TW200948605A - Decorative material and the manufacturing method thereof - Google Patents

Decorative material and the manufacturing method thereof Download PDF

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Publication number
TW200948605A
TW200948605A TW97119663A TW97119663A TW200948605A TW 200948605 A TW200948605 A TW 200948605A TW 97119663 A TW97119663 A TW 97119663A TW 97119663 A TW97119663 A TW 97119663A TW 200948605 A TW200948605 A TW 200948605A
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Taiwan
Prior art keywords
decorative substrate
layer
layered
resin
fiber
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TW97119663A
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Chinese (zh)
Inventor
er-zhou Zhang
jia-qi He
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Advanced Int Multitech Co Ltd
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Application filed by Advanced Int Multitech Co Ltd filed Critical Advanced Int Multitech Co Ltd
Priority to TW97119663A priority Critical patent/TW200948605A/en
Priority to JP2008289922A priority patent/JP2009285823A/en
Priority to US12/313,296 priority patent/US20090293663A1/en
Publication of TW200948605A publication Critical patent/TW200948605A/en

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Abstract

Provided are a decorative material and a manufacturing method thereof. The decorative material includes a plurality of stacked and laminated layer-like fiber units, and at least one cladding layer that is coated on the outmost surface of the layer-like fiber units. Each layer-like fiber unit has a basic layer that is made of resin-impregnating carbon fiber prepreg, and the cladding layer is made of glass fiber material. With the cladding layer made of glass fiber material, resin is blocked from losing from the resin-impregnating carbon fiber prepreg of each layer-like fiber unit during hot pressing process so as to prevent formation of depressions or pits on the product surface, thereby saving the surface working process of removing resin residuals left on the product periphery, and effectively improving product quality and simplifying the manufacturing processes.

Description

200948605 九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種基材,特別是指一種裝飾基材。 【先前技術】 隨著科技與社會的進步,人們對於產品的要求,漸漸 由要求產品堪用,轉變成要求產品具有質量輕、體積小、 強度高、壽命長…等特性。所以,相關業者近年來無不絞盡 腦汁,研發出各式各樣足以滿足人們需求的新興材質。 © 參閱圖1,現有較常見之新興材質當屬碳纖維板材1, 該碳纖維板材1包含多數層相互堆疊貼合之含浸樹脂的碳 纖維預浸布11。利用該碳纖維板材i成型預定產品時,是 將該碳纖維板材1置於一模具中,並施以熱壓,使所述含 浸樹脂的碳纖維預浸布n中的樹脂熔融,而將所述含浸樹 脂的碳纖維預浸布u相互緊密結合且硬化,進而成型出預 定形狀之產品,因為該碳纖維板材1質量輕、強度高及 剛性高等特性,使碳纖維板材1逐漸取代金屬材質。 β 但是,由於碳纖維板材1特性上的限制,利用該碳纖 維板材1成型預定形狀之產品時仍具有下列缺點有待改善 1 ·產品表面不佳·· 因為所述碳纖維預浸布11之孔隙較大,熱壓時容易 造成該碳纖維板材1表面之碳纖維預浸布u中的熔融樹 月曰流失’而在產品的表面形成許許多多的凹陷處或是坑洞 ’影響產品的品質。 5 200948605 2.成型程序複雜: 熱壓時自所述碳纖維預浸布11中流失的炫融樹脂時 常殘留在產品周緣之結合處,使得以該破纖維板材工所成 型的產品,往往需再經由後處理加工製程將殘留在產品外 周緣的樹脂去除,成型程序複雜無疑增加生產成本。 因此,如何防止所述含浸樹脂的碳纖維預浸布11中的 樹月曰在熱壓時流失,以有效改善彦品表面並簡化成型程序 ,成為相關業者所欲積極改善的問題。 β 【發明内容】 因此本發明之主要目的,即在提供一種可以防止樹 月曰流失,而有效改善產品表面之美觀性並簡化製造程序的 裝饰基材。 本發明之另一目的在於提供一種可以防止樹脂流失, 且有效改善產品表面並簡化製造程序之裝飾基材的製造方 法。 G 於是,本發明裝飾基材是包含複數個相互堆疊貼合的 層狀纖維單元,及至少一貼覆於所述層狀纖維單元最外侧 之—表面上的披覆層。 每層狀纖維單元皆具有一由含浸樹脂的碳纖維預浸 布所製成的基本層,而該彼覆層是由玻璃纖維材質所製成 〇 本發明裝飾基材的製造方法包含一準備步驟、一叠合 步驟,及一貼覆步驟。 該準備步驟是準備複數層狀纖維單元,且每一層狀纖 6 200948605 維單元皆具有一由含浸樹脂的碳纖維預浸布所製成之基本 層。 該疊合步驟是將所述層狀纖維單元相互堆叠,並使所 述層狀纖維單元相互貼合,而該貼覆步驟是將所述層狀纖 維單元最外側之一表面上貼覆至少一由玻璃纖維材質所製 成的披覆層。 本發明之功效在於藉由於所述層狀纖維單元最外側之 一表面上,貼覆以玻璃纖維材質所製成的披覆層,阻播每 〇 一層狀纖維單元之基本層中的樹脂在熱壓製程時流失,避 免產品產生凹陷或是坑洞’更可免除後績之產品表面的表 面加工製程,有效改善產品外觀的品質並簡化製造程序。 【實施方式】 有關本發明之前述及其他技術内容、特點與功效,在 以下配合參考圖式之三個較佳實施例的詳細說明中,將可 清楚的呈現。 在本發明被詳細描述之前,要注意的是,在以下的說 © 明内容中,類似的元件是以相同的編號來表示。 參閱圖2 ’本發明裝飾基材2之第一較佳實施例,大部 份應用在機械手臂、筆記型電腦、集電器等產品上,該裝 飾基材2概呈板體狀,且包含複數個相互堆疊貼合的層狀 纖維單元21 ’及兩個分別貼覆於所述層狀纖維單元21之最 外側之上表面212與下表面213上的披覆層22。 每一層狀纖維單元21皆具有一由含浸樹脂的碳纖維預 浸布所製成的基本層211,而所述彼覆層22是由玻璃纖維 7 200948605 材質所製成。 由於該二彼覆層22是以玻璃纖維材質所製成,而玻璃 纖維材質的孔隙較所述基本層211之含浸樹脂的碳纖維預浸 布的孔隙更小,所以本發明裝飾基材2在熱壓製程時,可 藉由該二披覆層22阻擋所述由含浸樹脂的碳纖維預浸布所 製成之基本層211中的樹脂流失,避免因樹脂流失而在產品 表面產生凹陷或是坑洞’更可避免流失的樹脂殘留在產品 外周緣’因此亦免除了去除殘留在產品外周緣之樹脂的表 〇 面加工製程,有效提升產品外觀的品質並簡化製造程序。 於本較佳實施例中,本發明裝飾基材2包含兩個分別 貼覆於所述層狀纖維單元21之最外側之上表面212與下表 面213上,當然,也可以僅具有一個貼覆於所述層狀纖維 單元21之最外側之上表面212上的披覆層22,亦可達成相 同之功效,並不應為本實施例之揭露所囿限。 參閱圖2、3,本發明裝飾基材2的製造方法的較佳實 施例,是用以製造上述第一較佳實施例之裝飾基材2,該裝 0 飾基材2的製造方法包含-準備步驟31、- #合步驟32, 及一貼覆步驟33。 該準備步驟31是準備複數層狀纖維單元21,每一層狀 纖維單tl 21皆具有-由含浸樹脂的碳纖維預浸布所製成之 基本層211。 忒疊合步驟32,是將所述層狀纖維單元21相互堆疊, 並使所述層狀纖維單元21相互貼合。 該貼覆步驟33,是於所述層狀纖維單元21之最外側的 8 200948605 上表面212與下表面213上分別貼覆一由玻璃纖維材質所 製成的彼覆層22。 於本較佳實施例中,本發明裝飾基材2的製造方法的 貼覆步驟33是在所述層狀纖維單元21之最外側的上表面 212與下表面213上,分別貼覆—個披覆層22,當然,也 可以僅於所述層狀纖維單元21之最外側的上表面 212上貼 覆一披覆層22,亦可達成相同之功效,並不應為本實施例 之揭露所囿限。 ❹ 參閱圖4,本發明裝飾基材2之第二較佳實施例,大致 上是與该裝飾基材2之第一較佳實施例相同,包含複數個 相互堆疊貼合的層狀纖維單元2丨,及兩個分別貼覆於所述 層狀纖維單元21之最外側的上表面212與下表面213上的 披覆層22,其中不相同之處在於:每一層狀纖維單元21皆 更具有一與戎基本層211相互貼合,且以玻璃纖維材質所製 成的玻璃纖維層214。利用每一層狀纖維單元21之以玻璃 纖維材質所製成的玻璃纖維層214,阻擒與其相貼合之以含 Θ 韻脂的碳纖維預浸布所製成之基本層211中的樹脂流失, 再配合貼覆於所述層狀纖維單元21之最外侧的上表面212 ”下表面213上的该二披覆層22,更可大幅提升阻擋樹脂 流失的效果。 參閱圖5 ’本發明裝都基材2之第三較佳實施例,大致 上疋與該裝飾基材2之第一較佳實施例相同,相同之處不 再贅言,其中不相同之處在於:該裝飾基材2概呈一曲狀 ,而名一披覆層22是分別貼覆於所述層狀纖維單元21最 200948605 外側表面215與最内側表面216上’提供一不同於該第一 , 較佳實施例的選擇,而同樣可以達成如第一較佳實施例的 功效。 综上所述,本發明裝飾基材2及其製造方法,利用分 別於所述層狀纖維單元21之最外側表面上,貼覆以玻璃纖 維材質所製成的披覆層22,利用以玻璃纖維材質所製成之 該二披覆層22的孔隙較所述基本層211之含浸樹脂的碳纖 維預浸布的孔隙更小,藉此阻擋每一層狀纖維單元21之基 ® 本層211令的樹脂在熱壓製程時流失,避免因樹脂流失而在 產品表面產生凹陷或是坑洞,更可以免除去除殘.留在產品 外周緣之樹脂的表面加工製程,有效改善產品外觀的品質 並簡化製造程序,故確實能達成本發明之目的。 惟以上所述者’僅為本發明之較佳實施例而已,當不 能以此限定本發明實施之範圍,即大凡依本發明申請專利 範圍及發明說明内容所作之簡單的等效變化與修飾,皆仍 屬本發明專利涵蓋之範圍内。 ❹ 【圖式簡單說明】 圖1是一刮面示意圖,說明現有碳纖維板材的態樣; 圖2是一剖面示意’說明本發明裝飾基材之第一較佳 實施例的態樣; 圖3是一流程圖,說明本發明裝飾基材的製造方法之 流程; 圖4是一剖面示意’說明本發明裝飾基材之第二較佳 實施例的態樣;及 10 200948605 圖5是一剖面示意,說明本發明裝飾基材之第三較佳 實施例的態樣。200948605 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to a substrate, and more particularly to a decorative substrate. [Prior Art] With the advancement of technology and society, people's requirements for products are gradually changed from the requirements of products to the requirements of products with light weight, small size, high strength, long life and so on. Therefore, in recent years, related companies have been racking their brains and developing a variety of emerging materials that are sufficient to meet people's needs. © Referring to Fig. 1, the more common emerging material is carbon fiber sheet 1, which comprises a plurality of layers of carbon fiber prepreg 11 impregnated with resin. When the predetermined product is formed by using the carbon fiber sheet i, the carbon fiber sheet 1 is placed in a mold, and hot pressing is performed to melt the resin in the resin-impregnated carbon fiber prepreg n, and the impregnating resin is applied. The carbon fiber prepreg u is closely bonded and hardened to form a product of a predetermined shape. Because of the light weight, high strength and high rigidity of the carbon fiber sheet 1, the carbon fiber sheet 1 is gradually replaced with a metal material. β However, due to the limitation of the characteristics of the carbon fiber sheet 1, the product having the predetermined shape by the carbon fiber sheet 1 has the following disadvantages to be improved. 1. The surface of the product is not good. · Because the pores of the carbon fiber prepreg 11 are large, When hot pressing, it is easy to cause the loss of the molten tree in the carbon fiber prepreg u on the surface of the carbon fiber sheet 1 and the formation of many depressions or potholes on the surface of the product affects the quality of the product. 5 200948605 2. Molding procedure is complicated: the smelting resin lost from the carbon fiber prepreg 11 during hot pressing often remains at the junction of the periphery of the product, so that the products formed by the broken fiber sheet work often need to pass through The post-treatment process removes the resin remaining on the outer periphery of the product, and the molding process is complicated to increase the production cost. Therefore, how to prevent the sap of the resin-impregnated carbon fiber prepreg 11 from being lost during hot pressing to effectively improve the surface of the product and simplify the molding process has become a problem that the related industry desires to actively improve. [Explanation] Therefore, the main object of the present invention is to provide a decorative substrate which can prevent the loss of tree stalks and effectively improve the appearance of the surface of the product and simplify the manufacturing process. Another object of the present invention is to provide a method for producing a decorative substrate which can prevent the loss of resin and which can effectively improve the surface of the product and simplify the manufacturing process. Therefore, the decorative substrate of the present invention comprises a plurality of layered fiber units laminated to each other, and at least one coating layer attached to the outermost surface of the layered fiber unit. Each layered fiber unit has a base layer made of a carbon fiber prepreg impregnated with a resin, and the other layer is made of a glass fiber material. The manufacturing method of the decorative substrate of the present invention comprises a preparation step, A stacking step and a pasting step. The preparation step is to prepare a plurality of layered fiber units, and each of the layered fibers 6 200948605 dimensions unit has a base layer made of a carbon fiber prepreg impregnated with a resin. The laminating step is to stack the layered fiber units on each other and to adhere the layered fiber units to each other, and the attaching step is to attach at least one of the outermost surfaces of the layered fiber units A coating made of fiberglass. The effect of the present invention is that the resin in the base layer of each layer of the fiber unit is blocked by coating the coating layer made of glass fiber material on the outermost surface of the layered fiber unit. Loss during hot pressing to avoid product dents or potholes', which eliminates the surface finish of the product surface, effectively improves the appearance of the product and simplifies the manufacturing process. The above and other technical contents, features and effects of the present invention will be apparent from the following detailed description of the preferred embodiments of the drawings. Before the present invention is described in detail, it is noted that in the following description, like elements are denoted by the same reference numerals. Referring to FIG. 2, a first preferred embodiment of the decorative substrate 2 of the present invention is mostly applied to a mechanical arm, a notebook computer, a current collector, etc., and the decorative substrate 2 is substantially plate-shaped and includes plural The layered fiber unit 21' and the two coating layers 22 respectively attached to the outermost upper surface 212 and the lower surface 213 of the layered fiber unit 21 are stacked. Each of the layered fiber units 21 has a base layer 211 made of a carbon fiber prepreg impregnated with a resin, and the other layer 22 is made of glass fiber 7 200948605. Since the two-layer cladding layer 22 is made of a glass fiber material, and the pores of the glass fiber material are smaller than the pores of the resin-impregnated carbon fiber prepreg of the base layer 211, the decorative substrate 2 of the present invention is hot. During the pressing process, the resin in the base layer 211 made of the carbon fiber prepreg impregnated with the impregnated resin can be blocked by the two coating layers 22, thereby avoiding the occurrence of depressions or potholes on the surface of the product due to resin loss. 'It is better to avoid the loss of resin remaining on the outer periphery of the product'. Therefore, it eliminates the need to remove the surface finish of the resin remaining on the outer periphery of the product, effectively improving the appearance of the product and simplifying the manufacturing process. In the preferred embodiment, the decorative substrate 2 of the present invention comprises two outermost surface 212 and lower surface 213 respectively attached to the layered fiber unit 21, and of course, only one overlay may be provided. The coating layer 22 on the outermost upper surface 212 of the layered fiber unit 21 can achieve the same effect, and should not be limited by the disclosure of the embodiment. 2 and 3, a preferred embodiment of the method for manufacturing the decorative substrate 2 of the present invention is for manufacturing the decorative substrate 2 of the first preferred embodiment, and the method for manufacturing the decorative substrate 2 comprises - Prepare step 31, - #合步骤32, and a pasting step 33. This preparation step 31 is to prepare a plurality of layered fiber units 21 each having a base layer 211 made of a carbon fiber prepreg impregnated with a resin. In the stacking step 32, the layered fiber units 21 are stacked on each other, and the layered fiber units 21 are bonded to each other. The attaching step 33 is to apply a cover layer 22 made of a glass fiber material to the upper surface 212 and the lower surface 213 of the outermost layer 8200948605 of the layered fiber unit 21. In the preferred embodiment, the attaching step 33 of the method for manufacturing the decorative substrate 2 of the present invention is applied to the outermost surface 212 and the lower surface 213 of the outermost layer of the layered fiber unit 21, respectively. The coating layer 22 may of course be attached to the outermost surface 212 of the outer layer of the layered fiber unit 21, and the same effect can be achieved, and should not be disclosed in the embodiment. Unlimited. Referring to FIG. 4, a second preferred embodiment of the decorative substrate 2 of the present invention is substantially the same as the first preferred embodiment of the decorative substrate 2, and includes a plurality of layered fiber units 2 laminated to each other.丨, and two coating layers 22 respectively attached to the outermost surface 212 and the lower surface 213 of the layered fiber unit 21, wherein the difference is that each layered fiber unit 21 is more There is a fiberglass layer 214 which is bonded to the base layer 211 and is made of a glass fiber material. The glass fiber layer 214 made of a glass fiber material of each of the layered fiber units 21 is used to block the resin loss in the base layer 211 made of the carbon fiber prepreg containing the ruthenium resin. And the two coating layers 22 attached to the lower surface 213 of the outermost surface 212 ” of the layered fiber unit 21 can greatly enhance the effect of blocking resin loss. Referring to FIG. 5 The third preferred embodiment of the substrate 2 is substantially the same as the first preferred embodiment of the decorative substrate 2. The same is not the same, and the difference is that the decorative substrate 2 is In a curved shape, the name of a coating layer 22 is respectively attached to the outermost surface 215 and the innermost surface 216 of the layered fiber unit 21, which is different from the first, preferred embodiment. The effect of the first preferred embodiment can also be achieved. In summary, the decorative substrate 2 of the present invention and the method of manufacturing the same are applied to the outermost surface of the layered fiber unit 21, respectively. Covered layer 22 made of fiberglass material, benefit The voids of the two cladding layers 22 made of glass fiber material are smaller than the pores of the resin-impregnated carbon fiber prepreg of the base layer 211, thereby blocking the base layer of each layered fiber unit 21 The resin of 211 orders is lost during the hot pressing process, avoiding the occurrence of depressions or potholes on the surface of the product due to the loss of resin, and it is also possible to eliminate the surface treatment process of the resin remaining on the outer periphery of the product, thereby effectively improving the appearance quality of the product. The simplification of the manufacturing process is intended to achieve the object of the present invention. The above is merely a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. And the simple equivalent changes and modifications made by the description of the invention are still within the scope of the invention. ❹ [Simple description of the drawing] Fig. 1 is a schematic view of a scraped surface, showing the appearance of the existing carbon fiber sheet; BRIEF DESCRIPTION OF THE DRAWINGS FIG. 3 is a flow chart showing the flow of a method for manufacturing a decorative substrate of the present invention; FIG. Figure 4 is a cross-sectional view showing the second preferred embodiment of the decorative substrate of the present invention; and 10 200948605 Figure 5 is a cross-sectional view showing the state of the third preferred embodiment of the decorative substrate of the present invention. kind.

11 200948605 【主要元件符號說明】 2 裝飾基材 215 最外側表面 21 層狀纖維單元 216 最内側表面 211 基本層 22 披覆層 212 上表面 31 準備步驟 213 下表面 32 疊合步驟 214 玻璃纖維層 33 貼覆步驟 ❹ 1211 200948605 [Description of main component symbols] 2 Decorative substrate 215 Outermost surface 21 Layered fiber unit 216 Innermost surface 211 Base layer 22 Coating layer 212 Upper surface 31 Preparation step 213 Lower surface 32 Lamination step 214 Glass fiber layer 33 Attachment step ❹ 12

Claims (1)

200948605 十、申請專利範团: 1. 一種裝飾基材,包含: 複數個相互堆疊貼合的層狀纖維單元,且每一層狀 纖維單70皆具有一由含浸樹脂的碳纖維預浸布所製成的 基本層;及 至少—個被覆層,貼覆於所述層狀纖維單元最外侧 之一表面上,該披覆層是由玻璃纖維材質所製成。 2·依據申請專利範圍第丨項所述之裝飾基材,其中,每一 ® 層狀纖維單元皆更具有一與該基本層相互貼合,且以玻 璃纖維材質所製成的玻璃纖維層。 3. 依據申請專利範圍第丨或2項所述之裝飾基材,是概呈 板體狀,且包含二個分別貼覆於所述層狀纖維單元最外 側之上表面與下表面上的彼覆層。 4. 依據申請專利範圍第丨或2項所述之裝飾基材,是概呈 曲狀,且包含二個分別貼覆於所述層狀纖維單元最外侧 表面與最内側表面上的披覆層。 ® 5.—種裝飾基材的製造方法,包含: 一準備步驟,準備複數層狀纖維單元,每一層狀纖 維單元皆具有一由含浸樹脂的碳纖維預浸布所製成之基 本層; 一疊合步驟,將所述層狀纖維單元相互堆叠,並使 所述層狀纖維單元相互貼合:及 一貼覆步驟,於所述層狀纖維單元最外側之一表面 上貼覆至少一由玻璃纖維材質所製成的披覆層。 13 200948605 6·依據申。青專利範圍第5項所述之裝飾基材的製造方法, 其中’每-層狀纖維單元皆更具有—與該基本層相互貼 σ且以破璃纖維材質所製成的玻璃纖維層。 7·依據I專利範圍第5或6項所述之裝飾基材的製造方 法,其中,該裝飾基材是概呈板體狀,而該貼覆步驟是 於所述層狀纖維單元之最外侧的上表面與下表面上分別 貼覆一由玻璃纖維材質所製成的披覆層。 8.依據U利範圍第5或6項所述之裝飾基材的製造方 〇 法,其中,該裝飾基材是概呈曲狀,而該貼覆步驟是於 所述層狀纖維單元之最外側表面與最内側表面上分別貼 覆一由玻璃纖維材質所製成的披覆層。 14200948605 X. Patent application group: 1. A decorative substrate comprising: a plurality of layered fiber units stacked on each other, and each layered fiber unit 70 has a carbon fiber prepreg made of impregnated resin. a base layer; and at least one coating layer attached to one of the outermost surfaces of the layered fiber unit, the coating layer being made of a glass fiber material. 2. The decorative substrate according to the invention of claim 2, wherein each of the layered fiber units further has a fiberglass layer which is bonded to the base layer and made of a glass fiber material. 3. The decorative substrate according to claim 2 or 2, which is substantially in the form of a plate and comprising two respectively attached to the outermost surface and the lower surface of the layered fiber unit. Cladding. 4. The decorative substrate according to claim 2 or 2, which is substantially curved and comprises two coating layers respectively attached to the outermost surface and the innermost surface of the layered fiber unit. . Manufacture of a decorative substrate comprising: a preparation step of preparing a plurality of layered fiber units each having a base layer made of a carbon fiber prepreg impregnated with a resin; a laminating step of stacking the layered fiber units on each other and bonding the layered fiber units to each other: and a laminating step of attaching at least one of the outermost surfaces of the layered fiber units A coating made of fiberglass. 13 200948605 6. According to the application. The method for producing a decorative substrate according to Item 5, wherein the 'each-layered fiber unit further has a glass fiber layer which is bonded to the base layer and is made of a glass fiber material. The method of manufacturing a decorative substrate according to the invention of claim 5, wherein the decorative substrate is substantially in the form of a plate, and the attaching step is on the outermost side of the layered fiber unit. A coating layer made of a glass fiber material is attached to the upper surface and the lower surface, respectively. 8. The method of manufacturing a decorative substrate according to Item 5 or 6, wherein the decorative substrate is substantially curved, and the attaching step is the highest of the layered fiber units. A coating layer made of a glass fiber material is attached to the outer side surface and the innermost side surface, respectively. 14
TW97119663A 2008-05-28 2008-05-28 Decorative material and the manufacturing method thereof TW200948605A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
TW97119663A TW200948605A (en) 2008-05-28 2008-05-28 Decorative material and the manufacturing method thereof
JP2008289922A JP2009285823A (en) 2008-05-28 2008-11-12 Robot arm, component of its holding means, and manufacturing method of the component
US12/313,296 US20090293663A1 (en) 2008-05-28 2008-11-18 Robot arm

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TW97119663A TW200948605A (en) 2008-05-28 2008-05-28 Decorative material and the manufacturing method thereof

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