201102050 六、發明說明： 【發明所屬之技術領域】 一種牙模及其製作方法。 【先前技術】 習知的牙模係由一熱塑物料所製成，該物料具有近似口腔之 ^ 需製作牙模部分的構形且此熱塑物料亦具有一種甚低的玻璃轉換 溫度，故可以在口腔外將該牙模加熱至高於其玻璃轉換溫度，然 後再置入人體之口腔内，用手在人體之口腔捏塑使之與牙齒部分 氆切付合。該熱塑物料具有一種高於體溫之玻璃轉換溫度，因此 當牙模在人體口_冷卻至低於其玻师換溫㈣，即可形成一 種剛硬結構，故該牙模可用作為—種正確符合人體口腔之塑製結 構。 . 此外，牙1診所或醫随專業的牙鄕作方法，則是利用具 (有可塑性的黏土與病人的牙齒緊密貼合，以取得吻合牙齒的牙 1之後利用石膏等卿材料形成_牙模，接著制用固.態牙 作套置於病人牙齒的牙模，該牙模製作技術為習知，故不於 劑、牙的功能頗多’可以在牙模内塗抹或置放要氟 俾翕#丨、η藥劑’再將牙模套1於使財的牙齒上， 、牙齒美㈣!或其他_可與牙齒觸錢離唾液。 201102050 舉例言之’牙齒美白在現今的科技之下，可採用雷射激光或 雙氧水複方藥劑塗抹兩項方法。雷射激光需到牙科診所請牙醫師 執行美白手術，美白效果良好，均勻程度由醫師控制可達相當水 準，安全程度亦高，但是費用高昂。雙氧水複方藥劑塗抹方法用 藥價廉’使用方法簡單’通常是使用者自行塗抹於口腔内牙齒上， 但疋谷易有塗抹不勻（牙齒與齒縫），及唾液中所含酵素干擾雙氧 水複方藥劑的問題，故美白的致果並不均勻與有效，同時相當高 比例的藥劑和唾液一起被吞食而下，在安全上亦有疑慮。 上述習知使用美白藥劑的問題，雖然可以透過牙模的輔助而 達到可將_與唾液作隔離，但仍然存在—㈣題，透過牙醫診 所或醫院與牙模技師製作的牙模，於套置時能與牙齒作較緊密的 …’因此較可克服藥劑和唾液—起被吞食的問題，然而此種牙 模裝作較費時且費用亦⑥，並不適合短暫少次或需頻繁替換牙模 的使用者，且該牙翻面與牙持__分不具有辅助藥劑擴散 =佈的特性，除非能夠將咖均勻塗抹在牙模關，否則會產生 藥劑無法平均與牙齒接觸的問題m祕習知技術所提 及的熱塑性牙模，_、有細者自行操作使㈣便獅，但内面 二牙=接觸的部分同财具錢助藥麵散分佈的躲，故仍會 藥劑.’、、法平均與牙#接_問題。即便能順綱將藥劑平均 、晶^齒接觸’然藥劑有特定的作用與療程時間，使用者在使用 並—衫握藥劑是否已經翻料，故會造成提前或過晚 201102050 再者則述驾知熱塑型牙模於塑型前的加熱過程中，需置於 一定範圍的溫度環境中，然使用者除非自備溫度計，否則僅能憑 經驗大致的判斷溫度是否在玻璃轉換溫度以上且不致過高，使用 上甚為不便。 如何解決上述習知牙模的種種缺點，遂成為業界的主要課題。 【發明内容】 本發明之主要目的，在於提供一種能透過簡易的操作即能形 成緊密貼合牙齒的牙模及其製法。 本發明之另一目的，在於提供一種能均勻擴散分佈置於與牙 齒接觸面的物質的牙模及其製法。 本發明之又一目地，在於提供一種能提示牙模成型過程中操 作溫度範圍的牙模。 本發明之再一目地，在於提供一種能提示形成於牙模與牙齒 接觸表面之藥劑作用完成之牙模。 為達成以上種種目地，本發明之牙模包括熱融固型樹脂以及 與熱融固型樹脂相結合之纖維布。 於本發明之一種型態中，復包括溫度感測元件，用以偵測熱 融固型樹脂於熱融塑型過程中的操作溫度。 於本發明之一種型態中，復包括用藥強度指示元件，用以提 示形成於牙模與芽齒接觸表面之藥劑的作用狀態。 該牙模之製法包括製備熱融固型樹脂以及纖維布，接著將熱 融固型樹脂與纖維布相接合。 201102050 相較於習知技術’本發明之牙模及其製法，透過簡易的操作 即能形成緊选貼合牙齒的牙模，該牙模除能均勻擴散分佈置於與 牙齒接觸面的物質外，透過溫度感測元件，復能偵測熱融固型樹 脂於熱融塑型過程中的操作溫度，而透過用藥強度指示元件，則 能提示形成於牙模與牙嵩接觸表面之藥劑作用完成。 【實施方式】 以下係藉由特定的具體實施例說明夯發明之實施方式，熟悉 此技藝之人士可由本說明書所揭示之内容輕易地瞭解本發明之其 他優點與功效。本發明亦可藉由其他不同的具體實施例加以施行 或應用’本說明書中的各項細節亦可基於不同觀點與應用，在不 惊離本發明之精神下進行各種修飾與變更。 明參閱第1圖’其係本發明之牙獅結構示意圖。如圖所示， 本發明之牙模包括_固型樹脂1()以及與熱融㈣樹脂1〇相結 合之纖維布11。 於本發明之較佳實施例中，熱融固型樹脂10與纖維布U係 透過加熱壓合方式結合。熱賴型樹脂1Q可 vinyl acetate)或者 TPUCThermoplastic Poly-Urethane)材 質然.不以此為限，其材質採用的性質範圍只要是符合第一玻璃 轉化/皿度範圍;^7G〜95°C，第二玻璃轉化溫度範圍是丨㈣赃之 條件即可。賴維布11絲⑽簡料、鹤布或水溶性壓克 201102050 力樹脂等糾崎態或杨祕質為顧。纖神u以及加壓熱 合製法容後詳述。 "树明之牙模之較佳者係具有孔_ 40〜6_積比，且孔隙 直徑騎值落在2Q〜5Q _之間，而成品具耐化性且無毒性的問 題。 請參閱第2圖’其係本發明之牙模製造方法的流程圖。如圖 籲所示’於步驟S10中，製備熱融固型樹脂10以及纖維布U。於本 發明中，較佳者，熱融固型樹脂1〇採用Tpu(Therm〇piastic⑽ ♦ Urethane，分子量！，_,_)，性質範圍係第一玻璃轉化溫度 範圍為70〜95。(：，第二玻璃轉化溫度範圍為14〇〜職。於本發明 卜較佳者’熱融固型樹脂10與纖維布H的截面積相同，或纖 維布11的截面積略小於熱融固型樹月旨1〇的截面積，且牙模的形 狀約等於上顆齒列及/或下顆齒列靑曲的弧度’而其寬度至少足以 齡包覆上顎齒列及/或下顎齒列。接著遠至步驟。 於步驟S11中’令熱融固型樹脂10與纖維Ϋ11進行熱塵合 程序。於本實施财，題合程序賴作條件是直接溫度是第一 破璃轉化溫度範圍以上5〜HTC，壓合力量在1G,gf/ciQ2，並施予 5 kHz以上的超音波’操作時間3〜5秒。上述的製法與條件可以確 保熱融_樹脂10及纖維布U之壓合強度，亦不損失纖維布u 之控制釋放能力。㈣品通過撕裂實驗，證實力足夠；再經 過水銀壓入實驗，孔隙率自53%降至41%。 201102050 較佳者’於本實施射，纖維布u之製法可例如但不限定為 先製備脫脂鮮m瓶脂㈣布涵浸於？基纖維素濃度 1〜15% (分子量100,000〜800,000)之甲醇溶液；接著，自甲醇溶^ 中取出脫脂棉紗布’於該赌棉紗布之甲醇溶液乾贿，於脫月旨 棉紗布表面喷塗水溶性壓克力樹脂（固形份丨〇〜3〇%、分子量 500,000〜2’_，GGG);之後，進人烤箱以95〜12{rc (是否有合理 操作溫度範圍如幾度到幾度之間）烘烤乾酒，即能形成纖維布⑴ 透過上述製法所產生的纖維布11，經過水銀壓入實驗達到的 性質是：孔隙率53%體積比、孔隙直徑高峰值落在32〜34以m之間、 分配率92% ;製成品放入30%的過氧化氫之十進行溶出實驗，pH 值〇. 1〜8· 5的範_，無促化氧氣析岐應，其後對過氧化氣溶 液進行IR、UV、VIS掃描，亦無溶出物質，證明其具有耐化性。 請參閱第3圖，其係透過本發明之牙模製法所製成之牙模的 剖面示意圖。如圖所示，透過本發明之牙模製法，熱融固型樹脂 10及纖維布11即可緊密結合。 於本發明之另一實施例中，復包括溫度感測元件12，係用以 偵測熱融固型樹脂10於熱融塑型過程中的操作溫度。於本實施例 中，溫度感測元件12係由熱敏顯色微膠囊與二劑型之環氧樹脂相 所組成，其製法可例如但不限定為熱敏顯色微膠囊與二劑型之環 氧樹脂注入細矽膠管之模具，待其固化後取出即為溫度感測元件 12。熱敏顯色微膠囊可採用日本東麗公司或是默克公司所開發的 產品，熱敏顯色微膠囊應選用75〜8(TC變色的產品，較佳者，其遲 201102050 滯時間1分鐘以内。透過前述製法所製成的溫度感測元件12，對 於溫度的反應靈敏，而且完全無毒性。溫度感測元件12係與熱融 固型樹脂10及/或纖維布11接合。 於本發明之又一實施例中，復包括用藥強度指示元件13，用 以提示形成於牙模與牙齒接觸表面之藥劑的作用狀態。用藥強度 指示元件13是將氧化還原指示劑、電解質、水溶膠體作成鹽橋之 (· 型式。前述之氧化還原指示劑可為靛胭脂[C16H10N208S2(indig〇 carmine)],電解質可為氯化卸或納，水溶穋體可為洋菜或者明 膠。前述製法所完成的用藥強度指示元件13，對於氧化劑的反應 靈敏，而且完全無毒性，符合口腔内使用之需求。於較〃佳實施例 中’製作方法是將先將氧化還原指示劑配製成3%、電解質配製成 15%、水溶膠體配製成9%，並先各自加熱到約9〇°c，拌合後注入 模具，降溫固化後取出後即為用藥強度指示元件13。前述製法所 φ 完成的用藥強度指示元件13，對於氧化還原電位的反應如表1所 示’反應遲滯短於人所能觀察的範圍内。 電位值（伏 特） -1.8 ~1. 35 -0.9 -0.45 顯色 綠色 赭紅色 紅色 黃色 表1 :靛胭脂對氧化還原電位之反應 於表1中，電位為相對於氫標準還原電位，其反應是2jj2〇 = 祕+2H+ + 2e— ’而氧化還原電位之控制是利用控制脇的活性度。 201102050 請參閱第4圖，其係本發明之牙模塑型之流程圖。透過塑型 步驟’可以將牙模塑型成吻合使用者上顎齒列及/或下顎齒列的牙 模。於本實施例中，為便於完整說明，本發明之牙模係包括溫度 感測元件與用藥強度指示元件，然於其他實施例中，可選擇性地 不包括溫度感測元件及/或用藥強度指示元件。 於步驟S20中，將牙模置入熱水内加熱（於不同的實施例令 可以使用其他的加熱方法）。接著進至步驟S21。 於步驟S21中’透過溫度感測元件的顏色變化判斷熱水溫度。 於本實施例中，設當溫度感測元件的顏色變成粉紅色的時候即已 達75 C以上，亦即熱融固型樹脂已達可塑型的狀況。接著進至步 驟 S22。 於步驟S22中，將牙模片自熱水中取出。接著進至步驟兕3。 .於步驟S23中’將溫度感測元件取下。接著進至步驟S24。 於步驟S24 +，將牙模置入使用者口中，其中具有纖維布之 表面貼於牙齒，再將一端於上顎齒列及上唇（或下顎齒列及下唇） 之間’並沿著牙緣向σ腔内彎折，用手指將牙模向牙齒密著壓合。 待硬化4，即完成屬於自己牙齒型狀的牙模之製作。接著進至步 驟 S25。 於步驟S25+，在進行牙齒美白或保健時，使用者將美白劑 或如氟劑等保健劑（於其他實施例中可為不同種類之藥劑）塗抹 於牙模上之纖維布上。接著進至步驟S26。 201102050 昭盖於_26中’將塗抹美白細_之牙縣上牙齒，按 =美白劑或保健劑說明書上的使用時間、限制及週期，進行牙齒 、白或保健。翻充說明者，當剛戴上牙_，美___ 的乳化力最高，用藥強度指示元件應為綠色（於不同的實施例可 =他顏色）’當氧化力消退時’用藥強度指示元件會先變成紅 口色（於不_實_可為其他顏色）錢黃色（於刊的實施例 w為其他顏色）’即表示美白劑或保健劑的藥效已;肖耗完畢。接 著進至步驟S27〇 於步驟S27中，使用者可將牙模取下，完成美白或保健工作。 本發明之牙模及其製法，透過簡易的操作即能形成緊密貼合 牙齒的牙模’該牙模除能㈣擴散分佈置於與牙鐘觸面的物質 外，透過溫度感測元件’復能侧熱融_概於熱融塑型過程 甲的操作溫度’而透㈣度指示元件，難提示形成於牙模 (鲁與牙齒接觸表面之藥劑作用完成。 上述實施例僅為例示性說明本發明之原理及其功效，而非用 於限制本發明。任何熟習此項技藝之人士均可在不違背本發明之 精神及範疇下，對上述實施例進行修飾與變化。因此，本發明之 權利保護範圍’應如後述之中請專利範圍所列。 【圖式簡單說明】 第1圖係本發明之牙模的結構示意圖； 第2圖係本發明之牙模製造方法的流程圖； 201102050 第3圖係透過本發明之牙模製法所製成之牙模的剖面示意 圖；以及 第4圖係本發明之牙模塑型之流程圖。 【主要元件符號說明】 10熱融固型樹脂 11纖維布 12溫度感測元件 13用藥強度指示元件 S10、S11 步驟 S20〜S27步驟201102050 VI. Description of the invention: [Technical field to which the invention pertains] A dental mold and a method of manufacturing the same. [Prior Art] A conventional dental mold is made of a thermoplastic material having a configuration similar to that of an oral cavity, and the thermoplastic material also has a very low glass transition temperature. The dental mold can be heated outside the oral cavity to a temperature higher than its glass transition temperature, and then placed in the oral cavity of the human body, and the human body is kneaded by hand to make it meet with the tooth portion. The thermoplastic material has a glass transition temperature higher than the body temperature, so when the dental mold is cooled to a temperature lower than the temperature of the glass (4), the dental mold can be formed into a rigid structure, so the dental mold can be used as a correct type. It conforms to the plastic structure of the human mouth. In addition, the dental 1 clinic or the medical professional's gingival method is to use the plastic (the plastic clay is closely attached to the patient's teeth to obtain the teeth of the anastomosed teeth 1 and then formed with gypsum and other materials) Then, the solid tooth is placed on the dental mold of the patient's teeth. The dental mold making technique is conventional, so there is a lot of function of the agent and the tooth, and the fluoroquine can be applied or placed in the dental mold.翕#丨,η药', then put the dental mold on the teeth of the wealth, the beauty of the teeth (four)! Or other _ can touch the teeth from the saliva. 201102050 For example, 'teeth whitening under the current technology, Laser laser or hydrogen peroxide compounding agent can be used to apply two methods. Laser laser needs to go to the dental clinic to perform the whitening operation. The whitening effect is good, the degree of uniformity can be controlled by the doctor to a considerable level, and the safety level is high, but the cost is high. The method of applying hydrogen peroxide compounding agent is cheaper than 'the method of use' is usually applied by the user to the teeth in the mouth, but the sputum is easy to spread unevenly (teeth and teeth), and the yeast contained in the saliva Interfering with the problem of hydrogen peroxide compounding agent, the whitening result is not uniform and effective, and a relatively high proportion of the drug and saliva are swallowed together, and there are doubts about safety. The above-mentioned problems of using whitening agents, although Through the aid of the dental mold, it can be separated from saliva, but still exists - (4). The dental mold made by the dentist or the hospital and the dental mold technician can be tightly placed with the teeth when placed... It can overcome the problem of swallowing of the medicament and saliva. However, the dental mold is more time-consuming and costly. It is not suitable for users who need to replace the dental mold frequently or temporarily, and the tooth is turned over and the teeth are held. __ does not have the characteristics of auxiliary drug diffusion = cloth, unless the coffee can be evenly applied to the die, otherwise it will produce the problem that the drug can not be in contact with the teeth on average. The thermoplastic dental mold mentioned in the prior art, _, There are finers who operate on their own to make (4) lions, but the inner two teeth = the part of the contact with the wealth of money and drug aids scattered, so it will still be pharmacy. ', , the average and the tooth # _ problem. Even if it can The average dose of the drug and the contact of the crystal teeth have a specific effect and treatment time. Whether the user has used the medicine and the medicine to hold the medicine, it will cause the advance or late 201102050. In the heating process before molding, the dental mold should be placed in a certain range of temperature environment. However, unless the user prepares a thermometer, the user can only judge whether the temperature is above the glass transition temperature and is not too high. It is inconvenient to solve the problem. How to solve the various shortcomings of the above-mentioned conventional dental molds has become a major problem in the industry. SUMMARY OF THE INVENTION The main object of the present invention is to provide a tooth capable of forming a close-fitting tooth through a simple operation. Another object of the present invention is to provide a dental mold capable of uniformly diffusing a substance disposed on a contact surface with a tooth and a method of manufacturing the same. Another object of the present invention is to provide a mold forming process capable of prompting a dental mold. The dental mold in the operating temperature range. Still another object of the present invention is to provide a dental mold capable of prompting the action of a drug formed on a contact surface between a dental mold and a tooth. In order to achieve the above objects, the dental mold of the present invention comprises a hot-melt type resin and a fiber cloth combined with a heat-melt type resin. In one version of the invention, a temperature sensing element is included to detect the operating temperature of the hot solid resin during the hot melt process. In one form of the invention, a drug strength indicating member is included to indicate the state of action of the agent formed on the contact surface between the dental mold and the germ. The dental mold is prepared by preparing a hot-melt resin and a fiber cloth, and then bonding the hot-melt resin to the fiber cloth. 201102050 Compared with the prior art 'the dental mold of the present invention and the manufacturing method thereof, the dental mold which is closely attached to the teeth can be formed through a simple operation, and the dental mold can be uniformly diffused and distributed outside the material contacting the teeth. Through the temperature sensing component, the complex energy can detect the operating temperature of the hot-melt resin in the hot-melt type process, and the drug strength indicating component can indicate that the agent formed on the contact surface of the dental mold and the gum is completed. . [Embodiment] The embodiments of the present invention are described by way of specific embodiments, and those skilled in the art can readily understand other advantages and effects of the present invention from the disclosure of the present disclosure. The present invention may be embodied or applied in various other specific embodiments. The details of the present invention can be variously modified and changed without departing from the spirit and scope of the invention. Referring to Figure 1 for a schematic view of the structure of the dental lion of the present invention. As shown, the dental mold of the present invention comprises a solid resin 1 () and a fiber cloth 11 bonded to a hot melt (tetra) resin. In a preferred embodiment of the invention, the hot-melt resin 10 is bonded to the fiber cloth U by heat compression bonding. Thermally based resin 1Q can be vinyl acetate) or TPUC Thermoplastic Poly-Urethane). However, the material range of the material is in accordance with the first glass conversion/dish range; ^7G~95°C, The second glass transition temperature range is the condition of 丨(四)赃. Lai Weibu 11 silk (10) simple material, crane cloth or water-soluble pressure 201102050 force resin and other akisaki state or Yang secret quality for Gu. The details of the product and the pressure heat method are detailed. "The preferred model of the tree model has a hole _ 40~6_ product ratio, and the pore diameter ride value falls between 2Q~5Q _, and the finished product has chemical resistance and no toxicity problem. Please refer to Fig. 2, which is a flow chart showing a method of manufacturing a dental mold of the present invention. As shown in the drawing, in step S10, a hot-melt resin 10 and a fiber cloth U are prepared. In the present invention, preferably, the hot-melt resin 1T uses Tpu (Therm〇piastic (10) ♦ Urethane, molecular weight!, _, _), and the property range is that the first glass transition temperature ranges from 70 to 95. (:, the second glass transition temperature ranges from 14 〇 to 职. In the preferred embodiment of the invention, the cross-sectional area of the hot-melt resin 10 and the fiber cloth H is the same, or the cross-sectional area of the fiber cloth 11 is slightly smaller than the hot-melt The cross-sectional area of the tree is 1 ,, and the shape of the dental mold is approximately equal to the curvature of the upper dentition and/or the lower dentition' and the width is at least sufficient to cover the upper dentition and/or the lower dentition. Then, as far as the step is reached, in step S11, the hot-melt resin 10 and the fiber bundle 11 are subjected to a hot-dusting process. In the present implementation, the condition of the procedure is that the direct temperature is above the first glass transition temperature range. 5~HTC, press force in 1G, gf/ciQ2, and apply ultrasonic wave above 5 kHz 'operation time 3~5 seconds. The above preparation method and conditions can ensure the fusion of hot melt_resin 10 and fiber cloth U The strength does not lose the control release ability of the fiber cloth u. (4) The product is confirmed to be sufficient by the tearing test; after the mercury intrusion test, the porosity is reduced from 53% to 41%. 201102050 The preferred one is shot in this embodiment. The method for preparing the fiber cloth u can be, for example, but not limited to, preparing the defatted fresh m bottle fat (4) The cullet is immersed in a methanol solution having a cellulose concentration of 1 to 15% (molecular weight: 100,000 to 800,000); and then, the cotton wool gauze is taken out from the methanol solution to dry the bribe in the methanol solution of the bet cotton gauze. The surface is sprayed with water-soluble acrylic resin (solid content 丨〇~3〇%, molecular weight 500,000~2'_, GGG); after that, enter the oven to 95~12{rc (whether there is a reasonable operating temperature range such as several degrees to Between several degrees) baking the dry wine, that is, forming the fiber cloth (1) The fiber cloth 11 produced by the above-mentioned production method, the properties obtained by the mercury intrusion test are: the porosity is 53% by volume, and the peak diameter is high and the peak value falls at 32~ 34 to m, the distribution rate is 92%; the finished product is placed in 30% hydrogen peroxide for the dissolution test, the pH value is 〜. 1~8·5 of the van _, no oxidizing oxygen, and then The oxygen peroxide solution was subjected to IR, UV, VIS scanning, and no elution material, which proved to have chemical resistance. Please refer to Fig. 3, which is a schematic cross-sectional view of a dental mold produced by the dental molding method of the present invention. As shown in the figure, through the dental molding method of the present invention, the hot-melt resin 10 and The fiber cloth 11 can be tightly coupled. In another embodiment of the present invention, the temperature sensing element 12 is included to detect the operating temperature of the hot-melt resin 10 during the hot-melt type process. In an embodiment, the temperature sensing element 12 is composed of a thermosensitive color developing microcapsule and a two-part epoxy resin phase, and the preparation method thereof can be, for example, but not limited to, a thermosensitive color developing microcapsule and a two-part epoxy resin injection. The mold of the rubber tube is taken out and is taken out as the temperature sensing element 12. The heat-sensitive color-developing micro-capsule can be developed by Toray or Merck, and the color-sensitive microcapsule should be 75. ~ 8 (TC color-changing products, preferably, the late 201102050 lag time within 1 minute. The temperature sensing element 12 produced by the above process is sensitive to temperature and completely non-toxic. The temperature sensing element 12 is joined to the thermosetting resin 10 and/or the fiber cloth 11. In still another embodiment of the present invention, the medication intensity indicating member 13 is included to prompt the action state of the medicament formed on the contact surface between the dental mold and the teeth. The drug strength indicating element 13 is formed by using a redox indicator, an electrolyte, or a hydrosol as a salt bridge. The redox indicator may be a resin (C16H10N208S2 (indig〇carmine)), and the electrolyte may be chlorinated or The water-soluble carcass may be a seaweed or gelatin. The drug strength indicating element 13 prepared by the above method is sensitive to the oxidizing agent and completely non-toxic, and meets the requirements for oral use. In a better embodiment, 'manufacturing The method is that the redox indicator is firstly formulated into 3%, the electrolyte is formulated into 15%, the hydrosol is prepared to be 9%, and each is heated to about 9 ° C, mixed and injected into the mold, and cooled and solidified. After taking out, it is the drug strength indicating element 13. The reaction intensity indicating element 13 of the above-mentioned manufacturing method φ reacts to the redox potential as shown in Table 1. The reaction hysteresis is shorter than the range that can be observed by humans. ) -1.8 ~1. 35 -0.9 -0.45 Color, green, red, red, yellow, yellow, Table 1: The reaction of the resin to the redox potential is shown in Table 1, and the potential is relative to the hydrogen standard reduction potential. The reaction is 2jj2 〇 = secret + 2H + + 2e - ' and the oxidation-reduction potential is controlled by the activity of controlling the threat. 201102050 Please refer to Fig. 4, which is a flow chart of the tooth molding type of the present invention. The type step ' can mold the teeth into a dental mold of the upper molar row and/or the lower molar row of the user. In the present embodiment, the dental mold of the present invention includes a temperature sensing component and a medication for convenience of complete description. The intensity indicating component, in other embodiments, may optionally not include the temperature sensing component and/or the medication intensity indicating component. In step S20, the dental mold is placed in hot water for heating (in different embodiments) Other heating methods can be used.) Then, the process proceeds to step S21. The hot water temperature is judged by the color change of the temperature sensing element in step S21. In the present embodiment, it is assumed that the color of the temperature sensing element becomes pink. At that time, it has reached 75 C or more, that is, the hot-melt resin has reached a moldable state. Then, it proceeds to step S22. In step S22, the dental sheet is taken out from the hot water, and then proceeds to step 兕3. In step S2 3, 'Remove the temperature sensing element. Then proceed to step S24. In step S24 +, the dental mold is placed in the user's mouth, wherein the surface of the fiber cloth is attached to the tooth, and the end is placed on the upper and lower lip lines. (or between the lower molar line and the lower lip) and bend along the rim into the σ cavity, and press the dental mold tightly against the teeth with your fingers. To be hardened 4, the dental mold belonging to your own tooth shape is completed. Then, the process proceeds to step S25. In step S25+, when performing tooth whitening or health care, the user applies a whitening agent or a health care agent such as a fluorine agent (in other embodiments, different types of drugs) to the dental mold. On the fiber cloth, it proceeds to step S26. 201102050 昭盖 in _26 will be applied to the teeth of the teeth of the whitening _, the teeth, white or health care according to the use time, restrictions and cycle on the whitening agent or health care agent instructions. If you just wear the upper teeth, the emulsification power is the highest, the medication intensity indicator should be green (in different embodiments can be = his color) 'when the oxidative power subsides' the medication strength indicator First, it turns into a red color (not _ real _ can be other colors) money yellow (in the example of the publication w is other colors) 'that means that the efficacy of whitening agent or health care agent has been; Xiao consumption is completed. Then, the process proceeds to step S27. In step S27, the user can remove the dental mold to complete the whitening or health care work. The dental mold of the present invention and the preparation method thereof can form a dental mold which closely adheres to the teeth through a simple operation. The dental mold can be dissipated (4) and the diffusion distribution is placed on the contact surface with the dental clock, and the temperature sensing element is recovered. The side can be hot-melt _ in the hot-melt type process A operating temperature 'transparent (four) degree indicating component, it is difficult to prompt the formation of the dental mold (Lu and the tooth contact surface of the drug effect is completed. The above embodiment is only an illustrative description of this The invention is not limited to the scope of the invention, and the invention may be modified and changed without departing from the spirit and scope of the invention. The scope of protection 'should be listed in the scope of patents mentioned below. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the structure of a dental mold of the present invention; Fig. 2 is a flow chart showing a method for manufacturing a dental mold of the present invention; 201102050 3 is a schematic cross-sectional view of a dental mold produced by the dental molding method of the present invention; and FIG. 4 is a flow chart of the dental molding type of the present invention. [Main Symbol Description] 10 Hot-melt Resin 11 Fiber cloth 12 temperature sensing element 13 drug strength indicating element S10, S11 Steps S20~S27