TW200948469A - Stirring device, stirrer, and stirring method - Google Patents

Abstract

Disclosed is a stirring device, stirrer, and stirring method that can effectively disintegrate aggregates into which primary particles contained in a stirred substance have aggregated. Disclosed is a stirring device provided with a stirring vessel into which the substance to be stirred is placed, a rotary part that rotates the aforementioned stirring vessel, and a stirrer, the outer circumferential surface of which is circular, which has a grinding part that grinds down the aggregates contained in the aforementioned substance to be stirred and an introduction part that introduces the aforementioned substance to be stirred to the aforementioned grinding part, and which is placed in the aforementioned stirring vessel together with the aforementioned substance to be stirred.

Description

200948469 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a stirring device, a stirring device and a stirring method. The present invention relates to a stirring device "agitating means and a stirring method" which have a BJ-shaped outer peripheral surface and which efficiently agglomerate the aggregate contained in the scrambled material. Further, the present application is related to the following application, and the related claims are from the following priority application of the present application. 1 Application 曰 2008 1 ❿ 1 Japanese Patent Application 2008- Ή51月16曰[Prior Art] Previously, a stirrer used when stirring a liquid was known. For example, the stirrer disclosed in the '1' is in the shape of a fish plate and has a bulge in the bottom surface thereof. The stir-mixer described in the patent is attached to the stirrer;

The core is buried and made so that it does not fall. Patent Document 2 discloses a method in which the mixing container is rotated while rotating around (four) revolution = planetary stirring device. [Patent Document 1] [Patent Document 2] Japanese Laid-Open Patent Publication No. Hei-4-57238-A No. 2000-84388 [Draft of the Invention] [Problems to be Solved by the Invention] Patent Document 1 When the stirrer is raised at the center of the bottom surface, 200948469 is easy to bounce in the vertical direction when used in the planetary stirring device described in Patent Document 2. Further, since it has projections or corners, it is impossible to smoothly contact the sliding in the agitating container. As a result, the stirrer described in the patent document can not be used for the purpose of dispersing agglomerates in which primary particles are aggregated in a liquid. In particular, when the primary particles are particles of several micrometers to submicrometers, they cannot be finely dispersed. In this regard, in one aspect of the present invention, it is an object to provide a mixing device, a scrambler, and a mixing method that can solve the above-mentioned problems. This object is achieved by a combination of features recited in separate items in the scope of the patent application. Further, the subsidiary item defines a more advantageous specific example of the present invention. [Means for Solving the Problems] In order to solve the above problems, a first aspect of the present invention provides a stirring device including: a stirring container into which a stirring material is placed; and a rotating portion that rotates the stirring container; And the enthalpy and the companion "the outer peripheral surface is circular, and is placed in the mixing device together with the agitating material" and has a pulverizing portion for abrading the agglomerates contained in the above-mentioned admixture, and The above-mentioned nutrient is introduced into the above-mentioned pulverizing portion. In the second aspect of the present invention, a kind of stirrer is provided, which is heterogeneous: ^ The contained agglomerate is ground between the inner surface of the stirring vessel:::: : Week: - In the third form of the above-mentioned pulverizing section, a stirring method is provided, which is different: 4 200948469 The step of preparing the stirring, the shape of the thorns and the tings are approximately The cylindrical shape and the tilting L have opposite sides with respect to the inner bottom surface of the mixing container, and the side surface=1; the inclined portion has an acute angle with the inner bottom surface, and connects the opposite surface to the side surface; τ, the composition and the above-mentioned teaching Steps in which the stirrer is placed in the above-mentioned disturbing container And a step of rotating the agitating vessel by a rotating portion;

In the step of rotating the agitating vessel, the agitating material is introduced between the inner bottom surface and the inclined portion, and is slid by contact between the inner bottom surface and the opposite surface to abrade the inclusion of the agitating substance. Condensed. Further, the summary of the above invention does not recite all of the essential features of the present invention, and the sub-combination of these feature groups may also be an invention. [Effect] According to the present invention, it is possible to provide a stirring device, a stirring bar and a stirring method for use in which agglomerates for agglomerating primary particles in a liquid are dispersed. In particular, when a kind of particles having a primary particle of several micrometers to a micrometer can be provided, a stirring device, a stirring bar and a stirring method which can be finely dispersed can be provided. [Embodiment] Hereinafter, one embodiment of the present invention will be described by way of embodiments of the invention. However, the following embodiments are not intended to limit the invention of the patent application No. 200948469; the combination of features described in the X' embodiment All of them are not necessarily required for the solution of the invention. In the following description, the same or similar reference numerals will be given to the same or similar reference numerals, and the description thereof will not be repeated. In addition, the drawings are expressed in the form of 77, the relationship between the thickness and the plane size, the ratio, and the like:: A case different from the actual one. For the convenience of explanation, there are cases where the meshes have mutually different dimensional relationships or ratios. Lu m Fig. 1 is a cross-sectional view showing the stirring device 10 of the present embodiment cut in a plane perpendicular to the horizontal direction. The stirring device 1A includes a stirring container 100, a rotating portion 104, and a stirring member 108, and the aggregate 24 contained in the agitated material 20 placed therein is pulverized. The agitating vessel 1 is formed into a bottomed cylindrical shape, and the agitating vessel 1 has a lid portion 11A, a peripheral wall portion 112, a bottom plate portion 114, and a caster U6. The lid portion 11A is disposed on the upper portion of the agitating vessel 1A and may have a circular plate shape. The peripheral wall portion 112 may have a cylindrical shape including an outer wall surface 122 facing the outer side of the agitating vessel 100 and an inner wall 124 facing the inner side of the agitating vessel 1 . The bottom plate portion 114 is disposed at the bottom of the agitating vessel 100 and may have a circular plate shape. The bottom plate portion 114 includes an outer bottom surface 132 facing the mixing chamber 1GG and an inner bottom surface 134 facing the inner side of the scramble container 100. The inner bottom surface 134 forms an inner surface 118 with the inner wall surface 124. The caster 116 can be disposed, for example, by a ball caster (baiicaster) on the outer bottom surface 132 of the bottom plate portion 114 to reduce the sliding friction of the agitating container 1〇〇. The lid portion 11A, the peripheral wall portion 112, and the bottom plate portion 114 may be a resin such as polypropylene, fluororesin, or rubber, or may be a metal such as sus. 6 200948469 The bottom plate 》P 114 may be integrally formed with the peripheral wall portion 112, and the bottom plate portion 114 may also be smoothly coupled with the peripheral wall portion 112. The agitating vessel 100 may also be made of polypropylene and having a cylindrical shape with a light inside of 56 mm. Further, in the embodiment, the side on which the adjacent Π is placed is referred to as the upper side, and the side on which the bottom plate portion 丨4 is disposed is referred to as the lower side. However, such a description is not intended to limit the use of the disrupting container 100 to the illustrated orientation.

The % rotating portion 104' may be a so-called planetary rotating device that rotates the agitating vessel 100. The rotating portion 104 allows the stirring container 1 to rotate while rotating around the horizontal axis A1 perpendicular to the horizontal axis. The rotating portion 104 has a revolution container 140, a crank 15A, a bearing 152, and a shaft 154. The rotating portion 104 has a motor 156, a balance weight 158, a temple portion 160, and a leg portion 162. The crutches of the stomach are 14 inches, and the inner diameter thereof is larger than the outer diameter of the outer diameter of the container, and the inside of the revolution container i4 is disposed with the stirring container 1 . The revolution container 140 includes a cylinder wall portion 142, a cylinder bottom portion 144, and a shaft j 146. The cylindrical wall portion 142' may be a cylindrical shape "the barrel bottom portion 144 extending along the rotation axis of the revolution container 14", and may be disposed at the bottom of the revolution container 140 in combination with one end of the cylindrical wall portion 142, and has a circular plate shape. The two wall portions I42 may also be integrally formed. The wall portion 142 and the bottom portion 144 of the tube can be gathered? A resin such as a dilute, a fluorinated resin or a rubber may be arranged such that a metal shaft portion such as stainless steel is disposed outside the cylinder bottom portion 144, and is white from the cylinder bottom portion 144.

The center is turned outwardly from the rotating portion HM, and extends along the rotation axis A of the revolution container (four). The revolution container may be made of a fluorinated resin and have an inner diameter of an iv tube shape. 200948469 The revolution 3 is a column shape extending in the horizontal direction to support the adapter 140. The bearing 152 is disposed in the crank of the crank revolving container paste (four) 146, and the end of the crucible (four) is rotated by the revolving container 140: The motor 156' causes the crank 15 via the drawbar 154 with the crank 15 〇 :: the revolving axis A1 as the center '. The balance weight 158 can also be configured by rotating the handle 1 at the other end. The support portion 16 can be used to support the frame 162 of the stable 156. The foot portion 162 can support the support portion from below.

Hey. Further, the "revolving container" is coupled to the support portion 160', for example, via an elastic cow, and the rotation of the revolution container 140 can be suppressed. Next, using the first drawing, the rotating unit 104 will be described as a revolving container 14 by a horse. It is possible to suppress the rotation from the A-axis Ai as a center. When the revolution container 14 is revolved, the agitating container 100 disposed inside is revolved around the revolution axis A1 with the revolution container 14A. The agitating vessel 100 that has started to revolve is slid on the inner surface of the cylinder bottom portion 144 by the action of centrifugal force, and presses the inner surface of the cylinder wall portion 142. The agitating vessel 1 is rotated by the frictional force acting between the outer wall surface 122 and the tubular wall portion 142 on the inner surface of the tubular wall portion 142, and is rotated about the rotation axis A3. Here, the rotation axis of the revolution container 14A may also have an inclination angle S1 and be inclined toward the revolution axis A1 side. Thereby, the revolution container 140 is continuously inclined toward the revolution axis A1 side during the revolution. Therefore, the centrifugal force applied to the mixing container 100 has two components: a force for pressing the agitating vessel 1 to the tubular wall portion 142 and a force for pressing the agitating vessel 100 toward the tubular bottom portion 144. The stirrer 108 is placed in the mixing vessel 〇〇 8 200948469 with the agitator 2〇. The outer diameter of the dialing pin l8 can be smaller than the radius of the inner wall surface i24. When the rotary turret is at 140 rpm, the tweezer (10) revolves around the revolution axis A1 with the revolution container 14 。. The stirrer (10) after the start of the revolution is pushed by the centrifugal force F1$ to the inner wall surface 124 of the agitating vessel 1〇〇. The stirring + 108 ' is rotated on the inner wall surface 124 by the frictional force acting on the outer wall from 122, and is rotated about the rotation sleeve A4. Here, the centrifugal force F acting on the agitating member 108 when the rotation axis A2 of the revolution container 140 is inclined toward the revolution axis ah has a "pushing pressure F2" for pressing the agitating bar ι 8 against the inner wall surface 124, and The two components β of the "pushing pressure F3" which are pushed by the stirring member 1〇8 to the inner bottom surface Η* are rotated by the stirring container 1〇〇, and the stirring member 1〇8 is given: stirring. The action of the pressing force 1?2 which is pressed against the inner wall surface 124 of the stirring container 100 and the pressing force F3 which the stirring element 108 is pressed against the inner bottom surface 134 of the stirring container 100 acts. Fig. 2 is a view showing the outline of the rotational movement of the agitating vessel 100, the agitator 1〇8, and the revolution container 140. The revolution container 14 公 revolves around the revolution axis A1 while rotating, for example, clockwise. The mixing container 100 revolves around the revolution axis A1 in clockwise rotation with the revolution container 140. Since the rotation of the revolving container 140 is suppressed, the mixing container 丨〇〇 is rotated in the opposite direction to the revolution direction of the revolving container 14 ,, that is, counterclockwise. The stirrer 'revolves around the revolution axis A1 clockwise with the stirring vessel 1 ,, and rotates in the same direction as the rotation of the stirring vessel 100 by the rotation of the stirring vessel 1 , that is, counterclockwise rotation. Further, the case where the revolution container 140 rotates in the direction of the clockwise 200948469 around the revolution axis A1 is described, but the rotation direction of the revolution container 14A is not limited thereto. In the first and second drawings, the revolving container 100 is rotated around the revolving axis A1 while suppressing the rotation, and the agitating container 100 is placed on the inner surface of the cylindrical wall portion 142 of the revolving container 140. The rotation (rolling) is performed with the rotation axis A3 as the center, but the method of rotating the stirring container by the rotating portion 1〇4 is not limited thereto. As another method, for example, the stirring container 100 may be fixed to the inside of the revolving container 140, and the revolving container 14 may be rotated around the rotation axis A2 while being rotated around the revolving axis A1 to stir. The container 1 revolves while revolving around the revolving axis A1. At this time, the agitating container 1〇〇 can be fixed to the revolving container 140 so that the rotation axis A3 and the revolving container 14 are located approximately from the rotation axis A2. On the same line. Further, the outer diameter of the mixing container is approximately the same as the inner diameter of the revolution container 140, and the outer wall surface 122 of the stirring container 1 can be connected to the cylindrical wall portion 142 of the revolution container 140 to be fixed. _ 帛 3 ® is an example of a side view of the stirrer 1 8 of the present embodiment. Fig. 4 is a view showing an example of a bottom view of the spreader 1〇8 of the present embodiment. The stirrer (10) will be described below using Figs. 3 and 4. As shown in the third lap, the plucking body (10) may have a shape of a rotator having the rotation axis A4 as an axis of symmetry. Thereby, the abrasion of the scrambler 1〇8 can be reduced. (4) The sub-portion 8 8 may be formed to be plane-symmetric by a plane P perpendicular to the rotation axis A4 and including the center of the disturbing sub-frame 1 8 as a plane of symmetry. Thereby, the outer shape of the stir frit (10) is formed to be vertically symmetrical. 10 200948469 First, the function of the stirrer 108 will be described. The agitator 108 has a pulverizing portion 2〇0 and a lead-in portion 202. The pulverizing portion 2 has a function of pulverizing the agglomerate #24 contained in the agitating material 20. In the pulverizing portion 2, the primary particles contained in the agitating material 20 are honed between the aggregate 24 contained in the agitating material and the inner surface ι 8 of the agitating vessel 1 (Kurota-cho, price 16) 22, agglutination to form agglomerates 24. (4) The sub-(10) abrades the aggregate 24 with a moderate force, whereby the aggregate 24 is disintegrated and dispersed into the primary particles. The introduction portion 202' has a function of introducing the agitated material 2〇 into the pulverizing portion 2〇〇. The crucible 202 is introduced, and may be connected to the pulverizing portion 2〇〇. Thereby, the aggregates are efficiently supplied to the pulverizing portion 2 (9), and the primary particles 22 are dispersed efficiently. Further, the function of the pulverizing portion 2A and the introducing portion 2〇2 functions in the plural of the agitating member 108. Further, the two functions are not clearly distinguishable from the members constituting the pulverizing portion 200, and the shackles of the introducing portion 2'2 constitute the members of the introducing portion 202, and may have the function of the pulverizing portion 2''. Next, an example of the configuration of the stirring unit 1〇8 will be described with reference to Fig. 3 . The agitator 108 has an outer peripheral surface 21A, an opposite surface 24A, and a top surface 25A. The outer peripheral surface 210' extends in the direction of the rotation axis A4 of the agitating member 108 to form the connectable opposing surface 240 and the top surface 250. The outer peripheral surface 21A may have a circular shape, for example, may have an approximately cylindrical shape extending in the direction of the rotation axis A4, and the plucking 108 has a circumferential surface extending in the direction of the rotation axis A4, thus stirring The area in which the inner wall surface 124 of the container 100 abuts increases, and the agitation of the agitator 108 and the inner wall surface 124 can be reduced, and the agitator ι 8 can be stably rotated inside the agitation vessel 100 at 200948469. The outer peripheral surface 210 may be formed in a shape matching the inner wall surface 124 of the agitating vessel 100, and at least one end of the approximately cylindrical outer shape in the direction of the rotation axis A4 may be smaller toward the end portion.

The outer peripheral surface 210' includes a side surface 212 and an outer peripheral inclined portion 214. The side surface 212 can be disposed in the vicinity of the center of the rotation axis of the agitator 1〇8 in the direction of the rotation axis. Side 212 can have a generally cylindrical shape. The side surface 212 may be formed opposite the inner wall surface 124 of the agitating vessel 100. The side surface 212 may be an example of a rupture portion. The outer peripheral inclined portion 214 is configured to connect the side surface 212 and the opposite surface 240 or the top surface 25〇β outer circumferential inclined portion 214, and the smaller the diameter becomes smaller from the side surface toward the opposite surface 240 or the top surface 25 . The outer peripheral inclined portion 214' may be an example of the introduction portion 2'2. The outer peripheral inclined portion 214' may have a tapered portion 222, an arcuate portion 226, and an arc portion 228. The tapered portion 222 and the arcuate portion ... can be disposed on the side surface 212 of the advancing 25 (), and the tapered portion and the odd portion 228 ' can be disposed on the side of the opposite side 24 from the side surface 212. The tapered portion and the tapered portion 226 are linearly connected to the side surface 212 and the opposite surface or the top surface tapered portion 222 and the tapered portion 226, and have a shape in which a part of the conical shape is cut away. The arcuate portion 224 and the arcuate portion (2) are smoothly connected to the side surface 212 and the opposite surface 24 or the top surface 25A. The tapered portion 222 may be at an acute angle S2 to the top surface 250, and the tapered portion 226 may be at an acute angle S2 to the imaginary opposing surface 240. Thereby, the distance from the outer peripheral surface (4) of the face plate including the opposite face 240 gradually decreases from the side surface 2 along the tapered portion. The tapered portion 222, the polygonal portion 226, and the curved portion: 12 200948469 'The tapered portion 226 and the opposite surface 240 the arc portion 228 may be an example of the introduction portion 202, and may be, for example, not a flat surface but an arc portion 228 Or a surface that smoothly connects the sides 212.

The opposite face 240 is disposed relative to the inner bottom surface 134 of the mixing container (10) when the agitator 1〇8 is placed in the agitating vessel 1〇〇. As shown in the first bucket diagram, the opposing face 240 can be a flat face. The opposite face 24() can be an example of a worn portion. The top surface 250 is configured for agitation? The relative positions of the opposite faces 24 of 1 〇 8 ° top surface 25G may also be arranged approximately parallel to the opposing faces 24G. The fifth circle shows the stirrer 5G8 of another embodiment. Fig. 5 is a cross-sectional view showing the state in which the pulverizer 508 is cut in the vicinity of the center of the (four) sub-axis in the direction of the rotation axis A4. Fig. 5 is a view showing that the mixture 2G and the scrambler 5〇8 are placed in the mixing container. _ The outline of the state in which the drop container 100 is rotated by the rotating portion (10). First, an example of the configuration of the stirrer 508 will be described. The holders are 5〇8 with outer peripheral surface 510, bottom Μη 3® TS work, low "Ί 530 and top surface 25〇. The outer peripheral surface 51A is extended in the direction of the rotation axis Α4 of the agitating member 5〇8 corresponding to the outer peripheral surface 2Η) ′ to form the connectable top surface 250 and the opposite surface 54〇. The outer peripheral surface 51A includes a side surface, an arcuate portion 524, and an arc portion 528. Side φ 512, corresponding to side 212, may have an approximately cylindrical shape. The fox 524 is slidable (four) connecting the side 2', and the top surface 250' is slidably connected to the side surface 512 and the opposite surface 540, and the arc portion 528 can be formed with the inner bottom surface 134 of the spoiler container 1 Sharp angle S4. The arc portion 528 may be an example of the introduction portion 2〇2. The bottom 530 includes opposing faces 54 and gullies 2. Here, "bottom" refers to a plane 较 which is perpendicular to the rotation axis 并4 and which contains the center of the mixer 508, and 13 200948469 is closer to the side of the opposite surface 540 side. The opposite face 54 is in the bottom 530 'with respect to the inner bottom surface 134 of the agitating vessel, and the opposing face 540 can be a flat face. Thereby, the opposing surface 54 is slid by the contact between the inner bottom surface 134 and the opposing surface 54A, and the aggregate 24 contained in the agitating material 20 is pulverized until it is dispersed into the primary particles 22. The opposing surface 54A may be an example 0 groove 542 of the pulverizing portion 2A, and may be formed on the bottom surface of the stirring element 5〇8 in the bottom portion 53〇. The φ groove 542 may have a linear shape extending over the entire length of the transverse direction. For example, the width w of the groove 542 may be about 500 ng, and the depth D of the groove 542 may be about 5 〇〇/zm. The groove 542 may be configured to pass through the center of the bottom surface, whereby a pair of opposing faces 540 are formed on the bottom surface of the agitator 508 in the bottom 卩 53 。. The groove 542 may be an example of the introduction portion 2G2. The groove 542 has a groove wall portion 544, a groove inclined portion 546, and a groove inclined portion 548. The groove wall portion 544 may have a U-shaped cross section. The groove inclined portion 5 and the groove inclined portion 548 may be a plane connecting the both ends of the open end of the groove wall portion 544 and the opposite surface 54. The groove inclined portion W and the groove inclination 4 548 are sharply angled with the inner bottom surface 134 of the mixing container 1〇〇. The arrangement position of the groove 542 is not limited to the bottom surface, and may be disposed on the side surface 512 or the outer circumference inclined portion 214. Next, the mechanism for grinding the aggregate 24 will be described using Fig. 5. The mixing system rotates while making contact sliding in the agitating vessel 100. At this time, the mixing 508 is introduced into the gap between the inner bottom 134 and the opposite surface 54 by the gap between the inner bottom surface 134 and the curved portion 528. Here, the so-called dialing 508 is used. The "introduction" of the scrambled material 20 is not limited to the case where the agitating material is brought close to the feeder 14 200948469 by the rotation of the stirrer. When the agitator 508 is contact-sliding on the inner bottom surface 134, it is also included in the "introduction" by the presence of the agitating material 2〇 in the traveling direction of the agitating member 5〇8. Further, by the flow of the agitator 20 in the agitating vessel 1 , the case where the agitator 2 冲 collides with or approaches the agitator 5 〇 8 is also included in the "introduction". Since the arcuate portion 528 smoothly connects the side surface 51 and the opposite surface 54, the gap between the bottom portion 530 and the inner bottom surface 134 gradually narrows from the side surface 512 to the opposite surface 54. Since the opposite side 540 of the ancestor is connected to the arcuate portion 528, the agglomerate 24 cannot directly enter (drill) the gap between the inner bottom surface 134 and the opposite surface 54. Although the agitate 20 contains aggregates 24 of various sizes, the aggregate 24 can only approach the opposite surface 54〇 to a position corresponding to its size, and the aggregate 24 is introduced into the inner bottom surface 134 and the curved portion 528, as the opposite direction In the front, the agglomerate 24 gradually disintegrated and gradually became smaller. By the gap between the inner bottom surface 134 and the arcuate portion 528, the agglomerate 24 introduced into the gap between the inner bottom surface 134 and the opposite surface 54 is slid by the contact between the inner bottom Φ surface 134 and the opposite surface 540. It was crushed and disintegrated. Since the aggregate 24 is formed by aggregation of the primary particles 22, the aggregates 24 are dispersed to the primary particles 22. According to the above configuration, the size of the aggregates 24 when they are introduced into the opposite faces 540 can be made uniform, and it is possible to suppress the force from being applied to one place and the primary particles 22 to be pulverized. When the rotation axis A2 of the "revolving container 14" is inclined toward the revolution axis A1 side, for example, the rotating portion 丨〇4 applies the opposing surface 540 of the stirring element 5〇8 to the stirring container 100 to the stirring element 5〇8. The pressing force F3 is pressed by the bottom surface 134. Thereby, the agitating member 5〇8 is pressed against the inner bottom surface 134, and is in contact with the inside of the stirring container 1 15 15 200948469. As a result, the force of the opposing surface 54 is attenuated by the agglomerate 24. Further, the stirrer 5〇8 can be stabilized in the stirring vessel 1〇〇 and made to contact and slide on the inner bottom surface. In addition, the agitator 508 also introduces the agitator 20 between the inner wall surface 124 and the arcuate portion 524. The agglomerates 24 contained in the introduced agitator 2 are gradually disintegrated and become introduced into the gap between the side surface 512 and the inner wall surface 124. The stirrer 508 can also pass through the side 512 and the inner wall surface 124 if the stirrer 508

Sliding between the contacts, the agglomerate 24 is abraded. For example, in the case of the stirring device 10, a stirring method may be provided which includes a step of placing the agitating member 20 and the agitating member 508 in the stirring vessel, and a step of rotating the agitating vessel 1 by the rotary crucible 104. In the step of rotating the mixing chamber 1GG of the stirring method, the feeding material is introduced into the inner bottom surface 134 "arc. Between 528" and slides by contact between the inner bottom surface ι34 and the opposite surface 54〇. The agglomerate 24 contained in the mixture 2 is crushed. Fig. 6 is a view showing another example of the cross-sectional shape of the groove. The groove 642 has a groove wall portion 644, a groove inclined portion 646, and a groove inclined portion 648. The four inclined faces 646 and the groove inclined portion "8 are slidably coupled to both ends of the open end of the groove wall portion 644 and the opposing faces 54". Fig. 7 is a view showing another example of the cross-sectional shape of the groove. The groove 742 has a slope 4 746 and a groove inclined portion 748. The inclined groove portion may be an inclined surface with respect to the opposite surface 540'; the inclined portion 748 may be an inclined surface with respect to the groove inclined portion 6 and with respect to the opposing surface 54. The ditch slope surface 7 village and the ditch are inclined. Ρ 748 is joined to each other at the ends of one side. The groove inclined portion and the other end portion of the groove 748 are joined to the opposing surface 540 to form a groove 742 having a V-shaped or triangular shape. Fig. 8 is a bottom view showing another example of the planar shape of the groove of the stirrer 5〇8. The agitator 508 may also have a circular arc shaped groove 842, the plurality of grooves 842 of which the arrangement of the grooves 842 may be arranged to expand outward from the center of the bottom surface. The groove 842 may be configured to form an opposite face 540' near the center of the bottom surface. The groove 842' may be configured such that its direction R1 from the inner side to the outer side of the circular arc is approximately the same as the rotational direction r2 of the agitating member 508. Thereby, the groove 842 is formed to easily introduce the scrambler 20. The groove 842 can extend to the vicinity of the center of the bottom surface as a stop, and the groove 842 can also be connected to other grooves near the center of the bottom surface. Fig. 9 is a bottom view showing another example of the planar shape of the groove of the agitating member 508. The mixer 508 may have a groove 942 having an arc shape. The groove 942 may be arranged such that it is reversed from the inner side to the outer side of the arc R1 and the groove 842.

In the first diagram, the bottom view of the planar shape of the groove of the stirrer 508 is not shown, and the groove 1042 of the plurality of straight grooves may be arranged, and the plurality of grooves 1〇42 may be arranged. It may be configured that the radial grooves 1042' may be configured to form an opposing face groove 1042 near the center of the bottom surface that extends to near the center of the bottom surface. The groove 1 θα may be connected to other grooves near the center of the bottom surface. Fig. 11 is a view showing another example of the planar shape of the groove of the agitating member 508. The bottom surface of the mixer 5G8 may have a spiral groove 1142 having a concentric shape with the stirrer. The groove 1142' may be configured such that its direction R3' from the inner side of the spiral is about the same as the direction of rotation of the puffing piece 5() 8. Thereby, it is easy to take the aggregate 24 into the inside of the groove. The groove 1142, also 17 200948469, may be arranged such that its direction R4 from the outer side to the inner side of the spiral is approximately the same as the direction of rotation R2 of the agitator 508. Figure 12 is a cross-sectional view showing a stirrer 12〇8 of another embodiment. Fig. 12 is a view showing a state in which the agitator 12〇8 is cut in the direction of the rotation axis A4 in the vicinity of the center of the agitator 12〇8. Fig. 12 is a view showing an outline of a state in which the agitator 20 and the agitator 1208 are placed in the agitating vessel 1 and the scrambler 1 is rotated by the rotating portion 104. Fig. 13 is a view showing an example of a bottom view of the agitator 1208 of the present embodiment. Hereinafter, the stirrer 12〇8 will be described using the Fig. 12 and Fig. 13 . As shown in the figure, the agitator 1208 has an opposing surface 1240, a top surface 1250, and a center hole 1260. Opposite face 1240 and top face 1250 correspond to opposing faces 540 and top face 250 of feeder 508, respectively, and opposing face 1240 is configured relative to inner bottom face 134, and top face 1250 is configured relative to opposing face 1240. The agitator 1208 can have a central bore 1260 at the center. The central bore 1260 can be configured to extend through the opposing face 1240 and the top face 1250, and the central bore 1260' can be configured as the center of its central bore 1260, adjacent the axis of rotation A4. Thereby, the stirrer 1208 can have the shape of a donut. The center hole 1260 includes a center hole inclined portion 1262, a center hole inclined portion 1264, and an inner peripheral surface 1266. The center hole inclined portion 1262 is disposed at an end portion on the top surface 1250 side of the center hole 1260, and the center hole inclined portion 1262 is connected to the inner peripheral surface 1266 and the top surface 1250. The center hole inclined portion 1264 is disposed at an end portion on the opposite surface 1240 side of the center hole 1260, and the center hole inclined portion 1264 connects the inner peripheral surface 1266 and the top surface 1250. The central hole inclined portion 1262 and the central hole inclined portion 1264 are along the rotation axis A4, respectively, along the top surface 1250

1S 200948469 Side or opposite side 1240 side increases internal diameter. The middle hole 1260 may be an example of the introduction portion 202. That is, the stirrer 12〇8 can introduce the agitating material 2〇 into the gap between the inner bottom surface 134 and the opposite surface 1240 via the central hole 1260, and the inner bottom surface 134 and the (4) φ 124〇& $ contact sliding, grinding The agglomerate 24 contained in the mixture 2 is stirred. In addition, even in this case, for example, the rotation axis 2 of the revolution container 140 is turned to the revolution axis eight! When the side is inclined, the rotating portion 1〇4 applies a pressing force F3 to the agitating member 12〇8 to press the opposing surface 124 of the agitating member 1208 against the inner bottom surface 134 of the agitating vessel 1A. The stirrer 1208 is also the same as the stirrer 508, and may have a groove 542 or the like. Fig. 14 is a view showing an example of a side view of the agitator 14〇8 of the present embodiment. Fig. 15 is a view showing an example of the bottom view ' of the agitator 14 8 of the present embodiment. Hereinafter, the stirrer 14〇8 will be described using the 笫14 diagram and the fifteenth diagram. The agitator 1408 can have a groove 1416 on the side 512. The groove 1416 has a cross-sectional shape and a planar shape, and can be formed in the same manner as the groove 542. The agitating fins 14A8 may form a groove 1442' in the bottom Φ surface. The cross-sectional shape of the groove 442 may be an arc shape, and the planar shape of the groove 1442 may be a shape that expands from the inner side to the outer side of the bottom surface. The planar shape of the groove 1442 may be, for example, a shape in which two arcs connected at one end and an end portion of the solute portion 528 are surrounded. The groove 1442 can be disposed in a direction in which the agitating object 2〇 is easily introduced accompanying the rotation of the throwing member 1408. Thereby, the introduced cocktail 2 can be effectively pressed into the vicinity of the center of the bottom surface. [Example 1] The effect of the present embodiment 19 200948469 was confirmed by using a conductive paste containing copper powder and a resin solution. The copper powder used had an average particle diameter of 12; (zm copper powder. The particle size was measured by a wet method. The resin solution was prepared by dissolving a phenoxy resin in triethylene glycol dimethyl ether. The composition was adjusted to a weight % of 3% by weight. The conductive rubber sample was prepared by mixing 13.8 g of copper powder, 94 cc of a resin solution, and triethylene glycol dimethyl ether. The stirring vessel 1 was a container having a capacity of 15 〇cm 3 made of polypropylene. A planetary rotating device was used for the rotating portion 104. The stirring container 1 was fixed to the revolution container 140, and the revolution container 14 was set to rotate at 340 rpm while rotating at 26 μrpm. The effect of stirring was copper powder. The degree of dispersion was evaluated according to the 4.7.2 line method of Japanese Industrial Standard jis K5400. That is, the sample which was sufficiently stirred was injected into the groove of the particle gauge, and was placed in a blade to form a sample layer having a continuous thickness in the groove. Observe the sample layer and read it in the sample surface. The scales of three or more continuous lines of 10 mm or more are arranged in a groove as the dispersion. The unit is expressed. The smaller the dispersion coefficient value, the more sufficient the copper powder is. Dispersion The conductive paste sample was not dispersed, and the particle size up to the oxime 111 was measured, and the degree of dispersion could not be measured. In Example 1, the outer diameter of the side surface 212 was 2〇111111, and the opposite surface 240 was used. The thickness between the top surface 250 is 1 mm, and the material is stainless steel stirrer 1 〇 8. The experiment is carried out in the following steps. The conductive paste sample and the stirrer adjusted as described above are placed in the stirring vessel. 8. The stirring vessel 1 is placed in the rotating portion 104, and then the rotating portion 1〇4 is rotated at a predetermined speed. The mixing time is changed to measure the degree of dispersion. The experimental results of Example 1 are shown in Table i. The degree of dispersion is recorded by "particles." As shown in the first table, as the stirring time elapses, the "particles" become smaller, and the charge is dispersed in 2009. The first table is implemented, m 30 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 捅 (minutes) 5 10 20 5 10 20 30 5 10 20 30 30 30 30 Cu powder 13.S ♦ — —— ** — *— 13.8 4— «—Resin solution (tree temple component 303⁄4) 9.4 <- K <- 9.4 <- · ·lt ;—Solution « 5 <1—5<--- 4— Stirring medium stirrer 108 4—·—Stirring 108 <- ♦ — No. and < — Ball One 傕 < — Three granules (Method B) 70 55 40 35 90 80 50 40 90 90 95 75 80 85 75 [Embodiment 2] In Embodiment 2, the outer diameter of the side surface 212 is 25 rnm, and between the opposite surface 240 and the top surface 250 The stirrer 108 is made of stainless steel and has a thickness of 1 mm. Other conditions and examples! The same, experiment. The experimental results of Example 2 are shown in Table 1. As shown in the table i, it can be seen that the "particles" become smaller and more dispersed. Then, the conditions in which the stir-mixer was not placed as the comparative example i were carried out in the same manner as in the first embodiment, and the details were ascertained. The results in Table 1 are compared with those in Example 1. As shown in the first table, there is almost no change in the value of "particles" even after the passing time. ('Comparative Example 2) 21 200948469 Next, an experiment was conducted using Comparative Oxidation Ball of 10 mm in diameter as Comparative Example 2. The stirring vessel 10 was placed in a conductive rubber sample and a zirconia ball. The mixing time is 30 minutes. Other conditions are the same as in the first embodiment. In the first table, the experimental results of Comparative Example 2 are shown. "As shown in Table 1, even if the stirring is for 30 minutes, the value of "particles" hardly changes from Comparative Example 1. (Comparative Example 3) Next, experiments were carried out using two zirconia balls having a diameter of 1 mm as Comparative Example 3. The stirring vessel 1 was placed in a conductive rubber sample and two zirconia balls. The other conditions are the same as in Comparative Example 2. The experimental results of Comparative Example 3 are shown in Table 1. As shown in the table, even if it was stirred for 30 minutes, the value of "particles" was almost unchanged from that of Comparative Example 1. (Comparative Example 4) Next, experiments were carried out using two oxidized wrong spheres having a diameter of 1 mm as Comparative Example 3. The stirring vessel 100 was placed with a conductive rubber sample and three zirconia balls. The other conditions are the same as in Comparative Example 2. The experimental results of Comparative Example φ 4 are shown in the third table. As shown in the first table, even if the mixture was stirred for 30 minutes, the value of "particles" hardly changed from that of Comparative Example 1. The graph showing the experimental results is shown in Fig. 16. In Comparative Example i to Comparative Example 4, the value of "particles" hardly changed even if it was stirred for thirty minutes. On the other hand, in the first embodiment and the second embodiment, it is understood that the "particles" sharply decrease as the transfer time elapses. According to the above results, the aggregating material contained in the raw material mixture can be effectively dispersed by the mixing device, the stirrer, and the mixing method of the present embodiment. In particular, even if it is a resin solution containing agglomerates in which primary particles having a particle diameter of several micrometers to a few micrometers are aggregated, the aggregates can be finely dispersed. Thereby, a resin solution, a conductive paste, or the like which can suppress the occurrence of uneven coating of particles such as ribs on the coated surface can be obtained. The present invention has been described above using the embodiments, but the technical scope of the present invention is not limited to the scope described in the above embodiments. It is obvious that the manufacturer can make various changes or improvements to the above embodiments. It is also known that the form of such a change or improvement is also included in the technical scope of the present invention. The order of execution of the processes, sequences, steps, and steps in the devices, systems, programs, and methods shown in the claims, the description, and the drawings is not specifically described as "before" or "first" In addition, the output of the previous processing is not limited to use in subsequent processing, and can be implemented in any order. Regarding the operation flow in the patent scope, the specification, and the drawing, even if it is convenient for explanation, "first" is used. "Next" and the like to illustrate 'but does not mean that it must be implemented in this order. [Industrial Applicability] The present invention can be utilized in an industry of a stirring device, a stirrer or a stirring method for dispersing particles in a liquid, and for example, can be used to produce a conductive particle dispersed in an organic polymer. The conductive adhesive made of materials is in the chemical industry. 23 200948469 [Brief Description of the Drawings] Fig. 1 is a cross-sectional view showing the feeding device 10 of the present embodiment not cut in a plane perpendicular to the horizontal direction. Fig. 2 is a view showing the outline of the rotational movement of the stirring container 100, the stirring unit 1〇8, and the revolution container 14〇.帛3® shows an example of a side view of the stirrer 1G8 of the present embodiment. Fig. 4 shows an example of a bottom view of the stirrer 108 of the present embodiment. Fig. 5 is a view showing a stirrer 5〇8 of another embodiment. Fig. 6 is a view showing another example of the cross-sectional shape of the groove. Fig. 7 is a view showing another example of the cross-sectional shape of the groove. Fig. 8 is a bottom view showing another example of the planar shape of the groove of the stirrer 5〇8.

Fig. 9 is a bottom view showing another example of the planar shape of the groove of the stirrer 5〇8. Fig. 10 is a bottom view showing another example of the planar shape of the groove of the stirrer 508. Fig. 11 is a bottom view showing another example of the planar shape of the groove of the agitating member 5Q8. Fig. 12 is a cross-sectional view showing a stirrer 1208 of another embodiment. Fig. 13 is a view showing an example of 24 200948469 of the bottom view of the stirrer 1208 of the present embodiment. Fig. 14 is a view showing an example of a side view of the agitator 1408 of the present embodiment. Fig. 15 is a view showing an example of a bottom view of the agitator 1408 of the present embodiment. The figure is a chart showing the results of the experiment. [Main component code description 1 ❹ 10 : Stirring device 20 : Stirring material 22 : Primary particle 24 : Aggregate 100 : Stirring container 104 : Rotating portion 108 : Stirrer 110 : Cover portion 112 : Peripheral wall portion 114 : Floor portion 116 : Caster 118: inner surface 122: outer wall surface 124: inner wall surface 132: outer bottom surface 134: inner bottom surface 140: revolution container 142: cylinder wall portion 144: cylinder bottom portion 146: shaft portion 150: crank 152: bearing 154: shaft 156. : balance weight 160 : support portion 162 : leg portion 200 : wear portion 202 : introduction portion 210 . outer peripheral portion 25 200948469

212 : side surface 214 : outer peripheral inclined portion 222 : tapered portion 224 : curved portion 226 : tapered portion 228 : curved portion 240 : opposite surface 250 : top surface 508 : stirring rod 510 : outer peripheral surface 512 : side surface 524 : round Arc portion 528: arc portion 530: bottom portion 540: opposite surface 542: groove 544: groove wall portion 546: groove inclined portion 548: groove inclined portion 642: groove 644: groove wall portion 646: groove inclined portion 648: groove inclined portion 742 : groove 746 : groove inclined portion 748 : groove inclined portion 842 : groove 942 : groove 1042 : groove 1142 : groove 1208 : stirring rod 1240 : opposite surface 1250 : top surface 1260 : center hole 1262 : center hole inclined portion 1264 : center Hole inclined portion 1266: inner peripheral surface 1408: stirrer 1416: groove 1442: groove 26

Claims (1)

200948469 VII. Patent application scope: V· A stirring device, which is provided with: a mixing container into which the mixing material is to be placed; a rotating portion for rotating the stirring container; and a stirring companion whose outer peripheral surface is circular, and The above-mentioned feeding material is placed in the above-mentioned mixing container t, and has a grinding portion for abrading the aggregate contained in the boiling material, and introducing the above-mentioned material portion of the upper (four) mixing (four) person. The mixing device according to claim 1, wherein the spoiler has an approximately cylindrical shape, and the portion of the fracturing portion has an opposite surface with respect to the inner bottom surface of the agitating container. The introduction raft has an inclined portion which is at an acute angle to the inner bottom surface of the agitating container and which connects the opposite surface to the side surface of the spoiler. 3. The sowing device according to claim 2, wherein the stirrer has a donut-shaped outer shape having a center hole at a center portion, and the grinding and drinking portion has a relative to the agitating container. The opposite side of the inner bottom surface, the introduction portion ' has the center hole. 27 200948469 4. 5. 6. The stomach mixing device of 2 or 3, wherein the introduction of the °P' system further has a groove formed at the bottom of the above-mentioned searcher. The mixing device according to Item 4, wherein the H. I system has an inclined portion which is a portion which is opposite to the opposite side of the agitating container and which is at an acute angle to the inner bottom surface of the search container. The agitating device according to claim 4, wherein the groove has a spiral shape concentric with the stirrer. 7. The agitating device according to any one of claims 2 and 3, wherein the stirring portion is provided by pressing the bottom of the stirrer to the bottom surface by the stirring mixer. Push the role of pressure. The rotation of the container, the above-mentioned inside of the above-mentioned stirring container A stirrer comprising: a lead-in portion in a portion of the agitating container; and an agglomerate in which the aggregate contained in the stirrer is crushed; and the above-mentioned object is introduced into the above-mentioned crusher The outer circumference of the circle. 9. If the scope of the patent application is symmetrical. The stirrer of the above-mentioned item is a shape of a stirrer as described in claim 8, which has an approximately cylindrical shape, and the above-mentioned abraded portion has a relative shape as described above. The opposing surface of the inner bottom surface of the container is lifted, and the introduction portion has an inclined portion, and the inner bottom surface of the deflector has an acute angle and connects the opposite surface and the upper side surface. Φ η 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 In the opposite side of the present invention, the above-mentioned introduction portion of the core hole has the above-mentioned mixing material according to the first aspect of the invention, wherein the human body portion further has a groove formed at the bottom of the upper-mixer. The scrambler according to claim 12, wherein the upper surface is inclined, and the inclined portion is connected to the stirrer and the knife and is at an acute angle to the inner bottom surface of the agitating container. The searcher described in claim 12, wherein the groove has a spiral shape concentric with the agitating member. 29 200948469 is an opposite surface of the inner cylindrical surface which is approximately cylindrical, and has an acute angle on the side surface, and is connected to the above-mentioned phase 15. A stirring method is provided with: a step of preparing a stirrer, the stirrer Having the inclined portion opposite to the inner bottom surface and the side surface with respect to the stirring container and the inclined portion; and the step of placing the aggregating material and the scrambler into the stirring container, the rotating container is rotated by the rotating portion In the step of rotating the mixing chamber 11 , the (4) material is introduced between the inner bottom surface and the inclined portion ′, and the agitating material is abraded by contact sliding between the inner bottom surface and the opposite surface The agglutination method included in the method of agitating, comprising: a step of preparing a stirrer, which is a doughnut having a doughnut shape and having a center hole of a center portion of the doughnut shape described above And the opposite side of the inner bottom surface of the agitating container; the step of placing the search mixture and the above-mentioned carrier into the above-mentioned spoiler container, and the above-mentioned teaching by the rotating portion a step of rotating the container; in the step of rotating the spoiler container, introducing the scramble into V and 'sliding by contact between the inner bottom surface and the opposite surface' The aggregates contained. 30 a step of rotating the agitating vessel by a rotating portion; and between the copper powder and the above, and pulverizing the copper powder and the above-mentioned 200948469 by the above-mentioned. 7. As described in claim 15 or 16 of the patent application. In the method of the above-mentioned (four) capacity H (four), the field (four) is given a pressing force against which the inner bottom surface of the agitating member is pressed against the inner bottom surface of the agitating container. H crawling Η — — — — — — — — — — — — — — — — — — — — — — — — 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电a side surface and an inclined portion of the bottom surface, the inclined portion and the inner bottom surface are at an acute angle, and the opposite surface and the side surface are connected; a step of placing the copper powder, the resin solution and the stirrer into the stirring container; In the step of rotating the agitating vessel, the resin solution is introduced into the contact between the inner bottom surface and the inner bottom surface of the inclined portion and the opposite surface, and the aggregate contained in the resin solution is described. A method for producing a conductive paste, comprising: a step of preparing a stirrer which is a donut having a doughnut shape and having a center hole of a center portion of the doughnut shape described above And a surface opposite to the inner bottom surface of the agitating vessel; a step of placing the copper powder, the resin solution, and the agitating member in the agitating vessel; and 31 200948469 a step of rotating the agitating vessel by a rotating portion; In the step of rotating the agitating vessel, the copper powder and the resin solution are introduced into contact between the opposite faces of the center hole, and the contained aggregate is ground. And, by the inner bottom surface and the above-mentioned phase, the copper powder and the resin solution are as described in the above-mentioned patent application, and the pressure of the bottom surface of the stirrer is pushed upwards. .上述 疋 疋 32 32 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 (2) A brief description of the component symbols of the representative drawing: 200: Fracturing portion 202: 210: outer peripheral portion 212: 214: outer peripheral inclined portion 222: 224: arc portion 226: 228: arc portion 240: 250: top surface Side of the introduction part = opposite side of the tapered part of the tapered part. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 200948469 Invention patent specification 'Do not change anything in the order of the item' ※Please do not fill in the part of the mark; please do not fill in the number of the mark; please fill in the form ※ ※Application number: 98101422 ※Working PC classification: ※Application deadline: 2009 1 Month 15曰1, invention name: (Chinese) Stirring device, stirrer and stirring method II. Abstract: The present invention provides a stirring device, a stirring device and an effective dispersing stirring spoon in a mixing method, which may have Things. Aggregation of primary particles contained in the present invention The present invention provides a stirring device which is incorporated into a mixing container; the mixing container is screwed, the mixture is placed in a container, and is useful for hemp: The agitating material is placed together with the above-mentioned stirring device to smash the agitating portion of the agitating material and the agglomerate of the agitating material 3 into the agitating portion. . III. English Abstract: 200948469 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a device (4) device and a _ sub-mixing method. The present invention relates to a mixing device i, a spaghetti, and a mixing method which have a circular outer peripheral surface and which efficiently agglomerate the agglomerates contained in the object. Further, the present application is related to the following application, which claims priority from the following application. L Japanese Patent Application No. 2〇〇8_7451 Application Date 2〇月16日 [Prior Art] Previously, a dial member for agitating a liquid was known. For example, the patent (m) provides a shape of a fish plate and a bulge in the bottom surface thereof. (4) The mix is described in (1), and the η is embedded in the core of (4), and the μ will be poured. In Patent Document 2, Bellow discloses a money mixing container-side rotation, side (four) (four) planetary stirring device. [Patent Document 1] 专利 专利 专利 4 τ Α 特 特 特 4 4 4 — — — — — 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 84 84 84 84 84 84 84 84 84 84 84 84 [Problems to be Solved by the Invention] The stirrer described in Patent Document 1 is raised at the center of the bottom surface of the butt: 200948469. When used in the planetary stirring device of 咋I πA described in Patent Document 2, it is easy to be used up and down. Bounce in the direction. Furthermore, due to the presence of protrusions or corners, it is not possible to smoothly slide in the mixing container. As a result, the stirrer described in Patent Document 1 cannot be used for the purpose of dispersing aggregates in which liquid and primary particles are aggregated. In particular, when the primary particles are particles of a few micrometers to a second micrometer, they cannot be finely dispersed. In this regard, in one aspect of the present invention, it is an object of the present invention to provide a stirring device, a stirring bar and a kneading method which can solve the above problems. This object is a more advantageous specific example clarified by the combination of the features described in the separate items in the scope of the patent application. [Means for Solving the Problems] In order to solve the above problems, the stirring device according to the present invention includes: a stirring container into which a stirring material is to be placed; a rotating portion that rotates the stirring container; and the above 1 The outer peripheral surface is (four), and is placed in the same manner as the above-mentioned (four) material, and has a pulverizing portion for pulverizing the aggregate contained in the above-mentioned feed mixture, and the above-mentioned portion. 4 The introduction of the search mixture into the above-mentioned honing portion is introduced into the second aspect of the present invention, and provides a catching and stirring device, which is provided with: agglomerates contained in the mixed towel, which are crushed in the collapse. The makeup and/or the inner surface of the agitated glutinous rice is milled and rounded/1, and the introduced portion is introduced into the introduction portion of the pulverizing portion; and a circular outer peripheral surface. A third aspect of the present invention provides a method of the fourth aspect, which is characterized in that: 200948469 is a step of preparing a scrambler, which is a cylindrical member having a shape of 4 (4) $4 (4) $4, which is relative to The opposite surface of the bottom surface of the agitating vessel, the side surface = the inclined portion', the inclined portion and the inner bottom surface are at an acute angle, the surface is connected to the opposite surface and the side surface; and the carrier and the stir frit are placed in the dialing container a step of rotating the stirring container by a rotating portion; φ, in the step of rotating the mixing container, introducing the object to be transferred between the inner bottom surface and the inclined portion, and by the inner bottom surface The above-mentioned "surface" "(4)" is aggravated by the agglutination included in the money mixture. X' The summary of the above invention does not recite all the essential features of the present invention, and the sub-combination of some of the feature groups may also become an invention. [Effect] According to the present invention, the material provides a stirring device, a stirring device and a stirring method for the purpose of dispersing the agglomerate in which the primary particles of the (four) towel are dispersed. In particular, a kind can be provided. The particles of the order of the particles of several micrometers to a few micrometers can be finely dispersed (four) mixing device, (four) sub- and sub-systems, and the following embodiments of the invention are described by the embodiments of the invention. The shape 1 is not intended to limit the invention of the patent application No. 200948469; however, all of the combinations of features described in the embodiments are not necessarily required for the solution of the invention. Further, in the following, reference is made to the drawings. In the description of the drawings, the same or similar components are denoted by the same reference numerals, and the description thereof will not be repeated. In addition, the relationship between the thickness and the plane size is shown by the schema. The ratio, the ratio, etc. may be different from the actual one. For the convenience of explanation, the drawings also have a relationship of mutually different sizes or ratios. φ Fig. 1 shows the direction perpendicular to the horizontal direction. The cross-sectional view of the stirring device of the present embodiment is cut in a plane. The stirring device 10 includes a stirring container 100, a rotating portion 104, and a stirring member 108. The agglomerate 24 contained in the agitating material 20 placed in the inside thereof is abraded. The agitating vessel i is a bottomed cylindrical shape, and the agitating vessel 100 has a lid portion 11A, a peripheral wall portion 112, and a bottom plate portion 114. And a caster U6. The lid portion 11A is disposed on the upper portion of the agitating vessel 1A, and may have a circular plate shape. The peripheral wall portion 112 may have a cylindrical shape and include an outer wall surface facing the outer side of the agitating vessel 丨22 and an inner wall surface 124 facing the inner side of the agitating vessel. The bottom plate portion 114 is disposed at the bottom of the agitating vessel 100 and may have a circular plate shape. The bottom plate portion 114 includes a bottom surface 132 facing the outer side of the agitating vessel 100, and The inner bottom surface 134 faces the inner side of the agitating vessel 100. The inner bottom surface 134 and the inner wall surface 124 together form an inner surface 118. The caster 116' may be, for example, a ball caster (baUe_r) disposed on the outer bottom surface 132 of the bottom plate portion 114 to reduce the sliding friction that disturbs the container (10). cover. The P110 sash portion 112 and the bottom plate portion 114 may be a resin such as polypropylene, vaporized tree, or rubber, or may be a metal such as stainless steel (sus). 200948469 The bottom plate portion 114 can be integrally formed with the peripheral wall portion 112, and the bottom plate portion ii4 can also be smoothly coupled to the peripheral wall portion 112. The agitating vessel 1 may be made of polypropylene and has a cylindrical shape β of an inner diameter of 4 56 mm. In the embodiment, the side on which the lid portion 110 is disposed is referred to as an upper side, and the bottom plate portion 114 is disposed. It has been carried on the lower side. However, such description is not intended to limit the use of the agitating vessel 100 to the illustrated orientation. The rotary cymbal 104' may be a so-called planetary rotary device that rotates the agitating vessel 0. The rotating portion 104 can rotate the stirring container (10) around the revolving axis perpendicular to the ruler, and the rotating container 104 can have the revolving container 140, the crank 150, and the bearing. 152 and the shaft 154 ° rotating portion 104' has a motor 156, a balance weight 158, a holding Ρ 160 and a foot 162. The revolution container 14 〇 can be the outer diameter of the inner diameter of the hopper The large bottomed cylindrical shape 'is disposed inside the revolving container 140 with the agitating container 1 〇〇. The % transducer 140' includes the cylindrical wall portion 142, the bottom portion of the barrel, and the shaft wall portion 142' may be along The cylindrical shape of the rotation axis of the container "0". The cylinder bottom portion 144' may be formed in a circular plate shape in combination with one end of the cylindrical wall portion (4), and may be formed integrally with the crucible body. The tubular wall portion 142 and the tubular bottom portion (4) may be a resin obtained by dissipating resin or rubber, or may be a metal such as stainless steel. :, "6, is disposed outside the bottom 144 of the cylinder, from the bottom of the cylinder (4) to the outside of the rotating portion 1G4, along the rotation of the revolution container 14 (), the shape of the rotation container can also be a gasification resin The circle having an inner diameter of 1〇〇_200948469 The crank 150' may be a column shape extending in the horizontal direction to support: the rotary container 140. The shaft * 152 is disposed at one end of the curved #15〇, The shaft portion 146 of the rotator 140 is inserted, and the bearing 152 supports the revolving container wo so as to be rotatable. The motor 156 is coupled to the crank 15A via the shaft 154, and the crank is centered on the revolving axis A1 to make the crank 15 〇 rotation. At the other end of the crank 150, a balance weight 158 may also be disposed. The support portion 160 may be a frame body 162 for supporting the horse 156 to support the support portion from below. 160. Further, the revolution container 140 and the support portion 16 are coupled, for example, via an elastic member, to suppress the rotation of the revolution container 140. Next, an outline of the operation of the rotating unit 1〇4 will be described using the 帛i diagram. The 公 156 and other 'revolving containers 14 〇 can revolve around the revolution axis Ai while suppressing the rotation. When the revolution container 14 is revolved, the mixing container 100 disposed inside is revolved around the revolution axis 伴随 with the revolution container 14〇. After the start of the revolution, the action of the stomach 1 〇 is slid, and the inner surface of the tube 2 is slid and the inner surface of the tube 2 is pushed. The agitating vessel 1 is rotated by the frictional force acting between the outer wall surface 122 and the tubular wall portion 142 on the inner surface of the tubular wall portion 142, and is rotated about the rotation axis A3. Here, the rotation axis μ of the revolution container (10) may have an inclination angle S1 and be inclined toward the revolution axis A1 side. Thereby, the revolution valley 140' is continuously tilted toward the revolution axis A1 side during the revolution. Therefore, the centrifugal force acting on the W container (10) has two components: a force for pressing the mixing container _ toward the cylindrical wall portion 142 and a force for pressing the stirring container 1 to the bottom of the cylinder. _ (4) The sub 1〇8' is placed inside the mixing container 1〇〇200948469 together with the scrambler 20. The outer diameter of the carrier 108 can be smaller than the radius of the inner wall surface 124. When the revolution container is 140 revolutions, the stirring unit 1〇8 revolves around the revolution axis A1 with the revolution container 14〇. The scrambler (10) after the start of the revolution is pushed to the inner wall surface 124 of the agitating vessel 100 by the action of the centrifugal force F1. The agitator 108 is rotated by the frictional force acting on the inner wall surface 124 with the frictional force acting on the outer wall surface 122, and is rotated about the rotation axis A4. Here, when the rotation axis A2 of the a-turner 140 is inclined toward the magic side of the revolution axis, the centrifugal force F acting on the Lu (four) sub-108 has a "pushing force" for pushing the feeder ι 8 against the inner wall surface 124. F2" and the two components of the repulsive force F3" that pushes the mixer 108 to the inner bottom surface 134. In this way, the revolving container 14 is provided with the action of the pressing force of the stirring member 1〇8 to the inner wall surface 124 of the stirring container 100 by the rotation of the stirring container 1〇0, and The action of pushing the stirrer (10) to the inner bottom surface 134 of the mixing container 1 is the action of the pushing force F3. Fig. 2 shows the mixing of the stomach, the transfer, the ι〇8 and the revolution container® 140. The outline of the rotary motion, the revolving container 14 is rotated around the revolution axis A1 while rotating, for example, clockwise. The drop container 100 revolves around the revolution axis AH 顺 clockwise together with the revolution valley € 140. Since the rotation of the revolving container 140 is suppressed, the mixing container _ is rotated in the opposite direction to the revolving direction of the revolving container, that is, rotating counterclockwise. The sand mixing piece 108 is attached to the stomach. Rotating clockwise around the revolution axis A1 4乍", by the rotation of the mixing container (10), it rotates in the same direction as the rotation of the search container (10), that is, rotates counterclockwise. Clocking around the revolution axis ai 200948469 The direction of rotation is explained, but the rotation of the revolving container 14A is limited to this. In addition, in the first and second figures, the rotation of the revolving container 14 is suppressed. A1 is the center for revolving, and the stirring container 1〇0 is rotated (rolled) on the inner surface of the wall portion (4) of the revolving container, and the rotation axis A3 is centered for rotation 'but the rotating portion 1G4 rotates the mixing container 100 The method is not limited to this. As another method, for example, the mixing container may be fixed to the inside of the revolving container 14A, and the revolving axis A1 may be rotated around the rotation axis A2 while the revolving axis A1 is used. In order to revolve the heart, the stirring container rotates once and rotates around the revolving axis A1. At this time, the agitating container 100 may be fixed to the revolving container 140 to rotate the axis A3 and the revolving container 14 The 〇 self-rotating shaft A2 is located approximately on the same line. Further, the outer diameter of the agitating vessel 100 is approximately the same as the inner diameter of the revolving container mo, and the outer wall surface 122 of the agitating vessel 100 can also be connected to the wall portion of the a-turner 14 〇 142 is fixed. Fig. 3 is a view showing an example of a side view of the stirrer 1〇8 of the present embodiment. Fig. 4 is a view showing a bottom view of the stirrer 1〇8 of the present embodiment, and below, using the third and fourth figures. The nutrient is shown in Fig. 3. The agitator 1〇8 may have a shape of a rotating body having the axis of rotation A4 as an axis of symmetry. Thereby, the wear of the agitator 108 can be reduced. The stirrer 1〇8 can also be The plane p perpendicular to the rotation axis A4 and including the center of the agitating bar 1〇8 is formed as a plane of symmetry, and is formed into a plane symmetry. Thereby, the shape of the agitating bar 1〇8 is formed to be vertically symmetrical. 200948469 First, the scrambling is explained. The function of child 108. The agitator 8 has a pulverizing portion 200 and a lead-in portion 202. The pulverizing portion 200 has a function of pulverizing the aggregate 24 contained in the agitating material 2, and a pulverizing portion 2 〇〇, which is an agglomerate 24 contained in the scrambled material 2 ,, and a stirring container 〇 The inner surface 118 of the crucible is worn apart. The primary particles contained in the agitator 20 are agglomerated to form agglomerates 24 » The agitators 1〇8 abrade the aggregates 24 with a moderate force, whereby the aggregates 24 can be disintegrated and dispersed into primary particles 22 until. The introduction portion 202' has a function of introducing the agitating material 2〇 into the pulverizing portion 2〇〇. The introduction portion 202 may be connected to the pulverizing portion 2A. Thereby, the aggregates 24 are efficiently supplied to the pulverizing portion 2, and the primary particles 22 can be efficiently dispersed. Further, the function of the squeezing portion and the introduction portion is to function in the plural of the feeders 1 to 8. Further, the two functions are not clearly distinguishable, and the members constituting the squeezing portion 200 may be constituted by the machine I having the introduction portion 2? The member of the human part 2G2' may have a grinding unit. Next, an example of the configuration of the stirring unit 1〇8 will be described with reference to Fig. 3 . The mixer 108 has an outer peripheral surface 21A, an opposite surface 24A, and a top outer surface 〇1〇 extending in the direction of the rotation axis A4 of the stirrer 108, and is formed to connect the opposite surface 240 and the top surface 25A. The outer peripheral surface 21A may have a circular shape: for example, may have a shape of an approximately cylindrical shape extending in the direction of the rotation axis A4, whereby the 'stirring pair 1' 8 has a circle extending in the direction of the rotation axis A4: a surface, and thus the stirring container The area in which the inner wall surface 124 of the one turn abuts becomes large, and the wear of the stirrer 108 and the inner wall surface 124 can be reduced, and the stirrer 1 〇 8 can be stably rotated inside the stirring container 100. The outer peripheral surface 210 may be formed in a shape matching the inner wall surface i 24 of the mixing container 100, and at least one end of the approximately cylindrical outer shape in the direction of the rotation axis A4 may have an outer diameter that becomes smaller toward the end portion. The outer peripheral surface 21 0 ' includes a side surface 2丨2 and an outer peripheral inclined portion 2丨4. The side surface 212' can be disposed near the center of the rotation axis of the stirring element 1〇8 in the four directions. Side 212 can have a generally cylindrical shape. The side surface 212 may be formed to oppose the inner wall surface 124 of the agitating vessel 1'''''''' The side surface 212 may be an example of the rupture portion 2A. The peripheral inclined portion 214 is configured to connect the side surface 212 with the opposite surface 240 or the top surface 250. The outer peripheral inclined portion 214 can be turned from the side surface 212 to the opposite side of the 240 or the top of the sheet, and the diameter of the crucible becomes a material. The outer peripheral inclined portion 214 may be an example of the introduction portion 2〇2. The outer peripheral inclined portion 214 may have a tapered portion 222, an isolated portion 226, and an arc portion 228. The tapered portion and the arcuate portion 224 may be disposed on the top surface 25 from the side surface 212 (the tapered portion 226 and the curved portion 228' may be disposed on the side of the opposite surface 240 from the side surface 212. The tapered portion 222 and the tapered portion 226 are linearly connected to the side surface 212 and the opposite surface or the top surface. The tapered portion 222 and the tapered portion have a conical shape of the conical portion. The 224 and the fox 228 are smoothly connected to the side surface 212 and the opposite surface 24 〇 or the top surface 25 〇. The tapered portion 222 can be topped and γη g & an acute angle s2, and the tapered portion 226 can be at an acute angle to the opposite surface 240 S2. The distance 藓 of the surface 210 is gradually narrowed from the side surface 212 toward the phase needle surface 240 along the tapered portion 226. The tapered portion 222, 'cone $ 226, arc portion 224 and 12 200948469 arc The portion 228 may be an example of the introduction portion 2〇2. For example, the tapered portion 226 may not be a flat surface but an arcuate portion 228 or a curved surface that smoothly connects the side surface 212 and the opposite surface 240. The opposite surface 240' When the agitator 108 is placed in the agitating vessel 1 , it is disposed to the inner bottom surface 134 of the agitating vessel 1 . As shown in FIG. 4 , 240 may be a flat surface. The opposing surface 24 may be an example of the squeezing portion 2 (10). The top surface 250 may be disposed at a position opposite to the opposing surface 24 of the stirring element 1 〇 8 The drawing is approximately parallel to the opposing surface 240. Fig. 5 is a view showing a stirring member 5 of another embodiment. Fig. 5 is a cross-sectional view showing the stirring member 508 when the stirring member 508 is cut toward the rotation axis A4 in the vicinity of the center of the stirring member 508. Fig. 5 is a view showing an outline of a state in which the agitating material 20 and the agitating member 508 are placed in the stirring container 1 and the stirring container 100 is rotated by the rotating portion. First, an example of the configuration of the stirring element 508 will be described. The stirrer 5〇8 has an outer peripheral surface 510, a bottom portion 53〇, and a top surface 25〇. The outer peripheral surface 51〇 corresponds to the outer peripheral surface 21〇, and extends toward the rotation axis of the stirrer 508 in the direction of the eighth axis, and forms a connectable top. The surface 250 and the opposite surface 54〇β outer peripheral surface 51〇 include a side surface 512, an arcuate portion 524 and a singular portion 528. The side surface 5 12, corresponding to the side surface 212, may have an approximately cylindrical outer shape. The arc portion 524 may The side surface 512 and the top surface 250 are smoothly connected, and the arc portion 528 can be smoothly connected to the side The face 512 and the opposite face 540' arcuate portion 528 may be at an acute angle S4 to the inner bottom surface 134 of the agitating vessel 1A. The arcuate portion 528 may be an example of the lead-in portion 2〇2. The bottom portion 530 includes an opposing face 54〇 and a groove 542. Here, the "bottom" is a portion ρ that is perpendicular to the rotation axis 并4 and includes the center of the agitator 5〇8, 13 200948469 is closer to the portion on the opposite surface 540 side. The opposite surface 540 is at the bottom 53 〇 relative to the insole s 134 of the mixing container 100, and the opposite surface "Ο can be a flat soil-face # this, the opposite surface 54 is between the inner bottom surface 134 and the opposite state The contact slides to grind the aggregate 24 contained in the scrambled material until it is dispersed into the primary particles 22. The opposing surface (10) may be an example of the pulverizing portion 200. / 542' may be formed in the bottom portion 530 at the stirring member 508. The bottom surface of the groove 542 may be a linear shape extending transversely to the entire length of the radial direction. For example, the width W of the groove W may be about 5 m, and the depth d of the groove (4) may be about 5 〇〇Μΐ n. It can be arranged to pass through the center of the bottom surface, whereby a pair of opposing faces 54 形成 are formed on the bottom surface of the stirrer 508 in the bottom portion 530. The groove 542 can be an example of the introduction portion 202. The groove 542 has a groove wall portion. 544, groove inclined portion 546 and groove inclined portion 548. The groove wall portion 544 may have a [shaped cross section] groove inclined portion 546 and the groove inclined portion 548 may be a connecting groove wall portion, ... The groove plane 546 and the groove inclined portion 548' are at an acute angle S3 to the inner bottom surface 134 of the agitating vessel 100. 542 #The position of the arrangement is not limited to the bottom, and may be disposed on the side surface $^2 or the outer circumference inclined portion 214. Next, the mechanism for grinding the aggregate 24 will be described using Fig. 5. The stirring rod 508 is rotated while rotating. The mixing chamber 510 is used for contact sliding. At this time, the agitating member 508 introduces the agitating material 20 into the gap between the inner bottom surface 134 and the opposite surface 54 through the gap between the inner bottom surface 134 and the curved portion 528. Here, the so-called agitator 508 "introduces" the agitator 2, and is not limited to the case where the agitator 20 is brought close to the attachment 200948469 of the agitator 508 by the rotation of the agitator 508. When the agitator 508 is contact-sliding on the inner bottom surface 134, it is also included in the "introduction" by the presence of the agitating material 2〇 existing in the traveling direction of the agitating member 508. Further, the case where the flow of the agitator 20 in the agitating vessel 1 is collided or brought close to the agitator 508 is also included in the "introduction". Since the arcuate portion 528 smoothly connects the side surface 5丨2 and the opposite surface 54〇, the gap between the bottom portion 530 and the inner bottom surface 134 gradually narrows from the side surface 512 toward the opposite φ surface 54〇. Since the opposing face 540 is coupled to the arcuate portion 528, the agglomerate 24 cannot directly enter (drill) the gap between the inner bottom surface 134 and the opposite surface 54. Although the agitate 20 contains aggregates 24 of various sizes, the aggregate 24 can only approach the opposite surface 540 to a position corresponding to its size, and the aggregate 24 is introduced into the inner bottom surface 134 and the curved portion 528 along the opposite side. 54〇 Advance, the agglomerate 24 gradually disintegrated and gradually became smaller. Through the gap between the inner bottom surface 134 and the arcuate portion 528, the agglomerate 24 introduced into the gap between the inner bottom surface 134 and the opposite surface 540 slides by contact between the inner bottom surface 134 and the opposite surface 54〇. It was crushed and disintegrated. Since the aggregate 24 is formed by aggregation of the primary particles 22, the aggregates 24 are dispersed to the primary particles 22. According to the above configuration, the size of the aggregates 24 when they are introduced into the opposite faces 540 can be made uniform, and it is possible to suppress the force from being applied to one place and the primary particles 22 to be pulverized. Here, for example, when the rotation axis A2 of the revolving unit 140 is inclined toward the revolving axis A1 side, the 'rotating part i 04' applies the opposing surface 540 of the agitating piece 5〇8 to the agitating container 1〇〇 to the agitating piece 5〇8. The pressing force F3 is pressed by the bottom surface 134. Thereby, the '(4) sub-508'' is pushed toward the inner bottom surface 134, and the contact sliding is performed in the mixing container 100 at 15 200948469. As a result, the force of the opposing surface 54 is attenuated by the agglomerate 24. Further, the agitator 508 can be stabilized in the agitating vessel 1 并 and brought into contact sliding on the inner bottom surface. Further, the agitator 508 also introduces the agitator 20 between the inner wall surface 124 and the arcuate portion 524. The agglomerates 24 contained in the introduced agitator 2 are gradually disintegrated and become introduced into the gap between the side surface 5] 2 and the inner wall surface 124. The agitator 508 can also be abraded by contact between the side surface 512 and the inner wall surface 124 to abrade the aggregate 24. For example, if the agitator 5〇8 is applied to the scrambler 1〇, a scramble method can be provided which has a step of placing the agitator 20 and the agitator 508 in the agitating vessel, and a rotating portion. The step of rotating the mixing container 1〇〇. In the step of rotating the stirring capacity n 100 of the mixing method, the agitating material is introduced between the inner bottom surface 134 and the arc portion 528, and is slipped by the contact of the inner bottom from the 134 and the opposite surface. Aggregate 24 contained in the substance 2〇. Fig. 6 is a view showing another example of the cross-sectional shape of the groove. The groove 642 has a groove wall portion 644, a groove inclined portion and a groove inclined portion 648. The groove wall portion (4) has a ^-shaped (four) surface. The groove inclined portion 646 and the groove inclined portion 648 can slide both ends of the open end of the groove wall portion 644 and the opposing surface 540. Fig. 7 is a view showing another example of the cross-sectional shape of the groove. The groove is inclined, the phase (4) 746, and the phase (4) is 5, the inclined portion 748, and the inclined portion of the groove is attached to the side. !) can be an inclined surface. The groove inclined surface 746 and the groove inclined portion 748 are combined with each other. The groove inclined portion 746 and the end portion of the groove ' are joined to the opposite surface 54A to form a groove 742 having a v-shape or a triangular shape on the cross-section 16 200948469. Fig. 8 is a bottom view showing another example of the planar shape of the groove of the stirrer 5〇8. The agitator 5〇8 may have a circular groove M2, and the groove M2 of the groove M2 may be arranged to expand from the center of the bottom surface to the outer side. The groove 842 may be arranged to form an opposite groove near the center of the bottom surface. The 842 can be configured such that its direction R1 from the inner side to the outer side of the circular arc is about the same in the direction of rotation R2 of the mixing 508. Thereby, the groove is φ so that the agitating material 2 is easily introduced. The groove 842 can be extended to the bottom surface. In the vicinity of the center, the groove 842 may be connected to the other groove near the center of the bottom surface. Fig. 9 is a bottom view showing another example of the planar shape of the groove without the stirring member 5〇8. The mixer 508 may have The groove 942 having an arc shape. The groove 942 may be disposed such that it is opposite to the groove 842 from the inner side to the outer side of the circular arc. The first drawing shows another planar shape of the groove of the agitating member 508. The bottom view of the example. The stirrer 5〇8' may also have a plurality of linear grooves = 2' grooves 1042, and the plurality of grooves 1〇42 may be configured to emit 5 grooves 1〇42, which may be configured to The salty opposite surface 冓 042 near the center of the bottom surface can extend to the center of the bottom surface. The groove 1 〇 42 may be connected to other grooves in the vicinity of the center of the bottom surface. Fig. 11 is a view showing another example of the planar shape of the groove of the agitating 508 = bottom view (4) sub-5G8 may have and (4) The sub-port 5G8 has a concentric outer-shaped groove 1142. The groove 1142' can be configured such that its direction R3' from the inner side of the spiral to the ί is approximately the same as the rotational direction R2 of the searcher 5〇8. This 'aggregates 24 It is easy to take in the inside of the groove. The groove 1142, also 17 200948469, can be arranged such that its direction R4 from the outer side to the inner side of the spiral is approximately the same as the direction of rotation R2 of the granter 508. Fig. 12 shows another Fig. 12 is a cross-sectional view showing the stirrer 12〇8 of the embodiment. Fig. 12 is a view showing the case where the stirrer 1208 is cut in the direction of the proximal axis A4 of the stirrer 12〇8 in the proximal direction. The outline of the state in which the stirring vessel 1 is placed in the stirring vessel 1 and the stirring vessel 1 is rotated by the rotating portion 104 is shown as an example of the bottom view of the stirring element 1208 according to the present embodiment. Below, use Figure 12 and Figure 13 to illustrate the stirrer丨2〇8 As shown in the figure, the stirrer 1208 has an opposite face 124〇, a top face 125〇 and a nail hole 1260. The opposite face 1240 and the top face 125〇 correspond to the opposite faces 540 and top of the stirrer 508, respectively. The face 25 〇, the opposing face 124 is configured to be disposed relative to the opposite face 1240 with respect to the inner bottom surface 134 ′. The agitator 1208 can have a central bore 126 中心 at the center. The central bore 1260 can be configured The through-hole facing surface 124〇 and the top surface i25〇, the center hole _ 1260, may be disposed as the center of the center hole 1260, located in the vicinity of the rotation axis A4. Thereby, the agitating member 1208 can have the shape of a donut. The center hole 1260 includes a central hole inclined portion ι262, a central hole inclined portion 1264, and an inner peripheral surface 1266. The center hole inclined portion i262 is disposed at an end portion on the top surface 1250 side of the center hole 1260, and the center hole inclined portion 1262 is connected to the inner peripheral surface 1266 and the top surface 1250. The center hole inclined portion 1264 is disposed at an end portion on the opposite surface 1240 side of the center hole 1260, and the center hole inclined portion 1264 connects the inner peripheral surface 1266 and the opposite surface 1240. The center hole inclined portion 1262 and the center hole inclined portion 1264' are along the rotation axis A4, and the inner diameter is increased toward the top surface 18 200948469 1250 side or the opposite surface 1240 side, respectively. The middle to hole 1260 may be an example of the introduction portion 202. That is, the stirrer 12〇8 can introduce the agitating material 2〇 into the gap between the inner bottom surface 134 and the opposite surface 1240 via the center hole 1260, and is slid by the contact between the inner bottom surface 134 and the opposite surface 1240. The agglutinate 24 contained in the mixture 2 is stirred. In addition, in this case, for example, when the rotation unit A2 of the revolution container 14A is inclined toward the revolution axis A1 side, the rotation unit 1〇4 applies the stirring surface 12〇8 to the agitating the opposite surface 124 of the stirring bowl 1208. The inner bottom surface 134 of the container 100 pushes the pushing force F3. The stirrer 12〇8 is also the same as the stirrer 5〇8, and may have a groove 542 or the like. Fig. 14 is a view showing an example of a side view of the agitator 1408 of the present embodiment. Fig. 15 is a view showing an example of a bottom view of the agitator 1408 of the present embodiment. Hereinafter, the stirrer 14〇8 will be described using Figs. 14 and 15. The agitator 1408 can have a groove 1416 on the side 512. The groove 1416 has a cross-sectional shape and a planar shape, and can be formed in the same manner as the groove 542. The stirrer 1408 can form a groove M42 on the bottom surface, and the cross-sectional shape of the groove 1442 can also be an arc shape, and the planar shape of the groove 1442 can also be a shape that expands from the inner side to the outer side of the bottom surface. The planar shape of the groove 1442 may be, for example, a shape in which two arcs connected at one end and an end portion of the arc portion 528 are surrounded. The groove 1442 can be disposed in a direction in which the agitating object 2 is easily introduced accompanying the rotation of the thrower 1408. Thereby, the introduced scrambler 20 can be effectively pressed into the vicinity of the center of the bottom surface. [Example 1] The effect of the present embodiment 19 200948469 was confirmed using a conductive paste containing copper powder and a resin solution. As the steel powder, copper powder having an average particle diameter of 12/zm was used. The particle size is measured by the wet method. The resin solution was prepared by dissolving an epoxy resin in triethylene glycol dimethyl ether. The phenoxy resin was adjusted to a weight % of 3% by weight. The conductive paste test was prepared by mixing copper powder of l3.8 g, resin solution 94%, and triethylene glycol dimethyl ether 5 cc. The agitating vessel 100 is a container having a capacity of 15 〇 cm 3 made of polypropylene. The rotating portion 104 uses a planetary rotating device. The agitating vessel 1 was fixed to the revolving vessel 140, and the revolving vessel 14 was set to rotate at 261 rpm while rotating at 34 rpm. The effect of stirring was evaluated by the dispersion method of copper powder according to the 4.7.2 line method of Japanese Industrial Standard jis K5400. That is, a sufficiently turbulent sample is injected into the groove of the particle gauge to mount the blade, and a sample layer having a continuous thickness is formed in the groove. The sample layer was observed and read in the sample surface, and three scales of continuous lines above m iOmm and above were arranged in one groove as the dispersion. The unit is represented by Am. The smaller the value of the dispersion coefficient, the more fully dispersed the copper powder. The conductive paste sample before the mixing was not dispersed, so that the particle size up to 1 〇〇 Mm could be measured, and the degree of dispersion could not be measured. In the first embodiment, the outer diameter of the side surface 212 is 2 (), and the thickness between the opposite surface 240 and the top surface 250 is 1 〇, and the material is a searcher which does not record steel. The experiment was carried out in the following steps. In the spoiler vessel 1 〇〇, the conductive paste sample and the stirrer ι 8 adjusted as described above were placed. The agitating vessel 100 is placed in the rotating portion 104, and then the rotating portion 1〇4 is rotated at a predetermined speed. The stirring time was changed and the degree of dispersion was measured. The experimental results of Example 1 are shown in the i-th table. The dispersion in the table is U "particles" to record. As shown in the first table, as the stirring time elapses, the "particles" become smaller, and the charge is dispersed in 2009. [Table 1] r stipulation " JI • - I - Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 «mixing time (minutes) 5 10 20 30 5 10 20 - 30 5 10 20 30 30 30 30 Cu powder 13.8 «I— ♦- < — 13.8 • 4— < — *— < — < — Resin solution (resin component 303⁄4 ) 9.4 < — < — 9.4 Μ — < — < — 溶 5 5 4 — 5 lt; — • 4 — Stirring medium mixer 108 «— 搀 子 108 108 108 108 108 108 108 108 108 108 70 70 70 70 70 70 70 70 70 90 50 90 90 90 95 75 80 85 75 [Embodiment 2] In Example 2, the outer diameter of the side surface 212 is 25 mm, the thickness between the opposite surface 240 and the top surface 250 is 1 mm, and the material is a stainless steel stirrer ιοί. The conditions were the same as in Example i, and experiments were carried out. The experimental results of Example 2 are shown in the Table ι. As shown in the first table, as the stirring time elapses, the "particles" become small and are sufficiently dispersed. V Comparative Example 1) The experiment was carried out by using the unmixed searcher as Comparative Example 1. The conditions were the same as in Example i, and experiments were carried out. In the table, the results are shown in Table 1. As shown in Table 1, the value of the "particles" hardly changed even after the mixing time. (Comparative Example 2) 21 200948469 Next, an experiment was carried out using a cerium oxide ball having a diameter of 10 mm as Comparative Example 2. The stirring vessel 100 was placed with a conductive rubber sample and a zirconia ball. Stirring time is thirty minutes. Other conditions are the same as in the embodiment. The experimental results of Comparative Example 2 are shown in Table 1. As shown in the first table, even if the disturbance was stirred for 30 minutes, the value of "particles" hardly changed from that of Comparative Example 1. (Comparative Example 3) Next, experiments were carried out using two zirconia balls having a diameter of 10 mm as Comparative Example 3 ❹. The stirring vessel 100 was placed with a conductive rubber sample and two cerium oxide balls. The other conditions are the same as in Comparative Example 2. The experimental results of Comparative Example 3 are shown in the third table. As shown in the table, even if it was stirred for 30 minutes, the value of "particles" was almost unchanged from that of Comparative Example 1. (Comparative Example 4) Next, experiments were carried out using three cerium oxide balls having a diameter of 丨0 mm as Comparative Example 4. The stirring vessel was just placed with a conductive rubber sample and three zirconia balls. The other conditions are the same as in Comparative Example 2. The experimental results of Comparative Example 4 are shown in the table. As shown in the first table, even if the mixture was mixed for 30 minutes, the value of "particles" hardly changed from that of Comparative Example 1. A graph showing the experimental results is shown in Fig. 16. In Comparative Example 1 to Comparative Example 4, the value of "particles" hardly changed even if it was stirred for twenty minutes. On the other hand, in the first embodiment and the second embodiment, it is understood that the "particles" sharply decrease as the stirring time elapses. According to the above results, the aggregating material contained in the scrambled material can be effectively scattered by the mixing device, the stirrer, and the mixing method of the present embodiment. In particular, even if it is a resin solution containing agglomerates in which a phase particle having a particle diameter of several micrometers to a second micrometer is aggregated, it is possible to prevent the resin solution and the conductive paste collected on the coated surface from being finely dispersion. Thereby, the occurrence of uneven coating of a green particle such as a rib can be obtained. The above description of the scope of the present invention is not limited to the above-described embodiments, and it is obvious that the above-described embodiments are variously changed, and such modifications are made or the technical scope of the present invention. The present invention is within the scope of the technical description of the present invention. The industry is clearly more or better. The form in which the scope of the patent application is modified may also be included in the order in which the processes, the procedures, the steps, the steps, and the steps of the mw method t, which are to be noted in the scope of application, the description and the drawings, are not in the order of execution, and are not In particular, "before", "first", and the like, the output of the previous processing is not limited to use in subsequent processing, and can be realized in any order. Regarding the action flow in the patent scope, #明书, and schema, even if it is used for the convenience of explanation, "first", "continue", etc., but does not mean that it must be implemented in this order. [Industrial Applicability] The present invention can be utilized in an industry of a stirring device, a stirring device, or a stirring method for dispersing particles in a liquid, and for example, can be used to produce a conductive particle dispersed in an organic polymer material. In the chemical industry of conductive adhesives. 23 200948469 [Brief Description of the Drawings] Fig. 1 is a cross-sectional view showing the stirring device 10 of the present embodiment cut in a plane perpendicular to the horizontal direction. Fig. 2 is a view showing the outline of the rotational movement of the agitating vessel 100, the agitator 108, and the revolution container 140. Fig. 3 is a view showing an example of a side view of the agitator 108 of the present embodiment. _ Fig. 4 shows an example of a bottom view of the agitator 108 of the present embodiment. Fig. 5 shows a stirrer 508 of another embodiment. Fig. 6 is a view showing another example of the cross-sectional shape of the groove. Fig. 7 is a view showing another example of the cross-sectional shape of the groove. Fig. 8 is a bottom view showing another example of the planar shape of the groove of the mixer 508. Fig. 9 is a bottom view showing another example of the planar shape of the groove of the stirrer 5〇8. Fig. 10 is a bottom view showing another example of the planar shape of the groove of the agitator 508. Fig. 11 is a bottom view showing another example of the planar shape of the groove of the agitating member 508. Figure 12 is a cross-sectional view showing the scramble + 1208 of another embodiment. Fig. 13 is a view showing an example of 24 200948469 of the bottom view of the sub-12 () 8 of the present embodiment. Fig. 14 is a view showing an example of a side view of the agitator 1408 of the present embodiment. Fig. 15 is a view showing a bottom view of the stirrer 1408 of the present embodiment. Fig. 16 is a graph showing experimental results. [Explanation of main component symbols] ❹ 10 : Stirring device 20 : Feeder 22 : Primary particle 24 : Aggregate 100 : Stirring vessel 104 : Rotating portion 108 : Stirrer 110 : Cover portion 112 : Peripheral wall portion 114 : Floor portion 116 : Caster 118: inner surface 122 • outer wall surface 124: inner wall surface 132: outer bottom surface 134: inner bottom surface 140: revolution container 142: cylinder wall portion 144: cylinder bottom portion 146: shaft portion 150: crank 152: bearing 154: shaft 156: motor 158: balance weight 160 • support portion 162: leg portion 200: wear portion 202: introduction portion 210: outer peripheral portion 25 200948469 212 : side surface 214 : outer peripheral inclined portion 222 : tapered portion 224 : curved portion 226 : tapered portion 228 : curved portion 240 : opposite surface 250 : top surface 508 : stirring rod 510 : outer peripheral surface 512 : side surface 5 24 : Arc portion 528 : arc portion 530 : bottom portion 540 : opposite surface 542 : groove 544 : groove wall portion 546 : groove inclined portion 548 : groove inclined portion 642 : groove 644 : groove wall portion 646 : groove inclined portion 648 : groove inclination Part 742 : Ditch 746 : Ditch inclined portion 748 : Ditch inclined portion 842 : Ditch 942 : Ditch 1042 : Ditch 1142 : Ditch 1208 : Stirrer 1240 : Opposite surface 1250 : Top surface 1260 : Center hole 1262 : Center hole inclined portion 1264 : Center hole inclined portion 1266: inner peripheral surface 1408: stirrer 1416: groove 1442: groove 26 200948469 Invention patent specification 'Do not change anything in the order of the item' ※Please do not fill in the part of the mark; please do not fill in the number of the mark; please fill in the form ※ ※Application number: 98101422 ※Working PC classification: ※Application deadline: 2009 1 Month 15曰1, invention name: (Chinese) Stirring device, stirrer and stirring method II. Abstract: The present invention provides a stirring device, a stirring device and an effective dispersing stirring spoon in a mixing method, which may have Things. Aggregation of primary particles contained in the present invention The present invention provides a stirring device which is incorporated into a mixing container; the mixing container is screwed, the mixture is placed in a container, and is useful for hemp: The agitating material is placed together with the above-mentioned stirring device to smash the agitating portion of the agitating material and the agglomerate of the agitating material 3 into the agitating portion. . III. English Abstracts: 200948469 VII. Application for Patent Scope··········································································· In the agitating vessel of the outer circumference MsiH, the agitating material is set to be used to grind the above-mentioned grinding machine (4), and the part included in the above-mentioned material=mixing material. (The agitating substance is introduced into the above-mentioned pulverizing portion L'. The internal bottom surface of the ninth portion of the above-mentioned pulverizing portion is as follows. 2. The above-mentioned stirring device of the above-mentioned stirring device as described in claim 1 has an approximately cylindrical shape. Having the opposite side with respect to the above-mentioned tolerance, β is provided with an inclined portion, the inclined portion and the upper portion The agitating and accommodating inner bottom surface of the agitating nozzle has an acute angle and connects the opposite surface and the upper side surface. The agitating device according to claim 1, wherein the spar has a donut-shaped outer shape having a central hole at a central portion, and the abrading portion has an inner bottom surface with respect to the agitating container On the opposite side, the introduction portion ' has the above-mentioned center hole. The agitating device according to claim 2, wherein the introduction portion further has a groove formed at a bottom portion of the agitating member. The mixing device according to claim 4, wherein the groove has an inclined portion which is a portion connecting the opposite faces of the agitating member, and is opposite to the inner bottom surface of the transfer container: The transfer device of claim 4, wherein the groove has a spiral shape concentric with the stirrer. The agitating device according to any one of claims 2, 5, or 6, wherein the W-switching device is provided with the above-mentioned stirrer by the rotation of the above-mentioned spoiler container The bottom of the bottom pushes the pushing force of the stirring capacity bottom surface. River A stirrer comprising: a grinding portion that is abraded between agglomerates contained in the agitating material on the inner surface of the agitating vessel; and the above-mentioned search compound is introduced into the above-mentioned crushing The introduction part of the part; a circular outer peripheral surface. The shape is shaped 9. The identities are as described above in the patent application 帛8. 28 200948469 10. The stirrer according to the eighth aspect of the invention, which has an approximately cylindrical outer shape, and the opposite side of the abrading portion has the introduction portion with respect to the inner bottom surface of the agitating container. The side surface of the inner bottom surface of the device. The utility model has an inclined portion which is perpendicular to the above-mentioned mixing capacity and which is connected to the opposite surface and the above-mentioned The system has a donut-shaped outer shape having a center hole as described in the above-mentioned patent _8, and the above-mentioned squeezing portion has a relationship with respect to the above The above-mentioned introduction portion is provided with the above-mentioned center hole 12. The above-mentioned introduction portion of the above-mentioned introduction portion is further provided with a stirrer as described in the item 1, wherein the groove 13 at the bottom of the above-mentioned stirrer The shit as described in claim 12, wherein the groove has an inclined portion that is a portion that connects the opposite surface of the wrestle and is at an acute angle to an inner bottom surface of the spoiler container. . The stirrer according to claim 12, wherein the groove has a spiral shape concentric with the above-mentioned stirrer. 29 14. 200948469 15. A method of stirring is provided with: a step of preparing a stirrer, which is a shape stirrer, which has a 俜1 古士非上', is approximately cylindrical, and has a relative stirring container The opposite surface of the inner bottom surface and the inclined portion, the inclined portion and the inner bottom surface are opposite to the side surface; and the step of connecting the phase to the stirrer and the stirrer and the stepper; a rotating portion for rotating the transfer container; in the step of rotating the mixing container, between the inner bottom surface and the inclined portion and sliding by the contact between the upper surface and the opposite side of the mixture, grinding- Face with the above body. The agglutination method included in the agitation on the top of the sputum 16. The stirring method is provided with a step of preparing a stirrer, the sap of the sap, the sacred and ancient..., the shape of the squid is a donut-shaped finger / , ',, the center hole of the center portion of the donut-shaped portion, and the opposite surface of the inner bottom surface of the stirring container: , placing the object of the wrestling and the smuggling and the disturbing device into the stirring container a step of rotating the spoiler container by a rotating portion; in the step of rotating the middle/falling container, introducing the search object into m' and connecting between the inner bottom surface and the opposite surface 'After the agglutination contained in the above agitated material. 30. The method of mixing and mixing according to the above-mentioned patent application, in the step of rotating the mixing container, the above-mentioned relative surface of the stirrer Push the pressure. a method for manufacturing a conductive paste according to the inner bottom surface of the agitator, comprising: U5 ❺: injury: a step of mixing the mixer, the shape of the stirrer is approximately cylindrical, and is opposite to the mixing container The opposite surface of the inner bottom surface, the side surface portion, the inclined portion and the inner bottom surface are at an acute angle, and the opposite surface and the side surface are connected; the copper powder, the resin solution and the stir frit are placed in the stirring step; and a rotating portion for rotating the mixing container; and in the step of rotating the mixing container, the copper powder and the fat solution are introduced between the inner bottom surface and the inclined portion, and the surface is The contact between the opposite faces slides to abrade the steel powder and the aggregate contained in the resin solution. A method for producing a conductive paste, comprising: a step of preparing a stirrer; the feeder is in the form of a doughnut shape, and has a center hole of a center portion of the doughnut shape, And a surface opposite to the inner bottom surface of the agitating vessel; a step of placing the copper powder, the resin solution and the scrambler into the mixing vessel; and 31 200948469 a step of rotating the agitating vessel by the rotating portion; In the step of rotating the stirring vessel, the copper powder and the resin solution are introduced into the center hole, and the copper powder and the resin solution are ground by sliding contact between the inner bottom surface and the opposite surface. The method for producing a conductive paste according to the invention of claim 19, wherein in the step of rotating the agitating vessel, the above-mentioned relative of the stirrer is imparted to the stirrer The pushing force against the inner bottom surface of the above-mentioned transfer container is raised. 32