可與如上文關於 獨立黏! 生膜1〇〇所述相同。因此,在所有或實質上所有鋪 築表面上使用此黏性膜_格柵複合物2⑼、或4〇〇為切實 可行的《亦可用於強化局部裂縫加(圖諸如膨服接 縫。 格柵10雖然為半剛性的,但易於平置。在已展開之後, 八^有極小乃至無回捲趨勢。咸信此係歸因於黏合劑及/ 或塗布树脂的適當選擇以及在格柵2 〇中使用複絲強化股 線,較佳使用玻璃》 圖9中所示之大格栅開口丨9容許瀝青混合物完全包封紗 線21或粗紗之各股線20,且容許複合物200 ' 300、400與 黏合層135及表面層14〇之間完全且實質性的接觸。表面層 14〇較佳以約1.5吋(40毫米)或1.5忖(40毫米)以上之厚度安 置。所得複合物200、300、400具有高模數及高強度與成 本比’其膨脹係數近似於道路建設材料之膨脹係數,且其 抵抗用於道路建設及見於道路環境中之材料(諸如道路用 鹽)腐蝕。 综上所述,可認識到自黏著黏性膜可單獨或與開口式格 栅及樹脂性塗層組合用於瀝青鋪面用之強化物中,該樹脂 性塗層在鋪築溫度、鋪築壓力或兩者下活化以形成與瀝青 鋪面相容之黏結。 實例2 製備經聚合樹脂塗布之膜 142390.doc -25· 201105510 製備12.7微米厚之聚乙稀(pE)與聚丙烯(pp)掺合薄膜。 將膜穿孔’每25.4毫米之間隔具有〇5毫来直徑之開口以便 於=自所塗覆表面層之熱拌瀝青混合物之熱量轉移至下部 瀝青層,且使膜黏著於瀝青鋪面層。在2rc下將膜浸入呈 礼液形式之本體聚合(氯乙烯)pvc丙烯酸系共聚物中且 在100 C下將經塗布之膜在對流烘箱中乾燥2分鐘直至達成 每平方公尺膜上123公克塗層之殘留率。 膜較佳為帶有與瀝青系統強黏著之聚合樹脂的合成材 料。以下說明但不限制可用之薄膜: 聚乙烯 聚丙烯 聚乙烯與聚丙烯共聚物 聚酯 聚氯乙烯 玻璃纖維亶毛 熱塑性聚烯烴 乙烯乙酸乙烯酯 可用於製備非瀝青樹脂之一些較佳聚合物包括丙烯酸系 共聚物,亦即,丙烯酸系共聚物及聚氯乙烯丙烯酸系共聚 物。 表2提供不同基底材料之各種膜的機械測試數據,在該 等基底材料上以每平方公尺123公克之塗覆率塗覆PVC丙 烯酸系共聚物塗層。所測試之基底材料包括PE與PP之摻合 膜(樣品1)、聚酯膜(樣品2)、熱塑性聚烯烴膜(樣品3)及玻 142390.doc • 26- 201105510 璃纖維氈(樣品4)。 表2 :機械測試數據 _ - — 樣品 基底材料 (厚度以微米為單位) 斷裂拉伸力* (N/mm2) 斷裂剪切力** (N/mm2) 1 PE(80%)/PP(20%) (12.7) 1.91 1.24 2 聚酯 (12.2) 9.44 1.03 3 聚烯烴 (25.4) 5.14 1.54 4 玻璃纖維氈 (254) 13.83 0.92 *拉伸測試在60%濕度下、於2TC下遵循ASTM D638-02a方 案。 **鋪面系統中之膜的機械黏結係藉由對四吋(1〇〇毫米)直徑 之瀝青圓柱形樣本量測剪切強度來測定,該等樣本係根據 ASTM D6926-04使用馬歇爾裝置(Marshall apparatus)來製 備。將各膜置放於包括兩個瀝青層之樣本中且以每分鐘1 毫米之恆定位移速率進行剪切。 可在製造格栅10或複合產品200期間將壓敏性黏著劑11 塗覆於格柵10之底部以有助於安裝,在安裝後,格柵10為 複合物200之底層。黏著劑11之類型可不同於用於使預塗 布之膜100附著於格柵10上之熱熔性黏著劑12。若存在壓 敏性黏著劑11,則其係藉由向複合物200之經聚合樹脂塗 布之膜1 00之表面施加壓力來活化。若使用壓敏性黏著劑 142390.doc •27· 201105510 11則可此需要實f力來使膜展開;可使用牽引機或其他 機械方式黏著劑佳為合成材料且可以任何合適方式 塗覆於經預塗布之膜上’諸如藉由使用乳膠系统、溶劑系 統或熱熔系統。在較佳乳膠系統中,將黏著劑11分散於水 中’使用凹版印刷輥印刷於膜上,且乾燥。在溶劑系統 中,將黏著劑溶解於適當溶劑中,印刷於膜上,且隨後蒸 發溶劑。在熱溶系統中,可使黏著劑在儲集器中熔融,塗 覆於輥上,且以嚴密控制之刀口將其計量於輥上以在輥上 形成液體黏著劑之均-膜。隨後使格柵10與輥接觸且使黏 著劑轉移至格柵1 0底部。此等塗覆方法僅為例示性的,且 一般熟習此項技術者可輕易地選擇使用乳膠、溶劑或熱熔 系統來塗覆黏著劑之其他方法。 實例3 圖11為來自對塗層120及/或塗層22中所用之組合物所進 行之一糸列試驗之數據的曲線圖。數據用於確定遞青乳液 以何百分比可與塗層120中所用之非瀝青樹脂性材料摻 合,而不使剪切效能相對於非樹脂性塗層之剪切效能實質 性降級。 將遞青乳液與表1中所述之聚合樹脂摻合,其相對量係 以乾重之百分比計。使用6種不同樹脂/遞青比製備掺合樹 脂:聚合物 / 瀝青(100% 樹脂、75:25、50:50、25:75、 10:90 > 0:100) 0 將未經塗布之電子級玻璃格柵織物(稱為「原胚」)手動 浸入樹脂或樹脂/瀝青混合物中且完全浸潰並乾透。將經 142390.doc -28- 201105510 手動塗布之織物置放於一對瀝青圓片(四吋直徑之圓柱形 樣品)之間。根據ASTM D6926-04,在146。匚下由75次擊實 標準馬歇爾壓實機以瀝青混合物來建構各圓片。藉助於直 接剪切測試法進行剪切效能測試》 如圖11中所示,剪切強度在對於純遞青塗層之1 kN至對 於100%非瀝青樹脂之3.68 kN之間變化。根據擬合數據點 之曲線’在约30%樹脂下,剪切強度約為單獨瀝青乳液之 剪切強度的兩倍。在約50%樹脂下’剪切強度約為瀝青乳 液之剪切強度的2.4倍。在約75%樹脂下,剪切強度約為瀝 青乳液之剪切強度的3.5倍。在約80%樹脂下,約3 5 kN之 剪切強度幾乎與100°/。聚合樹脂之剪切強度(約3.7 kN)一樣 咼。因此,約75%至約80〇/。樹脂之混合物提供1〇〇%樹脂塗 層之幾乎全部強度’同時提供較大經濟性。 因此,若欲使用經摻合之塗層,則用於黏性膜1〇〇之表 面層120之材料較佳包括5〇%或5〇%以上與瀝青乳液摻合之 非遞青聚合樹脂。 圖12-14展禾另一實施例。圖12展示產品5〇〇,其包含第 一非編織聚合物基材及第二非編織聚合物基材5〇1、夾入 非編織聚合物基材501之間的強化纖維層51〇,及使強化纖 維層與非編織基材接合之黏著劑5丨2。網織物或稀鬆織物 5H)與基材5_結且製成任意多種寬度及/或長度之輕。 在-些實施例中,基材5〇1可包含聚醋非編織毛鼓棉 網。2聚醋非編織基材之重量各標稱為17.〇 ―或以 〇Z/yd2。厚度各為0.14 _或〇 〇〇56"。此等聚醋非編織物 142390.doc •29· 201105510 可蹲自 Shalag Shamir Non-w〇vens(Upper Galiiee, Israel)。 在其他實施例中,基材5〇1可為聚乙烯非編織毛氈,但亦 可使用其他材料,諸如聚乙烯_聚丙烯共聚物。與瀝青相 合之其他聚合物可用於基材5〇1(例如pvc、耐綸(聚醯 胺)、丙烯酸系物、HDPE及某些聚丙烯,其提供所要剛 性、相容性及耐腐蝕性卜在其他實施例中,基材5〇1可包 含由此等材料中之兩者或兩者以上或此等材料之一與不同 相容材料之組合製成的多層片材。 強化纖維層5 10包括玻璃纖維網織物或稀鬆織物,該網 織物或稀鬆織物包括至少第一組實質上沿加工方向定向之 乡線。紗線可包含ECR或電子級玻璃長絲。在其他實施例 中,可使用其他南模數纖維,諸如聚(對苯二甲醯對苯二 胺)之聚醢胺纖維,稱為「KEVLAR⑧」。 黏著劑512能夠在鋪築溫度、鋪築壓力或兩者下活化以 形成與瀝月鋪面相容之黏結。黏著劑5丨2較佳包含5〇·99重 1 % PVC乳膠乳液。在一些實施例中,黏著劑5 12為上表ι 中所述之PVC乳膠乳液。 現參看圖12,在一些實施例中,產品包括經強化纖維塗 布之汐線(例如玻璃纖維)的網織物或稀鬆織物5丨〇及兩個聚 酯非編織基材501。玻璃纖維網織物或稀鬆織物51〇係由 「渦輪技術(turbine techn〇iogy)」形成。渦輪技術涉及使 用配備有橫向紗線之旋轉渦輪頭且利用機械螺旋機構控制 紗線之検向間距。隨後以黏合劑浸漬及塗布玻璃纖維稀鬆 織物510。許多樹脂可用於黏合劑,只要其在鋪築溫度' I42390.doc •30· 201105510 鋪築壓力或兩者下塑性流動即可。在一些實施例中,黏合 劑為上表1中所述之Pvc乳膠乳液。在其他實施例中,黏 合劑可為丙燁酸系物、PVC、耐綸、HDPE及某些聚乙烯 及聚丙烯,其提供所要剛性、相容性及耐腐蝕性。黏合劑 可使用熱熔、乳液、溶劑、熱固化或輻射固化系統來塗 覆。在用黏合劑塗布紗線之後,立即使用黏著劑512將稀 鬆織物510層壓至兩個聚酯基材5〇ι。 在些貫細*例中,黏著劑5 12與黏合劑均為上表1中所述 之相同PVC乳膠乳液,且使用單一塗覆步驟用黏合劑/黏著 劑次潰紗線且用黏著劑5 12塗布紗線以供層壓步綠用。在 其他實施例中,可獨立於用黏合劑浸潰紗線5 1〇之步驟來 塗覆黏著劑512。舉例而言,若黏合劑與黏著劑512為彼此 不同之材料’則使用獨立黏著劑塗覆步驟。 在塗布網織物或稀鬆織物510之後,隨後使產品5〇〇固化 (例如在機器之乾燥區段中)且纏繞成成品輥。獲得玻璃纖 維稀鬆織物510夾入聚酯非編織基材之頂層5〇1與底層5〇1 之間的三層層壓產品500。 圖14展示製備圖12產品之裝置之一實例。自輕552饋送 頂部基材及底部基材501,其可為聚酯非編織材料。基材 501之方向可由饋送輥558控制。玻璃纖維稀鬆織物51〇經 由另一輥558饋送且通過含有塗布稀鬆織物51〇之塗料512 的容器。經塗布之稀鬆織物5 10自塗布容器中浸出且由一 或多個輥560、561重定向^頂部非編織層501及經塗布之 稀鬆織物510隨後在第一層壓輥554下通過,同時維持第二 142390.doc •31 · 201105510 層壓報556與輥561之間的張力,從而使稀鬆織物與頂部非 爲織^ 5〇1接合。隨後將頂部非編織層501與層至其之稀 鬆織物510 一起饋送通過另-層壓輥556,該層壓輥556使 底P非編織基材501與稀鬆織物51〇底部接合形成產品 5〇〇。隨後將層壓產品5〇〇饋入乾燥烘箱(未圖示)中。 在其他κ施例(例如圖13)中,玻璃纖維稀鬆織物包括沿 加工方向延伸之第一組紗線51〇m及實質上沿橫向定向之第 二組紗線5l〇c。在一些實施例中,稀鬆織物5i〇c、別爪沿 加工方向與橫向每吋包括三根紗線(每公分約一根紗線)。 母寸八有一根紗線之產品適於在低交通量區域之輔面中使 用。每吋較大支數之紗線可用於為中等交通量區域提供較 大強化。 在對方法作少許修改下,可使用與產品5〇〇(圖i 2)相同 之機器來製備產品6〇〇(圖13)。橫向紗線5 1 〇c鋪設於加工方 向纖維51〇m之上,且實質上垂直於加工方向。聚酯之頂層 501t自頂部饋送,但與稀鬆織物510m、510c—起穿過塗布 盤及塗布輥(未圖示)。此用來維持成品600中之紗線間距 (其中稀鬆織物510c介於頂層50It與稀鬆織物510m之間)。 黏合劑/黏著劑5 12恰於稀鬆織物離開塗布輥時塗覆於其 上’而後立即以如上所述之相同方式塗覆聚酯之底層 501b。 圖15展示使用產品500(圖12)或600(圖13)之鋪面組態 5 50。在維護及修復鋪面550期間,將瀝青黏合層235覆蓋 於具有裂缝231之現有舊鋪面230之上》舊鋪面230通常由 142390.doc •32- 201105510 碾輥(未圖示)紋理化或碾平,從而為黏合層235提供良好嚙 合表面。(或者,產品500及600可覆蓋於新瀝青/波特蘭 (Portland)水泥混凝土鋪面表面上0 ) 瀝青黏性塗料係以例如熱噴霧或乳液形式塗覆。塗覆率 可為約0.1加侖/平方碼至約〇·3加侖/平方碼。在噴塗瀝青之 後,由機械方式或手動方式將產品5〇〇或6〇〇碾軋至瀝青 中。瀝青在產品500、600與黏合層235之間形成黏結,且 亦被吸收至產品500或600中以形成防水薄膜β隨後,以多 種厚度之一塗覆瀝青混凝土上覆層24〇。 雖然本發明已依照例示性實施例加以描述,但其並不限 於此貫際上,本發明應廣泛地理解為包括在不脫離本發 明等效物之範疇及範圍的情況下可由熟習此項技術者獲得 之其他變型及實施例。 【圖式簡單說明】 圖1為根據—實例之瀝青鋪面的經重新鋪築區段之部分 橫截面側視圖; 圖2為圖1令所示之黏性膜之一實施例的詳細橫截面視 圖» 4圖3為包括圖2之黏性膜之第一黏性膜-強化複合材料之 橫截面視圖; 圖4為圖3中所示之黏‘(·生膜_強化複合材料之變化的橫 面視圖; •圖5為圖3中所示之黏性膜·強化複合材料之另一變化的 橫載面視圖; 142390.doc •33· 201105510 圖6為包括圖3-5中之任一者之黏性膜強化複合材料的 瀝青鋪面之經修復區段之部分橫戴面側視圖; 圖7為圖3-5之黏性膜-強化複合材料之一實施例中所用 之強化材料股線之橫截面視圖; 圖8為圖7之股線在用樹脂浸潰後該股線之橫截面視圖; 圖9為包含圖8之股線之強化格柵的平面圖; 圖10為圖9中所示之格柵中之交又點的詳細放大圖; 圖11展示圖2之材料的剪切效能; 圖12為強化物之另一實施例之橫截面視圖; 圖13為圖12之實施例之變化的橫截面視圖; 圖14為製備圖12之產品之裝置的圖解;及 圖15為用圖12或圖13之強化物修復之鋪面區段的橫截面 視圖。 【主要元件符號說明】 10 格柵/強化層/強化材料 11 黏著劑/壓敏性黏著劑 12 黏著劑/熱熔性黏著層 19 開口 20 紗線/長絲 21 股線/紗線 22 非瀝青塗層/塗層/熱塑性樹脂/樹脂/樹脂性塗 層 25 細線/聚酯細線 100 預製樹脂性膜或浸潰有樹脂之臈/黏性膜/複合 142390.doc -34· 201105510 110 120 122 130 135 140 150 200 230 231 235 240 膜/複合黏性膜/黏性複合膜/經塗布之膜/層間 黏挫膜/複合層/膜/黏性膜層/複合黏性膜層或 树月曰性黏性臈層/底部黏性膜/頂部黏性膜層/黏 眭層/最終複合路面修復物/複合聚合物膜 聚合物薄膜/载體膜/薄膜/膜/载體層 樹脂/聚合樹脂/塗層/非瀝青樹脂性塗層/樹脂 非瀝月塗層(或樹脂與瀝青材料之塗布組合 物)或膜/塗層或膜/表面層/熱塑性樹脂/表面層 塗層/第二材料/塗布材料/樹脂性膜 黏著劑/壓敏性黏著劑/黏著層 舊鋪面/現有道路表面/待表面重整之鋪面 瀝青黏合層/黏合層/鋪面層/基層/瀝青/瀝青混 凝土層/瀝青層/瀝青鋪面/下伏鋪面/整平層/瀝 青混合物/層 表面層/鋪面層/上覆表面層/瀝青/瀝青層/瀝青 舖面/遞青表面層/遞f表面/表面遞青層/遞青 混合物/層/鋪面/上覆層 鋪面區段/鋪面 整體複合強化間層/整體複合材料/複合物/複合 材料/黏性膜·格柵複合物/複合產品 舊舖面 局部裂縫/裂縫 瀝青黏合層/黏合層 瀝青混凝土上覆層 142390.doc •35- 201105510 300 400 500 501 501b 501t 510 510c 510m 512 550 552 554 556 558 560 561 600 整體複合強化間層/整體複合材料/複合物/複合 材料/黏性暝-格柵複合物 整體複合強化間層/整體複合材料/複合物/複合 材料/黏性膜-格柵複合物 產品/三層層壓產品/層壓產品 第一非編織聚合物基材及第二非編織聚合物基 材/非編織聚合物基材/基材/聚酯非編織基材/ 聚酯基材/頂層/底層/頂部基材及底部基材/頂 部非編織層/底部非編織基材 底層 頂層 纖維層/,.周織物或稀鬆織物/破璃纖維網織 物或稀鬆織物/破螭纖維稀鬆織物/紗線 第二組紗線/稀鬆織物/橫向紗線 第一組紗線/稀鬆織物/加工方向纖維 黏著劑/塗料 舖面組態/舖面 輥 第一層壓輥 第二層壓輥/層麗輕 饋送輥/輥 輥 輥 產品/成品 142390.doc • 36 -Helzarin black can replace ASE-603 with Octojet black 104. 8A can be replaced by ASE-60 when immersed and coated with resinous non-asphalt coating 22 (Fig. 8), viscous membrane-grid composite 200, 300 or 400 ( Figure 3-5) is preferably semi-rigid and can be rolled onto the core for easy transport to the installation site in the form of a prefabricated continuous assembly where it can be easily spread out continuously for quick, economical and easy The ground is incorporated into the road surface. For example, it can be placed on a light weight of 5 inches (1.5 s 142390.doc -24 - 201105510 ft.). These rolls contain a single piece structure of 1 GG yards or longer. Adhesive film-grid composite fine, 300 or · installation procedure can be as independent as above! The film is the same as described above. Therefore, the use of this viscous film _ Grid Composite 2 (9), or 4 〇〇 on all or substantially all paving surfaces is practical. It can also be used to strengthen local cracks (such as expanded joints. Although it is semi-rigid, it is easy to lay flat. After it has been unfolded, there is little or no rewinding tendency. This is due to the proper choice of adhesive and/or coating resin and on the grille 2 The use of multifilament-strengthened strands, preferably glass, is shown in Figure 9. The large grid opening 丨 9 allows the asphalt mixture to completely enclose the strands 20 of the yarns 21 or rovings, and allows the composite 200 '300, 400 is completely and substantially in contact with the adhesive layer 135 and the surface layer 14A. The surface layer 14 is preferably disposed at a thickness of about 1.5 吋 (40 mm) or 1.5 忖 (40 mm) or more. The resulting composite 200, 300, 400 have high modulus and high strength to cost ratio 'the expansion coefficient is similar to the expansion coefficient of road construction materials, and it resists corrosion of materials used in road construction and in the road environment (such as road salt). Said that self-adhesive The viscous film can be used alone or in combination with an open grid and a resinous coating for reinforcement in asphalt paving. The resinous coating is activated at paving temperature, paving pressure or both to form an asphalt pavement. Compatible Bonding Example 2 Preparation of Polymerized Resin Coated Film 142390.doc -25·201105510 Preparation of a 12.7 micron thick polyethylene (pE) and polypropylene (pp) blend film. Perforation of the film '25.4 mm per The openings are 〇5 mm in diameter to facilitate transfer of heat from the hot mix asphalt mixture of the coated surface layer to the lower asphalt layer and to adhere the film to the asphalt surfacing layer. The film is immersed in a gift liquid at 2 rc The bulk polymerized (vinyl chloride) pvc acrylic copolymer and the coated film was dried in a convection oven at 100 C for 2 minutes until a residual ratio of 123 gram of coating per square meter of film was achieved. Synthetic material with a polymeric resin that is strongly adhered to the asphalt system. The following description but not limited to the available film: Polyethylene Polypropylene Polyethylene and Polypropylene Copolymer Polyester Polyvinyl Chloride Fiberglass Wool Thermoplastic Polyene Hydrocarbon Ethylene Vinyl Acetate Some of the preferred polymers useful in the preparation of non-asphalt resins include acrylic copolymers, i.e., acrylic copolymers and polyvinyl chloride acrylic copolymers. Table 2 provides machinery for various membranes of different substrate materials. Test data, coating a coating of PVC acrylic copolymer on the substrate material at a coating rate of 123 grams per square meter. The substrate material tested included a blend film of PE and PP (sample 1), polyester. Film (Sample 2), thermoplastic polyolefin film (Sample 3) and glass 142390.doc • 26-201105510 Glass fiber felt (Sample 4). Table 2: Mechanical test data _ - — Sample base material (thickness in microns) Tensile strength at break* (N/mm2) Shear shear force** (N/mm2) 1 PE(80%)/PP(20%) (12.7) 1.91 1.24 2 Polyester (12.2) 9.44 1.03 3 Polyolefin ( 25.4) 5.14 1.54 4 Glass Mat (254) 13.83 0.92 * Tensile test Follow the ASTM D638-02a protocol at 2% at 60% humidity. **The mechanical bond of the film in the paving system is determined by measuring the shear strength of a cylindrical sample of four 吋 (1 mm) diameter asphalt, which is based on ASTM D6926-04 using Marshall (Marshall) Apparatus) to prepare. Each film was placed in a sample comprising two asphalt layers and sheared at a constant displacement rate of 1 mm per minute. The pressure sensitive adhesive 11 can be applied to the bottom of the grid 10 during manufacture of the grid 10 or composite product 200 to facilitate installation, and after installation, the grid 10 is the bottom layer of the composite 200. The type of the adhesive 11 may be different from the hot-melt adhesive 12 for attaching the precoated film 100 to the grid 10. If the pressure-sensitive adhesive 11 is present, it is activated by applying pressure to the surface of the film 100 coated with the polymer resin of the composite 200. If a pressure sensitive adhesive 142390.doc •27·201105510 11 is used, a solid force may be required to unfold the film; a traction machine or other mechanical adhesive may be used as the synthetic material and may be applied to the warp in any suitable manner. Pre-coated on the film 'such as by using a latex system, a solvent system or a hot melt system. In a preferred latex system, the adhesive 11 is dispersed in water' printed on the film using a gravure roll and dried. In a solvent system, the adhesive is dissolved in a suitable solvent, printed on a film, and then the solvent is evaporated. In a hot melt system, the adhesive can be melted in a reservoir, coated onto a roll, and metered onto the roll with a tightly controlled knife edge to form a homogenous film of liquid adhesive on the roll. The grid 10 is then brought into contact with the rolls and the adhesive is transferred to the bottom of the grid 10. Such coating methods are merely illustrative, and other methods of applying adhesives using latex, solvent or hot melt systems are readily selected by those skilled in the art. Example 3 Figure 11 is a graph of data from one of the array tests performed on the coatings used in coating 120 and/or coating 22. The data was used to determine what percentage of the dip emulsion could be blended with the non-asphalt resinous material used in coating 120 without degrading the shear performance substantially relative to the shear performance of the non-resin coating. The bidet emulsion was blended with the polymeric resin described in Table 1, in relative amounts as a percentage of dry weight. Blend resin was prepared using 6 different resin/cyanine ratios: polymer / bitumen (100% resin, 75:25, 50:50, 25:75, 10:90 > 0:100) 0 uncoated Electronic grade glass grid fabrics (referred to as "original embryos") are manually immersed in a resin or resin/asphalt mixture and fully impregnated and dried. The fabric hand-coated by 142390.doc -28- 201105510 was placed between a pair of asphalt discs (cylindrical samples of four turns). According to ASTM D6926-04, at 146. The squats were constructed from 75 standard compact Marshall compactors with an asphalt mixture. The shear performance test was carried out by means of the direct shear test. As shown in Fig. 11, the shear strength was varied from 1 kN for the purely green coating to 3.68 kN for the 100% non-asphalt resin. The shear strength is about twice the shear strength of the individual asphalt emulsion at about 30% resin based on the curve of the fitted data points. The shear strength at about 50% resin is about 2.4 times the shear strength of the asphalt emulsion. At about 75% resin, the shear strength is about 3.5 times the shear strength of the asphalt emulsion. At about 80% resin, the shear strength of about 35 kN is almost 100 °/. The shear strength of the polymeric resin (approximately 3.7 kN) is the same as 咼. Therefore, about 75% to about 80 〇 /. The mixture of resins provides almost all strength of the 1% resin coating while providing greater economics. Therefore, if a blended coating is to be used, the material for the surface layer 120 of the viscous film 1 preferably comprises 5% or more by weight of the non-cyanurized polymer blended with the asphalt emulsion. 12-14 show another embodiment. 12 shows a product 5〇〇 comprising a first non-woven polymer substrate and a second non-woven polymer substrate 5〇1, a reinforcing fiber layer 51〇 sandwiched between non-woven polymer substrates 501, and An adhesive 5丨2 that bonds the reinforcing fiber layer to the non-woven substrate. The mesh or scrim 5H) is bonded to the substrate 5_ and made into any of a variety of widths and/or lengths. In some embodiments, the substrate 5〇1 may comprise a polyester woven non-woven wool tissue web. 2 The weight of the polyester woven non-woven substrate is nominally 17. 〇 ― or 〇Z/yd2. The thickness is 0.14 _ or 〇 〇〇 56". Such polyacetal non-woven fabrics 142390.doc •29· 201105510 available from Shalag Shamir Non-w〇vens (Upper Galiiee, Israel). In other embodiments, the substrate 5〇1 may be a polyethylene non-woven felt, but other materials such as a polyethylene-polypropylene copolymer may also be used. Other polymers compatible with asphalt can be used on substrates 5〇1 (eg pvc, nylon (polyamide), acrylics, HDPE and certain polypropylenes, which provide the desired rigidity, compatibility and corrosion resistance. In other embodiments, substrate 5〇1 may comprise a multilayer sheet of two or more of such materials or one of such materials and a combination of different compatible materials. Included is a fiberglass mesh or scrim comprising at least a first set of lines oriented substantially in the machine direction. The yarns may comprise ECR or electronic grade glass filaments. In other embodiments, may be used Other southern modulus fibers, such as poly(p-xylylene terephthalamide) polyamine fibers, are called "KEVLAR8". Adhesive 512 can be activated at paving temperature, paving pressure or both to form The adhesive is compatible with the lining of the lining. The adhesive 5 丨 2 preferably comprises 5 〇 99% 1% of the PVC latex emulsion. In some embodiments, the adhesive 5 12 is the PVC latex emulsion described in the above Table ι. Referring now to Figure 12, in some embodiments, a product package Reinforced fiber coated crepe (for example, glass fiber) mesh or scrim 5 丨〇 and two polyester non-woven substrates 501. Glass fiber mesh or scrim 51 由 is made of "turbine technology" Iogy). The turbine technology involves the use of a rotating turbine head equipped with transverse yarns and the use of a mechanical screw mechanism to control the spacing of the yarns. The glass fiber scrim 510 is then impregnated and coated with an adhesive. Many resins can be used for the adhesive. As long as it is plastically flowing at the paving temperature ' I42390.doc •30· 201105510 paving pressure or both. In some embodiments, the binder is the Pvc latex emulsion described in Table 1. In other implementations In the examples, the binder may be a propionic acid, PVC, nylon, HDPE, and certain polyethylenes and polypropylenes, which provide the desired rigidity, compatibility, and corrosion resistance. The adhesive may use hot melt, emulsion, A solvent, heat curing or radiation curing system is applied. Immediately after the yarn is coated with the adhesive, the scrim 510 is laminated to the two polyester substrates 5 〇 using the adhesive 512. In the adhesive latex 5 12 and the adhesive are the same PVC latex emulsions as described in Table 1, and the yarn is coated with the adhesive/adhesive agent and the yarn is coated with the adhesive 5 12 using a single coating step. The lamination step is used in green. In other embodiments, the adhesive 512 may be applied independently of the step of impregnating the yarn with a binder. For example, if the binder and the adhesive 512 are different materials from each other 'There is then a separate adhesive coating step. After coating the mesh or scrim 510, the product is then cured (eg in a drying section of the machine) and wound into a finished roll. A fiberglass scrim 510 is obtained. A three-layer laminate product 500 between the top layer 5〇1 and the bottom layer 5〇1 of the polyester nonwoven substrate. Figure 14 shows an example of a device for preparing the product of Figure 12. The top substrate and bottom substrate 501 are fed from light 552, which may be a polyester nonwoven material. The direction of the substrate 501 can be controlled by the feed roller 558. The glass fiber scrim 51 is fed by another roller 558 and passed through a container containing a coating 512 of a coated scrim 51. The coated scrim 5 10 is leached from the coating container and redirected by one or more rolls 560, 561. The top non-woven layer 501 and the coated scrim 510 are then passed under the first laminating roll 554 while maintaining Second 142390.doc •31 · 201105510 The tension between the 556 and the roll 561 is laminated so that the scrim is joined to the top of the woven fabric. The top nonwoven layer 501 is then fed with the layer of the scrim 510 thereof through a further lamination roll 556 which joins the bottom P nonwoven substrate 501 to the bottom of the scrim 51 to form the product 5〇〇 . The laminate product 5〇〇 is then fed into a drying oven (not shown). In other κ embodiments (e.g., Figure 13), the fiberglass scrim includes a first set of yarns 51〇m extending in the machine direction and a second set of yarns 510c oriented substantially transversely. In some embodiments, the scrim 5i〇c, the other claws comprise three yarns (about one yarn per centimeter) per direction in the machine direction and the transverse direction. A product with a yarn size of 8 is suitable for use in the auxiliary surface of low traffic areas. A larger count of yarn per turn can be used to provide greater reinforcement for moderate traffic areas. With a slight modification of the method, the product 6〇〇 can be prepared using the same machine as the product 5〇〇 (Fig. i 2) (Fig. 13). The transverse yarns 5 1 〇c are laid over the machine direction fibers 51 〇 m and are substantially perpendicular to the machine direction. The top layer of the polyester 501t is fed from the top but passes through the coating pan and the coating roll (not shown) together with the scrim 510m, 510c. This is used to maintain the yarn spacing in the finished product 600 (where the scrim 510c is between the top layer 50It and the scrim 510m). The adhesive/adhesive 5 12 is applied to the scrim when it leaves the coating roll, and the polyester underlayer 501b is applied immediately in the same manner as described above. Figure 15 shows a pavement configuration 5 50 using product 500 (Figure 12) or 600 (Figure 13). During maintenance and repair of the pavement 550, the asphalt binder layer 235 is overlaid onto the existing old pavement 230 having the crack 231. The old pavement 230 is typically textured or flattened by a 142390.doc •32-201105510 roller (not shown). Thereby providing a good meshing surface for the adhesive layer 235. (Alternatively, products 500 and 600 may be applied over a new asphalt/Portland cement concrete surfacing surface. 0) Asphalt viscous coatings are applied, for example, as a thermal spray or emulsion. The coating rate can range from about 0.1 gallons per square yard to about 3 gallons per square yard. After spraying the bitumen, the product 5 or 6 turns is milled into the bitumen mechanically or manually. The asphalt forms a bond between the products 500, 600 and the adhesive layer 235 and is also absorbed into the product 500 or 600 to form a waterproof film β. Subsequently, the asphalt concrete overcoat layer 24 is coated in one of a plurality of thicknesses. The present invention has been described in terms of the exemplary embodiments, and the invention is not limited thereto, and the invention is to be construed as being limited to the scope of the invention Other variations and embodiments are obtained. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a partial cross-sectional side view of a re-paved section of an asphalt pavement according to an example; FIG. 2 is a detailed cross-sectional view of an embodiment of the viscous film shown in FIG. » 4 Figure 3 is a cross-sectional view of the first viscous film-reinforced composite material including the viscous film of Figure 2; Figure 4 is the viscous of the viscous film shown in Figure 3. Fig. 5 is a cross-sectional view of another variation of the viscous film reinforced composite material shown in Fig. 3; 142390.doc • 33· 201105510 Fig. 6 is a view including any of Figs. 3-5 Partial cross-sectional side view of the repaired section of the asphalt pavement of the viscous film reinforced composite material; Figure 7 is a reinforcing material strand used in an embodiment of the viscous film-reinforced composite material of Figures 3-5 Figure 8 is a cross-sectional view of the strand of the strand of Figure 7 after being impregnated with resin; Figure 9 is a plan view of the reinforcing grid comprising the strand of Figure 8; Figure 10 is a view of Figure 9 A detailed enlarged view of the intersection of the grid; Figure 11 shows the shearing performance of the material of Figure 2; Figure 12 shows another of the reinforcements. Figure 13 is a cross-sectional view of a variation of the embodiment of Figure 12; Figure 14 is an illustration of the apparatus for preparing the product of Figure 12; and Figure 15 is a modification of the reinforcement of Figure 12 or Figure 13 Cross-sectional view of the paving section. [Main component symbol description] 10 Grid/reinforced layer/reinforced material 11 Adhesive/pressure-sensitive adhesive 12 Adhesive/hot-melt adhesive layer 19 Opening 20 Yarn/filament 21 Strand/yarn 22 Non-asphalt coating/coating/thermoplastic resin/resin/resin coating 25 Thin line/polyester fine line 100 Pre-formed resin film or resin impregnated/viscous film/composite 142390.doc -34· 201105510 110 120 122 130 135 140 150 200 230 231 235 240 Membrane / composite adhesive film / viscous composite film / coated film / interlayer adhesive film / composite layer / film / adhesive film / composite adhesive Film layer or tree glutinous viscous layer / bottom viscous film / top viscous film / viscous layer / final composite pavement restoration / composite polymer film polymer film / carrier film / film / film / Carrier layer resin / polymer resin / coating / non-asphalt resin coating / resin non-leaf coating (or resin and leaching) Coating composition for green material) or film/coating or film/surface layer/thermoplastic resin/surface layer coating/second material/coating material/resin film adhesive/pressure sensitive adhesive/adhesive layer old pavement/ Existing road surface / surface re-formed pavement asphalt adhesive layer / adhesive layer / surfacing layer / base layer / asphalt / asphalt concrete layer / asphalt layer / asphalt pavement / underlying pavement / leveling layer / asphalt mixture / layer surface layer / paving Layer/Overlay Surface Layer/Asphalt/Asphalt Layer/Asphalt Pavement/Transmitting Surface Layer/F-F Surface/Surface Tanning Layer/Dividing Mixture/Layer/Pavement/Overlay Pavement Section/Pavement Composite Reinforcement Interlayer /Integrated Composites/Composites/Composites/Adhesive Membrane·Grating Composites/Composite Products Old Paving Partial Cracks/Cracks Asphalt Adhesive Layer/Adhesive Layer Asphalt Concrete Overlay 142390.doc •35- 201105510 300 400 500 501 501b 501t 510 510c 510m 512 550 552 554 556 558 560 561 600 Integral composite reinforced interlayer/integrated composite/composite/composite/viscous 暝-grid composite integral composite reinforced interlayer/integrated composite/composite /composite / viscous film - grid Composite product/three-layer laminate/lamination product first non-woven polymer substrate and second non-woven polymer substrate/non-woven polymer substrate/substrate/polyester non-woven substrate/polyester Substrate/Top/Bottom/Top Substrate and Bottom Substrate/Top Non-woven Layer/Bottom Non-woven Substrate Underlayer Top Layer/,.Wave Fabric or Scrim/Fracture Fabric/Scarf/Broken Fiber Scrim/Yarn Second Group Yarn/Sludge/Transverse Yarn First Set Yarn/Slurry Fabric/Processing Direction Fiber Adhesive/Coating Pavement Configuration/Pave Roller First Laminating Roller Second Laminating Roller/ Layer Li light feed roller / roller roller product / finished product 142390.doc • 36 -

Claims (1)

201105510 七、申請專利範圍: 1. 一種複合物,其包含: 開口式格栅’其包含至少兩組股線,各組股線在相鄰 股線之間具有開口,且該等組係以彼此成一定角定向;及 層壓至該開口式格拇之黏性膜’該黏性膜具有第一主 表面及第二主表面,且該黏性膜之該第一主表面及該第 二主表面具有瀝青樹脂性材料,該瀝青樹脂性材料包括 與佔該瀝青樹脂性材料約50%或50%以上之非瀝青樹脂 性組份組合的遞青組份。 2. 如請求項1之複合物,其中該黏性膜之該表面之該材料 為在鋪築溫度、鋪築壓力或兩者下活化以形成與遞青鋪 面相谷之黏結的類型,該塗層在約20。(:之溫度及約一個 大氣壓之壓力下無黏性。 3. 如請求項1之複合物,其中該樹脂性非瀝青材料包含由 以下組成之群中之至少一者:聚氣乙烯、丙烯酸系物、 聚乙稀、聚醯胺、聚丙烯及乙烯乙酸乙烯酯。 4. 如請求項1之複合物,其中該黏性膜之該第一主表面及 遺第二主表面之該材料進一步包含約1 -10重量%由以下 組成之群中之一或多者:可溶性聚合物、氨、稠化劑、 碳黑、消泡劑及增塑劑。 5. 如請求項1之複合物,其中該材料進一步包含層壓至該 開口式格柵之與該第一黏性膜相反之面的第二黏性膜, 該第二點性膜具有第一主表面及第二主表面,使得該第 一黏! 生膜之該第—主表面及該第二主表面之材料為樹脂 142390.doc 201105510 性非瀝青材料或包括約50%或50%以上樹脂性非瀝青組 份及約50%或50°/。以下瀝青組份的材料。 6· —種鋪面結構,其包含: 瀝青鋪面材料黏合層; 鋪設於該黏合層上之複合材料層,其包含: 開口式格柵,其包含至少兩組股線,各組股線在相鄰 股線之間具有開口,且該等組係以彼此成一定角定向,及 層壓至該開口式格柵之黏性膜,該黏性膜具有第一主 表面及第二主表面,且該黏性膜之該第一主表面及該第 二主表面具有瀝青樹脂性材料,該瀝青樹脂性材料包括 與佔該瀝青樹脂性材料約5〇%或5 〇%以上之非瀝青樹脂 性組份組合的瀝青組份;及 處於該複合材料上之瀝青材料表面層。 7.如請求項6之鋪面結構,其中該黏性膜之該第一主表面 及該第二主表面之該材料包含聚氯乙烯丙烯酸系乳膠材 料。 > 8. 9. 如請求項6之鋪面結構,其中該黏性膜包含塗布有該聚 氣乙烯丙烯酸系乳膠材料之載體基材。 如吻求項6之鋪面結構,其中該複合材料進一步包含層 壓至該開口式格柵之與該第一黏性膜相反之面的第二黏 I·生膜’該帛二點性膜具有帛一主表面及帛二主表面,使 得該第二黏性膜之該第一主表面及該第二主表面之材料 為樹脂性非瀝青材料或包括約5〇%或5〇%以上樹脂性非 瀝青組份及約50%或5〇%以下瀝青組份的材料。 142390.doc 201105510 ιο· —種製備複合物之方法 &,其包含: 提供開口式格柵, 相鄰股線之間具有開 向;及 其包含至少兩組股線,各組股線在 口’且該等組係以彼此成實質角定 將黏性膜層壓至該開口式格柵,該黏性膜具有第一主 表面及第二主表面,且該黏性膜之該第一主表面及該第 二主表面具有瀝青樹脂性材料,該瀝青樹脂性材料包括 與佔該瀝青樹脂性材料約5〇%或50%以上之非瀝青樹脂 性組份組合的瀝青組份。 142390.doc201105510 VII. Patent Application Range: 1. A composite comprising: an open grille comprising at least two sets of strands, each set of strands having an opening between adjacent strands, and the sets are each other An angled orientation; and an adhesive film laminated to the open-type thumb. The adhesive film has a first major surface and a second major surface, and the first major surface and the second major of the adhesive film The surface has a pitch resinous material including a combination component of a non-asphalt resinous component in an amount of about 50% or more of the pitch resinous material. 2. The composite of claim 1 wherein the material of the surface of the viscous membrane is activated at a paving temperature, a paving pressure, or both to form a bond to the valley of the greening pavement. The layer is at about 20. (The temperature is at a pressure of about one atmosphere and is not viscous. 3. The composite of claim 1, wherein the resinous non-asphalt material comprises at least one of the group consisting of: polyethylene, acrylic 4. The composite of claim 1, wherein the material of the first major surface and the second major surface of the viscous membrane further comprises About 1 to 10% by weight of one or more of the group consisting of: a soluble polymer, ammonia, a thickener, carbon black, an antifoaming agent, and a plasticizer. 5. The composite of claim 1, wherein The material further includes a second viscous film laminated to a face of the open grid opposite the first viscous membrane, the second glazing film having a first major surface and a second major surface such that the first a sticky material of the first major surface and the second major surface of the green film is a resin 142390.doc 201105510 non-asphalt material or comprises about 50% or more of a resinous non-asphalt component and about 50% or 50 ° /. The material of the following asphalt components. 6 · - a kind of pavement structure, its package : an adhesive layer of asphalt pavement material; a composite material layer laid on the adhesive layer, comprising: an open grid comprising at least two sets of strands, each set of strands having an opening between adjacent strands, and the The groups are oriented at an angle to each other and laminated to the viscous membrane of the open grid, the viscous membrane having a first major surface and a second major surface, and the first major surface of the viscous membrane And the second major surface has a pitch resinous material comprising a bitumen component combined with a non-asphalt resinous component of about 5% or more by weight of the bituminous resinous material; 7. A surface layer of a bituminous material on a composite material. 7. The paving structure of claim 6, wherein the material of the first major surface and the second major surface of the viscous film comprises a polyvinyl chloride acrylic latex material. 8. The paving structure of claim 6, wherein the viscous film comprises a carrier substrate coated with the polyglycol acrylic lacquer material, such as the pavement structure of Kiss 6, wherein the composite further comprises lamination To the opening a second adhesive I. green film of the opposite side of the first adhesive film, the two-dimensional film has a first major surface and a second major surface, such that the second adhesive film The material of a major surface and the second major surface is a resinous non-asphalt material or a material comprising about 5% or more 5% of the resinous non-asphalt component and about 50% or less 5% of the asphalt component. .doc 201105510 ιο· A method of preparing a composite & comprising: providing an open grid with an open direction between adjacent strands; and comprising at least two sets of strands, each set of strands at the mouth' And the groups are laminated to the open grid at a substantial angle to each other, the viscous membrane having a first major surface and a second major surface, and the first major surface of the viscous membrane And the second major surface has a pitch resinous material comprising an asphalt component combined with a non-asphalt resinous component of about 5% or more by weight of the asphaltary resinous material. 142390.doc
TW98126240A 2009-08-04 2009-08-04 Composite with tack film for asphaltic paving, method of paving, and process for making a composite with tack film for asphaltic paving TW201105510A (en)

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