200941073 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一種液晶顯示器裝置及其製造方法, 特別有關於一種單層彩色膽固醇液晶顯示器裝置及其製造 方法。 【先前技術】 β 液晶顯示器(LCD)具有許多的優點,例如體積小、重量 輕、低電力消耗等等。因此,LCD已經廣泛地被應用於手 提式電腦、行動電話等電子產品。亦即,液晶顯示器技術 正持續朝向輕、薄且易於攜帶的領域發展。傳統反射式具 記憶效應的彩色化液晶顯示器已廣泛應用在電子書、電子 紙或其他顯示領域。傳統彩色膽固醇液晶顯示器的結構與 製作方法,使用紅(R)、綠(G)、藍(B)三層液晶堆疊結構, 搭配多種不同的驅動方式。然而,採用紅、綠、藍液晶堆 Q 疊結構造成視差現象,於製造時易造成面板結構對位不 易,增加電極設計難度及無法彎曲不便於攜帶,致使製程 複雜及製造成本過高。 因此,採用單層彩色化膽固醇型液晶顯示器的結構及 製程設計可有效避免視差、減少製程及降低成本,尤其是 用於彩色之軟性顯示器等應用領域。美國專利第US 5,825,451 揭露一種單層的彩色膽固醇液晶顯示器,利用 光可分解/聚合之旋光劑與單層膽固醇結構結合,可藉由 UV的照射,破壞或減少單一區域旋光劑的含量,進而達 6 200941073 • 到單層彩色化的效果。然而,此種顯示器易受到外界環境 光的影響,而降低其穩定性。 美國專利第US 6,741,321號揭露一種液晶顯示器裝 置,利用已知單層雙基板組立結構方法,進行分道液晶注 入,易造成不同顏色液晶溢流,進而形成液晶混色,造成 色差現象。 第1A圖係顯示傳統單層彩色膽固醇液晶顯示器裝置 的剖面示意圖。於第1A圖中,傳統單層彩色膽固醇液晶 ® 顯示面板2包括下基板6與上基板12對向設置之間具有一 間隙。一圍籬結構8設置於下基板6與上基板12之間,分 隔成複數個長條形彩色次畫素液晶通道。下基板6上設置 有第一電極4與配向層14,上基板12上設置有第二電極 10與配向層14,其中第一電極4與第二電極10的設置方 向彼此相互垂直。 第1Β圖係顯示第1Α圖所示單層膽固醇液晶顯示器裝 置的的下基板示意圖。於第1Β圖中,圍籬結構8分隔出 ® 複數個(R、G、Β)長條形彩色次晝素液晶通道CR、CG與 CB。直交段16與18設置於液晶通道CG與CB使其一端封 閉。於上下基板組裝後,以封止材將圍籬結構8的第二端 L2封住使液晶通道CG與CB成完全封閉結構,且使液晶通 道CR露出第一端Li做為液晶注入口。接著依序灌注各彩 色液晶於液晶通道Cr、Cg、Cb並封止住。然而’傳統的 單層彩色膽固醇液晶填充前,必需先行封止圍籬結構的第 二端,且於分道液晶注入時,易造成不同顏色液晶溢流, 7 200941073 * 進而形成液晶混色,造成色差現象。再者,習知單層膽固 醇液晶顯示器於液晶層與上、下基板之間,分別設置一預 傾配向層,顯然地,此含配向層的結構需大的驅動電壓, 且顯著地降低對比。 【發明内容】 有鑑於此,本發明提供一種彩色膽固醇液晶顯示器裝 置及製造方法,於基板上設計圍籬結構形成不同長度的液 @ 晶注入道,再利用該圍籬結構是一黏結層或塗佈一層黏著 材料於該圍籬結構表面或塗佈一層圖案化黏著材料於對向 基板上,進行組立。藉由切割、灌注紅、綠、藍的液晶及 封止工序,避免不同顏色液晶溢流及色差現象。由於各次 晝素區域實質上無圖案化黏結層,因此可同時降低驅動電 壓及增加對比。 本發明之實施例提供一種彩色膽固醇液晶顯示器裝 置,包括:一第一基板與一第二基板對向設置之間具有一 ❹ 間隙;一圖案化圍籬結構設置於該第一基板與該第二基板 之間,分隔成複數條長條形彩色次畫素液晶通道:以及複 數種顏色之彩色膽固醇液晶填充於對應該長條形彩色次晝 素液晶通道;其中該圖案化圍籬結構是一黏結層或該圖案 化圍籬結構與該第二基板或第一基板之間具有一對應的圖 案化黏結層,以防止鄰近的次畫素液晶通道溢流。 本發明之實施例另提供一種彩色膽固醇液晶顯示器裝 置的製造方法,包括:提供一第一基板;形成一圖案化圍 籬結構於該第一基板上,其中該圖案化圍籬結構包括複數 200941073 * 條牆狀結構,隔離成具有一第一開口的一第一液晶通道、 封閉的一第二液晶通道及封閉的一第三液晶通道,其中該 第一液晶通道的長度大於該第二液晶通道的長度大於該第 三液晶通道的長度;該圖案化圍籬結構是一黏結層或形成 一黏結層於該圖案化圍籬結構表面或提供一第二基板並形 成一圖案化黏結層於其上;對向組合該第一基板與該第二 基板,使該第二基板與該圖案化圍籬結構緊密結合;自該 第一開口灌注一第一色液晶於該第一液晶通道並以一第一 © 封止材料封止該第一液晶通道;施以一第一切割步驟使該 第二液晶通道露出一第二開口;自該第二開口灌注一第二 色液晶於該第二液晶通道並以一第二封止材料封止該第二 液晶通道;施以一第二切割步驟使該第三液晶通道露出一 第三開口;以及自該第三開口灌注一第三色液晶於該第三 液晶通道並以一第三封止材料封止該第三液晶通道。 本發明之實施例又提供一種彩色膽固醇液晶顯示器裝 置的製造方法,包括:提供一第一基板;形成一圖案化圍 ® 籬結構於該第一基板上,其中該圖案化圍籬結構包括複數 條牆狀結構,隔離成具有一第一開口的一第一液晶通道、 封閉的一第二液晶通道及封閉的一第三液晶通道,其中該 第一液晶通道的長度大於該第二液晶通道的長度大於該第 三液晶通道的長度,以及該圖案化圍籬結構為一具黏結性 的半固態狀態,例如:經過軟烤的光阻;提供一第二基板; 對向組合該第一基板與該第二基板,然後進行完全固化製 程,例如:硬烤或光固化,使具黏結性的該圖案化圍籬結 9 200941073 * 構緊密結合該第二基板;自該第一開口灌注一第一色液晶 於該第一液晶通道並以一第’封止材料封止該第一液晶通 道;施以一第一切割步驟使該第二液晶通道露出一第二開 口;自該第二開口灌注一第二色液晶於該第二液晶通道並 以一第二封止材料封止該第二液晶通道;施以一第二切割 步驟使該第三液晶通道露出一第三開口;以及自該第三開 口灌注一第三色液晶於該第三液晶通道並以一第三封止材 料封止該第三液晶通道。 籲 為使本發明能更明顯易懂,下文特舉實施例,並配合所附圖 式,作詳細說明如下: 【實施方式】 第2A圖係顯示根據本發明之一實施例之單層彩色膽 固醇型液晶顯示器裝置的製造流程圖。請參閱第2A圖, 首先進行第一基板(例如下基板)的製作步驟,包括提供第 一基板(S210),沿第一方向形成第一電極於第一基板上 ❹ (S212)。接著,形成圖案化圍籬結構於第一基板上(S216), 該圖案化圍籬結構包括複數條牆狀結構,各牆狀結構的一 端直交一平直的封止端’以隔離成具有一第一液晶注入口 的一第一液晶通道、封閉的一第二液晶通道及封閉的一第 三液晶通道。 接著,進行第二基板(例如上基板)的製作步驟,包括 提供第二基板(S220),沿第二方向形成第二電極於第二基 板上(S222)。接著,形成一黏結層於該圖案化圍籬結構表 面或开> 成一對應的圖案化黏結層於第二基板上(S23〇〇)。 10 200941073 • 組合第一基板及第二基板(S230),於組合時第一基板 及第二基板對向設置,且之間夾置一間隙。利用該圖案化 黏結層,使該圖案化圍籬結構與該第二基板緊密結合,以 防止後續液晶灌注時,鄰近的次晝素液晶通道溢流。接著, 灌注第一色膽固醇液晶並封止(S240)。施以第一切割以露 出第二長條狀液晶穴(S250),並灌注第二色膽固醇液晶並 封止(S260)。接著,施以第二切割以露出第三長條狀液晶 穴(S270),並灌注第三色膽固醇液晶並封止(S280)。於完成 ® 各色液晶流道填充步驟後,進行後續顯示器面板製程 (S290)。由於各次晝素區域實質上無圖案化黏結層,因此 可同時降低驅動電壓及增加對比。 根據本發明另一實施例,可於步驟S216,直接形成具 黏結性的圖案化圍籬結構於第一基板上。例如,形成未完 全固化的圖案化光阻圍籬結構(例如:經過軟烤的光阻) 於第一基板上,保留其具黏結性的半固態狀態,在經過與 底二基板組合步驟後,才將圖案化光阻圍籬結構完全固化 ® (例如:經過硬烤或光固化的光阻)。如此,可省略原應 形成圖案化的黏結層的步驟,如第2B圖所示。 第3A圖係顯示本發明之一實施例的組合第一與第二 基板步驟的示意圖。請參閱第3A圖,一圖案化圍籬結構 340形成於第一基板360上。圖案化圍籬結構340包括複 數條牆狀結構,隔離成具有一第一液晶注入口的一第一液 晶通道、封閉的一第二液晶通道及封閉的一第三液晶通 道。各液晶通道對應於單層彩色膽固醇液晶顯示器的次晝 200941073 • 素區域,次晝素區域包括晝素電極第一基板上,例如沿第 一方向的第一電極。圖案化圍籬結構可由任何圖案化製程 形成,例如微影製程或網版印刷,其材質可包括一光阻材 料。 第一基板的材質包括一硬質基板或一具撓曲性的軟 質基板。例如,具撓曲性的軟質基板包括一聚碳酸酯(PC) 基板、一聚醚砜樹脂(PES)基板、一聚對苯二曱酸乙二酯 (PET)基板或一聚亞醯胺(PI)基板。第一基板上可包括控制 ⑩ 晝素電極的電路元件,例如薄膜電晶體(TFT)及電容。 接著,提供一第二基板310,其材質包括一硬質基板 或一具撓曲性的軟質基板。於第二基板320上是沿第二方 向的第二電極。第一電極與第二電極彼此實質上相互垂 直。接著,形成一黏結層於該圖案化圍籬結構表面或形成 一圖案化的黏結層330於第二基板310上。圖案化黏結層 330的材質包括一膠狀材料或一固狀材料。例如,固狀材 料包括一光固化材料或一熱固化材料。黏結層330的厚度 ® 小於圖案化圍籬結構340的高度。並且,於各次晝素區域 實質上無圖案化黏結層330,因此可同時降低驅動電壓及 增加對比。 應注意的是,圖案化黏結層可選擇直接塗佈於第一基 板的圖案化圍籬結構上,如3B圖所示。藉由精確地定位 控制與喷墨技術,可使黏結層直接形成於對應的圖案化圍 籬結構上。 接著,對向組合第一基板360與第二基板310,使圖 12 200941073 ’ 案化黏結層330與對應的圖案化圍籬結構340緊密結合, 或使圖案化黏結層330與第二基板310緊密結合,以防止 後續液晶灌注時,鄰近的次晝素液晶通道溢流。 第3C圖係顯示本發明另一實施例的組合第一與第二 基板步驟的示意圖。形成一具黏結性的圖案化圍籬結構 340’於第一基板360上。圖案化圍籬結構340’包括複數條 牆狀結構,隔離成多條液晶通道對應於單層彩色膽固醇液 晶顯示器的次晝素區域。各次晝素區域包括畫素電極第一 ® 基板上,例如沿第一方向的第一電極。圖案化圍籬結構可 由任何圖案化製程形成,例如微影製程或網版印刷,其材 質包括未經硬烤固化的光阻材料。 第一基板的材質包括一硬質基板或一具撓曲性的軟 質基板。再者,第一基板上可包括控制晝素電極的電路元 件,例如薄膜電晶體(TFT)及電容。 接著,提供一第二基板310,其材質包括一硬質基板 或一具撓曲性的軟質基板。於第二基板310上可包括電極 ® 320,例如沿第二方向的第二電極。由於圖案化圍籬結構 340’本身具黏結性,因此可省略製作圖案化黏結層於第二 基板上。並且,於各次畫素區域實質上無圖案化黏結層, 因此可同時降低驅動電壓及增加對比。 接著,對向組合第一基板360與第二基板310,使具 黏結性的圖案化圍籬結構340’與第二基板310緊密結合, 以防止後續液晶灌注時,鄰近的次晝素液晶通道溢流。 第4圖係顯示根據本發明實施例之圍離結構的示意 13 200941073 , 圖。於第4圖中,圖案化圍籬結構420包括複數條牆狀結 構410。各牆狀結構410的^端直交一平直的封止端422 以及一整塊區域440使圖案化圍籬結構隔離成具有一第, 液晶注入口的一第一液晶通道q、封閉的一第二液晶通道 C2及封閉的一第三液晶通道C3。第一液晶通道C!的長度 大於第二液晶通道C2的長度大於第三液晶通道C3的长 度。整塊區域440可使黏結層與圖案化圍籬結構之間的妹 合更緊密,防止後續液晶灌注時,鄰近的次晝素液晶通道 ❷溢流。 第5A圖係顯示根據本發明實施例之基板結合後,沿 第4圖切割線A-A的剖面示意圖。請參閱第5A圖,基板 結合後的結構包括第一基板560與一第二基板510對甸譟 置,其間夾置複數條平行的液晶通道,以容納各顏色的膽 固醇液晶。各液晶通道對應於單層彩色膽固醇液晶顯示舞 的次畫素區域535R、535G、535B。第一基板560上具有 沿第一方向之第一電極550。第二基板510上具有沿第夕 ® 方向之第二電極520,且第一方向與第二方向是相立# 直。於第一基板560與第二基板510之間設置圖案化黏結 層530與其對應的圖案化圍籬結構540,彼此間緊密結舍’ 防止後續液晶灌注時’鄰近的次畫素液晶通道溢流。由於 各次晝素區域實質上無圖案化黏結層,因此可同時降低麟 動電壓及增加對比。 第5B圖係顯示根據本發明另一實施例之基板結舍 後’沿第4圖切割線A-A的剖面示意圖。基板結合後的結 14 200941073 構包括第一基板560與一第二基板510對向設置,其間夾 置複數條平行的液晶通道,以容納各顏色的膽固醇液晶。 各液晶通道對應於單層彩色膽固醇液晶顯示器的彩色次晝 素535R、535G、535B。第—基板560上具有沿第一方向 之第一電極550。第二基板51〇上具有沿第二方向之第二 電極520,且第一方向與第二方向是相互垂直。於第一基 板560與第二基板510之間設置圖案化圍籬結構540,,彼 此間緊密結合,防止後續液晶灌注時,鄰近的次晝素液晶 通道溢流。由於各次晝素區域實質上無圖案化黏結層,因 此可同時降低驅動電壓及增加對比。 灌注步驟的示意圖。請參閱第6A圖 色)膽固醇液晶490R於第—液BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid crystal display device and a method of fabricating the same, and more particularly to a single-layer color cholesteric liquid crystal display device and a method of fabricating the same. [Prior Art] A β liquid crystal display (LCD) has many advantages such as small size, light weight, low power consumption, and the like. Therefore, LCDs have been widely used in electronic products such as hand-held computers and mobile phones. That is, liquid crystal display technology is continuing to develop in a light, thin, and easy to carry field. Conventional reflective color-coded liquid crystal displays with memory effects have been widely used in e-books, electronic paper or other display fields. The structure and manufacturing method of the conventional color cholesteric liquid crystal display uses a three-layer liquid crystal stack structure of red (R), green (G), and blue (B), and is matched with various driving methods. However, the parallax phenomenon caused by the red, green, and blue liquid crystal stacks of Q stacks is not easy to cause the alignment of the panel structure during manufacturing, and the difficulty in designing the electrodes and the inability to bend are difficult to carry, resulting in complicated process and high manufacturing cost. Therefore, the structure and process design of a single-layer color cholesteric liquid crystal display can effectively avoid parallax, reduce process and reduce cost, especially for applications such as color soft displays. US Patent No. 5,825,451 discloses a single-layer color cholesteric liquid crystal display that utilizes a photodecomposable/polymeric optically active agent in combination with a single layer of cholesterol structure to destroy or reduce the content of a single region of optically active agent by UV irradiation. 6 200941073 • The effect of colorization to a single layer. However, such displays are susceptible to ambient light and reduce their stability. U.S. Patent No. 6,741,321 discloses a liquid crystal display device which utilizes a known single-layer dual-substrate assembly structure method to perform split-channel liquid crystal injection, which tends to cause overflow of liquid crystals of different colors, thereby forming liquid crystal mixed colors, resulting in chromatic aberration. Fig. 1A is a schematic cross-sectional view showing a conventional single-layer color cholesteric liquid crystal display device. In Fig. 1A, the conventional single-layer color cholesteric liquid crystal display panel 2 includes a gap between the lower substrate 6 and the upper substrate 12 oppositely disposed. A fence structure 8 is disposed between the lower substrate 6 and the upper substrate 12, and is divided into a plurality of elongated color sub-pixel liquid crystal channels. The lower substrate 6 is provided with a first electrode 4 and an alignment layer 14, and the upper substrate 12 is provided with a second electrode 10 and an alignment layer 14, wherein the arrangement directions of the first electrode 4 and the second electrode 10 are perpendicular to each other. Fig. 1 is a schematic view showing the lower substrate of the single-layered cholesteric liquid crystal display device shown in Fig. 1. In the first diagram, the fence structure 8 separates a plurality of (R, G, Β) strip-shaped color sub-halogen liquid crystal channels CR, CG and CB. The orthogonal sections 16 and 18 are disposed in the liquid crystal channels CG and CB to be closed at one end. After the upper and lower substrates are assembled, the second end L2 of the fence structure 8 is sealed with a sealing material to completely close the liquid crystal channels CG and CB, and the liquid crystal channel CR is exposed to the first end Li as a liquid crystal injection port. Then, the color liquid crystals are sequentially poured into the liquid crystal channels Cr, Cg, Cb and sealed. However, before the traditional single-layer color cholesteric liquid crystal is filled, it is necessary to first seal the second end of the fence structure, and when the liquid crystal is injected, it is easy to cause different color liquid crystal overflow, 7 200941073 * and then form a liquid crystal color mixture, resulting in chromatic aberration phenomenon. Furthermore, a conventional single-layer cholesteric liquid crystal display is provided with a pretilt alignment layer between the liquid crystal layer and the upper and lower substrates. Obviously, the structure containing the alignment layer requires a large driving voltage and significantly reduces the contrast. SUMMARY OF THE INVENTION In view of the above, the present invention provides a color cholesteric liquid crystal display device and a manufacturing method thereof, wherein a fence structure is formed on a substrate to form a liquid @ crystal injection channel of different length, and the fence structure is a bonding layer or a coating. A layer of adhesive material is applied to the surface of the fence structure or a layer of patterned adhesive material is applied to the opposite substrate for assembly. By cutting and injecting red, green, and blue liquid crystals and sealing processes, liquid crystal overflow and chromatic aberration of different colors are avoided. Since each of the halogen regions has substantially no patterned bonding layer, the driving voltage can be simultaneously reduced and the contrast can be increased. An embodiment of the present invention provides a color cholesteric liquid crystal display device comprising: a first substrate and a second substrate having a gap therebetween; a patterned fence structure disposed on the first substrate and the second Between the substrates, a plurality of strip-shaped color sub-pixel liquid crystal channels are separated: and a plurality of colors of colored cholesteric liquid crystals are filled in the corresponding color-shaped color sub-halogen liquid crystal channels; wherein the patterned fence structure is a bond The layer or the patterned fence structure has a corresponding patterned bonding layer between the second substrate or the first substrate to prevent overflow of adjacent sub-pixel liquid crystal channels. The embodiment of the present invention further provides a method for manufacturing a color cholesteric liquid crystal display device, comprising: providing a first substrate; forming a patterned fence structure on the first substrate, wherein the patterned fence structure comprises a plurality of 200941073 * a wall-shaped structure is separated into a first liquid crystal channel having a first opening, a closed second liquid crystal channel, and a closed third liquid crystal channel, wherein the length of the first liquid crystal channel is greater than the length of the second liquid crystal channel The length of the pattern is greater than the length of the third liquid crystal channel; the patterned fence structure is a bonding layer or a bonding layer is formed on the surface of the patterned fence structure or a second substrate is formed and a patterned bonding layer is formed thereon; Combining the first substrate and the second substrate oppositely, the second substrate is tightly coupled to the patterned fence structure; a first color liquid crystal is poured into the first liquid crystal channel from the first opening and is first The sealing material seals the first liquid crystal channel; applying a first cutting step to expose the second liquid crystal channel to a second opening; and injecting a second color from the second opening Liquid crystal is in the second liquid crystal channel and the second liquid crystal channel is sealed by a second sealing material; a second cutting step is performed to expose the third liquid crystal channel to a third opening; and a third opening is infused The third color liquid crystal is in the third liquid crystal channel and the third liquid crystal channel is sealed by a third sealing material. The embodiment of the present invention further provides a method for fabricating a color cholesteric liquid crystal display device, comprising: providing a first substrate; forming a patterned surrounding structure on the first substrate, wherein the patterned fence structure comprises a plurality of The wall-shaped structure is separated into a first liquid crystal channel having a first opening, a closed second liquid crystal channel, and a closed third liquid crystal channel, wherein the length of the first liquid crystal channel is greater than the length of the second liquid crystal channel a length greater than the length of the third liquid crystal channel, and the patterned fence structure is a semi-solid state of bonding, for example, a soft baked photoresist; providing a second substrate; and combining the first substrate and the The second substrate is then subjected to a complete curing process, such as hard baking or photocuring, to make the patterned fence of the bond 9 200941073 * tightly bonded to the second substrate; a first color is poured from the first opening Liquid crystal is in the first liquid crystal channel and seals the first liquid crystal channel with a first sealing material; applying a first cutting step to expose the second liquid crystal channel to a second Porting a second color liquid crystal from the second opening to the second liquid crystal channel and sealing the second liquid crystal channel with a second sealing material; applying a second cutting step to expose the third liquid crystal channel a third opening; and injecting a third color liquid crystal from the third opening into the third liquid crystal channel and sealing the third liquid crystal channel with a third sealing material. DETAILED DESCRIPTION OF THE INVENTION In order to make the present invention more apparent and easy to understand, the following detailed description of the embodiments and the accompanying drawings will be described in detail as follows: [Embodiment] FIG. 2A shows a single layer of color cholesterol according to an embodiment of the present invention. Flow chart for manufacturing a liquid crystal display device. Referring to Fig. 2A, a first step of fabricating a first substrate (e.g., a lower substrate) is performed, including providing a first substrate (S210), and forming a first electrode on the first substrate in a first direction (S212). Next, forming a patterned fence structure on the first substrate (S216), the patterned fence structure includes a plurality of wall structures, one end of each wall structure is orthogonal to a flat sealing end' to be isolated to have a a first liquid crystal channel of the first liquid crystal injection port, a closed second liquid crystal channel, and a closed third liquid crystal channel. Next, a fabrication step of the second substrate (e.g., the upper substrate) is performed, including providing the second substrate (S220), and forming the second electrode on the second substrate in the second direction (S222). Then, a bonding layer is formed on the surface of the patterned fence structure or is formed into a corresponding patterned bonding layer on the second substrate (S23〇〇). 10 200941073 • The first substrate and the second substrate are combined (S230), and the first substrate and the second substrate are opposed to each other when combined, and a gap is interposed therebetween. The patterned barrier layer is used to tightly bond the patterned fence structure to the second substrate to prevent overflow of the adjacent sub-halogen liquid crystal channel during subsequent liquid crystal infusion. Next, the first color cholesteric liquid crystal is poured and sealed (S240). The first slit is applied to expose the second elongated liquid crystal cell (S250), and the second color cholesteric liquid crystal is poured and sealed (S260). Next, a second cut is applied to expose the third elongated liquid crystal cell (S270), and the third color cholesteric liquid crystal is poured and sealed (S280). After the completion of the ® color liquid crystal channel filling step, the subsequent display panel process (S290) is performed. Since each of the halogen regions has substantially no patterned bonding layer, the driving voltage can be simultaneously reduced and the contrast can be increased. According to another embodiment of the present invention, in step S216, a patterned patterned fence structure can be directly formed on the first substrate. For example, forming an incompletely cured patterned photoresist fence structure (eg, a soft baked photoresist) on the first substrate, retaining its adhesive semi-solid state, after passing through the combination with the bottom two substrates, The patterned photoresist fence is fully cured (for example: hard-baked or light-cured photoresist). Thus, the step of forming the patterned bonding layer should be omitted, as shown in Fig. 2B. Fig. 3A is a schematic view showing the steps of combining the first and second substrates in an embodiment of the present invention. Referring to FIG. 3A, a patterned fence structure 340 is formed on the first substrate 360. The patterned fence structure 340 includes a plurality of wall structures separated into a first liquid crystal channel having a first liquid crystal injection port, a closed second liquid crystal channel, and a closed third liquid crystal channel. Each liquid crystal channel corresponds to a single-layer color cholesteric liquid crystal display. 200941073 • The prime region, the secondary halogen region includes a first substrate of a halogen electrode, such as a first electrode in a first direction. The patterned fence structure can be formed by any patterning process, such as lithography or screen printing, and the material can include a photoresist. The material of the first substrate comprises a rigid substrate or a flexible flexible substrate. For example, the flexible flexible substrate comprises a polycarbonate (PC) substrate, a polyethersulfone resin (PES) substrate, a polyethylene terephthalate (PET) substrate or a polyimide ( PI) substrate. The first substrate may include circuit elements for controlling the 10 pixel electrodes, such as a thin film transistor (TFT) and a capacitor. Next, a second substrate 310 is provided, which is made of a rigid substrate or a flexible flexible substrate. On the second substrate 320 is a second electrode in the second direction. The first electrode and the second electrode are substantially perpendicular to each other. Then, a bonding layer is formed on the surface of the patterned fence structure or a patterned bonding layer 330 is formed on the second substrate 310. The material of the patterned adhesive layer 330 includes a gelatinous material or a solid material. For example, the solid material comprises a photocurable material or a heat curable material. The thickness of the bonding layer 330 is less than the height of the patterned fence structure 340. Further, since the bonding layer 330 is substantially not patterned in each of the halogen regions, the driving voltage can be simultaneously lowered and the contrast can be increased. It should be noted that the patterned bonding layer may optionally be applied directly to the patterned fence structure of the first substrate, as shown in Figure 3B. By precisely positioning the control and ink jet technology, the bonding layer can be formed directly on the corresponding patterned fence structure. Then, the first substrate 360 and the second substrate 310 are oppositely combined, so that the patterned bonding layer 330 of FIG. 12 and the corresponding patterned fence structure 340 are tightly bonded, or the patterned bonding layer 330 is tightly coupled to the second substrate 310. The combination is to prevent overflow of the adjacent sub-halogen liquid crystal channel when the subsequent liquid crystal is poured. Fig. 3C is a schematic view showing the steps of combining the first and second substrates in another embodiment of the present invention. A cemented patterned fence structure 340' is formed on the first substrate 360. The patterned fence structure 340' includes a plurality of wall structures separated into a plurality of liquid crystal channels corresponding to the secondary halogen regions of the single layer color cholesterol liquid crystal display. Each of the halogen regions includes a first electrode of the pixel electrode, such as a first electrode along the first direction. The patterned fence structure can be formed by any patterning process, such as lithography or screen printing, and the material includes a photoresist material that has not been cured by hard bake. The material of the first substrate comprises a rigid substrate or a flexible flexible substrate. Furthermore, the first substrate may include circuit elements for controlling the pixel electrodes, such as thin film transistors (TFTs) and capacitors. Next, a second substrate 310 is provided, which is made of a rigid substrate or a flexible flexible substrate. An electrode ® 320 may be included on the second substrate 310, such as a second electrode in a second direction. Since the patterned fence structure 340' is inherently viscous, the patterned bonding layer can be omitted from the second substrate. Moreover, there is substantially no patterned bonding layer in each pixel region, so that the driving voltage can be simultaneously reduced and the contrast can be increased. Then, the first substrate 360 and the second substrate 310 are oppositely combined to make the adhesive patterned fence structure 340' and the second substrate 310 tightly combined to prevent the adjacent sub-halogen liquid crystal channel from overflowing during subsequent liquid crystal infusion. flow. Figure 4 is a schematic representation of a surrounding structure according to an embodiment of the invention 13 200941073, Fig. In FIG. 4, the patterned fence structure 420 includes a plurality of wall structures 410. The end of each wall structure 410 is orthogonal to a flat sealing end 422 and a monolithic region 440 isolating the patterned fence structure into a first liquid crystal channel q having a liquid crystal injection port, and a closed first Two liquid crystal channels C2 and a closed third liquid crystal channel C3. The length of the first liquid crystal channel C! is greater than the length of the second liquid crystal channel C2 is greater than the length of the third liquid crystal channel C3. The monolithic region 440 allows the bonding between the bonding layer and the patterned fence structure to be more tight, preventing adjacent sub-halogen liquid crystal channels from overflowing during subsequent liquid crystal infusion. Fig. 5A is a schematic cross-sectional view showing the cutting line A-A along the fourth embodiment after the substrate is bonded according to the embodiment of the present invention. Referring to FIG. 5A, the substrate-bonded structure includes a first substrate 560 and a second substrate 510, and a plurality of parallel liquid crystal channels are interposed therebetween to accommodate cholesteric liquid crystals of respective colors. Each of the liquid crystal channels corresponds to a sub-pixel area 535R, 535G, 535B of a single-layer color cholesteric liquid crystal display dance. The first substrate 560 has a first electrode 550 along the first direction. The second substrate 510 has a second electrode 520 along the ‧th direction, and the first direction is opposite to the second direction. A patterned bonding layer 530 and a corresponding patterned fence structure 540 are disposed between the first substrate 560 and the second substrate 510, and are closely tied to each other to prevent overflow of adjacent sub-pixel liquid crystal channels during subsequent liquid crystal infusion. Since each of the halogen regions has substantially no patterned bonding layer, the nucleus voltage can be simultaneously reduced and the contrast can be increased. Fig. 5B is a cross-sectional view showing the cutting line A-A along the fourth drawing after the substrate is tied according to another embodiment of the present invention. The substrate-bonded junction 14 200941073 includes a first substrate 560 disposed opposite to a second substrate 510 with a plurality of parallel liquid crystal channels interposed therebetween to accommodate cholesteric liquid crystals of respective colors. Each of the liquid crystal channels corresponds to a color sub-single 535R, 535G, 535B of a single-layer color cholesteric liquid crystal display. The first substrate 560 has a first electrode 550 along the first direction. The second substrate 51 has a second electrode 520 in the second direction, and the first direction and the second direction are perpendicular to each other. A patterned fence structure 540 is disposed between the first substrate 560 and the second substrate 510, and is tightly coupled to each other to prevent overflow of the adjacent sub-halogen liquid crystal channel during subsequent liquid crystal infusion. Since each of the halogen regions has substantially no patterned bonding layer, the driving voltage can be simultaneously reduced and the contrast can be increased. Schematic diagram of the infusion step. Please refer to Figure 6A) Cholesterol LCD 490R in the first liquid
第6A至6C圖係顯示根據本發明實施例之各彩色液晶 3第6A圖,灌注第一色(例如紅 -液晶通道中,並以第一封止材 I晶層包括一紅色染料及一含旋 封正材料480a包括一光固化材 施以第—切割步驟(例如沿切割 I晶通道C:2。第一切割步驟包括 請务閲第6B圖,灌、、主 490G於第二液晶通道中,第二色(例如綠色)膽固醇液晶 綠色膽固醇液晶層包括一 ^以第—封止材料480b封止。 列液晶。第二封止材料48(^杂料及—含旋光劑之扭轉向 材料。接著,施以第二切宅i括光固化材料或一熱固化 第三長條狀液晶通道。°]步驟(例如沿切割線C-C),露出 3°第二切割步驟包括一輪刀切割步 15 200941073 ' 驟或一雷射切割步驟。 請參閱第6C圖,灌注第三色(例如藍色)膽固醇液晶 490B於第三液晶通道中,並以第三封止材料480c封止。 藍色膽固醇液晶層包括一藍色染料及一含旋光劑之扭轉向 列液晶。第三封止材料480c包括一光固化材料或一熱固化 材料。於完成各色液晶流道填充步驟後,進行後續顯示器 面板製程。 本發明實施例提供一種彩色液晶顯示器之結構與製 ❹ 作方法,其特徵及優點在於設計不同長度的液晶注入道及 電極,再利用圖案化圍籬結構是一黏結層或塗佈一層黏著 材料於該圖案化圍籬結構表面或塗佈一層對應的圖案化 黏著材料於另一具有電極的基板上,並進行對位組立。該 第一基板或第二基板與圖案化圍籬結構彼此間緊密結合, 防止後續液晶灌注時,鄰近的次晝素液晶通道溢流。 表一6A to 6C are diagrams showing a sixth color diagram of each color liquid crystal 3 according to an embodiment of the present invention, infused with a first color (for example, in a red-liquid crystal channel, and the first sealing material I crystal layer includes a red dye and a The spin-sealing material 480a includes a photocuring material to be subjected to a first-cutting step (for example, along the cutting I crystal channel C: 2. The first cutting step includes consulting the sixth panel, the filling, and the main 490G in the second liquid crystal channel. The second color (for example, green) cholesterol liquid crystal green cholesteric liquid crystal layer comprises a first sealing material 480b. The column liquid crystal. The second sealing material 48 (the miscellaneous material and the torsion material containing the optically active agent. Applying a second cut house i-light curing material or a heat curing third long strip liquid crystal channel. The step (for example, along the cutting line CC) exposes 3°. The second cutting step includes a round knife cutting step 15 200941073 ' Step or a laser cutting step. Referring to Figure 6C, a third color (e.g., blue) cholesteric liquid crystal 490B is infused into the third liquid crystal channel and sealed with a third sealing material 480c. The blue cholesteric liquid crystal layer includes a blue dye and an optically active agent The third sealing material 480c comprises a photocurable material or a heat curing material. After the liquid crystal channel filling step of each color is completed, the subsequent display panel process is performed. The embodiment of the invention provides a structure and system of the color liquid crystal display. The method and the advantages thereof are to design liquid crystal injection channels and electrodes of different lengths, and then use the patterned fence structure to be a bonding layer or apply a layer of adhesive material on the surface of the patterned fence structure or apply a layer corresponding to Patterning the adhesive material on another substrate having electrodes and performing alignment assembly. The first substrate or the second substrate and the patterned fence structure are tightly coupled to each other to prevent adjacent sub-halogen liquid crystal during subsequent liquid crystal infusion. Channel overflow. Table 1
Green Ch-LCD Cell gap 6.3 μιη Vl(100 Hz) 〜10V 〜7V* V2(100 Hz) 〜60V 〜46V* 對比 〜8 〜12* 16 200941073 ' 黏著層膜厚〜0.8 μιη,*無黏著層結構(V2: 60V+46V, 對比:8 + 12)。 由於各次晝素區域實質上無圖案化黏結層,因此可同 時降低驅動電壓及增加對比。因此,膽固醇液晶顯示器的 顯示驅動電壓可大幅下降約15V,並且使顯示對比自8提 高至12,如表一所示。更有甚者,由於同時簡化膽固醇液 晶顯示器結構與製程,故增加其應用在可攜式產品的使用 時間、降低驅動系統成本且提高影像品質。 ❹ 本發明雖以較佳實施例揭露如上,然其並非用以限定 本發明的範圍,任何所屬技術領域中具有通常知識者,在 不脫離本發明之精神和範圍内,當可做些許的更動與潤 飾,因此本發明之保護範圍當視後附之申請專利範圍所界 定者為準。 200941073 【圖式簡單說明】 第1A圖係顯示傳統單層彩色膽固醇液晶顯示器裝置 的剖面示意圖; 第1B圖係顯示第1A圖所示單層膽固醇液晶顯示器裝 置的的下基板示意圖; 第2A圖係顯示根據本發明之一實施例之單層彩色膽 固醇型液晶顯示器裝置的製造流程圖; @ 第2B圖係顯示根據本發明另一實施例之單層彩色膽 固醇型液晶顯示器裝置的製造流程圖; 第3A-3B圖係顯示本發明之一實施例的組合第一與 弟·一基板步驟的不意圖, 第3C圖係顯示本發明另一實施例的組合第一與第二 基板步驟的示意圖; 第4圖係顯示根據本發明實施例之圍離結構的示意 圖; ❹ 第5A圖係顯示根據本發明實施例之基板結合後,沿 弟4圖切割線A-A的剖面不意圖, 第5B圖係顯示根據本發明另一實施例之基板結合 後,沿第4圖切割線A-A的剖面示意圖;以及 第6A至6C圖係顯示根據本發明實施例之各彩色液晶 灌注步驟的示意圖。 【主要元件符號說明】 18 200941073 習知部分(第ία〜1B圈) 2〜傳統單層彩色膽固醇液晶顯示面板; 4~第一電極; 6〜下基板; 8〜圍籬結構; 10〜第二電極; 12〜上基板; 14〜配向層; 瘳 16、18~直交段; CR、CG與CB〜長條形彩色次晝素液晶通道; L广第一端; L2〜第二端。 本案部分(第24C圈) S210-S290〜單層彩色膽固醇型液晶顯示器的製程步 驟; ❹ 310〜第二基板; 320〜第二電極; 330〜圖案化黏結層; 340〜圖案化圍籬結構; 340’〜具黏結性的圖案化圍籬結構; 350〜第一電極; 360〜第一基板; 420〜圍籬結構; 19 200941073 ' 410〜牆狀結構; 422〜平直的封止端; 440〜圍籬結構的整塊區域;Green Ch-LCD Cell gap 6.3 μιη Vl (100 Hz) ~10V ~7V* V2 (100 Hz) ~60V ~46V* Contrast ~8 ~12* 16 200941073 ' Adhesive film thickness ~0.8 μιη, *No adhesive layer structure (V2: 60V+46V, contrast: 8 + 12). Since each of the halogen regions has substantially no patterned bonding layer, the driving voltage can be lowered and the contrast can be increased at the same time. Therefore, the display driving voltage of the cholesteric liquid crystal display can be drastically reduced by about 15 V, and the display contrast can be increased from 8 to 12, as shown in Table 1. What's more, since the structure and process of the cholesterol liquid crystal display are simultaneously simplified, the application time of the portable product is increased, the cost of the driving system is lowered, and the image quality is improved. 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 And the scope of the present invention is defined by the scope of the appended claims. 200941073 [Simple description of the drawing] Fig. 1A is a schematic cross-sectional view showing a conventional single-layer color cholesteric liquid crystal display device; Fig. 1B is a schematic view showing a lower substrate of the single-layer cholesteric liquid crystal display device shown in Fig. 1A; A flow chart showing the manufacture of a single-layer color cholesteric liquid crystal display device according to an embodiment of the present invention; @2B is a flow chart showing the manufacture of a single-layer color cholesteric liquid crystal display device according to another embodiment of the present invention; 3A-3B is a schematic diagram showing the steps of combining the first and second substrates in one embodiment of the present invention, and FIG. 3C is a schematic view showing the steps of combining the first and second substrates in another embodiment of the present invention; 4 is a schematic view showing a structure according to an embodiment of the present invention; ❹ FIG. 5A is a cross-sectional view showing a section AA of the cutting line AA according to the embodiment of the present invention, and FIG. 5B is a view showing A cross-sectional view along the cutting line AA of FIG. 4 after the substrate of another embodiment of the present invention is bonded; and FIGS. 6A to 6C are diagrams showing an embodiment according to the present invention. The step of filling each a schematic view color LCD. [Main component symbol description] 18 200941073 Conventional part (第ία~1B circle) 2~ Traditional single-layer color cholesterol liquid crystal display panel; 4~first electrode; 6~lower substrate; 8~fence structure; 10~second Electrode; 12~ upper substrate; 14~ alignment layer; 瘳16, 18~ orthogonal section; CR, CG and CB~ strip-shaped color secondary ruthenium liquid crystal channel; L wide first end; L2~ second end. Part of the case (24C circle) S210-S290~ single layer color cholesteric liquid crystal display process steps; ❹ 310~ second substrate; 320~ second electrode; 330~ patterned bonding layer; 340~ patterned fence structure; 340'~bonded patterned fence structure; 350~first electrode; 360~first substrate; 420~fence structure; 19 200941073 '410~wall structure; 422~straight sealing end; 440 ~ the entire area of the fence structure;
Ci、C2、C3〜液晶通道, 510〜第二基板; 520〜第二電極; 530〜圖案化黏結層; 540〜圖案化圍籬結構; Φ 54〇’〜具黏結性的圖案化圍籬結構; 535R、535G、535B〜彩色次晝素; 550〜第一電極; 560〜第一基板; 490R〜第一色膽固醇液晶; 490G〜第二色膽固醇液晶; 490B〜第三色膽固醇液晶; 480a〜第一封止材料; © 480b〜第二封止材料; 480c〜第三封止材料。 20Ci, C2, C3~ liquid crystal channel, 510~second substrate; 520~second electrode; 530~patterned bonding layer; 540~patterned fence structure; Φ 54〇'~bonded patterned fence structure ; 535R, 535G, 535B ~ color secondary halogen; 550 ~ first electrode; 560 ~ first substrate; 490R ~ first color cholesterol liquid crystal; 490G ~ second color cholesterol liquid crystal; 490B ~ third color cholesterol liquid crystal; First stop material; © 480b ~ second sealing material; 480c ~ third sealing material. 20