201036874 f、發明說明： 【發明所屬之技術領域】 本發明係與包裝材印刷方法有關，更詳而言之，尤指 無污染的印刷方式，以無毒性之水性油（彩）墨作印刷、 ==著.黏著，完全残害人體，如關隔離結構 將有害物質隔絕，為環保、ϋ喜、九k …f無5染的一種食品包裝 材。 【先前技術】 Ο Ο 按’先行所知，隨著速食物品快速發展，讀於人們 間便食用’速食麵（泡麵）用量愈來愈多，而且速食麵係 以塑膝膜作包裝，有關以塑膠膜作包裝的食品，尚有餅乾 、糖果、麵條、使用的塑膠包裝袋、零食、、、、等等， 由於該等娜膜内面必需作_產品名稱牌' 品出處、成份等字樣及圖案，而且顏色鮮I如第一圖所 示，該塑賴主要含斜層為-層卿料稀（0rient poly—經配向延伸的聚丙烯)，於〇pp聚丙烯層内 面印顧樣’印刷細有機溶_油墨㈤赠驗趾） 印製於0PP料烯層β φ，再財機溶_接著劑(s〇lvent Base Dry Lamination )黏著一内層 VM_cpp 之聚丙烯 【Vacuum Metalized—Cast polypropylene 真空蒸著鍍銘， 未配向延伸（可延展）的聚丙烯】，雖有外層〇pp聚丙烯與 一内層VM-CPP作隔離有機溶劑型油墨SB_Ink及有機溶劑 型接著劑SB-DL，但是時間一久，該等有機溶劑型油墨 SB-Ink及有機溶劑型接著劑SB_DL内毒物會揮發出來，影 201036874 響人體的身體； 如附件一所示’係食品工業發展研究所對上述包裝材 的測試，其特殊氣體透過率為13.79，此測試的氣體為曱苯 這些有機溶劑型油墨SB_Ink及或有機溶劑型接著劑 SB-DL對人體健康的危害越來越明顯，都有可能讓人們成 為油墨汙染的受害者，最主要印刷OPP聚丙烯中的汙染物 (油墨、接著劑）中常使用乙醇、異丙醇、丁醇、丙醇、 丁酿1、醋酸乙醋、醋酸丁醋、甲苯、二甲苯等有機溶劑， 雖然這些有機溶劑係使用乾式貼合方式，但是會有殘留上 述的汙染物，對人體造成危害，如果是印刷面積較大、墨 層較厚的印刷塑膠膜品，其殘留溶劑較多，在使用過程中 釋放出的有毒物質汙染空氣、危害人們的健康，含甲笨的 稀釋劑，帶有毒性，刺激性氣味較大，在滲入食品後，長 ’月食用據報導會致癌亦會影響大腦中樞神經，對人體健康 造成極大的危害； 目前雖然有以無毒的水性油（彩）墨取代有機溶劑型 油墨，但是仍然以有機溶劑型接著劑，有機溶劑型接著劑 内含甲苯成份，一樣危害人體，並非完全無毒之包裴； 有鑑於此，本案發明人乃基於上述弊端，仍積極努力 開發、研究改良，並累積多年製造、生產經驗，而終於有 —足以解決上述弊端之發明產生。 【發明内容】 即，本發明一種食品包裝材，其主要目的係提供水性 201036874 油（彩）墨.，叙基、益、、元s 九 ^ 毋無/7木’不影響人體之健康。201036874 f, invention description: [Technical field of invention] The present invention relates to a packaging material printing method, and more particularly, a non-polluting printing method, which uses non-toxic water-based oil (color) ink for printing, == 着. Adhesive, completely maimed the human body, such as the isolation structure to isolate harmful substances, a food packaging material for environmental protection, ϋ喜, 九k ... f no 5 dyeing. [Prior Art] Ο Ο According to the 'first known, with the rapid development of fast food products, the consumption of 'fast food noodles (bubble noodles) is more and more used in people, and the instant noodles are packaged with plastic knee pads. Plastic film packaging food, there are still biscuits, candy, noodles, plastic bags used, snacks,,,, and so on, because the inner surface of the film must be _ product name brand 'products', ingredients and other words and patterns And the color fresh I is as shown in the first figure, the plastic ray mainly consists of a layer of slanting layer - a layer of fine material (0rient poly - oriented extended polypropylene), printed on the 〇pp polypropylene layer Organic solvent _ ink (five) toe test) printed on 0PP olefin layer β φ, then _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Platinum, unaligned (extensible) polypropylene, although the outer layer pp pp polypropylene and an inner layer VM-CPP as the isolation organic solvent type ink SB_Ink and the organic solvent type adhesive SB-DL, but for a long time, Organic solution The SB-Ink and the organic solvent-based adhesive SB_DL will evaporate, and the shadow of 201036874 will ring the body of the human body; as shown in Annex I, the Food Industry Development Institute tests the above-mentioned packaging materials, and its special gas permeability is 13.79. The gas tested in this test is benzene. These organic solvent-based inks SB_Ink and or organic solvent-based adhesive SB-DL are more and more harmful to human health. They may cause people to become victims of ink pollution. Organic solvents such as ethanol, isopropanol, butanol, propanol, distillate 1, ethyl acetate, butyl acetate, toluene, xylene, etc. are commonly used in contaminants (inks, adhesives) in OPP polypropylene, although these organic The solvent is dry-bonded, but it will leave the above-mentioned contaminants and cause harm to the human body. If it is a printed plastic film with a large printing area and a thick ink layer, it has more residual solvent and is released during use. The toxic substances that pollute the air and endanger people's health, contain a thinner of the stupid, with toxicity, irritating odor, after infiltrating the food, long Monthly consumption is reported to cause cancer, which also affects the central nervous system of the brain, causing great harm to human health. At present, although organic solvent-based inks are replaced by non-toxic water-based oil (color) inks, organic solvent-based adhesives and organic solvents are still used. The type of adhesive contains toluene, which is harmful to the human body. It is not completely non-toxic. In view of this, the inventor of this case is still actively developing, researching and improving, and accumulating years of manufacturing and production experience, and finally has - An invention that is sufficient to solve the above drawbacks. SUMMARY OF THE INVENTION That is, a food packaging material of the present invention, whose main purpose is to provide water 201036874 oil (color) ink., Xuji, Yi, yuan s 九 ^ 毋 no / 7 wood ' does not affect the health of the human body.
本發明一種食品包裝材，A 添,j，益主λ.. 目的係提供水性接著 "]…、母、無巧染，不影響人體之健康。 本發明-種食品包裝材，其再一目的係提供— 處理，即使為有機溶劑型油 ’、巧且隔 強力隔絕甲笨等有害«，不影響人體之健康均可 緣是’本發明—種食品找材，其係包含有： ΟThe invention relates to a food packaging material, A 添, j, 益主 λ.. The purpose is to provide water and then "]..., mother, no coincidence, does not affect the health of the human body. The present invention is a food packaging material, and the other object is to provide - treatment, even if it is an organic solvent type oil, and it is harmful and harmful, and does not affect the health of the human body. Food looking for materials, including: Ο
-為-瓣膜，作為印刷之基材，内面可印刷 圖案’可透視外層之圖案； 一油墨處理，將油墨印製_於該外層之内面； 一接著劑，將外層内面與一内層之内面人· 一内層’為-塑膠膜，位於外層内面下方，為一熱封 一高阻隔處理，作塗佈於外層與内層之間，作隔離之 結構處理； 據此，以高阻隔處理，使油墨、接著劑作隔離不揮發 散出，達到環保、無毒、無污染之包裝材。 為使貴審查委員，對本發明之内容、特徵及目的， 有著更進—步之瞭解與認同，茲舉一較佳實施例，並配合 圖式、圖號說明於后： 【實施方式】 首先’本發明一種食品包裝材’第一實施例，如第二 、三圖所示，該包裝材10由外部至内部的順序分別為一 外層11、油墨處理12、接著劑13、高阻隔處理A及 5 201036874 朗1 4 亥外層1 1為一塑膠膜，係為聚丙歸材質(0PP 聚丙烯〇1^拉]3〇1沖1*〇1^£加），係經配向延伸之聚丙烯，作 為印刷之基材，内面可印刷圖案，可透視外層之圖案，該 -彳層1 H⑽材質為亮面’印棚雜财性油（彩 )墨處理 1 2WB_INK (WaterBaselnk) ’ 將水性油（彩） 墨印製圖案於該外層之内面，再作一高阻隔處理A，以水 性奈米材質（圖以A表示）作塗佈於内層14之内面’作 ㉟離之結構處理，該高阻隔處理A之水性奈料質係以聚 〔烯醇、調節劑、奈米氧切、偶糊、魏劑和水組成 的’調節劑為甲醇與乙醇的混合物，偶聯劑由氨基石夕烧、 醇胺鈦酸脂、醇胺烧氧基鈦酸醋組成，增點劑為聚乙稀亞 胺’接下來以水性接著劑丄3 wb_dl (Water Base Dry ' Lamination)，將外層1 1與一内層1 4之内面作結合，該 内層14仍為一塑膠膜，位於外層丄i内面下方，内層丄 4為聚丙_質，係為CPP之聚丙稀（CastpdypiOpylene) ❹ ，係未配向延伸（可延展）之聚丙烯； 如附件二，係食品工業發展研究所對上述包裝材的測 試，其透養度為0.7，係較同級產品低許多； 或如第四圖，外層11之聚丙烯材質，為表面可經過 霧面之處理，以MOPP聚丙浠（〇rjentp〇iypr〇pyiene)表示 j 或如第五圖，内層1 4為聚丙烯材質，係為VM — CPP 之^^丙烯（Vacuum Metalized-Cast polypropylene真空蒸著鍵 鋁）’係未配向延伸（可延展）之聚丙烯，表面經過真空蒸 201036874 • 著鍍上鋁箔之處理，略半透明但不易透視； 或如第六圖，以MOPP聚丙烯作外層丄丄，而以 篇-CPP之聚丙__ ! 4，翻於不同食品之包裳材 藉由上述之結構組合’本發明—種食品包裝材，將— 高阻隔A結構，置於外層！工與内層14之間，可使油墨 12、接著劑13作隔離不揮發散出，達到環保、無毒、 無污染之包裝材，對人體健康不影響之作用； 帛一實施例原本水性油（彩）墨處理12及水性接著 劑13兩者就未含甲苯等有機溶劑的有毒物品，即使未加 強作-道高阻隔A結構處理’也無毒物散發出來，於第三 實施例會述及； ' 其巾高賴A處理之水性奈米材質為界於外層；[!與 内層14之間，可位於内層i 4之内面，或位於外層工工 的内面印刷之下’高阻隔A處理成膜後，具有耐水性，對 〇 紫外光和紅外光的反射性佳，並耐磨、阻止滲透，其氧氣 透過I大幅降低了10倍以上，水蒸氣透過量降低了 5倍 能提升_性，且延長了包裝產品的保存期； 一第二實施例係包裝材2 0由頂部至底部的順序分別為 一外層21、有機溶劑型油墨22、有機溶劑型接著劑2 3、高阻隔A處理及-内層2 4，如第七、人_示，該 外層2 1為opp聚丙稀（〇riem pdypr〇pyiene)，該外層2 1之聚丙糖質，表面可經過霧面之處理 刷圖案係以她_油墨22處祕她㈤二馳 201036874 . ink) ’將機溶劑型油墨2 2SB-Ink印製圖案於該外層2工 之内面，再作一高阻隔A處理，以水性奈米材質（圖以A 表示）作塗佈於-内層24之内面，作隔離之結構處理， ' 該高阻隔入處理之水性奈米材質如第-實施例所述，接下 • 來以有機溶劑型接著劑2 3SB-DL (Solvent Base Dly- for - valve, as a substrate for printing, the inner surface can be printed with a pattern of 'out of the outer layer pattern; an ink treatment to print the ink on the inner surface of the outer layer; an adhesive to the inner surface of the outer layer and the inner layer of the inner layer · An inner layer is a plastic film located below the inner surface of the outer layer. It is a heat-sealing and high-barrier treatment. It is applied between the outer layer and the inner layer for isolation. According to this, the ink is treated with high barrier. The agent is then isolated and non-volatile to achieve environmentally friendly, non-toxic, non-polluting packaging materials. In order to enable the review committee to have a better understanding and recognition of the contents, features and objectives of the present invention, a preferred embodiment will be described with reference to the drawings and drawings: [Embodiment] Firstly A first embodiment of a food packaging material according to the present invention, as shown in the second and third figures, the order of the packaging material 10 from the outside to the inside is an outer layer 11, an ink treatment 12, an adhesive 13, a high barrier treatment A and 5 201036874 朗1 4 亥 outer layer 1 1 is a plastic film, which is made of polyacryl material (0PP polypropylene 〇1^ pull]3〇1 冲1*〇1^£加), which is a polypropylene extending through the alignment. Printed substrate, the inner surface can be printed with a pattern, and the outer layer can be seen through the pattern. The -1 layer (H) is made of bright surface 'printed miscellaneous oil (color) ink treatment 1 2WB_INK (WaterBaselnk) ' water-based oil (color) The ink-printed pattern is on the inner surface of the outer layer, and is further subjected to a high-barrier treatment A, and the water-repellent nano-material (shown as A) is applied to the inner surface of the inner layer 14 as a 35-separation structure treatment, and the high-barrier treatment A The aqueous system is a poly[enol, a regulator, a nanometer The modifier of the odor, the agent and the water is a mixture of methanol and ethanol, and the coupling agent is composed of amino sulfonate, alcohol amine titanate, alcohol amine alkoxy vinegar, and the addition agent is polyethylene. The dilute imine' is then bonded to the inner surface of an inner layer 14 by an aqueous binder 丄3 wb_dl (Water Base Dry 'Lamination), which is still a plastic film located below the inner surface of the outer layer 丄i The inner layer 丄4 is a polypropylene material, which is CPP polypropylene (CastpdypiOpylene) ❹, which is an unaligned (extensible) polypropylene; as in Annex 2, the Food Industry Development Research Institute tests the above packaging materials, The degree of osmoticity is 0.7, which is much lower than that of the same grade product; or as shown in the fourth figure, the outer layer 11 is made of polypropylene, and the surface can be treated with matte surface, represented by MOPP polypyrene (〇rjentp〇iypr〇pyiene) or As shown in the fifth figure, the inner layer 14 is made of polypropylene, which is a VM-CPP propylene (Vacuum Metalized-Cast polypropylene), which is an unaligned (extensible) polypropylene, and the surface is vacuumed. Steaming 201036874 • Plated with aluminum Treatment, slightly translucent but not easy to see through; or as in the sixth figure, using MOPP polypropylene as the outer layer, and the article -CPP poly __! 4, turning over the food of different foods by the above structure Combine 'the invention' - a kind of food packaging material, will be - high barrier A structure, placed in the outer layer! Between the work and the inner layer 14, the ink 12 and the adhesive 13 can be isolated and non-volatile to achieve environmental protection, non-toxic, non-polluting packaging materials, and have no effect on human health; 帛 an example of the original water-based oil (color Both the ink treatment 12 and the aqueous adhesive 13 are toxic to an toxic substance that does not contain an organic solvent such as toluene, and the non-toxic substance is emitted even if it is not reinforced by the high-barrier A structure treatment, which will be described in the third embodiment; The water-repellent nano material treated by the towel is treated as the outer layer; [! and the inner layer 14 may be located on the inner surface of the inner layer i 4 or under the inner surface printing of the outer worker] after the high barrier A treatment is formed, It has water resistance, good reflectivity to ultraviolet light and infrared light, wear resistance and prevent penetration. Its oxygen permeation I is greatly reduced by more than 10 times, water vapor transmission is reduced by 5 times, and it can be improved and extended. The storage period of the packaged product; a second embodiment of the packaging material 20 from the top to the bottom in the order of an outer layer 21, an organic solvent type ink 22, an organic solvent type adhesive 23, a high barrier A treatment and an inner layer 2 4, such as the seventh, people _ The outer layer 2 1 is opp polypropylene (〇riem pdypr〇pyiene), the outer layer 21 of the polytriglycerose, the surface can be treated by the matte surface of the brush pattern to her _ ink 22 secret her (five) two Chi 201036874. 'The machine solvent type ink 2 2SB-Ink is printed on the inner surface of the outer layer 2, and then treated as a high barrier A, and coated on the inner surface of the inner layer 24 with a water-based nano material (shown as A). For the structural treatment of the isolation, 'the water-resistant nano material of the high-resistance treatment is as described in the first embodiment, and then the organic solvent-based adhesive 2 3SB-DL (Solvent Base Dly)
LaminatI0n) ’將外層2 1與内層2 4之内面作結合，内層 2 4為聚丙烯材質’係為VM_cpp之聚丙烯（vacuum 〇 Me⑹ized_Castpolypr—e真空蒸著慰呂），係未配向延伸 (可延展）之聚丙稀，或内面經過真空蒸著鍍上㈣之處 理； 雖二有該機丨谷劑型油墨2 2SB-Ink及機溶劑型接著劑 2 3SB DL含有甲笨，但以一道高阻隔a結構，置於印刷 ’ 圖案接著劑23與一内層之間，可使油墨22、接著劑 2 3作隔離不揮發散出，達到無污染之包裝材，對人體健 康不影響之作用； ❹ 第三實施例，如第九圖所示，係以PET材質當外層，水 I4J1WB-INK ( Water Base Ink) > 7jc|i^^f.|WB-DL 及㈨阻隔A處理，内層為聚丙稀材質（cpp之聚丙烯）； 第四實施例’如第十、十—圖所示，該包裝材3 〇由 /至内部的順序分別為-外層31、油墨3 2處理、接 j 3 3及内層3 4，該外層3 1為一娜膜，係為聚 =細1貝⑴冲聚丙缚0rient polypropylene)，係經配向延 取聚丙稀’作為印刷之基材，表面可印刷圖案，該外層 之來丙缔材質為亮面，印刷圖案係以水性油（彩）墨3 2 8 201036874 處理WB-INK (Water Base Ink)，將水性油（彩）墨 3 2 印製圖案於該外層3 1之内面，再以水性接著劑3 3 WB-DL (Water Base Diy Lamination) ’ 將外層 3 1 印刷面 與一内層3 4之内面作結合，該内層3 4仍為—塑膠膜， 位於外層3 1内面下方，可透視或半透視外層3丄之圖 案，内層 3 4 為VM-CPP之聚丙稀（vacuumMetaiized_Cast polypropylene真空蒸著鍍鋁），係未配向延伸（可延展）之 聚丙烯；或如上實施例外層31之聚丙烯材質，為表面可 〇 經過霧面之處理；或外層3 4為聚丙騎質，係為CPP之聚 丙烯（Castpolypropylene)’未配向延伸（可延展）之聚丙 稀’表面經過真空蒸著鍍上鋁羯之處理，或wM〇pp聚丙埽 . 作外層3 1，而以狐⑽之聚丙烯作内層3 4，作各種變 化實施，應用於不同食品之包裝材，以水性油（彩）墨3 2、水性接著劑3 3為主搭配其他基材，無污染、無毒害 人體之虞； ° 〇 綜上所述，本發明一種食品包裝材，其新穎性、實用 性乃毋庸置疑，為此懇祈t審查委員，-秉發明人努力 創作初衷，賜准本案專利，則申請人是幸！ 附件-：係食品工業發展研究所對習知包裝材的測試報生 書。 。 附件二：係食品工業發展研究所對本發明包裝材的測 告書。 201036874 【圖式簡單說明】 第一圖係習知包裝材之製作流程示意圖。 第二圖係本發明第一實施例之剖面示意圖。 第三圖係本發明第一實施例之製作流程示意圖。 第四圖係本發明第一實施例使用霧面聚丙烯底層之製作流 程示意圖。 第五圖係本發明第一實施例使用VM_CPP内層之製作流程 示意圖。 第六圖係本發明第一實施例以MOPP聚丙烯作外層，而以 VM-CPP作内層之製作流程示意圖。 第七圖係本發明第二實施例以SB-INK及SB-DL之剖面示意 圖。 第八圖係本發明第二實施例以SB-INK及SB-DL之製作流程 不意圖。 第九圖係本發明第三實施例以PET當外層之製作流程示意 第十圖係本發明第四實施例以WB-INK及WB-DL之剖面示 意圖。 第十一圖係本發明第四實施例以WB-INK及WB-DL之製作 流程示意圖。 201036874 【主要元件符號說明】 1 0包裝材 1 1外層 12油墨處理 1 3接著劑 A南阻隔 1 4内層 2 0包裝材 2 1外層 2 2油墨處理 2 3接著劑 2 4内層 3 0包裝材 3 1外層 3 4内層 3 2油墨處理 3 3接著劑LaminatI0n) 'The outer layer 2 1 is combined with the inner surface of the inner layer 2 4 , and the inner layer 24 is made of polypropylene material 'VM_cpp polypropylene (vacuum 〇Me (6) ized_Castpolypr-e vacuum steaming comfort), unaligned extension (extensible) Polypropylene, or the inner surface is subjected to vacuum evaporation plating (4); although there are two types of glutinous type ink 2 2SB-Ink and machine solvent type adhesive 2 3SB DL containing a stupid, but a high barrier a structure , placed between the printing 'pattern adhesive 23 and an inner layer, the ink 22, the adhesive 2 3 can be isolated and non-volatile to achieve a non-polluting packaging material, does not affect the human health; ❹ third implementation For example, as shown in the ninth figure, the outer layer is made of PET, water I4J1WB-INK (Water Base Ink) > 7jc|i^^f.|WB-DL and (9) barrier A treatment, and the inner layer is made of polypropylene material ( The fourth embodiment, as shown in the tenth and tenth drawings, the order of the packaging material 3 from / to the inside is - outer layer 31, ink 3 2 treatment, j 3 3 and inner layer 3 4, the outer layer 3 1 is a Na Na film, the system is poly = fine 1 shell (1) poly-encapsulated 0rient polypropylen e), by extending the polypropylene to the substrate as a printing substrate, the surface can be printed with a pattern, the outer layer of the material is a bright surface, and the printing pattern is treated with water-based oil (color) ink 3 2 8 201036874 WB- INK (Water Base Ink), printing a water-based oil (color) ink 3 2 on the inner surface of the outer layer 31, and printing the outer layer 3 1 with an aqueous adhesive 3 3 WB-DL (Water Base Diy Lamination) In combination with the inner surface of an inner layer 34, the inner layer 34 is still a plastic film, located below the inner surface of the outer layer 31, and can be seen in a perspective or semi-perspective pattern of the outer layer 3, and the inner layer 34 is a polypropylene-VMP-polypropylene (vacuumMetaiized_Cast) Polypropylene (aluminum vacuum evaporation), which is an unaligned (extensible) polypropylene; or a polypropylene material of the exception layer 31 as described above, the surface may be treated with a matte finish; or the outer layer 34 is a polypropylene alloy. The surface of the CPP polypropylene (Castpolypropylene) unaligned (extensible) polypropylene surface is vacuum-vapor-plated with aluminum crucible, or wM〇pp polypropylene. As the outer layer 3 1, and the fox (10) Polypropylene as inner layer 3 4, for various changes Implemented, applied to different food packaging materials, with water-based oil (color) ink 3 2, water-based adhesive 3 3 as the main combination with other substrates, no pollution, no toxicity to the human body; ° 〇 所述, the present invention A kind of food packaging material, its novelty and practicality are unquestionable. For this reason, the inspector has tried to create the original intention and granted the patent in this case. The applicant is fortunate! Attachment-: Test report for the custom packaging materials of the Food Industry Development Research Institute. . Annex II: The report of the packaging industry of the invention by the Food Industry Development Research Institute. 201036874 [Simple description of the diagram] The first diagram is a schematic diagram of the production process of the conventional packaging material. The second drawing is a schematic cross-sectional view of a first embodiment of the present invention. The third figure is a schematic diagram of the production process of the first embodiment of the present invention. The fourth drawing is a schematic view showing the production process of the matte polypropylene underlayer in the first embodiment of the present invention. The fifth figure is a schematic diagram of a manufacturing flow using the VM_CPP inner layer in the first embodiment of the present invention. Fig. 6 is a schematic view showing the manufacturing process of the first embodiment of the present invention in which MOPP polypropylene is used as the outer layer and VM-CPP is used as the inner layer. Fig. 7 is a schematic cross-sectional view showing the second embodiment of the present invention in SB-INK and SB-DL. The eighth drawing is a production flow of SB-INK and SB-DL in the second embodiment of the present invention. The ninth embodiment shows a third embodiment of the present invention in which the outer layer is formed by PET. The tenth embodiment is a cross-sectional view of the fourth embodiment of the present invention in the form of WB-INK and WB-DL. The eleventh drawing is a flow chart showing the production process of the WB-INK and WB-DL in the fourth embodiment of the present invention. 201036874 [Description of main components] 1 0 packaging material 1 1 outer layer 12 ink treatment 1 3 adhesive A south barrier 1 4 inner layer 2 0 packaging material 2 1 outer layer 2 2 ink treatment 2 3 adhesive 2 4 inner layer 3 0 packaging material 3 1 outer layer 3 4 inner layer 3 2 ink treatment 3 3 adhesive