TW200924273A - Apparatus for evaluating electrochemical properties of fuel cell - Google Patents

Apparatus for evaluating electrochemical properties of fuel cell Download PDF

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Publication number
TW200924273A
TW200924273A TW097144836A TW97144836A TW200924273A TW 200924273 A TW200924273 A TW 200924273A TW 097144836 A TW097144836 A TW 097144836A TW 97144836 A TW97144836 A TW 97144836A TW 200924273 A TW200924273 A TW 200924273A
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Taiwan
Prior art keywords
fuel cell
plate
battery
electrochemical
evaluation
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TW097144836A
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Chinese (zh)
Inventor
Sang-Kyun Kim
Jae-Youl Oh
Byung-Kak Kang
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Nara Cell Tech Corp
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Publication of TW200924273A publication Critical patent/TW200924273A/en

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/3644Constructional arrangements
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/396Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Fuel Cell (AREA)

Abstract

The present invention relates to a device for evaluating electrochemic properties of a fuel battery, the device comprises an electric cooker for containing a fuel battery to be evaluated, and heat after power supply to improve temperature around the fuel battery; a pressurizing mechanism capable of applying preset fixed pressure on the fuel battery contained in the electric cooker; and a control unit for controlling the integral action of the evaluating device. The invention may set temperature suitable for evaluating properties of a high-temperature fuel battery, use the cooker to maintain higher temperature around the battery, and use the pressurizing mechanism to apply certain pressure from up side to the battery to maintain certain pressure between the battery and a manifold fastening joint face, thereby providing a best surrounding for evaluating electrochemic properties of the high-temperature fuel battery, and ensuring accuracy and reliability of the evaluation. Further corresponding properties data along variation of the surroundings can be obtained, thus best operation surrounding of the fuel battery can be set.

Description

200924273 九、發明說明: 【發明所屬之技術領域】 本發明係一種燃料電池之電化學特性評估裴置,本發明可針對需要高 溫環境的燃料電池的性能評估作業而使燃料電池之週圍溫度維持在高门 溫,使歧管(manifold)緊固接合面的壓力維持—固定值,為烬料電池=電 化學特性評估作業提供最佳環境,顧評估結果數據的準確性與可 性。 、 【先前技術】200924273 IX. Description of the Invention: [Technical Field] The present invention is an electrochemical characteristic evaluation device for a fuel cell, and the present invention can maintain the ambient temperature of the fuel cell for the performance evaluation of a fuel cell requiring a high temperature environment. The high door temperature maintains the pressure of the manifold fastening joint—a fixed value—providing an optimal environment for the dip battery=electrochemical property evaluation operation, and the accuracy and feasibility of the evaluation result data. [Prior Art]

燃料電池是-種可以把氫與氧的化學能轉換成電能的電化學裝置,辦 =通過電化學的形態進行反應而產生電流,在上述過程也會时產生熱 =因此可以高效率地發電,由於有害氣體的排放量較少而減輕了公害' 問題,是一種頗受歡迎的高效率綠色能量轉換裝置。 Q 上述簡電池的基本财包括1料極,作為 =離子與電子;氧極,通過電_過來的陽離子與氧== 括Ϊ二電解質’由燃料極產生的陽離子的移動。燃料極與氧極包 括·催化劑層’可以引起電化學反應;氣體擴散層(咖,娜碰 Ξ即使體分散到催化劑上;以及_道,導賤體移動。分 ίίΓ隹:Γ 的_是電極,械—物嫩生的電子進行 ,氣_辭分散到各 輸燃料電池 :r_ 電· 化度—固體氧 對於根據供應給池的電極上連接電負荷, =而變化的輪出電量進行分析, :以^ 電化學特性評估裝置進^ 别電化學特性評估裝置沒有考慮到根據燃料電池的種類而 200924273 坏千篇一律的條件下針對所有的燃料電 因此‘,、、法確保砰估結果之準確性與可靠性。 於型燃料電池的發電溫度高 程中;:度的高:需=== 置。子“ &gt;皿型燃料電池的評估作業而調節並維持適當溫度的評二裝 態氧化物型燃料電池需要在高溫狀 而,-般金2 1 因此通過各自獨立的歧管供應。然 在燃料電池與歧管接間的高溫會出現氧化反應’因此报難 前也-有二;=題=裝r也會蝴。目 【發明内容】 【所欲解決之技術課題】 為了解決先前燃料電池之電化璺 =提供一種具有下列優點的燃料電池之電^學特性 =古題裳3之 二 或固體氧化物型燃料電池等r 與歧管 性,還可以鸭…, 崎保汗估、纟。果之準確性與可靠 【技術方案】 爐恤辦_物包括:電 燃料電池之週圍溫度;:壓機====後發熱而提高 r預先設定之_力,“===: 200924273 池的上-Hr電=殼ir/稍了㈣容納作树估«之燃料電 _疋工間’電熱益’安裝在上述機殼之内牆,接 位於上述機殼與電熱器之間,可以防止電熱=量 上述電熱器是堪塔爾(Kanthal)電線埋入式加教器。 ,上爐 1外f裝了可以實時檢測電爐内部溫度的溫度感測器,上述 ΖίΓ 電爐内部之溫度信息信號將反饋給上述控制 和控制部根據上述反饋信號而為電熱器供 電爐内部之溫度-直轉—定值。 ’從而使 對ϋ加ff構包括:安裝部,從下方支持燃料電池;加愿部,從上方 #置,在上核訪上的燃料電池施加動;以及 述加昼部沿着上下方向舫料勒。 W .赚上 包括:固定板,其上部直接置放燃料電池並且從下方給予 =從下方鱗上述㈣板;以及絲,其j^結合在上 的尾端’其下方固定緊固在上述電爐底部’支持上述下固定 上^加壓部包括:加藏,對於上述安裝騎支持_料電池之上部 轭加壓力,以及上加麼桿,上部尾端結合在上述加壓驅動部,下側尾 端結合在上述加壓板之上部,隨着加動_部的動作而升降並驅使 加壓板進行升降運動。 上述加壓驅動部是由汽缸與活塞桿組成的空壓致動器。 上述安裝部與加麼部使用錄基超合金(ineonel)材料製作較為適宜。 上述上加壓桿與加壓板通過萬向接頭連接較為適宜。 連接件可以把上述上加壓桿與加壓板連接起來,上述連接件之上部中 間位^形成了允許上述上加壓桿之下側尾端插入的插槽,其下部直徑小 於上部直徑,其外柱面之敝可以和上述加壓板之上部進行螺紋結合, 其上部之外柱面具有多個螺絲孔,上述上加壓桿之下側尾端做了圓°开^加 工處理’其上部之外柱面形成了環槽,上述上減桿之下側尾端被插入 上述連接件的姉後把岐獅fg]在上聊職,就能使上述固定螺 200924273 絲安置在上加壓桿的環_部並對上祕桿施 【效果】 ㈣防止脫離。 如前所述,本發明可崎定㈣合評估舰碳__ 氧化物型燃料電池等高溫型燃料電池的特性的溫度條件Ί 爐使燃料電池的周圍溫度維持高溫,通過 =用電 疒定壓力而使燃料電_歧管緊固接合面之間維持枓J二 u出適合評估高溫型燃料電池的電化學特性的最佳環境,進2二 估結果之準確性與可靠性。還可以隨着環境條件的變化而相^ 能特性資料,進-步設定出燃料電池的最佳工作環境。&amp;應他 【實施方式】 結構下及面作參用考圖式詳細地描述本發明燃料電池之電化學特性評估褒置的 本。㈣峨'峨版咖,第2圖係 加:二::,之瓣特性評估裝置包括電爐, 如别所述,上述電爐100可以使燃料電池的周圍溫度上昇到测 左右,而營造出適合評估縣碳_型燃料電池或固體氧化物 聖燃料電池等高溫型燃料電池性能的高溫環境。 第3圖係上述電爐100之具體結構側視圖。如圖中所示,上述雷爐 ⑽包括機殼11〇、電熱器12〇、隔熱層13〇及溫度感測器14〇。爐 上逑機殼1K)是-個内置了後述的電熱器120並具有近似於正六面體 ,狀之盖體,該盒體内部的收容部具有一定空間並可以放置作為評估對 之燃料電池’應該制耐麟性良好的不綱材料製倾為適宜。 上述機殼110的開閉式門112可以把作為評估對象之燃料電池投入内 j或者從㈣取出’上述卿式門112通過其—綱鉸鏈以旋轉方式進 =開閉動作’因此在上述開閉式門112的_側面形成了可以在開閉動作 時方便把持的手柄114。上述機殼110的下面另外安裝了方便電爐则 200924273 移動的小輪15〇。 電妖圖^,上述電爐卿的機殼U°内牆安裝電熱器⑽。上述 12G接料部電源並發熱,本發明之上述電12G使用堪拔爾 較树宜。也就是說,發細_塔㈣線122, 線Γ2以安裝在陶隸料等耐火物124内部的方式配置 ^内牆’織在供應電源時對内部進行間接加孰。 μ 電熱器120產生的熱量流失到外部,上述電爐卿在上述機 二傳導之間形成隔熱層130較為適宜。上述隔熱層13〇使 性材料製作,可以«再生«之 玻璃面或者把石材融化後纖維化之岩面等。 達至=7單相5KW電源驅動上述電爐100的電熱器120,加熱溫度 上述電爐⑽的-側絲溫度感靡⑽。上述溫度制器⑽實 溫度後把溫度信息信號傳輸給後述的控制部300, 從而把电爐100的内部溫度調整成燃料電池評估作業中所 上述溫度感測器14°使用熱電偶。請參閱第; =電偶^度感· 14G從外部貫穿電爐觸的機殼⑽,其尾端位 於书爐100的内部空間並實時檢測電爐1〇〇内部溫度。A fuel cell is an electrochemical device that converts the chemical energy of hydrogen and oxygen into electrical energy. The electric field is generated by reacting in an electrochemical form, and heat is generated in the above process. Therefore, power can be efficiently generated. It is a popular high-efficiency green energy conversion device because it reduces the pollution hazard due to less harmful gas emissions. Q The basics of the above simple battery include 1 material, as the ion and electron; the oxygen electrode, the cation and the oxygen through the electricity == the second electrolyte, the movement of the cation generated by the fuel electrode. The fuel electrode and the oxygen electrode include a catalyst layer' to cause an electrochemical reaction; a gas diffusion layer (a coffee, a nano-collar, even if the body is dispersed on the catalyst; and a channel, the conductive body moves. ί ίίΓ隹: Γ _ is an electrode The mechanical-physical and intensive electrons are carried out, and the gas_distribution is distributed to each fuel cell: r_electricity degree-solid oxygen is analyzed for the electric power connected to the electrode supplied to the pool, and the variation : The electrochemical characteristic evaluation device of the electrochemical evaluation device does not take into account the fact that according to the type of fuel cell, 200924273 is not uniform for all fuels, so the accuracy of the evaluation results is ensured. Reliability: The temperature of the power generation temperature of the fuel cell is high; the degree is high: need to be === set. Sub- &gt; evaluation of the fuel cell of the fuel cell to adjust and maintain the proper temperature of the two-state oxide fuel The battery needs to be in a high temperature, and the gold 2 1 is therefore supplied through separate manifolds. However, the oxidation reaction occurs at the high temperature between the fuel cell and the manifold. = question = loading r will also be butterfly. [invention content] [the technical problem to be solved] In order to solve the previous fuel cell electrolysis 提供 = provide a fuel cell with the following advantages of electrical characteristics = ancient title 3 Second, or solid oxide fuel cells, etc. r and manifold, can also be duck..., 崎保汗 estimates, 纟. The accuracy and reliability of the fruit [technical solution] furnaces _ things include: the surrounding temperature of the electric fuel cell ;: Press ==== After heating, increase the pre-set _ force, "===: 200924273 The upper part of the pool - Hr electricity = shell ir / slightly (four) accommodated the tree estimate « fuel power _ labor room 'Electrical heat benefit' is installed on the inner wall of the above casing, and is located between the above casing and the electric heater to prevent electric heat=the above electric heater is a Kanthal wire buried type teaching device. 1 The external f is equipped with a temperature sensor capable of detecting the internal temperature of the electric furnace in real time, and the temperature information signal inside the electric furnace is fed back to the control and control unit for the temperature inside the electric heater to supply the electric furnace according to the feedback signal-direct conversion- Fixed value. 'Therefore, the confrontation plus ff includes: Ministry, support the fuel cell from below; the Ministry of Health, from the top # set, the fuel cell on the upper nuclear visit to move; and the twisting section along the up and down direction. W. Earnings include: fixed plate, The fuel cell is placed directly on the upper part thereof and is given from below (the above-mentioned (four) plate from the lower scale; and the wire is combined with the upper end of the upper end 'fixed and fastened to the bottom of the electric furnace' to support the above-mentioned lower fixing The part includes: adding, adding pressure to the upper yoke of the mounting support, and adding a rod, the upper end is coupled to the pressing driving portion, and the lower end is coupled to the upper portion of the pressing plate, The pressurizing plate is moved up and down as the action of the moving portion moves up and down. The pressurizing drive portion is a pneumatic actuator composed of a cylinder and a piston rod. It is preferable that the mounting portion and the adding portion are made of a base superalloy (ineonel) material. It is preferable that the upper pressing rod and the pressure plate are connected by a universal joint. The connecting member may connect the upper pressing rod and the pressing plate, and the upper portion of the connecting member forms a slot for allowing the lower end end of the upper pressing rod to be inserted, and the lower portion has a diameter smaller than the upper diameter, and The outer cylindrical surface may be threadedly coupled with the upper portion of the pressing plate, and the upper surface of the upper pressing portion has a plurality of screw holes, and the lower end end of the upper pressing rod is rounded and processed. The outer cylinder surface forms a ring groove, and the lower end end of the upper reduction rod is inserted into the shackle of the connecting member, and the lion lion is placed on the upper stalk, so that the fixing screw 200924273 wire can be placed on the upper pressure rod. The ring _ part and the upper secret pole [effect] (four) to prevent detachment. As described above, the present invention can satisfactorily determine the temperature conditions of the characteristics of a high-temperature fuel cell such as a carbon-based fuel cell such as an oxide fuel cell. The furnace maintains a high temperature around the fuel cell, and the pressure is determined by the electric power. In order to maintain the optimum environment for evaluating the electrochemical characteristics of the high-temperature fuel cell, the fuel cell-manifold fastening interface is maintained to be accurate and reliable. It is also possible to set the optimal working environment of the fuel cell in accordance with the changes in environmental conditions. &amp; </ RTI> [Embodiment] The structure of the electrochemical characteristics of the fuel cell of the present invention is described in detail under the structure and the reference. (4) 峨 '峨版咖, the second figure is added: two::, the valve characteristic evaluation device includes an electric furnace, as described above, the electric furnace 100 can raise the ambient temperature of the fuel cell to the left and right, and create a suitable evaluation High-temperature environment with high-temperature fuel cell performance such as carbon-type fuel cell or solid oxide holy fuel cell. Fig. 3 is a side view showing the specific structure of the above electric furnace 100. As shown in the figure, the above-mentioned lightning furnace (10) includes a casing 11 〇, an electric heater 12 〇, a heat insulating layer 13 〇, and a temperature sensor 14 〇. The furnace upper casing 1K) is a cover body having a built-in electric heater 120 to be described later and having a shape similar to a regular hexahedron, and the housing portion inside the casing has a certain space and can be placed as an evaluation fuel cell. It is appropriate to make a non-structural material with good lining resistance. The opening and closing door 112 of the casing 110 can take the fuel cell as the evaluation target or take it out from the (four) 'the above-mentioned sluice gate 112 is rotated in a manner to open and close the door through the hinge thereof'. Therefore, the above-mentioned opening and closing door 112 is opened. The side of the _ is formed with a handle 114 that can be easily held during the opening and closing operation. The lower side of the casing 110 is additionally provided with a small wheel 15 移动 which is convenient for the electric furnace to be moved in 200924273. Electric demon figure ^, the above-mentioned electric furnace Qing's casing U ° inner wall installed electric heater (10). The above 12G receiving unit is powered and generates heat, and the above-mentioned electric 12G of the present invention is more suitable for use. That is, the hair _ tower (four) line 122, the wire Γ 2 is disposed so as to be installed inside the refractory 124 such as the ceramic material. The inner wall woven is indirectly twisted when the power is supplied. The heat generated by the electrothermal heater 120 is lost to the outside, and it is preferable that the electric furnace is formed with the heat insulating layer 130 between the two conductions. The above-mentioned heat insulating layer 13 is made of a material, and can be a glass surface of "recycled" or a rock surface which is melted by a stone and then fibrillated. Up to 7 = single-phase 5 KW power source drives the electric heater 120 of the electric furnace 100, and the heating temperature of the electric furnace (10) is sensed by the side wire temperature (10). The temperature controller (10) transmits the temperature information signal to the control unit 300, which will be described later, to adjust the internal temperature of the electric furnace 100 to the temperature sensor 14 in the fuel cell evaluation operation. Please refer to the section; = galvanic ^ feeling sensation · 14G from the outside through the electric furnace touch casing (10), the tail end is located in the internal space of the book furnace 100 and the internal temperature of the electric furnace 1 实时 is detected in real time.

具有上述結構的電爐觸可以在評估高溫型燃 時滿足200t到lOOOt之間的高溫條件。 的电化子特H 如^述二本發明燃料電池之電化學特性評估褒置配備了加壓機構 唯射信^十0把一定勤施加到作為評估對象之燃料電池並The electric furnace contact having the above structure can satisfy the high temperature condition between 200t and 1000t when evaluating the high-temperature type combustion. The electrochemical characteristics of the fuel cell of the present invention are equipped with a pressurizing mechanism, and only a certain amount of power is applied to the fuel cell to be evaluated.

ϋ _ _裝部22G、_卩細及加壓驅動 4 26—〇。第4圖係上述加麵構細的具體結構及結合關圖 I 體顯示了上述加壓機構200中加壓部24〇的連接關係。 /、 上述安裝部220在作為評估對象之燃料電池被放置在其上部的情形 ίΐ側給與支持’如第4圖所示包翻雜222、下_軸224及底 上述固定板222是-種大約呈矩形的板件,它的上面置放燃料電池並 200924273 且從下方給予支持。 件定車由224是一種可以在上述固定板222的下藉與支持的棒 979 圖’上部尾端的脉面上職了職並且與上賴定板 姑二進行螺紋結合’下側尾端的外柱面上也形成了螺紋並且與底 扳226之上部進行螺紋結合。 222ΐΐ底/i226是—種可以針對結合在上部的下峡轴224與固定板 ϋΐ 定件’上述底板226被固定緊固在電爐觸的機殼110 二二/下固定轴224貫穿電爐⑽後以突出於外部的方式安裝並結 &amp;在其下側而受到支撐座等的支持。 上述加壓部240可以從上方對置放個定板222上的燃料電池施加一 疋莖力’如第3圖到第5圖所示包括加堡板2私與上加壓桿242。 願是一板件,位於固定板222之上部並根據後述的加壓 驅動4 260的動作而進行升降運動,同時按照預先設定之—定壓力對置 放在上述固定板222上的燃料電池施加壓力。 請參閱第4圖,上述上加廢桿242是一棒件,其上側結合後述的加塵 驅動部260,下側結合加壓板⑽,可以隨着加壓驅動部的動作而 升降並驅使加壓板244進行升降運動。 上述上加壓桿242可以和安裝部22〇的下固定軸224 —樣斑上述加遂 板施直接進行螺紋結合,通過萬向接頭進行連接較為適宜。 v. 第5圖與第6圖係本發明一較佳實施例的上加雖242與加壓板施 之結合構造圖。 如圖中所示,上述上加麼桿242之下側尾端經過圓形加工處理,其上 部之外柱面形成了環槽243。上述上加廢桿242之下側尾端部插入連接 件246之上部並結合。 請參閱第5圖’上述連接件246之上部中間位置形成了允許上述上加 壓桿242之下側尾端插入的圓形插槽247 ’該圓形槽的深度應該在上述 上加塵桿242插人時足卩完全容納上加堡桿如外柱面之環槽泌。上 述連接件246的下部直徑小於上部直徑,其外柱面之螺紋可以0和加屢板 244之上部進行螺紋結合。上述連接件施上部之外柱面具有多個螺絲 200924273 述豸絲孔248之位置對應於上加遂桿242插入連接件246的 插槽247時上加麼桿242的外柱面環槽243之位置。 的兒明具有上述結構的連接件246結合上加愿桿242與加壓板244 插把上加轉242的尾端部插入連接件246上部中間位置的 述上加麼桿242中經過圓形加工處理的尾端正面接 位於上祕桿242外柱面之環槽243也完全進入上述 插槽247内和把固定螺絲249緊固在位於上述連接件施的上側外柱 固定螺絲249將如第6圖所示貫穿連接件246並通 。249在安置到上加壓桿= 上述環槽243的内側撐捏指住,一般外力無法把上加 干*連接件246脫離分開。然後,使上述連接件246之下側與加 結合施之上部進行螺紋結合’從而完成上加壓桿242與加壓板2私、的 述安裝部220與加壓部240錢在高溫電爐娜内部,因此需 良好之材料。本發明之上述安裝部220與加_ 24〇使用 鎳基超口金㈣㈣材料製作。錄基超合金(inc〇nei)s一種以 =!5%的絡、6〜7%的鐵、2 5%的鈦及1%以下_ •猛·料耐^ „僅耐熱性良好,即使在9_以上的氧化氣流里也不會氧化: ,不會被3硫大氣浸潰。其延伸•拉伸強度·屈服點等各種性質也 〇〇C以下的溫度偏林變轉持良好的機械性能,也不會受到= 梅。邮_合姆娜爾賴爐觸_ 上述加遂部240隨着位於其上方的加麼驅動部細 :,從而對置放在固定板222上的燃料電池施加=:運 力。只要可以驅動上述上加壓桿242進行 二:;罐 ㈣可以使用例如空塵致動器,油屋致動器或 動=動 本發明之上述加壓驅動部施使Μ觀動器較為適宜。第動3機圖構及等第 11 200924273 4圓 較佳實施例的上_242與空屡致動器的連接圖。 如圖中所不,上述空舰動器包括汽紅26 丧圆 62接文來自外部的麵空氣 活塞土二上述/诚 ^上述汽虹262安裝在電爐⑽之上部復移 =機殼= 動::逑供應空氣而驅使上述活塞捍264進行往復移 圖)的開是峨述的控卿㈣電錢參考第7 方向進行升降移動'I的。活塞桿崩隨着電磁閥的開閉動作而沿着上下 可以進^結:在上述活塞桿264尾端的上加壓桿242 對置放在祕板244可以隨着上加_242的移動而 丁罝敌在固疋板222上的燃料電池施加屋力或解除該麼力。 作上 制部300可以控制上述本發明電化學特性評估裝置之整體動 量轉應估裝置—樣’可以控制評估時所需要的各種氣體之供應 加ϋ ί從連接到燃料電池的電極上之電負荷接收電量數據後 部該轉電池之f化學雛。本發卿估裝置的控制 i 140 據予貝先設定之溫度數據驅動電熱器120,以來自温度感測 : …爐_畴溫度信息為基礎控織顯12()的動作,可以使 :二内部溫度一直維持在預先設定之溫度。本發明評估裝置的控制 ^向燃料電池施加壓力而控制電磁閥,可以視需要而以汽缸加 =活塞(糊示)為中心驅使空氣向其_交替流人及流出,從而使 / ^桿264進行升降運動並對燃料電池施加壓力或解除該壓力。 則文對本發明電化學特性評估裝置的結構做了詳細說明。下面結合第 圖對本發明評估裝置的動作關係做進一步說明。第7圖係本發明評估 发置的結構之概略方塊圖。 首先’工作人員把作為評估對象之燃料電池放在電爐1〇〇 0部的固定 A 222上。通過控制面板對評估時所需要的電爐100内部溫度進行設 二’控制部300對電熱器12〇供電而使堪塔爾(Kan_發熱體加熱。溫 :感測Is 140實時檢測電爐1〇〇内部的溫度狀饋到控制部3〇〇,控制 4 300根據反饋信號而對電熱㈣12〇供應或切斷電源’使電爐⑽的内 12 200924273 部溫度始終維持在設定溫度。 通過控制面板下達要求對燃料電池施加勤的命令時,控 ^控制電磁職彻第7 _膨麟供應空氣,從而驅使活絲活 =下降’連接在桿綱尾端社加壓桿242料下降並驅使連接 在/、尾端的加壓板244 T降,然後對婦電池之上部表面施加愿力。 通過上财法軸了適合評储溫_魏_ 二3極為陰極供應氧氣後發電。上述陽極與陰極事先連 Ϊ2何 與氧進行反應後產生之電量進行測定與分析,然後評 估燃料電池之電化學特性與性能。 排放反物應ίΓΓ極排放出來的氣體被排放到外部,利用除水器彻把陽極 排1物貝中的水分除掉後排水,剩下的氫氣則由點火器獨燃燒。 雖…、'本發明已上述之較佳之實例詳細揭示,雜並刺以限 =,凡熟習此-發明者,在不脫離本發明之精神和^内 :ίΐ修改,因此本發明之保_#視作後㈣所界 ^ 【圖式簡單說明】 本發明燃觸池之電化學雖評倾置之前視圖; 明燃料電池之電化學特性評估裝置之側視圖; 弟3圖係本發明之電爐之具體結構側視圖; ^ 4圖係本發明之加麵麟聽構及結合關係圖; 2,本發明之加壓機構中加壓部之連接關係圖; 第7 Θ ^佳實關的上缚桿與域板之結合構造圖;以及 ^圖係本發籠料電池之電化學特性評储置雜·構之概略方塊 _電爐 112開閉式門 12〇電熱器 【主要元件符號說明】 11〇機殼 114手柄 122堪塔爾電線 200924273 124财火物 130隔熱層 140溫度感測器 150小輪 200加壓機構 222固定板 226底板 242上加壓桿 244加壓板 247插槽 249固定螺絲 262汽缸 300控制部 500點火器 220安裝部 224下固定軸 240加壓部 243環槽 246連接件 248螺絲孔 260加壓驅動部 264活塞桿 400除水器 14ϋ _ _ loading part 22G, _ 卩 thin and pressurized drive 4 26 - 〇. Fig. 4 is a view showing the specific structure of the above-described surface-added structure and the connection diagram. The body of the above-described pressurizing mechanism 200 shows the connection relationship of the pressurizing portion 24A. / The mounting portion 220 is provided with the support in the case where the fuel cell to be evaluated is placed on the upper side, as shown in Fig. 4, as shown in Fig. 4, the package 222, the lower shaft 224, and the bottom fixed plate 222 are Approximately rectangular plate with a fuel cell placed on top of it and 200924273 with support from below. The 224 is a type of rod 979 which can be borrowed and supported on the fixed plate 222, and is attached to the upper end of the ninth end of the rod and is threadedly coupled with the upper slab. A thread is also formed on the face and threadedly engaged with the upper portion of the bottom plate 226. 222 ΐΐ bottom / i226 is a type that can be attached to the upper lower gorge 224 and the fixed plate ϋΐ member 'the bottom plate 226 is fixed and fastened to the electric furnace, the casing 110 22 / the lower fixed shaft 224 penetrates the electric furnace (10) It is mounted on the outside and is supported on the lower side by a support base or the like. The pressurizing portion 240 may apply a click force to the fuel cell placed on the fixed plate 222 from above. As shown in Figs. 3 to 5, the upper and lower pressurizing rods 242 are included. It is desirable that a plate member is located above the fixed plate 222 and is moved up and down according to the action of the pressurizing drive 4 260 to be described later, while applying pressure to the fuel cell placed on the fixed plate 222 in accordance with a predetermined constant pressure. . Referring to Fig. 4, the upper scraping rod 242 is a rod, and the upper side is coupled with a dust driving unit 260, which will be described later, and the lower side is coupled with a pressure plate (10), which can be lifted and lowered in accordance with the operation of the pressurizing driving unit. The platen 244 performs a lifting movement. The upper pressing rod 242 may be directly threadedly coupled to the lower fixing shaft 224 of the mounting portion 22A, and is preferably connected by a universal joint. v. Fig. 5 and Fig. 6 are views showing a combined construction of a 242 and a pressure plate according to a preferred embodiment of the present invention. As shown in the figure, the lower end of the upper side of the upper rod 242 is subjected to a circular processing, and the outer cylindrical surface of the upper rod 243 is formed with a ring groove 243. The lower end portion of the upper side of the upper scraping rod 242 is inserted into the upper portion of the connecting member 246 and joined. Referring to Fig. 5, the upper portion of the upper portion of the connecting member 246 is formed with a circular slot 247 which allows the insertion of the lower end of the upper pressing rod 242. The depth of the circular groove should be above the upper dusting rod 242. When inserting a person, the foot is fully accommodated in the ring of the outer cylinder. The lower diameter of the connecting member 246 is smaller than the upper diameter, and the thread of the outer cylindrical surface can be threadedly coupled to the upper portion of the additional plate 244. The upper surface of the connecting member has a plurality of screws 200924273. The position of the wire opening 248 corresponds to the outer cylindrical ring groove 243 of the upper rod 242 when the upper clamping rod 242 is inserted into the slot 247 of the connecting member 246. position. The connecting member 246 having the above structure is combined with the upper rod 242 and the pressing plate 244, and the end portion of the upper rotating portion 242 is inserted into the upper portion of the upper portion of the connecting member 246. The front end of the treated end is connected to the annular groove 243 of the outer cylindrical surface of the upper cue 242 and also completely enters the above-mentioned slot 247 and fastens the fixing screw 249 to the upper outer column fixing screw 249 located at the above-mentioned connecting member. The through connector 246 is shown open. 249 is placed on the inner side of the upper pressing groove = the above-mentioned annular groove 243, and the external force cannot be detached from the upper connecting member 246. Then, the lower side of the connecting member 246 is screwed to the upper portion of the bonding and the upper portion of the pressing member 242 and the pressing plate 2, and the mounting portion 220 and the pressing portion 240 are inside the high temperature electric furnace. Therefore, good materials are required. The mounting portion 220 of the present invention is fabricated using a nickel-based super-gold (4) (four) material. Recording super alloy (inc〇nei) s a type of =! 5% of the network, 6 to 7% of iron, 25% of titanium and less than 1% _ • violent material resistance ^ „ only heat resistance, even in 9_ or more of the oxidizing gas stream will not oxidize: it will not be impregnated by the 3 sulphur atmosphere. Its properties such as elongation, tensile strength and yield point are also 温度C. And will not be subject to = Mei. Mail_合姆纳尔赖炉触_ The above-mentioned twisting portion 240 is fine with the driving portion located above it, so that the fuel cell placed on the fixed plate 222 is applied = : Capacity: as long as the upper pressing rod 242 can be driven to perform two:; the tank (4) can use, for example, an air dust actuator, the oil house actuator or the moving pressure driving portion of the present invention Appropriate. Fig. 3 is a connection diagram of the upper _242 and the air idling actuator of the preferred embodiment of the present invention. The air carrier includes a steam red 26 squad. 62 received text from the external surface air piston soil II above / Cheng ^ above the steam rainbow 262 installed in the upper part of the electric furnace (10) relocation = chassis = moving:: 逑 supply air to drive The above-mentioned piston 捍 264 is reciprocated (the reciprocating movement) is the control of the control (4) electric money refers to the 7th direction to move up and down 'I. The piston rod collapses along with the solenoid valve opening and closing action and can be connected up and down: The upper pressing rod 242 at the end of the above-mentioned piston rod 264 is opposed to the secret plate 244, and the fuel cell on the solid plate 222 can be used to exert the force or release the force as the upper _242 moves. The upper portion 300 can control the overall momentum conversion device of the electrochemical characteristic evaluation device of the present invention as described above - the 'supply of various gases required to control the evaluation ϋ ί from the electric load connected to the electrode of the fuel cell Receiving the power data, the control unit of the battery is controlled. The control unit 140 of the present evaluation device drives the electric heater 120 according to the temperature data set by the beijing, and controls the weaving from the temperature sensing: ... furnace_domain temperature information. The action of 12() can be such that: the internal temperature is maintained at a preset temperature. The control device of the present invention controls the solenoid valve by applying pressure to the fuel cell, and can add a piston to the cylinder as needed (paste )for The center drives the air to alternately flow and flow out, thereby causing the rod 264 to move up and down and apply pressure to the fuel cell or release the pressure. The structure of the electrochemical characteristic evaluation device of the present invention is described in detail. The figure further illustrates the action relationship of the evaluation apparatus of the present invention. Fig. 7 is a schematic block diagram of the structure of the evaluation apparatus of the present invention. First, the 'worker puts the fuel cell as the evaluation object in the fixed A of the electric furnace 1〇〇0 part. At 222, the internal temperature of the electric furnace 100 required for the evaluation is set by the control panel, and the control unit 300 supplies power to the electric heater 12 to heat the Kan_heating body. Temperature: Sensing Is 140 real-time detection of the temperature inside the electric furnace 1 馈 is fed to the control unit 3〇〇, and the control 4 300 supplies or cuts off the electric power to the electric heating (4) according to the feedback signal 'to make the electric furnace (10) inner 12 200924273 part temperature Always maintain the set temperature. When the control panel issues a request to apply a diligent command to the fuel cell, the control of the electromagnetic operation of the seventh _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The pressure plate 244 T connected to the / end is driven to drop, and then a force is applied to the upper surface of the battery. Through the upper axis of the financial system, it is suitable for the evaluation of the storage temperature _ Wei _ 2 3 extremely cathode supply of oxygen after power generation. The above-mentioned anode and cathode are connected and analyzed in advance, and the amount of electricity generated by the reaction with oxygen is measured and analyzed, and then the electrochemical characteristics and performance of the fuel cell are evaluated. The gas discharged from the exhaust gas is discharged to the outside, and the water in the anode of the anode is removed by the water remover, and the remaining hydrogen is burned by the igniter. Although the present invention has been described in detail in the above preferred embodiments, the invention is inconsistent with the inventor, without departing from the spirit and scope of the invention: As shown in the following (4) boundary [Simplified description of the drawing] The electrochemistry of the fuel cell of the present invention is evaluated as a front view; the side view of the electrochemical characteristic evaluation device of the fuel cell; the third figure is the specificity of the electric furnace of the present invention 4 is a side view of the structure of the present invention; 2, the connection diagram of the pressurizing part in the pressurizing mechanism of the present invention; 7th Θ ^The upper binding rod of Jiashiguan The structural diagram of the combination of the domain board; and the schematic diagram of the electrochemical characteristics of the battery of the present invention. The electric furnace is opened and closed. Handle 122 Cantal wire 200924273 124 Fortune 130 insulation layer 140 temperature sensor 150 small wheel 200 pressurizing mechanism 222 fixed plate 226 bottom plate 242 upper pressure rod 244 pressure plate 247 slot 249 fixed screw 262 cylinder 300 Control unit 500 igniter 220 mounting portion 224 lower fixed shaft 240 pressurizing section 243 ring groove 246 connector 248 screw hole 260 pressurizing drive section 264 piston rod 400 water eliminator 14

Claims (1)

200924273 十、申請專利範園: 1 .一種燃料電池之電化學特性評估裝置,包括. 電爐100,其_可以容納作為評賴象之 熱而提高燃料電池之週圍溫度; 加^構勘,可崎收容麵述则㈣ 設定之固定壓力;以及 书也她加f貝无 控制部300,控制所述評估裝置之整體動作。 2 ·如申請專利細第丨顿叙畴魏之統學雜 中,所述電爐100包括: f估裝置其 f 機=〇,其内部形成了可以容納作為評估對象之燃料電池的一定空 電2咖安裝在所述機殼110的内牆,接受外部電源併發熱; 隔熱層請,位於所述機殼110與電熱器120 產生的熱量流失到外部。 增止電熱S 3 ·=申請補顧第2補叙轉祕之電化 中,所述電熱器12〇是堪塔爾電線埋入式加熱器。博裝置其 4 · ^申請專利制第〗顿述之燃料電池之電化學雛評估裝置,盆 中,所述電爐100另外包括可以實時檢測電爐⑽ -iH HO ^ 14〇 1〇〇 J =反饋給所述控制部綱,所述控制部細ϋ = 5 ·=申請專纖圍第丨顧述之燃料電池之電化學概評 中,所述加壓機構200包括: 裝置八 安裝部220,從下方支持燃料電池; 加=部=,從上方對置_所述安裝部22q上的_電池施加壓 加壓驅動部260,驅使所述加壓部沿着上下方向進行升降運動。 15 200924273 6. 如申請摘伽第5項所述之鮮f電池之電化學特 中,所述安裝部220包括: ^ 固定板222,其上部直接置放燃料電池並且從下方給予支持; 下固定軸224 ’從下方支持所述固定板222 ;以及 底板226、,其上方結合在所述下固定轴224的尾端,其下方固定緊固 在所述電爐1〇〇底部,支持所述下固定轴224與固定板。 7. 如申請專利範圍第5項所述之燃料電池之電化學特性 苴 中,所述加壓部240包括: 〃 加=244,對於所述安裝部22〇戶斤支持的燃料電池之上部面施加塵 力,以及 上加壓# 242 ’上部尾端結合在所述加麼驅動部,下侧結合 在所述加驗244之上部’隨着加壓驅動部加的動作而升降並 驅使所述加壓板244進行升降運動。 8 .如申請專利範圍第5項所述之崎電池之電化學特性評 =,所述加_動部遍是由汽叙262與活塞桿264組成的蜂致動 9 .如申請專職圍第5項所述之畴電池之電化學概評 立 户I述ΐ裝部220與加麼部240使用錄基超合金(1職_料製; 11 10 ·=請專利細第7項所述之燃料電池之電化學特性娜裝乍其 中,所述上加壓才旱242與加壓板244通過萬向接頭連接。 • ^申請專利顧第7項所叙崎電池之電化學特性評估裝置,盆 二 與加壓板244連接起來,所述 =妍晨之上种間位置形成了允許所述上加壓桿如之下側尾 Μ #入的插槽247 ’其下部直徑小於上部直徑,其外柱面之螺紋可 :所述加麼板244之上部進行螺紋結合,其上部之外柱面且有多 =訊248 ’所述上加麗桿242之下側尾端做了圓形加工處理, t 了補243,所述上加壓桿242之下側尾端被 =斤述^件246的插槽247後把固定螺絲泌緊固在所述螺絲 孔248 ’滅所述固定螺絲249安置在上加壓桿242的環槽243内 16 200924273 部並對上加壓桿242施加壓力、防止脫離。 17200924273 X. Application for Patent Park: 1. A device for evaluating the electrochemical characteristics of a fuel cell, including an electric furnace 100, which can accommodate the heat of the fuel cell as a heat of evaluation; The accommodating face (4) sets the fixed pressure; and the book also adds the scaly no control unit 300 to control the overall operation of the evaluation device. 2. In the patent application, the electric furnace 100 includes: an evaluation device whose f machine = 〇, which internally forms a certain air-electric 2 coffee installation capable of accommodating the fuel cell as an evaluation object The inner wall of the casing 110 receives external power and generates heat; the heat insulation layer, the heat generated in the casing 110 and the electric heater 120 is lost to the outside. Increasing the electric heating S 3 ·= Applying to supplement the electrification of the second supplement, the electric heater 12 is a Kantar wire embedded heater. The device is equipped with an electrochemical device for evaluating a fuel cell of the fuel cell of the invention. In the basin, the electric furnace 100 additionally includes a real-time detection of the electric furnace (10) -iH HO ^ 14〇1〇〇J = feedback to In the control part, the control part is finely ϋ = 5 ·= In the electrochemical evaluation of the fuel cell of the application, the pressurizing mechanism 200 comprises: a device eight mounting part 220, which is supported from below The fuel cell; the addition portion =, the pressure pressurization driving portion 260 is applied to the battery on the mounting portion 22q from above, and the pressurizing portion is driven to move up and down in the vertical direction. 15 200924273 6. The application part 220 includes: ^ a fixing plate 222, the fuel cell is directly placed on the upper part thereof and is supported from below; The shaft 224' supports the fixing plate 222 from below; and a bottom plate 226, which is coupled to the rear end of the lower fixing shaft 224, and is fixedly fastened at the bottom of the electric furnace 1 to support the lower fixing Shaft 224 and fixed plate. 7. The electrochemical component of the fuel cell according to claim 5, wherein the pressurizing portion 240 comprises: 〃 plus = 244, and the upper surface of the fuel cell supported by the mounting portion 22 Applying a dust force, and an upper pressurization # 242 'the upper end is coupled to the driving portion, and the lower side is coupled to the upper portion of the inspection 244 to ascend and elevate with the action of the pressurizing drive portion The pressure plate 244 performs a lifting movement. 8. The electrochemical characteristics of the saki battery according to item 5 of the patent application scope is as follows: the _ moving portion is actuated by a bee consisting of a steam 262 and a piston rod 264. The electrochemical evaluation of the battery of the domain described in the above-mentioned item is described in the description of the fuel cell of the above-mentioned armored part 220 and the affixed part 240 using the recording base superalloy (1 job_material; 11 10 ·= please patent detail item 7) The electrochemical characteristics are contained therein, and the upper pressurization 242 and the pressurizing plate 244 are connected by a universal joint. • ^ The patent application of the electrochemical evaluation device of the Suzaki battery of the seventh item, the basin II and the addition The pressure plate 244 is connected, and the inter-species position on the upper side of the morning is formed to allow the upper pressing rod, such as the lower side tail Μ, to enter the slot 247' whose lower diameter is smaller than the upper diameter, and the outer cylindrical surface thereof The thread can be: the upper part of the plate 244 is threadedly coupled, and the upper part of the upper plate and the outer surface of the plate 244 are circumscribed by the circular end processing. 243, the lower end of the upper pressing rod 242 is tightened to the screw by the slot 247 of the 246. 248 'off the set screw 249 is disposed on the pressing rod 16 plus 200,924,273 and 243 within the annular groove 242 of plunger 242 is applied pressure and prevent detachment. 17
TW097144836A 2007-11-22 2008-11-20 Apparatus for evaluating electrochemical properties of fuel cell TW200924273A (en)

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KR101307872B1 (en) * 2011-04-14 2013-09-12 한국에너지기술연구원 Efficiency test device for fuel cell
CN107576913B (en) * 2017-08-16 2021-05-07 国网四川省电力公司电力科学研究院 Hydrogen load operation analysis method in active power distribution network
CN109420899B (en) * 2017-08-29 2024-06-21 上海铭寰新能源科技有限公司 Fuel cell press with movable tool
KR20190105775A (en) 2018-03-06 2019-09-18 주식회사 엘지화학 Apparatus for evaluating the performance of a fuel cell stack
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