TW200930297A - Fungicidal mixtures - Google Patents

Abstract

The present invention relates to fungicidal mixtures comprising, as active components, (1) azolylmethyloxiranes of the general formula I in which A is phenyl which is substituted by two F, B is unsubstituted pyridyl, thienyl, thiazolyl, oxazolyl or furyl or is phenyl which is substituted by one to three of the following substituents: halogen, NO2, amino, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, Cl-C4-haloalkoxy, C1-C4-alkylamino, Cl-C4-dialkylamino, thio or C1-C4-alkylthio, with the proviso that B is not o-methylphenyl if A is 2, 4-difluorophenyl, and the plant-compatible acid addition salts or metal salts thereof, and (2) a fungicidal compound II as described in the application, to the use of the fungicidal mixtures for controlling phytopathogenic fungi and to compositions comprising them.

Description

200930297 IX. Description of the invention: [Technical field to which the invention pertains] The fungicidal mixture contains a synergistically effective amount of the following components as active components: 1) oxazolylhydrazones of the formula I 0, N /\

f, N - CH2 - C - CH I I (i)

A B

Wherein A is a phenyl group substituted by 2 F, and B is an unsubstituted pyridyl group, a thienyl group, a thiazolyl group, an oxazolyl group or a furyl group or a phenyl group substituted with 1 to 3 or less substituents: N02, amine group, (VC4 alkyl, CVCU alkoxy, C4 dentate, C1-C4 dentate oxy, C1-C4 alkylamino, Cl_c4 dialkylamino, thio or hydrazine, - ^alkylthio, wherein the restriction is that if A is 2,4-difluorophenyl, then B is not o-methylphenyl,

And an acid addition salt or a metal salt thereof, and 2) a fungicidal compound II selected from the group consisting of: strobiiurin selected from the group consisting of: (azoxystrobin), dimethomycin (dimoXyStrobin), enestroburin, fluoxastrobin, kresoxim-methyl, rneth〇minostrobin, oriprozamide (orysastrobin),. Aqueousoxin (pic〇XyStr〇bin), Baikemin 136128.doc 200930297 (pyraclostrobin), pyribencarb, trifloxystrobin, 2-(2-(6-(3-chloro-2) -Methylphenoxy)-5-fluoropyrimidin-4-yloxy)phenyl)-2-methoxyimino-N-methylacetamide, 2-(o ((2,5·) —methyl-based oxyalkylidene)phenyl)_3 -decyloxyindole ratio β-sodium methacrylate, 3-methoxy-2-(2-(Ν-(4-methoxybenzene) Cyclopropane carboxy quinone iminyl thio sulfhydryl) phenyl) decyl acrylate, 2-(2-(3-(2,6-di-phenyl)-1-methylallylamine Benzyloxymethyl)phenyl)-2-methoxyimino-N-methylacetamide; 2.2) Carboxamide which is selected from the group consisting of: - carboxanilide : benaxyl, benalaxyl-M, benodanil, bixafen, boscalid, carboxin, furfurylamine Fenfuram), fenhexamid, flutolanil, furametpyr, isopyrazam, isotianil, carat (kiralaxyl), mepronil, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl, Oxycarboxin, penthiopyrad, tecloftalam, thifluzamide, tiadinil, 2-amino-4-methylindole -5-anilinoguanidine, 2-gas_N-(1,1,3-tridecylindan-4-yl)nicotinamide, N-(3',4'-dichloro-5- Fluorbiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-decylamine, N-[2-(l,3-dimercaptobutyl)phenyl ]-5·Fluorate 1,3-dimercapto-1H-pyrazole-4-formamide, N-(4,-gas-3,,5-difluorobiphenyl-136128.doc -8 * 200930297 2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(4'-chloro-3',5-difluorobiphenyl-2-yl) -3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3',4'-di-5-ethanebiphenyl-2-yl)-3-tri Gas methyl-1-methyl_111-pyrazole-4-carboxamide,;^-(3|,5-difluoro-4'-methylbiphenyl-2-yl)-3-difluoromethyl -1-methyl-1H-pyrazole-4-carboxamide, Ν-(3·,5-two Fluoro-4·-mercaptobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1Η-pyrazole-4-carboxamide, Ν-(2-dicycloprop-2-yl) Phenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-cartoamine, N-(cis-2-bicycloprop-2-yl)-3-dimethoxy -1 -methyl-1H-pyrazole-4-carboxamide, N-(trans-2-dicyclopropan-2-ylphenyl)-3-difluoromethyl-1-indolyl-1H -pyrazole-4-carboxamide, N-(2'-fluoro-4'-chloro-5'-mercaptobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- Pyrazole-4-carboxamide, Ν-ρ·〆^-trifluorobiphenyl-2-yl)-1-mercapto-3-trifluoromethyl-1H-pyrazole-4-carboxamide, hydrazine -(3·,4',5·-trifluorobiphenyl-2-yl)-1-mercapto-3-difluoroindolyl-1H-pyrazole-4-carboxamide, N-(2, 4 , 5'-Trifluorobiphenyl-2-yl)-1-indolyl-3-difluoroindolyl-1H-pyrazole-4-carboxamide, Ν-(3',4',5·-three Fluorobiphenyl-2-yl)-3-fluorofluoroindol-1-yl-1Η-pyrazole-4-decylamine, Ν-(4'-(trifluoromethylthio)biphenyl-2 -yl)-3 -di-lactylmethyl-1 -methyl-1Η - ° ratio - 0 - 4 - tyranamine, Ν-(4^(trimethylsulfonylthio)biphenyl-2-yl)- 1-methyl-3-tris-methyl-1H-pyrazole-4-decylamine, N'-(4-(4-chloro-3-trifluoro) Phenyloxy)-2,5-diamidinophenyl)-N-ethyl-N-mercaptomethylhydrazine, N'-(4-(4-fluoro-3-trifluorodecylphenoxy) -2,5-diamidinophenyl)-N-ethyl-N-indenyl hydrazine, hydrazine--(2-mercapto-5-trifluoromethyl-4-(3-trimethyldecyl) Propyloxy)phenyl)-N-ethyl-N-methylformamidine and N'-(5-difluorodecyl-2-mercapto-4-(3-tridecylfluorenylpropyloxy) Phenyl)-N-ethyl-N-methylformamidine, N-136128.doc -9- 200930297 (2·,4'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 -mercapto-1H-pyrazole-4-carboxamide, Ν-(2',4'-di-biphenyl-2-yl)_3_difluoromethylmethyl_m_carbazole-4-carboxamidine Amine, N-(2,5,-difluorobiphenyl-2-yl)-3-difluoroindol-1-yl-1H-pyrazole-4-carboxamide, n-(2,, 5'-di-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole_4_formamidine, N_(3',5,-difluorobiphenyl-2 -yl)-3 -a-1 gas fluorenyl-1-methyl-1H-0 than 0 ke-4-cartoamine, N-(3',5'-di-biphenyl-2-yl)-3 -difluoromethyl-j-methyl_1H_pyrazole_4_decylamine, N_(3'-fluorobiphenyl-2-yl)-3-difluorodecyl-1-methyl-1H- Pyrazole-4-carbamide, Ν-(3·-chlorobiphenyl-2-yl)-3-difluoro -1-methyl-1H-pyrazole-4-carboxamide, Ν-(2·-fluorobiphenyl-2-yl)_3_difluoromethyl-1-methyl-1H-" -4-carboxamide, Ν-(2·-biphenyl-2-yl)-3-difluoromethyl-1-indolyl-111-pyrazole-4-carboxamide, >^[2 -(1,1,2,3,3,3-hexafluoropropoxy)phenyl]-3-difluoroindol-1-yl-1H-pyrazole-4-nonylamine, N-[ 2-(1,1,2,2·tetrafluoroethoxy)phenyl]_3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, Ν-(2·(1 ,3,3-trimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1Η-pyrazole-4-formamide, N-[l,2,3,4-tetra Hydrogen-9-(1-methylethyl)-1,4-methylnaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide - carboxylic acid morpholide: dimethomorph, flumorph; - benzamide: flumetover, flu " fluopicolide Fluoryram, zoxamide, N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-carboxamido-2- Hydroxybenzamide; 136128.doc -10- 200930297 - Other slow-acting amines: carpropamid, diclosan ( Diclocymet), mandipropamid, oxytetracyclin, silthiofam, N-(6-methoxyl-pyridin-3-yl)cyclopropanecarboxamide; 2.3) Select the azoles of the following groups:

- Three-degree sitting: azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole ), Dakli-M, fluorocyclic 'epoxiconazole, fenbucon', fenbuconazole, fiUqUinc〇nazole, fusilazole, flurifaol , hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, oxpoconazole, multi-effect (paclobutrazole), penconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, and trimethoate Triadimefon), triadimenol, cyclobacteria, triticonazole, uniconazole, 1-(4-chlorophenyl)-2-([1,2,4]three-zero -1- Base)-cycloheptanol; - 啼 :: cyazofamid, imazalil, sulfuric acid Column, pefurazoate, prochloraz, triflumizole; I36128.doc 200930297 _benzimidazole: benomyl (benomy1), fenfenex (carbendazim), wheat earling (fuberidazole) ), thiabendaz〇le; ethaboxam, etridiazole, hymeXaz〇le, ^(4·gasphenyl)·b (propyne) · 2 - oxy) 3 - (4-(3,4-dimethoxyphenyl)isoxazole _5 yl) propan-2-one, 2-(4-chlorophenyl)-N-[4- (3,4-dimethoxyphenyl)isoxazol-5-yl]_2-propan-2-alkynylacetamide; 2.4) a nitrogen-containing heterocyclic group selected from the group consisting of the following Compound: -0 pyridine: fluazinam, pyrifenox, 3-[5-(4-phenylphenyl)-2,3-diindenyl thiophene-3-yl] More than bite, 3-[5-(4-methylphenyl)-2,3-dimercapto- " vomiting bite _3_ base]. Than 0, 2, 3, 5, 6 - 4 gas - 4 A burning item, brewing base 0 bite, 3, 4, 5_ three gas ratio "definite-2,6-dicarbonitrile, N- (1-(5-Bromo-3-azinopyridin-2-yl)ethyl)-2,4-di-nicotinamide, N-((5-bromo-3-chloro- 0-bit-2-yl) ) methyl)-2,4-dichloro in the amine; - η determinate: read bupirimate, cyprodinil, diflumetorim, fenremore ( Fenarimol), ferimzone, mepanipyrim, nitrapyrin, nuarimol, pyrimethanil; -pyrazine: triforins; 0 比洛: fludioxonil, fenpiclonil; - lin: adimorph, dodemorph, acetic acid carbendazim, rust lin (fenPr〇Pim〇rph ), tridemorph; - piperidine: fenpropidin; - bismuthimide: fluoroimide, 136128.doc -12- 200930297 (iprodione), Procymidone, vinclozolin; - non-aromatic 5-membered heterocyclic ring: "famoxadone", 13 m "Saccharomyces cerevisiae" Idone), flutianil, octhilinone, probenazole, S-allyl 5-amino-2-isopropyl-3-oxo-4-o-toluene Base-2,3-dihydropyrazole-1-thiocarbamate; -Others: acibenzolar-S-methyl, amisulbrom, carbendazim (anilazine), blasticidin-S, captafol, captan, chinomethionat, dazomet, debacarb, dabacteria (diclomezine), difenzoquat, thiol sulfate, fen〇xanU, folpet, ox〇iinic acid, piperalin ), proquinazid, pyroquilone, quin〇xyfen, triazoxide, triCyClazole, 5_gas_7_(4-decylpyridinium- 1-yl)-6-(2,4'6-trifluorophenyltriazolo[15a]pyrimidine, 2-butoxy-6-iodo-3-propylnonene_4·one, 5• Chloromethoxypyrimidin-2-yl)-2-methyl-1H-benzimidazole, 6-(3,4-dioxaphenyl)_5-methyl-[1,2,4] Azolo[l,5-a]pyrimidin-7-amine, 6-(4-tert-butylphenyl)-5-mercapto-[1'2'4]diazolo[15-a]pyrimidin-7-amine ,5-methyl_6_(3,5,5-trimethylhexyl)-[1,2,4]triazolo(1)"]pyrimidin-7-amine, 5-methyl-6-octyl-[1 '2,4]triazolo[l 5_a]pyrimidin-7-amine, 6•methyl-5-octyl-[1,2,4]triazino[ny-pyrimidine-7-amine, &ethyl 136128.doc -13- 200930297 Octyl-[1,2,4]triazolo[! 5 ]pyrimazin-7-ylamine, 5-ethyl-6-octyl_[1,2'4 Triazolo-n,5-a]pyrimidin-7-amine, %ethyl- ortho-, trimethylhexyl H!, 2,4]trim-indenyl, 5-decyl-7-ylamine, 6-octyl $propyl-[1,2,4]disaphthyl 7 r J street pyridine-7-ylamine, 5·decyloxymethyl-6_octyl-[1,2,4]diindole[ua] Mouth bite _7_ylamine, ^octyl I tris-methyl-[1,2,4] triterpene and bleed _7_ylamine and ^three gas methyl ^ (3,5,5-triterpenoid Hexyl group Hl, 2'4] triterpene (1) is called a mouth bite _7_ylamine; 2.5) a group of urethane and dithiocarbamate selected from the group consisting of: _ thio And dithiocarbamate formic acid: fermifine (ferba (4), manganese powder (mancozeb), manganese napu (ma) Neb), metam, methasulfocarb, metiram, propineb, thiram, zineb, ziram ; - methionine vinegar · diethofencarb, benthiavalicarb, iprovaHcarb, propamocarb, propamocarb hydrochloride, valiphenal, N_ ( 4-(1-(4-cyanophenyl)ethanesulfonyl)butan-2-yl)aminobutanoic acid 4-fluorophenyl ester; 2·6) selected from the group consisting of the following Fungal agents: - pulse: dodine, donut free test, guazatine, acetic acid double vein salt, dioctyl octylamine (iminoctadine), dicaprylin triacetate, ginseng (burning benzoic acid) bismuth Amine (iminoctadine tris (albesilate)); antibiotics: kasugamycin, kasugamycin hydrochloride 136128.doc -14- 200930297, polyoxins, streptomycin, weili Validamycin A; • Basic bamboo biology · binapacryl, dicloran, dinobuton, Dinocap, nitrothal-isopropyl, tecnazene; - organometallic compound: fentin salt, such as fentin acetate, triphenyltin Fentin chloride, fentin hydroxide; - sulfur-containing heterocyclic compounds: isoprothiolane, dithianon; - organic scale compounds: edifenphos , foetyl, fosetyl-aluminum, iprobenfos 'pyrazophos, tolclofos-methyl; -organochlorine compound: four Chlorothalonil, dichlofluanid, dichlorophen, flusulfamide, hexachlorobenzene, pencycuron, pentachlorophenol and Salt, phthalide, quintozene, thiophanate-methyl, tolylfluanid, N-(4-gas-2-nitrophenyl)-N- Ethyl-4-mercaptobenzenesulfonamide; -Inorganic active compound: Asian acid Salt, sulfur, Bordeaux mixture, copper salt, such as copper acetate, copper hydroxide, gas 136128.doc 200930297 oxy ketone, basic copper sulphate; - other: benzene, nitrocellulose (bronopol) , ° cyflufenamid, cymoxanil, diphenylamine, metrafenone, mildiomycin > oxine copper, cyclamate -prohexadione-calcium, spiroxamine, proronin, N-(cyclopropyl decyloxyimino-(6-difluoromethoxy-2,3-difluorophenyl) )methyl)-2-phenylacetamide, Ν·-(4-(4-carbo-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-indole-B Base-oxime-methylformamidine, Ν-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-oxime-ethyl-oxime-methyl Base, Ν'-(2-methyl-5-trifluoromethyl_4-(3-tridecyldecylpropoxy)phenyl)-indole-ethyl-hydrazine-methylformamidine, Ν,-(5-Difluorodecyl-2-methyl-4-(3-trimethyldecylpropoxy)phenyl)-indole-ethylmethylformamidine, oxime-methyl-N- (l,2,3,4-tetrahydronaphthalen-1-yl)-2-{1- [2·(5·methyl-3-trifluoromethyl°bazol-1-yl)ethyl aryl] 〇 bottom bite _4_ base} thia _4·carbamamine, (r)_N-• Methyl-N-(l,2,3,4-tetrahydronaphthalen-1-yl)-2·{1-[2·(5-methyl-3-trifluoromethyl) "乙)基基]派咬_4-基}thiazolecarbamamine, acetic acid 6-t-butyl-8-fluoro-2,3-dimercaptoquinolin-4-yl ester, methoxyacetic acid 6 - Tert-butyl-8-fluoro-2,3-dimercaptoin-4-yl ester. Further, the present invention relates to the use of a fungicidal mixture for controlling a phytopathogenic fungus and a composition comprising the same. [Prior Art] The azolylmethyloxy fluorocarbon of the component 1, its preparation and its use in crop protection are known from WO2007147778 and ΕΡ 06115766.5 (WO2007147778 136128.doc -16 - 200930297 based thereon). The active compounds described above as component 2, their preparation and their action against pathogenic pathogens are known (see http://www.hclrss.demon.co.uk/index.html; http://www. Alanwood.net/pesticides/); it is commercially available. Compounds having the IUPAC nomenclature, their preparation and their fungicidal activity are also known (see Can. J. piant sci. 48(6), 587-94, 1968; EP-A 141 317; EP-A 152 031; -A 226 917 ; EP-A 256 503 ; HP-A 428 941 ; EP-A 532 022 ; EP-A 1 028 ' 125 ; EP-A 1 035 122 ; EP-A 1 201 648 ; EP-A 1 122 244,

JP 2002316902; DE 19650197; DE 10021412; DE 102005009458; US 3,296,272; US 3,325,503; WO

98/46608; WO 99/14187; WO 99/24413; WO 99/27783; WO 00/29404; WO 00/46148; WO 00/65913;

01/54501; WO 01/56358; WO 02/22583; WO 02/40431; WO 03/10149; WO 03/1 1853; WO 03/14103; WO 03/16286; WO 03/53145; WO 03/61388; WO 03/66609;

WO 03/74491; WO 04/49804; WO 05/120234; WO

WO 05/123690; WO 05/63721; WO 05/87772; WO 05/87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; WO 07/90624) SUMMARY OF THE INVENTION In view of reducing the amount of application and expanding the range of activity of known compounds, it is an object of the present invention to provide an improved display of the activity against harmful fungi, particularly of certain indications, at a reduced total amount of active compound applied. mixture. 136128.doc -17- 200930297 Therefore, the mixture defined at the beginning has been found. Accordingly, the invention is also particularly concerned with the inclusion of at least one Hb compound of the formula and at least one other fungicidal active compound (Component 2) (for example one or more, for example 1 or 2, of the groups 2.1 to 2.6 mentioned above) An active compound) and a fungicidal composition according to one or more agriculturally acceptable carriers. In addition, it has been found that simultaneous (in combination or separate) administration of the compound hydrazine and the compound hydrazine or the compound hydrazine with the compound π continuous application allows for better harmful fungal control (synergy mixed mash) than the individual compounds. Considering the reduced application rate, these mixtures are of concern because many substances are applied in a reduced total amount of active compound with improved activity against harmful fungi, especially for certain indications. Simultaneously (in combination or separately) administration of Compound I and Compound π increases the killing activity in a superadditive manner. In the sense of the present invention, co-administration means that at least one compound I and at least one other active compound are present simultaneously in the field of action (ie, the fungus that damages the plant to be controlled and its habitat) in an amount sufficient to effectively control the growth of the fungus. 'such as infected plants, plant propagation material (especially seeds), soil, matter or space and (4) to be protected against fungal attack, plant propagation material (especially seeds), soil, matter or space). This can be achieved by the combination of a compound of the active compound in combination with at least one other active compound or a compound I and at least one other active compound which are administered simultaneously in at least two separate active compound formulations, Alternatively, the biochemical sigma is applied continuously to the site of application, and the gate spacing between individual active compound administrations is selected such that the first active compound is present in the active site in a sufficient amount when administered. The active compound is applied 136128.doc 200930297 The order is not important. Due to the basicity of the nitrogen atom, the compound I can form a salt or an adduct with a mineral acid or an organic acid or with a metal ion. Examples of inorganic acids are hydrohalic acids (such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide), carbonic acid, sulfuric acid, phosphoric acid and nitric acid. • Suitable organic acids are, for example, formic acid and alkanoic acids such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, as well as glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid , cinnamic acid, oxalic acid, alkyl sulfonic acid (sulfonic acid having a linear or branched alkyl group of i ® to 20 carbon atoms), aryl sulfonic acid or aryl disulfonic acid (containing one or two An aromatic group of a sulfonic acid group (such as a phenyl group and a naphthyl group), an alkylphosphonic acid (a phosphonic acid having a linear or branched alkyl group of 1 to 20 carbon atoms), an arylphosphonic acid or an aryl group a bisphosphonic acid (an aromatic group bearing one or two phosphate groups (such as 'stupyl and naphthyl)), wherein the alkyl or aryl group may carry other substituents such as p-toluenesulfonic acid, salicylic acid, Aminosalicylic acid, 2-phenoxybenzoic acid, 2-ethoxylated benzoic acid, and the like. φ Suitable metal ions are especially ions of the second main group of elements (especially calcium and magnesium), ions of the third and fourth main elements (especially aluminum, tin and lead) and one to eight transition elements (especially chromium, manganese, Ions of iron, cobalt, nickel, copper, zinc and others. Particularly preferred is the metal ion of the transition element of the fourth period. Metals can exist at various valences that they can be presented. [Embodiment] In the definition of the symbols given in the above formula, common terms generally referring to the following substituents are used: Halogen: fluorine, gas, bromine and iodine; 136128.doc -19- 200930297 Alkyl and complex groups ( An alkyl moiety such as an alkylamino group: a saturated straight or branched hydrocarbon group preferably having from 1 to 4 carbon atoms, such as methyl, ethyl, propyl, 1-methylethyl, butyl, Methyl propyl, 2-methylpropyl and 1,1-dimethylethyl. Halogen group: an alkyl group as mentioned above wherein some or all of the hydrogen atoms in the group are replaced by a tooth atom as mentioned above. In one embodiment, the alkyl group is substituted at least once or all with a particular halogen atom (preferably, fluorine, gas or bromine). In another embodiment, the alkyl group is partially or fully halogenated via a different atom; in the case of a mixed dentate substitution, a combination of gas and fluorine is preferred. Particularly preferred is a (C1-C4)haloalkyl group, more preferably a (Cl_C2)haloalkyl group such as a gas methyl group, a bromomethyl group, a dihalofluorenyl group, a trimethyl group, a fluoromethyl group or a difluoromethyl group. , difluoromethyl, fluorofluoromethyl, difluorofluoroindolyl, gaseous difluoromethyl, oxiranyl ethyl, 1-bromoethyl, hydrazine-fluoroethyl, 2-fluoroethyl, 2,2_ Difluoroethyl, 2,2,2·trifluoroethyl, 2_gas_2_fluoroethyl, 2_gas_2,2_difluoroethyl, 2'2-digas_2_fluoroethyl Base, 2,2,2-trisoleethyl, pentafluoroethyl or 1,1,1-trifluoroprop-2-yl. Alkoxy group: an alkyl group as defined above which preferably has from 丨 to 4 carbon atoms via an oxygen linkage. Examples of preferred alkoxy groups are: decyloxy, ethoxy, n-propoxy, 1-methylethoxy, butoxy, 1-mercaptopropoxy, 2-methylpropoxy or 1,1-Dimercaptoethoxy. Alkoxy groups: alkoxy groups as defined above, wherein some or all of the nitrogen atoms of these groups are replaced by a tooth atom (especially fluorine*, gas or moisture) as described above under the tooth alkyl group. Examples of preferred haloalkoxy groups are ruthenium CH2F, 〇CHF2, 〇cf3, 〇CH2C1, 〇CHCl2, 〇ccl3, fluorinated hydrazine 136128.doc ·20· 200930297 base, difluoro fluoromethoxy group, gas difluoride Oxyloxy, 2_glycolyloxy, 2_glycolyloxy 2-filled ethoxy, 2-filled ethoxy, 2,2-difluoroethoxy, hi trifluoroethoxy, 2- Gas-2_fluoroethoxy, 2-chloro-2,2-difluoroethoxy, '2-nitro-2-fluoroethoxy, 2,2,2-trichloroethoxy, 〇C2f5, 2_Fluoropropyloxy, %propyloxy, 2,2.difluoropropoxy, 2,3-difluoropropoxy, 2_&propoxy, 3-propyloxy, 2 , 3-dipropoxy, 2·bromopropoxy, 3 bromopropoxy, 3,3,3-trifluoropropoxy, 3,3,3·tri-propoxy, φ 〇CH2- C2F5, 0 is called he, l-(CH2F)-2-fluoroethoxy, ^(CH2C1)-2_gas ethoxy, 1-(CH2Br)-2-bromoethoxy, 4·fluorobutoxy 4-cyclobutoxy, 4-bromobutoxy or nonafluorobutoxy. Sulfyl group: an alkyl group as defined above attached via a sulfur atom. The compounds of formula I are obtained in the form of a mixture of palmitic centers and generally racemates or diastereoisomers of erythro and threo. For example, the erythro and threo diastereomers of the compounds of the present invention can be separated and isolated, in pure form, based on different solubilities or by column chromatography. These homogeneous diastereomeric pairs can be used to obtain the homo-enantiomers using known methods. The homogeneous diastereomers or enantiomers obtained in the synthesis and mixtures thereof are suitable as antibacterial agents. This applies correspondingly to fungicidal compositions. Preferred herein are the enantiomeric pairs or the enantiomers of the cis-arrangement of the cyclic oxime and the triazolyl fluorenyl substituent. Compound I can exist in a variety of crystal modifications that may differ in biological activity. Such materials are included within the scope of the invention. In the compounds of the formula I used according to the invention, the meaning of the following substituents is especially preferred in each case, either alone or in combination. Here, if appropriate, a preferred substituent of 136128.doc -21 200930297 or a preferred combination of substituents is suitably applied to the precursor of the compound of the present invention. Substituent A is a stupid group substituted by 2 F, thus producing a total of 6 substituents from the following formula:

F A4 A5 A6 〇 According to an embodiment, A is A1 or A2. According to a preferred embodiment, A is A1. Another embodiment relates to compound I in which B is unsubstituted pyridyl, thienyl, thioxyl, thiophene or cumyl. According to a preferred embodiment, B is a bite base or a stalk base. According to another preferred embodiment, the hydrazine is a pyridyl group. In another embodiment of the present invention, hydrazine is a phenyl group substituted with 1 to 3 or less substituents: halogen, oxime 02, amine group, alkyl group, C "C4 alkoxy group, C"-C4 haloalkyl group, (VC* haloalkoxy, C, -C4 alkylamino, (V C4 dialkylamino, thio or (^-(: 4 alkylthio). In another embodiment, B is 1 to 3 substituents substituted by stupid 136128.doc •22· 200930297 base: alizarin, (Vq alkyl, (^-(^ alkoxy, Ci_C4_alkyl or Ci_ c4 haloalkoxy. In another In one embodiment, 'B is a phenyl group substituted with 1 to 3 halogens. Particularly in view of the use of the compound I of the present invention, preferred are the compounds of the present invention as set forth in Tables 2 to 6 below. The groups mentioned for the substituents in the tables in which they are mentioned are themselves the substituents in question = a particularly preferred embodiment. Table 1 e 〇行威代竿 R 1-1 2-methylbenzene Base---- 1-2 3-methylphenyl---- 1-3 4·methylphenyl---- 1-4 2-methoxyphenyl---- 1-5 3- Methoxy phenyl group ----- 1-6 4-methoxy phenyl group - 1-7 2_- gas group ~~' '~~~--- 1-8 3-gas phenyl--- - 1-9 4-gas benzene Base--- 1-10 _2-fluorophenyl- 1-11 3-fluorophenyl- 1-12 4-fluorophenyl-one-1-13 2-ox-3-oxooxy^--- 1-14 2-Chloro-4-oxime base 1-15 2,3-diqi stupyl----- 1-16 2,4-diqi stupid---- 1-17 3,4 - 二气笨基*-- 1-18 2,3-Difluorophenyl-- 1-19 2,4-Difluoro-p-yl---- 1-20 2-Chloro-3-gas base 1- 21 2-Chloro-4-fluorophenyl 1-22 2-β ratio bite base -- -- 1-23 3-port ratio bite base - 1-24 4-pyridyl----- 1-25 2- Thienyl--- 1-26 3-thienyl~~^*~~--- 1-27 thiazol-4-yl---------- 136128.doc •23- 200930297 --- &quot ;"Γ^ο ---- Row Substitute - 1^70 — Bite-5-Base---- 嗔吐-4-基 1-30---- 鸣嗤-5·基1 〇1 --1 ~^_-_ 2-furanyl 2 Formula 1 Compound, wherein A is A1 and B corresponds to one of the substituents of Table 1 in each case, with the exception of 2-methylbenzene. Base. Table 3

A compound of formula 1 wherein A is A2 and B corresponds to the substituents of one of Table 1 in each case. Table 4 Compounds of formula 1 wherein A is A3 and B corresponds to the substituents of one of Table 1 in each case. Table 5 Compounds of formula 1 wherein A is A4 and B corresponds to the substituents of one of Table 1 in each case. Table 6 Compound of formula 1 wherein A is A5 and B corresponds to the substituents of one of Table 1 in each case. Table 7 Compound of formula 1 wherein A is A6 and B corresponds to the substituents of one of Table 1 in each case. In a preferred embodiment, the invention relates to a fungicidal mixture comprising as an active ingredient an synergistically effective amount of the following: 1} oxazolylmethyloxime of formula 1, wherein 136128.doc -24- 200930297 A is a phenyl substituted by 2 F, which is an unsubstituted n-substituted phenyl group, a thiophene group, a fluorenyl group, a fluorene group or a furyl group or a substituent substituted with 1 to 3 or less substituents. : halogen, oxime 02, amine group, c _c4 alkyl group, oxy group, c] _ c4 nanthyl group, Cl_C4 dentate alkoxy group, Cl_C4 alkylamino group, Cl_C4 dialkylamino group, thio group or Ci- a C4 alkylthio group, wherein the limitation is that if A is 2,4-difluorophenyl, then B is not o-methylphenyl, > and its plant compatible acid addition salt or metal salt, and 2 a fungicidal compound II selected from the group consisting of: 2.1) anthraquinone selected from the group consisting of: atropine, ether oxystrobin, enestrobin, fluoxetine, kexinxin , phenoxystrobin, orimycin, oxystrobin, baikemin, baibo, trifluoro, 2_(2-(6-(3-chloro-2-methylphenoxy)_5_fluoro Pyrimidine _4_yloxy)phenyl)_2-methoxyimine -N-methylacetamide, 2-(o-((2,5-dimethylphenyloxyfluorenylene)phenyl)-3-methoxyethyl acrylate, 3-methoxy-2 (2_(ν_(4methoxyphenyl)cyclopropanone carboxy-iminylthiomethyl)phenyl) acrylate methyl ester; 2·2) a carboxy group selected from the group consisting of the following Indoleamine: - anilinocarbamidine: benzoxanthin, benzophenone, malacic acid, bxixifene, bokley, wiltonin, metoprofen, cycloheximide, flonidine, flara Ratio, Isotianil, Carrageen, rust-free amine, chlordamine, furosemide, octopus, oxidized rust, penthiopyramine, gram rot, thifluzamide, thiophene, 2 -Amino_4-methylthiazolylaminocarboxamidine, 2_gas_Ν_ 136128.doc •25- 200930297 (1,1,3-tridecylindan-4-yl)nicotinamide, > 1-(3|,4'-di-5-fluorobiphenyl-2-yl)-3-difluorodecyl-1-methyl-1H-pyrazole-4-carboxamide, N-[2 -(1,3-Didecylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(4'-gas-3,5 -difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-decylamine, Ν-(4·-chloro-3',5-difluoro benzene- 2-yl)-3-trifluoromethyl-1-indolyl-1H-pyrazole-4-carboxamide, Ν-(3·,4'-di-5-fluorobiphenyl-2-yl) -3-trifluoromethyl-1-indolyl-1Η-pyrazole-4-decylamine, Ν-(3·,5-difluoro-41-methylbiphenyl-2-yl)-3-di Fluorenyl-1-methyl-1H-pyrazole-4-decylamine, N-(3',5-difluoro-4.-indenylbiphenyl-2-yl)-3-trifluoromethyl 1-methyl-1H-pyrazole-4-decylamine, N-(2-dicyclopropan-2-ylphenyl)-3-difluoroindol-1-yl-1H-pyrazole- 4-decylamine, N-(cis-2-dicyclopropan-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N- (trans-2-dicycloprop-2-ylphenyl)-3-dimethyl fluorenyl-1-indolyl-1 Η-Π 嗤 嗤 4- 4-indoleamine, N-(2匕fluoro-4' -Ga-5-methyl-biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3',f-trifluoro Benz-2-yl)-1-mercapto-3-trifluoromethyl-1H-pyrazole-4-decylamine, N-(3,4W-trifluorobiphenyl-2-yl)-1-anthracene 3--3-difluoroindolyl-1H-pyrazole-4-decylamine, Ν-(2·,4',5'-trifluorobiphenyl-2-yl)-1-indolyl-3-di Fluorinyl-1H-indazole-4-decylamine, N-(3,4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H- Azole-4-decylamine, N-(4'-(trifluoromethylthio)biphenyl-2-yl)-3-difluoroindol-1-yl-1H-pyrazole-4-indole Indoleamine, Ν-(4·-(trifluoromethylsulfenyl)biphenyl-2-yl)-1-methyl-3-trifluorodecyl-1Η-pyrazole-4-carboxamide, N' -(4-(4-chloro-3-trifluoromethylphenoxy)-2,5-diamidinophenyl)-N-ethyl-N-indenyl sulphate, N'-(4-( 4-fluoro-3-trifluoromethyl phenoxy)- 136128.doc -26- 200930297 2,5-Dimethylphenylethyl_N-methylformamidine, Ν·-(2-mercapto- 5-trifluoromethyl-4-(3-trimethyldecylpropoxy)phenyl)-indole_ethyl_Ν_methylformamidine and oxime,-(5·difluoromethyl-2-methyl 4-(3-trimethyldecylpropoxy)phenyl)-N-ethyl-N-methylhydrazine; - hydrazine carboxylic acid morpholine: dadifene, flumorph; Indoleamine: flumethalin, fluopyram, fluopyram, phenhydramine, N-(3-ethyl-3,5,5-trimethylcyclohexyl)_3-carbamimidamine Base 2_hydroxybenzamide;

- other carboxamides: gupamine, dioxime, dipropargylamine, hydroxytetracycline, pyrithione, N-(6-methoxy n ratio _3_yl) cyclopropanolamide ; 2.3) An azole selected from the group consisting of: azoconazole, bistriazole, carbendazole, cycloxazole, difenyl guanidine, Dakli, Dakli-M, defeat Huanjun, Fenbu Kangxi, Qikuikang 0 sit, protect the stone Xidan, read, Shiyebian Taifen,hexaconazole, amizole, eppoxazole, leaf sputum, nitrile Sister & %, imidazole, paclobutrazol, pingkerazone, puglione, thiopyrazine, acesulfame, beta creek, fludroxazole, triptyron, triterpenic '% _ 嗤, thin effect #, Huan Sit, 丨_(4-Phenylphenyl)-2-([1,2,4]triazol-1-yl)-cycloheptanol; Saiwei, 灭, column, sulphuric acid Fukushima; • Benzomethine "Sitting: Stupid cockroach Benefito, Mai Sui Ling, thiabendazole; Alkynyloxy (tetra) t, dysentery, called gas stupid... C 2_ net; ' Monomethoxyphenyl)isoxazole-5-yl)propane - I36128.doc -27· 200930297 2.4) selected from the group consisting of the following Nitrogen-containing heterocyclic compound. -Pig bite: chlorinated amine, bifenofol. ^ ° ^ * 3~[5-(4-Phenylphenyl)_2 3--methyl thiazolidine-3-yl]-pyridine, 2-labeled 2,3-methyliso-w ^ , , 5, 6~4 gas_4_methanesulfonylpyridine, 3,4,5-dioxin bite_2,6-methystr r λ - ^ ^ ~, N_(1_(5 bromo-3-pyridine -2-yl)ethyl)-2,4-one gas sulphate, Ν·((5-bromo-3-chloro-pyridin-2-yl)methyl)_2,4-dichloroin the amine; -Blowing bite: Continued acid dying, sputum, sputum, flurazin, fenrimyl, azoxystrobin

Yuezong, destroying the forest, gas biting, Nerimo, Pimeni; - Pyrrole: protecting the Ning, seeding slightly; - Scaring: Adi Linlin, 菌菌雷' 囷 、, acetic acid haloxime, Powder rust, Sande-3⁄4•······································································ Insectamine, carbendazim, chlortetracycline, tetrazolium, captan, chlorpyrifos, milong, imiprozil, sputum, clear enemy, methyl sulphate, fast, oxazolone, Imidazolidone, oxacillin, fenpropidin, fore, octyl ketone, oxolinic acid, dysprosium, thiabendazole, prunazide, praziquantel, vafenfen, triazosin, tri赛azole, 赛福宁, 5-gas-7-(4-methylpiperidinyl)_6_(2,4,6-trifluorophenyl)-[1,2,4]triazolo[l,5 -a]pyrimidine, 2-butoxy-6-moth-3-propyl nonen-4-one; 2_5) an amino phthalate and a dithioamino decanoic acid selected from the group consisting of the following Ester: -thio and dithiocarbamate: melamine, manganese powder, manganese napu, weibai mu, sulfavir, free rotten, bismuth zinc napro, deen '辞乃136128.doc -28· 200930297 浦,福美锌; - urethane: carbendazim, phenothi- valide, carbendazim, propamocarb, chlorpyrifos hydrochloride, valprone, N- (1-(1-Cyanophenyl)ethanesulfonyl)butan-2-yl)aminopyruic acid 4-fluorophenyl ester; 2.6) Other fungicides selected from the group consisting of the following Agent: - pulse: Doning, Doning free test, biguanide salt, acetic acid double vein salt, bis-octylamine, bis-octylamine triacetate, ginseng (alkylbenzene sulfonate) diphthylamine; - antibiotics: kasugamycin, Kasugamycin hydrochloride hydrate, polyoxin®, streptomycin, weili microtin A; - phenylbenzene derivatives: baiqi, aerobic amine, large devolution, white powder, ugly bacteria , tetrakis-nitrobenzene; - organometallic compounds: triphenyltin salts, such as triphenyltin, triphenyltin, triphenyltin hydroxide; - sulfur-containing heterocyclic compounds: indole, nitrile ; _ - Organic dish compound: Pleurotus ostreatus, Triethylene sulphate, Ethyl aluminum, Propyl sylvestris, Pinus sylvestris, Methyl-Dexazone; - Organic gas compound: Four gas isophthalonitrile, Yifaling, double Gas expectant Hexabenzene, Binclones, pentaphenol and their salts, benzoquinone, quetiacin, methylpolyprofen, yiluoning, guanidine-(4·qi-2-nitrophenyl)-沁ethyl- 4-methylbenzene decylamine; - inorganic active compound: phosphorous acid and its salt, sulfur, Bordeaux mixture, copper salt such as copper acetate, copper hydroxide, oxyalkylene oxide, basic copper sulfate; 136128.doc - 29- 200930297 - Others. Biphenyl, bromide, thifenamide, cymoxanil, diphenylamine, melfene, chlorfenapyr, copper quinolate, cyclamate _ calcium, spirulina, benefit洛宁,Ν·(cyclopropylmethoxyimino-(6-difluoromethoxy~ 2,3-difluorophenyl)methyl)_2-phenylacetamide, ν, _(4_ (4-chlorotrifluoromethylphenoxy)-2,5-dimethylphenyl)-indole_ethyl_Ν_methylformamidine, hydrazine, _ (4-(4-fluoro-3-difluoro) Methylphenoxy)_2,5-dimethylphenyl)_Ν_ethyl_Ν-methylformamidine, ν'-(2-methyl-5-trifluoromethyl-4-(3-tri) Methyl decyl propoxy)phenyl)-N-ethylmethylmethyl, n,-(5-difluoromethyl-2-indolyl-4-(3-tridecylfluorenyl)propoxy )phenyl)_N_ethyl_N_methylhydrazine. Preferably, compound II is selected from the group consisting of: atorine, dextromethorphan, oxystrobin, dexamethasone, and trifluoro-sensitive. More preferred compound II is selected from the group consisting of: atorine, kexinxin, baikemin and trifluoro-sensitive. In addition, preferred compounds II are wiltonin, basixifene, acetamiprid, oxadione, halal, Ν-(3·, 4·-digas-5-fluoro phenyl-2-yl )_3·Difluorodecyl-1-indolyl-1Η-pyrazole-4-nonylamine, Ν-(2·dicycloprop-2-ylphenyl)_3_difluoroindol-1-yl- 1Η-° ratio 0 sit-4-methanamine, (cis-dicycloprop-2-ylphenyl)-3-di-IL methyl-1-mercapto-1Η-11 ratio 0 sit-4-a Amine, Ν-(trans-2-cyclopropyl-propyl-2-phenyl)-3-difluorodecyl-1-indenyl-4-indolylamine, fluorene-(2'-fluoro-4 '-Ga-5--methylbiphenyl-2·yl)-1-methyl_3_trifluoromethyl _111-<1 than oxa-4-carbamide, 1^-(3', 4',5|-Trifluorobiphenyl-2_yl)_1_methyl_3_trifluoromethyl-1H-pyrazole-4-decylamine, (3,4,5,-trifluoro Biphenyl-2-yl)_1-methyl-3-difluoro> methyl-1Η-° ratio 0 sit-4-carboxamide, I36128.doc -30- 200930297 phenyl-2-yl)-1 -mercapto-3-difluorodecyl-1H-pyrazole-4-carboxamide, N-(3·,4·,5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl -1-methyl-1H-pyrazole-4-decylamine, N-(4'-(trifluoromethylthio)biphenyl-2-yl)-3-difluoromethyl-1-methyl -1H-pyrazole-4- Formamide, Ν-(4·-(trifluoromethylsulfenyl)biphenyl-2-yl)-1-indolyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N '-(4-(4-Gas-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine, N'-(4- (4-A-3-trifluoromethyl-phenoxy)-2,5-dimercaptophenyl)-N-ethyl-N-indenyl hydrazine, N'-(2-mercapto-5 -Trifluoromethyl-4-(3-trimethyldecylpropoxy)phenyl)-N-ethyl-N-methylindole and N'-(5-difluorodecyl-2-indole 4-(3-Trimethyldecylpropoxy)phenyl)-N-ethyl-N-indenylhydrazine. Preferred compound II is selected from the group consisting of: bxixifene, N-(2-dicyclopropan-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole 4-carbamamine, N-(cis-dicyclopropan-2-ylphenyl)-3-difluoromethyl-1-methyl-1Η-»bazole-4-decylamine, N- (trans-2-dicyclopropyl-2-phenyl)-3-difluoroindol-1-yl-1H-pyrazole-4-carboxamide, N-(2'-fluoro-4' - gas-5'-methylbiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-decylamine, Ν-(3',4\5·- Trifluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1Η-pyrazole-4-carboxamide, Ν-(3',4',5'-trifluorobiphenyl- 2-yl)-1-methyl-3-difluoromethyl-11^pyrazole-4-carboxamide, N-(2',4',5'-trifluorobiphenyl-2-yl)- 1-methyl-3-difluoromethyl-1H-0 is 0 圭-4-曱, amine, N-(3,4',5'-trifluorobiphenyl-2-yl)-3-fluoro Methyl-1-methyl-1H-pyrazole-4-decylamine, Ν-(4·-(trifluoromethylthio)biphenyl-2-yl)-3-difluorodecyl-1- Mercapto-1Η-pyrazole-4-decylamine, Ν-(4'-(trifluoromethylthio)biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1Η- »Bizozol-4-carbamide, Ν·-(4-(4-Ga-3-trifluorodecylphenoxy)- 2,5-Dimethylphenyl)-N-ethyl 136128.doc -31- 200930297 ke-N-methyl oxime, Ν·-(4·(4-fluoro-3-trifluoromethylphenoxy) -2,5-Dimethylphenyl)-N-ethyl-N-methylformamidine, N'-(2-methyl-5-trifluoromethyl-4-(3-trimethyldecane) Propyloxy)phenyl)·Ν-ethyl-N-mercaptomethylhydrazine and]Sf,-(5-difluoromethyl-2-indolyl-4-(3-tridecylfluorenyl)propoxy Phenyl)-N-ethyl-N-methylformamidine. The preferred compound lanthanide is selected from the group consisting of cycloxazole, stupid; ether methylcyclazole, epoxiconazole, oxime, dimethoate, myclobutanil, cytosine, pleckley, pu Sulphur is sitting, getting Klee, fluoroether, and poker.

A ^ Preferred compound lanthanide is selected from the group consisting of cycloxazole, cycloheximide, meconazole, pucliron, prothiocanthazole, dextran, fluconazole, and flu. Preferred compound II is selected from the group consisting of: befenate, phenylimidazole, spirox, chlorhexidine, porphyrin, captan, fenpropidin, dermis, tetraisophthalonitrile , methyl poly-safe, sulfur, copper hydroxide, melfene and spirocycline. Q Preferred compound 11 is selected from the group consisting of: befenate, porphyrin and melfene. In a preferred embodiment, the compound is selected from the group consisting of: tetraisophthalonitrile, melfene, befenfen, captan, spiroxyl, epoxiconazole, care Teflon, myclobutanil, dexamethasone, meconazole, trifluoro-sensitive, sulfur, prothioconazole, methylpolyprofen, kekemin and N_(2-dicycloprop-2-ylphenyl)-3 _Difluoromethyl-1-methyl-1H-pyrazole _4. carbamide. 2. Two preferred compounds! (Component) and at least one group derived from the sphenanthrene are especially selected from the following Active compound of the group consisting of components (component 136128.doc -32- 200930297 = composition: atoramine, bacteriocin, amphotericin, kexinxin, orimycin, oxystrobin, baikemin and It is also preferred that the compound ι (component υ and 至2) is taken from a combination of an active compound (plant 2) which is especially selected from the group consisting of the following: Cyclosporin, chlorhexidine, methyl phenanthrene, fluocrin, fluoxetamide (pikebenzamide, amine, chlorfenapyr, gupamine, and (tetra)-amine. pleGbenzamid) ,gas

Also preferred are compounds! (component υ and at least - a group selected from the group of saliva 2) :: a group of active compounds selected from the group consisting of the following: (component 2): ring gram, Benzene mystery ring ° sitting, fluorine ring saliva, fluoroquinone 护, 护石夕得, 护 芬, leaf fungus saliva, nitrile saliva, pingke saliva, pugli, thiopyrazine, di taifen, three Tyrone, Dekley L sitting, ring g saliva, poker pull, sagiler, benomyl, befenfen and ethipramine. Also preferred is compound 1 (component im at least one selected from nitrogen-containing heterocyclic groups) Groups of compounds 2.4) and especially selected from the group consisting of active compounds (component 2) consisting of: edugamine, cypro, fenremore, chlorpyrifos, pimeni, saifinin , 护宁宁, 菌菌灵, 粉录琳, 三得芬, 苯锈啶, 依普同, 免克宁, oxazolone, imidazoprilz, ar, tetragen, forelup It is also preferred to use Compound #1 (component 丨) and at least one group selected from the group consisting of urethane groups 2.5) and especially selected from the group consisting of (4) compounds (component 2) Composition: Manganese Gram, free of rotten, methyl sinensis, sedative, scorpion, flubenthiavalicarb and ruthenium. I36128.doc -33- 200930297 is also preferably compound I (component 1) and At least one composition selected from the group consisting of fungicides from group 2.6) and especially selected from the group consisting of active compounds (component 2) consisting of nitrile sulfonium, triphenyltin salts (such as triphenyltin sulphate) , triethylphosphoric acid, aluminum phosphate, h3po3 and its salts, tetrachloroisophthalonitrile, Yifaling, methylpolybao, copper acetate, copper hydroxide, copper oxide, copper sulfate, sulfur, cymoxan, beauty Triflurane, spirocyclam and 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4] - Triazolo[l,5-a]sulfudidine. It is also preferred to use the mixtures and combinations of the combinations mentioned in the examples. Further, the present invention is preferably related to the compositions listed in Table A, Each row of A corresponds to a compound comprising Formula I (Component 1), which is preferably one of the preferred compounds described herein, and comprises the other active compound 11 as indicated in the row discussed in each case (Component 2) Fungicidal Thereof. According to one embodiment of the present invention, each row of Table 2 of the component 1 in in each condition is one of the specific individual compounds of formula I are detailed in Tables 1 to 7.

Line component 1 Component 2 A-1 Compound of formula I Atropine A-2 Compound I of the formula I-3 A compound of the formula I A fatty acid ester A-4 Formula I compound fluoxetamine A-5 Formula I Compound kexinxin A-6 Formula I compound phenoxybamine A-7 Formula I compound origami A-8 Formula I compound oxystrobin A-9 Formula I compound Baikemin A-10 Compound I Baibo Card A-11 Compound of formula I, trifluoro-sensitive A-12 Compound of formula I 2-(2-(6-(3-Ga-2-methylphenoxy)-5-fluoropyrimidin-4-yloxy)benzene ))-2-oximeimido-N-mercaptoacetamide 136128.doc -34- 200930297

Line component 1 Component 2 A-13 Compound of formula I 2-(o-((2,5-didecylphenyloxymethylene)phenyl)phenyl)-3-methoxy acrylate methyl ester A-14 I Compound 3-Oxyloxy-2-(2-(N-(4-decyloxyphenyl)cyclopropanecarboxylimine)-decylthiomethyl)phenyl) decyl acrylate A-15 Compound of formula I Benxixin A-16 Formula I Compound Jingbu Cream A-17 Formula I Compound Mai Rust A-18 Formula I Compound Bicoxifene A-19 Compound I Compound Bockley A-20 Formula I Compound Rust A- 21 Compound of formula I oxifenamide A-22 Compound of formula I Cyclosporin A-23 Formula I compound flunin A-24 Formula I compound Folabi A-25 Formula I compound Isotianil A-26 I compound carrageen A-27 compound of formula I rust amine A-28 compound of formula I statin A-29 compound of formula I furfuramine A-30 compound of formula I acesulfame A-31 compound I oxidized rust A-32 Compound I of the formula I pyretiramine A-33 Compound of the formula I thifluzamide A-34 Compound of formula I gram rot A-35 Compound of formula I steroidal A-36 Compound of formula I 2-amino-4 - mercaptothiazole-5-anilinocarbazide A-37 Compound of formula I 2-gas-N-(l,l,3-three Methyl indane-4-yl)-nicotinium amide A-38 Compound of formula I Ν-(3|,4·-dichloro-5-fluorobiphenyl-2-yl)-3-difluoroindolyl- 1-mercapto-1H-0 ratio topi-4-carboxamide A-39 compound of formula I 5-fluoro-1,3-didecyl-1H-pyrazole-4-carboxylic acid [2-(1,3- Dimercaptobutyl)phenyl]decylamine A-40 Compound of formula I Ν-(4·-chloro-3',5-difluorobiphenyl-2-yl)-3-difluoroindol-1-yl -1-1H-〇比峻-4-甲的胺 A-41 A compound of formula I Ν-(4·-gas-3',5-difluorobiphenyl-2-yl)-3-trifluoromethyl-1 -mercapto-1H-indopazole-4-cartoamine A-42 Compound of formula I N-(3 V-di-5-fluorobiphenyl-2-yl)-3-trifluorodecyl-1- Mercapto-1H-° ratio 吐-4- 曱 胺 A-43 Compound I of formula I N-(3',5-difluoro-4·-fluorenylbiphenyl-2-yl)-3-difluoroindolyl 1-methyl-1H-pyrazole-4-decylamine A-44 Compound of formula I N-(3>difluoropipe-methylbiphenyl-2-yl)-3-trifluorodecyl-1-曱--1H-0 ratio. Sodium-4-branched amine A-45 Compound of formula I Ν·(2-dicycloprop-2-ylphenyl)-3-dimethylmethyl-1·indolyl 4- Methionine 136128.doc -35- 200930297 Row component 1 Component 2 A-46 Compound of formula I N-(川页-2-bicycloprop-2-ylphenyl)·3-dimethyl fluorenyl- 1-methyl-1H-port唾 唾 醯 醯 醯 A A A A A A A 47 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( (圭-4-Mercaptoamine A-48 Compound of formula I, dafenac A-49, compound of formula I, flurazin A-50, compound of formula I, flumethalin A-51, compound of formula I, flu'biproza (p-benzoquinone) Indoleamine A-52 Compound of formula I Fluorine ratio guanamine A-53 Compound of formula I Benzeneamine A-54 Compound of formula I N-(3-ethyl-3,5,5-trimethylcyclohexyl -3-mercaptoamino-2-hydroxybenzamide A-55 Compound of formula I gupamine A-56 Compound of formula I di-simo A-57 Compound of formula I di-propargylamine A-58 Compound of formula I via tetracycline A-59 Compound of formula I A-60 Compound of formula I N-(6-decylpyridin-3-yl)cyclopropanecarbamide A-61 Compound of formula I Azconazole A-62 Compound I, benzotriazole A-63, compound I, carbazole A-64, compound of formula I, cycloheximide A-65, compound of formula I, diphenylcarbazole, A-66, compound of formula I, Dakley A-67, compound of formula I Dakli-M A-68 Formula I Compound ff^(enilconazole) A-69 Formula I Compound epoxiconazole A-70 Formula I Compound Fenbucames A -71 Compound I of formula I A-72 Formula I Compound fluoroquinazole A-73 Formula I compound Refractory A-74 Formula I compound Heconazole A-75 Formula I compound Easy Azole A-76 Formula I Compound Epprozol A-77 Compound I of the formula I genus A-78 Formula I Compound Nitrile A-79 Formula I Compound MV A-80 Formula I Compound Multi-effect '• Sit A-81 Compound of Formula I Pinker's A-82 Formula I Compound Ppkley A-83 Formula I Compound Phromconazole A-84 Formula I Compound Hydrazine A-85 Formula I Compound Kelly 136128.doc -36- 200930297 Row Component Group 1 2 A-86 Compound I of the formula I occupies A-87 Compound of formula I 泰泰隆 A-88 Compound of formula I 泰泰分 A-89 Compound of formula I Cycloheximide A-90 Compound of formula I Compound of formula I 1-(4-Phenylphenyl)-2·([1,2,4]triazol-1-yl)cycloheptanol A-92 Compound of formula I races A-93 Compound of formula I Column A-94 Compound of formula I Sulfate A-95 Compound of formula I Rice cancer ester A-96 Compound of formula I Poker A-97 Formula I compound Saifu A-98 Formula I compound benomyl A-99 I compound befenfen A-100 compound of formula I Maisuiling A-101 Formula I Compound Benzene 11 Meters Sit A-102 Formula I Compound Thiabamide A-103 Formula I Compound Dependent A-104 Formula I Compound Moxacillin A-105 Compound I吉amine A-106 Compound of formula I fenfenol A-107 Compound of formula I 1-(4-Phenylphenyl)-1-(propyn-2-yloxy)-3-(4-(3,4- Dimethoxyphenyl)isoxazol-5-yl)propan-2-one A-108 Compound of formula I 3-[5-(4-Phenylphenyl)-2,3-dimercaptoisoxazole 3-yl]pyridine A-109 Compound of formula I 2,3,5,6-tetraki-4-methanesulfonylpyridine A-110 Compound of formula I 3,4,5-trispyridine-2,6- Diacetonitrile A-ll Compound I-(l-(5-bromo-3-pyridin-2-yl)ethyl)-2,4-di-nicotinamide A-112 Compound I of formula I ((5-Bromo-3-apyridin-2-yl)indenyl)-2,4-di-nicotinylguanamine A-113 Compound of formula I sulfonate-pyrimidine A-114 Compound of formula I cypro A- 115 Compound I of formula I Fluoromycin A-116 Compound of formula I Azulamide A-117 Compound of formula I, fenrimyl A-118 Compound of formula I, chlorpyrifos A-119 Compound of formula I, bite A-120, compound I Remo A-121 Formula I Compound Pimeni A-122 Formula I Compound Reliance A-123 Compound of formula I saponin A-124 compound of formula I adimorpholine A-125 compound of formula I carbendazim A-126 compound of formula I acesulfame acetate A-127 compound of formula I rust 136128.doc -37- 200930297 Component 1 Component 2 A-128 Compound of formula I, selefen A-129 Compound of formula I, oxazide A-130, compound of formula I, exemplified by A-131, compound of formula I, chlorpyrifos A-132, compound of formula I克宁 A-133 Compound I of formula I Axibenzazole-S-methyl A-134 Compound of formula I carbazole sulfamethoxazole A-135 Compound of formula I carbendazim A-136 Compound of formula I saponin A-137 Formula I Compound Captan A-138 Compound of formula I Tetra- dan A-139 Compound of formula I 螨 螨 A-140 Compound of formula I Mellon A-141 Compound of formula I imipenem A-142 Compound of formula I bacteriostatic A- 143 Formula I Compound Benzoin A-144 Formula I Compound Methyl Sulfate Benzene Express A-145 Compound of Formula I °Esophagia_ A-146 Compound of Formula I π 米0 sputum A-147 Compound I草灵 A-148 Formula I Compound Benzene biting A-149 Formula I Compound Forepe A-150 Formula I Compound Ciclophone A-151 Formula I Compound Oxalic Acid A-152 Formula I Compound Powder Disease A-153 Formula I Compound Thiabendazole A-154 Compound I of Formula I A-155 Formula I Compound Loxophone A-156 Compound I of Formula I A-157 Formula I Compound 3 0 Sitting 0 Qin A-158 Formula I Compound Trixazole A-159 Compound of Formula I Safing A-160 Compound of Formula I 5-Ga-7-(4-Methylpiperidin-1-yl)-6-(2,4 ,6-trifluorophenyl)-[1,2,4]tripeptide and [l,5-a] squeezing A-161 compound of formula I 2-butoxypropyl p-carbamate-4-嗣A -162 Formula I Compounds Ferrocene A-163 Formula I Compound Manganese Powder A-164 Formula I Compound Manganese A-165 Formula I Compound Free of A-166 Formula I Compound Weibai A-167 Compound I威A-168 Formula I Compound 曱-based Zinc Napurin A-169 Formula I Compound 136128.doc -38- 200930297 Row Component 1 Component 2 A-170 Formula I Compound Zinc Napo A-171 Compound I Fami Zinc A-172 Compound of formula I, carbaryl A-173, compound of formula I, fluorobenzil A-174, compound of formula I, carbaryl A-175, compound of formula I, oxazide A-176, compound of formula I, chlorpyrifos A -177 Formula I Compound 3-(4-Phenylphenyl)-3-(2-isopropoxycarbonylamine Methyl -3-mercaptodecylamino)propionic acid A-178 Compound of formula I valliated benzene A-179 Compound of formula I N-(l-(l-(4-cyanophenyl)ethanesulfonyl) 4-fluorophenylammonium 4-fluorophenyl ester A-180 Compound of formula I, A-181, compound of formula I, doxine, free base, A-182, compound of formula I, bis-octylamine A-183, compound of formula I, biguanide Octylamine A-184 Formula I Compound (Alkylbenzenesulfonic acid) Bis-octylamine A-185 Formula I Compound Bismuth Salt A-186 Formula I Compound Acetate Bismuth Salt A-187 Formula I Compound Chamomycin A-188 Compound I Chunnomycin Hydrochloride Salt A-189 Formula I Compound Polyoxin A-190 Formula I Compound Streptomycin A-191 Formula I Compound Willin Micro A A-192 Formula I Compound Baike A -193 Compound I of the formula I, amin A-194, a compound of the formula I, a large dissociation A-195, a compound of the formula I, a white powder, A-196, a compound of the formula I, a bacteriocin A-197, a compound of the formula I, a tetranitrobenzene A-198, Compound triphenylacetate A-199 Formula I compound Triphenyltin A-200 Formula I compound Triphenyltin hydroxide A-201 Formula I compound Indigo A-202 Formula I compound sulphur brewing A-103 I compound Pleurotus sinensis A-204 Formula I Compound Triethyl Phosphate A-205 Formula I Compound Ethyl Phosphate A-206 Formula I Compound Lysin Pine A-207 Formula I Compound White Pine A-208 Formula I Compound Sulfhydryl-Poke Pine A-209 Formula I Compound Tetraisophthalonitrile A-210 Formula I Compound Yifaling 136128.doc •39- 200930297

Line component 1 Component 2 A-211 Compound of formula I Bisphenol A-212 Compound of formula I Sulfamide A-213 Compound of formula I Hexachlorobenzene A-214 Compound of formula I Binding A-215 Compound of formula I Phenol and its salt A-216 Compound of formula I Phenylhydrazine A-217 Compound of formula I quetiacin A-218 Compound of formula I Methylpreservative A-219 Compound of formula I Ilonine A-220 Compound of formula I N-( 4-oxo-2-nitrophenyl)-N-ethyl-4-methylbenzenesulfonamide A-221 Compound I phosphorous acid and its salt A-222 Compound of formula I sulfur A-223 Compound of formula I Bordeaux Mixture A-224 Formula I Compound Acetone A-225 Formula I Compound Copper A-226 Formula I Compound Copper Oxide A-227 Formula I Compound Basic Copper Sulfate A-228 Formula I Compound Biphenyl A-229 Compound I bromide A-230 Compound I of the formula I-phenanthramine A-231 Compound of the formula I cream cyanide j A-232 Compound of the formula I diphenylamine A-233 Compound of the formula I meiflufenol A-234 Compound of the formula I Acetone A-235 Formula I Compound Quinoline Copper A-236 Formula I Compound Cyclocycline-Calcium A-237 Formula I Compound spirulina A-238 Formula I Compound Ilonine A-239 Formula I Compound N-(cyclopropylmethoxyimino-(6-difluoromethoxy-2,3-difluorophenyl)methyl)-2-phenylacetamide A-240 Compound I of formula I NH4 -(4-A-3-trifluorodecylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methyl silicin A-241 Compound I' N'-(4 -(4-Fluoro-3-trifluorodecylphenoxy)-2,5-diamidinophenyl)-N-ethyl-N-methyl silicin A-242 Compound of formula I Ν·-(2 -Methyl-5-trifluoromethyl-4-(3-trimethylsulfanylpropoxy)phenyl)-N-ethyl-N-methylformamidine A-243 Compound of formula I N'- (5-Difluoromethyl-2-methyl-4-(3-trimethyldecylpropoxy)phenyl)-N-ethyl-N-mercaptomethyl lung A-244 Compound I of formula I (Z-Fluoro-4'-Ga-5-methylbiphenyl-2-yl)-1-indolyl-3-trifluoromethyl-1H-0 ratio 曱-4- 曱 胺 A-245 Formula I The compound Ν-(3·,4'-5--trifluorobiphenyl-2-yl) benzhydrin-3-trifluoromethyl-indole-oxime-4-anthracene A-246 compound I (3',4i,5'-trifluorobiphenyl-2-yl)-1-indolyl-3-difluoromethyl-1Η-" ratio 136128.doc -40- 200930297 row component 1 component 2 Azole-4-decylamine A-247 A compound of formula I Ν-(2\4Ά-trifluorobiphenyl-2-yl)-1-methyl-3-difluoroindolyl-1H- "Bizozol-4-decylamine A-248 Compound of formula I N-PWJ-trifluorobiphenyl-2-yl)-3-fluorofluoroindol-1-methyl-1H-indazole-4-indole Indole A-249 Compound of formula I N-(4匕(trimethylmethylthio)biphenyl-2-yl)-3-difluoroindol-1-yl-1Η-σ ratio 吐_4_曱Amine A-250 A compound of formula I Ν-(4匕(trifluoromethylsulfenyl)biphenyl-2-yl)-1-methyl-3-dihydroxyl-1H-pyrazole-4-carboxamidine Amine A-251 Compound of formula I N'-(4-(4-Gas-3-trifluorodecylphenoxy)-2,5-diamidinophenyl)-N-ethyl-N-methylindole脒A-252 Formula I Compound N'-(4-(4-Fluoro-3-trifluorodecylphenoxy)-2,5-diamidinophenyl)-N-ethyl-N-methyl脒A-253 Formula I Compound N_-(2-Mercapto-5-trifluoromethyl-4-(3-trimethylsulfanylpropoxy)phenyl)-N-ethyl-N-methyl Formamidine A-254 Formula I Compound N'-(5-Difluorodecyl-2-mercapto-4-(3-tridecyldecylpropoxy)phenyl)-N-ethyl-N-oxime Methyl hydrazide A-255 Compound of formula I 2-(2-(3-(2,6-diphenyl)-1-indolyl-allylaminooxyindolyl)-phenyl)-2 - oxime imino-N-mercapto-acetamide A-256 Compound I of formula I A-257 Formula I compound Jingjialing (Mecosyl) A-258 Compound of formula I Ν-(2',4·-difluorobiphenyl-2-yl)-3-difluoroindol-1-yl-1H-pyrazole-4-decylamine A-259 Compound of formula I N-(2',4'-di-biphenyl-2-yl)-3-difluorodecyl-1-indolyl-1H-pyrazole-4-nonylamine A-260 Compound of formula I Ν-(2·,5·-Difluorobiphenyl-2-yl)-3-difluorodecyl-1-indolyl-1H-pyrazole· 4-carboxamide A-261 Compound of formula I Ν-( 2Ά di-biphenyl-2-yl)-3-difluoromethyl-1-indolyl-1H-pyrazole-4-decylamine A-262 Compound of formula I N-(3V5'-difluorobiphenyl- 2-yl)-3-difluoroindol-1-yl-1H-indazole-4-carboxamide A-263 Compound of formula I Ν-(3·,5·-di-biphenyl-2-yl )-3-difluoromethyl-1-methyl-lH-o-biazole-4-decylamine A-264 Compound of formula I N-(3_-fluorobiphenyl-2-yl)-3-difluoroindole Alkyl-1-indenyl-1H-pyrazole-4-nonylamine A-265 Compound of formula I N-(3'- gasbiphenyl-2-yl)-3-difluoromethyl-1-indenyl- 1Η-°Bizozol-4-carboxamide A-266 The compound of formula I N-(2'-fluorobiphenyl-2-yl)-3-difluoromethyl-1_mercapto-1H-» -4-decylamine A-267 Compound of formula I NP-chlorobiphenyl-2-yl)-3-difluoromethyl-1-indenyl-lH-ηpyrazole-4-carboxamide A-268 I compound N-[2-(l,l, 2,3,3,3-hexafluoropropoxy)-phenyl]-3-difluoromethyl-1-indolyl-1H-pyrazole-4-carboxamide A-269 Compound I-N 2-(l,l,2,2-tetrafluoroethoxy)phenyl]-3-difluoroindolyl-1-methyl- 136128.doc -41 - 200930297 Row component 1 component 2 1H-pyridyl Oxazole-4-carboxamide A-270 Compound of formula I N-(2-(l,3,3-tridecylbutyl)phenyl)-1,3-didecyl-5-fluoro-1Η-» Ratio "Supplemented 4-Amine A-271 Formula I Compound N-[l,2,3,4-Tetrahydro-9-(1-indolylethyl)-1,4-anthracene-5 -yl]-3-(difluoroindolyl)-1-methyl-1H-pyrazole-4-carboxamide A-272 Compound of formula I 2-(4-phenylphenyl)-N-[4-( 3,4-dimethoxy-phenyl)isoxazol-5-yl]-2-propan-2-freeoxy-ethylamine A-273 Compound of formula I 3-[5-(4-A Phenyl)-2,3-dimethylisoxazolidine-3-yl]pyridine A-274 S-allyl 5-amino-2-isopropyl-3- oxo- 4-o-tolyl-2,3-dihydropyrazole-1-thiodecanoate A-275 Compound of formula I 5-Gas-1-(4,6-dimethoxypyrimidin-2-yl)- 2-methyl-1沁benzimidazole A-276 Compound of formula I 6-(3,4-Dichlorophenyl)-5-mercapto-[1,2,4]triazolo[l,5-a Pyrimidine-7-ylamine A-277 Compound 6 of formula I (4-t-butylphenyl)-5-mercapto-[1,2,4]triazolo[1,5-&]pyrimidin-7-ylamine A-278 Compound of formula I 5-methyl -6-(3,5,5·tridecylhexyl)-[1,2,4]triazolo[l,5-a]pyrimidin-7-ylamine A-279 Compound of formula I 5-methyl -6-octyl-[1,2,4]triazolo[l,5-a]pyrimidin-7-ylamine A-280 Compound of formula I 6-methyl-5-octyl-[1,2, 4] Triazolo[1,5-a]pyrimidin-7-ylamine A-281 Compound of formula I 6-ethyl-5-octyl-[1,2,4]triazolo[l,5-a Pyrimidine-7-ylamine A-282 Compound of formula I 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine A-283 I Compound 5-Ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[l,5-a]pyrimidin-7-ylamine A-284 Formula I Compound 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine A-285 Compound of formula I 5-nonyloxyindenyl-6- Octyl-[1,2,4]triazolo[l,5-a]pyrimidin-7-ylamine A-286 Compound of formula I 6-octyl-5-trifluoromethyl-[1,2,4 Triazolo[1,5-a]pyrimidin-7-ylamine and 5-trifluoromethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazole [l,5-a] Mouth bit 7-ylamine A-287 Compound of formula I N-mercapto-N-(l,2,3,4-tetrahydronaphthalene -1-yl)-2-{1-[2-(5-fluorenyl-3-trifluoromethylpyrazol-1-yl)ethenyl]piperidin-4-yl}thiazole-4-carboxamidine Amine A-288 Compound of formula I (R)-N-indenyl-N-(l,2,3,4-tetrahydronaphthalen-1-yl)-2-{1-[2-(5-methyl- 3-trifluoromethylpyrazol-1-yl)ethinyl]piperidin-4-yl}thiazole-4-carboxamide A-289 Compound of formula I acetate 6-tert-butyl-8-fluoro-2 3-Dimercaptoquinolin-4-yl ester A-290 Compound of formula I methoxyacetic acid 6-tert-butyl-8-fluoro-2,3-dimercaptoquinolin-4-yl ester Mixtures of the compounds I and II (= mixtures of the invention) and compositions thereof are suitable as fungicides for the control of harmful fungi. These fungicides are characterized by their excellent activity against a wide range of phytopathogenic fungi, including pathogens carried by the soil, which are particularly derived from the following classes: Rhizoctonia 136128.doc -42- 200930297 (Plasmodiophoromycetes), Peronosporomycetes (synonymous: Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes ( Basidiomycetes) and Deuteromycetes (synonym: Fungi imperfecti). Certain fungicides are systemically effective and can be used as crop fungicides, fungicides for seed dressing and soil fungicides for crop protection

in. Moreover, such fungicides are suitable for controlling fungi which in particular attack the roots of wood or plants. The mixtures of the compounds I and π of the invention (= mixtures of the invention) and compositions thereof are of particular importance for controlling a number of pathogenic fungi on the following plants as well as reproductive material (for example seeds) and the harvested material of such plants: Various crop plants, such as grains, such as wheat, rye, buckwheat, triticale, oats or rice; leek, such as sugar beet or beet. 'Class 2, stone fruit and non-nuclear fruit, such as apple, Pear, plum, kernel, floor peach, strawberry, wood, kgitg kidney bean, flat... chestnut; legumes, such as 2:, glutinous or soy; oil plants, such as rape, sauerkraut, sauerkraut, sri choi, Coconut, cocoa, or soy; Cucurbitaceae, such as pumpkin 1, oil palm, peanut: 'such as cotton, linen, hemp or yellow fiber, lemon, grapefruit or hanging orange; vegetables such as orange, asparagus, cabbage Plants, carrots such as spinach, squash or sweet pepper; laurel, singapore, horse-aged potato, southern raw material plants, such as corn bran, cinnamon or camphor; energy and 136128.doc Soybean, wheat, rapeseed, ginseng or oil•43· 200930297 brown; corn; in grass; nuts; curry; tea; banana; vine (edible grape and wine grape); hop; grass, such as grass; Rubber plants; ornamental plants and forest plants such as flowers, shrubs, and deciduous conifers. And, a mixture of the compounds 1 and 11 of the present invention (= a mixture of the present invention) and a composition thereof are preferably used for controlling the following plants and the propagation material (for example, seed) and the harvested products of such plants. a large number of fungal pathogens: crops such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, sorghum, canola, legumes, geranium, coffee or sugar cane; fruit trees, Grape vines and ornamental plants and vegetables such as cucumbers, tomatoes, beans and pumpkins. "plant propagation material" includes all production parts of plants, such as seeds, and vegetatively propagated plant parts, such as seedlings and tubers (eg, potatoes) that can be used to propagate plants. These include seeds, roots, fruits, tubers. , bulbs, rhizomes, buds and other plant parts, including seedlings and seedlings transplanted after germination or after germination of the scorpion. Seedlings can be protected by partial or complete treatment, for example by dipping or watering to resist harmful fungi Treatment of plant propagation material with a mixture of compounds 1 and 11 of the invention (= mixtures of the invention) and compositions thereof for controlling a large number of fungal pathogens in plants such as grasses, such as wheat, rye, barley or Oats, rice, corn, cotton and soybeans. The term crop plants also includes cultivated, mutant-induced or genetically engineered plants, including other plants, including biotechnologies for sale or under development (see for example Http://www.bi〇〇136128.doc • 44 - 200930297 Genetically modified plants are not produced under natural conditions A method of modifying a plant of genetic material by hybridization, mutation, or by natural recombination (ie, genetic information recombination). In general, one or more genes are integrated into the genetic material of the plant to improve plant properties. Genetically engineered modifications include, for example, by glycosylation or by linking a polymer (such as a prenylation, acetamidine or farnesylate group or a PEG* group) to a protein, oligopeptide or polypeptide. Perform post-translational modifications.

By way of example, mention may be made of plants which are tolerant to certain classes of herbicides by cultivation and genetic engineering, such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors, acetamidine lactate synthase ( ALS) inhibitors (such as sulfonylurea (EP-A 257 993, US 5,013, 659) or imidazolinone (for example US 6,222,100 > WO 01/82685, WO

00/26390, WO 97/41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073), Enol-type propyl-based oxalic acid-3-phosphate synthase (EPSPS) inhibitors (such as glyphosate (see for example WO 92/00377)), glutamic acid synthesis (GS) inhibition Agents such as glufosinate (see for example Ep_A 236, EP-A 242 246) or oxynil herbicides (see US 5,559, 〇 24). For example, for imidazoline _ (for example, 〆 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Produce resistance to glyphosate or glufosinate by means of genetic methods'

RoundupReady' resistance to glyphosate, Monsanto, U, S, a, ) and Liberty 136128.doc 45- 200930297

Crop plants (such as soybean, cotton, corn, sugar beet, and canola) obtained from Link (resistance to glufosinate, Bayer CropScience, Germany). Also included are plants which produce one or more toxins (e.g., the toxins of the genus Bacillus) due to genetic engineering. Toxins produced by such genetically modified plants include, for example, Bacillus sp. (especially B. thuringiensis) insecticidal proteins such as endotoxin CrylAb, CrylAC, CrylF, CrylFa2, Cry2Ab, (four) eight ,

Cry3Bbl, Cry9c, Cry34Abl or Cry35Abl; or vegetative insecticidal protein (νιρ), such as VIP1, VIP2, VIp3 or VIp3A; nematode-transplanted bacteria (for example, Phytophthora (ph〇i〇rhabdus spp) or pathogenic genus ( Xenorhabdus spp.)) a pesticidal protein; a toxin of an animal organism, such as a wasp, a spider or a toxin; for example, a mycotoxin from Strept〇 mycetes; for example, a lectin from pea or barley; agglutination Agglutinin; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cysteine trypsin inhibitor or papain inhibitor; ribosome inactivating protein (RIP), such as ricin, corn_Rlp, abrin, loofin ribosome inactivating protein (luffin), saporin (sporin) 4 beryodin; steroid metabolism enzyme For example, 3_ silk steroid oxygen. oxidase, ecdysteroid steroid "DP glycosyltransferase, cholesterol oxidase, ecdysone inhibitor or (Μ: - original enzyme; ion channel blocker, such as sodium channel or calcium Inhibitor of channel; juvenile hormone esterase; diuretic hormone receptor (helicokinin receptor); stilbene synthase, bibenzyl synthase, chitinase and glucanase ( Glucanase). In these plants 136128.doc -46- 200930297, these toxins may also be present as pretoxins, hybrid proteins or truncated or otherwise modified proteins. The characteristics of the hybrid proteins are different. A novel combination of protein domains (see, for example, WO 2002/015701). Other examples of such toxins or genetically modified plants that produce such toxins are disclosed in Ugly-in 374 753, \¥〇93/07278, \¥ 〇95/34656, ugly-A 427 529, EP-A 451 878, WO 03/18810 and WO 03/52073. Methods for producing such genetically modified plants are known to those skilled in the art and It is disclosed, for example, in the publications mentioned above. Many of the toxins mentioned above are given to plants which produce them from all taxonomic arthropods, especially aphids (Coeleropta), Diptera insects (double Diptera (Diptera) and butterfly (Lepidopter) a)) and the tolerance of nematodes (Nematoda). Genetically modified plants that produce one or more genes encoding insecticidal toxins are described, for example, in the publications mentioned above, and Some of these plants are available for 'YieldGard® (corn variety producing toxin CrylAb), YieldGard® Plus (corn variety producing toxin CrylAb and Cry3Bbl), Starlink® (corn variety producing toxin Cry9c), Herculex® RW (Corn varieties producing the toxins Cry34Abl, Cry35Abl and the enzymes phosphinothricin-N-acetyltransferase [PAT]), NuCOTN® 33B (the cotton variety producing the toxin CrylAc), Bollgard® 1 (the cotton producing the toxin Cryl Ac) Variety), Bollgard® 11 (cotton variety producing toxin Cryl Ac and Cry2Ab2), VIPCOT® (cotton variety producing VIP toxin), NewLeaf® (potato variety producing toxin Cry3A), Bt-Xtra®, NatureGard®, KnockOut® , BiteGard®, Protecta®, Btl 1 (eg, Agrisure® CB) and Btl76 (from 136128.doc -47- 200930297

Syngenta Seeds SAS, France) (maize variety producing toxin CrylAb and PAT enzymes), MIR604 (from Syngenta Seeds SAS, France) (a maize variety producing a modified version of the toxin Cry3A, see WO 03/018810), MON 863 (from Monsanto) Europe SA, Belgium), a corn variety that produces the toxin Cry3Bbl, IPC 531 (from Monsanto Europe SA, Belgium) (a cotton variety that produces a modified version of the toxin CrylAc) and 1507 (from Pioneer Overseas Corporation, Belgium) (produces the toxin CrylF and PAT enzyme corn variety). Also included are genetically engineered one or more proteins that are more robust or have increased resistance to bacterial, viral or fungal pathogens (eg, pathologically related proteins (PR protein, see EP-A 0 392 225), resistance proteins ( For example, 'produce two species of horse mash potato against the resistance gene of Phytophthora infestans from the wild species Solanum bulbocastanum) or T4 lysozyme (for example, by producing this protein to resist such as A plant of the potato variety of the bacterium of Erwinia amylvora))). Also included by means of genetic engineering methods, for example by enhancing potential yield (eg, biomass, yield, starch, oil or protein content), tolerance to drought, salt or other limiting environmental factors, or pests Plants with improved resistance to fungal, bacterial and viral pathogens also include plants that have been genetically engineered to modify the composition of the human or animal diet, for example to produce healthy long-chain omega-3 fatty acids or An oil plant of unsaturated omega-9 fatty acids (eg, Nexera® canola, DOW Agro Sciences, Canada). It also includes plants that have been modified to improve the yield of raw materials (eg, key powder content) by means of genetic engineering 136128.doc -48 · 200930297 by adding horses and potatoes, BASF SE, method (Amfl〇ra) ® Germany) °Special σ, the olfactory mixture of the compounds of the invention, and mixtures thereof, are suitable for controlling the following plant diseases:

Ornamental plants, vegetable crops (eg, A. candida) and sunflowers (eg, Brahman's genus (9) (4) (10)))) (Albugo spp.) (white rust) Vegetables, rapeseed (for example, A. brassicola or a brassicae), sugar beet (eg 'A. tenuis'), fruit, Alternada spp. on rice, soybeans, and potatoes (eg, A. solani or A. alternata) and cannabis (eg, 'bottom rot or brown smut'). (black spot disease, black spot) and the genus Bacillus (blackhead) on wheat; Aphanomyces spp. on sugar beet and vegetables; (Asc〇chyta spp.) 'For example, wheat rot (A. tritici) (Ascochyta leaf blight) and barley black rot on barley (Α· hordei) 'flat umbilical hernia Spp) and Drechslera spp. (having a trait: c〇chli〇b〇lus spp.) Leaf spot disease (D. maydis and zeic 〇la), such as wheat grain blight (glume bl〇tch) (wheat root) B. sorokiniana and B. oryZae on rice and grassland; Blumeria graminis on cereals (eg, wheat or barley) (formerly 136128. Doc -49- 200930297 Erysiphe graminis (powdery mildew); Botryosphaeria spp. ('Black Death') (eg, round grapevine) B. obtusa); seedless small fruit and pear fruit (especially strawberry), vegetables (especially lettuce, carrot, celeriac and cabbage), rapeseed, flowers, vines, forest crops and wheat (ear mold) )) Botrytis cinerea (having a sexual state: Botryotinia fuckeliana: gray mold, gray rot); lettuce on the lettuce, Bremia lactucae (Cream) Downy mildew); Ceratocystis spp. on deciduous and coniferous trees ( Ophiostoma spp. (blue stain fungus), such as the stalk of the tree on the tree, C. ulmi (Dutch' elm) Disease)); corn (for example, C. zeae_ maydis), rice, sugar beet (for example, c. beticola), sugar cane, vegetables, coffee beans, soybeans (eg, C. sojina or C. kikuchii) and Cercospora spp. (C. cerevisiae leaf spot); tomato (eg, Xanthomonas oryzae) C. fulvum: tomato leaf mold) and Cladosporium spp. 'for example, c. herbarum (ear rot) on wheat; Ciaviceps purpurea (O. ergot) on corn; corn (for example, c. carbonum), sputum (eg 'C. sativus', asexual state : B. sorokiniana: wheat spot blight) and rice (for example, C. miyabeanus), asexual state: Spirospora Helicobacter pylori on the bacterium (H. oryzae) (non-sexual state: Helminthosporium 136128.doc • 50· 200930297 (Helminthosporium) or Helminthosporium) (cotton leaf spot); cotton (for example, cotton Anthracnose (C. gossypii), corn (eg, c, graminicola: stem rot and anthracn〇sis), seedless small fruit, potato (eg 'potato anthrax (c) · coce〇des): wilt disease) beans (such as 'C. lindemuthianum') and soybeans (such as 'C. truncatum') on Colletotrichum sPP. Behavior: G1〇merella SPP.) (Carassius auratus); Corticium spp., such as C. sasakii on rice (sclerotium); soybean And the mountain on the ornamental plant is Corynespora cassiicola (leaf leaf spot); the genus Cyeloconium spp., such as the oil peacock spot (C oleaginum), fruit trees, vines (for example) , C. liriodendri, has a sexual state: Liriodendron chinense ctHa liriodendri), and the Cylindrocarpon spp. on many ornamental trees (for example, the disease of the fruit tree or the vine of the vine, having a sexual state: Nectria spp. or Neonectria SPP·) Dematophora necatrix (sexual state: Rosellian necatrix) (root/stalk rot); Diaporthe spp.), for example, D phaseol〇rum (stem disease) on soybeans; corn, grain (such as barley (eg, D. teres, net spot disease) And wheat (for example, D. tritici_repentis: DTR leaf spot), rice) and the genus Drechslera spp. (synonym: Helminthosporium, sexual state: Pyrenophora spp.; esca disease on vines (esca 136128.doc -51· 200930297 disease) (vine wilt disease, apoplexia) (Formitiporia punctata) (synonym: Phellinus punctatus), diarrhea (F. mediterranea), Phaeomoniella chlamydospora (formerly known as Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and/or Rhizoctonia solani; E. pyri (E. pyri) and non-nuclear small fruit (E. veneta: anthracnose) and vine (E. amPelina: anthrax) Disease) Elsinoe spp.; Entyloma oryzae on rice (Erythrium oryzae); Epicoccum spp. (blackhead) on wheat; sugar Beets (E. betae), vegetables (eg, E. pisi), such as cucumber species (eg, 'E. cichoracearum') and cabbage species (such as rapeseed (eg, Erysiphe spp. (E. crucifera)); fruit trees, vines, and Euthypa lata on many ornamental trees (cracking pathogens or Shoot blight, asexuality: rotten skin disease (Cytosporina lata), Synonym: Libertella blepharis); Exserohilum spp. on corn (synonymous: Long worm) (eg, E. turcicum); recorded on various plants Fusarium spp. (having a sexual state: Gibberella) (allergic diseases, root and stem rot), such as Fusarium graminearum (F_ graminearum) on booties (eg, wheat or barley) Or F. culmorum (root rot and silver top disease), F. oxysporum on tomato, Fusarium solani on 136128.doc -52- 200930297 (F. S〇lani) and f verticillioides on corn; cereals (eg, wheat or barley) and Gaeumannomyces graminis on corn (whole wheat eclipse); 'G. zeae' and rice (for example, GUberella spp.) on vines, pomegranates and other plants on the genus Ganoderma lucidum (〇. fujikuroi. G1〇merelu cingulata and cotton sclerotium (G_ g〇ssypii) on rice; rice Granstaining complex; Guignardia bidwellii (black rot) on the vine; genus Gymnosporangium spp. on the genus Rosaceae and cypress [eg pear tree on pear) G. sabinae (pear rust); corn, scorpion and Helicobacter spp. on rice (synonymous: inner umbilical creep 'has a sexual state: circumflex bacterium); Hemileia spp.), for example, H vastatrix (coffee leaf rust) on coffee; Isariopsis clavispora on grapevine (synonym: clad〇sp〇rium vitis )); Macr〇ph〇mina phaseolina (synonym: Macr〇ph〇mina phaseoli) (root/stalk rot) on soybeans and cotton; Microdochium nivale (synonymous: Fusarium nivale) (pink snow rot) on wheat or barley; Micr〇sphaera diffnsa (soy powdery mildew) on soybean; Brown rot (M0niiinia spp.), such as stone fruit and other nucleus M. laxa, M. fructicola and M. fructigena (flower and branch blight); grains, bananas, seedless fruits and balls on peanuts Phytophthora 136128.doc •53- 200930297 (Mycosphaerella spp.), such as wheat gram nematode (m gramini C〇la) (asexuality: Septoria tritici, genus Spot disease) or M. fijiensis (banana leaf spot) on bananas, ▲ (for example, seaweed downy mildew (Ρ·brassicae)), rapeseed (for example, parasitic downy mildew (P· Parasitica)), bulbous plants (eg, onion destructor), tobacco (P. tabacina), and soy (eg, P. manshurica) (Peronospora spp.) (downy mildew); Phak〇psora pachyrhizi and P. sylvestris rust (p meib〇miaex soybean rust) on soybeans, such as vines (eg, vine bottles) Mold disease (p. tracheiphila) and P. sphaeroides (p tetrasp〇ra) and soybeans (eg, soy mold (P. g) Regata): Phialophora PP. 'Ph〇ma ungam on rapeseed and cabbage (root and stem rot) and beetle on sugar beet (p Betae) (leaf leaf disease, wide sunflower, vine (for example, 单 vi vi ( : ρ : : : : : ) ) ) ) ) ) ) ) ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( P. phaseoli, a sexual state. Phpm〇psis spp. on the Diap〇rthe phase〇l〇rum; corngrass on corn Physoderma maydis (brown spot disease); Phytophthora spp. (wild wilt, root, leaf, stem and fruit rot) on various plants, such as sweet pepper and cucumber species (eg, pepper plague) P. capsici), large Dan (for example, large and plague megasperma, synonymous: Phytophthora sojae), horse yam and yum (eg, Phytophthora ( Ρ·infestans)··late blight and brown rot) and fall (4) (for example, oak death 136128.doc •54- 200930297 (Ρ·ramorum): eucalyptus dead fungus); Plasmodiophora brassicae (root swollen disease) on rapeseed, radish and other plants; Plasmopara Spp., such as P. viticola on grape vines Rattan downy mildew, downy mildew) and geranium downy mildew (P_halstedii); Rosaceae, hops, pome fruit and non-nuclear small fruit on the stellate sclerotium (p〇d 〇Sphaera Spp.) (powder disease), such as P. leucotricha on apples; Polymyxa spp., such as grains (such as barley and wheat) P. graminis) and sugar beet (p betae) and viral diseases that are transmitted; Pseudocercosporella herpotrichoides on cereals (eg, wheat or barley) (eye-like markings/broken stems, sexuality: Tapesia yallundae); Pseudoperonospora (downy mildew) on various plants, such as cucumber downy mildew (P. cubensis) or hops on cucumber species P. humili ' grape horn spot on vine Pseudo 〇pezicuia tracheiphila (corner leaf coke, asexuality: genus); various plants of the genus Puccinia spp. (rust), such as grains (such as wheat, barley or naked) Wheat rust (Ρ·tritieina) (wheat leaf rust), wheat stripe rust (P. striiformisx yellow rust), p. h〇rdei (barley dwarf rust) or hollyhock stalk P. graminis (black rust) or P. rec〇ndita (rye leaf rust) and asparagus (eg, p. asparagi); Pyrenophora tritici-repentis (non-sexual state: Helminthosporium) (leaf blight) or P. cerevisiae (net spot) on the barley 136128.doc •55· 200930297 (Pyricularia spp.), such as rice cultivar on rice (ρ· 〇ryzae) (having a sexual state, Magnaporthe grisea, rice blast) and rice on grassland and stork P. grisea; grassland, rice, corn, wheat, cotton, canola, sunflower, sugar beet, vegetables and Plant rot, mold (Pythium s. pp.) (Bacterial blight), (for example, cotton rot (p. ultimum) or Pythium aphid (Ρ· aphanidermatum); mul 抱 ( (Ramularia spp. ) 'For example, R c〇n〇-cygni on barley (column and leaf spot/physiological leaf spot) and beet leaf spot on sugar beet (R. beticola); Rhizoctonia spp. on cotton, rice, potato, grassland, corn, canola, potato, sugar beet, vegetables and various other plants, for example, the nucleus of soybean on the soybean R. solani (root and stem rot), Rhizoctonia solani (strain blight) on rice or r' cerealis on wheat or barley (clear ocular pattern (sharp) Eyespot)) Rhizopus stol〇nifer (soft rot) on strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporium secalis on barley, rye and black wheat ( Leaf spot disease; Sarocladium 〇ryzae and Mycobacterium fungus (s , attenuatum ) on rice Rot); Sclerotinia spp. (stalk rot or white rot) on vegetables and field crops, such as rapeseed, geranium (for example, Sclerotinia scier〇ti〇rum) And soybeans (for example, S. cerevisiae (S. rolfsii)); Seponia spp. on various plants, such as s glycines on soybeans (leaf spots) Disease), wheat s. tritici (Saccharomyces cerevisiae leaf spot) and sputum on the sputum (sn〇d〇rum) (synonym: Ying 136128.doc - 56- 200930297 Stagonospora nodorum (leaf leaf spot and wheat spot blotch); Uncinula necator on grapevine (synonym: Erysiphe) (powder disease, no Behavior: oidium tuckeri); corn (for example, S. turcicum, synonymous: Helminthosporium turcicum) and Setosphaeria on the grass Spp.) (leaf leaf spot); corn (for example, S. reiliana: grain smut), millet and sweet Sphacelotheca spp. (smut) on sugarcane; Sphaerotheca fuliginea (powder disease) on cucumber species; Spongospora subterranea (powder on potato) Rickets) and the viral diseases that are transmitted therethrough; Stag0nospora spp., such as S. nodorum on wheat (spotted leaf spot and wheat spot blotch) , sexual status: Leptosphaeria nodorum [synonym: Phaeosphaeria nodorum]; Synchytrium endobioticum (potato cancer disease) on potato; Taphrina spp. ), for example, the ectoparasites def0rmans on the peach (curve leaf disease) and the outer bacillus (t pruni) on the plum; on the grass, kernels, vegetable crops, soybeans and cotton (4) The pearl emblem belongs to SPP.) (black root rot), such as cotton root bacillus (Τ· -α) (synonym: cadmium elegans); smut of smut on grain Etiaspp.) (wheat smut), such as wheat smut (T _ tritici) (synonymous [also

.,, ^ Yi. Wheat candida (T canes), wheat smut smut) and small. C〇ntr〇Versa) (wheat dwarf smut); large ^ * wheat or wheat Wheat snow 136I28.doc •57- 200930297 Typhuia incarnata (grey snow rot); ur0cystis spp., such as rye smut on rye (1) 〇CCUlta) (rod black powder disease); Uromyces SPP. (rust disease) on vegetable plants such as kidney beans (eg, Bean rust (1) appendicuUtus) 'synonym: long bean rust (u phase〇 H)) and sugar beet (for example, sugar beet rust (U_betae)); cockroach (for example, U. nuda and u. avaenae), corn (for example) , U. maydis: corn smut) and Ustilago spp. on sugarcane (i00se sniut); apple (eg 'black worm (V) . inaequalis)) and the genus Venturia spp. (scab) on pears; and various plants (such as fruit trees and ornamental trees, vines, seedless Cladosporium the wheel of fruits, vegetables and field crops) (Verticillium spp.) (Bud and leaf blight), such as Verticillium fungus (V. dahliae) on the strawberries, rape, Ma Qian potato and tomato. Furthermore, 'the mixture of the compound I of the invention and hydrazine (=mixture of the invention) and combinations thereof are suitable for controlling harmful fungi to protect substances and structures (for example 'wood, paper, paint dispersion, fiber or tissue) and to protect storage product. In the protection of wood and construction, pay special attention to the following harmful fungi: Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, and pseudo-stem Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes, Such as Coniophora spp., Coriolus spp., 136128.doc -58- 200930297 Gloeophyllum spp., Lentinus spp., Pleurotus Pleurotus spp., P〇ria spp., Serpula spp., and Tyromyces spp.; deuteromycetes, such as Aspergillus spp. , Penicillium, Penicillium, (PeniciUium spp.), Trichoderma spp., Paecilomyces spp.; and zygomycetes, such as the genus (Mucor) Spp.) 'and in addition, pay special attention to the following yeast fungi in the protection of substances: Candida (Ca Ndida spp.) and Saccharomyces cerevisae (a mixture of the compounds I and II of the present invention (= a mixture of the invention) and compositions thereof are suitable for improving plant health" In addition, the present invention relates to an improved plant health The method 'is carried out by treating a plant, plant propagation material and/or plant growth or intended place of growth with an effective amount of a mixture of the compounds j and II of the present invention (= a mixture of the invention) and a composition thereof. The term ''plant health') includes the state of the plant mash and/or its harvested material as determined by individual or combination of various indicators' such indicators as yield (eg, increased biological quality and/or increased available ingredients). Content), plant vitality - (for example, accelerated plant growth and / or greener leaves (,, green effect ")), quality (for example, increased content or composition of certain ingredients) and Or tolerance to abiotic stresses. The indicators mentioned herein for the state of health of the plants may occur independently of each other or may interact with each other. Compounds I and II may be administered simultaneously (in combination or separately) or continuously, wherein the administration alone In this case, the order generally has no effect on the control results by administering Compound I and Compound Π or Compound 1 and Compound 136128.doc -59- 200930297 mixture by singly or in combination, either before or after plant sowing or after Method of controlling harmful truths is carried out by spraying or sprinkling on seeds, plants or soil before or after germination of plant seeds. Active Compounds 1 and 11 The form of their agriculturally acceptable salts used. These salts are usually an alkali or alkaline earth metal M, such as sodium, potassium or calcium salts, or as described herein for the case of the compound of formula〗 other salts.

By treating a harmful fungus, its habitat or a plant or plant propagation material (eg, seed material), soil, region, substance or space to be protected from fungal attack with a fungicidal effective amount of the compound; as such or in combination The form uses a mixture of the compound and the mixture (= mixture of the invention). It can be applied before or after the fungal infection of the plant, the plant propagation material (for example, the seed material), the soil, the area, the substance or the space. The plant propagation material is prophylactically treated with a mixture of the compounds of the invention (=mixtures of the invention) and combinations thereof during or even prior to sowing or during transplantation or even before transplantation. Furthermore, the invention relates to A solvent or solid carrier and an agrochemical composition of at least one compound I and at least one compound „, and also for the use of such compositions for controlling harmful fungi. Accordingly, the invention also encompasses formulations or agrochemical compositions comprising a solid or liquid carrier and a fungicidal mixture of the invention. In this context, the term "liquid carrier" has the same meaning as "solvent". The agrochemical composition comprises a fungicidally effective amount of a mixture of compounds 1 and 11 (= a mixture of the invention). The term "effective amount" means an agrochemical composition or compound 丨 and π sufficient to control harmful fungi or protective substances and structures on agricultural plants without any significant damage to the treated plant 136128.doc 200930297 The amount of the mixture. The amount can vary over a wide range and is affected by many factors such as the harmful fungi to be controlled, the individual crop plants or materials being treated, climatic conditions and the compound. In a binary mixture (i.e., a composition of the invention comprising Compound I and another active compound (e.g., 'Active Compounds of Groups 2.1 to 2.6), the weight ratio of Compound 1 to another active compound is usually In the range of 1:1 〇〇 to 100:1, usually in the range of 1:50 to 50:1, preferably in the range of ι:2〇 to 2〇:ι®, especially preferably 1: From 1〇 to 10:1, especially in the range of 1:3 to 3:1. If necessary, the other active ingredients are added in a ratio of from 20:1 to 1:20 to the mixture of the compound and the compound. The components of the compositions of the present invention may be packaged and used individually or in the form of a premix or in a kit of parts. In one embodiment of the invention, the kit may comprise one or more and even components that are useful in preparing the agrochemical compositions of the present invention. For example, the kits may comprise one or more fungicidal components and/or adjuvant components - and/or insecticide components and/or growth regulator components and/or herbicides. One or more components may be combined with each other or pre-formulated. In two or more embodiments, the components may be combined with one another and packaged in a single device such as a blood, bottle, can, bag, linen bag or * in other embodiments, Two or more components of the kit may be individually sealed = '. That is, without pre-mixing or mixing. The kit may contain one or more separate containers, such as utensils, bottles, cans, bags, linen bags or canisters, each containing a separate component of the agrochemical composition. The group of wounds of the compositions of the present invention may be packaged and used individually or in the form of a premix or in a kit of parts. The 'components' can be used in either form, either alone or in combination with other components or as part of a partial kit of the invention to prepare a mixture of the invention. The user uses the compositions of the invention typically used in pre-dosing devices (kapped sprayers, spray boxes or sprayers). Here, the agrochemical composition is diluted with water and/or a buffer to the desired application concentration, and if appropriate, other additives are added to produce a ready-to-use spray liquid or an agricultural chemical composition of the present invention. Typically, 50 to 500 liters of ready-to-use spray liquid is applied per hectare of agricultural area, preferably 100 to 4 inches. According to an embodiment, the user himself may mix individual group injuries (such as a 'set of parts) or two or three-component mixtures of the composition of the invention in a spray bowl and, if appropriate, add other auxiliaries ( Bucket mix). In another embodiment, 'the user can combine the individual components of the composition of the invention with a portion of the pre-mixed component (eg, a component comprising a compound and/or an active compound from Group 2. to 2.6) Mix in a spray box and, if appropriate, add other auxiliaries (tank mix). In another embodiment, the user may combine (eg, in the form of a tank mix) or continuously use the individual components of the compositions of the present invention with a portion of the pre-mixed group & (eg, 'comprising a compound and/or from Both of the components of the active compound of the group 2) are both. When the field is used for crop protection, depending on the type of compound and the desired effect, the application amount of the mixture of the present invention is 1 to 2 kg per hectare (ha) of the active compound, and preferably per hectare. 〇$ to 2 kg of active compound mixture, 136128.doc «62- 200930297 Especially preferably 0.05 to 0.9 kg of active compound mixture per hectare, especially 0.1 to 0.75 kg of active compound mixture per hectare. Accordingly, the application rate of the compound is generally from 1 to 1 〇 00 g/ha, preferably from 1 〇〇 to 9 〇〇 g/ha, especially from 2 〇 to 750 g/ha. Accordingly, the application amount of the active compound π is generally from 1 to 2 〇〇 0 g/ha', preferably from 1 〇 to 9 〇〇 g/ha, especially from 40 to 500 g/ha. In the treatment of plant propagation material (for example, seeds), the amount of active compound mixture used is generally from 1" to 1000 g per 1 kg of propagation material or seed, preferably from 1 to 1 per 100 kg of propagation material or seed. g, particularly preferably 1 to 1 g per 1 kg of propagation material or seed, especially 5 to 1 g per 1 kg of propagation material or seed. When applied to the protection of a substance or stored product, the amount of active compound applied will depend on the type of application area and the desired effect. The usual application rate in the substance protection is, for example, from 0.001 g to 2 kg, preferably from 0 005 g to 1 kg, of the active compound per cubic meter of the treatment substance. The mixtures of the invention or the compounds I and II of the compounds I and II and their N-oxides and salts and their respective N-oxides and salts can be converted into the common types of agrochemical compositions such as solutions, emulsions, suspensions Liquid, powder, powder, liquid and granules. The type of composition will depend on the individual purpose desired; in each case' should ensure that the compounds of the invention are finely and uniformly distributed. In this context, the term "formulation" has the same meaning as "composition,, in particular, agrochemical composition" &"mixture". Here, an example of a composition type is a suspension. (sc, 〇d, FS), serum, tablets, wettable powders or powders (WP, sp, SS, WS, DP, DS) or particles soluble in water or dispersed in water (wettable) (GR , FG, 136128.doc -63 · 200930297 GG, MG) and gelling agent (GF) for the treatment of plant propagation material (such as seeds). Generally, 'composition type (eg, SC, OD, FS, WG, SG, WP, SP, SS, WS, GF) are used in diluted form. Composition types such as DP, DS, GR, FG, GG and MG are generally used in undiluted form. Compounds I and II may be present in the combination. In the composition or in a separate composition, the type and preparation of the individual compositions herein corresponds to the type and preparation as described herein for the composition in a general manner. Agrochemical compositions are prepared in a known manner (see for example us) 3,060,084, EP-A 707 445 (for liquid concentrates), Browning, "Agglomeration", Chemical Engineering, December 4, 1967, 147-48, Perry's Chemical Engineer's Handbook, 4th edition, McGraw-Hill, New York, 1963, 8-57 and later, WO 91/13546, US 4, 172,714, US 4,144,050, US 3,920,442, US 5,180,587 > US 5,232,701 ' US 5,208,030 'GB 2,095,558 ' US 3,299,566 'Klingman: Weed Control as a Science (John Wiley & Sons, New York, 1961), Hance et al. Weed Control Handbook (8th Edition, Blackwell Scientific Publications, Oxford, 1989) and Mollet, H. and Grubemann, A.:

Formulation Technology (Wiley VCH Verlag, Weinheim, 2001)) In addition, agrochemical compositions may also contain adjuvants commonly used in crop protection compositions, depending on the form of use or active compound 136128.doc - 64- 200930297 Depends on the property. Suitable additives 杳 · / I 1 j < Examples are solvents, weekly, other solubilizers, carrier agents, surfactants (all and inorganic agents and tackifiers, organic agents and adhesives (10), for example, The suitable solvent for treating seed bn (if appropriate) is water, organic solvent (such as mineral oil fraction (such as 烊" has medium to...

Animal-derived oils, fats:: in addition to coal tars) and plants or sputum, hospital Ahuacai; ^ family smoke (for example, stone butterfly, tetrahydrocin and its derivatives, alkylated benzene and its derivatives), alcohol (Banban, propanol, butanol and cyclohexanol), diols, ketones (hexanone γ butyl vinegar), dimercapto fatty amines, fatty acids and fatty acid vinegars and strong polar solvents (eg Amines, such as oxime-methylpyrrolidone, in principle, it is also possible to use solvent mixtures and mixtures of solvents and water mentioned above. Solid carriers are mineral soils (such as citric acid, yttrium, citrate, talc). , Shangling soil, limestone, lime, chalk, red basalt, loess, clay, dolomite, diatomaceous earth, calcium sulfate and magnesium sulfate, magnesium oxide), ground synthetic materials, fertilizers (such as ammonium sulfate, phosphoric acid) Ammonium, ammonium nitrate, urea) and plant products (such as glutinous rice flour, bark flour, wood flour and nut shell powder), cellulose powder or other solid carrier. Suitable surfactants (adjuvant, wetting agent, viscosity-increasing) Agent, dispersant or emulsifier) is an aromatic acid ( For example, wood acid (Borresperse® type, Borregaard, Norway), benzoic acid, naphthalene acid (Morwet® type, Akzo Nobel, USA) and dibutyl naphthalene sulfonic acid (Nekal® type, BASF, 136128.doc -65- 200930297

Germany)) and alkali metal salts, alkaline earth metal salts and ammonium salts of fatty acids, alkyl and alkyl aryl sulfonates, alkyl ethers, lauryl ethers and fatty alcohol sulfates, and sulfated hexanol, heptanol and ten a salt of octaol and a fatty alcohol glycol ether, a condensate of a sulfonated naphthalene and a derivative thereof with furfural, a condensate of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, a polyoxyethyl octylphenol ether, and a Oxylated iso-octylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ether, • tributylphenyl polyglycol ether, alkyl aryl polyether alcohol, isotrix Alcohol, fatty alcohol/ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene ethyl decyl ether or polyoxypropyl propyl ether, lauryl polyethylene glycol ether acetate, sorbose Alcohol esters, lignosulfite waste liquids and proteins, denatured proteins, polysaccharides (eg, mercapto cellulose), hydrophobic modified starch, polyethylene glycol (Mowiol® type, Clariant, Switzerland), poly Slow acid vinegar (Sokalan® type, BASF, Germany), polyoxyalkylate, polyvinylamine (Lupamin® Type, BASF, Germany), polyethyleneimine (Lupasol® type, BASF, Germany), polyethylene 11 acetonone and its copolymer. Examples of thickeners (i.e., compounds which impart improved flow properties to the composition (i.e., high viscosity at rest and low viscosity during exercise) are polysaccharides and organic and inorganic layered structural minerals such as Sanxianjiao ( Kelzan®, CP 1 Kelco, USA), Rhodopol® 23 (Rhodia, France) or Veegum® (RT Vanderbilt, USA) or Attaclay® (Engelhard Corp., NJ, USA). A bactericide can be added to stabilize the composition. Examples of bactericides are bactericides based on diclolophen and benzyl alcohol 136128.doc -66-200930297 hemiformal (Proxel® from iCI or Acticide® RS from Thor Chemie and from Rohm & Kathon® MK from Haas) and isothiazolinone derivatives such as alkylisothiazolinone and benzoisosinone (from Acticide® MBS from Thor Chemie). Examples of suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin. Examples of defoamers are polyoxyl emulsions (such as Silik〇n®. SRE (Wacker, Germany) or Rhodorsil® (Rhodia, France)), long-chain leaven, fatty acids, fatty acid salts, organofluorine compounds and mixtures thereof . Examples of colorants are small amounts of water soluble pigments and water soluble dyes. Examples which may be mentioned are dyes and pigments known under the following names: Rhodamine B, CI Pigment Red 112 and CI Solvent Red 1, Pigment Blue 15:4, Pigment Blue 15:3, Pigment Blue 15:2, Pigment Blue 15:1, Pigment Blue 8〇, Pigment Yellow 1, Pigment Yellow 13, Pigment Red 48:2, Pigment Red 48:1, Pigment Red 57:1, Pigment Red 53:1, Pigment Orange 43 , Pigment Orange 34, Pigment Orange 5, Pigment Green 36, Pigment Green 7, Pigment White 6, Pigment Brown 25, Alkaline Violet 1 碱性, Alkaline φ Violet 49, Acid Red 5 1, Acid Red 52, Acid Red 14, Acid blue 9, acid yellow 23, alkaline red 1 碱性, alkaline red 丨〇 8. • Examples of adhesives are polyvinylpyrrolidine _, polyvinyl acetate, polyethylene glycol and cellulose ether (Tyl〇se®, Shin-Etsu, japan) 〇' Suitable for the preparation of direct spray solutions, emulsions, slurries Or oily dispersions are medium to high boiling mineral oil fractions (such as kerosene or diesel, in addition to coal tar) and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons (eg, toluene, xylene, Paraffin, tetrahydronaphthalene, alkylated naphthalene or its derivatives: sterol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophoric 136128.doc •67· 200930297 Erming, strong polarity Solvent (for example, dimethyl sulfoxide, N-methylpyrrolidine remaining or water). The I agent, the substance (4), and the dispersible product can be prepared by mixing or co-milling the compounds I and II and, if present, other active compounds with at least one solid carrier. Granules such as coated granules, impregnated granules and homogeneous granules can be prepared by combining the active compound or mixture of active compounds with at least one solid carrier. Examples of solid carriers are: mineral soils such as cerium oxide gel, strontium silicate, talc, kaolin, American activated clay, limestone, lime, chalk, red basalt, loess, clay, dolomite, diatomaceous earth, Calcium sulfate, magnesium sulfate, magnesium oxide; ground synthetic materials; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea; and plant-derived products such as cereal flour, bark flour, wood flour and nut shell powder; Powder and other solid carriers. The following are examples of the type of composition: 1. Composition type diluted with water 0 Water-soluble concentrate (SL, LS) 1 part by weight of the active compound or active compound mixture with 90 parts by weight of water or water-soluble solvent Dissolved. Alternatively, add a wetting agent or other auxiliaries. The active compound is diluted with water and dissolved. This resulted in a composition having an active compound content of 10% by weight. Ii) Dispersible Concentrate (DC) By adding 10 parts by weight of a dispersing agent (for example, polyvinylpyrrole bitumen), 20 parts by weight of the active compound or active compound mixture is dissolved in 7 〇 by weight I36128.doc -68 - 200930297 part of the ring brewed i. Diluted with water to produce a dispersion. The active compound content is 20% by weight β Π ) emulsifiable concentrate (EC) by adding calcium dodecylbenzene sulfonate and castor oil ethoxylate (5 parts by weight in each case), 15 weight The active compound or active compound mixture is dissolved in 75 parts by weight of xylene. Dilute with water to produce an emulsion. • The composition has an active compound content of 15% by weight. Iv) Emulsion (EW, EO, ES) 25 25 parts by weight of active compound or active compound by addition of calcium dodecylbenzene sulfonate and sesame oil ethoxylate (5 parts by weight in each case) The mixture was dissolved in 35 parts by weight of diphenylbenzene. This mixture was added to 30 parts by weight of water by means of an emulsifier (e.g., 'Ultraturrax') and allowed to form a homogeneous emulsion. Dilute with water to produce an emulsion. The composition has an active compound content of 25 wt%. v) suspension (SC, OD, FS) φ 20 parts by weight of active compound or live in a stirred ball mill with the addition of 10 parts by weight of dispersant and wetting agent and 7 parts by weight of water or organic solvent - Sex compound mixture is comminuted to produce a fine active compound suspension. Dilution with water produces a stable suspension of the active compound. The active compound content in the composition was 20% by weight. Vi) water-dispersible granules and water-soluble granules (WG, SG) by means of technical equipment (for example, extruder, spray tower, fluidized bed), with the addition of 50 parts by weight of dispersant and wetting agent, 5 〇 The parts by weight of the active compound or active compound mixture are finely ground and made into water-dispersible or water 136128.doc • 69- 200930297 soluble particles. Dilution with water produces a stable dispersion or solution of the active compound. The composition has an active compound content of 50% by weight. VII) Water-dispersible powders and water-soluble powders (WP, SP, SS, WS) 75 parts by weight of active compound or active compound are milled in a rotor-stator mill by adding 25 parts by weight of dispersant, wetting agent and silicone rubber mixture. Dilution with water produces a stable dispersion or solution of the active compound. The composition has an active compound content of 75 wtm/〇. Viii) Gel (GF) ❹ 20 parts by weight of active compound or active compound mixture, 1 part by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or organic solvent are ground in a ball mill to produce fine suspension liquid. Dilution with water yielded a stable suspension having an active compound content of 2% by weight. 2. Type of composition to be applied without unreleased ix) Powder (DP, DS) 5 parts by weight of the active compound or active compound mixture are finely ground, H and thoroughly mixed with 95 parts by weight of finely powdered kaolin. This produces a sprinkable product having a content of 5% by weight of active compound. X) Granules (GR, FG, GG, MG) 1 5 parts by weight of the active compound or active compound mixture are finely ground and combined with 99.5 parts by weight of a carrier. Current methods are extrusion, spray drying or fluidized beds. This resulted in particles intended to be applied undiluted with a content of active compound of 0.5% by weight. Xi) ULV solution (UL) Dissolve 1 part by weight of the active compound or active compound present in 9 〇 weight θ 136128.doc -70 · 200930297 parts of organic solvent (eg diterpene benzene). This produces a composition intended to be applied undiluted with a content of 5% by weight of active compound. In general, the composition of the mixture of the invention comprises from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the compound I and II. Preferably, the compound and II are from 90% to 1% by weight, preferably 95% to 100% purity.水溶性 Water Soluble Concentrate (LS), Suspension (FS), Powder (DS), Water Dispersible and Water Soluble Powder (WS, SS), Emulsion (ES), Emulsifying Concentrate (EC) and Gel (GF) ) is commonly used to treat plant propagation material, especially seeds. These compositions can be applied to the propagation material, especially the seed, in undiluted or preferably diluted form. In this case, the corresponding composition can be diluted 2 to 1 times, so that the composition used for seed dressing has a weight of from 0 01 to 60% by weight, preferably 〇丨. /〇 active compound. Application can be carried out before or during sowing. The treatment of plant propagation material, especially the treatment of seeds, is known to those skilled in the art and is carried out by coating, coating, granulating, impregnating or soaking plant propagation material, preferably by granulation, coating Cloth and spreading or by furrow treatment to, for example, prevent premature germination of the seeds. = For seed treatment, it is preferred to make (iv) float. Such compositions typically comprise, per liter of active compound per liter of § surfactant, per liter of § to 防 anti-bed agent, up to 4 gram of binder per liter of enamel, 0 to 200 g of colorant per solvent and solvent (preferably water). The active compound or the active compound mixture may be sprayed as it is, or in the form of a composition thereof, a spray, a liquid, a dispersion, a dispersion, a slurry, a spreadable product, a spray of a dispersing substance, or a spray of a substance. Atomization, spreading, spreading, squirting, impregnation or pouring 136128.doc •71 200930297 J. The type of composition used depends entirely on the intended purpose. The active compound of the invention is most likely to be finely distributed under all conditions. The present invention can be used to prepare an aqueous use form by adding water from the emulsion phase, the slurry cutting stray =,: dispersion. For the preparation of emulsion, liquid or oily knife solution, it can be aided by a wetting agent, a viscosity increasing agent and a dispersing agent. Or the sputum agent is used to "water" the substance as it is or dissolved in oil or solvent. Or 'may be prepared from active substances, wetting agents, tackifiers, dispersants or

A concentrate of a chemical and, where appropriate, a solvent or oil, and such concentrates are suitable for dilution with water. The degree of activity (four degrees) in the ready-to-use preparations can vary over a relatively wide range. In general, it is 0.0001 to 1%, preferably 〇1 to. The active compounds can also be used successfully in ultra low volume (ULV) processes, whereby it is possible to apply a formulation comprising more than 95% by weight of active compound or even to apply an active compound without additives. Various types of oils, wetting agents, adjuvants, herbicides, bactericides, other fungicides and/or other insecticides, fungicides may be added to the active compound or mixture of active compounds or compositions thereof, if It is also suitable to be added immediately before use (mixed preparation). These compositions may be added to the compositions of the present invention in a weight ratio of from 1:1 Torr to 100 Torr, preferably from 1:10 to 10:1. The following materials are particularly suitable as adjuvants in this context: organically modified polycondensation Alkanes such as Break Thru S 240®; alcohol alkoxylates, for example

Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30® ; EO-PO segmentation polymers, eg piur〇nic rpe 136128.doc -72- 200930297 2035® and Genap〇1 B®; alcohol B Oxylates, such as Lutens〇i χρ ' and the sulphonic acid, a sinner, such as Leophen RA®. The invention also comprises a mixture of component 1 (compound of formula I) with one or more other active compounds (for example, herbicides, insecticides, growth regulators or fertilizers) as a premix or, if appropriate, It is added immediately before use (barrel formulation), wherein such active compounds can be used in place of or in addition to compound ι (Component 2). 0

When Compound I or a mixture of Compound 1 and hydrazine or a composition comprising the same is mixed with one or more other active compounds, it is possible, for example, to broaden the range of activity or prevent the development of resistance under various conditions. Synergistic effects are obtained in a variety of situations. This also applies to mixtures of the individual compounds I with one or more other active compounds. The preparation of such compositions of the mixture of the living compounds is carried out in a known manner, for example, in the form of a composition according to a mixture of the compound and the compound, in the presence of a solvent or solid in addition to the active compound. Compositions of the compositions. With regard to the usual ingredients of such compositions, reference is made to the compositions described for the compositions comprising the compounds I and π. The compositions of the active compound mixtures are suitable as fungicides for the control of harmful fungi, and Characterized by the excellent activity against a wide range of phytopathogenic fungi as described for the inventive mixtures of Compound 1 and Compound π. The following list of other active compounds which may be administered with the mixtures of the invention or compositions thereof is intended Explain the possible combinations without any restrictions: Α) Growth regulator 136128.doc -73. 200930297 Abscisic acid, amidochlor, ancymidol, 6-mercaptoamine 6-benzylaminopurine, brassinolide, butralin, chlorme Quat) (chlormequat chloride), choline chloride, cyclanilide, daminozide, dikegulac, dimethipin , 2,6-dimethylpuridine, ethephon, flumetralin, flurprimidol, fluthiacet, Gas 0 for urea (forchlorfenuron), gibberellic acid, inabenfid, 0 bowa-3-acetic acid, maleic hydrazide, mefluidide, Mepiquat (gasified strong cotton), meconazole, naphthalene acetic acid, N-6-benzyladenine, multi-effect Sitting, prohexadione (protonated acid - mother), jasmonone (Pr〇hydrojasmon), thidiazuron, triapenthenol, trithiocyanate (tributyl phosphorotrithioate) ), 2,3,5-trie-benzoic acid, trinexapac-ethyl and uniconazole; B) herbicide-acetamide: acetochlor Acetochlor), alachlor, butachlor, dimethachlor, dimethenamid, flufenacet, mefenacet, Metochlor, n metazachlor, napropamide, naphthylamine 136128.doc -74- 200930297 (naproanilide), pethoxamid, propionamide Pretilachlor), propachlor, thenylamine; - amino acid analogues: bianafos, glyphosate, glufosinate, sulfosate; Oxyphenoxypropionate: clodinafop, cyhalofop-butyl, fenoxaprop, fluazifop, haloxyfop, um Sitting on miamifop, propaquizafop, quizalofop, quizalofop-p-tefuryl; - combination ratio: diquat, paraquat ( Paraquat); -carbamate and thioamino phthalate: asulam, butabut, carb Etamide), desmedipham, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, beetine (phenmedipham), prosulfocarb, pyributicarb, thiobencarb, triallate; • cyclohexanedione: butyl benzoate _ (butroxydim), clethodid (clethodim) ), cyclooxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim; dinitroaniline: benfluralin , etalfluralin, oryzalin, pendimethalin 136128.doc -75- 200930297 (pendimethalin), prodiamine, trifluralin; diphenyl ether : acifluorfen, aclofenfen, bifenox, diclofop, ethoxyfen, fomesafen, milk Lactofen, oxyfluorfen; benzobenzonitrile: bromoxynil, Bromoxynil (dichlobenil), moth benzonitrile (ioxynil);

-w米嗤琳晒: p rice grass S (imazamethabenz), methoxymethane (imazamox), methyl w rice imazapic, imazapyr, imazaquin, u Imazethapyr; - phenoxyacetic acid: valeric acid (〇1〇11]^1*〇?), 2,4-dichlorophenoxyacetic acid (2,4-D) ), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB, mecoprop; -0 call: chloridazone, fluoxazine Flufenpyr ethyl, fluthiacet, norflurazone, pyridate; -0 ratio bite: chloramine-based ratio aminopyralid, gram Clopyralid, ° diflufenican, dithiopyr, fluridone, fluroxypyr, amine gas 0 to 0 picoram, I 0 is picolinafen, thiazopyr; 136I28.doc -76- 200930297 - continued parotid gland: amidosulfuron, azimsulfuron, bensulfuron ( Bensulfuron), chlorimuron On-ethyl), chlorsulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flupiron (flucetosulfuron), flupyrsulfuron, foramsulfuron, gas "halosulfuron, oxazolidine 0, imazosulfuron, moth sequel (iodosulfuron) ), mesosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron, trifluoropropanol Prosulfuron), 0 than pyrazosulfuron, rimsulfuron, sulfometuron, continuation, sulfosulfuron, thifensulfuron, triasulfuron ), tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1-((2-chloro-6-propylimidazolium) [l,2-b]pyridazin-3-yl)sulfonyl)-3-(4,6-diindole) Azinyl-β-yl) gland, -triazine: ametryn, atrazine, cyanazine, dimethametryn, thiazinone , hexazinone, metamitron, metribuzin, prometryn, simazine, terbuthylazine, chlorpyrifos Terbutryn), triterpenoid 136128.doc -77- 200930297 (triaziflam); - urea: chlorotoluron, daimuron, diuron, fluometuron, Isoproturon, lisuron, methabenzthiazuron, tebuthiuron; - other inhibitors of acetaminolate lactase: bispyribac-sodium , cloransulam-methyl, diclosulam, florasulam, flucarbazone, flumetsulam, succulent Metolamam, ortho-sulfamuron, penoxsulam, propoxol Ycarbazone), pyribambenz-propyl, pyribenzoxim, pyrifalid, pyriminobac-methyl, pyrimisulfan, sulphur _ (pyrithiobac), pyroxasulfone, pyroxsulam; - others: amine amicarbazone, aminotriazole, anilofos, aerated Beflubutamid, benazolin, bencarbazone, benfluresate, n-benzofenap, bentazone, benzodiazepine (benzobicyclon), bromocil, bromobutide, butafenacil, butamifos, cavenstrole, carfentrazone , 0 bow 丨 keid vinegar (cinidon-ethyl), diquat 136128.doc -78- 200930297 (chlorthal), ginniethylin, clomazone, cunyluron ), cyprosulfamide, dianlba, benzophenone, flupyridin Diflufenzopyr, Drec/zWeror mowocerai, endothal, ethofumesate, etiobenzanid, tetradecylbenzamide Fentrazamide), fiumiclorac-pentyl, flumioxazin, flupoxam, fluorochloridone, flurtamone, valerone (indanofan) ), isoxaxamine, isoxaflutole, lenacil, propanil, propyzamide, quinclorac , quinmerac, mesotrione, methylarsenic acid, naptalam, oxadiargyl, oxadiazon, oxazine Oxaziclomefone, pentoxazone, pinoxaden, pyraclonil, pyraflufen-ethyl, pyraulfotol, Grassy (pyrazoxyfen), pyrazolynate, quinoclamine, saflufen (sa Flufenacil), sulcotrion, sulfentrazone, terbacil, tefuryltrione, tembotrione, thiencarbazone, special Topramezone, 4-carbyl-3-[2-(2-methoxyethoxymethyl)-6-trifluoromethylacridin-3-carbonyl]bicyclo 136128.doc -79- 200930297 [3.2.1] Oct-3-en-2-one, (3-[2- gas-4-fluoro-5-(3-methyl-2,6-di- oxy-4-trifluoromethyl) Ethyl-3,6-dihydro-2H-pyrimidin-1-yl)phenoxy]"pyridin-2-yloxy)acetate, 6-amino-5-a-2-cyclopropylpyrimidine -4-carboxylate, 6-gas-3-(2-cyclopropyl-6-mercaptophenoxy)pyridazin-4-ol, 4-amino-3-gas-6-(4-gas Phenyl)-5-fluoropyridine-2-carboxylic acid, 4-amino-3-chloro-6-(4-gas-2.fluoro-3-methoxyphenyl)pyridine-2-furic acid methyl ester and Methyl 4-amino-3-gas-6-(4-carb-3-dimethylamino-2-fluorophenyl)pyridine-2-carboxylate; C) insecticide

-Organic (thio) disc salts: acephate, methyl beta than azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, Chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, chlorpyrifos (fenitrothion), fenthion, isoxathion, malathion, methamidophos, methidathion, methyl-parathion ), mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone ), phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prosulfine ( Prothiofos), sulprophos, insecticide 136128.doc •80 200930297 (tetrachlorvinphos), terfufos (tribuphos), triazophos, trichlorfon; - amino phthalate: alanycarb, aldicarb, antibiotics ( Bendiocarb), benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, and chlorfenapyr (furathiocarb) Methiocarb), methodomyl, oxamyl, pirimicarb, propoxur, thiodicarb, triazamate; pyrethroid (pyrethroid): pyrethroid (allethrin), bifenthrin, cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, a-gas Cypermethrin, beta-cypermethrin, guanidine-cyanidin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, Ipprothrin, lambda-cylon Halothrin), permethrin, prallethrin, pyrethrin I and pyrethrin II, resmethrin, sirafu Silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, trolomethrin, transfluthrin, fenvalerate Profluthrin, dimefluthrin; 136128.doc -81 - 200930297

- Insect growth inhibitors: a) Chitin synthesis inhibitors: benzalkonium urea: chlorfluazuron, cyromazine, diflubenzuron, flucycloxuron, flufen Flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron, buprofezin, diefenolan ), 嗔瞒_ (hexythiazox), etoxazole, clofentazin; b) ecdysone antagonist: halofenozide, methoxyfenozide, Tebufenozide, azadirachtin; c) juvenile hormone analogues · pyriproxyfen, metopor, fenoxycarb; d) lipid biosynthesis inhibition Agent: spirodiclofen, spiromesifen, spirotetramate *» - final receptor agonist/antagonist: clothianidin, flubendiamide (dinotefuran), imidacloprid, thiamethoxam Nitenpyram, acetamiprid, thiacloprid, 1-(2-chlorosindol-5-ylmethyl)-2-nitroimido-3, 5-dimercapto-[1,3,5]triazine; -GAB A antagonist: endosulfan, ethiprol, fipronil (f*ipronil), vaniliprol ), pyrafluprol, pyriprol, 5-amino-1-(2,6-dioxa-4-mercaptophenyl)-4-amine sulfinyl-1H- Pyrazole-3-thiocartoamine; 136128.doc -82 - 200930297 - Macrocyclic vinegar: abamectin, due to extinction; emamectin, milbemectin, leipi T, lepimectin, spinosad, spinetoram; - mitochondrial electron transport chain inhibitor (METI) I acaricide: quinazaquin, pyridaben π, bu 瞒 te (tebufenpyrad), η 醢 醢 醢 to (tolfenpyrad), flufenerim (flufenerim); -METI II and III substances: sub-Squine (acequinocyl), flucyprim (fluacyprim), moth Hydr (hydramethylnon); - uncoupling agent: chlorfenapyr; - oxidative acid Inhibitors: cyhexatin, diafenthiuron, fenbutatin oxide, propargite; - insect molting inhibitor: cryomazine; - mixed functional oxidation Enzyme inhibitor: piperonyl butoxide; - sodium channel blocker: indoxacarb, metaflumizone; - others: benbenzi (benclothiaz), bifenazate (bifenazate), kill Cartap, flonicamid, pyridalyl, pymetrozine, sulfur, thiocyclam, flubendiamid, chloramphenicol (chlorantraniliprol), cyazypyr (HGW86); cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet, metre Kefen 136128.doc -83 - 200930297 (imicyafos), bistrifluron and "pyrfluquinazon"

The active compounds mentioned above as possible substitutes or other components, their preparation and their action against harmful fungi are known (see: http://www.hcIrss.demonxo.ukAmdex.html; http:/ /www.alanwood.net/pesticides/); It is commercially available. Compounds named according to IUPAC, their preparation and their fungicidal action are also known (see Can. J. Plant Sci. 48(6), 587-94, 1968; EP-A 141 317; EP-A 152 03 1; EP-A 243 970; EP-A 256 503; EP-A 428 941; EP-A 532 022; EP-A 1 028 125; EP-A 1 035 122; EP-A 1 201 648 EP-A 1 122 244 ; JP 2002316902 ; DE 19650197 ; DE

10021412; DE 102005009458; US 3,296,272; US 3,325,503; WO 98/46608; WO 99/14187; WO 99/24413; WO 99/27783; WO 00/29404; WO 00/46148;

00/65913; WO 01/54501; WO 01/56358; WO 02/22583; WO 02/40431; WO 03/10149; WO 03/11853;

03/14103; WO 03/16286; WO 03/53145; WO 03/61388; WO 03/66609; WO 03/74491; WO 04/49804;

WO 05/123689; WO 05/123690; WO 05/63721; WO 05/87772; WO 05/87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; 07/90624) ° in a ternary mixture (ie containing active compound I and the first other active compound and a second other active compound (eg from group 2.1 to 2.6 or 136128.doc -84 to 200930297 A to C) In the composition of the invention of the two different active compounds), the weight ratio of the compound I to the first other active compound depends on the nature of the individual active compound; it preferably ranges from 1:50 to 50:1. Inside and especially in the range of 1:10 to 10:1. The weight of the compound I and the second other active compound is preferably in the range of from 1:50 to 50:1, especially in the range of from 1:10 to 10:1. The weight of the first other active compound and the second other active compound is preferably in the range of 1:50 to 50:1, especially in the range of 1·10 to 10:1. Preferred are the compositions listed in the Table, wherein one of the labels corresponds to a compound comprising Formula I (Component 1) (which is preferably one of the preferred compounds described herein) and is discussed under various conditions. The fungicidal composition of component 2 given in the column. In accordance with an embodiment of the present invention, component 1 of each column of Table 2 is, in each case, one of the compounds of Formula I detailed in Tables 1 through 13, preferably in Tables 1 through 7. Table

Line component 1 Component 2 Β-1 Compound of formula I plus Pauline-2 Compound of formula I plus Baofu-3 Formula I compound butyl plus Baofu-4 Formula I compound for killing insects, thiodicarb Β-5 Compound of formula I, bifenin Β-6, compound of formula I, sylvesine -7, compound of formula I, cypermethrin Β-8, compound of formula I, alpha-cypermethrin Β-9, compound of formula I, cypromethrin Β-10, compound of formula I Detamethrin Β-11 Compound of formula I esfenvalerate Β-12 Compound of formula I λ-赛洛宁Β-13 Compound of formula I 百灭宁Β-14 Formula I compound cyhalothrin Β 15 Compound I of the formula II Fufulong 136128.doc -85- 200930297 Row component 1 Component 2 B-16 Compound of formula I Flufuron B-17 Compound of formula I Ruffolon B-18 Formula I compound Pestido B- 19 Compound of formula I Spirotetraethyl ester B-20 Compound of formula I Cotinine B-21 Compound of formula I dinotefuran B-22 Compound of formula I edamine B-23 Compound of formula I thiamethoxam B-24 Compound of formula I Sub-cure B-25 Formula I Compound Fructus B-26 Formula I Compound Endosulfan B-27 Formula I Compound Fipronil B-28 Formula I Compound Abatatin B-29 Compound of Formula I Inhibitor B-30 Formula I Compound Benedict B-31 Formula I Compound Spintom B-32 Formula I Compound Voltam B-33 Formula I Compound Insectonitrile B-34 Formula I Compound Butyltin B -35 Formula I Compound Indoxacarb B-36 Formula I Compound American B-37 Formula I Compound Flunidamine B-38 Formula I Compound Flufenidin B-39 Formula I Compound Insectamine B-40 Compound ISapi (HGW86) B-41 Compound I of the formula I tiflumemide B-42 Compound I of the formula I acetochlor B-43 Compound of the formula I dimethenamid B-44 Compound of the formula I is metolachlor B-45 Compound of formula I pyridoxamine B-46 compound of formula I glyphosate B-47 compound of formula I glufosinate B-48 compound of formula I glufosinate B-49 compound of formula I cyanobacteria B-50 compound of formula I Herbicide B-51 Formula I Compound Volt B-52 Formula I Compound Azine Fluorine B-53 Formula I Compound Paraquat B-54 Formula I Compound Beet Ning B-55 Formula I Compound Isooxanes B-56 Formula I Compound Cycloheximide B-57 Formula I Compound Cyclopentanone B-58 Compound I chlorpyrifos 136128.doc -86- 200930297 Row component 1 Component 2 B-59 Compound of formula I is herbicide B-60 I Compound diquinonerin B-61 Formula I compound aniline B-62 Formula I compound trifluralin B-63 Formula I compound acifluorfen B-64 Formula I compound bromoxynil B-65 Compound I Herbyl ester B-66 Compound I of the formula I oxime B-67 Formula I compound 曱 imipenem B-68 Formula I compound oxaloin B-69 Formula I compound chlorpyrifos B-70 Formula I compound Tobacco B-71 Compound of formula I 2,4-diphenophenoxyacetic acid (2,4-D) B-72 Compound of formula I, rudine ketone B-73 Compound of formula I, ketonelite B-74 Compound of formula I Grass tobacco B-75 Formula I compound amine gas pyridine acid B-76 Formula I compound fluorine 0 oxalic acid B-77 Formula I compound bensulfuron-methyl B-78 Compound I compound sulfometuron B-79 Compound ring of formula I Prosulfuron-B-80 Compound I Iodosulfuron-B-81 Compound of formula I Sulfonamide B-82 Compound of formula I Sulfonolone B-83 Compound of formula I Nicosulfuron B-84 Compound I sulfone of formula I Sulfasulfuron-B-85 Compound of formula I flucarbazone B-86 Compound of formula I atrazine B-87 Compound of formula I hexahydrate with B-88 Compound of formula I diuron B-89 Compound of formula I bisflufen Amine B-90 Compound, oxindole B-91 Formula I Compound Bendasone B-92 Compound of formula I ° 引等草草酯 B-93 Compound of formula I Cyclopentate B-94 Formula I compound dicamba B-95 Formula I Compound Fluorine Ratio Herbaceous B-96 Formula I Compound Dioxetine B-97 Formula I Compound Quinoxaic Acid B-98 Formula I Compound Sulfyl Sulfone B-99 Formula I Compound Saflufen B-100 I compound Te Pumei Yuezong 136128.doc -87- 200930297 Synthesis Example 1) 1-Gas-2-(2,4-difluorophenyl)-3·(4-phenylphenyl)propan-2-ol Synthesis: Magnesium tUrning (390 mg, 16 3 lysine 1) and iodine were added to a solution of 4-gas benzyl gas (250 mg, 1.55 axis 〇1) in anhydrous diethyl ether (25 ml). The reaction mixture was slowly warmed until the iodine color disappeared and the reaction was started by refluxing the solvent. The remaining 4-chlorophenylhydrazine-based gas '(2·25 g, 14_0 mmol)' was added dropwise to keep the reaction mixture under reflux. After the addition was completed, the mixture was further stirred at room temperature for 2 hours and then cooled to 〇 C. At this temperature, α gas _ 2' 4-difluoroacetophenone (2.36 g, 12 4 mm 〇 1) in anhydrous toluene (1 〇 mi) was added dropwise. The mixture was then warmed to room temperature and stirred for a further 3 hours. Thereafter, the mixture was again cooled to a spoon and a saturated aqueous solution of ammonium sulfate (10 ml) was added. The organic phase was separated and the aqueous phase was extracted with ethyl acetate (2×20 ml). The combined organic extracts were dried over sodium sulfate and solvent free. The crude product (4. g) obtained in this way was used in the next reaction step without purification. Synthesis of φ 2)(Z)-l-[3-chloro·1_(4·gasphenyl)propen-2-yl]_2 4_difluorobenzene at 〇C' first acetic anhydride (1.4 ml, ns mm 〇i) and then concentrated sulfuric acid ^ (77 μl, 1.5·mmo1) added to 1-gas-2-(2,4-trifluorophenyl)-3-(4-indolyl)propan-2- A solution of the alcohol (4.0 g, ca. 12.6 mmol) in 1,4-dioxane/THF mixture (44 ml, 1 : 1). The reaction mixture was then warmed to room temperature, stirred for a further 18 hours and then cooled again to hydrazine. (: At this temperature, a saturated gasified sodium solution (20 ml) was added, and the mixture was neutralized with an aqueous sodium hydroxide solution (6 2 ml, 5 % w/w). The obtained mixture was ethyl acetate (3×20) Ml) extract 'and combine the organic phases and dry over sodium sulfate. Filter under reduced pressure and 136128.doc •88- 200930297 After removing the solvent, the residue is purified by column chromatography (矽胜, 烧烧) The appropriate fractions were combined to give the title compound as a colorless oil (700 mg, 19% over 2 steps). H NMR (300 MHz, CDC13) δ 7.43-7.36 (m, 5 Η), 6.96-6.82 (m, 2Η), 6.74 (s, 1Η), 4.53 (s, 2Η). 3) trans-2-(2,4-difluorophenyl)_2_(chloroindenyl)_3_(4-chlorophenyl) Oxygen p-unit • Synthesis © Add maleic anhydride (2.3 g, 23.0 mmol) and aqueous hydrogen peroxide (1.6 ml 5〇Q/0 strength solution, 23 〇mm〇1) to chloro-1 (4_ A solution of phenylphenyl)prop-1-en-2-yl]_2,4-difluorobenzene (700 mg, 2.3 mmol) in acetic acid (20 ml). The reaction mixture was stirred at 45 ° C for 18 hours, and then cooled to room temperature, and water (2 〇 ml) and thiosulfate brine / sulphate (10% strength solution, 4 ml) was added. The aqueous phase was extracted with di-methane (3 X 15 ml) and the combined organic phases were washed with a sodium carbonated solution (2 χ丨〇 。). The organic phase was dried over sodium sulfate and filtered, and the solvent was evaporated. The residue obtained in this manner was purified by column column analysing (gelatin < 25:1 hexane/ethyl acetate). The appropriate fractions were combined to give the title compound (600 mg, 81%). , H NMR (300 MHz, CDC13) δ 7.58-7.51 (m, 1H), 7.43-7.36 (m, 4H), 6-"*6-84 (m, 2H), 4.20 (s, 1H), 3.73 (d, 1=12.0

Hz, 1H), 3.40 (d, J = i2. 〇 Hz, 1H). Synthesis of [(trans) 2 (2,4-fluorophenyl)_3_(4_ phenyl)oxy (1 1-2 yl)methyl]-1 Η-1,2,4-triazole Add I2,4-triazole (230 mg, 3.3 mmol) and sodium decyl 136128.doc -89· 200930297 (178 mg, 3.3 mmol) to trans _2_(2,4-difluoro at room temperature Phenyl) 2_(gasmethyl)-3-(4-chlorophenyl)oxy'• (6〇〇mg, 2.2 mmol) in anhydrous N,N-dimethylformamide (20 ml) In solution. The mixture was initially stirred at seven times for two hours and then at 50 ° C for an additional 16 hours. The mixture was then cooled to room temperature to be diluted with ethyl acetate (2 mL) and washed with sodium sulfate (3 x 15 ml). The organic phase was separated' dried over sodium sulfate and filtered, and solvent was left. The residue obtained in this manner was purified by column chromatography (EtOAc, 7:3hexane/ethyl acetate). The appropriate fractions were combined to give the title compound (180 mg, 27%) as a colorless solid. ]H NMR (300 MHz, CDC13) δ 8.11 (s, 1Η), 7.71 (s, 1H), 7.64 (d, J=9.0 Hz, 2H), 7.54 (d, J=9.0 Hz, 2H), 7.28- 7.20 (m, 1H), 7.11-7.04 (m, 1H), 6.96-6.90 (m, 1H), 4.64 (d, J=15.0 Hz, 1H), 4.42 (s, 1H), 4.28 (d, J= 15.0 Hz, 1H). Similar to these synthetic examples, the following compound of the formula (I) was prepared in the form of a racemic form of the triazolylmethyl substituent and the ring B of Table B. ❹ Table 8 Compound No. AB Physical Data FP [°C], ^-NMR (300 MHz, CDC13) 8.1 2,4-Difluorophenyl 4-Phenylphenyl 69-72 8.2 2,4-Difluorophenyl 3 -Chlorophenyl 8.12 (1H), 7.72 (1H), 7.65 (4H), 7.26 (1H), 7.09 (1H), 6.94 (1H), 4.64 (1H), 4.45 (1H), 4.31 (1H) [C Mesh-d6] 8.3 2,4-difluorophenyl 3,4-dichlorophenyl 98-99 8.4 2,4-difluorophenyl 2-fluorophenyl 91-93 8.5 2,4-difluorophenyl 3,4-digas radicals 7.88 (1H), 7.81 (1H), 7.34 (3H), 7.13 (1H), 6.84 (2H), 4.61 (1H), 4.19 (1H), 4.07 (1H) 136128.doc -90- 200930297 Compound No. AB Physical Data FP [°C], !H-NMR (300 MHz, CDC13) 8.6 2,4-Difluorophenyl 4-mercaptophenyl 7.86 (1H), 7.78 (1H), 7.42 (2H), 7.30 (2H), 7.17 (1H), 6.84 (2H), 4.60 (1H), 4.21 (1H), 4.12 (1H), 2.41 (3H) 8.7 2,4-difluorophenyl 3, 5-二气笨基127-129 8.8 2,4-Difluorophenyl 3-methylphenyl 7.87 (1H), 7.79 (1H), 7.33 (3H), 7.26 (2H), 6.80 (2H), 4.61 (1H), 4.20 (1H), 4.12 (1H), 2.43 (3H) 8.9 2,4-Difluorophenyl 3,5-dimethylphenyl 7.88 (1H), 7.79 (1H), 7.16 (3H) , 7.04 (1H), 6.80 (2H), 4.63 (1H), 4 .17 (1H), 4.10 (1H), 2.38 (6H) 8.10 2,4-Difluorophenyl 3,5-difluorophenyl 96-99 8.11 2,4-Difluorophenyl 2-trifluoromethyl Stupid 7.91 (1H), 7.76 (4H), 7.54 (1H), 7.30 (1H), 6.85 (2H), 4.87 (1H), 4.38 (1H), 3.93 (1H) 8.12 2,4-Difluorophenyl 2-Phenylphenyl 113-115 8.13 2,5-Difluorophenyl 2-Phenylphenyl 148-150 8.14 2,5-diphenylphenyl 4-phenylphenyl 100-103 8.15 2,5-difluorobenzene 2-fluorophenyl 144-146 8.16 2,5-difluorophenyl 2-mercaptophenyl 7.91 (1H), 7.79 (1H), 7.53 (1H), 7.30 (3H), 7.06 (3H), 4.77 (1H), 4.20 (1H), 4.00 (1H), 2.45 (3H) 8.17 2,5-Difluorophenyl 3-Phenylphenyl 7.91 (1H), 7.82 (1H), 7.53 (1H), 7.42 (3H ), 6.99 (3H), 4.71 (1H), 4.22 (1H), 4.06 (1H) 8.18 3,4-difluorophenyl 2-indolyl 136-139 8.19 3,4-diphenylphenyl 4-fluoro Phenyl 103-105 8.20 3,4-difluorophenyl 2-methylphenyl 112-114 8.21 3,4-difluorophenyl 2-fluorophenyl 110-112 8.22 3,5-diphenylene 2 - gas phenyl 164-165 8.23 3,5-difluorophenyl 2-mercaptophenyl 77-78 8.24 3,5-difluorophenyl 4- phenyl 148-149 fungicides using the compounds and mixtures of the examples Function It is proved by the following test: Preparation of the active compound The active compound is prepared singly or in combination as a stock solution containing 25 mg of the active compound, using acetone and/or DMSO and emulsifier Wettol EM 31 (with emulsification based on ethoxylated alkylphenol) And a dispersing humectant) The stock solution was made into 1 〇ml in a mixture of solvent/emulsifier volume ratio of 99:1 136128.doc -91 - 200930297. This mixture is then made up to 10 Torr using water. The stock solution is diluted with the solvent/emulsifier/water mixture to produce the active compound concentration specified below. Use Example 1 - Fight against scabies caused by Venturia inaequalis on apple leaves, 1 day protective application (Ventinpi) Spray the leaves of apple plants to an aqueous suspension having the concentration of active compound specified below Overflow point. The next day, the treated plants were inoculated with an aqueous suspension of spores of S. glabrata. The apple plants were then initially placed in a water vapor-saturated chamber at 24 ° C for 24 hours and then in the greenhouse at a temperature between (10) and 24 C for 21 days. Then visually measure the degree of development above the blade. The measured value of the percentage of infection on the leaves was converted to the efficacy of the untreated control. /〇. 0 efficacy means the same degree of infection as the untreated control; 1 〇〇 efficacy means 0% infection. The expected efficacy of the active compound combination is determined using the C〇lby f〇rmuU (c〇lby, SR -Calculating synergistic and antagonistic responses of herbicide combinations", Weeds, 15, pages 20-22, 1967). And compare it to the observed efficacy. Efficacy (E) was calculated using Abbot's formula as follows: Ε = (1-α/β) . 1〇〇α corresponds to the fungal infection (%) of the treated plants and β corresponds to untreated (Control) Fungal infection of plants (./0). The effect of 〇 means that the degree of infection of the treated plant is equivalent to that of untreated 136128.doc • 92- 200930297 The degree of infection of the control plant; 100 efficacy means that the treated plant is not infected. The expected efficacy of the active compound combination was determined using Colby's (Calby, SR "Calculating synergistie and antagonistic responses of herbicide Combinations", Weeds, page I5 '20-22, 1967) and compared to the observed efficacy ratio. Kolber's style:

❹ E E=X+y-x-y/l〇〇 The expected efficacy when a mixture of active compound A at concentration a and active compound at concentration b is used, expressed as % of untreated control;

X Efficacy when using active compound A at a concentration, expressed as % of untreated control; y, when using active compound B of wave b, expressed as % of untreated control. Preparation of Active Compounds for Microtiter Testing The active compounds are formulated individually or in combination as a stock solution having a concentration of 1 〇 〇〇〇 ppm in 8 〇. The active compounds epoxiconazole, dextromethorphan, trifluoroamine and sulphur are used as commercial formulations and are referenced to the active compounds, diluted with water. The calculation method of the microtiter test compares the measured parameters with the control variant growth of the inactive compound (100%) and the blank value of the fungus-free and active compound to determine the relative growth of the individual active compound (%) . Initially, the average of the values for the relative growth percentages was calculated and then converted to the efficacy (%) of the control variants of the inactive 136228.doc-93-200930297 compound. The sputum efficacy was the same as the control variant of the inactive compound, with 100 efficacy of 0% growth. The expected efficacy of the combination of active compounds was determined using the Kolber's formula as above and compared to the observed efficacy. Example 2 - Activity against the late blight pathogen Phytophthora infestans in a microtiter test The stock solution was aspirated into a microtiter plate (MTP) and diluted with water to the specified concentration of active compound. An aqueous zoospore suspension of Phytophthora infestans based on pea juice is then added. The plate was placed in a saturated water vapor chamber at a temperature of 18 °C. On the 7th day after inoculation, the MTP was measured using an absorption photometer at 405 nm.

Active compound/active concentration mixture observed according to Körber meter synergistic compound combination (ppm) Activity calculated (%) Compound 8.5 0.25 - 5 Compound 8.20 4 40 0.25 - 1 Compound 8.10 0.25 - 0 Compound 8.22 1 _ 20 Tetra-isophthalonitrile 1-78 Metrexazole 1 - 45 Compound II-1 4 - 25 Compound 8.5 0.25 1:4 100 79 21 Tetraisophthalonitrile 1 Compound 8.20 0.25 1:4 100 78 22 Tetrabenzene Nitrile 1 Compound 8.20 4 4:1 100 67 33 Metrexazole 1 Compound 8.10 Tetraisophthalonitrile 0.25 1 1:4 100 78 22 Compound 8.22 1 1:4 100 40 60 Compound Π-1 4 136128.doc -94 - 200930297 Combination of compound II-1 (for trans: 68:32 trans: cis diastereomeric mixture)

Use Example 3 - Activity against Botrytis cinerea pathogen in the microtiter test (botrci) The stock solution was aspirated into a microtiter plate (MTP) and diluted with water to the specified concentration of active compound. A malt-based aqueous spore suspension of Botrytis cinerea is then added. The plate was placed in a saturated steam chamber at a temperature of 18 °C. On the 7th day after inoculation, the MTP was measured using an absorption photometer at 405 nm.

Active compound/active concentration mixture observed according to Körber meter synergistic compound combination (ppm) activity activity (%) Compound 8.5 0.016 3 Compound 8.20 1 44 0.25 22 Compound 8.10 1 25 0.25 13 0.063 12 Compound 8.11 0.25 29 Compound 8.22 1 15 0.016 2 Beffene 0.016 20 . Captan 1 69 0.25 42 spirulina 4 34 epoxiconazole 0.25 64 Tetraisophthalonitrile 0.25 19 Refining 4 19 Nitrile '• Sitting 4 29 136128 .doc -95- 200930297 Active compound/active compound combination concentration (ppm) Activity observed in the mixture Synergistic activity according to Körber calculation (%) Metrofenolone 1 11 Compound 8.5 Beffen=0.016 0.016 1:1 49 22 27 Compound 8.20 Captan 0.25 1 1:4 98 76 22 Compound 8.20 Spirocycline 1 4 1:4 97 62 35 Compound 8.10 Fluoroxazole 1 0.25 4:1 87 67 20 Compound 8.10 Captan 0.25 1 1 :4 100 72 28 Compound 8.10 Tetraisophthalonitrile 0.063 0.25 1:4 43 21 22 Compound 8.11 Difen 0.25 4 1:16 83 42 41 Compound 8.11 Nitrile D sitting 0.25 4 1:16 96 50 46 Compound 8.11 Spirocyclam 0.25 4 1:16 97 53 44 Compound 8.22 Captan 0.016 0.25 1:16 68 43 25 Compound 8.22 Metrexino 1 1 1:1 100 25 75 Example 4 - Activity against the rice blast pathogen Pyricularia oryzae in a microtiter test The stock solution is aspirated into a microtiter plate (MTP) and diluted with water to the specified concentration of active compound. A malt-based aqueous spore suspension of P. oxysporum is then added. The plate was placed in a saturated water vapor chamber at a temperature of 18 °C. On the 7th day after inoculation, the MTP was measured using an absorption photometer at 405 nm. Active compound/active compound combination concentration (ppm) mixture observed activity activity according to Körber calculation synergy (%) compound 8.5 0.25 1 compound 8.20 1 2 0.25 1 136128.doc -96- 200930297

Active compound/active concentration mixture observed according to Körber meter synergistic compound combination (ppm) activity activity (%) Compound 8.10 0.25 0 Compound 8.11 0.25 0 0.063 1 0.016 2 Compound 8.22 1 0 0.063 7 0.016 7 1 61 Fluorine ring 0.25 0 Leaf bacterium ° 0.25 0 Captan 1 29 0.25 25 Hydrating 4 6 Nitrile saliva 4 29 Trifluoromethane 0.25 42 Beffen 0.25 25 Sulfur 4 57 Metrexene 1 25 Compound 8.5 0.25 1:4 82 61 21 Dekley 1 Compound 8.20 1 4:1 23 2 21 epoxiconazole 0.25 Compound 8.20 1 4:1 29 2 27 Xanthox 0.25 Compound 8.20 0.25 1:4 50 30 20 Captan 1 Compound 8.20 1 1:4 36 7 29 Difen 4 Compound 8.20 1 1:4 63 31 32 Myclobutanil 4 Compound 8.10 0.25 1:1 66 42 24 Trifluoro-sensitive 0.25 Compound 8.10 0.25 1:4 62 29 33 Kapu Tan 1 Compound 8.11 0.25 1:1 38 0 38 Fluorocyclo D sitting 0.25 Compound 8.11 0.016 1:16 60 27 33 Captan 0.25 Compound 8.11 0.063 1:4 82 26 56 Beffene 0.25 Compound 8.22 0.016 1:16 73 30 43 Captan 0.25 136128.doc •97- 200930297 Active compound/active compound combination concentration (ppm) observed in the mixture of active ke - synergistic effect (%) 37 Compound 8.22 Befendi 0.063 0.25 1:4 68 Activity 31 Compound 8.22 Sulfur 0.063 4 1:64 80 61 19 Compound 8.22 Metrexazole 1 1 1:1 100 25 75 Example 5 - Microtiter test for anti-C. The activity of the leaf spot pathogen wheat stalk ("Sepior/a irz'iz'cz") (septtr) The stock solution is inhaled into a microtiter plate (MTP) and diluted with water to the specified concentration of active compound. Next, a malt-based aqueous spore suspension of S. cerevisiae was added. The plate was placed in a saturated steam chamber at a temperature of 18 °C. On the 7th day after inoculation, the MTP was measured using an absorption photometer at 405 nm.

Active compound/active compound combination concentration (PPm) The activity observed in the mixture is based on the synergistic effect of the enzyme (%). Compound 8.5 4 23 0.25 8 0.004 2 Compound 8.20 0.25 52 0.063 4 0.004 7 Compound 8.10 4 16 0.25 5 0.004 3 Compound 8.11 0.016 33 0.004 0 Compound 8.22 0.063 11 0.016 15 0.004 8 Prosulfonazole 0.016 75 Trifluoro-sensitive 0.016 69 0.004 25 Captan 1 33 > Quito Bao 63 21 Refining 0.25 6 Nitrile saliva 0.25 11 136128.doc -98· 200930297 Active compound/active compound combination concentration (ppm) Activity observed in the mixture Synergistic activity according to Körber calculation (%) spirulina 1 2 Sulfur 1 0.25 22 11 Metrexino 0.063 0 Leaf sputum 0.016 15 克克敏0.004 19 Compound 8.5 thioconazole 0.004 0.016 1:4 98 75 23 Compound 8.5 Trifluoro-sensitive 0.004 0.004 1:1 64 27 37 Compound 8.5 Captan 0.25 1 1:4 57 38 19 Compound 8.5 Methyl Multi-Net 4 63 1:16 60 39 21 Compound 8.20 Fluorine Fluoride 0.004 0.004 1:1 50 31 19 Compound 8.20 Captan 0.25 1 1:4 98 68 30 Compound 8.20 Difen 0.063 0.25 1:4 31 10 21 Compound 8.20 Mycoxazole 0.063 0.25 1:4 41 15 26 Compound 8.20 spirocyclam 0.25 1 1:4 100 53 47 Compound 8.20 Sulfur 0.063 0.25 1:4 54 29 25 Compound 8.20 Meltrexazole 0.25 0.063 4:1 72 52 20 Compound 8.10 Trifluoro-sensitive 0.004 0.004 1:1 49 28 21 Compound 8.10 Captan 0.25 1 1:4 79 36 43 Compound 8.10 Indole-based 4 63 1:16 56 33 23 Compound 8.11 Yezosin 0.016 0.016 1:1 65 43 22 Compound 8.11 Fluorine-sensitive 0.004 0.016 1:4 93 69 24 Compound 8.22 Baikemin 0.016 0.004 4:1 51 26 25 Compound 8.22 Trifluoro-sensitive 0.004 0.016 1:4 98 70 28 136128.doc -99- 200930297 Active compound/active compound combination concentration (PPm) Mixture observation Activity to Synergistic Activity According to Körber Calculation (%) Compound 8.22 Captan 0.063 1 1:16 100 35 65 Compound 8.22 Sulfur 0.063 1 1:16 69 29 40 Test results show the mixture of the present invention due to synergy Than using Colbert's Calculation significantly more effective. ❹ 136128.doc -100-

Claims (1)

200930297 X. Patent application scope: 1. A fungicidal mixture comprising a synergistically effective amount of the following components as active components: 1) oxazolylmethyloxane of the general formula I, fN, N-CH2-N= / Λ C—CH AB (I) Wherein A is a phenyl group substituted by 2 F, and B is an unsubstituted 11 benzoyl group substituted with a thiol group, a 11-thyl group, a fluorenyl group, a fluorenyl group or a furyl group or substituted with 1 to 3 or less substituents. Base: element, no2, amine group, C--C4, base, cvc4 alkoxy, cv C4 haloalkyl, (:!-0:4 haloalkoxy, q-CU alkylamine, q- a C4 dialkylamino group, a thio group or a c丨-C4 alkylthio group, wherein the restriction is that if A is a 2,4-difluorophenyl group, then b is not an o-methylphenyl group, and the plant is compatible An acid addition salt or a metal salt, and 2) a fungicidal compound η 2.1 selected from the group consisting of strobilurin consisting of: azoxystrobin, shouting Dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, oressastrobin, pyridine Picoxystrobin, baikemin 136128.doc 200930297 (pyraclostrobin), pyribencarb, trifloxystrobin, 2-(2-(6-(3-)-2-mercaptophenoxy )·5-fluoropyrimidine Bite-4-yloxy)phenyl)-2-methoxyimino-indole-methylethylamine, 2_(o((2,5-dimethylphenyloxymethylene)benzene) Benzyl-3-methoxy"biazole methyl acrylate, 3-methoxy-2-(2-(N-(4-methoxyphenyl)cyclopropane carboxy anilide thiol) Ethyl phenyl) decyl acrylate, 2-(2-(3·(2,6-di-phenyl)-1·methylallylaminooxymethyl)phenyl)-2-yl oxyimino-N.methyl-acetamide; 2.2) Carboxamide which is selected from the group consisting of: - anthranilyl (earboxanilide) · benylaxyl, benzene cream Spirit (benalaxyl-M), benodanil, bixafen, boscalid, carboxin, fenfuram, fenhexamid, Flutolanil, furametpyr, isopyrazam, isotianil, kiralaxyl, mepronil, metalaxyl, Metalaxyl-M (mefenoxam), 〇furace, oxadixyl, oxygen OXyCarb〇xin, penthiopyrad, teci〇ftaiam, thifluzamide, tiadinii, 2-amino-4- Methyl hydrazine-5-anilinoindole, 2-gas-N-(l,l,3-trimethylindan-4-yl), decylamine, N_(3',4,-two gas 5-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole 4-indoleamine, N-[2-(l,3-dimethylbutyl 136128 .doc 200930297 phenyl]-5-fluoro-1,3-dimercapto-1H-pyrazole-4-carboxamide, N-(4'-chloro-3',5-difluorobiphenyl- 2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, Ν-(4·-gas-3\5-difluorobiphenyl-2-yl)- 3-Trifluorodecyl-1-methyl-1H-pyrazole-4-carboxamide, Ν-(3',4·-dichloro-5-fluorobiphenyl-2-yl)-3-trifluoro Methyl-1-mercapto-1Η-pyrazole-4-carboxamide, N-(3',5-dilac-41-methylbiphenyl-2-yl)-3-dimethylmethyl-1 · Mercapto-1H-pyrazole-4-carbamide, N-(3',5-difluoro-4.-indenylbiphenyl-2-yl)-3-trifluorodecyl-1-methyl -1H-. Biazole-4-carboxamide, N-(2-dicycloprop-2-ylphenyl)-3-difluoromethyl-1-methyl-1 Η-pyrazole-4-cartoamine, hydrazine -(cis-2 -dicycloprop-2-ylphenyl)-3-dimethylmethyl-1_methyl-1Η-pyrazole-4-carboxamide, Ν-(trans-2-bicyclo) Prop-2-ylphenyl)-3-difluoromethyl-1-methyl-1Η-pyrazole-4-carboxamide, Ν-(2'-fluoro-4·-a-5--methyl Biphenyl-2-yl)-1-indolyl-3-trifluorodecyl-1Η-pyrazole-4-carboxamide, Ν-(3|,4·,5'-trifluorobiphenyl-2- ))-1-mercapto-3- 3-trifluoromethyl-1H-pyrazole-4-carboxamide, Ν-(3·,4·,5'-trifluorobiphenyl-2-yl)-1- Mercapto-3-difluoroindolyl-1Η-pyrazole-4-decylamine, Ν-(2·,4',5'-trifluorobiphenyl-2-yl)-1-indolyl-3- Difluorodecyl-lH-αbiazole-4-carboxamide, Ν-(3·,4',5·-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl -1H-pyrazole-4-decylamine, N-(4'-(trifluoromethylsulfanyl)biphenyl-2-yl)-3-difluoromethyl-1-indolyl-1Η-» ratio Azole-4-decylamine, Ν-(4·-(trifluoromethylsulfanyl)biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-methyl Indoleamine, Ν-(4-(4-chloro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-indole- Ethyl-fluorene-fluorenyl hydrazine, hydrazine, (4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-:^-ethyl- 136128. Doc 200930297 N-methylformamidine, N,-(2-methyl-5-trifluoromethyl.4_(3-trimethylsulfonylpropoxy)phenyl)-indole-ethyl-hydrazine- Methyl sulphate and gas methyl-2-mercapto-4-(3-trimethylsulfonylpropoxy)phenyl)-hydrazine-ethyl-hydrazone-hydrazino; Ν-(2', 4,-Difluorobiphenyl-2-yl)-3-difluorodecyl-1-methyl-1Η-pyrazole-4-decylamine, Ν-(2',4,-di-biphenyl) 2_yl)-3-dimethylmethyl-1-mercapto-4-carboxamide, Ν-(2,5-fluorobiphenyl-2-yl)-3-difluorodecyl-1-methyl Than 4-pyridylamine, Ν·(2,5,-dichlorobiphenyl-2-yl)-3-difluoroindolyl_ι_methyl-1H-indole-4-indole amine, N-(3',5'-difluorobiphenyl-2-yl)·-methylmethyl-1-methyl-1H-0 is a 4-mercaptoamine, s1--chlorobenzene-2 Base)-3-di is decyl-1-methyl-1 Η-0 ratio. Sodium-4-mercaptoamine, Ν-(3'-biphenyl-2-yl)-3-difluoromethyl-1-indenyl ΐΗ ο ο 比 唑 醯 醯 醯 醯 醯 ( ( ( ( ( ( - gasbiphenyl-2-yl)-3-difluoromethyl-1-methyl-indole-n-biazole-4-decylamine, N-(2'-fluorobiphenyl-2-yl)-3 -difluoromethyl-1 -mercapto-1H-pyrazole-4-decylamine, N-(2,-azabiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H ·pyridin-4-carboxamide, N-[2-(l,l,2,3,3,3-hexafluoropropoxy)phenyl]-3-diazinyl-l-fluorenyl- 111-pyrazole-4-carboxamide,;^-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-3-difluoromethyl-1-indolyl-1Η- Λββ-4-ene amine, N-(2-(1,3,3-trimethylbutyl)phenyl)-1,3-didecyl-5-fluoro-1H-pyrazole-4- Indoleamine, N-[l,2,3,4-tetrahydro-9-(1-indolylethyl)-1,4-methylnaphthalen-5-yl]-3-(difluoromethyl) · 1-methyl-1H-pyrazole-4-carboxamide; carboxylic acid morpholide: dimethomorph, flumorph; 136128.doc -4- 200930297 - Benzoylamine: Flumetover, Fluopicolide, Fluopyram, Chloroquinone (2〇乂&11^4 6),; -(3-ethyl-3,5,5-trimethylcyclohexyl)-3-carboxyaminoamino-2-hydroxybenzamide; - other slow amine: gupamine (carpropamid), diclocymet, mandipropamid, oxytetracyclin, silthiofam, N-(6-decylpyridin-3-yl) ring Propane methotrexate; 2.3) An azole selected from the group consisting of: - Three-degree sitting: Azaconazole, bismuthene (bitertanol), bacillus sputum (bromuconazole), ring gram 0 sitting (cyproconazole), difenoconazole, diniconazole, dyckle-oxime, epoxiconazole, fenbuconazole, quinucconazole, quinacconazole, Fusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, nitrile Sit (myclobutanil), umpoxazole, octopodazole, penconazole, penconazole, propiconazole, prothioconazole, shixi fluoride (simeconazole), tebuconazole, tetraconazole, triadimefon, triadimenol, ring bacteria. Triticonazole, uniconazole, 1-(4-benzene benzene 136128.doc 200930297 base)-2·([1,2,4]triazol-1_yl)·cycloheptanol; Saliva: cyazofamid, imazalil, sulphate sulphate, pefurazoate, prochloraz, triflumizole; - 0 啥 苯 苯 bacteria Benomyl, carbendazim, fuberidazole, thiabendazole; other. ethaboxam, etridiazole, hymexazole , chlorophenyl)_丨_(propynej-yloxy)-3-(4-(3,4-dimethoxyphenyl)isoxazole·5-yl)propan-2-_, 2-(4 - phenyl)-N-[4-(3,4-dimethoxyphenyl)isoxazolyl]-2-prop-2-ynyloxyacetamide; 2.4) selected from the following a group of nitrogen-containing heterocyclic compounds: 'pyridine: qiazinam, phenanthene, 夂[5-(4- oxa)-2,3-dimethylisopropanoid Bite _3_yl]0 pyridine, 夂[5-(4-mercaptophenyl)-2,3-dimethylisoxazole pyridine-3-yl]pyridine, 2,3'5,6-tetra Chloro-4_decane Mercapto-β-pyridyl, 3,4,5-tris-pyridine, 2,6-dicarbonitrile, N-(l-(5-bromo-3·chloropyridinyl)_2, quinone dinicotinamide , Ν-((5-bromopyridine-2-yl)methyl)_2,4 di-nicotinine amide; - pyrimidine: bupirimate, cyprodinil, fluzalazine (diflumet〇rim), fenarimol, ferimzone, mepanipyrim ^ nitrapydn, ririm 136128.doc -6 - 200930297 (nuarimol), pimeni (pyrimethanil); - nchinazine: triforins; - n bilo: fludioxonil, fenpiclonil; - linlin: adimorph (aldimorph), morphin (dodemorph) ), oxytetracycline acetate, fenpropimorph, tridemorph; - brigade D: fenpropidin; - two rebel imine: σ 吱 吱 ( (fluoroimide) Iprodione, procymidone, vinclozolin; - non-aromatic 5-membered heterocyclic ring: °D-dfaoxadone, fenamidone, defeat Flutianil, 辛°塞酮 (oct Hilinone), carbendazim (probenazole), S-propyl propyl 5-amino-2-isopropyl-3-sideoxy-4-o-phenylene-2,3-dichloro-β -1 _ thioformate; Α - Other: acibenzolar-S-methyl, 0 ❹. Amisulbrom, anilazine, blasticidin-S, captafol, captan, chinomethionat, mammoth' (dazomet) ) debacarb, diclomezine, difenzoquat, benzoic acid methyl sulfonate, fenoxanil, folpet, oxolinic Acid), piperalin, proquinazid, pyroquilone, foxofen 136128.doc 200930297 (quinoxyfen), tris-xylazine (8) az〇xide, tricyclazole, 5_gas_7_(4_mercaptopipridine small group)·heart (2 4 azole trifluorophenyl M1,2,4]triazolo[Ha]pyrimidine, 2_butoxy' · iodine_3_propyl Kethenone, 5-gas 4-(4,6-dimethoxypyrimidinyl)_2-mercapto-1H-benzimidazole, 6-(3,4·diphenyl)-5-methyl a [丨, 2, 4] triindole and [1L-decyl-7-ylamine, 6-(tetra)tributylphenyl)-5-fluorenyl-H4]triazolo-n,5-a]pyrimidine-7-ylamine, % 6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo-n,5-a]indolyl-7-ylamine, 5-methyl-6-octyl-π , 2,4] triterpenoid and 6-methyl-5-octyl-fl, 2,4]^ sit-amine, 6-ethyl_5-octylhydrazine, 2,4]triazole π,5_μ^ylamine, 5-ethyl-6-octyl_[124]triazolopyran 1 = amine, 5-ethyl_6_(3,5,5-tridecylhexyl Hi, 24] Triazolo[1'5-a] ringing-7-ylamine, 6-octyl_5_propyl_π,2,4]tris-[l,5-a]pyrimidin-7-ylamine , 5-methoxymethyl -6 octyl _[124] tri φ oxazolo[1,5_a]pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl^^ And [l,5-a]pyrimidine-7-ylamine and 5-trifluoromethyl-6 (3,55 trimethylhexyl)-[1,2,4]trim[i,5-a] 〇 〇 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ · ferbate, mancozeb, maneb, metam, methasulfocarb, metiram, propineb, Thiram, zineb, 136128.doc 200930297 ziram; • amino phthalic acid S: diethofencarb, benzene π Benthiavalicarb, iprovalicarb, propamocarb, propamocarb hydrochloride, valiphenal, N-(l-(l-(4-cyanophenyl)ethane 4-fluorophenyl sulfonyl)butan-2-yl)carbamate; 2.6) Other fungicides selected from the group consisting of: - 胍: dodine, toxin free base, biguanide Salt φ (guazatine), diammonium acetate, iminoctadine, dioctylamine triacetate, iminoctadine tris (albesilate); 'antibiotics: kasugamycin , kasugamycin hydrochloride hydrate, polyoxins, streptomycin, validamycin A; - nitrobenzene derivatives: φ binapacryl, gas Dicloran, dinobuton, dinocap, nitrothal-isopropyl, tecnazene; - organometallic compound: fentin salt ), such as fentin acetate, fentin chloride, triphenyl hydroxide Fentin hydroxide; sulfur-containing heterocyclic compounds: isoprothiolane, dithianon; - organophosphorus compounds: edifenphos, triethylphosphoric acid 136128.doc 200930297 (fosetyl ), fosetyl-aluminum, iprobenfos, pyraz0ph〇s, tolclofos-methyl; - organic gas compounds. tetra-isophthalonitrile ( Chlorothalonil), dichlofluanid, dichlorophen, flusulfamide, hexachlorobenzene, pencycuron, pentacle 〇rophenol and its salts, benzene Phthalide, quintozene, thiophanate-methyl, tolylfluanid, N-(4-carb-2-nitrophenyl)-N-ethyl- 4-methylbenzenesulfonamide; - inorganic active compound: phosphorous acid and its salt, sulfur, Bordeaux mixture, copper salt, such as copper acetate, copper hydroxide, chlorooxyketone, basic copper sulfate; - Others: biphenyl, bronopol, 嚷Cyflufenamid, cymoxanil, diphenylamine, metrafenone, mildiomycin, oxine copper, prohexadione- Calcium), spiroxamine, yiluonine, N-(cyclopropylmethoxyimino-(6-difluoromethoxy-2,3-difluorophenyl)methyl)- 2·Phenylacetamide, Ν·-(4-(4-Gas-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-fluorene-ethyl-fluorenyl-fluorenyl Formazan, Ν'-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-diamidinophenyl)-indole·ethyl_Ν-methylformamidine, Ν· -(2-methyl-5-trifluoromethyl-4-(3-tridecyldecylpropoxy)phenyl)-indole-ethyl-hydrazine-methylmethyl 136128.doc -10 - 200930297 Lung , N'-(5-Difluoroindolyl-2-ylindolyl-4_(3-trimethylsulfonyloxy)phenyl)-indole-ethylmercaptomethylhydrazine, hydrazine-methyl-N- (l,2,3,4-tetramethyl-l-yl)-2-{1-[2-(5-methyl-3-trifluoromethyl 0-t-but-1-yl)ethenyl] Piperidin-4-yl}thiazole-4-carboxamide, (R)-N-mercapto-• Ν·(1,2,3,4-tetrahydronaphthalene_ι·yl)_2·{ΐ_[2 -(5-fluorenyl_3_trifluoromethyl Ratio-1 -yl)ethinyl]piperidin-4-yl}thiazole-4-carboxamide, acetic acid 6-tert-butyl_8_fluoro-2,3-dimethylquinoline·4 _ base ester, methoxyacetic acid 6-tert-butyl_8-fluoro-2,3-dimethylquinolin-4-yl ester. The fungicidal mixture of claim 1, wherein in component I of formula I, A is 2,4.difluorophenyl or 3,4-difluorophenyl. 3. The fungicidal mixture according to claim 1 or 2, wherein in the component j of the formula I, 'B is a pyridyl group, a thienyl group, a thiazolyl group, an oxazolyl group or a furyl group. 4. The fungicidal mixture according to claim 1 or 2, wherein in the component 1 of the formula I, 'B is a phenyl group substituted with 1 to 3 substituents: halogen, n〇2, amine group, c〗 -c4, Ke_C4 alkoxy, Ci_C4 sleek > base, Ci_C4_ sensyloxy, CrCU alkylamine, CVC4 dialkylamino, thio or (: widely C4 alkylthio. The fungicidal mixture according to claim 4, wherein in the component oxime of the formula j, B is a phenyl group substituted with 1 to 3 or less substituents: dentate, Ci_C4 alkyl, Ci-C4 alkoxy, Ci_C4 A haloalkyl group or a Ci_C4 haloalkoxy group. The fungicidal mixture according to any one of claims 1 to 5, which comprises 1 to 1.100 by weight of one of the compounds 1 and the compound 2 The fungicidal mixture according to any one of claims 1 to 6, which comprises a compound 2 selected from the group consisting of axils: atorine, kexinxin, biting oxygen 136128.doc • 11 The fungicidal mixture according to any one of claims 1 to 6, which comprises a compound 2 selected from the group consisting of: bxixifene, wilt Ling, D is more than carbamide, pyrimidinedione, chlorhexidine, N_(3,,4'-dichloro-5-fluoro-biphenyl)-3--milylmethyl-1-mercapto-1Η- 0 to 0 -4- an amine, Ν-(2-dipropion-2-ylphenyl)-3-difluoromethyl_1_methyl-1 Η-pyrazole-4-carboxamide, Ν (cis-a-cyclopropyl phenyl)-3-difluoroindol-1-yl-iH-f than 唉_4 carbamide, N-(trans _2_dicyclopropyl_2_ Phenyl)_3_difluoromethyl·丨_methyl-1H-pyrazole-4-carboxamide, N_(2,·fluoro-4, gas-5,-methylbiphenyl·2-yl) 1 -methyl-3-trifluoromethyl-ϊη-pyrazole_4_formamidine, Ν-(3·,4,5·-trifluorobiphenyl-2-yl)_1·decyl-3- Trifluoromethyl-1 Η-pyrazole-4-cartoamine, hydrazine (3',4',5'-trifluorobiphenyl-2-yl) hydrazino_3_difluoroindolyl_out_pyridinium Sit _^ 甲 胺, Ν-(2,4,5,-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-° than saliva-4-曱Amine, I(3|,4,5,-trifluorobiphenyl-2-yl)-3-fluorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-( 4,-(trifluoromethylsulfanyl)biphenyl)-3•difluoromethyl-1-indolyl-1H-pyrazole-4-cartoamine, (trifluorodecylthio)biphenyl_ 2-yl)-1-methyl-3-trifluoromethyl-lH-u than salivation 4- 4-carbamide, Ν'·(4-(4-Gas-3·trifluoromethylphenoxy) -2,5-dimethylphenyl)-oxime-ethyl-oxime-methylformamidine, ν,-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5- Dimethylphenyl)_ν_ethylmethylmethyl lung, Ν'-(2-methyl_5_trimethyl-4-(3-trimethylsulfonyloxy)phenyl)-indole- Ethylmercaptomethylhydrazine and Ν'-(5-difluoroindolyl-2-methyl-4(3-trimethyldecylpropoxy)phenyl)-indole-ethyl-indole-methyl Hey. The fungicidal mixture according to any one of items 1 to 6, which comprises a compound selected from the group consisting of 136128.doc •12·200930297 and the like: cycloglycol, difenophenazole, fluorine Ring saliva, stone eve, defoliation, myclobutanil, meconazole, puglione, sulphur, sitting, degli, fluorinated, "sit, poker." The fungicidal mixture according to any one of claims 1 to 6, which comprises a compound 2 selected from the group consisting of: befenate, phenidazole, cypro, tidying, powder rust Lin, Captan, Benzene, Dean, Tetrachloroisophthalonitrile, Hydrazine, Sulfur, Copper Hydroxide, Metrexantine and spirulina. 11. A fungicidal mixture according to claim 10 which comprises a compound 2 selected from the group consisting of: befenate, porphyrin and melfene. 12. Use of a fungicidal mixture according to any one of claims 6 to 6 for controlling a phytopathogenic fungus. 13. Agrochemical composition comprising a solvent or a solid carrier and a fungicidal mixture according to any one of claims 1 to 6. 14. A seed comprising the fungicidal mixture of any one of claims (1) Things. 15. A method for controlling a phytopathogenic fungus, which is treated with a fungicidal mixture of an effective amount/monthly item 1 to 6 to treat the fungus or a substance or plant to be protected against fungal attack. , soil or seeds. 136128.doc •13. 200930297 VII. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: 〇 (I) CH2—C—CH A B 136128.doc