201026892 六、發明說明： 【發明所屬之技術領域】 本發明係有闕於一種埶處 鋅工法，驻社收 …慝理滲碳工件之熱浸鍍 辞工法特別各將鑽尾螺絲或 之埶虛揮步细Me 文螺絲等需經過滲碳 件：、…Γ、表面及心部硬度之熱處理滲碳工 熱‘二χ5()ί)±5ίΠ:及浸料間35±1〇秒下進行 【先前技術】 ❹ ❿ 按铁鋼鐵材料為今日人類生活中不可或缺的重要 >源’然㈣其本相性❹:，使得 鋼材’並無時無刻地損耗著鋼材，尤：台二! 處尚溫咼濕的海洋性季風的亞戈 亇丨竽矾的恶劣缞境下，"銹蝕"問題 較其他各國更為嚴重。 先進諸國，很早就注意到"銹蝕"的嚴重性，據估 計，因防朗造成的損失，在日本—年約達國民= 毛，（GNP)的3.5%。在美國，此—比率為4·2 %， 在英國為3.5% ’西德為3% ’而台灣則遠超過以上 比率，如以日本之3.5%來計算，在2〇〇1年我們不 知不覺中損失了新台幣三千三百三十億元（2〇〇1年 國民生產毛額約為新台幣九兆五千一百三十九億）。 所以先進國豕均成立了有關的防钱技術研究機構，以 採取各種有效的措施，來避免或減少其損失。然而我 國目前似乎尚沒有一主要機構來正視此一問題。因 此’到處可以看到因防蝕技術不良或防蝕方法錯誤所 201026892 -造成的「銹飯」景觀，實在令人非常痛心’而執浸鍵 鋅的使用已有150年以上的歷史了，據估計，全^ 每年經熱浸鍵辞保護的鋼材約有 20, 000, 000W噸）’其對人類有限資源之維護價值 實在是難以估計。（節錄自中華民國熱浸錄辞協會網 頁 httP://www.gaitw.org.tw/inf〇 htm)，目前在二 參 灣將熱浸鑛辞使用於-般之螺絲、螺帽上以形成鑛： 層來做防钮之功能已有30餘年，但由於熱浸^必 須於500 C左右之高溫下進行，其本身即為一項熱處 理作業，而-般特殊工件通常會經由調質熱處理或渗 碳熱處理來調整其表面及心部硬度，經由調質熱處理 之工件會改變工件内部的成分粒子，讓工件材質達到 所需要的等級需求，因此調質熱處理會將工件硬度加 強並使工件内部組織穩定化，而滲碳熱處理主要ς利 用碳70素滲透進去工件表面，使工件形成滲碳層，達 到工件表面層硬化，其對工件心部硬度影響較小但 由於經過調質熱處理之工件其内部組織穩定，因此其 經由熱浸鍍辞處理後，對於工件之機械性質影響較 小’但對於如同鑽尾螺絲或自攻螺絲等熱處理滲碳工 ^需經過滲碳之熱處理來調整其表面及心部硬度而 二，由於滲碳層較薄，且滲碳熱處理對工件心部硬度 衫響較小，因此熱浸鍍鋅之浸鍍溫度之高低及浸鍍時 間之長短，以及後續冷卻作業常常導致熱處理滲碳工 件之機械性質改變，無法符合該成品之要求，因此只 201026892 能使用電鍍法或機械鑛鋅法來形成鑛辞層， =含有滲鋅法、塗辞法或噴鋅法等機械方^ “ 鍍法形成之鍍鋅層厚度有限且 一電 法不执a盔焱拉、上^ ^ 貫差’而機械錢鋅 差I:點或嘴辞法皆有隅角均一性 【=内容Γ其防#效果不若熱浸鑛辞佳。 羑此’有鑑於習知鑽尾螺絲或自攻螺 之熱處理來調整其表面及心部硬 = 二件無法使用熱浸鍍鋅之缺點，故本發明提供一種 …處理滲碳工件之熱浸鍍鋅工法，其步驟為： Α·將熱處理滲碳工件做清潔之前置作業。 Β.將完成前置作業的熱處理滲碳工件:、 浸鍍溫度500 土 5(TC及浸鍍時間為35+ 工’、在 浸鍍鋅作業，形成鑛辞層為5-1〇秒下進行熱 φ C·將形成鍍辞層之熱處理滲碳 餘鋅液之作業。 逆仃刀離夕 D·將分離多餘鋅液後之熱處料碳I件做 ^除雜質及冷卻之作業，係先將熱處理渗碳工件^ /於溫度為loot之氯化氨溶液中去 ， w後再㈣於㈣⑽之冷卻水中作 上述該熱處理滲碳工件之熱浸鍍鋅工法其進疒 除先檢測熱處理滲碳工件之機械性質:並： 上述該熱處理滲碳工件係為鑽尾螺絲或自攻螺 201026892 絲。 上述該清潔之前製作業順序係經由高溫脫脂、水 洗、酸洗除銹、再次水洗、浸泡助熔劑及熱風乾燥。 上述該助溶劑係為氯化氨溶液。 上述該第二次冷卻需不定時補充冷卻水。 ❹201026892 VI. Description of the invention: [Technical field to which the invention pertains] The present invention is related to a method of zinc smelting at a shovel, and the hot dip-plating method of the carburizing workpiece is specially treated by the squeezing screw or the smashing screw Slip fine Me text screws, etc. need to go through the carburizing parts:,...Γ, surface and core hardness heat treatment carburizing heat '2χ5()ί)±5ίΠ: and 35±1〇 seconds between the dip Prior Art] ❹ ❿ Iron and steel materials are an indispensable important factor in human life today. (4) The nature of the ❹: (4) The steel is 'depleted of steel at all times, especially: Taiwan II! In the harsh environment of the wet maritime monsoon, the "corrosion" problem is more serious than other countries. The advanced countries have long noticed the seriousness of "corrosion", and it is estimated that the damage caused by the anti-language is in Japan - about 3% of the nationals = Mao, (GNP). In the United States, this ratio is 4.2%, in the UK 3.5% 'West Germany is 3%' and Taiwan is far above the above ratio, such as 3.5% of Japan, we don’t know in 2〇〇1 I felt that I lost NT$333.0 billion (the gross domestic product in 2001 was about NT$915.13 billion). Therefore, advanced state-owned countries have established relevant anti-money technology research institutions to take various effective measures to avoid or reduce their losses. However, there seems to be no major institution in China to face this problem. Therefore, 'there can be seen everywhere because of the poor anti-corrosion technology or the anti-corrosion method error 201026892 - caused by the "rust rice" landscape, it is very sad" and the use of zinc has been used for more than 150 years, it is estimated that The total amount of steel that is protected by hot dip is about 2,000,000 10,000 tons per year. 'The maintenance value of human limited resources is hard to estimate. (Excerpted from the website of the Republic of China's Hot Dip Forum, httP://www.gaitw.org.tw/inf〇htm), currently used in Ersangwan for the use of hot-dip mines on the screws and nuts to form Mine: The layer has been used as a button for more than 30 years. However, since the hot dip must be carried out at a high temperature of about 500 C, it is a heat treatment operation, and the special workpiece is usually heat treated by tempering or Carburizing heat treatment to adjust the surface and core hardness, the workpiece through the quenching and tempering heat treatment will change the composition particles inside the workpiece, so that the workpiece material can reach the required grade requirements, so the heat treatment will strengthen the hardness of the workpiece and the internal organization of the workpiece. Stabilization, while carburizing heat treatment mainly uses carbon 70 to penetrate into the surface of the workpiece, so that the workpiece forms a carburized layer, and the surface layer of the workpiece is hardened, which has little effect on the hardness of the workpiece core, but the internal part of the workpiece is heat treated by quenching and tempering. The structure is stable, so it has little effect on the mechanical properties of the workpiece after hot dip plating. But for heat treatment carburizing work such as self-tapping screws or self-tapping screws The heat treatment of carburizing is used to adjust the hardness of the surface and the core. Secondly, because the carburized layer is thin, and the carburizing heat treatment has a small impact on the hardness of the core of the workpiece, the temperature of the hot dip galvanizing immersion plating and the immersion plating The length of time, as well as the subsequent cooling operations often lead to changes in the mechanical properties of the heat-treated carburized workpiece, which cannot meet the requirements of the finished product. Therefore, only 201026892 can use the electroplating method or the mechanical mineral zinc method to form the mineral layer, = containing zinc leaching method, Mechanical methods such as smear or zinc spray method ^ "The thickness of the galvanized layer formed by the plating method is limited and one electric method does not hold the a helmet, the upper part, the upper part, the difference" and the mechanical money, the zinc difference: I: point or mouth All have corner uniformity [= content Γ 防 # 效果 effect is not as good as hot leaching mine. 羑 ' 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 有 钻 钻 钻 钻 钻 钻 钻 钻The utility model provides a hot dip galvanizing method for treating a carburized workpiece, and the steps thereof are as follows: Α· The heat treatment of the carburized workpiece is performed before cleaning. Β. The pre-operation will be completed. Heat treated carburized workpiece: immersion plating temperature 500 Soil 5 (TC and immersion plating time is 35+ work', in the immersion galvanizing operation, the formation of the mineral layer is 5-1 〇 second, the heat φ C· will form the heat-treated carburizing residual zinc solution The reverse boring knife D. will separate the excess zinc liquid after the hot material carbon I part to do the impurity and cooling operation, the first heat treatment of the carburizing workpiece ^ / in the temperature of the loot ammonia solution , after w (4) in the cooling water of (4) (10), the hot-dip galvanizing method of the heat-treated carburizing workpiece is carried out, and the mechanical properties of the heat-treated carburized workpiece are first detected: and: the heat-treated carburized workpiece is a self-drilling screw Or self-tapping screw 201026892. The above-mentioned pre-cleaning operation sequence is degreased by high temperature, washed with water, pickled and rusted, washed again, soaked with flux and dried by hot air. The above cosolvent is an ammonia chloride solution. The second cooling described above needs to replenish the cooling water from time to time. ❹
因熱次鍍鋅本身即為一項熱處理作業，對於熱處 ，滲碳工件而言，若無法控制熱浸鍍辞相關參數其 合易在進行熱浸鍍鋅時，再次改變其機械性質，導致 無法符合該成品之要求，而本發明則提供了使熱處理 滲碳工件能使用熱浸鍍辞形成鍍鋅層之相關參數。 本發明具有以下優點： 1·提供如同鑽尾螺絲或自攻螺絲等熱處理滲碳 工件經由熱浸鍍鋅形成鍍鋅層之方法。 2.經由熱浸鍍鋅處理後’產品之機械特性與電鍍 或機械麟-致，但其防銹功能超越電鑛或機械鑛辞 加工甚多。 【實施方式】 首先，請參閲第一圖所示’本發明 理滲碳工件之熱浸鍍鋅工法，其步驟為. ·、、'處 A.將熱處理滲碳工件做清潔之前置作 續作熱浸鍍鋅時在熱處理渗碳 、"i 之鍍鋅層（2)，避免浸鍍時鋅 Ί ^ Μ X , ^ t L &附者在熱處理滲 碳工件（1)上，導致成品防銹、防蝕 層（2)剝落，故必須先做清潔 佳或鍍鋅 月4之則製作業，順序係經 201026892 由高溫脫脂、水洗、酸洗除銹、再次水洗浸泡助 如第二圖所示)’以去除熱處理滲碳 工件（1)表面的雜質，而該助熔劑係為氯化氨溶液， 另外，做清潔之前製作業前，先檢測熱處理渗碳 (1)之機械性質，並篩除不良品。 ❹ Ο B.將完成前置作業的熱處理滲碳工件，控制其 浸鍍溫度500 ± 5(TC及浸鍍時間為35 ±丨〇秒下二埶 浸鑛鋅作業，形成鍵辞層：熱浸鑛辞之溫度約為 t：左右’然而如同鑽尾螺絲或自攻螺絲等熱處理滲碳 工件（1)都必須經過滲碳之熱處理來調整盆 部硬度’為避免浸鑛之高溫改變其機械性質，益法= 合該成品之要求，本發明將浸鑛溫度控制在5〇〇土^ C，而浸料間為35±1G秒，在鑽尾螺絲或自 絲等熱處理滲碳工件⑴表面形歧鋅 :、 圖所示）。 八那乐二 C.將形成鍍鋅層之熱處理滲碳工件進行 餘鋅液之作業：由於螺絲、螺帽等產品精度要求二 Γ為避免鑛辞層厚度太厚，使其尺寸改變而無法也 口，故將該鑽尾螺絲或自攻螺絲等熱處 ( 於浸鑛完成後，將多餘鋅液在尚未凝固前分離。⑴ D.將分離多餘鋅液後之熱處理滲碳工件做二^ :去：雜質及冷卻之作業’係先將熱處理滲碳工件‘ 取=ivorc之氣化氨溶液中去除雜質及冷卻， 後再改泡於60±1(rc之冷卻水中作第二次冷 201026892 部次鍍凡成之熱處理滲碳工件（1)溫度約為5〇(rc 左右因此必須將其冷卻，而冷卻之環境亦會影響及 改變該熱處理滲碳工件⑴之機械性質，故本發明在 =驟D係採用二段式作業’先將熱處理滲碳工件⑴ 二泡於溫度4 1G(rc：^氯化氨溶液中去除雜質及冷 Φ Φ ^取出後再浸泡於6G±1(rc之冷卻水中作第二次^ 二’且該第二次冷卻需不定時補充冷卻水，維持其溫 X為60 ± 1〇 c，縮小冷卻時對該熱處理滲碳工 =械性質的影響，使其符合產品需求。〈附件為六 木牙螺栓採用本發明之熱處理渗碳卫件之熱㈣ ,工法其鍍鋅前、後機械性質及成品標準比較表，表 該Γ角木牙螺检，其心部硬度、表面硬度及滲 灭層皆能符合成品需求> 熱浸鍍辞法可使整個熱處理滲碳工 :均勾之鍵辞層⑵，無論在凹陷處或任何 /恨難進入之角落，熱浸鑛辞法均很容易均句的覆蓋 ^因此可使熱處理滲碳工件⑴之機械性質與電鍵 鋅一致’但其防錄功能超越電鑛或機械料 【圖式簡單說明】 第一圖係為本發明之流程示意圖。 第二圖係為本發明步驟Α清潔順序示意圖 第三圖係為本發明於熱處理滲碳 錢鋅層之示意圖 牛表面形 8 201026892 * 附件為六角木牙螺栓採用本發明之熱處理滲碳 工件之熱浸鍍鋅工法其鍍鋅前、後機械性質及成品標 準比較表，表中顯示該六角木牙螺栓，其心部硬度、 表面硬度及滲碳層皆能符合成品需求。 【主要元件符號說明】 (1) 熱處理滲碳工件 （2) 鍍鋅層Because hot-dip galvanizing itself is a heat treatment operation, for hot parts, carburizing parts, if it is impossible to control the parameters related to hot dip plating, it is easy to change the mechanical properties when hot dip galvanizing, resulting in The requirements of the finished product cannot be met, and the present invention provides relevant parameters for forming a galvanized layer by heat-dip galvanizing of the heat-treated carburized workpiece. The present invention has the following advantages: 1. A method of forming a galvanized layer by hot dip galvanizing of a heat-treated carburized workpiece such as a self-tapping screw or a self-tapping screw. 2. After hot dip galvanizing treatment, the mechanical properties of the product are related to electroplating or mechanical lining, but its anti-rust function is much more than that of electro-mineral or mechanical mining. [Embodiment] First, please refer to the hot dip galvanizing method of the present invention for the carburizing workpiece, the steps of which are as follows: ·, 'At the position of the heat treated carburized workpiece before cleaning Continued hot-dip galvanizing in the heat treatment of carburizing, "i galvanized layer (2), to avoid zinc Ί ^ Μ X , ^ t L & in the heat treatment of carburized workpiece (1) Leading to the anti-rust and anti-corrosion layer (2) of the finished product, it is necessary to do the cleaning or galvanizing month 4, the order is 201026892 by high-temperature degreasing, washing, pickling and rusting, re-washing and soaking as the second The figure shows 'to remove the impurities on the surface of the heat-treated carburized workpiece (1), and the flux is an ammonia chloride solution. In addition, before the cleaning operation, the mechanical properties of the heat-treated carburizing (1) are detected. And screening out bad products. ❹ Ο B. The heat-treated carburizing workpiece of the pre-operation will be completed, and the immersion plating temperature of 500 ± 5 (TC and immersion plating time of 35 ± 丨〇 seconds will be used to form the leaching layer: hot dip The temperature of the mine is about t: around 'however, heat treated carburizing parts such as self-tapping screws or self-tapping screws (1) must be subjected to carburizing heat treatment to adjust the hardness of the bowl' to avoid the high temperature of the leaching and change its mechanical properties. , Yifa = the requirements of the finished product, the present invention will control the immersion temperature in 5 ^ ^ ^ C, and the immersion between 35 ± 1 G seconds, in the surface of the carburizing workpiece or the heat treatment of the carburizing workpiece (1) Zinc zinc:, as shown in the figure). Ba Na Le Er C. will form a galvanized layer of heat-treated carburized workpiece for the operation of residual zinc solution: due to the precision requirements of screws, nuts and other products, in order to avoid the thickness of the mineral layer is too thick, so its size can not be changed The mouth, so the drilling screw or self-tapping screws and other hot places (after the completion of the leaching, the excess zinc liquid is separated before it has been solidified. (1) D. The heat treatment of the carburized workpiece after separating the excess zinc liquid is done 2: Go: Impurities and cooling operations 'Before heat treatment of carburized workpieces' Take the air purification ammonia solution of =ivorc to remove impurities and cool, then change the bubble to 60±1 (rc cooling water for the second cold 201026892 The heat-treated carburized workpiece of the secondary plating (1) has a temperature of about 5 〇 (about rc, so it must be cooled, and the cooling environment also affects and changes the mechanical properties of the heat-treated carburized workpiece (1), so the present invention is at = Step D is a two-stage operation 'First heat treatment of carburized workpiece (1) Second bubble at temperature 4 1G (rc: ^ ammonia solution to remove impurities and cold Φ Φ ^ removed and then immersed in 6G ± 1 (rc cooling The second time in the water ^ two 'and the second cooling needs to be supplemented cold from time to time However, the water maintains its temperature X of 60 ± 1〇c, which reduces the influence of the heat treatment on the carburizing work = mechanical properties, so that it meets the product requirements. <The attachment is the six-toothed bolt using the heat-treated carburizing of the present invention. The heat of the piece (4), the comparison method of the mechanical properties and the finished product standard of the galvanizing before and after the galvanizing method, the hardness of the heart, the surface hardness and the bleed layer can meet the demand of the finished product. > Hot dip plating The lexical process can make the whole heat treatment carburizing work: the key layer of the hook (2), no matter in the depression or any corner where the hate is difficult to enter, the hot leaching method is easy to cover the entire sentence. The mechanical properties of the workpiece (1) are the same as those of the zinc bond 'but the anti-recording function is beyond the electro-mineral or mechanical material. [The simple description of the drawings] The first figure is a schematic diagram of the process of the present invention. The second figure is a schematic diagram of the cleaning sequence of the steps of the present invention. The third figure is a schematic diagram of the invention for heat-treating the carburized zinc layer. The surface shape of the cattle is 8 201026892 * The attachment is a hexagonal wood tooth bolt. The hot-dip galvanizing method of the heat-treated carburizing workpiece of the present invention is used for the mechanical properties before and after galvanization. And finished product Quasi comparison table, shown in the table the teeth hexagonal wood bolt, which core hardness, and surface hardness of the carburized layer Jieneng meet the needs of the finished product. The main element REFERENCE NUMERALS (1) heat treatment carburizing the workpiece (2) zinc coating